Li6Mn(OF)3 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one F(2), and one F(4) atom to form distorted LiO2F2 trigonal pyramids that share corners with two equivalent Mn(2)O3F3 octahedra,  a cornercorner with one Li(10)O3F trigonal pyramid,  a cornercorner with one Li(8)OF3 trigonal pyramid,  an edgeedge with one Mn(1)O3F3 octahedra,  an edgeedge with one Li(3)O2F2 trigonal pyramid, and  an edgeedge with one Li(5)O2F2 trigonal pyramid. The corner-sharing octahedral tilt angles range from 39-65°. In the second Li site, Li(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. In the third Li site, Li(3) is bonded to one O(1), one O(5), one F(1), and one F(4) atom to form distorted LiO2F2 trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(8)OF3 trigonal pyramid,  an edgeedge with one Mn(2)O3F3 octahedra,  an edgeedge with one Li(1)O2F2 trigonal pyramid, and  an edgeedge with one Li(5)O2F2 trigonal pyramid. The corner-sharing octahedral tilt angles range from 42-59°. In the fourth Li site, Li(4) is bonded in a distorted see-saw-like geometry to one O(2), one O(4), one O(6), and one F(3) atom. In the fifth Li site, Li(5) is bonded to one O(3), one O(5), one F(1), and one F(2) atom to form distorted LiO2F2 trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(10)O3F trigonal pyramid,  an edgeedge with one Mn(2)O3F3 octahedra,  an edgeedge with one Li(1)O2F2 trigonal pyramid, and  an edgeedge with one Li(3)O2F2 trigonal pyramid. The corner-sharing octahedral tilt angles range from 47-59°. In the sixth Li site, Li(6) is bonded to one O(2), one O(4), one F(5), and one F(6) atom to form distorted LiO2F2 trigonal pyramids that share corners with two equivalent Mn(1)O3F3 octahedra, corners with two equivalent Li(10)O3F trigonal pyramids, corners with two equivalent Li(8)OF3 trigonal pyramids, and  an edgeedge with one Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the seventh Li site, Li(7) is bonded in a distorted see-saw-like geometry to one O(2), one O(5), one F(1), and one F(5) atom. In the eighth Li site, Li(8) is bonded to one O(4), one F(3), one F(4), and one F(6) atom to form distorted LiOF3 trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(1)O2F2 trigonal pyramid,  a cornercorner with one Li(3)O2F2 trigonal pyramid, corners with two equivalent Li(6)O2F2 trigonal pyramids,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Li(10)O3F trigonal pyramid. The corner-sharing octahedral tilt angles range from 45-68°. In the ninth Li site, Li(9) is bonded in a distorted see-saw-like geometry to one O(1), one O(5), one F(2), and one F(5) atom. In the tenth Li site, Li(10) is bonded to one O(3), one O(4), one O(6), and one F(6) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(1)O2F2 trigonal pyramid,  a cornercorner with one Li(5)O2F2 trigonal pyramid, corners with two equivalent Li(6)O2F2 trigonal pyramids,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Li(8)OF3 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-62°. In the eleventh Li site, Li(11) is bonded in a distorted see-saw-like geometry to one O(6), one F(3), one F(5), and one F(6) atom. In the twelfth Li site, Li(12) is bonded in a distorted see-saw-like geometry to one O(3), one O(6), one F(3), and one F(4) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(6), one F(2), one F(3), and one F(5) atom to form distorted MnO3F3 octahedra that share  a cornercorner with one Li(3)O2F2 trigonal pyramid,  a cornercorner with one Li(5)O2F2 trigonal pyramid,  a cornercorner with one Li(10)O3F trigonal pyramid,  a cornercorner with one Li(8)OF3 trigonal pyramid, corners with two equivalent Li(6)O2F2 trigonal pyramids, and  an edgeedge with one Li(1)O2F2 trigonal pyramid. In the second Mn site, Mn(2) is bonded to one O(3), one O(4), one O(5), one F(1), one F(4), and one F(6) atom to form distorted MnO3F3 octahedra that share  a cornercorner with one Li(3)O2F2 trigonal pyramid,  a cornercorner with one Li(5)O2F2 trigonal pyramid,  a cornercorner with one Li(10)O3F trigonal pyramid,  a cornercorner with one Li(8)OF3 trigonal pyramid, corners with two equivalent Li(1)O2F2 trigonal pyramids,  an edgeedge with one Li(3)O2F2 trigonal pyramid,  an edgeedge with one Li(5)O2F2 trigonal pyramid,  an edgeedge with one Li(6)O2F2 trigonal pyramid,  an edgeedge with one Li(10)O3F trigonal pyramid, and  an edgeedge with one Li(8)OF3 trigonal pyramid. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(9), and one Mn(1) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(3)Li4Mn trigonal bipyramid,  a cornercorner with one O(6)Li4Mn trigonal bipyramid, corners with two equivalent O(2)Li4Mn trigonal bipyramids, corners with two equivalent O(5)Li4Mn trigonal bipyramids,  an edgeedge with one F(4)Li4Mn trigonal bipyramid, and  an edgeedge with one F(5)Li4Mn trigonal bipyramid. In the second O site, O(2) is bonded to one Li(2), one Li(4), one Li(6), one Li(7), and one Mn(1) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(5)Li4Mn trigonal bipyramid,  a cornercorner with one F(5)Li4Mn trigonal bipyramid,  a cornercorner with one F(6)Li4Mn trigonal bipyramid, corners with two equivalent O(1)Li4Mn trigonal bipyramids,  an edgeedge with one O(4)Li4Mn trigonal bipyramid,  an edgeedge with one O(6)Li4Mn trigonal bipyramid, and  an edgeedge with one F(5)Li4Mn trigonal bipyramid. In the third O site, O(3) is bonded to one Li(1), one Li(10), one Li(12), one Li(5), and one Mn(2) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(1)Li4Mn trigonal bipyramid,  a cornercorner with one F(4)Li4Mn trigonal bipyramid, corners with two equivalent O(5)Li4Mn trigonal bipyramids, corners with two equivalent F(6)Li4Mn trigonal bipyramids,  an edgeedge with one O(4)Li4Mn trigonal bipyramid,  an edgeedge with one O(6)Li4Mn trigonal bipyramid, and  an edgeedge with one F(4)Li4Mn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one Li(6), one Li(8), and one Mn(2) atom to form OLi4Mn trigonal bipyramids that share  a cornercorner with one O(5)Li4Mn trigonal bipyramid,  a cornercorner with one F(5)Li4Mn trigonal bipyramid, corners with two equivalent O(6)Li4Mn trigonal bipyramids, corners with two equivalent F(4)Li4Mn trigonal bipyramids,  an edgeedge with one O(2)Li4Mn trigonal bipyramid,  an edgeedge with one O(3)Li4Mn trigonal bipyramid, and edges with two equivalent F(6)Li4Mn trigonal bipyramids. In the fifth O site, O(5) is bonded to one Li(3), one Li(5), one Li(7), one Li(9), and one Mn(2) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(2)Li4Mn trigonal bipyramid,  a cornercorner with one O(4)Li4Mn trigonal bipyramid,  a cornercorner with one F(6)Li4Mn trigonal bipyramid, corners with two equivalent O(1)Li4Mn trigonal bipyramids, corners with two equivalent O(3)Li4Mn trigonal bipyramids,  an edgeedge with one F(4)Li4Mn trigonal bipyramid, and  an edgeedge with one F(5)Li4Mn trigonal bipyramid. In the sixth O site, O(6) is bonded to one Li(10), one Li(11), one Li(12), one Li(4), and one Mn(1) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(1)Li4Mn trigonal bipyramid,  a cornercorner with one F(4)Li4Mn trigonal bipyramid, corners with two equivalent O(4)Li4Mn trigonal bipyramids, corners with two equivalent F(5)Li4Mn trigonal bipyramids,  an edgeedge with one O(2)Li4Mn trigonal bipyramid,  an edgeedge with one O(3)Li4Mn trigonal bipyramid, and  an edgeedge with one F(6)Li4Mn trigonal bipyramid. There are six inequivalent F sites. In the first F site, F(1) is bonded in a 5-coordinate geometry to one Li(2), one Li(3), one Li(5), one Li(7), and one Mn(2) atom. In the second F site, F(2) is bonded in a 5-coordinate geometry to one Li(1), one Li(2), one Li(5), one Li(9), and one Mn(1) atom. In the third F site, F(3) is bonded in a 5-coordinate geometry to one Li(11), one Li(12), one Li(4), one Li(8), and one Mn(1) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(12), one Li(3), one Li(8), and one Mn(2) atom to form distorted FLi4Mn trigonal bipyramids that share  a cornercorner with one O(3)Li4Mn trigonal bipyramid,  a cornercorner with one O(6)Li4Mn trigonal bipyramid, corners with two equivalent O(4)Li4Mn trigonal bipyramids,  an edgeedge with one O(1)Li4Mn trigonal bipyramid,  an edgeedge with one O(3)Li4Mn trigonal bipyramid,  an edgeedge with one O(5)Li4Mn trigonal bipyramid, and  an edgeedge with one F(6)Li4Mn trigonal bipyramid. In the fifth F site, F(5) is bonded to one Li(11), one Li(6), one Li(7), one Li(9), and one Mn(1) atom to form distorted FLi4Mn trigonal bipyramids that share  a cornercorner with one O(2)Li4Mn trigonal bipyramid,  a cornercorner with one O(4)Li4Mn trigonal bipyramid, corners with two equivalent O(6)Li4Mn trigonal bipyramids,  an edgeedge with one O(1)Li4Mn trigonal bipyramid,  an edgeedge with one O(2)Li4Mn trigonal bipyramid,  an edgeedge with one O(5)Li4Mn trigonal bipyramid, and  an edgeedge with one F(6)Li4Mn trigonal bipyramid. In the sixth F site, F(6) is bonded to one Li(10), one Li(11), one Li(6), one Li(8), and one Mn(2) atom to form distorted FLi4Mn trigonal bipyramids that share  a cornercorner with one O(2)Li4Mn trigonal bipyramid,  a cornercorner with one O(5)Li4Mn trigonal bipyramid, corners with two equivalent O(3)Li4Mn trigonal bipyramids,  an edgeedge with one O(6)Li4Mn trigonal bipyramid,  an edgeedge with one F(4)Li4Mn trigonal bipyramid,  an edgeedge with one F(5)Li4Mn trigonal bipyramid, and edges with two equivalent O(4)Li4Mn trigonal bipyramids.
Li6Mn(OF)3 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one F(2), and one F(4) atom to form distorted LiO2F2 trigonal pyramids that share corners with two equivalent Mn(2)O3F3 octahedra,  a cornercorner with one Li(10)O3F trigonal pyramid,  a cornercorner with one Li(8)OF3 trigonal pyramid,  an edgeedge with one Mn(1)O3F3 octahedra,  an edgeedge with one Li(3)O2F2 trigonal pyramid, and  an edgeedge with one Li(5)O2F2 trigonal pyramid. The corner-sharing octahedral tilt angles range from 39-65°. The Li(1)-O(1) bond length is 1.95 Å. The Li(1)-O(3) bond length is 1.91 Å. The Li(1)-F(2) bond length is 1.95 Å. The Li(1)-F(4) bond length is 2.05 Å. In the second Li site, Li(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. The Li(2)-O(1) bond length is 1.97 Å. The Li(2)-O(2) bond length is 1.96 Å. The Li(2)-F(1) bond length is 1.95 Å. The Li(2)-F(2) bond length is 1.99 Å. In the third Li site, Li(3) is bonded to one O(1), one O(5), one F(1), and one F(4) atom to form distorted LiO2F2 trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(8)OF3 trigonal pyramid,  an edgeedge with one Mn(2)O3F3 octahedra,  an edgeedge with one Li(1)O2F2 trigonal pyramid, and  an edgeedge with one Li(5)O2F2 trigonal pyramid. The corner-sharing octahedral tilt angles range from 42-59°. The Li(3)-O(1) bond length is 1.90 Å. The Li(3)-O(5) bond length is 1.90 Å. The Li(3)-F(1) bond length is 1.91 Å. The Li(3)-F(4) bond length is 1.99 Å. In the fourth Li site, Li(4) is bonded in a distorted see-saw-like geometry to one O(2), one O(4), one O(6), and one F(3) atom. The Li(4)-O(2) bond length is 1.95 Å. The Li(4)-O(4) bond length is 1.93 Å. The Li(4)-O(6) bond length is 1.94 Å. The Li(4)-F(3) bond length is 1.97 Å. In the fifth Li site, Li(5) is bonded to one O(3), one O(5), one F(1), and one F(2) atom to form distorted LiO2F2 trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(10)O3F trigonal pyramid,  an edgeedge with one Mn(2)O3F3 octahedra,  an edgeedge with one Li(1)O2F2 trigonal pyramid, and  an edgeedge with one Li(3)O2F2 trigonal pyramid. The corner-sharing octahedral tilt angles range from 47-59°. The Li(5)-O(3) bond length is 1.97 Å. The Li(5)-O(5) bond length is 1.94 Å. The Li(5)-F(1) bond length is 1.97 Å. The Li(5)-F(2) bond length is 1.93 Å. In the sixth Li site, Li(6) is bonded to one O(2), one O(4), one F(5), and one F(6) atom to form distorted LiO2F2 trigonal pyramids that share corners with two equivalent Mn(1)O3F3 octahedra, corners with two equivalent Li(10)O3F trigonal pyramids, corners with two equivalent Li(8)OF3 trigonal pyramids, and  an edgeedge with one Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. The Li(6)-O(2) bond length is 1.94 Å. The Li(6)-O(4) bond length is 1.95 Å. The Li(6)-F(5) bond length is 2.00 Å. The Li(6)-F(6) bond length is 1.97 Å. In the seventh Li site, Li(7) is bonded in a distorted see-saw-like geometry to one O(2), one O(5), one F(1), and one F(5) atom. The Li(7)-O(2) bond length is 1.92 Å. The Li(7)-O(5) bond length is 1.95 Å. The Li(7)-F(1) bond length is 1.98 Å. The Li(7)-F(5) bond length is 2.07 Å. In the eighth Li site, Li(8) is bonded to one O(4), one F(3), one F(4), and one F(6) atom to form distorted LiOF3 trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(1)O2F2 trigonal pyramid,  a cornercorner with one Li(3)O2F2 trigonal pyramid, corners with two equivalent Li(6)O2F2 trigonal pyramids,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Li(10)O3F trigonal pyramid. The corner-sharing octahedral tilt angles range from 45-68°. The Li(8)-O(4) bond length is 1.91 Å. The Li(8)-F(3) bond length is 1.94 Å. The Li(8)-F(4) bond length is 1.99 Å. The Li(8)-F(6) bond length is 1.93 Å. In the ninth Li site, Li(9) is bonded in a distorted see-saw-like geometry to one O(1), one O(5), one F(2), and one F(5) atom. The Li(9)-O(1) bond length is 1.93 Å. The Li(9)-O(5) bond length is 1.91 Å. The Li(9)-F(2) bond length is 1.95 Å. The Li(9)-F(5) bond length is 2.03 Å. In the tenth Li site, Li(10) is bonded to one O(3), one O(4), one O(6), and one F(6) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O3F3 octahedra,  a cornercorner with one Li(1)O2F2 trigonal pyramid,  a cornercorner with one Li(5)O2F2 trigonal pyramid, corners with two equivalent Li(6)O2F2 trigonal pyramids,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Li(8)OF3 trigonal pyramid. The corner-sharing octahedral tilt angles range from 32-62°. The Li(10)-O(3) bond length is 1.96 Å. The Li(10)-O(4) bond length is 1.93 Å. The Li(10)-O(6) bond length is 1.91 Å. The Li(10)-F(6) bond length is 1.98 Å. In the eleventh Li site, Li(11) is bonded in a distorted see-saw-like geometry to one O(6), one F(3), one F(5), and one F(6) atom. The Li(11)-O(6) bond length is 1.93 Å. The Li(11)-F(3) bond length is 1.96 Å. The Li(11)-F(5) bond length is 1.98 Å. The Li(11)-F(6) bond length is 1.94 Å. In the twelfth Li site, Li(12) is bonded in a distorted see-saw-like geometry to one O(3), one O(6), one F(3), and one F(4) atom. The Li(12)-O(3) bond length is 1.93 Å. The Li(12)-O(6) bond length is 1.95 Å. The Li(12)-F(3) bond length is 1.94 Å. The Li(12)-F(4) bond length is 2.00 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(6), one F(2), one F(3), and one F(5) atom to form distorted MnO3F3 octahedra that share  a cornercorner with one Li(3)O2F2 trigonal pyramid,  a cornercorner with one Li(5)O2F2 trigonal pyramid,  a cornercorner with one Li(10)O3F trigonal pyramid,  a cornercorner with one Li(8)OF3 trigonal pyramid, corners with two equivalent Li(6)O2F2 trigonal pyramids, and  an edgeedge with one Li(1)O2F2 trigonal pyramid. The Mn(1)-O(1) bond length is 1.91 Å. The Mn(1)-O(2) bond length is 1.88 Å. The Mn(1)-O(6) bond length is 1.91 Å. The Mn(1)-F(2) bond length is 2.45 Å. The Mn(1)-F(3) bond length is 2.44 Å. The Mn(1)-F(5) bond length is 2.23 Å. In the second Mn site, Mn(2) is bonded to one O(3), one O(4), one O(5), one F(1), one F(4), and one F(6) atom to form distorted MnO3F3 octahedra that share  a cornercorner with one Li(3)O2F2 trigonal pyramid,  a cornercorner with one Li(5)O2F2 trigonal pyramid,  a cornercorner with one Li(10)O3F trigonal pyramid,  a cornercorner with one Li(8)OF3 trigonal pyramid, corners with two equivalent Li(1)O2F2 trigonal pyramids,  an edgeedge with one Li(3)O2F2 trigonal pyramid,  an edgeedge with one Li(5)O2F2 trigonal pyramid,  an edgeedge with one Li(6)O2F2 trigonal pyramid,  an edgeedge with one Li(10)O3F trigonal pyramid, and  an edgeedge with one Li(8)OF3 trigonal pyramid. The Mn(2)-O(3) bond length is 1.89 Å. The Mn(2)-O(4) bond length is 1.90 Å. The Mn(2)-O(5) bond length is 1.90 Å. The Mn(2)-F(1) bond length is 2.42 Å. The Mn(2)-F(4) bond length is 2.24 Å. The Mn(2)-F(6) bond length is 2.44 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Li(9), and one Mn(1) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(3)Li4Mn trigonal bipyramid,  a cornercorner with one O(6)Li4Mn trigonal bipyramid, corners with two equivalent O(2)Li4Mn trigonal bipyramids, corners with two equivalent O(5)Li4Mn trigonal bipyramids,  an edgeedge with one F(4)Li4Mn trigonal bipyramid, and  an edgeedge with one F(5)Li4Mn trigonal bipyramid. In the second O site, O(2) is bonded to one Li(2), one Li(4), one Li(6), one Li(7), and one Mn(1) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(5)Li4Mn trigonal bipyramid,  a cornercorner with one F(5)Li4Mn trigonal bipyramid,  a cornercorner with one F(6)Li4Mn trigonal bipyramid, corners with two equivalent O(1)Li4Mn trigonal bipyramids,  an edgeedge with one O(4)Li4Mn trigonal bipyramid,  an edgeedge with one O(6)Li4Mn trigonal bipyramid, and  an edgeedge with one F(5)Li4Mn trigonal bipyramid. In the third O site, O(3) is bonded to one Li(1), one Li(10), one Li(12), one Li(5), and one Mn(2) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(1)Li4Mn trigonal bipyramid,  a cornercorner with one F(4)Li4Mn trigonal bipyramid, corners with two equivalent O(5)Li4Mn trigonal bipyramids, corners with two equivalent F(6)Li4Mn trigonal bipyramids,  an edgeedge with one O(4)Li4Mn trigonal bipyramid,  an edgeedge with one O(6)Li4Mn trigonal bipyramid, and  an edgeedge with one F(4)Li4Mn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one Li(6), one Li(8), and one Mn(2) atom to form OLi4Mn trigonal bipyramids that share  a cornercorner with one O(5)Li4Mn trigonal bipyramid,  a cornercorner with one F(5)Li4Mn trigonal bipyramid, corners with two equivalent O(6)Li4Mn trigonal bipyramids, corners with two equivalent F(4)Li4Mn trigonal bipyramids,  an edgeedge with one O(2)Li4Mn trigonal bipyramid,  an edgeedge with one O(3)Li4Mn trigonal bipyramid, and edges with two equivalent F(6)Li4Mn trigonal bipyramids. In the fifth O site, O(5) is bonded to one Li(3), one Li(5), one Li(7), one Li(9), and one Mn(2) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(2)Li4Mn trigonal bipyramid,  a cornercorner with one O(4)Li4Mn trigonal bipyramid,  a cornercorner with one F(6)Li4Mn trigonal bipyramid, corners with two equivalent O(1)Li4Mn trigonal bipyramids, corners with two equivalent O(3)Li4Mn trigonal bipyramids,  an edgeedge with one F(4)Li4Mn trigonal bipyramid, and  an edgeedge with one F(5)Li4Mn trigonal bipyramid. In the sixth O site, O(6) is bonded to one Li(10), one Li(11), one Li(12), one Li(4), and one Mn(1) atom to form distorted OLi4Mn trigonal bipyramids that share  a cornercorner with one O(1)Li4Mn trigonal bipyramid,  a cornercorner with one F(4)Li4Mn trigonal bipyramid, corners with two equivalent O(4)Li4Mn trigonal bipyramids, corners with two equivalent F(5)Li4Mn trigonal bipyramids,  an edgeedge with one O(2)Li4Mn trigonal bipyramid,  an edgeedge with one O(3)Li4Mn trigonal bipyramid, and  an edgeedge with one F(6)Li4Mn trigonal bipyramid. There are six inequivalent F sites. In the first F site, F(1) is bonded in a 5-coordinate geometry to one Li(2), one Li(3), one Li(5), one Li(7), and one Mn(2) atom. In the second F site, F(2) is bonded in a 5-coordinate geometry to one Li(1), one Li(2), one Li(5), one Li(9), and one Mn(1) atom. In the third F site, F(3) is bonded in a 5-coordinate geometry to one Li(11), one Li(12), one Li(4), one Li(8), and one Mn(1) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(12), one Li(3), one Li(8), and one Mn(2) atom to form distorted FLi4Mn trigonal bipyramids that share  a cornercorner with one O(3)Li4Mn trigonal bipyramid,  a cornercorner with one O(6)Li4Mn trigonal bipyramid, corners with two equivalent O(4)Li4Mn trigonal bipyramids,  an edgeedge with one O(1)Li4Mn trigonal bipyramid,  an edgeedge with one O(3)Li4Mn trigonal bipyramid,  an edgeedge with one O(5)Li4Mn trigonal bipyramid, and  an edgeedge with one F(6)Li4Mn trigonal bipyramid. In the fifth F site, F(5) is bonded to one Li(11), one Li(6), one Li(7), one Li(9), and one Mn(1) atom to form distorted FLi4Mn trigonal bipyramids that share  a cornercorner with one O(2)Li4Mn trigonal bipyramid,  a cornercorner with one O(4)Li4Mn trigonal bipyramid, corners with two equivalent O(6)Li4Mn trigonal bipyramids,  an edgeedge with one O(1)Li4Mn trigonal bipyramid,  an edgeedge with one O(2)Li4Mn trigonal bipyramid,  an edgeedge with one O(5)Li4Mn trigonal bipyramid, and  an edgeedge with one F(6)Li4Mn trigonal bipyramid. In the sixth F site, F(6) is bonded to one Li(10), one Li(11), one Li(6), one Li(8), and one Mn(2) atom to form distorted FLi4Mn trigonal bipyramids that share  a cornercorner with one O(2)Li4Mn trigonal bipyramid,  a cornercorner with one O(5)Li4Mn trigonal bipyramid, corners with two equivalent O(3)Li4Mn trigonal bipyramids,  an edgeedge with one O(6)Li4Mn trigonal bipyramid,  an edgeedge with one F(4)Li4Mn trigonal bipyramid,  an edgeedge with one F(5)Li4Mn trigonal bipyramid, and edges with two equivalent O(4)Li4Mn trigonal bipyramids.