(CrCdN2)2Cd crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-43-9 atoms inside a CrCdN2 framework. In the CrCdN2 framework, Cr(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of edge and corner-sharing CrN4 tetrahedra. Cd(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Cr(1) and two equivalent Cd(1) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cr(1) atoms.
(CrCdN2)2Cd crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-43-9 atoms inside a CrCdN2 framework. In the CrCdN2 framework, Cr(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of edge and corner-sharing CrN4 tetrahedra. There is one shorter (1.83 Å) and one longer (1.84 Å) Cr(1)-N(1) bond length. There is one shorter (1.73 Å) and one longer (1.76 Å) Cr(1)-N(2) bond length. Cd(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There is one shorter (2.36 Å) and one longer (2.40 Å) Cd(1)-N(1) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Cr(1) and two equivalent Cd(1) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cr(1) atoms.