V2CAs is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to three equivalent C(1) and three equivalent As(1) atoms to form a mixture of distorted edge, corner, and face-sharing VAs3C3 octahedra. The corner-sharing octahedral tilt angles range from 0-42°. C(1) is bonded to six equivalent V(1) atoms to form edge-sharing CV6 octahedra. As(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.
V2CAs is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to three equivalent C(1) and three equivalent As(1) atoms to form a mixture of distorted edge, corner, and face-sharing VAs3C3 octahedra. The corner-sharing octahedral tilt angles range from 0-42°. All V(1)-C(1) bond lengths are 2.07 Å. All V(1)-As(1) bond lengths are 2.53 Å. C(1) is bonded to six equivalent V(1) atoms to form edge-sharing CV6 octahedra. As(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.