VF4 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four tetrafluorovanadium molecules. V(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom.
VF4 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four tetrafluorovanadium molecules. V(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(4) atom. The V(1)-F(1) bond length is 1.81 Å. The V(1)-F(2) bond length is 1.80 Å. The V(1)-F(3) bond length is 1.80 Å. The V(1)-F(4) bond length is 1.79 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom.