Na2MnP2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Na2MnP2 cluster. Na(1) is bonded in a distorted single-bond geometry to one P(1) atom. Mn(1) is bonded in a linear geometry to two equivalent P(1) atoms. P(1) is bonded in a distorted linear geometry to one Na(1) and one Mn(1) atom.
Na2MnP2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Na2MnP2 cluster. Na(1) is bonded in a distorted single-bond geometry to one P(1) atom. The Na(1)-P(1) bond length is 2.78 Å. Mn(1) is bonded in a linear geometry to two equivalent P(1) atoms. Both Mn(1)-P(1) bond lengths are 2.30 Å. P(1) is bonded in a distorted linear geometry to one Na(1) and one Mn(1) atom.