AcAg3 crystallizes in the orthorhombic Cmcm space group. Ac(1) is bonded in a 12-coordinate geometry to four equivalent Ag(2) and eight equivalent Ag(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 10-coordinate geometry to four equivalent Ac(1), three equivalent Ag(1), and three equivalent Ag(2) atoms. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to four equivalent Ac(1) and six equivalent Ag(1) atoms.
AcAg3 crystallizes in the orthorhombic Cmcm space group. Ac(1) is bonded in a 12-coordinate geometry to four equivalent Ag(2) and eight equivalent Ag(1) atoms. There are two shorter (3.35 Å) and two longer (3.50 Å) Ac(1)-Ag(2) bond lengths. There are four shorter (3.35 Å) and four longer (3.52 Å) Ac(1)-Ag(1) bond lengths. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 10-coordinate geometry to four equivalent Ac(1), three equivalent Ag(1), and three equivalent Ag(2) atoms. There are two shorter (2.90 Å) and one longer (2.91 Å) Ag(1)-Ag(1) bond length. There is one shorter (2.90 Å) and two longer (2.91 Å) Ag(1)-Ag(2) bond lengths. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to four equivalent Ac(1) and six equivalent Ag(1) atoms.