(BeNF4)2NiO6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four BeNF4 clusters and two NiO6 clusters. In each BeNF4 cluster, Be(1) is bonded in a distorted trigonal planar geometry to one F(2), one F(3), and one F(4) atom. N(1) is bonded in a water-like geometry to one F(1) and one F(3) atom. There are four inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Be(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Be(1) atom. In the fourth F site, F(3) is bonded in a bent 120 degrees geometry to one Be(1) and one N(1) atom. In each NiO6 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Ni(1) atom.
(BeNF4)2NiO6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four BeNF4 clusters and two NiO6 clusters. In each BeNF4 cluster, Be(1) is bonded in a distorted trigonal planar geometry to one F(2), one F(3), and one F(4) atom. The Be(1)-F(2) bond length is 1.42 Å. The Be(1)-F(3) bond length is 1.73 Å. The Be(1)-F(4) bond length is 1.42 Å. N(1) is bonded in a water-like geometry to one F(1) and one F(3) atom. The N(1)-F(1) bond length is 1.32 Å. The N(1)-F(3) bond length is 1.53 Å. There are four inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Be(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Be(1) atom. In the fourth F site, F(3) is bonded in a bent 120 degrees geometry to one Be(1) and one N(1) atom. In each NiO6 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Ni(1)-O(1) bond lengths are 1.81 Å. Both Ni(1)-O(2) bond lengths are 1.83 Å. Both Ni(1)-O(3) bond lengths are 1.81 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Ni(1) atom.