MnCo3C is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Mn(1) is bonded to twelve equivalent Co(1) atoms to form MnCo12 cuboctahedra that share corners with twelve equivalent Mn(1)Co12 cuboctahedra, faces with six equivalent Mn(1)Co12 cuboctahedra, and faces with eight equivalent C(1)Co6 octahedra. Co(1) is bonded in a linear geometry to four equivalent Mn(1) and two equivalent C(1) atoms. C(1) is bonded to six equivalent Co(1) atoms to form CCo6 octahedra that share corners with six equivalent C(1)Co6 octahedra and faces with eight equivalent Mn(1)Co12 cuboctahedra. The corner-sharing octahedra are not tilted.
MnCo3C is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Mn(1) is bonded to twelve equivalent Co(1) atoms to form MnCo12 cuboctahedra that share corners with twelve equivalent Mn(1)Co12 cuboctahedra, faces with six equivalent Mn(1)Co12 cuboctahedra, and faces with eight equivalent C(1)Co6 octahedra. All Mn(1)-Co(1) bond lengths are 2.65 Å. Co(1) is bonded in a linear geometry to four equivalent Mn(1) and two equivalent C(1) atoms. Both Co(1)-C(1) bond lengths are 1.88 Å. C(1) is bonded to six equivalent Co(1) atoms to form CCo6 octahedra that share corners with six equivalent C(1)Co6 octahedra and faces with eight equivalent Mn(1)Co12 cuboctahedra. The corner-sharing octahedra are not tilted.