Li2AuTl crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent Au(1) atoms to form distorted corner-sharing LiAu4 tetrahedra. In the second Li site, Li(2) is bonded to four equivalent Tl(1) atoms to form distorted corner-sharing LiTl4 tetrahedra. Au(1) is bonded in a body-centered cubic geometry to four equivalent Li(1) and four equivalent Tl(1) atoms. Tl(1) is bonded in a body-centered cubic geometry to four equivalent Li(2) and four equivalent Au(1) atoms.
Li2AuTl crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent Au(1) atoms to form distorted corner-sharing LiAu4 tetrahedra. All Li(1)-Au(1) bond lengths are 2.89 Å. In the second Li site, Li(2) is bonded to four equivalent Tl(1) atoms to form distorted corner-sharing LiTl4 tetrahedra. All Li(2)-Tl(1) bond lengths are 2.89 Å. Au(1) is bonded in a body-centered cubic geometry to four equivalent Li(1) and four equivalent Tl(1) atoms. All Au(1)-Tl(1) bond lengths are 2.89 Å. Tl(1) is bonded in a body-centered cubic geometry to four equivalent Li(2) and four equivalent Au(1) atoms.