V3Mn is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Mn(1) atoms. In the second V site, V(2) is bonded in a 14-coordinate geometry to eight equivalent V(1) and six equivalent Mn(1) atoms. Mn(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.
V3Mn is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Mn(1) atoms. All V(1)-V(2) bond lengths are 2.52 Å. All V(1)-Mn(1) bond lengths are 2.52 Å. In the second V site, V(2) is bonded in a 14-coordinate geometry to eight equivalent V(1) and six equivalent Mn(1) atoms. All V(2)-Mn(1) bond lengths are 2.91 Å. Mn(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.