Li4Ti3Fe2Co3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with three equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the second Ti site, Ti(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the third Ti site, Ti(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form FeO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. In the second Fe site, Fe(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one Fe(1), and one Co(2) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one Ti(2), and one Fe(1) atom to form distorted OLiTi2Fe tetrahedra that share  a cornercorner with one O(7)LiTiFeCo tetrahedra,  a cornercorner with one O(8)LiTiFeCo tetrahedra, corners with two equivalent O(4)LiTi2Co tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(7)LiTiFeCo tetrahedra, and  an edgeedge with one O(8)LiTiFeCo tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Ti(1), one Ti(2), and one Co(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one Ti(1), one Ti(2), and one Co(1) atom to form distorted OLiTi2Co tetrahedra that share corners with two equivalent O(2)LiTi2Fe tetrahedra, corners with two equivalent O(7)LiTiFeCo tetrahedra, corners with two equivalent O(8)LiTiFeCo tetrahedra, and  a cornercorner with one O(10)LiFeCo2 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Ti(3), one Co(2), and one Co(3) atom to form distorted OLiTiCo2 tetrahedra that share corners with two equivalent O(15)LiFeCo2 tetrahedra, corners with two equivalent O(11)LiTiFeCo tetrahedra, corners with two equivalent O(12)LiTiFeCo trigonal pyramids, and  an edgeedge with one O(10)LiFeCo2 trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one Fe(1), and one Co(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one Fe(1), and one Co(1) atom to form distorted OLiTiFeCo tetrahedra that share  a cornercorner with one O(2)LiTi2Fe tetrahedra,  a cornercorner with one O(8)LiTiFeCo tetrahedra, corners with two equivalent O(4)LiTi2Co tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(2)LiTi2Fe tetrahedra, and  an edgeedge with one O(8)LiTiFeCo tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Ti(2), one Fe(1), and one Co(1) atom to form distorted OLiTiFeCo tetrahedra that share  a cornercorner with one O(2)LiTi2Fe tetrahedra,  a cornercorner with one O(7)LiTiFeCo tetrahedra, corners with two equivalent O(4)LiTi2Co tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(2)LiTi2Fe tetrahedra, and  an edgeedge with one O(7)LiTiFeCo tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Ti(2), and one Fe(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one Fe(1), one Co(2), and one Co(3) atom to form distorted OLiFeCo2 trigonal pyramids that share  a cornercorner with one O(4)LiTi2Co tetrahedra,  a cornercorner with one O(2)LiTi2Fe tetrahedra,  a cornercorner with one O(11)LiTiFeCo tetrahedra,  a cornercorner with one O(7)LiTiFeCo tetrahedra,  a cornercorner with one O(8)LiTiFeCo tetrahedra, corners with two equivalent O(15)LiFeCo2 tetrahedra,  a cornercorner with one O(12)LiTiFeCo trigonal pyramid, and  an edgeedge with one O(5)LiTiCo2 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one Ti(3), one Fe(2), and one Co(2) atom to form distorted OLiTiFeCo tetrahedra that share  a cornercorner with one O(15)LiFeCo2 tetrahedra, corners with two equivalent O(5)LiTiCo2 tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  a cornercorner with one O(12)LiTiFeCo trigonal pyramid,  an edgeedge with one O(15)LiFeCo2 tetrahedra, and  an edgeedge with one O(12)LiTiFeCo trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one Ti(3), one Fe(2), and one Co(3) atom to form distorted OLiTiFeCo trigonal pyramids that share  a cornercorner with one O(15)LiFeCo2 tetrahedra,  a cornercorner with one O(11)LiTiFeCo tetrahedra, corners with two equivalent O(5)LiTiCo2 tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(15)LiFeCo2 tetrahedra, and  an edgeedge with one O(11)LiTiFeCo tetrahedra. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Ti(3), one Co(2), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Fe(2), and one Co(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Fe(2), one Co(2), and one Co(3) atom to form distorted OLiFeCo2 tetrahedra that share  a cornercorner with one O(11)LiTiFeCo tetrahedra, corners with two equivalent O(5)LiTiCo2 tetrahedra,  a cornercorner with one O(12)LiTiFeCo trigonal pyramid, corners with two equivalent O(10)LiFeCo2 trigonal pyramids,  an edgeedge with one O(11)LiTiFeCo tetrahedra, and  an edgeedge with one O(12)LiTiFeCo trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one Fe(2), and one Co(1) atom.
Li4Ti3Fe2Co3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. The Li(1)-O(11) bond length is 1.91 Å. The Li(1)-O(12) bond length is 1.92 Å. The Li(1)-O(15) bond length is 1.97 Å. The Li(1)-O(3) bond length is 2.01 Å. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. The Li(2)-O(14) bond length is 1.89 Å. The Li(2)-O(16) bond length is 1.89 Å. The Li(2)-O(5) bond length is 1.77 Å. The Li(2)-O(9) bond length is 2.00 Å. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. The Li(3)-O(1) bond length is 1.92 Å. The Li(3)-O(10) bond length is 1.88 Å. The Li(3)-O(4) bond length is 1.79 Å. The Li(3)-O(6) bond length is 1.94 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with three equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. The Li(4)-O(13) bond length is 1.98 Å. The Li(4)-O(2) bond length is 1.90 Å. The Li(4)-O(7) bond length is 1.94 Å. The Li(4)-O(8) bond length is 1.95 Å. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. The Ti(1)-O(14) bond length is 2.00 Å. The Ti(1)-O(2) bond length is 1.96 Å. The Ti(1)-O(3) bond length is 1.96 Å. The Ti(1)-O(4) bond length is 1.96 Å. The Ti(1)-O(7) bond length is 1.95 Å. The Ti(1)-O(9) bond length is 1.99 Å. In the second Ti site, Ti(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. The Ti(2)-O(16) bond length is 2.00 Å. The Ti(2)-O(2) bond length is 1.96 Å. The Ti(2)-O(3) bond length is 1.96 Å. The Ti(2)-O(4) bond length is 1.96 Å. The Ti(2)-O(8) bond length is 1.95 Å. The Ti(2)-O(9) bond length is 1.99 Å. In the third Ti site, Ti(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. The Ti(3)-O(1) bond length is 2.01 Å. The Ti(3)-O(11) bond length is 1.93 Å. The Ti(3)-O(12) bond length is 1.96 Å. The Ti(3)-O(13) bond length is 1.95 Å. The Ti(3)-O(5) bond length is 1.96 Å. The Ti(3)-O(6) bond length is 2.03 Å. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form FeO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. The Fe(1)-O(1) bond length is 1.99 Å. The Fe(1)-O(10) bond length is 2.04 Å. The Fe(1)-O(2) bond length is 2.11 Å. The Fe(1)-O(6) bond length is 2.04 Å. The Fe(1)-O(7) bond length is 2.09 Å. The Fe(1)-O(8) bond length is 2.12 Å. In the second Fe site, Fe(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. The Fe(2)-O(11) bond length is 2.09 Å. The Fe(2)-O(12) bond length is 2.12 Å. The Fe(2)-O(14) bond length is 2.00 Å. The Fe(2)-O(15) bond length is 2.12 Å. The Fe(2)-O(16) bond length is 2.02 Å. The Fe(2)-O(9) bond length is 2.02 Å. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. The Co(1)-O(14) bond length is 1.98 Å. The Co(1)-O(16) bond length is 1.98 Å. The Co(1)-O(3) bond length is 1.96 Å. The Co(1)-O(4) bond length is 1.91 Å. The Co(1)-O(7) bond length is 1.95 Å. The Co(1)-O(8) bond length is 1.96 Å. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. The Co(2)-O(1) bond length is 1.97 Å. The Co(2)-O(10) bond length is 1.97 Å. The Co(2)-O(11) bond length is 1.95 Å. The Co(2)-O(13) bond length is 1.93 Å. The Co(2)-O(15) bond length is 1.93 Å. The Co(2)-O(5) bond length is 1.92 Å. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Fe(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. The Co(3)-O(10) bond length is 1.89 Å. The Co(3)-O(12) bond length is 1.91 Å. The Co(3)-O(13) bond length is 1.94 Å. The Co(3)-O(15) bond length is 1.90 Å. The Co(3)-O(5) bond length is 1.92 Å. The Co(3)-O(6) bond length is 1.91 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one Fe(1), and one Co(2) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one Ti(2), and one Fe(1) atom to form distorted OLiTi2Fe tetrahedra that share  a cornercorner with one O(7)LiTiFeCo tetrahedra,  a cornercorner with one O(8)LiTiFeCo tetrahedra, corners with two equivalent O(4)LiTi2Co tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(7)LiTiFeCo tetrahedra, and  an edgeedge with one O(8)LiTiFeCo tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Ti(1), one Ti(2), and one Co(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one Ti(1), one Ti(2), and one Co(1) atom to form distorted OLiTi2Co tetrahedra that share corners with two equivalent O(2)LiTi2Fe tetrahedra, corners with two equivalent O(7)LiTiFeCo tetrahedra, corners with two equivalent O(8)LiTiFeCo tetrahedra, and  a cornercorner with one O(10)LiFeCo2 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Ti(3), one Co(2), and one Co(3) atom to form distorted OLiTiCo2 tetrahedra that share corners with two equivalent O(15)LiFeCo2 tetrahedra, corners with two equivalent O(11)LiTiFeCo tetrahedra, corners with two equivalent O(12)LiTiFeCo trigonal pyramids, and  an edgeedge with one O(10)LiFeCo2 trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one Fe(1), and one Co(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one Fe(1), and one Co(1) atom to form distorted OLiTiFeCo tetrahedra that share  a cornercorner with one O(2)LiTi2Fe tetrahedra,  a cornercorner with one O(8)LiTiFeCo tetrahedra, corners with two equivalent O(4)LiTi2Co tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(2)LiTi2Fe tetrahedra, and  an edgeedge with one O(8)LiTiFeCo tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Ti(2), one Fe(1), and one Co(1) atom to form distorted OLiTiFeCo tetrahedra that share  a cornercorner with one O(2)LiTi2Fe tetrahedra,  a cornercorner with one O(7)LiTiFeCo tetrahedra, corners with two equivalent O(4)LiTi2Co tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(2)LiTi2Fe tetrahedra, and  an edgeedge with one O(7)LiTiFeCo tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Ti(2), and one Fe(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one Fe(1), one Co(2), and one Co(3) atom to form distorted OLiFeCo2 trigonal pyramids that share  a cornercorner with one O(4)LiTi2Co tetrahedra,  a cornercorner with one O(2)LiTi2Fe tetrahedra,  a cornercorner with one O(11)LiTiFeCo tetrahedra,  a cornercorner with one O(7)LiTiFeCo tetrahedra,  a cornercorner with one O(8)LiTiFeCo tetrahedra, corners with two equivalent O(15)LiFeCo2 tetrahedra,  a cornercorner with one O(12)LiTiFeCo trigonal pyramid, and  an edgeedge with one O(5)LiTiCo2 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one Ti(3), one Fe(2), and one Co(2) atom to form distorted OLiTiFeCo tetrahedra that share  a cornercorner with one O(15)LiFeCo2 tetrahedra, corners with two equivalent O(5)LiTiCo2 tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  a cornercorner with one O(12)LiTiFeCo trigonal pyramid,  an edgeedge with one O(15)LiFeCo2 tetrahedra, and  an edgeedge with one O(12)LiTiFeCo trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one Ti(3), one Fe(2), and one Co(3) atom to form distorted OLiTiFeCo trigonal pyramids that share  a cornercorner with one O(15)LiFeCo2 tetrahedra,  a cornercorner with one O(11)LiTiFeCo tetrahedra, corners with two equivalent O(5)LiTiCo2 tetrahedra,  a cornercorner with one O(10)LiFeCo2 trigonal pyramid,  an edgeedge with one O(15)LiFeCo2 tetrahedra, and  an edgeedge with one O(11)LiTiFeCo tetrahedra. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Ti(3), one Co(2), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Fe(2), and one Co(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Fe(2), one Co(2), and one Co(3) atom to form distorted OLiFeCo2 tetrahedra that share  a cornercorner with one O(11)LiTiFeCo tetrahedra, corners with two equivalent O(5)LiTiCo2 tetrahedra,  a cornercorner with one O(12)LiTiFeCo trigonal pyramid, corners with two equivalent O(10)LiFeCo2 trigonal pyramids,  an edgeedge with one O(11)LiTiFeCo tetrahedra, and  an edgeedge with one O(12)LiTiFeCo trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one Fe(2), and one Co(1) atom.