CF3CF4(SbF5)2COF is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two carbon tetrafluoride molecules, two formyl fluoride molecules, two trifluoromethane molecules, and two SbF5 clusters. In each SbF5 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form distorted corner-sharing SbF6 octahedra. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(6), one F(7), and one F(8) atom to form distorted corner-sharing SbF5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent F sites. In the first F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom.
CF3CF4(SbF5)2COF is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two carbon tetrafluoride molecules, two formyl fluoride molecules, two trifluoromethane molecules, and two SbF5 clusters. In each SbF5 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form distorted corner-sharing SbF6 octahedra. The Sb(1)-F(1) bond length is 1.90 Å. The Sb(1)-F(2) bond length is 1.89 Å. The Sb(1)-F(3) bond length is 1.90 Å. The Sb(1)-F(4) bond length is 1.90 Å. The Sb(1)-F(5) bond length is 1.89 Å. The Sb(1)-F(6) bond length is 2.32 Å. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(6), one F(7), and one F(8) atom to form distorted corner-sharing SbF5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 35°. The Sb(2)-F(10) bond length is 1.87 Å. The Sb(2)-F(11) bond length is 1.88 Å. The Sb(2)-F(6) bond length is 1.97 Å. The Sb(2)-F(7) bond length is 1.88 Å. The Sb(2)-F(8) bond length is 1.88 Å. There are ten inequivalent F sites. In the first F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom.