NaCrN2 is Chalcopyrite structured and crystallizes in the tetragonal I-42d space group. Na(1) is bonded to four equivalent N(1) atoms to form distorted NaN4 trigonal pyramids that share corners with eight equivalent Cr(1)N4 tetrahedra and corners with four equivalent Na(1)N4 trigonal pyramids. Cr(1) is bonded to four equivalent N(1) atoms to form CrN4 tetrahedra that share corners with four equivalent Cr(1)N4 tetrahedra and corners with eight equivalent Na(1)N4 trigonal pyramids. N(1) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Cr(1) atoms.
NaCrN2 is Chalcopyrite structured and crystallizes in the tetragonal I-42d space group. Na(1) is bonded to four equivalent N(1) atoms to form distorted NaN4 trigonal pyramids that share corners with eight equivalent Cr(1)N4 tetrahedra and corners with four equivalent Na(1)N4 trigonal pyramids. All Na(1)-N(1) bond lengths are 2.45 Å. Cr(1) is bonded to four equivalent N(1) atoms to form CrN4 tetrahedra that share corners with four equivalent Cr(1)N4 tetrahedra and corners with eight equivalent Na(1)N4 trigonal pyramids. All Cr(1)-N(1) bond lengths are 1.77 Å. N(1) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Cr(1) atoms.