Rb2Zn(SO6)2O2 crystallizes in the monoclinic P2_1/c space group. The structure consists of two hydrogen peroxide molecules inside a Rb2Zn(SO6)2 framework. In the Rb2Zn(SO6)2 framework, Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(7) atoms. Zn(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(5) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(7) atom. There are six inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(5) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(3) atom.
Rb2Zn(SO6)2O2 crystallizes in the monoclinic P2_1/c space group. The structure consists of two hydrogen peroxide molecules inside a Rb2Zn(SO6)2 framework. In the Rb2Zn(SO6)2 framework, Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(7) atoms. The Rb(1)-O(1) bond length is 2.95 Å. The Rb(1)-O(3) bond length is 3.10 Å. The Rb(1)-O(4) bond length is 2.94 Å. The Rb(1)-O(5) bond length is 3.31 Å. There is one shorter (3.01 Å) and one longer (3.32 Å) Rb(1)-O(2) bond length. There is one shorter (2.98 Å) and one longer (3.01 Å) Rb(1)-O(7) bond length. Zn(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(5) atoms. Both Zn(1)-O(3) bond lengths are 2.10 Å. Both Zn(1)-O(5) bond lengths are 1.91 Å. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(7) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.50 Å. The S(1)-O(4) bond length is 1.50 Å. The S(1)-O(7) bond length is 1.48 Å. There are six inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(5) atom. The O(3)-O(5) bond length is 1.35 Å. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(3) atom.