ReF6 is Tungsten structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of two rhenium hexafluoride molecules. Re(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom.
ReF6 is Tungsten structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of two rhenium hexafluoride molecules. Re(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. Both Re(1)-F(1) bond lengths are 1.83 Å. All Re(1)-F(2) bond lengths are 1.87 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom.