Tl(NbTe)O6 crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a NbTeO6 framework. In the NbTeO6 framework, Nb(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form NbO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-44°. Te(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-45°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Nb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Nb(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Nb(1) and one Te(1) atom.
Tl(NbTe)O6 crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a NbTeO6 framework. In the NbTeO6 framework, Nb(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form NbO6 octahedra that share corners with two equivalent Nb(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-44°. There is one shorter (1.85 Å) and one longer (2.18 Å) Nb(1)-O(2) bond length. Both Nb(1)-O(3) bond lengths are 2.00 Å. Both Nb(1)-O(4) bond lengths are 2.05 Å. Te(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Nb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-45°. Both Te(1)-O(1) bond lengths are 1.98 Å. Both Te(1)-O(3) bond lengths are 1.92 Å. Both Te(1)-O(4) bond lengths are 1.93 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Nb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Nb(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Nb(1) and one Te(1) atom.