LiRhO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. O(1) is bonded to three equivalent Li(1) and three equivalent Rh(1) atoms to form a mixture of edge and corner-sharing OLi3Rh3 octahedra. The corner-sharing octahedra are not tilted.
LiRhO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. All Li(1)-O(1) bond lengths are 2.17 Å. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. All Rh(1)-O(1) bond lengths are 2.06 Å. O(1) is bonded to three equivalent Li(1) and three equivalent Rh(1) atoms to form a mixture of edge and corner-sharing OLi3Rh3 octahedra. The corner-sharing octahedra are not tilted.