C2N4H7SBr is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two C2N4H7SBr clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one H(4), and one H(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(2), and one H(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(1) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) and one Br(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. Br(1) is bonded in a distorted single-bond geometry to one H(1) atom.
C2N4H7SBr is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two C2N4H7SBr clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one S(1) atom. The C(1)-N(3) bond length is 1.39 Å. The C(1)-N(4) bond length is 1.34 Å. The C(1)-S(1) bond length is 1.68 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(2) bond length is 1.33 Å. The C(2)-N(3) bond length is 1.37 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one H(4), and one H(7) atom. The N(1)-H(4) bond length is 1.03 Å. The N(1)-H(7) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(2), and one H(6) atom. The N(2)-H(2) bond length is 1.03 Å. The N(2)-H(6) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(1) atom. The N(3)-H(1) bond length is 1.05 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(5) atom. The N(4)-H(3) bond length is 1.02 Å. The N(4)-H(5) bond length is 1.02 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) and one Br(1) atom. The H(1)-Br(1) bond length is 2.27 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. Br(1) is bonded in a distorted single-bond geometry to one H(1) atom.