WIrO6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-26°. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-26°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Ir(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one Ir(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Ir(1) atom.
WIrO6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-26°. Both W(1)-O(1) bond lengths are 1.93 Å. Both W(1)-O(2) bond lengths are 1.93 Å. Both W(1)-O(3) bond lengths are 1.93 Å. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-26°. Both Ir(1)-O(1) bond lengths are 1.91 Å. Both Ir(1)-O(2) bond lengths are 1.91 Å. Both Ir(1)-O(3) bond lengths are 1.91 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Ir(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one Ir(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Ir(1) atom.