NaAg3S2 crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing NaS6 octahedra. Ag(1) is bonded in a distorted bent 150 degrees geometry to two equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent Ag(1) atoms.
NaAg3S2 crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing NaS6 octahedra. All Na(1)-S(1) bond lengths are 2.93 Å. Ag(1) is bonded in a distorted bent 150 degrees geometry to two equivalent S(1) atoms. Both Ag(1)-S(1) bond lengths are 2.47 Å. S(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent Ag(1) atoms.