BiInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. In(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. Bi(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent In(1) and two equivalent Bi(1) atoms to form distorted corner-sharing OIn2Bi2 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent In(1) and one Bi(1) atom.
BiInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. In(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. Both In(1)-O(1) bond lengths are 2.21 Å. There are two shorter (2.21 Å) and two longer (2.23 Å) In(1)-O(2) bond lengths. Bi(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There is one shorter (2.23 Å) and one longer (2.60 Å) Bi(1)-O(1) bond length. Both Bi(1)-O(2) bond lengths are 2.29 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent In(1) and two equivalent Bi(1) atoms to form distorted corner-sharing OIn2Bi2 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent In(1) and one Bi(1) atom.