AgFAuF6 crystallizes in the orthorhombic Pnma space group. Au(1) is bonded to one F(2), one F(5), two equivalent F(3), and two equivalent F(4) atoms to form AuF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. Ag(1) is bonded to one F(2), two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent Au(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one Au(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 34-46°. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the fourth F site, F(3) is bonded in a water-like geometry to one Au(1) and one Ag(1) atom. In the fifth F site, F(4) is bonded in a bent 150 degrees geometry to one Au(1) and one Ag(1) atom.
AgFAuF6 crystallizes in the orthorhombic Pnma space group. Au(1) is bonded to one F(2), one F(5), two equivalent F(3), and two equivalent F(4) atoms to form AuF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. The Au(1)-F(2) bond length is 1.95 Å. The Au(1)-F(5) bond length is 1.90 Å. Both Au(1)-F(3) bond lengths are 1.93 Å. Both Au(1)-F(4) bond lengths are 1.93 Å. Ag(1) is bonded to one F(2), two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent Au(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one Au(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 34-46°. The Ag(1)-F(2) bond length is 2.33 Å. Both Ag(1)-F(1) bond lengths are 2.01 Å. Both Ag(1)-F(3) bond lengths are 2.40 Å. Both Ag(1)-F(4) bond lengths are 2.30 Å. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the fourth F site, F(3) is bonded in a water-like geometry to one Au(1) and one Ag(1) atom. In the fifth F site, F(4) is bonded in a bent 150 degrees geometry to one Au(1) and one Ag(1) atom.