Re2Co(MoS4)2 crystallizes in the orthorhombic Imm2 space group. Mo(1) is bonded in a 6-coordinate geometry to one S(1), one S(3), two equivalent S(2), and two equivalent S(4) atoms. Re(1) is bonded in a 6-coordinate geometry to one S(2), one S(4), two equivalent S(1), and two equivalent S(3) atoms. Co(1) is bonded in a tetrahedral geometry to two equivalent S(3) and two equivalent S(4) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Re(1) atoms. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one Re(1) atom. In the third S site, S(3) is bonded to one Mo(1), two equivalent Re(1), and one Co(1) atom to form distorted SCoRe2Mo tetrahedra that share  a cornercorner with one S(3)CoRe2Mo tetrahedra, corners with two equivalent S(4)CoReMo2 tetrahedra,  an edgeedge with one S(3)CoRe2Mo tetrahedra, and edges with two equivalent S(4)CoReMo2 tetrahedra. In the fourth S site, S(4) is bonded to two equivalent Mo(1), one Re(1), and one Co(1) atom to form distorted SCoReMo2 tetrahedra that share  a cornercorner with one S(4)CoReMo2 tetrahedra, corners with two equivalent S(3)CoRe2Mo tetrahedra,  an edgeedge with one S(4)CoReMo2 tetrahedra, and edges with two equivalent S(3)CoRe2Mo tetrahedra.
Re2Co(MoS4)2 crystallizes in the orthorhombic Imm2 space group. Mo(1) is bonded in a 6-coordinate geometry to one S(1), one S(3), two equivalent S(2), and two equivalent S(4) atoms. The Mo(1)-S(1) bond length is 2.35 Å. The Mo(1)-S(3) bond length is 2.61 Å. Both Mo(1)-S(2) bond lengths are 2.35 Å. Both Mo(1)-S(4) bond lengths are 2.59 Å. Re(1) is bonded in a 6-coordinate geometry to one S(2), one S(4), two equivalent S(1), and two equivalent S(3) atoms. The Re(1)-S(2) bond length is 2.34 Å. The Re(1)-S(4) bond length is 2.53 Å. Both Re(1)-S(1) bond lengths are 2.34 Å. Both Re(1)-S(3) bond lengths are 2.54 Å. Co(1) is bonded in a tetrahedral geometry to two equivalent S(3) and two equivalent S(4) atoms. Both Co(1)-S(3) bond lengths are 2.27 Å. Both Co(1)-S(4) bond lengths are 2.24 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Re(1) atoms. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one Re(1) atom. In the third S site, S(3) is bonded to one Mo(1), two equivalent Re(1), and one Co(1) atom to form distorted SCoRe2Mo tetrahedra that share  a cornercorner with one S(3)CoRe2Mo tetrahedra, corners with two equivalent S(4)CoReMo2 tetrahedra,  an edgeedge with one S(3)CoRe2Mo tetrahedra, and edges with two equivalent S(4)CoReMo2 tetrahedra. In the fourth S site, S(4) is bonded to two equivalent Mo(1), one Re(1), and one Co(1) atom to form distorted SCoReMo2 tetrahedra that share  a cornercorner with one S(4)CoReMo2 tetrahedra, corners with two equivalent S(3)CoRe2Mo tetrahedra,  an edgeedge with one S(4)CoReMo2 tetrahedra, and edges with two equivalent S(3)CoRe2Mo tetrahedra.