CsVTeO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form distorted CsO6 octahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-74°. V(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-74°. Te(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-71°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one Te(1) atom.
CsVTeO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form distorted CsO6 octahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 66-74°. The Cs(1)-O(1) bond length is 3.07 Å. The Cs(1)-O(2) bond length is 3.26 Å. All Cs(1)-O(3) bond lengths are 3.13 Å. V(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-74°. Both V(1)-O(2) bond lengths are 1.85 Å. All V(1)-O(3) bond lengths are 1.92 Å. Te(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-71°. Both Te(1)-O(1) bond lengths are 1.98 Å. All Te(1)-O(3) bond lengths are 1.93 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one Te(1) atom.