Zn3As2 crystallizes in the cubic Pn-3m space group. Zn(1) is bonded to four equivalent As(1) atoms to form a mixture of corner and edge-sharing ZnAs4 tetrahedra. As(1) is bonded in a 6-coordinate geometry to six equivalent Zn(1) atoms.
Zn3As2 crystallizes in the cubic Pn-3m space group. Zn(1) is bonded to four equivalent As(1) atoms to form a mixture of corner and edge-sharing ZnAs4 tetrahedra. All Zn(1)-As(1) bond lengths are 2.58 Å. As(1) is bonded in a 6-coordinate geometry to six equivalent Zn(1) atoms.