TiWP2 is Tungsten Carbide-derived structured and crystallizes in the orthorhombic Imm2 space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent P(1) and four equivalent P(2) atoms. W(1) is bonded in a 6-coordinate geometry to two equivalent P(2) and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent Ti(1) and four equivalent W(1) atoms to form distorted PTi2W4 pentagonal pyramids that share corners with four equivalent P(1)Ti2W4 pentagonal pyramids, corners with eight equivalent P(2)Ti4W2 pentagonal pyramids, edges with two equivalent P(1)Ti2W4 pentagonal pyramids, edges with four equivalent P(2)Ti4W2 pentagonal pyramids, and faces with two equivalent P(1)Ti2W4 pentagonal pyramids. In the second P site, P(2) is bonded to four equivalent Ti(1) and two equivalent W(1) atoms to form distorted PTi4W2 pentagonal pyramids that share corners with four equivalent P(2)Ti4W2 pentagonal pyramids, corners with eight equivalent P(1)Ti2W4 pentagonal pyramids, edges with two equivalent P(2)Ti4W2 pentagonal pyramids, edges with four equivalent P(1)Ti2W4 pentagonal pyramids, and faces with two equivalent P(2)Ti4W2 pentagonal pyramids.
TiWP2 is Tungsten Carbide-derived structured and crystallizes in the orthorhombic Imm2 space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent P(1) and four equivalent P(2) atoms. Both Ti(1)-P(1) bond lengths are 2.49 Å. All Ti(1)-P(2) bond lengths are 2.47 Å. W(1) is bonded in a 6-coordinate geometry to two equivalent P(2) and four equivalent P(1) atoms. Both W(1)-P(2) bond lengths are 2.44 Å. All W(1)-P(1) bond lengths are 2.50 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent Ti(1) and four equivalent W(1) atoms to form distorted PTi2W4 pentagonal pyramids that share corners with four equivalent P(1)Ti2W4 pentagonal pyramids, corners with eight equivalent P(2)Ti4W2 pentagonal pyramids, edges with two equivalent P(1)Ti2W4 pentagonal pyramids, edges with four equivalent P(2)Ti4W2 pentagonal pyramids, and faces with two equivalent P(1)Ti2W4 pentagonal pyramids. In the second P site, P(2) is bonded to four equivalent Ti(1) and two equivalent W(1) atoms to form distorted PTi4W2 pentagonal pyramids that share corners with four equivalent P(2)Ti4W2 pentagonal pyramids, corners with eight equivalent P(1)Ti2W4 pentagonal pyramids, edges with two equivalent P(2)Ti4W2 pentagonal pyramids, edges with four equivalent P(1)Ti2W4 pentagonal pyramids, and faces with two equivalent P(2)Ti4W2 pentagonal pyramids.