Ti3As crystallizes in the cubic Pm-3n space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Ti(1) and four equivalent As(1) atoms. As(1) is bonded to twelve equivalent Ti(1) atoms to form a mixture of edge and face-sharing AsTi12 cuboctahedra.
Ti3As crystallizes in the cubic Pm-3n space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Ti(1) and four equivalent As(1) atoms. Both Ti(1)-Ti(1) bond lengths are 2.51 Å. All Ti(1)-As(1) bond lengths are 2.81 Å. As(1) is bonded to twelve equivalent Ti(1) atoms to form a mixture of edge and face-sharing AsTi12 cuboctahedra.