Zn(SbO2)2 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(17), one O(3), and one O(4) atom to form distorted ZnO4 trigonal pyramids that share  a cornercorner with one Sb(12)O5 square pyramid and  a cornercorner with one Zn(3)O4 trigonal pyramid. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(6), and one O(9) atom. In the third Zn site, Zn(3) is bonded to one O(21), one O(23), one O(24), and one O(4) atom to form distorted ZnO4 trigonal pyramids that share corners with three equivalent Sb(12)O5 square pyramids and  a cornercorner with one Zn(1)O4 trigonal pyramid. In the fourth Zn site, Zn(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(14), one O(18), and one O(20) atom. In the fifth Zn site, Zn(5) is bonded in a tetrahedral geometry to one O(11), one O(16), one O(5), and one O(7) atom. In the sixth Zn site, Zn(6) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(15), and one O(19) atom. There are twelve inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(7) atom. In the second Sb site, Sb(2) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(4), and one O(8) atom. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(10), one O(15), and one O(6) atom. In the fourth Sb site, Sb(4) is bonded in a distorted see-saw-like geometry to one O(1), one O(11), one O(2), and one O(5) atom. In the fifth Sb site, Sb(5) is bonded in a rectangular see-saw-like geometry to one O(11), one O(12), one O(5), and one O(7) atom. In the sixth Sb site, Sb(6) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(16), and one O(9) atom. In the seventh Sb site, Sb(7) is bonded in a 4-coordinate geometry to one O(14), one O(18), one O(20), and one O(22) atom. In the eighth Sb site, Sb(8) is bonded in a rectangular see-saw-like geometry to one O(10), one O(13), one O(19), and one O(6) atom. In the ninth Sb site, Sb(9) is bonded in a distorted trigonal non-coplanar geometry to one O(20), one O(22), and one O(24) atom. In the tenth Sb site, Sb(10) is bonded in a distorted square pyramidal geometry to one O(13), one O(14), one O(15), one O(18), and one O(19) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(17), one O(21), and one O(23) atom. In the twelfth Sb site, Sb(12) is bonded to one O(17), one O(21), one O(23), one O(24), and one O(8) atom to form SbO5 square pyramids that share  a cornercorner with one Zn(1)O4 trigonal pyramid and corners with three equivalent Zn(3)O4 trigonal pyramids. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Sb(1), and one Sb(4) atom. In the second O site, O(2) is bonded in a water-like geometry to one Sb(1) and one Sb(4) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Zn(3), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Zn(5), one Sb(4), and one Sb(5) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Zn(2), one Sb(3), and one Sb(8) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Zn(5), one Sb(1), and one Sb(5) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Sb(12) and one Sb(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one Sb(6) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Zn(4), one Sb(3), and one Sb(8) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Zn(5), one Sb(4), and one Sb(5) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Zn(2), one Sb(5), and one Sb(6) atom. In the thirteenth O site, O(13) is bonded in a trigonal non-coplanar geometry to one Zn(6), one Sb(10), and one Sb(8) atom. In the fourteenth O site, O(14) is bonded in a distorted tetrahedral geometry to one Zn(4), one Zn(6), one Sb(10), and one Sb(7) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(5) and one Sb(6) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Zn(1), one Sb(11), and one Sb(12) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Zn(4), one Sb(10), and one Sb(7) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Zn(4), one Sb(7), and one Sb(9) atom. In the twenty-first O site, O(21) is bonded in a trigonal non-coplanar geometry to one Zn(3), one Sb(11), and one Sb(12) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Sb(7) and one Sb(9) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Zn(3), one Sb(11), and one Sb(12) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Zn(3), one Sb(12), and one Sb(9) atom.
Zn(SbO2)2 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(17), one O(3), and one O(4) atom to form distorted ZnO4 trigonal pyramids that share  a cornercorner with one Sb(12)O5 square pyramid and  a cornercorner with one Zn(3)O4 trigonal pyramid. The Zn(1)-O(1) bond length is 2.03 Å. The Zn(1)-O(17) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 2.01 Å. The Zn(1)-O(4) bond length is 2.07 Å. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(6), and one O(9) atom. The Zn(2)-O(12) bond length is 1.92 Å. The Zn(2)-O(6) bond length is 2.20 Å. The Zn(2)-O(9) bond length is 1.88 Å. In the third Zn site, Zn(3) is bonded to one O(21), one O(23), one O(24), and one O(4) atom to form distorted ZnO4 trigonal pyramids that share corners with three equivalent Sb(12)O5 square pyramids and  a cornercorner with one Zn(1)O4 trigonal pyramid. The Zn(3)-O(21) bond length is 2.06 Å. The Zn(3)-O(23) bond length is 2.07 Å. The Zn(3)-O(24) bond length is 2.03 Å. The Zn(3)-O(4) bond length is 1.95 Å. In the fourth Zn site, Zn(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(14), one O(18), and one O(20) atom. The Zn(4)-O(10) bond length is 2.22 Å. The Zn(4)-O(14) bond length is 1.96 Å. The Zn(4)-O(18) bond length is 1.90 Å. The Zn(4)-O(20) bond length is 2.22 Å. In the fifth Zn site, Zn(5) is bonded in a tetrahedral geometry to one O(11), one O(16), one O(5), and one O(7) atom. The Zn(5)-O(11) bond length is 2.03 Å. The Zn(5)-O(16) bond length is 1.97 Å. The Zn(5)-O(5) bond length is 2.02 Å. The Zn(5)-O(7) bond length is 2.06 Å. In the sixth Zn site, Zn(6) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(15), and one O(19) atom. The Zn(6)-O(13) bond length is 2.03 Å. The Zn(6)-O(14) bond length is 2.34 Å. The Zn(6)-O(15) bond length is 1.98 Å. The Zn(6)-O(19) bond length is 1.94 Å. There are twelve inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(7) atom. The Sb(1)-O(1) bond length is 2.04 Å. The Sb(1)-O(2) bond length is 2.02 Å. The Sb(1)-O(3) bond length is 2.44 Å. The Sb(1)-O(7) bond length is 2.14 Å. In the second Sb site, Sb(2) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(4), and one O(8) atom. The Sb(2)-O(3) bond length is 1.96 Å. The Sb(2)-O(4) bond length is 1.99 Å. The Sb(2)-O(8) bond length is 2.02 Å. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(10), one O(15), and one O(6) atom. The Sb(3)-O(10) bond length is 2.05 Å. The Sb(3)-O(15) bond length is 1.97 Å. The Sb(3)-O(6) bond length is 2.02 Å. In the fourth Sb site, Sb(4) is bonded in a distorted see-saw-like geometry to one O(1), one O(11), one O(2), and one O(5) atom. The Sb(4)-O(1) bond length is 2.29 Å. The Sb(4)-O(11) bond length is 2.23 Å. The Sb(4)-O(2) bond length is 1.99 Å. The Sb(4)-O(5) bond length is 2.00 Å. In the fifth Sb site, Sb(5) is bonded in a rectangular see-saw-like geometry to one O(11), one O(12), one O(5), and one O(7) atom. The Sb(5)-O(11) bond length is 2.03 Å. The Sb(5)-O(12) bond length is 2.35 Å. The Sb(5)-O(5) bond length is 2.26 Å. The Sb(5)-O(7) bond length is 2.04 Å. In the sixth Sb site, Sb(6) is bonded in a distorted trigonal non-coplanar geometry to one O(12), one O(16), and one O(9) atom. The Sb(6)-O(12) bond length is 2.04 Å. The Sb(6)-O(16) bond length is 1.93 Å. The Sb(6)-O(9) bond length is 1.96 Å. In the seventh Sb site, Sb(7) is bonded in a 4-coordinate geometry to one O(14), one O(18), one O(20), and one O(22) atom. The Sb(7)-O(14) bond length is 2.03 Å. The Sb(7)-O(18) bond length is 2.46 Å. The Sb(7)-O(20) bond length is 2.17 Å. The Sb(7)-O(22) bond length is 2.00 Å. In the eighth Sb site, Sb(8) is bonded in a rectangular see-saw-like geometry to one O(10), one O(13), one O(19), and one O(6) atom. The Sb(8)-O(10) bond length is 2.01 Å. The Sb(8)-O(13) bond length is 2.03 Å. The Sb(8)-O(19) bond length is 2.13 Å. The Sb(8)-O(6) bond length is 2.26 Å. In the ninth Sb site, Sb(9) is bonded in a distorted trigonal non-coplanar geometry to one O(20), one O(22), and one O(24) atom. The Sb(9)-O(20) bond length is 1.98 Å. The Sb(9)-O(22) bond length is 2.02 Å. The Sb(9)-O(24) bond length is 1.98 Å. In the tenth Sb site, Sb(10) is bonded in a distorted square pyramidal geometry to one O(13), one O(14), one O(15), one O(18), and one O(19) atom. The Sb(10)-O(13) bond length is 2.06 Å. The Sb(10)-O(14) bond length is 2.31 Å. The Sb(10)-O(15) bond length is 2.59 Å. The Sb(10)-O(18) bond length is 2.05 Å. The Sb(10)-O(19) bond length is 2.10 Å. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(17), one O(21), and one O(23) atom. The Sb(11)-O(17) bond length is 1.99 Å. The Sb(11)-O(21) bond length is 1.99 Å. The Sb(11)-O(23) bond length is 2.01 Å. In the twelfth Sb site, Sb(12) is bonded to one O(17), one O(21), one O(23), one O(24), and one O(8) atom to form SbO5 square pyramids that share  a cornercorner with one Zn(1)O4 trigonal pyramid and corners with three equivalent Zn(3)O4 trigonal pyramids. The Sb(12)-O(17) bond length is 2.20 Å. The Sb(12)-O(21) bond length is 2.25 Å. The Sb(12)-O(23) bond length is 2.24 Å. The Sb(12)-O(24) bond length is 2.50 Å. The Sb(12)-O(8) bond length is 1.95 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Sb(1), and one Sb(4) atom. In the second O site, O(2) is bonded in a water-like geometry to one Sb(1) and one Sb(4) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Zn(3), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Zn(5), one Sb(4), and one Sb(5) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Zn(2), one Sb(3), and one Sb(8) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Zn(5), one Sb(1), and one Sb(5) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Sb(12) and one Sb(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one Sb(6) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Zn(4), one Sb(3), and one Sb(8) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Zn(5), one Sb(4), and one Sb(5) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Zn(2), one Sb(5), and one Sb(6) atom. In the thirteenth O site, O(13) is bonded in a trigonal non-coplanar geometry to one Zn(6), one Sb(10), and one Sb(8) atom. In the fourteenth O site, O(14) is bonded in a distorted tetrahedral geometry to one Zn(4), one Zn(6), one Sb(10), and one Sb(7) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(5) and one Sb(6) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Zn(1), one Sb(11), and one Sb(12) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Zn(4), one Sb(10), and one Sb(7) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Zn(4), one Sb(7), and one Sb(9) atom. In the twenty-first O site, O(21) is bonded in a trigonal non-coplanar geometry to one Zn(3), one Sb(11), and one Sb(12) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Sb(7) and one Sb(9) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Zn(3), one Sb(11), and one Sb(12) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Zn(3), one Sb(12), and one Sb(9) atom.