LaZrNO2 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 8-coordinate geometry to two equivalent N(1) and six equivalent O(1) atoms. Zr(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form corner-sharing ZrN2O4 octahedra. The corner-sharing octahedral tilt angles range from 30-33°. N(1) is bonded to two equivalent La(1) and two equivalent Zr(1) atoms to form distorted corner-sharing NLa2Zr2 tetrahedra. O(1) is bonded in a 5-coordinate geometry to three equivalent La(1) and two equivalent Zr(1) atoms.
LaZrNO2 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 8-coordinate geometry to two equivalent N(1) and six equivalent O(1) atoms. There is one shorter (2.36 Å) and one longer (2.55 Å) La(1)-N(1) bond length. There are a spread of La(1)-O(1) bond distances ranging from 2.48-2.97 Å. Zr(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form corner-sharing ZrN2O4 octahedra. The corner-sharing octahedral tilt angles range from 30-33°. Both Zr(1)-N(1) bond lengths are 2.18 Å. There are two shorter (2.15 Å) and two longer (2.16 Å) Zr(1)-O(1) bond lengths. N(1) is bonded to two equivalent La(1) and two equivalent Zr(1) atoms to form distorted corner-sharing NLa2Zr2 tetrahedra. O(1) is bonded in a 5-coordinate geometry to three equivalent La(1) and two equivalent Zr(1) atoms.