CsCd13 crystallizes in the cubic Fm-3c space group. Cs(1) is bonded in a 24-coordinate geometry to twenty-four equivalent Cd(2) atoms. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a cuboctahedral geometry to twelve equivalent Cd(2) atoms. In the second Cd site, Cd(2) is bonded in a 12-coordinate geometry to two equivalent Cs(1), one Cd(1), and nine equivalent Cd(2) atoms.
CsCd13 crystallizes in the cubic Fm-3c space group. Cs(1) is bonded in a 24-coordinate geometry to twenty-four equivalent Cd(2) atoms. All Cs(1)-Cd(2) bond lengths are 4.05 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a cuboctahedral geometry to twelve equivalent Cd(2) atoms. All Cd(1)-Cd(2) bond lengths are 3.02 Å. In the second Cd site, Cd(2) is bonded in a 12-coordinate geometry to two equivalent Cs(1), one Cd(1), and nine equivalent Cd(2) atoms. There are a spread of Cd(2)-Cd(2) bond distances ranging from 2.90-3.37 Å.