LiBaN crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. Ba(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent N(1) atoms. N(1) is bonded to three equivalent Li(1) and four equivalent Ba(1) atoms to form a mixture of distorted edge and corner-sharing NBa4Li3 pentagonal bipyramids.
LiBaN crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. There is one shorter (2.08 Å) and two longer (2.17 Å) Li(1)-N(1) bond lengths. Ba(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent N(1) atoms. There are a spread of Ba(1)-N(1) bond distances ranging from 2.77-2.91 Å. N(1) is bonded to three equivalent Li(1) and four equivalent Ba(1) atoms to form a mixture of distorted edge and corner-sharing NBa4Li3 pentagonal bipyramids.