Na2CN2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 6-coordinate geometry to one C(1) and five equivalent N(1) atoms. C(1) is bonded in a linear geometry to two equivalent Na(1) and two equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to five equivalent Na(1) and one C(1) atom.
Na2CN2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 6-coordinate geometry to one C(1) and five equivalent N(1) atoms. The Na(1)-C(1) bond length is 2.71 Å. There are a spread of Na(1)-N(1) bond distances ranging from 2.40-2.58 Å. C(1) is bonded in a linear geometry to two equivalent Na(1) and two equivalent N(1) atoms. Both C(1)-N(1) bond lengths are 1.24 Å. N(1) is bonded in a 6-coordinate geometry to five equivalent Na(1) and one C(1) atom.