ZnSnP2 is Chalcopyrite-like structured and crystallizes in the tetragonal P-4m2 space group. Zn(1) is bonded to four equivalent P(1) atoms to form ZnP4 tetrahedra that share corners with four equivalent Zn(1)P4 tetrahedra and corners with eight equivalent Sn(1)P4 tetrahedra. Sn(1) is bonded to four equivalent P(1) atoms to form SnP4 tetrahedra that share corners with four equivalent Sn(1)P4 tetrahedra and corners with eight equivalent Zn(1)P4 tetrahedra. P(1) is bonded to two equivalent Zn(1) and two equivalent Sn(1) atoms to form corner-sharing PZn2Sn2 tetrahedra.
ZnSnP2 is Chalcopyrite-like structured and crystallizes in the tetragonal P-4m2 space group. Zn(1) is bonded to four equivalent P(1) atoms to form ZnP4 tetrahedra that share corners with four equivalent Zn(1)P4 tetrahedra and corners with eight equivalent Sn(1)P4 tetrahedra. All Zn(1)-P(1) bond lengths are 2.37 Å. Sn(1) is bonded to four equivalent P(1) atoms to form SnP4 tetrahedra that share corners with four equivalent Sn(1)P4 tetrahedra and corners with eight equivalent Zn(1)P4 tetrahedra. All Sn(1)-P(1) bond lengths are 2.52 Å. P(1) is bonded to two equivalent Zn(1) and two equivalent Sn(1) atoms to form corner-sharing PZn2Sn2 tetrahedra.