Cs5Bi(MoO4)4 crystallizes in the triclinic P1 space group. There are ten inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(20), one O(27), one O(28), one O(32), one O(4), one O(5), and one O(9) atom. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(18), one O(19), one O(2), one O(30), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(16), one O(18), one O(19), one O(21), one O(22), and one O(24) atom. In the fourth Cs site, Cs(4) is bonded in a 9-coordinate geometry to one O(11), one O(15), one O(28), one O(29), one O(30), one O(5), one O(6), one O(7), and one O(8) atom. In the fifth Cs site, Cs(5) is bonded in a 8-coordinate geometry to one O(14), one O(15), one O(16), one O(18), one O(2), one O(23), one O(30), and one O(9) atom. In the sixth Cs site, Cs(6) is bonded in a 10-coordinate geometry to one O(12), one O(14), one O(16), one O(17), one O(19), one O(21), one O(22), one O(24), one O(26), and one O(3) atom. In the seventh Cs site, Cs(7) is bonded in a 8-coordinate geometry to one O(14), one O(16), one O(19), one O(2), one O(21), one O(23), one O(24), and one O(26) atom. In the eighth Cs site, Cs(8) is bonded in a 2-coordinate geometry to one O(26) and one O(3) atom. In the ninth Cs site, Cs(9) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(15), one O(18), one O(2), one O(23), one O(30), one O(4), one O(8), and one O(9) atom. In the tenth Cs site, Cs(10) is bonded in a 9-coordinate geometry to one O(10), one O(17), one O(22), one O(24), one O(25), one O(27), one O(32), one O(5), and one O(7) atom. There are eight inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(14), one O(18), one O(25), and one O(26) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the second Mo site, Mo(2) is bonded to one O(11), one O(24), one O(3), and one O(5) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the third Mo site, Mo(3) is bonded to one O(10), one O(30), one O(4), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(13), one O(16), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the fifth Mo site, Mo(5) is bonded to one O(17), one O(21), one O(27), and one O(28) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. In the sixth Mo site, Mo(6) is bonded to one O(29), one O(32), one O(8), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-60°. In the seventh Mo site, Mo(7) is bonded to one O(12), one O(2), one O(22), and one O(31) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the eighth Mo site, Mo(8) is bonded to one O(15), one O(19), one O(20), and one O(23) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(10), one O(20), one O(28), one O(29), one O(5), and one O(6) atom to form BiO6 octahedra that share  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(8)O4 tetrahedra. In the second Bi site, Bi(2) is bonded to one O(11), one O(25), one O(27), one O(31), one O(32), and one O(7) atom to form BiO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(7)O4 tetrahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(9), and one Mo(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(5), one Cs(7), one Cs(9), and one Mo(7) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Cs(6), one Cs(8), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(9), and one Mo(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Cs(4), one Mo(2), and one Bi(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(4), one Mo(4), and one Bi(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Cs(10), one Cs(4), one Mo(3), and one Bi(2) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Cs(4), one Cs(9), and one Mo(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(5), one Cs(9), and one Mo(6) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(3), and one Bi(1) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Cs(4), one Mo(2), and one Bi(2) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(6), and one Mo(7) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(9), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Cs(5), one Cs(6), one Cs(7), and one Mo(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(4), one Cs(5), one Cs(9), and one Mo(8) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(5), one Cs(6), one Cs(7), and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(6), and one Mo(5) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(5), one Cs(9), and one Mo(1) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(7), and one Mo(8) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Mo(8), and one Bi(1) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(6), one Cs(7), and one Mo(5) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), and one Mo(7) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one Cs(5), one Cs(7), one Cs(9), and one Mo(8) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), one Cs(7), and one Mo(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one Cs(10), one Mo(1), and one Bi(2) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(6), one Cs(7), one Cs(8), and one Mo(1) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(5), and one Bi(2) atom. In the twenty-eighth O site, O(28) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(4), one Mo(5), and one Bi(1) atom. In the twenty-ninth O site, O(29) is bonded in a 2-coordinate geometry to one Cs(4), one Mo(6), and one Bi(1) atom. In the thirtieth O site, O(30) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(4), one Cs(5), one Cs(9), and one Mo(3) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 150 degrees geometry to one Mo(7) and one Bi(2) atom. In the thirty-second O site, O(32) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Mo(6), and one Bi(2) atom.
Cs5Bi(MoO4)4 crystallizes in the triclinic P1 space group. There are ten inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(20), one O(27), one O(28), one O(32), one O(4), one O(5), and one O(9) atom. The Cs(1)-O(10) bond length is 3.41 Å. The Cs(1)-O(13) bond length is 3.07 Å. The Cs(1)-O(20) bond length is 3.51 Å. The Cs(1)-O(27) bond length is 3.56 Å. The Cs(1)-O(28) bond length is 3.38 Å. The Cs(1)-O(32) bond length is 3.67 Å. The Cs(1)-O(4) bond length is 2.89 Å. The Cs(1)-O(5) bond length is 3.32 Å. The Cs(1)-O(9) bond length is 3.35 Å. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(18), one O(19), one O(2), one O(30), and one O(9) atom. The Cs(2)-O(1) bond length is 2.97 Å. The Cs(2)-O(12) bond length is 3.17 Å. The Cs(2)-O(13) bond length is 3.16 Å. The Cs(2)-O(18) bond length is 3.48 Å. The Cs(2)-O(19) bond length is 3.19 Å. The Cs(2)-O(2) bond length is 3.29 Å. The Cs(2)-O(30) bond length is 3.41 Å. The Cs(2)-O(9) bond length is 3.23 Å. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(16), one O(18), one O(19), one O(21), one O(22), and one O(24) atom. The Cs(3)-O(1) bond length is 3.21 Å. The Cs(3)-O(12) bond length is 2.99 Å. The Cs(3)-O(16) bond length is 3.32 Å. The Cs(3)-O(18) bond length is 3.19 Å. The Cs(3)-O(19) bond length is 3.53 Å. The Cs(3)-O(21) bond length is 3.37 Å. The Cs(3)-O(22) bond length is 3.14 Å. The Cs(3)-O(24) bond length is 3.24 Å. In the fourth Cs site, Cs(4) is bonded in a 9-coordinate geometry to one O(11), one O(15), one O(28), one O(29), one O(30), one O(5), one O(6), one O(7), and one O(8) atom. The Cs(4)-O(11) bond length is 3.52 Å. The Cs(4)-O(15) bond length is 3.06 Å. The Cs(4)-O(28) bond length is 3.33 Å. The Cs(4)-O(29) bond length is 3.36 Å. The Cs(4)-O(30) bond length is 3.38 Å. The Cs(4)-O(5) bond length is 3.37 Å. The Cs(4)-O(6) bond length is 3.58 Å. The Cs(4)-O(7) bond length is 3.66 Å. The Cs(4)-O(8) bond length is 2.88 Å. In the fifth Cs site, Cs(5) is bonded in a 8-coordinate geometry to one O(14), one O(15), one O(16), one O(18), one O(2), one O(23), one O(30), and one O(9) atom. The Cs(5)-O(14) bond length is 3.20 Å. The Cs(5)-O(15) bond length is 3.14 Å. The Cs(5)-O(16) bond length is 3.20 Å. The Cs(5)-O(18) bond length is 3.35 Å. The Cs(5)-O(2) bond length is 3.55 Å. The Cs(5)-O(23) bond length is 2.99 Å. The Cs(5)-O(30) bond length is 3.26 Å. The Cs(5)-O(9) bond length is 3.39 Å. In the sixth Cs site, Cs(6) is bonded in a 10-coordinate geometry to one O(12), one O(14), one O(16), one O(17), one O(19), one O(21), one O(22), one O(24), one O(26), and one O(3) atom. The Cs(6)-O(12) bond length is 3.10 Å. The Cs(6)-O(14) bond length is 3.11 Å. The Cs(6)-O(16) bond length is 3.17 Å. The Cs(6)-O(17) bond length is 3.40 Å. The Cs(6)-O(19) bond length is 3.18 Å. The Cs(6)-O(21) bond length is 3.33 Å. The Cs(6)-O(22) bond length is 3.53 Å. The Cs(6)-O(24) bond length is 3.29 Å. The Cs(6)-O(26) bond length is 3.48 Å. The Cs(6)-O(3) bond length is 3.43 Å. In the seventh Cs site, Cs(7) is bonded in a 8-coordinate geometry to one O(14), one O(16), one O(19), one O(2), one O(21), one O(23), one O(24), and one O(26) atom. The Cs(7)-O(14) bond length is 2.98 Å. The Cs(7)-O(16) bond length is 3.49 Å. The Cs(7)-O(19) bond length is 3.33 Å. The Cs(7)-O(2) bond length is 3.19 Å. The Cs(7)-O(21) bond length is 3.24 Å. The Cs(7)-O(23) bond length is 3.19 Å. The Cs(7)-O(24) bond length is 3.38 Å. The Cs(7)-O(26) bond length is 3.15 Å. In the eighth Cs site, Cs(8) is bonded in a 2-coordinate geometry to one O(26) and one O(3) atom. The Cs(8)-O(26) bond length is 3.06 Å. The Cs(8)-O(3) bond length is 2.88 Å. In the ninth Cs site, Cs(9) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(15), one O(18), one O(2), one O(23), one O(30), one O(4), one O(8), and one O(9) atom. The Cs(9)-O(1) bond length is 3.12 Å. The Cs(9)-O(13) bond length is 3.46 Å. The Cs(9)-O(15) bond length is 3.53 Å. The Cs(9)-O(18) bond length is 3.18 Å. The Cs(9)-O(2) bond length is 3.17 Å. The Cs(9)-O(23) bond length is 3.11 Å. The Cs(9)-O(30) bond length is 3.30 Å. The Cs(9)-O(4) bond length is 3.36 Å. The Cs(9)-O(8) bond length is 3.42 Å. The Cs(9)-O(9) bond length is 3.31 Å. In the tenth Cs site, Cs(10) is bonded in a 9-coordinate geometry to one O(10), one O(17), one O(22), one O(24), one O(25), one O(27), one O(32), one O(5), and one O(7) atom. The Cs(10)-O(10) bond length is 3.54 Å. The Cs(10)-O(17) bond length is 2.88 Å. The Cs(10)-O(22) bond length is 3.06 Å. The Cs(10)-O(24) bond length is 3.39 Å. The Cs(10)-O(25) bond length is 3.57 Å. The Cs(10)-O(27) bond length is 3.39 Å. The Cs(10)-O(32) bond length is 3.34 Å. The Cs(10)-O(5) bond length is 3.62 Å. The Cs(10)-O(7) bond length is 3.37 Å. There are eight inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(14), one O(18), one O(25), and one O(26) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. The Mo(1)-O(14) bond length is 1.77 Å. The Mo(1)-O(18) bond length is 1.78 Å. The Mo(1)-O(25) bond length is 1.87 Å. The Mo(1)-O(26) bond length is 1.78 Å. In the second Mo site, Mo(2) is bonded to one O(11), one O(24), one O(3), and one O(5) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. The Mo(2)-O(11) bond length is 1.85 Å. The Mo(2)-O(24) bond length is 1.78 Å. The Mo(2)-O(3) bond length is 1.76 Å. The Mo(2)-O(5) bond length is 1.82 Å. In the third Mo site, Mo(3) is bonded to one O(10), one O(30), one O(4), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. The Mo(3)-O(10) bond length is 1.85 Å. The Mo(3)-O(30) bond length is 1.78 Å. The Mo(3)-O(4) bond length is 1.76 Å. The Mo(3)-O(7) bond length is 1.83 Å. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(13), one O(16), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. The Mo(4)-O(1) bond length is 1.77 Å. The Mo(4)-O(13) bond length is 1.78 Å. The Mo(4)-O(16) bond length is 1.78 Å. The Mo(4)-O(6) bond length is 1.87 Å. In the fifth Mo site, Mo(5) is bonded to one O(17), one O(21), one O(27), and one O(28) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. The Mo(5)-O(17) bond length is 1.76 Å. The Mo(5)-O(21) bond length is 1.78 Å. The Mo(5)-O(27) bond length is 1.85 Å. The Mo(5)-O(28) bond length is 1.83 Å. In the sixth Mo site, Mo(6) is bonded to one O(29), one O(32), one O(8), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-60°. The Mo(6)-O(29) bond length is 1.85 Å. The Mo(6)-O(32) bond length is 1.83 Å. The Mo(6)-O(8) bond length is 1.76 Å. The Mo(6)-O(9) bond length is 1.78 Å. In the seventh Mo site, Mo(7) is bonded to one O(12), one O(2), one O(22), and one O(31) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. The Mo(7)-O(12) bond length is 1.77 Å. The Mo(7)-O(2) bond length is 1.78 Å. The Mo(7)-O(22) bond length is 1.78 Å. The Mo(7)-O(31) bond length is 1.87 Å. In the eighth Mo site, Mo(8) is bonded to one O(15), one O(19), one O(20), and one O(23) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. The Mo(8)-O(15) bond length is 1.78 Å. The Mo(8)-O(19) bond length is 1.78 Å. The Mo(8)-O(20) bond length is 1.87 Å. The Mo(8)-O(23) bond length is 1.77 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(10), one O(20), one O(28), one O(29), one O(5), and one O(6) atom to form BiO6 octahedra that share  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(8)O4 tetrahedra. The Bi(1)-O(10) bond length is 2.39 Å. The Bi(1)-O(20) bond length is 2.24 Å. The Bi(1)-O(28) bond length is 2.60 Å. The Bi(1)-O(29) bond length is 2.42 Å. The Bi(1)-O(5) bond length is 2.63 Å. The Bi(1)-O(6) bond length is 2.23 Å. In the second Bi site, Bi(2) is bonded to one O(11), one O(25), one O(27), one O(31), one O(32), and one O(7) atom to form BiO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(7)O4 tetrahedra. The Bi(2)-O(11) bond length is 2.40 Å. The Bi(2)-O(25) bond length is 2.24 Å. The Bi(2)-O(27) bond length is 2.41 Å. The Bi(2)-O(31) bond length is 2.24 Å. The Bi(2)-O(32) bond length is 2.60 Å. The Bi(2)-O(7) bond length is 2.60 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(9), and one Mo(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(5), one Cs(7), one Cs(9), and one Mo(7) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Cs(6), one Cs(8), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(9), and one Mo(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Cs(4), one Mo(2), and one Bi(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(4), one Mo(4), and one Bi(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Cs(10), one Cs(4), one Mo(3), and one Bi(2) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one Cs(4), one Cs(9), and one Mo(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(5), one Cs(9), and one Mo(6) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(3), and one Bi(1) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Cs(4), one Mo(2), and one Bi(2) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(6), and one Mo(7) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(9), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Cs(5), one Cs(6), one Cs(7), and one Mo(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(4), one Cs(5), one Cs(9), and one Mo(8) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(5), one Cs(6), one Cs(7), and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(6), and one Mo(5) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(5), one Cs(9), and one Mo(1) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(7), and one Mo(8) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Mo(8), and one Bi(1) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(6), one Cs(7), and one Mo(5) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), and one Mo(7) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one Cs(5), one Cs(7), one Cs(9), and one Mo(8) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), one Cs(7), and one Mo(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one Cs(10), one Mo(1), and one Bi(2) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(6), one Cs(7), one Cs(8), and one Mo(1) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(5), and one Bi(2) atom. In the twenty-eighth O site, O(28) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(4), one Mo(5), and one Bi(1) atom. In the twenty-ninth O site, O(29) is bonded in a 2-coordinate geometry to one Cs(4), one Mo(6), and one Bi(1) atom. In the thirtieth O site, O(30) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(4), one Cs(5), one Cs(9), and one Mo(3) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 150 degrees geometry to one Mo(7) and one Bi(2) atom. In the thirty-second O site, O(32) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Mo(6), and one Bi(2) atom.