K2PtS6 crystallizes in the triclinic P-1 space group. K(1) is bonded in a distorted square co-planar geometry to one S(2), one S(3), and two equivalent S(1) atoms. Pt(1) is bonded in a distorted octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Pt(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(3) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(2) atom.
K2PtS6 crystallizes in the triclinic P-1 space group. K(1) is bonded in a distorted square co-planar geometry to one S(2), one S(3), and two equivalent S(1) atoms. The K(1)-S(2) bond length is 3.26 Å. The K(1)-S(3) bond length is 3.24 Å. Both K(1)-S(1) bond lengths are 3.09 Å. Pt(1) is bonded in a distorted octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. Both Pt(1)-S(1) bond lengths are 2.33 Å. Both Pt(1)-S(2) bond lengths are 2.39 Å. Both Pt(1)-S(3) bond lengths are 2.39 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Pt(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(3) atom. The S(2)-S(3) bond length is 2.05 Å. In the third S site, S(3) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one S(2) atom.