N3S4O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N3S4O2F clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(3), one O(1), one O(2), and one F(1) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. F(1) is bonded in a single-bond geometry to one S(3) atom.
N3S4O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N3S4O2F clusters. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. The N(1)-S(1) bond length is 1.57 Å. The N(1)-S(4) bond length is 1.61 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.60 Å. The N(2)-S(2) bond length is 1.63 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(3)-S(2) bond length is 1.60 Å. The N(3)-S(3) bond length is 1.61 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(3), one O(1), one O(2), and one F(1) atom. The S(3)-O(1) bond length is 1.44 Å. The S(3)-O(2) bond length is 1.43 Å. The S(3)-F(1) bond length is 1.61 Å. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(3) atom. F(1) is bonded in a single-bond geometry to one S(3) atom.