U7V5Ag3O35 crystallizes in the monoclinic Pm space group. There are seven inequivalent U sites. In the first U site, U(1) is bonded to one O(12), one O(14), one O(27), two equivalent O(1), and two equivalent O(10) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(6)O6 octahedra, corners with two equivalent V(4)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. The corner-sharing octahedra are not tilted. In the second U site, U(2) is bonded to one O(11), one O(2), one O(28), one O(3), one O(9), and two equivalent O(13) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(7)O6 octahedra, corners with two equivalent V(3)O4 tetrahedra, and  an edgeedge with one V(2)O4 tetrahedra. The corner-sharing octahedra are not tilted. In the third U site, U(3) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(26), one O(3), one O(9), and two equivalent O(4) atoms. In the fourth U site, U(4) is bonded in a 7-coordinate geometry to one O(26), one O(5), one O(6), two equivalent O(1), and two equivalent O(10) atoms. In the fifth U site, U(5) is bonded to one O(21), one O(22), one O(23), one O(25), and two equivalent O(24) atoms to form UO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra and corners with two equivalent V(2)O4 tetrahedra. In the sixth U site, U(6) is bonded to one O(16), one O(17), one O(27), one O(7), and two equivalent O(18) atoms to form UO6 octahedra that share  a cornercorner with one U(1)O7 pentagonal bipyramid, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. In the seventh U site, U(7) is bonded to one O(28); one O(8); two equivalent O(15); and two equivalent O(19,20) atoms to form UO6 octahedra that share  a cornercorner with one U(2)O7 pentagonal bipyramid, corners with two equivalent V(4)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(23), one O(25), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 34°. In the second V site, V(2) is bonded to one O(2), one O(3), and two equivalent O(24) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(2)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 36°. In the third V site, V(3) is bonded to one O(11), one O(9), and two equivalent O(18) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(2)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the fourth V site, V(4) is bonded to two equivalent O(10) and two equivalent O(19,20) atoms to form VO4 tetrahedra that share corners with two equivalent U(7)O6 octahedra and corners with two equivalent U(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the fifth V site, V(5) is bonded to one O(16), one O(17), and two equivalent O(15) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(21), one O(5), one O(6), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(22), one O(7), and two equivalent O(4) atoms. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one U(3) and one Ag(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one U(6) and one Ag(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one U(7) and two equivalent Ag(1) atoms. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one U(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one U(2) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one U(1) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one U(7) and one V(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one U(6) and one V(3) atom. In the nineteenth O site, O(19,20) is bonded in a bent 150 degrees geometry to one U(7) and one V(4) atom. In the twentieth O site, O(21) is bonded in a trigonal planar geometry to one U(5) and two equivalent Ag(1) atoms. In the twenty-first O site, O(22) is bonded in a bent 120 degrees geometry to one U(5) and one Ag(2) atom. In the twenty-second O site, O(23) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-third O site, O(24) is bonded in a bent 150 degrees geometry to one U(5) and one V(2) atom. In the twenty-fourth O site, O(25) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-fifth O site, O(26) is bonded in a linear geometry to one U(3) and one U(4) atom. In the twenty-sixth O site, O(27) is bonded in a linear geometry to one U(1) and one U(6) atom. In the twenty-seventh O site, O(28) is bonded in a linear geometry to one U(2) and one U(7) atom.
U7V5Ag3O35 crystallizes in the monoclinic Pm space group. There are seven inequivalent U sites. In the first U site, U(1) is bonded to one O(12), one O(14), one O(27), two equivalent O(1), and two equivalent O(10) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(6)O6 octahedra, corners with two equivalent V(4)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. The corner-sharing octahedra are not tilted. The U(1)-O(12) bond length is 1.82 Å. The U(1)-O(14) bond length is 1.82 Å. The U(1)-O(27) bond length is 2.36 Å. Both U(1)-O(1) bond lengths are 2.50 Å. Both U(1)-O(10) bond lengths are 2.35 Å. In the second U site, U(2) is bonded to one O(11), one O(2), one O(28), one O(3), one O(9), and two equivalent O(13) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(7)O6 octahedra, corners with two equivalent V(3)O4 tetrahedra, and  an edgeedge with one V(2)O4 tetrahedra. The corner-sharing octahedra are not tilted. The U(2)-O(11) bond length is 2.36 Å. The U(2)-O(2) bond length is 2.51 Å. The U(2)-O(28) bond length is 2.39 Å. The U(2)-O(3) bond length is 2.50 Å. The U(2)-O(9) bond length is 2.37 Å. Both U(2)-O(13) bond lengths are 1.80 Å. In the third U site, U(3) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(26), one O(3), one O(9), and two equivalent O(4) atoms. The U(3)-O(11) bond length is 2.60 Å. The U(3)-O(2) bond length is 2.38 Å. The U(3)-O(26) bond length is 2.20 Å. The U(3)-O(3) bond length is 2.38 Å. The U(3)-O(9) bond length is 2.60 Å. Both U(3)-O(4) bond lengths are 1.82 Å. In the fourth U site, U(4) is bonded in a 7-coordinate geometry to one O(26), one O(5), one O(6), two equivalent O(1), and two equivalent O(10) atoms. The U(4)-O(26) bond length is 2.11 Å. The U(4)-O(5) bond length is 1.85 Å. The U(4)-O(6) bond length is 1.85 Å. Both U(4)-O(1) bond lengths are 2.37 Å. Both U(4)-O(10) bond lengths are 2.63 Å. In the fifth U site, U(5) is bonded to one O(21), one O(22), one O(23), one O(25), and two equivalent O(24) atoms to form UO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra and corners with two equivalent V(2)O4 tetrahedra. The U(5)-O(21) bond length is 1.91 Å. The U(5)-O(22) bond length is 1.84 Å. The U(5)-O(23) bond length is 2.24 Å. The U(5)-O(25) bond length is 2.22 Å. Both U(5)-O(24) bond lengths are 2.22 Å. In the sixth U site, U(6) is bonded to one O(16), one O(17), one O(27), one O(7), and two equivalent O(18) atoms to form UO6 octahedra that share  a cornercorner with one U(1)O7 pentagonal bipyramid, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. The U(6)-O(16) bond length is 2.23 Å. The U(6)-O(17) bond length is 2.23 Å. The U(6)-O(27) bond length is 1.95 Å. The U(6)-O(7) bond length is 1.85 Å. Both U(6)-O(18) bond lengths are 2.21 Å. In the seventh U site, U(7) is bonded to one O(28); one O(8); two equivalent O(15); and two equivalent O(19,20) atoms to form UO6 octahedra that share  a cornercorner with one U(2)O7 pentagonal bipyramid, corners with two equivalent V(4)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. The U(7)-O(28) bond length is 1.93 Å. The U(7)-O(8) bond length is 1.90 Å. Both U(7)-O(15) bond lengths are 2.20 Å. Both U(7)-O(19,20) bond lengths are 2.22 Å. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(23), one O(25), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 34°. The V(1)-O(23) bond length is 1.73 Å. The V(1)-O(25) bond length is 1.72 Å. Both V(1)-O(1) bond lengths are 1.75 Å. In the second V site, V(2) is bonded to one O(2), one O(3), and two equivalent O(24) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(2)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 36°. The V(2)-O(2) bond length is 1.74 Å. The V(2)-O(3) bond length is 1.74 Å. Both V(2)-O(24) bond lengths are 1.73 Å. In the third V site, V(3) is bonded to one O(11), one O(9), and two equivalent O(18) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(2)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. The V(3)-O(11) bond length is 1.74 Å. The V(3)-O(9) bond length is 1.74 Å. Both V(3)-O(18) bond lengths are 1.74 Å. In the fourth V site, V(4) is bonded to two equivalent O(10) and two equivalent O(19,20) atoms to form VO4 tetrahedra that share corners with two equivalent U(7)O6 octahedra and corners with two equivalent U(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. Both V(4)-O(10) bond lengths are 1.74 Å. Both V(4)-O(19,20) bond lengths are 1.74 Å. In the fifth V site, V(5) is bonded to one O(16), one O(17), and two equivalent O(15) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. The V(5)-O(16) bond length is 1.73 Å. The V(5)-O(17) bond length is 1.74 Å. Both V(5)-O(15) bond lengths are 1.76 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(21), one O(5), one O(6), and one O(8) atom. The Ag(1)-O(21) bond length is 2.31 Å. The Ag(1)-O(5) bond length is 2.65 Å. The Ag(1)-O(6) bond length is 2.65 Å. The Ag(1)-O(8) bond length is 2.32 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(22), one O(7), and two equivalent O(4) atoms. The Ag(2)-O(22) bond length is 2.31 Å. The Ag(2)-O(7) bond length is 2.30 Å. Both Ag(2)-O(4) bond lengths are 2.64 Å. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one U(3) and one Ag(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one U(6) and one Ag(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one U(7) and two equivalent Ag(1) atoms. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one U(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one U(2) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one U(1) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one U(7) and one V(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one U(6) and one V(3) atom. In the nineteenth O site, O(19,20) is bonded in a bent 150 degrees geometry to one U(7) and one V(4) atom. In the twentieth O site, O(21) is bonded in a trigonal planar geometry to one U(5) and two equivalent Ag(1) atoms. In the twenty-first O site, O(22) is bonded in a bent 120 degrees geometry to one U(5) and one Ag(2) atom. In the twenty-second O site, O(23) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-third O site, O(24) is bonded in a bent 150 degrees geometry to one U(5) and one V(2) atom. In the twenty-fourth O site, O(25) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-fifth O site, O(26) is bonded in a linear geometry to one U(3) and one U(4) atom. In the twenty-sixth O site, O(27) is bonded in a linear geometry to one U(1) and one U(6) atom. In the twenty-seventh O site, O(28) is bonded in a linear geometry to one U(2) and one U(7) atom.