Ga3Te crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 8-coordinate geometry to four equivalent Ga(1) and four equivalent Te(1) atoms. In the second Ga site, Ga(2) is bonded in a square co-planar geometry to four equivalent Te(1) atoms. Te(1) is bonded in a distorted square co-planar geometry to four equivalent Ga(2) and eight equivalent Ga(1) atoms.
Ga3Te crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 8-coordinate geometry to four equivalent Ga(1) and four equivalent Te(1) atoms. All Ga(1)-Ga(1) bond lengths are 3.09 Å. All Ga(1)-Te(1) bond lengths are 3.32 Å. In the second Ga site, Ga(2) is bonded in a square co-planar geometry to four equivalent Te(1) atoms. All Ga(2)-Te(1) bond lengths are 3.09 Å. Te(1) is bonded in a distorted square co-planar geometry to four equivalent Ga(2) and eight equivalent Ga(1) atoms.