AgPbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share corners with nine equivalent Pb(1)O6 octahedra, edges with three equivalent Ag(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with nine equivalent Ag(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. O(1) is bonded to two equivalent Ag(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OAg2Pb2 trigonal pyramids.
AgPbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share corners with nine equivalent Pb(1)O6 octahedra, edges with three equivalent Ag(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. There are three shorter (2.28 Å) and three longer (2.39 Å) Ag(1)-O(1) bond lengths. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with nine equivalent Ag(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. There are three shorter (2.21 Å) and three longer (2.31 Å) Pb(1)-O(1) bond lengths. O(1) is bonded to two equivalent Ag(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OAg2Pb2 trigonal pyramids.