AuAgS2 crystallizes in the orthorhombic Pccm space group. Au(1) is bonded in a linear geometry to two equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded to one Au(1), two equivalent Ag(1), and one S(1) atom to form a mixture of corner and edge-sharing SAg2AuS tetrahedra.
AuAgS2 crystallizes in the orthorhombic Pccm space group. Au(1) is bonded in a linear geometry to two equivalent S(1) atoms. Both Au(1)-S(1) bond lengths are 2.28 Å. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All Ag(1)-S(1) bond lengths are 2.58 Å. S(1) is bonded to one Au(1), two equivalent Ag(1), and one S(1) atom to form a mixture of corner and edge-sharing SAg2AuS tetrahedra. The S(1)-S(1) bond length is 2.11 Å.