Os(CO)6(SbF6)2 is Fluorite structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of two Os(CO)6 clusters and four SbF6 clusters. In each Os(CO)6 cluster, Os(1) is bonded in an octahedral geometry to two equivalent C(2) and four equivalent C(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom.
Os(CO)6(SbF6)2 is Fluorite structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of two Os(CO)6 clusters and four SbF6 clusters. In each Os(CO)6 cluster, Os(1) is bonded in an octahedral geometry to two equivalent C(2) and four equivalent C(1) atoms. Both Os(1)-C(2) bond lengths are 2.01 Å. All Os(1)-C(1) bond lengths are 2.02 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Os(1) and one O(1) atom. The C(1)-O(1) bond length is 1.14 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(2) atom. The C(2)-O(2) bond length is 1.14 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. Both Sb(1)-F(1) bond lengths are 1.92 Å. All Sb(1)-F(2) bond lengths are 1.92 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom.