IrCl6(RuN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two IrCl6 clusters, and four RuN3Cl2 clusters. In each IrCl6 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(1,5) is bonded in a single-bond geometry to one Ir(1) atom. In each RuN3Cl2 cluster, Ru(1) is bonded in a tetrahedral geometry to one N(3), two equivalent N(1), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Cl(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one N(3) atom.
IrCl6(RuN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two IrCl6 clusters, and four RuN3Cl2 clusters. In each IrCl6 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,5) atoms. Both Ir(1)-Cl(4) bond lengths are 2.33 Å. All Ir(1)-Cl(1,5) bond lengths are 2.29 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(1,5) is bonded in a single-bond geometry to one Ir(1) atom. In each RuN3Cl2 cluster, Ru(1) is bonded in a tetrahedral geometry to one N(3), two equivalent N(1), and one Cl(2) atom. The Ru(1)-N(3) bond length is 1.90 Å. Both Ru(1)-N(1) bond lengths are 1.70 Å. The Ru(1)-Cl(2) bond length is 2.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Cl(3) atom. The N(3)-Cl(3) bond length is 1.60 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one N(3) atom.