Re3SeBr6Re3Se3Br4(Re3Se2Br5)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re3Se2Br5 cluster, one Re3Se3Br4 cluster, and one Re3SeBr6 cluster. In the Re3Se2Br5 cluster, there are six inequivalent Re sites. In the first Re site, Re(4) is bonded to one Se(3), one Se(5), one Br(3), one Br(4), and one Br(7) atom to form distorted edge-sharing ReSe2Br3 square pyramids. In the second Re site, Re(5) is bonded to one Se(3), one Se(6), one Br(12), one Br(4), and one Br(6) atom to form distorted edge-sharing ReSe2Br3 square pyramids. In the third Re site, Re(6) is bonded in a distorted see-saw-like geometry to one Se(5), one Se(8), one Br(12), and one Br(4) atom. In the fourth Re site, Re(7) is bonded to one Se(3), one Se(6), one Br(15), one Br(7), and one Br(9) atom to form distorted edge-sharing ReSe2Br3 square pyramids. In the fifth Re site, Re(8) is bonded in a 4-coordinate geometry to one Se(5), one Br(13), one Br(15), and one Br(7) atom. In the sixth Re site, Re(9) is bonded in a distorted see-saw-like geometry to one Se(6), one Br(12), one Br(15), and one Br(17) atom. There are four inequivalent Se sites. In the first Se site, Se(3) is bonded in a 3-coordinate geometry to one Re(4), one Re(5), and one Re(7) atom. In the second Se site, Se(5) is bonded in a 3-coordinate geometry to one Re(4), one Re(6), and one Re(8) atom. In the third Se site, Se(6) is bonded in a 3-coordinate geometry to one Re(5), one Re(7), and one Re(9) atom. In the fourth Se site, Se(8) is bonded in a bent 120 degrees geometry to one Re(6) and one Br(10) atom. There are ten inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Re(4) atom. In the second Br site, Br(4) is bonded in a 3-coordinate geometry to one Re(4), one Re(5), and one Re(6) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one Re(5) atom. In the fourth Br site, Br(7) is bonded in a 3-coordinate geometry to one Re(4), one Re(7), and one Re(8) atom. In the fifth Br site, Br(9) is bonded in a single-bond geometry to one Re(7) atom. In the sixth Br site, Br(10) is bonded in a single-bond geometry to one Se(8) atom. In the seventh Br site, Br(12) is bonded in a 3-coordinate geometry to one Re(5), one Re(6), and one Re(9) atom. In the eighth Br site, Br(13) is bonded in a single-bond geometry to one Re(8) atom. In the ninth Br site, Br(15) is bonded in a 3-coordinate geometry to one Re(7), one Re(8), and one Re(9) atom. In the tenth Br site, Br(17) is bonded in a single-bond geometry to one Re(9) atom. In the Re3Se3Br4 cluster, there are three inequivalent Re sites. In the first Re site, Re(3) is bonded in a 4-coordinate geometry to one Se(1), one Se(2), one Br(11), and one Br(5) atom. In the second Re site, Re(11) is bonded in a 4-coordinate geometry to one Se(1), one Se(7), one Br(20), and one Br(5) atom. In the third Re site, Re(12) is bonded in a 4-coordinate geometry to one Se(1), one Se(2), one Se(7), and one Br(18) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(11), one Re(12), and one Re(3) atom. In the second Se site, Se(2) is bonded in a 2-coordinate geometry to one Re(12) and one Re(3) atom. In the third Se site, Se(7) is bonded in a 2-coordinate geometry to one Re(11) and one Re(12) atom. There are four inequivalent Br sites. In the first Br site, Br(18) is bonded in a single-bond geometry to one Re(12) atom. In the second Br site, Br(20) is bonded in a single-bond geometry to one Re(11) atom. In the third Br site, Br(5) is bonded in a 2-coordinate geometry to one Re(11) and one Re(3) atom. In the fourth Br site, Br(11) is bonded in a single-bond geometry to one Re(3) atom. In the Re3SeBr6 cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 2-coordinate geometry to one Re(10), one Br(19), and one Br(2) atom. In the second Re site, Re(2) is bonded in a distorted trigonal non-coplanar geometry to one Re(10), one Se(4), one Br(1), and one Br(14) atom. In the third Re site, Re(10) is bonded in a 5-coordinate geometry to one Re(1), one Re(2), one Br(14), one Br(16), and one Br(8) atom. Se(4) is bonded in a single-bond geometry to one Re(2) atom. There are six inequivalent Br sites. In the first Br site, Br(14) is bonded in a 2-coordinate geometry to one Re(10) and one Re(2) atom. In the second Br site, Br(16) is bonded in a single-bond geometry to one Re(10) atom. In the third Br site, Br(19) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Br site, Br(1) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Br site, Br(2) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one Re(10) atom.
Re3SeBr6Re3Se3Br4(Re3Se2Br5)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re3Se2Br5 cluster, one Re3Se3Br4 cluster, and one Re3SeBr6 cluster. In the Re3Se2Br5 cluster, there are six inequivalent Re sites. In the first Re site, Re(4) is bonded to one Se(3), one Se(5), one Br(3), one Br(4), and one Br(7) atom to form distorted edge-sharing ReSe2Br3 square pyramids. The Re(4)-Se(3) bond length is 2.55 Å. The Re(4)-Se(5) bond length is 2.55 Å. The Re(4)-Br(3) bond length is 2.52 Å. The Re(4)-Br(4) bond length is 2.61 Å. The Re(4)-Br(7) bond length is 2.62 Å. In the second Re site, Re(5) is bonded to one Se(3), one Se(6), one Br(12), one Br(4), and one Br(6) atom to form distorted edge-sharing ReSe2Br3 square pyramids. The Re(5)-Se(3) bond length is 2.50 Å. The Re(5)-Se(6) bond length is 2.51 Å. The Re(5)-Br(12) bond length is 2.63 Å. The Re(5)-Br(4) bond length is 2.72 Å. The Re(5)-Br(6) bond length is 2.52 Å. In the third Re site, Re(6) is bonded in a distorted see-saw-like geometry to one Se(5), one Se(8), one Br(12), and one Br(4) atom. The Re(6)-Se(5) bond length is 2.49 Å. The Re(6)-Se(8) bond length is 2.46 Å. The Re(6)-Br(12) bond length is 2.67 Å. The Re(6)-Br(4) bond length is 2.69 Å. In the fourth Re site, Re(7) is bonded to one Se(3), one Se(6), one Br(15), one Br(7), and one Br(9) atom to form distorted edge-sharing ReSe2Br3 square pyramids. The Re(7)-Se(3) bond length is 2.49 Å. The Re(7)-Se(6) bond length is 2.52 Å. The Re(7)-Br(15) bond length is 2.67 Å. The Re(7)-Br(7) bond length is 2.67 Å. The Re(7)-Br(9) bond length is 2.52 Å. In the fifth Re site, Re(8) is bonded in a 4-coordinate geometry to one Se(5), one Br(13), one Br(15), and one Br(7) atom. The Re(8)-Se(5) bond length is 2.50 Å. The Re(8)-Br(13) bond length is 2.46 Å. The Re(8)-Br(15) bond length is 2.64 Å. The Re(8)-Br(7) bond length is 2.77 Å. In the sixth Re site, Re(9) is bonded in a distorted see-saw-like geometry to one Se(6), one Br(12), one Br(15), and one Br(17) atom. The Re(9)-Se(6) bond length is 2.56 Å. The Re(9)-Br(12) bond length is 2.60 Å. The Re(9)-Br(15) bond length is 2.57 Å. The Re(9)-Br(17) bond length is 2.48 Å. There are four inequivalent Se sites. In the first Se site, Se(3) is bonded in a 3-coordinate geometry to one Re(4), one Re(5), and one Re(7) atom. In the second Se site, Se(5) is bonded in a 3-coordinate geometry to one Re(4), one Re(6), and one Re(8) atom. In the third Se site, Se(6) is bonded in a 3-coordinate geometry to one Re(5), one Re(7), and one Re(9) atom. In the fourth Se site, Se(8) is bonded in a bent 120 degrees geometry to one Re(6) and one Br(10) atom. The Se(8)-Br(10) bond length is 2.36 Å. There are ten inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Re(4) atom. In the second Br site, Br(4) is bonded in a 3-coordinate geometry to one Re(4), one Re(5), and one Re(6) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one Re(5) atom. In the fourth Br site, Br(7) is bonded in a 3-coordinate geometry to one Re(4), one Re(7), and one Re(8) atom. In the fifth Br site, Br(9) is bonded in a single-bond geometry to one Re(7) atom. In the sixth Br site, Br(10) is bonded in a single-bond geometry to one Se(8) atom. In the seventh Br site, Br(12) is bonded in a 3-coordinate geometry to one Re(5), one Re(6), and one Re(9) atom. In the eighth Br site, Br(13) is bonded in a single-bond geometry to one Re(8) atom. In the ninth Br site, Br(15) is bonded in a 3-coordinate geometry to one Re(7), one Re(8), and one Re(9) atom. In the tenth Br site, Br(17) is bonded in a single-bond geometry to one Re(9) atom. In the Re3Se3Br4 cluster, there are three inequivalent Re sites. In the first Re site, Re(3) is bonded in a 4-coordinate geometry to one Se(1), one Se(2), one Br(11), and one Br(5) atom. The Re(3)-Se(1) bond length is 2.45 Å. The Re(3)-Se(2) bond length is 2.43 Å. The Re(3)-Br(11) bond length is 2.48 Å. The Re(3)-Br(5) bond length is 2.61 Å. In the second Re site, Re(11) is bonded in a 4-coordinate geometry to one Se(1), one Se(7), one Br(20), and one Br(5) atom. The Re(11)-Se(1) bond length is 2.46 Å. The Re(11)-Se(7) bond length is 2.35 Å. The Re(11)-Br(20) bond length is 2.46 Å. The Re(11)-Br(5) bond length is 2.59 Å. In the third Re site, Re(12) is bonded in a 4-coordinate geometry to one Se(1), one Se(2), one Se(7), and one Br(18) atom. The Re(12)-Se(1) bond length is 2.45 Å. The Re(12)-Se(2) bond length is 2.44 Å. The Re(12)-Se(7) bond length is 2.52 Å. The Re(12)-Br(18) bond length is 2.46 Å. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(11), one Re(12), and one Re(3) atom. In the second Se site, Se(2) is bonded in a 2-coordinate geometry to one Re(12) and one Re(3) atom. In the third Se site, Se(7) is bonded in a 2-coordinate geometry to one Re(11) and one Re(12) atom. There are four inequivalent Br sites. In the first Br site, Br(18) is bonded in a single-bond geometry to one Re(12) atom. In the second Br site, Br(20) is bonded in a single-bond geometry to one Re(11) atom. In the third Br site, Br(5) is bonded in a 2-coordinate geometry to one Re(11) and one Re(3) atom. In the fourth Br site, Br(11) is bonded in a single-bond geometry to one Re(3) atom. In the Re3SeBr6 cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 2-coordinate geometry to one Re(10), one Br(19), and one Br(2) atom. The Re(1)-Re(10) bond length is 2.26 Å. The Re(1)-Br(19) bond length is 2.37 Å. The Re(1)-Br(2) bond length is 2.38 Å. In the second Re site, Re(2) is bonded in a distorted trigonal non-coplanar geometry to one Re(10), one Se(4), one Br(1), and one Br(14) atom. The Re(2)-Re(10) bond length is 2.54 Å. The Re(2)-Se(4) bond length is 2.25 Å. The Re(2)-Br(1) bond length is 2.41 Å. The Re(2)-Br(14) bond length is 2.52 Å. In the third Re site, Re(10) is bonded in a 5-coordinate geometry to one Re(1), one Re(2), one Br(14), one Br(16), and one Br(8) atom. The Re(10)-Br(14) bond length is 2.76 Å. The Re(10)-Br(16) bond length is 2.40 Å. The Re(10)-Br(8) bond length is 2.41 Å. Se(4) is bonded in a single-bond geometry to one Re(2) atom. There are six inequivalent Br sites. In the first Br site, Br(14) is bonded in a 2-coordinate geometry to one Re(10) and one Re(2) atom. In the second Br site, Br(16) is bonded in a single-bond geometry to one Re(10) atom. In the third Br site, Br(19) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Br site, Br(1) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Br site, Br(2) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one Re(10) atom.