ZnHg(SCN)4 crystallizes in the tetragonal I-4 space group. Hg(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a linear geometry to one Zn(1) and one C(1) atom. S(1) is bonded in a water-like geometry to one Hg(1) and one C(1) atom.
ZnHg(SCN)4 crystallizes in the tetragonal I-4 space group. Hg(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All Hg(1)-S(1) bond lengths are 2.62 Å. Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All Zn(1)-N(1) bond lengths are 1.97 Å. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.64 Å. N(1) is bonded in a linear geometry to one Zn(1) and one C(1) atom. S(1) is bonded in a water-like geometry to one Hg(1) and one C(1) atom.