PrN3O13O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and one PrN3O13 cluster. In the PrN3O13 cluster, Pr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(13), one O(2), one O(4), one O(5), and one O(7) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one N(3) and one O(12) atom. There are thirteen inequivalent O sites. In the first O site, O(13) is bonded in a 2-coordinate geometry to one Pr(1) and one O(10) atom. In the second O site, O(15) is bonded in a single-bond geometry to one O(11) atom. In the third O site, O(1) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(4) is bonded in an L-shaped geometry to one Pr(1) and one N(2) atom. In the seventh O site, O(5) is bonded in an L-shaped geometry to one Pr(1) and one N(2) atom. In the eighth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(7) is bonded in an L-shaped geometry to one Pr(1) and one O(8) atom. In the tenth O site, O(8) is bonded in a single-bond geometry to one O(7) atom. In the eleventh O site, O(10) is bonded in a 2-coordinate geometry to one Pr(1) and one O(13) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Pr(1) and one O(15) atom. In the thirteenth O site, O(12) is bonded in a single-bond geometry to one Pr(1) and one N(3) atom.
PrN3O13O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules and one PrN3O13 cluster. In the PrN3O13 cluster, Pr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(13), one O(2), one O(4), one O(5), and one O(7) atom. The Pr(1)-O(1) bond length is 2.46 Å. The Pr(1)-O(10) bond length is 2.39 Å. The Pr(1)-O(11) bond length is 2.85 Å. The Pr(1)-O(12) bond length is 3.02 Å. The Pr(1)-O(13) bond length is 2.40 Å. The Pr(1)-O(2) bond length is 2.48 Å. The Pr(1)-O(4) bond length is 2.43 Å. The Pr(1)-O(5) bond length is 2.46 Å. The Pr(1)-O(7) bond length is 2.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.31 Å. The N(1)-O(2) bond length is 1.30 Å. The N(1)-O(3) bond length is 1.22 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(2)-O(4) bond length is 1.32 Å. The N(2)-O(5) bond length is 1.30 Å. The N(2)-O(6) bond length is 1.21 Å. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one N(3) and one O(12) atom. The N(3)-N(3) bond length is 1.20 Å. The N(3)-O(12) bond length is 1.22 Å. There are thirteen inequivalent O sites. In the first O site, O(13) is bonded in a 2-coordinate geometry to one Pr(1) and one O(10) atom. The O(13)-O(10) bond length is 1.34 Å. In the second O site, O(15) is bonded in a single-bond geometry to one O(11) atom. The O(15)-O(11) bond length is 1.23 Å. In the third O site, O(1) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(1) atom. In the fourth O site, O(2) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(4) is bonded in an L-shaped geometry to one Pr(1) and one N(2) atom. In the seventh O site, O(5) is bonded in an L-shaped geometry to one Pr(1) and one N(2) atom. In the eighth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(7) is bonded in an L-shaped geometry to one Pr(1) and one O(8) atom. The O(7)-O(8) bond length is 1.24 Å. In the tenth O site, O(8) is bonded in a single-bond geometry to one O(7) atom. In the eleventh O site, O(10) is bonded in a 2-coordinate geometry to one Pr(1) and one O(13) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Pr(1) and one O(15) atom. In the thirteenth O site, O(12) is bonded in a single-bond geometry to one Pr(1) and one N(3) atom.