BaGaB4H3O10 crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 9-coordinate geometry to one H(1), one O(1), one O(2), one O(3), one O(5), one O(6), one O(8), and two equivalent O(4) atoms. Ga(1) is bonded in a 3-coordinate geometry to one O(2), one O(4), one O(6), and one O(7) atom. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 4-coordinate geometry to one O(1), one O(5), one O(6), and one O(7) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. In the fourth B site, B(4) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ba(1) and one O(8) atom. In the second H site, H(2) is bonded in a bent 150 degrees geometry to one O(10) and one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one B(1), and one B(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ba(1), one Ga(1), and one B(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one B(2), and one B(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Ga(1), and one B(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one B(1), and one B(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ba(1), one Ga(1), and one B(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Ga(1), one B(1), one B(4), and one H(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Ba(1), one B(4), and one H(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one B(4) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one H(2) and one H(3) atom.
BaGaB4H3O10 crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 9-coordinate geometry to one H(1), one O(1), one O(2), one O(3), one O(5), one O(6), one O(8), and two equivalent O(4) atoms. The Ba(1)-H(1) bond length is 2.38 Å. The Ba(1)-O(1) bond length is 2.95 Å. The Ba(1)-O(2) bond length is 3.36 Å. The Ba(1)-O(3) bond length is 2.64 Å. The Ba(1)-O(5) bond length is 2.88 Å. The Ba(1)-O(6) bond length is 2.60 Å. The Ba(1)-O(8) bond length is 2.35 Å. There is one shorter (2.83 Å) and one longer (3.44 Å) Ba(1)-O(4) bond length. Ga(1) is bonded in a 3-coordinate geometry to one O(2), one O(4), one O(6), and one O(7) atom. The Ga(1)-O(2) bond length is 1.90 Å. The Ga(1)-O(4) bond length is 1.83 Å. The Ga(1)-O(6) bond length is 2.05 Å. The Ga(1)-O(7) bond length is 2.35 Å. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 4-coordinate geometry to one O(1), one O(5), one O(6), and one O(7) atom. The B(1)-O(1) bond length is 1.46 Å. The B(1)-O(5) bond length is 1.69 Å. The B(1)-O(6) bond length is 1.27 Å. The B(1)-O(7) bond length is 1.97 Å. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The B(2)-O(1) bond length is 1.57 Å. The B(2)-O(2) bond length is 1.30 Å. The B(2)-O(3) bond length is 1.48 Å. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The B(3)-O(3) bond length is 1.41 Å. The B(3)-O(4) bond length is 1.66 Å. The B(3)-O(5) bond length is 1.53 Å. In the fourth B site, B(4) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. The B(4)-O(7) bond length is 1.77 Å. The B(4)-O(8) bond length is 1.74 Å. The B(4)-O(9) bond length is 0.94 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ba(1) and one O(8) atom. The H(1)-O(8) bond length is 1.23 Å. In the second H site, H(2) is bonded in a bent 150 degrees geometry to one O(10) and one O(7) atom. The H(2)-O(10) bond length is 0.94 Å. The H(2)-O(7) bond length is 1.51 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) atom. The H(3)-O(10) bond length is 0.98 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one B(1), and one B(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ba(1), one Ga(1), and one B(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one B(2), and one B(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Ga(1), and one B(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one B(1), and one B(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ba(1), one Ga(1), and one B(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Ga(1), one B(1), one B(4), and one H(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Ba(1), one B(4), and one H(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one B(4) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one H(2) and one H(3) atom.