Bi2OF2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Bi2OF2 cluster. Bi(1) is bonded in a linear geometry to one O(1) and one F(1) atom. O(1) is bonded in a linear geometry to two equivalent Bi(1) atoms. F(1) is bonded in a single-bond geometry to one Bi(1) atom.
Bi2OF2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Bi2OF2 cluster. Bi(1) is bonded in a linear geometry to one O(1) and one F(1) atom. The Bi(1)-O(1) bond length is 2.16 Å. The Bi(1)-F(1) bond length is 2.09 Å. O(1) is bonded in a linear geometry to two equivalent Bi(1) atoms. F(1) is bonded in a single-bond geometry to one Bi(1) atom.