(K)2TlAsCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlAsCl6 framework. In the TlAsCl6 framework, Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent As(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. As(1) is bonded to six equivalent Cl(1) atoms to form AsCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Tl(1) and one As(1) atom.
(K)2TlAsCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlAsCl6 framework. In the TlAsCl6 framework, Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent As(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Cl(1) bond lengths are 3.00 Å. As(1) is bonded to six equivalent Cl(1) atoms to form AsCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All As(1)-Cl(1) bond lengths are 2.51 Å. Cl(1) is bonded in a linear geometry to one Tl(1) and one As(1) atom.