CdSO4 crystallizes in the orthorhombic Pmn2_1 space group. Cd(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), and four equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(1) atom.
CdSO4 crystallizes in the orthorhombic Pmn2_1 space group. Cd(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), and four equivalent O(1) atoms. The Cd(1)-O(2) bond length is 2.24 Å. The Cd(1)-O(3) bond length is 2.30 Å. There are two shorter (2.25 Å) and two longer (2.57 Å) Cd(1)-O(1) bond lengths. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.47 Å. Both S(1)-O(1) bond lengths are 1.48 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one S(1) atom.