K2PdBr3Cl crystallizes in the orthorhombic Amm2 space group. K(1) is bonded in a body-centered cubic geometry to two equivalent Br(1), four equivalent Br(2), and two equivalent Cl(1) atoms. Pd(1) is bonded in a square co-planar geometry to one Br(1), two equivalent Br(2), and one Cl(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded to four equivalent K(1) and one Pd(1) atom to form BrK4Pd square pyramids that share corners with five equivalent Cl(1)K4Pd square pyramids, corners with eight equivalent Br(2)K4Pd square pyramids, edges with two equivalent Br(1)K4Pd square pyramids, edges with two equivalent Br(2)K4Pd square pyramids, edges with two equivalent Cl(1)K4Pd square pyramids, and faces with two equivalent Br(2)K4Pd square pyramids. In the second Br site, Br(2) is bonded to four equivalent K(1) and one Pd(1) atom to form BrK4Pd square pyramids that share corners with four equivalent Br(1)K4Pd square pyramids, corners with four equivalent Cl(1)K4Pd square pyramids, corners with five equivalent Br(2)K4Pd square pyramids,  an edgeedge with one Br(1)K4Pd square pyramid,  an edgeedge with one Cl(1)K4Pd square pyramid, edges with four equivalent Br(2)K4Pd square pyramids,  a faceface with one Br(1)K4Pd square pyramid, and  a faceface with one Cl(1)K4Pd square pyramid. Cl(1) is bonded to four equivalent K(1) and one Pd(1) atom to form ClK4Pd square pyramids that share corners with five equivalent Br(1)K4Pd square pyramids, corners with eight equivalent Br(2)K4Pd square pyramids, edges with two equivalent Br(1)K4Pd square pyramids, edges with two equivalent Br(2)K4Pd square pyramids, edges with two equivalent Cl(1)K4Pd square pyramids, and faces with two equivalent Br(2)K4Pd square pyramids.
K2PdBr3Cl crystallizes in the orthorhombic Amm2 space group. K(1) is bonded in a body-centered cubic geometry to two equivalent Br(1), four equivalent Br(2), and two equivalent Cl(1) atoms. Both K(1)-Br(1) bond lengths are 3.47 Å. There are two shorter (3.42 Å) and two longer (3.45 Å) K(1)-Br(2) bond lengths. Both K(1)-Cl(1) bond lengths are 3.39 Å. Pd(1) is bonded in a square co-planar geometry to one Br(1), two equivalent Br(2), and one Cl(1) atom. The Pd(1)-Br(1) bond length is 2.46 Å. Both Pd(1)-Br(2) bond lengths are 2.47 Å. The Pd(1)-Cl(1) bond length is 2.35 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded to four equivalent K(1) and one Pd(1) atom to form BrK4Pd square pyramids that share corners with five equivalent Cl(1)K4Pd square pyramids, corners with eight equivalent Br(2)K4Pd square pyramids, edges with two equivalent Br(1)K4Pd square pyramids, edges with two equivalent Br(2)K4Pd square pyramids, edges with two equivalent Cl(1)K4Pd square pyramids, and faces with two equivalent Br(2)K4Pd square pyramids. In the second Br site, Br(2) is bonded to four equivalent K(1) and one Pd(1) atom to form BrK4Pd square pyramids that share corners with four equivalent Br(1)K4Pd square pyramids, corners with four equivalent Cl(1)K4Pd square pyramids, corners with five equivalent Br(2)K4Pd square pyramids,  an edgeedge with one Br(1)K4Pd square pyramid,  an edgeedge with one Cl(1)K4Pd square pyramid, edges with four equivalent Br(2)K4Pd square pyramids,  a faceface with one Br(1)K4Pd square pyramid, and  a faceface with one Cl(1)K4Pd square pyramid. Cl(1) is bonded to four equivalent K(1) and one Pd(1) atom to form ClK4Pd square pyramids that share corners with five equivalent Br(1)K4Pd square pyramids, corners with eight equivalent Br(2)K4Pd square pyramids, edges with two equivalent Br(1)K4Pd square pyramids, edges with two equivalent Br(2)K4Pd square pyramids, edges with two equivalent Cl(1)K4Pd square pyramids, and faces with two equivalent Br(2)K4Pd square pyramids.