AlSO6(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 7782-44-7 molecules inside a AlSO6 framework. In the AlSO6 framework, Al(1) is bonded to one O(1), one O(4), one O(6), and one O(8) atom to form AlO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Al(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Al(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Al(1) and one O(1) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one O(4) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Al(1) and one S(1) atom.
AlSO6(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 7782-44-7 molecules inside a AlSO6 framework. In the AlSO6 framework, Al(1) is bonded to one O(1), one O(4), one O(6), and one O(8) atom to form AlO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. The Al(1)-O(1) bond length is 1.87 Å. The Al(1)-O(4) bond length is 1.86 Å. The Al(1)-O(6) bond length is 1.76 Å. The Al(1)-O(8) bond length is 1.75 Å. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Al(1)O4 tetrahedra. The S(1)-O(6) bond length is 1.57 Å. The S(1)-O(7) bond length is 1.44 Å. The S(1)-O(8) bond length is 1.56 Å. The S(1)-O(9) bond length is 1.44 Å. There are six inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Al(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Al(1) and one O(1) atom. The O(1)-O(1) bond length is 1.39 Å. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one O(4) atom. The O(4)-O(4) bond length is 1.38 Å. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Al(1) and one S(1) atom.