Li2VCoO4 is beta Polonium-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the second Li site, Li(2) is bonded to one O(11), one O(12), one O(3), one O(4), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the third Li site, Li(3) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fourth Li site, Li(4) is bonded to one O(1), one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fifth Li site, Li(5) is bonded to one O(1), one O(10), one O(2), one O(3), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the sixth Li site, Li(6) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the third V site, V(3) is bonded to one O(10), one O(12), one O(3), one O(5), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. In the second Co site, Co(2) is bonded to one O(2), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the third Co site, Co(3) is bonded to one O(10), one O(11), one O(4), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Li(5), one V(1), one V(2), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(10)Li3V2Co octahedra,  a cornercorner with one O(12)Li3V2Co octahedra, corners with two equivalent O(11)Li3VCo2 octahedra, corners with two equivalent O(9)Li3VCo2 octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra, edges with two equivalent O(8)Li3V2Co octahedra, edges with two equivalent O(2)Li3VCo2 octahedra, and edges with two equivalent O(7)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second O site, O(2) is bonded to one Li(1), one Li(4), one Li(5), one V(1), one Co(1), and one Co(2) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(11)Li3VCo2 octahedra,  a cornercorner with one O(9)Li3VCo2 octahedra, corners with two equivalent O(10)Li3V2Co octahedra, corners with two equivalent O(12)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(1)Li3V2Co octahedra, edges with two equivalent O(8)Li3V2Co octahedra, and edges with two equivalent O(7)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the third O site, O(3) is bonded to one Li(2), one Li(5), one Li(6), one V(2), one V(3), and one Co(2) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(12)Li3V2Co octahedra,  a cornercorner with one O(8)Li3V2Co octahedra, corners with two equivalent O(11)Li3VCo2 octahedra, corners with two equivalent O(7)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra, edges with two equivalent O(10)Li3V2Co octahedra, edges with two equivalent O(4)Li3VCo2 octahedra, and edges with two equivalent O(9)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fourth O site, O(4) is bonded to one Li(2), one Li(4), one Li(6), one V(2), one Co(2), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(11)Li3VCo2 octahedra,  a cornercorner with one O(7)Li3VCo2 octahedra, corners with two equivalent O(12)Li3V2Co octahedra, corners with two equivalent O(8)Li3V2Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(10)Li3V2Co octahedra, edges with two equivalent O(3)Li3V2Co octahedra, and edges with two equivalent O(9)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one V(1), one V(3), and one Co(3) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(8)Li3V2Co octahedra,  a cornercorner with one O(9)Li3VCo2 octahedra, corners with two equivalent O(10)Li3V2Co octahedra, corners with two equivalent O(7)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(12)Li3V2Co octahedra, edges with two equivalent O(11)Li3VCo2 octahedra, and edges with two equivalent O(6)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(6), one V(3), one Co(1), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(10)Li3V2Co octahedra,  a cornercorner with one O(7)Li3VCo2 octahedra, corners with two equivalent O(8)Li3V2Co octahedra, corners with two equivalent O(9)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(12)Li3V2Co octahedra, edges with two equivalent O(5)Li3V2Co octahedra, and edges with two equivalent O(11)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Li(4), one V(2), one Co(1), and one Co(2) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(4)Li3VCo2 octahedra,  a cornercorner with one O(6)Li3VCo2 octahedra, corners with two equivalent O(3)Li3V2Co octahedra, corners with two equivalent O(5)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(1)Li3V2Co octahedra, edges with two equivalent O(8)Li3V2Co octahedra, and edges with two equivalent O(2)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(5), one V(1), one V(2), and one Co(2) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra, corners with two equivalent O(4)Li3VCo2 octahedra, corners with two equivalent O(6)Li3VCo2 octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(1)Li3V2Co octahedra, edges with two equivalent O(2)Li3VCo2 octahedra, and edges with two equivalent O(7)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the ninth O site, O(9) is bonded to one Li(2), one Li(4), one Li(5), one V(3), one Co(2), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(5)Li3V2Co octahedra,  a cornercorner with one O(2)Li3VCo2 octahedra, corners with two equivalent O(1)Li3V2Co octahedra, corners with two equivalent O(6)Li3VCo2 octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(10)Li3V2Co octahedra, edges with two equivalent O(3)Li3V2Co octahedra, and edges with two equivalent O(4)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the tenth O site, O(10) is bonded to one Li(4), one Li(5), one Li(6), one V(2), one V(3), and one Co(3) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(6)Li3VCo2 octahedra, corners with two equivalent O(5)Li3V2Co octahedra, corners with two equivalent O(2)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(3)Li3V2Co octahedra, edges with two equivalent O(4)Li3VCo2 octahedra, and edges with two equivalent O(9)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(2), one Li(6), one V(1), one Co(1), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(2)Li3VCo2 octahedra,  a cornercorner with one O(4)Li3VCo2 octahedra, corners with two equivalent O(1)Li3V2Co octahedra, corners with two equivalent O(3)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(12)Li3V2Co octahedra, edges with two equivalent O(5)Li3V2Co octahedra, and edges with two equivalent O(6)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one Li(6), one V(1), one V(3), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra, corners with two equivalent O(2)Li3VCo2 octahedra, corners with two equivalent O(4)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(5)Li3V2Co octahedra, edges with two equivalent O(11)Li3VCo2 octahedra, and edges with two equivalent O(6)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°.
Li2VCoO4 is beta Polonium-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. The Li(1)-O(11) bond length is 2.13 Å. The Li(1)-O(2) bond length is 2.08 Å. The Li(1)-O(5) bond length is 2.21 Å. The Li(1)-O(6) bond length is 2.22 Å. The Li(1)-O(7) bond length is 2.21 Å. The Li(1)-O(8) bond length is 2.23 Å. In the second Li site, Li(2) is bonded to one O(11), one O(12), one O(3), one O(4), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. The Li(2)-O(11) bond length is 2.13 Å. The Li(2)-O(12) bond length is 2.08 Å. The Li(2)-O(3) bond length is 2.18 Å. The Li(2)-O(4) bond length is 2.20 Å. The Li(2)-O(5) bond length is 2.22 Å. The Li(2)-O(9) bond length is 2.14 Å. In the third Li site, Li(3) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. The Li(3)-O(1) bond length is 2.23 Å. The Li(3)-O(12) bond length is 2.22 Å. The Li(3)-O(5) bond length is 2.06 Å. The Li(3)-O(6) bond length is 2.15 Å. The Li(3)-O(7) bond length is 2.05 Å. The Li(3)-O(8) bond length is 2.11 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. The Li(4)-O(1) bond length is 2.26 Å. The Li(4)-O(10) bond length is 2.22 Å. The Li(4)-O(2) bond length is 2.18 Å. The Li(4)-O(4) bond length is 2.12 Å. The Li(4)-O(7) bond length is 2.08 Å. The Li(4)-O(9) bond length is 2.21 Å. In the fifth Li site, Li(5) is bonded to one O(1), one O(10), one O(2), one O(3), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. The Li(5)-O(1) bond length is 2.13 Å. The Li(5)-O(10) bond length is 2.09 Å. The Li(5)-O(2) bond length is 2.05 Å. The Li(5)-O(3) bond length is 2.22 Å. The Li(5)-O(8) bond length is 2.23 Å. The Li(5)-O(9) bond length is 2.13 Å. In the sixth Li site, Li(6) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. The Li(6)-O(10) bond length is 2.22 Å. The Li(6)-O(11) bond length is 2.20 Å. The Li(6)-O(12) bond length is 2.17 Å. The Li(6)-O(3) bond length is 2.08 Å. The Li(6)-O(4) bond length is 2.11 Å. The Li(6)-O(6) bond length is 2.15 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. The V(1)-O(1) bond length is 1.98 Å. The V(1)-O(11) bond length is 1.88 Å. The V(1)-O(12) bond length is 2.04 Å. The V(1)-O(2) bond length is 1.98 Å. The V(1)-O(5) bond length is 2.00 Å. The V(1)-O(8) bond length is 2.03 Å. In the second V site, V(2) is bonded to one O(1), one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. The V(2)-O(1) bond length is 2.02 Å. The V(2)-O(10) bond length is 2.00 Å. The V(2)-O(3) bond length is 2.04 Å. The V(2)-O(4) bond length is 1.89 Å. The V(2)-O(7) bond length is 1.96 Å. The V(2)-O(8) bond length is 1.98 Å. In the third V site, V(3) is bonded to one O(10), one O(12), one O(3), one O(5), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The V(3)-O(10) bond length is 2.03 Å. The V(3)-O(12) bond length is 2.01 Å. The V(3)-O(3) bond length is 2.01 Å. The V(3)-O(5) bond length is 2.04 Å. The V(3)-O(6) bond length is 1.91 Å. The V(3)-O(9) bond length is 1.90 Å. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. The Co(1)-O(1) bond length is 2.10 Å. The Co(1)-O(11) bond length is 2.13 Å. The Co(1)-O(12) bond length is 2.09 Å. The Co(1)-O(2) bond length is 2.08 Å. The Co(1)-O(6) bond length is 2.12 Å. The Co(1)-O(7) bond length is 2.12 Å. In the second Co site, Co(2) is bonded to one O(2), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. The Co(2)-O(2) bond length is 2.09 Å. The Co(2)-O(3) bond length is 2.09 Å. The Co(2)-O(4) bond length is 2.14 Å. The Co(2)-O(7) bond length is 2.08 Å. The Co(2)-O(8) bond length is 2.11 Å. The Co(2)-O(9) bond length is 2.13 Å. In the third Co site, Co(3) is bonded to one O(10), one O(11), one O(4), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. The Co(3)-O(10) bond length is 2.08 Å. The Co(3)-O(11) bond length is 2.15 Å. The Co(3)-O(4) bond length is 2.14 Å. The Co(3)-O(5) bond length is 2.09 Å. The Co(3)-O(6) bond length is 2.09 Å. The Co(3)-O(9) bond length is 2.10 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one Li(5), one V(1), one V(2), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(10)Li3V2Co octahedra,  a cornercorner with one O(12)Li3V2Co octahedra, corners with two equivalent O(11)Li3VCo2 octahedra, corners with two equivalent O(9)Li3VCo2 octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra, edges with two equivalent O(8)Li3V2Co octahedra, edges with two equivalent O(2)Li3VCo2 octahedra, and edges with two equivalent O(7)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second O site, O(2) is bonded to one Li(1), one Li(4), one Li(5), one V(1), one Co(1), and one Co(2) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(11)Li3VCo2 octahedra,  a cornercorner with one O(9)Li3VCo2 octahedra, corners with two equivalent O(10)Li3V2Co octahedra, corners with two equivalent O(12)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(1)Li3V2Co octahedra, edges with two equivalent O(8)Li3V2Co octahedra, and edges with two equivalent O(7)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the third O site, O(3) is bonded to one Li(2), one Li(5), one Li(6), one V(2), one V(3), and one Co(2) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(12)Li3V2Co octahedra,  a cornercorner with one O(8)Li3V2Co octahedra, corners with two equivalent O(11)Li3VCo2 octahedra, corners with two equivalent O(7)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra, edges with two equivalent O(10)Li3V2Co octahedra, edges with two equivalent O(4)Li3VCo2 octahedra, and edges with two equivalent O(9)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fourth O site, O(4) is bonded to one Li(2), one Li(4), one Li(6), one V(2), one Co(2), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(11)Li3VCo2 octahedra,  a cornercorner with one O(7)Li3VCo2 octahedra, corners with two equivalent O(12)Li3V2Co octahedra, corners with two equivalent O(8)Li3V2Co octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(10)Li3V2Co octahedra, edges with two equivalent O(3)Li3V2Co octahedra, and edges with two equivalent O(9)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one V(1), one V(3), and one Co(3) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(8)Li3V2Co octahedra,  a cornercorner with one O(9)Li3VCo2 octahedra, corners with two equivalent O(10)Li3V2Co octahedra, corners with two equivalent O(7)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(12)Li3V2Co octahedra, edges with two equivalent O(11)Li3VCo2 octahedra, and edges with two equivalent O(6)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(6), one V(3), one Co(1), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(10)Li3V2Co octahedra,  a cornercorner with one O(7)Li3VCo2 octahedra, corners with two equivalent O(8)Li3V2Co octahedra, corners with two equivalent O(9)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(12)Li3V2Co octahedra, edges with two equivalent O(5)Li3V2Co octahedra, and edges with two equivalent O(11)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Li(4), one V(2), one Co(1), and one Co(2) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(4)Li3VCo2 octahedra,  a cornercorner with one O(6)Li3VCo2 octahedra, corners with two equivalent O(3)Li3V2Co octahedra, corners with two equivalent O(5)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(1)Li3V2Co octahedra, edges with two equivalent O(8)Li3V2Co octahedra, and edges with two equivalent O(2)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(5), one V(1), one V(2), and one Co(2) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(3)Li3V2Co octahedra,  a cornercorner with one O(5)Li3V2Co octahedra, corners with two equivalent O(4)Li3VCo2 octahedra, corners with two equivalent O(6)Li3VCo2 octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(1)Li3V2Co octahedra, edges with two equivalent O(2)Li3VCo2 octahedra, and edges with two equivalent O(7)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the ninth O site, O(9) is bonded to one Li(2), one Li(4), one Li(5), one V(3), one Co(2), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(5)Li3V2Co octahedra,  a cornercorner with one O(2)Li3VCo2 octahedra, corners with two equivalent O(1)Li3V2Co octahedra, corners with two equivalent O(6)Li3VCo2 octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(5)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(10)Li3V2Co octahedra, edges with two equivalent O(3)Li3V2Co octahedra, and edges with two equivalent O(4)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the tenth O site, O(10) is bonded to one Li(4), one Li(5), one Li(6), one V(2), one V(3), and one Co(3) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(6)Li3VCo2 octahedra, corners with two equivalent O(5)Li3V2Co octahedra, corners with two equivalent O(2)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(12)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(11)Li3VCo2 octahedra,  an edgeedge with one O(6)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra, edges with two equivalent O(3)Li3V2Co octahedra, edges with two equivalent O(4)Li3VCo2 octahedra, and edges with two equivalent O(9)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(2), one Li(6), one V(1), one Co(1), and one Co(3) atom to form OLi3VCo2 octahedra that share  a cornercorner with one O(2)Li3VCo2 octahedra,  a cornercorner with one O(4)Li3VCo2 octahedra, corners with two equivalent O(1)Li3V2Co octahedra, corners with two equivalent O(3)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(2)Li3VCo2 octahedra,  an edgeedge with one O(4)Li3VCo2 octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(12)Li3V2Co octahedra, edges with two equivalent O(5)Li3V2Co octahedra, and edges with two equivalent O(6)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one Li(6), one V(1), one V(3), and one Co(1) atom to form OLi3V2Co octahedra that share  a cornercorner with one O(1)Li3V2Co octahedra,  a cornercorner with one O(3)Li3V2Co octahedra, corners with two equivalent O(2)Li3VCo2 octahedra, corners with two equivalent O(4)Li3VCo2 octahedra,  an edgeedge with one O(1)Li3V2Co octahedra,  an edgeedge with one O(10)Li3V2Co octahedra,  an edgeedge with one O(3)Li3V2Co octahedra,  an edgeedge with one O(8)Li3V2Co octahedra,  an edgeedge with one O(7)Li3VCo2 octahedra,  an edgeedge with one O(9)Li3VCo2 octahedra, edges with two equivalent O(5)Li3V2Co octahedra, edges with two equivalent O(11)Li3VCo2 octahedra, and edges with two equivalent O(6)Li3VCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°.