NH4(IO3)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonium molecules and one IO3 cluster. In the IO3 cluster, there are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted single-bond geometry to one I(1) and one I(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one I(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one I(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one I(2) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one I(2) atom. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one I(1) and one I(3) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one I(1) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one I(3) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one I(1) and one I(2) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(3), one O(4), and one O(8) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(5), one O(7), and one O(9) atom.
NH4(IO3)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonium molecules and one IO3 cluster. In the IO3 cluster, there are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted single-bond geometry to one I(1) and one I(3) atom. The O(9)-I(1) bond length is 2.70 Å. The O(9)-I(3) bond length is 1.87 Å. In the second O site, O(1) is bonded in a single-bond geometry to one I(1) atom. The O(1)-I(1) bond length is 1.86 Å. In the third O site, O(2) is bonded in a distorted single-bond geometry to one I(1) atom. The O(2)-I(1) bond length is 1.83 Å. In the fourth O site, O(3) is bonded in a single-bond geometry to one I(2) atom. The O(3)-I(2) bond length is 1.84 Å. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one I(2) atom. The O(4)-I(2) bond length is 1.85 Å. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one I(1) and one I(3) atom. The O(5)-I(1) bond length is 2.37 Å. The O(5)-I(3) bond length is 1.85 Å. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one I(1) atom. The O(6)-I(1) bond length is 1.87 Å. In the eighth O site, O(7) is bonded in a single-bond geometry to one I(3) atom. The O(7)-I(3) bond length is 1.83 Å. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one I(1) and one I(2) atom. The O(8)-I(1) bond length is 2.64 Å. The O(8)-I(2) bond length is 1.85 Å. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(3), one O(4), and one O(8) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(5), one O(7), and one O(9) atom.