Co3Cu3(TeO8)2 is beta Vanadium nitride-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(2), one Cu(3), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one Cu(2), and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Co(3), one Cu(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Co(1), one Cu(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Co(2), one Cu(3), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Co(3), one Cu(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Co(1), one Cu(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(2), and one Te(2) atom.
Co3Cu3(TeO8)2 is beta Vanadium nitride-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. The Co(1)-O(14) bond length is 1.98 Å. The Co(1)-O(16) bond length is 1.99 Å. The Co(1)-O(3) bond length is 1.84 Å. The Co(1)-O(4) bond length is 1.87 Å. The Co(1)-O(7) bond length is 1.90 Å. The Co(1)-O(8) bond length is 1.91 Å. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. The Co(2)-O(1) bond length is 1.98 Å. The Co(2)-O(10) bond length is 1.98 Å. The Co(2)-O(11) bond length is 1.91 Å. The Co(2)-O(13) bond length is 1.86 Å. The Co(2)-O(15) bond length is 1.91 Å. The Co(2)-O(5) bond length is 1.88 Å. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. The Co(3)-O(10) bond length is 1.93 Å. The Co(3)-O(12) bond length is 1.92 Å. The Co(3)-O(13) bond length is 1.86 Å. The Co(3)-O(15) bond length is 1.96 Å. The Co(3)-O(5) bond length is 1.90 Å. The Co(3)-O(6) bond length is 1.98 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. The Cu(1)-O(14) bond length is 2.09 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 1.90 Å. The Cu(1)-O(4) bond length is 1.91 Å. The Cu(1)-O(7) bond length is 2.18 Å. The Cu(1)-O(9) bond length is 1.98 Å. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. The Cu(2)-O(16) bond length is 2.19 Å. The Cu(2)-O(2) bond length is 1.94 Å. The Cu(2)-O(3) bond length is 1.88 Å. The Cu(2)-O(4) bond length is 1.88 Å. The Cu(2)-O(8) bond length is 2.32 Å. The Cu(2)-O(9) bond length is 1.92 Å. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. The Cu(3)-O(1) bond length is 2.06 Å. The Cu(3)-O(11) bond length is 2.11 Å. The Cu(3)-O(12) bond length is 2.00 Å. The Cu(3)-O(13) bond length is 1.92 Å. The Cu(3)-O(5) bond length is 1.93 Å. The Cu(3)-O(6) bond length is 1.97 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. The Te(1)-O(1) bond length is 1.92 Å. The Te(1)-O(10) bond length is 2.02 Å. The Te(1)-O(2) bond length is 2.06 Å. The Te(1)-O(6) bond length is 2.00 Å. The Te(1)-O(7) bond length is 1.99 Å. The Te(1)-O(8) bond length is 1.96 Å. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. The Te(2)-O(11) bond length is 2.01 Å. The Te(2)-O(12) bond length is 2.06 Å. The Te(2)-O(14) bond length is 1.91 Å. The Te(2)-O(15) bond length is 2.05 Å. The Te(2)-O(16) bond length is 1.90 Å. The Te(2)-O(9) bond length is 1.97 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(2), one Cu(3), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one Cu(2), and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Co(3), one Cu(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Co(1), one Cu(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Co(2), one Cu(3), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Co(3), one Cu(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Co(1), one Cu(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(2), and one Te(2) atom.