NbCl6AsCl3PCl4 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules, four arsenic trichloride molecules, and four NbCl6 clusters. In each NbCl6 cluster, Nb(1) is bonded in an octahedral geometry to one Cl(8), one Cl(9), two equivalent Cl(4), and two equivalent Cl(7) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Nb(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Nb(1) atom. In the fourth Cl site, Cl(9) is bonded in a single-bond geometry to one Nb(1) atom.
NbCl6AsCl3PCl4 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules, four arsenic trichloride molecules, and four NbCl6 clusters. In each NbCl6 cluster, Nb(1) is bonded in an octahedral geometry to one Cl(8), one Cl(9), two equivalent Cl(4), and two equivalent Cl(7) atoms. The Nb(1)-Cl(8) bond length is 2.38 Å. The Nb(1)-Cl(9) bond length is 2.39 Å. Both Nb(1)-Cl(4) bond lengths are 2.38 Å. Both Nb(1)-Cl(7) bond lengths are 2.40 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one Nb(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Nb(1) atom. In the fourth Cl site, Cl(9) is bonded in a single-bond geometry to one Nb(1) atom.