PtCl6((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dimethylazanium molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.
PtCl6((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dimethylazanium molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. Both Pt(1)-Cl(2) bond lengths are 2.37 Å. All Pt(1)-Cl(1) bond lengths are 2.36 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.