LiSnPO4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded in a distorted trigonal planar geometry to one O(2), one O(3), and one O(4) atom. Sn(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and one O(4) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Li(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom.
LiSnPO4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded in a distorted trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The Li(1)-O(2) bond length is 1.85 Å. The Li(1)-O(3) bond length is 1.94 Å. The Li(1)-O(4) bond length is 1.93 Å. Sn(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and one O(4) atom. The Sn(1)-O(1) bond length is 2.12 Å. The Sn(1)-O(3) bond length is 2.31 Å. The Sn(1)-O(4) bond length is 2.35 Å. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The P(1)-O(1) bond length is 1.54 Å. The P(1)-O(2) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.57 Å. The P(1)-O(4) bond length is 1.57 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Li(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom.