NiH6(NO)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four sulfur trioxide molecules, and two NiH6 clusters. In each NiH6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent H(1), two equivalent H(2), and two equivalent H(3) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a 2-coordinate geometry to one Ni(1) and one H(3) atom. In the second H site, H(3) is bonded in a 2-coordinate geometry to one Ni(1) and one H(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one Ni(1) atom.
NiH6(NO)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four sulfur trioxide molecules, and two NiH6 clusters. In each NiH6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent H(1), two equivalent H(2), and two equivalent H(3) atoms. Both Ni(1)-H(1) bond lengths are 1.54 Å. Both Ni(1)-H(2) bond lengths are 1.49 Å. Both Ni(1)-H(3) bond lengths are 1.53 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a 2-coordinate geometry to one Ni(1) and one H(3) atom. The H(1)-H(3) bond length is 0.88 Å. In the second H site, H(3) is bonded in a 2-coordinate geometry to one Ni(1) and one H(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one Ni(1) atom.