CaWF4 crystallizes in the tetragonal I4/mcm space group. Ca(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. W(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a trigonal planar geometry to two equivalent Ca(1) and one W(1) atom.
CaWF4 crystallizes in the tetragonal I4/mcm space group. Ca(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. All Ca(1)-F(1) bond lengths are 2.41 Å. W(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All W(1)-F(1) bond lengths are 2.16 Å. F(1) is bonded in a trigonal planar geometry to two equivalent Ca(1) and one W(1) atom.