CePd3In2 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 7-coordinate geometry to three equivalent Pd(1), three equivalent Pd(2), three equivalent Pd(3), and one In(2) atom. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to three equivalent Ce(1), two equivalent Pd(2), two equivalent In(2), and three equivalent In(1) atoms. In the second Pd site, Pd(2) is bonded in a 11-coordinate geometry to three equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(3), two equivalent In(1), and two equivalent In(2) atoms. In the third Pd site, Pd(3) is bonded in a 7-coordinate geometry to three equivalent Ce(1), two equivalent Pd(2), one In(1), and three equivalent In(2) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 5-coordinate geometry to one Pd(3), two equivalent Pd(2), and three equivalent Pd(1) atoms. In the second In site, In(2) is bonded in a 8-coordinate geometry to one Ce(1), two equivalent Pd(1), two equivalent Pd(2), and three equivalent Pd(3) atoms.
CePd3In2 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 7-coordinate geometry to three equivalent Pd(1), three equivalent Pd(2), three equivalent Pd(3), and one In(2) atom. There is one shorter (3.15 Å) and two longer (3.47 Å) Ce(1)-Pd(1) bond lengths. There is one shorter (2.94 Å) and two longer (3.12 Å) Ce(1)-Pd(2) bond lengths. There is one shorter (3.09 Å) and two longer (3.18 Å) Ce(1)-Pd(3) bond lengths. The Ce(1)-In(2) bond length is 3.28 Å. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to three equivalent Ce(1), two equivalent Pd(2), two equivalent In(2), and three equivalent In(1) atoms. Both Pd(1)-Pd(2) bond lengths are 2.88 Å. There is one shorter (2.83 Å) and one longer (3.01 Å) Pd(1)-In(2) bond length. There are two shorter (2.75 Å) and one longer (2.81 Å) Pd(1)-In(1) bond length. In the second Pd site, Pd(2) is bonded in a 11-coordinate geometry to three equivalent Ce(1), two equivalent Pd(1), two equivalent Pd(3), two equivalent In(1), and two equivalent In(2) atoms. There is one shorter (2.84 Å) and one longer (3.07 Å) Pd(2)-Pd(3) bond length. There is one shorter (2.76 Å) and one longer (3.06 Å) Pd(2)-In(1) bond length. Both Pd(2)-In(2) bond lengths are 2.85 Å. In the third Pd site, Pd(3) is bonded in a 7-coordinate geometry to three equivalent Ce(1), two equivalent Pd(2), one In(1), and three equivalent In(2) atoms. The Pd(3)-In(1) bond length is 2.82 Å. There is one shorter (2.75 Å) and two longer (2.76 Å) Pd(3)-In(2) bond lengths. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 5-coordinate geometry to one Pd(3), two equivalent Pd(2), and three equivalent Pd(1) atoms. In the second In site, In(2) is bonded in a 8-coordinate geometry to one Ce(1), two equivalent Pd(1), two equivalent Pd(2), and three equivalent Pd(3) atoms.