MnTiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ti(1) is bonded to six equivalent O(1) atoms to form distorted TiO6 octahedra that share corners with nine equivalent Mn(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. Mn(1) is bonded to six equivalent O(1) atoms to form distorted MnO6 octahedra that share corners with nine equivalent Ti(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Ti(1) and two equivalent Mn(1) atoms.
MnTiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ti(1) is bonded to six equivalent O(1) atoms to form distorted TiO6 octahedra that share corners with nine equivalent Mn(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. There are three shorter (1.89 Å) and three longer (2.09 Å) Ti(1)-O(1) bond lengths. Mn(1) is bonded to six equivalent O(1) atoms to form distorted MnO6 octahedra that share corners with nine equivalent Ti(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-61°. There are three shorter (2.09 Å) and three longer (2.25 Å) Mn(1)-O(1) bond lengths. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Ti(1) and two equivalent Mn(1) atoms.