(NH4)3TiF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 1333-74-0 molecule, one hydrofluoric acid atom, one molecular hydrogen;hydrofluoride molecule, one monofluoroamine molecule, one NH4F cluster, and one TiNH2F3 cluster. In the NH4F cluster, N(2) is bonded in a distorted T-shaped geometry to one H(5), one H(6), and one H(7) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(2) and one F(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one F(2) atom. F(2) is bonded in a 2-coordinate geometry to one H(6) and one H(9) atom. In the TiNH2F3 cluster, Ti(1) is bonded in a 2-coordinate geometry to one N(3), one F(1), and one F(5) atom. N(3) is bonded in a 3-coordinate geometry to one Ti(1), one H(8), and one F(5) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a linear geometry to one F(3) and one F(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one H(2) atom. In the third F site, F(5) is bonded in a distorted water-like geometry to one Ti(1), one N(3), and one H(2) atom.
(NH4)3TiF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 1333-74-0 molecule, one hydrofluoric acid atom, one molecular hydrogen;hydrofluoride molecule, one monofluoroamine molecule, one NH4F cluster, and one TiNH2F3 cluster. In the NH4F cluster, N(2) is bonded in a distorted T-shaped geometry to one H(5), one H(6), and one H(7) atom. The N(2)-H(5) bond length is 1.22 Å. The N(2)-H(6) bond length is 0.91 Å. The N(2)-H(7) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(2) and one F(2) atom. The H(6)-F(2) bond length is 1.63 Å. In the third H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one F(2) atom. The H(9)-F(2) bond length is 1.61 Å. F(2) is bonded in a 2-coordinate geometry to one H(6) and one H(9) atom. In the TiNH2F3 cluster, Ti(1) is bonded in a 2-coordinate geometry to one N(3), one F(1), and one F(5) atom. The Ti(1)-N(3) bond length is 1.44 Å. The Ti(1)-F(1) bond length is 2.40 Å. The Ti(1)-F(5) bond length is 1.50 Å. N(3) is bonded in a 3-coordinate geometry to one Ti(1), one H(8), and one F(5) atom. The N(3)-H(8) bond length is 0.71 Å. The N(3)-F(5) bond length is 1.75 Å. There are two inequivalent H sites. In the first H site, H(2) is bonded in a linear geometry to one F(3) and one F(5) atom. The H(2)-F(3) bond length is 0.75 Å. The H(2)-F(5) bond length is 1.33 Å. In the second H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one H(2) atom. In the third F site, F(5) is bonded in a distorted water-like geometry to one Ti(1), one N(3), and one H(2) atom.