K2Sn(OH)6 crystallizes in the trigonal R-3 space group. K(1) is bonded in a 9-coordinate geometry to three equivalent H(1) and six equivalent O(1) atoms. Sn(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. H(1) is bonded in a single-bond geometry to one K(1) and one O(1) atom. O(1) is bonded in a distorted single-bond geometry to two equivalent K(1), one Sn(1), and one H(1) atom.
K2Sn(OH)6 crystallizes in the trigonal R-3 space group. K(1) is bonded in a 9-coordinate geometry to three equivalent H(1) and six equivalent O(1) atoms. All K(1)-H(1) bond lengths are 2.74 Å. There are three shorter (2.80 Å) and three longer (3.02 Å) K(1)-O(1) bond lengths. Sn(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Sn(1)-O(1) bond lengths are 2.11 Å. H(1) is bonded in a single-bond geometry to one K(1) and one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. O(1) is bonded in a distorted single-bond geometry to two equivalent K(1), one Sn(1), and one H(1) atom.