AgInTe2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form AgTe6 octahedra that share corners with six equivalent Ag(1)Te6 octahedra, edges with four equivalent Ag(1)Te6 octahedra, and edges with eight equivalent In(1)Te6 octahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to two equivalent Te(2) and four equivalent Te(1) atoms to form InTe6 octahedra that share corners with six equivalent In(1)Te6 octahedra, edges with four equivalent In(1)Te6 octahedra, and edges with eight equivalent Ag(1)Te6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent Ag(1) and four equivalent In(1) atoms to form TeIn4Ag2 octahedra that share corners with six equivalent Te(1)In4Ag2 octahedra, edges with four equivalent Te(1)In4Ag2 octahedra, and edges with eight equivalent Te(2)In2Ag4 octahedra. The corner-sharing octahedra are not tilted. In the second Te site, Te(2) is bonded to four equivalent Ag(1) and two equivalent In(1) atoms to form TeIn2Ag4 octahedra that share corners with six equivalent Te(2)In2Ag4 octahedra, edges with four equivalent Te(2)In2Ag4 octahedra, and edges with eight equivalent Te(1)In4Ag2 octahedra. The corner-sharing octahedra are not tilted.
AgInTe2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form AgTe6 octahedra that share corners with six equivalent Ag(1)Te6 octahedra, edges with four equivalent Ag(1)Te6 octahedra, and edges with eight equivalent In(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Both Ag(1)-Te(1) bond lengths are 3.00 Å. All Ag(1)-Te(2) bond lengths are 3.04 Å. In(1) is bonded to two equivalent Te(2) and four equivalent Te(1) atoms to form InTe6 octahedra that share corners with six equivalent In(1)Te6 octahedra, edges with four equivalent In(1)Te6 octahedra, and edges with eight equivalent Ag(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Both In(1)-Te(2) bond lengths are 3.00 Å. All In(1)-Te(1) bond lengths are 3.04 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent Ag(1) and four equivalent In(1) atoms to form TeIn4Ag2 octahedra that share corners with six equivalent Te(1)In4Ag2 octahedra, edges with four equivalent Te(1)In4Ag2 octahedra, and edges with eight equivalent Te(2)In2Ag4 octahedra. The corner-sharing octahedra are not tilted. In the second Te site, Te(2) is bonded to four equivalent Ag(1) and two equivalent In(1) atoms to form TeIn2Ag4 octahedra that share corners with six equivalent Te(2)In2Ag4 octahedra, edges with four equivalent Te(2)In2Ag4 octahedra, and edges with eight equivalent Te(1)In4Ag2 octahedra. The corner-sharing octahedra are not tilted.