LiAg4(RuO3)4 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to two equivalent Ag(1) and two equivalent Ag(2) atoms to form LiAg4 tetrahedra that share  an edgeedge with one O(3)Ag2Ru2 tetrahedra,  an edgeedge with one O(4)Ag2Ru2 tetrahedra, and edges with four equivalent O(1)Ag2Ru2 tetrahedra. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form RuO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra, corners with four equivalent Ru(2)O6 octahedra, edges with two equivalent Ag(1)LiO6 hexagonal pyramids, and edges with four equivalent Ag(2)LiO6 hexagonal pyramids. The corner-sharing octahedral tilt angles range from 43-45°. In the second Ru site, Ru(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form RuO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra, corners with four equivalent Ru(1)O6 octahedra, edges with two equivalent Ag(2)LiO6 hexagonal pyramids, and edges with four equivalent Ag(1)LiO6 hexagonal pyramids. The corner-sharing octahedral tilt angles range from 43-45°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one Li(1), one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form distorted AgLiO6 hexagonal pyramids that share  a cornercorner with one Ag(1)LiO6 hexagonal pyramid, corners with two equivalent Ag(2)LiO6 hexagonal pyramids,  an edgeedge with one Ag(1)LiO6 hexagonal pyramid, edges with two equivalent Ag(2)LiO6 hexagonal pyramids, edges with two equivalent Ru(1)O6 octahedra, and edges with four equivalent Ru(2)O6 octahedra. In the second Ag site, Ag(2) is bonded to one Li(1), one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form distorted AgLiO6 hexagonal pyramids that share  a cornercorner with one Ag(2)LiO6 hexagonal pyramid, corners with two equivalent Ag(1)LiO6 hexagonal pyramids,  an edgeedge with one Ag(2)LiO6 hexagonal pyramid, edges with two equivalent Ag(1)LiO6 hexagonal pyramids, edges with two equivalent Ru(2)O6 octahedra, and edges with four equivalent Ru(1)O6 octahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom to form distorted OAg2Ru2 tetrahedra that share corners with two equivalent O(3)Ag2Ru2 tetrahedra, corners with two equivalent O(4)Ag2Ru2 tetrahedra, corners with four equivalent O(1)Ag2Ru2 tetrahedra, and  an edgeedge with one Li(1)Ag4 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom. In the third O site, O(3) is bonded to two equivalent Ru(1) and two equivalent Ag(2) atoms to form distorted OAg2Ru2 tetrahedra that share corners with eight equivalent O(1)Ag2Ru2 tetrahedra and  an edgeedge with one Li(1)Ag4 tetrahedra. In the fourth O site, O(4) is bonded to two equivalent Ru(2) and two equivalent Ag(1) atoms to form distorted OAg2Ru2 tetrahedra that share corners with eight equivalent O(1)Ag2Ru2 tetrahedra and  an edgeedge with one Li(1)Ag4 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ru(2) and two equivalent Ag(1) atoms. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ru(1) and two equivalent Ag(2) atoms.
LiAg4(RuO3)4 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to two equivalent Ag(1) and two equivalent Ag(2) atoms to form LiAg4 tetrahedra that share  an edgeedge with one O(3)Ag2Ru2 tetrahedra,  an edgeedge with one O(4)Ag2Ru2 tetrahedra, and edges with four equivalent O(1)Ag2Ru2 tetrahedra. Both Li(1)-Ag(1) bond lengths are 2.68 Å. Both Li(1)-Ag(2) bond lengths are 2.69 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form RuO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra, corners with four equivalent Ru(2)O6 octahedra, edges with two equivalent Ag(1)LiO6 hexagonal pyramids, and edges with four equivalent Ag(2)LiO6 hexagonal pyramids. The corner-sharing octahedral tilt angles range from 43-45°. The Ru(1)-O(3) bond length is 1.96 Å. The Ru(1)-O(6) bond length is 1.95 Å. Both Ru(1)-O(1) bond lengths are 1.96 Å. Both Ru(1)-O(2) bond lengths are 1.95 Å. In the second Ru site, Ru(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form RuO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra, corners with four equivalent Ru(1)O6 octahedra, edges with two equivalent Ag(2)LiO6 hexagonal pyramids, and edges with four equivalent Ag(1)LiO6 hexagonal pyramids. The corner-sharing octahedral tilt angles range from 43-45°. The Ru(2)-O(4) bond length is 1.96 Å. The Ru(2)-O(5) bond length is 1.95 Å. Both Ru(2)-O(1) bond lengths are 1.96 Å. Both Ru(2)-O(2) bond lengths are 1.95 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one Li(1), one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form distorted AgLiO6 hexagonal pyramids that share  a cornercorner with one Ag(1)LiO6 hexagonal pyramid, corners with two equivalent Ag(2)LiO6 hexagonal pyramids,  an edgeedge with one Ag(1)LiO6 hexagonal pyramid, edges with two equivalent Ag(2)LiO6 hexagonal pyramids, edges with two equivalent Ru(1)O6 octahedra, and edges with four equivalent Ru(2)O6 octahedra. The Ag(1)-O(4) bond length is 2.68 Å. The Ag(1)-O(5) bond length is 2.56 Å. Both Ag(1)-O(1) bond lengths are 2.69 Å. Both Ag(1)-O(2) bond lengths are 2.54 Å. In the second Ag site, Ag(2) is bonded to one Li(1), one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form distorted AgLiO6 hexagonal pyramids that share  a cornercorner with one Ag(2)LiO6 hexagonal pyramid, corners with two equivalent Ag(1)LiO6 hexagonal pyramids,  an edgeedge with one Ag(2)LiO6 hexagonal pyramid, edges with two equivalent Ag(1)LiO6 hexagonal pyramids, edges with two equivalent Ru(2)O6 octahedra, and edges with four equivalent Ru(1)O6 octahedra. The Ag(2)-O(3) bond length is 2.68 Å. The Ag(2)-O(6) bond length is 2.54 Å. Both Ag(2)-O(1) bond lengths are 2.67 Å. Both Ag(2)-O(2) bond lengths are 2.55 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom to form distorted OAg2Ru2 tetrahedra that share corners with two equivalent O(3)Ag2Ru2 tetrahedra, corners with two equivalent O(4)Ag2Ru2 tetrahedra, corners with four equivalent O(1)Ag2Ru2 tetrahedra, and  an edgeedge with one Li(1)Ag4 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom. In the third O site, O(3) is bonded to two equivalent Ru(1) and two equivalent Ag(2) atoms to form distorted OAg2Ru2 tetrahedra that share corners with eight equivalent O(1)Ag2Ru2 tetrahedra and  an edgeedge with one Li(1)Ag4 tetrahedra. In the fourth O site, O(4) is bonded to two equivalent Ru(2) and two equivalent Ag(1) atoms to form distorted OAg2Ru2 tetrahedra that share corners with eight equivalent O(1)Ag2Ru2 tetrahedra and  an edgeedge with one Li(1)Ag4 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ru(2) and two equivalent Ag(1) atoms. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ru(1) and two equivalent Ag(2) atoms.