Re4As5S4 crystallizes in the cubic F-43m space group. Re(1) is bonded in a 6-coordinate geometry to three equivalent As(2) and three equivalent S(1) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a tetrahedral geometry to four equivalent As(2) atoms. In the second As site, As(2) is bonded to three equivalent Re(1) and one As(1) atom to form a mixture of distorted corner and edge-sharing AsRe3As tetrahedra. S(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms.
Re4As5S4 crystallizes in the cubic F-43m space group. Re(1) is bonded in a 6-coordinate geometry to three equivalent As(2) and three equivalent S(1) atoms. All Re(1)-As(2) bond lengths are 2.63 Å. All Re(1)-S(1) bond lengths are 2.33 Å. There are two inequivalent As sites. In the first As site, As(1) is bonded in a tetrahedral geometry to four equivalent As(2) atoms. All As(1)-As(2) bond lengths are 2.48 Å. In the second As site, As(2) is bonded to three equivalent Re(1) and one As(1) atom to form a mixture of distorted corner and edge-sharing AsRe3As tetrahedra. S(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms.