Ce2Ru2In3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 13-coordinate geometry to two equivalent Ru(1), two equivalent Ru(2), three equivalent In(1), three equivalent In(2), and three equivalent In(3) atoms. In the second Ce site, Ce(2) is bonded in a distorted bent 150 degrees geometry to one Ru(1), one Ru(2), two equivalent In(1), two equivalent In(3), and three equivalent In(2) atoms. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a distorted single-bond geometry to one Ce(2), two equivalent Ce(1), one In(3), and three equivalent In(2) atoms. In the second Ru site, Ru(2) is bonded in a distorted single-bond geometry to one Ce(2), two equivalent Ce(1), three equivalent In(1), and three equivalent In(3) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), three equivalent Ru(2), one In(2), and three equivalent In(3) atoms. In the second In site, In(2) is bonded in a 12-coordinate geometry to three equivalent Ce(1), three equivalent Ce(2), three equivalent Ru(1), one In(1), and two equivalent In(2) atoms. In the third In site, In(3) is bonded in a 12-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), one Ru(1), three equivalent Ru(2), and three equivalent In(1) atoms.
Ce2Ru2In3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 13-coordinate geometry to two equivalent Ru(1), two equivalent Ru(2), three equivalent In(1), three equivalent In(2), and three equivalent In(3) atoms. Both Ce(1)-Ru(1) bond lengths are 3.52 Å. Both Ce(1)-Ru(2) bond lengths are 3.49 Å. There is one shorter (3.20 Å) and two longer (3.31 Å) Ce(1)-In(1) bond lengths. There is one shorter (3.21 Å) and two longer (3.44 Å) Ce(1)-In(2) bond lengths. There are two shorter (3.31 Å) and one longer (3.34 Å) Ce(1)-In(3) bond length. In the second Ce site, Ce(2) is bonded in a distorted bent 150 degrees geometry to one Ru(1), one Ru(2), two equivalent In(1), two equivalent In(3), and three equivalent In(2) atoms. The Ce(2)-Ru(1) bond length is 2.28 Å. The Ce(2)-Ru(2) bond length is 2.32 Å. Both Ce(2)-In(1) bond lengths are 3.56 Å. Both Ce(2)-In(3) bond lengths are 3.39 Å. There are two shorter (3.45 Å) and one longer (3.75 Å) Ce(2)-In(2) bond length. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a distorted single-bond geometry to one Ce(2), two equivalent Ce(1), one In(3), and three equivalent In(2) atoms. The Ru(1)-In(3) bond length is 2.84 Å. There are two shorter (2.79 Å) and one longer (2.88 Å) Ru(1)-In(2) bond length. In the second Ru site, Ru(2) is bonded in a distorted single-bond geometry to one Ce(2), two equivalent Ce(1), three equivalent In(1), and three equivalent In(3) atoms. There is one shorter (2.82 Å) and two longer (2.84 Å) Ru(2)-In(1) bond lengths. There are two shorter (2.87 Å) and one longer (2.93 Å) Ru(2)-In(3) bond length. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), three equivalent Ru(2), one In(2), and three equivalent In(3) atoms. The In(1)-In(2) bond length is 2.97 Å. There is one shorter (3.12 Å) and two longer (3.28 Å) In(1)-In(3) bond lengths. In the second In site, In(2) is bonded in a 12-coordinate geometry to three equivalent Ce(1), three equivalent Ce(2), three equivalent Ru(1), one In(1), and two equivalent In(2) atoms. Both In(2)-In(2) bond lengths are 3.22 Å. In the third In site, In(3) is bonded in a 12-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), one Ru(1), three equivalent Ru(2), and three equivalent In(1) atoms.