PCl4ICl2 is beta-prime cadmium gold structured and crystallizes in the tetragonal P-42_1m space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two ICl2 clusters. In each ICl2 cluster, I(1) is bonded in a linear geometry to two equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one I(1) atom.
PCl4ICl2 is beta-prime cadmium gold structured and crystallizes in the tetragonal P-42_1m space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two ICl2 clusters. In each ICl2 cluster, I(1) is bonded in a linear geometry to two equivalent Cl(1) atoms. Both I(1)-Cl(1) bond lengths are 2.57 Å. Cl(1) is bonded in a single-bond geometry to one I(1) atom.