CsV2S2O crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a distorted body-centered cubic geometry to eight equivalent S(1) atoms. V(1) is bonded in a distorted linear geometry to four equivalent S(1) and two equivalent O(1) atoms. S(1) is bonded in a 8-coordinate geometry to four equivalent Cs(1) and four equivalent V(1) atoms. O(1) is bonded in a square co-planar geometry to four equivalent V(1) atoms.
CsV2S2O crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a distorted body-centered cubic geometry to eight equivalent S(1) atoms. All Cs(1)-S(1) bond lengths are 3.63 Å. V(1) is bonded in a distorted linear geometry to four equivalent S(1) and two equivalent O(1) atoms. All V(1)-S(1) bond lengths are 2.61 Å. Both V(1)-O(1) bond lengths are 2.05 Å. S(1) is bonded in a 8-coordinate geometry to four equivalent Cs(1) and four equivalent V(1) atoms. O(1) is bonded in a square co-planar geometry to four equivalent V(1) atoms.