KTlCl4 is Zircon-like structured and crystallizes in the tetragonal I4_1/a space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. Tl(1) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Tl(1) atom.
KTlCl4 is Zircon-like structured and crystallizes in the tetragonal I4_1/a space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. There are four shorter (3.20 Å) and four longer (3.26 Å) K(1)-Cl(1) bond lengths. Tl(1) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. All Tl(1)-Cl(1) bond lengths are 2.46 Å. Cl(1) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Tl(1) atom.