Nd2Ge2In crystallizes in the tetragonal P4/mbm space group. Nd(1) is bonded in a 10-coordinate geometry to four equivalent In(1) and six equivalent Ge(1) atoms. In(1) is bonded to eight equivalent Nd(1) and four equivalent Ge(1) atoms to form a mixture of face and corner-sharing InNd8Ge4 cuboctahedra. Ge(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1), two equivalent In(1), and one Ge(1) atom.
Nd2Ge2In crystallizes in the tetragonal P4/mbm space group. Nd(1) is bonded in a 10-coordinate geometry to four equivalent In(1) and six equivalent Ge(1) atoms. All Nd(1)-In(1) bond lengths are 3.52 Å. There are two shorter (3.07 Å) and four longer (3.16 Å) Nd(1)-Ge(1) bond lengths. In(1) is bonded to eight equivalent Nd(1) and four equivalent Ge(1) atoms to form a mixture of face and corner-sharing InNd8Ge4 cuboctahedra. All In(1)-Ge(1) bond lengths are 3.03 Å. Ge(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1), two equivalent In(1), and one Ge(1) atom. The Ge(1)-Ge(1) bond length is 2.50 Å.