IrN5Cl(NO3)2 is Fluorite structured and crystallizes in the tetragonal I4mm space group. The structure is zero-dimensional and consists of four nitric acid molecules and two IrN5Cl clusters. In each IrN5Cl cluster, Ir(1) is bonded in a 5-coordinate geometry to one N(3), four equivalent N(2), and one Cl(1) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. Cl(1) is bonded in a single-bond geometry to one Ir(1) atom.
IrN5Cl(NO3)2 is Fluorite structured and crystallizes in the tetragonal I4mm space group. The structure is zero-dimensional and consists of four nitric acid molecules and two IrN5Cl clusters. In each IrN5Cl cluster, Ir(1) is bonded in a 5-coordinate geometry to one N(3), four equivalent N(2), and one Cl(1) atom. The Ir(1)-N(3) bond length is 1.74 Å. All Ir(1)-N(2) bond lengths are 1.95 Å. The Ir(1)-Cl(1) bond length is 2.65 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. Cl(1) is bonded in a single-bond geometry to one Ir(1) atom.