Cs(MnP)2 crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. Mn(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing MnP4 tetrahedra. P(1) is bonded in a 4-coordinate geometry to four equivalent Cs(1) and four equivalent Mn(1) atoms.
Cs(MnP)2 crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. All Cs(1)-P(1) bond lengths are 3.79 Å. Mn(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing MnP4 tetrahedra. All Mn(1)-P(1) bond lengths are 2.36 Å. P(1) is bonded in a 4-coordinate geometry to four equivalent Cs(1) and four equivalent Mn(1) atoms.