CoN5Br3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CoN5Br3 clusters. Co(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Co(1), two equivalent N(4), and one Br(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Co(1) and two equivalent Br(2) atoms. In the fourth N site, N(4) is bonded in a distorted L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one N(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(3) atom.
CoN5Br3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CoN5Br3 clusters. Co(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and two equivalent N(4) atoms. The Co(1)-N(1) bond length is 2.15 Å. The Co(1)-N(2) bond length is 1.56 Å. The Co(1)-N(3) bond length is 1.81 Å. Both Co(1)-N(4) bond lengths are 1.90 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Co(1), two equivalent N(4), and one Br(1) atom. Both N(1)-N(4) bond lengths are 1.28 Å. The N(1)-Br(1) bond length is 2.01 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Co(1) and two equivalent Br(2) atoms. Both N(3)-Br(2) bond lengths are 1.89 Å. In the fourth N site, N(4) is bonded in a distorted L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one N(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(3) atom.