RbCdC3(NS)3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one C(2), one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent S(1) atoms. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent S(2), and two equivalent S(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Rb(1), one N(2), and one S(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(2), and one C(3) atom.
RbCdC3(NS)3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one C(2), one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. The Rb(1)-C(2) bond length is 3.59 Å. The Rb(1)-N(1) bond length is 3.02 Å. The Rb(1)-N(2) bond length is 3.36 Å. The Rb(1)-N(3) bond length is 3.22 Å. The Rb(1)-S(2) bond length is 3.71 Å. There is one shorter (3.72 Å) and one longer (3.78 Å) Rb(1)-S(1) bond length. There is one shorter (3.56 Å) and one longer (3.77 Å) Rb(1)-S(3) bond length. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent S(1) atoms. Both Cd(1)-N(1) bond lengths are 2.35 Å. Both Cd(1)-N(3) bond lengths are 2.32 Å. Both Cd(1)-S(1) bond lengths are 2.78 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent S(2), and two equivalent S(3) atoms. Both Cd(2)-N(2) bond lengths are 2.33 Å. Both Cd(2)-S(2) bond lengths are 2.75 Å. Both Cd(2)-S(3) bond lengths are 2.80 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.63 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Rb(1), one N(2), and one S(2) atom. The C(2)-N(2) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.63 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. The C(3)-N(3) bond length is 1.18 Å. The C(3)-S(3) bond length is 1.64 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Rb(1), one Cd(2), and one C(2) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(2), and one C(3) atom.