CeRhPb crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 11-coordinate geometry to one Rh(1), four equivalent Rh(2), and six equivalent Pb(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Pb(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Pb(1) atoms. Pb(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.
CeRhPb crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 11-coordinate geometry to one Rh(1), four equivalent Rh(2), and six equivalent Pb(1) atoms. The Ce(1)-Rh(1) bond length is 3.17 Å. All Ce(1)-Rh(2) bond lengths are 3.08 Å. There are two shorter (3.26 Å) and four longer (3.43 Å) Ce(1)-Pb(1) bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Pb(1) atoms. All Rh(1)-Pb(1) bond lengths are 2.83 Å. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Pb(1) atoms. All Rh(2)-Pb(1) bond lengths are 2.91 Å. Pb(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.