(Cs)2CsBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsBiBr6 framework. In the CsBiBr6 framework, Cs(2) is bonded to six equivalent Br(1) atoms to form CsBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Cs(2)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Cs(2) and one Bi(1) atom.
(Cs)2CsBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsBiBr6 framework. In the CsBiBr6 framework, Cs(2) is bonded to six equivalent Br(1) atoms to form CsBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Cs(2)-Br(1) bond lengths are 3.42 Å. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Cs(2)Br6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-Br(1) bond lengths are 2.87 Å. Br(1) is bonded in a linear geometry to one Cs(2) and one Bi(1) atom.