ZrOS crystallizes in the cubic P2_13 space group. Zr(1) is bonded in a 7-coordinate geometry to four equivalent S(1) and three equivalent O(1) atoms. S(1) is bonded to four equivalent Zr(1) atoms to form corner-sharing SZr4 trigonal pyramids. O(1) is bonded in a trigonal planar geometry to three equivalent Zr(1) atoms.
ZrOS crystallizes in the cubic P2_13 space group. Zr(1) is bonded in a 7-coordinate geometry to four equivalent S(1) and three equivalent O(1) atoms. There is one shorter (2.59 Å) and three longer (2.74 Å) Zr(1)-S(1) bond lengths. All Zr(1)-O(1) bond lengths are 2.09 Å. S(1) is bonded to four equivalent Zr(1) atoms to form corner-sharing SZr4 trigonal pyramids. O(1) is bonded in a trigonal planar geometry to three equivalent Zr(1) atoms.