Ce2Ru3Fe crystallizes in the trigonal R-3m space group. Ce(1) is bonded in a 3-coordinate geometry to nine equivalent Ru(1) atoms. Ru(1) is bonded in a 12-coordinate geometry to six equivalent Ce(1), four equivalent Ru(1), and two equivalent Fe(1) atoms. Fe(1) is bonded to six equivalent Ru(1) atoms to form distorted corner-sharing FeRu6 cuboctahedra.
Ce2Ru3Fe crystallizes in the trigonal R-3m space group. Ce(1) is bonded in a 3-coordinate geometry to nine equivalent Ru(1) atoms. There are three shorter (2.82 Å) and six longer (3.20 Å) Ce(1)-Ru(1) bond lengths. Ru(1) is bonded in a 12-coordinate geometry to six equivalent Ce(1), four equivalent Ru(1), and two equivalent Fe(1) atoms. All Ru(1)-Ru(1) bond lengths are 2.81 Å. Both Ru(1)-Fe(1) bond lengths are 2.52 Å. Fe(1) is bonded to six equivalent Ru(1) atoms to form distorted corner-sharing FeRu6 cuboctahedra.