Sr2ScOsO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Sr(1) is bonded to twelve equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Sc(1)O6 octahedra, and faces with four equivalent Os(1)O6 octahedra. Sc(1) is bonded to six equivalent O(1) atoms to form ScO6 octahedra that share corners with six equivalent Os(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Os(1) is bonded to six equivalent O(1) atoms to form OsO6 octahedra that share corners with six equivalent Sc(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Sr(1), one Sc(1), and one Os(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4ScOs octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
Sr2ScOsO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Sr(1) is bonded to twelve equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Sc(1)O6 octahedra, and faces with four equivalent Os(1)O6 octahedra. All Sr(1)-O(1) bond lengths are 2.86 Å. Sc(1) is bonded to six equivalent O(1) atoms to form ScO6 octahedra that share corners with six equivalent Os(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Sc(1)-O(1) bond lengths are 2.08 Å. Os(1) is bonded to six equivalent O(1) atoms to form OsO6 octahedra that share corners with six equivalent Sc(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Os(1)-O(1) bond lengths are 1.97 Å. O(1) is bonded to four equivalent Sr(1), one Sc(1), and one Os(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4ScOs octahedra. The corner-sharing octahedral tilt angles range from 0-60°.