CeCrSb3 crystallizes in the orthorhombic Pbcm space group. Ce(1) is bonded in a 9-coordinate geometry to one Sb(2), four equivalent Sb(1), and four equivalent Sb(3) atoms. Cr(1) is bonded to two equivalent Sb(3) and four equivalent Sb(2) atoms to form a mixture of distorted face, corner, and edge-sharing CrSb6 octahedra. The corner-sharing octahedral tilt angles are 44°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(1) atoms. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one Ce(1) and four equivalent Cr(1) atoms. In the third Sb site, Sb(3) is bonded in a 6-coordinate geometry to four equivalent Ce(1) and two equivalent Cr(1) atoms.
CeCrSb3 crystallizes in the orthorhombic Pbcm space group. Ce(1) is bonded in a 9-coordinate geometry to one Sb(2), four equivalent Sb(1), and four equivalent Sb(3) atoms. The Ce(1)-Sb(2) bond length is 3.23 Å. All Ce(1)-Sb(1) bond lengths are 3.32 Å. There are a spread of Ce(1)-Sb(3) bond distances ranging from 3.25-3.32 Å. Cr(1) is bonded to two equivalent Sb(3) and four equivalent Sb(2) atoms to form a mixture of distorted face, corner, and edge-sharing CrSb6 octahedra. The corner-sharing octahedral tilt angles are 44°. Both Cr(1)-Sb(3) bond lengths are 2.78 Å. There are two shorter (2.71 Å) and two longer (2.72 Å) Cr(1)-Sb(2) bond lengths. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(1) atoms. There are two shorter (3.07 Å) and two longer (3.14 Å) Sb(1)-Sb(1) bond lengths. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one Ce(1) and four equivalent Cr(1) atoms. In the third Sb site, Sb(3) is bonded in a 6-coordinate geometry to four equivalent Ce(1) and two equivalent Cr(1) atoms.