SbCl6H5O2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two molecular hydrogen;dihydrate molecules and two SbCl6 clusters. In each SbCl6 cluster, Sb(1,2) is bonded in an octahedral geometry to one Cl(1,6); one Cl(2,5); one Cl(3,4); one Cl(7,12); one Cl(8,11); and one Cl(9,10) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1,6) is bonded in a single-bond geometry to one Sb(1,2) atom. In the second Cl site, Cl(2,5) is bonded in a single-bond geometry to one Sb(1,2) atom. In the third Cl site, Cl(3,4) is bonded in a single-bond geometry to one Sb(1,2) atom. In the fourth Cl site, Cl(7,12) is bonded in a single-bond geometry to one Sb(1,2) atom. In the fifth Cl site, Cl(8,11) is bonded in a single-bond geometry to one Sb(1,2) atom. In the sixth Cl site, Cl(9,10) is bonded in a single-bond geometry to one Sb(1,2) atom.
SbCl6H5O2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two molecular hydrogen;dihydrate molecules and two SbCl6 clusters. In each SbCl6 cluster, Sb(1,2) is bonded in an octahedral geometry to one Cl(1,6); one Cl(2,5); one Cl(3,4); one Cl(7,12); one Cl(8,11); and one Cl(9,10) atom. The Sb(1,2)-Cl(1,6) bond length is 2.47 Å. The Sb(1,2)-Cl(2,5) bond length is 2.46 Å. The Sb(1,2)-Cl(3,4) bond length is 2.38 Å. The Sb(1,2)-Cl(7,12) bond length is 2.42 Å. The Sb(1,2)-Cl(8,11) bond length is 2.43 Å. The Sb(1,2)-Cl(9,10) bond length is 2.42 Å. There are six inequivalent Cl sites. In the first Cl site, Cl(1,6) is bonded in a single-bond geometry to one Sb(1,2) atom. In the second Cl site, Cl(2,5) is bonded in a single-bond geometry to one Sb(1,2) atom. In the third Cl site, Cl(3,4) is bonded in a single-bond geometry to one Sb(1,2) atom. In the fourth Cl site, Cl(7,12) is bonded in a single-bond geometry to one Sb(1,2) atom. In the fifth Cl site, Cl(8,11) is bonded in a single-bond geometry to one Sb(1,2) atom. In the sixth Cl site, Cl(9,10) is bonded in a single-bond geometry to one Sb(1,2) atom.