Cs2Zr(AgTe2)2 crystallizes in the orthorhombic C222 space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent Te(1) atoms. Zr(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), and four equivalent Te(1) atoms to form distorted corner-sharing ZrAg4Te4 tetrahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Te(1) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Te(1) atoms. Te(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Zr(1), one Ag(1), and one Ag(2) atom.
Cs2Zr(AgTe2)2 crystallizes in the orthorhombic C222 space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent Te(1) atoms. There are a spread of Cs(1)-Te(1) bond distances ranging from 3.96-4.06 Å. Zr(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), and four equivalent Te(1) atoms to form distorted corner-sharing ZrAg4Te4 tetrahedra. Both Zr(1)-Ag(1) bond lengths are 3.31 Å. Both Zr(1)-Ag(2) bond lengths are 3.31 Å. All Zr(1)-Te(1) bond lengths are 2.76 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Te(1) atoms. All Ag(1)-Te(1) bond lengths are 2.84 Å. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Te(1) atoms. All Ag(2)-Te(1) bond lengths are 2.84 Å. Te(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Zr(1), one Ag(1), and one Ag(2) atom.