XeF5AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four XeF5 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(10), one F(11), one F(4), one F(6), one F(7), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), one F(2), one F(3), one F(5), and one F(8) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom.
XeF5AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four XeF5 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(10), one F(11), one F(4), one F(6), one F(7), and one F(9) atom. The As(1)-F(10) bond length is 1.80 Å. The As(1)-F(11) bond length is 1.74 Å. The As(1)-F(4) bond length is 1.85 Å. The As(1)-F(6) bond length is 1.81 Å. The As(1)-F(7) bond length is 1.74 Å. The As(1)-F(9) bond length is 1.74 Å. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), one F(2), one F(3), one F(5), and one F(8) atom. The Xe(1)-F(1) bond length is 1.96 Å. The Xe(1)-F(2) bond length is 1.98 Å. The Xe(1)-F(3) bond length is 1.98 Å. The Xe(1)-F(5) bond length is 1.98 Å. The Xe(1)-F(8) bond length is 1.97 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom.