FeNF4(NF)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and one FeNF4 cluster. In the FeNF4 cluster, Fe(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), one F(4), and one F(6) atom. N(1) is bonded in a single-bond geometry to one F(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Fe(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Fe(1) and one N(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Fe(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Fe(1) atom.
FeNF4(NF)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and one FeNF4 cluster. In the FeNF4 cluster, Fe(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), one F(4), and one F(6) atom. The Fe(1)-F(1) bond length is 1.79 Å. The Fe(1)-F(2) bond length is 2.51 Å. The Fe(1)-F(4) bond length is 1.79 Å. The Fe(1)-F(6) bond length is 1.79 Å. N(1) is bonded in a single-bond geometry to one F(2) atom. The N(1)-F(2) bond length is 1.37 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Fe(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Fe(1) and one N(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Fe(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Fe(1) atom.