VOF2 crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form corner-sharing VO2F4 octahedra. The corner-sharing octahedral tilt angles range from 17-27°. O(1) is bonded in a linear geometry to two equivalent V(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.
VOF2 crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form corner-sharing VO2F4 octahedra. The corner-sharing octahedral tilt angles range from 17-27°. Both V(1)-O(1) bond lengths are 1.82 Å. All V(1)-F(1) bond lengths are 1.98 Å. O(1) is bonded in a linear geometry to two equivalent V(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.