(MnF3)2Hg2S crystallizes in the cubic Fd-3m space group. The structure consists of one Hg2S framework and one MnF3 framework. In the Hg2S framework, Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. S(1) is bonded to four equivalent Hg(1) atoms to form corner-sharing SHg4 tetrahedra. In the MnF3 framework, Mn(1) is bonded to six equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles are 46°. F(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Mn(1) atoms.
(MnF3)2Hg2S crystallizes in the cubic Fd-3m space group. The structure consists of one Hg2S framework and one MnF3 framework. In the Hg2S framework, Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. Both Hg(1)-S(1) bond lengths are 2.42 Å. S(1) is bonded to four equivalent Hg(1) atoms to form corner-sharing SHg4 tetrahedra. In the MnF3 framework, Mn(1) is bonded to six equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles are 46°. All Mn(1)-F(1) bond lengths are 2.15 Å. F(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Mn(1) atoms.