Au12Cd3In is Uranium Silicide-derived structured and crystallizes in the hexagonal P-6m2 space group. There are three inequivalent Au sites. In the first Au site, Au(1) is bonded to two equivalent Cd(2) and two equivalent In(1) atoms to form a mixture of distorted corner and face-sharing AuCd2In2 cuboctahedra. In the second Au site, Au(2) is bonded in a distorted see-saw-like geometry to two equivalent Cd(1) and two equivalent Cd(2) atoms. In the third Au site, Au(3) is bonded in a distorted square co-planar geometry to one Cd(1), two equivalent Cd(2), and one In(1) atom. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to six equivalent Au(2) and six equivalent Au(3) atoms to form CdAu12 cuboctahedra that share corners with six equivalent Cd(1)Au12 cuboctahedra, corners with six equivalent In(1)Au12 cuboctahedra, and faces with six equivalent Cd(2)Au12 cuboctahedra. In the second Cd site, Cd(2) is bonded to three equivalent Au(1), three equivalent Au(2), and six equivalent Au(3) atoms to form CdAu12 cuboctahedra that share corners with six equivalent Cd(2)Au12 cuboctahedra, faces with two equivalent Cd(2)Au12 cuboctahedra, faces with three equivalent Cd(1)Au12 cuboctahedra, and faces with three equivalent In(1)Au12 cuboctahedra. In(1) is bonded to six equivalent Au(1) and six equivalent Au(3) atoms to form InAu12 cuboctahedra that share corners with six equivalent Cd(1)Au12 cuboctahedra, corners with six equivalent In(1)Au12 cuboctahedra, and faces with six equivalent Cd(2)Au12 cuboctahedra.
Au12Cd3In is Uranium Silicide-derived structured and crystallizes in the hexagonal P-6m2 space group. There are three inequivalent Au sites. In the first Au site, Au(1) is bonded to two equivalent Cd(2) and two equivalent In(1) atoms to form a mixture of distorted corner and face-sharing AuCd2In2 cuboctahedra. Both Au(1)-Cd(2) bond lengths are 3.00 Å. Both Au(1)-In(1) bond lengths are 2.92 Å. In the second Au site, Au(2) is bonded in a distorted see-saw-like geometry to two equivalent Cd(1) and two equivalent Cd(2) atoms. Both Au(2)-Cd(1) bond lengths are 2.92 Å. Both Au(2)-Cd(2) bond lengths are 2.97 Å. In the third Au site, Au(3) is bonded in a distorted square co-planar geometry to one Cd(1), two equivalent Cd(2), and one In(1) atom. The Au(3)-Cd(1) bond length is 2.97 Å. Both Au(3)-Cd(2) bond lengths are 2.92 Å. The Au(3)-In(1) bond length is 3.00 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to six equivalent Au(2) and six equivalent Au(3) atoms to form CdAu12 cuboctahedra that share corners with six equivalent Cd(1)Au12 cuboctahedra, corners with six equivalent In(1)Au12 cuboctahedra, and faces with six equivalent Cd(2)Au12 cuboctahedra. In the second Cd site, Cd(2) is bonded to three equivalent Au(1), three equivalent Au(2), and six equivalent Au(3) atoms to form CdAu12 cuboctahedra that share corners with six equivalent Cd(2)Au12 cuboctahedra, faces with two equivalent Cd(2)Au12 cuboctahedra, faces with three equivalent Cd(1)Au12 cuboctahedra, and faces with three equivalent In(1)Au12 cuboctahedra. In(1) is bonded to six equivalent Au(1) and six equivalent Au(3) atoms to form InAu12 cuboctahedra that share corners with six equivalent Cd(1)Au12 cuboctahedra, corners with six equivalent In(1)Au12 cuboctahedra, and faces with six equivalent Cd(2)Au12 cuboctahedra.