C5N2H12S2O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1,1-dimethyl-3,3-bis(methylsulfonyl)urea molecules. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(2) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(5) atom. In the fourth C site, C(4) is bonded to one N(2), one H(7), one H(8), and one H(9) atom to form corner-sharing CH3N tetrahedra. In the fifth C site, C(5) is bonded to one N(2), one H(10), one H(11), and one H(12) atom to form corner-sharing CH3N tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(3), one S(1), and one S(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one C(1), one N(1), one O(1), and one O(2) atom to form distorted corner-sharing SCNO2 tetrahedra. In the second S site, S(2) is bonded to one C(2), one N(1), one O(3), and one O(4) atom to form distorted corner-sharing SCNO2 tetrahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(3) atom.
C5N2H12S2O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1,1-dimethyl-3,3-bis(methylsulfonyl)urea molecules. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.09 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.78 Å. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(2) atom. The C(2)-H(4) bond length is 1.09 Å. The C(2)-H(5) bond length is 1.09 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-S(2) bond length is 1.77 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(5) atom. The C(3)-N(1) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-O(5) bond length is 1.24 Å. In the fourth C site, C(4) is bonded to one N(2), one H(7), one H(8), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(7) bond length is 1.10 Å. The C(4)-H(8) bond length is 1.10 Å. The C(4)-H(9) bond length is 1.09 Å. In the fifth C site, C(5) is bonded to one N(2), one H(10), one H(11), and one H(12) atom to form corner-sharing CH3N tetrahedra. The C(5)-N(2) bond length is 1.46 Å. The C(5)-H(10) bond length is 1.10 Å. The C(5)-H(11) bond length is 1.10 Å. The C(5)-H(12) bond length is 1.09 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(3), one S(1), and one S(2) atom. The N(1)-S(1) bond length is 1.71 Å. The N(1)-S(2) bond length is 1.73 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one C(1), one N(1), one O(1), and one O(2) atom to form distorted corner-sharing SCNO2 tetrahedra. The S(1)-O(1) bond length is 1.45 Å. The S(1)-O(2) bond length is 1.44 Å. In the second S site, S(2) is bonded to one C(2), one N(1), one O(3), and one O(4) atom to form distorted corner-sharing SCNO2 tetrahedra. The S(2)-O(3) bond length is 1.45 Å. The S(2)-O(4) bond length is 1.44 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(3) atom.