CN4S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CN4S3 clusters. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(3) and one N(4) atom. In the second S site, S(2) is bonded in a single-bond geometry to one N(3) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one N(2) and one N(4) atom.
CN4S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CN4S3 clusters. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-N(2) bond length is 1.31 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(3) atom. The N(2)-S(3) bond length is 1.60 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(3)-S(1) bond length is 1.57 Å. The N(3)-S(2) bond length is 1.61 Å. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. The N(4)-S(1) bond length is 1.60 Å. The N(4)-S(3) bond length is 1.64 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(3) and one N(4) atom. In the second S site, S(2) is bonded in a single-bond geometry to one N(3) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to one N(2) and one N(4) atom.