Ag3Si3(SnP3)2 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Sn(1) and two equivalent P(1) atoms. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. Si(1) is bonded to four equivalent P(1) atoms to form corner-sharing SiP4 tetrahedra. P(1) is bonded to one Ag(1), one Sn(1), and two equivalent Si(1) atoms to form corner-sharing PSi2AgSn tetrahedra.
Ag3Si3(SnP3)2 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Sn(1) and two equivalent P(1) atoms. Both Ag(1)-Sn(1) bond lengths are 3.03 Å. Both Ag(1)-P(1) bond lengths are 2.61 Å. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. All Sn(1)-P(1) bond lengths are 2.64 Å. Si(1) is bonded to four equivalent P(1) atoms to form corner-sharing SiP4 tetrahedra. All Si(1)-P(1) bond lengths are 2.28 Å. P(1) is bonded to one Ag(1), one Sn(1), and two equivalent Si(1) atoms to form corner-sharing PSi2AgSn tetrahedra.