K2PdC4(NS)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to two equivalent K(1) and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pd(1), and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(2) atom.
K2PdC4(NS)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. There is one shorter (2.84 Å) and one longer (3.03 Å) K(1)-N(1) bond length. There is one shorter (2.78 Å) and one longer (2.93 Å) K(1)-N(2) bond length. There is one shorter (3.41 Å) and one longer (3.58 Å) K(1)-S(1) bond length. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. Both Pd(1)-S(1) bond lengths are 2.39 Å. Both Pd(1)-S(2) bond lengths are 2.39 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(1)-N(2) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.66 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. The C(2)-N(1) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.65 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to two equivalent K(1) and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pd(1), and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(2) atom.