DyMnO3 crystallizes in the orthorhombic Pnma space group. Dy(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of edge and corner-sharing DyO6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. Mn(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to four equivalent Dy(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Dy(1) and two equivalent Mn(1) atoms.
DyMnO3 crystallizes in the orthorhombic Pnma space group. Dy(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of edge and corner-sharing DyO6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. Both Dy(1)-O(2) bond lengths are 2.26 Å. There are a spread of Dy(1)-O(1) bond distances ranging from 2.23-2.33 Å. Mn(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. There are two shorter (2.00 Å) and two longer (2.01 Å) Mn(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to four equivalent Dy(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Dy(1) and two equivalent Mn(1) atoms.