LiSr2WCdO6 crystallizes in the triclinic P-1 space group. Li(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted LiO6 octahedra that share faces with two equivalent W(1)O6 octahedra. Sr(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share faces with two equivalent Li(1)O6 octahedra. Cd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Sr(1), one W(1), and one Cd(1) atom to form a mixture of distorted corner, edge, and face-sharing OSr2LiCdW trigonal bipyramids. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sr(1), and one W(1) atom. In the third O site, O(3) is bonded to one Li(1), two equivalent Sr(1), one W(1), and one Cd(1) atom to form a mixture of distorted corner, edge, and face-sharing OSr2LiCdW trigonal bipyramids.
LiSr2WCdO6 crystallizes in the triclinic P-1 space group. Li(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted LiO6 octahedra that share faces with two equivalent W(1)O6 octahedra. Both Li(1)-O(1) bond lengths are 2.08 Å. Both Li(1)-O(2) bond lengths are 2.38 Å. Both Li(1)-O(3) bond lengths are 2.09 Å. Sr(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(3) atoms. The Sr(1)-O(2) bond length is 2.50 Å. There is one shorter (2.51 Å) and one longer (2.56 Å) Sr(1)-O(1) bond length. There is one shorter (2.51 Å) and one longer (2.58 Å) Sr(1)-O(3) bond length. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share faces with two equivalent Li(1)O6 octahedra. Both W(1)-O(1) bond lengths are 2.08 Å. Both W(1)-O(2) bond lengths are 1.93 Å. Both W(1)-O(3) bond lengths are 2.08 Å. Cd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. Both Cd(1)-O(1) bond lengths are 2.22 Å. Both Cd(1)-O(3) bond lengths are 2.24 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Sr(1), one W(1), and one Cd(1) atom to form a mixture of distorted corner, edge, and face-sharing OSr2LiCdW trigonal bipyramids. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sr(1), and one W(1) atom. In the third O site, O(3) is bonded to one Li(1), two equivalent Sr(1), one W(1), and one Cd(1) atom to form a mixture of distorted corner, edge, and face-sharing OSr2LiCdW trigonal bipyramids.