RbMnH4O2Cl3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), three equivalent Cl(2), and three equivalent Cl(3) atoms. Mn(1) is bonded to one O(1), one O(2), one Cl(2), one Cl(3), and two equivalent Cl(1) atoms to form edge-sharing MnCl4O2 octahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(3), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to three equivalent Rb(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom.
RbMnH4O2Cl3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), three equivalent Cl(2), and three equivalent Cl(3) atoms. There is one shorter (3.33 Å) and one longer (3.68 Å) Rb(1)-Cl(1) bond length. There are a spread of Rb(1)-Cl(2) bond distances ranging from 3.31-3.41 Å. There are a spread of Rb(1)-Cl(3) bond distances ranging from 3.54-3.80 Å. Mn(1) is bonded to one O(1), one O(2), one Cl(2), one Cl(3), and two equivalent Cl(1) atoms to form edge-sharing MnCl4O2 octahedra. The Mn(1)-O(1) bond length is 2.20 Å. The Mn(1)-O(2) bond length is 2.20 Å. The Mn(1)-Cl(2) bond length is 2.54 Å. The Mn(1)-Cl(3) bond length is 2.54 Å. There is one shorter (2.56 Å) and one longer (2.66 Å) Mn(1)-Cl(1) bond length. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(3), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to three equivalent Rb(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom.