K2VAgS2 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 12-coordinate geometry to three equivalent K(1), three equivalent V(1), two equivalent Ag(1), and four equivalent S(1) atoms. V(1) is bonded in a 4-coordinate geometry to six equivalent K(1) and four equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent K(1) and two equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent K(1), two equivalent V(1), and one Ag(1) atom.
K2VAgS2 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 12-coordinate geometry to three equivalent K(1), three equivalent V(1), two equivalent Ag(1), and four equivalent S(1) atoms. There are a spread of K(1)-K(1) bond distances ranging from 3.08-3.54 Å. There are a spread of K(1)-V(1) bond distances ranging from 3.54-3.95 Å. There is one shorter (3.06 Å) and one longer (3.69 Å) K(1)-Ag(1) bond length. There are a spread of K(1)-S(1) bond distances ranging from 3.37-3.58 Å. V(1) is bonded in a 4-coordinate geometry to six equivalent K(1) and four equivalent S(1) atoms. There are two shorter (2.47 Å) and two longer (2.67 Å) V(1)-S(1) bond lengths. Ag(1) is bonded in a 4-coordinate geometry to four equivalent K(1) and two equivalent S(1) atoms. Both Ag(1)-S(1) bond lengths are 2.39 Å. S(1) is bonded in a 7-coordinate geometry to four equivalent K(1), two equivalent V(1), and one Ag(1) atom.