(K)2NaMoI6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaMoI6 framework. In the NaMoI6 framework, Na(1) is bonded to six equivalent I(1) atoms to form NaI6 octahedra that share corners with six equivalent Mo(1)I6 octahedra. The corner-sharing octahedra are not tilted. Mo(1) is bonded to six equivalent I(1) atoms to form MoI6 octahedra that share corners with six equivalent Na(1)I6 octahedra. The corner-sharing octahedra are not tilted. I(1) is bonded in a linear geometry to one Na(1) and one Mo(1) atom.
(K)2NaMoI6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaMoI6 framework. In the NaMoI6 framework, Na(1) is bonded to six equivalent I(1) atoms to form NaI6 octahedra that share corners with six equivalent Mo(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-I(1) bond lengths are 3.13 Å. Mo(1) is bonded to six equivalent I(1) atoms to form MoI6 octahedra that share corners with six equivalent Na(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Mo(1)-I(1) bond lengths are 2.81 Å. I(1) is bonded in a linear geometry to one Na(1) and one Mo(1) atom.