BaAgSb crystallizes in the hexagonal P6_3/mmc space group. Ba(1) is bonded in a 11-coordinate geometry to six equivalent Ag(1) and five equivalent Sb(1) atoms. Ag(1) is bonded in a distorted body-centered cubic geometry to six equivalent Ba(1) and two equivalent Ag(1) atoms. Sb(1) is bonded to five equivalent Ba(1) atoms to form a mixture of corner and edge-sharing SbBa5 trigonal bipyramids.
BaAgSb crystallizes in the hexagonal P6_3/mmc space group. Ba(1) is bonded in a 11-coordinate geometry to six equivalent Ag(1) and five equivalent Sb(1) atoms. All Ba(1)-Ag(1) bond lengths are 3.75 Å. There are three shorter (3.33 Å) and two longer (3.48 Å) Ba(1)-Sb(1) bond lengths. Ag(1) is bonded in a distorted body-centered cubic geometry to six equivalent Ba(1) and two equivalent Ag(1) atoms. Both Ag(1)-Ag(1) bond lengths are 3.48 Å. Sb(1) is bonded to five equivalent Ba(1) atoms to form a mixture of corner and edge-sharing SbBa5 trigonal bipyramids.