MnFe2Pb2(OF4)3 crystallizes in the orthorhombic Amm2 space group. Mn(1) is bonded to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms to form MnF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra and corners with two equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-29°. Fe(1) is bonded to one F(1), one F(2), one F(6), one F(7), and two equivalent F(4) atoms to form FeF6 octahedra that share  a cornercorner with one Mn(1)F6 octahedra and corners with three equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-29°. Pb(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(2), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Pb(1) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Fe(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one Fe(1) atom. In the third F site, F(3) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the fourth F site, F(4) is bonded in a linear geometry to two equivalent Fe(1) atoms. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one Mn(1) and two equivalent Pb(1) atoms. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one Fe(1) and two equivalent Pb(1) atoms. In the seventh F site, F(7) is bonded in a distorted single-bond geometry to one Fe(1) and two equivalent Pb(1) atoms.
MnFe2Pb2(OF4)3 crystallizes in the orthorhombic Amm2 space group. Mn(1) is bonded to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms to form MnF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra and corners with two equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-29°. Both Mn(1)-F(2) bond lengths are 1.92 Å. Both Mn(1)-F(3) bond lengths are 2.01 Å. Both Mn(1)-F(5) bond lengths are 1.89 Å. Fe(1) is bonded to one F(1), one F(2), one F(6), one F(7), and two equivalent F(4) atoms to form FeF6 octahedra that share  a cornercorner with one Mn(1)F6 octahedra and corners with three equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 1-29°. The Fe(1)-F(1) bond length is 1.96 Å. The Fe(1)-F(2) bond length is 1.98 Å. The Fe(1)-F(6) bond length is 1.92 Å. The Fe(1)-F(7) bond length is 1.92 Å. Both Fe(1)-F(4) bond lengths are 2.01 Å. Pb(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(2), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. The Pb(1)-O(1) bond length is 2.74 Å. There is one shorter (2.72 Å) and one longer (2.74 Å) Pb(1)-O(2) bond length. Both Pb(1)-F(5) bond lengths are 2.64 Å. Both Pb(1)-F(6) bond lengths are 2.62 Å. Both Pb(1)-F(7) bond lengths are 2.61 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Pb(1) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Fe(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one Fe(1) atom. In the third F site, F(3) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the fourth F site, F(4) is bonded in a linear geometry to two equivalent Fe(1) atoms. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one Mn(1) and two equivalent Pb(1) atoms. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one Fe(1) and two equivalent Pb(1) atoms. In the seventh F site, F(7) is bonded in a distorted single-bond geometry to one Fe(1) and two equivalent Pb(1) atoms.