Sm2Br2F is Cyanogen Chloride-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Sm2Br2F cluster. Sm(1) is bonded in a linear geometry to one Br(1) and one F(1) atom. Br(1) is bonded in a single-bond geometry to one Sm(1) atom. F(1) is bonded in a linear geometry to two equivalent Sm(1) atoms.
Sm2Br2F is Cyanogen Chloride-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Sm2Br2F cluster. Sm(1) is bonded in a linear geometry to one Br(1) and one F(1) atom. The Sm(1)-Br(1) bond length is 2.61 Å. The Sm(1)-F(1) bond length is 2.30 Å. Br(1) is bonded in a single-bond geometry to one Sm(1) atom. F(1) is bonded in a linear geometry to two equivalent Sm(1) atoms.