Li4AuS4 crystallizes in the orthorhombic Fddd space group. Li(1) is bonded in a 3-coordinate geometry to three equivalent S(1) atoms. Au(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 3-coordinate geometry to three equivalent Li(1) and one Au(1) atom.
Li4AuS4 crystallizes in the orthorhombic Fddd space group. Li(1) is bonded in a 3-coordinate geometry to three equivalent S(1) atoms. There are two shorter (2.35 Å) and one longer (2.36 Å) Li(1)-S(1) bond length. Au(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All Au(1)-S(1) bond lengths are 2.54 Å. S(1) is bonded in a 3-coordinate geometry to three equivalent Li(1) and one Au(1) atom.