SrLaVFeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(11), two equivalent O(7), and two equivalent O(9) atoms. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(10), two equivalent O(12), and two equivalent O(8) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra and corners with three equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-25°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra and corners with three equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. In the second Fe site, Fe(2) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-25°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(1), and one Fe(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(2), and one Fe(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(1), and one Fe(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(2), and one Fe(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(1), and one Fe(1) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(2), and one Fe(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one V(1), and one Fe(2) atom. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one V(2), and one Fe(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one V(1), and one Fe(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one V(2), and one Fe(1) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one V(1), and one Fe(2) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one V(2), and one Fe(1) atom.
SrLaVFeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(11), two equivalent O(7), and two equivalent O(9) atoms. The Sr(1)-O(1) bond length is 2.65 Å. The Sr(1)-O(2) bond length is 2.90 Å. The Sr(1)-O(3) bond length is 3.17 Å. The Sr(1)-O(4) bond length is 2.51 Å. The Sr(1)-O(5) bond length is 2.58 Å. The Sr(1)-O(6) bond length is 2.96 Å. There is one shorter (2.67 Å) and one longer (2.89 Å) Sr(1)-O(11) bond length. There is one shorter (2.57 Å) and one longer (3.04 Å) Sr(1)-O(7) bond length. There is one shorter (2.81 Å) and one longer (2.82 Å) Sr(1)-O(9) bond length. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(10), two equivalent O(12), and two equivalent O(8) atoms. The Sr(2)-O(1) bond length is 2.96 Å. The Sr(2)-O(2) bond length is 2.68 Å. The Sr(2)-O(3) bond length is 2.49 Å. The Sr(2)-O(4) bond length is 3.05 Å. The Sr(2)-O(5) bond length is 3.04 Å. The Sr(2)-O(6) bond length is 2.56 Å. There is one shorter (2.80 Å) and one longer (2.83 Å) Sr(2)-O(10) bond length. There is one shorter (2.70 Å) and one longer (2.86 Å) Sr(2)-O(12) bond length. There is one shorter (2.59 Å) and one longer (3.01 Å) Sr(2)-O(8) bond length. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. The La(1)-O(10) bond length is 2.44 Å. The La(1)-O(11) bond length is 2.46 Å. The La(1)-O(12) bond length is 3.15 Å. The La(1)-O(7) bond length is 2.55 Å. The La(1)-O(8) bond length is 2.94 Å. The La(1)-O(9) bond length is 3.19 Å. There is one shorter (2.46 Å) and one longer (3.14 Å) La(1)-O(1) bond length. There is one shorter (2.76 Å) and one longer (2.87 Å) La(1)-O(3) bond length. There is one shorter (2.57 Å) and one longer (2.97 Å) La(1)-O(5) bond length. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. The La(2)-O(10) bond length is 3.16 Å. The La(2)-O(11) bond length is 3.06 Å. The La(2)-O(12) bond length is 2.45 Å. The La(2)-O(7) bond length is 2.98 Å. The La(2)-O(8) bond length is 2.68 Å. The La(2)-O(9) bond length is 2.43 Å. There is one shorter (2.50 Å) and one longer (3.10 Å) La(2)-O(2) bond length. There is one shorter (2.80 Å) and one longer (2.81 Å) La(2)-O(4) bond length. There is one shorter (2.58 Å) and one longer (2.96 Å) La(2)-O(6) bond length. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra and corners with three equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-25°. The V(1)-O(1) bond length is 1.99 Å. The V(1)-O(11) bond length is 2.01 Å. The V(1)-O(3) bond length is 1.89 Å. The V(1)-O(5) bond length is 1.98 Å. The V(1)-O(7) bond length is 1.98 Å. The V(1)-O(9) bond length is 1.93 Å. In the second V site, V(2) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra and corners with three equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. The V(2)-O(10) bond length is 2.01 Å. The V(2)-O(12) bond length is 1.99 Å. The V(2)-O(2) bond length is 1.92 Å. The V(2)-O(4) bond length is 1.97 Å. The V(2)-O(6) bond length is 2.00 Å. The V(2)-O(8) bond length is 1.89 Å. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. The Fe(1)-O(1) bond length is 1.99 Å. The Fe(1)-O(10) bond length is 2.00 Å. The Fe(1)-O(12) bond length is 2.03 Å. The Fe(1)-O(3) bond length is 2.08 Å. The Fe(1)-O(5) bond length is 2.01 Å. The Fe(1)-O(8) bond length is 2.08 Å. In the second Fe site, Fe(2) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with three equivalent V(1)O6 octahedra and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-25°. The Fe(2)-O(11) bond length is 2.02 Å. The Fe(2)-O(2) bond length is 2.06 Å. The Fe(2)-O(4) bond length is 1.99 Å. The Fe(2)-O(6) bond length is 2.02 Å. The Fe(2)-O(7) bond length is 2.00 Å. The Fe(2)-O(9) bond length is 2.07 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(1), and one Fe(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(2), and one Fe(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(1), and one Fe(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(2), and one Fe(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one V(1), and one Fe(1) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one V(2), and one Fe(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one V(1), and one Fe(2) atom. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one V(2), and one Fe(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one V(1), and one Fe(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one V(2), and one Fe(1) atom. In the eleventh O site, O(11) is bonded in a 6-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one V(1), and one Fe(2) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one V(2), and one Fe(1) atom.