CdTiO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-30°. Cd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and three equivalent Cd(1) atoms. In the second O site, O(2) is bonded to two equivalent Ti(1) and two equivalent Cd(1) atoms to form distorted corner-sharing OTi2Cd2 tetrahedra.
CdTiO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 29-30°. Both Ti(1)-O(2) bond lengths are 1.99 Å. There are two shorter (1.98 Å) and two longer (1.99 Å) Ti(1)-O(1) bond lengths. Cd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.28 Å) and one longer (2.43 Å) Cd(1)-O(2) bond length. There are a spread of Cd(1)-O(1) bond distances ranging from 2.30-2.71 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and three equivalent Cd(1) atoms. In the second O site, O(2) is bonded to two equivalent Ti(1) and two equivalent Cd(1) atoms to form distorted corner-sharing OTi2Cd2 tetrahedra.