MnPtN2 crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing MnN4 tetrahedra. Pt(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Mn(1) and two equivalent Pt(1) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Pt(1) atoms to form distorted corner-sharing NMn2Pt2 tetrahedra.
MnPtN2 crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing MnN4 tetrahedra. There is one shorter (1.83 Å) and one longer (1.84 Å) Mn(1)-N(1) bond length. There is one shorter (1.82 Å) and one longer (1.84 Å) Mn(1)-N(2) bond length. Pt(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. There is one shorter (2.07 Å) and one longer (2.20 Å) Pt(1)-N(1) bond length. There is one shorter (2.09 Å) and one longer (2.16 Å) Pt(1)-N(2) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Mn(1) and two equivalent Pt(1) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Pt(1) atoms to form distorted corner-sharing NMn2Pt2 tetrahedra.