Na2Ag2Cu(SO)2 crystallizes in the tetragonal I4/mmm space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Ag(1) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing AgS4 tetrahedra. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. S(1) is bonded in a 8-coordinate geometry to four equivalent Na(1) and four equivalent Ag(1) atoms. O(1) is bonded to four equivalent Na(1) and two equivalent Cu(1) atoms to form a mixture of corner, edge, and face-sharing ONa4Cu2 octahedra. The corner-sharing octahedra are not tilted.
Na2Ag2Cu(SO)2 crystallizes in the tetragonal I4/mmm space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. All Na(1)-S(1) bond lengths are 3.24 Å. All Na(1)-O(1) bond lengths are 2.45 Å. Ag(1) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing AgS4 tetrahedra. All Ag(1)-S(1) bond lengths are 2.59 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Cu(1)-O(1) bond lengths are 1.96 Å. S(1) is bonded in a 8-coordinate geometry to four equivalent Na(1) and four equivalent Ag(1) atoms. O(1) is bonded to four equivalent Na(1) and two equivalent Cu(1) atoms to form a mixture of corner, edge, and face-sharing ONa4Cu2 octahedra. The corner-sharing octahedra are not tilted.