LiAg2P3(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(6), and one O(8) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(8), one O(9), and two equivalent O(2) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(4), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Ag(1)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Li(1), one Ag(2), and one P(2) atom. In the second O site, O(10) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), one H(1), and one H(2) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one P(1) atom. In the fourth O site, O(2) is bonded in a 1-coordinate geometry to one Ag(1), two equivalent Ag(2), and one P(1) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(3) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one P(3) atom. In the ninth O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(2) atom.
LiAg2P3(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. The Li(1)-O(1) bond length is 1.96 Å. The Li(1)-O(10) bond length is 1.99 Å. The Li(1)-O(6) bond length is 1.90 Å. The Li(1)-O(9) bond length is 1.91 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(6), and one O(8) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The Ag(1)-O(1) bond length is 2.30 Å. The Ag(1)-O(2) bond length is 2.34 Å. The Ag(1)-O(5) bond length is 2.58 Å. The Ag(1)-O(6) bond length is 2.55 Å. The Ag(1)-O(8) bond length is 2.56 Å. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(8), one O(9), and two equivalent O(2) atoms. The Ag(2)-O(10) bond length is 2.36 Å. The Ag(2)-O(5) bond length is 2.66 Å. The Ag(2)-O(8) bond length is 2.48 Å. The Ag(2)-O(9) bond length is 2.61 Å. There is one shorter (2.45 Å) and one longer (2.84 Å) Ag(2)-O(2) bond length. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. The P(1)-O(1) bond length is 1.49 Å. The P(1)-O(2) bond length is 1.50 Å. The P(1)-O(3) bond length is 1.59 Å. The P(1)-O(4) bond length is 1.59 Å. In the second P site, P(2) is bonded to one O(4), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one Ag(1)O5 trigonal bipyramid. The P(2)-O(4) bond length is 1.60 Å. The P(2)-O(7) bond length is 1.59 Å. The P(2)-O(8) bond length is 1.50 Å. The P(2)-O(9) bond length is 1.48 Å. In the third P site, P(3) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Ag(1)O5 trigonal bipyramids. The P(3)-O(3) bond length is 1.60 Å. The P(3)-O(5) bond length is 1.49 Å. The P(3)-O(6) bond length is 1.48 Å. The P(3)-O(7) bond length is 1.59 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. The H(1)-O(10) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 0.99 Å. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Li(1), one Ag(2), and one P(2) atom. In the second O site, O(10) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), one H(1), and one H(2) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one P(1) atom. In the fourth O site, O(2) is bonded in a 1-coordinate geometry to one Ag(1), two equivalent Ag(2), and one P(1) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(3) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one P(3) atom. In the ninth O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(2) atom.