CuZnF4 crystallizes in the orthorhombic Ima2 space group. Cu(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Zn(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent Zn(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent Zn(1) atoms.
CuZnF4 crystallizes in the orthorhombic Ima2 space group. Cu(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Cu(1)-F(1) bond lengths are 1.92 Å. Both Cu(1)-F(2) bond lengths are 1.92 Å. Zn(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two shorter (2.21 Å) and two longer (2.22 Å) Zn(1)-F(1) bond lengths. There are two shorter (2.18 Å) and two longer (2.27 Å) Zn(1)-F(2) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent Zn(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Cu(1) and two equivalent Zn(1) atoms.