PNCl2 is Indium-like structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of two akos000271203 molecules. P(1) is bonded to two equivalent N(1), one Cl(1), and one Cl(2) atom to form corner-sharing PN2Cl2 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom.
PNCl2 is Indium-like structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of two akos000271203 molecules. P(1) is bonded to two equivalent N(1), one Cl(1), and one Cl(2) atom to form corner-sharing PN2Cl2 tetrahedra. Both P(1)-N(1) bond lengths are 1.57 Å. The P(1)-Cl(1) bond length is 2.00 Å. The P(1)-Cl(2) bond length is 2.00 Å. N(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom.