NdRh3Si2 crystallizes in the hexagonal P6/mmm space group. Nd(1) is bonded in a 18-coordinate geometry to twelve equivalent Rh(1) and six equivalent Si(1) atoms. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Nd(1) and four equivalent Si(1) atoms. Si(1) is bonded in a 6-coordinate geometry to three equivalent Nd(1) and six equivalent Rh(1) atoms.
NdRh3Si2 crystallizes in the hexagonal P6/mmm space group. Nd(1) is bonded in a 18-coordinate geometry to twelve equivalent Rh(1) and six equivalent Si(1) atoms. All Nd(1)-Rh(1) bond lengths are 3.31 Å. All Nd(1)-Si(1) bond lengths are 3.20 Å. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Nd(1) and four equivalent Si(1) atoms. All Rh(1)-Si(1) bond lengths are 2.41 Å. Si(1) is bonded in a 6-coordinate geometry to three equivalent Nd(1) and six equivalent Rh(1) atoms.