CF3I is Ammonia-derived structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of eight trifluoromethyl iodide molecules. C(1) is bonded in a trigonal non-coplanar geometry to one I(1), one F(2), and two equivalent F(1) atoms. I(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(1) atom.
CF3I is Ammonia-derived structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of eight trifluoromethyl iodide molecules. C(1) is bonded in a trigonal non-coplanar geometry to one I(1), one F(2), and two equivalent F(1) atoms. The C(1)-I(1) bond length is 2.17 Å. The C(1)-F(2) bond length is 1.35 Å. Both C(1)-F(1) bond lengths are 1.35 Å. I(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(1) atom.