TiN2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. N(1) is bonded in a 5-coordinate geometry to four equivalent Ti(1) and one N(1) atom.
TiN2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. All Ti(1)-N(1) bond lengths are 2.20 Å. N(1) is bonded in a 5-coordinate geometry to four equivalent Ti(1) and one N(1) atom. The N(1)-N(1) bond length is 1.38 Å.