Na4Au is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Na4Au clusters. Na(1) is bonded in a single-bond geometry to one Au(1) atom. Au(1) is bonded in a tetrahedral geometry to four equivalent Na(1) atoms.
Na4Au is Iron carbide-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Na4Au clusters. Na(1) is bonded in a single-bond geometry to one Au(1) atom. The Na(1)-Au(1) bond length is 2.80 Å. Au(1) is bonded in a tetrahedral geometry to four equivalent Na(1) atoms.