TiCuGe crystallizes in the orthorhombic Cmcm space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Cu(1) and five equivalent Ge(1) atoms. Cu(1) is bonded to six equivalent Ti(1), two equivalent Cu(1), and four equivalent Ge(1) atoms to form a mixture of distorted face, corner, and edge-sharing CuTi6Cu2Ge4 cuboctahedra. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Cu(1) atoms.
TiCuGe crystallizes in the orthorhombic Cmcm space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Cu(1) and five equivalent Ge(1) atoms. There are four shorter (2.93 Å) and two longer (3.03 Å) Ti(1)-Cu(1) bond lengths. There are a spread of Ti(1)-Ge(1) bond distances ranging from 2.58-2.81 Å. Cu(1) is bonded to six equivalent Ti(1), two equivalent Cu(1), and four equivalent Ge(1) atoms to form a mixture of distorted face, corner, and edge-sharing CuTi6Cu2Ge4 cuboctahedra. Both Cu(1)-Cu(1) bond lengths are 2.57 Å. All Cu(1)-Ge(1) bond lengths are 2.48 Å. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Cu(1) atoms.