N(CN)2 crystallizes in the orthorhombic Cmc2_1 space group. C(1) is bonded to one N(2) and three equivalent N(1) atoms to form corner-sharing CN4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to three equivalent C(1) atoms. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms.
N(CN)2 crystallizes in the orthorhombic Cmc2_1 space group. C(1) is bonded to one N(2) and three equivalent N(1) atoms to form corner-sharing CN4 tetrahedra. The C(1)-N(2) bond length is 1.45 Å. There are a spread of C(1)-N(1) bond distances ranging from 1.45-1.48 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to three equivalent C(1) atoms. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms.