LiPb3 is alpha Rhenium trioxide structured and crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded to two equivalent Pb(1) and four equivalent Pb(2) atoms to form corner-sharing LiPb6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a linear geometry to two equivalent Li(1) atoms. In the second Pb site, Pb(2) is bonded in a linear geometry to two equivalent Li(1) atoms.
LiPb3 is alpha Rhenium trioxide structured and crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded to two equivalent Pb(1) and four equivalent Pb(2) atoms to form corner-sharing LiPb6 octahedra. The corner-sharing octahedra are not tilted. Both Li(1)-Pb(1) bond lengths are 2.56 Å. All Li(1)-Pb(2) bond lengths are 2.60 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a linear geometry to two equivalent Li(1) atoms. In the second Pb site, Pb(2) is bonded in a linear geometry to two equivalent Li(1) atoms.