BaMg(SbO3)2 is Ilmenite-derived structured and crystallizes in the trigonal P-31m space group. Ba(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share edges with six equivalent Sb(1)O6 octahedra. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share edges with three equivalent Mg(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. O(1) is bonded to one Ba(1), one Mg(1), and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing OBaMgSb2 trigonal pyramids.
BaMg(SbO3)2 is Ilmenite-derived structured and crystallizes in the trigonal P-31m space group. Ba(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Ba(1)-O(1) bond lengths are 2.80 Å. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share edges with six equivalent Sb(1)O6 octahedra. All Mg(1)-O(1) bond lengths are 2.15 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share edges with three equivalent Mg(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. All Sb(1)-O(1) bond lengths are 2.18 Å. O(1) is bonded to one Ba(1), one Mg(1), and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing OBaMgSb2 trigonal pyramids.