CuRh2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Cu(1)O4 tetrahedra and edges with six equivalent Rh(1)O6 octahedra. Cu(1) is bonded to four equivalent O(1) atoms to form CuO4 tetrahedra that share corners with twelve equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. O(1) is bonded to three equivalent Rh(1) and one Cu(1) atom to form a mixture of distorted edge and corner-sharing OCuRh3 trigonal pyramids.
CuRh2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Cu(1)O4 tetrahedra and edges with six equivalent Rh(1)O6 octahedra. All Rh(1)-O(1) bond lengths are 2.07 Å. Cu(1) is bonded to four equivalent O(1) atoms to form CuO4 tetrahedra that share corners with twelve equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Cu(1)-O(1) bond lengths are 2.03 Å. O(1) is bonded to three equivalent Rh(1) and one Cu(1) atom to form a mixture of distorted edge and corner-sharing OCuRh3 trigonal pyramids.