K2MnS2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. S(1) is bonded in a 7-coordinate geometry to five equivalent K(1) and two equivalent Mn(1) atoms.
K2MnS2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. There are a spread of K(1)-S(1) bond distances ranging from 3.17-3.34 Å. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. All Mn(1)-S(1) bond lengths are 2.44 Å. S(1) is bonded in a 7-coordinate geometry to five equivalent K(1) and two equivalent Mn(1) atoms.