AgTaS3 crystallizes in the orthorhombic Cmcm space group. Ta(1) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. Ag(1) is bonded in a 6-coordinate geometry to two equivalent S(2) and four equivalent S(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to three equivalent Ta(1) and two equivalent Ag(1) atoms. In the second S site, S(2) is bonded to two equivalent Ta(1) and two equivalent Ag(1) atoms to form corner-sharing STa2Ag2 tetrahedra.
AgTaS3 crystallizes in the orthorhombic Cmcm space group. Ta(1) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. Both Ta(1)-S(2) bond lengths are 2.54 Å. There are four shorter (2.53 Å) and two longer (2.66 Å) Ta(1)-S(1) bond lengths. Ag(1) is bonded in a 6-coordinate geometry to two equivalent S(2) and four equivalent S(1) atoms. Both Ag(1)-S(2) bond lengths are 2.43 Å. All Ag(1)-S(1) bond lengths are 3.02 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to three equivalent Ta(1) and two equivalent Ag(1) atoms. In the second S site, S(2) is bonded to two equivalent Ta(1) and two equivalent Ag(1) atoms to form corner-sharing STa2Ag2 tetrahedra.