LiSrPrTeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Li(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. Sr(1) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. Pr(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(2), and two equivalent O(3) atoms. Te(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form TeO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Sr(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Pr(1), and one Te(1) atom.
LiSrPrTeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Li(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form LiO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. The Li(1)-O(1) bond length is 2.15 Å. The Li(1)-O(4) bond length is 2.19 Å. Both Li(1)-O(2) bond lengths are 2.11 Å. Both Li(1)-O(3) bond lengths are 2.15 Å. Sr(1) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. The Sr(1)-O(1) bond length is 2.47 Å. Both Sr(1)-O(2) bond lengths are 2.60 Å. Both Sr(1)-O(3) bond lengths are 2.65 Å. Pr(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(2), and two equivalent O(3) atoms. The Pr(1)-O(4) bond length is 2.41 Å. Both Pr(1)-O(2) bond lengths are 2.49 Å. Both Pr(1)-O(3) bond lengths are 2.49 Å. Te(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form TeO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. The Te(1)-O(1) bond length is 1.93 Å. The Te(1)-O(4) bond length is 1.96 Å. Both Te(1)-O(2) bond lengths are 1.95 Å. Both Te(1)-O(3) bond lengths are 1.94 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Sr(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Pr(1), and one Te(1) atom.