K2GaOF5 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 7-coordinate geometry to two equivalent F(2), two equivalent F(3), and three equivalent F(1) atoms. Ga(1) is bonded in an octahedral geometry to one O(1), one F(2), two equivalent F(1), and two equivalent F(3) atoms. O(1) is bonded in a single-bond geometry to one Ga(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Ga(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Ga(1) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Ga(1) atom.
K2GaOF5 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 7-coordinate geometry to two equivalent F(2), two equivalent F(3), and three equivalent F(1) atoms. There is one shorter (2.77 Å) and one longer (2.92 Å) K(1)-F(2) bond length. There is one shorter (2.70 Å) and one longer (2.72 Å) K(1)-F(3) bond length. There are a spread of K(1)-F(1) bond distances ranging from 2.67-2.81 Å. Ga(1) is bonded in an octahedral geometry to one O(1), one F(2), two equivalent F(1), and two equivalent F(3) atoms. The Ga(1)-O(1) bond length is 2.11 Å. The Ga(1)-F(2) bond length is 1.89 Å. Both Ga(1)-F(1) bond lengths are 1.91 Å. Both Ga(1)-F(3) bond lengths are 1.91 Å. O(1) is bonded in a single-bond geometry to one Ga(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Ga(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Ga(1) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Ga(1) atom.