SrV3O7 crystallizes in the orthorhombic Pmmn space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sr(1) and one V(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one V(1), and two equivalent V(2) atoms.
SrV3O7 crystallizes in the orthorhombic Pmmn space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. Both Sr(1)-O(1) bond lengths are 2.94 Å. Both Sr(1)-O(2) bond lengths are 2.45 Å. All Sr(1)-O(3) bond lengths are 2.59 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. The V(1)-O(1) bond length is 1.64 Å. All V(1)-O(3) bond lengths are 1.97 Å. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(3) atoms. The V(2)-O(2) bond length is 1.63 Å. All V(2)-O(3) bond lengths are 1.96 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sr(1) and one V(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one V(1), and two equivalent V(2) atoms.