Li2VO2F is alpha Po-derived structured and crystallizes in the monoclinic C2 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O2F4 octahedra,  a cornercorner with one Li(5)O2F4 octahedra,  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(5)O2F4 octahedra,  an edgeedge with one V(2)O2F4 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(2)O4F2 octahedra, and edges with three equivalent Li(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O2F4 octahedra,  a cornercorner with one Li(5)O2F4 octahedra,  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(5)O2F4 octahedra,  an edgeedge with one V(2)O2F4 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O4F2 octahedra, and edges with three equivalent Li(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the third Li site, Li(3) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form LiO2F4 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent Li(5)O2F4 octahedra, and edges with three equivalent V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O2F4 octahedra,  a cornercorner with one Li(5)O2F4 octahedra,  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(5)O2F4 octahedra,  an edgeedge with one V(2)O2F4 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O4F2 octahedra, and edges with three equivalent Li(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form LiO2F4 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent Li(3)O2F4 octahedra, and edges with three equivalent V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form VO2F4 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent Li(3)O2F4 octahedra, and edges with three equivalent Li(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the fourth V site, V(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(4), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(3)Li3V3 octahedra, and edges with four equivalent O(4)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one V(2) atom to form OLi5V octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra, edges with four equivalent F(1)Li5V octahedra, and edges with four equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(4), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(1)Li3V3 octahedra, and edges with four equivalent O(4)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(1)Li3V3 octahedra, and edges with four equivalent O(3)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with four equivalent O(2)Li5V octahedra, and edges with four equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second F site, F(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(2)Li5V octahedra, and edges with four equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 2-10°.
Li2VO2F is alpha Po-derived structured and crystallizes in the monoclinic C2 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O2F4 octahedra,  a cornercorner with one Li(5)O2F4 octahedra,  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(5)O2F4 octahedra,  an edgeedge with one V(2)O2F4 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(2)O4F2 octahedra, and edges with three equivalent Li(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. The Li(1)-O(1) bond length is 2.17 Å. The Li(1)-O(2) bond length is 2.04 Å. The Li(1)-O(3) bond length is 2.24 Å. The Li(1)-O(4) bond length is 2.13 Å. The Li(1)-F(1) bond length is 2.14 Å. The Li(1)-F(2) bond length is 2.15 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O2F4 octahedra,  a cornercorner with one Li(5)O2F4 octahedra,  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(5)O2F4 octahedra,  an edgeedge with one V(2)O2F4 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O4F2 octahedra, and edges with three equivalent Li(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. The Li(2)-O(1) bond length is 2.15 Å. The Li(2)-O(2) bond length is 2.06 Å. The Li(2)-O(3) bond length is 2.11 Å. The Li(2)-O(4) bond length is 2.22 Å. The Li(2)-F(1) bond length is 2.15 Å. The Li(2)-F(2) bond length is 2.25 Å. In the third Li site, Li(3) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form LiO2F4 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent Li(5)O2F4 octahedra, and edges with three equivalent V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. Both Li(3)-O(2) bond lengths are 2.05 Å. Both Li(3)-F(1) bond lengths are 2.17 Å. Both Li(3)-F(2) bond lengths are 2.13 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form LiO4F2 octahedra that share  a cornercorner with one Li(3)O2F4 octahedra,  a cornercorner with one Li(5)O2F4 octahedra,  a cornercorner with one V(2)O2F4 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(5)O2F4 octahedra,  an edgeedge with one V(2)O2F4 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O4F2 octahedra, and edges with three equivalent Li(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. The Li(4)-O(1) bond length is 2.31 Å. The Li(4)-O(2) bond length is 2.03 Å. The Li(4)-O(3) bond length is 2.14 Å. The Li(4)-O(4) bond length is 2.14 Å. The Li(4)-F(1) bond length is 2.16 Å. The Li(4)-F(2) bond length is 2.14 Å. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form LiO2F4 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent Li(3)O2F4 octahedra, and edges with three equivalent V(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. Both Li(5)-O(2) bond lengths are 2.10 Å. Both Li(5)-F(1) bond lengths are 2.12 Å. Both Li(5)-F(2) bond lengths are 2.08 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. Both V(1)-O(1) bond lengths are 2.05 Å. Both V(1)-O(3) bond lengths are 2.06 Å. Both V(1)-O(4) bond lengths are 2.06 Å. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form VO2F4 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent Li(3)O2F4 octahedra, and edges with three equivalent Li(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. Both V(2)-O(2) bond lengths are 1.90 Å. Both V(2)-F(1) bond lengths are 2.10 Å. Both V(2)-F(2) bond lengths are 2.13 Å. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. Both V(3)-O(1) bond lengths are 2.05 Å. Both V(3)-O(3) bond lengths are 2.06 Å. Both V(3)-O(4) bond lengths are 2.06 Å. In the fourth V site, V(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O4F2 octahedra, corners with two equivalent Li(2)O4F2 octahedra, corners with two equivalent Li(4)O4F2 octahedra, edges with two equivalent Li(1)O4F2 octahedra, edges with two equivalent Li(2)O4F2 octahedra, edges with two equivalent Li(4)O4F2 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. Both V(4)-O(1) bond lengths are 2.05 Å. Both V(4)-O(3) bond lengths are 2.06 Å. Both V(4)-O(4) bond lengths are 2.06 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(4), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(3)Li3V3 octahedra, and edges with four equivalent O(4)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one V(2) atom to form OLi5V octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra, edges with four equivalent F(1)Li5V octahedra, and edges with four equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(4), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(1)Li3V3 octahedra, and edges with four equivalent O(4)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), one V(1), one V(3), and one V(4) atom to form OLi3V3 octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one O(2)Li5V octahedra,  an edgeedge with one F(1)Li5V octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(1)Li3V3 octahedra, and edges with four equivalent O(3)Li3V3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one F(1)Li5V octahedra, edges with four equivalent O(2)Li5V octahedra, and edges with four equivalent F(2)Li5V octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second F site, F(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Li(5), and one V(2) atom to form FLi5V octahedra that share  a cornercorner with one O(1)Li3V3 octahedra,  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(4)Li3V3 octahedra,  a cornercorner with one O(2)Li5V octahedra,  a cornercorner with one F(1)Li5V octahedra,  a cornercorner with one F(2)Li5V octahedra,  an edgeedge with one O(1)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(4)Li3V3 octahedra,  an edgeedge with one F(2)Li5V octahedra, edges with four equivalent O(2)Li5V octahedra, and edges with four equivalent F(1)Li5V octahedra. The corner-sharing octahedral tilt angles range from 2-10°.