PtSbTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pt(1) is bonded to three equivalent Sb(1) and three equivalent Te(1) atoms to form PtSb3Te3 octahedra that share corners with twelve equivalent Pt(1)Sb3Te3 octahedra, corners with three equivalent Sb(1)TePt3 trigonal pyramids, and corners with three equivalent Te(1)SbPt3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 62-63°. Sb(1) is bonded to three equivalent Pt(1) and one Te(1) atom to form distorted SbTePt3 trigonal pyramids that share corners with three equivalent Pt(1)Sb3Te3 octahedra, corners with six equivalent Sb(1)TePt3 trigonal pyramids, and corners with nine equivalent Te(1)SbPt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°. Te(1) is bonded to three equivalent Pt(1) and one Sb(1) atom to form distorted TeSbPt3 trigonal pyramids that share corners with three equivalent Pt(1)Sb3Te3 octahedra, corners with six equivalent Te(1)SbPt3 trigonal pyramids, and corners with nine equivalent Sb(1)TePt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.
PtSbTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pt(1) is bonded to three equivalent Sb(1) and three equivalent Te(1) atoms to form PtSb3Te3 octahedra that share corners with twelve equivalent Pt(1)Sb3Te3 octahedra, corners with three equivalent Sb(1)TePt3 trigonal pyramids, and corners with three equivalent Te(1)SbPt3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 62-63°. All Pt(1)-Sb(1) bond lengths are 2.70 Å. All Pt(1)-Te(1) bond lengths are 2.77 Å. Sb(1) is bonded to three equivalent Pt(1) and one Te(1) atom to form distorted SbTePt3 trigonal pyramids that share corners with three equivalent Pt(1)Sb3Te3 octahedra, corners with six equivalent Sb(1)TePt3 trigonal pyramids, and corners with nine equivalent Te(1)SbPt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°. The Sb(1)-Te(1) bond length is 2.90 Å. Te(1) is bonded to three equivalent Pt(1) and one Sb(1) atom to form distorted TeSbPt3 trigonal pyramids that share corners with three equivalent Pt(1)Sb3Te3 octahedra, corners with six equivalent Te(1)SbPt3 trigonal pyramids, and corners with nine equivalent Sb(1)TePt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.