Th2SbN2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. Th(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent N(1) atoms. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Th(1) atoms. N(1) is bonded to four equivalent Th(1) atoms to form a mixture of corner and edge-sharing NTh4 tetrahedra.
Th2SbN2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. Th(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent N(1) atoms. All Th(1)-Sb(1) bond lengths are 3.69 Å. All Th(1)-N(1) bond lengths are 2.33 Å. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Th(1) atoms. N(1) is bonded to four equivalent Th(1) atoms to form a mixture of corner and edge-sharing NTh4 tetrahedra.