Ag2NO3Cl crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent O(2) and three equivalent Cl(1) atoms to form distorted AgCl3O4 pentagonal bipyramids that share corners with two equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, edges with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, and edges with three equivalent Ag(2)Cl2O4 pentagonal pyramids. In the second Ag site, Ag(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms to form distorted AgCl2O4 pentagonal pyramids that share corners with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, and edges with three equivalent Ag(1)Cl3O4 pentagonal bipyramids. N(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one N(1) atom. Cl(1) is bonded to two equivalent Ag(2) and three equivalent Ag(1) atoms to form a mixture of corner and edge-sharing ClAg5 trigonal bipyramids.
Ag2NO3Cl crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent O(2) and three equivalent Cl(1) atoms to form distorted AgCl3O4 pentagonal bipyramids that share corners with two equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, edges with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, and edges with three equivalent Ag(2)Cl2O4 pentagonal pyramids. There are two shorter (2.68 Å) and two longer (2.76 Å) Ag(1)-O(2) bond lengths. There is one shorter (2.78 Å) and two longer (2.83 Å) Ag(1)-Cl(1) bond lengths. In the second Ag site, Ag(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms to form distorted AgCl2O4 pentagonal pyramids that share corners with four equivalent Ag(1)Cl3O4 pentagonal bipyramids, corners with four equivalent Ag(2)Cl2O4 pentagonal pyramids, and edges with three equivalent Ag(1)Cl3O4 pentagonal bipyramids. Both Ag(2)-O(1) bond lengths are 2.66 Å. Both Ag(2)-O(2) bond lengths are 2.70 Å. There is one shorter (2.63 Å) and one longer (2.66 Å) Ag(2)-Cl(1) bond length. N(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. The N(1)-O(1) bond length is 1.27 Å. Both N(1)-O(2) bond lengths are 1.27 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one N(1) atom. Cl(1) is bonded to two equivalent Ag(2) and three equivalent Ag(1) atoms to form a mixture of corner and edge-sharing ClAg5 trigonal bipyramids.