Sr2MnCu2(SO)2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Mn(1) is bonded in a square co-planar geometry to two equivalent S(1) and four equivalent O(1) atoms. Cu(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing CuS4 tetrahedra. S(1) is bonded in a 9-coordinate geometry to four equivalent Sr(1), one Mn(1), and four equivalent Cu(1) atoms. O(1) is bonded to four equivalent Sr(1) and two equivalent Mn(1) atoms to form a mixture of corner, face, and edge-sharing OSr4Mn2 octahedra. The corner-sharing octahedra are not tilted.
Sr2MnCu2(SO)2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. All Sr(1)-S(1) bond lengths are 3.24 Å. All Sr(1)-O(1) bond lengths are 2.63 Å. Mn(1) is bonded in a square co-planar geometry to two equivalent S(1) and four equivalent O(1) atoms. Both Mn(1)-S(1) bond lengths are 3.07 Å. All Mn(1)-O(1) bond lengths are 2.06 Å. Cu(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing CuS4 tetrahedra. All Cu(1)-S(1) bond lengths are 2.45 Å. S(1) is bonded in a 9-coordinate geometry to four equivalent Sr(1), one Mn(1), and four equivalent Cu(1) atoms. O(1) is bonded to four equivalent Sr(1) and two equivalent Mn(1) atoms to form a mixture of corner, face, and edge-sharing OSr4Mn2 octahedra. The corner-sharing octahedra are not tilted.