SBSCs crystallizes in the orthorhombic Immm space group. Cs(1) is bonded in a 9-coordinate geometry to four equivalent S(2) and five equivalent S(1) atoms. B(1) is bonded in a distorted trigonal planar geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to five equivalent Cs(1) and one B(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to four equivalent Cs(1) and two equivalent B(1) atoms.
SBSCs crystallizes in the orthorhombic Immm space group. Cs(1) is bonded in a 9-coordinate geometry to four equivalent S(2) and five equivalent S(1) atoms. All Cs(1)-S(2) bond lengths are 3.79 Å. There is one shorter (3.47 Å) and four longer (3.87 Å) Cs(1)-S(1) bond lengths. B(1) is bonded in a distorted trigonal planar geometry to one S(1) and two equivalent S(2) atoms. The B(1)-S(1) bond length is 1.73 Å. Both B(1)-S(2) bond lengths are 1.86 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to five equivalent Cs(1) and one B(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to four equivalent Cs(1) and two equivalent B(1) atoms.