WMo3Cd4O16 is Zircon-derived structured and crystallizes in the tetragonal P-4 space group. W(1) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. In the second Cd site, Cd(2) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. In the third Cd site, Cd(3) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one Cd(1), and one Cd(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Cd(1), and one Cd(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(2), one Cd(1), and one Cd(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Cd(1), and one Cd(3) atom.
WMo3Cd4O16 is Zircon-derived structured and crystallizes in the tetragonal P-4 space group. W(1) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. All W(1)-O(4) bond lengths are 1.83 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Mo(1)-O(1) bond lengths are 1.81 Å. Both Mo(1)-O(2) bond lengths are 1.81 Å. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. All Mo(2)-O(3) bond lengths are 1.81 Å. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both Cd(1)-O(1) bond lengths are 2.44 Å. Both Cd(1)-O(2) bond lengths are 2.44 Å. Both Cd(1)-O(3) bond lengths are 2.47 Å. Both Cd(1)-O(4) bond lengths are 2.45 Å. In the second Cd site, Cd(2) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. All Cd(2)-O(1) bond lengths are 2.47 Å. All Cd(2)-O(3) bond lengths are 2.44 Å. In the third Cd site, Cd(3) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. All Cd(3)-O(2) bond lengths are 2.47 Å. All Cd(3)-O(4) bond lengths are 2.43 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one Cd(1), and one Cd(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Cd(1), and one Cd(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(2), one Cd(1), and one Cd(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Cd(1), and one Cd(3) atom.