CrCoNF6 crystallizes in the orthorhombic Imma space group. Cr(1) is bonded in a distorted body-centered cubic geometry to two equivalent N(1), two equivalent F(1), and four equivalent F(3) atoms. Co(1) is bonded in a distorted body-centered cubic geometry to two equivalent N(1), two equivalent F(2), and four equivalent F(3) atoms. N(1) is bonded to two equivalent Cr(1) and two equivalent Co(1) atoms to form corner-sharing NCr2Co2 tetrahedra. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Co(1) atoms. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Cr(1) and one Co(1) atom.
CrCoNF6 crystallizes in the orthorhombic Imma space group. Cr(1) is bonded in a distorted body-centered cubic geometry to two equivalent N(1), two equivalent F(1), and four equivalent F(3) atoms. Both Cr(1)-N(1) bond lengths are 2.21 Å. Both Cr(1)-F(1) bond lengths are 2.01 Å. All Cr(1)-F(3) bond lengths are 1.97 Å. Co(1) is bonded in a distorted body-centered cubic geometry to two equivalent N(1), two equivalent F(2), and four equivalent F(3) atoms. Both Co(1)-N(1) bond lengths are 2.13 Å. Both Co(1)-F(2) bond lengths are 1.99 Å. All Co(1)-F(3) bond lengths are 2.06 Å. N(1) is bonded to two equivalent Cr(1) and two equivalent Co(1) atoms to form corner-sharing NCr2Co2 tetrahedra. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Co(1) atoms. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Cr(1) and one Co(1) atom.