PN5S3F2 is Indium-like structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of nine PN5S3F2 clusters. P(1) is bonded in a tetrahedral geometry to two equivalent N(1), one F(1), and one F(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to two equivalent N(3) atoms. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one N(3) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.
PN5S3F2 is Indium-like structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of nine PN5S3F2 clusters. P(1) is bonded in a tetrahedral geometry to two equivalent N(1), one F(1), and one F(2) atom. Both P(1)-N(1) bond lengths are 1.59 Å. The P(1)-F(1) bond length is 1.56 Å. The P(1)-F(2) bond length is 1.57 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(2) atom. The N(1)-S(2) bond length is 1.62 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. Both N(2)-S(2) bond lengths are 1.63 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(3)-S(1) bond length is 1.56 Å. The N(3)-S(2) bond length is 1.74 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to two equivalent N(3) atoms. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one N(3) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.