B4COCl6 is Tungsten structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three B4COCl6 clusters. There are two inequivalent B sites. In the first B site, B(1) is bonded in a distorted trigonal planar geometry to one B(2), one Cl(1), and one Cl(2) atom. In the second B site, B(2) is bonded in a distorted single-bond geometry to three equivalent B(1) and one C(1) atom. C(1) is bonded in a linear geometry to one B(2) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom.
B4COCl6 is Tungsten structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three B4COCl6 clusters. There are two inequivalent B sites. In the first B site, B(1) is bonded in a distorted trigonal planar geometry to one B(2), one Cl(1), and one Cl(2) atom. The B(1)-B(2) bond length is 1.72 Å. The B(1)-Cl(1) bond length is 1.76 Å. The B(1)-Cl(2) bond length is 1.75 Å. In the second B site, B(2) is bonded in a distorted single-bond geometry to three equivalent B(1) and one C(1) atom. The B(2)-C(1) bond length is 1.50 Å. C(1) is bonded in a linear geometry to one B(2) and one O(1) atom. The C(1)-O(1) bond length is 1.15 Å. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom.