SiH2SO3CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four SiH2SO3 clusters. In each SiH2SO3 cluster, Si(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Si(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Si(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Si(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom.
SiH2SO3CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four SiH2SO3 clusters. In each SiH2SO3 cluster, Si(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. The Si(1)-H(1) bond length is 1.48 Å. The Si(1)-H(2) bond length is 1.48 Å. The Si(1)-O(1) bond length is 1.76 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Si(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Si(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.55 Å. The S(1)-O(2) bond length is 1.43 Å. The S(1)-O(3) bond length is 1.45 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Si(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom.