V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(4), two equivalent O(1), one F(1), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(4)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second V site, V(2) is bonded to one O(3), one O(5), two equivalent O(1), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the third V site, V(3) is bonded to one O(4), one O(5), two equivalent O(2), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the fourth V site, V(4) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent F(4) atoms to form distorted VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the fifth V site, V(5) is bonded to two equivalent O(1), two equivalent O(2), one F(2), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the sixth V site, V(6) is bonded to one O(3), one O(4), one F(2), one F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom.
V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(4), two equivalent O(1), one F(1), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(4)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. The V(1)-O(4) bond length is 1.91 Å. Both V(1)-O(1) bond lengths are 1.98 Å. The V(1)-F(1) bond length is 2.10 Å. Both V(1)-F(4) bond lengths are 2.15 Å. In the second V site, V(2) is bonded to one O(3), one O(5), two equivalent O(1), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. The V(2)-O(3) bond length is 2.10 Å. The V(2)-O(5) bond length is 2.17 Å. Both V(2)-O(1) bond lengths are 1.96 Å. The V(2)-F(1) bond length is 2.05 Å. The V(2)-F(3) bond length is 2.05 Å. In the third V site, V(3) is bonded to one O(4), one O(5), two equivalent O(2), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. The V(3)-O(4) bond length is 2.02 Å. The V(3)-O(5) bond length is 1.95 Å. Both V(3)-O(2) bond lengths are 2.01 Å. The V(3)-F(1) bond length is 2.17 Å. The V(3)-F(2) bond length is 2.10 Å. In the fourth V site, V(4) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent F(4) atoms to form distorted VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. The V(4)-O(3) bond length is 1.93 Å. The V(4)-O(5) bond length is 1.91 Å. Both V(4)-O(2) bond lengths are 1.88 Å. Both V(4)-F(4) bond lengths are 2.26 Å. In the fifth V site, V(5) is bonded to two equivalent O(1), two equivalent O(2), one F(2), and one F(3) atom to form VO4F2 octahedra that share corners with two equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. Both V(5)-O(1) bond lengths are 1.96 Å. Both V(5)-O(2) bond lengths are 2.04 Å. The V(5)-F(2) bond length is 2.05 Å. The V(5)-F(3) bond length is 2.05 Å. In the sixth V site, V(6) is bonded to one O(3), one O(4), one F(2), one F(3), and two equivalent F(4) atoms to form VO2F4 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with three equivalent V(1)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 51-58°. The V(6)-O(3) bond length is 2.03 Å. The V(6)-O(4) bond length is 1.96 Å. The V(6)-F(2) bond length is 2.05 Å. The V(6)-F(3) bond length is 2.04 Å. Both V(6)-F(4) bond lengths are 2.01 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom.