LiLiU2O5 crystallizes in the tetragonal P4/mmm space group. The structure consists of one 7439-93-2 atom inside a LiU2O5 framework. In the LiU2O5 framework, Li(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. U(1) is bonded to one O(2) and four equivalent O(1) atoms to form distorted corner-sharing UO5 trigonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1) and two equivalent U(1) atoms to form a mixture of distorted corner and edge-sharing OLi2U2 tetrahedra. In the second O site, O(2) is bonded in a linear geometry to two equivalent U(1) atoms.
LiLiU2O5 crystallizes in the tetragonal P4/mmm space group. The structure consists of one 7439-93-2 atom inside a LiU2O5 framework. In the LiU2O5 framework, Li(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.51 Å. U(1) is bonded to one O(2) and four equivalent O(1) atoms to form distorted corner-sharing UO5 trigonal bipyramids. The U(1)-O(2) bond length is 2.16 Å. All U(1)-O(1) bond lengths are 2.13 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1) and two equivalent U(1) atoms to form a mixture of distorted corner and edge-sharing OLi2U2 tetrahedra. In the second O site, O(2) is bonded in a linear geometry to two equivalent U(1) atoms.