Ag4TeSO4 crystallizes in the cubic P2_13 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to two equivalent Te(1), one O(1), and one O(2) atom. Te(1) is bonded in a 6-coordinate geometry to six equivalent Ag(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(2) and one S(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom.
Ag4TeSO4 crystallizes in the cubic P2_13 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) atoms. All Ag(1)-O(1) bond lengths are 2.46 Å. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to two equivalent Te(1), one O(1), and one O(2) atom. There is one shorter (2.78 Å) and one longer (2.84 Å) Ag(2)-Te(1) bond length. The Ag(2)-O(1) bond length is 2.45 Å. The Ag(2)-O(2) bond length is 2.64 Å. Te(1) is bonded in a 6-coordinate geometry to six equivalent Ag(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(2) and three equivalent O(1) atoms. The S(1)-O(2) bond length is 1.49 Å. All S(1)-O(1) bond lengths are 1.50 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(2) and one S(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom.