ZrSO6 crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), and four equivalent O(4) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Zr(1) and one O(4) atom.
ZrSO6 crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), and four equivalent O(4) atoms. The Zr(1)-O(1) bond length is 2.20 Å. The Zr(1)-O(2) bond length is 2.18 Å. Both Zr(1)-O(3) bond lengths are 2.19 Å. There are two shorter (2.15 Å) and two longer (2.16 Å) Zr(1)-O(4) bond lengths. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.47 Å. Both S(1)-O(3) bond lengths are 1.48 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Zr(1) and one O(4) atom. The O(4)-O(4) bond length is 1.52 Å.