V(OH)2 crystallizes in the orthorhombic Pnnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 51°. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent V(1) and one H(1) atom.
V(OH)2 crystallizes in the orthorhombic Pnnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are four shorter (2.22 Å) and two longer (2.23 Å) V(1)-O(1) bond lengths. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent V(1) and one H(1) atom.