Li4TiCo3O8 is alpha Po-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra, corners with three equivalent Ti(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(3)O6 octahedra, corners with three equivalent Co(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Co(5)O6 octahedra, corners with three equivalent Co(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms to form TiO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Ti site, Ti(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form TiO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles are 6°. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. In the fourth Co site, Co(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fifth Co site, Co(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. In the sixth Co site, Co(6) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 6°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Li(4), one Co(2), one Co(3), and one Co(6) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li3TiCo2 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra,  an edgeedge with one O(7)Li3TiCo2 octahedra, edges with three equivalent O(3)Li3TiCo2 octahedra, edges with three equivalent O(6)Li3TiCo2 octahedra, and edges with three equivalent O(8)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one Li(4), one Co(1), one Co(4), and one Co(5) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li3TiCo2 octahedra,  an edgeedge with one O(6)Li3TiCo2 octahedra,  an edgeedge with one O(8)Li3TiCo2 octahedra, edges with three equivalent O(4)Li3TiCo2 octahedra, edges with three equivalent O(5)Li3TiCo2 octahedra, and edges with three equivalent O(7)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(4), one Ti(2), one Co(3), and one Co(6) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(3)Li3TiCo2 octahedra, corners with three equivalent O(4)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra,  an edgeedge with one O(7)Li3TiCo2 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with three equivalent O(6)Li3TiCo2 octahedra, and edges with three equivalent O(8)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Li(4), one Ti(1), one Co(4), and one Co(5) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(3)Li3TiCo2 octahedra, corners with three equivalent O(4)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(6)Li3TiCo2 octahedra,  an edgeedge with one O(8)Li3TiCo2 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(5)Li3TiCo2 octahedra, and edges with three equivalent O(7)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(4), one Ti(1), one Co(1), and one Co(5) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(5)Li3TiCo2 octahedra, corners with three equivalent O(6)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(3)Li3TiCo2 octahedra,  an edgeedge with one O(8)Li3TiCo2 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3TiCo2 octahedra, and edges with three equivalent O(7)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(4), one Ti(2), one Co(2), and one Co(6) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(5)Li3TiCo2 octahedra, corners with three equivalent O(6)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li3TiCo2 octahedra,  an edgeedge with one O(7)Li3TiCo2 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with three equivalent O(3)Li3TiCo2 octahedra, and edges with three equivalent O(8)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Co(1), and one Co(4) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(7)Li3TiCo2 octahedra, corners with three equivalent O(8)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(3)Li3TiCo2 octahedra,  an edgeedge with one O(6)Li3TiCo2 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3TiCo2 octahedra, and edges with three equivalent O(5)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Li(3), one Ti(2), one Co(2), and one Co(3) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(7)Li3TiCo2 octahedra, corners with three equivalent O(8)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li3TiCo2 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with three equivalent O(3)Li3TiCo2 octahedra, and edges with three equivalent O(6)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°.
Li4TiCo3O8 is alpha Po-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra, corners with three equivalent Ti(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. The Li(1)-O(3) bond length is 2.20 Å. The Li(1)-O(4) bond length is 2.19 Å. The Li(1)-O(5) bond length is 2.20 Å. The Li(1)-O(6) bond length is 2.21 Å. The Li(1)-O(7) bond length is 2.21 Å. The Li(1)-O(8) bond length is 2.21 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. The Li(2)-O(1) bond length is 2.09 Å. The Li(2)-O(2) bond length is 2.28 Å. The Li(2)-O(5) bond length is 2.13 Å. The Li(2)-O(6) bond length is 2.11 Å. The Li(2)-O(7) bond length is 2.12 Å. The Li(2)-O(8) bond length is 2.10 Å. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(3)O6 octahedra, corners with three equivalent Co(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. The Li(3)-O(1) bond length is 2.21 Å. The Li(3)-O(2) bond length is 2.21 Å. The Li(3)-O(3) bond length is 2.13 Å. The Li(3)-O(4) bond length is 2.16 Å. The Li(3)-O(7) bond length is 2.12 Å. The Li(3)-O(8) bond length is 2.13 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Co(5)O6 octahedra, corners with three equivalent Co(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. The Li(4)-O(1) bond length is 2.22 Å. The Li(4)-O(2) bond length is 2.12 Å. The Li(4)-O(3) bond length is 2.13 Å. The Li(4)-O(4) bond length is 2.09 Å. The Li(4)-O(5) bond length is 2.10 Å. The Li(4)-O(6) bond length is 2.16 Å. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms to form TiO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. Both Ti(1)-O(4) bond lengths are 2.00 Å. Both Ti(1)-O(5) bond lengths are 1.98 Å. Both Ti(1)-O(7) bond lengths are 1.99 Å. In the second Ti site, Ti(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form TiO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles are 2°. Both Ti(2)-O(3) bond lengths are 2.00 Å. Both Ti(2)-O(6) bond lengths are 1.99 Å. Both Ti(2)-O(8) bond lengths are 1.99 Å. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles are 6°. Both Co(1)-O(2) bond lengths are 1.93 Å. Both Co(1)-O(5) bond lengths are 2.08 Å. Both Co(1)-O(7) bond lengths are 2.08 Å. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. Both Co(2)-O(1) bond lengths are 2.10 Å. Both Co(2)-O(6) bond lengths are 2.10 Å. Both Co(2)-O(8) bond lengths are 2.10 Å. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. Both Co(3)-O(1) bond lengths are 1.98 Å. Both Co(3)-O(3) bond lengths are 2.08 Å. Both Co(3)-O(8) bond lengths are 2.07 Å. In the fourth Co site, Co(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. Both Co(4)-O(2) bond lengths are 2.00 Å. Both Co(4)-O(4) bond lengths are 2.04 Å. Both Co(4)-O(7) bond lengths are 2.07 Å. In the fifth Co site, Co(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. Both Co(5)-O(2) bond lengths are 2.09 Å. Both Co(5)-O(4) bond lengths are 2.10 Å. Both Co(5)-O(5) bond lengths are 2.08 Å. In the sixth Co site, Co(6) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 6°. Both Co(6)-O(1) bond lengths are 1.99 Å. Both Co(6)-O(3) bond lengths are 2.07 Å. Both Co(6)-O(6) bond lengths are 2.06 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Li(4), one Co(2), one Co(3), and one Co(6) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li3TiCo2 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra,  an edgeedge with one O(7)Li3TiCo2 octahedra, edges with three equivalent O(3)Li3TiCo2 octahedra, edges with three equivalent O(6)Li3TiCo2 octahedra, and edges with three equivalent O(8)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one Li(4), one Co(1), one Co(4), and one Co(5) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li3TiCo2 octahedra,  an edgeedge with one O(6)Li3TiCo2 octahedra,  an edgeedge with one O(8)Li3TiCo2 octahedra, edges with three equivalent O(4)Li3TiCo2 octahedra, edges with three equivalent O(5)Li3TiCo2 octahedra, and edges with three equivalent O(7)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(4), one Ti(2), one Co(3), and one Co(6) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(3)Li3TiCo2 octahedra, corners with three equivalent O(4)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra,  an edgeedge with one O(7)Li3TiCo2 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with three equivalent O(6)Li3TiCo2 octahedra, and edges with three equivalent O(8)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Li(4), one Ti(1), one Co(4), and one Co(5) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(3)Li3TiCo2 octahedra, corners with three equivalent O(4)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(6)Li3TiCo2 octahedra,  an edgeedge with one O(8)Li3TiCo2 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(5)Li3TiCo2 octahedra, and edges with three equivalent O(7)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(4), one Ti(1), one Co(1), and one Co(5) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(5)Li3TiCo2 octahedra, corners with three equivalent O(6)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(3)Li3TiCo2 octahedra,  an edgeedge with one O(8)Li3TiCo2 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3TiCo2 octahedra, and edges with three equivalent O(7)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(4), one Ti(2), one Co(2), and one Co(6) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(5)Li3TiCo2 octahedra, corners with three equivalent O(6)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li3TiCo2 octahedra,  an edgeedge with one O(7)Li3TiCo2 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with three equivalent O(3)Li3TiCo2 octahedra, and edges with three equivalent O(8)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Co(1), and one Co(4) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(7)Li3TiCo2 octahedra, corners with three equivalent O(8)Li3TiCo2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(3)Li3TiCo2 octahedra,  an edgeedge with one O(6)Li3TiCo2 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3TiCo2 octahedra, and edges with three equivalent O(5)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Li(3), one Ti(2), one Co(2), and one Co(3) atom to form OLi3TiCo2 octahedra that share corners with three equivalent O(7)Li3TiCo2 octahedra, corners with three equivalent O(8)Li3TiCo2 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li3TiCo2 octahedra,  an edgeedge with one O(5)Li3TiCo2 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with three equivalent O(3)Li3TiCo2 octahedra, and edges with three equivalent O(6)Li3TiCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°.