LiLa4Ga2(FeO6)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded to one Fe(1), one O(12), one O(2), one O(8), and one O(9) atom to form distorted LiFeO4 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra,  a cornercorner with one Ga(2)O6 octahedra, and  an edgeedge with one Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-53°. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(9) atom. In the second La site, La(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(5), and one O(6) atom. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth La site, La(4) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 7-coordinate geometry to one Li(1), one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Ga(2)O6 octahedra and corners with four equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-31°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form GaO6 octahedra that share corners with four equivalent Fe(2)O6 octahedra and  a cornercorner with one Li(1)FeO4 tetrahedra. The corner-sharing octahedral tilt angles range from 25-31°. In the second Ga site, Ga(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)FeO4 tetrahedra, and  an edgeedge with one Li(1)FeO4 tetrahedra. The corner-sharing octahedral tilt angles range from 28-29°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Fe(2), and one Ga(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Fe(1), and one Ga(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one La(3), one La(4), one Fe(1), and one Ga(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Fe(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(4), one Fe(2), and one Ga(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Li(1), one La(3), one La(4), one Fe(1), and one Ga(2) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to one Li(1), one La(1), one La(3), one Fe(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal bipyramidal geometry to one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Fe(2), and one Ga(1) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Li(1), one La(1), one La(2), one La(4), one Fe(1), and one Ga(2) atom.
LiLa4Ga2(FeO6)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded to one Fe(1), one O(12), one O(2), one O(8), and one O(9) atom to form distorted LiFeO4 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra,  a cornercorner with one Ga(2)O6 octahedra, and  an edgeedge with one Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-53°. The Li(1)-Fe(1) bond length is 2.27 Å. The Li(1)-O(12) bond length is 1.91 Å. The Li(1)-O(2) bond length is 1.97 Å. The Li(1)-O(8) bond length is 1.98 Å. The Li(1)-O(9) bond length is 1.77 Å. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(9) atom. The La(1)-O(1) bond length is 2.40 Å. The La(1)-O(11) bond length is 2.46 Å. The La(1)-O(12) bond length is 2.84 Å. The La(1)-O(2) bond length is 2.50 Å. The La(1)-O(5) bond length is 2.43 Å. The La(1)-O(6) bond length is 2.65 Å. The La(1)-O(9) bond length is 2.62 Å. In the second La site, La(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(5), and one O(6) atom. The La(2)-O(1) bond length is 2.42 Å. The La(2)-O(10) bond length is 2.60 Å. The La(2)-O(11) bond length is 2.41 Å. The La(2)-O(12) bond length is 2.57 Å. The La(2)-O(2) bond length is 2.60 Å. The La(2)-O(5) bond length is 2.60 Å. The La(2)-O(6) bond length is 2.40 Å. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. The La(3)-O(10) bond length is 2.64 Å. The La(3)-O(11) bond length is 2.83 Å. The La(3)-O(3) bond length is 2.43 Å. The La(3)-O(4) bond length is 2.50 Å. The La(3)-O(5) bond length is 2.90 Å. The La(3)-O(7) bond length is 2.47 Å. The La(3)-O(8) bond length is 2.72 Å. The La(3)-O(9) bond length is 2.38 Å. In the fourth La site, La(4) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. The La(4)-O(10) bond length is 2.44 Å. The La(4)-O(12) bond length is 2.73 Å. The La(4)-O(3) bond length is 2.54 Å. The La(4)-O(4) bond length is 2.37 Å. The La(4)-O(6) bond length is 2.77 Å. The La(4)-O(7) bond length is 2.63 Å. The La(4)-O(8) bond length is 2.41 Å. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 7-coordinate geometry to one Li(1), one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom. The Fe(1)-O(12) bond length is 2.14 Å. The Fe(1)-O(2) bond length is 2.37 Å. The Fe(1)-O(4) bond length is 2.06 Å. The Fe(1)-O(5) bond length is 2.05 Å. The Fe(1)-O(8) bond length is 2.28 Å. The Fe(1)-O(9) bond length is 2.27 Å. In the second Fe site, Fe(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom to form FeO6 octahedra that share corners with two equivalent Ga(2)O6 octahedra and corners with four equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-31°. The Fe(2)-O(1) bond length is 2.08 Å. The Fe(2)-O(10) bond length is 2.12 Å. The Fe(2)-O(11) bond length is 2.10 Å. The Fe(2)-O(3) bond length is 2.07 Å. The Fe(2)-O(6) bond length is 2.06 Å. The Fe(2)-O(7) bond length is 1.98 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form GaO6 octahedra that share corners with four equivalent Fe(2)O6 octahedra and  a cornercorner with one Li(1)FeO4 tetrahedra. The corner-sharing octahedral tilt angles range from 25-31°. The Ga(1)-O(10) bond length is 2.07 Å. The Ga(1)-O(11) bond length is 2.12 Å. The Ga(1)-O(2) bond length is 2.01 Å. The Ga(1)-O(4) bond length is 1.99 Å. The Ga(1)-O(6) bond length is 2.10 Å. The Ga(1)-O(7) bond length is 2.00 Å. In the second Ga site, Ga(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)FeO4 tetrahedra, and  an edgeedge with one Li(1)FeO4 tetrahedra. The corner-sharing octahedral tilt angles range from 28-29°. The Ga(2)-O(1) bond length is 2.17 Å. The Ga(2)-O(12) bond length is 2.09 Å. The Ga(2)-O(3) bond length is 2.04 Å. The Ga(2)-O(5) bond length is 1.95 Å. The Ga(2)-O(8) bond length is 2.03 Å. The Ga(2)-O(9) bond length is 2.08 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Fe(2), and one Ga(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Fe(1), and one Ga(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one La(3), one La(4), one Fe(1), and one Ga(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Fe(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(4), one Fe(2), and one Ga(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Li(1), one La(3), one La(4), one Fe(1), and one Ga(2) atom. In the ninth O site, O(9) is bonded in a 1-coordinate geometry to one Li(1), one La(1), one La(3), one Fe(1), and one Ga(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal bipyramidal geometry to one La(2), one La(3), one La(4), one Fe(2), and one Ga(1) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Fe(2), and one Ga(1) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Li(1), one La(1), one La(2), one La(4), one Fe(1), and one Ga(2) atom.