CNH3OF3AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two CNH3OF3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In each CNH3OF3 cluster, C(1) is bonded in a tetrahedral geometry to one N(1), one F(7), one F(8), and one F(9) atom. N(1) is bonded in a tetrahedral geometry to one C(1), one H(1), one H(2), and one O(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one N(1) and one H(3) atom. There are three inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(9) is bonded in a single-bond geometry to one C(1) atom.
CNH3OF3AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two CNH3OF3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.78 Å. The As(1)-F(2) bond length is 1.79 Å. The As(1)-F(3) bond length is 1.79 Å. The As(1)-F(4) bond length is 1.77 Å. The As(1)-F(5) bond length is 1.77 Å. The As(1)-F(6) bond length is 1.76 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In each CNH3OF3 cluster, C(1) is bonded in a tetrahedral geometry to one N(1), one F(7), one F(8), and one F(9) atom. The C(1)-N(1) bond length is 1.53 Å. The C(1)-F(7) bond length is 1.33 Å. The C(1)-F(8) bond length is 1.34 Å. The C(1)-F(9) bond length is 1.33 Å. N(1) is bonded in a tetrahedral geometry to one C(1), one H(1), one H(2), and one O(1) atom. The N(1)-H(1) bond length is 1.05 Å. The N(1)-H(2) bond length is 1.05 Å. The N(1)-O(1) bond length is 1.41 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 0.99 Å. O(1) is bonded in a water-like geometry to one N(1) and one H(3) atom. There are three inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(9) is bonded in a single-bond geometry to one C(1) atom.