Na3RuN2 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 9-coordinate geometry to one Na(1) and eight equivalent Na(2) atoms. In the second Na site, Na(2) is bonded in a 2-coordinate geometry to four equivalent Na(1) and two equivalent N(1) atoms. Ru(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) atoms. N(1) is bonded in a 4-coordinate geometry to two equivalent Na(2), one Ru(1), and one N(1) atom.
Na3RuN2 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 9-coordinate geometry to one Na(1) and eight equivalent Na(2) atoms. The Na(1)-Na(1) bond length is 3.76 Å. There are four shorter (3.73 Å) and four longer (3.97 Å) Na(1)-Na(2) bond lengths. In the second Na site, Na(2) is bonded in a 2-coordinate geometry to four equivalent Na(1) and two equivalent N(1) atoms. Both Na(2)-N(1) bond lengths are 2.77 Å. Ru(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) atoms. Both Ru(1)-N(1) bond lengths are 1.91 Å. N(1) is bonded in a 4-coordinate geometry to two equivalent Na(2), one Ru(1), and one N(1) atom. The N(1)-N(1) bond length is 1.25 Å.