Li6V3Mn(PO4)6 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(16), one O(2), one O(6), and one O(7) atom. In the second Li site, Li(2) is bonded to one O(16), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(18), one O(20), one O(21), and one O(8) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(17), one O(4), one O(5), and one O(7) atom. In the fifth Li site, Li(5) is bonded to one O(11), one O(14), one O(19), one O(21), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(1)O6 octahedra, and  a faceface with one V(2)O6 octahedra. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(11), one O(18), one O(19), one O(23), one O(24), and one O(9) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(14), one O(17), one O(4), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. In the second V site, V(2) is bonded to one O(11), one O(15), one O(19), one O(21), one O(24), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. In the third V site, V(3) is bonded to one O(13), one O(18), one O(20), one O(22), one O(23), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. Mn(1) is bonded to one O(12), one O(16), one O(2), one O(3), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(14), one O(22), one O(24), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-50°. In the second P site, P(2) is bonded to one O(16), one O(23), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-47°. In the third P site, P(3) is bonded to one O(13), one O(15), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-49°. In the fourth P site, P(4) is bonded to one O(10), one O(12), one O(18), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-48°. In the fifth P site, P(5) is bonded to one O(17), one O(2), one O(21), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-48°. In the sixth P site, P(6) is bonded to one O(1), one O(11), one O(20), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-49°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(6) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(5) atom. In the third O site, O(3) is bonded in a linear geometry to one Mn(1) and one P(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(4), one Li(5), one V(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(5), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(4), one Mn(1), and one P(3) atom to form distorted corner-sharing OLi3MnP trigonal bipyramids. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(6), one V(3), and one P(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one V(1) and one P(4) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(5), one Li(6), one V(2), and one P(6) atom to form distorted corner-sharing OLi3VP trigonal bipyramids. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(3), one V(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(4), one Li(5), one V(1), and one P(1) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(11)Li3VP trigonal bipyramid and corners with two equivalent O(7)Li3MnP trigonal bipyramids. In the fifteenth O site, O(15) is bonded in a linear geometry to one V(2) and one P(3) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Li(4), one V(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(3), one Li(6), one V(3), and one P(4) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(7)Li3MnP trigonal bipyramid and corners with two equivalent O(11)Li3VP trigonal bipyramids. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one V(2), and one P(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(3), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), one V(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a linear geometry to one V(3) and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(6), one V(3), and one P(2) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one V(2), and one P(1) atom.
Li6V3Mn(PO4)6 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(16), one O(2), one O(6), and one O(7) atom. The Li(1)-O(1) bond length is 2.32 Å. The Li(1)-O(14) bond length is 2.25 Å. The Li(1)-O(16) bond length is 2.55 Å. The Li(1)-O(2) bond length is 2.18 Å. The Li(1)-O(6) bond length is 2.01 Å. The Li(1)-O(7) bond length is 2.45 Å. In the second Li site, Li(2) is bonded to one O(16), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The Li(2)-O(16) bond length is 2.26 Å. The Li(2)-O(18) bond length is 2.31 Å. The Li(2)-O(20) bond length is 2.25 Å. The Li(2)-O(5) bond length is 2.15 Å. The Li(2)-O(7) bond length is 2.29 Å. The Li(2)-O(9) bond length is 2.25 Å. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(18), one O(20), one O(21), and one O(8) atom. The Li(3)-O(11) bond length is 2.45 Å. The Li(3)-O(13) bond length is 2.30 Å. The Li(3)-O(18) bond length is 2.28 Å. The Li(3)-O(20) bond length is 2.01 Å. The Li(3)-O(21) bond length is 2.62 Å. The Li(3)-O(8) bond length is 2.28 Å. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(17), one O(4), one O(5), and one O(7) atom. The Li(4)-O(12) bond length is 2.29 Å. The Li(4)-O(14) bond length is 2.46 Å. The Li(4)-O(17) bond length is 2.27 Å. The Li(4)-O(4) bond length is 2.62 Å. The Li(4)-O(5) bond length is 1.97 Å. The Li(4)-O(7) bond length is 2.28 Å. In the fifth Li site, Li(5) is bonded to one O(11), one O(14), one O(19), one O(21), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one V(1)O6 octahedra, and  a faceface with one V(2)O6 octahedra. The Li(5)-O(11) bond length is 2.28 Å. The Li(5)-O(14) bond length is 2.27 Å. The Li(5)-O(19) bond length is 2.27 Å. The Li(5)-O(21) bond length is 2.23 Å. The Li(5)-O(4) bond length is 2.23 Å. The Li(5)-O(6) bond length is 2.27 Å. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(11), one O(18), one O(19), one O(23), one O(24), and one O(9) atom. The Li(6)-O(11) bond length is 2.26 Å. The Li(6)-O(18) bond length is 2.45 Å. The Li(6)-O(19) bond length is 2.01 Å. The Li(6)-O(23) bond length is 2.23 Å. The Li(6)-O(24) bond length is 2.29 Å. The Li(6)-O(9) bond length is 2.61 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(14), one O(17), one O(4), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. The V(1)-O(1) bond length is 2.01 Å. The V(1)-O(10) bond length is 1.95 Å. The V(1)-O(14) bond length is 2.06 Å. The V(1)-O(17) bond length is 2.05 Å. The V(1)-O(4) bond length is 2.05 Å. The V(1)-O(6) bond length is 2.06 Å. In the second V site, V(2) is bonded to one O(11), one O(15), one O(19), one O(21), one O(24), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(5)O6 octahedra. The V(2)-O(11) bond length is 2.08 Å. The V(2)-O(15) bond length is 1.97 Å. The V(2)-O(19) bond length is 2.05 Å. The V(2)-O(21) bond length is 2.02 Å. The V(2)-O(24) bond length is 1.98 Å. The V(2)-O(8) bond length is 2.05 Å. In the third V site, V(3) is bonded to one O(13), one O(18), one O(20), one O(22), one O(23), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. The V(3)-O(13) bond length is 2.01 Å. The V(3)-O(18) bond length is 2.06 Å. The V(3)-O(20) bond length is 2.09 Å. The V(3)-O(22) bond length is 1.93 Å. The V(3)-O(23) bond length is 2.10 Å. The V(3)-O(9) bond length is 2.02 Å. Mn(1) is bonded to one O(12), one O(16), one O(2), one O(3), one O(5), and one O(7) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Li(2)O6 octahedra. The Mn(1)-O(12) bond length is 1.98 Å. The Mn(1)-O(16) bond length is 2.04 Å. The Mn(1)-O(2) bond length is 2.12 Å. The Mn(1)-O(3) bond length is 1.90 Å. The Mn(1)-O(5) bond length is 2.19 Å. The Mn(1)-O(7) bond length is 2.01 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(14), one O(22), one O(24), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-50°. The P(1)-O(14) bond length is 1.58 Å. The P(1)-O(22) bond length is 1.52 Å. The P(1)-O(24) bond length is 1.55 Å. The P(1)-O(5) bond length is 1.54 Å. In the second P site, P(2) is bonded to one O(16), one O(23), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-47°. The P(2)-O(16) bond length is 1.57 Å. The P(2)-O(23) bond length is 1.54 Å. The P(2)-O(4) bond length is 1.56 Å. The P(2)-O(8) bond length is 1.55 Å. In the third P site, P(3) is bonded to one O(13), one O(15), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-49°. The P(3)-O(13) bond length is 1.53 Å. The P(3)-O(15) bond length is 1.52 Å. The P(3)-O(6) bond length is 1.55 Å. The P(3)-O(7) bond length is 1.59 Å. In the fourth P site, P(4) is bonded to one O(10), one O(12), one O(18), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-48°. The P(4)-O(10) bond length is 1.52 Å. The P(4)-O(12) bond length is 1.55 Å. The P(4)-O(18) bond length is 1.57 Å. The P(4)-O(19) bond length is 1.55 Å. In the fifth P site, P(5) is bonded to one O(17), one O(2), one O(21), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-48°. The P(5)-O(17) bond length is 1.55 Å. The P(5)-O(2) bond length is 1.54 Å. The P(5)-O(21) bond length is 1.56 Å. The P(5)-O(9) bond length is 1.56 Å. In the sixth P site, P(6) is bonded to one O(1), one O(11), one O(20), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-49°. The P(6)-O(1) bond length is 1.54 Å. The P(6)-O(11) bond length is 1.57 Å. The P(6)-O(20) bond length is 1.55 Å. The P(6)-O(3) bond length is 1.53 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(6) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(5) atom. In the third O site, O(3) is bonded in a linear geometry to one Mn(1) and one P(6) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(4), one Li(5), one V(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(5), one V(1), and one P(3) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(4), one Mn(1), and one P(3) atom to form distorted corner-sharing OLi3MnP trigonal bipyramids. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(3), one V(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(2), one Li(6), one V(3), and one P(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one V(1) and one P(4) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(5), one Li(6), one V(2), and one P(6) atom to form distorted corner-sharing OLi3VP trigonal bipyramids. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(4), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(3), one V(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(4), one Li(5), one V(1), and one P(1) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(11)Li3VP trigonal bipyramid and corners with two equivalent O(7)Li3MnP trigonal bipyramids. In the fifteenth O site, O(15) is bonded in a linear geometry to one V(2) and one P(3) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Mn(1), and one P(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Li(4), one V(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(3), one Li(6), one V(3), and one P(4) atom to form distorted OLi3VP trigonal bipyramids that share  a cornercorner with one O(7)Li3MnP trigonal bipyramid and corners with two equivalent O(11)Li3VP trigonal bipyramids. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one V(2), and one P(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(3), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), one V(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a linear geometry to one V(3) and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(6), one V(3), and one P(2) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one V(2), and one P(1) atom.