Pd(PbBr3)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in a distorted square co-planar geometry to two equivalent Br(2) and two equivalent Br(3) atoms. Pb(1) is bonded in a 7-coordinate geometry to two equivalent Br(2), two equivalent Br(3), and three equivalent Br(1) atoms. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Pb(1) atoms. In the second Br site, Br(2) is bonded in a distorted single-bond geometry to one Pd(1) and two equivalent Pb(1) atoms. In the third Br site, Br(3) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pb(1) atoms.
Pd(PbBr3)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in a distorted square co-planar geometry to two equivalent Br(2) and two equivalent Br(3) atoms. Both Pd(1)-Br(2) bond lengths are 2.46 Å. Both Pd(1)-Br(3) bond lengths are 2.46 Å. Pb(1) is bonded in a 7-coordinate geometry to two equivalent Br(2), two equivalent Br(3), and three equivalent Br(1) atoms. There is one shorter (3.27 Å) and one longer (3.36 Å) Pb(1)-Br(2) bond length. There is one shorter (3.15 Å) and one longer (3.18 Å) Pb(1)-Br(3) bond length. There are a spread of Pb(1)-Br(1) bond distances ranging from 2.99-3.10 Å. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Pb(1) atoms. In the second Br site, Br(2) is bonded in a distorted single-bond geometry to one Pd(1) and two equivalent Pb(1) atoms. In the third Br site, Br(3) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pb(1) atoms.