V2Mn3Si3 crystallizes in the hexagonal P6_3/mcm space group. V(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent Si(1) atoms. Mn(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to four equivalent V(1) and five equivalent Mn(1) atoms.
V2Mn3Si3 crystallizes in the hexagonal P6_3/mcm space group. V(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent Si(1) atoms. Both V(1)-V(1) bond lengths are 2.40 Å. All V(1)-Si(1) bond lengths are 2.51 Å. Mn(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. There are a spread of Mn(1)-Si(1) bond distances ranging from 2.38-2.54 Å. Si(1) is bonded in a 9-coordinate geometry to four equivalent V(1) and five equivalent Mn(1) atoms.