AgNiO2 crystallizes in the triclinic P-1 space group. Ni(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing NiO6 octahedra. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Ni(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing ONi3Ag tetrahedra. In the second O site, O(2) is bonded to three equivalent Ni(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing ONi3Ag tetrahedra.
AgNiO2 crystallizes in the triclinic P-1 space group. Ni(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing NiO6 octahedra. There are two shorter (1.95 Å) and one longer (2.12 Å) Ni(1)-O(1) bond length. There are two shorter (1.94 Å) and one longer (2.12 Å) Ni(1)-O(2) bond length. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. The Ag(1)-O(1) bond length is 2.08 Å. The Ag(1)-O(2) bond length is 2.08 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Ni(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing ONi3Ag tetrahedra. In the second O site, O(2) is bonded to three equivalent Ni(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing ONi3Ag tetrahedra.