FeWB crystallizes in the orthorhombic Pnma space group. W(1) is bonded in a 11-coordinate geometry to six equivalent Fe(1) and five equivalent B(1) atoms. Fe(1) is bonded in a 12-coordinate geometry to six equivalent W(1), two equivalent Fe(1), and four equivalent B(1) atoms. B(1) is bonded in a 9-coordinate geometry to five equivalent W(1) and four equivalent Fe(1) atoms.
FeWB crystallizes in the orthorhombic Pnma space group. W(1) is bonded in a 11-coordinate geometry to six equivalent Fe(1) and five equivalent B(1) atoms. There are a spread of W(1)-Fe(1) bond distances ranging from 2.61-2.74 Å. There are four shorter (2.37 Å) and one longer (2.49 Å) W(1)-B(1) bond length. Fe(1) is bonded in a 12-coordinate geometry to six equivalent W(1), two equivalent Fe(1), and four equivalent B(1) atoms. Both Fe(1)-Fe(1) bond lengths are 2.43 Å. There are a spread of Fe(1)-B(1) bond distances ranging from 2.12-2.24 Å. B(1) is bonded in a 9-coordinate geometry to five equivalent W(1) and four equivalent Fe(1) atoms.