CsCN3H4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 5-coordinate geometry to one C(1), two equivalent H(1), and two equivalent H(2) atoms. C(1) is bonded in a trigonal planar geometry to one Cs(1), one N(1), and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1) and two equivalent H(1) atoms. In the second N site, N(2) is bonded in a water-like geometry to one C(1) and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom.
CsCN3H4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 5-coordinate geometry to one C(1), two equivalent H(1), and two equivalent H(2) atoms. The Cs(1)-C(1) bond length is 3.26 Å. Both Cs(1)-H(1) bond lengths are 3.10 Å. Both Cs(1)-H(2) bond lengths are 3.28 Å. C(1) is bonded in a trigonal planar geometry to one Cs(1), one N(1), and two equivalent N(2) atoms. The C(1)-N(1) bond length is 1.39 Å. Both C(1)-N(2) bond lengths are 1.35 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1) and two equivalent H(1) atoms. Both N(1)-H(1) bond lengths are 1.03 Å. In the second N site, N(2) is bonded in a water-like geometry to one C(1) and one H(2) atom. The N(2)-H(2) bond length is 1.03 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom.