KZr2O6Bi crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-69-9 atoms inside a KZr2O6 framework. In the KZr2O6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra and faces with eight equivalent Zr(1)O6 octahedra. Zr(1) is bonded to six equivalent O(1) atoms to form ZrO6 octahedra that share corners with six equivalent Zr(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent K(1) and two equivalent Zr(1) atoms.
KZr2O6Bi crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-69-9 atoms inside a KZr2O6 framework. In the KZr2O6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra and faces with eight equivalent Zr(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.96 Å. Zr(1) is bonded to six equivalent O(1) atoms to form ZrO6 octahedra that share corners with six equivalent Zr(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Zr(1)-O(1) bond lengths are 2.09 Å. O(1) is bonded in a distorted linear geometry to two equivalent K(1) and two equivalent Zr(1) atoms.