GaH13(C2N)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one GaH13(C2N)2 cluster. Ga(1) is bonded to one N(1), two equivalent N(2), and one H(9) atom to form GaHN3 tetrahedra that share  a cornercorner with one C(1)H3N tetrahedra,  a cornercorner with one C(3)H3N tetrahedra, corners with two equivalent C(2)H3N tetrahedra, corners with two equivalent C(4)H3N tetrahedra, and  an edgeedge with one Ga(1)HN3 tetrahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(3), one H(4), and one H(6) atom to form CH3N tetrahedra that share  a cornercorner with one Ga(1)HN3 tetrahedra and  a cornercorner with one C(3)H3N tetrahedra. In the second C site, C(2) is bonded to one N(2), one H(1), one H(10), and one H(8) atom to form CH3N tetrahedra that share  a cornercorner with one C(4)H3N tetrahedra and corners with two equivalent Ga(1)HN3 tetrahedra. In the third C site, C(3) is bonded to one N(1), one H(11), one H(5), and one H(7) atom to form CH3N tetrahedra that share  a cornercorner with one Ga(1)HN3 tetrahedra and  a cornercorner with one C(1)H3N tetrahedra. In the fourth C site, C(4) is bonded to one N(2), one H(12), one H(13), and one H(2) atom to form CH3N tetrahedra that share  a cornercorner with one C(2)H3N tetrahedra and corners with two equivalent Ga(1)HN3 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ga(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded to two equivalent Ga(1), one C(2), and one C(4) atom to form edge-sharing NGa2C2 tetrahedra. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one Ga(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(4) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(4) atom.
GaH13(C2N)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one GaH13(C2N)2 cluster. Ga(1) is bonded to one N(1), two equivalent N(2), and one H(9) atom to form GaHN3 tetrahedra that share  a cornercorner with one C(1)H3N tetrahedra,  a cornercorner with one C(3)H3N tetrahedra, corners with two equivalent C(2)H3N tetrahedra, corners with two equivalent C(4)H3N tetrahedra, and  an edgeedge with one Ga(1)HN3 tetrahedra. The Ga(1)-N(1) bond length is 1.87 Å. There is one shorter (2.04 Å) and one longer (2.06 Å) Ga(1)-N(2) bond length. The Ga(1)-H(9) bond length is 1.56 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(3), one H(4), and one H(6) atom to form CH3N tetrahedra that share  a cornercorner with one Ga(1)HN3 tetrahedra and  a cornercorner with one C(3)H3N tetrahedra. The C(1)-N(1) bond length is 1.45 Å. The C(1)-H(3) bond length is 1.11 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-H(6) bond length is 1.11 Å. In the second C site, C(2) is bonded to one N(2), one H(1), one H(10), and one H(8) atom to form CH3N tetrahedra that share  a cornercorner with one C(4)H3N tetrahedra and corners with two equivalent Ga(1)HN3 tetrahedra. The C(2)-N(2) bond length is 1.48 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(10) bond length is 1.10 Å. The C(2)-H(8) bond length is 1.10 Å. In the third C site, C(3) is bonded to one N(1), one H(11), one H(5), and one H(7) atom to form CH3N tetrahedra that share  a cornercorner with one Ga(1)HN3 tetrahedra and  a cornercorner with one C(1)H3N tetrahedra. The C(3)-N(1) bond length is 1.45 Å. The C(3)-H(11) bond length is 1.11 Å. The C(3)-H(5) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.11 Å. In the fourth C site, C(4) is bonded to one N(2), one H(12), one H(13), and one H(2) atom to form CH3N tetrahedra that share  a cornercorner with one C(2)H3N tetrahedra and corners with two equivalent Ga(1)HN3 tetrahedra. The C(4)-N(2) bond length is 1.48 Å. The C(4)-H(12) bond length is 1.10 Å. The C(4)-H(13) bond length is 1.10 Å. The C(4)-H(2) bond length is 1.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ga(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded to two equivalent Ga(1), one C(2), and one C(4) atom to form edge-sharing NGa2C2 tetrahedra. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one Ga(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(4) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(4) atom.