CaZrF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedra are not tilted. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Ca(1) and one Zr(1) atom.
CaZrF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Ca(1)-F(1) bond lengths are 2.25 Å. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Zr(1)-F(1) bond lengths are 2.02 Å. F(1) is bonded in a linear geometry to one Ca(1) and one Zr(1) atom.