Sr3RhN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing SrN5 trigonal bipyramids. Rh(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded to five equivalent Sr(1) and one Rh(1) atom to form a mixture of distorted corner and edge-sharing NSr5Rh octahedra. The corner-sharing octahedral tilt angles range from 12-49°.
Sr3RhN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing SrN5 trigonal bipyramids. There are a spread of Sr(1)-N(1) bond distances ranging from 2.66-2.88 Å. Rh(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All Rh(1)-N(1) bond lengths are 1.89 Å. N(1) is bonded to five equivalent Sr(1) and one Rh(1) atom to form a mixture of distorted corner and edge-sharing NSr5Rh octahedra. The corner-sharing octahedral tilt angles range from 12-49°.