SbF6HFSF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrofluoric acid molecules, four SF3 clusters, and four SbF6 clusters. In each SF3 cluster, S(1) is bonded in a distorted T-shaped geometry to one F(7) and two equivalent F(8,9) atoms. There are two inequivalent F sites. In the first F site, F(8,9) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.
SbF6HFSF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrofluoric acid molecules, four SF3 clusters, and four SbF6 clusters. In each SF3 cluster, S(1) is bonded in a distorted T-shaped geometry to one F(7) and two equivalent F(8,9) atoms. The S(1)-F(7) bond length is 1.54 Å. There is one shorter (1.54 Å) and one longer (1.55 Å) S(1)-F(8,9) bond length. There are two inequivalent F sites. In the first F site, F(8,9) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Sb(1)-F(1) bond length is 1.94 Å. The Sb(1)-F(2) bond length is 1.90 Å. The Sb(1)-F(3) bond length is 1.90 Å. The Sb(1)-F(4) bond length is 1.90 Å. The Sb(1)-F(5) bond length is 1.95 Å. The Sb(1)-F(6) bond length is 1.94 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.