Ba4La6Mn(Co3O10)3 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. Ba(1) is bonded to two equivalent O(2), two equivalent O(7), four equivalent O(1), and four equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with five equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Mn(1)O6 octahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(2)O6 octahedra, and faces with two equivalent Co(4)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to two equivalent O(3), two equivalent O(9), and eight equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra, faces with four equivalent Co(3)O6 octahedra, and faces with four equivalent Co(5)O6 octahedra. In the second La site, La(2) is bonded to two equivalent O(4), two equivalent O(8), four equivalent O(1), and four equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, faces with two equivalent Co(4)O6 octahedra, and faces with two equivalent Co(5)O6 octahedra. Mn(1) is bonded to two equivalent O(2) and four equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Co(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(7), one O(8), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the second Co site, Co(2) is bonded to two equivalent O(7) and four equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Co site, Co(3) is bonded to one O(8), one O(9), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(5)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fourth Co site, Co(4) is bonded to one O(2), one O(4), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the fifth Co site, Co(5) is bonded to one O(3), one O(4), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are nine inequivalent O sites. In the first O site, O(7) is bonded to four equivalent Ba(1), one Co(1), and one Co(2) atom to form distorted OBa4Co2 octahedra that share corners with five equivalent O(7)Ba4Co2 octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-57°. In the second O site, O(8) is bonded in a distorted linear geometry to four equivalent La(2), one Co(1), and one Co(3) atom. In the third O site, O(9) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(3) atoms. In the fourth O site, O(1) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent La(2), one Co(1), and one Co(4) atom. In the fifth O site, O(2) is bonded to four equivalent Ba(1), one Mn(1), and one Co(4) atom to form distorted OBa4MnCo octahedra that share corners with five equivalent O(2)Ba4MnCo octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(7)Ba4Co2 octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the sixth O site, O(3) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(5) atoms. In the seventh O site, O(4) is bonded in a distorted linear geometry to four equivalent La(2), one Co(4), and one Co(5) atom. In the eighth O site, O(5) is bonded to four equivalent Ba(1), one Mn(1), and one Co(2) atom to form distorted OBa4MnCo octahedra that share corners with two equivalent O(5)Ba4MnCo octahedra, corners with four equivalent O(7)Ba4Co2 octahedra, corners with four equivalent O(2)Ba4MnCo octahedra, edges with two equivalent O(5)Ba4MnCo octahedra, faces with two equivalent O(7)Ba4Co2 octahedra, faces with two equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the ninth O site, O(6) is bonded to two equivalent La(1), two equivalent La(2), one Co(3), and one Co(5) atom to form a mixture of distorted edge, face, and corner-sharing OLa4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°.
Ba4La6Mn(Co3O10)3 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. Ba(1) is bonded to two equivalent O(2), two equivalent O(7), four equivalent O(1), and four equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent Ba(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with five equivalent Ba(1)O12 cuboctahedra, faces with two equivalent Mn(1)O6 octahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(2)O6 octahedra, and faces with two equivalent Co(4)O6 octahedra. Both Ba(1)-O(2) bond lengths are 2.80 Å. Both Ba(1)-O(7) bond lengths are 2.80 Å. All Ba(1)-O(1) bond lengths are 2.99 Å. All Ba(1)-O(5) bond lengths are 2.77 Å. There are two inequivalent La sites. In the first La site, La(1) is bonded to two equivalent O(3), two equivalent O(9), and eight equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra, faces with four equivalent Co(3)O6 octahedra, and faces with four equivalent Co(5)O6 octahedra. Both La(1)-O(3) bond lengths are 2.80 Å. Both La(1)-O(9) bond lengths are 2.80 Å. All La(1)-O(6) bond lengths are 2.70 Å. In the second La site, La(2) is bonded to two equivalent O(4), two equivalent O(8), four equivalent O(1), and four equivalent O(6) atoms to form LaO12 cuboctahedra that share corners with four equivalent Ba(1)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra, faces with two equivalent Co(1)O6 octahedra, faces with two equivalent Co(3)O6 octahedra, faces with two equivalent Co(4)O6 octahedra, and faces with two equivalent Co(5)O6 octahedra. Both La(2)-O(4) bond lengths are 2.80 Å. Both La(2)-O(8) bond lengths are 2.80 Å. All La(2)-O(1) bond lengths are 2.56 Å. All La(2)-O(6) bond lengths are 2.82 Å. Mn(1) is bonded to two equivalent O(2) and four equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Co(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Both Mn(1)-O(2) bond lengths are 1.98 Å. All Mn(1)-O(5) bond lengths are 1.99 Å. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(7), one O(8), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. The Co(1)-O(7) bond length is 1.75 Å. The Co(1)-O(8) bond length is 2.02 Å. All Co(1)-O(1) bond lengths are 2.06 Å. In the second Co site, Co(2) is bonded to two equivalent O(7) and four equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Both Co(2)-O(7) bond lengths are 2.11 Å. All Co(2)-O(5) bond lengths are 1.97 Å. In the third Co site, Co(3) is bonded to one O(8), one O(9), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(5)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. The Co(3)-O(8) bond length is 1.85 Å. The Co(3)-O(9) bond length is 1.92 Å. All Co(3)-O(6) bond lengths are 1.98 Å. In the fourth Co site, Co(4) is bonded to one O(2), one O(4), and four equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-15°. The Co(4)-O(2) bond length is 2.00 Å. The Co(4)-O(4) bond length is 1.98 Å. All Co(4)-O(1) bond lengths are 1.93 Å. In the fifth Co site, Co(5) is bonded to one O(3), one O(4), and four equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with four equivalent La(1)O12 cuboctahedra, and faces with four equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-4°. The Co(5)-O(3) bond length is 1.91 Å. The Co(5)-O(4) bond length is 1.79 Å. All Co(5)-O(6) bond lengths are 1.98 Å. There are nine inequivalent O sites. In the first O site, O(7) is bonded to four equivalent Ba(1), one Co(1), and one Co(2) atom to form distorted OBa4Co2 octahedra that share corners with five equivalent O(7)Ba4Co2 octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-57°. In the second O site, O(8) is bonded in a distorted linear geometry to four equivalent La(2), one Co(1), and one Co(3) atom. In the third O site, O(9) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(3) atoms. In the fourth O site, O(1) is bonded in a 6-coordinate geometry to two equivalent Ba(1), two equivalent La(2), one Co(1), and one Co(4) atom. In the fifth O site, O(2) is bonded to four equivalent Ba(1), one Mn(1), and one Co(4) atom to form distorted OBa4MnCo octahedra that share corners with five equivalent O(2)Ba4MnCo octahedra, corners with eight equivalent O(5)Ba4MnCo octahedra, edges with four equivalent O(7)Ba4Co2 octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the sixth O site, O(3) is bonded in a distorted linear geometry to four equivalent La(1) and two equivalent Co(5) atoms. In the seventh O site, O(4) is bonded in a distorted linear geometry to four equivalent La(2), one Co(4), and one Co(5) atom. In the eighth O site, O(5) is bonded to four equivalent Ba(1), one Mn(1), and one Co(2) atom to form distorted OBa4MnCo octahedra that share corners with two equivalent O(5)Ba4MnCo octahedra, corners with four equivalent O(7)Ba4Co2 octahedra, corners with four equivalent O(2)Ba4MnCo octahedra, edges with two equivalent O(5)Ba4MnCo octahedra, faces with two equivalent O(7)Ba4Co2 octahedra, faces with two equivalent O(2)Ba4MnCo octahedra, and faces with four equivalent O(5)Ba4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the ninth O site, O(6) is bonded to two equivalent La(1), two equivalent La(2), one Co(3), and one Co(5) atom to form a mixture of distorted edge, face, and corner-sharing OLa4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°.