VCoP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Co(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing CoP4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Co(1) atoms.
VCoP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. There are a spread of V(1)-P(1) bond distances ranging from 2.41-2.53 Å. Co(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing CoP4 tetrahedra. There are a spread of Co(1)-P(1) bond distances ranging from 2.21-2.23 Å. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Co(1) atoms.