VB6O6 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dihydroxyboranyl molecules and two V(B2O)2 clusters. In each V(B2O)2 cluster, V(1) is bonded in an octahedral geometry to four equivalent B(2) and two equivalent O(2) atoms. B(2) is bonded in a single-bond geometry to one V(1) and one O(2) atom. O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and two equivalent B(2) atoms.
VB6O6 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dihydroxyboranyl molecules and two V(B2O)2 clusters. In each V(B2O)2 cluster, V(1) is bonded in an octahedral geometry to four equivalent B(2) and two equivalent O(2) atoms. All V(1)-B(2) bond lengths are 2.23 Å. Both V(1)-O(2) bond lengths are 2.15 Å. B(2) is bonded in a single-bond geometry to one V(1) and one O(2) atom. The B(2)-O(2) bond length is 1.37 Å. O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and two equivalent B(2) atoms.