Mg(TiS2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mg(1) is bonded to four equivalent S(1) atoms to form MgS4 tetrahedra that share corners with twelve equivalent Ti(1)S6 octahedra. The corner-sharing octahedral tilt angles are 58°. Ti(1) is bonded to six equivalent S(1) atoms to form TiS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra and edges with six equivalent Ti(1)S6 octahedra. S(1) is bonded to one Mg(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing SMgTi3 trigonal pyramids.
Mg(TiS2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mg(1) is bonded to four equivalent S(1) atoms to form MgS4 tetrahedra that share corners with twelve equivalent Ti(1)S6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Mg(1)-S(1) bond lengths are 2.41 Å. Ti(1) is bonded to six equivalent S(1) atoms to form TiS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra and edges with six equivalent Ti(1)S6 octahedra. All Ti(1)-S(1) bond lengths are 2.50 Å. S(1) is bonded to one Mg(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing SMgTi3 trigonal pyramids.