RbP2(HO2)3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 10-coordinate geometry to one H(3), one O(3), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one Rb(1), one O(1), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Rb(1), one P(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(2), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Rb(1), one P(2), and one H(3) atom.
RbP2(HO2)3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 10-coordinate geometry to one H(3), one O(3), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. The Rb(1)-H(3) bond length is 3.10 Å. The Rb(1)-O(3) bond length is 3.40 Å. The Rb(1)-O(5) bond length is 3.05 Å. The Rb(1)-O(6) bond length is 3.29 Å. There is one shorter (3.18 Å) and one longer (3.21 Å) Rb(1)-O(1) bond length. There is one shorter (3.21 Å) and one longer (3.27 Å) Rb(1)-O(2) bond length. There is one shorter (3.09 Å) and one longer (3.38 Å) Rb(1)-O(4) bond length. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The P(1)-O(1) bond length is 1.52 Å. The P(1)-O(2) bond length is 1.56 Å. The P(1)-O(3) bond length is 1.57 Å. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. The P(2)-O(4) bond length is 1.53 Å. The P(2)-O(5) bond length is 1.53 Å. The P(2)-O(6) bond length is 1.59 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. The H(1)-O(2) bond length is 1.13 Å. The H(1)-O(5) bond length is 1.30 Å. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. The H(2)-O(3) bond length is 1.07 Å. The H(2)-O(4) bond length is 1.42 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one Rb(1), one O(1), and one O(6) atom. The H(3)-O(1) bond length is 1.54 Å. The H(3)-O(6) bond length is 1.03 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Rb(1), one P(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(2), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Rb(1), one P(2), and one H(3) atom.