CdAs2 crystallizes in the tetragonal I4_122 space group. Cd(1) is bonded to four equivalent As(1) atoms to form distorted corner-sharing CdAs4 trigonal pyramids. As(1) is bonded in a 4-coordinate geometry to two equivalent Cd(1) and two equivalent As(1) atoms.
CdAs2 crystallizes in the tetragonal I4_122 space group. Cd(1) is bonded to four equivalent As(1) atoms to form distorted corner-sharing CdAs4 trigonal pyramids. All Cd(1)-As(1) bond lengths are 2.72 Å. As(1) is bonded in a 4-coordinate geometry to two equivalent Cd(1) and two equivalent As(1) atoms. Both As(1)-As(1) bond lengths are 2.44 Å.