CsNH2SO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one N(1), one H(2), two equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom.
CsNH2SO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one N(1), one H(2), two equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. The Cs(1)-N(1) bond length is 3.43 Å. The Cs(1)-H(2) bond length is 3.39 Å. There is one shorter (3.22 Å) and one longer (3.25 Å) Cs(1)-O(1) bond length. There are a spread of Cs(1)-O(2) bond distances ranging from 3.16-3.52 Å. There are a spread of Cs(1)-O(3) bond distances ranging from 3.16-3.27 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one S(1) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-S(1) bond length is 1.68 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.47 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom.