PtN4(NO3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen nitric acid molecules and eight PtN4 clusters. In four of the PtN4 clusters, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2,3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In four of the PtN4 clusters, Pt(2) is bonded in a square co-planar geometry to two equivalent N(2,3) and two equivalent N(4) atoms. There are two inequivalent N sites. In the first N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Pt(2) atom.
PtN4(NO3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen nitric acid molecules and eight PtN4 clusters. In four of the PtN4 clusters, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2,3) atoms. Both Pt(1)-N(1) bond lengths are 1.93 Å. Both Pt(1)-N(2,3) bond lengths are 1.83 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In four of the PtN4 clusters, Pt(2) is bonded in a square co-planar geometry to two equivalent N(2,3) and two equivalent N(4) atoms. Both Pt(2)-N(2,3) bond lengths are 1.83 Å. Both Pt(2)-N(4) bond lengths are 1.94 Å. There are two inequivalent N sites. In the first N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Pt(2) atom.