Li2AgF5 crystallizes in the orthorhombic Cmcm space group. Li(1) is bonded in a 6-coordinate geometry to one F(3), two equivalent F(2), and three equivalent F(1) atoms. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are three inequivalent F sites. In the first F site, F(1) is bonded to three equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing FLi3Ag trigonal pyramids. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms.
Li2AgF5 crystallizes in the orthorhombic Cmcm space group. Li(1) is bonded in a 6-coordinate geometry to one F(3), two equivalent F(2), and three equivalent F(1) atoms. The Li(1)-F(3) bond length is 1.81 Å. There is one shorter (1.94 Å) and one longer (1.96 Å) Li(1)-F(2) bond length. There are two shorter (2.22 Å) and one longer (2.51 Å) Li(1)-F(1) bond length. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 47°. Both Ag(1)-F(1) bond lengths are 1.98 Å. Both Ag(1)-F(2) bond lengths are 1.93 Å. Both Ag(1)-F(3) bond lengths are 2.37 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded to three equivalent Li(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing FLi3Ag trigonal pyramids. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms.