VSi2 is Titanium Disilicide-like structured and crystallizes in the hexagonal P6_222 space group. V(1) is bonded in a distorted q6 geometry to ten equivalent Si(1) atoms. Si(1) is bonded in a 10-coordinate geometry to five equivalent V(1) and five equivalent Si(1) atoms.
VSi2 is Titanium Disilicide-like structured and crystallizes in the hexagonal P6_222 space group. V(1) is bonded in a distorted q6 geometry to ten equivalent Si(1) atoms. There are a spread of V(1)-Si(1) bond distances ranging from 2.49-2.65 Å. Si(1) is bonded in a 10-coordinate geometry to five equivalent V(1) and five equivalent Si(1) atoms. There are a spread of Si(1)-Si(1) bond distances ranging from 2.46-2.65 Å.