(Mn(CO)5)2InCl is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one InCl cluster and four Mn(CO)5 clusters. In the InCl cluster, In(1) is bonded in a 2-coordinate geometry to two equivalent Cl(1) atoms. Cl(1) is bonded in a water-like geometry to two equivalent In(1) atoms. In two of the Mn(CO)5 clusters, Mn(1) is bonded in a square pyramidal geometry to one C(1), one C(10), one C(2), one C(3), and one C(7) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1,5) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(1,5) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(6) atom. In the fourth C site, C(7) is bonded in a linear geometry to one Mn(1) and one O(3) atom. In the fifth C site, C(10) is bonded in a linear geometry to one Mn(1) and one O(7) atom. There are four inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(7) is bonded in a single-bond geometry to one C(10) atom. In the third O site, O(1,5) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In two of the Mn(CO)5 clusters, Mn(2) is bonded in a square pyramidal geometry to one C(4), one C(5), one C(6), one C(8), and one C(9) atom. There are five inequivalent C sites. In the first C site, C(5) is bonded in a linear geometry to one Mn(2) and one O(4) atom. In the second C site, C(4) is bonded in a linear geometry to one Mn(2) and one O(9) atom. In the third C site, C(6) is bonded in a linear geometry to one Mn(2) and one O(8) atom. In the fourth C site, C(8) is bonded in a linear geometry to one Mn(2) and one O(10) atom. In the fifth C site, C(9) is bonded in a linear geometry to one Mn(2) and one O(2) atom. There are five inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(9) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(10) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(9) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one C(5) atom.
(Mn(CO)5)2InCl is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one InCl cluster and four Mn(CO)5 clusters. In the InCl cluster, In(1) is bonded in a 2-coordinate geometry to two equivalent Cl(1) atoms. There is one shorter (2.62 Å) and one longer (2.67 Å) In(1)-Cl(1) bond length. Cl(1) is bonded in a water-like geometry to two equivalent In(1) atoms. In two of the Mn(CO)5 clusters, Mn(1) is bonded in a square pyramidal geometry to one C(1), one C(10), one C(2), one C(3), and one C(7) atom. The Mn(1)-C(1) bond length is 1.86 Å. The Mn(1)-C(10) bond length is 1.86 Å. The Mn(1)-C(2) bond length is 1.82 Å. The Mn(1)-C(3) bond length is 1.87 Å. The Mn(1)-C(7) bond length is 1.86 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1,5) atom. The C(1)-O(1,5) bond length is 1.16 Å. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(1,5) atom. The C(2)-O(1,5) bond length is 1.16 Å. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(6) atom. The C(3)-O(6) bond length is 1.16 Å. In the fourth C site, C(7) is bonded in a linear geometry to one Mn(1) and one O(3) atom. The C(7)-O(3) bond length is 1.16 Å. In the fifth C site, C(10) is bonded in a linear geometry to one Mn(1) and one O(7) atom. The C(10)-O(7) bond length is 1.16 Å. There are four inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(7) is bonded in a single-bond geometry to one C(10) atom. In the third O site, O(1,5) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In two of the Mn(CO)5 clusters, Mn(2) is bonded in a square pyramidal geometry to one C(4), one C(5), one C(6), one C(8), and one C(9) atom. The Mn(2)-C(4) bond length is 1.85 Å. The Mn(2)-C(5) bond length is 1.85 Å. The Mn(2)-C(6) bond length is 1.86 Å. The Mn(2)-C(8) bond length is 1.86 Å. The Mn(2)-C(9) bond length is 1.82 Å. There are five inequivalent C sites. In the first C site, C(5) is bonded in a linear geometry to one Mn(2) and one O(4) atom. The C(5)-O(4) bond length is 1.16 Å. In the second C site, C(4) is bonded in a linear geometry to one Mn(2) and one O(9) atom. The C(4)-O(9) bond length is 1.16 Å. In the third C site, C(6) is bonded in a linear geometry to one Mn(2) and one O(8) atom. The C(6)-O(8) bond length is 1.16 Å. In the fourth C site, C(8) is bonded in a linear geometry to one Mn(2) and one O(10) atom. The C(8)-O(10) bond length is 1.16 Å. In the fifth C site, C(9) is bonded in a linear geometry to one Mn(2) and one O(2) atom. The C(9)-O(2) bond length is 1.16 Å. There are five inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(9) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(10) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(9) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one C(5) atom.