K3PdHS2(O3Cl)2 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(2), three equivalent O(1), and two equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent Cl(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. H(1) is bonded in a linear geometry to two equivalent O(3) atoms. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one K(1), one H(1), and one S(1) atom. Cl(1) is bonded to two equivalent K(1), two equivalent K(2), and one Pd(1) atom to form a mixture of distorted corner and face-sharing ClK4Pd square pyramids.
K3PdHS2(O3Cl)2 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(2), three equivalent O(1), and two equivalent Cl(1) atoms. The K(1)-O(3) bond length is 2.81 Å. There is one shorter (2.89 Å) and one longer (2.95 Å) K(1)-O(2) bond length. There are a spread of K(1)-O(1) bond distances ranging from 2.85-2.99 Å. There is one shorter (3.36 Å) and one longer (3.37 Å) K(1)-Cl(1) bond length. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent Cl(1) atoms. Both K(2)-O(2) bond lengths are 2.77 Å. There are two shorter (3.17 Å) and two longer (3.20 Å) K(2)-Cl(1) bond lengths. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. Both Pd(1)-S(1) bond lengths are 2.30 Å. Both Pd(1)-Cl(1) bond lengths are 2.42 Å. H(1) is bonded in a linear geometry to two equivalent O(3) atoms. Both H(1)-O(3) bond lengths are 1.20 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.49 Å. The S(1)-O(3) bond length is 1.55 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one K(1), one H(1), and one S(1) atom. Cl(1) is bonded to two equivalent K(1), two equivalent K(2), and one Pd(1) atom to form a mixture of distorted corner and face-sharing ClK4Pd square pyramids.