CuVO2 crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. Cu(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent V(1) and one Cu(1) atom to form a mixture of distorted corner and edge-sharing OV3Cu trigonal pyramids.
CuVO2 crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. All V(1)-O(1) bond lengths are 2.05 Å. Cu(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Cu(1)-O(1) bond lengths are 1.85 Å. O(1) is bonded to three equivalent V(1) and one Cu(1) atom to form a mixture of distorted corner and edge-sharing OV3Cu trigonal pyramids.