CsRe2OsSe4Cl3 crystallizes in the monoclinic Cc space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one Se(3), one Se(4), one Se(5), one Se(6), one Se(7), and one Se(8) atom. There are four inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(3), one Se(4), one Se(7), and one Cl(2) atom. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(4), one Se(5), one Se(6), and one Cl(3) atom. In the third Re site, Re(3) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(5), one Se(6), one Se(8), and one Cl(4) atom. In the fourth Re site, Re(4) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(3), one Se(7), one Se(8), and one Cl(6) atom. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(1), one Se(3), one Se(5), one Se(8), and one Cl(1) atom. In the second Os site, Os(2) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(2), one Se(4), one Se(6), one Se(7), and one Cl(5) atom. There are eight inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Os(1) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(3), one Re(4), and one Os(2) atom. In the third Se site, Se(3) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(1) atom. In the fourth Se site, Se(4) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(2), and one Os(2) atom. In the fifth Se site, Se(5) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(1) atom. In the sixth Se site, Se(6) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(2) atom. In the seventh Se site, Se(7) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(2) atom. In the eighth Se site, Se(8) is bonded in a 4-coordinate geometry to one Cs(2), one Re(3), one Re(4), and one Os(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(4) atom.
CsRe2OsSe4Cl3 crystallizes in the monoclinic Cc space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. The Cs(1)-Cl(1) bond length is 3.82 Å. The Cs(1)-Cl(2) bond length is 3.84 Å. The Cs(1)-Cl(3) bond length is 3.83 Å. The Cs(1)-Cl(4) bond length is 3.83 Å. The Cs(1)-Cl(5) bond length is 3.84 Å. The Cs(1)-Cl(6) bond length is 3.81 Å. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one Se(3), one Se(4), one Se(5), one Se(6), one Se(7), and one Se(8) atom. The Cs(2)-Se(3) bond length is 3.98 Å. The Cs(2)-Se(4) bond length is 3.97 Å. The Cs(2)-Se(5) bond length is 4.01 Å. The Cs(2)-Se(6) bond length is 4.00 Å. The Cs(2)-Se(7) bond length is 3.97 Å. The Cs(2)-Se(8) bond length is 3.98 Å. There are four inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(3), one Se(4), one Se(7), and one Cl(2) atom. The Re(1)-Os(1) bond length is 2.65 Å. The Re(1)-Os(2) bond length is 2.65 Å. The Re(1)-Se(1) bond length is 2.54 Å. The Re(1)-Se(3) bond length is 2.54 Å. The Re(1)-Se(4) bond length is 2.54 Å. The Re(1)-Se(7) bond length is 2.55 Å. The Re(1)-Cl(2) bond length is 2.41 Å. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(1), one Se(4), one Se(5), one Se(6), and one Cl(3) atom. The Re(2)-Os(1) bond length is 2.65 Å. The Re(2)-Os(2) bond length is 2.66 Å. The Re(2)-Se(1) bond length is 2.54 Å. The Re(2)-Se(4) bond length is 2.54 Å. The Re(2)-Se(5) bond length is 2.54 Å. The Re(2)-Se(6) bond length is 2.55 Å. The Re(2)-Cl(3) bond length is 2.41 Å. In the third Re site, Re(3) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(5), one Se(6), one Se(8), and one Cl(4) atom. The Re(3)-Os(1) bond length is 2.66 Å. The Re(3)-Os(2) bond length is 2.65 Å. The Re(3)-Se(2) bond length is 2.54 Å. The Re(3)-Se(5) bond length is 2.55 Å. The Re(3)-Se(6) bond length is 2.54 Å. The Re(3)-Se(8) bond length is 2.54 Å. The Re(3)-Cl(4) bond length is 2.41 Å. In the fourth Re site, Re(4) is bonded in a 5-coordinate geometry to one Os(1), one Os(2), one Se(2), one Se(3), one Se(7), one Se(8), and one Cl(6) atom. The Re(4)-Os(1) bond length is 2.65 Å. The Re(4)-Os(2) bond length is 2.65 Å. The Re(4)-Se(2) bond length is 2.54 Å. The Re(4)-Se(3) bond length is 2.55 Å. The Re(4)-Se(7) bond length is 2.54 Å. The Re(4)-Se(8) bond length is 2.54 Å. The Re(4)-Cl(6) bond length is 2.41 Å. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(1), one Se(3), one Se(5), one Se(8), and one Cl(1) atom. The Os(1)-Se(1) bond length is 2.52 Å. The Os(1)-Se(3) bond length is 2.51 Å. The Os(1)-Se(5) bond length is 2.51 Å. The Os(1)-Se(8) bond length is 2.53 Å. The Os(1)-Cl(1) bond length is 2.41 Å. In the second Os site, Os(2) is bonded in a 9-coordinate geometry to one Re(1), one Re(2), one Re(3), one Re(4), one Se(2), one Se(4), one Se(6), one Se(7), and one Cl(5) atom. The Os(2)-Se(2) bond length is 2.52 Å. The Os(2)-Se(4) bond length is 2.53 Å. The Os(2)-Se(6) bond length is 2.51 Å. The Os(2)-Se(7) bond length is 2.51 Å. The Os(2)-Cl(5) bond length is 2.41 Å. There are eight inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Os(1) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(3), one Re(4), and one Os(2) atom. In the third Se site, Se(3) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(1) atom. In the fourth Se site, Se(4) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(2), and one Os(2) atom. In the fifth Se site, Se(5) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(1) atom. In the sixth Se site, Se(6) is bonded in a 4-coordinate geometry to one Cs(2), one Re(2), one Re(3), and one Os(2) atom. In the seventh Se site, Se(7) is bonded in a 4-coordinate geometry to one Cs(2), one Re(1), one Re(4), and one Os(2) atom. In the eighth Se site, Se(8) is bonded in a 4-coordinate geometry to one Cs(2), one Re(3), one Re(4), and one Os(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a distorted single-bond geometry to one Cs(1) and one Os(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(4) atom.