NH2(NH)2P2NH6O6 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia molecules, two ammonia molecules, and one P2NH6O6 cluster. In the P2NH6O6 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. N(4) is bonded in a trigonal non-coplanar geometry to one H(10), one H(6), and one H(7) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(6) is bonded in a distorted linear geometry to one N(4) and one O(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(10) is bonded in a distorted single-bond geometry to one N(4) and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(6) atom. In the third O site, O(3) is bonded in a water-like geometry to one P(1) and one H(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one P(2) and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one H(2) atom.
NH2(NH)2P2NH6O6 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia molecules, two ammonia molecules, and one P2NH6O6 cluster. In the P2NH6O6 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The P(1)-O(1) bond length is 1.60 Å. The P(1)-O(2) bond length is 1.52 Å. The P(1)-O(3) bond length is 1.51 Å. The P(1)-O(4) bond length is 1.63 Å. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. The P(2)-O(4) bond length is 1.65 Å. The P(2)-O(5) bond length is 1.64 Å. The P(2)-O(6) bond length is 1.65 Å. N(4) is bonded in a trigonal non-coplanar geometry to one H(10), one H(6), and one H(7) atom. The N(4)-H(10) bond length is 1.07 Å. The N(4)-H(6) bond length is 1.08 Å. The N(4)-H(7) bond length is 1.04 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 1.02 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. The H(2)-O(6) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 0.99 Å. In the fourth H site, H(6) is bonded in a distorted linear geometry to one N(4) and one O(2) atom. The H(6)-O(2) bond length is 1.59 Å. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(10) is bonded in a distorted single-bond geometry to one N(4) and one O(3) atom. The H(10)-O(3) bond length is 1.64 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(6) atom. In the third O site, O(3) is bonded in a water-like geometry to one P(1) and one H(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one P(2) and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one H(2) atom.