HgHgO(ZnF3)2 crystallizes in the cubic Fd-3m space group. The structure consists of one HgHgO framework and one ZnF3 framework. In the HgHgO framework, Hg(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent Hg(1) atoms to form corner-sharing OHg4 tetrahedra. In the ZnF3 framework, Zn(1) is bonded to six equivalent F(1) atoms to form corner-sharing ZnF6 octahedra. The corner-sharing octahedral tilt angles are 46°. F(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Zn(1) atoms.
HgHgO(ZnF3)2 crystallizes in the cubic Fd-3m space group. The structure consists of one HgHgO framework and one ZnF3 framework. In the HgHgO framework, Hg(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. Both Hg(1)-O(1) bond lengths are 2.30 Å. O(1) is bonded to four equivalent Hg(1) atoms to form corner-sharing OHg4 tetrahedra. In the ZnF3 framework, Zn(1) is bonded to six equivalent F(1) atoms to form corner-sharing ZnF6 octahedra. The corner-sharing octahedral tilt angles are 46°. All Zn(1)-F(1) bond lengths are 2.04 Å. F(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Zn(1) atoms.