MgWF6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent F(1) atoms to form MgF6 octahedra that share corners with six equivalent W(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. W(1) is bonded to six equivalent F(1) atoms to form WF6 octahedra that share corners with six equivalent Mg(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. F(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one W(1) atom.
MgWF6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent F(1) atoms to form MgF6 octahedra that share corners with six equivalent W(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. All Mg(1)-F(1) bond lengths are 1.98 Å. W(1) is bonded to six equivalent F(1) atoms to form WF6 octahedra that share corners with six equivalent Mg(1)F6 octahedra. The corner-sharing octahedral tilt angles are 35°. All W(1)-F(1) bond lengths are 1.98 Å. F(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one W(1) atom.