Ga3Zr2 crystallizes in the orthorhombic Fdd2 space group. Zr(1) is bonded in a 9-coordinate geometry to three equivalent Ga(1) and six equivalent Ga(2) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1) and four equivalent Ga(2) atoms. In the second Ga site, Ga(2) is bonded in a 10-coordinate geometry to six equivalent Zr(1), two equivalent Ga(1), and two equivalent Ga(2) atoms.
Ga3Zr2 crystallizes in the orthorhombic Fdd2 space group. Zr(1) is bonded in a 9-coordinate geometry to three equivalent Ga(1) and six equivalent Ga(2) atoms. There are a spread of Zr(1)-Ga(1) bond distances ranging from 2.83-3.18 Å. There are a spread of Zr(1)-Ga(2) bond distances ranging from 2.84-3.02 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1) and four equivalent Ga(2) atoms. There are two shorter (2.59 Å) and two longer (2.67 Å) Ga(1)-Ga(2) bond lengths. In the second Ga site, Ga(2) is bonded in a 10-coordinate geometry to six equivalent Zr(1), two equivalent Ga(1), and two equivalent Ga(2) atoms. Both Ga(2)-Ga(2) bond lengths are 2.74 Å.