Zr4AgZn crystallizes in the cubic F-43m space group. There are three inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent Zn(1) atoms. In the second Zr site, Zr(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. In the third Zr site, Zr(3) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. Ag(1) is bonded in a 12-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), three equivalent Zr(3), and three equivalent Ag(1) atoms. Zn(1) is bonded in a 9-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), and three equivalent Zr(3) atoms.
Zr4AgZn crystallizes in the cubic F-43m space group. There are three inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent Zn(1) atoms. All Zr(1)-Ag(1) bond lengths are 2.83 Å. All Zr(1)-Zn(1) bond lengths are 2.75 Å. In the second Zr site, Zr(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. Both Zr(2)-Ag(1) bond lengths are 3.28 Å. Both Zr(2)-Zn(1) bond lengths are 2.83 Å. In the third Zr site, Zr(3) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. Both Zr(3)-Ag(1) bond lengths are 2.99 Å. Both Zr(3)-Zn(1) bond lengths are 3.23 Å. Ag(1) is bonded in a 12-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), three equivalent Zr(3), and three equivalent Ag(1) atoms. All Ag(1)-Ag(1) bond lengths are 3.00 Å. Zn(1) is bonded in a 9-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), and three equivalent Zr(3) atoms.