LiSr2WCoO6 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Sr(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. W(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Co(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), three equivalent Sr(1), and one W(1) atom. In the second O site, O(2) is bonded to one Li(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted edge and corner-sharing OSr2LiCoW trigonal bipyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Sr(1), one W(1), and one Co(1) atom.
LiSr2WCoO6 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Li(1)-O(1) bond lengths are 2.50 Å. Both Li(1)-O(2) bond lengths are 1.98 Å. Both Li(1)-O(3) bond lengths are 1.99 Å. Sr(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. There is one shorter (2.52 Å) and one longer (2.64 Å) Sr(1)-O(2) bond length. There is one shorter (2.52 Å) and one longer (2.71 Å) Sr(1)-O(3) bond length. There are a spread of Sr(1)-O(1) bond distances ranging from 2.50-2.91 Å. W(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both W(1)-O(1) bond lengths are 1.93 Å. Both W(1)-O(2) bond lengths are 2.08 Å. Both W(1)-O(3) bond lengths are 2.08 Å. Co(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. Both Co(1)-O(2) bond lengths are 2.01 Å. Both Co(1)-O(3) bond lengths are 2.00 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), three equivalent Sr(1), and one W(1) atom. In the second O site, O(2) is bonded to one Li(1), two equivalent Sr(1), one W(1), and one Co(1) atom to form a mixture of distorted edge and corner-sharing OSr2LiCoW trigonal bipyramids. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Sr(1), one W(1), and one Co(1) atom.