K2NaInP2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 9-coordinate geometry to two equivalent Na(1), two equivalent In(1), and five equivalent P(1) atoms. Na(1) is bonded in a 4-coordinate geometry to four equivalent K(1) and four equivalent P(1) atoms. In(1) is bonded to four equivalent K(1) and four equivalent P(1) atoms to form distorted face-sharing InK4P4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent K(1), two equivalent Na(1), and two equivalent In(1) atoms.
K2NaInP2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 9-coordinate geometry to two equivalent Na(1), two equivalent In(1), and five equivalent P(1) atoms. Both K(1)-Na(1) bond lengths are 3.53 Å. Both K(1)-In(1) bond lengths are 3.60 Å. There are a spread of K(1)-P(1) bond distances ranging from 3.37-3.69 Å. Na(1) is bonded in a 4-coordinate geometry to four equivalent K(1) and four equivalent P(1) atoms. All Na(1)-P(1) bond lengths are 2.94 Å. In(1) is bonded to four equivalent K(1) and four equivalent P(1) atoms to form distorted face-sharing InK4P4 tetrahedra. All In(1)-P(1) bond lengths are 2.66 Å. P(1) is bonded in a 9-coordinate geometry to five equivalent K(1), two equivalent Na(1), and two equivalent In(1) atoms.