NbCoAs crystallizes in the orthorhombic Pnma space group. Nb(1) is bonded in a 5-coordinate geometry to five equivalent As(1) atoms. Co(1) is bonded to four equivalent As(1) atoms to form a mixture of distorted corner and edge-sharing CoAs4 tetrahedra. As(1) is bonded in a 9-coordinate geometry to five equivalent Nb(1) and four equivalent Co(1) atoms.
NbCoAs crystallizes in the orthorhombic Pnma space group. Nb(1) is bonded in a 5-coordinate geometry to five equivalent As(1) atoms. There are a spread of Nb(1)-As(1) bond distances ranging from 2.64-2.70 Å. Co(1) is bonded to four equivalent As(1) atoms to form a mixture of distorted corner and edge-sharing CoAs4 tetrahedra. There are a spread of Co(1)-As(1) bond distances ranging from 2.32-2.39 Å. As(1) is bonded in a 9-coordinate geometry to five equivalent Nb(1) and four equivalent Co(1) atoms.