Zn2VO4 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Zn(2)O6 octahedra. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the second Zn site, Zn(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent Zn(2)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one Zn(1), and two equivalent Zn(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent V(1), one Zn(1), and one Zn(2) atom.
Zn2VO4 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Zn(2)O6 octahedra. Both V(1)-O(1) bond lengths are 1.88 Å. All V(1)-O(2) bond lengths are 1.99 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. Both Zn(1)-O(1) bond lengths are 1.97 Å. Both Zn(1)-O(2) bond lengths are 1.97 Å. In the second Zn site, Zn(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra, edges with two equivalent Zn(2)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. Both Zn(2)-O(2) bond lengths are 2.15 Å. All Zn(2)-O(1) bond lengths are 2.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one Zn(1), and two equivalent Zn(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent V(1), one Zn(1), and one Zn(2) atom.