Fe(H2O)6PtCl6 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two iron hexahydrate molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1,2) is bonded in an octahedral geometry to one Cl(10), one Cl(11), one Cl(2), one Cl(3), one Cl(5), and one Cl(7) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Pt(1,2) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Pt(1,2) atom. In the third Cl site, Cl(10) is bonded in a single-bond geometry to one Pt(1,2) atom. In the fourth Cl site, Cl(11) is bonded in a single-bond geometry to one Pt(1,2) atom. In the fifth Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1,2) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1,2) atom.
Fe(H2O)6PtCl6 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two iron hexahydrate molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1,2) is bonded in an octahedral geometry to one Cl(10), one Cl(11), one Cl(2), one Cl(3), one Cl(5), and one Cl(7) atom. The Pt(1,2)-Cl(10) bond length is 2.35 Å. The Pt(1,2)-Cl(11) bond length is 2.35 Å. The Pt(1,2)-Cl(2) bond length is 2.35 Å. The Pt(1,2)-Cl(3) bond length is 2.35 Å. The Pt(1,2)-Cl(5) bond length is 2.35 Å. The Pt(1,2)-Cl(7) bond length is 2.35 Å. There are six inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Pt(1,2) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Pt(1,2) atom. In the third Cl site, Cl(10) is bonded in a single-bond geometry to one Pt(1,2) atom. In the fourth Cl site, Cl(11) is bonded in a single-bond geometry to one Pt(1,2) atom. In the fifth Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1,2) atom. In the sixth Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1,2) atom.