ZnC6S12(N2O)6(AsF6)2 is Indium-derived structured and crystallizes in the trigonal P-3 space group. The structure is zero-dimensional and consists of two AsF6 clusters and one ZnC6S12(N2O)6 cluster. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the ZnC6S12(N2O)6 cluster, Zn(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one N(2), one S(2), and one O(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom.
ZnC6S12(N2O)6(AsF6)2 is Indium-derived structured and crystallizes in the trigonal P-3 space group. The structure is zero-dimensional and consists of two AsF6 clusters and one ZnC6S12(N2O)6 cluster. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. All As(1)-F(1) bond lengths are 1.78 Å. All As(1)-F(2) bond lengths are 1.78 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the ZnC6S12(N2O)6 cluster, Zn(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Zn(1)-O(1) bond lengths are 2.12 Å. C(1) is bonded in a distorted bent 120 degrees geometry to one N(2), one S(2), and one O(1) atom. The C(1)-N(2) bond length is 1.35 Å. The C(1)-S(2) bond length is 1.82 Å. The C(1)-O(1) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.59 Å. The N(1)-S(2) bond length is 1.62 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. The N(2)-S(1) bond length is 1.59 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom.