Sr3La7Ti3Mn7O30 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(3), one O(4), one O(5), and two equivalent O(7) atoms. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(1), one O(11), one O(20), one O(24), one O(26), one O(27), one O(30), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(25), one O(26), one O(30), one O(4), one O(5), and two equivalent O(29) atoms. There are seven inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(10), one O(16), one O(17), one O(18), one O(3), one O(8), one O(9), and two equivalent O(13) atoms. In the second La site, La(2) is bonded in a 3-coordinate geometry to one O(15), one O(23), and one O(24) atom. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(17), one O(2), one O(3), one O(4), one O(9), and two equivalent O(6) atoms. In the fourth La site, La(4) is bonded in a 12-coordinate geometry to one O(14), one O(18), one O(20), one O(21), one O(22), one O(26), one O(27), one O(28), one O(29), one O(30), and two equivalent O(25) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(17), one O(23), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. In the sixth La site, La(6) is bonded in a 3-coordinate geometry to one O(13), one O(14), and one O(22) atom. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(19), one O(20), one O(21), one O(26), one O(27), one O(28), one O(30), and two equivalent O(24) atoms. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(2), one O(20), one O(26), one O(29), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with two equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(17), one O(4), one O(6), and one O(7) atom to form TiO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-23°. In the third Ti site, Ti(3) is bonded to one O(1), one O(2), one O(27), one O(29), one O(30), and one O(4) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-20°. There are seven inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(13), one O(16), one O(23), one O(3), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 15-22°. In the second Mn site, Mn(2) is bonded to one O(15), one O(18), one O(19), one O(22), one O(28), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 20-21°. In the third Mn site, Mn(3) is bonded to one O(11), one O(3), one O(5), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-23°. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(21), one O(24), one O(25), one O(27), and one O(30) atom to form MnO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, and corners with two equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-21°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(17), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-22°. In the sixth Mn site, Mn(6) is bonded to one O(14), one O(16), one O(18), one O(19), one O(21), and one O(23) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. In the seventh Mn site, Mn(7) is bonded to one O(20), one O(22), one O(24), one O(25), one O(26), and one O(28) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Ti(2), and one Ti(3) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Sr(2), one La(3), one Ti(1), and one Ti(3) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), one La(3), one Mn(1), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ti(2), and one Ti(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Ti(1), and one Mn(3) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Sr(2), two equivalent La(3), one Ti(2), and one Mn(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(5), one Ti(2), and one Mn(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(1), one La(5), one Mn(2), and one Mn(5) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one La(1), one La(3), one La(5), one Mn(1), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Sr(1), one La(1), one La(3), one Ti(2), and one Mn(5) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ti(1), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(5), one Mn(1), and one Mn(5) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(6), two equivalent La(1), one Mn(1), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one La(4), one La(6), one Mn(4), and one Mn(6) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one La(2), one La(5), one Mn(2), and one Mn(5) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one La(1), one La(5), one Mn(1), and one Mn(6) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one La(1), one La(3), one La(5), one Ti(2), and one Mn(5) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one La(1), one La(4), one Mn(2), and one Mn(6) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one La(7), one Mn(2), and one Mn(6) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Sr(2), one La(4), one La(7), one Ti(1), and one Mn(7) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one La(4), one La(7), one Mn(4), and one Mn(6) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one La(4), one La(6), one Mn(2), and one Mn(7) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one La(2), one La(5), one Mn(1), and one Mn(6) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Sr(2), one La(2), two equivalent La(7), one Mn(4), and one Mn(7) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to one Sr(3), two equivalent La(4), one Mn(4), and one Mn(7) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(4), one La(7), one Ti(1), and one Mn(7) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one Sr(2), one La(4), one La(7), one Ti(3), and one Mn(4) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one La(4), one La(7), one Mn(2), and one Mn(7) atom. In the twenty-ninth O site, O(29) is bonded in a 5-coordinate geometry to two equivalent Sr(3), one La(4), one Ti(1), and one Ti(3) atom. In the thirtieth O site, O(30) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(4), one La(7), one Ti(3), and one Mn(4) atom.
Sr3La7Ti3Mn7O30 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(3), one O(4), one O(5), and two equivalent O(7) atoms. The Sr(1)-O(1) bond length is 2.82 Å. The Sr(1)-O(10) bond length is 2.89 Å. The Sr(1)-O(11) bond length is 2.56 Å. The Sr(1)-O(12) bond length is 2.53 Å. The Sr(1)-O(3) bond length is 2.84 Å. The Sr(1)-O(4) bond length is 2.58 Å. The Sr(1)-O(5) bond length is 2.82 Å. There is one shorter (2.81 Å) and one longer (2.82 Å) Sr(1)-O(7) bond length. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(1), one O(11), one O(20), one O(24), one O(26), one O(27), one O(30), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. The Sr(2)-O(1) bond length is 2.83 Å. The Sr(2)-O(11) bond length is 3.06 Å. The Sr(2)-O(20) bond length is 2.85 Å. The Sr(2)-O(24) bond length is 3.17 Å. The Sr(2)-O(26) bond length is 2.55 Å. The Sr(2)-O(27) bond length is 2.85 Å. The Sr(2)-O(30) bond length is 2.55 Å. The Sr(2)-O(4) bond length is 3.10 Å. The Sr(2)-O(5) bond length is 2.77 Å. The Sr(2)-O(6) bond length is 2.56 Å. There is one shorter (2.80 Å) and one longer (2.81 Å) Sr(2)-O(2) bond length. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(25), one O(26), one O(30), one O(4), one O(5), and two equivalent O(29) atoms. The Sr(3)-O(1) bond length is 2.59 Å. The Sr(3)-O(11) bond length is 2.81 Å. The Sr(3)-O(25) bond length is 2.54 Å. The Sr(3)-O(26) bond length is 2.84 Å. The Sr(3)-O(30) bond length is 2.85 Å. The Sr(3)-O(4) bond length is 2.87 Å. The Sr(3)-O(5) bond length is 2.54 Å. There is one shorter (2.80 Å) and one longer (2.82 Å) Sr(3)-O(29) bond length. There are seven inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(10), one O(16), one O(17), one O(18), one O(3), one O(8), one O(9), and two equivalent O(13) atoms. The La(1)-O(10) bond length is 2.76 Å. The La(1)-O(16) bond length is 2.80 Å. The La(1)-O(17) bond length is 2.43 Å. The La(1)-O(18) bond length is 2.47 Å. The La(1)-O(3) bond length is 2.72 Å. The La(1)-O(8) bond length is 2.83 Å. The La(1)-O(9) bond length is 2.46 Å. Both La(1)-O(13) bond lengths are 2.82 Å. In the second La site, La(2) is bonded in a 3-coordinate geometry to one O(15), one O(23), and one O(24) atom. The La(2)-O(15) bond length is 2.45 Å. The La(2)-O(23) bond length is 2.43 Å. The La(2)-O(24) bond length is 2.45 Å. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(17), one O(2), one O(3), one O(4), one O(9), and two equivalent O(6) atoms. The La(3)-O(10) bond length is 2.44 Å. The La(3)-O(11) bond length is 2.76 Å. The La(3)-O(17) bond length is 2.82 Å. The La(3)-O(2) bond length is 2.50 Å. The La(3)-O(3) bond length is 2.46 Å. The La(3)-O(4) bond length is 2.79 Å. The La(3)-O(9) bond length is 2.78 Å. There is one shorter (2.79 Å) and one longer (2.82 Å) La(3)-O(6) bond length. In the fourth La site, La(4) is bonded in a 12-coordinate geometry to one O(14), one O(18), one O(20), one O(21), one O(22), one O(26), one O(27), one O(28), one O(29), one O(30), and two equivalent O(25) atoms. The La(4)-O(14) bond length is 2.84 Å. The La(4)-O(18) bond length is 3.16 Å. The La(4)-O(20) bond length is 2.74 Å. The La(4)-O(21) bond length is 2.47 Å. The La(4)-O(22) bond length is 2.80 Å. The La(4)-O(26) bond length is 3.05 Å. The La(4)-O(27) bond length is 2.81 Å. The La(4)-O(28) bond length is 2.45 Å. The La(4)-O(29) bond length is 2.48 Å. The La(4)-O(30) bond length is 3.12 Å. There is one shorter (2.80 Å) and one longer (2.81 Å) La(4)-O(25) bond length. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(17), one O(23), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. The La(5)-O(15) bond length is 2.84 Å. The La(5)-O(16) bond length is 2.43 Å. The La(5)-O(17) bond length is 2.83 Å. The La(5)-O(23) bond length is 2.81 Å. The La(5)-O(7) bond length is 2.42 Å. The La(5)-O(8) bond length is 2.47 Å. The La(5)-O(9) bond length is 2.79 Å. There is one shorter (2.80 Å) and one longer (2.81 Å) La(5)-O(12) bond length. In the sixth La site, La(6) is bonded in a 3-coordinate geometry to one O(13), one O(14), and one O(22) atom. The La(6)-O(13) bond length is 2.45 Å. The La(6)-O(14) bond length is 2.45 Å. The La(6)-O(22) bond length is 2.44 Å. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(19), one O(20), one O(21), one O(26), one O(27), one O(28), one O(30), and two equivalent O(24) atoms. The La(7)-O(19) bond length is 2.44 Å. The La(7)-O(20) bond length is 2.44 Å. The La(7)-O(21) bond length is 2.84 Å. The La(7)-O(26) bond length is 2.72 Å. The La(7)-O(27) bond length is 2.47 Å. The La(7)-O(28) bond length is 2.80 Å. The La(7)-O(30) bond length is 2.78 Å. There is one shorter (2.81 Å) and one longer (2.82 Å) La(7)-O(24) bond length. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(2), one O(20), one O(26), one O(29), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with two equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. The Ti(1)-O(11) bond length is 1.91 Å. The Ti(1)-O(2) bond length is 2.01 Å. The Ti(1)-O(20) bond length is 2.04 Å. The Ti(1)-O(26) bond length is 2.00 Å. The Ti(1)-O(29) bond length is 2.04 Å. The Ti(1)-O(5) bond length is 1.90 Å. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(17), one O(4), one O(6), and one O(7) atom to form TiO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-23°. The Ti(2)-O(1) bond length is 1.97 Å. The Ti(2)-O(10) bond length is 2.03 Å. The Ti(2)-O(17) bond length is 2.03 Å. The Ti(2)-O(4) bond length is 1.97 Å. The Ti(2)-O(6) bond length is 1.93 Å. The Ti(2)-O(7) bond length is 1.95 Å. In the third Ti site, Ti(3) is bonded to one O(1), one O(2), one O(27), one O(29), one O(30), and one O(4) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-20°. The Ti(3)-O(1) bond length is 2.02 Å. The Ti(3)-O(2) bond length is 2.00 Å. The Ti(3)-O(27) bond length is 1.95 Å. The Ti(3)-O(29) bond length is 1.99 Å. The Ti(3)-O(30) bond length is 1.91 Å. The Ti(3)-O(4) bond length is 2.02 Å. There are seven inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(13), one O(16), one O(23), one O(3), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 15-22°. The Mn(1)-O(12) bond length is 2.00 Å. The Mn(1)-O(13) bond length is 2.01 Å. The Mn(1)-O(16) bond length is 2.02 Å. The Mn(1)-O(23) bond length is 2.01 Å. The Mn(1)-O(3) bond length is 1.99 Å. The Mn(1)-O(9) bond length is 1.99 Å. In the second Mn site, Mn(2) is bonded to one O(15), one O(18), one O(19), one O(22), one O(28), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 20-21°. The Mn(2)-O(15) bond length is 2.02 Å. The Mn(2)-O(18) bond length is 2.01 Å. The Mn(2)-O(19) bond length is 2.01 Å. The Mn(2)-O(22) bond length is 2.03 Å. The Mn(2)-O(28) bond length is 2.00 Å. The Mn(2)-O(8) bond length is 2.00 Å. In the third Mn site, Mn(3) is bonded to one O(11), one O(3), one O(5), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, and corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-23°. The Mn(3)-O(11) bond length is 2.06 Å. The Mn(3)-O(3) bond length is 2.03 Å. The Mn(3)-O(5) bond length is 2.06 Å. The Mn(3)-O(6) bond length is 2.06 Å. The Mn(3)-O(7) bond length is 2.10 Å. The Mn(3)-O(9) bond length is 2.05 Å. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(21), one O(24), one O(25), one O(27), and one O(30) atom to form MnO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, and corners with two equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-21°. The Mn(4)-O(14) bond length is 2.03 Å. The Mn(4)-O(21) bond length is 2.03 Å. The Mn(4)-O(24) bond length is 2.03 Å. The Mn(4)-O(25) bond length is 1.99 Å. The Mn(4)-O(27) bond length is 2.07 Å. The Mn(4)-O(30) bond length is 2.05 Å. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(17), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-22°. The Mn(5)-O(10) bond length is 2.02 Å. The Mn(5)-O(12) bond length is 1.99 Å. The Mn(5)-O(13) bond length is 2.04 Å. The Mn(5)-O(15) bond length is 2.00 Å. The Mn(5)-O(17) bond length is 2.05 Å. The Mn(5)-O(8) bond length is 2.01 Å. In the sixth Mn site, Mn(6) is bonded to one O(14), one O(16), one O(18), one O(19), one O(21), and one O(23) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. The Mn(6)-O(14) bond length is 1.99 Å. The Mn(6)-O(16) bond length is 2.00 Å. The Mn(6)-O(18) bond length is 2.01 Å. The Mn(6)-O(19) bond length is 2.02 Å. The Mn(6)-O(21) bond length is 1.98 Å. The Mn(6)-O(23) bond length is 2.01 Å. In the seventh Mn site, Mn(7) is bonded to one O(20), one O(22), one O(24), one O(25), one O(26), and one O(28) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. The Mn(7)-O(20) bond length is 2.04 Å. The Mn(7)-O(22) bond length is 2.01 Å. The Mn(7)-O(24) bond length is 2.02 Å. The Mn(7)-O(25) bond length is 1.99 Å. The Mn(7)-O(26) bond length is 2.01 Å. The Mn(7)-O(28) bond length is 2.01 Å. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Ti(2), and one Ti(3) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Sr(2), one La(3), one Ti(1), and one Ti(3) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), one La(3), one Mn(1), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ti(2), and one Ti(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Ti(1), and one Mn(3) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Sr(2), two equivalent La(3), one Ti(2), and one Mn(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(5), one Ti(2), and one Mn(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(1), one La(5), one Mn(2), and one Mn(5) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one La(1), one La(3), one La(5), one Mn(1), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Sr(1), one La(1), one La(3), one Ti(2), and one Mn(5) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ti(1), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(5), one Mn(1), and one Mn(5) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(6), two equivalent La(1), one Mn(1), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one La(4), one La(6), one Mn(4), and one Mn(6) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one La(2), one La(5), one Mn(2), and one Mn(5) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one La(1), one La(5), one Mn(1), and one Mn(6) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one La(1), one La(3), one La(5), one Ti(2), and one Mn(5) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one La(1), one La(4), one Mn(2), and one Mn(6) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one La(7), one Mn(2), and one Mn(6) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Sr(2), one La(4), one La(7), one Ti(1), and one Mn(7) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one La(4), one La(7), one Mn(4), and one Mn(6) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one La(4), one La(6), one Mn(2), and one Mn(7) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one La(2), one La(5), one Mn(1), and one Mn(6) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Sr(2), one La(2), two equivalent La(7), one Mn(4), and one Mn(7) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to one Sr(3), two equivalent La(4), one Mn(4), and one Mn(7) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(4), one La(7), one Ti(1), and one Mn(7) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one Sr(2), one La(4), one La(7), one Ti(3), and one Mn(4) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one La(4), one La(7), one Mn(2), and one Mn(7) atom. In the twenty-ninth O site, O(29) is bonded in a 5-coordinate geometry to two equivalent Sr(3), one La(4), one Ti(1), and one Ti(3) atom. In the thirtieth O site, O(30) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(4), one La(7), one Ti(3), and one Mn(4) atom.