DyN3O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and two DyN3O11 clusters. In each DyN3O11 cluster, Dy(1) is bonded in a 8-coordinate geometry to one N(2), one O(10), one O(14), one O(2), one O(4), one O(5), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(5) atom. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one O(2), one O(7), and one O(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one O(13), one O(4), and one O(6) atom. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(14) is bonded in a bent 150 degrees geometry to one Dy(1) and one O(3) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Dy(1) and one N(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one O(14) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Dy(1) and one N(3) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Dy(1) and one N(1) atom. In the seventh O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one N(3) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Dy(1) and one N(2) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Dy(1) and one N(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one N(1) atom.
DyN3O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and two DyN3O11 clusters. In each DyN3O11 cluster, Dy(1) is bonded in a 8-coordinate geometry to one N(2), one O(10), one O(14), one O(2), one O(4), one O(5), one O(6), and one O(9) atom. The Dy(1)-N(2) bond length is 2.09 Å. The Dy(1)-O(10) bond length is 2.22 Å. The Dy(1)-O(14) bond length is 2.74 Å. The Dy(1)-O(2) bond length is 2.46 Å. The Dy(1)-O(4) bond length is 2.92 Å. The Dy(1)-O(5) bond length is 2.97 Å. The Dy(1)-O(6) bond length is 2.60 Å. The Dy(1)-O(9) bond length is 1.91 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(5) atom. The N(1)-O(10) bond length is 1.52 Å. The N(1)-O(11) bond length is 1.35 Å. The N(1)-O(5) bond length is 0.98 Å. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one O(2), one O(7), and one O(9) atom. The N(2)-O(2) bond length is 1.49 Å. The N(2)-O(7) bond length is 0.89 Å. The N(2)-O(9) bond length is 1.78 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one O(13), one O(4), and one O(6) atom. The N(3)-O(13) bond length is 1.46 Å. The N(3)-O(4) bond length is 1.25 Å. The N(3)-O(6) bond length is 1.41 Å. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(14) is bonded in a bent 150 degrees geometry to one Dy(1) and one O(3) atom. The O(14)-O(3) bond length is 1.15 Å. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Dy(1) and one N(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one O(14) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Dy(1) and one N(3) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Dy(1) and one N(1) atom. In the seventh O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one N(3) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Dy(1) and one N(2) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Dy(1) and one N(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one N(1) atom.