TiCu2N3 crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form corner-sharing TiN6 octahedra. The corner-sharing octahedra are not tilted. Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a square co-planar geometry to two equivalent Ti(1) and two equivalent Cu(1) atoms. In the second N site, N(2) is bonded to two equivalent Ti(1) and four equivalent Cu(1) atoms to form corner-sharing NTi2Cu4 octahedra. The corner-sharing octahedra are not tilted.
TiCu2N3 crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form corner-sharing TiN6 octahedra. The corner-sharing octahedra are not tilted. Both Ti(1)-N(2) bond lengths are 2.02 Å. All Ti(1)-N(1) bond lengths are 2.06 Å. Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 2.02 Å. Both Cu(1)-N(2) bond lengths are 2.06 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a square co-planar geometry to two equivalent Ti(1) and two equivalent Cu(1) atoms. In the second N site, N(2) is bonded to two equivalent Ti(1) and four equivalent Cu(1) atoms to form corner-sharing NTi2Cu4 octahedra. The corner-sharing octahedra are not tilted.