AlSO8O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and two AlSO8 clusters. In each AlSO8 cluster, Al(1) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(8), and two equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(6), one O(7), one O(8), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Al(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Al(1) atoms. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one O(5) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Al(1) atom. In the seventh O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one O(3) atom. In the eighth O site, O(6) is bonded in a distorted single-bond geometry to one S(1) atom.
AlSO8O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and two AlSO8 clusters. In each AlSO8 cluster, Al(1) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(8), and two equivalent O(1) atoms. The Al(1)-O(4) bond length is 1.77 Å. The Al(1)-O(5) bond length is 2.17 Å. The Al(1)-O(8) bond length is 1.76 Å. There is one shorter (1.83 Å) and one longer (1.84 Å) Al(1)-O(1) bond length. S(1) is bonded in a tetrahedral geometry to one O(6), one O(7), one O(8), and one O(9) atom. The S(1)-O(6) bond length is 1.67 Å. The S(1)-O(7) bond length is 1.44 Å. The S(1)-O(8) bond length is 1.55 Å. The S(1)-O(9) bond length is 1.44 Å. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Al(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Al(1) atoms. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one O(5) atom. The O(3)-O(5) bond length is 1.23 Å. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Al(1) atom. In the seventh O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one O(3) atom. In the eighth O site, O(6) is bonded in a distorted single-bond geometry to one S(1) atom.