Nd3La(GaO3)4 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pm space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the third Nd site, Nd(3) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(8) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 25-29°. In the second Ga site, Ga(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 26-29°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Nd(1), one La(1), and two equivalent Ga(2) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Nd(1), one La(1), and two equivalent Ga(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Nd(2), one Nd(3), and two equivalent Ga(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Nd(2), one Nd(3), and two equivalent Ga(1) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Nd(1), one Nd(3), one La(1), one Ga(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Nd(1), one Nd(2), one La(1), one Ga(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Nd(1), one Nd(2), one Nd(3), one Ga(1), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Nd(2), one Nd(3), one La(1), one Ga(1), and one Ga(2) atom.
Nd3La(GaO3)4 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pm space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. The Nd(1)-O(1) bond length is 2.37 Å. The Nd(1)-O(2) bond length is 2.46 Å. Both Nd(1)-O(5) bond lengths are 2.40 Å. Both Nd(1)-O(6) bond lengths are 2.62 Å. Both Nd(1)-O(7) bond lengths are 2.76 Å. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. The Nd(2)-O(3) bond length is 2.46 Å. The Nd(2)-O(4) bond length is 2.37 Å. Both Nd(2)-O(6) bond lengths are 2.73 Å. Both Nd(2)-O(7) bond lengths are 2.60 Å. Both Nd(2)-O(8) bond lengths are 2.41 Å. In the third Nd site, Nd(3) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms. The Nd(3)-O(3) bond length is 2.37 Å. The Nd(3)-O(4) bond length is 2.46 Å. Both Nd(3)-O(5) bond lengths are 2.72 Å. Both Nd(3)-O(7) bond lengths are 2.41 Å. Both Nd(3)-O(8) bond lengths are 2.61 Å. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(8) atoms. The La(1)-O(1) bond length is 2.54 Å. The La(1)-O(2) bond length is 2.40 Å. Both La(1)-O(5) bond lengths are 2.68 Å. Both La(1)-O(6) bond lengths are 2.42 Å. Both La(1)-O(8) bond lengths are 2.77 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 25-29°. The Ga(1)-O(2) bond length is 2.02 Å. The Ga(1)-O(4) bond length is 2.00 Å. The Ga(1)-O(5) bond length is 2.03 Å. The Ga(1)-O(6) bond length is 2.00 Å. The Ga(1)-O(7) bond length is 2.03 Å. The Ga(1)-O(8) bond length is 2.01 Å. In the second Ga site, Ga(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 26-29°. The Ga(2)-O(1) bond length is 2.02 Å. The Ga(2)-O(3) bond length is 2.00 Å. The Ga(2)-O(5) bond length is 2.00 Å. The Ga(2)-O(6) bond length is 2.03 Å. The Ga(2)-O(7) bond length is 2.02 Å. The Ga(2)-O(8) bond length is 2.02 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Nd(1), one La(1), and two equivalent Ga(2) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Nd(1), one La(1), and two equivalent Ga(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Nd(2), one Nd(3), and two equivalent Ga(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Nd(2), one Nd(3), and two equivalent Ga(1) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Nd(1), one Nd(3), one La(1), one Ga(1), and one Ga(2) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Nd(1), one Nd(2), one La(1), one Ga(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Nd(1), one Nd(2), one Nd(3), one Ga(1), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Nd(2), one Nd(3), one La(1), one Ga(1), and one Ga(2) atom.