Ca3AsN is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ca(1) is bonded in a linear geometry to four equivalent As(1) and two equivalent N(1) atoms. As(1) is bonded to twelve equivalent Ca(1) atoms to form AsCa12 cuboctahedra that share corners with twelve equivalent As(1)Ca12 cuboctahedra, faces with six equivalent As(1)Ca12 cuboctahedra, and faces with eight equivalent N(1)Ca6 octahedra. N(1) is bonded to six equivalent Ca(1) atoms to form NCa6 octahedra that share corners with six equivalent N(1)Ca6 octahedra and faces with eight equivalent As(1)Ca12 cuboctahedra. The corner-sharing octahedra are not tilted.
Ca3AsN is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ca(1) is bonded in a linear geometry to four equivalent As(1) and two equivalent N(1) atoms. All Ca(1)-As(1) bond lengths are 3.36 Å. Both Ca(1)-N(1) bond lengths are 2.38 Å. As(1) is bonded to twelve equivalent Ca(1) atoms to form AsCa12 cuboctahedra that share corners with twelve equivalent As(1)Ca12 cuboctahedra, faces with six equivalent As(1)Ca12 cuboctahedra, and faces with eight equivalent N(1)Ca6 octahedra. N(1) is bonded to six equivalent Ca(1) atoms to form NCa6 octahedra that share corners with six equivalent N(1)Ca6 octahedra and faces with eight equivalent As(1)Ca12 cuboctahedra. The corner-sharing octahedra are not tilted.