CaAgF5 crystallizes in the triclinic P-1 space group. Ca(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Ca(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a linear geometry to one Ca(1) and one Ag(2) atom. In the third F site, F(3) is bonded in a linear geometry to one Ca(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a distorted L-shaped geometry to one Ca(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Ag(2) atom.
CaAgF5 crystallizes in the triclinic P-1 space group. Ca(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The Ca(1)-F(1) bond length is 2.41 Å. The Ca(1)-F(2) bond length is 2.73 Å. The Ca(1)-F(3) bond length is 2.90 Å. The Ca(1)-F(4) bond length is 2.04 Å. The Ca(1)-F(5) bond length is 1.82 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. Both Ag(1)-F(1) bond lengths are 1.91 Å. Both Ag(1)-F(3) bond lengths are 2.57 Å. Both Ag(1)-F(4) bond lengths are 2.19 Å. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. Both Ag(2)-F(1) bond lengths are 2.34 Å. Both Ag(2)-F(2) bond lengths are 2.61 Å. Both Ag(2)-F(5) bond lengths are 2.03 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Ca(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a linear geometry to one Ca(1) and one Ag(2) atom. In the third F site, F(3) is bonded in a linear geometry to one Ca(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a distorted L-shaped geometry to one Ca(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Ag(2) atom.