NiC2H4(NS2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NiC2H4(NS2)2 clusters. Ni(1) is bonded in a square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(4) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(2), and one S(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent S sites. In the first S site, S(2) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the second S site, S(3) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the third S site, S(4) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the fourth S site, S(1) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom.
NiC2H4(NS2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NiC2H4(NS2)2 clusters. Ni(1) is bonded in a square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. The Ni(1)-S(1) bond length is 2.21 Å. The Ni(1)-S(2) bond length is 2.21 Å. The Ni(1)-S(3) bond length is 2.20 Å. The Ni(1)-S(4) bond length is 2.21 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(4) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-S(1) bond length is 1.71 Å. The C(1)-S(4) bond length is 1.72 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(2), and one S(3) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-S(2) bond length is 1.72 Å. The C(2)-S(3) bond length is 1.72 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent S sites. In the first S site, S(2) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the second S site, S(3) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the third S site, S(4) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the fourth S site, S(1) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom.