SbCl3F2 is Indium-like structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of two SbCl3F2 clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one F(2), and two equivalent F(1) atoms to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles are 12°. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms.
SbCl3F2 is Indium-like structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of two SbCl3F2 clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one F(2), and two equivalent F(1) atoms to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles are 12°. The Sb(1)-Cl(1) bond length is 2.30 Å. The Sb(1)-Cl(2) bond length is 2.30 Å. The Sb(1)-Cl(3) bond length is 2.29 Å. The Sb(1)-F(2) bond length is 1.88 Å. Both Sb(1)-F(1) bond lengths are 2.08 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms.