Ba3TiN3 crystallizes in the hexagonal P6_3/m space group. Ba(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing BaN4 trigonal pyramids. Ti(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded to four equivalent Ba(1) and one Ti(1) atom to form a mixture of distorted edge and corner-sharing NBa4Ti trigonal bipyramids.
Ba3TiN3 crystallizes in the hexagonal P6_3/m space group. Ba(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing BaN4 trigonal pyramids. There are a spread of Ba(1)-N(1) bond distances ranging from 2.67-3.04 Å. Ti(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All Ti(1)-N(1) bond lengths are 1.89 Å. N(1) is bonded to four equivalent Ba(1) and one Ti(1) atom to form a mixture of distorted edge and corner-sharing NBa4Ti trigonal bipyramids.