TbWO4Cl crystallizes in the monoclinic C2/m space group. Tb(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), four equivalent O(3), and two equivalent Cl(1) atoms. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Tb(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Tb(1) and one W(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Tb(1) and one W(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent Tb(1) atoms.
TbWO4Cl crystallizes in the monoclinic C2/m space group. Tb(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), four equivalent O(3), and two equivalent Cl(1) atoms. The Tb(1)-O(1) bond length is 2.32 Å. The Tb(1)-O(2) bond length is 2.32 Å. There are two shorter (2.32 Å) and two longer (2.69 Å) Tb(1)-O(3) bond lengths. There is one shorter (2.74 Å) and one longer (2.77 Å) Tb(1)-Cl(1) bond length. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. The W(1)-O(1) bond length is 1.80 Å. The W(1)-O(2) bond length is 1.80 Å. Both W(1)-O(3) bond lengths are 1.83 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Tb(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Tb(1) and one W(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Tb(1) and one W(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent Tb(1) atoms.