(CuOCl3)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules and two CuOCl3 clusters. In each CuOCl3 cluster, Cu(1) is bonded to one O(1), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form distorted edge-sharing CuCl4O square pyramids. O(1) is bonded in a single-bond geometry to one Cu(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Cu(1) atoms.
(CuOCl3)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules and two CuOCl3 clusters. In each CuOCl3 cluster, Cu(1) is bonded to one O(1), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form distorted edge-sharing CuCl4O square pyramids. The Cu(1)-O(1) bond length is 1.91 Å. The Cu(1)-Cl(1) bond length is 2.24 Å. The Cu(1)-Cl(2) bond length is 2.22 Å. There is one shorter (2.29 Å) and one longer (2.34 Å) Cu(1)-Cl(3) bond length. O(1) is bonded in a single-bond geometry to one Cu(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Cu(1) atoms.