V2O2F3 crystallizes in the orthorhombic Cmcm space group. V(1) is bonded to three equivalent O(1), one F(1), and two equivalent F(2) atoms to form a mixture of edge and corner-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.
V2O2F3 crystallizes in the orthorhombic Cmcm space group. V(1) is bonded to three equivalent O(1), one F(1), and two equivalent F(2) atoms to form a mixture of edge and corner-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-37°. There are two shorter (1.90 Å) and one longer (2.07 Å) V(1)-O(1) bond length. The V(1)-F(1) bond length is 2.00 Å. There is one shorter (1.94 Å) and one longer (2.05 Å) V(1)-F(2) bond length. O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.