KN3H8 crystallizes in the orthorhombic C222_1 space group. K(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent H(2), and two equivalent H(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to two equivalent K(1) and two equivalent H(3) atoms. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one K(1), one H(1), one H(2), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(1) and one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one K(1) and one N(2) atom.
KN3H8 crystallizes in the orthorhombic C222_1 space group. K(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent H(2), and two equivalent H(4) atoms. Both K(1)-N(1) bond lengths are 2.80 Å. Both K(1)-N(2) bond lengths are 2.93 Å. Both K(1)-H(2) bond lengths are 2.80 Å. Both K(1)-H(4) bond lengths are 2.78 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to two equivalent K(1) and two equivalent H(3) atoms. Both N(1)-H(3) bond lengths are 1.03 Å. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one K(1), one H(1), one H(2), and one H(4) atom. The N(2)-H(1) bond length is 1.02 Å. The N(2)-H(2) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.02 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one K(1) and one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one K(1) and one N(2) atom.