ZrPd3F6 crystallizes in the triclinic P-1 space group. Zr(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Pd site, Pd(2) is bonded in a linear geometry to two equivalent F(3) atoms. In the third Pd site, Pd(3) is bonded in a linear geometry to two equivalent F(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Zr(1) and one Pd(3) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Zr(1) and one Pd(2) atom.
ZrPd3F6 crystallizes in the triclinic P-1 space group. Zr(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Zr(1)-F(1) bond lengths are 2.07 Å. Both Zr(1)-F(2) bond lengths are 2.04 Å. Both Zr(1)-F(3) bond lengths are 2.06 Å. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a linear geometry to two equivalent F(2) atoms. Both Pd(1)-F(2) bond lengths are 2.10 Å. In the second Pd site, Pd(2) is bonded in a linear geometry to two equivalent F(3) atoms. Both Pd(2)-F(3) bond lengths are 2.11 Å. In the third Pd site, Pd(3) is bonded in a linear geometry to two equivalent F(1) atoms. Both Pd(3)-F(1) bond lengths are 2.12 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Zr(1) and one Pd(3) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Zr(1) and one Pd(2) atom.