TmPdBi is half-Heusler structured and crystallizes in the cubic F-43m space group. Tm(1) is bonded to four equivalent Pd(1) and six equivalent Bi(1) atoms to form a mixture of distorted corner and face-sharing TmBi6Pd4 tetrahedra. Pd(1) is bonded in a body-centered cubic geometry to four equivalent Tm(1) and four equivalent Bi(1) atoms. Bi(1) is bonded in a 10-coordinate geometry to six equivalent Tm(1) and four equivalent Pd(1) atoms.
TmPdBi is half-Heusler structured and crystallizes in the cubic F-43m space group. Tm(1) is bonded to four equivalent Pd(1) and six equivalent Bi(1) atoms to form a mixture of distorted corner and face-sharing TmBi6Pd4 tetrahedra. All Tm(1)-Pd(1) bond lengths are 2.87 Å. All Tm(1)-Bi(1) bond lengths are 3.31 Å. Pd(1) is bonded in a body-centered cubic geometry to four equivalent Tm(1) and four equivalent Bi(1) atoms. All Pd(1)-Bi(1) bond lengths are 2.87 Å. Bi(1) is bonded in a 10-coordinate geometry to six equivalent Tm(1) and four equivalent Pd(1) atoms.