Rb3K is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a body-centered cubic geometry to four equivalent Rb(2) and four equivalent K(1) atoms. In the second Rb site, Rb(2) is bonded in a body-centered cubic geometry to eight equivalent Rb(1) atoms. K(1) is bonded in a body-centered cubic geometry to eight equivalent Rb(1) atoms.
Rb3K is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a body-centered cubic geometry to four equivalent Rb(2) and four equivalent K(1) atoms. All Rb(1)-Rb(2) bond lengths are 4.89 Å. All Rb(1)-K(1) bond lengths are 4.89 Å. In the second Rb site, Rb(2) is bonded in a body-centered cubic geometry to eight equivalent Rb(1) atoms. K(1) is bonded in a body-centered cubic geometry to eight equivalent Rb(1) atoms.