ThCl4 crystallizes in the tetragonal I4_1/a space group. Th(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. Cl(1) is bonded in a water-like geometry to two equivalent Th(1) atoms.
ThCl4 crystallizes in the tetragonal I4_1/a space group. Th(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. There are four shorter (2.77 Å) and four longer (2.86 Å) Th(1)-Cl(1) bond lengths. Cl(1) is bonded in a water-like geometry to two equivalent Th(1) atoms.