Na2AgF4 is Corundum-derived structured and crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded to three equivalent F(1) and three equivalent F(2) atoms to form a mixture of edge and corner-sharing NaF6 octahedra. The corner-sharing octahedral tilt angles range from 54-71°. Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded to three equivalent Na(1) and one Ag(1) atom to form corner-sharing FNa3Ag tetrahedra. In the second F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Na(1) and one Ag(1) atom.
Na2AgF4 is Corundum-derived structured and crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded to three equivalent F(1) and three equivalent F(2) atoms to form a mixture of edge and corner-sharing NaF6 octahedra. The corner-sharing octahedral tilt angles range from 54-71°. There are a spread of Na(1)-F(1) bond distances ranging from 2.29-2.37 Å. There is one shorter (2.23 Å) and two longer (2.27 Å) Na(1)-F(2) bond lengths. Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Ag(1)-F(1) bond lengths are 2.10 Å. Both Ag(1)-F(2) bond lengths are 2.09 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded to three equivalent Na(1) and one Ag(1) atom to form corner-sharing FNa3Ag tetrahedra. In the second F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Na(1) and one Ag(1) atom.