PdAg2Cl4 crystallizes in the orthorhombic Cmce space group. Pd(1) is bonded in a square co-planar geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. Ag(1) is bonded to two equivalent Cl(1) and four equivalent Cl(2) atoms to form a mixture of distorted corner and edge-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 7-34°. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1) and two equivalent Ag(1) atoms. In the second Cl site, Cl(2) is bonded to one Pd(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClAg4Pd square pyramids.
PdAg2Cl4 crystallizes in the orthorhombic Cmce space group. Pd(1) is bonded in a square co-planar geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. Both Pd(1)-Cl(1) bond lengths are 2.32 Å. Both Pd(1)-Cl(2) bond lengths are 2.32 Å. Ag(1) is bonded to two equivalent Cl(1) and four equivalent Cl(2) atoms to form a mixture of distorted corner and edge-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 7-34°. Both Ag(1)-Cl(1) bond lengths are 2.62 Å. There are two shorter (2.72 Å) and two longer (3.06 Å) Ag(1)-Cl(2) bond lengths. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1) and two equivalent Ag(1) atoms. In the second Cl site, Cl(2) is bonded to one Pd(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClAg4Pd square pyramids.