ReOCl4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ReOCl4 clusters. Re(1,2) is bonded in a 5-coordinate geometry to one O(2); one Cl(5); one Cl(8); and two equivalent Cl(3,4) atoms. O(2) is bonded in a single-bond geometry to one Re(1,2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a single-bond geometry to one Re(1,2) atom. In the second Cl site, Cl(3,4) is bonded in a single-bond geometry to one Re(1,2) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1,2) atom.
ReOCl4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ReOCl4 clusters. Re(1,2) is bonded in a 5-coordinate geometry to one O(2); one Cl(5); one Cl(8); and two equivalent Cl(3,4) atoms. The Re(1,2)-O(2) bond length is 1.69 Å. The Re(1,2)-Cl(5) bond length is 2.29 Å. The Re(1,2)-Cl(8) bond length is 2.29 Å. Both Re(1,2)-Cl(3,4) bond lengths are 2.28 Å. O(2) is bonded in a single-bond geometry to one Re(1,2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a single-bond geometry to one Re(1,2) atom. In the second Cl site, Cl(3,4) is bonded in a single-bond geometry to one Re(1,2) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1,2) atom.