XeNS2O4F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeNS2O4F3 clusters. Xe(1) is bonded in a linear geometry to one N(1) and one F(2) atom. N(1) is bonded in a trigonal planar geometry to one Xe(1), one S(1), and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(3), and one F(1) atom to form corner-sharing SNO2F tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(2), one O(4), and one F(3) atom to form corner-sharing SNO2F tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one S(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one S(1) atom.
XeNS2O4F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeNS2O4F3 clusters. Xe(1) is bonded in a linear geometry to one N(1) and one F(2) atom. The Xe(1)-N(1) bond length is 2.28 Å. The Xe(1)-F(2) bond length is 2.07 Å. N(1) is bonded in a trigonal planar geometry to one Xe(1), one S(1), and one S(2) atom. The N(1)-S(1) bond length is 1.65 Å. The N(1)-S(2) bond length is 1.65 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(3), and one F(1) atom to form corner-sharing SNO2F tetrahedra. The S(1)-O(1) bond length is 1.42 Å. The S(1)-O(3) bond length is 1.42 Å. The S(1)-F(1) bond length is 1.60 Å. In the second S site, S(2) is bonded to one N(1), one O(2), one O(4), and one F(3) atom to form corner-sharing SNO2F tetrahedra. The S(2)-O(2) bond length is 1.43 Å. The S(2)-O(4) bond length is 1.43 Å. The S(2)-F(3) bond length is 1.59 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one S(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one S(1) atom.