Rb2LiPu(OCl2)2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a distorted body-centered cubic geometry to eight equivalent Cl(1) atoms. Li(1) is bonded in a distorted octahedral geometry to two equivalent O(1) and four equivalent Cl(1) atoms. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. O(1) is bonded in a water-like geometry to one Li(1) and one Pu(1) atom. Cl(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Li(1), and one Pu(1) atom.
Rb2LiPu(OCl2)2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a distorted body-centered cubic geometry to eight equivalent Cl(1) atoms. There are a spread of Rb(1)-Cl(1) bond distances ranging from 3.43-3.69 Å. Li(1) is bonded in a distorted octahedral geometry to two equivalent O(1) and four equivalent Cl(1) atoms. Both Li(1)-O(1) bond lengths are 2.03 Å. All Li(1)-Cl(1) bond lengths are 2.76 Å. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. Both Pu(1)-O(1) bond lengths are 1.83 Å. All Pu(1)-Cl(1) bond lengths are 2.75 Å. O(1) is bonded in a water-like geometry to one Li(1) and one Pu(1) atom. Cl(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Li(1), and one Pu(1) atom.