Mn2CuN2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to four equivalent N(1) atoms to form a mixture of corner and edge-sharing MnN4 trigonal pyramids. Cu(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to four equivalent Mn(1) and one Cu(1) atom to form a mixture of corner and edge-sharing NMn4Cu trigonal bipyramids.
Mn2CuN2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to four equivalent N(1) atoms to form a mixture of corner and edge-sharing MnN4 trigonal pyramids. There are three shorter (1.88 Å) and one longer (2.00 Å) Mn(1)-N(1) bond length. Cu(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Cu(1)-N(1) bond lengths are 1.90 Å. N(1) is bonded to four equivalent Mn(1) and one Cu(1) atom to form a mixture of corner and edge-sharing NMn4Cu trigonal bipyramids.