CrSn2 is Khatyrkite-like structured and crystallizes in the orthorhombic Fddd space group. Cr(1) is bonded in a 10-coordinate geometry to two equivalent Cr(1), four equivalent Sn(1), and four equivalent Sn(2) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to four equivalent Cr(1) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to four equivalent Cr(1) atoms.
CrSn2 is Khatyrkite-like structured and crystallizes in the orthorhombic Fddd space group. Cr(1) is bonded in a 10-coordinate geometry to two equivalent Cr(1), four equivalent Sn(1), and four equivalent Sn(2) atoms. Both Cr(1)-Cr(1) bond lengths are 2.70 Å. There are two shorter (2.81 Å) and two longer (2.84 Å) Cr(1)-Sn(1) bond lengths. There are two shorter (2.77 Å) and two longer (2.80 Å) Cr(1)-Sn(2) bond lengths. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to four equivalent Cr(1) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to four equivalent Cr(1) atoms.