AgZn3GaS5 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form AgS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Ga(1)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. In the second Ag site, Ag(2) is bonded to one S(2), one S(3), one S(4), and one S(9) atom to form AgS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Ga(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(1)S4 tetrahedra. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(3), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(1)S4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(10), one S(4), one S(6), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ga(1)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. In the third Zn site, Zn(3) is bonded to one S(10), one S(5), one S(6), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Ga(1)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. In the fourth Zn site, Zn(4) is bonded to one S(1), one S(2), one S(5), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Zn(6)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Ga(1)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. In the fifth Zn site, Zn(5) is bonded to one S(1), one S(2), one S(3), and one S(8) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(6)S4 tetrahedra,  a cornercorner with one Ga(2)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Ga(1)S4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one S(10), one S(3), one S(4), and one S(5) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one S(2), one S(7), one S(8), and one S(9) atom to form GaS4 tetrahedra that share  a cornercorner with one Zn(2)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(5)S4 tetrahedra. In the second Ga site, Ga(2) is bonded to one S(1), one S(4), one S(5), and one S(6) atom to form GaS4 tetrahedra that share  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(6)S4 tetrahedra. There are ten inequivalent S sites. In the first S site, S(1) is bonded to one Ag(1), one Zn(4), one Zn(5), and one Ga(2) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(4)Zn2GaAg tetrahedra,  a cornercorner with one S(3)Zn3Ag tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, and corners with two equivalent S(5)Zn3Ga tetrahedra. In the second S site, S(2) is bonded to one Ag(2), one Zn(4), one Zn(5), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(4)Zn2GaAg tetrahedra,  a cornercorner with one S(5)Zn3Ga tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, and corners with two equivalent S(3)Zn3Ag tetrahedra. In the third S site, S(3) is bonded to one Ag(2), one Zn(1), one Zn(5), and one Zn(6) atom to form SZn3Ag tetrahedra that share  a cornercorner with one S(1)Zn2GaAg tetrahedra,  a cornercorner with one S(5)Zn3Ga tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fourth S site, S(4) is bonded to one Ag(2), one Zn(2), one Zn(6), and one Ga(2) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(1)Zn2GaAg tetrahedra,  a cornercorner with one S(2)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, corners with two equivalent S(3)Zn3Ag tetrahedra, corners with two equivalent S(5)Zn3Ga tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fifth S site, S(5) is bonded to one Zn(3), one Zn(4), one Zn(6), and one Ga(2) atom to form SZn3Ga tetrahedra that share  a cornercorner with one S(2)Zn2GaAg tetrahedra,  a cornercorner with one S(3)Zn3Ag tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the sixth S site, S(6) is bonded to one Ag(1), one Zn(2), one Zn(3), and one Ga(2) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(8)Zn2GaAg tetrahedra,  a cornercorner with one S(9)Zn2GaAg tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(5)Zn3Ga tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the seventh S site, S(7) is bonded to one Ag(1), one Zn(3), one Zn(4), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(9)Zn2GaAg tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, and corners with two equivalent S(5)Zn3Ga tetrahedra. In the eighth S site, S(8) is bonded to one Ag(1), one Zn(1), one Zn(5), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(6)Zn2GaAg tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, and corners with two equivalent S(3)Zn3Ag tetrahedra. In the ninth S site, S(9) is bonded to one Ag(2), one Zn(1), one Zn(2), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(6)Zn2GaAg tetrahedra,  a cornercorner with one S(7)Zn2GaAg tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, corners with two equivalent S(3)Zn3Ag tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the tenth S site, S(10) is bonded to one Zn(1), one Zn(2), one Zn(3), and one Zn(6) atom to form SZn4 tetrahedra that share  a cornercorner with one S(7)Zn2GaAg tetrahedra,  a cornercorner with one S(8)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, corners with two equivalent S(3)Zn3Ag tetrahedra, and corners with two equivalent S(5)Zn3Ga tetrahedra.
AgZn3GaS5 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form AgS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Ga(1)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. The Ag(1)-S(1) bond length is 2.55 Å. The Ag(1)-S(6) bond length is 2.55 Å. The Ag(1)-S(7) bond length is 2.55 Å. The Ag(1)-S(8) bond length is 2.55 Å. In the second Ag site, Ag(2) is bonded to one S(2), one S(3), one S(4), and one S(9) atom to form AgS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Ga(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(1)S4 tetrahedra. The Ag(2)-S(2) bond length is 2.55 Å. The Ag(2)-S(3) bond length is 2.54 Å. The Ag(2)-S(4) bond length is 2.56 Å. The Ag(2)-S(9) bond length is 2.55 Å. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(3), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(1)S4 tetrahedra. The Zn(1)-S(10) bond length is 2.40 Å. The Zn(1)-S(3) bond length is 2.33 Å. The Zn(1)-S(8) bond length is 2.36 Å. The Zn(1)-S(9) bond length is 2.38 Å. In the second Zn site, Zn(2) is bonded to one S(10), one S(4), one S(6), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Ag(1)S4 tetrahedra,  a cornercorner with one Ga(1)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. The Zn(2)-S(10) bond length is 2.36 Å. The Zn(2)-S(4) bond length is 2.38 Å. The Zn(2)-S(6) bond length is 2.35 Å. The Zn(2)-S(9) bond length is 2.38 Å. In the third Zn site, Zn(3) is bonded to one S(10), one S(5), one S(6), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Ga(1)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. The Zn(3)-S(10) bond length is 2.36 Å. The Zn(3)-S(5) bond length is 2.42 Å. The Zn(3)-S(6) bond length is 2.36 Å. The Zn(3)-S(7) bond length is 2.36 Å. In the fourth Zn site, Zn(4) is bonded to one S(1), one S(2), one S(5), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Zn(6)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Ga(1)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. The Zn(4)-S(1) bond length is 2.36 Å. The Zn(4)-S(2) bond length is 2.33 Å. The Zn(4)-S(5) bond length is 2.42 Å. The Zn(4)-S(7) bond length is 2.37 Å. In the fifth Zn site, Zn(5) is bonded to one S(1), one S(2), one S(3), and one S(8) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(6)S4 tetrahedra,  a cornercorner with one Ga(2)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Ga(1)S4 tetrahedra. The Zn(5)-S(1) bond length is 2.38 Å. The Zn(5)-S(2) bond length is 2.36 Å. The Zn(5)-S(3) bond length is 2.32 Å. The Zn(5)-S(8) bond length is 2.36 Å. In the sixth Zn site, Zn(6) is bonded to one S(10), one S(3), one S(4), and one S(5) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, and corners with two equivalent Ga(2)S4 tetrahedra. The Zn(6)-S(10) bond length is 2.37 Å. The Zn(6)-S(3) bond length is 2.32 Å. The Zn(6)-S(4) bond length is 2.37 Å. The Zn(6)-S(5) bond length is 2.43 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one S(2), one S(7), one S(8), and one S(9) atom to form GaS4 tetrahedra that share  a cornercorner with one Zn(2)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Ag(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(5)S4 tetrahedra. The Ga(1)-S(2) bond length is 2.31 Å. The Ga(1)-S(7) bond length is 2.32 Å. The Ga(1)-S(8) bond length is 2.30 Å. The Ga(1)-S(9) bond length is 2.32 Å. In the second Ga site, Ga(2) is bonded to one S(1), one S(4), one S(5), and one S(6) atom to form GaS4 tetrahedra that share  a cornercorner with one Ag(2)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Ag(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(6)S4 tetrahedra. The Ga(2)-S(1) bond length is 2.32 Å. The Ga(2)-S(4) bond length is 2.29 Å. The Ga(2)-S(5) bond length is 2.36 Å. The Ga(2)-S(6) bond length is 2.31 Å. There are ten inequivalent S sites. In the first S site, S(1) is bonded to one Ag(1), one Zn(4), one Zn(5), and one Ga(2) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(4)Zn2GaAg tetrahedra,  a cornercorner with one S(3)Zn3Ag tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, and corners with two equivalent S(5)Zn3Ga tetrahedra. In the second S site, S(2) is bonded to one Ag(2), one Zn(4), one Zn(5), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(4)Zn2GaAg tetrahedra,  a cornercorner with one S(5)Zn3Ga tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, and corners with two equivalent S(3)Zn3Ag tetrahedra. In the third S site, S(3) is bonded to one Ag(2), one Zn(1), one Zn(5), and one Zn(6) atom to form SZn3Ag tetrahedra that share  a cornercorner with one S(1)Zn2GaAg tetrahedra,  a cornercorner with one S(5)Zn3Ga tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fourth S site, S(4) is bonded to one Ag(2), one Zn(2), one Zn(6), and one Ga(2) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(1)Zn2GaAg tetrahedra,  a cornercorner with one S(2)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, corners with two equivalent S(3)Zn3Ag tetrahedra, corners with two equivalent S(5)Zn3Ga tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fifth S site, S(5) is bonded to one Zn(3), one Zn(4), one Zn(6), and one Ga(2) atom to form SZn3Ga tetrahedra that share  a cornercorner with one S(2)Zn2GaAg tetrahedra,  a cornercorner with one S(3)Zn3Ag tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the sixth S site, S(6) is bonded to one Ag(1), one Zn(2), one Zn(3), and one Ga(2) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(8)Zn2GaAg tetrahedra,  a cornercorner with one S(9)Zn2GaAg tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(5)Zn3Ga tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the seventh S site, S(7) is bonded to one Ag(1), one Zn(3), one Zn(4), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(9)Zn2GaAg tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, and corners with two equivalent S(5)Zn3Ga tetrahedra. In the eighth S site, S(8) is bonded to one Ag(1), one Zn(1), one Zn(5), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(6)Zn2GaAg tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2GaAg tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(7)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, and corners with two equivalent S(3)Zn3Ag tetrahedra. In the ninth S site, S(9) is bonded to one Ag(2), one Zn(1), one Zn(2), and one Ga(1) atom to form SZn2GaAg tetrahedra that share  a cornercorner with one S(6)Zn2GaAg tetrahedra,  a cornercorner with one S(7)Zn2GaAg tetrahedra, corners with two equivalent S(2)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(8)Zn2GaAg tetrahedra, corners with two equivalent S(3)Zn3Ag tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the tenth S site, S(10) is bonded to one Zn(1), one Zn(2), one Zn(3), and one Zn(6) atom to form SZn4 tetrahedra that share  a cornercorner with one S(7)Zn2GaAg tetrahedra,  a cornercorner with one S(8)Zn2GaAg tetrahedra, corners with two equivalent S(4)Zn2GaAg tetrahedra, corners with two equivalent S(6)Zn2GaAg tetrahedra, corners with two equivalent S(9)Zn2GaAg tetrahedra, corners with two equivalent S(3)Zn3Ag tetrahedra, and corners with two equivalent S(5)Zn3Ga tetrahedra.