CsNO2 crystallizes in the trigonal P3_121 space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent N(1) and eight equivalent O(1) atoms. N(1) is bonded in a bent 120 degrees geometry to two equivalent Cs(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one N(1) atom.
CsNO2 crystallizes in the trigonal P3_121 space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent N(1) and eight equivalent O(1) atoms. Both Cs(1)-N(1) bond lengths are 3.40 Å. There are a spread of Cs(1)-O(1) bond distances ranging from 3.09-3.51 Å. N(1) is bonded in a bent 120 degrees geometry to two equivalent Cs(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.27 Å. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one N(1) atom.