CsVWO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form distorted CsO6 octahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 69-73°. V(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-73°. W(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-73°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one W(1) atom.
CsVWO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form distorted CsO6 octahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 69-73°. The Cs(1)-O(1) bond length is 3.19 Å. The Cs(1)-O(2) bond length is 3.27 Å. All Cs(1)-O(3) bond lengths are 3.22 Å. V(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-73°. Both V(1)-O(2) bond lengths are 1.86 Å. All V(1)-O(3) bond lengths are 1.90 Å. W(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-73°. Both W(1)-O(1) bond lengths are 1.96 Å. All W(1)-O(3) bond lengths are 1.92 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one W(1) atom.