NSF3 is Cubane-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four amino-sulfur trifluoride molecules. N(1) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one F(2), and two equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom.
NSF3 is Cubane-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four amino-sulfur trifluoride molecules. N(1) is bonded in a single-bond geometry to one S(1) atom. The N(1)-S(1) bond length is 1.43 Å. S(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one F(2), and two equivalent F(1) atoms. The S(1)-F(2) bond length is 1.59 Å. Both S(1)-F(1) bond lengths are 1.59 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom.