Li(CrS2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded to four equivalent S(1) atoms to form LiS4 tetrahedra that share corners with twelve equivalent Cr(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. Cr(1) is bonded to six equivalent S(1) atoms to form CrS6 octahedra that share corners with six equivalent Li(1)S4 tetrahedra and edges with six equivalent Cr(1)S6 octahedra. S(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Cr(1) atoms.
Li(CrS2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded to four equivalent S(1) atoms to form LiS4 tetrahedra that share corners with twelve equivalent Cr(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. All Li(1)-S(1) bond lengths are 2.36 Å. Cr(1) is bonded to six equivalent S(1) atoms to form CrS6 octahedra that share corners with six equivalent Li(1)S4 tetrahedra and edges with six equivalent Cr(1)S6 octahedra. There are four shorter (2.39 Å) and two longer (2.41 Å) Cr(1)-S(1) bond lengths. S(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Cr(1) atoms.