LiEuF2 crystallizes in the tetragonal I4_1/amd space group. The structure consists of a LiEuF2 framework. Li(1) is bonded in a linear geometry to two equivalent F(1) atoms. Eu(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent F(1) atoms. F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1) and two equivalent Eu(1) atoms.
LiEuF2 crystallizes in the tetragonal I4_1/amd space group. The structure consists of a LiEuF2 framework. Li(1) is bonded in a linear geometry to two equivalent F(1) atoms. Both Li(1)-F(1) bond lengths are 1.86 Å. Eu(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent F(1) atoms. All Eu(1)-F(1) bond lengths are 2.49 Å. F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1) and two equivalent Eu(1) atoms.