MnTeO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Mn(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one Te(1) atom.
MnTeO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. Both Mn(1)-O(1) bond lengths are 2.22 Å. There are two shorter (2.22 Å) and two longer (2.33 Å) Mn(1)-O(2) bond lengths. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1) and two equivalent O(2) atoms. The Te(1)-O(1) bond length is 1.93 Å. Both Te(1)-O(2) bond lengths are 1.95 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Mn(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one Te(1) atom.