LiNi2O4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of three 12054-48-7 molecules and one Li2NiO2 cluster. In the Li2NiO2 cluster, Li(1) is bonded in a 1-coordinate geometry to one O(3) atom. Ni(3) is bonded in a distorted linear geometry to two equivalent O(3) atoms. O(3) is bonded in a distorted L-shaped geometry to one Li(1) and one Ni(3) atom.
LiNi2O4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of three 12054-48-7 molecules and one Li2NiO2 cluster. In the Li2NiO2 cluster, Li(1) is bonded in a 1-coordinate geometry to one O(3) atom. The Li(1)-O(3) bond length is 1.35 Å. Ni(3) is bonded in a distorted linear geometry to two equivalent O(3) atoms. Both Ni(3)-O(3) bond lengths are 1.41 Å. O(3) is bonded in a distorted L-shaped geometry to one Li(1) and one Ni(3) atom.