Ce(NO3)6N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two Ce(NO3)6 clusters. In each Ce(NO3)6 cluster, Ce(1) is bonded in a cuboctahedral geometry to two equivalent O(1), two equivalent O(2), two equivalent O(4), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Ce(1) and one N(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Ce(1) and one N(4) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Ce(1) and one N(4) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Ce(1) and one N(2) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one N(4) atom. In the seventh O site, O(2) is bonded in a distorted single-bond geometry to one Ce(1) and one N(2) atom. In the eighth O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one Ce(1) and one N(3) atom.
Ce(NO3)6N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two Ce(NO3)6 clusters. In each Ce(NO3)6 cluster, Ce(1) is bonded in a cuboctahedral geometry to two equivalent O(1), two equivalent O(2), two equivalent O(4), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms. Both Ce(1)-O(1) bond lengths are 2.57 Å. Both Ce(1)-O(2) bond lengths are 2.60 Å. Both Ce(1)-O(4) bond lengths are 2.59 Å. Both Ce(1)-O(5) bond lengths are 2.57 Å. Both Ce(1)-O(7) bond lengths are 2.60 Å. Both Ce(1)-O(8) bond lengths are 2.62 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(2)-O(1) bond length is 1.28 Å. The N(2)-O(2) bond length is 1.28 Å. The N(2)-O(3) bond length is 1.23 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(3)-O(4) bond length is 1.28 Å. The N(3)-O(5) bond length is 1.28 Å. The N(3)-O(6) bond length is 1.23 Å. In the third N site, N(4) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. The N(4)-O(7) bond length is 1.27 Å. The N(4)-O(8) bond length is 1.27 Å. The N(4)-O(9) bond length is 1.24 Å. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Ce(1) and one N(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Ce(1) and one N(4) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Ce(1) and one N(4) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Ce(1) and one N(2) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one N(4) atom. In the seventh O site, O(2) is bonded in a distorted single-bond geometry to one Ce(1) and one N(2) atom. In the eighth O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one Ce(1) and one N(3) atom.