CN3(CN3Br)2Bi2Br7 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four bromoguanidine molecules, two diaziridinimine molecules, and two Bi2Br7 clusters. In each Bi2Br7 cluster, Bi(1) is bonded to one Br(1), one Br(2), one Br(3), one Br(5), and one Br(6) atom to form distorted face-sharing BiBr5 square pyramids. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the third Br site, Br(3) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth Br site, Br(6) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms.
CN3(CN3Br)2Bi2Br7 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four bromoguanidine molecules, two diaziridinimine molecules, and two Bi2Br7 clusters. In each Bi2Br7 cluster, Bi(1) is bonded to one Br(1), one Br(2), one Br(3), one Br(5), and one Br(6) atom to form distorted face-sharing BiBr5 square pyramids. The Bi(1)-Br(1) bond length is 3.06 Å. The Bi(1)-Br(2) bond length is 3.07 Å. The Bi(1)-Br(3) bond length is 2.69 Å. The Bi(1)-Br(5) bond length is 2.67 Å. The Bi(1)-Br(6) bond length is 2.86 Å. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the third Br site, Br(3) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth Br site, Br(6) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms.