N5S4F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four N5S4F clusters. In two of the N5S4F clusters, there are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one N(4), and one N(5) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one F(1) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one N(2), one N(3), and one N(5) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. F(1) is bonded in a single-bond geometry to one S(2) atom. In two of the N5S4F clusters, there are five inequivalent N sites. In the first N site, N(9) is bonded in a bent 120 degrees geometry to one S(5) and one S(8) atom. In the second N site, N(10) is bonded in a bent 120 degrees geometry to one S(5) and one S(7) atom. In the third N site, N(6) is bonded in a bent 120 degrees geometry to one S(5) and one S(6) atom. In the fourth N site, N(7) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. In the fifth N site, N(8) is bonded in a bent 120 degrees geometry to one S(7) and one S(8) atom. There are four inequivalent S sites. In the first S site, S(5) is bonded in a trigonal non-coplanar geometry to one N(10), one N(6), and one N(9) atom. In the second S site, S(6) is bonded in a trigonal non-coplanar geometry to one N(6), one N(7), and one F(2) atom. In the third S site, S(7) is bonded in a trigonal non-coplanar geometry to one N(10), one N(7), and one N(8) atom. In the fourth S site, S(8) is bonded in a bent 120 degrees geometry to one N(8) and one N(9) atom. F(2) is bonded in a single-bond geometry to one S(6) atom.
N5S4F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four N5S4F clusters. In two of the N5S4F clusters, there are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.65 Å. The N(1)-S(2) bond length is 1.60 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(2)-S(2) bond length is 1.59 Å. The N(2)-S(3) bond length is 1.65 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. The N(3)-S(3) bond length is 1.73 Å. The N(3)-S(4) bond length is 1.56 Å. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. The N(4)-S(1) bond length is 1.72 Å. The N(4)-S(4) bond length is 1.56 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. The N(5)-S(1) bond length is 1.63 Å. The N(5)-S(3) bond length is 1.64 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one N(4), and one N(5) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one F(1) atom. The S(2)-F(1) bond length is 1.73 Å. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one N(2), one N(3), and one N(5) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. F(1) is bonded in a single-bond geometry to one S(2) atom. In two of the N5S4F clusters, there are five inequivalent N sites. In the first N site, N(9) is bonded in a bent 120 degrees geometry to one S(5) and one S(8) atom. The N(9)-S(5) bond length is 1.73 Å. The N(9)-S(8) bond length is 1.56 Å. In the second N site, N(10) is bonded in a bent 120 degrees geometry to one S(5) and one S(7) atom. The N(10)-S(5) bond length is 1.64 Å. The N(10)-S(7) bond length is 1.64 Å. In the third N site, N(6) is bonded in a bent 120 degrees geometry to one S(5) and one S(6) atom. The N(6)-S(5) bond length is 1.64 Å. The N(6)-S(6) bond length is 1.60 Å. In the fourth N site, N(7) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. The N(7)-S(6) bond length is 1.60 Å. The N(7)-S(7) bond length is 1.64 Å. In the fifth N site, N(8) is bonded in a bent 120 degrees geometry to one S(7) and one S(8) atom. The N(8)-S(7) bond length is 1.74 Å. The N(8)-S(8) bond length is 1.56 Å. There are four inequivalent S sites. In the first S site, S(5) is bonded in a trigonal non-coplanar geometry to one N(10), one N(6), and one N(9) atom. In the second S site, S(6) is bonded in a trigonal non-coplanar geometry to one N(6), one N(7), and one F(2) atom. The S(6)-F(2) bond length is 1.70 Å. In the third S site, S(7) is bonded in a trigonal non-coplanar geometry to one N(10), one N(7), and one N(8) atom. In the fourth S site, S(8) is bonded in a bent 120 degrees geometry to one N(8) and one N(9) atom. F(2) is bonded in a single-bond geometry to one S(6) atom.