NdLa3(GaO3)4 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pm space group. Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the third La site, La(3) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-25°. In the second Ga site, Ga(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-27°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(2) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(2) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one Ga(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom.
NdLa3(GaO3)4 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pm space group. Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. The Nd(1)-O(1) bond length is 2.53 Å. The Nd(1)-O(2) bond length is 2.38 Å. Both Nd(1)-O(5) bond lengths are 2.43 Å. Both Nd(1)-O(6) bond lengths are 2.58 Å. Both Nd(1)-O(7) bond lengths are 2.81 Å. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. There is one shorter (2.40 Å) and one longer (3.18 Å) La(1)-O(1) bond length. There is one shorter (2.61 Å) and one longer (3.04 Å) La(1)-O(2) bond length. Both La(1)-O(5) bond lengths are 2.64 Å. Both La(1)-O(6) bond lengths are 2.45 Å. Both La(1)-O(7) bond lengths are 3.26 Å. Both La(1)-O(8) bond lengths are 2.82 Å. In the second La site, La(2) is bonded in a 12-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. There is one shorter (2.61 Å) and one longer (3.02 Å) La(2)-O(3) bond length. There is one shorter (2.40 Å) and one longer (3.17 Å) La(2)-O(4) bond length. Both La(2)-O(5) bond lengths are 2.84 Å. Both La(2)-O(6) bond lengths are 3.26 Å. Both La(2)-O(7) bond lengths are 2.45 Å. Both La(2)-O(8) bond lengths are 2.65 Å. In the third La site, La(3) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. The La(3)-O(3) bond length is 2.41 Å. The La(3)-O(4) bond length is 2.60 Å. Both La(3)-O(6) bond lengths are 2.86 Å. Both La(3)-O(7) bond lengths are 2.64 Å. Both La(3)-O(8) bond lengths are 2.44 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-25°. The Ga(1)-O(1) bond length is 2.01 Å. The Ga(1)-O(3) bond length is 2.02 Å. The Ga(1)-O(5) bond length is 2.01 Å. The Ga(1)-O(6) bond length is 2.01 Å. The Ga(1)-O(7) bond length is 2.02 Å. The Ga(1)-O(8) bond length is 2.00 Å. In the second Ga site, Ga(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-27°. The Ga(2)-O(2) bond length is 2.01 Å. The Ga(2)-O(4) bond length is 2.02 Å. The Ga(2)-O(5) bond length is 2.01 Å. The Ga(2)-O(6) bond length is 2.01 Å. The Ga(2)-O(7) bond length is 2.00 Å. The Ga(2)-O(8) bond length is 2.00 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Ga(2) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one La(3), two equivalent La(2), and two equivalent Ga(2) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one Ga(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Nd(1), one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Ga(1), and one Ga(2) atom.