RbZrMnF7 crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(3), four equivalent F(1), and four equivalent F(2) atoms. Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Mn(1)F7 pentagonal bipyramids and edges with two equivalent Mn(1)F7 pentagonal bipyramids. Mn(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. There are four inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the second F site, F(2) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the third F site, F(3) is bonded in a linear geometry to one Rb(1), one Zr(1), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom.
RbZrMnF7 crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent F(3), four equivalent F(1), and four equivalent F(2) atoms. Both Rb(1)-F(3) bond lengths are 3.36 Å. All Rb(1)-F(1) bond lengths are 2.97 Å. All Rb(1)-F(2) bond lengths are 2.98 Å. Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Mn(1)F7 pentagonal bipyramids and edges with two equivalent Mn(1)F7 pentagonal bipyramids. The Zr(1)-F(4) bond length is 2.08 Å. Both Zr(1)-F(1) bond lengths are 2.12 Å. Both Zr(1)-F(2) bond lengths are 2.15 Å. Both Zr(1)-F(3) bond lengths are 2.06 Å. Mn(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. The Mn(1)-F(4) bond length is 2.19 Å. Both Mn(1)-F(1) bond lengths are 2.31 Å. Both Mn(1)-F(2) bond lengths are 2.18 Å. Both Mn(1)-F(3) bond lengths are 2.16 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the second F site, F(2) is bonded to two equivalent Rb(1), one Zr(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing FRb2ZrMn tetrahedra. In the third F site, F(3) is bonded in a linear geometry to one Rb(1), one Zr(1), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom.