K2CuCl4O2 crystallizes in the tetragonal I4/mmm space group. The structure consists of two hydrogen peroxide molecules inside a K2CuCl4 framework. In the K2CuCl4 framework, K(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Cu(1) atom.
K2CuCl4O2 crystallizes in the tetragonal I4/mmm space group. The structure consists of two hydrogen peroxide molecules inside a K2CuCl4 framework. In the K2CuCl4 framework, K(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. All K(1)-Cl(1) bond lengths are 3.37 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. All Cu(1)-Cl(1) bond lengths are 2.28 Å. Cl(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Cu(1) atom.