Ag2H2OIF crystallizes in the monoclinic P2_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to one O(1), two equivalent I(1), and one F(1) atom. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one O(1), two equivalent I(1), and one F(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one F(1) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(1) and one F(1) atom. O(1) is bonded in a distorted water-like geometry to one Ag(1), one Ag(2), one H(1), and one H(2) atom. I(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Ag(2) atoms. F(1) is bonded in a distorted tetrahedral geometry to one Ag(1), one Ag(2), one H(1), and one H(2) atom.
Ag2H2OIF crystallizes in the monoclinic P2_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to one O(1), two equivalent I(1), and one F(1) atom. The Ag(1)-O(1) bond length is 2.43 Å. There is one shorter (2.81 Å) and one longer (2.90 Å) Ag(1)-I(1) bond length. The Ag(1)-F(1) bond length is 2.38 Å. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one O(1), two equivalent I(1), and one F(1) atom. The Ag(2)-O(1) bond length is 2.35 Å. There is one shorter (2.86 Å) and one longer (2.94 Å) Ag(2)-I(1) bond length. The Ag(2)-F(1) bond length is 2.44 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one F(1) atom. The H(1)-O(1) bond length is 1.01 Å. The H(1)-F(1) bond length is 1.58 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(1) and one F(1) atom. The H(2)-O(1) bond length is 1.01 Å. The H(2)-F(1) bond length is 1.57 Å. O(1) is bonded in a distorted water-like geometry to one Ag(1), one Ag(2), one H(1), and one H(2) atom. I(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Ag(2) atoms. F(1) is bonded in a distorted tetrahedral geometry to one Ag(1), one Ag(2), one H(1), and one H(2) atom.