PrPdSb crystallizes in the trigonal P-3m1 space group. Pr(1) is bonded in a 13-coordinate geometry to one Pr(1), six equivalent Pd(1), and six equivalent Sb(1) atoms. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Pr(1), three equivalent Pd(1), and one Sb(1) atom. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Pr(1), one Pd(1), and three equivalent Sb(1) atoms.
PrPdSb crystallizes in the trigonal P-3m1 space group. Pr(1) is bonded in a 13-coordinate geometry to one Pr(1), six equivalent Pd(1), and six equivalent Sb(1) atoms. The Pr(1)-Pr(1) bond length is 3.21 Å. There are three shorter (3.15 Å) and three longer (3.48 Å) Pr(1)-Pd(1) bond lengths. There are three shorter (3.32 Å) and three longer (3.63 Å) Pr(1)-Sb(1) bond lengths. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Pr(1), three equivalent Pd(1), and one Sb(1) atom. All Pd(1)-Pd(1) bond lengths are 2.97 Å. The Pd(1)-Sb(1) bond length is 2.91 Å. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Pr(1), one Pd(1), and three equivalent Sb(1) atoms. All Sb(1)-Sb(1) bond lengths are 2.94 Å.