YWO2 crystallizes in the tetragonal I4_1/amd space group. Y(1) is bonded to six equivalent O(1) atoms to form edge-sharing YO6 octahedra. W(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Y(1) and two equivalent W(1) atoms to form a mixture of distorted edge and corner-sharing OY3W2 trigonal bipyramids.
YWO2 crystallizes in the tetragonal I4_1/amd space group. Y(1) is bonded to six equivalent O(1) atoms to form edge-sharing YO6 octahedra. There are two shorter (2.38 Å) and four longer (2.42 Å) Y(1)-O(1) bond lengths. W(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All W(1)-O(1) bond lengths are 2.23 Å. O(1) is bonded to three equivalent Y(1) and two equivalent W(1) atoms to form a mixture of distorted edge and corner-sharing OY3W2 trigonal bipyramids.