InH12(N2Cl)2InH6(NCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one InH12(N2Cl)2 cluster and one InH6(NCl2)2 cluster. In the InH12(N2Cl)2 cluster, In(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent Cl(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(1), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(2), one H(7), and one H(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. Cl(2) is bonded in a single-bond geometry to one In(1) atom. In the InH6(NCl2)2 cluster, In(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent Cl(1), and two equivalent Cl(3) atoms. N(3) is bonded in a distorted trigonal non-coplanar geometry to one In(2), one H(3), one H(6), and one H(8) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one In(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one In(2) atom.
InH12(N2Cl)2InH6(NCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one InH12(N2Cl)2 cluster and one InH6(NCl2)2 cluster. In the InH12(N2Cl)2 cluster, In(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent Cl(2) atoms. Both In(1)-N(1) bond lengths are 2.27 Å. Both In(1)-N(2) bond lengths are 2.28 Å. Both In(1)-Cl(2) bond lengths are 2.57 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(1), one H(4), and one H(5) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(4) bond length is 1.03 Å. The N(1)-H(5) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(2), one H(7), and one H(9) atom. The N(2)-H(2) bond length is 1.03 Å. The N(2)-H(7) bond length is 1.03 Å. The N(2)-H(9) bond length is 1.02 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. Cl(2) is bonded in a single-bond geometry to one In(1) atom. In the InH6(NCl2)2 cluster, In(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent Cl(1), and two equivalent Cl(3) atoms. Both In(2)-N(3) bond lengths are 2.24 Å. Both In(2)-Cl(1) bond lengths are 2.60 Å. Both In(2)-Cl(3) bond lengths are 2.58 Å. N(3) is bonded in a distorted trigonal non-coplanar geometry to one In(2), one H(3), one H(6), and one H(8) atom. The N(3)-H(3) bond length is 1.02 Å. The N(3)-H(6) bond length is 1.03 Å. The N(3)-H(8) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one In(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one In(2) atom.