LiSrGaF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles are 56°. Sr(1) is bonded to six equivalent F(1) atoms to form SrF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. Ga(1) is bonded to six equivalent F(1) atoms to form GaF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 49°. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Sr(1), and one Ga(1) atom.
LiSrGaF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Li(1)-F(1) bond lengths are 2.05 Å. Sr(1) is bonded to six equivalent F(1) atoms to form SrF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. All Sr(1)-F(1) bond lengths are 2.46 Å. Ga(1) is bonded to six equivalent F(1) atoms to form GaF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Ga(1)-F(1) bond lengths are 1.92 Å. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Sr(1), and one Ga(1) atom.