Ag6GeSO8 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Ge(1) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one S(1) atom. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Ge(1) atom to form corner-sharing OAg3Ge tetrahedra.
Ag6GeSO8 crystallizes in the tetragonal I4_1/amd space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ag(1)-O(1) bond lengths are 2.60 Å. Both Ag(1)-O(2) bond lengths are 2.21 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ag(2)-O(1) bond lengths are 2.59 Å. Both Ag(2)-O(2) bond lengths are 2.44 Å. Ge(1) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. All Ge(1)-O(2) bond lengths are 1.79 Å. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All S(1)-O(1) bond lengths are 1.50 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2), two equivalent Ag(1), and one S(1) atom. In the second O site, O(2) is bonded to one Ag(2), two equivalent Ag(1), and one Ge(1) atom to form corner-sharing OAg3Ge tetrahedra.