NaMgO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Mg(1)O6 octahedra. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent Na(1) and two equivalent Mg(1) atoms.
NaMgO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Mg(1)O6 octahedra. All Na(1)-O(1) bond lengths are 2.84 Å. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Mg(1)-O(1) bond lengths are 2.01 Å. O(1) is bonded in a distorted linear geometry to four equivalent Na(1) and two equivalent Mg(1) atoms.