IF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-41-4 molecule, one IF5 cluster, and one IF7 cluster. In the IF5 cluster, I(1) is bonded in a distorted square pyramidal geometry to one F(10), one F(13), one F(2), one F(5), and one F(6) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one I(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one I(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one I(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one I(1) atom. In the fifth F site, F(13) is bonded in a single-bond geometry to one I(1) atom. In the IF7 cluster, I(2) is bonded in a 6-coordinate geometry to one F(11), one F(12), one F(14), one F(4), one F(7), and one F(9) atom. There are seven inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one I(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one I(2) atom. In the third F site, F(8) is bonded in a single-bond geometry to one F(9) atom. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to one I(2) and one F(8) atom. In the fifth F site, F(11) is bonded in a single-bond geometry to one I(2) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one I(2) atom. In the seventh F site, F(14) is bonded in a single-bond geometry to one I(2) atom.
IF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-41-4 molecule, one IF5 cluster, and one IF7 cluster. In the IF5 cluster, I(1) is bonded in a distorted square pyramidal geometry to one F(10), one F(13), one F(2), one F(5), and one F(6) atom. The I(1)-F(10) bond length is 1.86 Å. The I(1)-F(13) bond length is 1.98 Å. The I(1)-F(2) bond length is 1.90 Å. The I(1)-F(5) bond length is 1.95 Å. The I(1)-F(6) bond length is 1.94 Å. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one I(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one I(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one I(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one I(1) atom. In the fifth F site, F(13) is bonded in a single-bond geometry to one I(1) atom. In the IF7 cluster, I(2) is bonded in a 6-coordinate geometry to one F(11), one F(12), one F(14), one F(4), one F(7), and one F(9) atom. The I(2)-F(11) bond length is 1.88 Å. The I(2)-F(12) bond length is 1.87 Å. The I(2)-F(14) bond length is 1.92 Å. The I(2)-F(4) bond length is 1.90 Å. The I(2)-F(7) bond length is 1.90 Å. The I(2)-F(9) bond length is 2.56 Å. There are seven inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one I(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one I(2) atom. In the third F site, F(8) is bonded in a single-bond geometry to one F(9) atom. The F(8)-F(9) bond length is 1.54 Å. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to one I(2) and one F(8) atom. In the fifth F site, F(11) is bonded in a single-bond geometry to one I(2) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one I(2) atom. In the seventh F site, F(14) is bonded in a single-bond geometry to one I(2) atom.