CrTe(WO6)2 crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted WO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. In the second W site, W(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. Cr(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form distorted CrO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. Te(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom.
CrTe(WO6)2 crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted WO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. The W(1)-O(1) bond length is 1.93 Å. The W(1)-O(11) bond length is 1.77 Å. The W(1)-O(12) bond length is 1.95 Å. The W(1)-O(2) bond length is 2.21 Å. The W(1)-O(4) bond length is 1.93 Å. The W(1)-O(9) bond length is 1.95 Å. In the second W site, W(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. The W(2)-O(10) bond length is 2.19 Å. The W(2)-O(3) bond length is 1.79 Å. The W(2)-O(5) bond length is 1.80 Å. The W(2)-O(6) bond length is 1.96 Å. The W(2)-O(7) bond length is 1.94 Å. The W(2)-O(8) bond length is 2.17 Å. Cr(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form distorted CrO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. The Cr(1)-O(10) bond length is 1.67 Å. The Cr(1)-O(11) bond length is 2.12 Å. The Cr(1)-O(2) bond length is 1.65 Å. The Cr(1)-O(3) bond length is 2.10 Å. The Cr(1)-O(5) bond length is 2.07 Å. The Cr(1)-O(8) bond length is 1.67 Å. Te(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. The Te(1)-O(1) bond length is 1.93 Å. The Te(1)-O(12) bond length is 1.93 Å. The Te(1)-O(4) bond length is 1.93 Å. The Te(1)-O(6) bond length is 1.93 Å. The Te(1)-O(7) bond length is 1.94 Å. The Te(1)-O(9) bond length is 1.94 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom.