ZnSnF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sn(1) atom.
ZnSnF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. All Zn(1)-F(1) bond lengths are 2.02 Å. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. All Sn(1)-F(1) bond lengths are 1.98 Å. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sn(1) atom.