WOF4 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two WOF4 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1), one F(2), one F(5), and two equivalent F(1) atoms to form corner-sharing WO2F4 octahedra. The corner-sharing octahedral tilt angles are 1°. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent F(3), and two equivalent F(4) atoms to form corner-sharing WO2F4 octahedra. The corner-sharing octahedral tilt angles are 1°. O(1) is bonded in a linear geometry to one W(1) and one W(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom.
WOF4 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two WOF4 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1), one F(2), one F(5), and two equivalent F(1) atoms to form corner-sharing WO2F4 octahedra. The corner-sharing octahedral tilt angles are 1°. Both W(1)-O(1) bond lengths are 1.89 Å. The W(1)-F(2) bond length is 1.85 Å. The W(1)-F(5) bond length is 1.87 Å. Both W(1)-F(1) bond lengths are 1.86 Å. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent F(3), and two equivalent F(4) atoms to form corner-sharing WO2F4 octahedra. The corner-sharing octahedral tilt angles are 1°. Both W(2)-O(1) bond lengths are 1.89 Å. Both W(2)-F(3) bond lengths are 1.86 Å. Both W(2)-F(4) bond lengths are 1.86 Å. O(1) is bonded in a linear geometry to one W(1) and one W(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom.