La2NiReO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. La(1) is bonded to twelve equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with six equivalent La(1)O12 cuboctahedra, faces with four equivalent Re(1)O6 octahedra, and faces with four equivalent Ni(1)O6 octahedra. Re(1) is bonded to six equivalent O(1) atoms to form ReO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Re(1)O6 octahedra and faces with eight equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent La(1), one Re(1), and one Ni(1) atom to form a mixture of distorted edge, face, and corner-sharing OLa4ReNi octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
La2NiReO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. La(1) is bonded to twelve equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with six equivalent La(1)O12 cuboctahedra, faces with four equivalent Re(1)O6 octahedra, and faces with four equivalent Ni(1)O6 octahedra. All La(1)-O(1) bond lengths are 2.82 Å. Re(1) is bonded to six equivalent O(1) atoms to form ReO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Re(1)-O(1) bond lengths are 1.99 Å. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Re(1)O6 octahedra and faces with eight equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ni(1)-O(1) bond lengths are 1.99 Å. O(1) is bonded to four equivalent La(1), one Re(1), and one Ni(1) atom to form a mixture of distorted edge, face, and corner-sharing OLa4ReNi octahedra. The corner-sharing octahedral tilt angles range from 0-60°.