PbOBr crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and five equivalent Br(1) atoms. O(1) is bonded in a trigonal non-coplanar geometry to three equivalent Pb(1) atoms. Br(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms.
PbOBr crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and five equivalent Br(1) atoms. All Pb(1)-O(1) bond lengths are 2.26 Å. There are a spread of Pb(1)-Br(1) bond distances ranging from 3.10-3.38 Å. O(1) is bonded in a trigonal non-coplanar geometry to three equivalent Pb(1) atoms. Br(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms.