RbLiMnS2 crystallizes in the tetragonal I-4m2 space group. Rb(1) is bonded in a body-centered cubic geometry to eight equivalent S(1) atoms. Li(1) is bonded to four equivalent S(1) atoms to form distorted LiS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and edges with four equivalent Mn(1)S4 tetrahedra. Mn(1) is bonded to four equivalent S(1) atoms to form distorted MnS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra and edges with four equivalent Li(1)S4 tetrahedra. S(1) is bonded in a 4-coordinate geometry to four equivalent Rb(1), two equivalent Li(1), and two equivalent Mn(1) atoms.
RbLiMnS2 crystallizes in the tetragonal I-4m2 space group. Rb(1) is bonded in a body-centered cubic geometry to eight equivalent S(1) atoms. All Rb(1)-S(1) bond lengths are 3.49 Å. Li(1) is bonded to four equivalent S(1) atoms to form distorted LiS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and edges with four equivalent Mn(1)S4 tetrahedra. All Li(1)-S(1) bond lengths are 2.27 Å. Mn(1) is bonded to four equivalent S(1) atoms to form distorted MnS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra and edges with four equivalent Li(1)S4 tetrahedra. All Mn(1)-S(1) bond lengths are 2.27 Å. S(1) is bonded in a 4-coordinate geometry to four equivalent Rb(1), two equivalent Li(1), and two equivalent Mn(1) atoms.