Co(NH3)6(PF6)2 is Fluorite structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one azane;cobalt molecule and two PF6 clusters. In each PF6 cluster, P(1,2) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one P(1,2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one P(1,2) atom. In the third F site, F(2) is bonded in a single-bond geometry to one P(1,2) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one P(1,2) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one P(1,2) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one P(1,2) atom.
Co(NH3)6(PF6)2 is Fluorite structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one azane;cobalt molecule and two PF6 clusters. In each PF6 cluster, P(1,2) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The P(1,2)-F(1) bond length is 1.64 Å. The P(1,2)-F(2) bond length is 1.63 Å. The P(1,2)-F(3) bond length is 1.65 Å. The P(1,2)-F(4) bond length is 1.64 Å. The P(1,2)-F(5) bond length is 1.64 Å. The P(1,2)-F(6) bond length is 1.63 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one P(1,2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one P(1,2) atom. In the third F site, F(2) is bonded in a single-bond geometry to one P(1,2) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one P(1,2) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one P(1,2) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one P(1,2) atom.