TlPS3 is Indium-derived structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and two PS3 clusters. In each PS3 cluster, P(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form edge-sharing PS4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to two equivalent P(1) atoms.
TlPS3 is Indium-derived structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and two PS3 clusters. In each PS3 cluster, P(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form edge-sharing PS4 tetrahedra. Both P(1)-S(1) bond lengths are 1.97 Å. Both P(1)-S(2) bond lengths are 2.14 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to two equivalent P(1) atoms.