Li2AgF5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(1) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(5) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one Ag(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), one Ag(1), and one Ag(2) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to two equivalent Li(2) and one Ag(2) atom.
Li2AgF5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(1) atoms. The Li(1)-F(2) bond length is 2.26 Å. The Li(1)-F(3) bond length is 2.05 Å. The Li(1)-F(4) bond length is 1.90 Å. There is one shorter (1.98 Å) and one longer (2.14 Å) Li(1)-F(1) bond length. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(2), one F(3), one F(4), and two equivalent F(5) atoms. The Li(2)-F(2) bond length is 1.98 Å. The Li(2)-F(3) bond length is 2.36 Å. The Li(2)-F(4) bond length is 1.88 Å. There is one shorter (1.97 Å) and one longer (1.98 Å) Li(2)-F(5) bond length. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(4) atoms. Both Ag(1)-F(1) bond lengths are 2.01 Å. Both Ag(1)-F(2) bond lengths are 1.97 Å. Both Ag(1)-F(4) bond lengths are 2.64 Å. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. Both Ag(2)-F(3) bond lengths are 1.96 Å. Both Ag(2)-F(4) bond lengths are 2.47 Å. Both Ag(2)-F(5) bond lengths are 2.01 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(2), and one Ag(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), one Ag(1), and one Ag(2) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to two equivalent Li(2) and one Ag(2) atom.