Nd3(BN2)2 crystallizes in the orthorhombic Immm space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. In the second Nd site, Nd(2) is bonded in a distorted body-centered cubic geometry to eight equivalent N(1) atoms. B(1) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. N(1) is bonded in a distorted single-bond geometry to two equivalent Nd(2), three equivalent Nd(1), and one B(1) atom.
Nd3(BN2)2 crystallizes in the orthorhombic Immm space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. There are two shorter (2.48 Å) and four longer (2.56 Å) Nd(1)-N(1) bond lengths. In the second Nd site, Nd(2) is bonded in a distorted body-centered cubic geometry to eight equivalent N(1) atoms. All Nd(2)-N(1) bond lengths are 2.67 Å. B(1) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. Both B(1)-N(1) bond lengths are 1.47 Å. N(1) is bonded in a distorted single-bond geometry to two equivalent Nd(2), three equivalent Nd(1), and one B(1) atom.