ReVO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic C2/m space group. V(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form VO6 octahedra that share corners with eight equivalent Re(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-51°. Re(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-51°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Re(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Re(1) atom.
ReVO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic C2/m space group. V(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form VO6 octahedra that share corners with eight equivalent Re(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-51°. The V(1)-O(1) bond length is 1.95 Å. The V(1)-O(2) bond length is 1.98 Å. There are two shorter (1.95 Å) and two longer (1.96 Å) V(1)-O(3) bond lengths. Re(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-51°. Both Re(1)-O(1) bond lengths are 1.97 Å. Both Re(1)-O(2) bond lengths are 2.03 Å. Both Re(1)-O(3) bond lengths are 1.95 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Re(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Re(1) atom.