TiAsTe crystallizes in the orthorhombic Immm space group. Ti(1) is bonded in a 8-coordinate geometry to four equivalent As(1) and four equivalent Te(1) atoms. As(1) is bonded in a 6-coordinate geometry to four equivalent Ti(1) and two equivalent As(1) atoms. Te(1) is bonded to four equivalent Ti(1) atoms to form a mixture of distorted edge and corner-sharing TeTi4 tetrahedra.
TiAsTe crystallizes in the orthorhombic Immm space group. Ti(1) is bonded in a 8-coordinate geometry to four equivalent As(1) and four equivalent Te(1) atoms. All Ti(1)-As(1) bond lengths are 2.70 Å. There are two shorter (2.85 Å) and two longer (2.90 Å) Ti(1)-Te(1) bond lengths. As(1) is bonded in a 6-coordinate geometry to four equivalent Ti(1) and two equivalent As(1) atoms. There is one shorter (2.59 Å) and one longer (2.68 Å) As(1)-As(1) bond length. Te(1) is bonded to four equivalent Ti(1) atoms to form a mixture of distorted edge and corner-sharing TeTi4 tetrahedra.