LiVF3 is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. V(1) is bonded to six equivalent F(1) atoms to form distorted corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 52°. F(1) is bonded to two equivalent Li(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing FLi2V2 trigonal pyramids.
LiVF3 is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. There are three shorter (1.97 Å) and three longer (2.28 Å) Li(1)-F(1) bond lengths. V(1) is bonded to six equivalent F(1) atoms to form distorted corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are three shorter (2.13 Å) and three longer (2.14 Å) V(1)-F(1) bond lengths. F(1) is bonded to two equivalent Li(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing FLi2V2 trigonal pyramids.