Mn2O2F3 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to three equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 34-53°. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(1) is bonded in a water-like geometry to two equivalent Mn(1) atoms.
Mn2O2F3 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to three equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 34-53°. There are a spread of Mn(1)-O(1) bond distances ranging from 1.91-1.96 Å. The Mn(1)-F(2) bond length is 1.95 Å. There is one shorter (1.93 Å) and one longer (2.03 Å) Mn(1)-F(1) bond length. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(1) is bonded in a water-like geometry to two equivalent Mn(1) atoms.