LiCsN2 is I4/mcm-derived structured and crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. Li(1) is bonded to four equivalent N(1) atoms to form distorted edge-sharing LiN4 tetrahedra. N(1) is bonded in a 2-coordinate geometry to four equivalent Cs(1) and two equivalent Li(1) atoms.
LiCsN2 is I4/mcm-derived structured and crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. There are a spread of Cs(1)-N(1) bond distances ranging from 3.22-3.57 Å. Li(1) is bonded to four equivalent N(1) atoms to form distorted edge-sharing LiN4 tetrahedra. There are two shorter (2.01 Å) and two longer (2.05 Å) Li(1)-N(1) bond lengths. N(1) is bonded in a 2-coordinate geometry to four equivalent Cs(1) and two equivalent Li(1) atoms.