LiRhNiF6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form LiF6 octahedra that share corners with four equivalent Rh(1)F6 octahedra, corners with four equivalent Ni(1)F6 octahedra,  an edgeedge with one Rh(1)F6 octahedra, and  an edgeedge with one Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. Rh(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form RhF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Ni(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. Ni(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form NiF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Rh(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Ni(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Ni(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Ni(1) atom.
LiRhNiF6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form LiF6 octahedra that share corners with four equivalent Rh(1)F6 octahedra, corners with four equivalent Ni(1)F6 octahedra,  an edgeedge with one Rh(1)F6 octahedra, and  an edgeedge with one Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. Both Li(1)-F(1) bond lengths are 2.04 Å. Both Li(1)-F(2) bond lengths are 2.04 Å. Both Li(1)-F(3) bond lengths are 2.03 Å. Rh(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form RhF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Ni(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. Both Rh(1)-F(1) bond lengths are 2.02 Å. Both Rh(1)-F(2) bond lengths are 2.02 Å. Both Rh(1)-F(3) bond lengths are 2.01 Å. Ni(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form NiF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Rh(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Both Ni(1)-F(1) bond lengths are 2.04 Å. Both Ni(1)-F(2) bond lengths are 2.02 Å. Both Ni(1)-F(3) bond lengths are 2.02 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Ni(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Ni(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Ni(1) atom.