S is alpha-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the second S site, S(3) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the third S site, S(2) is bonded in a water-like geometry to one S(3) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(2) and one S(4) atom.
S is alpha-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(1) and one S(3) atom. The S(1)-S(1) bond length is 2.06 Å. The S(1)-S(3) bond length is 2.05 Å. In the second S site, S(3) is bonded in a water-like geometry to one S(1) and one S(2) atom. The S(3)-S(2) bond length is 2.05 Å. In the third S site, S(2) is bonded in a water-like geometry to one S(3) and one S(4) atom. The S(2)-S(4) bond length is 2.05 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one S(2) and one S(4) atom. The S(4)-S(4) bond length is 2.04 Å.