Li7CoOF7 is Molybdenum Carbide MAX Phase-derived structured and crystallizes in the triclinic P1 space group. There are twenty-eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one F(1), one F(24), one F(25), and one F(3) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(5)F6 octahedra,  a cornercorner with one Li(8)F6 octahedra, corners with two equivalent Co(2)O2F4 octahedra, corners with two equivalent Co(3)O2F4 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra, and edges with two equivalent Co(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one F(1), one F(2), one F(23), and one F(26) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(7)F6 octahedra, corners with two equivalent Co(1)O2F4 octahedra, corners with two equivalent Co(4)O2F4 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra, and edges with two equivalent Co(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third Li site, Li(3) is bonded to one O(3), one O(4), one F(22), one F(27), one F(3), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(7)F6 octahedra, corners with two equivalent Co(1)O2F4 octahedra, corners with two equivalent Co(4)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Co(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fourth Li site, Li(4) is bonded to one O(2), one O(4), one F(2), one F(21), one F(28), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(5)F6 octahedra,  a cornercorner with one Li(8)F6 octahedra, corners with two equivalent Co(2)O2F4 octahedra, corners with two equivalent Co(3)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Co(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fifth Li site, Li(5) is bonded to one F(11), one F(21), one F(25), one F(5), one F(7), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(1)O2F4 octahedra,  a cornercorner with one Li(4)O2F4 octahedra, corners with two equivalent Li(10)F6 octahedra, corners with two equivalent Li(11)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra, and edges with two equivalent Li(9)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the sixth Li site, Li(6) is bonded to one F(10), one F(22), one F(26), one F(5), one F(6), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(2)O2F4 octahedra,  a cornercorner with one Li(3)O2F4 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent Li(9)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra, and edges with two equivalent Li(10)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the seventh Li site, Li(7) is bonded to one F(11), one F(12), one F(23), one F(27), one F(7), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Li(2)O2F4 octahedra,  a cornercorner with one Li(3)O2F4 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent Li(9)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(11)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the eighth Li site, Li(8) is bonded to one F(10), one F(12), one F(24), one F(28), one F(6), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Li(1)O2F4 octahedra,  a cornercorner with one Li(4)O2F4 octahedra, corners with two equivalent Li(10)F6 octahedra, corners with two equivalent Li(11)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the ninth Li site, Li(9) is bonded to one F(11), one F(13), one F(17), one F(5), one F(7), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Co(1)O2F4 octahedra,  a cornercorner with one Co(4)O2F4 octahedra, corners with two equivalent Li(6)F6 octahedra, corners with two equivalent Li(7)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra, and edges with two equivalent Li(5)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the tenth Li site, Li(10) is bonded to one F(10), one F(14), one F(18), one F(5), one F(6), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Co(2)O2F4 octahedra,  a cornercorner with one Co(3)O2F4 octahedra, corners with two equivalent Li(5)F6 octahedra, corners with two equivalent Li(8)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra, and edges with two equivalent Li(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the eleventh Li site, Li(11) is bonded to one F(11), one F(12), one F(15), one F(19), one F(7), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Co(2)O2F4 octahedra,  a cornercorner with one Co(3)O2F4 octahedra, corners with two equivalent Li(5)F6 octahedra, corners with two equivalent Li(8)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(7)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the twelfth Li site, Li(12) is bonded to one F(10), one F(12), one F(16), one F(20), one F(6), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Co(1)O2F4 octahedra,  a cornercorner with one Co(4)O2F4 octahedra, corners with two equivalent Li(6)F6 octahedra, corners with two equivalent Li(7)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(8)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the thirteenth Li site, Li(13) is bonded to one F(13), one F(14), one F(21), one F(22), one F(4), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(17)F6 octahedra,  a cornercorner with one Li(20)F6 octahedra, corners with two equivalent Li(22)OF5 octahedra, corners with two equivalent Li(23)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(24)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the fourteenth Li site, Li(14) is bonded to one F(10), one F(14), one F(16), one F(22), one F(24), and one F(3) atom to form LiF6 octahedra that share  a cornercorner with one Li(18)F6 octahedra,  a cornercorner with one Li(19)F6 octahedra, corners with two equivalent Li(21)OF5 octahedra, corners with two equivalent Li(24)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(23)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the fifteenth Li site, Li(15) is bonded to one F(11), one F(13), one F(15), one F(2), one F(21), and one F(23) atom to form LiF6 octahedra that share  a cornercorner with one Li(18)F6 octahedra,  a cornercorner with one Li(19)F6 octahedra, corners with two equivalent Li(21)OF5 octahedra, corners with two equivalent Li(24)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(22)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the sixteenth Li site, Li(16) is bonded to one F(1), one F(12), one F(15), one F(16), one F(23), and one F(24) atom to form LiF6 octahedra that share  a cornercorner with one Li(17)F6 octahedra,  a cornercorner with one Li(20)F6 octahedra, corners with two equivalent Li(22)OF5 octahedra, corners with two equivalent Li(23)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(21)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the seventeenth Li site, Li(17) is bonded to one F(1), one F(17), one F(18), one F(25), one F(26), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(13)F6 octahedra,  a cornercorner with one Li(16)F6 octahedra, corners with two equivalent Li(26)OF5 octahedra, corners with two equivalent Li(27)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(25)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the eighteenth Li site, Li(18) is bonded to one F(10), one F(18), one F(2), one F(20), one F(26), and one F(28) atom to form LiF6 octahedra that share  a cornercorner with one Li(14)F6 octahedra,  a cornercorner with one Li(15)F6 octahedra, corners with two equivalent Li(25)OF5 octahedra, corners with two equivalent Li(28)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(26)OF5 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the nineteenth Li site, Li(19) is bonded to one F(11), one F(17), one F(19), one F(25), one F(27), and one F(3) atom to form LiF6 octahedra that share  a cornercorner with one Li(14)F6 octahedra,  a cornercorner with one Li(15)F6 octahedra, corners with two equivalent Li(25)OF5 octahedra, corners with two equivalent Li(28)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(27)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the twentieth Li site, Li(20) is bonded to one F(12), one F(19), one F(20), one F(27), one F(28), and one F(4) atom to form LiF6 octahedra that share  a cornercorner with one Li(13)F6 octahedra,  a cornercorner with one Li(16)F6 octahedra, corners with two equivalent Li(26)OF5 octahedra, corners with two equivalent Li(27)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(28)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the twenty-first Li site, Li(21) is bonded to one O(1), one F(15), one F(16), one F(23), one F(24), and one F(8) atom to form LiOF5 octahedra that share  a cornercorner with one Li(25)OF5 octahedra,  a cornercorner with one Li(28)OF5 octahedra, corners with two equivalent Li(14)F6 octahedra, corners with two equivalent Li(15)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(16)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the twenty-second Li site, Li(22) is bonded to one O(2), one F(13), one F(15), one F(21), one F(23), and one F(7) atom to form LiOF5 octahedra that share  a cornercorner with one Li(26)OF5 octahedra,  a cornercorner with one Li(27)OF5 octahedra, corners with two equivalent Li(13)F6 octahedra, corners with two equivalent Li(16)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(15)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the twenty-third Li site, Li(23) is bonded to one O(3), one F(14), one F(16), one F(22), one F(24), and one F(6) atom to form LiOF5 octahedra that share  a cornercorner with one Li(26)OF5 octahedra,  a cornercorner with one Li(27)OF5 octahedra, corners with two equivalent Li(13)F6 octahedra, corners with two equivalent Li(16)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(14)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the twenty-fourth Li site, Li(24) is bonded to one O(4), one F(13), one F(14), one F(21), one F(22), and one F(5) atom to form LiOF5 octahedra that share  a cornercorner with one Li(25)OF5 octahedra,  a cornercorner with one Li(28)OF5 octahedra, corners with two equivalent Li(14)F6 octahedra, corners with two equivalent Li(15)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(13)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the twenty-fifth Li site, Li(25) is bonded to one O(1), one F(17), one F(18), one F(25), one F(26), and one F(5) atom to form LiOF5 octahedra that share  a cornercorner with one Li(21)OF5 octahedra,  a cornercorner with one Li(24)OF5 octahedra, corners with two equivalent Li(18)F6 octahedra, corners with two equivalent Li(19)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(17)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the twenty-sixth Li site, Li(26) is bonded to one O(2), one F(18), one F(20), one F(26), one F(28), and one F(6) atom to form LiOF5 octahedra that share  a cornercorner with one Li(22)OF5 octahedra,  a cornercorner with one Li(23)OF5 octahedra, corners with two equivalent Li(17)F6 octahedra, corners with two equivalent Li(20)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(18)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the twenty-seventh Li site, Li(27) is bonded to one O(3), one F(17), one F(19), one F(25), one F(27), and one F(7) atom to form LiOF5 octahedra that share  a cornercorner with one Li(22)OF5 octahedra,  a cornercorner with one Li(23)OF5 octahedra, corners with two equivalent Li(17)F6 octahedra, corners with two equivalent Li(20)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(19)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the twenty-eighth Li site, Li(28) is bonded to one O(4), one F(19), one F(20), one F(27), one F(28), and one F(8) atom to form LiOF5 octahedra that share  a cornercorner with one Li(21)OF5 octahedra,  a cornercorner with one Li(24)OF5 octahedra, corners with two equivalent Li(18)F6 octahedra, corners with two equivalent Li(19)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(20)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(3), one F(1), one F(16), one F(17), and one F(3) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra, corners with two equivalent Li(2)O2F4 octahedra, corners with two equivalent Li(3)O2F4 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the second Co site, Co(2) is bonded to one O(3), one O(4), one F(14), one F(19), one F(3), and one F(4) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(10)F6 octahedra,  a cornercorner with one Li(11)F6 octahedra, corners with two equivalent Li(1)O2F4 octahedra, corners with two equivalent Li(4)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the third Co site, Co(3) is bonded to one O(1), one O(2), one F(1), one F(15), one F(18), and one F(2) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(10)F6 octahedra,  a cornercorner with one Li(11)F6 octahedra, corners with two equivalent Li(1)O2F4 octahedra, corners with two equivalent Li(4)O2F4 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth Co site, Co(4) is bonded to one O(2), one O(4), one F(13), one F(2), one F(20), and one F(4) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra, corners with two equivalent Li(2)O2F4 octahedra, corners with two equivalent Li(3)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(21), one Li(25), one Co(1), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(5)Li6 octahedra,  a cornercorner with one F(8)Li6 octahedra, corners with two equivalent F(2)Li4Co2 octahedra, corners with two equivalent F(3)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra, and edges with two equivalent F(1)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the second O site, O(2) is bonded to one Li(2), one Li(22), one Li(26), one Li(4), one Co(3), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(6)Li6 octahedra,  a cornercorner with one F(7)Li6 octahedra, corners with two equivalent F(1)Li4Co2 octahedra, corners with two equivalent F(4)Li4Co2 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent F(2)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the third O site, O(3) is bonded to one Li(1), one Li(23), one Li(27), one Li(3), one Co(1), and one Co(2) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(6)Li6 octahedra,  a cornercorner with one F(7)Li6 octahedra, corners with two equivalent F(1)Li4Co2 octahedra, corners with two equivalent F(4)Li4Co2 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra, and edges with two equivalent F(3)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth O site, O(4) is bonded to one Li(24), one Li(28), one Li(3), one Li(4), one Co(2), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(5)Li6 octahedra,  a cornercorner with one F(8)Li6 octahedra, corners with two equivalent F(2)Li4Co2 octahedra, corners with two equivalent F(3)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent F(4)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are twenty-eight inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(16), one Li(17), one Li(2), one Co(1), and one Co(3) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(12)Li6 octahedra,  a cornercorner with one F(9)Li6 octahedra, corners with two equivalent O(2)Li4Co2 octahedra, corners with two equivalent O(3)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra, and edges with two equivalent O(1)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the second F site, F(2) is bonded to one Li(15), one Li(18), one Li(2), one Li(4), one Co(3), and one Co(4) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(10)Li6 octahedra,  a cornercorner with one F(11)Li6 octahedra, corners with two equivalent O(1)Li4Co2 octahedra, corners with two equivalent O(4)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent O(2)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the third F site, F(3) is bonded to one Li(1), one Li(14), one Li(19), one Li(3), one Co(1), and one Co(2) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(10)Li6 octahedra,  a cornercorner with one F(11)Li6 octahedra, corners with two equivalent O(1)Li4Co2 octahedra, corners with two equivalent O(4)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra, and edges with two equivalent O(3)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth F site, F(4) is bonded to one Li(13), one Li(20), one Li(3), one Li(4), one Co(2), and one Co(4) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(12)Li6 octahedra,  a cornercorner with one F(9)Li6 octahedra, corners with two equivalent O(2)Li4Co2 octahedra, corners with two equivalent O(3)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent O(4)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the fifth F site, F(5) is bonded to one Li(10), one Li(24), one Li(25), one Li(5), one Li(6), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one O(1)Li4Co2 octahedra,  a cornercorner with one O(4)Li4Co2 octahedra, corners with two equivalent F(10)Li6 octahedra, corners with two equivalent F(11)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra, and edges with two equivalent F(9)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the sixth F site, F(6) is bonded to one Li(10), one Li(12), one Li(23), one Li(26), one Li(6), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one O(2)Li4Co2 octahedra,  a cornercorner with one O(3)Li4Co2 octahedra, corners with two equivalent F(12)Li6 octahedra, corners with two equivalent F(9)Li6 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(10)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the seventh F site, F(7) is bonded to one Li(11), one Li(22), one Li(27), one Li(5), one Li(7), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one O(2)Li4Co2 octahedra,  a cornercorner with one O(3)Li4Co2 octahedra, corners with two equivalent F(12)Li6 octahedra, corners with two equivalent F(9)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(11)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighth F site, F(8) is bonded to one Li(11), one Li(12), one Li(21), one Li(28), one Li(7), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one O(1)Li4Co2 octahedra,  a cornercorner with one O(4)Li4Co2 octahedra, corners with two equivalent F(10)Li6 octahedra, corners with two equivalent F(11)Li6 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra, and edges with two equivalent F(12)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the ninth F site, F(9) is bonded to one Li(10), one Li(13), one Li(17), one Li(5), one Li(6), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one F(1)Li4Co2 octahedra,  a cornercorner with one F(4)Li4Co2 octahedra, corners with two equivalent F(6)Li6 octahedra, corners with two equivalent F(7)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra, and edges with two equivalent F(5)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the tenth F site, F(10) is bonded to one Li(10), one Li(12), one Li(14), one Li(18), one Li(6), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(2)Li4Co2 octahedra,  a cornercorner with one F(3)Li4Co2 octahedra, corners with two equivalent F(5)Li6 octahedra, corners with two equivalent F(8)Li6 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(6)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the eleventh F site, F(11) is bonded to one Li(11), one Li(15), one Li(19), one Li(5), one Li(7), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one F(2)Li4Co2 octahedra,  a cornercorner with one F(3)Li4Co2 octahedra, corners with two equivalent F(5)Li6 octahedra, corners with two equivalent F(8)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(7)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the twelfth F site, F(12) is bonded to one Li(11), one Li(12), one Li(16), one Li(20), one Li(7), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(1)Li4Co2 octahedra,  a cornercorner with one F(4)Li4Co2 octahedra, corners with two equivalent F(6)Li6 octahedra, corners with two equivalent F(7)Li6 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent F(8)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the thirteenth F site, F(13) is bonded to one Li(13), one Li(15), one Li(22), one Li(24), one Li(9), and one Co(4) atom to form FLi5Co octahedra that share  a cornercorner with one F(17)Li5Co octahedra,  a cornercorner with one F(20)Li5Co octahedra, corners with two equivalent F(22)Li6 octahedra, corners with two equivalent F(23)Li6 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(21)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the fourteenth F site, F(14) is bonded to one Li(10), one Li(13), one Li(14), one Li(23), one Li(24), and one Co(2) atom to form FLi5Co octahedra that share  a cornercorner with one F(18)Li5Co octahedra,  a cornercorner with one F(19)Li5Co octahedra, corners with two equivalent F(21)Li6 octahedra, corners with two equivalent F(24)Li6 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(22)Li6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the fifteenth F site, F(15) is bonded to one Li(11), one Li(15), one Li(16), one Li(21), one Li(22), and one Co(3) atom to form FLi5Co octahedra that share  a cornercorner with one F(18)Li5Co octahedra,  a cornercorner with one F(19)Li5Co octahedra, corners with two equivalent F(21)Li6 octahedra, corners with two equivalent F(24)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(23)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the sixteenth F site, F(16) is bonded to one Li(12), one Li(14), one Li(16), one Li(21), one Li(23), and one Co(1) atom to form FLi5Co octahedra that share  a cornercorner with one F(17)Li5Co octahedra,  a cornercorner with one F(20)Li5Co octahedra, corners with two equivalent F(22)Li6 octahedra, corners with two equivalent F(23)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(24)Li6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the seventeenth F site, F(17) is bonded to one Li(17), one Li(19), one Li(25), one Li(27), one Li(9), and one Co(1) atom to form FLi5Co octahedra that share  a cornercorner with one F(13)Li5Co octahedra,  a cornercorner with one F(16)Li5Co octahedra, corners with two equivalent F(26)Li6 octahedra, corners with two equivalent F(27)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(25)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the eighteenth F site, F(18) is bonded to one Li(10), one Li(17), one Li(18), one Li(25), one Li(26), and one Co(3) atom to form FLi5Co octahedra that share  a cornercorner with one F(14)Li5Co octahedra,  a cornercorner with one F(15)Li5Co octahedra, corners with two equivalent F(25)Li6 octahedra, corners with two equivalent F(28)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(26)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the nineteenth F site, F(19) is bonded to one Li(11), one Li(19), one Li(20), one Li(27), one Li(28), and one Co(2) atom to form FLi5Co octahedra that share  a cornercorner with one F(14)Li5Co octahedra,  a cornercorner with one F(15)Li5Co octahedra, corners with two equivalent F(25)Li6 octahedra, corners with two equivalent F(28)Li6 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(27)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the twentieth F site, F(20) is bonded to one Li(12), one Li(18), one Li(20), one Li(26), one Li(28), and one Co(4) atom to form FLi5Co octahedra that share  a cornercorner with one F(13)Li5Co octahedra,  a cornercorner with one F(16)Li5Co octahedra, corners with two equivalent F(26)Li6 octahedra, corners with two equivalent F(27)Li6 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(28)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the twenty-first F site, F(21) is bonded to one Li(13), one Li(15), one Li(22), one Li(24), one Li(4), and one Li(5) atom to form FLi6 octahedra that share  a cornercorner with one F(25)Li6 octahedra,  a cornercorner with one F(28)Li6 octahedra, corners with two equivalent F(14)Li5Co octahedra, corners with two equivalent F(15)Li5Co octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(13)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twenty-second F site, F(22) is bonded to one Li(13), one Li(14), one Li(23), one Li(24), one Li(3), and one Li(6) atom to form FLi6 octahedra that share  a cornercorner with one F(26)Li6 octahedra,  a cornercorner with one F(27)Li6 octahedra, corners with two equivalent F(13)Li5Co octahedra, corners with two equivalent F(16)Li5Co octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(14)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-third F site, F(23) is bonded to one Li(15), one Li(16), one Li(2), one Li(21), one Li(22), and one Li(7) atom to form FLi6 octahedra that share  a cornercorner with one F(26)Li6 octahedra,  a cornercorner with one F(27)Li6 octahedra, corners with two equivalent F(13)Li5Co octahedra, corners with two equivalent F(16)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(15)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twenty-fourth F site, F(24) is bonded to one Li(1), one Li(14), one Li(16), one Li(21), one Li(23), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(25)Li6 octahedra,  a cornercorner with one F(28)Li6 octahedra, corners with two equivalent F(14)Li5Co octahedra, corners with two equivalent F(15)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(16)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-fifth F site, F(25) is bonded to one Li(1), one Li(17), one Li(19), one Li(25), one Li(27), and one Li(5) atom to form FLi6 octahedra that share  a cornercorner with one F(21)Li6 octahedra,  a cornercorner with one F(24)Li6 octahedra, corners with two equivalent F(18)Li5Co octahedra, corners with two equivalent F(19)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(17)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-sixth F site, F(26) is bonded to one Li(17), one Li(18), one Li(2), one Li(25), one Li(26), and one Li(6) atom to form FLi6 octahedra that share  a cornercorner with one F(22)Li6 octahedra,  a cornercorner with one F(23)Li6 octahedra, corners with two equivalent F(17)Li5Co octahedra, corners with two equivalent F(20)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(18)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twenty-seventh F site, F(27) is bonded to one Li(19), one Li(20), one Li(27), one Li(28), one Li(3), and one Li(7) atom to form FLi6 octahedra that share  a cornercorner with one F(22)Li6 octahedra,  a cornercorner with one F(23)Li6 octahedra, corners with two equivalent F(17)Li5Co octahedra, corners with two equivalent F(20)Li5Co octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(19)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-eighth F site, F(28) is bonded to one Li(18), one Li(20), one Li(26), one Li(28), one Li(4), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(21)Li6 octahedra,  a cornercorner with one F(24)Li6 octahedra, corners with two equivalent F(18)Li5Co octahedra, corners with two equivalent F(19)Li5Co octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(20)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°.
Li7CoOF7 is Molybdenum Carbide MAX Phase-derived structured and crystallizes in the triclinic P1 space group. There are twenty-eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one F(1), one F(24), one F(25), and one F(3) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(5)F6 octahedra,  a cornercorner with one Li(8)F6 octahedra, corners with two equivalent Co(2)O2F4 octahedra, corners with two equivalent Co(3)O2F4 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra, and edges with two equivalent Co(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(1)-O(1) bond length is 2.02 Å. The Li(1)-O(3) bond length is 2.01 Å. The Li(1)-F(1) bond length is 2.16 Å. The Li(1)-F(24) bond length is 2.13 Å. The Li(1)-F(25) bond length is 2.13 Å. The Li(1)-F(3) bond length is 2.16 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one F(1), one F(2), one F(23), and one F(26) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(7)F6 octahedra, corners with two equivalent Co(1)O2F4 octahedra, corners with two equivalent Co(4)O2F4 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra, and edges with two equivalent Co(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Li(2)-O(1) bond length is 2.01 Å. The Li(2)-O(2) bond length is 2.00 Å. The Li(2)-F(1) bond length is 2.14 Å. The Li(2)-F(2) bond length is 2.17 Å. The Li(2)-F(23) bond length is 2.14 Å. The Li(2)-F(26) bond length is 2.13 Å. In the third Li site, Li(3) is bonded to one O(3), one O(4), one F(22), one F(27), one F(3), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(7)F6 octahedra, corners with two equivalent Co(1)O2F4 octahedra, corners with two equivalent Co(4)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Co(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(3)-O(3) bond length is 2.00 Å. The Li(3)-O(4) bond length is 2.02 Å. The Li(3)-F(22) bond length is 2.13 Å. The Li(3)-F(27) bond length is 2.13 Å. The Li(3)-F(3) bond length is 2.16 Å. The Li(3)-F(4) bond length is 2.17 Å. In the fourth Li site, Li(4) is bonded to one O(2), one O(4), one F(2), one F(21), one F(28), and one F(4) atom to form LiO2F4 octahedra that share  a cornercorner with one Li(5)F6 octahedra,  a cornercorner with one Li(8)F6 octahedra, corners with two equivalent Co(2)O2F4 octahedra, corners with two equivalent Co(3)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Co(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Li(4)-O(2) bond length is 2.01 Å. The Li(4)-O(4) bond length is 2.02 Å. The Li(4)-F(2) bond length is 2.16 Å. The Li(4)-F(21) bond length is 2.14 Å. The Li(4)-F(28) bond length is 2.13 Å. The Li(4)-F(4) bond length is 2.13 Å. In the fifth Li site, Li(5) is bonded to one F(11), one F(21), one F(25), one F(5), one F(7), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(1)O2F4 octahedra,  a cornercorner with one Li(4)O2F4 octahedra, corners with two equivalent Li(10)F6 octahedra, corners with two equivalent Li(11)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra, and edges with two equivalent Li(9)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Li(5)-F(11) bond length is 2.08 Å. The Li(5)-F(21) bond length is 2.02 Å. The Li(5)-F(25) bond length is 2.02 Å. The Li(5)-F(5) bond length is 2.07 Å. The Li(5)-F(7) bond length is 2.07 Å. The Li(5)-F(9) bond length is 2.08 Å. In the sixth Li site, Li(6) is bonded to one F(10), one F(22), one F(26), one F(5), one F(6), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(2)O2F4 octahedra,  a cornercorner with one Li(3)O2F4 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent Li(9)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra, and edges with two equivalent Li(10)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Li(6)-F(10) bond length is 2.08 Å. The Li(6)-F(22) bond length is 2.03 Å. The Li(6)-F(26) bond length is 2.02 Å. The Li(6)-F(5) bond length is 2.07 Å. The Li(6)-F(6) bond length is 2.06 Å. The Li(6)-F(9) bond length is 2.08 Å. In the seventh Li site, Li(7) is bonded to one F(11), one F(12), one F(23), one F(27), one F(7), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Li(2)O2F4 octahedra,  a cornercorner with one Li(3)O2F4 octahedra, corners with two equivalent Li(12)F6 octahedra, corners with two equivalent Li(9)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(11)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Li(7)-F(11) bond length is 2.08 Å. The Li(7)-F(12) bond length is 2.08 Å. The Li(7)-F(23) bond length is 2.02 Å. The Li(7)-F(27) bond length is 2.02 Å. The Li(7)-F(7) bond length is 2.07 Å. The Li(7)-F(8) bond length is 2.06 Å. In the eighth Li site, Li(8) is bonded to one F(10), one F(12), one F(24), one F(28), one F(6), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Li(1)O2F4 octahedra,  a cornercorner with one Li(4)O2F4 octahedra, corners with two equivalent Li(10)F6 octahedra, corners with two equivalent Li(11)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Li(8)-F(10) bond length is 2.08 Å. The Li(8)-F(12) bond length is 2.08 Å. The Li(8)-F(24) bond length is 2.02 Å. The Li(8)-F(28) bond length is 2.02 Å. The Li(8)-F(6) bond length is 2.07 Å. The Li(8)-F(8) bond length is 2.07 Å. In the ninth Li site, Li(9) is bonded to one F(11), one F(13), one F(17), one F(5), one F(7), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Co(1)O2F4 octahedra,  a cornercorner with one Co(4)O2F4 octahedra, corners with two equivalent Li(6)F6 octahedra, corners with two equivalent Li(7)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra, and edges with two equivalent Li(5)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. The Li(9)-F(11) bond length is 2.10 Å. The Li(9)-F(13) bond length is 1.99 Å. The Li(9)-F(17) bond length is 2.02 Å. The Li(9)-F(5) bond length is 2.07 Å. The Li(9)-F(7) bond length is 2.07 Å. The Li(9)-F(9) bond length is 2.09 Å. In the tenth Li site, Li(10) is bonded to one F(10), one F(14), one F(18), one F(5), one F(6), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Co(2)O2F4 octahedra,  a cornercorner with one Co(3)O2F4 octahedra, corners with two equivalent Li(5)F6 octahedra, corners with two equivalent Li(8)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra, and edges with two equivalent Li(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. The Li(10)-F(10) bond length is 2.09 Å. The Li(10)-F(14) bond length is 2.02 Å. The Li(10)-F(18) bond length is 1.99 Å. The Li(10)-F(5) bond length is 2.07 Å. The Li(10)-F(6) bond length is 2.07 Å. The Li(10)-F(9) bond length is 2.10 Å. In the eleventh Li site, Li(11) is bonded to one F(11), one F(12), one F(15), one F(19), one F(7), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Co(2)O2F4 octahedra,  a cornercorner with one Co(3)O2F4 octahedra, corners with two equivalent Li(5)F6 octahedra, corners with two equivalent Li(8)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(7)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. The Li(11)-F(11) bond length is 2.09 Å. The Li(11)-F(12) bond length is 2.09 Å. The Li(11)-F(15) bond length is 2.00 Å. The Li(11)-F(19) bond length is 2.01 Å. The Li(11)-F(7) bond length is 2.07 Å. The Li(11)-F(8) bond length is 2.07 Å. In the twelfth Li site, Li(12) is bonded to one F(10), one F(12), one F(16), one F(20), one F(6), and one F(8) atom to form LiF6 octahedra that share  a cornercorner with one Co(1)O2F4 octahedra,  a cornercorner with one Co(4)O2F4 octahedra, corners with two equivalent Li(6)F6 octahedra, corners with two equivalent Li(7)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra, and edges with two equivalent Li(8)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. The Li(12)-F(10) bond length is 2.10 Å. The Li(12)-F(12) bond length is 2.10 Å. The Li(12)-F(16) bond length is 2.02 Å. The Li(12)-F(20) bond length is 1.99 Å. The Li(12)-F(6) bond length is 2.07 Å. The Li(12)-F(8) bond length is 2.07 Å. In the thirteenth Li site, Li(13) is bonded to one F(13), one F(14), one F(21), one F(22), one F(4), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(17)F6 octahedra,  a cornercorner with one Li(20)F6 octahedra, corners with two equivalent Li(22)OF5 octahedra, corners with two equivalent Li(23)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(24)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. The Li(13)-F(13) bond length is 2.07 Å. The Li(13)-F(14) bond length is 2.07 Å. The Li(13)-F(21) bond length is 2.03 Å. The Li(13)-F(22) bond length is 2.03 Å. The Li(13)-F(4) bond length is 2.15 Å. The Li(13)-F(9) bond length is 2.00 Å. In the fourteenth Li site, Li(14) is bonded to one F(10), one F(14), one F(16), one F(22), one F(24), and one F(3) atom to form LiF6 octahedra that share  a cornercorner with one Li(18)F6 octahedra,  a cornercorner with one Li(19)F6 octahedra, corners with two equivalent Li(21)OF5 octahedra, corners with two equivalent Li(24)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(23)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. The Li(14)-F(10) bond length is 1.99 Å. The Li(14)-F(14) bond length is 2.07 Å. The Li(14)-F(16) bond length is 2.07 Å. The Li(14)-F(22) bond length is 2.03 Å. The Li(14)-F(24) bond length is 2.03 Å. The Li(14)-F(3) bond length is 2.16 Å. In the fifteenth Li site, Li(15) is bonded to one F(11), one F(13), one F(15), one F(2), one F(21), and one F(23) atom to form LiF6 octahedra that share  a cornercorner with one Li(18)F6 octahedra,  a cornercorner with one Li(19)F6 octahedra, corners with two equivalent Li(21)OF5 octahedra, corners with two equivalent Li(24)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(22)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. The Li(15)-F(11) bond length is 1.99 Å. The Li(15)-F(13) bond length is 2.08 Å. The Li(15)-F(15) bond length is 2.08 Å. The Li(15)-F(2) bond length is 2.16 Å. The Li(15)-F(21) bond length is 2.03 Å. The Li(15)-F(23) bond length is 2.03 Å. In the sixteenth Li site, Li(16) is bonded to one F(1), one F(12), one F(15), one F(16), one F(23), and one F(24) atom to form LiF6 octahedra that share  a cornercorner with one Li(17)F6 octahedra,  a cornercorner with one Li(20)F6 octahedra, corners with two equivalent Li(22)OF5 octahedra, corners with two equivalent Li(23)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(21)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. The Li(16)-F(1) bond length is 2.15 Å. The Li(16)-F(12) bond length is 1.99 Å. The Li(16)-F(15) bond length is 2.07 Å. The Li(16)-F(16) bond length is 2.07 Å. The Li(16)-F(23) bond length is 2.03 Å. The Li(16)-F(24) bond length is 2.03 Å. In the seventeenth Li site, Li(17) is bonded to one F(1), one F(17), one F(18), one F(25), one F(26), and one F(9) atom to form LiF6 octahedra that share  a cornercorner with one Li(13)F6 octahedra,  a cornercorner with one Li(16)F6 octahedra, corners with two equivalent Li(26)OF5 octahedra, corners with two equivalent Li(27)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(25)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. The Li(17)-F(1) bond length is 2.16 Å. The Li(17)-F(17) bond length is 2.07 Å. The Li(17)-F(18) bond length is 2.08 Å. The Li(17)-F(25) bond length is 2.04 Å. The Li(17)-F(26) bond length is 2.02 Å. The Li(17)-F(9) bond length is 2.00 Å. In the eighteenth Li site, Li(18) is bonded to one F(10), one F(18), one F(2), one F(20), one F(26), and one F(28) atom to form LiF6 octahedra that share  a cornercorner with one Li(14)F6 octahedra,  a cornercorner with one Li(15)F6 octahedra, corners with two equivalent Li(25)OF5 octahedra, corners with two equivalent Li(28)OF5 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(26)OF5 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. The Li(18)-F(10) bond length is 2.00 Å. The Li(18)-F(18) bond length is 2.07 Å. The Li(18)-F(2) bond length is 2.16 Å. The Li(18)-F(20) bond length is 2.07 Å. The Li(18)-F(26) bond length is 2.04 Å. The Li(18)-F(28) bond length is 2.03 Å. In the nineteenth Li site, Li(19) is bonded to one F(11), one F(17), one F(19), one F(25), one F(27), and one F(3) atom to form LiF6 octahedra that share  a cornercorner with one Li(14)F6 octahedra,  a cornercorner with one Li(15)F6 octahedra, corners with two equivalent Li(25)OF5 octahedra, corners with two equivalent Li(28)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(27)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. The Li(19)-F(11) bond length is 1.99 Å. The Li(19)-F(17) bond length is 2.07 Å. The Li(19)-F(19) bond length is 2.07 Å. The Li(19)-F(25) bond length is 2.03 Å. The Li(19)-F(27) bond length is 2.03 Å. The Li(19)-F(3) bond length is 2.15 Å. In the twentieth Li site, Li(20) is bonded to one F(12), one F(19), one F(20), one F(27), one F(28), and one F(4) atom to form LiF6 octahedra that share  a cornercorner with one Li(13)F6 octahedra,  a cornercorner with one Li(16)F6 octahedra, corners with two equivalent Li(26)OF5 octahedra, corners with two equivalent Li(27)OF5 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(28)OF5 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. The Li(20)-F(12) bond length is 2.00 Å. The Li(20)-F(19) bond length is 2.07 Å. The Li(20)-F(20) bond length is 2.07 Å. The Li(20)-F(27) bond length is 2.04 Å. The Li(20)-F(28) bond length is 2.02 Å. The Li(20)-F(4) bond length is 2.16 Å. In the twenty-first Li site, Li(21) is bonded to one O(1), one F(15), one F(16), one F(23), one F(24), and one F(8) atom to form LiOF5 octahedra that share  a cornercorner with one Li(25)OF5 octahedra,  a cornercorner with one Li(28)OF5 octahedra, corners with two equivalent Li(14)F6 octahedra, corners with two equivalent Li(15)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(16)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(21)-O(1) bond length is 2.06 Å. The Li(21)-F(15) bond length is 2.17 Å. The Li(21)-F(16) bond length is 2.18 Å. The Li(21)-F(23) bond length is 2.04 Å. The Li(21)-F(24) bond length is 2.04 Å. The Li(21)-F(8) bond length is 2.09 Å. In the twenty-second Li site, Li(22) is bonded to one O(2), one F(13), one F(15), one F(21), one F(23), and one F(7) atom to form LiOF5 octahedra that share  a cornercorner with one Li(26)OF5 octahedra,  a cornercorner with one Li(27)OF5 octahedra, corners with two equivalent Li(13)F6 octahedra, corners with two equivalent Li(16)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(15)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. The Li(22)-O(2) bond length is 2.06 Å. The Li(22)-F(13) bond length is 2.17 Å. The Li(22)-F(15) bond length is 2.17 Å. The Li(22)-F(21) bond length is 2.04 Å. The Li(22)-F(23) bond length is 2.04 Å. The Li(22)-F(7) bond length is 2.12 Å. In the twenty-third Li site, Li(23) is bonded to one O(3), one F(14), one F(16), one F(22), one F(24), and one F(6) atom to form LiOF5 octahedra that share  a cornercorner with one Li(26)OF5 octahedra,  a cornercorner with one Li(27)OF5 octahedra, corners with two equivalent Li(13)F6 octahedra, corners with two equivalent Li(16)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(14)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(23)-O(3) bond length is 2.06 Å. The Li(23)-F(14) bond length is 2.19 Å. The Li(23)-F(16) bond length is 2.18 Å. The Li(23)-F(22) bond length is 2.04 Å. The Li(23)-F(24) bond length is 2.04 Å. The Li(23)-F(6) bond length is 2.08 Å. In the twenty-fourth Li site, Li(24) is bonded to one O(4), one F(13), one F(14), one F(21), one F(22), and one F(5) atom to form LiOF5 octahedra that share  a cornercorner with one Li(25)OF5 octahedra,  a cornercorner with one Li(28)OF5 octahedra, corners with two equivalent Li(14)F6 octahedra, corners with two equivalent Li(15)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(13)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(24)-O(4) bond length is 2.06 Å. The Li(24)-F(13) bond length is 2.16 Å. The Li(24)-F(14) bond length is 2.19 Å. The Li(24)-F(21) bond length is 2.04 Å. The Li(24)-F(22) bond length is 2.05 Å. The Li(24)-F(5) bond length is 2.10 Å. In the twenty-fifth Li site, Li(25) is bonded to one O(1), one F(17), one F(18), one F(25), one F(26), and one F(5) atom to form LiOF5 octahedra that share  a cornercorner with one Li(21)OF5 octahedra,  a cornercorner with one Li(24)OF5 octahedra, corners with two equivalent Li(18)F6 octahedra, corners with two equivalent Li(19)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(17)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(25)-O(1) bond length is 2.05 Å. The Li(25)-F(17) bond length is 2.19 Å. The Li(25)-F(18) bond length is 2.16 Å. The Li(25)-F(25) bond length is 2.05 Å. The Li(25)-F(26) bond length is 2.04 Å. The Li(25)-F(5) bond length is 2.10 Å. In the twenty-sixth Li site, Li(26) is bonded to one O(2), one F(18), one F(20), one F(26), one F(28), and one F(6) atom to form LiOF5 octahedra that share  a cornercorner with one Li(22)OF5 octahedra,  a cornercorner with one Li(23)OF5 octahedra, corners with two equivalent Li(17)F6 octahedra, corners with two equivalent Li(20)F6 octahedra,  an edgeedge with one Li(10)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(6)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(2)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(3)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(18)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. The Li(26)-O(2) bond length is 2.02 Å. The Li(26)-F(18) bond length is 2.15 Å. The Li(26)-F(20) bond length is 2.15 Å. The Li(26)-F(26) bond length is 2.06 Å. The Li(26)-F(28) bond length is 2.06 Å. The Li(26)-F(6) bond length is 2.13 Å. In the twenty-seventh Li site, Li(27) is bonded to one O(3), one F(17), one F(19), one F(25), one F(27), and one F(7) atom to form LiOF5 octahedra that share  a cornercorner with one Li(22)OF5 octahedra,  a cornercorner with one Li(23)OF5 octahedra, corners with two equivalent Li(17)F6 octahedra, corners with two equivalent Li(20)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(5)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Li(1)O2F4 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(2)O2F4 octahedra, and edges with two equivalent Li(19)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(27)-O(3) bond length is 2.05 Å. The Li(27)-F(17) bond length is 2.19 Å. The Li(27)-F(19) bond length is 2.18 Å. The Li(27)-F(25) bond length is 2.04 Å. The Li(27)-F(27) bond length is 2.04 Å. The Li(27)-F(7) bond length is 2.09 Å. In the twenty-eighth Li site, Li(28) is bonded to one O(4), one F(19), one F(20), one F(27), one F(28), and one F(8) atom to form LiOF5 octahedra that share  a cornercorner with one Li(21)OF5 octahedra,  a cornercorner with one Li(24)OF5 octahedra, corners with two equivalent Li(18)F6 octahedra, corners with two equivalent Li(19)F6 octahedra,  an edgeedge with one Li(11)F6 octahedra,  an edgeedge with one Li(12)F6 octahedra,  an edgeedge with one Li(7)F6 octahedra,  an edgeedge with one Li(8)F6 octahedra,  an edgeedge with one Li(3)O2F4 octahedra,  an edgeedge with one Li(4)O2F4 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(20)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Li(28)-O(4) bond length is 2.05 Å. The Li(28)-F(19) bond length is 2.19 Å. The Li(28)-F(20) bond length is 2.15 Å. The Li(28)-F(27) bond length is 2.06 Å. The Li(28)-F(28) bond length is 2.04 Å. The Li(28)-F(8) bond length is 2.10 Å. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(3), one F(1), one F(16), one F(17), and one F(3) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra, corners with two equivalent Li(2)O2F4 octahedra, corners with two equivalent Li(3)O2F4 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. The Co(1)-O(1) bond length is 1.95 Å. The Co(1)-O(3) bond length is 1.96 Å. The Co(1)-F(1) bond length is 2.23 Å. The Co(1)-F(16) bond length is 2.16 Å. The Co(1)-F(17) bond length is 2.14 Å. The Co(1)-F(3) bond length is 2.20 Å. In the second Co site, Co(2) is bonded to one O(3), one O(4), one F(14), one F(19), one F(3), and one F(4) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(10)F6 octahedra,  a cornercorner with one Li(11)F6 octahedra, corners with two equivalent Li(1)O2F4 octahedra, corners with two equivalent Li(4)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(14)F6 octahedra,  an edgeedge with one Li(19)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(23)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(27)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. The Co(2)-O(3) bond length is 1.96 Å. The Co(2)-O(4) bond length is 1.95 Å. The Co(2)-F(14) bond length is 2.14 Å. The Co(2)-F(19) bond length is 2.16 Å. The Co(2)-F(3) bond length is 2.20 Å. The Co(2)-F(4) bond length is 2.23 Å. In the third Co site, Co(3) is bonded to one O(1), one O(2), one F(1), one F(15), one F(18), and one F(2) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(10)F6 octahedra,  a cornercorner with one Li(11)F6 octahedra, corners with two equivalent Li(1)O2F4 octahedra, corners with two equivalent Li(4)O2F4 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(16)F6 octahedra,  an edgeedge with one Li(17)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(21)OF5 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(25)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Co(1)O2F4 octahedra,  an edgeedge with one Co(4)O2F4 octahedra, and edges with two equivalent Li(2)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. The Co(3)-O(1) bond length is 1.95 Å. The Co(3)-O(2) bond length is 1.97 Å. The Co(3)-F(1) bond length is 2.19 Å. The Co(3)-F(15) bond length is 2.15 Å. The Co(3)-F(18) bond length is 2.19 Å. The Co(3)-F(2) bond length is 2.19 Å. In the fourth Co site, Co(4) is bonded to one O(2), one O(4), one F(13), one F(2), one F(20), and one F(4) atom to form CoO2F4 octahedra that share  a cornercorner with one Li(12)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra, corners with two equivalent Li(2)O2F4 octahedra, corners with two equivalent Li(3)O2F4 octahedra,  an edgeedge with one Li(13)F6 octahedra,  an edgeedge with one Li(15)F6 octahedra,  an edgeedge with one Li(18)F6 octahedra,  an edgeedge with one Li(20)F6 octahedra,  an edgeedge with one Li(22)OF5 octahedra,  an edgeedge with one Li(24)OF5 octahedra,  an edgeedge with one Li(26)OF5 octahedra,  an edgeedge with one Li(28)OF5 octahedra,  an edgeedge with one Co(2)O2F4 octahedra,  an edgeedge with one Co(3)O2F4 octahedra, and edges with two equivalent Li(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. The Co(4)-O(2) bond length is 1.97 Å. The Co(4)-O(4) bond length is 1.94 Å. The Co(4)-F(13) bond length is 2.15 Å. The Co(4)-F(2) bond length is 2.19 Å. The Co(4)-F(20) bond length is 2.19 Å. The Co(4)-F(4) bond length is 2.18 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(21), one Li(25), one Co(1), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(5)Li6 octahedra,  a cornercorner with one F(8)Li6 octahedra, corners with two equivalent F(2)Li4Co2 octahedra, corners with two equivalent F(3)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra, and edges with two equivalent F(1)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the second O site, O(2) is bonded to one Li(2), one Li(22), one Li(26), one Li(4), one Co(3), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(6)Li6 octahedra,  a cornercorner with one F(7)Li6 octahedra, corners with two equivalent F(1)Li4Co2 octahedra, corners with two equivalent F(4)Li4Co2 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent F(2)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the third O site, O(3) is bonded to one Li(1), one Li(23), one Li(27), one Li(3), one Co(1), and one Co(2) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(6)Li6 octahedra,  a cornercorner with one F(7)Li6 octahedra, corners with two equivalent F(1)Li4Co2 octahedra, corners with two equivalent F(4)Li4Co2 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra, and edges with two equivalent F(3)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth O site, O(4) is bonded to one Li(24), one Li(28), one Li(3), one Li(4), one Co(2), and one Co(4) atom to form OLi4Co2 octahedra that share  a cornercorner with one F(5)Li6 octahedra,  a cornercorner with one F(8)Li6 octahedra, corners with two equivalent F(2)Li4Co2 octahedra, corners with two equivalent F(3)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent F(4)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are twenty-eight inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(16), one Li(17), one Li(2), one Co(1), and one Co(3) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(12)Li6 octahedra,  a cornercorner with one F(9)Li6 octahedra, corners with two equivalent O(2)Li4Co2 octahedra, corners with two equivalent O(3)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra, and edges with two equivalent O(1)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the second F site, F(2) is bonded to one Li(15), one Li(18), one Li(2), one Li(4), one Co(3), and one Co(4) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(10)Li6 octahedra,  a cornercorner with one F(11)Li6 octahedra, corners with two equivalent O(1)Li4Co2 octahedra, corners with two equivalent O(4)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent O(2)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the third F site, F(3) is bonded to one Li(1), one Li(14), one Li(19), one Li(3), one Co(1), and one Co(2) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(10)Li6 octahedra,  a cornercorner with one F(11)Li6 octahedra, corners with two equivalent O(1)Li4Co2 octahedra, corners with two equivalent O(4)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra, and edges with two equivalent O(3)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth F site, F(4) is bonded to one Li(13), one Li(20), one Li(3), one Li(4), one Co(2), and one Co(4) atom to form FLi4Co2 octahedra that share  a cornercorner with one F(12)Li6 octahedra,  a cornercorner with one F(9)Li6 octahedra, corners with two equivalent O(2)Li4Co2 octahedra, corners with two equivalent O(3)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent O(4)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the fifth F site, F(5) is bonded to one Li(10), one Li(24), one Li(25), one Li(5), one Li(6), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one O(1)Li4Co2 octahedra,  a cornercorner with one O(4)Li4Co2 octahedra, corners with two equivalent F(10)Li6 octahedra, corners with two equivalent F(11)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra, and edges with two equivalent F(9)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the sixth F site, F(6) is bonded to one Li(10), one Li(12), one Li(23), one Li(26), one Li(6), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one O(2)Li4Co2 octahedra,  a cornercorner with one O(3)Li4Co2 octahedra, corners with two equivalent F(12)Li6 octahedra, corners with two equivalent F(9)Li6 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(10)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the seventh F site, F(7) is bonded to one Li(11), one Li(22), one Li(27), one Li(5), one Li(7), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one O(2)Li4Co2 octahedra,  a cornercorner with one O(3)Li4Co2 octahedra, corners with two equivalent F(12)Li6 octahedra, corners with two equivalent F(9)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(11)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighth F site, F(8) is bonded to one Li(11), one Li(12), one Li(21), one Li(28), one Li(7), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one O(1)Li4Co2 octahedra,  a cornercorner with one O(4)Li4Co2 octahedra, corners with two equivalent F(10)Li6 octahedra, corners with two equivalent F(11)Li6 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra, and edges with two equivalent F(12)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the ninth F site, F(9) is bonded to one Li(10), one Li(13), one Li(17), one Li(5), one Li(6), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one F(1)Li4Co2 octahedra,  a cornercorner with one F(4)Li4Co2 octahedra, corners with two equivalent F(6)Li6 octahedra, corners with two equivalent F(7)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra, and edges with two equivalent F(5)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the tenth F site, F(10) is bonded to one Li(10), one Li(12), one Li(14), one Li(18), one Li(6), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(2)Li4Co2 octahedra,  a cornercorner with one F(3)Li4Co2 octahedra, corners with two equivalent F(5)Li6 octahedra, corners with two equivalent F(8)Li6 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(6)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the eleventh F site, F(11) is bonded to one Li(11), one Li(15), one Li(19), one Li(5), one Li(7), and one Li(9) atom to form FLi6 octahedra that share  a cornercorner with one F(2)Li4Co2 octahedra,  a cornercorner with one F(3)Li4Co2 octahedra, corners with two equivalent F(5)Li6 octahedra, corners with two equivalent F(8)Li6 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(7)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the twelfth F site, F(12) is bonded to one Li(11), one Li(12), one Li(16), one Li(20), one Li(7), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(1)Li4Co2 octahedra,  a cornercorner with one F(4)Li4Co2 octahedra, corners with two equivalent F(6)Li6 octahedra, corners with two equivalent F(7)Li6 octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra, and edges with two equivalent F(8)Li6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the thirteenth F site, F(13) is bonded to one Li(13), one Li(15), one Li(22), one Li(24), one Li(9), and one Co(4) atom to form FLi5Co octahedra that share  a cornercorner with one F(17)Li5Co octahedra,  a cornercorner with one F(20)Li5Co octahedra, corners with two equivalent F(22)Li6 octahedra, corners with two equivalent F(23)Li6 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(21)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the fourteenth F site, F(14) is bonded to one Li(10), one Li(13), one Li(14), one Li(23), one Li(24), and one Co(2) atom to form FLi5Co octahedra that share  a cornercorner with one F(18)Li5Co octahedra,  a cornercorner with one F(19)Li5Co octahedra, corners with two equivalent F(21)Li6 octahedra, corners with two equivalent F(24)Li6 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(22)Li6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the fifteenth F site, F(15) is bonded to one Li(11), one Li(15), one Li(16), one Li(21), one Li(22), and one Co(3) atom to form FLi5Co octahedra that share  a cornercorner with one F(18)Li5Co octahedra,  a cornercorner with one F(19)Li5Co octahedra, corners with two equivalent F(21)Li6 octahedra, corners with two equivalent F(24)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(13)Li5Co octahedra,  an edgeedge with one F(16)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(23)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the sixteenth F site, F(16) is bonded to one Li(12), one Li(14), one Li(16), one Li(21), one Li(23), and one Co(1) atom to form FLi5Co octahedra that share  a cornercorner with one F(17)Li5Co octahedra,  a cornercorner with one F(20)Li5Co octahedra, corners with two equivalent F(22)Li6 octahedra, corners with two equivalent F(23)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(14)Li5Co octahedra,  an edgeedge with one F(15)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(24)Li6 octahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the seventeenth F site, F(17) is bonded to one Li(17), one Li(19), one Li(25), one Li(27), one Li(9), and one Co(1) atom to form FLi5Co octahedra that share  a cornercorner with one F(13)Li5Co octahedra,  a cornercorner with one F(16)Li5Co octahedra, corners with two equivalent F(26)Li6 octahedra, corners with two equivalent F(27)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(25)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the eighteenth F site, F(18) is bonded to one Li(10), one Li(17), one Li(18), one Li(25), one Li(26), and one Co(3) atom to form FLi5Co octahedra that share  a cornercorner with one F(14)Li5Co octahedra,  a cornercorner with one F(15)Li5Co octahedra, corners with two equivalent F(25)Li6 octahedra, corners with two equivalent F(28)Li6 octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(26)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the nineteenth F site, F(19) is bonded to one Li(11), one Li(19), one Li(20), one Li(27), one Li(28), and one Co(2) atom to form FLi5Co octahedra that share  a cornercorner with one F(14)Li5Co octahedra,  a cornercorner with one F(15)Li5Co octahedra, corners with two equivalent F(25)Li6 octahedra, corners with two equivalent F(28)Li6 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(17)Li5Co octahedra,  an edgeedge with one F(20)Li5Co octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(27)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the twentieth F site, F(20) is bonded to one Li(12), one Li(18), one Li(20), one Li(26), one Li(28), and one Co(4) atom to form FLi5Co octahedra that share  a cornercorner with one F(13)Li5Co octahedra,  a cornercorner with one F(16)Li5Co octahedra, corners with two equivalent F(26)Li6 octahedra, corners with two equivalent F(27)Li6 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(18)Li5Co octahedra,  an edgeedge with one F(19)Li5Co octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(28)Li6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the twenty-first F site, F(21) is bonded to one Li(13), one Li(15), one Li(22), one Li(24), one Li(4), and one Li(5) atom to form FLi6 octahedra that share  a cornercorner with one F(25)Li6 octahedra,  a cornercorner with one F(28)Li6 octahedra, corners with two equivalent F(14)Li5Co octahedra, corners with two equivalent F(15)Li5Co octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(13)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twenty-second F site, F(22) is bonded to one Li(13), one Li(14), one Li(23), one Li(24), one Li(3), and one Li(6) atom to form FLi6 octahedra that share  a cornercorner with one F(26)Li6 octahedra,  a cornercorner with one F(27)Li6 octahedra, corners with two equivalent F(13)Li5Co octahedra, corners with two equivalent F(16)Li5Co octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(14)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-third F site, F(23) is bonded to one Li(15), one Li(16), one Li(2), one Li(21), one Li(22), and one Li(7) atom to form FLi6 octahedra that share  a cornercorner with one F(26)Li6 octahedra,  a cornercorner with one F(27)Li6 octahedra, corners with two equivalent F(13)Li5Co octahedra, corners with two equivalent F(16)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(21)Li6 octahedra,  an edgeedge with one F(24)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(15)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twenty-fourth F site, F(24) is bonded to one Li(1), one Li(14), one Li(16), one Li(21), one Li(23), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(25)Li6 octahedra,  a cornercorner with one F(28)Li6 octahedra, corners with two equivalent F(14)Li5Co octahedra, corners with two equivalent F(15)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(22)Li6 octahedra,  an edgeedge with one F(23)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(16)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-fifth F site, F(25) is bonded to one Li(1), one Li(17), one Li(19), one Li(25), one Li(27), and one Li(5) atom to form FLi6 octahedra that share  a cornercorner with one F(21)Li6 octahedra,  a cornercorner with one F(24)Li6 octahedra, corners with two equivalent F(18)Li5Co octahedra, corners with two equivalent F(19)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(17)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-sixth F site, F(26) is bonded to one Li(17), one Li(18), one Li(2), one Li(25), one Li(26), and one Li(6) atom to form FLi6 octahedra that share  a cornercorner with one F(22)Li6 octahedra,  a cornercorner with one F(23)Li6 octahedra, corners with two equivalent F(17)Li5Co octahedra, corners with two equivalent F(20)Li5Co octahedra,  an edgeedge with one O(1)Li4Co2 octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one F(1)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(5)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(9)Li6 octahedra, and edges with two equivalent F(18)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twenty-seventh F site, F(27) is bonded to one Li(19), one Li(20), one Li(27), one Li(28), one Li(3), and one Li(7) atom to form FLi6 octahedra that share  a cornercorner with one F(22)Li6 octahedra,  a cornercorner with one F(23)Li6 octahedra, corners with two equivalent F(17)Li5Co octahedra, corners with two equivalent F(20)Li5Co octahedra,  an edgeedge with one O(3)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(3)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(11)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(25)Li6 octahedra,  an edgeedge with one F(28)Li6 octahedra,  an edgeedge with one F(7)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(19)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-eighth F site, F(28) is bonded to one Li(18), one Li(20), one Li(26), one Li(28), one Li(4), and one Li(8) atom to form FLi6 octahedra that share  a cornercorner with one F(21)Li6 octahedra,  a cornercorner with one F(24)Li6 octahedra, corners with two equivalent F(18)Li5Co octahedra, corners with two equivalent F(19)Li5Co octahedra,  an edgeedge with one O(2)Li4Co2 octahedra,  an edgeedge with one O(4)Li4Co2 octahedra,  an edgeedge with one F(2)Li4Co2 octahedra,  an edgeedge with one F(4)Li4Co2 octahedra,  an edgeedge with one F(10)Li6 octahedra,  an edgeedge with one F(12)Li6 octahedra,  an edgeedge with one F(26)Li6 octahedra,  an edgeedge with one F(27)Li6 octahedra,  an edgeedge with one F(6)Li6 octahedra,  an edgeedge with one F(8)Li6 octahedra, and edges with two equivalent F(20)Li5Co octahedra. The corner-sharing octahedral tilt angles range from 1-7°.