VSe is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent Se(1) atoms to form a mixture of distorted edge and corner-sharing VSe6 pentagonal pyramids. Se(1) is bonded to six equivalent V(1) atoms to form a mixture of edge, face, and corner-sharing SeV6 octahedra. The corner-sharing octahedral tilt angles are 45°.
VSe is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent Se(1) atoms to form a mixture of distorted edge and corner-sharing VSe6 pentagonal pyramids. All V(1)-Se(1) bond lengths are 2.63 Å. Se(1) is bonded to six equivalent V(1) atoms to form a mixture of edge, face, and corner-sharing SeV6 octahedra. The corner-sharing octahedral tilt angles are 45°.