CrP4(CO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CrP4(CO)2 clusters. Cr(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent P(1), and two equivalent P(2) atoms. C(1) is bonded in a linear geometry to one Cr(1) and one O(1) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second P site, P(2) is bonded in a single-bond geometry to one Cr(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom.
CrP4(CO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CrP4(CO)2 clusters. Cr(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent P(1), and two equivalent P(2) atoms. Both Cr(1)-C(1) bond lengths are 1.95 Å. Both Cr(1)-P(1) bond lengths are 2.21 Å. Both Cr(1)-P(2) bond lengths are 2.24 Å. C(1) is bonded in a linear geometry to one Cr(1) and one O(1) atom. The C(1)-O(1) bond length is 1.16 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second P site, P(2) is bonded in a single-bond geometry to one Cr(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom.