Ca5Sc2(CoO6)2 crystallizes in the triclinic P1 space group. There are five inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. In the second Ca site, Ca(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. In the third Ca site, Ca(3) is bonded in a 8-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. In the fourth Ca site, Ca(4) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(4), one O(5), one O(7), and one O(9) atom. In the fifth Ca site, Ca(5) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(7), and one O(8) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(1)O6 octahedra and  a faceface with one Co(2)O6 octahedra. In the second Sc site, Sc(2) is bonded in a 6-coordinate geometry to one O(10), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(12), one O(3), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(2), one Ca(4), one Ca(5), one Sc(1), and one Co(1) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(4)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with three equivalent O(11)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(5)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 5-67°. In the second O site, O(2) is bonded to one Ca(3), one Ca(4), one Ca(5), one Sc(1), and one Co(2) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(3)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with three equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(8)Ca4ScCo octahedra, and  a faceface with one O(6)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-67°. In the third O site, O(3) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(5), one Sc(2), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with four equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid, corners with two equivalent O(2)Ca3ScCo trigonal bipyramids, edges with two equivalent O(8)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(5)Ca3ScCo square pyramid, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 53-61°. In the fourth O site, O(4) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(4), one Sc(2), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(12)Ca3ScCo square pyramids, corners with four equivalent O(5)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, corners with two equivalent O(1)Ca3ScCo trigonal bipyramids, edges with two equivalent O(7)Ca4ScCo octahedra,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid,  a faceface with one O(11)Ca3ScCo square pyramid, and  a faceface with one O(6)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 53-61°. In the fifth O site, O(5) is bonded to one Ca(1), one Ca(2), one Ca(4), one Sc(2), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra, corners with four equivalent O(4)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid, corners with two equivalent O(12)Ca3ScCo square pyramids, corners with two equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(11)Ca3ScCo square pyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(9)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-62°. In the sixth O site, O(6) is bonded to one Ca(1), one Ca(3), one Ca(5), one Sc(2), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra, corners with four equivalent O(3)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with two equivalent O(5)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-63°. In the seventh O site, O(7) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(4), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(3)Ca4ScCo octahedra, corners with four equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids, corners with two equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, edges with two equivalent O(4)Ca4ScCo octahedra,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(5)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-61°. In the eighth O site, O(8) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(5), one Sc(1), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(4)Ca4ScCo octahedra, corners with four equivalent O(7)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid, corners with two equivalent O(5)Ca3ScCo square pyramids, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, edges with two equivalent O(3)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(6)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-61°. In the ninth O site, O(9) is bonded to one Ca(3), one Ca(4), one Ca(5), one Sc(2), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid, corners with three equivalent O(10)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(6)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra, and  a faceface with one O(5)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-50°. In the tenth O site, O(10) is bonded to one Ca(2), one Ca(4), one Ca(5), one Sc(2), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid, corners with three equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(5)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra, and  a faceface with one O(6)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-50°. In the eleventh O site, O(11) is bonded to one Ca(1), one Ca(2), one Ca(4), one Sc(1), and one Co(2) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(3)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, corners with three equivalent O(1)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(5)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(8)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the twelfth O site, O(12) is bonded to one Ca(1), one Ca(3), one Ca(5), one Sc(1), and one Co(1) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(4)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(5)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid, corners with three equivalent O(2)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(6)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(8)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 42-54°.
Ca5Sc2(CoO6)2 crystallizes in the triclinic P1 space group. There are five inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Ca(1)-O(11) bond length is 2.34 Å. The Ca(1)-O(12) bond length is 2.34 Å. The Ca(1)-O(3) bond length is 2.60 Å. The Ca(1)-O(4) bond length is 2.60 Å. The Ca(1)-O(5) bond length is 2.50 Å. The Ca(1)-O(6) bond length is 2.49 Å. The Ca(1)-O(7) bond length is 2.56 Å. The Ca(1)-O(8) bond length is 2.57 Å. In the second Ca site, Ca(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. The Ca(2)-O(1) bond length is 2.42 Å. The Ca(2)-O(10) bond length is 2.35 Å. The Ca(2)-O(11) bond length is 2.48 Å. The Ca(2)-O(3) bond length is 2.50 Å. The Ca(2)-O(4) bond length is 2.49 Å. The Ca(2)-O(5) bond length is 2.39 Å. The Ca(2)-O(7) bond length is 2.67 Å. The Ca(2)-O(8) bond length is 2.46 Å. In the third Ca site, Ca(3) is bonded in a 8-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. The Ca(3)-O(12) bond length is 2.48 Å. The Ca(3)-O(2) bond length is 2.43 Å. The Ca(3)-O(3) bond length is 2.49 Å. The Ca(3)-O(4) bond length is 2.50 Å. The Ca(3)-O(6) bond length is 2.38 Å. The Ca(3)-O(7) bond length is 2.46 Å. The Ca(3)-O(8) bond length is 2.67 Å. The Ca(3)-O(9) bond length is 2.34 Å. In the fourth Ca site, Ca(4) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(4), one O(5), one O(7), and one O(9) atom. The Ca(4)-O(1) bond length is 2.43 Å. The Ca(4)-O(10) bond length is 2.61 Å. The Ca(4)-O(11) bond length is 2.51 Å. The Ca(4)-O(2) bond length is 2.51 Å. The Ca(4)-O(4) bond length is 2.60 Å. The Ca(4)-O(5) bond length is 2.66 Å. The Ca(4)-O(7) bond length is 2.35 Å. The Ca(4)-O(9) bond length is 2.51 Å. In the fifth Ca site, Ca(5) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. The Ca(5)-O(1) bond length is 2.53 Å. The Ca(5)-O(10) bond length is 2.51 Å. The Ca(5)-O(12) bond length is 2.51 Å. The Ca(5)-O(2) bond length is 2.43 Å. The Ca(5)-O(3) bond length is 2.60 Å. The Ca(5)-O(6) bond length is 2.67 Å. The Ca(5)-O(8) bond length is 2.36 Å. The Ca(5)-O(9) bond length is 2.59 Å. There are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(7), and one O(8) atom to form distorted ScO6 pentagonal pyramids that share  a faceface with one Co(1)O6 octahedra and  a faceface with one Co(2)O6 octahedra. The Sc(1)-O(1) bond length is 2.11 Å. The Sc(1)-O(11) bond length is 2.13 Å. The Sc(1)-O(12) bond length is 2.12 Å. The Sc(1)-O(2) bond length is 2.11 Å. The Sc(1)-O(7) bond length is 2.16 Å. The Sc(1)-O(8) bond length is 2.16 Å. In the second Sc site, Sc(2) is bonded in a 6-coordinate geometry to one O(10), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. The Sc(2)-O(10) bond length is 2.07 Å. The Sc(2)-O(3) bond length is 2.17 Å. The Sc(2)-O(4) bond length is 2.16 Å. The Sc(2)-O(5) bond length is 2.10 Å. The Sc(2)-O(6) bond length is 2.11 Å. The Sc(2)-O(9) bond length is 2.07 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(12), one O(3), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid. The Co(1)-O(1) bond length is 1.93 Å. The Co(1)-O(12) bond length is 1.90 Å. The Co(1)-O(3) bond length is 1.92 Å. The Co(1)-O(5) bond length is 1.88 Å. The Co(1)-O(7) bond length is 1.94 Å. The Co(1)-O(9) bond length is 1.93 Å. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid. The Co(2)-O(10) bond length is 1.92 Å. The Co(2)-O(11) bond length is 1.90 Å. The Co(2)-O(2) bond length is 1.94 Å. The Co(2)-O(4) bond length is 1.93 Å. The Co(2)-O(6) bond length is 1.87 Å. The Co(2)-O(8) bond length is 1.94 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(2), one Ca(4), one Ca(5), one Sc(1), and one Co(1) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(4)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with three equivalent O(11)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(5)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 5-67°. In the second O site, O(2) is bonded to one Ca(3), one Ca(4), one Ca(5), one Sc(1), and one Co(2) atom to form distorted OCa3ScCo trigonal bipyramids that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(3)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with three equivalent O(12)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(8)Ca4ScCo octahedra, and  a faceface with one O(6)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 4-67°. In the third O site, O(3) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(5), one Sc(2), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with four equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid, corners with two equivalent O(2)Ca3ScCo trigonal bipyramids, edges with two equivalent O(8)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(5)Ca3ScCo square pyramid, and  a faceface with one O(9)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 53-61°. In the fourth O site, O(4) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(4), one Sc(2), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(12)Ca3ScCo square pyramids, corners with four equivalent O(5)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, corners with two equivalent O(1)Ca3ScCo trigonal bipyramids, edges with two equivalent O(7)Ca4ScCo octahedra,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid,  a faceface with one O(11)Ca3ScCo square pyramid, and  a faceface with one O(6)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 53-61°. In the fifth O site, O(5) is bonded to one Ca(1), one Ca(2), one Ca(4), one Sc(2), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra, corners with four equivalent O(4)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid, corners with two equivalent O(12)Ca3ScCo square pyramids, corners with two equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(11)Ca3ScCo square pyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra,  a faceface with one O(9)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-62°. In the sixth O site, O(6) is bonded to one Ca(1), one Ca(3), one Ca(5), one Sc(2), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra, corners with four equivalent O(3)Ca4ScCo octahedra,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(11)Ca3ScCo square pyramids, corners with two equivalent O(5)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(8)Ca4ScCo octahedra,  a faceface with one O(10)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-63°. In the seventh O site, O(7) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(4), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(3)Ca4ScCo octahedra, corners with four equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(10)Ca3ScCo square pyramids, corners with two equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, edges with two equivalent O(4)Ca4ScCo octahedra,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(5)Ca3ScCo square pyramid, and  a faceface with one O(1)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-61°. In the eighth O site, O(8) is bonded to one Ca(1), one Ca(2), one Ca(3), one Ca(5), one Sc(1), and one Co(2) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(4)Ca4ScCo octahedra, corners with four equivalent O(7)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid, corners with two equivalent O(5)Ca3ScCo square pyramids, corners with two equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, edges with two equivalent O(3)Ca4ScCo octahedra,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(11)Ca3ScCo square pyramid,  a faceface with one O(12)Ca3ScCo square pyramid,  a faceface with one O(6)Ca3ScCo square pyramid, and  a faceface with one O(2)Ca3ScCo trigonal bipyramid. The corner-sharing octahedral tilt angles range from 30-61°. In the ninth O site, O(9) is bonded to one Ca(3), one Ca(4), one Ca(5), one Sc(2), and one Co(1) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra, corners with two equivalent O(8)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid, corners with three equivalent O(10)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(4)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4ScCo octahedra,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(6)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra, and  a faceface with one O(5)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-50°. In the tenth O site, O(10) is bonded to one Ca(2), one Ca(4), one Ca(5), one Sc(2), and one Co(2) atom to form distorted OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(7)Ca4ScCo octahedra,  a cornercorner with one O(11)Ca3ScCo square pyramid,  a cornercorner with one O(12)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid, corners with three equivalent O(9)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(3)Ca4ScCo octahedra,  an edgeedge with one O(8)Ca4ScCo octahedra,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(5)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra, and  a faceface with one O(6)Ca3ScCo square pyramid. The corner-sharing octahedral tilt angles range from 3-50°. In the eleventh O site, O(11) is bonded to one Ca(1), one Ca(2), one Ca(4), one Sc(1), and one Co(2) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(4)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(3)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(5)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(6)Ca3ScCo square pyramids,  a cornercorner with one O(2)Ca3ScCo trigonal bipyramid, corners with three equivalent O(1)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(10)Ca3ScCo square pyramid,  an edgeedge with one O(12)Ca3ScCo square pyramid,  an edgeedge with one O(5)Ca3ScCo square pyramid,  an edgeedge with one O(2)Ca3ScCo trigonal bipyramid,  a faceface with one O(4)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(8)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the twelfth O site, O(12) is bonded to one Ca(1), one Ca(3), one Ca(5), one Sc(1), and one Co(1) atom to form OCa3ScCo square pyramids that share  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(7)Ca4ScCo octahedra,  a cornercorner with one O(8)Ca4ScCo octahedra, corners with two equivalent O(4)Ca4ScCo octahedra,  a cornercorner with one O(10)Ca3ScCo square pyramid,  a cornercorner with one O(6)Ca3ScCo square pyramid,  a cornercorner with one O(9)Ca3ScCo square pyramid, corners with two equivalent O(5)Ca3ScCo square pyramids,  a cornercorner with one O(1)Ca3ScCo trigonal bipyramid, corners with three equivalent O(2)Ca3ScCo trigonal bipyramids,  an edgeedge with one O(11)Ca3ScCo square pyramid,  an edgeedge with one O(6)Ca3ScCo square pyramid,  an edgeedge with one O(9)Ca3ScCo square pyramid,  an edgeedge with one O(1)Ca3ScCo trigonal bipyramid,  a faceface with one O(3)Ca4ScCo octahedra,  a faceface with one O(7)Ca4ScCo octahedra, and  a faceface with one O(8)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 42-54°.