Cs2UO2Cl4 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1) and eight equivalent Cl(1) atoms. U(1) is bonded in a distorted octahedral geometry to two equivalent O(1) and four equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one Cs(1) and one U(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one U(1) atom.
Cs2UO2Cl4 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1) and eight equivalent Cl(1) atoms. The Cs(1)-O(1) bond length is 3.41 Å. There are a spread of Cs(1)-Cl(1) bond distances ranging from 3.64-3.77 Å. U(1) is bonded in a distorted octahedral geometry to two equivalent O(1) and four equivalent Cl(1) atoms. Both U(1)-O(1) bond lengths are 1.81 Å. All U(1)-Cl(1) bond lengths are 2.68 Å. O(1) is bonded in a single-bond geometry to one Cs(1) and one U(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one U(1) atom.