Li3VO3F is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent F(1) atoms to form LiO4F2 octahedra that share corners with three equivalent Li(7)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(3)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 7-15°. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(4), two equivalent O(5), and one F(2) atom to form LiO5F octahedra that share corners with three equivalent Li(7)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(8)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-15°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent F(1) atoms to form LiO4F2 octahedra that share corners with two equivalent Li(4)O4F2 octahedra, corners with two equivalent Li(6)O4F2 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent V(1)O5F octahedra, edges with two equivalent V(2)O5F octahedra, and edges with four equivalent Li(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. In the fourth Li site, Li(4) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent F(2) atoms to form LiO4F2 octahedra that share corners with two equivalent Li(3)O4F2 octahedra, corners with two equivalent Li(8)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, edges with two equivalent V(1)O5F octahedra, and edges with four equivalent Li(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O4F2 octahedra, corners with two equivalent Li(8)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, edges with two equivalent V(1)O5F octahedra, and edges with four equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the sixth Li site, Li(6) is bonded to one O(1), one O(2), one O(5), one O(6), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(8)O4F2 octahedra, corners with four equivalent V(1)O5F octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the seventh Li site, Li(7) is bonded to one O(5), one O(6), two equivalent O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share corners with three equivalent Li(1)O4F2 octahedra, corners with three equivalent Li(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-15°. In the eighth Li site, Li(8) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent F(2) atoms to form LiO4F2 octahedra that share corners with two equivalent Li(4)O4F2 octahedra, corners with two equivalent Li(6)O4F2 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent V(1)O5F octahedra, edges with two equivalent V(2)O5F octahedra, and edges with four equivalent Li(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-13°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(6)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(5), two equivalent O(3), and one F(1) atom to form VO5F octahedra that share corners with three equivalent Li(1)O4F2 octahedra, corners with three equivalent Li(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 6-15°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Li(5), one Li(6), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one O(6)Li5V octahedra, corners with two equivalent O(1)Li4V2 octahedra, corners with two equivalent F(2)Li5V octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, edges with two equivalent O(6)Li5V octahedra, edges with three equivalent O(3)Li3V3 octahedra, and edges with three equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(2), one Li(5), one Li(6), one Li(8), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent O(2)Li4V2 octahedra, corners with two equivalent O(6)Li5V octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, edges with two equivalent F(2)Li5V octahedra, edges with three equivalent O(3)Li3V3 octahedra, and edges with three equivalent O(5)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(5), one V(1), and two equivalent V(2) atoms to form OLi3V3 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li5V octahedra, corners with two equivalent O(5)Li5V octahedra, corners with two equivalent F(1)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one O(6)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with three equivalent O(1)Li4V2 octahedra, and edges with three equivalent O(2)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), two equivalent Li(7), and one V(1) atom to form OLi5V octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li5V octahedra, corners with two equivalent O(5)Li5V octahedra, corners with two equivalent F(1)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with three equivalent O(6)Li5V octahedra, and edges with three equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fifth O site, O(5) is bonded to one Li(6), one Li(7), one Li(8), two equivalent Li(2), and one V(2) atom to form OLi5V octahedra that share  a cornercorner with one O(5)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra, corners with two equivalent O(3)Li3V3 octahedra, corners with two equivalent O(4)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one O(6)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with three equivalent O(2)Li4V2 octahedra, and edges with three equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(4), one Li(6), one Li(7), and one V(1) atom to form OLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent O(2)Li4V2 octahedra, corners with two equivalent O(6)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(5)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, edges with two equivalent F(2)Li5V octahedra, edges with three equivalent O(4)Li5V octahedra, and edges with three equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-15°. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(3), one Li(6), one Li(7), two equivalent Li(1), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(5)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra, corners with two equivalent O(3)Li3V3 octahedra, corners with two equivalent O(4)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with three equivalent O(1)Li4V2 octahedra, and edges with three equivalent O(6)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the second F site, F(2) is bonded to one Li(2), one Li(4), one Li(6), one Li(7), one Li(8), and one V(1) atom to form FLi5V octahedra that share  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one O(6)Li5V octahedra, corners with two equivalent O(1)Li4V2 octahedra, corners with two equivalent F(2)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, edges with two equivalent O(6)Li5V octahedra, edges with three equivalent O(4)Li5V octahedra, and edges with three equivalent O(5)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-9°.
Li3VO3F is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one O(4), one O(6), and two equivalent F(1) atoms to form LiO4F2 octahedra that share corners with three equivalent Li(7)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(3)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 7-15°. The Li(1)-O(1) bond length is 2.20 Å. The Li(1)-O(3) bond length is 2.11 Å. The Li(1)-O(4) bond length is 2.00 Å. The Li(1)-O(6) bond length is 2.05 Å. There is one shorter (2.12 Å) and one longer (2.20 Å) Li(1)-F(1) bond length. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(4), two equivalent O(5), and one F(2) atom to form LiO5F octahedra that share corners with three equivalent Li(7)O4F2 octahedra, corners with three equivalent V(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(8)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-15°. The Li(2)-O(2) bond length is 2.14 Å. The Li(2)-O(3) bond length is 2.37 Å. The Li(2)-O(4) bond length is 1.98 Å. There is one shorter (2.13 Å) and one longer (2.14 Å) Li(2)-O(5) bond length. The Li(2)-F(2) bond length is 2.22 Å. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent F(1) atoms to form LiO4F2 octahedra that share corners with two equivalent Li(4)O4F2 octahedra, corners with two equivalent Li(6)O4F2 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent V(1)O5F octahedra, edges with two equivalent V(2)O5F octahedra, and edges with four equivalent Li(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. Both Li(3)-O(1) bond lengths are 2.05 Å. Both Li(3)-O(6) bond lengths are 2.11 Å. Both Li(3)-F(1) bond lengths are 2.17 Å. In the fourth Li site, Li(4) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent F(2) atoms to form LiO4F2 octahedra that share corners with two equivalent Li(3)O4F2 octahedra, corners with two equivalent Li(8)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, edges with two equivalent V(1)O5F octahedra, and edges with four equivalent Li(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. Both Li(4)-O(4) bond lengths are 2.27 Å. Both Li(4)-O(6) bond lengths are 2.07 Å. Both Li(4)-F(2) bond lengths are 2.04 Å. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O4F2 octahedra, corners with two equivalent Li(8)O4F2 octahedra, corners with two equivalent V(1)O5F octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, edges with two equivalent V(1)O5F octahedra, and edges with four equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 6-13°. Both Li(5)-O(1) bond lengths are 2.11 Å. Both Li(5)-O(2) bond lengths are 2.15 Å. Both Li(5)-O(3) bond lengths are 2.16 Å. In the sixth Li site, Li(6) is bonded to one O(1), one O(2), one O(5), one O(6), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O4F2 octahedra,  a cornercorner with one Li(8)O4F2 octahedra, corners with four equivalent V(1)O5F octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Li(6)-O(1) bond length is 2.13 Å. The Li(6)-O(2) bond length is 2.39 Å. The Li(6)-O(5) bond length is 2.07 Å. The Li(6)-O(6) bond length is 2.12 Å. The Li(6)-F(1) bond length is 2.04 Å. The Li(6)-F(2) bond length is 2.08 Å. In the seventh Li site, Li(7) is bonded to one O(5), one O(6), two equivalent O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share corners with three equivalent Li(1)O4F2 octahedra, corners with three equivalent Li(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(6)O4F2 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-15°. The Li(7)-O(5) bond length is 2.16 Å. The Li(7)-O(6) bond length is 2.13 Å. There is one shorter (2.02 Å) and one longer (2.06 Å) Li(7)-O(4) bond length. The Li(7)-F(1) bond length is 2.22 Å. The Li(7)-F(2) bond length is 2.14 Å. In the eighth Li site, Li(8) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent F(2) atoms to form LiO4F2 octahedra that share corners with two equivalent Li(4)O4F2 octahedra, corners with two equivalent Li(6)O4F2 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent V(1)O5F octahedra, edges with two equivalent V(2)O5F octahedra, and edges with four equivalent Li(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 1-13°. Both Li(8)-O(2) bond lengths are 2.04 Å. Both Li(8)-O(5) bond lengths are 2.17 Å. Both Li(8)-F(2) bond lengths are 2.11 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(4)O4F2 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(6)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(4)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(7)O4F2 octahedra, edges with two equivalent Li(2)O5F octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The V(1)-O(1) bond length is 1.92 Å. The V(1)-O(2) bond length is 2.02 Å. The V(1)-O(3) bond length is 2.15 Å. The V(1)-O(4) bond length is 1.86 Å. The V(1)-O(6) bond length is 1.81 Å. The V(1)-F(2) bond length is 2.22 Å. In the second V site, V(2) is bonded to one O(1), one O(2), one O(5), two equivalent O(3), and one F(1) atom to form VO5F octahedra that share corners with three equivalent Li(1)O4F2 octahedra, corners with three equivalent Li(2)O5F octahedra,  an edgeedge with one Li(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F2 octahedra,  an edgeedge with one Li(7)O4F2 octahedra,  an edgeedge with one Li(8)O4F2 octahedra,  an edgeedge with one Li(2)O5F octahedra,  an edgeedge with one V(2)O5F octahedra, edges with two equivalent Li(6)O4F2 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 6-15°. The V(2)-O(1) bond length is 2.05 Å. The V(2)-O(2) bond length is 1.95 Å. The V(2)-O(5) bond length is 1.77 Å. There is one shorter (1.94 Å) and one longer (2.09 Å) V(2)-O(3) bond length. The V(2)-F(1) bond length is 2.10 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Li(5), one Li(6), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one O(6)Li5V octahedra, corners with two equivalent O(1)Li4V2 octahedra, corners with two equivalent F(2)Li5V octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, edges with two equivalent O(6)Li5V octahedra, edges with three equivalent O(3)Li3V3 octahedra, and edges with three equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(2), one Li(5), one Li(6), one Li(8), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent O(2)Li4V2 octahedra, corners with two equivalent O(6)Li5V octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, edges with two equivalent F(2)Li5V octahedra, edges with three equivalent O(3)Li3V3 octahedra, and edges with three equivalent O(5)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(5), one V(1), and two equivalent V(2) atoms to form OLi3V3 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li5V octahedra, corners with two equivalent O(5)Li5V octahedra, corners with two equivalent F(1)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one O(6)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with three equivalent O(1)Li4V2 octahedra, and edges with three equivalent O(2)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), two equivalent Li(7), and one V(1) atom to form OLi5V octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li5V octahedra, corners with two equivalent O(5)Li5V octahedra, corners with two equivalent F(1)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with three equivalent O(6)Li5V octahedra, and edges with three equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fifth O site, O(5) is bonded to one Li(6), one Li(7), one Li(8), two equivalent Li(2), and one V(2) atom to form OLi5V octahedra that share  a cornercorner with one O(5)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra, corners with two equivalent O(3)Li3V3 octahedra, corners with two equivalent O(4)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(1)Li4V2 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one O(6)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with three equivalent O(2)Li4V2 octahedra, and edges with three equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(4), one Li(6), one Li(7), and one V(1) atom to form OLi5V octahedra that share  a cornercorner with one O(1)Li4V2 octahedra,  a cornercorner with one F(2)Li5V octahedra, corners with two equivalent O(2)Li4V2 octahedra, corners with two equivalent O(6)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(5)Li5V octahedra, edges with two equivalent O(1)Li4V2 octahedra, edges with two equivalent F(2)Li5V octahedra, edges with three equivalent O(4)Li5V octahedra, and edges with three equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-15°. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(3), one Li(6), one Li(7), two equivalent Li(1), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(5)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra, corners with two equivalent O(3)Li3V3 octahedra, corners with two equivalent O(4)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(2)Li4V2 octahedra,  an edgeedge with one O(4)Li5V octahedra,  an edgeedge with one O(5)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with three equivalent O(1)Li4V2 octahedra, and edges with three equivalent O(6)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the second F site, F(2) is bonded to one Li(2), one Li(4), one Li(6), one Li(7), one Li(8), and one V(1) atom to form FLi5V octahedra that share  a cornercorner with one O(2)Li4V2 octahedra,  a cornercorner with one O(6)Li5V octahedra, corners with two equivalent O(1)Li4V2 octahedra, corners with two equivalent F(2)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with two equivalent O(2)Li4V2 octahedra, edges with two equivalent O(6)Li5V octahedra, edges with three equivalent O(4)Li5V octahedra, and edges with three equivalent O(5)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-9°.