NaBa3RuO6 crystallizes in the trigonal R-3c space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Ba(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Ru(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded to one Na(1), four equivalent Ba(1), and one Ru(1) atom to form a mixture of distorted corner, edge, and face-sharing OBa4NaRu octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
NaBa3RuO6 crystallizes in the trigonal R-3c space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.45 Å. Ba(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are a spread of Ba(1)-O(1) bond distances ranging from 2.74-2.92 Å. Ru(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Ru(1)-O(1) bond lengths are 2.02 Å. O(1) is bonded to one Na(1), four equivalent Ba(1), and one Ru(1) atom to form a mixture of distorted corner, edge, and face-sharing OBa4NaRu octahedra. The corner-sharing octahedral tilt angles range from 0-60°.