Zr2N is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Zr(1) is bonded in a distorted T-shaped geometry to three equivalent N(1) atoms. N(1) is bonded to six equivalent Zr(1) atoms to form a mixture of corner and edge-sharing NZr6 octahedra. The corner-sharing octahedral tilt angles are 47°.
Zr2N is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Zr(1) is bonded in a distorted T-shaped geometry to three equivalent N(1) atoms. All Zr(1)-N(1) bond lengths are 2.27 Å. N(1) is bonded to six equivalent Zr(1) atoms to form a mixture of corner and edge-sharing NZr6 octahedra. The corner-sharing octahedral tilt angles are 47°.