LiN4N2PNH2S3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia atoms, two LiN4 clusters, and two PNH2S3 clusters. In each LiN4 cluster, Li(1) is bonded in a rectangular see-saw-like geometry to one N(2), one N(4), one N(5), and one N(7) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Li(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Li(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Li(1) atom. In the fourth N site, N(7) is bonded in a single-bond geometry to one Li(1) atom. In each PNH2S3 cluster, P(1) is bonded in a 4-coordinate geometry to one N(1), one S(1), one S(2), and one S(3) atom. N(1) is bonded in a trigonal planar geometry to one P(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 2-coordinate geometry to one P(1) and one S(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one P(1) and one S(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one P(1) atom.
LiN4N2PNH2S3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia atoms, two LiN4 clusters, and two PNH2S3 clusters. In each LiN4 cluster, Li(1) is bonded in a rectangular see-saw-like geometry to one N(2), one N(4), one N(5), and one N(7) atom. The Li(1)-N(2) bond length is 2.28 Å. The Li(1)-N(4) bond length is 2.12 Å. The Li(1)-N(5) bond length is 2.22 Å. The Li(1)-N(7) bond length is 2.13 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Li(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Li(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Li(1) atom. In the fourth N site, N(7) is bonded in a single-bond geometry to one Li(1) atom. In each PNH2S3 cluster, P(1) is bonded in a 4-coordinate geometry to one N(1), one S(1), one S(2), and one S(3) atom. The P(1)-N(1) bond length is 1.63 Å. The P(1)-S(1) bond length is 2.12 Å. The P(1)-S(2) bond length is 2.08 Å. The P(1)-S(3) bond length is 1.94 Å. N(1) is bonded in a trigonal planar geometry to one P(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.02 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 2-coordinate geometry to one P(1) and one S(2) atom. The S(1)-S(2) bond length is 2.14 Å. In the second S site, S(2) is bonded in a distorted single-bond geometry to one P(1) and one S(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one P(1) atom.