AgCuS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ag(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Cu(1) is bonded to four equivalent S(1) atoms to form a mixture of edge and corner-sharing CuS4 tetrahedra. S(1) is bonded in a 9-coordinate geometry to five equivalent Ag(1) and four equivalent Cu(1) atoms.
AgCuS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ag(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. There is one shorter (2.62 Å) and four longer (2.91 Å) Ag(1)-S(1) bond lengths. Cu(1) is bonded to four equivalent S(1) atoms to form a mixture of edge and corner-sharing CuS4 tetrahedra. All Cu(1)-S(1) bond lengths are 2.45 Å. S(1) is bonded in a 9-coordinate geometry to five equivalent Ag(1) and four equivalent Cu(1) atoms.