VOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. O(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms.
VOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There is one shorter (1.88 Å) and two longer (1.95 Å) V(1)-O(1) bond lengths. There are two shorter (2.06 Å) and one longer (2.10 Å) V(1)-F(1) bond length. O(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms.