CrOCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CrOCl3 clusters. Cr(1,2) is bonded in a 5-coordinate geometry to one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1,2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1,2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cr(1,2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cr(1,2) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Cr(1,2) atoms. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Cr(1,2) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Cr(1,2) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Cr(1,2) atom.
CrOCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CrOCl3 clusters. Cr(1,2) is bonded in a 5-coordinate geometry to one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Cr(1,2)-O(1) bond length is 1.57 Å. The Cr(1,2)-Cl(1) bond length is 2.19 Å. The Cr(1,2)-Cl(2) bond length is 2.20 Å. The Cr(1,2)-Cl(3) bond length is 2.37 Å. The Cr(1,2)-Cl(4) bond length is 2.38 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1,2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1,2) atom. The O(2)-Cr(1,2) bond length is 1.57 Å. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cr(1,2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cr(1,2) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Cr(1,2) atoms. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Cr(1,2) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Cr(1,2) atom. The Cl(5)-Cr(1,2) bond length is 2.19 Å. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Cr(1,2) atom. The Cl(6)-Cr(1,2) bond length is 2.20 Å.