OsO4FN(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Aem2 space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four OsO4F clusters. In each OsO4F cluster, Os(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), two equivalent O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. F(1) is bonded in a single-bond geometry to one Os(1) atom.
OsO4FN(CH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Aem2 space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four OsO4F clusters. In each OsO4F cluster, Os(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), two equivalent O(3), and one F(1) atom. The Os(1)-O(1) bond length is 1.75 Å. The Os(1)-O(2) bond length is 1.74 Å. Both Os(1)-O(3) bond lengths are 1.74 Å. The Os(1)-F(1) bond length is 2.14 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. F(1) is bonded in a single-bond geometry to one Os(1) atom.