CaP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one CaP3(OBr3)3 cluster. In the CaP3(OBr3)3 cluster, Ca(1) is bonded in a 5-coordinate geometry to one O(2), one Br(10), one Br(12), one Br(6), and one Br(7) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one Br(12), and one Br(5) atom. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one O(1), one Br(1), one Br(6), and one Br(7) atom. In the third P site, P(3) is bonded in a tetrahedral geometry to one O(2), one Br(4), one Br(8), and one Br(9) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(2) atom. In the second O site, O(2) is bonded in a linear geometry to one Ca(1) and one P(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one P(3) atom. In the third Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth Br site, Br(6) is bonded in an L-shaped geometry to one Ca(1) and one P(2) atom. In the fifth Br site, Br(7) is bonded in a distorted L-shaped geometry to one Ca(1) and one P(2) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(10) is bonded in a single-bond geometry to one Ca(1) atom. In the ninth Br site, Br(12) is bonded in a water-like geometry to one Ca(1) and one P(1) atom.
CaP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one CaP3(OBr3)3 cluster. In the CaP3(OBr3)3 cluster, Ca(1) is bonded in a 5-coordinate geometry to one O(2), one Br(10), one Br(12), one Br(6), and one Br(7) atom. The Ca(1)-O(2) bond length is 2.25 Å. The Ca(1)-Br(10) bond length is 2.74 Å. The Ca(1)-Br(12) bond length is 2.76 Å. The Ca(1)-Br(6) bond length is 3.18 Å. The Ca(1)-Br(7) bond length is 3.22 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one Br(12), and one Br(5) atom. The P(1)-O(3) bond length is 1.49 Å. The P(1)-Br(12) bond length is 2.70 Å. The P(1)-Br(5) bond length is 2.37 Å. In the second P site, P(2) is bonded in a distorted tetrahedral geometry to one O(1), one Br(1), one Br(6), and one Br(7) atom. The P(2)-O(1) bond length is 1.48 Å. The P(2)-Br(1) bond length is 2.18 Å. The P(2)-Br(6) bond length is 2.27 Å. The P(2)-Br(7) bond length is 2.26 Å. In the third P site, P(3) is bonded in a tetrahedral geometry to one O(2), one Br(4), one Br(8), and one Br(9) atom. The P(3)-O(2) bond length is 1.49 Å. The P(3)-Br(4) bond length is 2.18 Å. The P(3)-Br(8) bond length is 2.17 Å. The P(3)-Br(9) bond length is 2.18 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(2) atom. In the second O site, O(2) is bonded in a linear geometry to one Ca(1) and one P(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one P(3) atom. In the third Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth Br site, Br(6) is bonded in an L-shaped geometry to one Ca(1) and one P(2) atom. In the fifth Br site, Br(7) is bonded in a distorted L-shaped geometry to one Ca(1) and one P(2) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(10) is bonded in a single-bond geometry to one Ca(1) atom. In the ninth Br site, Br(12) is bonded in a water-like geometry to one Ca(1) and one P(1) atom.