PtH8(N4O)2 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PtH8(N4O)2 clusters. Pt(1) is bonded in an octahedral geometry to one N(1), one N(4), one N(7), one N(8), one O(1), and one O(2) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. In the eighth N site, N(8) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(4), one H(5), and one H(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pt(1) and one H(8) atom.
PtH8(N4O)2 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PtH8(N4O)2 clusters. Pt(1) is bonded in an octahedral geometry to one N(1), one N(4), one N(7), one N(8), one O(1), and one O(2) atom. The Pt(1)-N(1) bond length is 2.06 Å. The Pt(1)-N(4) bond length is 2.09 Å. The Pt(1)-N(7) bond length is 2.07 Å. The Pt(1)-N(8) bond length is 2.07 Å. The Pt(1)-O(1) bond length is 2.04 Å. The Pt(1)-O(2) bond length is 2.05 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(2) atom. The N(1)-N(2) bond length is 1.21 Å. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.17 Å. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(5) atom. The N(4)-N(5) bond length is 1.22 Å. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.16 Å. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. The N(7)-H(1) bond length is 1.03 Å. The N(7)-H(2) bond length is 1.03 Å. The N(7)-H(3) bond length is 1.03 Å. In the eighth N site, N(8) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(4), one H(5), and one H(6) atom. The N(8)-H(4) bond length is 1.03 Å. The N(8)-H(5) bond length is 1.05 Å. The N(8)-H(6) bond length is 1.04 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(1) atom. The H(7)-O(1) bond length is 0.98 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(2) atom. The H(8)-O(2) bond length is 0.98 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pt(1) and one H(8) atom.