In3AsF6 crystallizes in the triclinic P-1 space group. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second In site, In(2) is bonded in a linear geometry to two equivalent F(3) atoms. In the third In site, In(3) is bonded in a distorted linear geometry to two equivalent F(1) atoms. As(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one In(1) and one As(1) atom. In the third F site, F(3) is bonded in a distorted L-shaped geometry to one In(2) and one As(1) atom.
In3AsF6 crystallizes in the triclinic P-1 space group. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 4-coordinate geometry to two equivalent F(1) and two equivalent F(2) atoms. Both In(1)-F(1) bond lengths are 2.72 Å. Both In(1)-F(2) bond lengths are 2.73 Å. In the second In site, In(2) is bonded in a linear geometry to two equivalent F(3) atoms. Both In(2)-F(3) bond lengths are 2.64 Å. In the third In site, In(3) is bonded in a distorted linear geometry to two equivalent F(1) atoms. Both In(3)-F(1) bond lengths are 2.68 Å. As(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both As(1)-F(1) bond lengths are 2.09 Å. Both As(1)-F(2) bond lengths are 2.11 Å. Both As(1)-F(3) bond lengths are 2.06 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one In(1) and one As(1) atom. In the third F site, F(3) is bonded in a distorted L-shaped geometry to one In(2) and one As(1) atom.