Na3GaP6(NO4)6 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(5), one O(8), and one O(9) atom. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. Ga(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form GaO6 octahedra that share corners with two equivalent P(1)N2O2 tetrahedra and corners with two equivalent P(3)N2O2 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one O(5), and one O(6) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(3)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 43°. In the second P site, P(2) is bonded in a trigonal planar geometry to one N(1), one O(3), and one O(4) atom. In the third P site, P(3) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(1)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one P(2), one P(3), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one P(1), one P(3), and one O(10) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(1), one O(12), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Ga(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Na(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(2) and one N(1) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one O(11) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Na(1), one Na(2), and one N(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Na(1) and one N(2) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one O(8) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one N(3) atom.
Na3GaP6(NO4)6 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(5), one O(8), and one O(9) atom. The Na(1)-O(10) bond length is 2.38 Å. The Na(1)-O(12) bond length is 2.39 Å. The Na(1)-O(3) bond length is 2.52 Å. The Na(1)-O(4) bond length is 2.91 Å. The Na(1)-O(5) bond length is 2.93 Å. The Na(1)-O(8) bond length is 2.69 Å. The Na(1)-O(9) bond length is 3.07 Å. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. Both Na(2)-O(7) bond lengths are 2.94 Å. Both Na(2)-O(8) bond lengths are 2.75 Å. Both Na(2)-O(9) bond lengths are 2.67 Å. Ga(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form GaO6 octahedra that share corners with two equivalent P(1)N2O2 tetrahedra and corners with two equivalent P(3)N2O2 tetrahedra. Both Ga(1)-O(2) bond lengths are 1.93 Å. Both Ga(1)-O(4) bond lengths are 1.99 Å. Both Ga(1)-O(6) bond lengths are 2.01 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one O(5), and one O(6) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(3)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 43°. The P(1)-N(2) bond length is 1.74 Å. The P(1)-N(3) bond length is 1.89 Å. The P(1)-O(5) bond length is 1.47 Å. The P(1)-O(6) bond length is 1.51 Å. In the second P site, P(2) is bonded in a trigonal planar geometry to one N(1), one O(3), and one O(4) atom. The P(2)-N(1) bond length is 1.71 Å. The P(2)-O(3) bond length is 1.48 Å. The P(2)-O(4) bond length is 1.52 Å. In the third P site, P(3) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(1)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 44°. The P(3)-N(1) bond length is 1.82 Å. The P(3)-N(2) bond length is 1.76 Å. The P(3)-O(1) bond length is 1.47 Å. The P(3)-O(2) bond length is 1.52 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one P(2), one P(3), and one O(7) atom. The N(1)-O(7) bond length is 1.29 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one P(1), one P(3), and one O(10) atom. The N(2)-O(10) bond length is 1.30 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(1), one O(12), and one O(9) atom. The N(3)-O(12) bond length is 1.26 Å. The N(3)-O(9) bond length is 1.25 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Ga(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Na(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(2) and one N(1) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one O(11) atom. The O(8)-O(11) bond length is 1.23 Å. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Na(1), one Na(2), and one N(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Na(1) and one N(2) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one O(8) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one N(3) atom.