O7Cl2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four O7Cl2 clusters. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Cl(1) atoms. In the third O site, O(3,4) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded to one O(1); one O(2); and two equivalent O(3,4) atoms to form corner-sharing ClO4 tetrahedra.
O7Cl2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four O7Cl2 clusters. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. The O(1)-Cl(1) bond length is 1.40 Å. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Cl(1) atoms. Both O(2)-Cl(1) bond lengths are 1.74 Å. In the third O site, O(3,4) is bonded in a single-bond geometry to one Cl(1) atom. The O(3,4)-Cl(1) bond length is 1.41 Å. Cl(1) is bonded to one O(1); one O(2); and two equivalent O(3,4) atoms to form corner-sharing ClO4 tetrahedra.