LiOsN2 is Chalcopyrite structured and crystallizes in the tetragonal I-42d space group. Li(1) is bonded to four equivalent N(1) atoms to form LiN4 tetrahedra that share corners with four equivalent Li(1)N4 tetrahedra and corners with eight equivalent Os(1)N4 tetrahedra. Os(1) is bonded to four equivalent N(1) atoms to form OsN4 tetrahedra that share corners with four equivalent Os(1)N4 tetrahedra and corners with eight equivalent Li(1)N4 tetrahedra. N(1) is bonded to two equivalent Li(1) and two equivalent Os(1) atoms to form corner-sharing NLi2Os2 tetrahedra.
LiOsN2 is Chalcopyrite structured and crystallizes in the tetragonal I-42d space group. Li(1) is bonded to four equivalent N(1) atoms to form LiN4 tetrahedra that share corners with four equivalent Li(1)N4 tetrahedra and corners with eight equivalent Os(1)N4 tetrahedra. All Li(1)-N(1) bond lengths are 2.14 Å. Os(1) is bonded to four equivalent N(1) atoms to form OsN4 tetrahedra that share corners with four equivalent Os(1)N4 tetrahedra and corners with eight equivalent Li(1)N4 tetrahedra. All Os(1)-N(1) bond lengths are 1.90 Å. N(1) is bonded to two equivalent Li(1) and two equivalent Os(1) atoms to form corner-sharing NLi2Os2 tetrahedra.