KAgCl3 is (Cubic) Perovskite structured and crystallizes in the triclinic P1 space group. K(1) is bonded to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms to form KCl12 cuboctahedra that share corners with twelve equivalent K(1)Cl12 cuboctahedra, faces with six equivalent K(1)Cl12 cuboctahedra, and faces with eight equivalent Ag(1)Cl6 octahedra. Ag(1) is bonded to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms to form AgCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra and faces with eight equivalent K(1)Cl12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner, face, and edge-sharing ClK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the second Cl site, Cl(2) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner, face, and edge-sharing ClK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the third Cl site, Cl(3) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner, face, and edge-sharing ClK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°.
KAgCl3 is (Cubic) Perovskite structured and crystallizes in the triclinic P1 space group. K(1) is bonded to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms to form KCl12 cuboctahedra that share corners with twelve equivalent K(1)Cl12 cuboctahedra, faces with six equivalent K(1)Cl12 cuboctahedra, and faces with eight equivalent Ag(1)Cl6 octahedra. There are a spread of K(1)-Cl(1) bond distances ranging from 3.52-3.63 Å. There are a spread of K(1)-Cl(2) bond distances ranging from 3.56-3.59 Å. There are two shorter (3.54 Å) and two longer (3.62 Å) K(1)-Cl(3) bond lengths. Ag(1) is bonded to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms to form AgCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra and faces with eight equivalent K(1)Cl12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. Both Ag(1)-Cl(1) bond lengths are 2.53 Å. Both Ag(1)-Cl(2) bond lengths are 2.53 Å. Both Ag(1)-Cl(3) bond lengths are 2.53 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner, face, and edge-sharing ClK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the second Cl site, Cl(2) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner, face, and edge-sharing ClK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the third Cl site, Cl(3) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner, face, and edge-sharing ClK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°.