Mg6V crystallizes in the cubic Fm-3m space group. Mg(1) is bonded in a 10-coordinate geometry to eight equivalent Mg(1) and two equivalent V(1) atoms. V(1) is bonded to twelve equivalent Mg(1) atoms to form corner-sharing VMg12 cuboctahedra.
Mg6V crystallizes in the cubic Fm-3m space group. Mg(1) is bonded in a 10-coordinate geometry to eight equivalent Mg(1) and two equivalent V(1) atoms. All Mg(1)-Mg(1) bond lengths are 3.06 Å. Both Mg(1)-V(1) bond lengths are 3.06 Å. V(1) is bonded to twelve equivalent Mg(1) atoms to form corner-sharing VMg12 cuboctahedra.