(K)2AgBiBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a AgBiBr6 framework. In the AgBiBr6 framework, Ag(1) is bonded to six equivalent Br(1) atoms to form AgBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Ag(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Ag(1) and one Bi(1) atom.
(K)2AgBiBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a AgBiBr6 framework. In the AgBiBr6 framework, Ag(1) is bonded to six equivalent Br(1) atoms to form AgBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Ag(1)-Br(1) bond lengths are 2.82 Å. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Ag(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-Br(1) bond lengths are 2.87 Å. Br(1) is bonded in a linear geometry to one Ag(1) and one Bi(1) atom.