IMn(CO)5 is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four IMn(CO)5 clusters. Mn(1) is bonded in a distorted square pyramidal geometry to one C(1), four equivalent C(2), and one I(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. I(1) is bonded in a single-bond geometry to one Mn(1) atom.
IMn(CO)5 is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four IMn(CO)5 clusters. Mn(1) is bonded in a distorted square pyramidal geometry to one C(1), four equivalent C(2), and one I(1) atom. The Mn(1)-C(1) bond length is 1.84 Å. All Mn(1)-C(2) bond lengths are 1.88 Å. The Mn(1)-I(1) bond length is 2.76 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. The C(1)-O(1) bond length is 1.15 Å. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. The C(2)-O(2) bond length is 1.15 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. I(1) is bonded in a single-bond geometry to one Mn(1) atom.