ZrPb3F10 crystallizes in the orthorhombic Cmcm space group. Zr(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), and four equivalent F(4) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. In the second Pb site, Pb(2) is bonded in a body-centered cubic geometry to four equivalent F(3) and four equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to one Zr(1) and one Pb(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Zr(1) and two equivalent Pb(1) atoms. In the third F site, F(3) is bonded to two equivalent Pb(1) and two equivalent Pb(2) atoms to form a mixture of corner and edge-sharing FPb4 tetrahedra. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Zr(1), one Pb(1), and one Pb(2) atom.
ZrPb3F10 crystallizes in the orthorhombic Cmcm space group. Zr(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), and four equivalent F(4) atoms. Both Zr(1)-F(1) bond lengths are 2.12 Å. Both Zr(1)-F(2) bond lengths are 2.05 Å. All Zr(1)-F(4) bond lengths are 2.15 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. The Pb(1)-F(1) bond length is 2.55 Å. Both Pb(1)-F(2) bond lengths are 2.58 Å. Both Pb(1)-F(3) bond lengths are 2.56 Å. Both Pb(1)-F(4) bond lengths are 2.63 Å. In the second Pb site, Pb(2) is bonded in a body-centered cubic geometry to four equivalent F(3) and four equivalent F(4) atoms. All Pb(2)-F(3) bond lengths are 2.51 Å. All Pb(2)-F(4) bond lengths are 2.60 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to one Zr(1) and one Pb(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Zr(1) and two equivalent Pb(1) atoms. In the third F site, F(3) is bonded to two equivalent Pb(1) and two equivalent Pb(2) atoms to form a mixture of corner and edge-sharing FPb4 tetrahedra. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Zr(1), one Pb(1), and one Pb(2) atom.