Sr2V3Bi3O14 crystallizes in the triclinic P-1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(14), one O(3), one O(4), one O(7), and two equivalent O(10) atoms. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(12), one O(13), one O(2), one O(9), two equivalent O(6), and two equivalent O(8) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(4), and one O(7) atom. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(12), one O(2), one O(6), and one O(9) atom. In the third V site, V(3) is bonded in a tetrahedral geometry to one O(10), one O(13), one O(14), and one O(5) atom. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(7), one O(8), and one O(9) atom. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to one O(12), one O(13), one O(14), one O(3), one O(6), and one O(8) atom. In the third Bi site, Bi(3) is bonded in a 5-coordinate geometry to one O(11), one O(2), one O(3), one O(4), and one O(5) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sr(2), one V(2), and one Bi(3) atom. In the third O site, O(3) is bonded to one Sr(1), one Bi(1), one Bi(2), and one Bi(3) atom to form OSrBi3 tetrahedra that share  a cornercorner with one O(6)Sr2VBi tetrahedra and  an edgeedge with one O(8)Sr2Bi2 tetrahedra. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sr(1), one V(1), and one Bi(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(3), one Bi(1), and one Bi(3) atom. In the sixth O site, O(6) is bonded to two equivalent Sr(2), one V(2), and one Bi(2) atom to form distorted OSr2VBi tetrahedra that share  a cornercorner with one O(3)SrBi3 tetrahedra, corners with three equivalent O(8)Sr2Bi2 tetrahedra,  an edgeedge with one O(8)Sr2Bi2 tetrahedra, and  an edgeedge with one O(6)Sr2VBi tetrahedra. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Sr(1), one V(1), and one Bi(1) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(2), one Bi(1), and one Bi(2) atom to form OSr2Bi2 tetrahedra that share corners with three equivalent O(6)Sr2VBi tetrahedra,  an edgeedge with one O(8)Sr2Bi2 tetrahedra,  an edgeedge with one O(6)Sr2VBi tetrahedra, and  an edgeedge with one O(3)SrBi3 tetrahedra. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Sr(2), one V(2), and one Bi(1) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Sr(1), one V(1), and one Bi(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Sr(2), one V(2), and one Bi(2) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Sr(2), one V(3), and one Bi(2) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one Sr(1), one V(3), and one Bi(2) atom.
Sr2V3Bi3O14 crystallizes in the triclinic P-1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(14), one O(3), one O(4), one O(7), and two equivalent O(10) atoms. The Sr(1)-O(1) bond length is 2.63 Å. The Sr(1)-O(11) bond length is 2.64 Å. The Sr(1)-O(14) bond length is 2.86 Å. The Sr(1)-O(3) bond length is 2.75 Å. The Sr(1)-O(4) bond length is 2.89 Å. The Sr(1)-O(7) bond length is 2.59 Å. There is one shorter (2.62 Å) and one longer (2.69 Å) Sr(1)-O(10) bond length. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(12), one O(13), one O(2), one O(9), two equivalent O(6), and two equivalent O(8) atoms. The Sr(2)-O(12) bond length is 2.62 Å. The Sr(2)-O(13) bond length is 2.70 Å. The Sr(2)-O(2) bond length is 2.91 Å. The Sr(2)-O(9) bond length is 2.71 Å. Both Sr(2)-O(6) bond lengths are 2.69 Å. There is one shorter (2.52 Å) and one longer (2.64 Å) Sr(2)-O(8) bond length. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(4), and one O(7) atom. The V(1)-O(1) bond length is 1.69 Å. The V(1)-O(11) bond length is 1.80 Å. The V(1)-O(4) bond length is 1.75 Å. The V(1)-O(7) bond length is 1.76 Å. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(12), one O(2), one O(6), and one O(9) atom. The V(2)-O(12) bond length is 1.74 Å. The V(2)-O(2) bond length is 1.73 Å. The V(2)-O(6) bond length is 1.78 Å. The V(2)-O(9) bond length is 1.75 Å. In the third V site, V(3) is bonded in a tetrahedral geometry to one O(10), one O(13), one O(14), and one O(5) atom. The V(3)-O(10) bond length is 1.72 Å. The V(3)-O(13) bond length is 1.73 Å. The V(3)-O(14) bond length is 1.73 Å. The V(3)-O(5) bond length is 1.81 Å. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(7), one O(8), and one O(9) atom. The Bi(1)-O(3) bond length is 2.18 Å. The Bi(1)-O(5) bond length is 2.48 Å. The Bi(1)-O(7) bond length is 2.41 Å. The Bi(1)-O(8) bond length is 2.19 Å. The Bi(1)-O(9) bond length is 2.33 Å. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to one O(12), one O(13), one O(14), one O(3), one O(6), and one O(8) atom. The Bi(2)-O(12) bond length is 2.56 Å. The Bi(2)-O(13) bond length is 2.66 Å. The Bi(2)-O(14) bond length is 2.31 Å. The Bi(2)-O(3) bond length is 2.28 Å. The Bi(2)-O(6) bond length is 2.38 Å. The Bi(2)-O(8) bond length is 2.18 Å. In the third Bi site, Bi(3) is bonded in a 5-coordinate geometry to one O(11), one O(2), one O(3), one O(4), and one O(5) atom. The Bi(3)-O(11) bond length is 2.24 Å. The Bi(3)-O(2) bond length is 2.69 Å. The Bi(3)-O(3) bond length is 2.27 Å. The Bi(3)-O(4) bond length is 2.41 Å. The Bi(3)-O(5) bond length is 2.25 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sr(2), one V(2), and one Bi(3) atom. In the third O site, O(3) is bonded to one Sr(1), one Bi(1), one Bi(2), and one Bi(3) atom to form OSrBi3 tetrahedra that share  a cornercorner with one O(6)Sr2VBi tetrahedra and  an edgeedge with one O(8)Sr2Bi2 tetrahedra. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sr(1), one V(1), and one Bi(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(3), one Bi(1), and one Bi(3) atom. In the sixth O site, O(6) is bonded to two equivalent Sr(2), one V(2), and one Bi(2) atom to form distorted OSr2VBi tetrahedra that share  a cornercorner with one O(3)SrBi3 tetrahedra, corners with three equivalent O(8)Sr2Bi2 tetrahedra,  an edgeedge with one O(8)Sr2Bi2 tetrahedra, and  an edgeedge with one O(6)Sr2VBi tetrahedra. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Sr(1), one V(1), and one Bi(1) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(2), one Bi(1), and one Bi(2) atom to form OSr2Bi2 tetrahedra that share corners with three equivalent O(6)Sr2VBi tetrahedra,  an edgeedge with one O(8)Sr2Bi2 tetrahedra,  an edgeedge with one O(6)Sr2VBi tetrahedra, and  an edgeedge with one O(3)SrBi3 tetrahedra. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Sr(2), one V(2), and one Bi(1) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Sr(1), one V(1), and one Bi(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Sr(2), one V(2), and one Bi(2) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Sr(2), one V(3), and one Bi(2) atom. In the fourteenth O site, O(14) is bonded in a 1-coordinate geometry to one Sr(1), one V(3), and one Bi(2) atom.