SrLaMnRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. La(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-28°. Ru(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form RuO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-28°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one Mn(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one Mn(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one Mn(1), and one Ru(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(1), one Mn(1), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(1), one Mn(1), and one Ru(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(1), one Mn(1), and one Ru(1) atom.
SrLaMnRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. The Sr(1)-O(4) bond length is 2.50 Å. The Sr(1)-O(5) bond length is 2.49 Å. The Sr(1)-O(6) bond length is 2.50 Å. There is one shorter (2.74 Å) and one longer (3.00 Å) Sr(1)-O(1) bond length. There is one shorter (2.77 Å) and one longer (2.98 Å) Sr(1)-O(2) bond length. There is one shorter (2.77 Å) and one longer (2.92 Å) Sr(1)-O(3) bond length. La(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. The La(1)-O(1) bond length is 2.39 Å. The La(1)-O(2) bond length is 2.40 Å. The La(1)-O(3) bond length is 2.37 Å. There is one shorter (2.82 Å) and one longer (2.84 Å) La(1)-O(4) bond length. There is one shorter (2.77 Å) and one longer (2.95 Å) La(1)-O(5) bond length. There is one shorter (2.75 Å) and one longer (2.96 Å) La(1)-O(6) bond length. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-28°. The Mn(1)-O(1) bond length is 2.11 Å. The Mn(1)-O(2) bond length is 2.11 Å. The Mn(1)-O(3) bond length is 2.13 Å. The Mn(1)-O(4) bond length is 2.19 Å. The Mn(1)-O(5) bond length is 2.12 Å. The Mn(1)-O(6) bond length is 2.12 Å. Ru(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form RuO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-28°. The Ru(1)-O(1) bond length is 2.00 Å. The Ru(1)-O(2) bond length is 2.00 Å. The Ru(1)-O(3) bond length is 2.04 Å. The Ru(1)-O(4) bond length is 1.97 Å. The Ru(1)-O(5) bond length is 1.96 Å. The Ru(1)-O(6) bond length is 1.96 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one Mn(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one Mn(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one Mn(1), and one Ru(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(1), one Mn(1), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(1), one Mn(1), and one Ru(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Sr(1), two equivalent La(1), one Mn(1), and one Ru(1) atom.