K2NaAlP2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. Na(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. Al(1) is bonded to four equivalent P(1) atoms to form distorted edge-sharing AlP4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1), two equivalent Na(1), and two equivalent Al(1) atoms.
K2NaAlP2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. There are a spread of K(1)-P(1) bond distances ranging from 3.26-3.41 Å. Na(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. All Na(1)-P(1) bond lengths are 2.86 Å. Al(1) is bonded to four equivalent P(1) atoms to form distorted edge-sharing AlP4 tetrahedra. All Al(1)-P(1) bond lengths are 2.43 Å. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1), two equivalent Na(1), and two equivalent Al(1) atoms.