V3Re is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Re(1) atoms. In the second V site, V(2) is bonded in a 14-coordinate geometry to eight equivalent V(1) and six equivalent Re(1) atoms. Re(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.
V3Re is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Re(1) atoms. All V(1)-V(2) bond lengths are 2.60 Å. All V(1)-Re(1) bond lengths are 2.60 Å. In the second V site, V(2) is bonded in a 14-coordinate geometry to eight equivalent V(1) and six equivalent Re(1) atoms. All V(2)-Re(1) bond lengths are 3.00 Å. Re(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.