LiMoO2 is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the orthorhombic Pnnm space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra, corners with eight equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with four equivalent Mo(1)O6 octahedra, and faces with two equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. Mo(1) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with eight equivalent Mo(1)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and faces with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. O(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Mo(1) atoms.
LiMoO2 is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the orthorhombic Pnnm space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra, corners with eight equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with four equivalent Mo(1)O6 octahedra, and faces with two equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. There are two shorter (2.07 Å) and four longer (2.30 Å) Li(1)-O(1) bond lengths. Mo(1) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with eight equivalent Mo(1)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and faces with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. There are four shorter (2.18 Å) and two longer (2.19 Å) Mo(1)-O(1) bond lengths. O(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Mo(1) atoms.