CNH3S(OCl)2 is alpha U structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four n,n-dichloromethanesulfonamide molecules. C(1) is bonded in a trigonal non-coplanar geometry to one H(2), two equivalent H(1), and one S(1) atom. N(1) is bonded in a trigonal non-coplanar geometry to one S(1) and two equivalent Cl(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one N(1) atom.
CNH3S(OCl)2 is alpha U structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four n,n-dichloromethanesulfonamide molecules. C(1) is bonded in a trigonal non-coplanar geometry to one H(2), two equivalent H(1), and one S(1) atom. The C(1)-H(2) bond length is 1.10 Å. Both C(1)-H(1) bond lengths are 1.10 Å. The C(1)-S(1) bond length is 1.78 Å. N(1) is bonded in a trigonal non-coplanar geometry to one S(1) and two equivalent Cl(1) atoms. The N(1)-S(1) bond length is 1.79 Å. Both N(1)-Cl(1) bond lengths are 1.75 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), and two equivalent O(1) atoms. Both S(1)-O(1) bond lengths are 1.44 Å. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one N(1) atom.