Rh2P is Fluorite structured and crystallizes in the cubic Fm-3m space group. Rh(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing RhP4 tetrahedra. P(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms.
Rh2P is Fluorite structured and crystallizes in the cubic Fm-3m space group. Rh(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing RhP4 tetrahedra. All Rh(1)-P(1) bond lengths are 2.39 Å. P(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms.