NaAsF6 crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent As(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. As(1) is bonded to six equivalent F(1) atoms to form AsF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one As(1) atom.
NaAsF6 crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent As(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Na(1)-F(1) bond lengths are 2.28 Å. As(1) is bonded to six equivalent F(1) atoms to form AsF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All As(1)-F(1) bond lengths are 1.74 Å. F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one As(1) atom.