AgC2N3 crystallizes in the trigonal P3_121 space group. Ag(1) is bonded in a hexagonal planar geometry to four equivalent C(1) and two equivalent N(1) atoms. C(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Ag(1), one C(1), and one N(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms.
AgC2N3 crystallizes in the trigonal P3_121 space group. Ag(1) is bonded in a hexagonal planar geometry to four equivalent C(1) and two equivalent N(1) atoms. There are two shorter (2.42 Å) and two longer (2.67 Å) Ag(1)-C(1) bond lengths. Both Ag(1)-N(1) bond lengths are 2.65 Å. C(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(1) atom. The C(1)-N(1) bond length is 1.35 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms.