PtV is beta-prime cadmium gold structured and crystallizes in the orthorhombic Pmma space group. V(1) is bonded to four equivalent V(1) and eight equivalent Pt(1) atoms to form distorted VV4Pt8 cuboctahedra that share corners with eight equivalent Pt(1)V8Pt4 cuboctahedra, corners with ten equivalent V(1)V4Pt8 cuboctahedra, edges with six equivalent V(1)V4Pt8 cuboctahedra, edges with twelve equivalent Pt(1)V8Pt4 cuboctahedra, faces with eight equivalent Pt(1)V8Pt4 cuboctahedra, and faces with twelve equivalent V(1)V4Pt8 cuboctahedra. Pt(1) is bonded to eight equivalent V(1) and four equivalent Pt(1) atoms to form distorted PtV8Pt4 cuboctahedra that share corners with eight equivalent V(1)V4Pt8 cuboctahedra, corners with ten equivalent Pt(1)V8Pt4 cuboctahedra, edges with six equivalent Pt(1)V8Pt4 cuboctahedra, edges with twelve equivalent V(1)V4Pt8 cuboctahedra, faces with eight equivalent V(1)V4Pt8 cuboctahedra, and faces with twelve equivalent Pt(1)V8Pt4 cuboctahedra.
PtV is beta-prime cadmium gold structured and crystallizes in the orthorhombic Pmma space group. V(1) is bonded to four equivalent V(1) and eight equivalent Pt(1) atoms to form distorted VV4Pt8 cuboctahedra that share corners with eight equivalent Pt(1)V8Pt4 cuboctahedra, corners with ten equivalent V(1)V4Pt8 cuboctahedra, edges with six equivalent V(1)V4Pt8 cuboctahedra, edges with twelve equivalent Pt(1)V8Pt4 cuboctahedra, faces with eight equivalent Pt(1)V8Pt4 cuboctahedra, and faces with twelve equivalent V(1)V4Pt8 cuboctahedra. There are two shorter (2.68 Å) and two longer (2.73 Å) V(1)-V(1) bond lengths. There are a spread of V(1)-Pt(1) bond distances ranging from 2.67-2.78 Å. Pt(1) is bonded to eight equivalent V(1) and four equivalent Pt(1) atoms to form distorted PtV8Pt4 cuboctahedra that share corners with eight equivalent V(1)V4Pt8 cuboctahedra, corners with ten equivalent Pt(1)V8Pt4 cuboctahedra, edges with six equivalent Pt(1)V8Pt4 cuboctahedra, edges with twelve equivalent V(1)V4Pt8 cuboctahedra, faces with eight equivalent V(1)V4Pt8 cuboctahedra, and faces with twelve equivalent Pt(1)V8Pt4 cuboctahedra. There are two shorter (2.68 Å) and two longer (2.79 Å) Pt(1)-Pt(1) bond lengths.