EuVO2 crystallizes in the tetragonal I4_1/amd space group. Eu(1) is bonded to six equivalent O(1) atoms to form edge-sharing EuO6 octahedra. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Eu(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OEu3V2 square pyramids.
EuVO2 crystallizes in the tetragonal I4_1/amd space group. Eu(1) is bonded to six equivalent O(1) atoms to form edge-sharing EuO6 octahedra. There are four shorter (2.47 Å) and two longer (2.52 Å) Eu(1)-O(1) bond lengths. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 2.14 Å. O(1) is bonded to three equivalent Eu(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OEu3V2 square pyramids.