RbCOF3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to three equivalent O(1), one F(3), three equivalent F(1), and three equivalent F(2) atoms. C(1) is bonded in a tetrahedral geometry to one O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Rb(1) and one C(1) atom.
RbCOF3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to three equivalent O(1), one F(3), three equivalent F(1), and three equivalent F(2) atoms. There are a spread of Rb(1)-O(1) bond distances ranging from 2.92-3.01 Å. The Rb(1)-F(3) bond length is 3.02 Å. There are a spread of Rb(1)-F(1) bond distances ranging from 2.99-3.27 Å. There are a spread of Rb(1)-F(2) bond distances ranging from 2.95-3.07 Å. C(1) is bonded in a tetrahedral geometry to one O(1), one F(1), one F(2), and one F(3) atom. The C(1)-O(1) bond length is 1.23 Å. The C(1)-F(1) bond length is 1.44 Å. The C(1)-F(2) bond length is 1.47 Å. The C(1)-F(3) bond length is 1.43 Å. O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Rb(1) and one C(1) atom.