CeO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Ce(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing CeO6 octahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a trigonal planar geometry to three equivalent Ce(1) atoms.
CeO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Ce(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing CeO6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Ce(1)-O(1) bond lengths are 2.27 Å. O(1) is bonded in a trigonal planar geometry to three equivalent Ce(1) atoms.