CePdSn crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 11-coordinate geometry to one Pd(2), four equivalent Pd(1), and six equivalent Sn(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Sn(1) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Sn(1) atoms. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.
CePdSn crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 11-coordinate geometry to one Pd(2), four equivalent Pd(1), and six equivalent Sn(1) atoms. The Ce(1)-Pd(2) bond length is 3.13 Å. All Ce(1)-Pd(1) bond lengths are 3.08 Å. There are two shorter (3.28 Å) and four longer (3.43 Å) Ce(1)-Sn(1) bond lengths. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Sn(1) atoms. All Pd(1)-Sn(1) bond lengths are 2.88 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Sn(1) atoms. All Pd(2)-Sn(1) bond lengths are 2.81 Å. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.