CaCd2(O2Cl3)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules inside a CaCd2(O2Cl3)2 framework. In the CaCd2(O2Cl3)2 framework, Ca(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one Cl(1), one Cl(2), and one Cl(6) atom. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms to form edge-sharing CdCl6 octahedra. In the second Cd site, Cd(2) is bonded to one Cl(2), one Cl(3), one Cl(5), one Cl(6), and two equivalent Cl(4) atoms to form edge-sharing CdCl6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(5) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Ca(1) and one O(6) atom. In the third O site, O(5) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Ca(1) and one O(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a distorted bent 150 degrees geometry to one Ca(1) and one Cd(2) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to one Cd(2) and two equivalent Cd(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1) and two equivalent Cd(2) atoms. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to one Cd(1) and one Cd(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted trigonal planar geometry to one Ca(1), one Cd(1), and one Cd(2) atom.
CaCd2(O2Cl3)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules inside a CaCd2(O2Cl3)2 framework. In the CaCd2(O2Cl3)2 framework, Ca(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one Cl(1), one Cl(2), and one Cl(6) atom. The Ca(1)-O(1) bond length is 2.71 Å. The Ca(1)-O(2) bond length is 2.61 Å. The Ca(1)-O(5) bond length is 2.73 Å. The Ca(1)-O(6) bond length is 2.77 Å. The Ca(1)-Cl(1) bond length is 2.67 Å. The Ca(1)-Cl(2) bond length is 2.57 Å. The Ca(1)-Cl(6) bond length is 2.71 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms to form edge-sharing CdCl6 octahedra. The Cd(1)-Cl(1) bond length is 2.67 Å. The Cd(1)-Cl(4) bond length is 2.65 Å. The Cd(1)-Cl(5) bond length is 2.54 Å. The Cd(1)-Cl(6) bond length is 2.97 Å. There is one shorter (2.73 Å) and one longer (2.76 Å) Cd(1)-Cl(3) bond length. In the second Cd site, Cd(2) is bonded to one Cl(2), one Cl(3), one Cl(5), one Cl(6), and two equivalent Cl(4) atoms to form edge-sharing CdCl6 octahedra. The Cd(2)-Cl(2) bond length is 2.59 Å. The Cd(2)-Cl(3) bond length is 2.74 Å. The Cd(2)-Cl(5) bond length is 2.59 Å. The Cd(2)-Cl(6) bond length is 2.74 Å. There is one shorter (2.62 Å) and one longer (2.85 Å) Cd(2)-Cl(4) bond length. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(5) atom. The O(1)-O(5) bond length is 1.25 Å. In the second O site, O(2) is bonded in an L-shaped geometry to one Ca(1) and one O(6) atom. The O(2)-O(6) bond length is 1.25 Å. In the third O site, O(5) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Ca(1) and one O(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a distorted bent 150 degrees geometry to one Ca(1) and one Cd(2) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to one Cd(2) and two equivalent Cd(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1) and two equivalent Cd(2) atoms. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to one Cd(1) and one Cd(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted trigonal planar geometry to one Ca(1), one Cd(1), and one Cd(2) atom.