BiVO4 crystallizes in the triclinic P1 space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Bi(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom.
BiVO4 crystallizes in the triclinic P1 space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The V(1)-O(1) bond length is 1.78 Å. The V(1)-O(2) bond length is 1.72 Å. The V(1)-O(3) bond length is 1.72 Å. The V(1)-O(4) bond length is 1.78 Å. Bi(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Bi(1)-O(1) bond length is 2.18 Å. The Bi(1)-O(2) bond length is 2.33 Å. The Bi(1)-O(3) bond length is 2.33 Å. The Bi(1)-O(4) bond length is 2.18 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one V(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Bi(1) atom.