CdIn2O4 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CdO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent Cd(1)O6 octahedra, and edges with four equivalent In(2)O6 octahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form InO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with six equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. In the second In site, In(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent In(2)O6 octahedra, and edges with four equivalent Cd(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Cd(1), one In(1), and two equivalent In(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cd(1), one In(1), and one In(2) atom.
CdIn2O4 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CdO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent Cd(1)O6 octahedra, and edges with four equivalent In(2)O6 octahedra. Both Cd(1)-O(1) bond lengths are 2.35 Å. All Cd(1)-O(2) bond lengths are 2.31 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form InO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with six equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. Both In(1)-O(1) bond lengths are 2.13 Å. Both In(1)-O(2) bond lengths are 2.10 Å. In the second In site, In(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent In(2)O6 octahedra, and edges with four equivalent Cd(1)O6 octahedra. Both In(2)-O(2) bond lengths are 2.19 Å. All In(2)-O(1) bond lengths are 2.24 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Cd(1), one In(1), and two equivalent In(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cd(1), one In(1), and one In(2) atom.