Mg(TiO2)4 is beta Vanadium nitride-derived structured and crystallizes in the tetragonal I4/m space group. The structure consists of two 7439-95-4 atoms inside a TiO2 framework. In the TiO2 framework, Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to three equivalent Ti(1) atoms.
Mg(TiO2)4 is beta Vanadium nitride-derived structured and crystallizes in the tetragonal I4/m space group. The structure consists of two 7439-95-4 atoms inside a TiO2 framework. In the TiO2 framework, Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 49°. There is one shorter (1.95 Å) and two longer (1.98 Å) Ti(1)-O(1) bond lengths. There are two shorter (2.00 Å) and one longer (2.05 Å) Ti(1)-O(2) bond length. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to three equivalent Ti(1) atoms.