CrC5PO5Br3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CrC5PO5Br3 clusters. Cr(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one C(4), one C(5), and one P(1) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Cr(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Cr(1) and one O(5) atom. In the third C site, C(3) is bonded in a linear geometry to one Cr(1) and one O(1) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Cr(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Cr(1) and one O(2) atom. P(1) is bonded in a tetrahedral geometry to one Cr(1), one Br(1), one Br(2), and one Br(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one P(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one P(1) atom.
CrC5PO5Br3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CrC5PO5Br3 clusters. Cr(1) is bonded in an octahedral geometry to one C(1), one C(2), one C(3), one C(4), one C(5), and one P(1) atom. The Cr(1)-C(1) bond length is 1.92 Å. The Cr(1)-C(2) bond length is 1.92 Å. The Cr(1)-C(3) bond length is 1.92 Å. The Cr(1)-C(4) bond length is 1.90 Å. The Cr(1)-C(5) bond length is 1.92 Å. The Cr(1)-P(1) bond length is 2.32 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Cr(1) and one O(3) atom. The C(1)-O(3) bond length is 1.16 Å. In the second C site, C(2) is bonded in a linear geometry to one Cr(1) and one O(5) atom. The C(2)-O(5) bond length is 1.16 Å. In the third C site, C(3) is bonded in a linear geometry to one Cr(1) and one O(1) atom. The C(3)-O(1) bond length is 1.16 Å. In the fourth C site, C(4) is bonded in a linear geometry to one Cr(1) and one O(4) atom. The C(4)-O(4) bond length is 1.16 Å. In the fifth C site, C(5) is bonded in a linear geometry to one Cr(1) and one O(2) atom. The C(5)-O(2) bond length is 1.16 Å. P(1) is bonded in a tetrahedral geometry to one Cr(1), one Br(1), one Br(2), and one Br(3) atom. The P(1)-Br(1) bond length is 2.25 Å. The P(1)-Br(2) bond length is 2.25 Å. The P(1)-Br(3) bond length is 2.24 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one P(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one P(1) atom.