NaV2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded to four equivalent O(1) atoms to form NaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Na(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. O(1) is bonded to one Na(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing ONaV3 tetrahedra.
NaV2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded to four equivalent O(1) atoms to form NaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. All Na(1)-O(1) bond lengths are 2.16 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Na(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. All V(1)-O(1) bond lengths are 2.00 Å. O(1) is bonded to one Na(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing ONaV3 tetrahedra.