K2AgSb crystallizes in the orthorhombic Cmcm space group. K(1) is bonded in a 6-coordinate geometry to four equivalent Ag(1) and four equivalent Sb(1) atoms. Ag(1) is bonded to eight equivalent K(1), two equivalent Ag(1), and two equivalent Sb(1) atoms to form a mixture of distorted edge, corner, and face-sharing AgK8Ag2Sb2 cuboctahedra. Sb(1) is bonded in a 10-coordinate geometry to eight equivalent K(1) and two equivalent Ag(1) atoms.
K2AgSb crystallizes in the orthorhombic Cmcm space group. K(1) is bonded in a 6-coordinate geometry to four equivalent Ag(1) and four equivalent Sb(1) atoms. There are two shorter (3.77 Å) and two longer (3.99 Å) K(1)-Ag(1) bond lengths. There are a spread of K(1)-Sb(1) bond distances ranging from 3.58-3.69 Å. Ag(1) is bonded to eight equivalent K(1), two equivalent Ag(1), and two equivalent Sb(1) atoms to form a mixture of distorted edge, corner, and face-sharing AgK8Ag2Sb2 cuboctahedra. Both Ag(1)-Ag(1) bond lengths are 3.14 Å. Both Ag(1)-Sb(1) bond lengths are 2.70 Å. Sb(1) is bonded in a 10-coordinate geometry to eight equivalent K(1) and two equivalent Ag(1) atoms.