CsRbO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Cs(1) is bonded to six equivalent O(1) atoms to form CsO6 octahedra that share corners with six equivalent Cs(1)O6 octahedra and faces with eight equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Rb(1) is bonded to twelve equivalent O(1) atoms to form RbO12 cuboctahedra that share corners with twelve equivalent Rb(1)O12 cuboctahedra, faces with six equivalent Rb(1)O12 cuboctahedra, and faces with eight equivalent Cs(1)O6 octahedra. O(1) is bonded in a distorted linear geometry to two equivalent Cs(1) and four equivalent Rb(1) atoms.
CsRbO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Cs(1) is bonded to six equivalent O(1) atoms to form CsO6 octahedra that share corners with six equivalent Cs(1)O6 octahedra and faces with eight equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Cs(1)-O(1) bond lengths are 2.28 Å. Rb(1) is bonded to twelve equivalent O(1) atoms to form RbO12 cuboctahedra that share corners with twelve equivalent Rb(1)O12 cuboctahedra, faces with six equivalent Rb(1)O12 cuboctahedra, and faces with eight equivalent Cs(1)O6 octahedra. All Rb(1)-O(1) bond lengths are 3.22 Å. O(1) is bonded in a distorted linear geometry to two equivalent Cs(1) and four equivalent Rb(1) atoms.