Li2OBr crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Br(1) atoms. O(1) is bonded in a square co-planar geometry to four equivalent Li(1) atoms. Br(1) is bonded in a body-centered cubic geometry to eight equivalent Li(1) atoms.
Li2OBr crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Br(1) atoms. Both Li(1)-O(1) bond lengths are 2.01 Å. All Li(1)-Br(1) bond lengths are 2.80 Å. O(1) is bonded in a square co-planar geometry to four equivalent Li(1) atoms. Br(1) is bonded in a body-centered cubic geometry to eight equivalent Li(1) atoms.