Li(H2O)4B(OH)4(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules, one B(OH)4 cluster, and one Li(H2O)4 cluster. In the B(OH)4 cluster, B(1) is bonded in a tetrahedral geometry to one O(10), one O(4), one O(8), and one O(9) atom. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(9) atom. In the second H site, H(3) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one B(1) and one H(8) atom. In the second O site, O(8) is bonded in a distorted water-like geometry to one B(1) and one H(4) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(2) atom. In the fourth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(3) atom. In the Li(H2O)4 cluster, Li(1) is bonded in a tetrahedral geometry to one O(2), one O(5), one O(6), and one O(7) atom. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one O(6) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one O(7) atom. In the sixth H site, H(12) is bonded in a distorted single-bond geometry to one O(5) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one O(2) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one O(2) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(15), and one H(16) atom. In the second O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(12), and one H(7) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Li(1), one H(5), and one H(9) atom. In the fourth O site, O(7) is bonded in a distorted water-like geometry to one Li(1), one H(10), and one H(6) atom.
Li(H2O)4B(OH)4(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules, one B(OH)4 cluster, and one Li(H2O)4 cluster. In the B(OH)4 cluster, B(1) is bonded in a tetrahedral geometry to one O(10), one O(4), one O(8), and one O(9) atom. The B(1)-O(10) bond length is 1.47 Å. The B(1)-O(4) bond length is 1.50 Å. The B(1)-O(8) bond length is 1.51 Å. The B(1)-O(9) bond length is 1.48 Å. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.99 Å. In the second H site, H(3) is bonded in a single-bond geometry to one O(10) atom. The H(3)-O(10) bond length is 0.99 Å. In the third H site, H(4) is bonded in a single-bond geometry to one O(8) atom. The H(4)-O(8) bond length is 0.99 Å. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. The H(8)-O(4) bond length is 0.99 Å. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one B(1) and one H(8) atom. In the second O site, O(8) is bonded in a distorted water-like geometry to one B(1) and one H(4) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(2) atom. In the fourth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(3) atom. In the Li(H2O)4 cluster, Li(1) is bonded in a tetrahedral geometry to one O(2), one O(5), one O(6), and one O(7) atom. The Li(1)-O(2) bond length is 1.98 Å. The Li(1)-O(5) bond length is 1.96 Å. The Li(1)-O(6) bond length is 1.98 Å. The Li(1)-O(7) bond length is 1.99 Å. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(6) atom. The H(5)-O(6) bond length is 1.00 Å. In the second H site, H(6) is bonded in a single-bond geometry to one O(7) atom. The H(6)-O(7) bond length is 1.00 Å. In the third H site, H(7) is bonded in a single-bond geometry to one O(5) atom. The H(7)-O(5) bond length is 1.00 Å. In the fourth H site, H(9) is bonded in a single-bond geometry to one O(6) atom. The H(9)-O(6) bond length is 1.01 Å. In the fifth H site, H(10) is bonded in a single-bond geometry to one O(7) atom. The H(10)-O(7) bond length is 1.00 Å. In the sixth H site, H(12) is bonded in a distorted single-bond geometry to one O(5) atom. The H(12)-O(5) bond length is 1.00 Å. In the seventh H site, H(15) is bonded in a single-bond geometry to one O(2) atom. The H(15)-O(2) bond length is 1.00 Å. In the eighth H site, H(16) is bonded in a single-bond geometry to one O(2) atom. The H(16)-O(2) bond length is 1.00 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(15), and one H(16) atom. In the second O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(12), and one H(7) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Li(1), one H(5), and one H(9) atom. In the fourth O site, O(7) is bonded in a distorted water-like geometry to one Li(1), one H(10), and one H(6) atom.