TiPb3 is beta Cu3Ti-like structured and crystallizes in the trigonal P-3m1 space group. Ti(1) is bonded to twelve equivalent Pb(1) atoms to form a mixture of face and corner-sharing TiPb12 cuboctahedra. Pb(1) is bonded in a 12-coordinate geometry to four equivalent Ti(1) and eight equivalent Pb(1) atoms.
TiPb3 is beta Cu3Ti-like structured and crystallizes in the trigonal P-3m1 space group. Ti(1) is bonded to twelve equivalent Pb(1) atoms to form a mixture of face and corner-sharing TiPb12 cuboctahedra. There are a spread of Ti(1)-Pb(1) bond distances ranging from 3.27-3.47 Å. Pb(1) is bonded in a 12-coordinate geometry to four equivalent Ti(1) and eight equivalent Pb(1) atoms. There are a spread of Pb(1)-Pb(1) bond distances ranging from 3.18-3.51 Å.