Ti3SnH is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ti(1) is bonded in a linear geometry to four equivalent Sn(1) and two equivalent H(1) atoms. Sn(1) is bonded to twelve equivalent Ti(1) atoms to form SnTi12 cuboctahedra that share corners with twelve equivalent Sn(1)Ti12 cuboctahedra, faces with six equivalent Sn(1)Ti12 cuboctahedra, and faces with eight equivalent H(1)Ti6 octahedra. H(1) is bonded to six equivalent Ti(1) atoms to form HTi6 octahedra that share corners with six equivalent H(1)Ti6 octahedra and faces with eight equivalent Sn(1)Ti12 cuboctahedra. The corner-sharing octahedra are not tilted.
Ti3SnH is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ti(1) is bonded in a linear geometry to four equivalent Sn(1) and two equivalent H(1) atoms. All Ti(1)-Sn(1) bond lengths are 2.95 Å. Both Ti(1)-H(1) bond lengths are 2.08 Å. Sn(1) is bonded to twelve equivalent Ti(1) atoms to form SnTi12 cuboctahedra that share corners with twelve equivalent Sn(1)Ti12 cuboctahedra, faces with six equivalent Sn(1)Ti12 cuboctahedra, and faces with eight equivalent H(1)Ti6 octahedra. H(1) is bonded to six equivalent Ti(1) atoms to form HTi6 octahedra that share corners with six equivalent H(1)Ti6 octahedra and faces with eight equivalent Sn(1)Ti12 cuboctahedra. The corner-sharing octahedra are not tilted.