Nd(CO3)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Nd(CO3)3 clusters. Nd(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one O(5) and one O(6) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Nd(1) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Nd(1) and one O(9) atom. In the fifth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(1) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Nd(1) and one O(8) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Nd(1) and one C(2) atom. In the ninth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one C(2) atom.
Nd(CO3)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Nd(CO3)3 clusters. Nd(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. The Nd(1)-O(1) bond length is 2.75 Å. The Nd(1)-O(3) bond length is 2.35 Å. The Nd(1)-O(4) bond length is 2.53 Å. The Nd(1)-O(5) bond length is 2.74 Å. The Nd(1)-O(7) bond length is 2.22 Å. The Nd(1)-O(8) bond length is 2.36 Å. The Nd(1)-O(9) bond length is 2.38 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.18 Å. The C(1)-O(2) bond length is 1.17 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(2)-O(3) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a linear geometry to one O(5) and one O(6) atom. The C(3)-O(5) bond length is 1.18 Å. The C(3)-O(6) bond length is 1.17 Å. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Nd(1) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Nd(1) and one O(9) atom. The O(8)-O(9) bond length is 1.35 Å. In the fifth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(1) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Nd(1) and one O(8) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Nd(1) and one C(2) atom. In the ninth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one C(2) atom.