Ba(AgO)2 crystallizes in the tetragonal I4_1/amd space group. Ba(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing BaO6 octahedra. The corner-sharing octahedral tilt angles are 4°. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent Ba(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OBa3Ag2 trigonal bipyramids.
Ba(AgO)2 crystallizes in the tetragonal I4_1/amd space group. Ba(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing BaO6 octahedra. The corner-sharing octahedral tilt angles are 4°. There are two shorter (2.62 Å) and four longer (2.93 Å) Ba(1)-O(1) bond lengths. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.08 Å. O(1) is bonded to three equivalent Ba(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OBa3Ag2 trigonal bipyramids.