CaMoF6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. F(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one Mo(1) atom.
CaMoF6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. All Ca(1)-F(1) bond lengths are 2.26 Å. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedral tilt angles are 30°. All Mo(1)-F(1) bond lengths are 1.96 Å. F(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one Mo(1) atom.