WZn2SnO6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-64°. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-92°. Sn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted SnO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-64°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Zn(1), and one Sn(1) atom. In the third O site, O(3) is bonded to one W(1), two equivalent Zn(1), and one Sn(1) atom to form distorted corner-sharing OZn2SnW trigonal pyramids.
WZn2SnO6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-64°. Both W(1)-O(1) bond lengths are 1.92 Å. Both W(1)-O(2) bond lengths are 1.94 Å. Both W(1)-O(3) bond lengths are 2.05 Å. Zn(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-92°. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(2) bond length is 2.01 Å. There is one shorter (2.03 Å) and one longer (2.09 Å) Zn(1)-O(3) bond length. Sn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted SnO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-64°. Both Sn(1)-O(1) bond lengths are 2.65 Å. Both Sn(1)-O(2) bond lengths are 2.36 Å. Both Sn(1)-O(3) bond lengths are 2.58 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Zn(1), and one Sn(1) atom. In the third O site, O(3) is bonded to one W(1), two equivalent Zn(1), and one Sn(1) atom to form distorted corner-sharing OZn2SnW trigonal pyramids.