C2S2O2FCClF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four chlorodifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one S(2) and one O(2) atom. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one S(1), one O(1), and one F(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(3) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(3) atom.
C2S2O2FCClF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four chlorodifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one S(2) and one O(2) atom. The C(1)-S(2) bond length is 1.80 Å. The C(1)-O(2) bond length is 1.21 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one S(1), one O(1), and one F(1) atom. The C(3)-S(1) bond length is 1.77 Å. The C(3)-O(1) bond length is 1.20 Å. The C(3)-F(1) bond length is 1.37 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(3) and one S(2) atom. The S(1)-S(2) bond length is 2.04 Å. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(3) atom.