Ca10Nb5InO24 crystallizes in the triclinic P1 space group. There are ten inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 4-coordinate geometry to one Ca(3), one Ca(7), one O(10), one O(14), one O(18), and one O(22) atom. In the second Ca site, Ca(2) is bonded in a 4-coordinate geometry to one O(12), one O(15), one O(19), and one O(24) atom. In the third Ca site, Ca(3) is bonded in a 7-coordinate geometry to one Ca(1), one Nb(1), one O(1), one O(14), one O(19), one O(22), and one O(7) atom. In the fourth Ca site, Ca(4) is bonded in a 6-coordinate geometry to one Nb(2), one In(1), one O(13), one O(2), one O(21), and one O(8) atom. In the fifth Ca site, Ca(5) is bonded in a 9-coordinate geometry to one Nb(3), one Nb(5), one O(16), one O(17), one O(20), one O(23), one O(3), one O(4), and one O(6) atom. In the sixth Ca site, Ca(6) is bonded in a 5-coordinate geometry to one Nb(4), one O(15), one O(24), one O(4), and one O(5) atom. In the seventh Ca site, Ca(7) is bonded in a 8-coordinate geometry to one Ca(1), one Nb(2), one O(10), one O(18), one O(22), one O(23), one O(3), and one O(5) atom. In the eighth Ca site, Ca(8) is bonded in a 5-coordinate geometry to one Nb(1), one In(1), one O(4), one O(6), and one O(9) atom. In the ninth Ca site, Ca(9) is bonded in a 5-coordinate geometry to one Nb(3), one O(10), one O(12), one O(19), one O(2), and one O(7) atom. In the tenth Ca site, Ca(10) is bonded in a 5-coordinate geometry to one Nb(4), one Nb(5), one O(1), one O(11), one O(7), and one O(8) atom. There are five inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a 6-coordinate geometry to one Ca(3), one Ca(8), one O(11), one O(16), one O(19), and one O(24) atom. In the second Nb site, Nb(2) is bonded in a 7-coordinate geometry to one Ca(4), one Ca(7), one O(12), one O(15), one O(2), one O(20), and one O(23) atom. In the third Nb site, Nb(3) is bonded in a 6-coordinate geometry to one Ca(5), one Ca(9), one O(10), one O(14), one O(17), and one O(21) atom. In the fourth Nb site, Nb(4) is bonded in a 7-coordinate geometry to one Ca(10), one Ca(6), one O(13), one O(18), one O(22), one O(8), and one O(9) atom. In the fifth Nb site, Nb(5) is bonded in a 6-coordinate geometry to one Ca(10), one Ca(5), one O(11), one O(16), one O(20), and one O(23) atom. In(1) is bonded in a 6-coordinate geometry to one Ca(4), one Ca(8), one O(13), one O(17), one O(21), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Ca(10), one Ca(3), and one O(11) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ca(4), one Ca(9), one Nb(2), and one O(12) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ca(5), one Ca(7), and one O(10) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ca(5), one Ca(6), one Ca(8), and one O(9) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ca(6), one Ca(7), and one O(15) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ca(5), one Ca(8), and one O(16) atom. In the seventh O site, O(7) is bonded in a distorted square co-planar geometry to one Ca(10), one Ca(3), one Ca(9), and one O(14) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Ca(10), one Ca(4), one Nb(4), and one O(13) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Ca(8), one Nb(4), one In(1), one O(21), and one O(4) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Ca(1), one Ca(7), one Ca(9), one Nb(3), and one O(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Ca(10), one Nb(1), one Nb(5), one O(1), and one O(23) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Ca(2), one Ca(9), one Nb(2), and one O(2) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Ca(4), one Nb(4), one In(1), and one O(8) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Ca(1), one Ca(3), one Nb(3), one O(18), and one O(7) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one Ca(2), one Ca(6), one Nb(2), one O(19), and one O(5) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Ca(5), one Nb(1), one Nb(5), and one O(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Ca(5), one Nb(3), and one In(1) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Ca(1), one Ca(7), one Nb(4), and one O(14) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Ca(2), one Ca(3), one Ca(9), one Nb(1), and one O(15) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Ca(5), one Nb(2), and one Nb(5) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Ca(4), one Nb(3), one In(1), and one O(9) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Ca(1), one Ca(3), one Ca(7), and one Nb(4) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one Ca(5), one Ca(7), one Nb(2), one Nb(5), and one O(11) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Ca(2), one Ca(6), and one Nb(1) atom.
Ca10Nb5InO24 crystallizes in the triclinic P1 space group. There are ten inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 4-coordinate geometry to one Ca(3), one Ca(7), one O(10), one O(14), one O(18), and one O(22) atom. The Ca(1)-Ca(3) bond length is 1.98 Å. The Ca(1)-Ca(7) bond length is 2.11 Å. The Ca(1)-O(10) bond length is 2.10 Å. The Ca(1)-O(14) bond length is 1.95 Å. The Ca(1)-O(18) bond length is 1.67 Å. The Ca(1)-O(22) bond length is 1.85 Å. In the second Ca site, Ca(2) is bonded in a 4-coordinate geometry to one O(12), one O(15), one O(19), and one O(24) atom. The Ca(2)-O(12) bond length is 2.03 Å. The Ca(2)-O(15) bond length is 1.99 Å. The Ca(2)-O(19) bond length is 1.71 Å. The Ca(2)-O(24) bond length is 1.77 Å. In the third Ca site, Ca(3) is bonded in a 7-coordinate geometry to one Ca(1), one Nb(1), one O(1), one O(14), one O(19), one O(22), and one O(7) atom. The Ca(3)-Nb(1) bond length is 2.15 Å. The Ca(3)-O(1) bond length is 2.12 Å. The Ca(3)-O(14) bond length is 2.06 Å. The Ca(3)-O(19) bond length is 2.69 Å. The Ca(3)-O(22) bond length is 2.50 Å. The Ca(3)-O(7) bond length is 2.43 Å. In the fourth Ca site, Ca(4) is bonded in a 6-coordinate geometry to one Nb(2), one In(1), one O(13), one O(2), one O(21), and one O(8) atom. The Ca(4)-Nb(2) bond length is 1.96 Å. The Ca(4)-In(1) bond length is 2.10 Å. The Ca(4)-O(13) bond length is 2.49 Å. The Ca(4)-O(2) bond length is 2.14 Å. The Ca(4)-O(21) bond length is 2.43 Å. The Ca(4)-O(8) bond length is 2.57 Å. In the fifth Ca site, Ca(5) is bonded in a 9-coordinate geometry to one Nb(3), one Nb(5), one O(16), one O(17), one O(20), one O(23), one O(3), one O(4), and one O(6) atom. The Ca(5)-Nb(3) bond length is 1.98 Å. The Ca(5)-Nb(5) bond length is 2.09 Å. The Ca(5)-O(16) bond length is 2.28 Å. The Ca(5)-O(17) bond length is 2.72 Å. The Ca(5)-O(20) bond length is 2.76 Å. The Ca(5)-O(23) bond length is 2.48 Å. The Ca(5)-O(3) bond length is 2.14 Å. The Ca(5)-O(4) bond length is 3.07 Å. The Ca(5)-O(6) bond length is 2.53 Å. In the sixth Ca site, Ca(6) is bonded in a 5-coordinate geometry to one Nb(4), one O(15), one O(24), one O(4), and one O(5) atom. The Ca(6)-Nb(4) bond length is 2.05 Å. The Ca(6)-O(15) bond length is 2.26 Å. The Ca(6)-O(24) bond length is 2.53 Å. The Ca(6)-O(4) bond length is 2.60 Å. The Ca(6)-O(5) bond length is 2.54 Å. In the seventh Ca site, Ca(7) is bonded in a 8-coordinate geometry to one Ca(1), one Nb(2), one O(10), one O(18), one O(22), one O(23), one O(3), and one O(5) atom. The Ca(7)-Nb(2) bond length is 2.03 Å. The Ca(7)-O(10) bond length is 2.57 Å. The Ca(7)-O(18) bond length is 2.32 Å. The Ca(7)-O(22) bond length is 2.93 Å. The Ca(7)-O(23) bond length is 2.87 Å. The Ca(7)-O(3) bond length is 2.59 Å. The Ca(7)-O(5) bond length is 2.32 Å. In the eighth Ca site, Ca(8) is bonded in a 5-coordinate geometry to one Nb(1), one In(1), one O(4), one O(6), and one O(9) atom. The Ca(8)-Nb(1) bond length is 2.13 Å. The Ca(8)-In(1) bond length is 1.98 Å. The Ca(8)-O(4) bond length is 2.42 Å. The Ca(8)-O(6) bond length is 1.95 Å. The Ca(8)-O(9) bond length is 2.12 Å. In the ninth Ca site, Ca(9) is bonded in a 5-coordinate geometry to one Nb(3), one O(10), one O(12), one O(19), one O(2), and one O(7) atom. The Ca(9)-Nb(3) bond length is 2.03 Å. The Ca(9)-O(10) bond length is 3.03 Å. The Ca(9)-O(12) bond length is 2.41 Å. The Ca(9)-O(19) bond length is 2.44 Å. The Ca(9)-O(2) bond length is 2.59 Å. The Ca(9)-O(7) bond length is 2.67 Å. In the tenth Ca site, Ca(10) is bonded in a 5-coordinate geometry to one Nb(4), one Nb(5), one O(1), one O(11), one O(7), and one O(8) atom. The Ca(10)-Nb(4) bond length is 2.00 Å. The Ca(10)-Nb(5) bond length is 2.06 Å. The Ca(10)-O(1) bond length is 2.41 Å. The Ca(10)-O(11) bond length is 2.17 Å. The Ca(10)-O(7) bond length is 3.06 Å. The Ca(10)-O(8) bond length is 2.12 Å. There are five inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a 6-coordinate geometry to one Ca(3), one Ca(8), one O(11), one O(16), one O(19), and one O(24) atom. The Nb(1)-O(11) bond length is 2.67 Å. The Nb(1)-O(16) bond length is 2.50 Å. The Nb(1)-O(19) bond length is 2.60 Å. The Nb(1)-O(24) bond length is 2.45 Å. In the second Nb site, Nb(2) is bonded in a 7-coordinate geometry to one Ca(4), one Ca(7), one O(12), one O(15), one O(2), one O(20), and one O(23) atom. The Nb(2)-O(12) bond length is 2.42 Å. The Nb(2)-O(15) bond length is 2.67 Å. The Nb(2)-O(2) bond length is 2.54 Å. The Nb(2)-O(20) bond length is 2.28 Å. The Nb(2)-O(23) bond length is 2.70 Å. In the third Nb site, Nb(3) is bonded in a 6-coordinate geometry to one Ca(5), one Ca(9), one O(10), one O(14), one O(17), and one O(21) atom. The Nb(3)-O(10) bond length is 2.29 Å. The Nb(3)-O(14) bond length is 2.73 Å. The Nb(3)-O(17) bond length is 2.28 Å. The Nb(3)-O(21) bond length is 2.56 Å. In the fourth Nb site, Nb(4) is bonded in a 7-coordinate geometry to one Ca(10), one Ca(6), one O(13), one O(18), one O(22), one O(8), and one O(9) atom. The Nb(4)-O(13) bond length is 2.35 Å. The Nb(4)-O(18) bond length is 2.64 Å. The Nb(4)-O(22) bond length is 2.28 Å. The Nb(4)-O(8) bond length is 2.55 Å. The Nb(4)-O(9) bond length is 2.69 Å. In the fifth Nb site, Nb(5) is bonded in a 6-coordinate geometry to one Ca(10), one Ca(5), one O(11), one O(16), one O(20), and one O(23) atom. The Nb(5)-O(11) bond length is 1.75 Å. The Nb(5)-O(16) bond length is 1.90 Å. The Nb(5)-O(20) bond length is 1.77 Å. The Nb(5)-O(23) bond length is 1.51 Å. In(1) is bonded in a 6-coordinate geometry to one Ca(4), one Ca(8), one O(13), one O(17), one O(21), and one O(9) atom. The In(1)-O(13) bond length is 2.00 Å. The In(1)-O(17) bond length is 1.81 Å. The In(1)-O(21) bond length is 1.66 Å. The In(1)-O(9) bond length is 1.93 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Ca(10), one Ca(3), and one O(11) atom. The O(1)-O(11) bond length is 1.78 Å. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ca(4), one Ca(9), one Nb(2), and one O(12) atom. The O(2)-O(12) bond length is 1.64 Å. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ca(5), one Ca(7), and one O(10) atom. The O(3)-O(10) bond length is 1.69 Å. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ca(5), one Ca(6), one Ca(8), and one O(9) atom. The O(4)-O(9) bond length is 1.87 Å. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ca(6), one Ca(7), and one O(15) atom. The O(5)-O(15) bond length is 1.68 Å. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ca(5), one Ca(8), and one O(16) atom. The O(6)-O(16) bond length is 1.72 Å. In the seventh O site, O(7) is bonded in a distorted square co-planar geometry to one Ca(10), one Ca(3), one Ca(9), and one O(14) atom. The O(7)-O(14) bond length is 1.80 Å. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Ca(10), one Ca(4), one Nb(4), and one O(13) atom. The O(8)-O(13) bond length is 1.69 Å. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Ca(8), one Nb(4), one In(1), one O(21), and one O(4) atom. The O(9)-O(21) bond length is 1.90 Å. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Ca(1), one Ca(7), one Ca(9), one Nb(3), and one O(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Ca(10), one Nb(1), one Nb(5), one O(1), and one O(23) atom. The O(11)-O(23) bond length is 1.86 Å. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Ca(2), one Ca(9), one Nb(2), and one O(2) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Ca(4), one Nb(4), one In(1), and one O(8) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Ca(1), one Ca(3), one Nb(3), one O(18), and one O(7) atom. The O(14)-O(18) bond length is 1.88 Å. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one Ca(2), one Ca(6), one Nb(2), one O(19), and one O(5) atom. The O(15)-O(19) bond length is 1.88 Å. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Ca(5), one Nb(1), one Nb(5), and one O(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Ca(5), one Nb(3), and one In(1) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Ca(1), one Ca(7), one Nb(4), and one O(14) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Ca(2), one Ca(3), one Ca(9), one Nb(1), and one O(15) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Ca(5), one Nb(2), and one Nb(5) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Ca(4), one Nb(3), one In(1), and one O(9) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Ca(1), one Ca(3), one Ca(7), and one Nb(4) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one Ca(5), one Ca(7), one Nb(2), one Nb(5), and one O(11) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Ca(2), one Ca(6), and one Nb(1) atom.