VPbO2 crystallizes in the tetragonal I4_1/a space group. V(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. O(1) is bonded to two equivalent V(1) and three equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing OV2Pb3 square pyramids.
VPbO2 crystallizes in the tetragonal I4_1/a space group. V(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. There are two shorter (2.09 Å) and two longer (2.17 Å) V(1)-O(1) bond lengths. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. There are a spread of Pb(1)-O(1) bond distances ranging from 2.56-2.66 Å. O(1) is bonded to two equivalent V(1) and three equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing OV2Pb3 square pyramids.