Nd2Pd2Pb crystallizes in the tetragonal P4/mbm space group. Nd(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Pb(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1), one Pd(1), and two equivalent Pb(1) atoms. Pb(1) is bonded to eight equivalent Nd(1) and four equivalent Pd(1) atoms to form a mixture of corner and face-sharing PbNd8Pd4 cuboctahedra.
Nd2Pd2Pb crystallizes in the tetragonal P4/mbm space group. Nd(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Pb(1) atoms. There are two shorter (2.96 Å) and four longer (3.08 Å) Nd(1)-Pd(1) bond lengths. All Nd(1)-Pb(1) bond lengths are 3.51 Å. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1), one Pd(1), and two equivalent Pb(1) atoms. The Pd(1)-Pd(1) bond length is 2.78 Å. Both Pd(1)-Pb(1) bond lengths are 3.17 Å. Pb(1) is bonded to eight equivalent Nd(1) and four equivalent Pd(1) atoms to form a mixture of corner and face-sharing PbNd8Pd4 cuboctahedra.