Bi2P3(PbO4)3 crystallizes in the hexagonal P6_3/m space group. Pb(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Bi(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one P(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1), two equivalent Bi(1), and one P(1) atom.
Bi2P3(PbO4)3 crystallizes in the hexagonal P6_3/m space group. Pb(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. The Pb(1)-O(2) bond length is 2.76 Å. There are two shorter (2.61 Å) and two longer (2.69 Å) Pb(1)-O(1) bond lengths. Bi(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(3) atoms. All Bi(1)-O(2) bond lengths are 2.51 Å. All Bi(1)-O(3) bond lengths are 2.57 Å. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. The P(1)-O(2) bond length is 1.59 Å. The P(1)-O(3) bond length is 1.56 Å. Both P(1)-O(1) bond lengths are 1.56 Å. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one P(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1), two equivalent Bi(1), and one P(1) atom.