LiWSbO7 crystallizes in the orthorhombic Imma space group. Li(1) is bonded in a distorted linear geometry to two equivalent O(1) and two equivalent O(4) atoms. W(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-41°. Sb(1) is bonded to two equivalent O(4) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-49°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Li(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Sb(1) atoms.
LiWSbO7 crystallizes in the orthorhombic Imma space group. Li(1) is bonded in a distorted linear geometry to two equivalent O(1) and two equivalent O(4) atoms. Both Li(1)-O(1) bond lengths are 1.95 Å. Both Li(1)-O(4) bond lengths are 2.55 Å. W(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-41°. Both W(1)-O(3) bond lengths are 1.95 Å. All W(1)-O(2) bond lengths are 1.94 Å. Sb(1) is bonded to two equivalent O(4) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-49°. Both Sb(1)-O(4) bond lengths are 2.03 Å. All Sb(1)-O(2) bond lengths are 1.99 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Li(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Sb(1) atoms.