RbP(OF)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 12-coordinate geometry to six equivalent O(1), two equivalent F(2), and four equivalent F(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to four equivalent Rb(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one P(1) atom.
RbP(OF)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 12-coordinate geometry to six equivalent O(1), two equivalent F(2), and four equivalent F(1) atoms. There are a spread of Rb(1)-O(1) bond distances ranging from 2.88-3.10 Å. There is one shorter (3.00 Å) and one longer (3.34 Å) Rb(1)-F(2) bond length. There are two shorter (3.25 Å) and two longer (3.46 Å) Rb(1)-F(1) bond lengths. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. Both P(1)-O(1) bond lengths are 1.47 Å. The P(1)-F(1) bond length is 1.58 Å. The P(1)-F(2) bond length is 1.58 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to four equivalent Rb(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to two equivalent Rb(1) and one P(1) atom.