NdSI is Baddeleyite-derived structured and crystallizes in the orthorhombic Pbca space group. Nd(1) is bonded in a 7-coordinate geometry to four equivalent S(1) and three equivalent I(1) atoms. S(1) is bonded to four equivalent Nd(1) atoms to form a mixture of edge and corner-sharing SNd4 tetrahedra. I(1) is bonded in a distorted trigonal planar geometry to three equivalent Nd(1) atoms.
NdSI is Baddeleyite-derived structured and crystallizes in the orthorhombic Pbca space group. Nd(1) is bonded in a 7-coordinate geometry to four equivalent S(1) and three equivalent I(1) atoms. There are a spread of Nd(1)-S(1) bond distances ranging from 2.83-2.85 Å. There are a spread of Nd(1)-I(1) bond distances ranging from 3.26-3.43 Å. S(1) is bonded to four equivalent Nd(1) atoms to form a mixture of edge and corner-sharing SNd4 tetrahedra. I(1) is bonded in a distorted trigonal planar geometry to three equivalent Nd(1) atoms.