LiVSiO4 crystallizes in the hexagonal P6_422 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Si(1)O4 tetrahedra. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom.
LiVSiO4 crystallizes in the hexagonal P6_422 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.06 Å. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Si(1)O4 tetrahedra. All V(1)-O(1) bond lengths are 1.91 Å. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra. All Si(1)-O(1) bond lengths are 1.64 Å. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom.