NaBaN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a distorted trigonal planar geometry to three equivalent N(1) atoms. Ba(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing BaN4 tetrahedra. N(1) is bonded to three equivalent Na(1) and four equivalent Ba(1) atoms to form a mixture of distorted corner and edge-sharing NBa4Na3 pentagonal bipyramids.
NaBaN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a distorted trigonal planar geometry to three equivalent N(1) atoms. There are two shorter (2.52 Å) and one longer (2.68 Å) Na(1)-N(1) bond length. Ba(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing BaN4 tetrahedra. There are a spread of Ba(1)-N(1) bond distances ranging from 2.84-2.86 Å. N(1) is bonded to three equivalent Na(1) and four equivalent Ba(1) atoms to form a mixture of distorted corner and edge-sharing NBa4Na3 pentagonal bipyramids.