KRuO4 crystallizes in the tetragonal I4_1 space group. K(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Ru(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ru(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ru(1) atom.
KRuO4 crystallizes in the tetragonal I4_1 space group. K(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two shorter (2.78 Å) and two longer (2.79 Å) K(1)-O(1) bond lengths. There are two shorter (2.78 Å) and two longer (2.79 Å) K(1)-O(2) bond lengths. Ru(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ru(1)-O(1) bond lengths are 1.73 Å. Both Ru(1)-O(2) bond lengths are 1.73 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ru(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ru(1) atom.