Rb2LiPu(OCl2)2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent Cl(1) atoms. Li(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one Pu(1) atom. Cl(1) is bonded to two equivalent Rb(1), one Li(1), and one Pu(1) atom to form a mixture of distorted corner and edge-sharing ClRb2LiPu tetrahedra.
Rb2LiPu(OCl2)2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent Cl(1) atoms. The Rb(1)-O(1) bond length is 2.95 Å. There are two shorter (3.29 Å) and two longer (3.32 Å) Rb(1)-Cl(1) bond lengths. Li(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. All Li(1)-Cl(1) bond lengths are 2.45 Å. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. Both Pu(1)-O(1) bond lengths are 1.82 Å. All Pu(1)-Cl(1) bond lengths are 2.84 Å. O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one Pu(1) atom. Cl(1) is bonded to two equivalent Rb(1), one Li(1), and one Pu(1) atom to form a mixture of distorted corner and edge-sharing ClRb2LiPu tetrahedra.