KNO2 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 7-coordinate geometry to one N(1) and six equivalent O(1) atoms. N(1) is bonded in a distorted bent 120 degrees geometry to one K(1) and two equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one N(1) atom.
KNO2 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 7-coordinate geometry to one N(1) and six equivalent O(1) atoms. The K(1)-N(1) bond length is 3.06 Å. There are a spread of K(1)-O(1) bond distances ranging from 2.80-2.94 Å. N(1) is bonded in a distorted bent 120 degrees geometry to one K(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.28 Å. O(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one N(1) atom.