Nd2Ni2In crystallizes in the orthorhombic Pbam space group. Nd(1) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. Ni(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1), one Ni(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Nd(1) and four equivalent Ni(1) atoms to form a mixture of corner and face-sharing InNd8Ni4 cuboctahedra.
Nd2Ni2In crystallizes in the orthorhombic Pbam space group. Nd(1) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. There are two shorter (2.92 Å) and four longer (2.97 Å) Nd(1)-Ni(1) bond lengths. There are two shorter (3.35 Å) and two longer (3.42 Å) Nd(1)-In(1) bond lengths. Ni(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1), one Ni(1), and two equivalent In(1) atoms. The Ni(1)-Ni(1) bond length is 2.53 Å. There is one shorter (2.95 Å) and one longer (3.15 Å) Ni(1)-In(1) bond length. In(1) is bonded to eight equivalent Nd(1) and four equivalent Ni(1) atoms to form a mixture of corner and face-sharing InNd8Ni4 cuboctahedra.