XeRuF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeRuF7 clusters. Xe(1) is bonded in a linear geometry to one F(3) and one F(4) atom. Ru(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Ru(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ru(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a bent 120 degrees geometry to one Xe(1) and one Ru(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Ru(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Ru(1) atom.
XeRuF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeRuF7 clusters. Xe(1) is bonded in a linear geometry to one F(3) and one F(4) atom. The Xe(1)-F(3) bond length is 1.98 Å. The Xe(1)-F(4) bond length is 2.22 Å. Ru(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. The Ru(1)-F(1) bond length is 1.86 Å. The Ru(1)-F(2) bond length is 1.86 Å. The Ru(1)-F(4) bond length is 1.99 Å. The Ru(1)-F(5) bond length is 1.84 Å. The Ru(1)-F(6) bond length is 1.86 Å. The Ru(1)-F(7) bond length is 1.87 Å. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Ru(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Ru(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a bent 120 degrees geometry to one Xe(1) and one Ru(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Ru(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Ru(1) atom.