V3As crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent As(1) atoms. As(1) is bonded to twelve equivalent V(1) atoms to form a mixture of face and edge-sharing AsV12 cuboctahedra.
V3As crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent As(1) atoms. Both V(1)-V(1) bond lengths are 2.36 Å. All V(1)-As(1) bond lengths are 2.63 Å. As(1) is bonded to twelve equivalent V(1) atoms to form a mixture of face and edge-sharing AsV12 cuboctahedra.