C2H6SBr2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2H6SBr2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(1) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one Br(2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Br(2) atom. In the second Br site, Br(2) is bonded in a distorted linear geometry to one S(1) and one Br(1) atom.
C2H6SBr2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2H6SBr2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.80 Å. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(1) atom. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-S(1) bond length is 1.80 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one Br(2) atom. The S(1)-Br(2) bond length is 2.41 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Br(2) atom. The Br(1)-Br(2) bond length is 2.66 Å. In the second Br site, Br(2) is bonded in a distorted linear geometry to one S(1) and one Br(1) atom.