CdTlSb crystallizes in the orthorhombic Pnma space group. Cd(1) is bonded in a 4-coordinate geometry to two equivalent Tl(1) and four equivalent Sb(1) atoms. Tl(1) is bonded in a 5-coordinate geometry to two equivalent Cd(1) and three equivalent Sb(1) atoms. Sb(1) is bonded in a 5-coordinate geometry to four equivalent Cd(1) and three equivalent Tl(1) atoms.
CdTlSb crystallizes in the orthorhombic Pnma space group. Cd(1) is bonded in a 4-coordinate geometry to two equivalent Tl(1) and four equivalent Sb(1) atoms. Both Cd(1)-Tl(1) bond lengths are 3.43 Å. There are a spread of Cd(1)-Sb(1) bond distances ranging from 2.91-3.04 Å. Tl(1) is bonded in a 5-coordinate geometry to two equivalent Cd(1) and three equivalent Sb(1) atoms. There is one shorter (3.39 Å) and two longer (3.54 Å) Tl(1)-Sb(1) bond lengths. Sb(1) is bonded in a 5-coordinate geometry to four equivalent Cd(1) and three equivalent Tl(1) atoms.