Eu2NiBiO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Ni(1)O6 octahedra, and faces with four equivalent Bi(1)O6 octahedra. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent Eu(1), one Ni(1), and one Bi(1) atom.
Eu2NiBiO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Ni(1)O6 octahedra, and faces with four equivalent Bi(1)O6 octahedra. All Eu(1)-O(1) bond lengths are 2.88 Å. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ni(1)-O(1) bond lengths are 2.00 Å. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Bi(1)-O(1) bond lengths are 2.08 Å. O(1) is bonded in a distorted linear geometry to four equivalent Eu(1), one Ni(1), and one Bi(1) atom.