(Tl)2TlGaF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-28-0 atoms inside a TlGaF6 framework. In the TlGaF6 framework, Tl(2) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Ga(1)F6 octahedra. The corner-sharing octahedra are not tilted. Ga(1) is bonded to six equivalent F(1) atoms to form GaF6 octahedra that share corners with six equivalent Tl(2)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Tl(2) and one Ga(1) atom.
(Tl)2TlGaF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-28-0 atoms inside a TlGaF6 framework. In the TlGaF6 framework, Tl(2) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Ga(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Tl(2)-F(1) bond lengths are 2.59 Å. Ga(1) is bonded to six equivalent F(1) atoms to form GaF6 octahedra that share corners with six equivalent Tl(2)F6 octahedra. The corner-sharing octahedra are not tilted. All Ga(1)-F(1) bond lengths are 1.90 Å. F(1) is bonded in a linear geometry to one Tl(2) and one Ga(1) atom.