CsCrO3F crystallizes in the monoclinic Cc space group. Cs(1) is bonded in a 12-coordinate geometry to three equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent F(1) atoms. Cr(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. F(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom.
CsCrO3F crystallizes in the monoclinic Cc space group. Cs(1) is bonded in a 12-coordinate geometry to three equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent F(1) atoms. There is one shorter (3.24 Å) and two longer (3.44 Å) Cs(1)-O(1) bond lengths. There are a spread of Cs(1)-O(2) bond distances ranging from 3.25-3.55 Å. There are a spread of Cs(1)-O(3) bond distances ranging from 3.23-3.57 Å. There is one shorter (3.22 Å) and two longer (3.47 Å) Cs(1)-F(1) bond lengths. Cr(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. The Cr(1)-O(1) bond length is 1.63 Å. The Cr(1)-O(2) bond length is 1.63 Å. The Cr(1)-O(3) bond length is 1.63 Å. The Cr(1)-F(1) bond length is 1.79 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom. F(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one Cr(1) atom.