ZrCrS4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Zr(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form ZrS6 octahedra that share edges with two equivalent Zr(1)S6 octahedra and edges with four equivalent Cr(1)S6 octahedra. Cr(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form CrS6 octahedra that share edges with two equivalent Cr(1)S6 octahedra and edges with four equivalent Zr(1)S6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to two equivalent Zr(1) and one Cr(1) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Zr(1) and two equivalent Cr(1) atoms.
ZrCrS4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Zr(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form ZrS6 octahedra that share edges with two equivalent Zr(1)S6 octahedra and edges with four equivalent Cr(1)S6 octahedra. Both Zr(1)-S(2) bond lengths are 2.55 Å. All Zr(1)-S(1) bond lengths are 2.57 Å. Cr(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form CrS6 octahedra that share edges with two equivalent Cr(1)S6 octahedra and edges with four equivalent Zr(1)S6 octahedra. Both Cr(1)-S(1) bond lengths are 2.41 Å. All Cr(1)-S(2) bond lengths are 2.38 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to two equivalent Zr(1) and one Cr(1) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Zr(1) and two equivalent Cr(1) atoms.