AgZnPS4 crystallizes in the orthorhombic Pna2_1 space group. Ag(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form AgS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. Zn(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form ZnS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. P(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form PS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra and corners with four equivalent Zn(1)S4 tetrahedra. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom.
AgZnPS4 crystallizes in the orthorhombic Pna2_1 space group. Ag(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form AgS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. The Ag(1)-S(1) bond length is 2.65 Å. The Ag(1)-S(2) bond length is 2.59 Å. The Ag(1)-S(3) bond length is 2.58 Å. The Ag(1)-S(4) bond length is 2.56 Å. Zn(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form ZnS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. The Zn(1)-S(1) bond length is 2.39 Å. The Zn(1)-S(2) bond length is 2.35 Å. The Zn(1)-S(3) bond length is 2.40 Å. The Zn(1)-S(4) bond length is 2.36 Å. P(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form PS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra and corners with four equivalent Zn(1)S4 tetrahedra. The P(1)-S(1) bond length is 2.06 Å. The P(1)-S(2) bond length is 2.08 Å. The P(1)-S(3) bond length is 2.07 Å. The P(1)-S(4) bond length is 2.08 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one P(1) atom.