Ag2VO2PO4 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 6-coordinate geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. P(1) is bonded in a tetrahedral geometry to one O(2), one O(5), and two equivalent O(3) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(1) and two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(1), one Ag(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), two equivalent Ag(1), and one P(1) atom.
Ag2VO2PO4 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 6-coordinate geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. The V(1)-O(4) bond length is 1.66 Å. The V(1)-O(5) bond length is 2.16 Å. There is one shorter (1.74 Å) and one longer (2.28 Å) V(1)-O(1) bond length. Both V(1)-O(3) bond lengths are 1.97 Å. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. The Ag(1)-O(1) bond length is 2.42 Å. The Ag(1)-O(2) bond length is 2.27 Å. The Ag(1)-O(3) bond length is 2.62 Å. The Ag(1)-O(5) bond length is 2.47 Å. P(1) is bonded in a tetrahedral geometry to one O(2), one O(5), and two equivalent O(3) atoms. The P(1)-O(2) bond length is 1.54 Å. The P(1)-O(5) bond length is 1.56 Å. Both P(1)-O(3) bond lengths are 1.56 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(1) and two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(1), one Ag(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), two equivalent Ag(1), and one P(1) atom.