Ag2O5I crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), and two equivalent O(5) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one I(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one I(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one I(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one I(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and two equivalent I(1) atoms. I(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form edge-sharing IO6 octahedra.
Ag2O5I crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), and two equivalent O(5) atoms. The Ag(1)-O(1) bond length is 2.42 Å. The Ag(1)-O(2) bond length is 2.27 Å. The Ag(1)-O(3) bond length is 2.26 Å. There is one shorter (2.21 Å) and one longer (2.73 Å) Ag(1)-O(4) bond length. There is one shorter (2.66 Å) and one longer (2.77 Å) Ag(1)-O(5) bond length. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Ag(2)-O(1) bond length is 2.57 Å. The Ag(2)-O(2) bond length is 2.23 Å. The Ag(2)-O(3) bond length is 2.40 Å. The Ag(2)-O(4) bond length is 2.36 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one I(1) atom. The O(1)-I(1) bond length is 1.84 Å. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one I(1) atom. The O(2)-I(1) bond length is 1.89 Å. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one I(1) atom. The O(3)-I(1) bond length is 1.90 Å. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one I(1) atom. The O(4)-I(1) bond length is 1.93 Å. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and two equivalent I(1) atoms. There is one shorter (2.03 Å) and one longer (2.14 Å) O(5)-I(1) bond length. I(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form edge-sharing IO6 octahedra.