CdZnSeTe is Stannite-like structured and crystallizes in the trigonal R3m space group. Cd(1) is bonded to three equivalent Te(1) and one Se(1) atom to form CdTe3Se tetrahedra that share corners with six equivalent Cd(1)Te3Se tetrahedra and corners with six equivalent Zn(1)TeSe3 tetrahedra. Zn(1) is bonded to one Te(1) and three equivalent Se(1) atoms to form ZnTeSe3 tetrahedra that share corners with six equivalent Cd(1)Te3Se tetrahedra and corners with six equivalent Zn(1)TeSe3 tetrahedra. Te(1) is bonded to three equivalent Cd(1) and one Zn(1) atom to form TeZnCd3 tetrahedra that share corners with six equivalent Te(1)ZnCd3 tetrahedra and corners with six equivalent Se(1)Zn3Cd tetrahedra. Se(1) is bonded to one Cd(1) and three equivalent Zn(1) atoms to form SeZn3Cd tetrahedra that share corners with six equivalent Te(1)ZnCd3 tetrahedra and corners with six equivalent Se(1)Zn3Cd tetrahedra.
CdZnSeTe is Stannite-like structured and crystallizes in the trigonal R3m space group. Cd(1) is bonded to three equivalent Te(1) and one Se(1) atom to form CdTe3Se tetrahedra that share corners with six equivalent Cd(1)Te3Se tetrahedra and corners with six equivalent Zn(1)TeSe3 tetrahedra. All Cd(1)-Te(1) bond lengths are 2.79 Å. The Cd(1)-Se(1) bond length is 2.67 Å. Zn(1) is bonded to one Te(1) and three equivalent Se(1) atoms to form ZnTeSe3 tetrahedra that share corners with six equivalent Cd(1)Te3Se tetrahedra and corners with six equivalent Zn(1)TeSe3 tetrahedra. The Zn(1)-Te(1) bond length is 2.67 Å. All Zn(1)-Se(1) bond lengths are 2.61 Å. Te(1) is bonded to three equivalent Cd(1) and one Zn(1) atom to form TeZnCd3 tetrahedra that share corners with six equivalent Te(1)ZnCd3 tetrahedra and corners with six equivalent Se(1)Zn3Cd tetrahedra. Se(1) is bonded to one Cd(1) and three equivalent Zn(1) atoms to form SeZn3Cd tetrahedra that share corners with six equivalent Te(1)ZnCd3 tetrahedra and corners with six equivalent Se(1)Zn3Cd tetrahedra.