XeF2IF5 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of four xenon;dihydrofluoride molecules and four IF5 clusters. In each IF5 cluster, I(1) is bonded in a square pyramidal geometry to one F(2) and four equivalent F(3) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one I(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one I(1) atom.
XeF2IF5 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of four xenon;dihydrofluoride molecules and four IF5 clusters. In each IF5 cluster, I(1) is bonded in a square pyramidal geometry to one F(2) and four equivalent F(3) atoms. The I(1)-F(2) bond length is 1.84 Å. All I(1)-F(3) bond lengths are 1.90 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one I(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one I(1) atom.