AgN3 crystallizes in the tetragonal I4/mcm space group. Ag(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to four equivalent Ag(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to two equivalent N(1) atoms.
AgN3 crystallizes in the tetragonal I4/mcm space group. Ag(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. All Ag(1)-N(1) bond lengths are 2.70 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to four equivalent Ag(1) and one N(2) atom. The N(1)-N(2) bond length is 1.19 Å. In the second N site, N(2) is bonded in a linear geometry to two equivalent N(1) atoms.