(TiCu(O2F3)2)2N2F2 is Indium-derived structured and crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of two ammonia atoms, two hydrofluoric acid atoms, and two TiCu(O2F3)2 clusters. In each TiCu(O2F3)2 cluster, Ti(1) is bonded to one F(1), one F(2), and four equivalent F(3) atoms to form TiF6 octahedra that share  a cornercorner with one Cu(1)O4F square pyramid. Cu(1) is bonded to four equivalent O(1) and one F(1) atom to form distorted CuO4F square pyramids that share  a cornercorner with one Ti(1)F6 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a single-bond geometry to one Cu(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Ti(1) and one Cu(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom.
(TiCu(O2F3)2)2N2F2 is Indium-derived structured and crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of two ammonia atoms, two hydrofluoric acid atoms, and two TiCu(O2F3)2 clusters. In each TiCu(O2F3)2 cluster, Ti(1) is bonded to one F(1), one F(2), and four equivalent F(3) atoms to form TiF6 octahedra that share  a cornercorner with one Cu(1)O4F square pyramid. The Ti(1)-F(1) bond length is 1.88 Å. The Ti(1)-F(2) bond length is 1.85 Å. All Ti(1)-F(3) bond lengths are 1.91 Å. Cu(1) is bonded to four equivalent O(1) and one F(1) atom to form distorted CuO4F square pyramids that share  a cornercorner with one Ti(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Cu(1)-O(1) bond lengths are 1.81 Å. The Cu(1)-F(1) bond length is 2.31 Å. O(1) is bonded in a single-bond geometry to one Cu(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Ti(1) and one Cu(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom.