SbF6(I)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydriodic acid atoms, three I clusters, and three SbF6 clusters. In one of the I clusters, there are two inequivalent I sites. In the first I site, I(6) is bonded in a linear geometry to two equivalent I(7) atoms. In the second I site, I(7) is bonded in a 3-coordinate geometry to one I(6) atom. In two of the I clusters, there are five inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(4) atom. In the second I site, I(2) is bonded in a distorted linear geometry to one I(3) and one I(8) atom. In the third I site, I(3) is bonded in a distorted L-shaped geometry to one I(2) and one I(4) atom. In the fourth I site, I(4) is bonded in a linear geometry to one I(1) and one I(3) atom. In the fifth I site, I(8) is bonded in a 2-coordinate geometry to one I(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(6), one F(7), one F(8), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom.
SbF6(I)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydriodic acid atoms, three I clusters, and three SbF6 clusters. In one of the I clusters, there are two inequivalent I sites. In the first I site, I(6) is bonded in a linear geometry to two equivalent I(7) atoms. Both I(6)-I(7) bond lengths are 2.90 Å. In the second I site, I(7) is bonded in a 3-coordinate geometry to one I(6) atom. In two of the I clusters, there are five inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(4) atom. The I(1)-I(4) bond length is 2.94 Å. In the second I site, I(2) is bonded in a distorted linear geometry to one I(3) and one I(8) atom. The I(2)-I(3) bond length is 2.77 Å. The I(2)-I(8) bond length is 3.10 Å. In the third I site, I(3) is bonded in a distorted L-shaped geometry to one I(2) and one I(4) atom. The I(3)-I(4) bond length is 2.88 Å. In the fourth I site, I(4) is bonded in a linear geometry to one I(1) and one I(3) atom. In the fifth I site, I(8) is bonded in a 2-coordinate geometry to one I(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(6), one F(7), one F(8), and one F(9) atom. The Sb(1)-F(1) bond length is 1.89 Å. The Sb(1)-F(2) bond length is 1.91 Å. The Sb(1)-F(6) bond length is 1.92 Å. The Sb(1)-F(7) bond length is 1.90 Å. The Sb(1)-F(8) bond length is 1.88 Å. The Sb(1)-F(9) bond length is 1.89 Å. There are six inequivalent F sites. In the first F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom.