DyFeC6H4(N3O)2(H2O)2 crystallizes in the orthorhombic Cmcm space group. The structure consists of eight water molecules inside a DyFeC6H4(N3O)2 framework. In the DyFeC6H4(N3O)2 framework, Dy(1) is bonded in a 8-coordinate geometry to two equivalent N(2), four equivalent N(1), and two equivalent O(1) atoms. Fe(1) is bonded in an octahedral geometry to two equivalent C(2) and four equivalent C(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Dy(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(2) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Dy(1) and two equivalent H(1) atoms.
DyFeC6H4(N3O)2(H2O)2 crystallizes in the orthorhombic Cmcm space group. The structure consists of eight water molecules inside a DyFeC6H4(N3O)2 framework. In the DyFeC6H4(N3O)2 framework, Dy(1) is bonded in a 8-coordinate geometry to two equivalent N(2), four equivalent N(1), and two equivalent O(1) atoms. Both Dy(1)-N(2) bond lengths are 2.47 Å. All Dy(1)-N(1) bond lengths are 2.46 Å. Both Dy(1)-O(1) bond lengths are 2.36 Å. Fe(1) is bonded in an octahedral geometry to two equivalent C(2) and four equivalent C(1) atoms. Both Fe(1)-C(2) bond lengths are 1.93 Å. All Fe(1)-C(1) bond lengths are 1.94 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Dy(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(2) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. O(1) is bonded in a distorted water-like geometry to one Dy(1) and two equivalent H(1) atoms.