CsClO4 crystallizes in the tetragonal P4_2/nmc space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms.
CsClO4 crystallizes in the tetragonal P4_2/nmc space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. There are four shorter (3.03 Å) and eight longer (3.12 Å) Cs(1)-O(1) bond lengths. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.46 Å. Cl(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms.