MgC4H8(N3O2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MgC4H8(N3O2)2 clusters. Mg(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(2) and one N(3) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Mg(1) and one C(2) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mg(1), one H(1), and one H(4) atom.
MgC4H8(N3O2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MgC4H8(N3O2)2 clusters. Mg(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Mg(1)-N(1) bond lengths are 2.14 Å. Both Mg(1)-O(1) bond lengths are 2.07 Å. Both Mg(1)-O(2) bond lengths are 2.18 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(2) and one N(3) atom. The C(1)-N(2) bond length is 1.18 Å. The C(1)-N(3) bond length is 1.29 Å. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The C(2)-N(1) bond length is 1.18 Å. The C(2)-N(3) bond length is 1.30 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Mg(1) and one C(2) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mg(1), one H(1), and one H(4) atom.