WMoZn2O6 crystallizes in the trigonal R3 space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. Mo(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Mo(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom.
WMoZn2O6 crystallizes in the trigonal R3 space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. All W(1)-O(1) bond lengths are 2.01 Å. All W(1)-O(2) bond lengths are 2.02 Å. Mo(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. All Mo(1)-O(1) bond lengths are 2.17 Å. All Mo(1)-O(2) bond lengths are 2.18 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. All Zn(1)-O(2) bond lengths are 1.95 Å. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) and three equivalent O(2) atoms. All Zn(2)-O(1) bond lengths are 1.98 Å. All Zn(2)-O(2) bond lengths are 2.54 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Mo(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom.