TcF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four technetium fluoride (tcf6), (oc-6-11)- molecules. Tc(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Tc(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Tc(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Tc(1) atom.
TcF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four technetium fluoride (tcf6), (oc-6-11)- molecules. Tc(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. The Tc(1)-F(1) bond length is 1.84 Å. The Tc(1)-F(2) bond length is 1.84 Å. Both Tc(1)-F(3) bond lengths are 1.82 Å. Both Tc(1)-F(4) bond lengths are 1.82 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Tc(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Tc(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Tc(1) atom.