Tl2TeBr6 is Fluorite structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and two TeBr6 clusters. In each TeBr6 cluster, Te(1) is bonded in an octahedral geometry to two equivalent Br(2) and four Br(1,1) atoms. There are three inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the third Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom.
Tl2TeBr6 is Fluorite structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and two TeBr6 clusters. In each TeBr6 cluster, Te(1) is bonded in an octahedral geometry to two equivalent Br(2) and four Br(1,1) atoms. Both Te(1)-Br(2) bond lengths are 2.73 Å. All Te(1)-Br(1,1) bond lengths are 2.71 Å. There are three inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the third Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom.