Li8V11O22 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(10) atoms to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the fourth Li site, Li(4) is bonded to one O(7), one O(8), two equivalent O(11), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(8), one O(9), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(6)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fourth V site, V(4) is bonded to one O(10), one O(11), one O(2), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(11), one O(2), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the sixth V site, V(6) is bonded to one O(1), one O(10), one O(11), one O(3), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one V(2), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(9)Li2V3 square pyramid, corners with two equivalent O(10)Li2V3 square pyramids, corners with three equivalent O(2)Li2V3 square pyramids,  an edgeedge with one O(4)Li3V3 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(6)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid, and  an edgeedge with one O(9)Li2V3 square pyramid. In the second O site, O(2) is bonded to one Li(1), one Li(2), one V(1), one V(4), and one V(5) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(9)Li2V3 square pyramid, corners with two equivalent O(10)Li2V3 square pyramids, corners with three equivalent O(1)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra, edges with two equivalent O(4)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid, and edges with two equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 3°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(3), and one V(6) atom to form OLi3V3 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(9)Li2V3 square pyramid, edges with two equivalent O(1)Li2V3 square pyramids, edges with two equivalent O(8)Li2V3 square pyramids, and edges with three equivalent O(6)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(3), one V(4), and two equivalent V(1) atoms to form OLi3V3 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(6)Li2V3 square pyramid, edges with two equivalent O(2)Li2V3 square pyramids, edges with two equivalent O(7)Li2V3 square pyramids, and edges with three equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 1°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one V(4), and two equivalent V(1) atoms to form OLi2V3 square pyramids that share  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(6)Li2V3 square pyramids, corners with two equivalent O(7)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra, edges with three equivalent O(4)Li3V3 octahedra,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid, and edges with two equivalent O(2)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 7°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one V(3), and two equivalent V(2) atoms to form OLi2V3 square pyramids that share  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(5)Li2V3 square pyramids, corners with two equivalent O(9)Li2V3 square pyramids,  an edgeedge with one O(4)Li3V3 octahedra, edges with three equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(6)Li2V3 square pyramid, and edges with two equivalent O(8)Li2V3 square pyramids. In the seventh O site, O(7) is bonded to one Li(3), one Li(4), one V(1), one V(4), and one V(5) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(9)Li2V3 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(5)Li2V3 square pyramids, edges with two equivalent O(4)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid, and  an edgeedge with one O(9)Li2V3 square pyramid. The corner-sharing octahedral tilt angles are 2°. In the eighth O site, O(8) is bonded to one Li(3), one Li(4), one V(2), one V(3), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(9)Li2V3 square pyramids, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(9)Li2V3 square pyramid, and edges with two equivalent O(6)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 5-8°. In the ninth O site, O(9) is bonded to two equivalent Li(4), one V(2), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(6)Li2V3 square pyramids, corners with two equivalent O(8)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(9)Li2V3 square pyramid, and edges with two equivalent O(11)Li2V3 square pyramids. In the tenth O site, O(10) is bonded to two equivalent Li(1), one V(4), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(1)Li2V3 square pyramids, corners with two equivalent O(2)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid, and  an edgeedge with one O(9)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 4-6°. In the eleventh O site, O(11) is bonded to two equivalent Li(4), one V(4), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(7)Li2V3 square pyramids, corners with two equivalent O(9)Li2V3 square pyramids,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid, and edges with two equivalent O(9)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 3°.
Li8V11O22 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(10) atoms to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The Li(1)-O(1) bond length is 2.22 Å. The Li(1)-O(2) bond length is 2.20 Å. The Li(1)-O(3) bond length is 2.30 Å. The Li(1)-O(4) bond length is 2.16 Å. There is one shorter (2.08 Å) and one longer (2.13 Å) Li(1)-O(10) bond length. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. The Li(2)-O(1) bond length is 2.21 Å. The Li(2)-O(2) bond length is 2.30 Å. The Li(2)-O(3) bond length is 2.19 Å. The Li(2)-O(4) bond length is 2.18 Å. The Li(2)-O(5) bond length is 2.20 Å. The Li(2)-O(6) bond length is 2.16 Å. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. The Li(3)-O(3) bond length is 2.19 Å. The Li(3)-O(4) bond length is 2.23 Å. The Li(3)-O(5) bond length is 2.14 Å. The Li(3)-O(6) bond length is 2.35 Å. The Li(3)-O(7) bond length is 2.15 Å. The Li(3)-O(8) bond length is 2.09 Å. In the fourth Li site, Li(4) is bonded to one O(7), one O(8), two equivalent O(11), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. The Li(4)-O(7) bond length is 2.17 Å. The Li(4)-O(8) bond length is 2.29 Å. There is one shorter (2.17 Å) and one longer (2.22 Å) Li(4)-O(11) bond length. There is one shorter (2.12 Å) and one longer (2.22 Å) Li(4)-O(9) bond length. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. The V(1)-O(2) bond length is 2.06 Å. The V(1)-O(7) bond length is 2.03 Å. There is one shorter (2.04 Å) and one longer (2.10 Å) V(1)-O(4) bond length. There is one shorter (2.03 Å) and one longer (2.04 Å) V(1)-O(5) bond length. In the second V site, V(2) is bonded to one O(1), one O(3), one O(8), one O(9), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. The V(2)-O(1) bond length is 2.01 Å. The V(2)-O(3) bond length is 2.11 Å. The V(2)-O(8) bond length is 2.04 Å. The V(2)-O(9) bond length is 2.05 Å. There is one shorter (2.02 Å) and one longer (2.03 Å) V(2)-O(6) bond length. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(6)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. Both V(3)-O(3) bond lengths are 2.01 Å. Both V(3)-O(6) bond lengths are 2.01 Å. Both V(3)-O(8) bond lengths are 1.95 Å. In the fourth V site, V(4) is bonded to one O(10), one O(11), one O(2), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. The V(4)-O(10) bond length is 2.04 Å. The V(4)-O(11) bond length is 2.06 Å. The V(4)-O(2) bond length is 2.08 Å. The V(4)-O(4) bond length is 2.07 Å. The V(4)-O(5) bond length is 2.03 Å. The V(4)-O(7) bond length is 2.04 Å. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(11), one O(2), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The V(5)-O(1) bond length is 2.02 Å. The V(5)-O(10) bond length is 1.98 Å. The V(5)-O(11) bond length is 2.02 Å. The V(5)-O(2) bond length is 1.90 Å. The V(5)-O(7) bond length is 2.03 Å. The V(5)-O(9) bond length is 1.98 Å. In the sixth V site, V(6) is bonded to one O(1), one O(10), one O(11), one O(3), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. The V(6)-O(1) bond length is 2.04 Å. The V(6)-O(10) bond length is 2.09 Å. The V(6)-O(11) bond length is 1.99 Å. The V(6)-O(3) bond length is 2.02 Å. The V(6)-O(8) bond length is 2.11 Å. The V(6)-O(9) bond length is 2.06 Å. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one V(2), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(9)Li2V3 square pyramid, corners with two equivalent O(10)Li2V3 square pyramids, corners with three equivalent O(2)Li2V3 square pyramids,  an edgeedge with one O(4)Li3V3 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(6)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid, and  an edgeedge with one O(9)Li2V3 square pyramid. In the second O site, O(2) is bonded to one Li(1), one Li(2), one V(1), one V(4), and one V(5) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(9)Li2V3 square pyramid, corners with two equivalent O(10)Li2V3 square pyramids, corners with three equivalent O(1)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra, edges with two equivalent O(4)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid, and edges with two equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 3°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(3), and one V(6) atom to form OLi3V3 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(9)Li2V3 square pyramid, edges with two equivalent O(1)Li2V3 square pyramids, edges with two equivalent O(8)Li2V3 square pyramids, and edges with three equivalent O(6)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(3), one V(4), and two equivalent V(1) atoms to form OLi3V3 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(6)Li2V3 square pyramid, edges with two equivalent O(2)Li2V3 square pyramids, edges with two equivalent O(7)Li2V3 square pyramids, and edges with three equivalent O(5)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 1°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one V(4), and two equivalent V(1) atoms to form OLi2V3 square pyramids that share  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(6)Li2V3 square pyramids, corners with two equivalent O(7)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra, edges with three equivalent O(4)Li3V3 octahedra,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid, and edges with two equivalent O(2)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 7°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one V(3), and two equivalent V(2) atoms to form OLi2V3 square pyramids that share  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(5)Li2V3 square pyramids, corners with two equivalent O(9)Li2V3 square pyramids,  an edgeedge with one O(4)Li3V3 octahedra, edges with three equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(6)Li2V3 square pyramid, and edges with two equivalent O(8)Li2V3 square pyramids. In the seventh O site, O(7) is bonded to one Li(3), one Li(4), one V(1), one V(4), and one V(5) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(9)Li2V3 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(5)Li2V3 square pyramids, edges with two equivalent O(4)Li3V3 octahedra,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid, and  an edgeedge with one O(9)Li2V3 square pyramid. The corner-sharing octahedral tilt angles are 2°. In the eighth O site, O(8) is bonded to one Li(3), one Li(4), one V(2), one V(3), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(6)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(9)Li2V3 square pyramids, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(9)Li2V3 square pyramid, and edges with two equivalent O(6)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 5-8°. In the ninth O site, O(9) is bonded to two equivalent Li(4), one V(2), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(1)Li2V3 square pyramid,  a cornercorner with one O(2)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(6)Li2V3 square pyramids, corners with two equivalent O(8)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(9)Li2V3 square pyramid, and edges with two equivalent O(11)Li2V3 square pyramids. In the tenth O site, O(10) is bonded to two equivalent Li(1), one V(4), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(1)Li2V3 square pyramids, corners with two equivalent O(2)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid, and  an edgeedge with one O(9)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 4-6°. In the eleventh O site, O(11) is bonded to two equivalent Li(4), one V(4), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(10)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(7)Li2V3 square pyramids, corners with two equivalent O(9)Li2V3 square pyramids,  an edgeedge with one O(1)Li2V3 square pyramid,  an edgeedge with one O(10)Li2V3 square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(2)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid, and edges with two equivalent O(9)Li2V3 square pyramids. The corner-sharing octahedral tilt angles are 3°.