N3S4Te2Cl9 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two N3S4 clusters and one Te2Cl9 cluster. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(3) atom. In the Te2Cl9 cluster, there are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and one Cl(8) atom to form distorted corner-sharing TeCl5 square pyramids. The corner-sharing octahedral tilt angles are 64°. In the second Te site, Te(2) is bonded to one Cl(1), one Cl(2), one Cl(7), one Cl(9), and two equivalent Cl(3) atoms to form TeCl6 octahedra that share  a cornercorner with one Te(1)Cl5 square pyramid and  an edgeedge with one Te(2)Cl6 octahedra. There are nine inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the fourth Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Te(2) atoms. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(7) is bonded in a single-bond geometry to one Te(2) atom. In the ninth Cl site, Cl(8) is bonded in a single-bond geometry to one Te(1) atom.
N3S4Te2Cl9 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two N3S4 clusters and one Te2Cl9 cluster. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. The N(1)-S(2) bond length is 1.56 Å. The N(1)-S(3) bond length is 1.56 Å. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.57 Å. The N(2)-S(2) bond length is 1.57 Å. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. The N(3)-S(1) bond length is 1.56 Å. The N(3)-S(4) bond length is 1.57 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(3) atom. In the Te2Cl9 cluster, there are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and one Cl(8) atom to form distorted corner-sharing TeCl5 square pyramids. The corner-sharing octahedral tilt angles are 64°. The Te(1)-Cl(1) bond length is 2.88 Å. The Te(1)-Cl(4) bond length is 2.36 Å. The Te(1)-Cl(5) bond length is 2.52 Å. The Te(1)-Cl(6) bond length is 2.61 Å. The Te(1)-Cl(8) bond length is 2.40 Å. In the second Te site, Te(2) is bonded to one Cl(1), one Cl(2), one Cl(7), one Cl(9), and two equivalent Cl(3) atoms to form TeCl6 octahedra that share  a cornercorner with one Te(1)Cl5 square pyramid and  an edgeedge with one Te(2)Cl6 octahedra. The Te(2)-Cl(1) bond length is 2.85 Å. The Te(2)-Cl(2) bond length is 2.42 Å. The Te(2)-Cl(7) bond length is 2.38 Å. The Te(2)-Cl(9) bond length is 2.40 Å. There is one shorter (2.78 Å) and one longer (2.98 Å) Te(2)-Cl(3) bond length. There are nine inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the fourth Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Te(2) atoms. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(7) is bonded in a single-bond geometry to one Te(2) atom. In the ninth Cl site, Cl(8) is bonded in a single-bond geometry to one Te(1) atom.