ZrO2 is beta Vanadium nitride-like structured and crystallizes in the tetragonal I4_1/amd space group. Zr(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing ZrO6 pentagonal pyramids. O(1) is bonded in a distorted T-shaped geometry to three equivalent Zr(1) atoms.
ZrO2 is beta Vanadium nitride-like structured and crystallizes in the tetragonal I4_1/amd space group. Zr(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing ZrO6 pentagonal pyramids. There are four shorter (2.07 Å) and two longer (2.16 Å) Zr(1)-O(1) bond lengths. O(1) is bonded in a distorted T-shaped geometry to three equivalent Zr(1) atoms.