KNSO3 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent O(1), and four equivalent O(2) atoms. N(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom.
KNSO3 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent O(1), and four equivalent O(2) atoms. Both K(1)-N(1) bond lengths are 3.16 Å. Both K(1)-O(1) bond lengths are 2.86 Å. There are two shorter (2.78 Å) and two longer (3.05 Å) K(1)-O(2) bond lengths. N(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom. The N(1)-S(1) bond length is 1.64 Å. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. The S(1)-O(1) bond length is 1.47 Å. Both S(1)-O(2) bond lengths are 1.47 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one S(1) atom.