CaTiO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Ca(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-27°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ca(1) and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ca(1) and two equivalent Ti(1) atoms.
CaTiO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Ca(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. The Ca(1)-O(2) bond length is 2.33 Å. All Ca(1)-O(1) bond lengths are 2.44 Å. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 20-27°. Both Ti(1)-O(2) bond lengths are 1.96 Å. All Ti(1)-O(1) bond lengths are 1.95 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ca(1) and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ca(1) and two equivalent Ti(1) atoms.