NaSbCl6 crystallizes in the tetragonal P4_2/m space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a water-like geometry to one Na(1) and one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Sb(1) atom.
NaSbCl6 crystallizes in the tetragonal P4_2/m space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Cl(1) and four equivalent Cl(2) atoms. All Na(1)-Cl(1) bond lengths are 3.25 Å. All Na(1)-Cl(2) bond lengths are 2.81 Å. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(2) atoms. Both Sb(1)-Cl(1) bond lengths are 2.39 Å. All Sb(1)-Cl(2) bond lengths are 2.39 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a water-like geometry to one Na(1) and one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Sb(1) atom.