BaS2(NO3)2 crystallizes in the orthorhombic Pna2_1 space group. Ba(1) is bonded in a 11-coordinate geometry to one N(2), one O(4), one O(5), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ba(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(2), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Ba(1) and one S(2) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one Ba(1) and one S(2) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(2) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom. In the fifth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom.
BaS2(NO3)2 crystallizes in the orthorhombic Pna2_1 space group. Ba(1) is bonded in a 11-coordinate geometry to one N(2), one O(4), one O(5), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms. The Ba(1)-N(2) bond length is 3.13 Å. The Ba(1)-O(4) bond length is 2.75 Å. The Ba(1)-O(5) bond length is 2.71 Å. There is one shorter (2.83 Å) and one longer (3.28 Å) Ba(1)-O(1) bond length. There is one shorter (2.91 Å) and one longer (3.38 Å) Ba(1)-O(2) bond length. There is one shorter (2.94 Å) and one longer (2.97 Å) Ba(1)-O(3) bond length. There is one shorter (2.95 Å) and one longer (3.35 Å) Ba(1)-O(6) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. The N(1)-S(1) bond length is 1.65 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Ba(1) and one S(2) atom. The N(2)-S(2) bond length is 1.64 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.48 Å. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(2), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.46 Å. The S(2)-O(5) bond length is 1.46 Å. The S(2)-O(6) bond length is 1.48 Å. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Ba(1) and one S(2) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one Ba(1) and one S(2) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(2) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom. In the fifth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one S(1) atom.