CF3FS(O2)OCO is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four FS(O2)OCO clusters. In each FS(O2)OCO cluster, C(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one F(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. F(2) is bonded in a single-bond geometry to one C(2) atom.
CF3FS(O2)OCO is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four FS(O2)OCO clusters. In each FS(O2)OCO cluster, C(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one F(2) atom. The C(2)-O(2) bond length is 1.36 Å. The C(2)-O(3) bond length is 1.19 Å. The C(2)-F(2) bond length is 1.34 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. The S(1)-O(1) bond length is 1.43 Å. The S(1)-O(2) bond length is 1.68 Å. The S(1)-O(4) bond length is 1.43 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. F(2) is bonded in a single-bond geometry to one C(2) atom.