TiMoP2 crystallizes in the trigonal P-3m1 space group. Ti(1) is bonded to six equivalent P(1) atoms to form TiP6 octahedra that share corners with twelve equivalent Mo(1)P6 octahedra, edges with six equivalent Ti(1)P6 octahedra, and faces with two equivalent Mo(1)P6 octahedra. The corner-sharing octahedral tilt angles are 44°. Mo(1) is bonded to six equivalent P(1) atoms to form MoP6 octahedra that share corners with twelve equivalent Ti(1)P6 octahedra, edges with six equivalent Mo(1)P6 octahedra, and faces with two equivalent Ti(1)P6 octahedra. The corner-sharing octahedral tilt angles are 44°. P(1) is bonded in a 6-coordinate geometry to three equivalent Ti(1) and three equivalent Mo(1) atoms.
TiMoP2 crystallizes in the trigonal P-3m1 space group. Ti(1) is bonded to six equivalent P(1) atoms to form TiP6 octahedra that share corners with twelve equivalent Mo(1)P6 octahedra, edges with six equivalent Ti(1)P6 octahedra, and faces with two equivalent Mo(1)P6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Ti(1)-P(1) bond lengths are 2.48 Å. Mo(1) is bonded to six equivalent P(1) atoms to form MoP6 octahedra that share corners with twelve equivalent Ti(1)P6 octahedra, edges with six equivalent Mo(1)P6 octahedra, and faces with two equivalent Ti(1)P6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Mo(1)-P(1) bond lengths are 2.48 Å. P(1) is bonded in a 6-coordinate geometry to three equivalent Ti(1) and three equivalent Mo(1) atoms.