LaHoO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing HoO6 octahedra. The corner-sharing octahedral tilt angles range from 39-43°. La(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ho(1) and two equivalent La(1) atoms to form distorted corner-sharing OLa2Ho2 trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ho(1) and three equivalent La(1) atoms.
LaHoO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing HoO6 octahedra. The corner-sharing octahedral tilt angles range from 39-43°. Both Ho(1)-O(1) bond lengths are 2.30 Å. There are two shorter (2.24 Å) and two longer (2.25 Å) Ho(1)-O(2) bond lengths. La(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. There is one shorter (2.36 Å) and one longer (2.57 Å) La(1)-O(1) bond length. There are a spread of La(1)-O(2) bond distances ranging from 2.38-3.17 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ho(1) and two equivalent La(1) atoms to form distorted corner-sharing OLa2Ho2 trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ho(1) and three equivalent La(1) atoms.