TiO2 is Baddeleyite structured and crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to three equivalent O(2) and four equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing TiO7 pentagonal bipyramids. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ti(1) atoms. In the second O site, O(1) is bonded to four equivalent Ti(1) atoms to form a mixture of edge and corner-sharing OTi4 tetrahedra.
TiO2 is Baddeleyite structured and crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to three equivalent O(2) and four equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing TiO7 pentagonal bipyramids. There are a spread of Ti(1)-O(2) bond distances ranging from 1.88-2.03 Å. There are a spread of Ti(1)-O(1) bond distances ranging from 2.00-2.20 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ti(1) atoms. In the second O site, O(1) is bonded to four equivalent Ti(1) atoms to form a mixture of edge and corner-sharing OTi4 tetrahedra.