CN2H5SnI3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the orthorhombic Amm2 space group. The structure consists of two iminomethanaminium molecules inside a SnI3 framework. In the SnI3 framework, Sn(1) is bonded to two equivalent I(2) and four equivalent I(1) atoms to form corner-sharing SnI6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. There are two inequivalent I sites. In the first I site, I(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second I site, I(1) is bonded in a linear geometry to two equivalent Sn(1) atoms.
CN2H5SnI3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the orthorhombic Amm2 space group. The structure consists of two iminomethanaminium molecules inside a SnI3 framework. In the SnI3 framework, Sn(1) is bonded to two equivalent I(2) and four equivalent I(1) atoms to form corner-sharing SnI6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. Both Sn(1)-I(2) bond lengths are 3.28 Å. There are two shorter (3.09 Å) and two longer (3.23 Å) Sn(1)-I(1) bond lengths. There are two inequivalent I sites. In the first I site, I(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second I site, I(1) is bonded in a linear geometry to two equivalent Sn(1) atoms.