LaTiSbO6 is Hydrophilite-derived structured and crystallizes in the trigonal P312 space group. La(1) is bonded to six equivalent O(1) atoms to form LaO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. O(1) is bonded in a distorted trigonal planar geometry to one La(1), one Ti(1), and one Sb(1) atom.
LaTiSbO6 is Hydrophilite-derived structured and crystallizes in the trigonal P312 space group. La(1) is bonded to six equivalent O(1) atoms to form LaO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. All La(1)-O(1) bond lengths are 2.47 Å. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Ti(1)-O(1) bond lengths are 1.99 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. All Sb(1)-O(1) bond lengths are 2.01 Å. O(1) is bonded in a distorted trigonal planar geometry to one La(1), one Ti(1), and one Sb(1) atom.