CaVF6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. F(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one V(1) atom.
CaVF6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Ca(1)-F(1) bond lengths are 2.26 Å. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All V(1)-F(1) bond lengths are 1.85 Å. F(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one V(1) atom.