CrPdP crystallizes in the hexagonal P-62m space group. Cr(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1), one P(2), and four equivalent P(1) atoms. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Cr(1), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Cr(1) and three equivalent Pd(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Cr(1) and six equivalent Pd(1) atoms.
CrPdP crystallizes in the hexagonal P-62m space group. Cr(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1), one P(2), and four equivalent P(1) atoms. There are two shorter (2.81 Å) and four longer (2.87 Å) Cr(1)-Pd(1) bond lengths. The Cr(1)-P(2) bond length is 2.53 Å. All Cr(1)-P(1) bond lengths are 2.67 Å. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Cr(1), two equivalent P(1), and two equivalent P(2) atoms. Both Pd(1)-P(1) bond lengths are 2.37 Å. Both Pd(1)-P(2) bond lengths are 2.50 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Cr(1) and three equivalent Pd(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Cr(1) and six equivalent Pd(1) atoms.