ReNS8O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and one ReNS8 cluster. In the ReNS8 cluster, Re(1) is bonded to one S(3), one S(4), one S(6), one S(8), and two equivalent S(5) atoms to form distorted edge-sharing ReS6 octahedra. N(1) is bonded in a single-bond geometry to one S(5) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(7) atom. In the third S site, S(3) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(1) atom. In the fourth S site, S(4) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to two equivalent Re(1) and one N(1) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one Re(1) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(2) and one S(6) atom. In the eighth S site, S(8) is bonded in a bent 120 degrees geometry to one Re(1) and one S(1) atom.
ReNS8O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and one ReNS8 cluster. In the ReNS8 cluster, Re(1) is bonded to one S(3), one S(4), one S(6), one S(8), and two equivalent S(5) atoms to form distorted edge-sharing ReS6 octahedra. The Re(1)-S(3) bond length is 2.27 Å. The Re(1)-S(4) bond length is 2.29 Å. The Re(1)-S(6) bond length is 2.50 Å. The Re(1)-S(8) bond length is 2.59 Å. There is one shorter (2.25 Å) and one longer (2.42 Å) Re(1)-S(5) bond length. N(1) is bonded in a single-bond geometry to one S(5) atom. The N(1)-S(5) bond length is 1.48 Å. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(8) atom. The S(1)-S(3) bond length is 2.06 Å. The S(1)-S(8) bond length is 1.99 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(7) atom. The S(2)-S(4) bond length is 2.06 Å. The S(2)-S(7) bond length is 2.06 Å. In the third S site, S(3) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(1) atom. In the fourth S site, S(4) is bonded in a distorted bent 120 degrees geometry to one Re(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to two equivalent Re(1) and one N(1) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one Re(1) and one S(7) atom. The S(6)-S(7) bond length is 2.03 Å. In the seventh S site, S(7) is bonded in a water-like geometry to one S(2) and one S(6) atom. In the eighth S site, S(8) is bonded in a bent 120 degrees geometry to one Re(1) and one S(1) atom.