NaRhO2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Na(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. O(1) is bonded to three equivalent Na(1) and three equivalent Rh(1) atoms to form a mixture of edge and corner-sharing ONa3Rh3 octahedra. The corner-sharing octahedra are not tilted.
NaRhO2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. All Na(1)-O(1) bond lengths are 2.35 Å. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Na(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. All Rh(1)-O(1) bond lengths are 2.07 Å. O(1) is bonded to three equivalent Na(1) and three equivalent Rh(1) atoms to form a mixture of edge and corner-sharing ONa3Rh3 octahedra. The corner-sharing octahedra are not tilted.