NS7 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four heptathiazocine molecules. N(1) is bonded in a bent 150 degrees geometry to two equivalent S(1) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to two equivalent S(3) atoms.
NS7 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four heptathiazocine molecules. N(1) is bonded in a bent 150 degrees geometry to two equivalent S(1) atoms. Both N(1)-S(1) bond lengths are 1.60 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. The S(1)-S(2) bond length is 2.07 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. The S(2)-S(3) bond length is 2.07 Å. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. The S(3)-S(4) bond length is 2.04 Å. In the fourth S site, S(4) is bonded in a water-like geometry to two equivalent S(3) atoms.