TlGeF3 is Potassium chlorate structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two GeF3 clusters. In each GeF3 cluster, Ge(1) is bonded in a distorted T-shaped geometry to one F(2) and two equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom.
TlGeF3 is Potassium chlorate structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two GeF3 clusters. In each GeF3 cluster, Ge(1) is bonded in a distorted T-shaped geometry to one F(2) and two equivalent F(1) atoms. The Ge(1)-F(2) bond length is 1.85 Å. Both Ge(1)-F(1) bond lengths are 1.85 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom.