AlCl4N2SeS2Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AlCl4 clusters and four N2SeS2Cl clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In each N2SeS2Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. Se(1) is bonded in a 3-coordinate geometry to one N(1), one S(2), and one Cl(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(2) and one Se(1) atom. Cl(1) is bonded in a single-bond geometry to one Se(1) atom.
AlCl4N2SeS2Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AlCl4 clusters and four N2SeS2Cl clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. The Al(1)-Cl(2) bond length is 2.16 Å. The Al(1)-Cl(3) bond length is 2.19 Å. The Al(1)-Cl(4) bond length is 2.16 Å. The Al(1)-Cl(5) bond length is 2.14 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In each N2SeS2Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. The N(1)-Se(1) bond length is 1.78 Å. The N(1)-S(1) bond length is 1.59 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.57 Å. The N(2)-S(2) bond length is 1.60 Å. Se(1) is bonded in a 3-coordinate geometry to one N(1), one S(2), and one Cl(1) atom. The Se(1)-S(2) bond length is 2.35 Å. The Se(1)-Cl(1) bond length is 2.25 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(2) and one Se(1) atom. Cl(1) is bonded in a single-bond geometry to one Se(1) atom.