CdSO3 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form a mixture of distorted edge and corner-sharing CdO6 pentagonal pyramids. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one S(1) atom.
CdSO3 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form a mixture of distorted edge and corner-sharing CdO6 pentagonal pyramids. There is one shorter (2.30 Å) and one longer (2.36 Å) Cd(1)-O(1) bond length. There is one shorter (2.34 Å) and one longer (2.38 Å) Cd(1)-O(2) bond length. There is one shorter (2.34 Å) and one longer (2.51 Å) Cd(1)-O(3) bond length. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.55 Å. The S(1)-O(2) bond length is 1.56 Å. The S(1)-O(3) bond length is 1.56 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one S(1) atom.