Na3Rh crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a distorted see-saw-like geometry to four equivalent Rh(1) atoms. Rh(1) is bonded to twelve equivalent Na(1) atoms to form a mixture of corner and face-sharing RhNa12 cuboctahedra.
Na3Rh crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a distorted see-saw-like geometry to four equivalent Rh(1) atoms. There are two shorter (3.12 Å) and two longer (3.18 Å) Na(1)-Rh(1) bond lengths. Rh(1) is bonded to twelve equivalent Na(1) atoms to form a mixture of corner and face-sharing RhNa12 cuboctahedra.