Rb2PdN2(O2Cl)2 crystallizes in the orthorhombic Cmce space group. Rb(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. N(1) is bonded in a trigonal planar geometry to one Pd(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one N(1) atom. Cl(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Pd(1) atom.
Rb2PdN2(O2Cl)2 crystallizes in the orthorhombic Cmce space group. Rb(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. There are a spread of Rb(1)-O(1) bond distances ranging from 3.11-3.37 Å. There are two shorter (3.51 Å) and two longer (3.52 Å) Rb(1)-Cl(1) bond lengths. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Pd(1)-N(1) bond lengths are 2.05 Å. Both Pd(1)-Cl(1) bond lengths are 2.36 Å. N(1) is bonded in a trigonal planar geometry to one Pd(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.25 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one N(1) atom. Cl(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Pd(1) atom.