SrAg2(O2I)4 crystallizes in the tetragonal I422 space group. Sr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to one Sr(1), one Ag(1), and two equivalent I(1) atoms to form a mixture of distorted corner and edge-sharing OSrAgI2 tetrahedra. I(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms.
SrAg2(O2I)4 crystallizes in the tetragonal I422 space group. Sr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Sr(1)-O(1) bond lengths are 2.64 Å. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Ag(1)-O(1) bond lengths are 2.38 Å. O(1) is bonded to one Sr(1), one Ag(1), and two equivalent I(1) atoms to form a mixture of distorted corner and edge-sharing OSrAgI2 tetrahedra. There is one shorter (2.01 Å) and one longer (2.40 Å) O(1)-I(1) bond length. I(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms.