Al(SnO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Al(1) is bonded to four equivalent O(1) atoms to form AlO4 tetrahedra that share corners with twelve equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. Sn(1) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Al(1)O4 tetrahedra and edges with six equivalent Sn(1)O6 octahedra. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Al(1) and three equivalent Sn(1) atoms.
Al(SnO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Al(1) is bonded to four equivalent O(1) atoms to form AlO4 tetrahedra that share corners with twelve equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. All Al(1)-O(1) bond lengths are 1.82 Å. Sn(1) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Al(1)O4 tetrahedra and edges with six equivalent Sn(1)O6 octahedra. All Sn(1)-O(1) bond lengths are 2.41 Å. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Al(1) and three equivalent Sn(1) atoms.