PbClBr crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 7-coordinate geometry to three equivalent Br(1) and four equivalent Cl(1) atoms. Br(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Pb(1) atoms. Cl(1) is bonded to four equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing ClPb4 tetrahedra.
PbClBr crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 7-coordinate geometry to three equivalent Br(1) and four equivalent Cl(1) atoms. There is one shorter (3.02 Å) and two longer (3.23 Å) Pb(1)-Br(1) bond lengths. There are a spread of Pb(1)-Cl(1) bond distances ranging from 2.91-3.21 Å. Br(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Pb(1) atoms. Cl(1) is bonded to four equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing ClPb4 tetrahedra.