Na3Fe crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a distorted see-saw-like geometry to four equivalent Fe(1) atoms. Fe(1) is bonded to twelve equivalent Na(1) atoms to form a mixture of corner and face-sharing FeNa12 cuboctahedra.
Na3Fe crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a distorted see-saw-like geometry to four equivalent Fe(1) atoms. There are two shorter (3.30 Å) and two longer (3.47 Å) Na(1)-Fe(1) bond lengths. Fe(1) is bonded to twelve equivalent Na(1) atoms to form a mixture of corner and face-sharing FeNa12 cuboctahedra.