Ti2SnC is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded in a 3-coordinate geometry to three equivalent Sn(1) and three equivalent C(1) atoms. Sn(1) is bonded to six equivalent Ti(1) atoms to form distorted SnTi6 cuboctahedra that share corners with six equivalent C(1)Ti6 octahedra, edges with six equivalent Sn(1)Ti6 cuboctahedra, and edges with six equivalent C(1)Ti6 octahedra. The corner-sharing octahedral tilt angles are 20°. C(1) is bonded to six equivalent Ti(1) atoms to form CTi6 octahedra that share corners with six equivalent Sn(1)Ti6 cuboctahedra, edges with six equivalent Sn(1)Ti6 cuboctahedra, and edges with six equivalent C(1)Ti6 octahedra.
Ti2SnC is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded in a 3-coordinate geometry to three equivalent Sn(1) and three equivalent C(1) atoms. All Ti(1)-Sn(1) bond lengths are 2.95 Å. All Ti(1)-C(1) bond lengths are 2.14 Å. Sn(1) is bonded to six equivalent Ti(1) atoms to form distorted SnTi6 cuboctahedra that share corners with six equivalent C(1)Ti6 octahedra, edges with six equivalent Sn(1)Ti6 cuboctahedra, and edges with six equivalent C(1)Ti6 octahedra. The corner-sharing octahedral tilt angles are 20°. C(1) is bonded to six equivalent Ti(1) atoms to form CTi6 octahedra that share corners with six equivalent Sn(1)Ti6 cuboctahedra, edges with six equivalent Sn(1)Ti6 cuboctahedra, and edges with six equivalent C(1)Ti6 octahedra.