Pb3N4 is beta Polonium structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Pb3N4 clusters. Pb(1) is bonded in a 2-coordinate geometry to two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a T-shaped geometry to two equivalent Pb(1) and one N(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to three equivalent N(1) atoms.
Pb3N4 is beta Polonium structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three Pb3N4 clusters. Pb(1) is bonded in a 2-coordinate geometry to two equivalent N(1) atoms. Both Pb(1)-N(1) bond lengths are 2.43 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a T-shaped geometry to two equivalent Pb(1) and one N(2) atom. The N(1)-N(2) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to three equivalent N(1) atoms.