NOClF4 is Tetraauricupride structured and crystallizes in the tetragonal I4cm space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four ClF4 clusters. In each ClF4 cluster, Cl(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Cl(1) atom.
NOClF4 is Tetraauricupride structured and crystallizes in the tetragonal I4cm space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four ClF4 clusters. In each ClF4 cluster, Cl(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Cl(1)-F(1) bond lengths are 1.76 Å. Both Cl(1)-F(2) bond lengths are 1.91 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Cl(1) atom.