LiOBr crystallizes in the orthorhombic Pmma space group. Li(1) is bonded in a 2-coordinate geometry to two equivalent O(1) and four equivalent Br(1) atoms. O(1) is bonded in a linear geometry to two equivalent Li(1) atoms. Br(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Li(1) atoms.
LiOBr crystallizes in the orthorhombic Pmma space group. Li(1) is bonded in a 2-coordinate geometry to two equivalent O(1) and four equivalent Br(1) atoms. Both Li(1)-O(1) bond lengths are 1.95 Å. There are two shorter (2.73 Å) and two longer (2.95 Å) Li(1)-Br(1) bond lengths. O(1) is bonded in a linear geometry to two equivalent Li(1) atoms. Br(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Li(1) atoms.