VNiP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Ni(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Ni(1) atoms.
VNiP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. There are a spread of V(1)-P(1) bond distances ranging from 2.44-2.56 Å. Ni(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. There is one shorter (2.21 Å) and three longer (2.25 Å) Ni(1)-P(1) bond lengths. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Ni(1) atoms.