MnOF is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(5), one O(6), one F(3), one F(5), and one F(8) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-59°. In the second Mn site, Mn(2) is bonded to one O(1), one O(4), one O(5), one F(4), one F(5), and one F(7) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. In the third Mn site, Mn(3) is bonded to one O(3), one O(4), one O(7), one F(2), one F(4), and one F(6) atom to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. In the fourth Mn site, Mn(4) is bonded to one O(6), one O(7), one O(8), one F(1), one F(2), and one F(3) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(8), one F(2), one F(4), and one F(8) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 42-57°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(4), one O(8), one F(1), one F(5), and one F(6) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. In the seventh Mn site, Mn(7) is bonded to one O(3), one O(5), one O(6), one F(1), one F(6), and one F(7) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(3), one O(7), one F(3), one F(7), and one F(8) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(7), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(7) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(7), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(8) atom.
MnOF is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(5), one O(6), one F(3), one F(5), and one F(8) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-59°. The Mn(1)-O(2) bond length is 1.89 Å. The Mn(1)-O(5) bond length is 1.92 Å. The Mn(1)-O(6) bond length is 1.95 Å. The Mn(1)-F(3) bond length is 2.09 Å. The Mn(1)-F(5) bond length is 2.15 Å. The Mn(1)-F(8) bond length is 2.00 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(4), one O(5), one F(4), one F(5), and one F(7) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. The Mn(2)-O(1) bond length is 1.86 Å. The Mn(2)-O(4) bond length is 1.87 Å. The Mn(2)-O(5) bond length is 1.92 Å. The Mn(2)-F(4) bond length is 2.16 Å. The Mn(2)-F(5) bond length is 2.01 Å. The Mn(2)-F(7) bond length is 1.96 Å. In the third Mn site, Mn(3) is bonded to one O(3), one O(4), one O(7), one F(2), one F(4), and one F(6) atom to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. The Mn(3)-O(3) bond length is 1.93 Å. The Mn(3)-O(4) bond length is 1.97 Å. The Mn(3)-O(7) bond length is 1.99 Å. The Mn(3)-F(2) bond length is 2.13 Å. The Mn(3)-F(4) bond length is 2.14 Å. The Mn(3)-F(6) bond length is 2.13 Å. In the fourth Mn site, Mn(4) is bonded to one O(6), one O(7), one O(8), one F(1), one F(2), and one F(3) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. The Mn(4)-O(6) bond length is 1.87 Å. The Mn(4)-O(7) bond length is 1.88 Å. The Mn(4)-O(8) bond length is 1.90 Å. The Mn(4)-F(1) bond length is 1.99 Å. The Mn(4)-F(2) bond length is 1.97 Å. The Mn(4)-F(3) bond length is 2.07 Å. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(8), one F(2), one F(4), and one F(8) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 42-57°. The Mn(5)-O(1) bond length is 1.92 Å. The Mn(5)-O(2) bond length is 1.93 Å. The Mn(5)-O(8) bond length is 1.92 Å. The Mn(5)-F(2) bond length is 2.10 Å. The Mn(5)-F(4) bond length is 2.01 Å. The Mn(5)-F(8) bond length is 2.18 Å. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(4), one O(8), one F(1), one F(5), and one F(6) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. The Mn(6)-O(2) bond length is 1.91 Å. The Mn(6)-O(4) bond length is 1.93 Å. The Mn(6)-O(8) bond length is 1.92 Å. The Mn(6)-F(1) bond length is 2.17 Å. The Mn(6)-F(5) bond length is 2.13 Å. The Mn(6)-F(6) bond length is 2.02 Å. In the seventh Mn site, Mn(7) is bonded to one O(3), one O(5), one O(6), one F(1), one F(6), and one F(7) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. The Mn(7)-O(3) bond length is 1.92 Å. The Mn(7)-O(5) bond length is 1.90 Å. The Mn(7)-O(6) bond length is 1.93 Å. The Mn(7)-F(1) bond length is 2.14 Å. The Mn(7)-F(6) bond length is 2.06 Å. The Mn(7)-F(7) bond length is 2.21 Å. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(3), one O(7), one F(3), one F(7), and one F(8) atom to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. The Mn(8)-O(1) bond length is 1.99 Å. The Mn(8)-O(3) bond length is 1.89 Å. The Mn(8)-O(7) bond length is 1.93 Å. The Mn(8)-F(3) bond length is 2.04 Å. The Mn(8)-F(7) bond length is 2.09 Å. The Mn(8)-F(8) bond length is 2.05 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(7), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(7) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(6) atom. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(7) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(7), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(8) atom.