Cs2AgBiBr6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-22-4 atoms and four 7440-69-9 atoms inside a CsBr3 framework. In the CsBr3 framework, Cs(1) is bonded to six equivalent Br(1) atoms to form corner-sharing CsBr6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to two equivalent Cs(1) atoms.
Cs2AgBiBr6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-22-4 atoms and four 7440-69-9 atoms inside a CsBr3 framework. In the CsBr3 framework, Cs(1) is bonded to six equivalent Br(1) atoms to form corner-sharing CsBr6 octahedra. The corner-sharing octahedra are not tilted. All Cs(1)-Br(1) bond lengths are 3.29 Å. Br(1) is bonded in a linear geometry to two equivalent Cs(1) atoms.