TiAgF6 crystallizes in the triclinic P-1 space group. Ti(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form TiF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 41-45°. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form AgF6 octahedra that share corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 41-45°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one Ag(1) atom.
TiAgF6 crystallizes in the triclinic P-1 space group. Ti(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form TiF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 41-45°. Both Ti(1)-F(1) bond lengths are 1.84 Å. Both Ti(1)-F(2) bond lengths are 1.90 Å. Both Ti(1)-F(3) bond lengths are 1.90 Å. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form AgF6 octahedra that share corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 41-45°. Both Ag(1)-F(1) bond lengths are 2.44 Å. Both Ag(1)-F(2) bond lengths are 2.11 Å. Both Ag(1)-F(3) bond lengths are 2.11 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one Ag(1) atom.