MgLa2WO6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. O(1) is bonded in a 3-coordinate geometry to one Mg(1), three equivalent La(1), and one W(1) atom.
MgLa2WO6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. All Mg(1)-O(1) bond lengths are 2.08 Å. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. There are a spread of La(1)-O(1) bond distances ranging from 2.39-2.89 Å. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 28°. All W(1)-O(1) bond lengths are 2.07 Å. O(1) is bonded in a 3-coordinate geometry to one Mg(1), three equivalent La(1), and one W(1) atom.