SrCa2N2 crystallizes in the orthorhombic Pmmn space group. Sr(1) is bonded in a distorted bent 120 degrees geometry to four equivalent N(1) atoms. Ca(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing CaN5 square pyramids. N(1) is bonded in a 7-coordinate geometry to two equivalent Sr(1) and five equivalent Ca(1) atoms.
SrCa2N2 crystallizes in the orthorhombic Pmmn space group. Sr(1) is bonded in a distorted bent 120 degrees geometry to four equivalent N(1) atoms. There are two shorter (2.46 Å) and two longer (3.14 Å) Sr(1)-N(1) bond lengths. Ca(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing CaN5 square pyramids. There are a spread of Ca(1)-N(1) bond distances ranging from 2.45-2.79 Å. N(1) is bonded in a 7-coordinate geometry to two equivalent Sr(1) and five equivalent Ca(1) atoms.