SAs is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SAs clusters. There are four inequivalent As sites. In the first As site, As(1) is bonded in a trigonal non-coplanar geometry to one S(1), one S(3), and one S(4) atom. In the second As site, As(2) is bonded in a distorted water-like geometry to one S(1) and one S(2) atom. In the third As site, As(3) is bonded in a distorted water-like geometry to one S(2) and one S(3) atom. In the fourth As site, As(4) is bonded in a distorted single-bond geometry to one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one As(2) and one As(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one As(1) and one As(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one As(1) and one As(4) atom.
SAs is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SAs clusters. There are four inequivalent As sites. In the first As site, As(1) is bonded in a trigonal non-coplanar geometry to one S(1), one S(3), and one S(4) atom. The As(1)-S(1) bond length is 2.25 Å. The As(1)-S(3) bond length is 2.25 Å. The As(1)-S(4) bond length is 2.28 Å. In the second As site, As(2) is bonded in a distorted water-like geometry to one S(1) and one S(2) atom. The As(2)-S(1) bond length is 2.25 Å. The As(2)-S(2) bond length is 2.27 Å. In the third As site, As(3) is bonded in a distorted water-like geometry to one S(2) and one S(3) atom. The As(3)-S(2) bond length is 2.28 Å. The As(3)-S(3) bond length is 2.25 Å. In the fourth As site, As(4) is bonded in a distorted single-bond geometry to one S(4) atom. The As(4)-S(4) bond length is 2.20 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one As(2) and one As(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one As(1) and one As(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one As(1) and one As(4) atom.