BaSrPdF6 crystallizes in the orthorhombic Aea2 space group. Ba(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. Sr(1) is bonded in a distorted body-centered cubic geometry to four equivalent F(1) and four equivalent F(3) atoms. Pd(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(2) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Ba(1) and two equivalent Sr(1) atoms to form a mixture of corner and edge-sharing FBa2Sr2 tetrahedra. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Pd(1) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Sr(1) and one Pd(1) atom.
BaSrPdF6 crystallizes in the orthorhombic Aea2 space group. Ba(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two shorter (2.65 Å) and two longer (2.70 Å) Ba(1)-F(1) bond lengths. There are two shorter (2.68 Å) and two longer (2.70 Å) Ba(1)-F(2) bond lengths. Sr(1) is bonded in a distorted body-centered cubic geometry to four equivalent F(1) and four equivalent F(3) atoms. There are two shorter (2.57 Å) and two longer (2.58 Å) Sr(1)-F(1) bond lengths. There are two shorter (2.57 Å) and two longer (2.61 Å) Sr(1)-F(3) bond lengths. Pd(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(2) and two equivalent F(3) atoms. Both Pd(1)-F(2) bond lengths are 2.01 Å. Both Pd(1)-F(3) bond lengths are 2.01 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Ba(1) and two equivalent Sr(1) atoms to form a mixture of corner and edge-sharing FBa2Sr2 tetrahedra. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Pd(1) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Sr(1) and one Pd(1) atom.