TlEuPS4 crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a EuPS4 framework. In the EuPS4 framework, Eu(1) is bonded in a 8-coordinate geometry to one S(3), three equivalent S(2), and four equivalent S(1) atoms. P(1) is bonded in a tetrahedral geometry to one S(2), one S(3), and two equivalent S(1) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Eu(1) and one P(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to three equivalent Eu(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Eu(1) and one P(1) atom.
TlEuPS4 crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a EuPS4 framework. In the EuPS4 framework, Eu(1) is bonded in a 8-coordinate geometry to one S(3), three equivalent S(2), and four equivalent S(1) atoms. The Eu(1)-S(3) bond length is 2.97 Å. There is one shorter (3.02 Å) and two longer (3.46 Å) Eu(1)-S(2) bond lengths. There are two shorter (3.04 Å) and two longer (3.13 Å) Eu(1)-S(1) bond lengths. P(1) is bonded in a tetrahedral geometry to one S(2), one S(3), and two equivalent S(1) atoms. The P(1)-S(2) bond length is 2.06 Å. The P(1)-S(3) bond length is 2.05 Å. Both P(1)-S(1) bond lengths are 2.07 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Eu(1) and one P(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to three equivalent Eu(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Eu(1) and one P(1) atom.