Ag3P3O10 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(4), one O(5), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(4) and two equivalent O(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(5), one O(6), and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(2) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one P(2) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to two equivalent Ag(1) atoms. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent P(1) atoms. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one P(1) atom.
Ag3P3O10 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(4), one O(5), and one O(7) atom. The Ag(1)-O(3) bond length is 2.22 Å. The Ag(1)-O(4) bond length is 2.46 Å. The Ag(1)-O(5) bond length is 2.36 Å. The Ag(1)-O(7) bond length is 2.04 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(4) and two equivalent O(6) atoms. Both Ag(2)-O(4) bond lengths are 2.51 Å. Both Ag(2)-O(6) bond lengths are 2.39 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. The P(1)-O(1) bond length is 1.61 Å. The P(1)-O(2) bond length is 1.63 Å. The P(1)-O(3) bond length is 1.50 Å. The P(1)-O(4) bond length is 1.52 Å. In the second P site, P(2) is bonded to one O(5), one O(6), and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. The P(2)-O(5) bond length is 1.51 Å. The P(2)-O(6) bond length is 1.50 Å. Both P(2)-O(2) bond lengths are 1.63 Å. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(2) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one P(2) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to two equivalent Ag(1) atoms. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent P(1) atoms. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one P(1) atom.