MoTcZn is half-Heusler structured and crystallizes in the cubic F-43m space group. Mo(1) is bonded in a body-centered cubic geometry to four equivalent Tc(1) and four equivalent Zn(1) atoms. Tc(1) is bonded to four equivalent Mo(1) and six equivalent Zn(1) atoms to form distorted TcZn6Mo4 tetrahedra that share corners with four equivalent Zn(1)Tc6Mo4 tetrahedra, corners with six equivalent Tc(1)Zn6Mo4 tetrahedra, edges with six equivalent Zn(1)Tc6Mo4 tetrahedra, and faces with twelve equivalent Tc(1)Zn6Mo4 tetrahedra. Zn(1) is bonded to four equivalent Mo(1) and six equivalent Tc(1) atoms to form distorted ZnTc6Mo4 tetrahedra that share corners with four equivalent Tc(1)Zn6Mo4 tetrahedra, corners with six equivalent Zn(1)Tc6Mo4 tetrahedra, edges with six equivalent Tc(1)Zn6Mo4 tetrahedra, and faces with twelve equivalent Zn(1)Tc6Mo4 tetrahedra.
MoTcZn is half-Heusler structured and crystallizes in the cubic F-43m space group. Mo(1) is bonded in a body-centered cubic geometry to four equivalent Tc(1) and four equivalent Zn(1) atoms. All Mo(1)-Tc(1) bond lengths are 2.59 Å. All Mo(1)-Zn(1) bond lengths are 2.59 Å. Tc(1) is bonded to four equivalent Mo(1) and six equivalent Zn(1) atoms to form distorted TcZn6Mo4 tetrahedra that share corners with four equivalent Zn(1)Tc6Mo4 tetrahedra, corners with six equivalent Tc(1)Zn6Mo4 tetrahedra, edges with six equivalent Zn(1)Tc6Mo4 tetrahedra, and faces with twelve equivalent Tc(1)Zn6Mo4 tetrahedra. All Tc(1)-Zn(1) bond lengths are 2.99 Å. Zn(1) is bonded to four equivalent Mo(1) and six equivalent Tc(1) atoms to form distorted ZnTc6Mo4 tetrahedra that share corners with four equivalent Tc(1)Zn6Mo4 tetrahedra, corners with six equivalent Zn(1)Tc6Mo4 tetrahedra, edges with six equivalent Tc(1)Zn6Mo4 tetrahedra, and faces with twelve equivalent Zn(1)Tc6Mo4 tetrahedra.