KCN2H3SO crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 10-coordinate geometry to one N(2), two equivalent H(2), two equivalent H(3), two equivalent S(1), and three equivalent O(1) atoms. C(1) is bonded in a linear geometry to one N(1) and one O(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one C(1) and one H(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one S(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one H(3) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one H(2) atom. S(1) is bonded in a single-bond geometry to two equivalent K(1) and one N(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one C(1) atom.
KCN2H3SO crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 10-coordinate geometry to one N(2), two equivalent H(2), two equivalent H(3), two equivalent S(1), and three equivalent O(1) atoms. The K(1)-N(2) bond length is 2.84 Å. There is one shorter (2.63 Å) and one longer (2.93 Å) K(1)-H(2) bond length. There is one shorter (2.69 Å) and one longer (2.70 Å) K(1)-H(3) bond length. There is one shorter (3.50 Å) and one longer (3.72 Å) K(1)-S(1) bond length. There is one shorter (3.02 Å) and two longer (3.20 Å) K(1)-O(1) bond lengths. C(1) is bonded in a linear geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-O(1) bond length is 1.21 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one C(1) and one H(1) atom. The N(1)-H(1) bond length is 1.04 Å. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one S(1) atom. The N(2)-S(1) bond length is 1.58 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one H(3) atom. The H(2)-H(3) bond length is 0.76 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one H(2) atom. S(1) is bonded in a single-bond geometry to two equivalent K(1) and one N(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one C(1) atom.