PCl4ICl4 is Indium-derived structured and crystallizes in the orthorhombic Imma space group. The structure is zero-dimensional and consists of eight [pcl4]+1 molecules and eight ICl4 clusters. In each ICl4 cluster, I(1) is bonded in a rectangular see-saw-like geometry to two equivalent Cl(5) and two equivalent Cl(6) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one I(1) atom.
PCl4ICl4 is Indium-derived structured and crystallizes in the orthorhombic Imma space group. The structure is zero-dimensional and consists of eight [pcl4]+1 molecules and eight ICl4 clusters. In each ICl4 cluster, I(1) is bonded in a rectangular see-saw-like geometry to two equivalent Cl(5) and two equivalent Cl(6) atoms. Both I(1)-Cl(5) bond lengths are 2.52 Å. Both I(1)-Cl(6) bond lengths are 2.51 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one I(1) atom.