KPrInSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Pr(1)O12 cuboctahedra, faces with four equivalent In(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Pr(1) is bonded to twelve equivalent O(1) atoms to form PrO12 cuboctahedra that share corners with twelve equivalent Pr(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent In(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent In(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent K(1), two equivalent Pr(1), one In(1), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing OK2Pr2InSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
KPrInSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Pr(1)O12 cuboctahedra, faces with four equivalent In(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.90 Å. Pr(1) is bonded to twelve equivalent O(1) atoms to form PrO12 cuboctahedra that share corners with twelve equivalent Pr(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent In(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. All Pr(1)-O(1) bond lengths are 2.90 Å. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-O(1) bond lengths are 2.12 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent In(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Sb(1)-O(1) bond lengths are 1.98 Å. O(1) is bonded to two equivalent K(1), two equivalent Pr(1), one In(1), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing OK2Pr2InSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°.