ThCuPO is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Th(1) is bonded in a 4-coordinate geometry to four equivalent P(1) and four equivalent O(1) atoms. Cu(1) is bonded to four equivalent P(1) atoms to form a mixture of edge and corner-sharing CuP4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent Th(1) and four equivalent Cu(1) atoms. O(1) is bonded to four equivalent Th(1) atoms to form a mixture of edge and corner-sharing OTh4 tetrahedra.
ThCuPO is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Th(1) is bonded in a 4-coordinate geometry to four equivalent P(1) and four equivalent O(1) atoms. All Th(1)-P(1) bond lengths are 3.08 Å. All Th(1)-O(1) bond lengths are 2.40 Å. Cu(1) is bonded to four equivalent P(1) atoms to form a mixture of edge and corner-sharing CuP4 tetrahedra. All Cu(1)-P(1) bond lengths are 2.41 Å. P(1) is bonded in a 8-coordinate geometry to four equivalent Th(1) and four equivalent Cu(1) atoms. O(1) is bonded to four equivalent Th(1) atoms to form a mixture of edge and corner-sharing OTh4 tetrahedra.