K(CrS2)2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form distorted edge-sharing CrS6 octahedra. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 5-coordinate geometry to two equivalent K(1) and three equivalent Cr(1) atoms. In the second S site, S(1) is bonded in a 4-coordinate geometry to one K(1) and three equivalent Cr(1) atoms.
K(CrS2)2 crystallizes in the monoclinic C2/m space group. K(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Both K(1)-S(1) bond lengths are 3.19 Å. All K(1)-S(2) bond lengths are 3.16 Å. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form distorted edge-sharing CrS6 octahedra. There is one shorter (2.25 Å) and two longer (2.30 Å) Cr(1)-S(1) bond lengths. There are two shorter (2.38 Å) and one longer (2.41 Å) Cr(1)-S(2) bond length. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 5-coordinate geometry to two equivalent K(1) and three equivalent Cr(1) atoms. In the second S site, S(1) is bonded in a 4-coordinate geometry to one K(1) and three equivalent Cr(1) atoms.