Ti3V2Si3 crystallizes in the hexagonal P6_3/mcm space group. Ti(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. V(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent V(1) atoms.
Ti3V2Si3 crystallizes in the hexagonal P6_3/mcm space group. Ti(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. There are a spread of Ti(1)-Si(1) bond distances ranging from 2.55-2.70 Å. V(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent Si(1) atoms. Both V(1)-V(1) bond lengths are 2.46 Å. All V(1)-Si(1) bond lengths are 2.55 Å. Si(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent V(1) atoms.