XeAsTeO2F11 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two XeAsTeO2F11 clusters. Xe(1) is bonded in a linear geometry to one O(1) and one F(11) atom. As(1) is bonded in an octahedral geometry to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom. Te(1) is bonded in an octahedral geometry to one O(1), one O(2), one F(2), one F(3), one F(4), and one F(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Te(1) and one F(1) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one O(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the eleventh F site, F(11) is bonded in a distorted bent 120 degrees geometry to one Xe(1) and one As(1) atom.
XeAsTeO2F11 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two XeAsTeO2F11 clusters. Xe(1) is bonded in a linear geometry to one O(1) and one F(11) atom. The Xe(1)-O(1) bond length is 2.08 Å. The Xe(1)-F(11) bond length is 2.32 Å. As(1) is bonded in an octahedral geometry to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom. The As(1)-F(10) bond length is 1.76 Å. The As(1)-F(11) bond length is 1.94 Å. The As(1)-F(6) bond length is 1.77 Å. The As(1)-F(7) bond length is 1.74 Å. The As(1)-F(8) bond length is 1.75 Å. The As(1)-F(9) bond length is 1.76 Å. Te(1) is bonded in an octahedral geometry to one O(1), one O(2), one F(2), one F(3), one F(4), and one F(5) atom. The Te(1)-O(1) bond length is 1.97 Å. The Te(1)-O(2) bond length is 2.01 Å. The Te(1)-F(2) bond length is 1.87 Å. The Te(1)-F(3) bond length is 1.87 Å. The Te(1)-F(4) bond length is 1.89 Å. The Te(1)-F(5) bond length is 1.89 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Te(1) and one F(1) atom. The O(2)-F(1) bond length is 1.44 Å. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one O(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the eleventh F site, F(11) is bonded in a distorted bent 120 degrees geometry to one Xe(1) and one As(1) atom.