CF3N2Se2SSO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules, four trifluoromethane molecules, and four N2Se2S clusters. In each N2Se2S cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(2) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom.
CF3N2Se2SSO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules, four trifluoromethane molecules, and four N2Se2S clusters. In each N2Se2S cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one S(1) atom. The N(1)-Se(2) bond length is 1.80 Å. The N(1)-S(1) bond length is 1.57 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. The N(2)-Se(1) bond length is 1.80 Å. The N(2)-S(1) bond length is 1.57 Å. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(2) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom.