ReMnN2 crystallizes in the orthorhombic Pna2_1 space group. Re(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form distorted corner-sharing MnN4 trigonal pyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to two equivalent Re(1) and two equivalent Mn(1) atoms. In the second N site, N(2) is bonded to two equivalent Re(1) and two equivalent Mn(1) atoms to form distorted corner-sharing NMn2Re2 trigonal pyramids.
ReMnN2 crystallizes in the orthorhombic Pna2_1 space group. Re(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Re(1)-N(1) bond lengths are 2.06 Å. There is one shorter (1.98 Å) and one longer (1.99 Å) Re(1)-N(2) bond length. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form distorted corner-sharing MnN4 trigonal pyramids. There is one shorter (1.86 Å) and one longer (1.95 Å) Mn(1)-N(1) bond length. There is one shorter (1.89 Å) and one longer (1.94 Å) Mn(1)-N(2) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to two equivalent Re(1) and two equivalent Mn(1) atoms. In the second N site, N(2) is bonded to two equivalent Re(1) and two equivalent Mn(1) atoms to form distorted corner-sharing NMn2Re2 trigonal pyramids.