Pt(Na) crystallizes in the hexagonal P-6m2 space group. Na(1) is bonded to six equivalent Pt(1) atoms to form a mixture of distorted corner, edge, and face-sharing NaPt6 cuboctahedra. Pt(1) is bonded to six equivalent Na(1) atoms to form a mixture of distorted corner, edge, and face-sharing PtNa6 cuboctahedra.
Pt(Na) crystallizes in the hexagonal P-6m2 space group. Na(1) is bonded to six equivalent Pt(1) atoms to form a mixture of distorted corner, edge, and face-sharing NaPt6 cuboctahedra. All Na(1)-Pt(1) bond lengths are 2.95 Å. Pt(1) is bonded to six equivalent Na(1) atoms to form a mixture of distorted corner, edge, and face-sharing PtNa6 cuboctahedra.