Cs2Pu(OCl2)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one Pu(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pu(1) atom.
Cs2Pu(OCl2)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. There are a spread of Cs(1)-Cl(1) bond distances ranging from 3.55-3.88 Å. Pu(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. Both Pu(1)-O(1) bond lengths are 1.78 Å. All Pu(1)-Cl(1) bond lengths are 2.67 Å. O(1) is bonded in a single-bond geometry to one Pu(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pu(1) atom.