TlAgBr3 crystallizes in the trigonal R3c space group. The structure consists of six 7440-28-0 atoms inside a AgBr3 framework. In the AgBr3 framework, Ag(1) is bonded to six equivalent Br(1) atoms to form corner-sharing AgBr6 octahedra. The corner-sharing octahedral tilt angles are 18°. Br(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Ag(1) atoms.
TlAgBr3 crystallizes in the trigonal R3c space group. The structure consists of six 7440-28-0 atoms inside a AgBr3 framework. In the AgBr3 framework, Ag(1) is bonded to six equivalent Br(1) atoms to form corner-sharing AgBr6 octahedra. The corner-sharing octahedral tilt angles are 18°. All Ag(1)-Br(1) bond lengths are 2.74 Å. Br(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Ag(1) atoms.