Cd(BF4)(TaF6) crystallizes in the monoclinic P2_1/c space group. Ta(1) is bonded in an octahedral geometry to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom. Cd(1) is bonded in a 8-coordinate geometry to one F(1), one F(10), one F(2), one F(3), one F(4), one F(6), one F(7), and one F(8) atom. B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are ten inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Ta(1) and one Cd(1) atom. In the second F site, F(7) is bonded in a distorted single-bond geometry to one Ta(1) and one Cd(1) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to one Ta(1) and one Cd(1) atom. In the fourth F site, F(1) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth F site, F(2) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the seventh F site, F(10) is bonded in a bent 150 degrees geometry to one Ta(1) and one Cd(1) atom. In the eighth F site, F(3) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the ninth F site, F(4) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the tenth F site, F(5) is bonded in a single-bond geometry to one Ta(1) atom.
Cd(BF4)(TaF6) crystallizes in the monoclinic P2_1/c space group. Ta(1) is bonded in an octahedral geometry to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom. The Ta(1)-F(10) bond length is 1.97 Å. The Ta(1)-F(5) bond length is 1.88 Å. The Ta(1)-F(6) bond length is 1.96 Å. The Ta(1)-F(7) bond length is 1.94 Å. The Ta(1)-F(8) bond length is 1.94 Å. The Ta(1)-F(9) bond length is 1.88 Å. Cd(1) is bonded in a 8-coordinate geometry to one F(1), one F(10), one F(2), one F(3), one F(4), one F(6), one F(7), and one F(8) atom. The Cd(1)-F(1) bond length is 2.36 Å. The Cd(1)-F(10) bond length is 2.32 Å. The Cd(1)-F(2) bond length is 2.34 Å. The Cd(1)-F(3) bond length is 2.35 Å. The Cd(1)-F(4) bond length is 2.39 Å. The Cd(1)-F(6) bond length is 2.41 Å. The Cd(1)-F(7) bond length is 2.52 Å. The Cd(1)-F(8) bond length is 2.37 Å. B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. The B(1)-F(1) bond length is 1.42 Å. The B(1)-F(2) bond length is 1.42 Å. The B(1)-F(3) bond length is 1.42 Å. The B(1)-F(4) bond length is 1.41 Å. There are ten inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Ta(1) and one Cd(1) atom. In the second F site, F(7) is bonded in a distorted single-bond geometry to one Ta(1) and one Cd(1) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to one Ta(1) and one Cd(1) atom. In the fourth F site, F(1) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth F site, F(2) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the seventh F site, F(10) is bonded in a bent 150 degrees geometry to one Ta(1) and one Cd(1) atom. In the eighth F site, F(3) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the ninth F site, F(4) is bonded in a distorted single-bond geometry to one Cd(1) and one B(1) atom. In the tenth F site, F(5) is bonded in a single-bond geometry to one Ta(1) atom.