Pd(NS)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pd(NS)4 clusters. Pd(1) is bonded in a square co-planar geometry to one N(2), one N(3), one S(1), and one S(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(3) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one N(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one N(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom.
Pd(NS)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pd(NS)4 clusters. Pd(1) is bonded in a square co-planar geometry to one N(2), one N(3), one S(1), and one S(2) atom. The Pd(1)-N(2) bond length is 2.01 Å. The Pd(1)-N(3) bond length is 2.01 Å. The Pd(1)-S(1) bond length is 2.25 Å. The Pd(1)-S(2) bond length is 2.24 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. The N(4)-S(1) bond length is 1.62 Å. The N(4)-S(4) bond length is 1.62 Å. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(1)-S(2) bond length is 1.63 Å. The N(1)-S(3) bond length is 1.62 Å. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(3) atom. The N(2)-S(3) bond length is 1.54 Å. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(4) atom. The N(3)-S(4) bond length is 1.54 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one N(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one N(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom.