LiCu2BiO4 crystallizes in the tetragonal P4/nmm space group. Li(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. O(1) is bonded to one Li(1), two equivalent Cu(1), and one Bi(1) atom to form a mixture of corner and edge-sharing OLiCu2Bi tetrahedra.
LiCu2BiO4 crystallizes in the tetragonal P4/nmm space group. Li(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.01 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Cu(1)-O(1) bond lengths are 1.96 Å. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Bi(1)-O(1) bond lengths are 2.21 Å. O(1) is bonded to one Li(1), two equivalent Cu(1), and one Bi(1) atom to form a mixture of corner and edge-sharing OLiCu2Bi tetrahedra.