Cu(AgO)2 crystallizes in the orthorhombic Immm space group. Ag(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Ag(1) and two equivalent Cu(1) atoms to form a mixture of distorted corner and edge-sharing OCu2Ag4 octahedra. The corner-sharing octahedral tilt angles range from 0-10°.
Cu(AgO)2 crystallizes in the orthorhombic Immm space group. Ag(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are two shorter (2.27 Å) and two longer (2.66 Å) Ag(1)-O(1) bond lengths. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Cu(1)-O(1) bond lengths are 1.97 Å. O(1) is bonded to four equivalent Ag(1) and two equivalent Cu(1) atoms to form a mixture of distorted corner and edge-sharing OCu2Ag4 octahedra. The corner-sharing octahedral tilt angles range from 0-10°.