Li2CoCl4 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(5) atom. In the second Li site, Li(2) is bonded to one Cl(1), one Cl(19), one Cl(22), one Cl(24), one Cl(3), and one Cl(6) atom to form LiCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(3)Cl6 octahedra, edges with two equivalent Co(1)Cl6 octahedra, and edges with two equivalent Co(2)Cl6 octahedra. In the third Li site, Li(3) is bonded to one Cl(10), one Cl(2), one Cl(3), one Cl(5), one Cl(6), and one Cl(9) atom to form LiCl6 octahedra that share  an edgeedge with one Li(2)Cl6 octahedra,  an edgeedge with one Li(6)Cl6 octahedra,  an edgeedge with one Co(1)Cl6 octahedra,  an edgeedge with one Co(2)Cl6 octahedra,  an edgeedge with one Co(3)Cl6 octahedra, and  an edgeedge with one Co(5)Cl6 octahedra. In the fourth Li site, Li(4) is bonded in a trigonal non-coplanar geometry to one Cl(11), one Cl(4), and one Cl(7) atom. In the fifth Li site, Li(5) is bonded to one Cl(11), one Cl(13), one Cl(17), one Cl(18), one Cl(7), and one Cl(8) atom to form LiCl6 octahedra that share  an edgeedge with one Li(6)Cl6 octahedra,  an edgeedge with one Li(9)Cl6 octahedra,  an edgeedge with one Co(3)Cl6 octahedra,  an edgeedge with one Co(4)Cl6 octahedra,  an edgeedge with one Co(5)Cl6 octahedra, and  an edgeedge with one Co(6)Cl6 octahedra. In the sixth Li site, Li(6) is bonded to one Cl(14), one Cl(18), one Cl(2), one Cl(4), one Cl(8), and one Cl(9) atom to form LiCl6 octahedra that share  an edgeedge with one Li(3)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Co(3)Cl6 octahedra, and edges with two equivalent Co(5)Cl6 octahedra. In the seventh Li site, Li(7) is bonded in a trigonal non-coplanar geometry to one Cl(12), one Cl(15), and one Cl(19) atom. In the eighth Li site, Li(8) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(14), one Cl(3), and one Cl(6) atom. In the ninth Li site, Li(9) is bonded to one Cl(12), one Cl(16), one Cl(17), one Cl(21), one Cl(23), and one Cl(7) atom to form LiCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Co(4)Cl6 octahedra, and edges with two equivalent Co(6)Cl6 octahedra. In the tenth Li site, Li(10) is bonded to one Cl(15), one Cl(16), one Cl(19), one Cl(20), one Cl(22), and one Cl(23) atom to form LiCl6 octahedra that share  an edgeedge with one Li(2)Cl6 octahedra,  an edgeedge with one Li(9)Cl6 octahedra,  an edgeedge with one Co(1)Cl6 octahedra,  an edgeedge with one Co(2)Cl6 octahedra,  an edgeedge with one Co(4)Cl6 octahedra, and  an edgeedge with one Co(6)Cl6 octahedra. In the eleventh Li site, Li(11) is bonded in a trigonal non-coplanar geometry to one Cl(13), one Cl(21), and one Cl(8) atom. In the twelfth Li site, Li(12) is bonded in a 5-coordinate geometry to one Cl(16), one Cl(19), one Cl(20), one Cl(22), and one Cl(24) atom. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one Cl(1), one Cl(10), one Cl(15), one Cl(19), one Cl(24), and one Cl(6) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(3)Cl6 octahedra, edges with two equivalent Li(2)Cl6 octahedra, and edges with two equivalent Co(2)Cl6 octahedra. In the second Co site, Co(2) is bonded to one Cl(1), one Cl(10), one Cl(15), one Cl(22), one Cl(24), and one Cl(3) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(3)Cl6 octahedra, edges with two equivalent Li(2)Cl6 octahedra, and edges with two equivalent Co(1)Cl6 octahedra. In the third Co site, Co(3) is bonded to one Cl(13), one Cl(14), one Cl(18), one Cl(2), one Cl(4), and one Cl(5) atom to form CoCl6 octahedra that share  an edgeedge with one Li(3)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(6)Cl6 octahedra, and edges with two equivalent Co(5)Cl6 octahedra. In the fourth Co site, Co(4) is bonded to one Cl(11), one Cl(12), one Cl(20), one Cl(21), one Cl(23), and one Cl(7) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(9)Cl6 octahedra, and edges with two equivalent Co(6)Cl6 octahedra. In the fifth Co site, Co(5) is bonded to one Cl(13), one Cl(14), one Cl(4), one Cl(5), one Cl(8), and one Cl(9) atom to form CoCl6 octahedra that share  an edgeedge with one Li(3)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(6)Cl6 octahedra, and edges with two equivalent Co(3)Cl6 octahedra. In the sixth Co site, Co(6) is bonded to one Cl(11), one Cl(12), one Cl(16), one Cl(17), one Cl(20), and one Cl(21) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(9)Cl6 octahedra, and edges with two equivalent Co(4)Cl6 octahedra. There are twenty-four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 5-coordinate geometry to one Li(1), one Li(2), one Li(8), one Co(1), and one Co(2) atom. In the second Cl site, Cl(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Li(6), and one Co(3) atom. In the third Cl site, Cl(3) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one Li(8), and one Co(2) atom. In the fourth Cl site, Cl(4) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(6), one Co(3), and one Co(5) atom. In the fifth Cl site, Cl(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Co(3), and one Co(5) atom. In the sixth Cl site, Cl(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one Li(8), and one Co(1) atom. In the seventh Cl site, Cl(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(5), one Li(9), and one Co(4) atom. In the eighth Cl site, Cl(8) is bonded in a rectangular see-saw-like geometry to one Li(11), one Li(5), one Li(6), and one Co(5) atom. In the ninth Cl site, Cl(9) is bonded in a 3-coordinate geometry to one Li(3), one Li(6), and one Co(5) atom. In the tenth Cl site, Cl(10) is bonded in a 3-coordinate geometry to one Li(3), one Co(1), and one Co(2) atom. In the eleventh Cl site, Cl(11) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(5), one Co(4), and one Co(6) atom. In the twelfth Cl site, Cl(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Li(9), one Co(4), and one Co(6) atom. In the thirteenth Cl site, Cl(13) is bonded in a rectangular see-saw-like geometry to one Li(11), one Li(5), one Co(3), and one Co(5) atom. In the fourteenth Cl site, Cl(14) is bonded in a rectangular see-saw-like geometry to one Li(6), one Li(8), one Co(3), and one Co(5) atom. In the fifteenth Cl site, Cl(15) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(7), one Co(1), and one Co(2) atom. In the sixteenth Cl site, Cl(16) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(12), one Li(9), and one Co(6) atom. In the seventeenth Cl site, Cl(17) is bonded in a distorted T-shaped geometry to one Li(5), one Li(9), and one Co(6) atom. In the eighteenth Cl site, Cl(18) is bonded in a distorted T-shaped geometry to one Li(5), one Li(6), and one Co(3) atom. In the nineteenth Cl site, Cl(19) is bonded in a distorted square pyramidal geometry to one Li(10), one Li(12), one Li(2), one Li(7), and one Co(1) atom. In the twentieth Cl site, Cl(20) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(12), one Co(4), and one Co(6) atom. In the twenty-first Cl site, Cl(21) is bonded in a rectangular see-saw-like geometry to one Li(11), one Li(9), one Co(4), and one Co(6) atom. In the twenty-second Cl site, Cl(22) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(12), one Li(2), and one Co(2) atom. In the twenty-third Cl site, Cl(23) is bonded in a 3-coordinate geometry to one Li(10), one Li(9), and one Co(4) atom. In the twenty-fourth Cl site, Cl(24) is bonded in a rectangular see-saw-like geometry to one Li(12), one Li(2), one Co(1), and one Co(2) atom.
Li2CoCl4 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(5) atom. The Li(1)-Cl(1) bond length is 2.38 Å. The Li(1)-Cl(2) bond length is 2.35 Å. The Li(1)-Cl(5) bond length is 2.41 Å. In the second Li site, Li(2) is bonded to one Cl(1), one Cl(19), one Cl(22), one Cl(24), one Cl(3), and one Cl(6) atom to form LiCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(3)Cl6 octahedra, edges with two equivalent Co(1)Cl6 octahedra, and edges with two equivalent Co(2)Cl6 octahedra. The Li(2)-Cl(1) bond length is 2.62 Å. The Li(2)-Cl(19) bond length is 2.59 Å. The Li(2)-Cl(22) bond length is 2.56 Å. The Li(2)-Cl(24) bond length is 2.60 Å. The Li(2)-Cl(3) bond length is 2.58 Å. The Li(2)-Cl(6) bond length is 2.59 Å. In the third Li site, Li(3) is bonded to one Cl(10), one Cl(2), one Cl(3), one Cl(5), one Cl(6), and one Cl(9) atom to form LiCl6 octahedra that share  an edgeedge with one Li(2)Cl6 octahedra,  an edgeedge with one Li(6)Cl6 octahedra,  an edgeedge with one Co(1)Cl6 octahedra,  an edgeedge with one Co(2)Cl6 octahedra,  an edgeedge with one Co(3)Cl6 octahedra, and  an edgeedge with one Co(5)Cl6 octahedra. The Li(3)-Cl(10) bond length is 2.62 Å. The Li(3)-Cl(2) bond length is 2.51 Å. The Li(3)-Cl(3) bond length is 2.56 Å. The Li(3)-Cl(5) bond length is 2.53 Å. The Li(3)-Cl(6) bond length is 2.48 Å. The Li(3)-Cl(9) bond length is 2.48 Å. In the fourth Li site, Li(4) is bonded in a trigonal non-coplanar geometry to one Cl(11), one Cl(4), and one Cl(7) atom. The Li(4)-Cl(11) bond length is 2.41 Å. The Li(4)-Cl(4) bond length is 2.39 Å. The Li(4)-Cl(7) bond length is 2.37 Å. In the fifth Li site, Li(5) is bonded to one Cl(11), one Cl(13), one Cl(17), one Cl(18), one Cl(7), and one Cl(8) atom to form LiCl6 octahedra that share  an edgeedge with one Li(6)Cl6 octahedra,  an edgeedge with one Li(9)Cl6 octahedra,  an edgeedge with one Co(3)Cl6 octahedra,  an edgeedge with one Co(4)Cl6 octahedra,  an edgeedge with one Co(5)Cl6 octahedra, and  an edgeedge with one Co(6)Cl6 octahedra. The Li(5)-Cl(11) bond length is 2.53 Å. The Li(5)-Cl(13) bond length is 2.53 Å. The Li(5)-Cl(17) bond length is 2.49 Å. The Li(5)-Cl(18) bond length is 2.52 Å. The Li(5)-Cl(7) bond length is 2.56 Å. The Li(5)-Cl(8) bond length is 2.55 Å. In the sixth Li site, Li(6) is bonded to one Cl(14), one Cl(18), one Cl(2), one Cl(4), one Cl(8), and one Cl(9) atom to form LiCl6 octahedra that share  an edgeedge with one Li(3)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Co(3)Cl6 octahedra, and edges with two equivalent Co(5)Cl6 octahedra. The Li(6)-Cl(14) bond length is 2.53 Å. The Li(6)-Cl(18) bond length is 2.48 Å. The Li(6)-Cl(2) bond length is 2.55 Å. The Li(6)-Cl(4) bond length is 2.53 Å. The Li(6)-Cl(8) bond length is 2.57 Å. The Li(6)-Cl(9) bond length is 2.53 Å. In the seventh Li site, Li(7) is bonded in a trigonal non-coplanar geometry to one Cl(12), one Cl(15), and one Cl(19) atom. The Li(7)-Cl(12) bond length is 2.38 Å. The Li(7)-Cl(15) bond length is 2.40 Å. The Li(7)-Cl(19) bond length is 2.39 Å. In the eighth Li site, Li(8) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(14), one Cl(3), and one Cl(6) atom. The Li(8)-Cl(1) bond length is 2.99 Å. The Li(8)-Cl(14) bond length is 2.43 Å. The Li(8)-Cl(3) bond length is 2.32 Å. The Li(8)-Cl(6) bond length is 2.32 Å. In the ninth Li site, Li(9) is bonded to one Cl(12), one Cl(16), one Cl(17), one Cl(21), one Cl(23), and one Cl(7) atom to form LiCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Co(4)Cl6 octahedra, and edges with two equivalent Co(6)Cl6 octahedra. The Li(9)-Cl(12) bond length is 2.54 Å. The Li(9)-Cl(16) bond length is 2.58 Å. The Li(9)-Cl(17) bond length is 2.53 Å. The Li(9)-Cl(21) bond length is 2.53 Å. The Li(9)-Cl(23) bond length is 2.50 Å. The Li(9)-Cl(7) bond length is 2.53 Å. In the tenth Li site, Li(10) is bonded to one Cl(15), one Cl(16), one Cl(19), one Cl(20), one Cl(22), and one Cl(23) atom to form LiCl6 octahedra that share  an edgeedge with one Li(2)Cl6 octahedra,  an edgeedge with one Li(9)Cl6 octahedra,  an edgeedge with one Co(1)Cl6 octahedra,  an edgeedge with one Co(2)Cl6 octahedra,  an edgeedge with one Co(4)Cl6 octahedra, and  an edgeedge with one Co(6)Cl6 octahedra. The Li(10)-Cl(15) bond length is 2.66 Å. The Li(10)-Cl(16) bond length is 2.54 Å. The Li(10)-Cl(19) bond length is 2.47 Å. The Li(10)-Cl(20) bond length is 2.55 Å. The Li(10)-Cl(22) bond length is 2.50 Å. The Li(10)-Cl(23) bond length is 2.47 Å. In the eleventh Li site, Li(11) is bonded in a trigonal non-coplanar geometry to one Cl(13), one Cl(21), and one Cl(8) atom. The Li(11)-Cl(13) bond length is 2.37 Å. The Li(11)-Cl(21) bond length is 2.40 Å. The Li(11)-Cl(8) bond length is 2.36 Å. In the twelfth Li site, Li(12) is bonded in a 5-coordinate geometry to one Cl(16), one Cl(19), one Cl(20), one Cl(22), and one Cl(24) atom. The Li(12)-Cl(16) bond length is 2.41 Å. The Li(12)-Cl(19) bond length is 2.97 Å. The Li(12)-Cl(20) bond length is 2.42 Å. The Li(12)-Cl(22) bond length is 2.86 Å. The Li(12)-Cl(24) bond length is 2.38 Å. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one Cl(1), one Cl(10), one Cl(15), one Cl(19), one Cl(24), and one Cl(6) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(3)Cl6 octahedra, edges with two equivalent Li(2)Cl6 octahedra, and edges with two equivalent Co(2)Cl6 octahedra. The Co(1)-Cl(1) bond length is 2.52 Å. The Co(1)-Cl(10) bond length is 2.39 Å. The Co(1)-Cl(15) bond length is 2.49 Å. The Co(1)-Cl(19) bond length is 2.50 Å. The Co(1)-Cl(24) bond length is 2.47 Å. The Co(1)-Cl(6) bond length is 2.44 Å. In the second Co site, Co(2) is bonded to one Cl(1), one Cl(10), one Cl(15), one Cl(22), one Cl(24), and one Cl(3) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(3)Cl6 octahedra, edges with two equivalent Li(2)Cl6 octahedra, and edges with two equivalent Co(1)Cl6 octahedra. The Co(2)-Cl(1) bond length is 2.45 Å. The Co(2)-Cl(10) bond length is 2.39 Å. The Co(2)-Cl(15) bond length is 2.43 Å. The Co(2)-Cl(22) bond length is 2.36 Å. The Co(2)-Cl(24) bond length is 2.46 Å. The Co(2)-Cl(3) bond length is 2.39 Å. In the third Co site, Co(3) is bonded to one Cl(13), one Cl(14), one Cl(18), one Cl(2), one Cl(4), and one Cl(5) atom to form CoCl6 octahedra that share  an edgeedge with one Li(3)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(6)Cl6 octahedra, and edges with two equivalent Co(5)Cl6 octahedra. The Co(3)-Cl(13) bond length is 2.49 Å. The Co(3)-Cl(14) bond length is 2.44 Å. The Co(3)-Cl(18) bond length is 2.31 Å. The Co(3)-Cl(2) bond length is 2.46 Å. The Co(3)-Cl(4) bond length is 2.52 Å. The Co(3)-Cl(5) bond length is 2.56 Å. In the fourth Co site, Co(4) is bonded to one Cl(11), one Cl(12), one Cl(20), one Cl(21), one Cl(23), and one Cl(7) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(9)Cl6 octahedra, and edges with two equivalent Co(6)Cl6 octahedra. The Co(4)-Cl(11) bond length is 2.56 Å. The Co(4)-Cl(12) bond length is 2.53 Å. The Co(4)-Cl(20) bond length is 2.47 Å. The Co(4)-Cl(21) bond length is 2.44 Å. The Co(4)-Cl(23) bond length is 2.33 Å. The Co(4)-Cl(7) bond length is 2.44 Å. In the fifth Co site, Co(5) is bonded to one Cl(13), one Cl(14), one Cl(4), one Cl(5), one Cl(8), and one Cl(9) atom to form CoCl6 octahedra that share  an edgeedge with one Li(3)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(6)Cl6 octahedra, and edges with two equivalent Co(3)Cl6 octahedra. The Co(5)-Cl(13) bond length is 2.53 Å. The Co(5)-Cl(14) bond length is 2.57 Å. The Co(5)-Cl(4) bond length is 2.49 Å. The Co(5)-Cl(5) bond length is 2.44 Å. The Co(5)-Cl(8) bond length is 2.43 Å. The Co(5)-Cl(9) bond length is 2.32 Å. In the sixth Co site, Co(6) is bonded to one Cl(11), one Cl(12), one Cl(16), one Cl(17), one Cl(20), and one Cl(21) atom to form CoCl6 octahedra that share  an edgeedge with one Li(10)Cl6 octahedra,  an edgeedge with one Li(5)Cl6 octahedra, edges with two equivalent Li(9)Cl6 octahedra, and edges with two equivalent Co(4)Cl6 octahedra. The Co(6)-Cl(11) bond length is 2.47 Å. The Co(6)-Cl(12) bond length is 2.49 Å. The Co(6)-Cl(16) bond length is 2.44 Å. The Co(6)-Cl(17) bond length is 2.32 Å. The Co(6)-Cl(20) bond length is 2.52 Å. The Co(6)-Cl(21) bond length is 2.57 Å. There are twenty-four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 5-coordinate geometry to one Li(1), one Li(2), one Li(8), one Co(1), and one Co(2) atom. In the second Cl site, Cl(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Li(6), and one Co(3) atom. In the third Cl site, Cl(3) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one Li(8), and one Co(2) atom. In the fourth Cl site, Cl(4) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(6), one Co(3), and one Co(5) atom. In the fifth Cl site, Cl(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Co(3), and one Co(5) atom. In the sixth Cl site, Cl(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one Li(8), and one Co(1) atom. In the seventh Cl site, Cl(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(5), one Li(9), and one Co(4) atom. In the eighth Cl site, Cl(8) is bonded in a rectangular see-saw-like geometry to one Li(11), one Li(5), one Li(6), and one Co(5) atom. In the ninth Cl site, Cl(9) is bonded in a 3-coordinate geometry to one Li(3), one Li(6), and one Co(5) atom. In the tenth Cl site, Cl(10) is bonded in a 3-coordinate geometry to one Li(3), one Co(1), and one Co(2) atom. In the eleventh Cl site, Cl(11) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(5), one Co(4), and one Co(6) atom. In the twelfth Cl site, Cl(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Li(9), one Co(4), and one Co(6) atom. In the thirteenth Cl site, Cl(13) is bonded in a rectangular see-saw-like geometry to one Li(11), one Li(5), one Co(3), and one Co(5) atom. In the fourteenth Cl site, Cl(14) is bonded in a rectangular see-saw-like geometry to one Li(6), one Li(8), one Co(3), and one Co(5) atom. In the fifteenth Cl site, Cl(15) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(7), one Co(1), and one Co(2) atom. In the sixteenth Cl site, Cl(16) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(12), one Li(9), and one Co(6) atom. In the seventeenth Cl site, Cl(17) is bonded in a distorted T-shaped geometry to one Li(5), one Li(9), and one Co(6) atom. In the eighteenth Cl site, Cl(18) is bonded in a distorted T-shaped geometry to one Li(5), one Li(6), and one Co(3) atom. In the nineteenth Cl site, Cl(19) is bonded in a distorted square pyramidal geometry to one Li(10), one Li(12), one Li(2), one Li(7), and one Co(1) atom. In the twentieth Cl site, Cl(20) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(12), one Co(4), and one Co(6) atom. In the twenty-first Cl site, Cl(21) is bonded in a rectangular see-saw-like geometry to one Li(11), one Li(9), one Co(4), and one Co(6) atom. In the twenty-second Cl site, Cl(22) is bonded in a rectangular see-saw-like geometry to one Li(10), one Li(12), one Li(2), and one Co(2) atom. In the twenty-third Cl site, Cl(23) is bonded in a 3-coordinate geometry to one Li(10), one Li(9), and one Co(4) atom. In the twenty-fourth Cl site, Cl(24) is bonded in a rectangular see-saw-like geometry to one Li(12), one Li(2), one Co(1), and one Co(2) atom.