Mn3Co3(TeO6)2 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(11), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(3), one O(4), one O(7), and one O(9) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(2)O6 pentagonal pyramid, and edges with two equivalent Co(3)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 38-43°. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(2), one O(5), one O(7), and one O(8) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(2)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(2)O6 pentagonal pyramid,  an edgeedge with one Co(3)O6 pentagonal pyramid, and edges with two equivalent Co(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 37-43°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(5), and one O(7) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(2)O6 pentagonal pyramids, corners with two equivalent Co(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and edges with two equivalent Mn(3)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 35-43°. In the second Co site, Co(2) is bonded to one O(11), one O(12), one O(3), one O(5), one O(6), and one O(8) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(1)O6 pentagonal pyramids, corners with two equivalent Co(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and  an edgeedge with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 36-45°. In the third Co site, Co(3) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(1)O6 pentagonal pyramids, corners with two equivalent Co(2)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(3)O6 pentagonal pyramid, and edges with two equivalent Mn(2)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 34-44°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TeO6 octahedra that share  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(3)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(2)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Mn(3)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(2)O6 pentagonal pyramid, and  an edgeedge with one Co(3)O6 pentagonal pyramid. In the second Te site, Te(2) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(3)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(2)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Mn(3)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(2)O6 pentagonal pyramid, and  an edgeedge with one Co(3)O6 pentagonal pyramid. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(2), one Mn(3), one Co(3), and one Te(1) atom. In the second O site, O(2) is bonded to one Mn(1), one Mn(3), one Co(1), and one Te(1) atom to form distorted OMn2CoTe trigonal pyramids that share  a cornercorner with one O(9)Mn2CoTe tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra,  a cornercorner with one O(5)MnCo2Te trigonal pyramid, corners with two equivalent O(3)Mn2CoTe trigonal pyramids,  an edgeedge with one O(11)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te trigonal pyramid,  an edgeedge with one O(5)MnCo2Te trigonal pyramid, and  an edgeedge with one O(6)MnCo2Te trigonal pyramid. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Co(2), and one Te(1) atom to form distorted OMn2CoTe trigonal pyramids that share  a cornercorner with one O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra,  a cornercorner with one O(6)MnCo2Te trigonal pyramid, corners with two equivalent O(2)Mn2CoTe trigonal pyramids,  an edgeedge with one O(12)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te trigonal pyramid,  an edgeedge with one O(5)MnCo2Te trigonal pyramid, and  an edgeedge with one O(6)MnCo2Te trigonal pyramid. In the fourth O site, O(4) is bonded to one Mn(2), one Co(1), one Co(3), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(11)MnCo2Te tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra, corners with two equivalent O(5)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(2)Mn2CoTe trigonal pyramid, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid. In the fifth O site, O(5) is bonded to one Mn(3), one Co(1), one Co(2), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(12)MnCo2Te tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra,  a cornercorner with one O(2)Mn2CoTe trigonal pyramid, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(2)Mn2CoTe trigonal pyramid, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid. In the sixth O site, O(6) is bonded to one Mn(1), one Co(2), one Co(3), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(10)MnCo2Te tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra,  a cornercorner with one O(3)Mn2CoTe trigonal pyramid, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(2)Mn2CoTe trigonal pyramid, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid. In the seventh O site, O(7) is bonded to one Mn(2), one Mn(3), one Co(1), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(10)MnCo2Te tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra,  a cornercorner with one O(3)Mn2CoTe trigonal pyramid, corners with two equivalent O(2)Mn2CoTe trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(10)MnCo2Te tetrahedra, and  an edgeedge with one O(4)MnCo2Te trigonal pyramid. In the eighth O site, O(8) is bonded to one Mn(1), one Mn(3), one Co(2), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(11)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra, corners with two equivalent O(2)Mn2CoTe trigonal pyramids, corners with two equivalent O(3)Mn2CoTe trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(11)MnCo2Te tetrahedra, and  an edgeedge with one O(5)MnCo2Te trigonal pyramid. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(2), one Co(3), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(12)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra,  a cornercorner with one O(2)Mn2CoTe trigonal pyramid, corners with two equivalent O(3)Mn2CoTe trigonal pyramids, corners with two equivalent O(4)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(12)MnCo2Te tetrahedra, and  an edgeedge with one O(6)MnCo2Te trigonal pyramid. In the tenth O site, O(10) is bonded to one Mn(3), one Co(1), one Co(3), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra,  a cornercorner with one O(6)MnCo2Te trigonal pyramid, corners with two equivalent O(2)Mn2CoTe trigonal pyramids, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(11)MnCo2Te tetrahedra, and  an edgeedge with one O(12)MnCo2Te tetrahedra. In the eleventh O site, O(11) is bonded to one Mn(1), one Co(1), one Co(2), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(8)Mn2CoTe tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra,  a cornercorner with one O(4)MnCo2Te trigonal pyramid, corners with two equivalent O(3)Mn2CoTe trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(10)MnCo2Te tetrahedra,  an edgeedge with one O(12)MnCo2Te tetrahedra, and  an edgeedge with one O(2)Mn2CoTe trigonal pyramid. In the twelfth O site, O(12) is bonded to one Mn(2), one Co(2), one Co(3), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(9)Mn2CoTe tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra,  a cornercorner with one O(5)MnCo2Te trigonal pyramid, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(10)MnCo2Te tetrahedra,  an edgeedge with one O(11)MnCo2Te tetrahedra, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid.
Mn3Co3(TeO6)2 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(11), one O(2), one O(3), one O(6), one O(8), and one O(9) atom. The Mn(1)-O(11) bond length is 2.12 Å. The Mn(1)-O(2) bond length is 2.40 Å. The Mn(1)-O(3) bond length is 2.14 Å. The Mn(1)-O(6) bond length is 2.22 Å. The Mn(1)-O(8) bond length is 2.26 Å. The Mn(1)-O(9) bond length is 2.21 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(3), one O(4), one O(7), and one O(9) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(2)O6 pentagonal pyramid, and edges with two equivalent Co(3)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 38-43°. The Mn(2)-O(1) bond length is 2.13 Å. The Mn(2)-O(12) bond length is 2.12 Å. The Mn(2)-O(3) bond length is 2.38 Å. The Mn(2)-O(4) bond length is 2.22 Å. The Mn(2)-O(7) bond length is 2.22 Å. The Mn(2)-O(9) bond length is 2.25 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(2), one O(5), one O(7), and one O(8) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(2)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(2)O6 pentagonal pyramid,  an edgeedge with one Co(3)O6 pentagonal pyramid, and edges with two equivalent Co(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 37-43°. The Mn(3)-O(1) bond length is 2.40 Å. The Mn(3)-O(10) bond length is 2.12 Å. The Mn(3)-O(2) bond length is 2.14 Å. The Mn(3)-O(5) bond length is 2.21 Å. The Mn(3)-O(7) bond length is 2.26 Å. The Mn(3)-O(8) bond length is 2.21 Å. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(5), and one O(7) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(2)O6 pentagonal pyramids, corners with two equivalent Co(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and edges with two equivalent Mn(3)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 35-43°. The Co(1)-O(10) bond length is 2.21 Å. The Co(1)-O(11) bond length is 2.21 Å. The Co(1)-O(2) bond length is 2.09 Å. The Co(1)-O(4) bond length is 2.37 Å. The Co(1)-O(5) bond length is 2.07 Å. The Co(1)-O(7) bond length is 2.10 Å. In the second Co site, Co(2) is bonded to one O(11), one O(12), one O(3), one O(5), one O(6), and one O(8) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(1)O6 pentagonal pyramids, corners with two equivalent Co(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and  an edgeedge with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 36-45°. The Co(2)-O(11) bond length is 2.20 Å. The Co(2)-O(12) bond length is 2.19 Å. The Co(2)-O(3) bond length is 2.10 Å. The Co(2)-O(5) bond length is 2.37 Å. The Co(2)-O(6) bond length is 2.08 Å. The Co(2)-O(8) bond length is 2.12 Å. In the third Co site, Co(3) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(1)O6 pentagonal pyramids, corners with two equivalent Co(2)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(3)O6 pentagonal pyramid, and edges with two equivalent Mn(2)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 34-44°. The Co(3)-O(1) bond length is 2.12 Å. The Co(3)-O(10) bond length is 2.18 Å. The Co(3)-O(12) bond length is 2.18 Å. The Co(3)-O(4) bond length is 2.08 Å. The Co(3)-O(6) bond length is 2.32 Å. The Co(3)-O(9) bond length is 2.15 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TeO6 octahedra that share  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(3)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(2)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Mn(3)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(2)O6 pentagonal pyramid, and  an edgeedge with one Co(3)O6 pentagonal pyramid. The Te(1)-O(1) bond length is 1.96 Å. The Te(1)-O(2) bond length is 1.96 Å. The Te(1)-O(3) bond length is 1.97 Å. The Te(1)-O(4) bond length is 1.96 Å. The Te(1)-O(5) bond length is 1.96 Å. The Te(1)-O(6) bond length is 1.97 Å. In the second Te site, Te(2) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Mn(3)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(2)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Mn(3)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(2)O6 pentagonal pyramid, and  an edgeedge with one Co(3)O6 pentagonal pyramid. The Te(2)-O(10) bond length is 1.96 Å. The Te(2)-O(11) bond length is 1.95 Å. The Te(2)-O(12) bond length is 1.96 Å. The Te(2)-O(7) bond length is 1.97 Å. The Te(2)-O(8) bond length is 1.97 Å. The Te(2)-O(9) bond length is 1.96 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(2), one Mn(3), one Co(3), and one Te(1) atom. In the second O site, O(2) is bonded to one Mn(1), one Mn(3), one Co(1), and one Te(1) atom to form distorted OMn2CoTe trigonal pyramids that share  a cornercorner with one O(9)Mn2CoTe tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra,  a cornercorner with one O(5)MnCo2Te trigonal pyramid, corners with two equivalent O(3)Mn2CoTe trigonal pyramids,  an edgeedge with one O(11)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te trigonal pyramid,  an edgeedge with one O(5)MnCo2Te trigonal pyramid, and  an edgeedge with one O(6)MnCo2Te trigonal pyramid. In the third O site, O(3) is bonded to one Mn(1), one Mn(2), one Co(2), and one Te(1) atom to form distorted OMn2CoTe trigonal pyramids that share  a cornercorner with one O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra,  a cornercorner with one O(6)MnCo2Te trigonal pyramid, corners with two equivalent O(2)Mn2CoTe trigonal pyramids,  an edgeedge with one O(12)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te trigonal pyramid,  an edgeedge with one O(5)MnCo2Te trigonal pyramid, and  an edgeedge with one O(6)MnCo2Te trigonal pyramid. In the fourth O site, O(4) is bonded to one Mn(2), one Co(1), one Co(3), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(11)MnCo2Te tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra, corners with two equivalent O(5)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(2)Mn2CoTe trigonal pyramid, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid. In the fifth O site, O(5) is bonded to one Mn(3), one Co(1), one Co(2), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(12)MnCo2Te tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra,  a cornercorner with one O(2)Mn2CoTe trigonal pyramid, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(2)Mn2CoTe trigonal pyramid, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid. In the sixth O site, O(6) is bonded to one Mn(1), one Co(2), one Co(3), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(10)MnCo2Te tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra,  a cornercorner with one O(3)Mn2CoTe trigonal pyramid, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(2)Mn2CoTe trigonal pyramid, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid. In the seventh O site, O(7) is bonded to one Mn(2), one Mn(3), one Co(1), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(10)MnCo2Te tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra,  a cornercorner with one O(3)Mn2CoTe trigonal pyramid, corners with two equivalent O(2)Mn2CoTe trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(10)MnCo2Te tetrahedra, and  an edgeedge with one O(4)MnCo2Te trigonal pyramid. In the eighth O site, O(8) is bonded to one Mn(1), one Mn(3), one Co(2), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(11)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(12)MnCo2Te tetrahedra, corners with two equivalent O(2)Mn2CoTe trigonal pyramids, corners with two equivalent O(3)Mn2CoTe trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(11)MnCo2Te tetrahedra, and  an edgeedge with one O(5)MnCo2Te trigonal pyramid. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(2), one Co(3), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(12)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te tetrahedra, corners with two equivalent O(11)MnCo2Te tetrahedra,  a cornercorner with one O(2)Mn2CoTe trigonal pyramid, corners with two equivalent O(3)Mn2CoTe trigonal pyramids, corners with two equivalent O(4)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(12)MnCo2Te tetrahedra, and  an edgeedge with one O(6)MnCo2Te trigonal pyramid. In the tenth O site, O(10) is bonded to one Mn(3), one Co(1), one Co(3), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra,  a cornercorner with one O(6)MnCo2Te trigonal pyramid, corners with two equivalent O(2)Mn2CoTe trigonal pyramids, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids,  an edgeedge with one O(7)Mn2CoTe tetrahedra,  an edgeedge with one O(11)MnCo2Te tetrahedra, and  an edgeedge with one O(12)MnCo2Te tetrahedra. In the eleventh O site, O(11) is bonded to one Mn(1), one Co(1), one Co(2), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(8)Mn2CoTe tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(9)Mn2CoTe tetrahedra,  a cornercorner with one O(4)MnCo2Te trigonal pyramid, corners with two equivalent O(3)Mn2CoTe trigonal pyramids, corners with two equivalent O(5)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(8)Mn2CoTe tetrahedra,  an edgeedge with one O(10)MnCo2Te tetrahedra,  an edgeedge with one O(12)MnCo2Te tetrahedra, and  an edgeedge with one O(2)Mn2CoTe trigonal pyramid. In the twelfth O site, O(12) is bonded to one Mn(2), one Co(2), one Co(3), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(9)Mn2CoTe tetrahedra, corners with two equivalent O(7)Mn2CoTe tetrahedra, corners with two equivalent O(8)Mn2CoTe tetrahedra,  a cornercorner with one O(5)MnCo2Te trigonal pyramid, corners with two equivalent O(4)MnCo2Te trigonal pyramids, corners with two equivalent O(6)MnCo2Te trigonal pyramids,  an edgeedge with one O(9)Mn2CoTe tetrahedra,  an edgeedge with one O(10)MnCo2Te tetrahedra,  an edgeedge with one O(11)MnCo2Te tetrahedra, and  an edgeedge with one O(3)Mn2CoTe trigonal pyramid.