AgZnF5 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 39°. Zn(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ag(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one Zn(1) atom.
AgZnF5 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 39°. The Ag(1)-F(1) bond length is 2.11 Å. The Ag(1)-F(2) bond length is 2.07 Å. The Ag(1)-F(3) bond length is 2.08 Å. The Ag(1)-F(4) bond length is 2.12 Å. There is one shorter (2.11 Å) and one longer (2.12 Å) Ag(1)-F(5) bond length. Zn(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The Zn(1)-F(1) bond length is 2.04 Å. The Zn(1)-F(2) bond length is 2.06 Å. The Zn(1)-F(3) bond length is 1.91 Å. The Zn(1)-F(4) bond length is 1.89 Å. The Zn(1)-F(5) bond length is 2.48 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ag(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one Zn(1) atom.