MnCl4(H2O)2(NH4)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two MnCl4(H2O)2 clusters. In each MnCl4(H2O)2 cluster, Mn(1) is bonded in an octahedral geometry to one O(2), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(6), and one H(7) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mn(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Mn(1) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Mn(1) atom.
MnCl4(H2O)2(NH4)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two MnCl4(H2O)2 clusters. In each MnCl4(H2O)2 cluster, Mn(1) is bonded in an octahedral geometry to one O(2), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. The Mn(1)-O(2) bond length is 2.22 Å. The Mn(1)-O(3) bond length is 2.22 Å. The Mn(1)-Cl(2) bond length is 2.58 Å. The Mn(1)-Cl(3) bond length is 2.57 Å. The Mn(1)-Cl(6) bond length is 2.58 Å. The Mn(1)-Cl(7) bond length is 2.57 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.98 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(3) atom. The H(4)-O(3) bond length is 0.98 Å. In the third H site, H(6) is bonded in a single-bond geometry to one O(2) atom. The H(6)-O(2) bond length is 0.98 Å. In the fourth H site, H(7) is bonded in a single-bond geometry to one O(2) atom. The H(7)-O(2) bond length is 0.98 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(6), and one H(7) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mn(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Mn(1) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Mn(1) atom.