MgVMnP2(O4F)2 crystallizes in the triclinic P-1 space group. Mg(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent F(1) atoms to form MgO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with four equivalent P(1)O4 tetrahedra, and faces with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles are 43°. V(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent Mg(1)O4F2 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent F(1) atoms to form MnO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with four equivalent P(1)O4 tetrahedra, and faces with two equivalent Mg(1)O4F2 octahedra. The corner-sharing octahedral tilt angles are 50°. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Mg(1)O4F2 octahedra, corners with two equivalent V(1)O4F2 octahedra, and corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 30-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mg(1), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mg(1), one Mn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. F(1) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one Mn(1) atom.
MgVMnP2(O4F)2 crystallizes in the triclinic P-1 space group. Mg(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent F(1) atoms to form MgO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with four equivalent P(1)O4 tetrahedra, and faces with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles are 43°. Both Mg(1)-O(2) bond lengths are 2.04 Å. Both Mg(1)-O(3) bond lengths are 2.05 Å. Both Mg(1)-F(1) bond lengths are 2.07 Å. V(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent Mg(1)O4F2 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. Both V(1)-O(1) bond lengths are 1.88 Å. Both V(1)-O(4) bond lengths are 2.00 Å. Both V(1)-F(1) bond lengths are 1.99 Å. Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent F(1) atoms to form MnO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with four equivalent P(1)O4 tetrahedra, and faces with two equivalent Mg(1)O4F2 octahedra. The corner-sharing octahedral tilt angles are 50°. Both Mn(1)-O(2) bond lengths are 2.10 Å. Both Mn(1)-O(3) bond lengths are 2.13 Å. Both Mn(1)-F(1) bond lengths are 2.21 Å. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Mg(1)O4F2 octahedra, corners with two equivalent V(1)O4F2 octahedra, and corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 30-47°. The P(1)-O(1) bond length is 1.58 Å. The P(1)-O(2) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.54 Å. The P(1)-O(4) bond length is 1.54 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mg(1), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mg(1), one Mn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. F(1) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one Mn(1) atom.