ReO2 is beta Vanadium nitride-like structured and crystallizes in the orthorhombic Pbcn space group. Re(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. O(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms.
ReO2 is beta Vanadium nitride-like structured and crystallizes in the orthorhombic Pbcn space group. Re(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. There are two shorter (1.99 Å) and four longer (2.02 Å) Re(1)-O(1) bond lengths. O(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms.