LiV2(CO3)4 crystallizes in the monoclinic Pc space group. Li(1) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(12), and one O(2) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(5), one O(6), and one O(7) atom to form distorted edge-sharing VO7 pentagonal bipyramids. In the second V site, V(2) is bonded to one O(11), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form edge-sharing VO6 octahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(12), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(11), one O(7), and one O(8) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one C(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one V(2) and one C(2) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one V(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one C(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(2) and one C(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one C(4) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(4) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one V(1), one V(2), and one C(3) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one C(1) atom.
LiV2(CO3)4 crystallizes in the monoclinic Pc space group. Li(1) is bonded in a 3-coordinate geometry to one O(1), one O(10), one O(12), and one O(2) atom. The Li(1)-O(1) bond length is 2.39 Å. The Li(1)-O(10) bond length is 1.98 Å. The Li(1)-O(12) bond length is 2.02 Å. The Li(1)-O(2) bond length is 1.93 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(5), one O(6), and one O(7) atom to form distorted edge-sharing VO7 pentagonal bipyramids. The V(1)-O(1) bond length is 2.09 Å. The V(1)-O(10) bond length is 2.12 Å. The V(1)-O(11) bond length is 2.16 Å. The V(1)-O(12) bond length is 2.13 Å. The V(1)-O(5) bond length is 2.15 Å. The V(1)-O(6) bond length is 2.17 Å. The V(1)-O(7) bond length is 2.02 Å. In the second V site, V(2) is bonded to one O(11), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form edge-sharing VO6 octahedra. The V(2)-O(11) bond length is 2.07 Å. The V(2)-O(3) bond length is 1.93 Å. The V(2)-O(4) bond length is 1.82 Å. The V(2)-O(6) bond length is 2.10 Å. The V(2)-O(8) bond length is 1.99 Å. The V(2)-O(9) bond length is 2.01 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(12), and one O(5) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(12) bond length is 1.32 Å. The C(1)-O(5) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The C(2)-O(2) bond length is 1.23 Å. The C(2)-O(3) bond length is 1.32 Å. The C(2)-O(4) bond length is 1.33 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(11), one O(7), and one O(8) atom. The C(3)-O(11) bond length is 1.35 Å. The C(3)-O(7) bond length is 1.24 Å. The C(3)-O(8) bond length is 1.29 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(9) atom. The C(4)-O(10) bond length is 1.27 Å. The C(4)-O(6) bond length is 1.33 Å. The C(4)-O(9) bond length is 1.28 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one C(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one V(2) and one C(2) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one V(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one C(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(2) and one C(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one C(4) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(4) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one V(1), one V(2), and one C(3) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one C(1) atom.