UC4S2(NO5)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four UC4S2(NO5)2 clusters. U(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one C(2) and one S(1) atom. In the second C site, C(2) is bonded in a 2-coordinate geometry to one C(1) and one S(1) atom. N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(5) atom. S(1) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom.
UC4S2(NO5)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four UC4S2(NO5)2 clusters. U(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both U(1)-O(1) bond lengths are 1.79 Å. Both U(1)-O(2) bond lengths are 2.48 Å. Both U(1)-O(3) bond lengths are 2.47 Å. Both U(1)-O(4) bond lengths are 2.60 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one C(2) and one S(1) atom. The C(1)-C(2) bond length is 1.61 Å. The C(1)-S(1) bond length is 1.68 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one C(1) and one S(1) atom. The C(2)-S(1) bond length is 1.64 Å. N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(5) atom. The N(1)-O(2) bond length is 1.30 Å. The N(1)-O(3) bond length is 1.29 Å. The N(1)-O(5) bond length is 1.22 Å. S(1) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one O(4) atom. The S(1)-O(4) bond length is 1.47 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom.