GeH2(CF2)2(CF3)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen trifluoromethane molecules and eight GeH2(CF2)2 clusters. In each GeH2(CF2)2 cluster, Ge(1) is bonded in a tetrahedral geometry to two equivalent C(1) and two equivalent H(1) atoms. C(1) is bonded in a distorted water-like geometry to one Ge(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one Ge(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.
GeH2(CF2)2(CF3)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen trifluoromethane molecules and eight GeH2(CF2)2 clusters. In each GeH2(CF2)2 cluster, Ge(1) is bonded in a tetrahedral geometry to two equivalent C(1) and two equivalent H(1) atoms. Both Ge(1)-C(1) bond lengths are 2.03 Å. Both Ge(1)-H(1) bond lengths are 1.52 Å. C(1) is bonded in a distorted water-like geometry to one Ge(1), one F(1), and one F(2) atom. The C(1)-F(1) bond length is 1.38 Å. The C(1)-F(2) bond length is 1.38 Å. H(1) is bonded in a single-bond geometry to one Ge(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.