AgHgSBr crystallizes in the orthorhombic Pmma space group. Ag(1) is bonded to two equivalent S(1), one Br(1), and one Br(2) atom to form a mixture of distorted corner and edge-sharing AgS2Br2 tetrahedra. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Br(1) atoms. In the second Hg site, Hg(2) is bonded in a linear geometry to two equivalent S(1) atoms. S(1) is bonded to two equivalent Ag(1), one Hg(1), and one Hg(2) atom to form corner-sharing SAg2Hg2 trigonal pyramids. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Hg(1) atoms. In the second Br site, Br(2) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms.
AgHgSBr crystallizes in the orthorhombic Pmma space group. Ag(1) is bonded to two equivalent S(1), one Br(1), and one Br(2) atom to form a mixture of distorted corner and edge-sharing AgS2Br2 tetrahedra. Both Ag(1)-S(1) bond lengths are 2.55 Å. The Ag(1)-Br(1) bond length is 2.73 Å. The Ag(1)-Br(2) bond length is 3.00 Å. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Br(1) atoms. Both Hg(1)-S(1) bond lengths are 2.42 Å. Both Hg(1)-Br(1) bond lengths are 3.16 Å. In the second Hg site, Hg(2) is bonded in a linear geometry to two equivalent S(1) atoms. Both Hg(2)-S(1) bond lengths are 2.41 Å. S(1) is bonded to two equivalent Ag(1), one Hg(1), and one Hg(2) atom to form corner-sharing SAg2Hg2 trigonal pyramids. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Hg(1) atoms. In the second Br site, Br(2) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms.