LiAgF2 crystallizes in the monoclinic C2 space group. Li(1) is bonded to six equivalent F(1) atoms to form edge-sharing LiF6 octahedra. Ag(1) is bonded in a linear geometry to two equivalent F(1) atoms. F(1) is bonded to three equivalent Li(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing FLi3Ag trigonal pyramids.
LiAgF2 crystallizes in the monoclinic C2 space group. Li(1) is bonded to six equivalent F(1) atoms to form edge-sharing LiF6 octahedra. There are a spread of Li(1)-F(1) bond distances ranging from 2.04-2.09 Å. Ag(1) is bonded in a linear geometry to two equivalent F(1) atoms. Both Ag(1)-F(1) bond lengths are 2.08 Å. F(1) is bonded to three equivalent Li(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing FLi3Ag trigonal pyramids.