Li2NH crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded in a 4-coordinate geometry to three equivalent N(1) and one H(1) atom. N(1) is bonded in a distorted single-bond geometry to six equivalent Li(1) and one H(1) atom. H(1) is bonded in a distorted single-bond geometry to two equivalent Li(1) and one N(1) atom.
Li2NH crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded in a 4-coordinate geometry to three equivalent N(1) and one H(1) atom. There is one shorter (2.11 Å) and two longer (2.14 Å) Li(1)-N(1) bond lengths. The Li(1)-H(1) bond length is 1.82 Å. N(1) is bonded in a distorted single-bond geometry to six equivalent Li(1) and one H(1) atom. The N(1)-H(1) bond length is 1.03 Å. H(1) is bonded in a distorted single-bond geometry to two equivalent Li(1) and one N(1) atom.