BaLaInO4 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pca2_1 space group. Ba(1) is bonded in a 9-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and three equivalent O(1) atoms. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. In(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 20-34°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one La(1), and one In(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent La(1), and one In(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), and two equivalent In(1) atoms. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), and two equivalent In(1) atoms.
BaLaInO4 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pca2_1 space group. Ba(1) is bonded in a 9-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and three equivalent O(1) atoms. There is one shorter (2.94 Å) and one longer (3.19 Å) Ba(1)-O(2) bond length. There is one shorter (2.64 Å) and one longer (3.23 Å) Ba(1)-O(3) bond length. There is one shorter (2.83 Å) and one longer (2.97 Å) Ba(1)-O(4) bond length. There are a spread of Ba(1)-O(1) bond distances ranging from 2.59-3.14 Å. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. The La(1)-O(1) bond length is 2.36 Å. The La(1)-O(3) bond length is 2.48 Å. The La(1)-O(4) bond length is 2.47 Å. There is one shorter (2.42 Å) and one longer (2.45 Å) La(1)-O(2) bond length. In(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 20-34°. The In(1)-O(1) bond length is 2.23 Å. The In(1)-O(2) bond length is 2.45 Å. There is one shorter (2.15 Å) and one longer (2.18 Å) In(1)-O(3) bond length. There is one shorter (2.17 Å) and one longer (2.19 Å) In(1)-O(4) bond length. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one La(1), and one In(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent La(1), and one In(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), and two equivalent In(1) atoms. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), and two equivalent In(1) atoms.