MgTi3Zn2O8 is Corundum-derived structured and crystallizes in the trigonal R-3m space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share edges with six equivalent Ti(1)O6 octahedra. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form TiO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with four equivalent Ti(1)O6 octahedra. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mg(1), two equivalent Ti(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to three equivalent Ti(1) and one Zn(1) atom.
MgTi3Zn2O8 is Corundum-derived structured and crystallizes in the trigonal R-3m space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share edges with six equivalent Ti(1)O6 octahedra. All Mg(1)-O(1) bond lengths are 2.02 Å. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form TiO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with four equivalent Ti(1)O6 octahedra. Both Ti(1)-O(2) bond lengths are 2.06 Å. All Ti(1)-O(1) bond lengths are 2.03 Å. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2) and three equivalent O(1) atoms. The Zn(1)-O(2) bond length is 1.91 Å. All Zn(1)-O(1) bond lengths are 2.17 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mg(1), two equivalent Ti(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to three equivalent Ti(1) and one Zn(1) atom.