Re3S4O3(O2)3 crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of eighteen hydrogen peroxide molecules and three Re3S4O3 clusters. In each Re3S4O3 cluster, Re(1) is bonded in a distorted single-bond geometry to one S(1), three equivalent S(2), and one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. In the second S site, S(2) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. O(1) is bonded in a single-bond geometry to one Re(1) atom.
Re3S4O3(O2)3 crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of eighteen hydrogen peroxide molecules and three Re3S4O3 clusters. In each Re3S4O3 cluster, Re(1) is bonded in a distorted single-bond geometry to one S(1), three equivalent S(2), and one O(1) atom. The Re(1)-S(1) bond length is 2.40 Å. All Re(1)-S(2) bond lengths are 2.39 Å. The Re(1)-O(1) bond length is 1.70 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. In the second S site, S(2) is bonded in a distorted T-shaped geometry to three equivalent Re(1) atoms. O(1) is bonded in a single-bond geometry to one Re(1) atom.