B5NO12 is Indium-like structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two B5NO12 clusters. There are five inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(7) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(8) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(9) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(6) atom. N(1) is bonded in a single-bond geometry to one O(7) atom. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a single-bond geometry to one O(9) atom. In the second O site, O(12) is bonded in a single-bond geometry to one O(8) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the fourth O site, O(2) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one B(4) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one B(4) and one B(5) atom. In the eighth O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(5) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one B(2) and one N(1) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one B(3) and one O(12) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one B(4) and one O(11) atom. In the twelfth O site, O(10) is bonded in a single-bond geometry to one B(5) atom.
B5NO12 is Indium-like structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two B5NO12 clusters. There are five inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. The B(1)-O(1) bond length is 1.52 Å. The B(1)-O(3) bond length is 1.49 Å. The B(1)-O(4) bond length is 1.48 Å. The B(1)-O(6) bond length is 1.44 Å. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(7) atom. The B(2)-O(1) bond length is 1.31 Å. The B(2)-O(2) bond length is 1.36 Å. The B(2)-O(7) bond length is 1.54 Å. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(8) atom. The B(3)-O(2) bond length is 1.39 Å. The B(3)-O(3) bond length is 1.32 Å. The B(3)-O(8) bond length is 1.45 Å. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(9) atom. The B(4)-O(4) bond length is 1.33 Å. The B(4)-O(5) bond length is 1.35 Å. The B(4)-O(9) bond length is 1.49 Å. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(6) atom. The B(5)-O(10) bond length is 1.36 Å. The B(5)-O(5) bond length is 1.41 Å. The B(5)-O(6) bond length is 1.36 Å. N(1) is bonded in a single-bond geometry to one O(7) atom. The N(1)-O(7) bond length is 1.23 Å. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a single-bond geometry to one O(9) atom. The O(11)-O(9) bond length is 1.31 Å. In the second O site, O(12) is bonded in a single-bond geometry to one O(8) atom. The O(12)-O(8) bond length is 1.34 Å. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the fourth O site, O(2) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one B(4) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one B(4) and one B(5) atom. In the eighth O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(5) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one B(2) and one N(1) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one B(3) and one O(12) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one B(4) and one O(11) atom. In the twelfth O site, O(10) is bonded in a single-bond geometry to one B(5) atom.