Li2MnF4 crystallizes in the tetragonal P-42m space group. Li(1) is bonded to four equivalent F(1) atoms to form LiF4 tetrahedra that share corners with four equivalent Li(1)F4 tetrahedra and corners with four equivalent Mn(1)F4 tetrahedra. Mn(1) is bonded to four equivalent F(1) atoms to form distorted MnF4 tetrahedra that share corners with eight equivalent Li(1)F4 tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to two equivalent Li(1) and one Mn(1) atom.
Li2MnF4 crystallizes in the tetragonal P-42m space group. Li(1) is bonded to four equivalent F(1) atoms to form LiF4 tetrahedra that share corners with four equivalent Li(1)F4 tetrahedra and corners with four equivalent Mn(1)F4 tetrahedra. All Li(1)-F(1) bond lengths are 1.91 Å. Mn(1) is bonded to four equivalent F(1) atoms to form distorted MnF4 tetrahedra that share corners with eight equivalent Li(1)F4 tetrahedra. All Mn(1)-F(1) bond lengths are 2.03 Å. F(1) is bonded in a trigonal non-coplanar geometry to two equivalent Li(1) and one Mn(1) atom.