PuPb2 crystallizes in the tetragonal I4_1/amd space group. Pu(1) is bonded in a 10-coordinate geometry to four equivalent Pb(1) and six equivalent Pb(2) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Pu(1) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to six equivalent Pu(1) atoms.
PuPb2 crystallizes in the tetragonal I4_1/amd space group. Pu(1) is bonded in a 10-coordinate geometry to four equivalent Pb(1) and six equivalent Pb(2) atoms. There are two shorter (3.37 Å) and two longer (3.39 Å) Pu(1)-Pb(1) bond lengths. There are four shorter (3.41 Å) and two longer (3.48 Å) Pu(1)-Pb(2) bond lengths. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Pu(1) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to six equivalent Pu(1) atoms.