Li10GeP2S12 crystallizes in the triclinic P1 space group. There are twenty inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one S(10), one S(17), one S(3), one S(4), and one S(9) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one S(12), one S(19), one S(2), and one S(20) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one S(13), one S(14), one S(21), one S(22), one S(7), and one S(8) atom. In the fourth Li site, Li(4) is bonded to one S(15), one S(16), one S(23), one S(24), one S(5), and one S(6) atom to form distorted LiS6 octahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Li(11)S4 tetrahedra,  a cornercorner with one Li(12)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra, corners with two equivalent P(2)S4 tetrahedra,  an edgeedge with one Li(13)S4 tetrahedra,  an edgeedge with one Li(14)S4 tetrahedra,  an edgeedge with one Li(17)S4 tetrahedra,  an edgeedge with one Li(5)S4 tetrahedra,  an edgeedge with one Ge(2)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. In the fifth Li site, Li(5) is bonded to one S(20), one S(24), one S(6), and one S(9) atom to form distorted LiS4 tetrahedra that share corners with two equivalent Li(8)S5 square pyramids,  a cornercorner with one P(2)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(14)S4 tetrahedra,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(11)S4 tetrahedra, and  an edgeedge with one Ge(1)S4 tetrahedra. In the sixth Li site, Li(6) is bonded in a distorted see-saw-like geometry to one S(13), one S(19), one S(2), and one S(23) atom. In the seventh Li site, Li(7) is bonded to one S(15), one S(17), one S(22), and one S(7) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(20)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra, corners with two equivalent Li(15)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid, and  an edgeedge with one Ge(2)S4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. In the eighth Li site, Li(8) is bonded to one S(10), one S(13), one S(2), one S(20), and one S(24) atom to form distorted LiS5 square pyramids that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(11)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra,  an edgeedge with one Li(18)S4 tetrahedra,  an edgeedge with one Ge(1)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. The corner-sharing octahedral tilt angles are 80°. In the ninth Li site, Li(9) is bonded to one S(1), one S(14), one S(19), and one S(23) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(11)S4 tetrahedra,  an edgeedge with one Li(14)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. In the tenth Li site, Li(10) is bonded to one S(11), one S(21), one S(22), one S(3), and one S(4) atom to form LiS5 trigonal bipyramids that share  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(15)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra, corners with two equivalent Ge(2)S4 tetrahedra,  an edgeedge with one Li(12)S4 tetrahedra,  an edgeedge with one Li(20)S4 tetrahedra, and  an edgeedge with one P(2)S4 tetrahedra. In the eleventh Li site, Li(11) is bonded to one S(1), one S(14), one S(20), and one S(24) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra, corners with two equivalent Li(8)S5 square pyramids,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(9)S4 tetrahedra,  an edgeedge with one Li(5)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. The corner-sharing octahedral tilt angles are 41°. In the twelfth Li site, Li(12) is bonded to one S(16), one S(18), one S(21), and one S(4) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one P(2)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra, corners with two equivalent Li(17)S4 tetrahedra, corners with two equivalent Li(20)S4 tetrahedra,  an edgeedge with one Ge(2)S4 tetrahedra, and  an edgeedge with one Li(10)S5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 72°. In the thirteenth Li site, Li(13) is bonded to one S(10), one S(15), one S(3), and one S(5) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one Ge(2)S4 tetrahedra, corners with two equivalent Li(17)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(4)S6 octahedra, and  an edgeedge with one P(2)S4 tetrahedra. In the fourteenth Li site, Li(14) is bonded to one S(19), one S(23), one S(6), and one S(9) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one P(2)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(9)S4 tetrahedra, and  an edgeedge with one Ge(1)S4 tetrahedra. In the fifteenth Li site, Li(15) is bonded to one S(12), one S(17), one S(22), and one S(8) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Ge(2)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(7)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid, and  an edgeedge with one P(3)S4 tetrahedra. In the sixteenth Li site, Li(16) is bonded in a 5-coordinate geometry to one S(15), one S(18), one S(3), one S(6), and one S(9) atom. In the seventeenth Li site, Li(17) is bonded to one S(10), one S(16), one S(4), and one S(5) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one Ge(2)S4 tetrahedra, corners with two equivalent Li(12)S4 tetrahedra, corners with two equivalent Li(13)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(4)S6 octahedra, and  an edgeedge with one P(2)S4 tetrahedra. In the eighteenth Li site, Li(18) is bonded to one S(11), one S(13), one S(2), and one S(7) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(20)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(8)S5 square pyramid, and  an edgeedge with one P(1)S4 tetrahedra. In the nineteenth Li site, Li(19) is bonded in a 5-coordinate geometry to one S(1), one S(12), one S(18), one S(21), and one S(8) atom. In the twentieth Li site, Li(20) is bonded to one S(11), one S(18), one S(21), and one S(7) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Ge(2)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(12)S4 tetrahedra, corners with two equivalent Li(18)S4 tetrahedra,  an edgeedge with one P(3)S4 tetrahedra, and  an edgeedge with one Li(10)S5 trigonal bipyramid. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one S(10), one S(19), one S(20), and one S(9) atom to form distorted GeS4 tetrahedra that share  a cornercorner with one Li(11)S4 tetrahedra,  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  an edgeedge with one Li(8)S5 square pyramid,  an edgeedge with one Li(14)S4 tetrahedra, and  an edgeedge with one Li(5)S4 tetrahedra. In the second Ge site, Ge(2) is bonded to one S(15), one S(16), one S(21), and one S(22) atom to form GeS4 tetrahedra that share  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(15)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one Li(20)S4 tetrahedra, corners with two equivalent Li(10)S5 trigonal bipyramids,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(12)S4 tetrahedra, and  an edgeedge with one Li(7)S4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(7), and one S(8) atom to form PS4 tetrahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Li(11)S4 tetrahedra,  a cornercorner with one Li(15)S4 tetrahedra,  a cornercorner with one Li(20)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra, and  an edgeedge with one Li(18)S4 tetrahedra. In the second P site, P(2) is bonded to one S(3), one S(4), one S(5), and one S(6) atom to form PS4 tetrahedra that share corners with two equivalent Li(4)S6 octahedra,  a cornercorner with one Li(12)S4 tetrahedra,  a cornercorner with one Li(14)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  an edgeedge with one Li(13)S4 tetrahedra,  an edgeedge with one Li(17)S4 tetrahedra, and  an edgeedge with one Li(10)S5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 27-54°. In the third P site, P(3) is bonded to one S(11), one S(12), one S(17), and one S(18) atom to form PS4 tetrahedra that share  a cornercorner with one Li(12)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(15)S4 tetrahedra, and  an edgeedge with one Li(20)S4 tetrahedra. In the fourth P site, P(4) is bonded to one S(13), one S(14), one S(23), and one S(24) atom to form PS4 tetrahedra that share  a cornercorner with one Li(14)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(8)S5 square pyramid,  an edgeedge with one Li(11)S4 tetrahedra, and  an edgeedge with one Li(9)S4 tetrahedra. There are twenty-four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(11), one Li(19), one Li(9), and one P(1) atom. In the second S site, S(2) is bonded to one Li(18), one Li(2), one Li(6), one Li(8), and one P(1) atom to form distorted SLi4P square pyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(23)Li4P trigonal bipyramid,  a cornercorner with one S(24)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(8)Li3P trigonal pyramid,  an edgeedge with one S(19)Li4Ge square pyramid,  an edgeedge with one S(20)Li4Ge square pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid, and  an edgeedge with one S(7)Li4P trigonal bipyramid. In the third S site, S(3) is bonded to one Li(1), one Li(10), one Li(13), one Li(16), and one P(2) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(22)Li4Ge trigonal bipyramid,  a cornercorner with one S(18)Li4P trigonal bipyramid, and  a cornercorner with one S(17)Li3P trigonal pyramid. In the fourth S site, S(4) is bonded in a distorted pentagonal planar geometry to one Li(1), one Li(10), one Li(12), one Li(17), and one P(2) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to one Li(13), one Li(17), one Li(4), and one P(2) atom. In the sixth S site, S(6) is bonded in a 5-coordinate geometry to one Li(14), one Li(16), one Li(4), one Li(5), and one P(2) atom. In the seventh S site, S(7) is bonded to one Li(18), one Li(20), one Li(3), one Li(7), and one P(1) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(18)Li4P trigonal bipyramid,  a cornercorner with one S(14)Li3P trigonal pyramid,  a cornercorner with one S(17)Li3P trigonal pyramid, corners with two equivalent S(8)Li3P trigonal pyramids,  an edgeedge with one S(2)Li4P square pyramid,  an edgeedge with one S(22)Li4Ge trigonal bipyramid, and  an edgeedge with one S(13)Li4P trigonal bipyramid. In the eighth S site, S(8) is bonded to one Li(15), one Li(19), one Li(3), and one P(1) atom to form distorted SLi3P trigonal pyramids that share  a cornercorner with one S(2)Li4P square pyramid,  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(18)Li4P trigonal bipyramid, corners with two equivalent S(7)Li4P trigonal bipyramids,  a cornercorner with one S(14)Li3P trigonal pyramid,  a cornercorner with one S(17)Li3P trigonal pyramid, corners with two equivalent S(12)Li3P trigonal pyramids, and  an edgeedge with one S(22)Li4Ge trigonal bipyramid. In the ninth S site, S(9) is bonded in a distorted pentagonal planar geometry to one Li(1), one Li(14), one Li(16), one Li(5), and one Ge(1) atom. In the tenth S site, S(10) is bonded in a 5-coordinate geometry to one Li(1), one Li(13), one Li(17), one Li(8), and one Ge(1) atom. In the eleventh S site, S(11) is bonded in a 4-coordinate geometry to one Li(10), one Li(18), one Li(20), and one P(3) atom. In the twelfth S site, S(12) is bonded to one Li(15), one Li(19), one Li(2), and one P(3) atom to form SLi3P trigonal pyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  a cornercorner with one S(22)Li4Ge trigonal bipyramid, corners with two equivalent S(8)Li3P trigonal pyramids,  an edgeedge with one S(18)Li4P trigonal bipyramid, and  an edgeedge with one S(17)Li3P trigonal pyramid. In the thirteenth S site, S(13) is bonded to one Li(18), one Li(3), one Li(6), one Li(8), and one P(4) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  a cornercorner with one S(22)Li4Ge trigonal bipyramid,  a cornercorner with one S(8)Li3P trigonal pyramid,  an edgeedge with one S(2)Li4P square pyramid,  an edgeedge with one S(23)Li4P trigonal bipyramid,  an edgeedge with one S(24)Li4P trigonal bipyramid,  an edgeedge with one S(7)Li4P trigonal bipyramid, and  an edgeedge with one S(14)Li3P trigonal pyramid. In the fourteenth S site, S(14) is bonded to one Li(11), one Li(3), one Li(9), and one P(4) atom to form SLi3P trigonal pyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(22)Li4Ge trigonal bipyramid,  a cornercorner with one S(7)Li4P trigonal bipyramid,  a cornercorner with one S(8)Li3P trigonal pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid,  an edgeedge with one S(23)Li4P trigonal bipyramid, and  an edgeedge with one S(24)Li4P trigonal bipyramid. In the fifteenth S site, S(15) is bonded in a 5-coordinate geometry to one Li(13), one Li(16), one Li(4), one Li(7), and one Ge(2) atom. In the sixteenth S site, S(16) is bonded in a distorted see-saw-like geometry to one Li(12), one Li(17), one Li(4), and one Ge(2) atom. In the seventeenth S site, S(17) is bonded to one Li(1), one Li(15), one Li(7), and one P(3) atom to form SLi3P trigonal pyramids that share  a cornercorner with one S(18)Li4P trigonal bipyramid,  a cornercorner with one S(3)Li4P trigonal bipyramid,  a cornercorner with one S(7)Li4P trigonal bipyramid, corners with two equivalent S(22)Li4Ge trigonal bipyramids,  a cornercorner with one S(8)Li3P trigonal pyramid, and  an edgeedge with one S(12)Li3P trigonal pyramid. In the eighteenth S site, S(18) is bonded to one Li(12), one Li(16), one Li(19), one Li(20), and one P(3) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(3)Li4P trigonal bipyramid,  a cornercorner with one S(7)Li4P trigonal bipyramid,  a cornercorner with one S(17)Li3P trigonal pyramid,  a cornercorner with one S(8)Li3P trigonal pyramid, and  an edgeedge with one S(12)Li3P trigonal pyramid. In the nineteenth S site, S(19) is bonded to one Li(14), one Li(2), one Li(6), one Li(9), and one Ge(1) atom to form distorted SLi4Ge square pyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(23)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(14)Li3P trigonal pyramid,  an edgeedge with one S(20)Li4Ge square pyramid,  an edgeedge with one S(2)Li4P square pyramid, and  an edgeedge with one S(23)Li4P trigonal bipyramid. In the twentieth S site, S(20) is bonded to one Li(11), one Li(2), one Li(5), one Li(8), and one Ge(1) atom to form distorted SLi4Ge square pyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(24)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(14)Li3P trigonal pyramid,  an edgeedge with one S(19)Li4Ge square pyramid,  an edgeedge with one S(2)Li4P square pyramid, and  an edgeedge with one S(24)Li4P trigonal bipyramid. In the twenty-first S site, S(21) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(19), one Li(20), one Li(3), and one Ge(2) atom. In the twenty-second S site, S(22) is bonded to one Li(10), one Li(15), one Li(3), one Li(7), and one Ge(2) atom to form SLi4Ge trigonal bipyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(3)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(14)Li3P trigonal pyramid, corners with two equivalent S(17)Li3P trigonal pyramids,  an edgeedge with one S(7)Li4P trigonal bipyramid, and  an edgeedge with one S(8)Li3P trigonal pyramid. In the twenty-third S site, S(23) is bonded to one Li(14), one Li(4), one Li(6), one Li(9), and one P(4) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  an edgeedge with one S(19)Li4Ge square pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid,  an edgeedge with one S(24)Li4P trigonal bipyramid, and  an edgeedge with one S(14)Li3P trigonal pyramid. In the twenty-fourth S site, S(24) is bonded to one Li(11), one Li(4), one Li(5), one Li(8), and one P(4) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  an edgeedge with one S(20)Li4Ge square pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid,  an edgeedge with one S(23)Li4P trigonal bipyramid, and  an edgeedge with one S(14)Li3P trigonal pyramid.
Li10GeP2S12 crystallizes in the triclinic P1 space group. There are twenty inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one S(10), one S(17), one S(3), one S(4), and one S(9) atom. The Li(1)-S(10) bond length is 2.56 Å. The Li(1)-S(17) bond length is 2.53 Å. The Li(1)-S(3) bond length is 2.73 Å. The Li(1)-S(4) bond length is 2.70 Å. The Li(1)-S(9) bond length is 2.50 Å. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one S(12), one S(19), one S(2), and one S(20) atom. The Li(2)-S(12) bond length is 2.51 Å. The Li(2)-S(19) bond length is 2.56 Å. The Li(2)-S(2) bond length is 2.54 Å. The Li(2)-S(20) bond length is 2.71 Å. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one S(13), one S(14), one S(21), one S(22), one S(7), and one S(8) atom. The Li(3)-S(13) bond length is 2.65 Å. The Li(3)-S(14) bond length is 2.56 Å. The Li(3)-S(21) bond length is 3.01 Å. The Li(3)-S(22) bond length is 2.56 Å. The Li(3)-S(7) bond length is 2.76 Å. The Li(3)-S(8) bond length is 2.56 Å. In the fourth Li site, Li(4) is bonded to one S(15), one S(16), one S(23), one S(24), one S(5), and one S(6) atom to form distorted LiS6 octahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Li(11)S4 tetrahedra,  a cornercorner with one Li(12)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra, corners with two equivalent P(2)S4 tetrahedra,  an edgeedge with one Li(13)S4 tetrahedra,  an edgeedge with one Li(14)S4 tetrahedra,  an edgeedge with one Li(17)S4 tetrahedra,  an edgeedge with one Li(5)S4 tetrahedra,  an edgeedge with one Ge(2)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. The Li(4)-S(15) bond length is 2.60 Å. The Li(4)-S(16) bond length is 2.52 Å. The Li(4)-S(23) bond length is 2.73 Å. The Li(4)-S(24) bond length is 2.83 Å. The Li(4)-S(5) bond length is 2.76 Å. The Li(4)-S(6) bond length is 2.79 Å. In the fifth Li site, Li(5) is bonded to one S(20), one S(24), one S(6), and one S(9) atom to form distorted LiS4 tetrahedra that share corners with two equivalent Li(8)S5 square pyramids,  a cornercorner with one P(2)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(14)S4 tetrahedra,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(11)S4 tetrahedra, and  an edgeedge with one Ge(1)S4 tetrahedra. The Li(5)-S(20) bond length is 2.43 Å. The Li(5)-S(24) bond length is 2.47 Å. The Li(5)-S(6) bond length is 2.35 Å. The Li(5)-S(9) bond length is 2.47 Å. In the sixth Li site, Li(6) is bonded in a distorted see-saw-like geometry to one S(13), one S(19), one S(2), and one S(23) atom. The Li(6)-S(13) bond length is 2.58 Å. The Li(6)-S(19) bond length is 2.51 Å. The Li(6)-S(2) bond length is 2.65 Å. The Li(6)-S(23) bond length is 2.59 Å. In the seventh Li site, Li(7) is bonded to one S(15), one S(17), one S(22), and one S(7) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(20)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra, corners with two equivalent Li(15)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid, and  an edgeedge with one Ge(2)S4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. The Li(7)-S(15) bond length is 2.51 Å. The Li(7)-S(17) bond length is 2.41 Å. The Li(7)-S(22) bond length is 2.48 Å. The Li(7)-S(7) bond length is 2.47 Å. In the eighth Li site, Li(8) is bonded to one S(10), one S(13), one S(2), one S(20), and one S(24) atom to form distorted LiS5 square pyramids that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(11)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra,  an edgeedge with one Li(18)S4 tetrahedra,  an edgeedge with one Ge(1)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. The corner-sharing octahedral tilt angles are 80°. The Li(8)-S(10) bond length is 2.75 Å. The Li(8)-S(13) bond length is 2.72 Å. The Li(8)-S(2) bond length is 2.66 Å. The Li(8)-S(20) bond length is 2.55 Å. The Li(8)-S(24) bond length is 2.54 Å. In the ninth Li site, Li(9) is bonded to one S(1), one S(14), one S(19), and one S(23) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(11)S4 tetrahedra,  an edgeedge with one Li(14)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. The Li(9)-S(1) bond length is 2.37 Å. The Li(9)-S(14) bond length is 2.44 Å. The Li(9)-S(19) bond length is 2.45 Å. The Li(9)-S(23) bond length is 2.50 Å. In the tenth Li site, Li(10) is bonded to one S(11), one S(21), one S(22), one S(3), and one S(4) atom to form LiS5 trigonal bipyramids that share  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(15)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra, corners with two equivalent Ge(2)S4 tetrahedra,  an edgeedge with one Li(12)S4 tetrahedra,  an edgeedge with one Li(20)S4 tetrahedra, and  an edgeedge with one P(2)S4 tetrahedra. The Li(10)-S(11) bond length is 2.88 Å. The Li(10)-S(21) bond length is 2.85 Å. The Li(10)-S(22) bond length is 2.57 Å. The Li(10)-S(3) bond length is 2.43 Å. The Li(10)-S(4) bond length is 2.70 Å. In the eleventh Li site, Li(11) is bonded to one S(1), one S(14), one S(20), and one S(24) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra, corners with two equivalent Li(8)S5 square pyramids,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(9)S4 tetrahedra,  an edgeedge with one Li(5)S4 tetrahedra, and  an edgeedge with one P(4)S4 tetrahedra. The corner-sharing octahedral tilt angles are 41°. The Li(11)-S(1) bond length is 2.36 Å. The Li(11)-S(14) bond length is 2.44 Å. The Li(11)-S(20) bond length is 2.47 Å. The Li(11)-S(24) bond length is 2.60 Å. In the twelfth Li site, Li(12) is bonded to one S(16), one S(18), one S(21), and one S(4) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(4)S6 octahedra,  a cornercorner with one P(2)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra, corners with two equivalent Li(17)S4 tetrahedra, corners with two equivalent Li(20)S4 tetrahedra,  an edgeedge with one Ge(2)S4 tetrahedra, and  an edgeedge with one Li(10)S5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 72°. The Li(12)-S(16) bond length is 2.47 Å. The Li(12)-S(18) bond length is 2.65 Å. The Li(12)-S(21) bond length is 2.58 Å. The Li(12)-S(4) bond length is 2.52 Å. In the thirteenth Li site, Li(13) is bonded to one S(10), one S(15), one S(3), and one S(5) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one Ge(2)S4 tetrahedra, corners with two equivalent Li(17)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(4)S6 octahedra, and  an edgeedge with one P(2)S4 tetrahedra. The Li(13)-S(10) bond length is 2.52 Å. The Li(13)-S(15) bond length is 2.47 Å. The Li(13)-S(3) bond length is 2.46 Å. The Li(13)-S(5) bond length is 2.53 Å. In the fourteenth Li site, Li(14) is bonded to one S(19), one S(23), one S(6), and one S(9) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one P(2)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(9)S4 tetrahedra, and  an edgeedge with one Ge(1)S4 tetrahedra. The Li(14)-S(19) bond length is 2.55 Å. The Li(14)-S(23) bond length is 2.56 Å. The Li(14)-S(6) bond length is 2.41 Å. The Li(14)-S(9) bond length is 2.46 Å. In the fifteenth Li site, Li(15) is bonded to one S(12), one S(17), one S(22), and one S(8) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Ge(2)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(7)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid, and  an edgeedge with one P(3)S4 tetrahedra. The Li(15)-S(12) bond length is 2.48 Å. The Li(15)-S(17) bond length is 2.41 Å. The Li(15)-S(22) bond length is 2.41 Å. The Li(15)-S(8) bond length is 2.38 Å. In the sixteenth Li site, Li(16) is bonded in a 5-coordinate geometry to one S(15), one S(18), one S(3), one S(6), and one S(9) atom. The Li(16)-S(15) bond length is 2.46 Å. The Li(16)-S(18) bond length is 2.79 Å. The Li(16)-S(3) bond length is 2.51 Å. The Li(16)-S(6) bond length is 2.92 Å. The Li(16)-S(9) bond length is 2.67 Å. In the seventeenth Li site, Li(17) is bonded to one S(10), one S(16), one S(4), and one S(5) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Ge(1)S4 tetrahedra,  a cornercorner with one Ge(2)S4 tetrahedra, corners with two equivalent Li(12)S4 tetrahedra, corners with two equivalent Li(13)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(4)S6 octahedra, and  an edgeedge with one P(2)S4 tetrahedra. The Li(17)-S(10) bond length is 2.54 Å. The Li(17)-S(16) bond length is 2.45 Å. The Li(17)-S(4) bond length is 2.50 Å. The Li(17)-S(5) bond length is 2.54 Å. In the eighteenth Li site, Li(18) is bonded to one S(11), one S(13), one S(2), and one S(7) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(20)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(8)S5 square pyramid, and  an edgeedge with one P(1)S4 tetrahedra. The Li(18)-S(11) bond length is 2.62 Å. The Li(18)-S(13) bond length is 2.64 Å. The Li(18)-S(2) bond length is 2.49 Å. The Li(18)-S(7) bond length is 2.43 Å. In the nineteenth Li site, Li(19) is bonded in a 5-coordinate geometry to one S(1), one S(12), one S(18), one S(21), and one S(8) atom. The Li(19)-S(1) bond length is 2.97 Å. The Li(19)-S(12) bond length is 2.53 Å. The Li(19)-S(18) bond length is 2.61 Å. The Li(19)-S(21) bond length is 2.62 Å. The Li(19)-S(8) bond length is 2.42 Å. In the twentieth Li site, Li(20) is bonded to one S(11), one S(18), one S(21), and one S(7) atom to form distorted LiS4 tetrahedra that share  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Ge(2)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra, corners with two equivalent Li(12)S4 tetrahedra, corners with two equivalent Li(18)S4 tetrahedra,  an edgeedge with one P(3)S4 tetrahedra, and  an edgeedge with one Li(10)S5 trigonal bipyramid. The Li(20)-S(11) bond length is 2.55 Å. The Li(20)-S(18) bond length is 2.58 Å. The Li(20)-S(21) bond length is 2.54 Å. The Li(20)-S(7) bond length is 2.48 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one S(10), one S(19), one S(20), and one S(9) atom to form distorted GeS4 tetrahedra that share  a cornercorner with one Li(11)S4 tetrahedra,  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  an edgeedge with one Li(8)S5 square pyramid,  an edgeedge with one Li(14)S4 tetrahedra, and  an edgeedge with one Li(5)S4 tetrahedra. The Ge(1)-S(10) bond length is 2.25 Å. The Ge(1)-S(19) bond length is 2.23 Å. The Ge(1)-S(20) bond length is 2.24 Å. The Ge(1)-S(9) bond length is 2.25 Å. In the second Ge site, Ge(2) is bonded to one S(15), one S(16), one S(21), and one S(22) atom to form GeS4 tetrahedra that share  a cornercorner with one Li(13)S4 tetrahedra,  a cornercorner with one Li(15)S4 tetrahedra,  a cornercorner with one Li(17)S4 tetrahedra,  a cornercorner with one Li(20)S4 tetrahedra, corners with two equivalent Li(10)S5 trigonal bipyramids,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(12)S4 tetrahedra, and  an edgeedge with one Li(7)S4 tetrahedra. The Ge(2)-S(15) bond length is 2.26 Å. The Ge(2)-S(16) bond length is 2.22 Å. The Ge(2)-S(21) bond length is 2.27 Å. The Ge(2)-S(22) bond length is 2.25 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(7), and one S(8) atom to form PS4 tetrahedra that share  a cornercorner with one Li(8)S5 square pyramid,  a cornercorner with one Li(11)S4 tetrahedra,  a cornercorner with one Li(15)S4 tetrahedra,  a cornercorner with one Li(20)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra, and  an edgeedge with one Li(18)S4 tetrahedra. The P(1)-S(1) bond length is 2.05 Å. The P(1)-S(2) bond length is 2.07 Å. The P(1)-S(7) bond length is 2.07 Å. The P(1)-S(8) bond length is 2.02 Å. In the second P site, P(2) is bonded to one S(3), one S(4), one S(5), and one S(6) atom to form PS4 tetrahedra that share corners with two equivalent Li(4)S6 octahedra,  a cornercorner with one Li(12)S4 tetrahedra,  a cornercorner with one Li(14)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  an edgeedge with one Li(13)S4 tetrahedra,  an edgeedge with one Li(17)S4 tetrahedra, and  an edgeedge with one Li(10)S5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 27-54°. The P(2)-S(3) bond length is 2.06 Å. The P(2)-S(4) bond length is 2.06 Å. The P(2)-S(5) bond length is 2.05 Å. The P(2)-S(6) bond length is 2.04 Å. In the third P site, P(3) is bonded to one S(11), one S(12), one S(17), and one S(18) atom to form PS4 tetrahedra that share  a cornercorner with one Li(12)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(10)S5 trigonal bipyramid,  an edgeedge with one Li(15)S4 tetrahedra, and  an edgeedge with one Li(20)S4 tetrahedra. The P(3)-S(11) bond length is 2.07 Å. The P(3)-S(12) bond length is 2.06 Å. The P(3)-S(17) bond length is 2.05 Å. The P(3)-S(18) bond length is 2.07 Å. In the fourth P site, P(4) is bonded to one S(13), one S(14), one S(23), and one S(24) atom to form PS4 tetrahedra that share  a cornercorner with one Li(14)S4 tetrahedra,  a cornercorner with one Li(18)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  an edgeedge with one Li(4)S6 octahedra,  an edgeedge with one Li(8)S5 square pyramid,  an edgeedge with one Li(11)S4 tetrahedra, and  an edgeedge with one Li(9)S4 tetrahedra. The P(4)-S(13) bond length is 2.06 Å. The P(4)-S(14) bond length is 2.06 Å. The P(4)-S(23) bond length is 2.07 Å. The P(4)-S(24) bond length is 2.06 Å. There are twenty-four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(11), one Li(19), one Li(9), and one P(1) atom. In the second S site, S(2) is bonded to one Li(18), one Li(2), one Li(6), one Li(8), and one P(1) atom to form distorted SLi4P square pyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(23)Li4P trigonal bipyramid,  a cornercorner with one S(24)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(8)Li3P trigonal pyramid,  an edgeedge with one S(19)Li4Ge square pyramid,  an edgeedge with one S(20)Li4Ge square pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid, and  an edgeedge with one S(7)Li4P trigonal bipyramid. In the third S site, S(3) is bonded to one Li(1), one Li(10), one Li(13), one Li(16), and one P(2) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(22)Li4Ge trigonal bipyramid,  a cornercorner with one S(18)Li4P trigonal bipyramid, and  a cornercorner with one S(17)Li3P trigonal pyramid. In the fourth S site, S(4) is bonded in a distorted pentagonal planar geometry to one Li(1), one Li(10), one Li(12), one Li(17), and one P(2) atom. In the fifth S site, S(5) is bonded in a 4-coordinate geometry to one Li(13), one Li(17), one Li(4), and one P(2) atom. In the sixth S site, S(6) is bonded in a 5-coordinate geometry to one Li(14), one Li(16), one Li(4), one Li(5), and one P(2) atom. In the seventh S site, S(7) is bonded to one Li(18), one Li(20), one Li(3), one Li(7), and one P(1) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(18)Li4P trigonal bipyramid,  a cornercorner with one S(14)Li3P trigonal pyramid,  a cornercorner with one S(17)Li3P trigonal pyramid, corners with two equivalent S(8)Li3P trigonal pyramids,  an edgeedge with one S(2)Li4P square pyramid,  an edgeedge with one S(22)Li4Ge trigonal bipyramid, and  an edgeedge with one S(13)Li4P trigonal bipyramid. In the eighth S site, S(8) is bonded to one Li(15), one Li(19), one Li(3), and one P(1) atom to form distorted SLi3P trigonal pyramids that share  a cornercorner with one S(2)Li4P square pyramid,  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(18)Li4P trigonal bipyramid, corners with two equivalent S(7)Li4P trigonal bipyramids,  a cornercorner with one S(14)Li3P trigonal pyramid,  a cornercorner with one S(17)Li3P trigonal pyramid, corners with two equivalent S(12)Li3P trigonal pyramids, and  an edgeedge with one S(22)Li4Ge trigonal bipyramid. In the ninth S site, S(9) is bonded in a distorted pentagonal planar geometry to one Li(1), one Li(14), one Li(16), one Li(5), and one Ge(1) atom. In the tenth S site, S(10) is bonded in a 5-coordinate geometry to one Li(1), one Li(13), one Li(17), one Li(8), and one Ge(1) atom. In the eleventh S site, S(11) is bonded in a 4-coordinate geometry to one Li(10), one Li(18), one Li(20), and one P(3) atom. In the twelfth S site, S(12) is bonded to one Li(15), one Li(19), one Li(2), and one P(3) atom to form SLi3P trigonal pyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  a cornercorner with one S(22)Li4Ge trigonal bipyramid, corners with two equivalent S(8)Li3P trigonal pyramids,  an edgeedge with one S(18)Li4P trigonal bipyramid, and  an edgeedge with one S(17)Li3P trigonal pyramid. In the thirteenth S site, S(13) is bonded to one Li(18), one Li(3), one Li(6), one Li(8), and one P(4) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  a cornercorner with one S(22)Li4Ge trigonal bipyramid,  a cornercorner with one S(8)Li3P trigonal pyramid,  an edgeedge with one S(2)Li4P square pyramid,  an edgeedge with one S(23)Li4P trigonal bipyramid,  an edgeedge with one S(24)Li4P trigonal bipyramid,  an edgeedge with one S(7)Li4P trigonal bipyramid, and  an edgeedge with one S(14)Li3P trigonal pyramid. In the fourteenth S site, S(14) is bonded to one Li(11), one Li(3), one Li(9), and one P(4) atom to form SLi3P trigonal pyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(22)Li4Ge trigonal bipyramid,  a cornercorner with one S(7)Li4P trigonal bipyramid,  a cornercorner with one S(8)Li3P trigonal pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid,  an edgeedge with one S(23)Li4P trigonal bipyramid, and  an edgeedge with one S(24)Li4P trigonal bipyramid. In the fifteenth S site, S(15) is bonded in a 5-coordinate geometry to one Li(13), one Li(16), one Li(4), one Li(7), and one Ge(2) atom. In the sixteenth S site, S(16) is bonded in a distorted see-saw-like geometry to one Li(12), one Li(17), one Li(4), and one Ge(2) atom. In the seventeenth S site, S(17) is bonded to one Li(1), one Li(15), one Li(7), and one P(3) atom to form SLi3P trigonal pyramids that share  a cornercorner with one S(18)Li4P trigonal bipyramid,  a cornercorner with one S(3)Li4P trigonal bipyramid,  a cornercorner with one S(7)Li4P trigonal bipyramid, corners with two equivalent S(22)Li4Ge trigonal bipyramids,  a cornercorner with one S(8)Li3P trigonal pyramid, and  an edgeedge with one S(12)Li3P trigonal pyramid. In the eighteenth S site, S(18) is bonded to one Li(12), one Li(16), one Li(19), one Li(20), and one P(3) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(3)Li4P trigonal bipyramid,  a cornercorner with one S(7)Li4P trigonal bipyramid,  a cornercorner with one S(17)Li3P trigonal pyramid,  a cornercorner with one S(8)Li3P trigonal pyramid, and  an edgeedge with one S(12)Li3P trigonal pyramid. In the nineteenth S site, S(19) is bonded to one Li(14), one Li(2), one Li(6), one Li(9), and one Ge(1) atom to form distorted SLi4Ge square pyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(23)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(14)Li3P trigonal pyramid,  an edgeedge with one S(20)Li4Ge square pyramid,  an edgeedge with one S(2)Li4P square pyramid, and  an edgeedge with one S(23)Li4P trigonal bipyramid. In the twentieth S site, S(20) is bonded to one Li(11), one Li(2), one Li(5), one Li(8), and one Ge(1) atom to form distorted SLi4Ge square pyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(24)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(14)Li3P trigonal pyramid,  an edgeedge with one S(19)Li4Ge square pyramid,  an edgeedge with one S(2)Li4P square pyramid, and  an edgeedge with one S(24)Li4P trigonal bipyramid. In the twenty-first S site, S(21) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(19), one Li(20), one Li(3), and one Ge(2) atom. In the twenty-second S site, S(22) is bonded to one Li(10), one Li(15), one Li(3), one Li(7), and one Ge(2) atom to form SLi4Ge trigonal bipyramids that share  a cornercorner with one S(13)Li4P trigonal bipyramid,  a cornercorner with one S(3)Li4P trigonal bipyramid,  a cornercorner with one S(12)Li3P trigonal pyramid,  a cornercorner with one S(14)Li3P trigonal pyramid, corners with two equivalent S(17)Li3P trigonal pyramids,  an edgeedge with one S(7)Li4P trigonal bipyramid, and  an edgeedge with one S(8)Li3P trigonal pyramid. In the twenty-third S site, S(23) is bonded to one Li(14), one Li(4), one Li(6), one Li(9), and one P(4) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(19)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  an edgeedge with one S(19)Li4Ge square pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid,  an edgeedge with one S(24)Li4P trigonal bipyramid, and  an edgeedge with one S(14)Li3P trigonal pyramid. In the twenty-fourth S site, S(24) is bonded to one Li(11), one Li(4), one Li(5), one Li(8), and one P(4) atom to form distorted SLi4P trigonal bipyramids that share  a cornercorner with one S(20)Li4Ge square pyramid,  a cornercorner with one S(2)Li4P square pyramid,  an edgeedge with one S(20)Li4Ge square pyramid,  an edgeedge with one S(13)Li4P trigonal bipyramid,  an edgeedge with one S(23)Li4P trigonal bipyramid, and  an edgeedge with one S(14)Li3P trigonal pyramid.