MoSeOCl7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one MoSeOCl7 cluster. Mo(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. Se(1) is bonded in a 6-coordinate geometry to one Cl(1), one Cl(3), one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Mo(1) and one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(1) atom. In the sixth Cl site, Cl(6) is bonded in a water-like geometry to one Mo(1) and one Se(1) atom. In the seventh Cl site, Cl(7) is bonded in a distorted single-bond geometry to one Mo(1) and one Se(1) atom.
MoSeOCl7 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one MoSeOCl7 cluster. Mo(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. The Mo(1)-O(1) bond length is 1.69 Å. The Mo(1)-Cl(2) bond length is 2.34 Å. The Mo(1)-Cl(3) bond length is 2.44 Å. The Mo(1)-Cl(6) bond length is 2.41 Å. The Mo(1)-Cl(7) bond length is 2.41 Å. Se(1) is bonded in a 6-coordinate geometry to one Cl(1), one Cl(3), one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom. The Se(1)-Cl(1) bond length is 2.20 Å. The Se(1)-Cl(3) bond length is 2.90 Å. The Se(1)-Cl(4) bond length is 2.21 Å. The Se(1)-Cl(5) bond length is 2.20 Å. The Se(1)-Cl(6) bond length is 2.78 Å. The Se(1)-Cl(7) bond length is 2.93 Å. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Mo(1) and one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(1) atom. In the sixth Cl site, Cl(6) is bonded in a water-like geometry to one Mo(1) and one Se(1) atom. In the seventh Cl site, Cl(7) is bonded in a distorted single-bond geometry to one Mo(1) and one Se(1) atom.