InVO4 crystallizes in the monoclinic P2/c space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted VO6 octahedra that share corners with eight equivalent In(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-61°. In(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted InO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-61°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent In(1) atoms. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one In(1) atom.
InVO4 crystallizes in the monoclinic P2/c space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted VO6 octahedra that share corners with eight equivalent In(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-61°. Both V(1)-O(2) bond lengths are 1.78 Å. There are two shorter (1.89 Å) and two longer (2.09 Å) V(1)-O(1) bond lengths. In(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted InO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-61°. Both In(1)-O(1) bond lengths are 2.12 Å. There are two shorter (2.17 Å) and two longer (2.32 Å) In(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent In(1) atoms. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one In(1) atom.