ZrRhSb is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded to four equivalent Rh(1) and six equivalent Sb(1) atoms to form a mixture of distorted face and corner-sharing ZrSb6Rh4 tetrahedra. Rh(1) is bonded in a body-centered cubic geometry to four equivalent Zr(1) and four equivalent Sb(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1) and four equivalent Rh(1) atoms.
ZrRhSb is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded to four equivalent Rh(1) and six equivalent Sb(1) atoms to form a mixture of distorted face and corner-sharing ZrSb6Rh4 tetrahedra. All Zr(1)-Rh(1) bond lengths are 2.73 Å. All Zr(1)-Sb(1) bond lengths are 3.15 Å. Rh(1) is bonded in a body-centered cubic geometry to four equivalent Zr(1) and four equivalent Sb(1) atoms. All Rh(1)-Sb(1) bond lengths are 2.73 Å. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1) and four equivalent Rh(1) atoms.