KIn(WO3)2 crystallizes in the cubic Fm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent In(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent In(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to twelve equivalent O(1) atoms to form distorted InO12 cuboctahedra that share corners with twelve equivalent In(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. O(1) is bonded in a distorted linear geometry to two equivalent K(1), two equivalent W(1), and two equivalent In(1) atoms.
KIn(WO3)2 crystallizes in the cubic Fm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent In(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.86 Å. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent In(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All W(1)-O(1) bond lengths are 2.02 Å. In(1) is bonded to twelve equivalent O(1) atoms to form distorted InO12 cuboctahedra that share corners with twelve equivalent In(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. All In(1)-O(1) bond lengths are 2.86 Å. O(1) is bonded in a distorted linear geometry to two equivalent K(1), two equivalent W(1), and two equivalent In(1) atoms.