CoRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Co(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. Co(1) is bonded to four equivalent S(1) atoms to form CoS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 56°. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rh(1) and one Co(1) atom.
CoRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Co(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. All Rh(1)-S(1) bond lengths are 2.40 Å. Co(1) is bonded to four equivalent S(1) atoms to form CoS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Co(1)-S(1) bond lengths are 2.14 Å. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rh(1) and one Co(1) atom.