HFeCl4N2Cl is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four HFeCl4 clusters and four N2Cl clusters. In each HFeCl4 cluster, Fe(1) is bonded in a 5-coordinate geometry to one H(1), one Cl(1), one Cl(4), and two equivalent Cl(2) atoms. H(1) is bonded in a single-bond geometry to one Fe(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Fe(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Fe(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Fe(1) atom. In each N2Cl cluster, N(1) is bonded in a single-bond geometry to one Cl(3) atom. Cl(3) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms.
HFeCl4N2Cl is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four HFeCl4 clusters and four N2Cl clusters. In each HFeCl4 cluster, Fe(1) is bonded in a 5-coordinate geometry to one H(1), one Cl(1), one Cl(4), and two equivalent Cl(2) atoms. The Fe(1)-H(1) bond length is 1.50 Å. The Fe(1)-Cl(1) bond length is 2.10 Å. The Fe(1)-Cl(4) bond length is 2.13 Å. Both Fe(1)-Cl(2) bond lengths are 2.16 Å. H(1) is bonded in a single-bond geometry to one Fe(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Fe(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Fe(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Fe(1) atom. In each N2Cl cluster, N(1) is bonded in a single-bond geometry to one Cl(3) atom. The N(1)-Cl(3) bond length is 1.50 Å. Cl(3) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms.