Zr(O4Cl)4 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four Zr(O4Cl)4 clusters. Zr(1) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(14), one O(15), one O(5), and one O(6) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zr(1) and one Cl(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(10) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zr(1) and one Cl(4) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Zr(1) and one Cl(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Cl(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cl(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cl(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one O(16) and one O(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cl(1) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Zr(1) and one Cl(4) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cl(2) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Zr(1) and one Cl(3) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Zr(1) and one O(16) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one O(10), one O(15), and one Cl(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a trigonal non-coplanar geometry to one O(11), one O(16), and one O(7) atom. In the second Cl site, Cl(2) is bonded in a trigonal non-coplanar geometry to one O(13), one O(6), and one O(9) atom. In the third Cl site, Cl(3) is bonded in a tetrahedral geometry to one O(1), one O(14), one O(3), and one O(8) atom. In the fourth Cl site, Cl(4) is bonded in a trigonal non-coplanar geometry to one O(12), one O(2), and one O(5) atom.
Zr(O4Cl)4 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four Zr(O4Cl)4 clusters. Zr(1) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(14), one O(15), one O(5), and one O(6) atom. The Zr(1)-O(1) bond length is 2.46 Å. The Zr(1)-O(12) bond length is 2.22 Å. The Zr(1)-O(14) bond length is 2.18 Å. The Zr(1)-O(15) bond length is 1.90 Å. The Zr(1)-O(5) bond length is 2.29 Å. The Zr(1)-O(6) bond length is 2.01 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zr(1) and one Cl(3) atom. The O(1)-Cl(3) bond length is 1.49 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(4) atom. The O(2)-Cl(4) bond length is 1.45 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Cl(3) atom. The O(3)-Cl(3) bond length is 1.43 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(10) atom. The O(4)-O(10) bond length is 1.21 Å. In the fifth O site, O(5) is bonded in a water-like geometry to one Zr(1) and one Cl(4) atom. The O(5)-Cl(4) bond length is 1.55 Å. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Zr(1) and one Cl(2) atom. The O(6)-Cl(2) bond length is 1.70 Å. In the seventh O site, O(7) is bonded in a single-bond geometry to one Cl(1) atom. The O(7)-Cl(1) bond length is 1.45 Å. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cl(3) atom. The O(8)-Cl(3) bond length is 1.42 Å. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cl(2) atom. The O(9)-Cl(2) bond length is 1.45 Å. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one O(16) and one O(4) atom. The O(10)-O(16) bond length is 1.86 Å. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cl(1) atom. The O(11)-Cl(1) bond length is 1.45 Å. In the twelfth O site, O(12) is bonded in a water-like geometry to one Zr(1) and one Cl(4) atom. The O(12)-Cl(4) bond length is 1.57 Å. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cl(2) atom. The O(13)-Cl(2) bond length is 1.46 Å. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Zr(1) and one Cl(3) atom. The O(14)-Cl(3) bond length is 1.56 Å. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Zr(1) and one O(16) atom. The O(15)-O(16) bond length is 1.99 Å. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one O(10), one O(15), and one Cl(1) atom. The O(16)-Cl(1) bond length is 1.91 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a trigonal non-coplanar geometry to one O(11), one O(16), and one O(7) atom. In the second Cl site, Cl(2) is bonded in a trigonal non-coplanar geometry to one O(13), one O(6), and one O(9) atom. In the third Cl site, Cl(3) is bonded in a tetrahedral geometry to one O(1), one O(14), one O(3), and one O(8) atom. In the fourth Cl site, Cl(4) is bonded in a trigonal non-coplanar geometry to one O(12), one O(2), and one O(5) atom.