Na2W6PdS2(NO3)2 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a distorted trigonal planar geometry to one N(1), one O(2), and one O(3) atom. There are three inequivalent W sites. In the first W site, W(1) is bonded in a single-bond geometry to one O(3) atom. In the second W site, W(2) is bonded in a bent 150 degrees geometry to one N(1) and one O(1) atom. In the third W site, W(3) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. Pd(1) is bonded in a distorted linear geometry to two equivalent S(1) atoms. N(1) is bonded in a trigonal non-coplanar geometry to one Na(1), one W(2), and one W(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(2), one W(3), and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one S(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Na(1), one W(1), and one S(1) atom.
Na2W6PdS2(NO3)2 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a distorted trigonal planar geometry to one N(1), one O(2), and one O(3) atom. The Na(1)-N(1) bond length is 2.37 Å. The Na(1)-O(2) bond length is 2.23 Å. The Na(1)-O(3) bond length is 2.36 Å. There are three inequivalent W sites. In the first W site, W(1) is bonded in a single-bond geometry to one O(3) atom. The W(1)-O(3) bond length is 2.26 Å. In the second W site, W(2) is bonded in a bent 150 degrees geometry to one N(1) and one O(1) atom. The W(2)-N(1) bond length is 1.96 Å. The W(2)-O(1) bond length is 2.22 Å. In the third W site, W(3) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. The W(3)-N(1) bond length is 1.86 Å. The W(3)-O(1) bond length is 2.19 Å. Pd(1) is bonded in a distorted linear geometry to two equivalent S(1) atoms. Both Pd(1)-S(1) bond lengths are 2.27 Å. N(1) is bonded in a trigonal non-coplanar geometry to one Na(1), one W(2), and one W(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.64 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.55 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(2), one W(3), and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one S(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Na(1), one W(1), and one S(1) atom.