(NH3OH)3ScF6 crystallizes in the trigonal R3c space group. Sc(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. N(1) is bonded in a tetrahedral geometry to one H(2), one H(3), one H(4), and one O(1) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one F(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) and one F(2) atom. O(1) is bonded in a water-like geometry to one N(1) and one H(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Sc(1) and one H(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Sc(1), one H(2), and one H(4) atom.
(NH3OH)3ScF6 crystallizes in the trigonal R3c space group. Sc(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. All Sc(1)-F(1) bond lengths are 2.05 Å. All Sc(1)-F(2) bond lengths are 2.04 Å. N(1) is bonded in a tetrahedral geometry to one H(2), one H(3), one H(4), and one O(1) atom. The N(1)-H(2) bond length is 1.05 Å. The N(1)-H(3) bond length is 1.04 Å. The N(1)-H(4) bond length is 1.05 Å. The N(1)-O(1) bond length is 1.42 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one F(1) atom. The H(1)-O(1) bond length is 1.03 Å. The H(1)-F(1) bond length is 1.46 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one F(2) atom. The H(2)-F(2) bond length is 1.71 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) and one F(2) atom. The H(4)-F(2) bond length is 1.63 Å. O(1) is bonded in a water-like geometry to one N(1) and one H(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Sc(1) and one H(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Sc(1), one H(2), and one H(4) atom.