Ti3N2 is Corundum structured and crystallizes in the trigonal R-3c space group. Ti(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent N(1) atoms. N(1) is bonded to six equivalent Ti(1) atoms to form a mixture of edge, corner, and face-sharing NTi6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°.
Ti3N2 is Corundum structured and crystallizes in the trigonal R-3c space group. Ti(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent N(1) atoms. There are two shorter (2.07 Å) and two longer (2.13 Å) Ti(1)-N(1) bond lengths. N(1) is bonded to six equivalent Ti(1) atoms to form a mixture of edge, corner, and face-sharing NTi6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°.