LaCrSbO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom.
LaCrSbO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There is one shorter (2.39 Å) and one longer (3.13 Å) La(1)-O(1) bond length. There is one shorter (2.53 Å) and one longer (3.03 Å) La(1)-O(2) bond length. There is one shorter (2.45 Å) and one longer (3.05 Å) La(1)-O(3) bond length. There is one shorter (2.49 Å) and one longer (3.06 Å) La(1)-O(4) bond length. There is one shorter (2.53 Å) and one longer (2.96 Å) La(1)-O(5) bond length. There is one shorter (2.70 Å) and one longer (2.84 Å) La(1)-O(6) bond length. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. The Cr(1)-O(1) bond length is 2.03 Å. The Cr(1)-O(2) bond length is 1.89 Å. The Cr(1)-O(3) bond length is 1.96 Å. The Cr(1)-O(4) bond length is 1.90 Å. The Cr(1)-O(5) bond length is 1.95 Å. The Cr(1)-O(6) bond length is 1.98 Å. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. The Sb(1)-O(1) bond length is 1.98 Å. The Sb(1)-O(2) bond length is 2.02 Å. The Sb(1)-O(3) bond length is 1.99 Å. The Sb(1)-O(4) bond length is 2.02 Å. The Sb(1)-O(5) bond length is 1.99 Å. The Sb(1)-O(6) bond length is 1.98 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom.