CuC7NS2F4(CF3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight trifluoromethane molecules and four CuC7NS2F4 clusters. In each CuC7NS2F4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent C(1) and two equivalent S(1) atoms. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one Cu(1), one F(1), and one F(2) atom. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. In the third C site, C(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent S(1) atoms. N(1) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(3) atoms. S(1) is bonded in an L-shaped geometry to one Cu(1) and one C(5) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.
CuC7NS2F4(CF3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight trifluoromethane molecules and four CuC7NS2F4 clusters. In each CuC7NS2F4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent C(1) and two equivalent S(1) atoms. Both Cu(1)-C(1) bond lengths are 2.01 Å. Both Cu(1)-S(1) bond lengths are 2.32 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one Cu(1), one F(1), and one F(2) atom. The C(1)-F(1) bond length is 1.37 Å. The C(1)-F(2) bond length is 1.39 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. The C(3)-C(4) bond length is 1.28 Å. The C(3)-N(1) bond length is 1.32 Å. In the third C site, C(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent S(1) atoms. The C(5)-N(1) bond length is 1.50 Å. Both C(5)-S(1) bond lengths are 1.66 Å. N(1) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(3) atoms. S(1) is bonded in an L-shaped geometry to one Cu(1) and one C(5) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.