(WSbO6)2N2 crystallizes in the orthorhombic Imma space group. The structure consists of four ammonia atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-40°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom.
(WSbO6)2N2 crystallizes in the orthorhombic Imma space group. The structure consists of four ammonia atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-40°. Both W(1)-O(1) bond lengths are 1.95 Å. All W(1)-O(3) bond lengths are 1.93 Å. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. Both Sb(1)-O(2) bond lengths are 1.99 Å. All Sb(1)-O(3) bond lengths are 1.99 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom.