Tl(Tl(SbO3)4)2 crystallizes in the triclinic P1 space group. The structure consists of one 7440-28-0 atom inside a Tl(SbO3)4 framework. In the Tl(SbO3)4 framework, there are two inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a 5-coordinate geometry to one O(10), one O(15), one O(18), one O(20), and one O(24) atom. In the second Tl site, Tl(3) is bonded in a 5-coordinate geometry to one O(1), one O(16), one O(17), one O(18), and one O(21) atom. There are eight inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(16), one O(18), one O(24), and one O(7) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-48°. In the second Sb site, Sb(2) is bonded to one O(10), one O(16), one O(2), one O(20), one O(23), and one O(5) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. In the third Sb site, Sb(3) is bonded to one O(1), one O(2), one O(21), one O(23), one O(24), and one O(3) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. In the fourth Sb site, Sb(4) is bonded to one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 45-48°. In the fifth Sb site, Sb(5) is bonded to one O(12), one O(13), one O(15), one O(22), one O(4), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. In the sixth Sb site, Sb(6) is bonded to one O(11), one O(12), one O(13), one O(14), one O(17), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-47°. In the seventh Sb site, Sb(7) is bonded to one O(11), one O(14), one O(19), one O(22), one O(4), and one O(6) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-49°. In the eighth Sb site, Sb(8) is bonded to one O(15), one O(17), one O(18), one O(19), one O(20), and one O(21) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 45-49°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(1), and one Sb(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sb(2) and one Sb(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Sb(3) and one Sb(4) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sb(5) and one Sb(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(2) and one Sb(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Sb(4) and one Sb(7) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Sb(4) and one Sb(5) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sb(4) and one Sb(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(1), and one Sb(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Sb(6) and one Sb(7) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Sb(5) and one Sb(6) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Sb(5) and one Sb(6) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Sb(6) and one Sb(7) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(5), and one Sb(8) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(1), and one Sb(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(6), and one Sb(8) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Tl(2), one Tl(3), one Sb(1), and one Sb(8) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Sb(7) and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(2), and one Sb(8) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(3), and one Sb(8) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Sb(5) and one Sb(7) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Sb(2) and one Sb(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(1), and one Sb(3) atom.
Tl(Tl(SbO3)4)2 crystallizes in the triclinic P1 space group. The structure consists of one 7440-28-0 atom inside a Tl(SbO3)4 framework. In the Tl(SbO3)4 framework, there are two inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a 5-coordinate geometry to one O(10), one O(15), one O(18), one O(20), and one O(24) atom. The Tl(2)-O(10) bond length is 2.62 Å. The Tl(2)-O(15) bond length is 2.40 Å. The Tl(2)-O(18) bond length is 2.35 Å. The Tl(2)-O(20) bond length is 2.66 Å. The Tl(2)-O(24) bond length is 2.40 Å. In the second Tl site, Tl(3) is bonded in a 5-coordinate geometry to one O(1), one O(16), one O(17), one O(18), and one O(21) atom. The Tl(3)-O(1) bond length is 2.62 Å. The Tl(3)-O(16) bond length is 2.40 Å. The Tl(3)-O(17) bond length is 2.40 Å. The Tl(3)-O(18) bond length is 2.35 Å. The Tl(3)-O(21) bond length is 2.66 Å. There are eight inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(16), one O(18), one O(24), and one O(7) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-48°. The Sb(1)-O(1) bond length is 1.98 Å. The Sb(1)-O(10) bond length is 1.98 Å. The Sb(1)-O(16) bond length is 2.03 Å. The Sb(1)-O(18) bond length is 2.14 Å. The Sb(1)-O(24) bond length is 2.02 Å. The Sb(1)-O(7) bond length is 1.94 Å. In the second Sb site, Sb(2) is bonded to one O(10), one O(16), one O(2), one O(20), one O(23), and one O(5) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. The Sb(2)-O(10) bond length is 2.01 Å. The Sb(2)-O(16) bond length is 2.02 Å. The Sb(2)-O(2) bond length is 1.97 Å. The Sb(2)-O(20) bond length is 2.01 Å. The Sb(2)-O(23) bond length is 2.00 Å. The Sb(2)-O(5) bond length is 1.99 Å. In the third Sb site, Sb(3) is bonded to one O(1), one O(2), one O(21), one O(23), one O(24), and one O(3) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. The Sb(3)-O(1) bond length is 2.01 Å. The Sb(3)-O(2) bond length is 1.98 Å. The Sb(3)-O(21) bond length is 2.01 Å. The Sb(3)-O(23) bond length is 2.00 Å. The Sb(3)-O(24) bond length is 2.02 Å. The Sb(3)-O(3) bond length is 1.98 Å. In the fourth Sb site, Sb(4) is bonded to one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 45-48°. The Sb(4)-O(3) bond length is 2.00 Å. The Sb(4)-O(5) bond length is 2.01 Å. The Sb(4)-O(6) bond length is 2.00 Å. The Sb(4)-O(7) bond length is 1.99 Å. The Sb(4)-O(8) bond length is 2.00 Å. The Sb(4)-O(9) bond length is 1.99 Å. In the fifth Sb site, Sb(5) is bonded to one O(12), one O(13), one O(15), one O(22), one O(4), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. The Sb(5)-O(12) bond length is 2.01 Å. The Sb(5)-O(13) bond length is 2.00 Å. The Sb(5)-O(15) bond length is 2.03 Å. The Sb(5)-O(22) bond length is 1.99 Å. The Sb(5)-O(4) bond length is 1.99 Å. The Sb(5)-O(8) bond length is 1.99 Å. In the sixth Sb site, Sb(6) is bonded to one O(11), one O(12), one O(13), one O(14), one O(17), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-47°. The Sb(6)-O(11) bond length is 1.98 Å. The Sb(6)-O(12) bond length is 2.01 Å. The Sb(6)-O(13) bond length is 2.00 Å. The Sb(6)-O(14) bond length is 1.99 Å. The Sb(6)-O(17) bond length is 2.03 Å. The Sb(6)-O(9) bond length is 1.98 Å. In the seventh Sb site, Sb(7) is bonded to one O(11), one O(14), one O(19), one O(22), one O(4), and one O(6) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 43-49°. The Sb(7)-O(11) bond length is 1.99 Å. The Sb(7)-O(14) bond length is 2.01 Å. The Sb(7)-O(19) bond length is 2.00 Å. The Sb(7)-O(22) bond length is 2.00 Å. The Sb(7)-O(4) bond length is 2.00 Å. The Sb(7)-O(6) bond length is 1.99 Å. In the eighth Sb site, Sb(8) is bonded to one O(15), one O(17), one O(18), one O(19), one O(20), and one O(21) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 45-49°. The Sb(8)-O(15) bond length is 2.02 Å. The Sb(8)-O(17) bond length is 2.02 Å. The Sb(8)-O(18) bond length is 2.13 Å. The Sb(8)-O(19) bond length is 1.94 Å. The Sb(8)-O(20) bond length is 1.98 Å. The Sb(8)-O(21) bond length is 1.98 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(1), and one Sb(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sb(2) and one Sb(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Sb(3) and one Sb(4) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sb(5) and one Sb(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(2) and one Sb(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Sb(4) and one Sb(7) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Sb(4) and one Sb(5) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sb(4) and one Sb(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(1), and one Sb(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Sb(6) and one Sb(7) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Sb(5) and one Sb(6) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Sb(5) and one Sb(6) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Sb(6) and one Sb(7) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(5), and one Sb(8) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(1), and one Sb(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(6), and one Sb(8) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Tl(2), one Tl(3), one Sb(1), and one Sb(8) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Sb(7) and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(2), and one Sb(8) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Tl(3), one Sb(3), and one Sb(8) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Sb(5) and one Sb(7) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Sb(2) and one Sb(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Tl(2), one Sb(1), and one Sb(3) atom.