CsAuTe crystallizes in the orthorhombic Pmma space group. Cs(1) is bonded in a 6-coordinate geometry to four equivalent Au(1) and two equivalent Te(1) atoms. Au(1) is bonded to four equivalent Cs(1) and two equivalent Te(1) atoms to form a mixture of corner, edge, and face-sharing AuCs4Te2 octahedra. The corner-sharing octahedral tilt angles are 52°. Te(1) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent Au(1) atoms.
CsAuTe crystallizes in the orthorhombic Pmma space group. Cs(1) is bonded in a 6-coordinate geometry to four equivalent Au(1) and two equivalent Te(1) atoms. All Cs(1)-Au(1) bond lengths are 3.78 Å. Both Cs(1)-Te(1) bond lengths are 4.01 Å. Au(1) is bonded to four equivalent Cs(1) and two equivalent Te(1) atoms to form a mixture of corner, edge, and face-sharing AuCs4Te2 octahedra. The corner-sharing octahedral tilt angles are 52°. Both Au(1)-Te(1) bond lengths are 2.62 Å. Te(1) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent Au(1) atoms.