NdPdAs is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6_3mc space group. Nd(1) is bonded to six equivalent Pd(1) and six equivalent As(1) atoms to form a mixture of face and edge-sharing NdAs6Pd6 cuboctahedra. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent As(1) atoms. As(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent Pd(1) atoms.
NdPdAs is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6_3mc space group. Nd(1) is bonded to six equivalent Pd(1) and six equivalent As(1) atoms to form a mixture of face and edge-sharing NdAs6Pd6 cuboctahedra. There are three shorter (3.14 Å) and three longer (3.24 Å) Nd(1)-Pd(1) bond lengths. There are three shorter (3.14 Å) and three longer (3.24 Å) Nd(1)-As(1) bond lengths. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent As(1) atoms. All Pd(1)-As(1) bond lengths are 2.52 Å. As(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent Pd(1) atoms.