LiLa8V8O32 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one La(5), one O(1), one O(11), one O(16), one O(18), and one O(21) atom. There are eight inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(16), one O(27), one O(30), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(14), one O(19), one O(20), one O(29), one O(4), one O(5), one O(6), one O(8), and one O(9) atom. In the third La site, La(3) is bonded in a 10-coordinate geometry to one O(11), one O(12), one O(13), one O(15), one O(17), one O(23), one O(24), one O(3), one O(31), and one O(32) atom. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(15), one O(17), one O(2), one O(22), one O(23), and one O(26) atom. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one Li(1), one O(10), one O(11), one O(18), one O(21), one O(22), one O(23), one O(31), and one O(7) atom. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(1), one O(16), one O(18), one O(2), one O(20), one O(21), one O(22), one O(30), and one O(9) atom. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(13), one O(14), one O(19), one O(24), one O(25), one O(27), one O(28), one O(29), and one O(4) atom. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(17), one O(24), one O(25), one O(26), one O(28), one O(29), one O(3), one O(32), and one O(6) atom. There are eight inequivalent V sites. In the first V site, V(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(11), one O(15), and one O(7) atom. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(5), and one O(9) atom. In the third V site, V(3) is bonded in a tetrahedral geometry to one O(13), one O(3), one O(4), and one O(8) atom. In the fourth V site, V(4) is bonded in a tetrahedral geometry to one O(12), one O(17), one O(19), and one O(6) atom. In the fifth V site, V(5) is bonded in a tetrahedral geometry to one O(14), one O(16), one O(21), and one O(27) atom. In the sixth V site, V(6) is bonded in a tetrahedral geometry to one O(20), one O(25), one O(29), and one O(30) atom. In the seventh V site, V(7) is bonded in a tetrahedral geometry to one O(23), one O(24), one O(28), and one O(31) atom. In the eighth V site, V(8) is bonded in a tetrahedral geometry to one O(18), one O(22), one O(26), and one O(32) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one La(1), one La(6), and one V(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(4), one La(6), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(3), one La(8), and one V(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1), one La(2), one La(7), and one V(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one La(2), and one V(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(2), one La(8), and one V(4) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(1), one La(5), and one V(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(1), one La(2), and one V(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(1), one La(2), one La(6), and one V(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(4), one La(5), and one V(2) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Li(1), one La(3), one La(4), one La(5), and one V(1) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(3), one La(4), and one V(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(3), one La(7), and one V(3) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one La(2), one La(7), and one V(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one La(3), one La(4), and one V(1) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Li(1), one La(1), one La(6), and one V(5) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one La(3), one La(4), one La(8), and one V(4) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Li(1), one La(5), one La(6), and one V(8) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one La(2), one La(7), and one V(4) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one La(2), one La(6), and one V(6) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(1), one La(5), one La(6), and one V(5) atom. In the twenty-second O site, O(22) is bonded in a 1-coordinate geometry to one La(4), one La(5), one La(6), and one V(8) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one La(3), one La(4), one La(5), and one V(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one La(3), one La(7), one La(8), and one V(7) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one La(7), one La(8), and one V(6) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one La(4), one La(8), and one V(8) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one La(1), one La(7), and one V(5) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one La(7), one La(8), and one V(7) atom. In the twenty-ninth O site, O(29) is bonded in a distorted single-bond geometry to one La(2), one La(7), one La(8), and one V(6) atom. In the thirtieth O site, O(30) is bonded in a distorted single-bond geometry to one La(1), one La(6), and one V(6) atom. In the thirty-first O site, O(31) is bonded in a 3-coordinate geometry to one La(3), one La(5), and one V(7) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one La(3), one La(8), and one V(8) atom.
LiLa8V8O32 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one La(5), one O(1), one O(11), one O(16), one O(18), and one O(21) atom. The Li(1)-La(5) bond length is 2.56 Å. The Li(1)-O(1) bond length is 1.77 Å. The Li(1)-O(11) bond length is 2.28 Å. The Li(1)-O(16) bond length is 2.02 Å. The Li(1)-O(18) bond length is 2.06 Å. The Li(1)-O(21) bond length is 2.34 Å. There are eight inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(16), one O(27), one O(30), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. The La(1)-O(1) bond length is 2.46 Å. The La(1)-O(16) bond length is 2.82 Å. The La(1)-O(27) bond length is 2.60 Å. The La(1)-O(30) bond length is 2.51 Å. The La(1)-O(4) bond length is 3.03 Å. The La(1)-O(5) bond length is 2.55 Å. The La(1)-O(7) bond length is 2.52 Å. The La(1)-O(8) bond length is 2.65 Å. The La(1)-O(9) bond length is 2.55 Å. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(14), one O(19), one O(20), one O(29), one O(4), one O(5), one O(6), one O(8), and one O(9) atom. The La(2)-O(14) bond length is 2.54 Å. The La(2)-O(19) bond length is 2.72 Å. The La(2)-O(20) bond length is 2.51 Å. The La(2)-O(29) bond length is 2.68 Å. The La(2)-O(4) bond length is 2.57 Å. The La(2)-O(5) bond length is 2.56 Å. The La(2)-O(6) bond length is 2.53 Å. The La(2)-O(8) bond length is 2.53 Å. The La(2)-O(9) bond length is 3.01 Å. In the third La site, La(3) is bonded in a 10-coordinate geometry to one O(11), one O(12), one O(13), one O(15), one O(17), one O(23), one O(24), one O(3), one O(31), and one O(32) atom. The La(3)-O(11) bond length is 3.04 Å. The La(3)-O(12) bond length is 2.54 Å. The La(3)-O(13) bond length is 2.58 Å. The La(3)-O(15) bond length is 2.50 Å. The La(3)-O(17) bond length is 2.61 Å. The La(3)-O(23) bond length is 3.27 Å. The La(3)-O(24) bond length is 2.70 Å. The La(3)-O(3) bond length is 2.72 Å. The La(3)-O(31) bond length is 2.61 Å. The La(3)-O(32) bond length is 2.44 Å. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(12), one O(15), one O(17), one O(2), one O(22), one O(23), and one O(26) atom. The La(4)-O(10) bond length is 2.68 Å. The La(4)-O(11) bond length is 2.74 Å. The La(4)-O(12) bond length is 2.57 Å. The La(4)-O(15) bond length is 2.45 Å. The La(4)-O(17) bond length is 2.98 Å. The La(4)-O(2) bond length is 2.55 Å. The La(4)-O(22) bond length is 2.67 Å. The La(4)-O(23) bond length is 2.59 Å. The La(4)-O(26) bond length is 2.57 Å. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one Li(1), one O(10), one O(11), one O(18), one O(21), one O(22), one O(23), one O(31), and one O(7) atom. The La(5)-O(10) bond length is 2.39 Å. The La(5)-O(11) bond length is 2.76 Å. The La(5)-O(18) bond length is 2.71 Å. The La(5)-O(21) bond length is 2.69 Å. The La(5)-O(22) bond length is 2.48 Å. The La(5)-O(23) bond length is 2.47 Å. The La(5)-O(31) bond length is 2.45 Å. The La(5)-O(7) bond length is 2.42 Å. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(1), one O(16), one O(18), one O(2), one O(20), one O(21), one O(22), one O(30), and one O(9) atom. The La(6)-O(1) bond length is 2.55 Å. The La(6)-O(16) bond length is 2.60 Å. The La(6)-O(18) bond length is 2.74 Å. The La(6)-O(2) bond length is 2.43 Å. The La(6)-O(20) bond length is 2.49 Å. The La(6)-O(21) bond length is 2.53 Å. The La(6)-O(22) bond length is 2.90 Å. The La(6)-O(30) bond length is 2.64 Å. The La(6)-O(9) bond length is 2.81 Å. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(13), one O(14), one O(19), one O(24), one O(25), one O(27), one O(28), one O(29), and one O(4) atom. The La(7)-O(13) bond length is 2.49 Å. The La(7)-O(14) bond length is 2.70 Å. The La(7)-O(19) bond length is 2.54 Å. The La(7)-O(24) bond length is 2.94 Å. The La(7)-O(25) bond length is 2.54 Å. The La(7)-O(27) bond length is 2.49 Å. The La(7)-O(28) bond length is 2.51 Å. The La(7)-O(29) bond length is 2.58 Å. The La(7)-O(4) bond length is 2.72 Å. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(17), one O(24), one O(25), one O(26), one O(28), one O(29), one O(3), one O(32), and one O(6) atom. The La(8)-O(17) bond length is 2.71 Å. The La(8)-O(24) bond length is 2.57 Å. The La(8)-O(25) bond length is 2.60 Å. The La(8)-O(26) bond length is 2.59 Å. The La(8)-O(28) bond length is 2.53 Å. The La(8)-O(29) bond length is 2.98 Å. The La(8)-O(3) bond length is 2.46 Å. The La(8)-O(32) bond length is 2.68 Å. The La(8)-O(6) bond length is 2.54 Å. There are eight inequivalent V sites. In the first V site, V(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(11), one O(15), and one O(7) atom. The V(1)-O(1) bond length is 1.86 Å. The V(1)-O(11) bond length is 1.84 Å. The V(1)-O(15) bond length is 1.82 Å. The V(1)-O(7) bond length is 1.79 Å. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(5), and one O(9) atom. The V(2)-O(10) bond length is 1.75 Å. The V(2)-O(2) bond length is 1.75 Å. The V(2)-O(5) bond length is 1.75 Å. The V(2)-O(9) bond length is 1.73 Å. In the third V site, V(3) is bonded in a tetrahedral geometry to one O(13), one O(3), one O(4), and one O(8) atom. The V(3)-O(13) bond length is 1.74 Å. The V(3)-O(3) bond length is 1.73 Å. The V(3)-O(4) bond length is 1.75 Å. The V(3)-O(8) bond length is 1.75 Å. In the fourth V site, V(4) is bonded in a tetrahedral geometry to one O(12), one O(17), one O(19), and one O(6) atom. The V(4)-O(12) bond length is 1.76 Å. The V(4)-O(17) bond length is 1.74 Å. The V(4)-O(19) bond length is 1.73 Å. The V(4)-O(6) bond length is 1.75 Å. In the fifth V site, V(5) is bonded in a tetrahedral geometry to one O(14), one O(16), one O(21), and one O(27) atom. The V(5)-O(14) bond length is 1.72 Å. The V(5)-O(16) bond length is 1.73 Å. The V(5)-O(21) bond length is 1.77 Å. The V(5)-O(27) bond length is 1.74 Å. In the sixth V site, V(6) is bonded in a tetrahedral geometry to one O(20), one O(25), one O(29), and one O(30) atom. The V(6)-O(20) bond length is 1.76 Å. The V(6)-O(25) bond length is 1.75 Å. The V(6)-O(29) bond length is 1.75 Å. The V(6)-O(30) bond length is 1.72 Å. In the seventh V site, V(7) is bonded in a tetrahedral geometry to one O(23), one O(24), one O(28), and one O(31) atom. The V(7)-O(23) bond length is 1.75 Å. The V(7)-O(24) bond length is 1.73 Å. The V(7)-O(28) bond length is 1.74 Å. The V(7)-O(31) bond length is 1.74 Å. In the eighth V site, V(8) is bonded in a tetrahedral geometry to one O(18), one O(22), one O(26), and one O(32) atom. The V(8)-O(18) bond length is 1.77 Å. The V(8)-O(22) bond length is 1.76 Å. The V(8)-O(26) bond length is 1.74 Å. The V(8)-O(32) bond length is 1.73 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one La(1), one La(6), and one V(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(4), one La(6), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(3), one La(8), and one V(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1), one La(2), one La(7), and one V(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one La(2), and one V(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(2), one La(8), and one V(4) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(1), one La(5), and one V(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(1), one La(2), and one V(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(1), one La(2), one La(6), and one V(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(4), one La(5), and one V(2) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Li(1), one La(3), one La(4), one La(5), and one V(1) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(3), one La(4), and one V(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(3), one La(7), and one V(3) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one La(2), one La(7), and one V(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one La(3), one La(4), and one V(1) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Li(1), one La(1), one La(6), and one V(5) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one La(3), one La(4), one La(8), and one V(4) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Li(1), one La(5), one La(6), and one V(8) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one La(2), one La(7), and one V(4) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one La(2), one La(6), and one V(6) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(1), one La(5), one La(6), and one V(5) atom. In the twenty-second O site, O(22) is bonded in a 1-coordinate geometry to one La(4), one La(5), one La(6), and one V(8) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one La(3), one La(4), one La(5), and one V(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one La(3), one La(7), one La(8), and one V(7) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one La(7), one La(8), and one V(6) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one La(4), one La(8), and one V(8) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one La(1), one La(7), and one V(5) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one La(7), one La(8), and one V(7) atom. In the twenty-ninth O site, O(29) is bonded in a distorted single-bond geometry to one La(2), one La(7), one La(8), and one V(6) atom. In the thirtieth O site, O(30) is bonded in a distorted single-bond geometry to one La(1), one La(6), and one V(6) atom. In the thirty-first O site, O(31) is bonded in a 3-coordinate geometry to one La(3), one La(5), and one V(7) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one La(3), one La(8), and one V(8) atom.