NH2SF4AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two NH2SF4 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3,5) atoms. There are two inequivalent F sites. In the first F site, F(1,3,5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each NH2SF4 cluster, N(1) is bonded in a trigonal planar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a trigonal bipyramidal geometry to one N(1), one F(10), one F(7), one F(8), and one F(9) atom. There are four inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(9) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one S(1) atom.
NH2SF4AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two NH2SF4 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3,5) atoms. Both As(1)-F(2) bond lengths are 1.79 Å. There are two shorter (1.76 Å) and two longer (1.77 Å) As(1)-F(1,3,5) bond lengths. There are two inequivalent F sites. In the first F site, F(1,3,5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each NH2SF4 cluster, N(1) is bonded in a trigonal planar geometry to one H(1), one H(2), and one S(1) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-S(1) bond length is 1.55 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a trigonal bipyramidal geometry to one N(1), one F(10), one F(7), one F(8), and one F(9) atom. The S(1)-F(10) bond length is 1.59 Å. The S(1)-F(7) bond length is 1.59 Å. The S(1)-F(8) bond length is 1.55 Å. The S(1)-F(9) bond length is 1.55 Å. There are four inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(9) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one S(1) atom.