CsVSO6 crystallizes in the orthorhombic Pbca space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), two equivalent O(6), and three equivalent O(5) atoms. V(1) is bonded to one O(1), one O(4), one O(6), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. S(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to two equivalent Cs(1) and one V(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the fifth O site, O(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom.
CsVSO6 crystallizes in the orthorhombic Pbca space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), two equivalent O(6), and three equivalent O(5) atoms. The Cs(1)-O(1) bond length is 3.37 Å. The Cs(1)-O(2) bond length is 3.27 Å. The Cs(1)-O(4) bond length is 3.32 Å. There is one shorter (3.26 Å) and one longer (3.64 Å) Cs(1)-O(3) bond length. There is one shorter (3.45 Å) and one longer (3.53 Å) Cs(1)-O(6) bond length. There are a spread of Cs(1)-O(5) bond distances ranging from 3.21-3.59 Å. V(1) is bonded to one O(1), one O(4), one O(6), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent V(1)O5 trigonal bipyramids. The V(1)-O(1) bond length is 1.98 Å. The V(1)-O(4) bond length is 1.99 Å. The V(1)-O(6) bond length is 1.62 Å. There is one shorter (1.82 Å) and one longer (1.85 Å) V(1)-O(2) bond length. S(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids. The S(1)-O(1) bond length is 1.54 Å. The S(1)-O(3) bond length is 1.45 Å. The S(1)-O(4) bond length is 1.54 Å. The S(1)-O(5) bond length is 1.46 Å. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(6) is bonded in a single-bond geometry to two equivalent Cs(1) and one V(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1) and two equivalent V(1) atoms. In the fifth O site, O(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one S(1) atom.