LiBeF3NF crystallizes in the orthorhombic Pna2_1 space group. The structure consists of four monofluoroamine molecules inside a LiBeF3 framework. In the LiBeF3 framework, Li(1) is bonded in a trigonal planar geometry to one F(1), one F(3), and one F(4) atom. Be(1) is bonded in a trigonal planar geometry to one F(1), one F(3), and one F(4) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Be(1) atom. In the second F site, F(3) is bonded in a bent 120 degrees geometry to one Li(1) and one Be(1) atom. In the third F site, F(4) is bonded in a bent 150 degrees geometry to one Li(1) and one Be(1) atom.
LiBeF3NF crystallizes in the orthorhombic Pna2_1 space group. The structure consists of four monofluoroamine molecules inside a LiBeF3 framework. In the LiBeF3 framework, Li(1) is bonded in a trigonal planar geometry to one F(1), one F(3), and one F(4) atom. The Li(1)-F(1) bond length is 1.83 Å. The Li(1)-F(3) bond length is 1.85 Å. The Li(1)-F(4) bond length is 1.83 Å. Be(1) is bonded in a trigonal planar geometry to one F(1), one F(3), and one F(4) atom. The Be(1)-F(1) bond length is 1.48 Å. The Be(1)-F(3) bond length is 1.48 Å. The Be(1)-F(4) bond length is 1.47 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Be(1) atom. In the second F site, F(3) is bonded in a bent 120 degrees geometry to one Li(1) and one Be(1) atom. In the third F site, F(4) is bonded in a bent 150 degrees geometry to one Li(1) and one Be(1) atom.