NOOBrF4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four OBrF4 clusters. In each OBrF4 cluster, O(1) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a square pyramidal geometry to one O(1), two equivalent F(1), and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Br(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Br(1) atom.
NOOBrF4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four OBrF4 clusters. In each OBrF4 cluster, O(1) is bonded in a single-bond geometry to one Br(1) atom. The O(1)-Br(1) bond length is 1.60 Å. Br(1) is bonded in a square pyramidal geometry to one O(1), two equivalent F(1), and two equivalent F(2) atoms. Both Br(1)-F(1) bond lengths are 1.97 Å. Both Br(1)-F(2) bond lengths are 1.93 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Br(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Br(1) atom.