PbWO4 crystallizes in the monoclinic C2/c space group. W(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a 1-coordinate geometry to two equivalent W(1) and two equivalent Pb(1) atoms.
PbWO4 crystallizes in the monoclinic C2/c space group. W(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Both W(1)-O(1) bond lengths are 1.83 Å. There are two shorter (1.92 Å) and two longer (2.35 Å) W(1)-O(2) bond lengths. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two shorter (2.52 Å) and two longer (2.60 Å) Pb(1)-O(1) bond lengths. There are two shorter (2.67 Å) and two longer (2.81 Å) Pb(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a 1-coordinate geometry to two equivalent W(1) and two equivalent Pb(1) atoms.