KLi2HO3H2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two 1333-74-0 molecules inside a KLi2HO3 framework. In the KLi2HO3 framework, K(1) is bonded in a 4-coordinate geometry to one O(1) and three equivalent O(2) atoms. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. H(3) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent Li(1), and one O(2) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Li(1), and one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(3) atom.
KLi2HO3H2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two 1333-74-0 molecules inside a KLi2HO3 framework. In the KLi2HO3 framework, K(1) is bonded in a 4-coordinate geometry to one O(1) and three equivalent O(2) atoms. The K(1)-O(1) bond length is 2.59 Å. There is one shorter (2.58 Å) and two longer (3.01 Å) K(1)-O(2) bond lengths. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. The Li(1)-O(1) bond length is 1.88 Å. The Li(1)-O(2) bond length is 1.95 Å. There is one shorter (1.91 Å) and one longer (2.03 Å) Li(1)-O(3) bond length. H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 0.97 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent Li(1), and one O(2) atom. The O(1)-O(2) bond length is 1.54 Å. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Li(1), and one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(3) atom.