NHS3 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four 1,2,3,4,6,7,5,8-hexathiadiazocane molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1), one S(1), and one S(3) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(1) atom.
NHS3 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four 1,2,3,4,6,7,5,8-hexathiadiazocane molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1), one S(1), and one S(3) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-S(1) bond length is 1.68 Å. The N(1)-S(3) bond length is 1.70 Å. H(1) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. The S(1)-S(2) bond length is 2.06 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(2) atom. The S(2)-S(2) bond length is 2.09 Å. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(1) atom.