CsNaTe is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Cs(1) is bonded in a 5-coordinate geometry to five equivalent Te(1) atoms. Na(1) is bonded to four equivalent Te(1) atoms to form a mixture of corner and edge-sharing NaTe4 tetrahedra. Te(1) is bonded in a 9-coordinate geometry to five equivalent Cs(1) and four equivalent Na(1) atoms.
CsNaTe is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Cs(1) is bonded in a 5-coordinate geometry to five equivalent Te(1) atoms. There is one shorter (3.93 Å) and four longer (3.96 Å) Cs(1)-Te(1) bond lengths. Na(1) is bonded to four equivalent Te(1) atoms to form a mixture of corner and edge-sharing NaTe4 tetrahedra. All Na(1)-Te(1) bond lengths are 3.16 Å. Te(1) is bonded in a 9-coordinate geometry to five equivalent Cs(1) and four equivalent Na(1) atoms.