NaP3(PbO3)4 crystallizes in the hexagonal P6_3 space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(4) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Na(1), one Pb(1), one Pb(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Na(1), one Pb(1), one Pb(2), and one P(1) atom.
NaP3(PbO3)4 crystallizes in the hexagonal P6_3 space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(4) atoms. All Na(1)-O(3) bond lengths are 2.70 Å. All Na(1)-O(4) bond lengths are 2.50 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms. The Pb(1)-O(3) bond length is 2.30 Å. The Pb(1)-O(4) bond length is 2.84 Å. There is one shorter (2.57 Å) and one longer (2.62 Å) Pb(1)-O(1) bond length. There is one shorter (2.55 Å) and one longer (2.60 Å) Pb(1)-O(2) bond length. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(4) atoms. All Pb(2)-O(3) bond lengths are 2.78 Å. All Pb(2)-O(4) bond lengths are 2.51 Å. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The P(1)-O(1) bond length is 1.57 Å. The P(1)-O(2) bond length is 1.56 Å. The P(1)-O(3) bond length is 1.57 Å. The P(1)-O(4) bond length is 1.55 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Na(1), one Pb(1), one Pb(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Na(1), one Pb(1), one Pb(2), and one P(1) atom.