CNSF5 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four cyanopentafluorosulfur molecules. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted square pyramidal geometry to one C(1), one F(1), one F(2), one F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom.
CNSF5 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four cyanopentafluorosulfur molecules. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.16 Å. The C(1)-S(1) bond length is 1.76 Å. N(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted square pyramidal geometry to one C(1), one F(1), one F(2), one F(3), and two equivalent F(4) atoms. The S(1)-F(1) bond length is 1.60 Å. The S(1)-F(2) bond length is 1.60 Å. The S(1)-F(3) bond length is 1.61 Å. Both S(1)-F(4) bond lengths are 1.61 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom.