NiV crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form VV6Ni6 cuboctahedra that share corners with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent V(1)V6Ni6 cuboctahedra, and faces with twelve equivalent Ni(1)V6Ni6 cuboctahedra. Ni(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form NiV6Ni6 cuboctahedra that share corners with twelve equivalent Ni(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent Ni(1)V6Ni6 cuboctahedra, and faces with twelve equivalent V(1)V6Ni6 cuboctahedra.
NiV crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form VV6Ni6 cuboctahedra that share corners with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent V(1)V6Ni6 cuboctahedra, and faces with twelve equivalent Ni(1)V6Ni6 cuboctahedra. All V(1)-V(1) bond lengths are 2.55 Å. All V(1)-Ni(1) bond lengths are 2.59 Å. Ni(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form NiV6Ni6 cuboctahedra that share corners with twelve equivalent Ni(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent Ni(1)V6Ni6 cuboctahedra, and faces with twelve equivalent V(1)V6Ni6 cuboctahedra. All Ni(1)-Ni(1) bond lengths are 2.55 Å.