WCrZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one W(1), one Cr(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to one W(1), one Cr(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one W(1), one Cr(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(1), and one Zn(2) atom.
WCrZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. The W(1)-O(1) bond length is 2.01 Å. The W(1)-O(2) bond length is 2.04 Å. The W(1)-O(3) bond length is 2.04 Å. The W(1)-O(4) bond length is 1.98 Å. The W(1)-O(5) bond length is 2.02 Å. The W(1)-O(6) bond length is 2.01 Å. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. The Cr(1)-O(1) bond length is 2.04 Å. The Cr(1)-O(2) bond length is 2.03 Å. The Cr(1)-O(3) bond length is 2.04 Å. The Cr(1)-O(4) bond length is 2.03 Å. The Cr(1)-O(5) bond length is 2.03 Å. The Cr(1)-O(6) bond length is 2.03 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(2)-O(1) bond length is 2.50 Å. The Zn(2)-O(2) bond length is 2.43 Å. The Zn(2)-O(3) bond length is 2.49 Å. The Zn(2)-O(4) bond length is 2.00 Å. The Zn(2)-O(5) bond length is 1.97 Å. The Zn(2)-O(6) bond length is 1.97 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one W(1), one Cr(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to one W(1), one Cr(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one W(1), one Cr(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(1), and one Zn(2) atom.