N(CH3)4I(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four I(OF)2 clusters. In each I(OF)2 cluster, there are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in a see-saw-like geometry to one O(1), one O(2), and two equivalent F(1) atoms. F(1) is bonded in a single-bond geometry to one I(1) atom.
N(CH3)4I(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four tetramethylammonium molecules and four I(OF)2 clusters. In each I(OF)2 cluster, there are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one I(1) atom. The O(2)-I(1) bond length is 1.80 Å. In the second O site, O(1) is bonded in a single-bond geometry to one I(1) atom. The O(1)-I(1) bond length is 1.80 Å. I(1) is bonded in a see-saw-like geometry to one O(1), one O(2), and two equivalent F(1) atoms. Both I(1)-F(1) bond lengths are 2.06 Å. F(1) is bonded in a single-bond geometry to one I(1) atom.