VOSO4 crystallizes in the tetragonal P4/n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms.
VOSO4 crystallizes in the tetragonal P4/n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There is one shorter (1.62 Å) and one longer (2.35 Å) V(1)-O(2) bond length. All V(1)-O(1) bond lengths are 2.00 Å. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All S(1)-O(1) bond lengths are 1.47 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms.