V2H is Calaverite-like structured and crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a 3-coordinate geometry to three equivalent H(1) atoms. H(1) is bonded to six equivalent V(1) atoms to form edge-sharing HV6 octahedra.
V2H is Calaverite-like structured and crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a 3-coordinate geometry to three equivalent H(1) atoms. There is one shorter (1.79 Å) and two longer (2.06 Å) V(1)-H(1) bond lengths. H(1) is bonded to six equivalent V(1) atoms to form edge-sharing HV6 octahedra.