CCl3F is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight trichlorofluoromethane molecules. C(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one F(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(1) atom.
CCl3F is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight trichlorofluoromethane molecules. C(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one F(1) atom. The C(1)-Cl(1) bond length is 1.76 Å. The C(1)-Cl(2) bond length is 1.76 Å. The C(1)-Cl(3) bond length is 1.76 Å. The C(1)-F(1) bond length is 1.36 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(1) atom.