PdCu11N4 crystallizes in the tetragonal P4/mmm space group. Pd(1) is bonded in a distorted linear geometry to four equivalent Cu(4) and two equivalent N(1) atoms. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a linear geometry to four equivalent Cu(4) and two equivalent N(2) atoms. In the second Cu site, Cu(2) is bonded in a linear geometry to four equivalent Cu(4), one N(2), and one N(3) atom. In the third Cu site, Cu(3) is bonded in a linear geometry to four equivalent Cu(4) and two equivalent N(3) atoms. In the fourth Cu site, Cu(4) is bonded in a distorted single-bond geometry to one Pd(1), one Cu(1), two equivalent Cu(3), and four equivalent Cu(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to two equivalent Pd(1) atoms. In the second N site, N(2) is bonded to two equivalent Cu(1) and four equivalent Cu(2) atoms to form corner-sharing NCu6 octahedra. The corner-sharing octahedra are not tilted. In the third N site, N(3) is bonded in a square co-planar geometry to two equivalent Cu(2) and two equivalent Cu(3) atoms.
PdCu11N4 crystallizes in the tetragonal P4/mmm space group. Pd(1) is bonded in a distorted linear geometry to four equivalent Cu(4) and two equivalent N(1) atoms. All Pd(1)-Cu(4) bond lengths are 2.62 Å. Both Pd(1)-N(1) bond lengths are 1.87 Å. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a linear geometry to four equivalent Cu(4) and two equivalent N(2) atoms. All Cu(1)-Cu(4) bond lengths are 2.65 Å. Both Cu(1)-N(2) bond lengths are 1.87 Å. In the second Cu site, Cu(2) is bonded in a linear geometry to four equivalent Cu(4), one N(2), and one N(3) atom. All Cu(2)-Cu(4) bond lengths are 2.65 Å. The Cu(2)-N(2) bond length is 1.92 Å. The Cu(2)-N(3) bond length is 1.81 Å. In the third Cu site, Cu(3) is bonded in a linear geometry to four equivalent Cu(4) and two equivalent N(3) atoms. All Cu(3)-Cu(4) bond lengths are 2.64 Å. Both Cu(3)-N(3) bond lengths are 1.87 Å. In the fourth Cu site, Cu(4) is bonded in a distorted single-bond geometry to one Pd(1), one Cu(1), two equivalent Cu(3), and four equivalent Cu(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to two equivalent Pd(1) atoms. In the second N site, N(2) is bonded to two equivalent Cu(1) and four equivalent Cu(2) atoms to form corner-sharing NCu6 octahedra. The corner-sharing octahedra are not tilted. In the third N site, N(3) is bonded in a square co-planar geometry to two equivalent Cu(2) and two equivalent Cu(3) atoms.