ThPS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Th(1) is bonded in a 9-coordinate geometry to four equivalent P(1) and five equivalent S(1) atoms. P(1) is bonded in a 4-coordinate geometry to four equivalent Th(1) atoms. S(1) is bonded to five equivalent Th(1) atoms to form a mixture of distorted corner and edge-sharing STh5 trigonal bipyramids.
ThPS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Th(1) is bonded in a 9-coordinate geometry to four equivalent P(1) and five equivalent S(1) atoms. All Th(1)-P(1) bond lengths are 2.94 Å. There are four shorter (2.94 Å) and one longer (3.01 Å) Th(1)-S(1) bond length. P(1) is bonded in a 4-coordinate geometry to four equivalent Th(1) atoms. S(1) is bonded to five equivalent Th(1) atoms to form a mixture of distorted corner and edge-sharing STh5 trigonal bipyramids.