PrSO4Cl crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), and three equivalent Cl(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Pr(1) and one S(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Pr(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Pr(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one S(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent Pr(1) atoms.
PrSO4Cl crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), and three equivalent Cl(1) atoms. The Pr(1)-O(1) bond length is 2.43 Å. The Pr(1)-O(2) bond length is 2.52 Å. The Pr(1)-O(4) bond length is 2.48 Å. Both Pr(1)-O(3) bond lengths are 2.55 Å. There are a spread of Pr(1)-Cl(1) bond distances ranging from 2.92-2.94 Å. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.49 Å. The S(1)-O(3) bond length is 1.52 Å. The S(1)-O(4) bond length is 1.48 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Pr(1) and one S(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Pr(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Pr(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one S(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent Pr(1) atoms.