Mg2WTeO6 crystallizes in the triclinic P1 space group. There are two inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. In the second Mg site, Mg(2) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. W(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mg(1), one Mg(2), and one W(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mg(2) and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mg(1), one Mg(2), and one W(1) atom. In the fifth O site, O(5) is bonded in a distorted tetrahedral geometry to one Mg(1), one Mg(2), one W(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Mg(1), one Mg(2), and one Te(1) atom.
Mg2WTeO6 crystallizes in the triclinic P1 space group. There are two inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. The Mg(1)-O(1) bond length is 2.14 Å. The Mg(1)-O(2) bond length is 2.02 Å. The Mg(1)-O(4) bond length is 2.10 Å. The Mg(1)-O(5) bond length is 2.08 Å. The Mg(1)-O(6) bond length is 2.02 Å. In the second Mg site, Mg(2) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Mg(2)-O(2) bond length is 2.05 Å. The Mg(2)-O(3) bond length is 2.05 Å. The Mg(2)-O(4) bond length is 2.02 Å. The Mg(2)-O(5) bond length is 2.12 Å. The Mg(2)-O(6) bond length is 2.19 Å. W(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The W(1)-O(1) bond length is 2.04 Å. The W(1)-O(2) bond length is 1.92 Å. The W(1)-O(3) bond length is 1.82 Å. The W(1)-O(4) bond length is 1.95 Å. The W(1)-O(5) bond length is 1.93 Å. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(5), and one O(6) atom. The Te(1)-O(1) bond length is 2.02 Å. The Te(1)-O(5) bond length is 2.56 Å. The Te(1)-O(6) bond length is 1.95 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mg(1), one Mg(2), and one W(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mg(2) and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mg(1), one Mg(2), and one W(1) atom. In the fifth O site, O(5) is bonded in a distorted tetrahedral geometry to one Mg(1), one Mg(2), one W(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Mg(1), one Mg(2), and one Te(1) atom.