NdPdIn crystallizes in the monoclinic C2 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 10-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent In(2), and four equivalent In(1) atoms. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent In(2), and four equivalent In(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one In(2), and two equivalent In(1) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Nd(1), two equivalent Nd(2), two equivalent In(2), and four equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 11-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Pd(1), and four equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 11-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Pd(1), and four equivalent Pd(2) atoms.
NdPdIn crystallizes in the monoclinic C2 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 10-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent In(2), and four equivalent In(1) atoms. Both Nd(1)-Pd(1) bond lengths are 2.97 Å. Both Nd(1)-Pd(2) bond lengths are 2.94 Å. Both Nd(1)-In(2) bond lengths are 3.33 Å. There are two shorter (3.38 Å) and two longer (3.39 Å) Nd(1)-In(1) bond lengths. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent In(2), and four equivalent In(1) atoms. There is one shorter (2.96 Å) and one longer (3.01 Å) Nd(2)-Pd(1) bond length. There is one shorter (2.94 Å) and one longer (2.95 Å) Nd(2)-Pd(2) bond length. There is one shorter (3.35 Å) and one longer (3.39 Å) Nd(2)-In(2) bond length. There are a spread of Nd(2)-In(1) bond distances ranging from 3.34-3.39 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one In(2), and two equivalent In(1) atoms. The Pd(1)-In(2) bond length is 3.07 Å. Both Pd(1)-In(1) bond lengths are 3.11 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Nd(1), two equivalent Nd(2), two equivalent In(2), and four equivalent In(1) atoms. There is one shorter (3.18 Å) and one longer (3.22 Å) Pd(2)-In(2) bond length. There are a spread of Pd(2)-In(1) bond distances ranging from 3.11-3.26 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 11-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Pd(1), and four equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 11-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Pd(1), and four equivalent Pd(2) atoms.