VN is gamma CuTi structured and crystallizes in the tetragonal P4/nmm space group. V(1) is bonded to six equivalent N(1) atoms to form a mixture of corner and edge-sharing VN6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. N(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing NV6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°.
VN is gamma CuTi structured and crystallizes in the tetragonal P4/nmm space group. V(1) is bonded to six equivalent N(1) atoms to form a mixture of corner and edge-sharing VN6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. There are a spread of V(1)-N(1) bond distances ranging from 2.04-2.19 Å. N(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing NV6 octahedra. The corner-sharing octahedral tilt angles range from 0-11°.