KBrF4 crystallizes in the tetragonal I4/mcm space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. Br(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a trigonal planar geometry to two equivalent K(1) and one Br(1) atom.
KBrF4 crystallizes in the tetragonal I4/mcm space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. All K(1)-F(1) bond lengths are 2.71 Å. Br(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All Br(1)-F(1) bond lengths are 1.92 Å. F(1) is bonded in a trigonal planar geometry to two equivalent K(1) and one Br(1) atom.