LiMnSnO4 is Hausmannite-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Mn(1)O6 octahedra and corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent Sn(1)O6 octahedra. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Mn(1), and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded to one Li(1), two equivalent Mn(1), and one Sn(1) atom to form a mixture of distorted edge and corner-sharing OLiMn2Sn tetrahedra.
LiMnSnO4 is Hausmannite-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Mn(1)O6 octahedra and corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-61°. Both Li(1)-O(1) bond lengths are 1.98 Å. Both Li(1)-O(2) bond lengths are 2.18 Å. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent Sn(1)O6 octahedra. Both Mn(1)-O(1) bond lengths are 2.28 Å. All Mn(1)-O(2) bond lengths are 1.99 Å. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. Both Sn(1)-O(2) bond lengths are 2.15 Å. All Sn(1)-O(1) bond lengths are 2.08 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Mn(1), and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded to one Li(1), two equivalent Mn(1), and one Sn(1) atom to form a mixture of distorted edge and corner-sharing OLiMn2Sn tetrahedra.