FeOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/m space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. O(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a distorted T-shaped geometry to three equivalent Fe(1) atoms.
FeOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/m space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. There are two shorter (1.92 Å) and one longer (1.94 Å) Fe(1)-O(1) bond length. There is one shorter (2.08 Å) and two longer (2.11 Å) Fe(1)-F(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a distorted T-shaped geometry to three equivalent Fe(1) atoms.