Li4MnSb(WO6)2 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one O(2), one O(5), one O(6), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-38°. In the second W site, W(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. Mn(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-41°. Sb(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-42°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one W(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one W(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one W(2), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one W(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one W(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OLi2SbW tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one W(2), and one Mn(1) atom to form distorted OLi2MnW tetrahedra that share  a cornercorner with one O(5)Li2SbW tetrahedra, corners with two equivalent O(9)Li2MnW tetrahedra, and  an edgeedge with one O(5)Li2SbW tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one W(2), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one W(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one W(1), and one Mn(1) atom to form distorted OLi2MnW tetrahedra that share  a cornercorner with one O(5)Li2SbW tetrahedra and corners with two equivalent O(6)Li2MnW tetrahedra. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one W(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one W(1), and one Sb(1) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(4), one W(1), and one Mn(1) atom.
Li4MnSb(WO6)2 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. The Li(1)-O(1) bond length is 2.33 Å. The Li(1)-O(11) bond length is 2.37 Å. The Li(1)-O(4) bond length is 2.02 Å. The Li(1)-O(7) bond length is 1.99 Å. The Li(1)-O(8) bond length is 2.09 Å. The Li(1)-O(9) bond length is 2.26 Å. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. The Li(2)-O(10) bond length is 2.09 Å. The Li(2)-O(12) bond length is 2.00 Å. The Li(2)-O(2) bond length is 2.04 Å. The Li(2)-O(3) bond length is 2.56 Å. The Li(2)-O(5) bond length is 2.27 Å. The Li(2)-O(6) bond length is 2.20 Å. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one O(2), one O(5), one O(6), and one O(9) atom. The Li(3)-O(2) bond length is 2.59 Å. The Li(3)-O(5) bond length is 1.98 Å. The Li(3)-O(6) bond length is 1.95 Å. The Li(3)-O(9) bond length is 1.96 Å. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. The Li(4)-O(1) bond length is 2.05 Å. The Li(4)-O(11) bond length is 2.03 Å. The Li(4)-O(12) bond length is 2.24 Å. The Li(4)-O(3) bond length is 2.02 Å. The Li(4)-O(4) bond length is 2.28 Å. The Li(4)-O(7) bond length is 2.30 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-38°. The W(1)-O(1) bond length is 1.94 Å. The W(1)-O(11) bond length is 2.03 Å. The W(1)-O(12) bond length is 1.92 Å. The W(1)-O(2) bond length is 1.97 Å. The W(1)-O(4) bond length is 1.92 Å. The W(1)-O(9) bond length is 1.95 Å. In the second W site, W(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. The W(2)-O(10) bond length is 1.95 Å. The W(2)-O(3) bond length is 2.01 Å. The W(2)-O(5) bond length is 2.04 Å. The W(2)-O(6) bond length is 1.90 Å. The W(2)-O(7) bond length is 1.87 Å. The W(2)-O(8) bond length is 1.95 Å. Mn(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-41°. The Mn(1)-O(1) bond length is 1.96 Å. The Mn(1)-O(12) bond length is 2.02 Å. The Mn(1)-O(4) bond length is 1.99 Å. The Mn(1)-O(6) bond length is 2.14 Å. The Mn(1)-O(7) bond length is 2.20 Å. The Mn(1)-O(9) bond length is 1.94 Å. Sb(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-42°. The Sb(1)-O(10) bond length is 2.02 Å. The Sb(1)-O(11) bond length is 1.99 Å. The Sb(1)-O(2) bond length is 2.05 Å. The Sb(1)-O(3) bond length is 1.98 Å. The Sb(1)-O(5) bond length is 1.98 Å. The Sb(1)-O(8) bond length is 2.01 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one W(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one W(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one W(2), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one W(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one W(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OLi2SbW tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one W(2), and one Mn(1) atom to form distorted OLi2MnW tetrahedra that share  a cornercorner with one O(5)Li2SbW tetrahedra, corners with two equivalent O(9)Li2MnW tetrahedra, and  an edgeedge with one O(5)Li2SbW tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one W(2), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one W(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one W(1), and one Mn(1) atom to form distorted OLi2MnW tetrahedra that share  a cornercorner with one O(5)Li2SbW tetrahedra and corners with two equivalent O(6)Li2MnW tetrahedra. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(2), one W(2), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(4), one W(1), and one Sb(1) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(4), one W(1), and one Mn(1) atom.