CuOCl2ClO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hypochlorous acid molecules and two CuOCl2 clusters. In each CuOCl2 cluster, Cu(1) is bonded to one O(2), one Cl(1), and two equivalent Cl(3) atoms to form distorted edge-sharing CuCl3O tetrahedra. O(2) is bonded in a single-bond geometry to one Cu(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms.
CuOCl2ClO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hypochlorous acid molecules and two CuOCl2 clusters. In each CuOCl2 cluster, Cu(1) is bonded to one O(2), one Cl(1), and two equivalent Cl(3) atoms to form distorted edge-sharing CuCl3O tetrahedra. The Cu(1)-O(2) bond length is 1.74 Å. The Cu(1)-Cl(1) bond length is 2.19 Å. There is one shorter (2.30 Å) and one longer (2.33 Å) Cu(1)-Cl(3) bond length. O(2) is bonded in a single-bond geometry to one Cu(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms.