Ag2CO3 crystallizes in the monoclinic P2_1/m space group. Ag(1) is bonded in a 4-coordinate geometry to one O(2) and three equivalent O(1) atoms. C(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one C(1) atom. In the second O site, O(1) is bonded in a 1-coordinate geometry to three equivalent Ag(1) and one C(1) atom.
Ag2CO3 crystallizes in the monoclinic P2_1/m space group. Ag(1) is bonded in a 4-coordinate geometry to one O(2) and three equivalent O(1) atoms. The Ag(1)-O(2) bond length is 2.21 Å. There are a spread of Ag(1)-O(1) bond distances ranging from 2.23-2.69 Å. C(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. The C(1)-O(2) bond length is 1.30 Å. Both C(1)-O(1) bond lengths are 1.29 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one C(1) atom. In the second O site, O(1) is bonded in a 1-coordinate geometry to three equivalent Ag(1) and one C(1) atom.