Li2CoAlO4 is beta Polonium-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(13), two equivalent O(5), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Al(4)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Al(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the second Li site, Li(2) is bonded to one O(14), one O(2), two equivalent O(10), and two equivalent O(6) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Al(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Al(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the third Li site, Li(3) is bonded to one O(15), one O(3), two equivalent O(11), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Al(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Al(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Al(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the fourth Li site, Li(4) is bonded to one O(16), one O(4), two equivalent O(12), and two equivalent O(8) atoms to form LiO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Al(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Al(4)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Al(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the fifth Li site, Li(5) is bonded to one O(12), one O(5), two equivalent O(1), and two equivalent O(16) atoms to form LiO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Al(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Al(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Al(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the sixth Li site, Li(6) is bonded to one O(6), one O(9), two equivalent O(13), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Al(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Al(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. In the seventh Li site, Li(7) is bonded to one O(10), one O(7), two equivalent O(14), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Al(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Al(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the eighth Li site, Li(8) is bonded to one O(11), one O(8), two equivalent O(15), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Al(4)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Al(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Al(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(13), two equivalent O(2), and two equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Al(1)O6 octahedra, edges with two equivalent Al(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the second Co site, Co(2) is bonded to one O(11), one O(14), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(7)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Al(2)O6 octahedra, edges with two equivalent Al(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the third Co site, Co(3) is bonded to one O(16), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form CoO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Al(1)O6 octahedra, edges with two equivalent Al(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. In the fourth Co site, Co(4) is bonded to one O(12), one O(15), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(8)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Al(3)O6 octahedra, edges with two equivalent Al(4)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. There are four inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(2), one O(5), two equivalent O(13), and two equivalent O(9) atoms to form AlO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Al(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second Al site, Al(2) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(14) atoms to form AlO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(7)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Al(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the third Al site, Al(3) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(15) atoms to form AlO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(8)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Al(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fourth Al site, Al(4) is bonded to one O(1), one O(8), two equivalent O(12), and two equivalent O(16) atoms to form AlO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Al(4)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(5), two equivalent Co(3), and one Al(4) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(13)Li3Al2Co octahedra,  a cornercorner with one O(8)Li3AlCo2 octahedra, corners with two equivalent O(16)Li3Al2Co octahedra, corners with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(12)Li3Al2Co octahedra, edges with two equivalent O(9)Li3Al2Co octahedra, edges with two equivalent O(1)Li3AlCo2 octahedra, edges with three equivalent O(16)Li3Al2Co octahedra, and edges with three equivalent O(5)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(2), two equivalent Li(6), two equivalent Co(1), and one Al(1) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(14)Li3Al2Co octahedra,  a cornercorner with one O(5)Li3AlCo2 octahedra, corners with two equivalent O(13)Li3Al2Co octahedra, corners with two equivalent O(6)Li3AlCo2 octahedra, edges with two equivalent O(10)Li3Al2Co octahedra, edges with two equivalent O(9)Li3Al2Co octahedra, edges with two equivalent O(2)Li3AlCo2 octahedra, edges with three equivalent O(13)Li3Al2Co octahedra, and edges with three equivalent O(6)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the third O site, O(3) is bonded to one Li(3), two equivalent Li(7), two equivalent Co(2), and one Al(2) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(15)Li3Al2Co octahedra,  a cornercorner with one O(6)Li3AlCo2 octahedra, corners with two equivalent O(14)Li3Al2Co octahedra, corners with two equivalent O(7)Li3AlCo2 octahedra, edges with two equivalent O(10)Li3Al2Co octahedra, edges with two equivalent O(11)Li3Al2Co octahedra, edges with two equivalent O(3)Li3AlCo2 octahedra, edges with three equivalent O(14)Li3Al2Co octahedra, and edges with three equivalent O(7)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fourth O site, O(4) is bonded to one Li(4), two equivalent Li(8), two equivalent Co(4), and one Al(3) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(16)Li3Al2Co octahedra,  a cornercorner with one O(7)Li3AlCo2 octahedra, corners with two equivalent O(15)Li3Al2Co octahedra, corners with two equivalent O(8)Li3AlCo2 octahedra, edges with two equivalent O(11)Li3Al2Co octahedra, edges with two equivalent O(12)Li3Al2Co octahedra, edges with two equivalent O(4)Li3AlCo2 octahedra, edges with three equivalent O(15)Li3Al2Co octahedra, and edges with three equivalent O(8)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the fifth O site, O(5) is bonded to one Li(5), two equivalent Li(1), two equivalent Co(3), and one Al(1) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(12)Li3Al2Co octahedra,  a cornercorner with one O(2)Li3AlCo2 octahedra, corners with two equivalent O(9)Li3Al2Co octahedra, corners with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(13)Li3Al2Co octahedra, edges with two equivalent O(16)Li3Al2Co octahedra, edges with two equivalent O(5)Li3AlCo2 octahedra, edges with three equivalent O(9)Li3Al2Co octahedra, and edges with three equivalent O(1)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the sixth O site, O(6) is bonded to one Li(6), two equivalent Li(2), two equivalent Co(1), and one Al(2) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(9)Li3Al2Co octahedra,  a cornercorner with one O(3)Li3AlCo2 octahedra, corners with two equivalent O(10)Li3Al2Co octahedra, corners with two equivalent O(2)Li3AlCo2 octahedra, edges with two equivalent O(13)Li3Al2Co octahedra, edges with two equivalent O(14)Li3Al2Co octahedra, edges with two equivalent O(6)Li3AlCo2 octahedra, edges with three equivalent O(10)Li3Al2Co octahedra, and edges with three equivalent O(2)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the seventh O site, O(7) is bonded to one Li(7), two equivalent Li(3), two equivalent Co(2), and one Al(3) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(10)Li3Al2Co octahedra,  a cornercorner with one O(4)Li3AlCo2 octahedra, corners with two equivalent O(11)Li3Al2Co octahedra, corners with two equivalent O(3)Li3AlCo2 octahedra, edges with two equivalent O(14)Li3Al2Co octahedra, edges with two equivalent O(15)Li3Al2Co octahedra, edges with two equivalent O(7)Li3AlCo2 octahedra, edges with three equivalent O(11)Li3Al2Co octahedra, and edges with three equivalent O(3)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighth O site, O(8) is bonded to one Li(8), two equivalent Li(4), two equivalent Co(4), and one Al(4) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(11)Li3Al2Co octahedra,  a cornercorner with one O(1)Li3AlCo2 octahedra, corners with two equivalent O(12)Li3Al2Co octahedra, corners with two equivalent O(4)Li3AlCo2 octahedra, edges with two equivalent O(15)Li3Al2Co octahedra, edges with two equivalent O(16)Li3Al2Co octahedra, edges with two equivalent O(8)Li3AlCo2 octahedra, edges with three equivalent O(12)Li3Al2Co octahedra, and edges with three equivalent O(4)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the ninth O site, O(9) is bonded to one Li(6), two equivalent Li(1), one Co(3), and two equivalent Al(1) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(16)Li3Al2Co octahedra,  a cornercorner with one O(6)Li3AlCo2 octahedra, corners with two equivalent O(13)Li3Al2Co octahedra, corners with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(9)Li3Al2Co octahedra, edges with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(2)Li3AlCo2 octahedra, edges with three equivalent O(13)Li3Al2Co octahedra, and edges with three equivalent O(5)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the tenth O site, O(10) is bonded to one Li(7), two equivalent Li(2), one Co(1), and two equivalent Al(2) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(13)Li3Al2Co octahedra,  a cornercorner with one O(7)Li3AlCo2 octahedra, corners with two equivalent O(14)Li3Al2Co octahedra, corners with two equivalent O(6)Li3AlCo2 octahedra, edges with two equivalent O(10)Li3Al2Co octahedra, edges with two equivalent O(2)Li3AlCo2 octahedra, edges with two equivalent O(3)Li3AlCo2 octahedra, edges with three equivalent O(14)Li3Al2Co octahedra, and edges with three equivalent O(6)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the eleventh O site, O(11) is bonded to one Li(8), two equivalent Li(3), one Co(2), and two equivalent Al(3) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(14)Li3Al2Co octahedra,  a cornercorner with one O(8)Li3AlCo2 octahedra, corners with two equivalent O(15)Li3Al2Co octahedra, corners with two equivalent O(7)Li3AlCo2 octahedra, edges with two equivalent O(11)Li3Al2Co octahedra, edges with two equivalent O(3)Li3AlCo2 octahedra, edges with two equivalent O(4)Li3AlCo2 octahedra, edges with three equivalent O(15)Li3Al2Co octahedra, and edges with three equivalent O(7)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the twelfth O site, O(12) is bonded to one Li(5), two equivalent Li(4), one Co(4), and two equivalent Al(4) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(15)Li3Al2Co octahedra,  a cornercorner with one O(5)Li3AlCo2 octahedra, corners with two equivalent O(16)Li3Al2Co octahedra, corners with two equivalent O(8)Li3AlCo2 octahedra, edges with two equivalent O(12)Li3Al2Co octahedra, edges with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(4)Li3AlCo2 octahedra, edges with three equivalent O(16)Li3Al2Co octahedra, and edges with three equivalent O(8)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the thirteenth O site, O(13) is bonded to one Li(1), two equivalent Li(6), one Co(1), and two equivalent Al(1) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(10)Li3Al2Co octahedra,  a cornercorner with one O(1)Li3AlCo2 octahedra, corners with two equivalent O(9)Li3Al2Co octahedra, corners with two equivalent O(2)Li3AlCo2 octahedra, edges with two equivalent O(13)Li3Al2Co octahedra, edges with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(6)Li3AlCo2 octahedra, edges with three equivalent O(9)Li3Al2Co octahedra, and edges with three equivalent O(2)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fourteenth O site, O(14) is bonded to one Li(2), two equivalent Li(7), one Co(2), and two equivalent Al(2) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(11)Li3Al2Co octahedra,  a cornercorner with one O(2)Li3AlCo2 octahedra, corners with two equivalent O(10)Li3Al2Co octahedra, corners with two equivalent O(3)Li3AlCo2 octahedra, edges with two equivalent O(14)Li3Al2Co octahedra, edges with two equivalent O(6)Li3AlCo2 octahedra, edges with two equivalent O(7)Li3AlCo2 octahedra, edges with three equivalent O(10)Li3Al2Co octahedra, and edges with three equivalent O(3)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fifteenth O site, O(15) is bonded to one Li(3), two equivalent Li(8), one Co(4), and two equivalent Al(3) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(12)Li3Al2Co octahedra,  a cornercorner with one O(3)Li3AlCo2 octahedra, corners with two equivalent O(11)Li3Al2Co octahedra, corners with two equivalent O(4)Li3AlCo2 octahedra, edges with two equivalent O(15)Li3Al2Co octahedra, edges with two equivalent O(7)Li3AlCo2 octahedra, edges with two equivalent O(8)Li3AlCo2 octahedra, edges with three equivalent O(11)Li3Al2Co octahedra, and edges with three equivalent O(4)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the sixteenth O site, O(16) is bonded to one Li(4), two equivalent Li(5), one Co(3), and two equivalent Al(4) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(9)Li3Al2Co octahedra,  a cornercorner with one O(4)Li3AlCo2 octahedra, corners with two equivalent O(12)Li3Al2Co octahedra, corners with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(16)Li3Al2Co octahedra, edges with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(8)Li3AlCo2 octahedra, edges with three equivalent O(12)Li3Al2Co octahedra, and edges with three equivalent O(1)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°.
Li2CoAlO4 is beta Polonium-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(13), two equivalent O(5), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Al(4)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Al(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. The Li(1)-O(1) bond length is 2.08 Å. The Li(1)-O(13) bond length is 2.18 Å. There is one shorter (2.10 Å) and one longer (2.13 Å) Li(1)-O(5) bond length. There is one shorter (2.12 Å) and one longer (2.16 Å) Li(1)-O(9) bond length. In the second Li site, Li(2) is bonded to one O(14), one O(2), two equivalent O(10), and two equivalent O(6) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Al(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Al(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. The Li(2)-O(14) bond length is 2.10 Å. The Li(2)-O(2) bond length is 2.13 Å. There is one shorter (2.10 Å) and one longer (2.11 Å) Li(2)-O(10) bond length. There is one shorter (2.17 Å) and one longer (2.21 Å) Li(2)-O(6) bond length. In the third Li site, Li(3) is bonded to one O(15), one O(3), two equivalent O(11), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Al(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Al(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Al(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. The Li(3)-O(15) bond length is 2.09 Å. The Li(3)-O(3) bond length is 2.23 Å. There is one shorter (2.10 Å) and one longer (2.15 Å) Li(3)-O(11) bond length. There is one shorter (2.11 Å) and one longer (2.15 Å) Li(3)-O(7) bond length. In the fourth Li site, Li(4) is bonded to one O(16), one O(4), two equivalent O(12), and two equivalent O(8) atoms to form LiO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Al(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Al(4)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Al(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The Li(4)-O(16) bond length is 2.26 Å. The Li(4)-O(4) bond length is 2.13 Å. There is one shorter (2.13 Å) and one longer (2.15 Å) Li(4)-O(12) bond length. There is one shorter (2.08 Å) and one longer (2.09 Å) Li(4)-O(8) bond length. In the fifth Li site, Li(5) is bonded to one O(12), one O(5), two equivalent O(1), and two equivalent O(16) atoms to form LiO6 octahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Al(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Al(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Al(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Li(5)-O(12) bond length is 2.09 Å. The Li(5)-O(5) bond length is 2.14 Å. There is one shorter (2.12 Å) and one longer (2.15 Å) Li(5)-O(1) bond length. There is one shorter (2.11 Å) and one longer (2.15 Å) Li(5)-O(16) bond length. In the sixth Li site, Li(6) is bonded to one O(6), one O(9), two equivalent O(13), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Al(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Al(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. The Li(6)-O(6) bond length is 2.06 Å. The Li(6)-O(9) bond length is 2.22 Å. There is one shorter (2.11 Å) and one longer (2.13 Å) Li(6)-O(13) bond length. There is one shorter (2.14 Å) and one longer (2.17 Å) Li(6)-O(2) bond length. In the seventh Li site, Li(7) is bonded to one O(10), one O(7), two equivalent O(14), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Al(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Al(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. The Li(7)-O(10) bond length is 2.18 Å. The Li(7)-O(7) bond length is 2.16 Å. There is one shorter (2.11 Å) and one longer (2.16 Å) Li(7)-O(14) bond length. There is one shorter (2.09 Å) and one longer (2.13 Å) Li(7)-O(3) bond length. In the eighth Li site, Li(8) is bonded to one O(11), one O(8), two equivalent O(15), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Al(4)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Al(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Al(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. The Li(8)-O(11) bond length is 2.12 Å. The Li(8)-O(8) bond length is 2.23 Å. There is one shorter (2.13 Å) and one longer (2.15 Å) Li(8)-O(15) bond length. There is one shorter (2.09 Å) and one longer (2.12 Å) Li(8)-O(4) bond length. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(13), two equivalent O(2), and two equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Al(1)O6 octahedra, edges with two equivalent Al(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. The Co(1)-O(10) bond length is 1.95 Å. The Co(1)-O(13) bond length is 1.95 Å. There is one shorter (1.95 Å) and one longer (1.96 Å) Co(1)-O(2) bond length. Both Co(1)-O(6) bond lengths are 1.94 Å. In the second Co site, Co(2) is bonded to one O(11), one O(14), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(7)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Al(2)O6 octahedra, edges with two equivalent Al(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Co(2)-O(11) bond length is 2.03 Å. The Co(2)-O(14) bond length is 2.05 Å. There is one shorter (1.96 Å) and one longer (2.06 Å) Co(2)-O(3) bond length. There is one shorter (1.96 Å) and one longer (2.05 Å) Co(2)-O(7) bond length. In the third Co site, Co(3) is bonded to one O(16), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form CoO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Al(1)O6 octahedra, edges with two equivalent Al(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. The Co(3)-O(16) bond length is 1.92 Å. The Co(3)-O(9) bond length is 1.93 Å. There is one shorter (1.96 Å) and one longer (2.03 Å) Co(3)-O(1) bond length. There is one shorter (1.96 Å) and one longer (2.04 Å) Co(3)-O(5) bond length. In the fourth Co site, Co(4) is bonded to one O(12), one O(15), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(8)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Al(3)O6 octahedra, edges with two equivalent Al(4)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. The Co(4)-O(12) bond length is 2.05 Å. The Co(4)-O(15) bond length is 2.04 Å. There is one shorter (2.01 Å) and one longer (2.03 Å) Co(4)-O(4) bond length. There is one shorter (2.01 Å) and one longer (2.03 Å) Co(4)-O(8) bond length. There are four inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(2), one O(5), two equivalent O(13), and two equivalent O(9) atoms to form AlO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Al(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. The Al(1)-O(2) bond length is 1.92 Å. The Al(1)-O(5) bond length is 1.91 Å. There is one shorter (1.92 Å) and one longer (1.93 Å) Al(1)-O(13) bond length. There is one shorter (1.94 Å) and one longer (1.95 Å) Al(1)-O(9) bond length. In the second Al site, Al(2) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(14) atoms to form AlO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(7)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Al(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. The Al(2)-O(3) bond length is 1.94 Å. The Al(2)-O(6) bond length is 1.91 Å. There is one shorter (1.93 Å) and one longer (1.94 Å) Al(2)-O(10) bond length. Both Al(2)-O(14) bond lengths are 1.93 Å. In the third Al site, Al(3) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(15) atoms to form AlO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(8)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Al(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. The Al(3)-O(4) bond length is 1.93 Å. The Al(3)-O(7) bond length is 1.96 Å. There is one shorter (1.93 Å) and one longer (1.94 Å) Al(3)-O(11) bond length. Both Al(3)-O(15) bond lengths are 1.93 Å. In the fourth Al site, Al(4) is bonded to one O(1), one O(8), two equivalent O(12), and two equivalent O(16) atoms to form AlO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Al(4)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. The Al(4)-O(1) bond length is 1.92 Å. The Al(4)-O(8) bond length is 1.93 Å. There is one shorter (1.92 Å) and one longer (1.93 Å) Al(4)-O(12) bond length. There is one shorter (1.94 Å) and one longer (1.96 Å) Al(4)-O(16) bond length. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(5), two equivalent Co(3), and one Al(4) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(13)Li3Al2Co octahedra,  a cornercorner with one O(8)Li3AlCo2 octahedra, corners with two equivalent O(16)Li3Al2Co octahedra, corners with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(12)Li3Al2Co octahedra, edges with two equivalent O(9)Li3Al2Co octahedra, edges with two equivalent O(1)Li3AlCo2 octahedra, edges with three equivalent O(16)Li3Al2Co octahedra, and edges with three equivalent O(5)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(2), two equivalent Li(6), two equivalent Co(1), and one Al(1) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(14)Li3Al2Co octahedra,  a cornercorner with one O(5)Li3AlCo2 octahedra, corners with two equivalent O(13)Li3Al2Co octahedra, corners with two equivalent O(6)Li3AlCo2 octahedra, edges with two equivalent O(10)Li3Al2Co octahedra, edges with two equivalent O(9)Li3Al2Co octahedra, edges with two equivalent O(2)Li3AlCo2 octahedra, edges with three equivalent O(13)Li3Al2Co octahedra, and edges with three equivalent O(6)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the third O site, O(3) is bonded to one Li(3), two equivalent Li(7), two equivalent Co(2), and one Al(2) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(15)Li3Al2Co octahedra,  a cornercorner with one O(6)Li3AlCo2 octahedra, corners with two equivalent O(14)Li3Al2Co octahedra, corners with two equivalent O(7)Li3AlCo2 octahedra, edges with two equivalent O(10)Li3Al2Co octahedra, edges with two equivalent O(11)Li3Al2Co octahedra, edges with two equivalent O(3)Li3AlCo2 octahedra, edges with three equivalent O(14)Li3Al2Co octahedra, and edges with three equivalent O(7)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fourth O site, O(4) is bonded to one Li(4), two equivalent Li(8), two equivalent Co(4), and one Al(3) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(16)Li3Al2Co octahedra,  a cornercorner with one O(7)Li3AlCo2 octahedra, corners with two equivalent O(15)Li3Al2Co octahedra, corners with two equivalent O(8)Li3AlCo2 octahedra, edges with two equivalent O(11)Li3Al2Co octahedra, edges with two equivalent O(12)Li3Al2Co octahedra, edges with two equivalent O(4)Li3AlCo2 octahedra, edges with three equivalent O(15)Li3Al2Co octahedra, and edges with three equivalent O(8)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the fifth O site, O(5) is bonded to one Li(5), two equivalent Li(1), two equivalent Co(3), and one Al(1) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(12)Li3Al2Co octahedra,  a cornercorner with one O(2)Li3AlCo2 octahedra, corners with two equivalent O(9)Li3Al2Co octahedra, corners with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(13)Li3Al2Co octahedra, edges with two equivalent O(16)Li3Al2Co octahedra, edges with two equivalent O(5)Li3AlCo2 octahedra, edges with three equivalent O(9)Li3Al2Co octahedra, and edges with three equivalent O(1)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the sixth O site, O(6) is bonded to one Li(6), two equivalent Li(2), two equivalent Co(1), and one Al(2) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(9)Li3Al2Co octahedra,  a cornercorner with one O(3)Li3AlCo2 octahedra, corners with two equivalent O(10)Li3Al2Co octahedra, corners with two equivalent O(2)Li3AlCo2 octahedra, edges with two equivalent O(13)Li3Al2Co octahedra, edges with two equivalent O(14)Li3Al2Co octahedra, edges with two equivalent O(6)Li3AlCo2 octahedra, edges with three equivalent O(10)Li3Al2Co octahedra, and edges with three equivalent O(2)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the seventh O site, O(7) is bonded to one Li(7), two equivalent Li(3), two equivalent Co(2), and one Al(3) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(10)Li3Al2Co octahedra,  a cornercorner with one O(4)Li3AlCo2 octahedra, corners with two equivalent O(11)Li3Al2Co octahedra, corners with two equivalent O(3)Li3AlCo2 octahedra, edges with two equivalent O(14)Li3Al2Co octahedra, edges with two equivalent O(15)Li3Al2Co octahedra, edges with two equivalent O(7)Li3AlCo2 octahedra, edges with three equivalent O(11)Li3Al2Co octahedra, and edges with three equivalent O(3)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighth O site, O(8) is bonded to one Li(8), two equivalent Li(4), two equivalent Co(4), and one Al(4) atom to form OLi3AlCo2 octahedra that share  a cornercorner with one O(11)Li3Al2Co octahedra,  a cornercorner with one O(1)Li3AlCo2 octahedra, corners with two equivalent O(12)Li3Al2Co octahedra, corners with two equivalent O(4)Li3AlCo2 octahedra, edges with two equivalent O(15)Li3Al2Co octahedra, edges with two equivalent O(16)Li3Al2Co octahedra, edges with two equivalent O(8)Li3AlCo2 octahedra, edges with three equivalent O(12)Li3Al2Co octahedra, and edges with three equivalent O(4)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the ninth O site, O(9) is bonded to one Li(6), two equivalent Li(1), one Co(3), and two equivalent Al(1) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(16)Li3Al2Co octahedra,  a cornercorner with one O(6)Li3AlCo2 octahedra, corners with two equivalent O(13)Li3Al2Co octahedra, corners with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(9)Li3Al2Co octahedra, edges with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(2)Li3AlCo2 octahedra, edges with three equivalent O(13)Li3Al2Co octahedra, and edges with three equivalent O(5)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the tenth O site, O(10) is bonded to one Li(7), two equivalent Li(2), one Co(1), and two equivalent Al(2) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(13)Li3Al2Co octahedra,  a cornercorner with one O(7)Li3AlCo2 octahedra, corners with two equivalent O(14)Li3Al2Co octahedra, corners with two equivalent O(6)Li3AlCo2 octahedra, edges with two equivalent O(10)Li3Al2Co octahedra, edges with two equivalent O(2)Li3AlCo2 octahedra, edges with two equivalent O(3)Li3AlCo2 octahedra, edges with three equivalent O(14)Li3Al2Co octahedra, and edges with three equivalent O(6)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the eleventh O site, O(11) is bonded to one Li(8), two equivalent Li(3), one Co(2), and two equivalent Al(3) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(14)Li3Al2Co octahedra,  a cornercorner with one O(8)Li3AlCo2 octahedra, corners with two equivalent O(15)Li3Al2Co octahedra, corners with two equivalent O(7)Li3AlCo2 octahedra, edges with two equivalent O(11)Li3Al2Co octahedra, edges with two equivalent O(3)Li3AlCo2 octahedra, edges with two equivalent O(4)Li3AlCo2 octahedra, edges with three equivalent O(15)Li3Al2Co octahedra, and edges with three equivalent O(7)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the twelfth O site, O(12) is bonded to one Li(5), two equivalent Li(4), one Co(4), and two equivalent Al(4) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(15)Li3Al2Co octahedra,  a cornercorner with one O(5)Li3AlCo2 octahedra, corners with two equivalent O(16)Li3Al2Co octahedra, corners with two equivalent O(8)Li3AlCo2 octahedra, edges with two equivalent O(12)Li3Al2Co octahedra, edges with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(4)Li3AlCo2 octahedra, edges with three equivalent O(16)Li3Al2Co octahedra, and edges with three equivalent O(8)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the thirteenth O site, O(13) is bonded to one Li(1), two equivalent Li(6), one Co(1), and two equivalent Al(1) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(10)Li3Al2Co octahedra,  a cornercorner with one O(1)Li3AlCo2 octahedra, corners with two equivalent O(9)Li3Al2Co octahedra, corners with two equivalent O(2)Li3AlCo2 octahedra, edges with two equivalent O(13)Li3Al2Co octahedra, edges with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(6)Li3AlCo2 octahedra, edges with three equivalent O(9)Li3Al2Co octahedra, and edges with three equivalent O(2)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fourteenth O site, O(14) is bonded to one Li(2), two equivalent Li(7), one Co(2), and two equivalent Al(2) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(11)Li3Al2Co octahedra,  a cornercorner with one O(2)Li3AlCo2 octahedra, corners with two equivalent O(10)Li3Al2Co octahedra, corners with two equivalent O(3)Li3AlCo2 octahedra, edges with two equivalent O(14)Li3Al2Co octahedra, edges with two equivalent O(6)Li3AlCo2 octahedra, edges with two equivalent O(7)Li3AlCo2 octahedra, edges with three equivalent O(10)Li3Al2Co octahedra, and edges with three equivalent O(3)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fifteenth O site, O(15) is bonded to one Li(3), two equivalent Li(8), one Co(4), and two equivalent Al(3) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(12)Li3Al2Co octahedra,  a cornercorner with one O(3)Li3AlCo2 octahedra, corners with two equivalent O(11)Li3Al2Co octahedra, corners with two equivalent O(4)Li3AlCo2 octahedra, edges with two equivalent O(15)Li3Al2Co octahedra, edges with two equivalent O(7)Li3AlCo2 octahedra, edges with two equivalent O(8)Li3AlCo2 octahedra, edges with three equivalent O(11)Li3Al2Co octahedra, and edges with three equivalent O(4)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the sixteenth O site, O(16) is bonded to one Li(4), two equivalent Li(5), one Co(3), and two equivalent Al(4) atoms to form OLi3Al2Co octahedra that share  a cornercorner with one O(9)Li3Al2Co octahedra,  a cornercorner with one O(4)Li3AlCo2 octahedra, corners with two equivalent O(12)Li3Al2Co octahedra, corners with two equivalent O(1)Li3AlCo2 octahedra, edges with two equivalent O(16)Li3Al2Co octahedra, edges with two equivalent O(5)Li3AlCo2 octahedra, edges with two equivalent O(8)Li3AlCo2 octahedra, edges with three equivalent O(12)Li3Al2Co octahedra, and edges with three equivalent O(1)Li3AlCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°.