CoN14CoN10 is alpha structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN10 cluster and one CoN14 cluster. In the CoN10 cluster, Co(2) is bonded in an octahedral geometry to two equivalent N(11), two equivalent N(12), and two equivalent N(7) atoms. There are five inequivalent N sites. In the first N site, N(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one N(8) atom. In the second N site, N(8) is bonded in a linear geometry to one N(7) and one N(9) atom. In the third N site, N(9) is bonded in a single-bond geometry to one N(8) atom. In the fourth N site, N(11) is bonded in a single-bond geometry to one Co(2) atom. In the fifth N site, N(12) is bonded in a single-bond geometry to one Co(2) atom. In the CoN14 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(10), and two equivalent N(4) atoms. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Co(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(10) is bonded in a single-bond geometry to one Co(1) atom.
CoN14CoN10 is alpha structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN10 cluster and one CoN14 cluster. In the CoN10 cluster, Co(2) is bonded in an octahedral geometry to two equivalent N(11), two equivalent N(12), and two equivalent N(7) atoms. Both Co(2)-N(11) bond lengths are 1.91 Å. Both Co(2)-N(12) bond lengths are 1.90 Å. Both Co(2)-N(7) bond lengths are 1.87 Å. There are five inequivalent N sites. In the first N site, N(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one N(8) atom. The N(7)-N(8) bond length is 1.22 Å. In the second N site, N(8) is bonded in a linear geometry to one N(7) and one N(9) atom. The N(8)-N(9) bond length is 1.16 Å. In the third N site, N(9) is bonded in a single-bond geometry to one N(8) atom. In the fourth N site, N(11) is bonded in a single-bond geometry to one Co(2) atom. In the fifth N site, N(12) is bonded in a single-bond geometry to one Co(2) atom. In the CoN14 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(10), and two equivalent N(4) atoms. Both Co(1)-N(1) bond lengths are 1.89 Å. Both Co(1)-N(10) bond lengths are 1.92 Å. Both Co(1)-N(4) bond lengths are 1.92 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one N(2) atom. The N(1)-N(2) bond length is 1.22 Å. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.16 Å. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Co(1) and one N(5) atom. The N(4)-N(5) bond length is 1.22 Å. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.16 Å. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(10) is bonded in a single-bond geometry to one Co(1) atom.