TiSi2 is Modderite-like structured and crystallizes in the orthorhombic Fddd space group. Ti(1) is bonded in a 6-coordinate geometry to six equivalent Si(1) atoms. Si(1) is bonded in a 6-coordinate geometry to three equivalent Ti(1) and three equivalent Si(1) atoms.
TiSi2 is Modderite-like structured and crystallizes in the orthorhombic Fddd space group. Ti(1) is bonded in a 6-coordinate geometry to six equivalent Si(1) atoms. There are two shorter (2.60 Å) and four longer (2.61 Å) Ti(1)-Si(1) bond lengths. Si(1) is bonded in a 6-coordinate geometry to three equivalent Ti(1) and three equivalent Si(1) atoms. There is one shorter (2.59 Å) and two longer (2.61 Å) Si(1)-Si(1) bond lengths.