YTcN3 crystallizes in the orthorhombic Amm2 space group. Y(1) is bonded in a 7-coordinate geometry to three equivalent N(2) and four equivalent N(1) atoms. Tc(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form distorted TcN6 octahedra that share corners with six equivalent Tc(1)N6 octahedra and corners with four equivalent N(1)Y2Tc2N trigonal bipyramids. The corner-sharing octahedral tilt angles range from 6-22°. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Y(1), two equivalent Tc(1), and one N(1) atom to form distorted NY2Tc2N trigonal bipyramids that share corners with two equivalent Tc(1)N6 octahedra, corners with two equivalent N(2)Y3Tc2 trigonal bipyramids, corners with nine equivalent N(1)Y2Tc2N trigonal bipyramids, edges with four equivalent N(2)Y3Tc2 trigonal bipyramids, and  a faceface with one N(1)Y2Tc2N trigonal bipyramid. The corner-sharing octahedral tilt angles range from 51-108°. In the second N site, N(2) is bonded to three equivalent Y(1) and two equivalent Tc(1) atoms to form NY3Tc2 trigonal bipyramids that share corners with four equivalent N(1)Y2Tc2N trigonal bipyramids, corners with eight equivalent N(2)Y3Tc2 trigonal bipyramids, and edges with eight equivalent N(1)Y2Tc2N trigonal bipyramids.
YTcN3 crystallizes in the orthorhombic Amm2 space group. Y(1) is bonded in a 7-coordinate geometry to three equivalent N(2) and four equivalent N(1) atoms. There is one shorter (2.37 Å) and two longer (2.40 Å) Y(1)-N(2) bond lengths. All Y(1)-N(1) bond lengths are 2.51 Å. Tc(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form distorted TcN6 octahedra that share corners with six equivalent Tc(1)N6 octahedra and corners with four equivalent N(1)Y2Tc2N trigonal bipyramids. The corner-sharing octahedral tilt angles range from 6-22°. Both Tc(1)-N(2) bond lengths are 2.04 Å. There are two shorter (2.09 Å) and two longer (2.18 Å) Tc(1)-N(1) bond lengths. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Y(1), two equivalent Tc(1), and one N(1) atom to form distorted NY2Tc2N trigonal bipyramids that share corners with two equivalent Tc(1)N6 octahedra, corners with two equivalent N(2)Y3Tc2 trigonal bipyramids, corners with nine equivalent N(1)Y2Tc2N trigonal bipyramids, edges with four equivalent N(2)Y3Tc2 trigonal bipyramids, and  a faceface with one N(1)Y2Tc2N trigonal bipyramid. The corner-sharing octahedral tilt angles range from 51-108°. The N(1)-N(1) bond length is 1.33 Å. In the second N site, N(2) is bonded to three equivalent Y(1) and two equivalent Tc(1) atoms to form NY3Tc2 trigonal bipyramids that share corners with four equivalent N(1)Y2Tc2N trigonal bipyramids, corners with eight equivalent N(2)Y3Tc2 trigonal bipyramids, and edges with eight equivalent N(1)Y2Tc2N trigonal bipyramids.