Os2CdP crystallizes in the cubic F-43m space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 14-coordinate geometry to four equivalent Os(2), six equivalent Cd(1), and four equivalent P(1) atoms. In the second Os site, Os(2) is bonded to four equivalent Os(1) and four equivalent Cd(1) atoms to form distorted edge-sharing OsCd4Os4 tetrahedra. Cd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Os(2), six equivalent Os(1), and four equivalent P(1) atoms. P(1) is bonded in a distorted body-centered cubic geometry to four equivalent Os(1) and four equivalent Cd(1) atoms.
Os2CdP crystallizes in the cubic F-43m space group. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 14-coordinate geometry to four equivalent Os(2), six equivalent Cd(1), and four equivalent P(1) atoms. All Os(1)-Os(2) bond lengths are 2.73 Å. All Os(1)-Cd(1) bond lengths are 3.16 Å. All Os(1)-P(1) bond lengths are 2.73 Å. In the second Os site, Os(2) is bonded to four equivalent Os(1) and four equivalent Cd(1) atoms to form distorted edge-sharing OsCd4Os4 tetrahedra. All Os(2)-Cd(1) bond lengths are 2.73 Å. Cd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Os(2), six equivalent Os(1), and four equivalent P(1) atoms. All Cd(1)-P(1) bond lengths are 2.73 Å. P(1) is bonded in a distorted body-centered cubic geometry to four equivalent Os(1) and four equivalent Cd(1) atoms.