Sr3DyRhO6 crystallizes in the trigonal R-3c space group. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Dy(1) is bonded to six equivalent O(1) atoms to form distorted DyO6 pentagonal pyramids that share faces with two equivalent Rh(1)O6 octahedra. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share faces with two equivalent Dy(1)O6 pentagonal pyramids. O(1) is bonded to four equivalent Sr(1), one Dy(1), and one Rh(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4DyRh octahedra. The corner-sharing octahedral tilt angles range from 0-66°.
Sr3DyRhO6 crystallizes in the trigonal R-3c space group. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are a spread of Sr(1)-O(1) bond distances ranging from 2.54-2.77 Å. Dy(1) is bonded to six equivalent O(1) atoms to form distorted DyO6 pentagonal pyramids that share faces with two equivalent Rh(1)O6 octahedra. All Dy(1)-O(1) bond lengths are 2.29 Å. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share faces with two equivalent Dy(1)O6 pentagonal pyramids. All Rh(1)-O(1) bond lengths are 2.11 Å. O(1) is bonded to four equivalent Sr(1), one Dy(1), and one Rh(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr4DyRh octahedra. The corner-sharing octahedral tilt angles range from 0-66°.