SnO2 is Baddeleyite-like structured and crystallizes in the orthorhombic Pbca space group. Sn(1) is bonded to three equivalent O(1) and four equivalent O(2) atoms to form a mixture of distorted edge and corner-sharing SnO7 pentagonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent Sn(1) atoms. In the second O site, O(2) is bonded to four equivalent Sn(1) atoms to form a mixture of edge and corner-sharing OSn4 tetrahedra.
SnO2 is Baddeleyite-like structured and crystallizes in the orthorhombic Pbca space group. Sn(1) is bonded to three equivalent O(1) and four equivalent O(2) atoms to form a mixture of distorted edge and corner-sharing SnO7 pentagonal bipyramids. There are a spread of Sn(1)-O(1) bond distances ranging from 2.07-2.15 Å. There are a spread of Sn(1)-O(2) bond distances ranging from 2.18-2.27 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent Sn(1) atoms. In the second O site, O(2) is bonded to four equivalent Sn(1) atoms to form a mixture of edge and corner-sharing OSn4 tetrahedra.