CuSnO6 crystallizes in the orthorhombic Pnn2 space group. Cu(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. Sn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with six equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cu(1), one Sn(1), and one O(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cu(1), one Sn(1), and one O(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cu(1), one Sn(1), and one O(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one Sn(1), and one O(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one Sn(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one Sn(1) atom.
CuSnO6 crystallizes in the orthorhombic Pnn2 space group. Cu(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. The Cu(1)-O(1) bond length is 2.23 Å. The Cu(1)-O(2) bond length is 2.22 Å. The Cu(1)-O(3) bond length is 2.20 Å. The Cu(1)-O(4) bond length is 2.19 Å. The Cu(1)-O(5) bond length is 1.80 Å. The Cu(1)-O(6) bond length is 1.80 Å. Sn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with six equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. The Sn(1)-O(1) bond length is 2.29 Å. The Sn(1)-O(2) bond length is 2.28 Å. The Sn(1)-O(3) bond length is 2.25 Å. The Sn(1)-O(4) bond length is 2.27 Å. The Sn(1)-O(5) bond length is 1.96 Å. The Sn(1)-O(6) bond length is 1.93 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cu(1), one Sn(1), and one O(2) atom. The O(1)-O(2) bond length is 1.38 Å. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cu(1), one Sn(1), and one O(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cu(1), one Sn(1), and one O(4) atom. The O(3)-O(4) bond length is 1.40 Å. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one Sn(1), and one O(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one Sn(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one Sn(1) atom.