SrRuO3 crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. Ru(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form a mixture of edge and corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 33°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1) and two equivalent Ru(1) atoms. In the second O site, O(2) is bonded to three equivalent Sr(1) and two equivalent Ru(1) atoms to form a mixture of distorted edge and corner-sharing OSr3Ru2 square pyramids.
SrRuO3 crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. Both Sr(1)-O(1) bond lengths are 2.58 Å. There are two shorter (2.56 Å) and four longer (2.59 Å) Sr(1)-O(2) bond lengths. Ru(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form a mixture of edge and corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 33°. Both Ru(1)-O(1) bond lengths are 1.95 Å. All Ru(1)-O(2) bond lengths are 2.08 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1) and two equivalent Ru(1) atoms. In the second O site, O(2) is bonded to three equivalent Sr(1) and two equivalent Ru(1) atoms to form a mixture of distorted edge and corner-sharing OSr3Ru2 square pyramids.