Li3Mn(OF)2 is Caswellsilverite-derived structured and crystallizes in the monoclinic Cc space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(3) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O3F3 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra, corners with four equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(4), one F(1), one F(2), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(4)O2F4 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra, corners with four equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one F(1), one F(2), and one F(3) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra, corners with four equivalent Mn(1)O4F2 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the fourth Li site, Li(4) is bonded to one O(2), one O(4), one F(1), one F(2), one F(3), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(6)O2F4 octahedra,  a cornercorner with one Li(2)O3F3 octahedra, corners with four equivalent Mn(2)O3F3 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the fifth Li site, Li(5) is bonded to one O(1), one O(2), one O(3), one F(2), one F(3), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(3)O3F3 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra, corners with four equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the sixth Li site, Li(6) is bonded to one O(3), one O(4), one F(1), one F(2), one F(3), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(4)O2F4 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra, corners with four equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(3), and one F(4) atom to form MnO4F2 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra, corners with four equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), one F(1), one F(2), and one F(4) atom to form MnO3F3 octahedra that share  a cornercorner with one Li(6)O2F4 octahedra,  a cornercorner with one Li(2)O3F3 octahedra, corners with four equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li4Mn2 octahedra,  a cornercorner with one O(2)Li5Mn octahedra, corners with four equivalent F(3)Li5Mn octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(2)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one Mn(1) atom to form OLi5Mn octahedra that share  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one F(3)Li5Mn octahedra, corners with four equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(5), one Li(6), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one F(3)Li5Mn octahedra, corners with four equivalent O(2)Li5Mn octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), one Li(6), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one F(4)Li4Mn2 octahedra,  a cornercorner with one F(1)Li5Mn octahedra, corners with four equivalent F(2)Li5Mn octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. There are four inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(6), and one Mn(2) atom to form FLi5Mn octahedra that share  a cornercorner with one O(4)Li4Mn2 octahedra,  a cornercorner with one F(2)Li5Mn octahedra, corners with four equivalent F(4)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the second F site, F(2) is bonded to one Li(2), one Li(3), one Li(4), one Li(5), one Li(6), and one Mn(2) atom to form FLi5Mn octahedra that share  a cornercorner with one F(4)Li4Mn2 octahedra,  a cornercorner with one F(1)Li5Mn octahedra, corners with four equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the third F site, F(3) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Li(6), and one Mn(1) atom to form FLi5Mn octahedra that share  a cornercorner with one O(3)Li4Mn2 octahedra,  a cornercorner with one O(2)Li5Mn octahedra, corners with four equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(2)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the fourth F site, F(4) is bonded to one Li(2), one Li(4), one Li(5), one Li(6), one Mn(1), and one Mn(2) atom to form FLi4Mn2 octahedra that share  a cornercorner with one O(4)Li4Mn2 octahedra,  a cornercorner with one F(2)Li5Mn octahedra, corners with four equivalent F(1)Li5Mn octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-10°.
Li3Mn(OF)2 is Caswellsilverite-derived structured and crystallizes in the monoclinic Cc space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(3) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O3F3 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra, corners with four equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. The Li(1)-O(1) bond length is 2.06 Å. The Li(1)-O(2) bond length is 2.09 Å. The Li(1)-O(3) bond length is 2.30 Å. The Li(1)-O(4) bond length is 2.05 Å. The Li(1)-F(1) bond length is 2.18 Å. The Li(1)-F(3) bond length is 2.08 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(4), one F(1), one F(2), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(4)O2F4 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra, corners with four equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Li(2)-O(1) bond length is 2.33 Å. The Li(2)-O(2) bond length is 2.04 Å. The Li(2)-O(4) bond length is 2.16 Å. The Li(2)-F(1) bond length is 2.05 Å. The Li(2)-F(2) bond length is 2.28 Å. The Li(2)-F(4) bond length is 2.06 Å. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one F(1), one F(2), and one F(3) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra, corners with four equivalent Mn(1)O4F2 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. The Li(3)-O(1) bond length is 2.24 Å. The Li(3)-O(2) bond length is 2.03 Å. The Li(3)-O(3) bond length is 2.32 Å. The Li(3)-F(1) bond length is 2.06 Å. The Li(3)-F(2) bond length is 2.02 Å. The Li(3)-F(3) bond length is 2.11 Å. In the fourth Li site, Li(4) is bonded to one O(2), one O(4), one F(1), one F(2), one F(3), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(6)O2F4 octahedra,  a cornercorner with one Li(2)O3F3 octahedra, corners with four equivalent Mn(2)O3F3 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. The Li(4)-O(2) bond length is 2.04 Å. The Li(4)-O(4) bond length is 2.09 Å. The Li(4)-F(1) bond length is 2.03 Å. The Li(4)-F(2) bond length is 2.15 Å. The Li(4)-F(3) bond length is 2.09 Å. The Li(4)-F(4) bond length is 2.15 Å. In the fifth Li site, Li(5) is bonded to one O(1), one O(2), one O(3), one F(2), one F(3), and one F(4) atom to form LiO3F3 octahedra that share  a cornercorner with one Li(3)O3F3 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra, corners with four equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. The Li(5)-O(1) bond length is 2.04 Å. The Li(5)-O(2) bond length is 2.11 Å. The Li(5)-O(3) bond length is 2.26 Å. The Li(5)-F(2) bond length is 2.17 Å. The Li(5)-F(3) bond length is 2.02 Å. The Li(5)-F(4) bond length is 2.09 Å. In the sixth Li site, Li(6) is bonded to one O(3), one O(4), one F(1), one F(2), one F(3), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(4)O2F4 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra, corners with four equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Mn(2)O3F3 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. The Li(6)-O(3) bond length is 2.08 Å. The Li(6)-O(4) bond length is 2.06 Å. The Li(6)-F(1) bond length is 2.00 Å. The Li(6)-F(2) bond length is 2.25 Å. The Li(6)-F(3) bond length is 2.29 Å. The Li(6)-F(4) bond length is 2.08 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(3), and one F(4) atom to form MnO4F2 octahedra that share  a cornercorner with one Li(5)O3F3 octahedra,  a cornercorner with one Li(1)O4F2 octahedra, corners with four equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. The Mn(1)-O(1) bond length is 2.09 Å. The Mn(1)-O(2) bond length is 1.86 Å. The Mn(1)-O(3) bond length is 1.96 Å. The Mn(1)-O(4) bond length is 1.99 Å. The Mn(1)-F(3) bond length is 2.32 Å. The Mn(1)-F(4) bond length is 2.16 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), one F(1), one F(2), and one F(4) atom to form MnO3F3 octahedra that share  a cornercorner with one Li(6)O2F4 octahedra,  a cornercorner with one Li(2)O3F3 octahedra, corners with four equivalent Li(4)O2F4 octahedra, edges with two equivalent Li(6)O2F4 octahedra, edges with two equivalent Li(2)O3F3 octahedra, edges with two equivalent Li(3)O3F3 octahedra, edges with two equivalent Li(5)O3F3 octahedra, edges with two equivalent Li(1)O4F2 octahedra, and edges with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. The Mn(2)-O(1) bond length is 1.90 Å. The Mn(2)-O(3) bond length is 1.93 Å. The Mn(2)-O(4) bond length is 1.91 Å. The Mn(2)-F(1) bond length is 2.22 Å. The Mn(2)-F(2) bond length is 2.03 Å. The Mn(2)-F(4) bond length is 2.33 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li4Mn2 octahedra,  a cornercorner with one O(2)Li5Mn octahedra, corners with four equivalent F(3)Li5Mn octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(2)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one Mn(1) atom to form OLi5Mn octahedra that share  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one F(3)Li5Mn octahedra, corners with four equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(5), one Li(6), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one F(3)Li5Mn octahedra, corners with four equivalent O(2)Li5Mn octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), one Li(6), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one F(4)Li4Mn2 octahedra,  a cornercorner with one F(1)Li5Mn octahedra, corners with four equivalent F(2)Li5Mn octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. There are four inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(6), and one Mn(2) atom to form FLi5Mn octahedra that share  a cornercorner with one O(4)Li4Mn2 octahedra,  a cornercorner with one F(2)Li5Mn octahedra, corners with four equivalent F(4)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the second F site, F(2) is bonded to one Li(2), one Li(3), one Li(4), one Li(5), one Li(6), and one Mn(2) atom to form FLi5Mn octahedra that share  a cornercorner with one F(4)Li4Mn2 octahedra,  a cornercorner with one F(1)Li5Mn octahedra, corners with four equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the third F site, F(3) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Li(6), and one Mn(1) atom to form FLi5Mn octahedra that share  a cornercorner with one O(3)Li4Mn2 octahedra,  a cornercorner with one O(2)Li5Mn octahedra, corners with four equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(4)Li4Mn2 octahedra, edges with two equivalent F(1)Li5Mn octahedra, and edges with two equivalent F(2)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the fourth F site, F(4) is bonded to one Li(2), one Li(4), one Li(5), one Li(6), one Mn(1), and one Mn(2) atom to form FLi4Mn2 octahedra that share  a cornercorner with one O(4)Li4Mn2 octahedra,  a cornercorner with one F(2)Li5Mn octahedra, corners with four equivalent F(1)Li5Mn octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(3)Li4Mn2 octahedra, edges with two equivalent O(4)Li4Mn2 octahedra, edges with two equivalent O(2)Li5Mn octahedra, edges with two equivalent F(2)Li5Mn octahedra, and edges with two equivalent F(3)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-10°.