CuN4SO5 is gamma nitrogen structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuN4SO5 clusters. Cu(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1), one O(2), and one O(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one N(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Cu(1) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one S(1) atom.
CuN4SO5 is gamma nitrogen structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuN4SO5 clusters. Cu(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1), one O(2), and one O(4) atom. Both Cu(1)-N(1) bond lengths are 2.20 Å. The Cu(1)-O(2) bond length is 1.85 Å. The Cu(1)-O(4) bond length is 1.74 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one N(2) atom. The N(1)-N(2) bond length is 1.11 Å. In the second N site, N(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. The S(1)-O(2) bond length is 1.54 Å. The S(1)-O(3) bond length is 1.47 Å. Both S(1)-O(1) bond lengths are 1.47 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Cu(1) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one S(1) atom.