LiZnSb is half-Heusler structured and crystallizes in the cubic F-43m space group. Li(1) is bonded to six equivalent Zn(1) and four equivalent Sb(1) atoms to form LiZn6Sb4 tetrahedra that share corners with four equivalent Zn(1)Li6Sb4 tetrahedra, corners with six equivalent Li(1)Zn6Sb4 tetrahedra, edges with six equivalent Zn(1)Li6Sb4 tetrahedra, and faces with twelve equivalent Li(1)Zn6Sb4 tetrahedra. Zn(1) is bonded to six equivalent Li(1) and four equivalent Sb(1) atoms to form distorted ZnLi6Sb4 tetrahedra that share corners with four equivalent Li(1)Zn6Sb4 tetrahedra, corners with six equivalent Zn(1)Li6Sb4 tetrahedra, edges with six equivalent Li(1)Zn6Sb4 tetrahedra, and faces with twelve equivalent Zn(1)Li6Sb4 tetrahedra. Sb(1) is bonded in a body-centered cubic geometry to four equivalent Li(1) and four equivalent Zn(1) atoms.
LiZnSb is half-Heusler structured and crystallizes in the cubic F-43m space group. Li(1) is bonded to six equivalent Zn(1) and four equivalent Sb(1) atoms to form LiZn6Sb4 tetrahedra that share corners with four equivalent Zn(1)Li6Sb4 tetrahedra, corners with six equivalent Li(1)Zn6Sb4 tetrahedra, edges with six equivalent Zn(1)Li6Sb4 tetrahedra, and faces with twelve equivalent Li(1)Zn6Sb4 tetrahedra. All Li(1)-Zn(1) bond lengths are 3.17 Å. All Li(1)-Sb(1) bond lengths are 2.75 Å. Zn(1) is bonded to six equivalent Li(1) and four equivalent Sb(1) atoms to form distorted ZnLi6Sb4 tetrahedra that share corners with four equivalent Li(1)Zn6Sb4 tetrahedra, corners with six equivalent Zn(1)Li6Sb4 tetrahedra, edges with six equivalent Li(1)Zn6Sb4 tetrahedra, and faces with twelve equivalent Zn(1)Li6Sb4 tetrahedra. All Zn(1)-Sb(1) bond lengths are 2.75 Å. Sb(1) is bonded in a body-centered cubic geometry to four equivalent Li(1) and four equivalent Zn(1) atoms.