W7(OF5)6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three W7(OF5)6 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to six equivalent O(1) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 30°. In the second W site, W(2) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 30°. O(1) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(2) atom.
W7(OF5)6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three W7(OF5)6 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to six equivalent O(1) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 30°. All W(1)-O(1) bond lengths are 1.94 Å. In the second W site, W(2) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 30°. The W(2)-O(1) bond length is 1.92 Å. The W(2)-F(1) bond length is 1.88 Å. The W(2)-F(2) bond length is 1.88 Å. The W(2)-F(3) bond length is 1.89 Å. The W(2)-F(4) bond length is 1.88 Å. The W(2)-F(5) bond length is 1.89 Å. O(1) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(2) atom.