RbOH crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 4-coordinate geometry to one H(1) and three equivalent O(1) atoms. H(1) is bonded in a single-bond geometry to one Rb(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one H(1) atom.
RbOH crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 4-coordinate geometry to one H(1) and three equivalent O(1) atoms. The Rb(1)-H(1) bond length is 2.79 Å. There are two shorter (2.85 Å) and one longer (3.04 Å) Rb(1)-O(1) bond length. H(1) is bonded in a single-bond geometry to one Rb(1) and one O(1) atom. The H(1)-O(1) bond length is 0.97 Å. O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one H(1) atom.