KrAsF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrAsF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a bent 120 degrees geometry to one Kr(1) and one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Kr(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(1) atom.
KrAsF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrAsF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. The Kr(1)-F(3) bond length is 2.10 Å. The Kr(1)-F(4) bond length is 1.82 Å. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. The As(1)-F(1) bond length is 1.73 Å. The As(1)-F(2) bond length is 1.73 Å. The As(1)-F(3) bond length is 1.92 Å. The As(1)-F(5) bond length is 1.72 Å. The As(1)-F(6) bond length is 1.71 Å. The As(1)-F(7) bond length is 1.73 Å. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a bent 120 degrees geometry to one Kr(1) and one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Kr(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(1) atom.