Rb6MoN4 crystallizes in the tetragonal P4_2/nmc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) atoms. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. Mo(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to one Rb(1), four equivalent Rb(2), and one Mo(1) atom.
Rb6MoN4 crystallizes in the tetragonal P4_2/nmc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) atoms. Both Rb(1)-N(1) bond lengths are 2.88 Å. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. There are two shorter (2.87 Å) and two longer (3.12 Å) Rb(2)-N(1) bond lengths. Mo(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All Mo(1)-N(1) bond lengths are 1.92 Å. N(1) is bonded in a 6-coordinate geometry to one Rb(1), four equivalent Rb(2), and one Mo(1) atom.