LiZnSb crystallizes in the hexagonal P6_3mc space group. Li(1) is bonded in a 9-coordinate geometry to three equivalent Zn(1) and six equivalent Sb(1) atoms. Zn(1) is bonded in a 7-coordinate geometry to three equivalent Li(1) and four equivalent Sb(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Li(1) and four equivalent Zn(1) atoms.
LiZnSb crystallizes in the hexagonal P6_3mc space group. Li(1) is bonded in a 9-coordinate geometry to three equivalent Zn(1) and six equivalent Sb(1) atoms. All Li(1)-Zn(1) bond lengths are 2.81 Å. There are three shorter (2.99 Å) and three longer (3.26 Å) Li(1)-Sb(1) bond lengths. Zn(1) is bonded in a 7-coordinate geometry to three equivalent Li(1) and four equivalent Sb(1) atoms. There are three shorter (2.69 Å) and one longer (2.74 Å) Zn(1)-Sb(1) bond length. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Li(1) and four equivalent Zn(1) atoms.