Sn3(HO2)2 is Indium structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two Sn3(HO2)2 clusters. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sn(2), two equivalent Sn(1), and one H(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Sn(2) and two equivalent Sn(1) atoms.
Sn3(HO2)2 is Indium structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two Sn3(HO2)2 clusters. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There is one shorter (2.32 Å) and one longer (2.41 Å) Sn(1)-O(1) bond length. Both Sn(1)-O(2) bond lengths are 2.11 Å. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Sn(2)-O(1) bond lengths are 2.35 Å. Both Sn(2)-O(2) bond lengths are 2.13 Å. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sn(2), two equivalent Sn(1), and one H(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Sn(2) and two equivalent Sn(1) atoms.