AsCl3 is Ammonia-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four arsenic trichloride molecules. As(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom.
AsCl3 is Ammonia-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four arsenic trichloride molecules. As(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. The As(1)-Cl(1) bond length is 2.19 Å. The As(1)-Cl(2) bond length is 2.19 Å. The As(1)-Cl(3) bond length is 2.20 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom.