Pd3Bi is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(2) and four equivalent Bi(1) atoms. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to eight equivalent Pd(1) and six equivalent Bi(1) atoms. Bi(1) is bonded in a distorted body-centered cubic geometry to six equivalent Pd(2) and eight equivalent Pd(1) atoms.
Pd3Bi is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(2) and four equivalent Bi(1) atoms. All Pd(1)-Pd(2) bond lengths are 2.83 Å. All Pd(1)-Bi(1) bond lengths are 2.83 Å. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to eight equivalent Pd(1) and six equivalent Bi(1) atoms. All Pd(2)-Bi(1) bond lengths are 3.26 Å. Bi(1) is bonded in a distorted body-centered cubic geometry to six equivalent Pd(2) and eight equivalent Pd(1) atoms.