CoRh2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Co(1)O4 tetrahedra and edges with six equivalent Rh(1)O6 octahedra. Co(1) is bonded to four equivalent O(1) atoms to form CoO4 tetrahedra that share corners with twelve equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. O(1) is bonded to three equivalent Rh(1) and one Co(1) atom to form a mixture of distorted corner and edge-sharing OCoRh3 trigonal pyramids.
CoRh2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Co(1)O4 tetrahedra and edges with six equivalent Rh(1)O6 octahedra. All Rh(1)-O(1) bond lengths are 2.05 Å. Co(1) is bonded to four equivalent O(1) atoms to form CoO4 tetrahedra that share corners with twelve equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Co(1)-O(1) bond lengths are 1.97 Å. O(1) is bonded to three equivalent Rh(1) and one Co(1) atom to form a mixture of distorted corner and edge-sharing OCoRh3 trigonal pyramids.