Pd3Sb is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(2) and four equivalent Sb(1) atoms. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to eight equivalent Pd(1) and six equivalent Sb(1) atoms. Sb(1) is bonded in a distorted body-centered cubic geometry to six equivalent Pd(2) and eight equivalent Pd(1) atoms.
Pd3Sb is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(2) and four equivalent Sb(1) atoms. All Pd(1)-Pd(2) bond lengths are 2.77 Å. All Pd(1)-Sb(1) bond lengths are 2.77 Å. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to eight equivalent Pd(1) and six equivalent Sb(1) atoms. All Pd(2)-Sb(1) bond lengths are 3.19 Å. Sb(1) is bonded in a distorted body-centered cubic geometry to six equivalent Pd(2) and eight equivalent Pd(1) atoms.