LiNd2O6 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2), three equivalent O(1), and three equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1) and three equivalent Nd(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one O(2) atom. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one Li(1) and three equivalent Nd(1) atoms.
LiNd2O6 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. Both Li(1)-O(1) bond lengths are 1.89 Å. Both Li(1)-O(3) bond lengths are 1.91 Å. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2), three equivalent O(1), and three equivalent O(3) atoms. There is one shorter (2.53 Å) and one longer (2.55 Å) Nd(1)-O(2) bond length. There are two shorter (2.44 Å) and one longer (2.46 Å) Nd(1)-O(1) bond length. There is one shorter (2.45 Å) and two longer (2.46 Å) Nd(1)-O(3) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1) and three equivalent Nd(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one O(2) atom. The O(2)-O(2) bond length is 1.36 Å. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one Li(1) and three equivalent Nd(1) atoms.