TbOF is beta Vanadium nitride-derived structured and crystallizes in the monoclinic C2/m space group. Tb(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing TbO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-34°. O(1) is bonded in a T-shaped geometry to three equivalent Tb(1) atoms. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Tb(1) atoms.
TbOF is beta Vanadium nitride-derived structured and crystallizes in the monoclinic C2/m space group. Tb(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing TbO3F3 octahedra. The corner-sharing octahedral tilt angles range from 22-34°. There are a spread of Tb(1)-O(1) bond distances ranging from 2.17-2.22 Å. There are two shorter (2.30 Å) and one longer (2.45 Å) Tb(1)-F(1) bond length. O(1) is bonded in a T-shaped geometry to three equivalent Tb(1) atoms. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Tb(1) atoms.