Rb2BaPt2(CN)8 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a 16-coordinate geometry to eight equivalent C(1) and eight equivalent N(1) atoms. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent N(1) atoms. Pt(1) is bonded in a rectangular see-saw-like geometry to four equivalent C(1) atoms. C(1) is bonded in a distorted linear geometry to two equivalent Rb(1), one Pt(1), and one N(1) atom. N(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Ba(1), and one C(1) atom.
Rb2BaPt2(CN)8 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a 16-coordinate geometry to eight equivalent C(1) and eight equivalent N(1) atoms. All Rb(1)-C(1) bond lengths are 3.42 Å. All Rb(1)-N(1) bond lengths are 3.36 Å. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent N(1) atoms. All Ba(1)-N(1) bond lengths are 2.92 Å. Pt(1) is bonded in a rectangular see-saw-like geometry to four equivalent C(1) atoms. All Pt(1)-C(1) bond lengths are 1.99 Å. C(1) is bonded in a distorted linear geometry to two equivalent Rb(1), one Pt(1), and one N(1) atom. The C(1)-N(1) bond length is 1.18 Å. N(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Ba(1), and one C(1) atom.