NaTl2 is Calaverite-like structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent Tl(1) atoms to form edge-sharing NaTl6 octahedra. Tl(1) is bonded in a 3-coordinate geometry to three equivalent Na(1) atoms.
NaTl2 is Calaverite-like structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent Tl(1) atoms to form edge-sharing NaTl6 octahedra. All Na(1)-Tl(1) bond lengths are 3.19 Å. Tl(1) is bonded in a 3-coordinate geometry to three equivalent Na(1) atoms.