Li3Mn5OF11 is Corundum-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(1), one F(11), one F(3), one F(5), one F(7), and one F(9) atom to form distorted LiF6 octahedra that share  a cornercorner with one Mn(2)OF5 octahedra, corners with two equivalent Mn(3)F6 octahedra, corners with three equivalent Mn(4)F6 octahedra, corners with three equivalent Mn(5)OF5 octahedra,  an edgeedge with one Li(3)OF5 octahedra, edges with two equivalent Li(2)F6 octahedra, and  a faceface with one Mn(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the second Li site, Li(2) is bonded to one F(10), one F(2), one F(3), one F(5), one F(7), and one F(9) atom to form distorted LiF6 octahedra that share  a cornercorner with one Mn(5)OF5 octahedra, corners with two equivalent Mn(4)F6 octahedra, corners with three equivalent Mn(3)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(1)OF5 octahedra, edges with two equivalent Li(1)F6 octahedra, and  a faceface with one Mn(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-64°. In the third Li site, Li(3) is bonded to one O(1), one F(1), one F(11), one F(4), one F(6), and one F(8) atom to form LiOF5 octahedra that share  a cornercorner with one Mn(4)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with three equivalent Mn(3)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra,  an edgeedge with one Li(1)F6 octahedra, edges with two equivalent Mn(1)OF5 octahedra, and  a faceface with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-64°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(10), one F(2), one F(4), one F(6), and one F(8) atom to form distorted MnOF5 octahedra that share  a cornercorner with one Mn(3)F6 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with three equivalent Mn(4)F6 octahedra, corners with three equivalent Mn(5)OF5 octahedra,  an edgeedge with one Li(2)F6 octahedra, edges with two equivalent Li(3)OF5 octahedra, and  a faceface with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-66°. In the second Mn site, Mn(2) is bonded to one O(1), one F(10), one F(2), one F(3), one F(4), and one F(6) atom to form distorted MnOF5 octahedra that share  a cornercorner with one Li(1)F6 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with three equivalent Li(2)F6 octahedra, corners with three equivalent Li(3)OF5 octahedra,  an edgeedge with one Mn(5)OF5 octahedra, edges with two equivalent Mn(4)F6 octahedra, and  a faceface with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-66°. In the third Mn site, Mn(3) is bonded to one F(1), one F(11), one F(5), one F(7), one F(8), and one F(9) atom to form MnF6 octahedra that share  a cornercorner with one Mn(1)OF5 octahedra, corners with two equivalent Li(1)F6 octahedra, corners with three equivalent Li(2)F6 octahedra, corners with three equivalent Li(3)OF5 octahedra,  an edgeedge with one Mn(4)F6 octahedra, edges with two equivalent Mn(5)OF5 octahedra, and  a faceface with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. In the fourth Mn site, Mn(4) is bonded to one F(10), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form distorted MnF6 octahedra that share  a cornercorner with one Li(3)OF5 octahedra, corners with two equivalent Li(2)F6 octahedra, corners with three equivalent Li(1)F6 octahedra, corners with three equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(3)F6 octahedra, edges with two equivalent Mn(2)OF5 octahedra, and  a faceface with one Li(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. In the fifth Mn site, Mn(5) is bonded to one O(1), one F(1), one F(11), one F(6), one F(8), and one F(9) atom to form distorted MnOF5 octahedra that share  a cornercorner with one Li(2)F6 octahedra, corners with two equivalent Li(3)OF5 octahedra, corners with three equivalent Li(1)F6 octahedra, corners with three equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, edges with two equivalent Mn(3)F6 octahedra, and  a faceface with one Li(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. O(1) is bonded to one Li(3), one Mn(1), one Mn(2), and one Mn(5) atom to form OLiMn3 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(11)Li2Mn2 trigonal pyramids, corners with two equivalent F(10)LiMn3 trigonal pyramids, corners with two equivalent F(2)LiMn3 trigonal pyramids, corners with three equivalent F(4)LiMn3 trigonal pyramids,  an edgeedge with one F(1)Li2Mn2 trigonal pyramid, and  an edgeedge with one F(8)LiMn3 trigonal pyramid. There are eleven inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(3), one Mn(3), and one Mn(5) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(5)Li2Mn2 trigonal pyramids, corners with two equivalent F(7)Li2Mn2 trigonal pyramids, corners with three equivalent F(9)Li2Mn2 trigonal pyramids,  an edgeedge with one O(1)LiMn3 trigonal pyramid,  an edgeedge with one F(8)LiMn3 trigonal pyramid, and edges with two equivalent F(11)Li2Mn2 trigonal pyramids. In the second F site, F(2) is bonded to one Li(2), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent O(1)LiMn3 trigonal pyramids, corners with two equivalent F(5)Li2Mn2 trigonal pyramids, corners with three equivalent F(4)LiMn3 trigonal pyramids,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(7)Li2Mn2 trigonal pyramid, and edges with two equivalent F(10)LiMn3 trigonal pyramids. In the third F site, F(3) is bonded to one Li(1), one Li(2), one Mn(2), and one Mn(4) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one O(1)LiMn3 trigonal pyramid,  a cornercorner with one F(1)Li2Mn2 trigonal pyramid,  a cornercorner with one F(11)Li2Mn2 trigonal pyramid,  a cornercorner with one F(7)Li2Mn2 trigonal pyramid,  a cornercorner with one F(2)LiMn3 trigonal pyramid, corners with three equivalent F(5)Li2Mn2 trigonal pyramids, corners with three equivalent F(10)LiMn3 trigonal pyramids,  an edgeedge with one F(7)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid,  an edgeedge with one F(2)LiMn3 trigonal pyramid, and  an edgeedge with one F(4)LiMn3 trigonal pyramid. In the fourth F site, F(4) is bonded to one Li(3), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one F(1)Li2Mn2 trigonal pyramid,  a cornercorner with one F(11)Li2Mn2 trigonal pyramid,  a cornercorner with one F(5)Li2Mn2 trigonal pyramid,  a cornercorner with one F(7)Li2Mn2 trigonal pyramid,  a cornercorner with one F(10)LiMn3 trigonal pyramid, corners with three equivalent O(1)LiMn3 trigonal pyramids, corners with three equivalent F(2)LiMn3 trigonal pyramids,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(10)LiMn3 trigonal pyramid, and  an edgeedge with one F(8)LiMn3 trigonal pyramid. In the fifth F site, F(5) is bonded to one Li(1), one Li(2), one Mn(3), and one Mn(4) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(1)Li2Mn2 trigonal pyramids, corners with two equivalent F(10)LiMn3 trigonal pyramids, corners with two equivalent F(2)LiMn3 trigonal pyramids, corners with three equivalent F(3)Li2Mn2 trigonal pyramids,  an edgeedge with one F(11)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid, and edges with two equivalent F(7)Li2Mn2 trigonal pyramids. In the sixth F site, F(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(1), one Mn(2), and one Mn(5) atom. In the seventh F site, F(7) is bonded to one Li(1), one Li(2), one Mn(3), and one Mn(4) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(1)Li2Mn2 trigonal pyramids, corners with two equivalent F(11)Li2Mn2 trigonal pyramids, corners with two equivalent F(10)LiMn3 trigonal pyramids, corners with three equivalent F(9)Li2Mn2 trigonal pyramids,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(2)LiMn3 trigonal pyramid, and edges with two equivalent F(5)Li2Mn2 trigonal pyramids. In the eighth F site, F(8) is bonded to one Li(3), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one O(1)LiMn3 trigonal pyramid,  a cornercorner with one F(1)Li2Mn2 trigonal pyramid,  a cornercorner with one F(5)Li2Mn2 trigonal pyramid,  a cornercorner with one F(7)Li2Mn2 trigonal pyramid,  a cornercorner with one F(10)LiMn3 trigonal pyramid,  a cornercorner with one F(2)LiMn3 trigonal pyramid, corners with three equivalent F(11)Li2Mn2 trigonal pyramids,  an edgeedge with one O(1)LiMn3 trigonal pyramid,  an edgeedge with one F(1)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid, and  an edgeedge with one F(4)LiMn3 trigonal pyramid. In the ninth F site, F(9) is bonded to one Li(1), one Li(2), one Mn(3), and one Mn(5) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one O(1)LiMn3 trigonal pyramid,  a cornercorner with one F(11)Li2Mn2 trigonal pyramid,  a cornercorner with one F(5)Li2Mn2 trigonal pyramid,  a cornercorner with one F(10)LiMn3 trigonal pyramid,  a cornercorner with one F(2)LiMn3 trigonal pyramid, corners with three equivalent F(1)Li2Mn2 trigonal pyramids, corners with three equivalent F(7)Li2Mn2 trigonal pyramids,  an edgeedge with one F(11)Li2Mn2 trigonal pyramid,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(5)Li2Mn2 trigonal pyramid, and  an edgeedge with one F(8)LiMn3 trigonal pyramid. In the tenth F site, F(10) is bonded to one Li(2), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent O(1)LiMn3 trigonal pyramids, corners with two equivalent F(5)Li2Mn2 trigonal pyramids, corners with two equivalent F(7)Li2Mn2 trigonal pyramids, corners with three equivalent F(3)Li2Mn2 trigonal pyramids,  an edgeedge with one F(4)LiMn3 trigonal pyramid, and edges with two equivalent F(2)LiMn3 trigonal pyramids. In the eleventh F site, F(11) is bonded to one Li(1), one Li(3), one Mn(3), and one Mn(5) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid, corners with two equivalent O(1)LiMn3 trigonal pyramids, corners with two equivalent F(7)Li2Mn2 trigonal pyramids, corners with three equivalent F(8)LiMn3 trigonal pyramids,  an edgeedge with one F(5)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid, and edges with two equivalent F(1)Li2Mn2 trigonal pyramids.
Li3Mn5OF11 is Corundum-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(1), one F(11), one F(3), one F(5), one F(7), and one F(9) atom to form distorted LiF6 octahedra that share  a cornercorner with one Mn(2)OF5 octahedra, corners with two equivalent Mn(3)F6 octahedra, corners with three equivalent Mn(4)F6 octahedra, corners with three equivalent Mn(5)OF5 octahedra,  an edgeedge with one Li(3)OF5 octahedra, edges with two equivalent Li(2)F6 octahedra, and  a faceface with one Mn(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. The Li(1)-F(1) bond length is 1.97 Å. The Li(1)-F(11) bond length is 2.17 Å. The Li(1)-F(3) bond length is 2.09 Å. The Li(1)-F(5) bond length is 2.29 Å. The Li(1)-F(7) bond length is 2.06 Å. The Li(1)-F(9) bond length is 2.30 Å. In the second Li site, Li(2) is bonded to one F(10), one F(2), one F(3), one F(5), one F(7), and one F(9) atom to form distorted LiF6 octahedra that share  a cornercorner with one Mn(5)OF5 octahedra, corners with two equivalent Mn(4)F6 octahedra, corners with three equivalent Mn(3)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(1)OF5 octahedra, edges with two equivalent Li(1)F6 octahedra, and  a faceface with one Mn(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-64°. The Li(2)-F(10) bond length is 2.17 Å. The Li(2)-F(2) bond length is 2.34 Å. The Li(2)-F(3) bond length is 2.20 Å. The Li(2)-F(5) bond length is 2.04 Å. The Li(2)-F(7) bond length is 2.20 Å. The Li(2)-F(9) bond length is 1.99 Å. In the third Li site, Li(3) is bonded to one O(1), one F(1), one F(11), one F(4), one F(6), and one F(8) atom to form LiOF5 octahedra that share  a cornercorner with one Mn(4)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with three equivalent Mn(3)F6 octahedra, corners with three equivalent Mn(2)OF5 octahedra,  an edgeedge with one Li(1)F6 octahedra, edges with two equivalent Mn(1)OF5 octahedra, and  a faceface with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-64°. The Li(3)-O(1) bond length is 2.11 Å. The Li(3)-F(1) bond length is 2.28 Å. The Li(3)-F(11) bond length is 2.14 Å. The Li(3)-F(4) bond length is 2.19 Å. The Li(3)-F(6) bond length is 2.03 Å. The Li(3)-F(8) bond length is 2.17 Å. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(10), one F(2), one F(4), one F(6), and one F(8) atom to form distorted MnOF5 octahedra that share  a cornercorner with one Mn(3)F6 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with three equivalent Mn(4)F6 octahedra, corners with three equivalent Mn(5)OF5 octahedra,  an edgeedge with one Li(2)F6 octahedra, edges with two equivalent Li(3)OF5 octahedra, and  a faceface with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-66°. The Mn(1)-O(1) bond length is 2.01 Å. The Mn(1)-F(10) bond length is 2.29 Å. The Mn(1)-F(2) bond length is 2.17 Å. The Mn(1)-F(4) bond length is 2.27 Å. The Mn(1)-F(6) bond length is 2.24 Å. The Mn(1)-F(8) bond length is 2.16 Å. In the second Mn site, Mn(2) is bonded to one O(1), one F(10), one F(2), one F(3), one F(4), and one F(6) atom to form distorted MnOF5 octahedra that share  a cornercorner with one Li(1)F6 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with three equivalent Li(2)F6 octahedra, corners with three equivalent Li(3)OF5 octahedra,  an edgeedge with one Mn(5)OF5 octahedra, edges with two equivalent Mn(4)F6 octahedra, and  a faceface with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-66°. The Mn(2)-O(1) bond length is 2.01 Å. The Mn(2)-F(10) bond length is 2.36 Å. The Mn(2)-F(2) bond length is 2.14 Å. The Mn(2)-F(3) bond length is 2.12 Å. The Mn(2)-F(4) bond length is 2.29 Å. The Mn(2)-F(6) bond length is 2.31 Å. In the third Mn site, Mn(3) is bonded to one F(1), one F(11), one F(5), one F(7), one F(8), and one F(9) atom to form MnF6 octahedra that share  a cornercorner with one Mn(1)OF5 octahedra, corners with two equivalent Li(1)F6 octahedra, corners with three equivalent Li(2)F6 octahedra, corners with three equivalent Li(3)OF5 octahedra,  an edgeedge with one Mn(4)F6 octahedra, edges with two equivalent Mn(5)OF5 octahedra, and  a faceface with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. The Mn(3)-F(1) bond length is 2.10 Å. The Mn(3)-F(11) bond length is 2.20 Å. The Mn(3)-F(5) bond length is 2.19 Å. The Mn(3)-F(7) bond length is 2.12 Å. The Mn(3)-F(8) bond length is 2.10 Å. The Mn(3)-F(9) bond length is 2.20 Å. In the fourth Mn site, Mn(4) is bonded to one F(10), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form distorted MnF6 octahedra that share  a cornercorner with one Li(3)OF5 octahedra, corners with two equivalent Li(2)F6 octahedra, corners with three equivalent Li(1)F6 octahedra, corners with three equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(3)F6 octahedra, edges with two equivalent Mn(2)OF5 octahedra, and  a faceface with one Li(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. The Mn(4)-F(10) bond length is 2.12 Å. The Mn(4)-F(2) bond length is 2.20 Å. The Mn(4)-F(3) bond length is 2.22 Å. The Mn(4)-F(4) bond length is 2.13 Å. The Mn(4)-F(5) bond length is 2.10 Å. The Mn(4)-F(7) bond length is 2.20 Å. In the fifth Mn site, Mn(5) is bonded to one O(1), one F(1), one F(11), one F(6), one F(8), and one F(9) atom to form distorted MnOF5 octahedra that share  a cornercorner with one Li(2)F6 octahedra, corners with two equivalent Li(3)OF5 octahedra, corners with three equivalent Li(1)F6 octahedra, corners with three equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, edges with two equivalent Mn(3)F6 octahedra, and  a faceface with one Li(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. The Mn(5)-O(1) bond length is 2.06 Å. The Mn(5)-F(1) bond length is 2.25 Å. The Mn(5)-F(11) bond length is 2.14 Å. The Mn(5)-F(6) bond length is 2.17 Å. The Mn(5)-F(8) bond length is 2.34 Å. The Mn(5)-F(9) bond length is 2.14 Å. O(1) is bonded to one Li(3), one Mn(1), one Mn(2), and one Mn(5) atom to form OLiMn3 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(11)Li2Mn2 trigonal pyramids, corners with two equivalent F(10)LiMn3 trigonal pyramids, corners with two equivalent F(2)LiMn3 trigonal pyramids, corners with three equivalent F(4)LiMn3 trigonal pyramids,  an edgeedge with one F(1)Li2Mn2 trigonal pyramid, and  an edgeedge with one F(8)LiMn3 trigonal pyramid. There are eleven inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(3), one Mn(3), and one Mn(5) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(5)Li2Mn2 trigonal pyramids, corners with two equivalent F(7)Li2Mn2 trigonal pyramids, corners with three equivalent F(9)Li2Mn2 trigonal pyramids,  an edgeedge with one O(1)LiMn3 trigonal pyramid,  an edgeedge with one F(8)LiMn3 trigonal pyramid, and edges with two equivalent F(11)Li2Mn2 trigonal pyramids. In the second F site, F(2) is bonded to one Li(2), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent O(1)LiMn3 trigonal pyramids, corners with two equivalent F(5)Li2Mn2 trigonal pyramids, corners with three equivalent F(4)LiMn3 trigonal pyramids,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(7)Li2Mn2 trigonal pyramid, and edges with two equivalent F(10)LiMn3 trigonal pyramids. In the third F site, F(3) is bonded to one Li(1), one Li(2), one Mn(2), and one Mn(4) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one O(1)LiMn3 trigonal pyramid,  a cornercorner with one F(1)Li2Mn2 trigonal pyramid,  a cornercorner with one F(11)Li2Mn2 trigonal pyramid,  a cornercorner with one F(7)Li2Mn2 trigonal pyramid,  a cornercorner with one F(2)LiMn3 trigonal pyramid, corners with three equivalent F(5)Li2Mn2 trigonal pyramids, corners with three equivalent F(10)LiMn3 trigonal pyramids,  an edgeedge with one F(7)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid,  an edgeedge with one F(2)LiMn3 trigonal pyramid, and  an edgeedge with one F(4)LiMn3 trigonal pyramid. In the fourth F site, F(4) is bonded to one Li(3), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one F(1)Li2Mn2 trigonal pyramid,  a cornercorner with one F(11)Li2Mn2 trigonal pyramid,  a cornercorner with one F(5)Li2Mn2 trigonal pyramid,  a cornercorner with one F(7)Li2Mn2 trigonal pyramid,  a cornercorner with one F(10)LiMn3 trigonal pyramid, corners with three equivalent O(1)LiMn3 trigonal pyramids, corners with three equivalent F(2)LiMn3 trigonal pyramids,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(10)LiMn3 trigonal pyramid, and  an edgeedge with one F(8)LiMn3 trigonal pyramid. In the fifth F site, F(5) is bonded to one Li(1), one Li(2), one Mn(3), and one Mn(4) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(1)Li2Mn2 trigonal pyramids, corners with two equivalent F(10)LiMn3 trigonal pyramids, corners with two equivalent F(2)LiMn3 trigonal pyramids, corners with three equivalent F(3)Li2Mn2 trigonal pyramids,  an edgeedge with one F(11)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid, and edges with two equivalent F(7)Li2Mn2 trigonal pyramids. In the sixth F site, F(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(1), one Mn(2), and one Mn(5) atom. In the seventh F site, F(7) is bonded to one Li(1), one Li(2), one Mn(3), and one Mn(4) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent F(1)Li2Mn2 trigonal pyramids, corners with two equivalent F(11)Li2Mn2 trigonal pyramids, corners with two equivalent F(10)LiMn3 trigonal pyramids, corners with three equivalent F(9)Li2Mn2 trigonal pyramids,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(2)LiMn3 trigonal pyramid, and edges with two equivalent F(5)Li2Mn2 trigonal pyramids. In the eighth F site, F(8) is bonded to one Li(3), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one O(1)LiMn3 trigonal pyramid,  a cornercorner with one F(1)Li2Mn2 trigonal pyramid,  a cornercorner with one F(5)Li2Mn2 trigonal pyramid,  a cornercorner with one F(7)Li2Mn2 trigonal pyramid,  a cornercorner with one F(10)LiMn3 trigonal pyramid,  a cornercorner with one F(2)LiMn3 trigonal pyramid, corners with three equivalent F(11)Li2Mn2 trigonal pyramids,  an edgeedge with one O(1)LiMn3 trigonal pyramid,  an edgeedge with one F(1)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid, and  an edgeedge with one F(4)LiMn3 trigonal pyramid. In the ninth F site, F(9) is bonded to one Li(1), one Li(2), one Mn(3), and one Mn(5) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one O(1)LiMn3 trigonal pyramid,  a cornercorner with one F(11)Li2Mn2 trigonal pyramid,  a cornercorner with one F(5)Li2Mn2 trigonal pyramid,  a cornercorner with one F(10)LiMn3 trigonal pyramid,  a cornercorner with one F(2)LiMn3 trigonal pyramid, corners with three equivalent F(1)Li2Mn2 trigonal pyramids, corners with three equivalent F(7)Li2Mn2 trigonal pyramids,  an edgeedge with one F(11)Li2Mn2 trigonal pyramid,  an edgeedge with one F(3)Li2Mn2 trigonal pyramid,  an edgeedge with one F(5)Li2Mn2 trigonal pyramid, and  an edgeedge with one F(8)LiMn3 trigonal pyramid. In the tenth F site, F(10) is bonded to one Li(2), one Mn(1), one Mn(2), and one Mn(4) atom to form distorted FLiMn3 trigonal pyramids that share  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid,  a cornercorner with one F(8)LiMn3 trigonal pyramid, corners with two equivalent O(1)LiMn3 trigonal pyramids, corners with two equivalent F(5)Li2Mn2 trigonal pyramids, corners with two equivalent F(7)Li2Mn2 trigonal pyramids, corners with three equivalent F(3)Li2Mn2 trigonal pyramids,  an edgeedge with one F(4)LiMn3 trigonal pyramid, and edges with two equivalent F(2)LiMn3 trigonal pyramids. In the eleventh F site, F(11) is bonded to one Li(1), one Li(3), one Mn(3), and one Mn(5) atom to form distorted FLi2Mn2 trigonal pyramids that share  a cornercorner with one F(3)Li2Mn2 trigonal pyramid,  a cornercorner with one F(9)Li2Mn2 trigonal pyramid,  a cornercorner with one F(4)LiMn3 trigonal pyramid, corners with two equivalent O(1)LiMn3 trigonal pyramids, corners with two equivalent F(7)Li2Mn2 trigonal pyramids, corners with three equivalent F(8)LiMn3 trigonal pyramids,  an edgeedge with one F(5)Li2Mn2 trigonal pyramid,  an edgeedge with one F(9)Li2Mn2 trigonal pyramid, and edges with two equivalent F(1)Li2Mn2 trigonal pyramids.