K3GeH3S3O2 crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one H(1), two equivalent S(1), two equivalent S(3), one O(1), and one O(2) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one H(3), one S(3), three equivalent S(2), one O(1), and one O(2) atom. In the third K site, K(3) is bonded in a 7-coordinate geometry to one H(3), one S(2), one S(3), two equivalent S(1), one O(1), and one O(2) atom. Ge(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one O(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one K(2), one K(3), and one O(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 1-coordinate geometry to two equivalent K(1), two equivalent K(3), and one Ge(1) atom. In the second S site, S(2) is bonded in a 1-coordinate geometry to one K(3), three equivalent K(2), and one Ge(1) atom. In the third S site, S(3) is bonded in a 5-coordinate geometry to one K(2), one K(3), two equivalent K(1), and one Ge(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one K(1), one K(2), one K(3), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(3), one Ge(1), and one H(3) atom.
K3GeH3S3O2 crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one H(1), two equivalent S(1), two equivalent S(3), one O(1), and one O(2) atom. The K(1)-H(1) bond length is 2.84 Å. There is one shorter (3.26 Å) and one longer (3.37 Å) K(1)-S(1) bond length. There is one shorter (3.29 Å) and one longer (3.30 Å) K(1)-S(3) bond length. The K(1)-O(1) bond length is 3.11 Å. The K(1)-O(2) bond length is 3.10 Å. In the second K site, K(2) is bonded in a 7-coordinate geometry to one H(3), one S(3), three equivalent S(2), one O(1), and one O(2) atom. The K(2)-H(3) bond length is 2.99 Å. The K(2)-S(3) bond length is 3.22 Å. There are a spread of K(2)-S(2) bond distances ranging from 3.35-3.50 Å. The K(2)-O(1) bond length is 2.91 Å. The K(2)-O(2) bond length is 2.86 Å. In the third K site, K(3) is bonded in a 7-coordinate geometry to one H(3), one S(2), one S(3), two equivalent S(1), one O(1), and one O(2) atom. The K(3)-H(3) bond length is 2.84 Å. The K(3)-S(2) bond length is 3.38 Å. The K(3)-S(3) bond length is 3.15 Å. There is one shorter (3.23 Å) and one longer (3.25 Å) K(3)-S(1) bond length. The K(3)-O(1) bond length is 2.85 Å. The K(3)-O(2) bond length is 2.96 Å. Ge(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one O(2) atom. The Ge(1)-S(1) bond length is 2.21 Å. The Ge(1)-S(2) bond length is 2.21 Å. The Ge(1)-S(3) bond length is 2.21 Å. The Ge(1)-O(2) bond length is 1.86 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one K(2), one K(3), and one O(2) atom. The H(3)-O(2) bond length is 1.00 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 1-coordinate geometry to two equivalent K(1), two equivalent K(3), and one Ge(1) atom. In the second S site, S(2) is bonded in a 1-coordinate geometry to one K(3), three equivalent K(2), and one Ge(1) atom. In the third S site, S(3) is bonded in a 5-coordinate geometry to one K(2), one K(3), two equivalent K(1), and one Ge(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one K(1), one K(2), one K(3), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(3), one Ge(1), and one H(3) atom.