GeBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight germanium tetrabromide molecules. Ge(1) is bonded in a tetrahedral geometry to one Br(2) and three equivalent Br(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ge(1) atom.
GeBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight germanium tetrabromide molecules. Ge(1) is bonded in a tetrahedral geometry to one Br(2) and three equivalent Br(1) atoms. The Ge(1)-Br(2) bond length is 2.28 Å. All Ge(1)-Br(1) bond lengths are 2.29 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ge(1) atom.