V4OF11 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(1), one F(11), one F(2), one F(3), one F(4), and one F(6) atom. In the second V site, V(2) is bonded in a 4-coordinate geometry to one F(1), one F(11), one F(3), one F(5), one F(6), and one F(8) atom. In the third V site, V(3) is bonded in a 6-coordinate geometry to one F(1), one F(10), one F(5), one F(7), one F(8), and one F(9) atom. In the fourth V site, V(4) is bonded in a 4-coordinate geometry to one O(1), one F(10), one F(2), one F(4), one F(7), and one F(9) atom. O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one V(1) and one V(2) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the tenth F site, F(10) is bonded in a bent 120 degrees geometry to one V(3) and one V(4) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom.
V4OF11 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(1), one F(11), one F(2), one F(3), one F(4), and one F(6) atom. The V(1)-O(1) bond length is 1.59 Å. The V(1)-F(11) bond length is 2.14 Å. The V(1)-F(2) bond length is 2.45 Å. The V(1)-F(3) bond length is 2.44 Å. The V(1)-F(4) bond length is 2.18 Å. The V(1)-F(6) bond length is 1.65 Å. In the second V site, V(2) is bonded in a 4-coordinate geometry to one F(1), one F(11), one F(3), one F(5), one F(6), and one F(8) atom. The V(2)-F(1) bond length is 1.99 Å. The V(2)-F(11) bond length is 2.00 Å. The V(2)-F(3) bond length is 2.56 Å. The V(2)-F(5) bond length is 1.64 Å. The V(2)-F(6) bond length is 1.64 Å. The V(2)-F(8) bond length is 2.56 Å. In the third V site, V(3) is bonded in a 6-coordinate geometry to one F(1), one F(10), one F(5), one F(7), one F(8), and one F(9) atom. The V(3)-F(1) bond length is 2.16 Å. The V(3)-F(10) bond length is 1.64 Å. The V(3)-F(5) bond length is 1.65 Å. The V(3)-F(7) bond length is 2.17 Å. The V(3)-F(8) bond length is 2.44 Å. The V(3)-F(9) bond length is 2.42 Å. In the fourth V site, V(4) is bonded in a 4-coordinate geometry to one O(1), one F(10), one F(2), one F(4), one F(7), and one F(9) atom. The V(4)-O(1) bond length is 1.37 Å. The V(4)-F(10) bond length is 1.69 Å. The V(4)-F(2) bond length is 2.50 Å. The V(4)-F(4) bond length is 1.98 Å. The V(4)-F(7) bond length is 1.97 Å. The V(4)-F(9) bond length is 2.62 Å. O(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth F site, F(6) is bonded in a bent 120 degrees geometry to one V(1) and one V(2) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the tenth F site, F(10) is bonded in a bent 120 degrees geometry to one V(3) and one V(4) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom.