TiBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight titanium(iv) bromide molecules. Ti(1) is bonded in a tetrahedral geometry to four equivalent Br(1,2) atoms. Br(1,2) is bonded in a single-bond geometry to one Ti(1) atom.
TiBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight titanium(iv) bromide molecules. Ti(1) is bonded in a tetrahedral geometry to four equivalent Br(1,2) atoms. There is one shorter (2.32 Å) and three longer (2.33 Å) Ti(1)-Br(1,2) bond lengths. Br(1,2) is bonded in a single-bond geometry to one Ti(1) atom.