TiS2 is Hydrophilite-like structured and crystallizes in the cubic Pa-3 space group. Ti(1) is bonded to six equivalent S(1) atoms to form corner-sharing TiS6 octahedra. The corner-sharing octahedral tilt angles are 61°. S(1) is bonded in a trigonal planar geometry to three equivalent Ti(1) atoms.
TiS2 is Hydrophilite-like structured and crystallizes in the cubic Pa-3 space group. Ti(1) is bonded to six equivalent S(1) atoms to form corner-sharing TiS6 octahedra. The corner-sharing octahedral tilt angles are 61°. All Ti(1)-S(1) bond lengths are 2.47 Å. S(1) is bonded in a trigonal planar geometry to three equivalent Ti(1) atoms.