K6InP3 crystallizes in the triclinic P1 space group. There are twelve inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), one P(4), and one P(6) atom. In the second K site, K(2) is bonded in a 4-coordinate geometry to one P(1), one P(3), one P(4), and one P(5) atom. In the third K site, K(3) is bonded in a 4-coordinate geometry to one P(2), one P(4), one P(5), and one P(6) atom. In the fourth K site, K(4) is bonded in a 4-coordinate geometry to one P(1), one P(3), one P(5), and one P(6) atom. In the fifth K site, K(5) is bonded in a 4-coordinate geometry to one P(1), one P(2), one P(3), and one P(5) atom. In the sixth K site, K(6) is bonded in a 4-coordinate geometry to one P(1), one P(2), one P(4), and one P(6) atom. In the seventh K site, K(7) is bonded in a distorted tetrahedral geometry to one P(1), one P(2), one P(3), and one P(5) atom. In the eighth K site, K(8) is bonded in a 4-coordinate geometry to one P(1), one P(2), one P(4), and one P(6) atom. In the ninth K site, K(9) is bonded in a 6-coordinate geometry to one In(1), one In(2), one P(2), one P(3), one P(4), and one P(5) atom. In the tenth K site, K(10) is bonded in a 3-coordinate geometry to one P(1), one P(3), and one P(4) atom. In the eleventh K site, K(11) is bonded in a 3-coordinate geometry to one P(2), one P(4), and one P(5) atom. In the twelfth K site, K(12) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one P(3), one P(5), and one P(6) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted trigonal planar geometry to one K(9), one P(1), one P(3), and one P(5) atom. In the second In site, In(2) is bonded in a distorted trigonal planar geometry to one K(9), one P(2), one P(4), and one P(6) atom. There are six inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one K(10), one K(12), one K(2), one K(4), one K(5), one K(6), one K(7), one K(8), and one In(1) atom. In the second P site, P(2) is bonded in a 9-coordinate geometry to one K(1), one K(11), one K(3), one K(5), one K(6), one K(7), one K(8), one K(9), and one In(2) atom. In the third P site, P(3) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(12), one K(2), one K(4), one K(5), one K(7), one K(9), and one In(1) atom. In the fourth P site, P(4) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(11), one K(2), one K(3), one K(6), one K(8), one K(9), and one In(2) atom. In the fifth P site, P(5) is bonded in a 9-coordinate geometry to one K(11), one K(12), one K(2), one K(3), one K(4), one K(5), one K(7), one K(9), and one In(1) atom. In the sixth P site, P(6) is bonded in a 7-coordinate geometry to one K(1), one K(12), one K(3), one K(4), one K(6), one K(8), and one In(2) atom.
K6InP3 crystallizes in the triclinic P1 space group. There are twelve inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), one P(4), and one P(6) atom. The K(1)-P(2) bond length is 3.44 Å. The K(1)-P(3) bond length is 3.39 Å. The K(1)-P(4) bond length is 3.27 Å. The K(1)-P(6) bond length is 3.36 Å. In the second K site, K(2) is bonded in a 4-coordinate geometry to one P(1), one P(3), one P(4), and one P(5) atom. The K(2)-P(1) bond length is 3.50 Å. The K(2)-P(3) bond length is 3.31 Å. The K(2)-P(4) bond length is 3.31 Å. The K(2)-P(5) bond length is 3.25 Å. In the third K site, K(3) is bonded in a 4-coordinate geometry to one P(2), one P(4), one P(5), and one P(6) atom. The K(3)-P(2) bond length is 3.34 Å. The K(3)-P(4) bond length is 3.36 Å. The K(3)-P(5) bond length is 3.62 Å. The K(3)-P(6) bond length is 3.28 Å. In the fourth K site, K(4) is bonded in a 4-coordinate geometry to one P(1), one P(3), one P(5), and one P(6) atom. The K(4)-P(1) bond length is 3.41 Å. The K(4)-P(3) bond length is 3.36 Å. The K(4)-P(5) bond length is 3.30 Å. The K(4)-P(6) bond length is 3.49 Å. In the fifth K site, K(5) is bonded in a 4-coordinate geometry to one P(1), one P(2), one P(3), and one P(5) atom. The K(5)-P(1) bond length is 3.47 Å. The K(5)-P(2) bond length is 3.46 Å. The K(5)-P(3) bond length is 3.31 Å. The K(5)-P(5) bond length is 3.41 Å. In the sixth K site, K(6) is bonded in a 4-coordinate geometry to one P(1), one P(2), one P(4), and one P(6) atom. The K(6)-P(1) bond length is 3.44 Å. The K(6)-P(2) bond length is 3.41 Å. The K(6)-P(4) bond length is 3.39 Å. The K(6)-P(6) bond length is 3.42 Å. In the seventh K site, K(7) is bonded in a distorted tetrahedral geometry to one P(1), one P(2), one P(3), and one P(5) atom. The K(7)-P(1) bond length is 3.36 Å. The K(7)-P(2) bond length is 3.53 Å. The K(7)-P(3) bond length is 3.31 Å. The K(7)-P(5) bond length is 3.38 Å. In the eighth K site, K(8) is bonded in a 4-coordinate geometry to one P(1), one P(2), one P(4), and one P(6) atom. The K(8)-P(1) bond length is 3.62 Å. The K(8)-P(2) bond length is 3.19 Å. The K(8)-P(4) bond length is 3.25 Å. The K(8)-P(6) bond length is 3.17 Å. In the ninth K site, K(9) is bonded in a 6-coordinate geometry to one In(1), one In(2), one P(2), one P(3), one P(4), and one P(5) atom. The K(9)-In(1) bond length is 3.48 Å. The K(9)-In(2) bond length is 3.54 Å. The K(9)-P(2) bond length is 3.67 Å. The K(9)-P(3) bond length is 3.49 Å. The K(9)-P(4) bond length is 3.28 Å. The K(9)-P(5) bond length is 3.50 Å. In the tenth K site, K(10) is bonded in a 3-coordinate geometry to one P(1), one P(3), and one P(4) atom. The K(10)-P(1) bond length is 3.52 Å. The K(10)-P(3) bond length is 3.38 Å. The K(10)-P(4) bond length is 3.29 Å. In the eleventh K site, K(11) is bonded in a 3-coordinate geometry to one P(2), one P(4), and one P(5) atom. The K(11)-P(2) bond length is 3.45 Å. The K(11)-P(4) bond length is 3.47 Å. The K(11)-P(5) bond length is 3.36 Å. In the twelfth K site, K(12) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one P(3), one P(5), and one P(6) atom. The K(12)-P(1) bond length is 3.29 Å. The K(12)-P(3) bond length is 3.45 Å. The K(12)-P(5) bond length is 3.82 Å. The K(12)-P(6) bond length is 3.33 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted trigonal planar geometry to one K(9), one P(1), one P(3), and one P(5) atom. The In(1)-P(1) bond length is 2.54 Å. The In(1)-P(3) bond length is 2.54 Å. The In(1)-P(5) bond length is 2.54 Å. In the second In site, In(2) is bonded in a distorted trigonal planar geometry to one K(9), one P(2), one P(4), and one P(6) atom. The In(2)-P(2) bond length is 2.52 Å. The In(2)-P(4) bond length is 2.57 Å. The In(2)-P(6) bond length is 2.51 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one K(10), one K(12), one K(2), one K(4), one K(5), one K(6), one K(7), one K(8), and one In(1) atom. In the second P site, P(2) is bonded in a 9-coordinate geometry to one K(1), one K(11), one K(3), one K(5), one K(6), one K(7), one K(8), one K(9), and one In(2) atom. In the third P site, P(3) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(12), one K(2), one K(4), one K(5), one K(7), one K(9), and one In(1) atom. In the fourth P site, P(4) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(11), one K(2), one K(3), one K(6), one K(8), one K(9), and one In(2) atom. In the fifth P site, P(5) is bonded in a 9-coordinate geometry to one K(11), one K(12), one K(2), one K(3), one K(4), one K(5), one K(7), one K(9), and one In(1) atom. In the sixth P site, P(6) is bonded in a 7-coordinate geometry to one K(1), one K(12), one K(3), one K(4), one K(6), one K(8), and one In(2) atom.