NaAs2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded in a 12-coordinate geometry to twelve equivalent As(1) atoms. As(1) is bonded to six equivalent Na(1) and six equivalent As(1) atoms to form a mixture of edge, face, and corner-sharing AsNa6As6 cuboctahedra.
NaAs2 is Cubic Laves structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded in a 12-coordinate geometry to twelve equivalent As(1) atoms. All Na(1)-As(1) bond lengths are 3.38 Å. As(1) is bonded to six equivalent Na(1) and six equivalent As(1) atoms to form a mixture of edge, face, and corner-sharing AsNa6As6 cuboctahedra. All As(1)-As(1) bond lengths are 2.88 Å.