ClO2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight hydroxychloride hydrate molecules. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom.
ClO2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight hydroxychloride hydrate molecules. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. The O(1)-Cl(1) bond length is 1.49 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. The O(2)-Cl(1) bond length is 1.47 Å. Cl(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom.