K(RhP)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. Rh(1) is bonded to four equivalent P(1) atoms to form a mixture of corner and edge-sharing RhP4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Rh(1) atoms.
K(RhP)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. All K(1)-P(1) bond lengths are 3.42 Å. Rh(1) is bonded to four equivalent P(1) atoms to form a mixture of corner and edge-sharing RhP4 tetrahedra. All Rh(1)-P(1) bond lengths are 2.33 Å. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Rh(1) atoms.