Ti5AgSn3 crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Ag(1) and five equivalent Sn(1) atoms. In the second Ti site, Ti(2) is bonded in a 8-coordinate geometry to two equivalent Ti(2) and six equivalent Sn(1) atoms. Ag(1) is bonded in a 6-coordinate geometry to six equivalent Ti(1) atoms. Sn(1) is bonded in a 9-coordinate geometry to four equivalent Ti(2) and five equivalent Ti(1) atoms.
Ti5AgSn3 crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Ag(1) and five equivalent Sn(1) atoms. Both Ti(1)-Ag(1) bond lengths are 2.79 Å. There are a spread of Ti(1)-Sn(1) bond distances ranging from 2.78-2.90 Å. In the second Ti site, Ti(2) is bonded in a 8-coordinate geometry to two equivalent Ti(2) and six equivalent Sn(1) atoms. Both Ti(2)-Ti(2) bond lengths are 2.82 Å. All Ti(2)-Sn(1) bond lengths are 2.97 Å. Ag(1) is bonded in a 6-coordinate geometry to six equivalent Ti(1) atoms. Sn(1) is bonded in a 9-coordinate geometry to four equivalent Ti(2) and five equivalent Ti(1) atoms.