Li4Cr2Co3Sb3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-70°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with three equivalent Cr(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-70°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and corners with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the second Cr site, Cr(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form distorted CoO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Sb(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted CoO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sb(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-54°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Sb site, Sb(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the third Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cr(1), one Co(2), and one Sb(3) atom. In the second O site, O(2) is bonded to one Li(4), one Cr(1), one Sb(1), and one Sb(2) atom to form distorted OLiCrSb2 trigonal pyramids that share  a cornercorner with one O(7)LiCrCoSb tetrahedra,  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(13)LiCo2Sb trigonal pyramid,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid,  an edgeedge with one O(7)LiCrCoSb tetrahedra, and  an edgeedge with one O(8)LiCrCoSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), one Sb(1), and one Sb(2) atom to form distorted OLiCoSb2 tetrahedra that share corners with two equivalent O(7)LiCrCoSb tetrahedra, corners with two equivalent O(8)LiCrCoSb tetrahedra, corners with two equivalent O(2)LiCrSb2 trigonal pyramids,  an edgeedge with one O(14)LiCrCoSb trigonal pyramid, and  an edgeedge with one O(16)LiCrCoSb trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Co(2), one Co(3), and one Sb(3) atom to form OLiCo2Sb tetrahedra that share  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid, corners with two equivalent O(15)LiCrCo2 trigonal pyramids, and corners with three equivalent O(13)LiCo2Sb trigonal pyramids. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cr(1), one Co(3), and one Sb(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Cr(1), one Co(1), and one Sb(1) atom to form distorted OLiCrCoSb tetrahedra that share  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(13)LiCo2Sb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid, corners with two equivalent O(14)LiCrCoSb trigonal pyramids,  an edgeedge with one O(8)LiCrCoSb tetrahedra, and  an edgeedge with one O(2)LiCrSb2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one Cr(1), one Co(1), and one Sb(2) atom to form distorted OLiCrCoSb tetrahedra that share  a cornercorner with one O(7)LiCrCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(13)LiCo2Sb trigonal pyramid,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid, corners with two equivalent O(16)LiCrCoSb trigonal pyramids,  an edgeedge with one O(7)LiCrCoSb tetrahedra, and  an edgeedge with one O(2)LiCrSb2 trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Cr(2), one Sb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cr(1), one Co(2), and one Co(3) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(1), one Cr(2), one Co(2), and one Sb(3) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one Cr(2), one Co(3), and one Sb(3) atom. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(2), one Co(3), and one Sb(3) atom to form distorted OLiCo2Sb trigonal pyramids that share  a cornercorner with one O(7)LiCrCoSb tetrahedra,  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with three equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid, and  an edgeedge with one O(15)LiCrCo2 trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(2), one Cr(2), one Co(1), and one Sb(1) atom to form distorted OLiCrCoSb trigonal pyramids that share  a cornercorner with one O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with two equivalent O(7)LiCrCoSb tetrahedra,  a cornercorner with one O(15)LiCrCo2 trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid,  an edgeedge with one O(4)LiCoSb2 tetrahedra, and  an edgeedge with one O(16)LiCrCoSb trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(1), one Cr(2), one Co(2), and one Co(3) atom to form distorted OLiCrCo2 trigonal pyramids that share corners with two equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid, and  an edgeedge with one O(13)LiCo2Sb trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(2), one Cr(2), one Co(1), and one Sb(2) atom to form distorted OLiCrCoSb trigonal pyramids that share  a cornercorner with one O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(7)LiCrCoSb tetrahedra, corners with two equivalent O(8)LiCrCoSb tetrahedra,  a cornercorner with one O(15)LiCrCo2 trigonal pyramid,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid,  an edgeedge with one O(4)LiCoSb2 tetrahedra, and  an edgeedge with one O(14)LiCrCoSb trigonal pyramid.
Li4Cr2Co3Sb3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-70°. The Li(1)-O(11) bond length is 2.01 Å. The Li(1)-O(12) bond length is 1.99 Å. The Li(1)-O(15) bond length is 2.00 Å. The Li(1)-O(3) bond length is 2.12 Å. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. The Li(2)-O(14) bond length is 1.96 Å. The Li(2)-O(16) bond length is 1.97 Å. The Li(2)-O(5) bond length is 1.78 Å. The Li(2)-O(9) bond length is 2.23 Å. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra, corners with three equivalent Cr(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-70°. The Li(3)-O(1) bond length is 2.02 Å. The Li(3)-O(10) bond length is 1.89 Å. The Li(3)-O(4) bond length is 1.82 Å. The Li(3)-O(6) bond length is 2.01 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, and corners with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. The Li(4)-O(13) bond length is 1.97 Å. The Li(4)-O(2) bond length is 2.12 Å. The Li(4)-O(7) bond length is 2.02 Å. The Li(4)-O(8) bond length is 2.00 Å. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. The Cr(1)-O(1) bond length is 2.07 Å. The Cr(1)-O(10) bond length is 1.97 Å. The Cr(1)-O(2) bond length is 2.21 Å. The Cr(1)-O(6) bond length is 2.04 Å. The Cr(1)-O(7) bond length is 2.16 Å. The Cr(1)-O(8) bond length is 2.13 Å. In the second Cr site, Cr(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Cr(2)-O(11) bond length is 2.00 Å. The Cr(2)-O(12) bond length is 2.01 Å. The Cr(2)-O(14) bond length is 2.12 Å. The Cr(2)-O(15) bond length is 1.96 Å. The Cr(2)-O(16) bond length is 2.12 Å. The Cr(2)-O(9) bond length is 2.36 Å. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Co(1)-O(14) bond length is 2.11 Å. The Co(1)-O(16) bond length is 2.12 Å. The Co(1)-O(3) bond length is 2.13 Å. The Co(1)-O(4) bond length is 2.09 Å. The Co(1)-O(7) bond length is 2.10 Å. The Co(1)-O(8) bond length is 2.11 Å. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form distorted CoO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Sb(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-53°. The Co(2)-O(1) bond length is 2.23 Å. The Co(2)-O(10) bond length is 1.96 Å. The Co(2)-O(11) bond length is 2.23 Å. The Co(2)-O(13) bond length is 1.94 Å. The Co(2)-O(15) bond length is 1.97 Å. The Co(2)-O(5) bond length is 1.94 Å. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted CoO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sb(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-54°. The Co(3)-O(10) bond length is 2.14 Å. The Co(3)-O(12) bond length is 2.19 Å. The Co(3)-O(13) bond length is 2.07 Å. The Co(3)-O(15) bond length is 2.10 Å. The Co(3)-O(5) bond length is 2.05 Å. The Co(3)-O(6) bond length is 2.14 Å. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. The Sb(1)-O(14) bond length is 1.99 Å. The Sb(1)-O(2) bond length is 2.07 Å. The Sb(1)-O(3) bond length is 2.03 Å. The Sb(1)-O(4) bond length is 2.02 Å. The Sb(1)-O(7) bond length is 1.99 Å. The Sb(1)-O(9) bond length is 2.04 Å. In the second Sb site, Sb(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. The Sb(2)-O(16) bond length is 1.99 Å. The Sb(2)-O(2) bond length is 2.07 Å. The Sb(2)-O(3) bond length is 2.03 Å. The Sb(2)-O(4) bond length is 2.02 Å. The Sb(2)-O(8) bond length is 1.98 Å. The Sb(2)-O(9) bond length is 2.05 Å. In the third Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-52°. The Sb(3)-O(1) bond length is 2.03 Å. The Sb(3)-O(11) bond length is 2.04 Å. The Sb(3)-O(12) bond length is 2.03 Å. The Sb(3)-O(13) bond length is 2.01 Å. The Sb(3)-O(5) bond length is 2.00 Å. The Sb(3)-O(6) bond length is 2.04 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cr(1), one Co(2), and one Sb(3) atom. In the second O site, O(2) is bonded to one Li(4), one Cr(1), one Sb(1), and one Sb(2) atom to form distorted OLiCrSb2 trigonal pyramids that share  a cornercorner with one O(7)LiCrCoSb tetrahedra,  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(13)LiCo2Sb trigonal pyramid,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid,  an edgeedge with one O(7)LiCrCoSb tetrahedra, and  an edgeedge with one O(8)LiCrCoSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), one Sb(1), and one Sb(2) atom to form distorted OLiCoSb2 tetrahedra that share corners with two equivalent O(7)LiCrCoSb tetrahedra, corners with two equivalent O(8)LiCrCoSb tetrahedra, corners with two equivalent O(2)LiCrSb2 trigonal pyramids,  an edgeedge with one O(14)LiCrCoSb trigonal pyramid, and  an edgeedge with one O(16)LiCrCoSb trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Co(2), one Co(3), and one Sb(3) atom to form OLiCo2Sb tetrahedra that share  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid, corners with two equivalent O(15)LiCrCo2 trigonal pyramids, and corners with three equivalent O(13)LiCo2Sb trigonal pyramids. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cr(1), one Co(3), and one Sb(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Cr(1), one Co(1), and one Sb(1) atom to form distorted OLiCrCoSb tetrahedra that share  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(13)LiCo2Sb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid, corners with two equivalent O(14)LiCrCoSb trigonal pyramids,  an edgeedge with one O(8)LiCrCoSb tetrahedra, and  an edgeedge with one O(2)LiCrSb2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one Cr(1), one Co(1), and one Sb(2) atom to form distorted OLiCrCoSb tetrahedra that share  a cornercorner with one O(7)LiCrCoSb tetrahedra, corners with two equivalent O(4)LiCoSb2 tetrahedra,  a cornercorner with one O(13)LiCo2Sb trigonal pyramid,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid, corners with two equivalent O(16)LiCrCoSb trigonal pyramids,  an edgeedge with one O(7)LiCrCoSb tetrahedra, and  an edgeedge with one O(2)LiCrSb2 trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Cr(2), one Sb(1), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cr(1), one Co(2), and one Co(3) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(1), one Cr(2), one Co(2), and one Sb(3) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one Cr(2), one Co(3), and one Sb(3) atom. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(2), one Co(3), and one Sb(3) atom to form distorted OLiCo2Sb trigonal pyramids that share  a cornercorner with one O(7)LiCrCoSb tetrahedra,  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with three equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid, and  an edgeedge with one O(15)LiCrCo2 trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(2), one Cr(2), one Co(1), and one Sb(1) atom to form distorted OLiCrCoSb trigonal pyramids that share  a cornercorner with one O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(8)LiCrCoSb tetrahedra, corners with two equivalent O(7)LiCrCoSb tetrahedra,  a cornercorner with one O(15)LiCrCo2 trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid,  an edgeedge with one O(4)LiCoSb2 tetrahedra, and  an edgeedge with one O(16)LiCrCoSb trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(1), one Cr(2), one Co(2), and one Co(3) atom to form distorted OLiCrCo2 trigonal pyramids that share corners with two equivalent O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(16)LiCrCoSb trigonal pyramid, and  an edgeedge with one O(13)LiCo2Sb trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(2), one Cr(2), one Co(1), and one Sb(2) atom to form distorted OLiCrCoSb trigonal pyramids that share  a cornercorner with one O(5)LiCo2Sb tetrahedra,  a cornercorner with one O(7)LiCrCoSb tetrahedra, corners with two equivalent O(8)LiCrCoSb tetrahedra,  a cornercorner with one O(15)LiCrCo2 trigonal pyramid,  a cornercorner with one O(14)LiCrCoSb trigonal pyramid,  a cornercorner with one O(2)LiCrSb2 trigonal pyramid,  an edgeedge with one O(4)LiCoSb2 tetrahedra, and  an edgeedge with one O(14)LiCrCoSb trigonal pyramid.