Fe(CoN)3 crystallizes in the hexagonal P6_3/m space group. Fe(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. Co(1) is bonded in a see-saw-like geometry to four equivalent N(1) atoms. N(1) is bonded to one Fe(1) and four equivalent Co(1) atoms to form a mixture of corner and edge-sharing NFeCo4 trigonal bipyramids.
Fe(CoN)3 crystallizes in the hexagonal P6_3/m space group. Fe(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All Fe(1)-N(1) bond lengths are 1.79 Å. Co(1) is bonded in a see-saw-like geometry to four equivalent N(1) atoms. There are two shorter (1.92 Å) and two longer (1.94 Å) Co(1)-N(1) bond lengths. N(1) is bonded to one Fe(1) and four equivalent Co(1) atoms to form a mixture of corner and edge-sharing NFeCo4 trigonal bipyramids.