KP2(W3O11)2 is Potassium Silver Cyanide-like structured and crystallizes in the monoclinic Pm space group. K(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent W sites. In the first W site, W(1) is bonded to one O(13), one O(3), two equivalent O(2), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the second W site, W(2) is bonded to one O(14), one O(4), two equivalent O(1), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the third W site, W(3) is bonded to one O(7), one O(9), two equivalent O(12), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(6)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fourth W site, W(4) is bonded to one O(10), one O(8), two equivalent O(11), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(5)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fifth W site, W(5) is bonded to one O(13), one O(9), two equivalent O(11), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the sixth W site, W(6) is bonded to one O(10), one O(14), two equivalent O(12), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(7), and two equivalent O(1) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, and corners with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-39°. In the second P site, P(2) is bonded to one O(4), one O(8), and two equivalent O(2) atoms to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, and corners with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-40°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(2) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one W(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one W(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one K(1), one W(2), and one W(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one W(3), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(4) and one P(2) atom. In the ninth O site, O(9) is bonded in a linear geometry to one W(3) and one W(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one W(4) and one W(6) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one W(4) and one W(5) atom. In the twelfth O site, O(12) is bonded in a linear geometry to one W(3) and one W(6) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to one W(1) and one W(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one W(2) and one W(6) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one W(5) and one W(6) atom.
KP2(W3O11)2 is Potassium Silver Cyanide-like structured and crystallizes in the monoclinic Pm space group. K(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. The K(1)-O(3) bond length is 2.72 Å. The K(1)-O(7) bond length is 2.71 Å. Both K(1)-O(2) bond lengths are 2.90 Å. Both K(1)-O(4) bond lengths are 2.86 Å. Both K(1)-O(6) bond lengths are 3.09 Å. There are six inequivalent W sites. In the first W site, W(1) is bonded to one O(13), one O(3), two equivalent O(2), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 1-12°. The W(1)-O(13) bond length is 1.82 Å. The W(1)-O(3) bond length is 2.07 Å. Both W(1)-O(2) bond lengths are 2.09 Å. Both W(1)-O(5) bond lengths are 1.86 Å. In the second W site, W(2) is bonded to one O(14), one O(4), two equivalent O(1), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 2-13°. The W(2)-O(14) bond length is 1.82 Å. The W(2)-O(4) bond length is 2.09 Å. Both W(2)-O(1) bond lengths are 2.07 Å. Both W(2)-O(6) bond lengths are 1.87 Å. In the third W site, W(3) is bonded to one O(7), one O(9), two equivalent O(12), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(6)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-13°. The W(3)-O(7) bond length is 2.10 Å. The W(3)-O(9) bond length is 1.86 Å. Both W(3)-O(12) bond lengths are 1.89 Å. Both W(3)-O(6) bond lengths are 2.03 Å. In the fourth W site, W(4) is bonded to one O(10), one O(8), two equivalent O(11), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(5)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-12°. The W(4)-O(10) bond length is 1.87 Å. The W(4)-O(8) bond length is 2.09 Å. Both W(4)-O(11) bond lengths are 1.89 Å. Both W(4)-O(5) bond lengths are 2.01 Å. In the fifth W site, W(5) is bonded to one O(13), one O(9), two equivalent O(11), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. The W(5)-O(13) bond length is 2.02 Å. The W(5)-O(9) bond length is 1.98 Å. Both W(5)-O(11) bond lengths are 1.97 Å. Both W(5)-O(15) bond lengths are 1.93 Å. In the sixth W site, W(6) is bonded to one O(10), one O(14), two equivalent O(12), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. The W(6)-O(10) bond length is 1.96 Å. The W(6)-O(14) bond length is 2.02 Å. Both W(6)-O(12) bond lengths are 1.97 Å. Both W(6)-O(15) bond lengths are 1.91 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(7), and two equivalent O(1) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, and corners with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-39°. The P(1)-O(3) bond length is 1.57 Å. The P(1)-O(7) bond length is 1.54 Å. Both P(1)-O(1) bond lengths are 1.54 Å. In the second P site, P(2) is bonded to one O(4), one O(8), and two equivalent O(2) atoms to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, and corners with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-40°. The P(2)-O(4) bond length is 1.57 Å. The P(2)-O(8) bond length is 1.54 Å. Both P(2)-O(2) bond lengths are 1.53 Å. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(2) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one W(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one W(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one K(1), one W(2), and one W(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one W(3), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(4) and one P(2) atom. In the ninth O site, O(9) is bonded in a linear geometry to one W(3) and one W(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one W(4) and one W(6) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one W(4) and one W(5) atom. In the twelfth O site, O(12) is bonded in a linear geometry to one W(3) and one W(6) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to one W(1) and one W(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one W(2) and one W(6) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one W(5) and one W(6) atom.