ZnP2(WO5)2 crystallizes in the orthorhombic Fdd2 space group. W(1) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. Zn(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-56°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(1) atom.
ZnP2(WO5)2 crystallizes in the orthorhombic Fdd2 space group. W(1) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. The W(1)-O(1) bond length is 2.14 Å. The W(1)-O(3) bond length is 2.26 Å. The W(1)-O(4) bond length is 2.12 Å. The W(1)-O(5) bond length is 2.06 Å. There is one shorter (1.97 Å) and one longer (2.02 Å) W(1)-O(2) bond length. Zn(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. Both Zn(1)-O(2) bond lengths are 2.02 Å. Both Zn(1)-O(3) bond lengths are 1.97 Å. P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-56°. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(3) bond length is 1.60 Å. The P(1)-O(4) bond length is 1.53 Å. The P(1)-O(5) bond length is 1.56 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one P(1) atom.