Mn2InC10O10I is Hg_xSn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2InC10O10I cluster. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one In(1), one C(1), one C(10), one C(3), one C(6), and one C(9) atom to form corner-sharing MnInC5 square pyramids. In the second Mn site, Mn(2) is bonded to one In(1), one C(2), one C(4), one C(5), one C(7), and one C(8) atom to form corner-sharing MnInC5 square pyramids. In(1) is bonded to one Mn(1), one Mn(2), and two equivalent I(1) atoms to form distorted edge-sharing InMn2I2 tetrahedra. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(6) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(2) and one O(9) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Mn(1) and one O(8) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Mn(2) and one O(3) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Mn(2) and one O(5) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Mn(1) and one O(7) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Mn(1) and one O(10) atom. There are nine inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. I(1) is bonded in an L-shaped geometry to two equivalent In(1) atoms.
Mn2InC10O10I is Hg_xSn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2InC10O10I cluster. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one In(1), one C(1), one C(10), one C(3), one C(6), and one C(9) atom to form corner-sharing MnInC5 square pyramids. The Mn(1)-In(1) bond length is 2.73 Å. The Mn(1)-C(1) bond length is 1.86 Å. The Mn(1)-C(10) bond length is 1.82 Å. The Mn(1)-C(3) bond length is 1.86 Å. The Mn(1)-C(6) bond length is 1.86 Å. The Mn(1)-C(9) bond length is 1.86 Å. In the second Mn site, Mn(2) is bonded to one In(1), one C(2), one C(4), one C(5), one C(7), and one C(8) atom to form corner-sharing MnInC5 square pyramids. The Mn(2)-In(1) bond length is 2.72 Å. The Mn(2)-C(2) bond length is 1.81 Å. The Mn(2)-C(4) bond length is 1.86 Å. The Mn(2)-C(5) bond length is 1.86 Å. The Mn(2)-C(7) bond length is 1.86 Å. The Mn(2)-C(8) bond length is 1.87 Å. In(1) is bonded to one Mn(1), one Mn(2), and two equivalent I(1) atoms to form distorted edge-sharing InMn2I2 tetrahedra. There is one shorter (2.97 Å) and one longer (2.98 Å) In(1)-I(1) bond length. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2) atom. The C(1)-O(2) bond length is 1.16 Å. In the second C site, C(2) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. The C(2)-O(1,4) bond length is 1.16 Å. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(6) atom. The C(3)-O(6) bond length is 1.16 Å. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(2) and one O(9) atom. The C(4)-O(9) bond length is 1.16 Å. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(2) and one O(1,4) atom. The C(5)-O(1,4) bond length is 1.16 Å. In the sixth C site, C(6) is bonded in a linear geometry to one Mn(1) and one O(8) atom. The C(6)-O(8) bond length is 1.16 Å. In the seventh C site, C(7) is bonded in a linear geometry to one Mn(2) and one O(3) atom. The C(7)-O(3) bond length is 1.15 Å. In the eighth C site, C(8) is bonded in a linear geometry to one Mn(2) and one O(5) atom. The C(8)-O(5) bond length is 1.16 Å. In the ninth C site, C(9) is bonded in a linear geometry to one Mn(1) and one O(7) atom. The C(9)-O(7) bond length is 1.16 Å. In the tenth C site, C(10) is bonded in a linear geometry to one Mn(1) and one O(10) atom. The C(10)-O(10) bond length is 1.16 Å. There are nine inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one C(6) atom. In the eighth O site, O(9) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. I(1) is bonded in an L-shaped geometry to two equivalent In(1) atoms.