LaV4Mn3O12 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Im-3m space group. La(1) is bonded to twelve equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent Mn(1)O12 cuboctahedra, faces with six equivalent Mn(1)O12 cuboctahedra, and faces with eight equivalent V(1)O6 octahedra. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent V(1)O6 octahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with six equivalent Mn(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. Mn(1) is bonded to twelve equivalent O(1) atoms to form MnO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent Mn(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent Mn(1)O12 cuboctahedra, and faces with eight equivalent V(1)O6 octahedra. O(1) is bonded in a distorted linear geometry to one La(1), two equivalent V(1), and three equivalent Mn(1) atoms.
LaV4Mn3O12 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Im-3m space group. La(1) is bonded to twelve equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent Mn(1)O12 cuboctahedra, faces with six equivalent Mn(1)O12 cuboctahedra, and faces with eight equivalent V(1)O6 octahedra. All La(1)-O(1) bond lengths are 2.73 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent V(1)O6 octahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with six equivalent Mn(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. All V(1)-O(1) bond lengths are 1.93 Å. Mn(1) is bonded to twelve equivalent O(1) atoms to form MnO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with eight equivalent Mn(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent Mn(1)O12 cuboctahedra, and faces with eight equivalent V(1)O6 octahedra. There are four shorter (2.72 Å) and eight longer (2.73 Å) Mn(1)-O(1) bond lengths. O(1) is bonded in a distorted linear geometry to one La(1), two equivalent V(1), and three equivalent Mn(1) atoms.