SrAg2C4(N2O)2 crystallizes in the orthorhombic Pbcm space group. Sr(1) is bonded in a 9-coordinate geometry to two equivalent N(1), four equivalent N(2), one O(2), and two equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Ag(2) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(2) atom. In the second N site, N(1) is bonded in a linear geometry to one Sr(1) and one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Sr(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Sr(1) atom.
SrAg2C4(N2O)2 crystallizes in the orthorhombic Pbcm space group. Sr(1) is bonded in a 9-coordinate geometry to two equivalent N(1), four equivalent N(2), one O(2), and two equivalent O(1) atoms. Both Sr(1)-N(1) bond lengths are 2.62 Å. There are two shorter (2.73 Å) and two longer (2.99 Å) Sr(1)-N(2) bond lengths. The Sr(1)-O(2) bond length is 2.69 Å. There is one shorter (2.63 Å) and one longer (2.71 Å) Sr(1)-O(1) bond length. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. Both Ag(1)-C(1) bond lengths are 2.04 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent C(2) atoms. Both Ag(2)-C(2) bond lengths are 2.06 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a linear geometry to one Ag(2) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(2) atom. In the second N site, N(1) is bonded in a linear geometry to one Sr(1) and one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Sr(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Sr(1) atom.