Ag10Si4O13 crystallizes in the triclinic P-1 space group. There are ten inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(12), one O(3), one O(7), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 1-coordinate geometry to one O(10), one O(2), and one O(4) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(11), one O(3), one O(4), and one O(7) atom. In the fourth Ag site, Ag(4) is bonded in a distorted single-bond geometry to one O(13) atom. In the fifth Ag site, Ag(5) is bonded in a 2-coordinate geometry to one O(6) and one O(7) atom. In the sixth Ag site, Ag(6) is bonded in a 2-coordinate geometry to one O(2), one O(4), and one O(6) atom. In the seventh Ag site, Ag(7) is bonded in a 3-coordinate geometry to one O(10), one O(3), and one O(8) atom. In the eighth Ag site, Ag(8) is bonded in a 2-coordinate geometry to one O(3) and one O(9) atom. In the ninth Ag site, Ag(9) is bonded in a distorted single-bond geometry to one O(2), one O(4), and one O(7) atom. In the tenth Ag site, Ag(10) is bonded in a 2-coordinate geometry to one O(1) and one O(9) atom. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 4-coordinate geometry to one O(5), one O(6), one O(8), and one O(9) atom. In the second Si site, Si(2) is bonded in a 4-coordinate geometry to one O(1), one O(13), one O(4), and one O(5) atom. In the third Si site, Si(3) is bonded in a 4-coordinate geometry to one O(11), one O(2), one O(3), and one O(8) atom. In the fourth Si site, Si(4) is bonded in a 3-coordinate geometry to one O(10), one O(12), one O(13), and one O(7) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ag(10) and one Si(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ag(2), one Ag(6), one Ag(9), and one Si(3) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(3), one Ag(7), one Ag(8), and one Si(3) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ag(2), one Ag(3), one Ag(6), one Ag(9), and one Si(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Si(1) and one Si(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Ag(5), one Ag(6), and one Si(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(3), one Ag(5), one Ag(9), and one Si(4) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Ag(7), one Si(1), and one Si(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(10), one Ag(8), and one Si(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Ag(2), one Ag(7), and one Si(4) atom. In the eleventh O site, O(11) is bonded in a distorted L-shaped geometry to one Ag(3) and one Si(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Ag(1) and one Si(4) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Ag(4), one Si(2), and one Si(4) atom.
Ag10Si4O13 crystallizes in the triclinic P-1 space group. There are ten inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(12), one O(3), one O(7), and one O(9) atom. The Ag(1)-O(12) bond length is 2.43 Å. The Ag(1)-O(3) bond length is 2.13 Å. The Ag(1)-O(7) bond length is 2.46 Å. The Ag(1)-O(9) bond length is 2.41 Å. In the second Ag site, Ag(2) is bonded in a 1-coordinate geometry to one O(10), one O(2), and one O(4) atom. The Ag(2)-O(10) bond length is 1.99 Å. The Ag(2)-O(2) bond length is 2.46 Å. The Ag(2)-O(4) bond length is 2.74 Å. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(11), one O(3), one O(4), and one O(7) atom. The Ag(3)-O(11) bond length is 1.83 Å. The Ag(3)-O(3) bond length is 2.55 Å. The Ag(3)-O(4) bond length is 2.15 Å. The Ag(3)-O(7) bond length is 2.15 Å. In the fourth Ag site, Ag(4) is bonded in a distorted single-bond geometry to one O(13) atom. The Ag(4)-O(13) bond length is 2.44 Å. In the fifth Ag site, Ag(5) is bonded in a 2-coordinate geometry to one O(6) and one O(7) atom. The Ag(5)-O(6) bond length is 2.16 Å. The Ag(5)-O(7) bond length is 2.15 Å. In the sixth Ag site, Ag(6) is bonded in a 2-coordinate geometry to one O(2), one O(4), and one O(6) atom. The Ag(6)-O(2) bond length is 2.36 Å. The Ag(6)-O(4) bond length is 2.76 Å. The Ag(6)-O(6) bond length is 2.13 Å. In the seventh Ag site, Ag(7) is bonded in a 3-coordinate geometry to one O(10), one O(3), and one O(8) atom. The Ag(7)-O(10) bond length is 2.76 Å. The Ag(7)-O(3) bond length is 2.61 Å. The Ag(7)-O(8) bond length is 2.36 Å. In the eighth Ag site, Ag(8) is bonded in a 2-coordinate geometry to one O(3) and one O(9) atom. The Ag(8)-O(3) bond length is 2.30 Å. The Ag(8)-O(9) bond length is 2.55 Å. In the ninth Ag site, Ag(9) is bonded in a distorted single-bond geometry to one O(2), one O(4), and one O(7) atom. The Ag(9)-O(2) bond length is 2.71 Å. The Ag(9)-O(4) bond length is 2.19 Å. The Ag(9)-O(7) bond length is 2.75 Å. In the tenth Ag site, Ag(10) is bonded in a 2-coordinate geometry to one O(1) and one O(9) atom. The Ag(10)-O(1) bond length is 1.95 Å. The Ag(10)-O(9) bond length is 2.34 Å. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 4-coordinate geometry to one O(5), one O(6), one O(8), and one O(9) atom. The Si(1)-O(5) bond length is 1.75 Å. The Si(1)-O(6) bond length is 1.58 Å. The Si(1)-O(8) bond length is 1.68 Å. The Si(1)-O(9) bond length is 2.38 Å. In the second Si site, Si(2) is bonded in a 4-coordinate geometry to one O(1), one O(13), one O(4), and one O(5) atom. The Si(2)-O(1) bond length is 2.04 Å. The Si(2)-O(13) bond length is 1.74 Å. The Si(2)-O(4) bond length is 2.09 Å. The Si(2)-O(5) bond length is 1.61 Å. In the third Si site, Si(3) is bonded in a 4-coordinate geometry to one O(11), one O(2), one O(3), and one O(8) atom. The Si(3)-O(11) bond length is 1.71 Å. The Si(3)-O(2) bond length is 2.10 Å. The Si(3)-O(3) bond length is 1.99 Å. The Si(3)-O(8) bond length is 1.65 Å. In the fourth Si site, Si(4) is bonded in a 3-coordinate geometry to one O(10), one O(12), one O(13), and one O(7) atom. The Si(4)-O(10) bond length is 1.78 Å. The Si(4)-O(12) bond length is 1.37 Å. The Si(4)-O(13) bond length is 1.64 Å. The Si(4)-O(7) bond length is 2.50 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ag(10) and one Si(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Ag(2), one Ag(6), one Ag(9), and one Si(3) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(3), one Ag(7), one Ag(8), and one Si(3) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ag(2), one Ag(3), one Ag(6), one Ag(9), and one Si(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Si(1) and one Si(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Ag(5), one Ag(6), and one Si(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(3), one Ag(5), one Ag(9), and one Si(4) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Ag(7), one Si(1), and one Si(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(10), one Ag(8), and one Si(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Ag(2), one Ag(7), and one Si(4) atom. In the eleventh O site, O(11) is bonded in a distorted L-shaped geometry to one Ag(3) and one Si(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Ag(1) and one Si(4) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Ag(4), one Si(2), and one Si(4) atom.