Rb3H6Te(O2Cl)3 crystallizes in the trigonal R-3c space group. Rb(1) is bonded in a 5-coordinate geometry to two equivalent O(1) and three equivalent Cl(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 1-coordinate geometry to one Rb(1), one H(1), and one Te(1) atom. Cl(1) is bonded in a distorted T-shaped geometry to three equivalent Rb(1) atoms.
Rb3H6Te(O2Cl)3 crystallizes in the trigonal R-3c space group. Rb(1) is bonded in a 5-coordinate geometry to two equivalent O(1) and three equivalent Cl(1) atoms. Both Rb(1)-O(1) bond lengths are 3.04 Å. There are two shorter (3.25 Å) and one longer (3.28 Å) Rb(1)-Cl(1) bond length. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Te(1)-O(1) bond lengths are 1.96 Å. O(1) is bonded in a 1-coordinate geometry to one Rb(1), one H(1), and one Te(1) atom. Cl(1) is bonded in a distorted T-shaped geometry to three equivalent Rb(1) atoms.