Rb6WN4 crystallizes in the tetragonal P4_2/nmc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted bent 150 degrees geometry to two equivalent N(1) atoms. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. W(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to one Rb(1), four equivalent Rb(2), and one W(1) atom.
Rb6WN4 crystallizes in the tetragonal P4_2/nmc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted bent 150 degrees geometry to two equivalent N(1) atoms. Both Rb(1)-N(1) bond lengths are 2.88 Å. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. There are two shorter (2.88 Å) and two longer (3.11 Å) Rb(2)-N(1) bond lengths. W(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All W(1)-N(1) bond lengths are 1.93 Å. N(1) is bonded in a 6-coordinate geometry to one Rb(1), four equivalent Rb(2), and one W(1) atom.