NaZnAs is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Na(1) is bonded in a 9-coordinate geometry to four equivalent Zn(1) and five equivalent As(1) atoms. Zn(1) is bonded to four equivalent Na(1) and four equivalent As(1) atoms to form a mixture of distorted face and edge-sharing ZnNa4As4 tetrahedra. As(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Zn(1) atoms.
NaZnAs is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Na(1) is bonded in a 9-coordinate geometry to four equivalent Zn(1) and five equivalent As(1) atoms. All Na(1)-Zn(1) bond lengths are 3.21 Å. There is one shorter (3.04 Å) and four longer (3.07 Å) Na(1)-As(1) bond lengths. Zn(1) is bonded to four equivalent Na(1) and four equivalent As(1) atoms to form a mixture of distorted face and edge-sharing ZnNa4As4 tetrahedra. All Zn(1)-As(1) bond lengths are 2.58 Å. As(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Zn(1) atoms.