NaRuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Ru(1)O6 octahedra. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Na(1) and two equivalent Ru(1) atoms to form a mixture of distorted edge, corner, and face-sharing ONa4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
NaRuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Ru(1)O6 octahedra. All Na(1)-O(1) bond lengths are 2.73 Å. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ru(1)-O(1) bond lengths are 1.93 Å. O(1) is bonded to four equivalent Na(1) and two equivalent Ru(1) atoms to form a mixture of distorted edge, corner, and face-sharing ONa4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.