KZnAs crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded to six equivalent Zn(1) and six equivalent As(1) atoms to form a mixture of face and edge-sharing KZn6As6 cuboctahedra. Zn(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent As(1) atoms. As(1) is bonded in a distorted trigonal planar geometry to six equivalent K(1) and three equivalent Zn(1) atoms.
KZnAs crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded to six equivalent Zn(1) and six equivalent As(1) atoms to form a mixture of face and edge-sharing KZn6As6 cuboctahedra. All K(1)-Zn(1) bond lengths are 3.53 Å. All K(1)-As(1) bond lengths are 3.53 Å. Zn(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent As(1) atoms. All Zn(1)-As(1) bond lengths are 2.43 Å. As(1) is bonded in a distorted trigonal planar geometry to six equivalent K(1) and three equivalent Zn(1) atoms.