PbO7Cl2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four PbO7Cl2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1) and one Cl(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom.
PbO7Cl2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four PbO7Cl2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one O(4) and two equivalent O(3) atoms. The Pb(1)-O(4) bond length is 2.47 Å. Both Pb(1)-O(3) bond lengths are 2.71 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. The O(1)-Cl(1) bond length is 1.50 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. The O(2)-Cl(1) bond length is 1.49 Å. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1) and one Cl(1) atom. The O(3)-Cl(1) bond length is 1.55 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pb(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom.