FeOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-55°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms.
FeOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-55°. There are a spread of Fe(1)-O(1) bond distances ranging from 1.84-1.92 Å. There are a spread of Fe(1)-F(1) bond distances ranging from 2.06-2.18 Å. O(1) is bonded in a distorted trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms.