SnNH3F3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight SnNH3F3 clusters. Sn(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. N(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Sn(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Sn(1) and one H(1) atom.
SnNH3F3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight SnNH3F3 clusters. Sn(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. The Sn(1)-F(1) bond length is 2.15 Å. The Sn(1)-F(2) bond length is 2.11 Å. The Sn(1)-F(3) bond length is 2.14 Å. N(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.08 Å. The N(1)-H(2) bond length is 1.05 Å. The N(1)-H(3) bond length is 1.04 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(3) atom. The H(1)-F(3) bond length is 1.54 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Sn(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Sn(1) and one H(1) atom.