NaClO3 crystallizes in the triclinic P1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(8), one Cl(2), and one Cl(4) atom. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(5), one O(6), one O(7), one Cl(3), and one Cl(4) atom. In the third Na site, Na(3) is bonded in a 9-coordinate geometry to one O(12), one O(2), one O(5), one O(6), one O(8), one O(9), one Cl(1), one Cl(2), and one Cl(3) atom. In the fourth Na site, Na(4) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(9), one Cl(1), one Cl(3), and one Cl(4) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one Na(4), and one O(4) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(3), one Na(4), and one O(12) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Na(4) and one O(11) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Na(4) and one O(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), and one O(9) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(2), one Na(3), and one O(8) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Na(2) and one O(10) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Na(3), and one O(6) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Na(3), one Na(4), and one O(5) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(7) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to one Na(1) and one O(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Na(3), and one O(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to one Na(3) and one Na(4) atom. In the second Cl site, Cl(2) is bonded in a distorted linear geometry to one Na(1) and one Na(3) atom. In the third Cl site, Cl(3) is bonded in a distorted linear geometry to one Na(2), one Na(3), and one Na(4) atom. In the fourth Cl site, Cl(4) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one Na(4) atom.
NaClO3 crystallizes in the triclinic P1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(8), one Cl(2), and one Cl(4) atom. The Na(1)-O(10) bond length is 2.79 Å. The Na(1)-O(11) bond length is 2.53 Å. The Na(1)-O(12) bond length is 2.58 Å. The Na(1)-O(8) bond length is 2.83 Å. The Na(1)-Cl(2) bond length is 2.75 Å. The Na(1)-Cl(4) bond length is 2.58 Å. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(5), one O(6), one O(7), one Cl(3), and one Cl(4) atom. The Na(2)-O(1) bond length is 2.78 Å. The Na(2)-O(5) bond length is 2.86 Å. The Na(2)-O(6) bond length is 2.58 Å. The Na(2)-O(7) bond length is 2.53 Å. The Na(2)-Cl(3) bond length is 2.73 Å. The Na(2)-Cl(4) bond length is 2.57 Å. In the third Na site, Na(3) is bonded in a 9-coordinate geometry to one O(12), one O(2), one O(5), one O(6), one O(8), one O(9), one Cl(1), one Cl(2), and one Cl(3) atom. The Na(3)-O(12) bond length is 2.96 Å. The Na(3)-O(2) bond length is 2.92 Å. The Na(3)-O(5) bond length is 2.88 Å. The Na(3)-O(6) bond length is 2.97 Å. The Na(3)-O(8) bond length is 2.87 Å. The Na(3)-O(9) bond length is 2.95 Å. The Na(3)-Cl(1) bond length is 2.77 Å. The Na(3)-Cl(2) bond length is 2.74 Å. The Na(3)-Cl(3) bond length is 2.75 Å. In the fourth Na site, Na(4) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(9), one Cl(1), one Cl(3), and one Cl(4) atom. The Na(4)-O(1) bond length is 2.77 Å. The Na(4)-O(2) bond length is 2.83 Å. The Na(4)-O(3) bond length is 2.77 Å. The Na(4)-O(4) bond length is 2.60 Å. The Na(4)-O(9) bond length is 2.51 Å. The Na(4)-Cl(1) bond length is 2.71 Å. The Na(4)-Cl(3) bond length is 3.26 Å. The Na(4)-Cl(4) bond length is 2.55 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(2), one Na(4), and one O(4) atom. The O(1)-O(4) bond length is 1.24 Å. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(3), one Na(4), and one O(12) atom. The O(2)-O(12) bond length is 1.24 Å. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Na(4) and one O(11) atom. The O(3)-O(11) bond length is 1.24 Å. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Na(4) and one O(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), and one O(9) atom. The O(5)-O(9) bond length is 1.24 Å. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(2), one Na(3), and one O(8) atom. The O(6)-O(8) bond length is 1.24 Å. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Na(2) and one O(10) atom. The O(7)-O(10) bond length is 1.24 Å. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Na(3), and one O(6) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Na(3), one Na(4), and one O(5) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(7) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to one Na(1) and one O(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Na(3), and one O(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to one Na(3) and one Na(4) atom. In the second Cl site, Cl(2) is bonded in a distorted linear geometry to one Na(1) and one Na(3) atom. In the third Cl site, Cl(3) is bonded in a distorted linear geometry to one Na(2), one Na(3), and one Na(4) atom. In the fourth Cl site, Cl(4) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one Na(4) atom.