LiNd2(HO)6 crystallizes in the monoclinic Pm space group. Li(1) is bonded in a 5-coordinate geometry to one H(3), one O(2), one O(3), and two equivalent O(5) atoms. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(4), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Li(1) and one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Nd(1), two equivalent Nd(2), and one H(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Nd(2), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Li(1), one Nd(1), two equivalent Nd(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Nd(2), two equivalent Nd(1), and one H(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Li(1), two equivalent Nd(1), and one H(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Nd(2), two equivalent Nd(1), and one H(6) atom.
LiNd2(HO)6 crystallizes in the monoclinic Pm space group. Li(1) is bonded in a 5-coordinate geometry to one H(3), one O(2), one O(3), and two equivalent O(5) atoms. The Li(1)-H(3) bond length is 2.06 Å. The Li(1)-O(2) bond length is 1.89 Å. The Li(1)-O(3) bond length is 2.15 Å. Both Li(1)-O(5) bond lengths are 2.18 Å. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. The Nd(1)-O(1) bond length is 2.51 Å. The Nd(1)-O(3) bond length is 2.56 Å. Both Nd(1)-O(4) bond lengths are 2.43 Å. Both Nd(1)-O(5) bond lengths are 2.60 Å. Both Nd(1)-O(6) bond lengths are 2.49 Å. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(4), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. The Nd(2)-O(4) bond length is 2.51 Å. The Nd(2)-O(6) bond length is 2.48 Å. Both Nd(2)-O(1) bond lengths are 2.45 Å. Both Nd(2)-O(2) bond lengths are 2.44 Å. Both Nd(2)-O(3) bond lengths are 2.59 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one Li(1) and one O(3) atom. The H(3)-O(3) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(4) atom. The H(4)-O(4) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. The H(5)-O(5) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. The H(6)-O(6) bond length is 0.99 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Nd(1), two equivalent Nd(2), and one H(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Nd(2), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Li(1), one Nd(1), two equivalent Nd(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Nd(2), two equivalent Nd(1), and one H(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Li(1), two equivalent Nd(1), and one H(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Nd(2), two equivalent Nd(1), and one H(6) atom.