CsRuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Cs(1) is bonded to twelve equivalent O(1) atoms to form CsO12 cuboctahedra that share corners with twelve equivalent Cs(1)O12 cuboctahedra, faces with six equivalent Cs(1)O12 cuboctahedra, and faces with eight equivalent Ru(1)O6 octahedra. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Cs(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Cs(1) and two equivalent Ru(1) atoms to form a mixture of distorted corner, face, and edge-sharing OCs4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
CsRuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Cs(1) is bonded to twelve equivalent O(1) atoms to form CsO12 cuboctahedra that share corners with twelve equivalent Cs(1)O12 cuboctahedra, faces with six equivalent Cs(1)O12 cuboctahedra, and faces with eight equivalent Ru(1)O6 octahedra. All Cs(1)-O(1) bond lengths are 2.88 Å. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Cs(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ru(1)-O(1) bond lengths are 2.04 Å. O(1) is bonded to four equivalent Cs(1) and two equivalent Ru(1) atoms to form a mixture of distorted corner, face, and edge-sharing OCs4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.