N2(Sb4F13)2 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of two ammonia atoms and two Sb4F13 clusters. In each Sb4F13 cluster, Sb(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a square co-planar geometry to four equivalent Sb(1) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.
N2(Sb4F13)2 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of two ammonia atoms and two Sb4F13 clusters. In each Sb4F13 cluster, Sb(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and two equivalent F(3) atoms. The Sb(1)-F(1) bond length is 1.98 Å. The Sb(1)-F(2) bond length is 2.69 Å. Both Sb(1)-F(3) bond lengths are 1.94 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a square co-planar geometry to four equivalent Sb(1) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.