SV1 is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing VS6 pentagonal pyramids. S(1) is bonded to six equivalent V(1) atoms to form a mixture of corner, face, and edge-sharing SV6 octahedra. The corner-sharing octahedral tilt angles are 44°.
SV1 is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing VS6 pentagonal pyramids. All V(1)-S(1) bond lengths are 2.43 Å. S(1) is bonded to six equivalent V(1) atoms to form a mixture of corner, face, and edge-sharing SV6 octahedra. The corner-sharing octahedral tilt angles are 44°.