(NdN2O7)2(NO3)2(O2)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of five hydrogen peroxide molecules, two nitric acid molecules, and two NdN2O7 clusters. In each NdN2O7 cluster, Nd(1) is bonded in a 4-coordinate geometry to one N(2), one O(3), one O(8), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one O(11), one O(7), and one O(8) atom. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Nd(1), one O(1), one O(13), and one O(3) atom. There are seven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Nd(1) and one N(2) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one N(1) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one Nd(1) atom. In the seventh O site, O(11) is bonded in a single-bond geometry to one N(1) atom.
(NdN2O7)2(NO3)2(O2)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of five hydrogen peroxide molecules, two nitric acid molecules, and two NdN2O7 clusters. In each NdN2O7 cluster, Nd(1) is bonded in a 4-coordinate geometry to one N(2), one O(3), one O(8), and one O(9) atom. The Nd(1)-N(2) bond length is 2.14 Å. The Nd(1)-O(3) bond length is 1.80 Å. The Nd(1)-O(8) bond length is 2.49 Å. The Nd(1)-O(9) bond length is 2.12 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one O(11), one O(7), and one O(8) atom. The N(1)-O(11) bond length is 0.88 Å. The N(1)-O(7) bond length is 1.40 Å. The N(1)-O(8) bond length is 1.43 Å. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Nd(1), one O(1), one O(13), and one O(3) atom. The N(2)-O(1) bond length is 0.91 Å. The N(2)-O(13) bond length is 1.44 Å. The N(2)-O(3) bond length is 1.85 Å. There are seven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Nd(1) and one N(2) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one N(1) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one Nd(1) atom. In the seventh O site, O(11) is bonded in a single-bond geometry to one N(1) atom.