WBiO2 crystallizes in the tetragonal I4_1/amd space group. W(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form distorted edge-sharing BiO6 octahedra. O(1) is bonded in a 5-coordinate geometry to two equivalent W(1) and three equivalent Bi(1) atoms.
WBiO2 crystallizes in the tetragonal I4_1/amd space group. W(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. All W(1)-O(1) bond lengths are 2.20 Å. Bi(1) is bonded to six equivalent O(1) atoms to form distorted edge-sharing BiO6 octahedra. There are two shorter (2.43 Å) and four longer (2.67 Å) Bi(1)-O(1) bond lengths. O(1) is bonded in a 5-coordinate geometry to two equivalent W(1) and three equivalent Bi(1) atoms.