NdIrP is hexagonal omega structure-derived structured and crystallizes in the tetragonal I4_1md space group. Nd(1) is bonded to six Ir(1,1) and six equivalent P(1) atoms to form a mixture of edge and face-sharing NdP6Ir6 cuboctahedra. There are three inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent P(1) atoms. In the second Ir site, Ir(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent P(1) atoms. In the third Ir site, Ir(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three Ir(1,1) atoms.
NdIrP is hexagonal omega structure-derived structured and crystallizes in the tetragonal I4_1md space group. Nd(1) is bonded to six Ir(1,1) and six equivalent P(1) atoms to form a mixture of edge and face-sharing NdP6Ir6 cuboctahedra. There are two shorter (3.07 Å) and four longer (3.17 Å) Nd(1)-Ir(1,1) bond lengths. There are four shorter (3.11 Å) and two longer (3.18 Å) Nd(1)-P(1) bond lengths. There are three inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent P(1) atoms. There are two shorter (2.36 Å) and one longer (2.38 Å) Ir(1)-P(1) bond length. In the second Ir site, Ir(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent P(1) atoms. There are two shorter (2.36 Å) and one longer (2.38 Å) Ir(1)-P(1) bond length. In the third Ir site, Ir(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent P(1) atoms. There are two shorter (3.07 Å) and four longer (3.17 Å) Ir(1)-Nd(1) bond lengths. There are two shorter (2.36 Å) and one longer (2.38 Å) Ir(1)-P(1) bond length. P(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three Ir(1,1) atoms.