CaCu4P2 crystallizes in the tetragonal P4_2/mnm space group. Ca(1) is bonded in a 18-coordinate geometry to twelve equivalent Cu(1) and six equivalent P(1) atoms. Cu(1) is bonded in a 3-coordinate geometry to three equivalent Ca(1) and three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to three equivalent Ca(1) and six equivalent Cu(1) atoms.
CaCu4P2 crystallizes in the tetragonal P4_2/mnm space group. Ca(1) is bonded in a 18-coordinate geometry to twelve equivalent Cu(1) and six equivalent P(1) atoms. There are eight shorter (3.14 Å) and four longer (3.24 Å) Ca(1)-Cu(1) bond lengths. There are two shorter (2.88 Å) and four longer (2.94 Å) Ca(1)-P(1) bond lengths. Cu(1) is bonded in a 3-coordinate geometry to three equivalent Ca(1) and three equivalent P(1) atoms. There is one shorter (2.35 Å) and two longer (2.40 Å) Cu(1)-P(1) bond lengths. P(1) is bonded in a 9-coordinate geometry to three equivalent Ca(1) and six equivalent Cu(1) atoms.