XeOF5NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four XeOF5 clusters. In each XeOF5 cluster, Xe(1) is bonded in a pentagonal pyramidal geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. O(1) is bonded in a single-bond geometry to one Xe(1) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom.
XeOF5NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four XeOF5 clusters. In each XeOF5 cluster, Xe(1) is bonded in a pentagonal pyramidal geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The Xe(1)-O(1) bond length is 1.83 Å. The Xe(1)-F(1) bond length is 2.15 Å. The Xe(1)-F(2) bond length is 2.09 Å. The Xe(1)-F(3) bond length is 2.07 Å. The Xe(1)-F(4) bond length is 2.17 Å. The Xe(1)-F(5) bond length is 2.14 Å. O(1) is bonded in a single-bond geometry to one Xe(1) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom.