RhSbTe is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent Te(1) atoms to form RhSb3Te3 octahedra that share corners with twelve equivalent Rh(1)Sb3Te3 octahedra, corners with three equivalent Sb(1)TeRh3 trigonal pyramids, and corners with three equivalent Te(1)SbRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 63°. Sb(1) is bonded to three equivalent Rh(1) and one Te(1) atom to form distorted SbTeRh3 trigonal pyramids that share corners with three equivalent Rh(1)Sb3Te3 octahedra, corners with six equivalent Sb(1)TeRh3 trigonal pyramids, and corners with nine equivalent Te(1)SbRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°. Te(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form distorted TeSbRh3 trigonal pyramids that share corners with three equivalent Rh(1)Sb3Te3 octahedra, corners with six equivalent Te(1)SbRh3 trigonal pyramids, and corners with nine equivalent Sb(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.
RhSbTe is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent Te(1) atoms to form RhSb3Te3 octahedra that share corners with twelve equivalent Rh(1)Sb3Te3 octahedra, corners with three equivalent Sb(1)TeRh3 trigonal pyramids, and corners with three equivalent Te(1)SbRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 63°. All Rh(1)-Sb(1) bond lengths are 2.66 Å. All Rh(1)-Te(1) bond lengths are 2.68 Å. Sb(1) is bonded to three equivalent Rh(1) and one Te(1) atom to form distorted SbTeRh3 trigonal pyramids that share corners with three equivalent Rh(1)Sb3Te3 octahedra, corners with six equivalent Sb(1)TeRh3 trigonal pyramids, and corners with nine equivalent Te(1)SbRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°. The Sb(1)-Te(1) bond length is 2.82 Å. Te(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form distorted TeSbRh3 trigonal pyramids that share corners with three equivalent Rh(1)Sb3Te3 octahedra, corners with six equivalent Te(1)SbRh3 trigonal pyramids, and corners with nine equivalent Sb(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.