NaVS2 is Caswellsilverite-like structured and crystallizes in the trigonal R3m space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent S(1) and three equivalent S(2) atoms. V(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing VS6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Na(1) and three equivalent V(1) atoms to form edge-sharing SNa3V3 octahedra. In the second S site, S(2) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent V(1) atoms.
NaVS2 is Caswellsilverite-like structured and crystallizes in the trigonal R3m space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent S(1) and three equivalent S(2) atoms. All Na(1)-S(1) bond lengths are 2.85 Å. All Na(1)-S(2) bond lengths are 2.89 Å. V(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing VS6 octahedra. All V(1)-S(1) bond lengths are 2.46 Å. All V(1)-S(2) bond lengths are 2.46 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Na(1) and three equivalent V(1) atoms to form edge-sharing SNa3V3 octahedra. In the second S site, S(2) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent V(1) atoms.