V3Pd crystallizes in the trigonal R-3c space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Pd(1) atoms. Pd(1) is bonded to twelve equivalent V(1) atoms to form a mixture of face and edge-sharing PdV12 cuboctahedra.
V3Pd crystallizes in the trigonal R-3c space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Pd(1) atoms. Both V(1)-V(1) bond lengths are 2.40 Å. There are two shorter (2.68 Å) and two longer (2.69 Å) V(1)-Pd(1) bond lengths. Pd(1) is bonded to twelve equivalent V(1) atoms to form a mixture of face and edge-sharing PdV12 cuboctahedra.