CN2H5SnBr3 is alpha Rhenium trioxide-derived structured and crystallizes in the orthorhombic Amm2 space group. The structure consists of two iminomethanaminium molecules inside a SnBr3 framework. In the SnBr3 framework, Sn(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form corner-sharing SnBr6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second Br site, Br(1) is bonded in a linear geometry to two equivalent Sn(1) atoms.
CN2H5SnBr3 is alpha Rhenium trioxide-derived structured and crystallizes in the orthorhombic Amm2 space group. The structure consists of two iminomethanaminium molecules inside a SnBr3 framework. In the SnBr3 framework, Sn(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form corner-sharing SnBr6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. Both Sn(1)-Br(2) bond lengths are 3.12 Å. There are two shorter (2.96 Å) and two longer (2.97 Å) Sn(1)-Br(1) bond lengths. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second Br site, Br(1) is bonded in a linear geometry to two equivalent Sn(1) atoms.