Li2BiS2 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing LiS4 tetrahedra. Bi(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent Bi(1) atoms.
Li2BiS2 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing LiS4 tetrahedra. There are a spread of Li(1)-S(1) bond distances ranging from 2.38-2.54 Å. Bi(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. There are two shorter (2.81 Å) and two longer (2.83 Å) Bi(1)-S(1) bond lengths. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent Bi(1) atoms.