Co(MoO4)6GaO12(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one Co(MoO4)6 cluster, and one GaO12 cluster. In the Co(MoO4)6 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(9) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Co(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Mo(2), one Mo(3), and one Co(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(3) atom. In the GaO12 cluster, Ga(1) is bonded in a distorted linear geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(15) atoms. There are six inequivalent O sites. In the first O site, O(13) is bonded in a bent 150 degrees geometry to one Ga(1) and one O(18) atom. In the second O site, O(14) is bonded in a bent 120 degrees geometry to one Ga(1) and one O(17) atom. In the third O site, O(15) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth O site, O(16) is bonded in a single-bond geometry to one O(18) atom. In the fifth O site, O(17) is bonded in a single-bond geometry to one O(14) atom. In the sixth O site, O(18) is bonded in a bent 120 degrees geometry to one O(13) and one O(16) atom.
Co(MoO4)6GaO12(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one Co(MoO4)6 cluster, and one GaO12 cluster. In the Co(MoO4)6 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Mo(1)-O(1) bond length is 2.26 Å. The Mo(1)-O(2) bond length is 2.01 Å. The Mo(1)-O(3) bond length is 1.73 Å. The Mo(1)-O(4) bond length is 1.73 Å. The Mo(1)-O(5) bond length is 2.68 Å. The Mo(1)-O(6) bond length is 1.93 Å. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. The Mo(2)-O(10) bond length is 1.98 Å. The Mo(2)-O(5) bond length is 2.50 Å. The Mo(2)-O(6) bond length is 1.95 Å. The Mo(2)-O(7) bond length is 1.73 Å. The Mo(2)-O(8) bond length is 1.72 Å. The Mo(2)-O(9) bond length is 2.41 Å. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom. The Mo(3)-O(1) bond length is 2.31 Å. The Mo(3)-O(10) bond length is 1.97 Å. The Mo(3)-O(11) bond length is 1.72 Å. The Mo(3)-O(12) bond length is 1.73 Å. The Mo(3)-O(2) bond length is 1.98 Å. The Mo(3)-O(9) bond length is 2.54 Å. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(9) atoms. Both Co(1)-O(1) bond lengths are 1.91 Å. Both Co(1)-O(5) bond lengths are 1.77 Å. Both Co(1)-O(9) bond lengths are 1.80 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Co(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Mo(2), one Mo(3), and one Co(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Mo(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(3) atom. In the GaO12 cluster, Ga(1) is bonded in a distorted linear geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(15) atoms. Both Ga(1)-O(13) bond lengths are 2.55 Å. Both Ga(1)-O(14) bond lengths are 2.55 Å. Both Ga(1)-O(15) bond lengths are 1.73 Å. There are six inequivalent O sites. In the first O site, O(13) is bonded in a bent 150 degrees geometry to one Ga(1) and one O(18) atom. The O(13)-O(18) bond length is 1.31 Å. In the second O site, O(14) is bonded in a bent 120 degrees geometry to one Ga(1) and one O(17) atom. The O(14)-O(17) bond length is 1.23 Å. In the third O site, O(15) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth O site, O(16) is bonded in a single-bond geometry to one O(18) atom. The O(16)-O(18) bond length is 1.27 Å. In the fifth O site, O(17) is bonded in a single-bond geometry to one O(14) atom. In the sixth O site, O(18) is bonded in a bent 120 degrees geometry to one O(13) and one O(16) atom.