DyPdGe crystallizes in the orthorhombic Imm2 space group. There are four inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 12-coordinate geometry to two equivalent Pd(1), four equivalent Pd(3), two equivalent Ge(1), and four equivalent Ge(3) atoms. In the second Dy site, Dy(2) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(2), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. In the third Dy site, Dy(3) is bonded in a 12-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), two equivalent Ge(3), and four equivalent Ge(1) atoms. In the fourth Dy site, Dy(4) is bonded in a 12-coordinate geometry to one Pd(1), two equivalent Pd(3), three equivalent Pd(2), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to one Dy(1), one Dy(4), two equivalent Dy(2), two equivalent Dy(3), one Ge(1), one Ge(2), and two equivalent Ge(3) atoms. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to three equivalent Dy(2), three equivalent Dy(4), one Ge(3), and three equivalent Ge(2) atoms. In the third Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Dy(2), one Dy(3), two equivalent Dy(1), two equivalent Dy(4), one Pd(3), one Ge(3), and two equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Dy(1), one Dy(4), two equivalent Dy(2), two equivalent Dy(3), one Pd(1), two equivalent Pd(3), and one Ge(1) atom. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Dy(2), three equivalent Dy(4), one Pd(1), and three equivalent Pd(2) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Dy(2), one Dy(3), two equivalent Dy(1), two equivalent Dy(4), one Pd(2), one Pd(3), and two equivalent Pd(1) atoms.
DyPdGe crystallizes in the orthorhombic Imm2 space group. There are four inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 12-coordinate geometry to two equivalent Pd(1), four equivalent Pd(3), two equivalent Ge(1), and four equivalent Ge(3) atoms. Both Dy(1)-Pd(1) bond lengths are 3.09 Å. All Dy(1)-Pd(3) bond lengths are 3.08 Å. Both Dy(1)-Ge(1) bond lengths are 3.15 Å. All Dy(1)-Ge(3) bond lengths are 3.07 Å. In the second Dy site, Dy(2) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(2), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. The Dy(2)-Pd(3) bond length is 2.91 Å. Both Dy(2)-Pd(1) bond lengths are 2.98 Å. There is one shorter (3.12 Å) and two longer (3.16 Å) Dy(2)-Pd(2) bond lengths. The Dy(2)-Ge(3) bond length is 3.23 Å. Both Dy(2)-Ge(1) bond lengths are 3.16 Å. There are two shorter (2.98 Å) and one longer (3.08 Å) Dy(2)-Ge(2) bond length. In the third Dy site, Dy(3) is bonded in a 12-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), two equivalent Ge(3), and four equivalent Ge(1) atoms. Both Dy(3)-Pd(3) bond lengths are 3.18 Å. All Dy(3)-Pd(1) bond lengths are 3.21 Å. Both Dy(3)-Ge(3) bond lengths are 2.97 Å. All Dy(3)-Ge(1) bond lengths are 2.97 Å. In the fourth Dy site, Dy(4) is bonded in a 12-coordinate geometry to one Pd(1), two equivalent Pd(3), three equivalent Pd(2), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. The Dy(4)-Pd(1) bond length is 3.07 Å. Both Dy(4)-Pd(3) bond lengths are 3.11 Å. There is one shorter (3.00 Å) and two longer (3.01 Å) Dy(4)-Pd(2) bond lengths. The Dy(4)-Ge(1) bond length is 3.14 Å. Both Dy(4)-Ge(3) bond lengths are 3.04 Å. There are two shorter (3.13 Å) and one longer (3.16 Å) Dy(4)-Ge(2) bond length. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to one Dy(1), one Dy(4), two equivalent Dy(2), two equivalent Dy(3), one Ge(1), one Ge(2), and two equivalent Ge(3) atoms. The Pd(1)-Ge(1) bond length is 2.58 Å. The Pd(1)-Ge(2) bond length is 2.69 Å. Both Pd(1)-Ge(3) bond lengths are 2.53 Å. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to three equivalent Dy(2), three equivalent Dy(4), one Ge(3), and three equivalent Ge(2) atoms. The Pd(2)-Ge(3) bond length is 2.91 Å. There are two shorter (2.52 Å) and one longer (2.56 Å) Pd(2)-Ge(2) bond length. In the third Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Dy(2), one Dy(3), two equivalent Dy(1), two equivalent Dy(4), one Pd(3), one Ge(3), and two equivalent Ge(1) atoms. The Pd(3)-Pd(3) bond length is 3.03 Å. The Pd(3)-Ge(3) bond length is 2.53 Å. Both Pd(3)-Ge(1) bond lengths are 2.52 Å. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Dy(1), one Dy(4), two equivalent Dy(2), two equivalent Dy(3), one Pd(1), two equivalent Pd(3), and one Ge(1) atom. The Ge(1)-Ge(1) bond length is 2.70 Å. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Dy(2), three equivalent Dy(4), one Pd(1), and three equivalent Pd(2) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Dy(2), one Dy(3), two equivalent Dy(1), two equivalent Dy(4), one Pd(2), one Pd(3), and two equivalent Pd(1) atoms.