NaBa2O is I4/mcm-derived structured and crystallizes in the orthorhombic Cmme space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent Ba(1) atoms. Ba(1) is bonded in an L-shaped geometry to four equivalent Na(1) and two equivalent O(1) atoms. O(1) is bonded to four equivalent Ba(1) atoms to form edge-sharing OBa4 tetrahedra.
NaBa2O is I4/mcm-derived structured and crystallizes in the orthorhombic Cmme space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent Ba(1) atoms. There are a spread of Na(1)-Ba(1) bond distances ranging from 4.28-4.37 Å. Ba(1) is bonded in an L-shaped geometry to four equivalent Na(1) and two equivalent O(1) atoms. Both Ba(1)-O(1) bond lengths are 2.53 Å. O(1) is bonded to four equivalent Ba(1) atoms to form edge-sharing OBa4 tetrahedra.