Mo(PbN)3 crystallizes in the monoclinic P2_1/m space group. Mo(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to three equivalent N(2) atoms. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to three equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Pb(1) atoms. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Pb(2) atoms. In the third N site, N(3) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Pb(3) atoms.
Mo(PbN)3 crystallizes in the monoclinic P2_1/m space group. Mo(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The Mo(1)-N(1) bond length is 1.85 Å. The Mo(1)-N(2) bond length is 1.86 Å. The Mo(1)-N(3) bond length is 1.86 Å. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. There is one shorter (2.36 Å) and two longer (2.80 Å) Pb(1)-N(1) bond lengths. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to three equivalent N(2) atoms. There is one shorter (2.36 Å) and two longer (2.79 Å) Pb(2)-N(2) bond lengths. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to three equivalent N(3) atoms. There is one shorter (2.35 Å) and two longer (2.79 Å) Pb(3)-N(3) bond lengths. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Pb(1) atoms. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Pb(2) atoms. In the third N site, N(3) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Pb(3) atoms.