SrLaVO4 crystallizes in the orthorhombic Ima2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), two equivalent O(5), two equivalent O(6), and three equivalent O(4) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(4), two equivalent O(5), two equivalent O(7), and three equivalent O(3) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(2), one O(4), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the second V site, V(2) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. There are seven inequivalent O sites. In the first O site, O(5) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one V(1), and one V(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the second O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), and two equivalent V(2) atoms. In the third O site, O(7) is bonded to two equivalent Sr(2), two equivalent La(2), and two equivalent V(1) atoms to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fourth O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), and one V(1) atom. In the fifth O site, O(2) is bonded in a 5-coordinate geometry to one Sr(2), one La(2), two equivalent La(1), and one V(2) atom. In the sixth O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), three equivalent Sr(2), one La(1), and one V(1) atom. In the seventh O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), three equivalent Sr(1), one La(2), and one V(2) atom.
SrLaVO4 crystallizes in the orthorhombic Ima2 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), two equivalent O(5), two equivalent O(6), and three equivalent O(4) atoms. The Sr(1)-O(1) bond length is 2.42 Å. The Sr(1)-O(3) bond length is 3.13 Å. Both Sr(1)-O(5) bond lengths are 2.63 Å. Both Sr(1)-O(6) bond lengths are 2.82 Å. There is one shorter (2.59 Å) and two longer (2.80 Å) Sr(1)-O(4) bond lengths. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(4), two equivalent O(5), two equivalent O(7), and three equivalent O(3) atoms. The Sr(2)-O(2) bond length is 2.42 Å. The Sr(2)-O(4) bond length is 3.13 Å. Both Sr(2)-O(5) bond lengths are 2.63 Å. Both Sr(2)-O(7) bond lengths are 2.81 Å. There is one shorter (2.60 Å) and two longer (2.80 Å) Sr(2)-O(3) bond lengths. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. The La(1)-O(1) bond length is 2.44 Å. The La(1)-O(3) bond length is 2.33 Å. Both La(1)-O(2) bond lengths are 2.80 Å. Both La(1)-O(5) bond lengths are 2.70 Å. Both La(1)-O(6) bond lengths are 2.58 Å. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(2), one O(4), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. The La(2)-O(2) bond length is 2.43 Å. The La(2)-O(4) bond length is 2.33 Å. Both La(2)-O(1) bond lengths are 2.80 Å. Both La(2)-O(5) bond lengths are 2.70 Å. Both La(2)-O(7) bond lengths are 2.58 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. The V(1)-O(1) bond length is 2.13 Å. The V(1)-O(3) bond length is 2.15 Å. Both V(1)-O(5) bond lengths are 1.98 Å. Both V(1)-O(7) bond lengths are 2.00 Å. In the second V site, V(2) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. The V(2)-O(2) bond length is 2.13 Å. The V(2)-O(4) bond length is 2.15 Å. Both V(2)-O(5) bond lengths are 1.98 Å. Both V(2)-O(6) bond lengths are 2.01 Å. There are seven inequivalent O sites. In the first O site, O(5) is bonded to one Sr(1), one Sr(2), one La(1), one La(2), one V(1), and one V(2) atom to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the second O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), and two equivalent V(2) atoms. In the third O site, O(7) is bonded to two equivalent Sr(2), two equivalent La(2), and two equivalent V(1) atoms to form a mixture of distorted corner, edge, and face-sharing OSr2La2V2 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fourth O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), and one V(1) atom. In the fifth O site, O(2) is bonded in a 5-coordinate geometry to one Sr(2), one La(2), two equivalent La(1), and one V(2) atom. In the sixth O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), three equivalent Sr(2), one La(1), and one V(1) atom. In the seventh O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), three equivalent Sr(1), one La(2), and one V(2) atom.