C2S(NCl)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2S(NCl)3 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one Cl(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom.
C2S(NCl)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2S(NCl)3 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one Cl(3) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-Cl(3) bond length is 1.72 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(1) atom. The C(2)-N(2) bond length is 1.33 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-Cl(1) bond length is 1.72 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. The N(1)-S(1) bond length is 1.62 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. The N(2)-S(1) bond length is 1.62 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. The S(1)-Cl(2) bond length is 2.17 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom.