Ag7NO6 crystallizes in the cubic F-43m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to twelve equivalent Ag(2) atoms to form AgAg12 cuboctahedra that share corners with twelve equivalent Ag(1)Ag12 cuboctahedra, faces with four equivalent O(1)Ag6 octahedra, and faces with four equivalent O(2)Ag6 octahedra. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1), one O(1), one O(2), and two equivalent O(3) atoms. N(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(2)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(1)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(2) and one N(1) atom.
Ag7NO6 crystallizes in the cubic F-43m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to twelve equivalent Ag(2) atoms to form AgAg12 cuboctahedra that share corners with twelve equivalent Ag(1)Ag12 cuboctahedra, faces with four equivalent O(1)Ag6 octahedra, and faces with four equivalent O(2)Ag6 octahedra. All Ag(1)-Ag(2) bond lengths are 3.33 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1), one O(1), one O(2), and two equivalent O(3) atoms. The Ag(2)-O(1) bond length is 2.40 Å. The Ag(2)-O(2) bond length is 2.32 Å. Both Ag(2)-O(3) bond lengths are 2.36 Å. N(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. All N(1)-O(3) bond lengths are 1.38 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(2)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to six equivalent Ag(2) atoms to form OAg6 octahedra that share corners with six equivalent O(1)Ag6 octahedra and faces with four equivalent Ag(1)Ag12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(2) and one N(1) atom.