PrSO is Hazelwoodite-derived structured and crystallizes in the orthorhombic Immm space group. Pr(1) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Pr(1) and two equivalent S(1) atoms. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of edge and corner-sharing OPr4 tetrahedra.
PrSO is Hazelwoodite-derived structured and crystallizes in the orthorhombic Immm space group. Pr(1) is bonded in a 4-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. All Pr(1)-S(1) bond lengths are 3.13 Å. There are two shorter (2.36 Å) and two longer (2.49 Å) Pr(1)-O(1) bond lengths. S(1) is bonded in a 6-coordinate geometry to four equivalent Pr(1) and two equivalent S(1) atoms. There is one shorter (2.07 Å) and one longer (2.59 Å) S(1)-S(1) bond length. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of edge and corner-sharing OPr4 tetrahedra.