LaCrSnO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-26°. Sn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-26°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one La(1), one Cr(1), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom.
LaCrSnO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The La(1)-O(1) bond length is 2.36 Å. The La(1)-O(2) bond length is 2.56 Å. The La(1)-O(3) bond length is 2.41 Å. The La(1)-O(4) bond length is 2.47 Å. The La(1)-O(5) bond length is 2.51 Å. The La(1)-O(6) bond length is 2.67 Å. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-26°. The Cr(1)-O(1) bond length is 1.97 Å. The Cr(1)-O(2) bond length is 1.87 Å. The Cr(1)-O(3) bond length is 1.96 Å. The Cr(1)-O(4) bond length is 1.90 Å. The Cr(1)-O(5) bond length is 1.85 Å. The Cr(1)-O(6) bond length is 1.84 Å. Sn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-26°. The Sn(1)-O(1) bond length is 2.05 Å. The Sn(1)-O(2) bond length is 2.09 Å. The Sn(1)-O(3) bond length is 2.04 Å. The Sn(1)-O(4) bond length is 2.06 Å. The Sn(1)-O(5) bond length is 2.09 Å. The Sn(1)-O(6) bond length is 2.09 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one La(1), one Cr(1), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom.