Li4Ni3SbO8 is beta Polonium-derived structured and crystallizes in the monoclinic C2 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the second Li site, Li(2) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. In the sixth Li site, Li(6) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(8) atoms to form NiO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the second Ni site, Ni(2) is bonded to one O(4), one O(6), two equivalent O(2), and two equivalent O(7) atoms to form NiO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the third Ni site, Ni(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form NiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. Sb(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Li(6), one Ni(3), and two equivalent Ni(1) atoms to form OLi3Ni3 octahedra that share corners with three equivalent O(1)Li3Ni3 octahedra, corners with three equivalent O(2)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(7)Li3Ni2Sb octahedra, edges with three equivalent O(3)Li3Ni2Sb octahedra, edges with three equivalent O(5)Li3Ni2Sb octahedra, and edges with three equivalent O(8)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second O site, O(2) is bonded to one Li(3), one Li(4), one Li(5), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share corners with three equivalent O(1)Li3Ni3 octahedra, corners with three equivalent O(2)Li3Ni3 octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(8)Li3Ni2Sb octahedra, edges with three equivalent O(4)Li3Ni2Sb octahedra, edges with three equivalent O(6)Li3Ni2Sb octahedra, and edges with three equivalent O(7)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third O site, O(3) is bonded to one Li(1), one Li(4), one Li(6), one Ni(1), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(5)Li3Ni2Sb octahedra, corners with three equivalent O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(7)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni2Sb octahedra, edges with three equivalent O(8)Li3Ni2Sb octahedra, and edges with three equivalent O(1)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(5), one Ni(2), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(5)Li3Ni2Sb octahedra, corners with three equivalent O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni2Sb octahedra, edges with three equivalent O(7)Li3Ni2Sb octahedra, and edges with three equivalent O(2)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(6), one Ni(1), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(3)Li3Ni2Sb octahedra, corners with three equivalent O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(7)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni2Sb octahedra, edges with three equivalent O(8)Li3Ni2Sb octahedra, and edges with three equivalent O(1)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted. In the sixth O site, O(6) is bonded to one Li(2), one Li(4), one Li(5), one Ni(2), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(3)Li3Ni2Sb octahedra, corners with three equivalent O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni2Sb octahedra, edges with three equivalent O(7)Li3Ni2Sb octahedra, and edges with three equivalent O(2)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), two equivalent Ni(2), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(7)Li3Ni2Sb octahedra, corners with three equivalent O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with three equivalent O(4)Li3Ni2Sb octahedra, edges with three equivalent O(6)Li3Ni2Sb octahedra, and edges with three equivalent O(2)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), two equivalent Ni(1), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(7)Li3Ni2Sb octahedra, corners with three equivalent O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with three equivalent O(3)Li3Ni2Sb octahedra, edges with three equivalent O(5)Li3Ni2Sb octahedra, and edges with three equivalent O(1)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted.
Li4Ni3SbO8 is beta Polonium-derived structured and crystallizes in the monoclinic C2 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. Both Li(1)-O(3) bond lengths are 2.22 Å. Both Li(1)-O(5) bond lengths are 2.21 Å. Both Li(1)-O(8) bond lengths are 2.22 Å. In the second Li site, Li(2) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. Both Li(2)-O(4) bond lengths are 2.22 Å. Both Li(2)-O(6) bond lengths are 2.21 Å. Both Li(2)-O(7) bond lengths are 2.22 Å. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Li(3)-O(1) bond length is 2.18 Å. The Li(3)-O(2) bond length is 2.18 Å. The Li(3)-O(4) bond length is 2.11 Å. The Li(3)-O(5) bond length is 2.11 Å. The Li(3)-O(7) bond length is 2.15 Å. The Li(3)-O(8) bond length is 2.14 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Li(4)-O(1) bond length is 2.17 Å. The Li(4)-O(2) bond length is 2.19 Å. The Li(4)-O(3) bond length is 2.11 Å. The Li(4)-O(6) bond length is 2.11 Å. The Li(4)-O(7) bond length is 2.14 Å. The Li(4)-O(8) bond length is 2.15 Å. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. Both Li(5)-O(2) bond lengths are 2.30 Å. Both Li(5)-O(4) bond lengths are 2.15 Å. Both Li(5)-O(6) bond lengths are 2.14 Å. In the sixth Li site, Li(6) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. Both Li(6)-O(1) bond lengths are 2.30 Å. Both Li(6)-O(3) bond lengths are 2.15 Å. Both Li(6)-O(5) bond lengths are 2.14 Å. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(8) atoms to form NiO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Ni(1)-O(3) bond length is 2.11 Å. The Ni(1)-O(5) bond length is 2.12 Å. Both Ni(1)-O(1) bond lengths are 2.07 Å. Both Ni(1)-O(8) bond lengths are 2.10 Å. In the second Ni site, Ni(2) is bonded to one O(4), one O(6), two equivalent O(2), and two equivalent O(7) atoms to form NiO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Ni(2)-O(4) bond length is 2.11 Å. The Ni(2)-O(6) bond length is 2.11 Å. Both Ni(2)-O(2) bond lengths are 2.07 Å. Both Ni(2)-O(7) bond lengths are 2.10 Å. In the third Ni site, Ni(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form NiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. The Ni(3)-O(1) bond length is 1.93 Å. The Ni(3)-O(2) bond length is 1.93 Å. The Ni(3)-O(3) bond length is 2.09 Å. The Ni(3)-O(4) bond length is 2.09 Å. The Ni(3)-O(5) bond length is 2.10 Å. The Ni(3)-O(6) bond length is 2.10 Å. Sb(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. The Sb(1)-O(3) bond length is 2.03 Å. The Sb(1)-O(4) bond length is 2.03 Å. The Sb(1)-O(5) bond length is 2.02 Å. The Sb(1)-O(6) bond length is 2.02 Å. The Sb(1)-O(7) bond length is 2.01 Å. The Sb(1)-O(8) bond length is 2.01 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Li(6), one Ni(3), and two equivalent Ni(1) atoms to form OLi3Ni3 octahedra that share corners with three equivalent O(1)Li3Ni3 octahedra, corners with three equivalent O(2)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(7)Li3Ni2Sb octahedra, edges with three equivalent O(3)Li3Ni2Sb octahedra, edges with three equivalent O(5)Li3Ni2Sb octahedra, and edges with three equivalent O(8)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second O site, O(2) is bonded to one Li(3), one Li(4), one Li(5), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share corners with three equivalent O(1)Li3Ni3 octahedra, corners with three equivalent O(2)Li3Ni3 octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(8)Li3Ni2Sb octahedra, edges with three equivalent O(4)Li3Ni2Sb octahedra, edges with three equivalent O(6)Li3Ni2Sb octahedra, and edges with three equivalent O(7)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third O site, O(3) is bonded to one Li(1), one Li(4), one Li(6), one Ni(1), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(5)Li3Ni2Sb octahedra, corners with three equivalent O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(7)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni2Sb octahedra, edges with three equivalent O(8)Li3Ni2Sb octahedra, and edges with three equivalent O(1)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(5), one Ni(2), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(5)Li3Ni2Sb octahedra, corners with three equivalent O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni2Sb octahedra, edges with three equivalent O(7)Li3Ni2Sb octahedra, and edges with three equivalent O(2)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(6), one Ni(1), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(3)Li3Ni2Sb octahedra, corners with three equivalent O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(7)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni2Sb octahedra, edges with three equivalent O(8)Li3Ni2Sb octahedra, and edges with three equivalent O(1)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted. In the sixth O site, O(6) is bonded to one Li(2), one Li(4), one Li(5), one Ni(2), one Ni(3), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(3)Li3Ni2Sb octahedra, corners with three equivalent O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni2Sb octahedra, edges with three equivalent O(7)Li3Ni2Sb octahedra, and edges with three equivalent O(2)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), two equivalent Ni(2), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(7)Li3Ni2Sb octahedra, corners with three equivalent O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with three equivalent O(4)Li3Ni2Sb octahedra, edges with three equivalent O(6)Li3Ni2Sb octahedra, and edges with three equivalent O(2)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), two equivalent Ni(1), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share corners with three equivalent O(7)Li3Ni2Sb octahedra, corners with three equivalent O(8)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with three equivalent O(3)Li3Ni2Sb octahedra, edges with three equivalent O(5)Li3Ni2Sb octahedra, and edges with three equivalent O(1)Li3Ni3 octahedra. The corner-sharing octahedra are not tilted.