CsCo(CO)4 crystallizes in the tetragonal I-4 space group. Cs(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Co(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. O(1) is bonded in a distorted single-bond geometry to one Cs(1) and one C(1) atom.
CsCo(CO)4 crystallizes in the tetragonal I-4 space group. Cs(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Cs(1)-O(1) bond lengths are 3.24 Å. Co(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. All Co(1)-C(1) bond lengths are 1.74 Å. C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. The C(1)-O(1) bond length is 1.18 Å. O(1) is bonded in a distorted single-bond geometry to one Cs(1) and one C(1) atom.