NaPdPS4 crystallizes in the tetragonal I4/mcm space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent S(1) atoms. P(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded to two equivalent Na(1), one Pd(1), and one P(1) atom to form a mixture of corner and edge-sharing SNa2PPd trigonal pyramids.
NaPdPS4 crystallizes in the tetragonal I4/mcm space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. All Na(1)-S(1) bond lengths are 3.15 Å. Pd(1) is bonded in a square co-planar geometry to four equivalent S(1) atoms. All Pd(1)-S(1) bond lengths are 2.36 Å. P(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All P(1)-S(1) bond lengths are 2.06 Å. S(1) is bonded to two equivalent Na(1), one Pd(1), and one P(1) atom to form a mixture of corner and edge-sharing SNa2PPd trigonal pyramids.