LaMoFeZnO6 crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(12), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form MoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra, corners with two equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-47°. In the second Mo site, Mo(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(8) atom to form MoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, corners with two equivalent Zn(2)O4 trigonal pyramids, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-47°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(12), one O(4), one O(5), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, corners with two equivalent Zn(2)O4 trigonal pyramids, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-47°. In the second Fe site, Fe(2) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra, corners with four equivalent Mo(2)O6 octahedra, corners with two equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-47°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), one O(6), and one O(8) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra,  an edgeedge with one Mo(2)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-69°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-69°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one La(2), one Mo(2), one Fe(1), and one Zn(2) atom to form a mixture of corner and edge-sharing OLaZnFeMo trigonal pyramids. In the second O site, O(2) is bonded to one La(1), one Mo(1), one Fe(2), and one Zn(1) atom to form a mixture of corner and edge-sharing OLaZnFeMo trigonal pyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(2), one Fe(2), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(1), one Fe(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(1), one Fe(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(2), one Fe(2), and one Zn(1) atom. In the seventh O site, O(7) is bonded to one La(2), one Mo(1), one Fe(2), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OLaZnFeMo trigonal pyramids. In the eighth O site, O(8) is bonded to one La(1), one Mo(2), one Fe(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OLaZnFeMo trigonal pyramids. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one La(2), one Mo(1), and one Fe(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one La(1), one Mo(2), and one Fe(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(2), one Mo(2), and one Fe(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(1), one Mo(1), and one Fe(1) atom.
LaMoFeZnO6 crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. The La(1)-O(10) bond length is 2.34 Å. The La(1)-O(12) bond length is 2.49 Å. The La(1)-O(2) bond length is 2.53 Å. The La(1)-O(3) bond length is 2.75 Å. The La(1)-O(4) bond length is 2.60 Å. The La(1)-O(5) bond length is 2.74 Å. The La(1)-O(6) bond length is 2.63 Å. The La(1)-O(8) bond length is 2.40 Å. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. The La(2)-O(1) bond length is 2.52 Å. The La(2)-O(11) bond length is 2.49 Å. The La(2)-O(3) bond length is 2.59 Å. The La(2)-O(4) bond length is 2.76 Å. The La(2)-O(5) bond length is 2.64 Å. The La(2)-O(6) bond length is 2.73 Å. The La(2)-O(7) bond length is 2.41 Å. The La(2)-O(9) bond length is 2.34 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(12), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form MoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra, corners with two equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-47°. The Mo(1)-O(12) bond length is 1.83 Å. The Mo(1)-O(2) bond length is 2.07 Å. The Mo(1)-O(4) bond length is 2.12 Å. The Mo(1)-O(5) bond length is 2.17 Å. The Mo(1)-O(7) bond length is 2.02 Å. The Mo(1)-O(9) bond length is 1.96 Å. In the second Mo site, Mo(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(8) atom to form MoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra, corners with four equivalent Fe(2)O6 octahedra, corners with two equivalent Zn(2)O4 trigonal pyramids, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-47°. The Mo(2)-O(1) bond length is 2.07 Å. The Mo(2)-O(10) bond length is 1.96 Å. The Mo(2)-O(11) bond length is 1.83 Å. The Mo(2)-O(3) bond length is 2.12 Å. The Mo(2)-O(6) bond length is 2.18 Å. The Mo(2)-O(8) bond length is 2.02 Å. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(12), one O(4), one O(5), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Mo(2)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, corners with two equivalent Zn(2)O4 trigonal pyramids, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-47°. The Fe(1)-O(1) bond length is 2.11 Å. The Fe(1)-O(12) bond length is 2.18 Å. The Fe(1)-O(4) bond length is 2.39 Å. The Fe(1)-O(5) bond length is 2.30 Å. The Fe(1)-O(8) bond length is 2.07 Å. The Fe(1)-O(9) bond length is 2.09 Å. In the second Fe site, Fe(2) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra, corners with four equivalent Mo(2)O6 octahedra, corners with two equivalent Zn(1)O4 trigonal pyramids, and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-47°. The Fe(2)-O(10) bond length is 2.10 Å. The Fe(2)-O(11) bond length is 2.18 Å. The Fe(2)-O(2) bond length is 2.11 Å. The Fe(2)-O(3) bond length is 2.39 Å. The Fe(2)-O(6) bond length is 2.29 Å. The Fe(2)-O(7) bond length is 2.06 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), one O(6), and one O(8) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra,  an edgeedge with one Mo(2)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-69°. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 1.98 Å. The Zn(1)-O(6) bond length is 2.01 Å. The Zn(1)-O(8) bond length is 2.30 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-69°. The Zn(2)-O(1) bond length is 1.96 Å. The Zn(2)-O(3) bond length is 1.98 Å. The Zn(2)-O(5) bond length is 2.01 Å. The Zn(2)-O(7) bond length is 2.31 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one La(2), one Mo(2), one Fe(1), and one Zn(2) atom to form a mixture of corner and edge-sharing OLaZnFeMo trigonal pyramids. In the second O site, O(2) is bonded to one La(1), one Mo(1), one Fe(2), and one Zn(1) atom to form a mixture of corner and edge-sharing OLaZnFeMo trigonal pyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(2), one Fe(2), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(1), one Fe(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(1), one Fe(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Mo(2), one Fe(2), and one Zn(1) atom. In the seventh O site, O(7) is bonded to one La(2), one Mo(1), one Fe(2), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OLaZnFeMo trigonal pyramids. In the eighth O site, O(8) is bonded to one La(1), one Mo(2), one Fe(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OLaZnFeMo trigonal pyramids. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one La(2), one Mo(1), and one Fe(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one La(1), one Mo(2), and one Fe(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(2), one Mo(2), and one Fe(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(1), one Mo(1), and one Fe(1) atom.