WMoZn2O6 is pyrite-derived structured and crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mo(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom.
WMoZn2O6 is pyrite-derived structured and crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. The W(1)-O(1) bond length is 2.04 Å. The W(1)-O(2) bond length is 2.06 Å. The W(1)-O(3) bond length is 2.03 Å. The W(1)-O(4) bond length is 1.95 Å. The W(1)-O(5) bond length is 2.00 Å. The W(1)-O(6) bond length is 2.04 Å. Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-44°. The Mo(1)-O(1) bond length is 2.16 Å. The Mo(1)-O(2) bond length is 2.15 Å. The Mo(1)-O(3) bond length is 2.15 Å. The Mo(1)-O(4) bond length is 2.17 Å. The Mo(1)-O(5) bond length is 2.16 Å. The Mo(1)-O(6) bond length is 2.15 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.44 Å. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(3) bond length is 2.54 Å. The Zn(1)-O(5) bond length is 1.99 Å. The Zn(1)-O(6) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(2)-O(1) bond length is 1.99 Å. The Zn(2)-O(2) bond length is 2.38 Å. The Zn(2)-O(3) bond length is 2.00 Å. The Zn(2)-O(4) bond length is 2.03 Å. The Zn(2)-O(5) bond length is 2.55 Å. The Zn(2)-O(6) bond length is 2.42 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mo(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom.