KTiO2F is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. K(1) is bonded to eight equivalent O(1) and four equivalent F(1) atoms to form KO8F4 cuboctahedra that share corners with twelve equivalent K(1)O8F4 cuboctahedra, faces with six equivalent K(1)O8F4 cuboctahedra, and faces with eight equivalent Ti(1)O4F2 octahedra. Ti(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form TiO4F2 octahedra that share corners with six equivalent Ti(1)O4F2 octahedra and faces with eight equivalent K(1)O8F4 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent K(1) and two equivalent Ti(1) atoms. F(1) is bonded to four equivalent K(1) and two equivalent Ti(1) atoms to form a mixture of corner and edge-sharing FK4Ti2 octahedra. The corner-sharing octahedra are not tilted.
KTiO2F is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. K(1) is bonded to eight equivalent O(1) and four equivalent F(1) atoms to form KO8F4 cuboctahedra that share corners with twelve equivalent K(1)O8F4 cuboctahedra, faces with six equivalent K(1)O8F4 cuboctahedra, and faces with eight equivalent Ti(1)O4F2 octahedra. All K(1)-O(1) bond lengths are 2.85 Å. All K(1)-F(1) bond lengths are 2.74 Å. Ti(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form TiO4F2 octahedra that share corners with six equivalent Ti(1)O4F2 octahedra and faces with eight equivalent K(1)O8F4 cuboctahedra. The corner-sharing octahedra are not tilted. All Ti(1)-O(1) bond lengths are 1.94 Å. Both Ti(1)-F(1) bond lengths are 2.09 Å. O(1) is bonded in a distorted linear geometry to four equivalent K(1) and two equivalent Ti(1) atoms. F(1) is bonded to four equivalent K(1) and two equivalent Ti(1) atoms to form a mixture of corner and edge-sharing FK4Ti2 octahedra. The corner-sharing octahedra are not tilted.