VOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form VO2F4 octahedra that share corners with eight equivalent V(2)O4F2 octahedra and edges with two equivalent V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. In the second V site, V(2) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with eight equivalent V(1)O2F4 octahedra and edges with two equivalent V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. O(1) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms.
VOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form VO2F4 octahedra that share corners with eight equivalent V(2)O4F2 octahedra and edges with two equivalent V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. Both V(1)-O(1) bond lengths are 1.93 Å. All V(1)-F(1) bond lengths are 2.07 Å. In the second V site, V(2) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with eight equivalent V(1)O2F4 octahedra and edges with two equivalent V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. All V(2)-O(1) bond lengths are 2.01 Å. Both V(2)-F(1) bond lengths are 2.14 Å. O(1) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms.