NSOCl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NSOCl clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one N(2), one O(2), and one Cl(2) atom to form corner-sharing SN2ClO tetrahedra. In the second S site, S(2) is bonded to one N(1), one N(3), one O(3), and one Cl(3) atom to form corner-sharing SN2ClO tetrahedra. In the third S site, S(3) is bonded to one N(2), one N(3), one O(1), and one Cl(1) atom to form corner-sharing SN2ClO tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(2) atom.
NSOCl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NSOCl clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.59 Å. The N(1)-S(2) bond length is 1.59 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. The N(2)-S(1) bond length is 1.59 Å. The N(2)-S(3) bond length is 1.58 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(3)-S(2) bond length is 1.59 Å. The N(3)-S(3) bond length is 1.59 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one N(2), one O(2), and one Cl(2) atom to form corner-sharing SN2ClO tetrahedra. The S(1)-O(2) bond length is 1.43 Å. The S(1)-Cl(2) bond length is 2.03 Å. In the second S site, S(2) is bonded to one N(1), one N(3), one O(3), and one Cl(3) atom to form corner-sharing SN2ClO tetrahedra. The S(2)-O(3) bond length is 1.42 Å. The S(2)-Cl(3) bond length is 2.04 Å. In the third S site, S(3) is bonded to one N(2), one N(3), one O(1), and one Cl(1) atom to form corner-sharing SN2ClO tetrahedra. The S(3)-O(1) bond length is 1.43 Å. The S(3)-Cl(1) bond length is 2.05 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(2) atom.