(Na)2MnAuF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a MnAuF6 framework. In the MnAuF6 framework, Mn(1) is bonded to six equivalent F(1) atoms to form MnF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedra are not tilted. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent Mn(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted linear geometry to one Mn(1) and one Au(1) atom.
(Na)2MnAuF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a MnAuF6 framework. In the MnAuF6 framework, Mn(1) is bonded to six equivalent F(1) atoms to form MnF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Mn(1)-F(1) bond lengths are 1.96 Å. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent Mn(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Au(1)-F(1) bond lengths are 2.36 Å. F(1) is bonded in a distorted linear geometry to one Mn(1) and one Au(1) atom.