MgLa10Ti7O30 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal P3 space group. Mg(1) is bonded to three equivalent O(1) and three equivalent O(9) atoms to form MgO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra and corners with three equivalent Ti(7)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. There are ten inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(4), and three equivalent O(9) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to three equivalent O(10), three equivalent O(2), and three equivalent O(3) atoms. In the third La site, La(3) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(7) atoms. In the fourth La site, La(4) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(8) atoms. In the fifth La site, La(5) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(5) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to three equivalent O(4), three equivalent O(6), and three equivalent O(9) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(5), and three equivalent O(7) atoms. In the eighth La site, La(8) is bonded in a 6-coordinate geometry to three equivalent O(6) and three equivalent O(8) atoms. In the ninth La site, La(9) is bonded in a 6-coordinate geometry to three equivalent O(5) and three equivalent O(7) atoms. In the tenth La site, La(10) is bonded in a 9-coordinate geometry to three equivalent O(4), three equivalent O(6), and three equivalent O(8) atoms. There are seven inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to three equivalent O(1) and three equivalent O(7) atoms to form TiO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. In the second Ti site, Ti(2) is bonded to three equivalent O(2) and three equivalent O(8) atoms to form distorted corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 21°. In the third Ti site, Ti(3) is bonded to three equivalent O(3) and three equivalent O(5) atoms to form distorted corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 22°. In the fourth Ti site, Ti(4) is bonded to three equivalent O(4) and three equivalent O(6) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 20°. In the fifth Ti site, Ti(5) is bonded to three equivalent O(10) and three equivalent O(2) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-21°. In the sixth Ti site, Ti(6) is bonded to three equivalent O(10) and three equivalent O(3) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. In the seventh Ti site, Ti(7) is bonded to three equivalent O(4) and three equivalent O(9) atoms to form TiO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra and corners with three equivalent Ti(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(3), one La(7), and one Ti(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(2), one La(4), one Ti(2), and one Ti(5) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ti(3), and one Ti(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one La(10), one La(6), one Ti(4), and one Ti(7) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one La(5), one La(7), one La(9), and one Ti(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one La(10), one La(6), one La(8), and one Ti(4) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one La(3), one La(7), one La(9), and one Ti(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(10), one La(4), one La(8), and one Ti(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mg(1), one La(1), one La(6), and one Ti(7) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(2), one Ti(5), and one Ti(6) atom.
MgLa10Ti7O30 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal P3 space group. Mg(1) is bonded to three equivalent O(1) and three equivalent O(9) atoms to form MgO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra and corners with three equivalent Ti(7)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. All Mg(1)-O(1) bond lengths are 2.05 Å. All Mg(1)-O(9) bond lengths are 2.08 Å. There are ten inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(4), and three equivalent O(9) atoms. All La(1)-O(1) bond lengths are 2.67 Å. All La(1)-O(4) bond lengths are 2.90 Å. All La(1)-O(9) bond lengths are 2.44 Å. In the second La site, La(2) is bonded in a 9-coordinate geometry to three equivalent O(10), three equivalent O(2), and three equivalent O(3) atoms. All La(2)-O(10) bond lengths are 2.46 Å. All La(2)-O(2) bond lengths are 2.73 Å. All La(2)-O(3) bond lengths are 2.70 Å. In the third La site, La(3) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(7) atoms. All La(3)-O(1) bond lengths are 2.43 Å. All La(3)-O(7) bond lengths are 2.58 Å. In the fourth La site, La(4) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(8) atoms. All La(4)-O(2) bond lengths are 2.48 Å. All La(4)-O(8) bond lengths are 2.53 Å. In the fifth La site, La(5) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(5) atoms. All La(5)-O(3) bond lengths are 2.49 Å. All La(5)-O(5) bond lengths are 2.49 Å. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to three equivalent O(4), three equivalent O(6), and three equivalent O(9) atoms. All La(6)-O(4) bond lengths are 2.44 Å. All La(6)-O(6) bond lengths are 2.64 Å. All La(6)-O(9) bond lengths are 2.83 Å. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(5), and three equivalent O(7) atoms. All La(7)-O(1) bond lengths are 2.85 Å. All La(7)-O(5) bond lengths are 2.78 Å. All La(7)-O(7) bond lengths are 2.38 Å. In the eighth La site, La(8) is bonded in a 6-coordinate geometry to three equivalent O(6) and three equivalent O(8) atoms. All La(8)-O(6) bond lengths are 2.49 Å. All La(8)-O(8) bond lengths are 2.46 Å. In the ninth La site, La(9) is bonded in a 6-coordinate geometry to three equivalent O(5) and three equivalent O(7) atoms. All La(9)-O(5) bond lengths are 2.48 Å. All La(9)-O(7) bond lengths are 2.45 Å. In the tenth La site, La(10) is bonded in a 9-coordinate geometry to three equivalent O(4), three equivalent O(6), and three equivalent O(8) atoms. All La(10)-O(4) bond lengths are 2.83 Å. All La(10)-O(6) bond lengths are 2.40 Å. All La(10)-O(8) bond lengths are 2.73 Å. There are seven inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to three equivalent O(1) and three equivalent O(7) atoms to form TiO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. All Ti(1)-O(1) bond lengths are 2.01 Å. All Ti(1)-O(7) bond lengths are 1.95 Å. In the second Ti site, Ti(2) is bonded to three equivalent O(2) and three equivalent O(8) atoms to form distorted corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 21°. All Ti(2)-O(2) bond lengths are 2.16 Å. All Ti(2)-O(8) bond lengths are 1.86 Å. In the third Ti site, Ti(3) is bonded to three equivalent O(3) and three equivalent O(5) atoms to form distorted corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 22°. All Ti(3)-O(3) bond lengths are 2.17 Å. All Ti(3)-O(5) bond lengths are 1.85 Å. In the fourth Ti site, Ti(4) is bonded to three equivalent O(4) and three equivalent O(6) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 20°. All Ti(4)-O(4) bond lengths are 2.07 Å. All Ti(4)-O(6) bond lengths are 1.91 Å. In the fifth Ti site, Ti(5) is bonded to three equivalent O(10) and three equivalent O(2) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-21°. All Ti(5)-O(10) bond lengths are 2.02 Å. All Ti(5)-O(2) bond lengths are 1.94 Å. In the sixth Ti site, Ti(6) is bonded to three equivalent O(10) and three equivalent O(3) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. All Ti(6)-O(10) bond lengths are 2.04 Å. All Ti(6)-O(3) bond lengths are 1.92 Å. In the seventh Ti site, Ti(7) is bonded to three equivalent O(4) and three equivalent O(9) atoms to form TiO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra and corners with three equivalent Ti(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-22°. All Ti(7)-O(4) bond lengths are 2.05 Å. All Ti(7)-O(9) bond lengths are 1.91 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(3), one La(7), and one Ti(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(2), one La(4), one Ti(2), and one Ti(5) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ti(3), and one Ti(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one La(10), one La(6), one Ti(4), and one Ti(7) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one La(5), one La(7), one La(9), and one Ti(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one La(10), one La(6), one La(8), and one Ti(4) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one La(3), one La(7), one La(9), and one Ti(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(10), one La(4), one La(8), and one Ti(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mg(1), one La(1), one La(6), and one Ti(7) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(2), one Ti(5), and one Ti(6) atom.