AgZnF5 crystallizes in the triclinic P1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one F(1), one F(2), one F(4), one F(5), one F(7), and one F(9) atom to form AgF6 octahedra that share corners with two equivalent Ag(2)F6 octahedra, corners with three equivalent Zn(1)F5 trigonal bipyramids, and corners with three equivalent Zn(2)F5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 57°. In the second Ag site, Ag(2) is bonded to one F(1), one F(10), one F(2), one F(3), one F(6), and one F(8) atom to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra, corners with three equivalent Zn(1)F5 trigonal bipyramids, and corners with three equivalent Zn(2)F5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 57°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one F(10), one F(2), one F(7), one F(8), and one F(9) atom to form ZnF5 trigonal bipyramids that share corners with three equivalent Ag(1)F6 octahedra and corners with three equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 7-63°. In the second Zn site, Zn(2) is bonded to one F(1), one F(3), one F(4), one F(5), and one F(6) atom to form ZnF5 trigonal bipyramids that share corners with three equivalent Ag(1)F6 octahedra and corners with three equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 7-63°. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Zn(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Zn(1) atom. In the third F site, F(3) is bonded in a linear geometry to one Ag(2) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ag(1) and one Zn(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(2) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one Ag(2) and one Zn(2) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ag(2) and one Zn(1) atom. In the ninth F site, F(9) is bonded in a linear geometry to one Ag(1) and one Zn(1) atom. In the tenth F site, F(10) is bonded in a linear geometry to one Ag(2) and one Zn(1) atom.
AgZnF5 crystallizes in the triclinic P1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one F(1), one F(2), one F(4), one F(5), one F(7), and one F(9) atom to form AgF6 octahedra that share corners with two equivalent Ag(2)F6 octahedra, corners with three equivalent Zn(1)F5 trigonal bipyramids, and corners with three equivalent Zn(2)F5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 57°. The Ag(1)-F(1) bond length is 2.41 Å. The Ag(1)-F(2) bond length is 2.40 Å. The Ag(1)-F(4) bond length is 1.98 Å. The Ag(1)-F(5) bond length is 2.05 Å. The Ag(1)-F(7) bond length is 2.05 Å. The Ag(1)-F(9) bond length is 1.98 Å. In the second Ag site, Ag(2) is bonded to one F(1), one F(10), one F(2), one F(3), one F(6), and one F(8) atom to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra, corners with three equivalent Zn(1)F5 trigonal bipyramids, and corners with three equivalent Zn(2)F5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 57°. The Ag(2)-F(1) bond length is 2.37 Å. The Ag(2)-F(10) bond length is 2.00 Å. The Ag(2)-F(2) bond length is 2.36 Å. The Ag(2)-F(3) bond length is 1.98 Å. The Ag(2)-F(6) bond length is 2.07 Å. The Ag(2)-F(8) bond length is 2.07 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one F(10), one F(2), one F(7), one F(8), and one F(9) atom to form ZnF5 trigonal bipyramids that share corners with three equivalent Ag(1)F6 octahedra and corners with three equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 7-63°. The Zn(1)-F(10) bond length is 2.01 Å. The Zn(1)-F(2) bond length is 1.92 Å. The Zn(1)-F(7) bond length is 1.97 Å. The Zn(1)-F(8) bond length is 1.98 Å. The Zn(1)-F(9) bond length is 2.01 Å. In the second Zn site, Zn(2) is bonded to one F(1), one F(3), one F(4), one F(5), and one F(6) atom to form ZnF5 trigonal bipyramids that share corners with three equivalent Ag(1)F6 octahedra and corners with three equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 7-63°. The Zn(2)-F(1) bond length is 1.92 Å. The Zn(2)-F(3) bond length is 2.01 Å. The Zn(2)-F(4) bond length is 2.01 Å. The Zn(2)-F(5) bond length is 1.98 Å. The Zn(2)-F(6) bond length is 1.98 Å. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Zn(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Zn(1) atom. In the third F site, F(3) is bonded in a linear geometry to one Ag(2) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ag(1) and one Zn(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(2) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one Ag(2) and one Zn(2) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ag(2) and one Zn(1) atom. In the ninth F site, F(9) is bonded in a linear geometry to one Ag(1) and one Zn(1) atom. In the tenth F site, F(10) is bonded in a linear geometry to one Ag(2) and one Zn(1) atom.