MgV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Mg(1), one V(1), and one C(1) atom.
MgV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. All Mg(1)-O(1) bond lengths are 2.12 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. All V(1)-O(1) bond lengths are 2.20 Å. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All C(1)-O(1) bond lengths are 1.30 Å. O(1) is bonded in a trigonal planar geometry to one Mg(1), one V(1), and one C(1) atom.