AsNO3NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two AsNO3 clusters. In each AsNO3 cluster, As(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. N(2) is bonded in a bent 120 degrees geometry to one O(2) and one O(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom.
AsNO3NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two AsNO3 clusters. In each AsNO3 cluster, As(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. The As(1)-O(1) bond length is 1.64 Å. The As(1)-O(2) bond length is 2.44 Å. The As(1)-O(4) bond length is 2.06 Å. N(2) is bonded in a bent 120 degrees geometry to one O(2) and one O(4) atom. The N(2)-O(2) bond length is 1.25 Å. The N(2)-O(4) bond length is 1.31 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom.