PbF3 crystallizes in the tetragonal P4_2/mcm space group. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Pb site, Pb(2) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Pb(2) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Pb(1) and one Pb(2) atom.
PbF3 crystallizes in the tetragonal P4_2/mcm space group. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. All Pb(1)-F(1) bond lengths are 2.39 Å. In the second Pb site, Pb(2) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. Both Pb(2)-F(2) bond lengths are 2.12 Å. All Pb(2)-F(1) bond lengths are 2.08 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Pb(2) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Pb(1) and one Pb(2) atom.