MgP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one MgP3(OBr3)3 cluster. In the MgP3(OBr3)3 cluster, Mg(1) is bonded to one O(2), one Br(10), one Br(12), and one Br(6) atom to form distorted MgBr3O tetrahedra that share  a cornercorner with one P(2)Br3O tetrahedra and  a cornercorner with one P(3)Br3O tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one O(3), one Br(12), and one Br(5) atom. In the second P site, P(2) is bonded to one O(1), one Br(1), one Br(6), and one Br(7) atom to form distorted PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. In the third P site, P(3) is bonded to one O(2), one Br(4), one Br(8), and one Br(9) atom to form PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one P(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one P(3) atom. In the third Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth Br site, Br(6) is bonded in a water-like geometry to one Mg(1) and one P(2) atom. In the fifth Br site, Br(7) is bonded in a single-bond geometry to one P(2) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(10) is bonded in a single-bond geometry to one Mg(1) atom. In the ninth Br site, Br(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one P(1) atom.
MgP3(OBr3)3POBr3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one phosphorus oxybromide molecule and one MgP3(OBr3)3 cluster. In the MgP3(OBr3)3 cluster, Mg(1) is bonded to one O(2), one Br(10), one Br(12), and one Br(6) atom to form distorted MgBr3O tetrahedra that share  a cornercorner with one P(2)Br3O tetrahedra and  a cornercorner with one P(3)Br3O tetrahedra. The Mg(1)-O(2) bond length is 1.98 Å. The Mg(1)-Br(10) bond length is 2.42 Å. The Mg(1)-Br(12) bond length is 2.48 Å. The Mg(1)-Br(6) bond length is 2.80 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one O(3), one Br(12), and one Br(5) atom. The P(1)-O(3) bond length is 1.50 Å. The P(1)-Br(12) bond length is 2.74 Å. The P(1)-Br(5) bond length is 2.32 Å. In the second P site, P(2) is bonded to one O(1), one Br(1), one Br(6), and one Br(7) atom to form distorted PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. The P(2)-O(1) bond length is 1.48 Å. The P(2)-Br(1) bond length is 2.18 Å. The P(2)-Br(6) bond length is 2.31 Å. The P(2)-Br(7) bond length is 2.20 Å. In the third P site, P(3) is bonded to one O(2), one Br(4), one Br(8), and one Br(9) atom to form PBr3O tetrahedra that share  a cornercorner with one Mg(1)Br3O tetrahedra. The P(3)-O(2) bond length is 1.50 Å. The P(3)-Br(4) bond length is 2.19 Å. The P(3)-Br(8) bond length is 2.17 Å. The P(3)-Br(9) bond length is 2.18 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one P(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. There are nine inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one P(3) atom. In the third Br site, Br(5) is bonded in a single-bond geometry to one P(1) atom. In the fourth Br site, Br(6) is bonded in a water-like geometry to one Mg(1) and one P(2) atom. In the fifth Br site, Br(7) is bonded in a single-bond geometry to one P(2) atom. In the sixth Br site, Br(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Br site, Br(9) is bonded in a single-bond geometry to one P(3) atom. In the eighth Br site, Br(10) is bonded in a single-bond geometry to one Mg(1) atom. In the ninth Br site, Br(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one P(1) atom.