Zr5AgIn3 crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 7-coordinate geometry to two equivalent Ag(1) and five equivalent In(1) atoms. In the second Zr site, Zr(2) is bonded in a 8-coordinate geometry to two equivalent Zr(2) and six equivalent In(1) atoms. Ag(1) is bonded to six equivalent Zr(1) atoms to form distorted face-sharing AgZr6 octahedra. In(1) is bonded in a 9-coordinate geometry to four equivalent Zr(2) and five equivalent Zr(1) atoms.
Zr5AgIn3 crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 7-coordinate geometry to two equivalent Ag(1) and five equivalent In(1) atoms. Both Zr(1)-Ag(1) bond lengths are 2.97 Å. There are a spread of Zr(1)-In(1) bond distances ranging from 2.95-3.06 Å. In the second Zr site, Zr(2) is bonded in a 8-coordinate geometry to two equivalent Zr(2) and six equivalent In(1) atoms. Both Zr(2)-Zr(2) bond lengths are 2.99 Å. All Zr(2)-In(1) bond lengths are 3.15 Å. Ag(1) is bonded to six equivalent Zr(1) atoms to form distorted face-sharing AgZr6 octahedra. In(1) is bonded in a 9-coordinate geometry to four equivalent Zr(2) and five equivalent Zr(1) atoms.