(K)2KBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a KBiBr6 framework. In the KBiBr6 framework, K(2) is bonded to six equivalent Br(1) atoms to form KBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent K(2)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one K(2) and one Bi(1) atom.
(K)2KBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a KBiBr6 framework. In the KBiBr6 framework, K(2) is bonded to six equivalent Br(1) atoms to form KBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All K(2)-Br(1) bond lengths are 3.13 Å. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent K(2)Br6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-Br(1) bond lengths are 2.86 Å. Br(1) is bonded in a linear geometry to one K(2) and one Bi(1) atom.