PtPbF6 crystallizes in the trigonal R-3m space group. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Pb(1)F12 cuboctahedra and faces with two equivalent Pb(1)F12 cuboctahedra. Pb(1) is bonded to twelve equivalent F(1) atoms to form PbF12 cuboctahedra that share corners with six equivalent Pt(1)F6 octahedra, edges with six equivalent Pb(1)F12 cuboctahedra, and faces with two equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a single-bond geometry to one Pt(1) and two equivalent Pb(1) atoms.
PtPbF6 crystallizes in the trigonal R-3m space group. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Pb(1)F12 cuboctahedra and faces with two equivalent Pb(1)F12 cuboctahedra. All Pt(1)-F(1) bond lengths are 1.95 Å. Pb(1) is bonded to twelve equivalent F(1) atoms to form PbF12 cuboctahedra that share corners with six equivalent Pt(1)F6 octahedra, edges with six equivalent Pb(1)F12 cuboctahedra, and faces with two equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. There are six shorter (2.71 Å) and six longer (2.75 Å) Pb(1)-F(1) bond lengths. F(1) is bonded in a single-bond geometry to one Pt(1) and two equivalent Pb(1) atoms.