LiAg2(NO2)3 crystallizes in the monoclinic Cc space group. Li(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(2), one O(2), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one O(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one O(2), and one O(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the third O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(2), and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(1), and one N(2) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one N(1) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one N(2) atom.
LiAg2(NO2)3 crystallizes in the monoclinic Cc space group. Li(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Li(1)-O(1) bond length is 2.20 Å. The Li(1)-O(2) bond length is 2.10 Å. The Li(1)-O(3) bond length is 2.22 Å. The Li(1)-O(4) bond length is 2.13 Å. The Li(1)-O(5) bond length is 2.20 Å. The Li(1)-O(6) bond length is 2.16 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(2), one O(2), one O(5), and one O(6) atom. The Ag(1)-N(2) bond length is 2.42 Å. The Ag(1)-O(2) bond length is 2.46 Å. The Ag(1)-O(5) bond length is 2.45 Å. The Ag(1)-O(6) bond length is 2.59 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one O(1) atom. The Ag(2)-N(1) bond length is 2.29 Å. The Ag(2)-N(3) bond length is 2.20 Å. The Ag(2)-O(1) bond length is 2.41 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(3) atom. The N(1)-O(1) bond length is 1.27 Å. The N(1)-O(3) bond length is 1.25 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one O(2), and one O(4) atom. The N(2)-O(2) bond length is 1.28 Å. The N(2)-O(4) bond length is 1.25 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(5), and one O(6) atom. The N(3)-O(5) bond length is 1.26 Å. The N(3)-O(6) bond length is 1.26 Å. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one N(3) atom. In the third O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(2), and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(1), and one N(2) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Li(1) and one N(1) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one N(2) atom.