Tl2S2O3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TlS2O3 clusters. In each TlS2O3 cluster, Tl(2) is bonded in a distorted single-bond geometry to one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one S(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Tl(2) and one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom.
Tl2S2O3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TlS2O3 clusters. In each TlS2O3 cluster, Tl(2) is bonded in a distorted single-bond geometry to one O(1) atom. The Tl(2)-O(1) bond length is 2.79 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one S(2) atom. The S(1)-S(2) bond length is 2.06 Å. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(1), and two equivalent O(2) atoms. The S(2)-O(1) bond length is 1.49 Å. Both S(2)-O(2) bond lengths are 1.48 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Tl(2) and one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom.