GaN(Mg) crystallizes in the orthorhombic Pnma space group. Mg(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing MgN4 tetrahedra. Ga(1) is bonded in a single-bond geometry to one N(1) atom. N(1) is bonded to four equivalent Mg(1) and one Ga(1) atom to form a mixture of distorted edge and corner-sharing NMg4Ga trigonal bipyramids.
GaN(Mg) crystallizes in the orthorhombic Pnma space group. Mg(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing MgN4 tetrahedra. There are a spread of Mg(1)-N(1) bond distances ranging from 2.20-2.39 Å. Ga(1) is bonded in a single-bond geometry to one N(1) atom. The Ga(1)-N(1) bond length is 1.96 Å. N(1) is bonded to four equivalent Mg(1) and one Ga(1) atom to form a mixture of distorted edge and corner-sharing NMg4Ga trigonal bipyramids.