DyVO2 crystallizes in the tetragonal I4_1/amd space group. Dy(1) is bonded to six equivalent O(1) atoms to form edge-sharing DyO6 octahedra. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Dy(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing ODy3V2 trigonal bipyramids.
DyVO2 crystallizes in the tetragonal I4_1/amd space group. Dy(1) is bonded to six equivalent O(1) atoms to form edge-sharing DyO6 octahedra. All Dy(1)-O(1) bond lengths are 2.33 Å. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 2.20 Å. O(1) is bonded to three equivalent Dy(1) and two equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing ODy3V2 trigonal bipyramids.