Li4V3Mn3(TeO8)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-69°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Te(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-73°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 48-52°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-52°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted TeO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(4), one V(1), one V(2), and one Te(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form distorted OLiMnV2 tetrahedra that share corners with two equivalent O(8)LiMnVTe tetrahedra and  an edgeedge with one O(9)LiV2Te tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form OLiMn2V tetrahedra that share  a cornercorner with one O(9)LiV2Te tetrahedra and corners with two equivalent O(15)LiMn2Te tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(4), one V(1), one Mn(1), and one Te(1) atom. In the eighth O site, O(8) is bonded to one Li(4), one V(2), one Mn(1), and one Te(1) atom to form distorted OLiMnVTe tetrahedra that share  a cornercorner with one O(9)LiV2Te tetrahedra and corners with two equivalent O(4)LiMnV2 tetrahedra. In the ninth O site, O(9) is bonded to one Li(2), one V(1), one V(2), and one Te(2) atom to form distorted OLiV2Te tetrahedra that share  a cornercorner with one O(15)LiMn2Te tetrahedra,  a cornercorner with one O(5)LiMn2V tetrahedra,  a cornercorner with one O(8)LiMnVTe tetrahedra, and  an edgeedge with one O(4)LiMnV2 tetrahedra. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(2), one Mn(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Mn(2), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Mn(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Mn(2), one Mn(3), and one Te(2) atom to form distorted OLiMn2Te tetrahedra that share  a cornercorner with one O(9)LiV2Te tetrahedra and corners with two equivalent O(5)LiMn2V tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Te(2) atom.
Li4V3Mn3(TeO8)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-69°. The Li(1)-O(11) bond length is 2.07 Å. The Li(1)-O(12) bond length is 2.01 Å. The Li(1)-O(15) bond length is 2.00 Å. The Li(1)-O(3) bond length is 2.07 Å. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. The Li(2)-O(14) bond length is 1.98 Å. The Li(2)-O(16) bond length is 2.02 Å. The Li(2)-O(5) bond length is 1.89 Å. The Li(2)-O(9) bond length is 1.92 Å. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Te(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. The Li(3)-O(1) bond length is 2.05 Å. The Li(3)-O(10) bond length is 2.03 Å. The Li(3)-O(4) bond length is 1.89 Å. The Li(3)-O(6) bond length is 2.05 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-73°. The Li(4)-O(13) bond length is 2.25 Å. The Li(4)-O(2) bond length is 2.03 Å. The Li(4)-O(7) bond length is 2.01 Å. The Li(4)-O(8) bond length is 2.05 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. The V(1)-O(14) bond length is 2.19 Å. The V(1)-O(2) bond length is 2.00 Å. The V(1)-O(3) bond length is 2.05 Å. The V(1)-O(4) bond length is 2.04 Å. The V(1)-O(7) bond length is 1.77 Å. The V(1)-O(9) bond length is 1.98 Å. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. The V(2)-O(16) bond length is 1.97 Å. The V(2)-O(2) bond length is 2.02 Å. The V(2)-O(3) bond length is 2.02 Å. The V(2)-O(4) bond length is 2.04 Å. The V(2)-O(8) bond length is 1.88 Å. The V(2)-O(9) bond length is 1.98 Å. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 48-52°. The V(3)-O(1) bond length is 2.07 Å. The V(3)-O(11) bond length is 2.05 Å. The V(3)-O(12) bond length is 1.77 Å. The V(3)-O(13) bond length is 1.97 Å. The V(3)-O(5) bond length is 1.96 Å. The V(3)-O(6) bond length is 2.24 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. The Mn(1)-O(14) bond length is 2.21 Å. The Mn(1)-O(16) bond length is 2.02 Å. The Mn(1)-O(3) bond length is 1.98 Å. The Mn(1)-O(4) bond length is 1.95 Å. The Mn(1)-O(7) bond length is 2.26 Å. The Mn(1)-O(8) bond length is 2.05 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-52°. The Mn(2)-O(1) bond length is 2.20 Å. The Mn(2)-O(10) bond length is 2.07 Å. The Mn(2)-O(11) bond length is 2.21 Å. The Mn(2)-O(13) bond length is 1.93 Å. The Mn(2)-O(15) bond length is 2.12 Å. The Mn(2)-O(5) bond length is 1.92 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 55-56°. The Mn(3)-O(10) bond length is 2.18 Å. The Mn(3)-O(12) bond length is 2.25 Å. The Mn(3)-O(13) bond length is 2.16 Å. The Mn(3)-O(15) bond length is 2.18 Å. The Mn(3)-O(5) bond length is 2.09 Å. The Mn(3)-O(6) bond length is 2.18 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted TeO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. The Te(1)-O(1) bond length is 2.05 Å. The Te(1)-O(10) bond length is 2.00 Å. The Te(1)-O(2) bond length is 2.45 Å. The Te(1)-O(6) bond length is 1.97 Å. The Te(1)-O(7) bond length is 2.51 Å. The Te(1)-O(8) bond length is 2.50 Å. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-58°. The Te(2)-O(11) bond length is 2.10 Å. The Te(2)-O(12) bond length is 2.45 Å. The Te(2)-O(14) bond length is 1.97 Å. The Te(2)-O(15) bond length is 2.01 Å. The Te(2)-O(16) bond length is 2.28 Å. The Te(2)-O(9) bond length is 2.40 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(4), one V(1), one V(2), and one Te(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form distorted OLiMnV2 tetrahedra that share corners with two equivalent O(8)LiMnVTe tetrahedra and  an edgeedge with one O(9)LiV2Te tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form OLiMn2V tetrahedra that share  a cornercorner with one O(9)LiV2Te tetrahedra and corners with two equivalent O(15)LiMn2Te tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(4), one V(1), one Mn(1), and one Te(1) atom. In the eighth O site, O(8) is bonded to one Li(4), one V(2), one Mn(1), and one Te(1) atom to form distorted OLiMnVTe tetrahedra that share  a cornercorner with one O(9)LiV2Te tetrahedra and corners with two equivalent O(4)LiMnV2 tetrahedra. In the ninth O site, O(9) is bonded to one Li(2), one V(1), one V(2), and one Te(2) atom to form distorted OLiV2Te tetrahedra that share  a cornercorner with one O(15)LiMn2Te tetrahedra,  a cornercorner with one O(5)LiMn2V tetrahedra,  a cornercorner with one O(8)LiMnVTe tetrahedra, and  an edgeedge with one O(4)LiMnV2 tetrahedra. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(2), one Mn(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Mn(2), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Mn(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Mn(2), one Mn(3), and one Te(2) atom to form distorted OLiMn2Te tetrahedra that share  a cornercorner with one O(9)LiV2Te tetrahedra and corners with two equivalent O(5)LiMn2V tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Te(2) atom.