ZnPbF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Pb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. Pb(1) is bonded to six equivalent F(1) atoms to form PbF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Pb(1) atom.
ZnPbF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Pb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Zn(1)-F(1) bond lengths are 2.02 Å. Pb(1) is bonded to six equivalent F(1) atoms to form PbF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Pb(1)-F(1) bond lengths are 2.09 Å. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Pb(1) atom.