Ir(SeBr3)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ir(SeBr3)3 clusters. Ir(1) is bonded in an octahedral geometry to one Se(1), one Se(2), one Se(3), one Br(1), one Br(2), and one Br(3) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one Ir(1), one Br(4), and one Br(5) atom. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one Ir(1), one Br(6), and one Br(7) atom. In the third Se site, Se(3) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one Br(8), and one Br(9) atom. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one Ir(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Se(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Se(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Se(2) atom. In the seventh Br site, Br(7) is bonded in a single-bond geometry to one Se(2) atom. In the eighth Br site, Br(8) is bonded in a single-bond geometry to one Se(3) atom. In the ninth Br site, Br(9) is bonded in a single-bond geometry to one Se(3) atom.
Ir(SeBr3)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ir(SeBr3)3 clusters. Ir(1) is bonded in an octahedral geometry to one Se(1), one Se(2), one Se(3), one Br(1), one Br(2), and one Br(3) atom. The Ir(1)-Se(1) bond length is 2.37 Å. The Ir(1)-Se(2) bond length is 2.37 Å. The Ir(1)-Se(3) bond length is 2.38 Å. The Ir(1)-Br(1) bond length is 2.48 Å. The Ir(1)-Br(2) bond length is 2.56 Å. The Ir(1)-Br(3) bond length is 2.53 Å. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one Ir(1), one Br(4), and one Br(5) atom. The Se(1)-Br(4) bond length is 2.35 Å. The Se(1)-Br(5) bond length is 2.37 Å. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one Ir(1), one Br(6), and one Br(7) atom. The Se(2)-Br(6) bond length is 2.39 Å. The Se(2)-Br(7) bond length is 2.34 Å. In the third Se site, Se(3) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one Br(8), and one Br(9) atom. The Se(3)-Br(8) bond length is 2.36 Å. The Se(3)-Br(9) bond length is 2.38 Å. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one Ir(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Se(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Se(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Se(2) atom. In the seventh Br site, Br(7) is bonded in a single-bond geometry to one Se(2) atom. In the eighth Br site, Br(8) is bonded in a single-bond geometry to one Se(3) atom. In the ninth Br site, Br(9) is bonded in a single-bond geometry to one Se(3) atom.