Ce3Rh4Pb13 crystallizes in the cubic Pm-3n space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Rh(1) and twelve equivalent Pb(2) atoms. Rh(1) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Pb(2) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a 9-coordinate geometry to three equivalent Ce(1), two equivalent Rh(1), one Pb(1), and three equivalent Pb(2) atoms. In the second Pb site, Pb(1) is bonded in a cuboctahedral geometry to twelve equivalent Pb(2) atoms.
Ce3Rh4Pb13 crystallizes in the cubic Pm-3n space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Rh(1) and twelve equivalent Pb(2) atoms. All Ce(1)-Rh(1) bond lengths are 3.61 Å. There are four shorter (3.58 Å) and eight longer (3.59 Å) Ce(1)-Pb(2) bond lengths. Rh(1) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Pb(2) atoms. All Rh(1)-Pb(2) bond lengths are 2.79 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a 9-coordinate geometry to three equivalent Ce(1), two equivalent Rh(1), one Pb(1), and three equivalent Pb(2) atoms. The Pb(2)-Pb(1) bond length is 3.50 Å. There is one shorter (3.14 Å) and two longer (3.41 Å) Pb(2)-Pb(2) bond lengths. In the second Pb site, Pb(1) is bonded in a cuboctahedral geometry to twelve equivalent Pb(2) atoms.