Zn2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent F(1) atoms to form ZnO4F2 octahedra that share corners with four equivalent Zn(2)O5F octahedra, edges with two equivalent Zn(1)O4F2 octahedra, and edges with two equivalent Zn(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 52-57°. In the second Zn site, Zn(2) is bonded to one O(2), two equivalent O(1), two equivalent O(3), and one F(1) atom to form ZnO5F octahedra that share corners with four equivalent Zn(1)O4F2 octahedra, edges with two equivalent Zn(1)O4F2 octahedra, and edges with two equivalent Zn(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Zn(1) and two equivalent Zn(2) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Zn(2) and two equivalent Zn(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent Zn(2) atoms. F(1) is bonded in a distorted trigonal planar geometry to one Zn(2) and two equivalent Zn(1) atoms.
Zn2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent F(1) atoms to form ZnO4F2 octahedra that share corners with four equivalent Zn(2)O5F octahedra, edges with two equivalent Zn(1)O4F2 octahedra, and edges with two equivalent Zn(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 52-57°. The Zn(1)-O(1) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 1.94 Å. Both Zn(1)-O(2) bond lengths are 2.05 Å. Both Zn(1)-F(1) bond lengths are 2.11 Å. In the second Zn site, Zn(2) is bonded to one O(2), two equivalent O(1), two equivalent O(3), and one F(1) atom to form ZnO5F octahedra that share corners with four equivalent Zn(1)O4F2 octahedra, edges with two equivalent Zn(1)O4F2 octahedra, and edges with two equivalent Zn(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 52-57°. The Zn(2)-O(2) bond length is 2.07 Å. Both Zn(2)-O(1) bond lengths are 2.08 Å. Both Zn(2)-O(3) bond lengths are 1.99 Å. The Zn(2)-F(1) bond length is 2.07 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Zn(1) and two equivalent Zn(2) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Zn(2) and two equivalent Zn(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent Zn(2) atoms. F(1) is bonded in a distorted trigonal planar geometry to one Zn(2) and two equivalent Zn(1) atoms.