SF4 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight sulfur tetrafluoride molecules. S(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom.
SF4 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight sulfur tetrafluoride molecules. S(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. The S(1)-F(1) bond length is 1.56 Å. The S(1)-F(2) bond length is 1.56 Å. The S(1)-F(3) bond length is 1.67 Å. The S(1)-F(4) bond length is 1.71 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom.