Rb2Mn(TeS3)2 crystallizes in the trigonal P-3c1 space group. Rb(1) is bonded in a 7-coordinate geometry to one Te(1) and six equivalent S(1) atoms. Mn(1) is bonded in an octahedral geometry to six equivalent S(1) atoms. Te(1) is bonded in a 3-coordinate geometry to one Rb(1) and three equivalent S(1) atoms. S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Mn(1), and one Te(1) atom.
Rb2Mn(TeS3)2 crystallizes in the trigonal P-3c1 space group. Rb(1) is bonded in a 7-coordinate geometry to one Te(1) and six equivalent S(1) atoms. The Rb(1)-Te(1) bond length is 3.76 Å. There are three shorter (3.47 Å) and three longer (3.61 Å) Rb(1)-S(1) bond lengths. Mn(1) is bonded in an octahedral geometry to six equivalent S(1) atoms. All Mn(1)-S(1) bond lengths are 2.61 Å. Te(1) is bonded in a 3-coordinate geometry to one Rb(1) and three equivalent S(1) atoms. All Te(1)-S(1) bond lengths are 2.38 Å. S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Mn(1), and one Te(1) atom.