LiRuPbO3 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 3-coordinate geometry to one Pb(1), one O(1), and two equivalent O(2) atoms. Ru(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 1°. Pb(1) is bonded in a 4-coordinate geometry to one Li(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ru(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ru(1), and one Pb(1) atom.
LiRuPbO3 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 3-coordinate geometry to one Pb(1), one O(1), and two equivalent O(2) atoms. The Li(1)-Pb(1) bond length is 2.67 Å. The Li(1)-O(1) bond length is 1.94 Å. Both Li(1)-O(2) bond lengths are 1.94 Å. Ru(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 1°. There is one shorter (2.12 Å) and one longer (2.13 Å) Ru(1)-O(1) bond length. There are two shorter (2.11 Å) and two longer (2.13 Å) Ru(1)-O(2) bond lengths. Pb(1) is bonded in a 4-coordinate geometry to one Li(1), one O(1), and two equivalent O(2) atoms. The Pb(1)-O(1) bond length is 2.36 Å. Both Pb(1)-O(2) bond lengths are 2.37 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ru(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ru(1), and one Pb(1) atom.