LiInO2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded to six O(1,1,1) atoms to form LiO6 octahedra that share corners with two equivalent In(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with eight equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In(1) is bonded to six O(1,1,1,1) atoms to form InO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, edges with four equivalent In(1)O6 octahedra, and edges with eight equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are five inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fourth O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fifth O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°.
LiInO2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded to six O(1,1,1) atoms to form LiO6 octahedra that share corners with two equivalent In(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with eight equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are four shorter (2.17 Å) and two longer (2.46 Å) Li(1)-O(1,1,1) bond lengths. In(1) is bonded to six O(1,1,1,1) atoms to form InO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, edges with four equivalent In(1)O6 octahedra, and edges with eight equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are four shorter (2.17 Å) and two longer (2.18 Å) In(1)-O(1,1,1,1) bond lengths. There are five inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are two shorter (2.17 Å) and one longer (2.46 Å) O(1)-Li(1) bond length. In the fourth O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fifth O site, O(1) is bonded to three equivalent Li(1) and three equivalent In(1) atoms to form a mixture of edge and corner-sharing OLi3In3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are two shorter (2.17 Å) and one longer (2.46 Å) O(1)-Li(1) bond length. There are two shorter (2.17 Å) and one longer (2.18 Å) O(1)-In(1) bond length.