Rh3Te2 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to one Te(2) and four equivalent Te(1) atoms. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to two equivalent Te(1) and three equivalent Te(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. In the second Te site, Te(2) is bonded in a 7-coordinate geometry to one Rh(1) and six equivalent Rh(2) atoms.
Rh3Te2 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to one Te(2) and four equivalent Te(1) atoms. The Rh(1)-Te(2) bond length is 2.64 Å. All Rh(1)-Te(1) bond lengths are 2.72 Å. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to two equivalent Te(1) and three equivalent Te(2) atoms. Both Rh(2)-Te(1) bond lengths are 2.78 Å. All Rh(2)-Te(2) bond lengths are 2.64 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. In the second Te site, Te(2) is bonded in a 7-coordinate geometry to one Rh(1) and six equivalent Rh(2) atoms.