LiH4(NO2)3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four LiH4(NO2)3 clusters. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent N(2) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one N(1), one O(1), and one O(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(2) atom.
LiH4(NO2)3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four LiH4(NO2)3 clusters. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Li(1)-O(1) bond lengths are 2.06 Å. Both Li(1)-O(2) bond lengths are 1.97 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent N(2) atoms. Both N(1)-N(2) bond lengths are 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one N(1), one O(1), and one O(3) atom. The N(2)-O(1) bond length is 1.24 Å. The N(2)-O(3) bond length is 1.26 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.98 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(2) atom.