Nd6Pt13In22 crystallizes in the monoclinic C2/m space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 15-coordinate geometry to two equivalent Pt(2), two equivalent Pt(3), two equivalent Pt(6), one In(1), one In(11), one In(7), two equivalent In(2), two equivalent In(3), and two equivalent In(9) atoms. In the second Nd site, Nd(2) is bonded in a 1-coordinate geometry to one Pt(2), two equivalent Pt(4), two equivalent Pt(5), two equivalent In(3), and three equivalent In(10) atoms. In the third Nd site, Nd(3) is bonded in a 14-coordinate geometry to two equivalent Pt(1), two equivalent Pt(7), one In(2), one In(4), one In(8), two equivalent In(5), two equivalent In(7), and three equivalent In(6) atoms. There are seven inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 9-coordinate geometry to two equivalent Nd(3), one In(11), one In(5), one In(7), two equivalent In(4), and two equivalent In(8) atoms. In the second Pt site, Pt(2) is bonded in a 9-coordinate geometry to one Nd(2), two equivalent Nd(1), one Pt(6), one In(2), two equivalent In(1), and two equivalent In(3) atoms. In the third Pt site, Pt(3) is bonded in a 10-coordinate geometry to two equivalent Nd(1), one In(2), one In(9), two equivalent In(11), two equivalent In(7), and two equivalent In(8) atoms. In the fourth Pt site, Pt(4) is bonded in a 9-coordinate geometry to two equivalent Nd(2), one In(10), one In(11), one In(3), two equivalent In(4), and two equivalent In(9) atoms. In the fifth Pt site, Pt(5) is bonded in a 9-coordinate geometry to two equivalent Nd(2), one In(1), one In(4), two equivalent In(5), and three equivalent In(10) atoms. In the sixth Pt site, Pt(6) is bonded to four equivalent Nd(1), two equivalent Pt(2), two equivalent In(9), and four equivalent In(3) atoms to form distorted face-sharing PtNd4In6Pt2 cuboctahedra. In the seventh Pt site, Pt(7) is bonded in a 9-coordinate geometry to two equivalent Nd(3), one In(1), one In(7), two equivalent In(2), and three equivalent In(6) atoms. There are eleven inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to one Nd(1), one Pt(5), one Pt(7), and two equivalent Pt(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Nd(3), two equivalent Nd(1), one Pt(2), one Pt(3), and two equivalent Pt(7) atoms. In the third In site, In(3) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), one Pt(4), two equivalent Pt(2), two equivalent Pt(6), and two equivalent In(9) atoms. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to one Nd(3), one Pt(5), two equivalent Pt(1), two equivalent Pt(4), one In(8), and two equivalent In(10) atoms. In the fifth In site, In(5) is bonded in a 3-coordinate geometry to two equivalent Nd(3), one Pt(1), two equivalent Pt(5), and one In(10) atom. In the sixth In site, In(6) is bonded in a 3-coordinate geometry to three equivalent Nd(3) and three equivalent Pt(7) atoms. In the seventh In site, In(7) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent Nd(3), one Pt(1), one Pt(7), two equivalent Pt(3), and two equivalent In(8) atoms. In the eighth In site, In(8) is bonded in a 11-coordinate geometry to one Nd(3), two equivalent Pt(1), two equivalent Pt(3), one In(4), one In(8), two equivalent In(11), and two equivalent In(7) atoms. In the ninth In site, In(9) is bonded in a 6-coordinate geometry to two equivalent Nd(1), one Pt(3), one Pt(6), two equivalent Pt(4), and two equivalent In(3) atoms. In the tenth In site, In(10) is bonded in a 12-coordinate geometry to three equivalent Nd(2), one Pt(4), three equivalent Pt(5), one In(5), two equivalent In(10), and two equivalent In(4) atoms. In the eleventh In site, In(11) is bonded in a 4-coordinate geometry to one Nd(1), one Pt(1), one Pt(4), two equivalent Pt(3), and two equivalent In(8) atoms.
Nd6Pt13In22 crystallizes in the monoclinic C2/m space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 15-coordinate geometry to two equivalent Pt(2), two equivalent Pt(3), two equivalent Pt(6), one In(1), one In(11), one In(7), two equivalent In(2), two equivalent In(3), and two equivalent In(9) atoms. Both Nd(1)-Pt(2) bond lengths are 3.06 Å. Both Nd(1)-Pt(3) bond lengths are 3.46 Å. Both Nd(1)-Pt(6) bond lengths are 3.58 Å. The Nd(1)-In(1) bond length is 3.55 Å. The Nd(1)-In(11) bond length is 3.35 Å. The Nd(1)-In(7) bond length is 3.56 Å. Both Nd(1)-In(2) bond lengths are 3.26 Å. There is one shorter (3.21 Å) and one longer (3.47 Å) Nd(1)-In(3) bond length. Both Nd(1)-In(9) bond lengths are 3.29 Å. In the second Nd site, Nd(2) is bonded in a 1-coordinate geometry to one Pt(2), two equivalent Pt(4), two equivalent Pt(5), two equivalent In(3), and three equivalent In(10) atoms. The Nd(2)-Pt(2) bond length is 2.86 Å. Both Nd(2)-Pt(4) bond lengths are 3.31 Å. Both Nd(2)-Pt(5) bond lengths are 3.27 Å. Both Nd(2)-In(3) bond lengths are 3.50 Å. There are two shorter (3.28 Å) and one longer (3.40 Å) Nd(2)-In(10) bond length. In the third Nd site, Nd(3) is bonded in a 14-coordinate geometry to two equivalent Pt(1), two equivalent Pt(7), one In(2), one In(4), one In(8), two equivalent In(5), two equivalent In(7), and three equivalent In(6) atoms. Both Nd(3)-Pt(1) bond lengths are 3.24 Å. Both Nd(3)-Pt(7) bond lengths are 3.41 Å. The Nd(3)-In(2) bond length is 3.49 Å. The Nd(3)-In(4) bond length is 3.57 Å. The Nd(3)-In(8) bond length is 3.43 Å. Both Nd(3)-In(5) bond lengths are 3.29 Å. Both Nd(3)-In(7) bond lengths are 3.36 Å. There are two shorter (3.29 Å) and one longer (3.50 Å) Nd(3)-In(6) bond length. There are seven inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 9-coordinate geometry to two equivalent Nd(3), one In(11), one In(5), one In(7), two equivalent In(4), and two equivalent In(8) atoms. The Pt(1)-In(11) bond length is 2.76 Å. The Pt(1)-In(5) bond length is 2.90 Å. The Pt(1)-In(7) bond length is 2.81 Å. Both Pt(1)-In(4) bond lengths are 2.90 Å. Both Pt(1)-In(8) bond lengths are 2.89 Å. In the second Pt site, Pt(2) is bonded in a 9-coordinate geometry to one Nd(2), two equivalent Nd(1), one Pt(6), one In(2), two equivalent In(1), and two equivalent In(3) atoms. The Pt(2)-Pt(6) bond length is 2.80 Å. The Pt(2)-In(2) bond length is 2.76 Å. Both Pt(2)-In(1) bond lengths are 3.04 Å. Both Pt(2)-In(3) bond lengths are 2.93 Å. In the third Pt site, Pt(3) is bonded in a 10-coordinate geometry to two equivalent Nd(1), one In(2), one In(9), two equivalent In(11), two equivalent In(7), and two equivalent In(8) atoms. The Pt(3)-In(2) bond length is 2.82 Å. The Pt(3)-In(9) bond length is 2.99 Å. Both Pt(3)-In(11) bond lengths are 2.79 Å. Both Pt(3)-In(7) bond lengths are 2.84 Å. There is one shorter (2.89 Å) and one longer (3.15 Å) Pt(3)-In(8) bond length. In the fourth Pt site, Pt(4) is bonded in a 9-coordinate geometry to two equivalent Nd(2), one In(10), one In(11), one In(3), two equivalent In(4), and two equivalent In(9) atoms. The Pt(4)-In(10) bond length is 2.80 Å. The Pt(4)-In(11) bond length is 2.83 Å. The Pt(4)-In(3) bond length is 2.81 Å. Both Pt(4)-In(4) bond lengths are 2.92 Å. Both Pt(4)-In(9) bond lengths are 2.84 Å. In the fifth Pt site, Pt(5) is bonded in a 9-coordinate geometry to two equivalent Nd(2), one In(1), one In(4), two equivalent In(5), and three equivalent In(10) atoms. The Pt(5)-In(1) bond length is 2.87 Å. The Pt(5)-In(4) bond length is 2.89 Å. Both Pt(5)-In(5) bond lengths are 2.77 Å. There is one shorter (2.82 Å) and two longer (2.89 Å) Pt(5)-In(10) bond lengths. In the sixth Pt site, Pt(6) is bonded to four equivalent Nd(1), two equivalent Pt(2), two equivalent In(9), and four equivalent In(3) atoms to form distorted face-sharing PtNd4In6Pt2 cuboctahedra. Both Pt(6)-In(9) bond lengths are 3.11 Å. All Pt(6)-In(3) bond lengths are 2.91 Å. In the seventh Pt site, Pt(7) is bonded in a 9-coordinate geometry to two equivalent Nd(3), one In(1), one In(7), two equivalent In(2), and three equivalent In(6) atoms. The Pt(7)-In(1) bond length is 2.86 Å. The Pt(7)-In(7) bond length is 2.81 Å. Both Pt(7)-In(2) bond lengths are 2.76 Å. There is one shorter (2.78 Å) and two longer (2.79 Å) Pt(7)-In(6) bond lengths. There are eleven inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to one Nd(1), one Pt(5), one Pt(7), and two equivalent Pt(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Nd(3), two equivalent Nd(1), one Pt(2), one Pt(3), and two equivalent Pt(7) atoms. In the third In site, In(3) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), one Pt(4), two equivalent Pt(2), two equivalent Pt(6), and two equivalent In(9) atoms. Both In(3)-In(9) bond lengths are 3.22 Å. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to one Nd(3), one Pt(5), two equivalent Pt(1), two equivalent Pt(4), one In(8), and two equivalent In(10) atoms. The In(4)-In(8) bond length is 3.30 Å. Both In(4)-In(10) bond lengths are 3.31 Å. In the fifth In site, In(5) is bonded in a 3-coordinate geometry to two equivalent Nd(3), one Pt(1), two equivalent Pt(5), and one In(10) atom. The In(5)-In(10) bond length is 3.02 Å. In the sixth In site, In(6) is bonded in a 3-coordinate geometry to three equivalent Nd(3) and three equivalent Pt(7) atoms. In the seventh In site, In(7) is bonded in a 4-coordinate geometry to one Nd(1), two equivalent Nd(3), one Pt(1), one Pt(7), two equivalent Pt(3), and two equivalent In(8) atoms. Both In(7)-In(8) bond lengths are 3.21 Å. In the eighth In site, In(8) is bonded in a 11-coordinate geometry to one Nd(3), two equivalent Pt(1), two equivalent Pt(3), one In(4), one In(8), two equivalent In(11), and two equivalent In(7) atoms. The In(8)-In(8) bond length is 3.03 Å. Both In(8)-In(11) bond lengths are 3.11 Å. In the ninth In site, In(9) is bonded in a 6-coordinate geometry to two equivalent Nd(1), one Pt(3), one Pt(6), two equivalent Pt(4), and two equivalent In(3) atoms. In the tenth In site, In(10) is bonded in a 12-coordinate geometry to three equivalent Nd(2), one Pt(4), three equivalent Pt(5), one In(5), two equivalent In(10), and two equivalent In(4) atoms. Both In(10)-In(10) bond lengths are 3.21 Å. In the eleventh In site, In(11) is bonded in a 4-coordinate geometry to one Nd(1), one Pt(1), one Pt(4), two equivalent Pt(3), and two equivalent In(8) atoms.