LiLa(WO4)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(6), and one O(7) atom. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), one O(8), and two equivalent O(5) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(8), and two equivalent O(6) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one La(1), and one W(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(1) and one W(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1) and one W(2) atom. In the sixth O site, O(6) is bonded to one Li(1), one W(1), and two equivalent W(2) atoms to form distorted edge-sharing OLiW3 tetrahedra. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom.
LiLa(WO4)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(6), and one O(7) atom. The Li(1)-O(1) bond length is 2.11 Å. The Li(1)-O(2) bond length is 2.42 Å. The Li(1)-O(6) bond length is 2.01 Å. The Li(1)-O(7) bond length is 1.96 Å. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), one O(8), and two equivalent O(5) atoms. The La(1)-O(1) bond length is 2.48 Å. The La(1)-O(2) bond length is 2.49 Å. The La(1)-O(3) bond length is 2.50 Å. The La(1)-O(4) bond length is 2.53 Å. The La(1)-O(7) bond length is 2.63 Å. The La(1)-O(8) bond length is 2.50 Å. There is one shorter (2.46 Å) and one longer (2.66 Å) La(1)-O(5) bond length. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. The W(1)-O(1) bond length is 1.83 Å. The W(1)-O(2) bond length is 1.84 Å. The W(1)-O(3) bond length is 2.08 Å. The W(1)-O(6) bond length is 2.17 Å. The W(1)-O(7) bond length is 1.83 Å. The W(1)-O(8) bond length is 2.15 Å. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(8), and two equivalent O(6) atoms. The W(2)-O(3) bond length is 1.98 Å. The W(2)-O(4) bond length is 1.80 Å. The W(2)-O(5) bond length is 1.85 Å. The W(2)-O(8) bond length is 1.92 Å. There is one shorter (2.07 Å) and one longer (2.29 Å) W(2)-O(6) bond length. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one La(1), and one W(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(1) and one W(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1) and one W(2) atom. In the sixth O site, O(6) is bonded to one Li(1), one W(1), and two equivalent W(2) atoms to form distorted edge-sharing OLiW3 tetrahedra. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(1), one La(1), and one W(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one La(1), one W(1), and one W(2) atom.