LaLiBi2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal P4/nmm space group. Li(1) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing LiBi4 tetrahedra. La(1) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent Bi(2) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to four equivalent Li(1) and four equivalent La(1) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Bi(2) atoms.
LaLiBi2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal P4/nmm space group. Li(1) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing LiBi4 tetrahedra. All Li(1)-Bi(1) bond lengths are 2.87 Å. La(1) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent Bi(2) atoms. All La(1)-Bi(1) bond lengths are 3.41 Å. All La(1)-Bi(2) bond lengths are 3.51 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to four equivalent Li(1) and four equivalent La(1) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Bi(2) atoms. All Bi(2)-Bi(2) bond lengths are 3.22 Å.