Li5V5(CoO6)2 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(4), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(1)Li3V2Co octahedra, and edges with four equivalent O(3)Li3V2Co octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one V(1), one V(3), one V(4), and one Co(2) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(2)Li2V3Co octahedra, and edges with four equivalent O(4)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(4), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra, edges with four equivalent O(3)Li3V2Co octahedra, and edges with four equivalent O(5)Li3V2Co octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one V(1), one V(3), one V(4), and one Co(2) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(4)Li2V3Co octahedra, and edges with four equivalent O(6)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(4), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra, edges with four equivalent O(1)Li3V2Co octahedra, and edges with four equivalent O(5)Li3V2Co octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one V(1), one V(3), one V(4), and one Co(2) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(2)Li2V3Co octahedra, and edges with four equivalent O(6)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 1-9°.
Li5V5(CoO6)2 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. The Li(1)-O(1) bond length is 2.08 Å. The Li(1)-O(2) bond length is 2.22 Å. The Li(1)-O(3) bond length is 2.06 Å. The Li(1)-O(4) bond length is 2.25 Å. The Li(1)-O(5) bond length is 2.09 Å. The Li(1)-O(6) bond length is 2.27 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Li(2)-O(1) bond length is 2.10 Å. The Li(2)-O(2) bond length is 2.27 Å. The Li(2)-O(3) bond length is 2.11 Å. The Li(2)-O(4) bond length is 2.36 Å. The Li(2)-O(5) bond length is 2.02 Å. The Li(2)-O(6) bond length is 2.18 Å. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. Both Li(3)-O(1) bond lengths are 2.15 Å. Both Li(3)-O(3) bond lengths are 2.12 Å. Both Li(3)-O(5) bond lengths are 2.18 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. Both V(1)-O(2) bond lengths are 2.06 Å. Both V(1)-O(4) bond lengths are 2.09 Å. Both V(1)-O(6) bond lengths are 2.04 Å. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. Both V(2)-O(1) bond lengths are 2.02 Å. Both V(2)-O(3) bond lengths are 2.12 Å. Both V(2)-O(5) bond lengths are 2.08 Å. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. Both V(3)-O(2) bond lengths are 2.06 Å. Both V(3)-O(4) bond lengths are 2.02 Å. Both V(3)-O(6) bond lengths are 2.08 Å. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. The V(4)-O(1) bond length is 2.05 Å. The V(4)-O(2) bond length is 2.15 Å. The V(4)-O(3) bond length is 1.99 Å. The V(4)-O(4) bond length is 2.18 Å. The V(4)-O(5) bond length is 1.96 Å. The V(4)-O(6) bond length is 2.16 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. Both Co(1)-O(1) bond lengths are 2.08 Å. Both Co(1)-O(3) bond lengths are 2.10 Å. Both Co(1)-O(5) bond lengths are 2.21 Å. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. Both Co(2)-O(2) bond lengths are 2.18 Å. Both Co(2)-O(4) bond lengths are 2.10 Å. Both Co(2)-O(6) bond lengths are 2.10 Å. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(4), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(1)Li3V2Co octahedra, and edges with four equivalent O(3)Li3V2Co octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one V(1), one V(3), one V(4), and one Co(2) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(2)Li2V3Co octahedra, and edges with four equivalent O(4)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(4), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra, edges with four equivalent O(3)Li3V2Co octahedra, and edges with four equivalent O(5)Li3V2Co octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one V(1), one V(3), one V(4), and one Co(2) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(4)Li2V3Co octahedra, and edges with four equivalent O(6)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one V(2), one V(4), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(6)Li2V3Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra, edges with four equivalent O(1)Li3V2Co octahedra, and edges with four equivalent O(5)Li3V2Co octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one V(1), one V(3), one V(4), and one Co(2) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li2V3Co octahedra,  a cornercorner with one O(6)Li2V3Co octahedra,  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra,  an edgeedge with one O(4)Li2V3Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra, edges with four equivalent O(2)Li2V3Co octahedra, and edges with four equivalent O(6)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 1-9°.