NbFeF6 crystallizes in the trigonal R-3 space group. Nb(1) is bonded to six equivalent F(1) atoms to form NbF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Nb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. F(1) is bonded in a bent 150 degrees geometry to one Nb(1) and one Fe(1) atom.
NbFeF6 crystallizes in the trigonal R-3 space group. Nb(1) is bonded to six equivalent F(1) atoms to form NbF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. All Nb(1)-F(1) bond lengths are 2.01 Å. Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Nb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. All Fe(1)-F(1) bond lengths are 2.08 Å. F(1) is bonded in a bent 150 degrees geometry to one Nb(1) and one Fe(1) atom.