PbTl3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Tl(1) is bonded in a 4-coordinate geometry to four equivalent Pb(1) atoms. Pb(1) is bonded to twelve equivalent Tl(1) atoms to form a mixture of corner and face-sharing PbTl12 cuboctahedra.
PbTl3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Tl(1) is bonded in a 4-coordinate geometry to four equivalent Pb(1) atoms. There are two shorter (3.46 Å) and two longer (3.54 Å) Tl(1)-Pb(1) bond lengths. Pb(1) is bonded to twelve equivalent Tl(1) atoms to form a mixture of corner and face-sharing PbTl12 cuboctahedra.