K5In(MoO4)4 crystallizes in the monoclinic Cc space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(16), one O(2), one O(3), one O(5), one O(8), and one O(9) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(14), one O(15), one O(2), one O(3), one O(5), and one O(8) atom. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(16), one O(4), one O(6), one O(7), and two equivalent O(10) atoms. In the fourth K site, K(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(16), one O(3), and one O(4) atom. In the fifth K site, K(5) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(15), one O(3), one O(8), one O(9), and two equivalent O(2) atoms. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 45°. In the second Mo site, Mo(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. In the third Mo site, Mo(3) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 43°. In the fourth Mo site, Mo(4) is bonded to one O(13), one O(14), one O(15), and one O(16) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-48°. In(1) is bonded to one O(12), one O(14), one O(15), one O(4), one O(6), and one O(7) atom to form InO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one K(3), and one Mo(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(1), one K(2), two equivalent K(5), and one Mo(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(4), one K(5), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one K(3), one K(4), one Mo(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one K(2), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one K(1), one K(2), one K(5), and one Mo(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one K(1), one K(5), and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one K(1), one K(4), two equivalent K(3), and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(3), one K(4), and one Mo(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(3), and one In(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one K(1), one K(4), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one K(1), one K(3), one K(4), and one Mo(4) atom.
K5In(MoO4)4 crystallizes in the monoclinic Cc space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(16), one O(2), one O(3), one O(5), one O(8), and one O(9) atom. The K(1)-O(1) bond length is 3.07 Å. The K(1)-O(10) bond length is 3.03 Å. The K(1)-O(11) bond length is 2.98 Å. The K(1)-O(13) bond length is 3.00 Å. The K(1)-O(16) bond length is 3.38 Å. The K(1)-O(2) bond length is 2.93 Å. The K(1)-O(3) bond length is 3.01 Å. The K(1)-O(5) bond length is 2.93 Å. The K(1)-O(8) bond length is 3.30 Å. The K(1)-O(9) bond length is 3.05 Å. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(14), one O(15), one O(2), one O(3), one O(5), and one O(8) atom. The K(2)-O(11) bond length is 2.97 Å. The K(2)-O(12) bond length is 3.03 Å. The K(2)-O(14) bond length is 3.21 Å. The K(2)-O(15) bond length is 3.22 Å. The K(2)-O(2) bond length is 2.80 Å. The K(2)-O(3) bond length is 2.73 Å. The K(2)-O(5) bond length is 2.60 Å. The K(2)-O(8) bond length is 2.80 Å. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(16), one O(4), one O(6), one O(7), and two equivalent O(10) atoms. The K(3)-O(1) bond length is 2.68 Å. The K(3)-O(11) bond length is 3.07 Å. The K(3)-O(16) bond length is 2.90 Å. The K(3)-O(4) bond length is 3.07 Å. The K(3)-O(6) bond length is 2.97 Å. The K(3)-O(7) bond length is 3.00 Å. There is one shorter (2.88 Å) and one longer (3.23 Å) K(3)-O(10) bond length. In the fourth K site, K(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(16), one O(3), and one O(4) atom. The K(4)-O(10) bond length is 2.82 Å. The K(4)-O(11) bond length is 2.69 Å. The K(4)-O(13) bond length is 2.61 Å. The K(4)-O(16) bond length is 2.71 Å. The K(4)-O(3) bond length is 2.90 Å. The K(4)-O(4) bond length is 2.95 Å. In the fifth K site, K(5) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(15), one O(3), one O(8), one O(9), and two equivalent O(2) atoms. The K(5)-O(12) bond length is 3.06 Å. The K(5)-O(14) bond length is 2.96 Å. The K(5)-O(15) bond length is 2.95 Å. The K(5)-O(3) bond length is 3.02 Å. The K(5)-O(8) bond length is 2.85 Å. The K(5)-O(9) bond length is 2.73 Å. There is one shorter (2.91 Å) and one longer (3.21 Å) K(5)-O(2) bond length. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 45°. The Mo(1)-O(1) bond length is 1.77 Å. The Mo(1)-O(2) bond length is 1.80 Å. The Mo(1)-O(3) bond length is 1.79 Å. The Mo(1)-O(4) bond length is 1.86 Å. In the second Mo site, Mo(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. The Mo(2)-O(5) bond length is 1.75 Å. The Mo(2)-O(6) bond length is 1.84 Å. The Mo(2)-O(7) bond length is 1.84 Å. The Mo(2)-O(8) bond length is 1.78 Å. In the third Mo site, Mo(3) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 43°. The Mo(3)-O(10) bond length is 1.80 Å. The Mo(3)-O(11) bond length is 1.79 Å. The Mo(3)-O(12) bond length is 1.87 Å. The Mo(3)-O(9) bond length is 1.77 Å. In the fourth Mo site, Mo(4) is bonded to one O(13), one O(14), one O(15), and one O(16) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-48°. The Mo(4)-O(13) bond length is 1.75 Å. The Mo(4)-O(14) bond length is 1.84 Å. The Mo(4)-O(15) bond length is 1.84 Å. The Mo(4)-O(16) bond length is 1.78 Å. In(1) is bonded to one O(12), one O(14), one O(15), one O(4), one O(6), and one O(7) atom to form InO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. The In(1)-O(12) bond length is 2.17 Å. The In(1)-O(14) bond length is 2.20 Å. The In(1)-O(15) bond length is 2.22 Å. The In(1)-O(4) bond length is 2.17 Å. The In(1)-O(6) bond length is 2.19 Å. The In(1)-O(7) bond length is 2.22 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one K(3), and one Mo(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(1), one K(2), two equivalent K(5), and one Mo(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(4), one K(5), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one K(3), one K(4), one Mo(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one K(2), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one K(1), one K(2), one K(5), and one Mo(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one K(1), one K(5), and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one K(1), one K(4), two equivalent K(3), and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(3), one K(4), and one Mo(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(3), and one In(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one K(1), one K(4), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one K(1), one K(3), one K(4), and one Mo(4) atom.