PdSbTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pd(1) is bonded to three equivalent Sb(1) and three equivalent Te(1) atoms to form PdSb3Te3 octahedra that share corners with twelve equivalent Pd(1)Sb3Te3 octahedra, corners with three equivalent Sb(1)TePd3 trigonal pyramids, and corners with three equivalent Te(1)SbPd3 trigonal pyramids. The corner-sharing octahedral tilt angles are 63°. Sb(1) is bonded to three equivalent Pd(1) and one Te(1) atom to form SbTePd3 trigonal pyramids that share corners with three equivalent Pd(1)Sb3Te3 octahedra, corners with six equivalent Sb(1)TePd3 trigonal pyramids, and corners with nine equivalent Te(1)SbPd3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°. Te(1) is bonded to three equivalent Pd(1) and one Sb(1) atom to form TeSbPd3 trigonal pyramids that share corners with three equivalent Pd(1)Sb3Te3 octahedra, corners with six equivalent Te(1)SbPd3 trigonal pyramids, and corners with nine equivalent Sb(1)TePd3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.
PdSbTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pd(1) is bonded to three equivalent Sb(1) and three equivalent Te(1) atoms to form PdSb3Te3 octahedra that share corners with twelve equivalent Pd(1)Sb3Te3 octahedra, corners with three equivalent Sb(1)TePd3 trigonal pyramids, and corners with three equivalent Te(1)SbPd3 trigonal pyramids. The corner-sharing octahedral tilt angles are 63°. All Pd(1)-Sb(1) bond lengths are 2.71 Å. All Pd(1)-Te(1) bond lengths are 2.77 Å. Sb(1) is bonded to three equivalent Pd(1) and one Te(1) atom to form SbTePd3 trigonal pyramids that share corners with three equivalent Pd(1)Sb3Te3 octahedra, corners with six equivalent Sb(1)TePd3 trigonal pyramids, and corners with nine equivalent Te(1)SbPd3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°. The Sb(1)-Te(1) bond length is 2.88 Å. Te(1) is bonded to three equivalent Pd(1) and one Sb(1) atom to form TeSbPd3 trigonal pyramids that share corners with three equivalent Pd(1)Sb3Te3 octahedra, corners with six equivalent Te(1)SbPd3 trigonal pyramids, and corners with nine equivalent Sb(1)TePd3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.