Os3C9S2O9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3C9S2O9 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded to one C(2), one C(5), one C(7), one S(1), and one S(2) atom to form distorted edge-sharing OsC3S2 square pyramids. In the second Os site, Os(2) is bonded to one C(1), one C(3), one C(8), one S(1), and one S(2) atom to form distorted edge-sharing OsC3S2 square pyramids. In the third Os site, Os(3) is bonded to one C(4), one C(6), one C(9), one S(1), and one S(2) atom to form distorted edge-sharing OsC3S2 trigonal bipyramids. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(2) and one O(7) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(6) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(2) and one O(1) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Os(3) and one O(8) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Os(1) and one O(4) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Os(3) and one O(9) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Os(1) and one O(3) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Os(2) and one O(5) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Os(3) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(6) atom.
Os3C9S2O9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3C9S2O9 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded to one C(2), one C(5), one C(7), one S(1), and one S(2) atom to form distorted edge-sharing OsC3S2 square pyramids. The Os(1)-C(2) bond length is 1.92 Å. The Os(1)-C(5) bond length is 1.93 Å. The Os(1)-C(7) bond length is 1.89 Å. The Os(1)-S(1) bond length is 2.41 Å. The Os(1)-S(2) bond length is 2.43 Å. In the second Os site, Os(2) is bonded to one C(1), one C(3), one C(8), one S(1), and one S(2) atom to form distorted edge-sharing OsC3S2 square pyramids. The Os(2)-C(1) bond length is 1.89 Å. The Os(2)-C(3) bond length is 1.93 Å. The Os(2)-C(8) bond length is 1.92 Å. The Os(2)-S(1) bond length is 2.41 Å. The Os(2)-S(2) bond length is 2.43 Å. In the third Os site, Os(3) is bonded to one C(4), one C(6), one C(9), one S(1), and one S(2) atom to form distorted edge-sharing OsC3S2 trigonal bipyramids. The Os(3)-C(4) bond length is 1.91 Å. The Os(3)-C(6) bond length is 1.90 Å. The Os(3)-C(9) bond length is 1.91 Å. The Os(3)-S(1) bond length is 2.44 Å. The Os(3)-S(2) bond length is 2.47 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(2) and one O(7) atom. The C(1)-O(7) bond length is 1.16 Å. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(6) atom. The C(2)-O(6) bond length is 1.16 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(2) and one O(1) atom. The C(3)-O(1) bond length is 1.16 Å. In the fourth C site, C(4) is bonded in a linear geometry to one Os(3) and one O(8) atom. The C(4)-O(8) bond length is 1.16 Å. In the fifth C site, C(5) is bonded in a linear geometry to one Os(1) and one O(4) atom. The C(5)-O(4) bond length is 1.16 Å. In the sixth C site, C(6) is bonded in a linear geometry to one Os(3) and one O(9) atom. The C(6)-O(9) bond length is 1.16 Å. In the seventh C site, C(7) is bonded in a linear geometry to one Os(1) and one O(3) atom. The C(7)-O(3) bond length is 1.16 Å. In the eighth C site, C(8) is bonded in a linear geometry to one Os(2) and one O(5) atom. The C(8)-O(5) bond length is 1.16 Å. In the ninth C site, C(9) is bonded in a linear geometry to one Os(3) and one O(2) atom. The C(9)-O(2) bond length is 1.16 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(6) atom.