S is alpha structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(9) atom. In the second S site, S(4) is bonded in a water-like geometry to one S(1) and one S(12) atom. In the third S site, S(9) is bonded in a water-like geometry to one S(1) and one S(17) atom. In the fourth S site, S(12) is bonded in a water-like geometry to one S(20) and one S(4) atom. In the fifth S site, S(17) is bonded in a water-like geometry to one S(25) and one S(9) atom. In the sixth S site, S(20) is bonded in a water-like geometry to one S(12) and one S(28) atom. In the seventh S site, S(25) is bonded in a water-like geometry to one S(17) and one S(28) atom. In the eighth S site, S(28) is bonded in a water-like geometry to one S(20) and one S(25) atom.
S is alpha structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(9) atom. The S(1)-S(4) bond length is 2.08 Å. The S(1)-S(9) bond length is 1.98 Å. In the second S site, S(4) is bonded in a water-like geometry to one S(1) and one S(12) atom. The S(4)-S(12) bond length is 2.08 Å. In the third S site, S(9) is bonded in a water-like geometry to one S(1) and one S(17) atom. The S(9)-S(17) bond length is 2.14 Å. In the fourth S site, S(12) is bonded in a water-like geometry to one S(20) and one S(4) atom. The S(12)-S(20) bond length is 2.02 Å. In the fifth S site, S(17) is bonded in a water-like geometry to one S(25) and one S(9) atom. The S(17)-S(25) bond length is 2.07 Å. In the sixth S site, S(20) is bonded in a water-like geometry to one S(12) and one S(28) atom. The S(20)-S(28) bond length is 2.05 Å. In the seventh S site, S(25) is bonded in a water-like geometry to one S(17) and one S(28) atom. The S(25)-S(28) bond length is 2.04 Å. In the eighth S site, S(28) is bonded in a water-like geometry to one S(20) and one S(25) atom.