TiF3 is alpha Rhenium trioxide structured and crystallizes in the trigonal R-3c space group. Ti(1) is bonded to six equivalent F(1) atoms to form corner-sharing TiF6 octahedra. The corner-sharing octahedral tilt angles are 1°. F(1) is bonded in a linear geometry to two equivalent Ti(1) atoms.
TiF3 is alpha Rhenium trioxide structured and crystallizes in the trigonal R-3c space group. Ti(1) is bonded to six equivalent F(1) atoms to form corner-sharing TiF6 octahedra. The corner-sharing octahedral tilt angles are 1°. All Ti(1)-F(1) bond lengths are 1.96 Å. F(1) is bonded in a linear geometry to two equivalent Ti(1) atoms.