HgIn2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Hg(1) is bonded to four equivalent O(1) atoms to form HgO4 tetrahedra that share corners with twelve equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Hg(1)O4 tetrahedra and edges with six equivalent In(1)O6 octahedra. O(1) is bonded to one Hg(1) and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing OIn3Hg tetrahedra.
HgIn2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Hg(1) is bonded to four equivalent O(1) atoms to form HgO4 tetrahedra that share corners with twelve equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. All Hg(1)-O(1) bond lengths are 2.26 Å. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Hg(1)O4 tetrahedra and edges with six equivalent In(1)O6 octahedra. All In(1)-O(1) bond lengths are 2.19 Å. O(1) is bonded to one Hg(1) and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing OIn3Hg tetrahedra.