Y6Ge2O13F3 crystallizes in the triclinic P1 space group. There are six inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(2), one O(3), one O(6), one O(7), and one F(3) atom. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(4), one O(5), one O(8), one O(9), one F(1), and one F(2) atom. In the third Y site, Y(3) is bonded to one O(1), one O(11), one O(13), one O(3), one O(5), one O(7), and one F(2) atom to form distorted YO6F pentagonal bipyramids that share corners with two equivalent Ge(2)O5 trigonal bipyramids and  an edgeedge with one Ge(1)O5 trigonal bipyramid. In the fourth Y site, Y(4) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. In the fifth Y site, Y(5) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(3), one O(5), one O(7), and one F(2) atom. In the sixth Y site, Y(6) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(4), one O(5), one O(8), and one O(9) atom to form distorted GeO5 trigonal bipyramids that share  an edgeedge with one Y(3)O6F pentagonal bipyramid. In the second Ge site, Ge(2) is bonded to one O(10), one O(2), one O(3), one O(6), and one O(7) atom to form distorted GeO5 trigonal bipyramids that share corners with two equivalent Y(3)O6F pentagonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the second O site, O(2) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the third O site, O(3) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fourth O site, O(4) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fifth O site, O(5) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the sixth O site, O(6) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the seventh O site, O(7) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the eighth O site, O(8) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Y(2) and one Ge(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Y(1) and one Ge(2) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(6) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(5) atom. In the thirteenth O site, O(13) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(5) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(6) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(3), and one Y(5) atom. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(4), and one Y(6) atom.
Y6Ge2O13F3 crystallizes in the triclinic P1 space group. There are six inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(2), one O(3), one O(6), one O(7), and one F(3) atom. The Y(1)-O(10) bond length is 2.29 Å. The Y(1)-O(11) bond length is 2.36 Å. The Y(1)-O(13) bond length is 2.37 Å. The Y(1)-O(2) bond length is 2.36 Å. The Y(1)-O(3) bond length is 2.32 Å. The Y(1)-O(6) bond length is 2.43 Å. The Y(1)-O(7) bond length is 2.44 Å. The Y(1)-F(3) bond length is 2.53 Å. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(4), one O(5), one O(8), one O(9), one F(1), and one F(2) atom. The Y(2)-O(1) bond length is 2.33 Å. The Y(2)-O(12) bond length is 2.36 Å. The Y(2)-O(4) bond length is 2.37 Å. The Y(2)-O(5) bond length is 2.40 Å. The Y(2)-O(8) bond length is 2.42 Å. The Y(2)-O(9) bond length is 2.27 Å. The Y(2)-F(1) bond length is 2.50 Å. The Y(2)-F(2) bond length is 2.50 Å. In the third Y site, Y(3) is bonded to one O(1), one O(11), one O(13), one O(3), one O(5), one O(7), and one F(2) atom to form distorted YO6F pentagonal bipyramids that share corners with two equivalent Ge(2)O5 trigonal bipyramids and  an edgeedge with one Ge(1)O5 trigonal bipyramid. The Y(3)-O(1) bond length is 2.36 Å. The Y(3)-O(11) bond length is 2.36 Å. The Y(3)-O(13) bond length is 2.23 Å. The Y(3)-O(3) bond length is 2.32 Å. The Y(3)-O(5) bond length is 2.28 Å. The Y(3)-O(7) bond length is 2.29 Å. The Y(3)-F(2) bond length is 2.39 Å. In the fourth Y site, Y(4) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. The Y(4)-O(12) bond length is 2.32 Å. The Y(4)-O(2) bond length is 2.39 Å. The Y(4)-O(4) bond length is 2.33 Å. The Y(4)-O(6) bond length is 2.31 Å. The Y(4)-O(8) bond length is 2.33 Å. The Y(4)-F(1) bond length is 2.26 Å. The Y(4)-F(3) bond length is 2.35 Å. In the fifth Y site, Y(5) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(3), one O(5), one O(7), and one F(2) atom. The Y(5)-O(1) bond length is 2.39 Å. The Y(5)-O(12) bond length is 2.34 Å. The Y(5)-O(13) bond length is 2.35 Å. The Y(5)-O(3) bond length is 2.39 Å. The Y(5)-O(5) bond length is 2.32 Å. The Y(5)-O(7) bond length is 2.34 Å. The Y(5)-F(2) bond length is 2.27 Å. In the sixth Y site, Y(6) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. The Y(6)-O(11) bond length is 2.44 Å. The Y(6)-O(2) bond length is 2.34 Å. The Y(6)-O(4) bond length is 2.38 Å. The Y(6)-O(6) bond length is 2.30 Å. The Y(6)-O(8) bond length is 2.29 Å. The Y(6)-F(1) bond length is 2.39 Å. The Y(6)-F(3) bond length is 2.24 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(4), one O(5), one O(8), and one O(9) atom to form distorted GeO5 trigonal bipyramids that share  an edgeedge with one Y(3)O6F pentagonal bipyramid. The Ge(1)-O(1) bond length is 1.90 Å. The Ge(1)-O(4) bond length is 1.90 Å. The Ge(1)-O(5) bond length is 1.87 Å. The Ge(1)-O(8) bond length is 1.86 Å. The Ge(1)-O(9) bond length is 1.79 Å. In the second Ge site, Ge(2) is bonded to one O(10), one O(2), one O(3), one O(6), and one O(7) atom to form distorted GeO5 trigonal bipyramids that share corners with two equivalent Y(3)O6F pentagonal bipyramids. The Ge(2)-O(10) bond length is 1.79 Å. The Ge(2)-O(2) bond length is 1.89 Å. The Ge(2)-O(3) bond length is 1.92 Å. The Ge(2)-O(6) bond length is 1.87 Å. The Ge(2)-O(7) bond length is 1.84 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the second O site, O(2) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the third O site, O(3) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fourth O site, O(4) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fifth O site, O(5) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the sixth O site, O(6) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the seventh O site, O(7) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the eighth O site, O(8) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Y(2) and one Ge(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Y(1) and one Ge(2) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(6) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(5) atom. In the thirteenth O site, O(13) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(5) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(6) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(3), and one Y(5) atom. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(4), and one Y(6) atom.