ReCl6(RuN5Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, two rhenium (iv) hexachloride molecules, and four RuN5Cl clusters. In each RuN5Cl cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(3), two equivalent N(1), and two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Ru(1) and one N(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Ru(1) and one Cl(5) atom. Cl(5) is bonded in a single-bond geometry to one N(3) atom.
ReCl6(RuN5Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, two rhenium (iv) hexachloride molecules, and four RuN5Cl clusters. In each RuN5Cl cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(3), two equivalent N(1), and two equivalent N(2) atoms. The Ru(1)-N(3) bond length is 1.82 Å. Both Ru(1)-N(1) bond lengths are 2.67 Å. Both Ru(1)-N(2) bond lengths are 1.71 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Ru(1) and one N(1) atom. The N(1)-N(1) bond length is 1.12 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Ru(1) and one Cl(5) atom. The N(3)-Cl(5) bond length is 1.60 Å. Cl(5) is bonded in a single-bond geometry to one N(3) atom.