La2MoZnO6 crystallizes in the trigonal R-3 space group. La(1) is bonded in a distorted trigonal planar geometry to nine equivalent O(1) atoms. Mo(1) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. O(1) is bonded in a 3-coordinate geometry to three equivalent La(1), one Mo(1), and one Zn(1) atom.
La2MoZnO6 crystallizes in the trigonal R-3 space group. La(1) is bonded in a distorted trigonal planar geometry to nine equivalent O(1) atoms. There are a spread of La(1)-O(1) bond distances ranging from 2.36-2.90 Å. Mo(1) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. All Mo(1)-O(1) bond lengths are 2.07 Å. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. All Zn(1)-O(1) bond lengths are 2.12 Å. O(1) is bonded in a 3-coordinate geometry to three equivalent La(1), one Mo(1), and one Zn(1) atom.