Zr2Pd2In crystallizes in the tetragonal P4_2/mnm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. In the second Zr site, Zr(2) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. Pd(1) is bonded in a 10-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), two equivalent Pd(1), and two equivalent In(1) atoms. In(1) is bonded in a 12-coordinate geometry to four equivalent Zr(1), four equivalent Zr(2), and four equivalent Pd(1) atoms.
Zr2Pd2In crystallizes in the tetragonal P4_2/mnm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. There are two shorter (2.91 Å) and four longer (3.07 Å) Zr(1)-Pd(1) bond lengths. All Zr(1)-In(1) bond lengths are 3.53 Å. In the second Zr site, Zr(2) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. There are two shorter (2.93 Å) and four longer (3.02 Å) Zr(2)-Pd(1) bond lengths. All Zr(2)-In(1) bond lengths are 3.44 Å. Pd(1) is bonded in a 10-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), two equivalent Pd(1), and two equivalent In(1) atoms. There is one shorter (2.90 Å) and one longer (3.20 Å) Pd(1)-Pd(1) bond length. Both Pd(1)-In(1) bond lengths are 3.16 Å. In(1) is bonded in a 12-coordinate geometry to four equivalent Zr(1), four equivalent Zr(2), and four equivalent Pd(1) atoms.