SrOCl2 crystallizes in the orthorhombic Pnma space group. Sr(1) is bonded in a 9-coordinate geometry to two equivalent O(1), three equivalent Cl(2), and four equivalent Cl(1) atoms. O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Sr(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Sr(1) and one O(1) atom. In the second Cl site, Cl(1) is bonded in a 4-coordinate geometry to four equivalent Sr(1) atoms.
SrOCl2 crystallizes in the orthorhombic Pnma space group. Sr(1) is bonded in a 9-coordinate geometry to two equivalent O(1), three equivalent Cl(2), and four equivalent Cl(1) atoms. Both Sr(1)-O(1) bond lengths are 2.54 Å. There is one shorter (3.02 Å) and two longer (3.09 Å) Sr(1)-Cl(2) bond lengths. There are a spread of Sr(1)-Cl(1) bond distances ranging from 3.08-3.14 Å. O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Sr(1) and one Cl(2) atom. The O(1)-Cl(2) bond length is 2.42 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a 4-coordinate geometry to three equivalent Sr(1) and one O(1) atom. In the second Cl site, Cl(1) is bonded in a 4-coordinate geometry to four equivalent Sr(1) atoms.