V3Mo is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to four equivalent V(2) and four equivalent Mo(1) atoms to form a mixture of distorted corner, face, and edge-sharing VV4Mo4 tetrahedra. In the second V site, V(2) is bonded in a 14-coordinate geometry to eight equivalent V(1) and six equivalent Mo(1) atoms. Mo(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.
V3Mo is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to four equivalent V(2) and four equivalent Mo(1) atoms to form a mixture of distorted corner, face, and edge-sharing VV4Mo4 tetrahedra. All V(1)-V(2) bond lengths are 2.62 Å. All V(1)-Mo(1) bond lengths are 2.62 Å. In the second V site, V(2) is bonded in a 14-coordinate geometry to eight equivalent V(1) and six equivalent Mo(1) atoms. All V(2)-Mo(1) bond lengths are 3.02 Å. Mo(1) is bonded in a distorted body-centered cubic geometry to six equivalent V(2) and eight equivalent V(1) atoms.