Na8SbO3 crystallizes in the cubic Pm-3m space group. Na(1) is bonded to one Sb(1) and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing NaSbO3 tetrahedra. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms. O(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms.
Na8SbO3 crystallizes in the cubic Pm-3m space group. Na(1) is bonded to one Sb(1) and three equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing NaSbO3 tetrahedra. The Na(1)-Sb(1) bond length is 2.88 Å. All Na(1)-O(1) bond lengths are 2.60 Å. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms. O(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms.