V3Cr is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Cr(1) atoms. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to eight equivalent V(1) and six equivalent Cr(1) atoms. Cr(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.
V3Cr is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Cr(1) atoms. All V(1)-V(2) bond lengths are 2.55 Å. All V(1)-Cr(1) bond lengths are 2.55 Å. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to eight equivalent V(1) and six equivalent Cr(1) atoms. All V(2)-Cr(1) bond lengths are 2.94 Å. Cr(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.