MgWAgZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted MgO5 trigonal bipyramids that share corners with two equivalent W(1)O6 octahedra, corners with three equivalent Zn(1)O4 tetrahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-62°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 tetrahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, and  a faceface with one Mg(1)O5 trigonal bipyramid. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and corners with three equivalent Mg(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 39-58°. In the second Zn site, Zn(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one W(1), one Ag(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OMgZnAgW trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Ag(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mg(1), one W(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Ag(1), and one Zn(1) atom to form a mixture of distorted edge and corner-sharing OMgZnAgW trigonal pyramids. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Ag(1), and one Zn(1) atom to form a mixture of distorted edge and corner-sharing OMgZnAgW trigonal pyramids.
MgWAgZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted MgO5 trigonal bipyramids that share corners with two equivalent W(1)O6 octahedra, corners with three equivalent Zn(1)O4 tetrahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-62°. The Mg(1)-O(1) bond length is 2.06 Å. The Mg(1)-O(2) bond length is 2.12 Å. The Mg(1)-O(4) bond length is 2.01 Å. The Mg(1)-O(5) bond length is 2.17 Å. The Mg(1)-O(6) bond length is 2.14 Å. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 tetrahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, and  a faceface with one Mg(1)O5 trigonal bipyramid. The W(1)-O(1) bond length is 1.98 Å. The W(1)-O(2) bond length is 2.19 Å. The W(1)-O(3) bond length is 2.03 Å. The W(1)-O(4) bond length is 1.92 Å. The W(1)-O(5) bond length is 1.99 Å. The W(1)-O(6) bond length is 2.07 Å. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. The Ag(1)-O(1) bond length is 2.38 Å. The Ag(1)-O(2) bond length is 2.56 Å. The Ag(1)-O(3) bond length is 2.74 Å. The Ag(1)-O(5) bond length is 2.45 Å. The Ag(1)-O(6) bond length is 2.47 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and corners with three equivalent Mg(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 39-58°. The Zn(1)-O(2) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 2.08 Å. The Zn(1)-O(5) bond length is 1.97 Å. The Zn(1)-O(6) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Zn(2)-O(1) bond length is 2.00 Å. The Zn(2)-O(2) bond length is 2.07 Å. The Zn(2)-O(3) bond length is 2.02 Å. The Zn(2)-O(4) bond length is 2.05 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one W(1), one Ag(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OMgZnAgW trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Ag(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mg(1), one W(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Ag(1), and one Zn(1) atom to form a mixture of distorted edge and corner-sharing OMgZnAgW trigonal pyramids. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Ag(1), and one Zn(1) atom to form a mixture of distorted edge and corner-sharing OMgZnAgW trigonal pyramids.