ScVO2 crystallizes in the tetragonal I4_1/amd space group. Sc(1) is bonded to six equivalent O(1) atoms to form edge-sharing ScO6 octahedra. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Sc(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OSc3V2 trigonal bipyramids.
ScVO2 crystallizes in the tetragonal I4_1/amd space group. Sc(1) is bonded to six equivalent O(1) atoms to form edge-sharing ScO6 octahedra. All Sc(1)-O(1) bond lengths are 2.20 Å. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 2.16 Å. O(1) is bonded to three equivalent Sc(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OSc3V2 trigonal bipyramids.