CeAuCd crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 11-coordinate geometry to one Au(1), four equivalent Au(2), two equivalent Cd(2), and four equivalent Cd(1) atoms. In the second Ce site, Ce(2) is bonded in a 11-coordinate geometry to one Au(1), four equivalent Au(2), two equivalent Cd(2), and four equivalent Cd(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 9-coordinate geometry to one Ce(2), two equivalent Ce(1), two equivalent Cd(2), and four equivalent Cd(1) atoms. In the second Au site, Au(2) is bonded in a 9-coordinate geometry to two equivalent Ce(2), four equivalent Ce(1), one Cd(2), and two equivalent Cd(1) atoms. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 4-coordinate geometry to two equivalent Ce(2), four equivalent Ce(1), two equivalent Au(1), and two equivalent Au(2) atoms. In the second Cd site, Cd(2) is bonded in a 4-coordinate geometry to two equivalent Ce(2), four equivalent Ce(1), two equivalent Au(1), and two equivalent Au(2) atoms.
CeAuCd crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 11-coordinate geometry to one Au(1), four equivalent Au(2), two equivalent Cd(2), and four equivalent Cd(1) atoms. The Ce(1)-Au(1) bond length is 3.22 Å. All Ce(1)-Au(2) bond lengths are 3.15 Å. Both Ce(1)-Cd(2) bond lengths are 3.48 Å. There are two shorter (3.38 Å) and two longer (3.49 Å) Ce(1)-Cd(1) bond lengths. In the second Ce site, Ce(2) is bonded in a 11-coordinate geometry to one Au(1), four equivalent Au(2), two equivalent Cd(2), and four equivalent Cd(1) atoms. The Ce(2)-Au(1) bond length is 3.22 Å. All Ce(2)-Au(2) bond lengths are 3.16 Å. Both Ce(2)-Cd(2) bond lengths are 3.38 Å. All Ce(2)-Cd(1) bond lengths are 3.48 Å. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 9-coordinate geometry to one Ce(2), two equivalent Ce(1), two equivalent Cd(2), and four equivalent Cd(1) atoms. Both Au(1)-Cd(2) bond lengths are 2.86 Å. All Au(1)-Cd(1) bond lengths are 2.86 Å. In the second Au site, Au(2) is bonded in a 9-coordinate geometry to two equivalent Ce(2), four equivalent Ce(1), one Cd(2), and two equivalent Cd(1) atoms. The Au(2)-Cd(2) bond length is 3.01 Å. Both Au(2)-Cd(1) bond lengths are 3.00 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 4-coordinate geometry to two equivalent Ce(2), four equivalent Ce(1), two equivalent Au(1), and two equivalent Au(2) atoms. In the second Cd site, Cd(2) is bonded in a 4-coordinate geometry to two equivalent Ce(2), four equivalent Ce(1), two equivalent Au(1), and two equivalent Au(2) atoms.