Cd3S3O14(O2)3 crystallizes in the triclinic P1 space group. The structure consists of six hydrogen peroxide molecules inside a Cd3S3O14 framework. In the Cd3S3O14 framework, there are six inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a see-saw-like geometry to one O(10), one O(19), one O(20), and one O(9) atom. In the second Cd site, Cd(2) is bonded in a see-saw-like geometry to one O(11), one O(12), one O(17), and one O(18) atom. In the third Cd site, Cd(3) is bonded to one O(13), one O(23), one O(4), and one O(5) atom to form distorted CdO4 trigonal pyramids that share  a cornercorner with one S(1)O4 tetrahedra,  a cornercorner with one S(2)O4 tetrahedra,  a cornercorner with one S(3)O4 tetrahedra, and  a cornercorner with one S(5)O4 tetrahedra. In the fourth Cd site, Cd(4) is bonded to one O(14), one O(24), one O(3), and one O(6) atom to form distorted CdO4 tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra,  a cornercorner with one S(2)O4 tetrahedra,  a cornercorner with one S(4)O4 tetrahedra, and  a cornercorner with one S(6)O4 tetrahedra. In the fifth Cd site, Cd(5) is bonded in a 6-coordinate geometry to one O(15), one O(2), one O(21), one O(30), one O(34), and one O(7) atom. In the sixth Cd site, Cd(6) is bonded in a 6-coordinate geometry to one O(1), one O(16), one O(22), one O(29), one O(33), and one O(8) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra and  a cornercorner with one Cd(3)O4 trigonal pyramid. In the second S site, S(2) is bonded to one O(3), one O(4), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra and  a cornercorner with one Cd(3)O4 trigonal pyramid. In the third S site, S(3) is bonded to one O(13), one O(17), one O(21), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(3)O4 trigonal pyramid. In the fourth S site, S(4) is bonded to one O(10), one O(14), one O(18), and one O(22) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra. In the fifth S site, S(5) is bonded to one O(11), one O(15), one O(19), and one O(23) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(3)O4 trigonal pyramid. In the sixth S site, S(6) is bonded to one O(12), one O(16), one O(20), and one O(24) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(6) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(5) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Cd(4) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Cd(3) and one S(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cd(3) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cd(4) and one S(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cd(5) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cd(6) and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Cd(2) and one S(5) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Cd(2) and one S(6) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Cd(3) and one S(3) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Cd(4) and one S(4) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Cd(5) and one S(5) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Cd(6) and one S(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one S(3) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one S(4) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(5) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(6) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Cd(5) and one S(3) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Cd(6) and one S(4) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Cd(3) and one S(5) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Cd(4) and one S(6) atom. In the twenty-fifth O site, O(29) is bonded in a 2-coordinate geometry to one Cd(6) and one O(33) atom. In the twenty-sixth O site, O(30) is bonded in a 2-coordinate geometry to one Cd(5) and one O(34) atom. In the twenty-seventh O site, O(33) is bonded in a distorted L-shaped geometry to one Cd(6) and one O(29) atom. In the twenty-eighth O site, O(34) is bonded in a 2-coordinate geometry to one Cd(5) and one O(30) atom.
Cd3S3O14(O2)3 crystallizes in the triclinic P1 space group. The structure consists of six hydrogen peroxide molecules inside a Cd3S3O14 framework. In the Cd3S3O14 framework, there are six inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a see-saw-like geometry to one O(10), one O(19), one O(20), and one O(9) atom. The Cd(1)-O(10) bond length is 2.22 Å. The Cd(1)-O(19) bond length is 2.19 Å. The Cd(1)-O(20) bond length is 2.19 Å. The Cd(1)-O(9) bond length is 2.20 Å. In the second Cd site, Cd(2) is bonded in a see-saw-like geometry to one O(11), one O(12), one O(17), and one O(18) atom. The Cd(2)-O(11) bond length is 2.19 Å. The Cd(2)-O(12) bond length is 2.20 Å. The Cd(2)-O(17) bond length is 2.20 Å. The Cd(2)-O(18) bond length is 2.21 Å. In the third Cd site, Cd(3) is bonded to one O(13), one O(23), one O(4), and one O(5) atom to form distorted CdO4 trigonal pyramids that share  a cornercorner with one S(1)O4 tetrahedra,  a cornercorner with one S(2)O4 tetrahedra,  a cornercorner with one S(3)O4 tetrahedra, and  a cornercorner with one S(5)O4 tetrahedra. The Cd(3)-O(13) bond length is 2.17 Å. The Cd(3)-O(23) bond length is 2.22 Å. The Cd(3)-O(4) bond length is 2.22 Å. The Cd(3)-O(5) bond length is 2.19 Å. In the fourth Cd site, Cd(4) is bonded to one O(14), one O(24), one O(3), and one O(6) atom to form distorted CdO4 tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra,  a cornercorner with one S(2)O4 tetrahedra,  a cornercorner with one S(4)O4 tetrahedra, and  a cornercorner with one S(6)O4 tetrahedra. The Cd(4)-O(14) bond length is 2.17 Å. The Cd(4)-O(24) bond length is 2.23 Å. The Cd(4)-O(3) bond length is 2.22 Å. The Cd(4)-O(6) bond length is 2.18 Å. In the fifth Cd site, Cd(5) is bonded in a 6-coordinate geometry to one O(15), one O(2), one O(21), one O(30), one O(34), and one O(7) atom. The Cd(5)-O(15) bond length is 2.13 Å. The Cd(5)-O(2) bond length is 2.29 Å. The Cd(5)-O(21) bond length is 2.29 Å. The Cd(5)-O(30) bond length is 2.55 Å. The Cd(5)-O(34) bond length is 2.55 Å. The Cd(5)-O(7) bond length is 2.14 Å. In the sixth Cd site, Cd(6) is bonded in a 6-coordinate geometry to one O(1), one O(16), one O(22), one O(29), one O(33), and one O(8) atom. The Cd(6)-O(1) bond length is 2.27 Å. The Cd(6)-O(16) bond length is 2.14 Å. The Cd(6)-O(22) bond length is 2.29 Å. The Cd(6)-O(29) bond length is 2.59 Å. The Cd(6)-O(33) bond length is 2.56 Å. The Cd(6)-O(8) bond length is 2.14 Å. There are six inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra and  a cornercorner with one Cd(3)O4 trigonal pyramid. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(5) bond length is 1.49 Å. The S(1)-O(6) bond length is 1.50 Å. In the second S site, S(2) is bonded to one O(3), one O(4), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra and  a cornercorner with one Cd(3)O4 trigonal pyramid. The S(2)-O(3) bond length is 1.48 Å. The S(2)-O(4) bond length is 1.48 Å. The S(2)-O(7) bond length is 1.49 Å. The S(2)-O(8) bond length is 1.49 Å. In the third S site, S(3) is bonded to one O(13), one O(17), one O(21), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(3)O4 trigonal pyramid. The S(3)-O(13) bond length is 1.49 Å. The S(3)-O(17) bond length is 1.48 Å. The S(3)-O(21) bond length is 1.48 Å. The S(3)-O(9) bond length is 1.50 Å. In the fourth S site, S(4) is bonded to one O(10), one O(14), one O(18), and one O(22) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra. The S(4)-O(10) bond length is 1.49 Å. The S(4)-O(14) bond length is 1.49 Å. The S(4)-O(18) bond length is 1.48 Å. The S(4)-O(22) bond length is 1.49 Å. In the fifth S site, S(5) is bonded to one O(11), one O(15), one O(19), and one O(23) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(3)O4 trigonal pyramid. The S(5)-O(11) bond length is 1.49 Å. The S(5)-O(15) bond length is 1.48 Å. The S(5)-O(19) bond length is 1.48 Å. The S(5)-O(23) bond length is 1.49 Å. In the sixth S site, S(6) is bonded to one O(12), one O(16), one O(20), and one O(24) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(4)O4 tetrahedra. The S(6)-O(12) bond length is 1.49 Å. The S(6)-O(16) bond length is 1.48 Å. The S(6)-O(20) bond length is 1.48 Å. The S(6)-O(24) bond length is 1.48 Å. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(6) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(5) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Cd(4) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Cd(3) and one S(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cd(3) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cd(4) and one S(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cd(5) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cd(6) and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Cd(2) and one S(5) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Cd(2) and one S(6) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Cd(3) and one S(3) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Cd(4) and one S(4) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Cd(5) and one S(5) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Cd(6) and one S(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one S(3) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one S(4) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one S(5) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(6) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Cd(5) and one S(3) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Cd(6) and one S(4) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Cd(3) and one S(5) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Cd(4) and one S(6) atom. In the twenty-fifth O site, O(29) is bonded in a 2-coordinate geometry to one Cd(6) and one O(33) atom. The O(29)-O(33) bond length is 1.24 Å. In the twenty-sixth O site, O(30) is bonded in a 2-coordinate geometry to one Cd(5) and one O(34) atom. The O(30)-O(34) bond length is 1.24 Å. In the twenty-seventh O site, O(33) is bonded in a distorted L-shaped geometry to one Cd(6) and one O(29) atom. In the twenty-eighth O site, O(34) is bonded in a 2-coordinate geometry to one Cd(5) and one O(30) atom.