TeS7Br2 is Indium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four TeS7Br2 clusters. Te(1) is bonded in a see-saw-like geometry to two equivalent S(4), one Br(1), and one Br(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to two equivalent S(2) atoms. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one Te(1) and one S(3) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom.
TeS7Br2 is Indium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four TeS7Br2 clusters. Te(1) is bonded in a see-saw-like geometry to two equivalent S(4), one Br(1), and one Br(2) atom. Both Te(1)-S(4) bond lengths are 2.53 Å. The Te(1)-Br(1) bond length is 2.70 Å. The Te(1)-Br(2) bond length is 2.60 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to two equivalent S(2) atoms. Both S(1)-S(2) bond lengths are 2.06 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. The S(2)-S(3) bond length is 2.09 Å. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. The S(3)-S(4) bond length is 2.01 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one Te(1) and one S(3) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom.