B4NO10NO is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two nitroxyl molecules and two B4NO10 clusters. In each B4NO10 cluster, there are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(8) atom. In the second B site, B(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(7) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(11), one O(3), and one O(7) atom. N(2) is bonded in a bent 120 degrees geometry to one O(4) and one O(9) atom. There are ten inequivalent O sites. In the first O site, O(11) is bonded in a single-bond geometry to one B(4) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one B(1) and one B(3) atom. In the third O site, O(2) is bonded in a single-bond geometry to one B(2) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one B(3) and one B(4) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one B(2) and one N(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one B(3) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one B(2) and one B(4) atom. In the ninth O site, O(8) is bonded in a single-bond geometry to one B(1) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one N(2) atom.
B4NO10NO is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two nitroxyl molecules and two B4NO10 clusters. In each B4NO10 cluster, there are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(8) atom. The B(1)-O(1) bond length is 1.38 Å. The B(1)-O(6) bond length is 1.37 Å. The B(1)-O(8) bond length is 1.41 Å. In the second B site, B(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(7) atom. The B(2)-O(2) bond length is 1.47 Å. The B(2)-O(4) bond length is 1.52 Å. The B(2)-O(6) bond length is 1.48 Å. The B(2)-O(7) bond length is 1.43 Å. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. The B(3)-O(1) bond length is 1.37 Å. The B(3)-O(3) bond length is 1.38 Å. The B(3)-O(5) bond length is 1.41 Å. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(11), one O(3), and one O(7) atom. The B(4)-O(11) bond length is 1.47 Å. The B(4)-O(3) bond length is 1.37 Å. The B(4)-O(7) bond length is 1.34 Å. N(2) is bonded in a bent 120 degrees geometry to one O(4) and one O(9) atom. The N(2)-O(4) bond length is 1.38 Å. The N(2)-O(9) bond length is 1.21 Å. There are ten inequivalent O sites. In the first O site, O(11) is bonded in a single-bond geometry to one B(4) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one B(1) and one B(3) atom. In the third O site, O(2) is bonded in a single-bond geometry to one B(2) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one B(3) and one B(4) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one B(2) and one N(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one B(3) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one B(2) and one B(4) atom. In the ninth O site, O(8) is bonded in a single-bond geometry to one B(1) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one N(2) atom.