ReO2 is beta Vanadium nitride-like structured and crystallizes in the tetragonal P4_2/mnm space group. Re(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles are 42°. O(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms.
ReO2 is beta Vanadium nitride-like structured and crystallizes in the tetragonal P4_2/mnm space group. Re(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are two shorter (1.97 Å) and four longer (2.04 Å) Re(1)-O(1) bond lengths. O(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms.