CaV2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ca(1) is bonded to four equivalent O(1) atoms to form CaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 61°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Ca(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. O(1) is bonded to one Ca(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing OCaV3 tetrahedra.
CaV2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ca(1) is bonded to four equivalent O(1) atoms to form CaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 61°. All Ca(1)-O(1) bond lengths are 2.20 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Ca(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. All V(1)-O(1) bond lengths are 2.08 Å. O(1) is bonded to one Ca(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing OCaV3 tetrahedra.