Na2CuP crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. Cu(1) is bonded in a distorted linear geometry to two equivalent P(1) atoms. P(1) is bonded in a 10-coordinate geometry to eight equivalent Na(1) and two equivalent Cu(1) atoms.
Na2CuP crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. There are a spread of Na(1)-P(1) bond distances ranging from 2.94-3.06 Å. Cu(1) is bonded in a distorted linear geometry to two equivalent P(1) atoms. Both Cu(1)-P(1) bond lengths are 2.22 Å. P(1) is bonded in a 10-coordinate geometry to eight equivalent Na(1) and two equivalent Cu(1) atoms.