CrFeP2 is Modderite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. Cr(1) is bonded in a 6-coordinate geometry to two equivalent P(1) and four equivalent P(2) atoms. Fe(1) is bonded in a 6-coordinate geometry to two equivalent P(2) and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Fe(1) atoms. In the second P site, P(2) is bonded in a 6-coordinate geometry to four equivalent Cr(1) and two equivalent Fe(1) atoms.
CrFeP2 is Modderite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. Cr(1) is bonded in a 6-coordinate geometry to two equivalent P(1) and four equivalent P(2) atoms. There is one shorter (2.32 Å) and one longer (2.41 Å) Cr(1)-P(1) bond length. There are two shorter (2.33 Å) and two longer (2.37 Å) Cr(1)-P(2) bond lengths. Fe(1) is bonded in a 6-coordinate geometry to two equivalent P(2) and four equivalent P(1) atoms. There is one shorter (2.25 Å) and one longer (2.35 Å) Fe(1)-P(2) bond length. There are two shorter (2.30 Å) and two longer (2.34 Å) Fe(1)-P(1) bond lengths. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Fe(1) atoms. In the second P site, P(2) is bonded in a 6-coordinate geometry to four equivalent Cr(1) and two equivalent Fe(1) atoms.