CeCoSb2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded to four equivalent Co(1), four equivalent Sb(1), and four equivalent Sb(2) atoms to form a mixture of corner, edge, and face-sharing CeCo4Sb8 cuboctahedra. Co(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(1) atoms. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Co(1) atoms.
CeCoSb2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded to four equivalent Co(1), four equivalent Sb(1), and four equivalent Sb(2) atoms to form a mixture of corner, edge, and face-sharing CeCo4Sb8 cuboctahedra. All Ce(1)-Co(1) bond lengths are 3.18 Å. All Ce(1)-Sb(1) bond lengths are 3.37 Å. All Ce(1)-Sb(2) bond lengths are 3.26 Å. Co(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. All Co(1)-Sb(2) bond lengths are 2.56 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(1) atoms. All Sb(1)-Sb(1) bond lengths are 3.11 Å. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Co(1) atoms.