Mn(C2O)2(CO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four carbon dioxide molecules and two Mn(C2O)2 clusters. In each Mn(C2O)2 cluster, Mn(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent C(2) atoms. C(2) is bonded in an L-shaped geometry to one Mn(1) and one O(2) atom. O(2) is bonded in a bent 120 degrees geometry to two equivalent C(2) atoms.
Mn(C2O)2(CO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four carbon dioxide molecules and two Mn(C2O)2 clusters. In each Mn(C2O)2 cluster, Mn(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent C(2) atoms. All Mn(1)-C(2) bond lengths are 2.22 Å. C(2) is bonded in an L-shaped geometry to one Mn(1) and one O(2) atom. The C(2)-O(2) bond length is 1.35 Å. O(2) is bonded in a bent 120 degrees geometry to two equivalent C(2) atoms.