Gd(V)2GdPr2Ti2O12 crystallizes in the orthorhombic Pnnn space group. The structure consists of two 7440-54-2 atoms and four 7440-62-2 atoms inside a GdPr2Ti2O12 framework. In the GdPr2Ti2O12 framework, Gd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. In the second Pr site, Pr(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Ti(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Pr(2) and one Ti(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Gd(1) and one Ti(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Pr(1) and one Ti(1) atom.
Gd(V)2GdPr2Ti2O12 crystallizes in the orthorhombic Pnnn space group. The structure consists of two 7440-54-2 atoms and four 7440-62-2 atoms inside a GdPr2Ti2O12 framework. In the GdPr2Ti2O12 framework, Gd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. All Gd(1)-O(2) bond lengths are 3.13 Å. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. All Pr(1)-O(3) bond lengths are 3.21 Å. In the second Pr site, Pr(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Pr(2)-O(1) bond lengths are 3.22 Å. Ti(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Ti(1)-O(1) bond lengths are 2.69 Å. Both Ti(1)-O(2) bond lengths are 2.71 Å. Both Ti(1)-O(3) bond lengths are 2.69 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Pr(2) and one Ti(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Gd(1) and one Ti(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Pr(1) and one Ti(1) atom.