NiSnF6 crystallizes in the trigonal R-3 space group. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a bent 150 degrees geometry to one Ni(1) and one Sn(1) atom.
NiSnF6 crystallizes in the trigonal R-3 space group. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Ni(1)-F(1) bond lengths are 1.99 Å. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Sn(1)-F(1) bond lengths are 1.98 Å. F(1) is bonded in a bent 150 degrees geometry to one Ni(1) and one Sn(1) atom.