CaLa2FeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. O(1) is bonded in a 5-coordinate geometry to one Ca(1), three equivalent La(1), and one Fe(1) atom.
CaLa2FeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. All Ca(1)-O(1) bond lengths are 2.27 Å. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. There are a spread of La(1)-O(1) bond distances ranging from 2.40-3.07 Å. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 30°. All Fe(1)-O(1) bond lengths are 1.93 Å. O(1) is bonded in a 5-coordinate geometry to one Ca(1), three equivalent La(1), and one Fe(1) atom.