AsF5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two AsF5 clusters. As(1) is bonded in a trigonal bipyramidal geometry to two equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom.
AsF5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two AsF5 clusters. As(1) is bonded in a trigonal bipyramidal geometry to two equivalent F(1) and three equivalent F(2) atoms. Both As(1)-F(1) bond lengths are 1.73 Å. All As(1)-F(2) bond lengths are 1.69 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom.