PrCe3O8 is Fluorite-derived structured and crystallizes in the tetragonal I4/mmm space group. Pr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. In the second Ce site, Ce(2) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. O(1) is bonded to one Pr(1), one Ce(2), and two equivalent Ce(1) atoms to form a mixture of edge and corner-sharing OCe3Pr tetrahedra.
PrCe3O8 is Fluorite-derived structured and crystallizes in the tetragonal I4/mmm space group. Pr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Pr(1)-O(1) bond lengths are 2.45 Å. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Ce(1)-O(1) bond lengths are 2.37 Å. In the second Ce site, Ce(2) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Ce(2)-O(1) bond lengths are 2.37 Å. O(1) is bonded to one Pr(1), one Ce(2), and two equivalent Ce(1) atoms to form a mixture of edge and corner-sharing OCe3Pr tetrahedra.