TlNbCl6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four NbCl6 clusters. In each NbCl6 cluster, Nb(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(2,3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(2,3) is bonded in a single-bond geometry to one Nb(1) atom.
TlNbCl6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four NbCl6 clusters. In each NbCl6 cluster, Nb(1) is bonded in an octahedral geometry to two equivalent Cl(1) and four equivalent Cl(2,3) atoms. Both Nb(1)-Cl(1) bond lengths are 2.38 Å. All Nb(1)-Cl(2,3) bond lengths are 2.38 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(2,3) is bonded in a single-bond geometry to one Nb(1) atom.