NiZnF6 crystallizes in the trigonal R-3 space group. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a bent 150 degrees geometry to one Ni(1) and one Zn(1) atom.
NiZnF6 crystallizes in the trigonal R-3 space group. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Ni(1)-F(1) bond lengths are 1.79 Å. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Zn(1)-F(1) bond lengths are 2.00 Å. F(1) is bonded in a bent 150 degrees geometry to one Ni(1) and one Zn(1) atom.