RhB is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to six equivalent B(1) atoms to form a mixture of face, corner, and edge-sharing RhB6 octahedra. The corner-sharing octahedral tilt angles are 46°. B(1) is bonded to six equivalent Rh(1) atoms to form a mixture of distorted corner and edge-sharing BRh6 pentagonal pyramids.
RhB is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to six equivalent B(1) atoms to form a mixture of face, corner, and edge-sharing RhB6 octahedra. The corner-sharing octahedral tilt angles are 46°. All Rh(1)-B(1) bond lengths are 2.21 Å. B(1) is bonded to six equivalent Rh(1) atoms to form a mixture of distorted corner and edge-sharing BRh6 pentagonal pyramids.