RbC2N3 crystallizes in the triclinic P1 space group. There are eight inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one N(12), one N(15), one N(20), one N(23), one N(4), one N(8), and one N(9) atom. In the second Rb site, Rb(2) is bonded in a 7-coordinate geometry to one N(13), one N(14), one N(17), one N(21), one N(23), one N(4), and one N(6) atom. In the third Rb site, Rb(3) is bonded in a 7-coordinate geometry to one N(11), one N(13), one N(16), one N(2), one N(24), one N(5), and one N(7) atom. In the fourth Rb site, Rb(4) is bonded in a 7-coordinate geometry to one N(10), one N(11), one N(16), one N(19), one N(22), one N(3), and one N(9) atom. In the fifth Rb site, Rb(5) is bonded in a 7-coordinate geometry to one N(10), one N(15), one N(16), one N(19), one N(24), one N(3), and one N(9) atom. In the sixth Rb site, Rb(6) is bonded in a 7-coordinate geometry to one N(13), one N(14), one N(2), one N(21), one N(23), one N(6), and one N(8) atom. In the seventh Rb site, Rb(7) is bonded in a 7-coordinate geometry to one N(12), one N(15), one N(18), one N(20), one N(4), one N(6), and one N(8) atom. In the eighth Rb site, Rb(8) is bonded in a 7-coordinate geometry to one N(1), one N(11), one N(19), one N(2), one N(24), one N(5), and one N(7) atom. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(17) and one N(7) atom. In the second C site, C(2) is bonded in a linear geometry to one N(20) and one N(22) atom. In the third C site, C(3) is bonded in a linear geometry to one N(10) and one N(8) atom. In the fourth C site, C(4) is bonded in a linear geometry to one N(18) and one N(3) atom. In the fifth C site, C(5) is bonded in a linear geometry to one N(21) and one N(24) atom. In the sixth C site, C(6) is bonded in a linear geometry to one N(2) and one N(22) atom. In the seventh C site, C(7) is bonded in a linear geometry to one N(10) and one N(4) atom. In the eighth C site, C(8) is bonded in a linear geometry to one N(5) and one N(6) atom. In the ninth C site, C(9) is bonded in a linear geometry to one N(1) and one N(9) atom. In the tenth C site, C(10) is bonded in a linear geometry to one N(1) and one N(14) atom. In the eleventh C site, C(11) is bonded in a linear geometry to one N(12) and one N(19) atom. In the twelfth C site, C(12) is bonded in a linear geometry to one N(13) and one N(18) atom. In the thirteenth C site, C(13) is bonded in a linear geometry to one N(15) and one N(17) atom. In the fourteenth C site, C(14) is bonded in a linear geometry to one N(11) and one N(21) atom. In the fifteenth C site, C(15) is bonded in a linear geometry to one N(12) and one N(16) atom. In the sixteenth C site, C(16) is bonded in a linear geometry to one N(23) and one N(5) atom. There are twenty-four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Rb(8), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(6), one Rb(8), and one C(6) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Rb(4), one Rb(5), and one C(4) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(7), and one C(7) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Rb(3), one Rb(8), one C(16), and one C(8) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(6), one Rb(7), and one C(8) atom. In the seventh N site, N(7) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(8), and one C(1) atom. In the eighth N site, N(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(6), one Rb(7), and one C(3) atom. In the ninth N site, N(9) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(4), one Rb(5), and one C(9) atom. In the tenth N site, N(10) is bonded in a distorted bent 120 degrees geometry to one Rb(4), one Rb(5), one C(3), and one C(7) atom. In the eleventh N site, N(11) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(4), one Rb(8), and one C(14) atom. In the twelfth N site, N(12) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Rb(7), one C(11), and one C(15) atom. In the thirteenth N site, N(13) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), one Rb(6), and one C(12) atom. In the fourteenth N site, N(14) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(6), and one C(10) atom. In the fifteenth N site, N(15) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(5), one Rb(7), and one C(13) atom. In the sixteenth N site, N(16) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(4), one Rb(5), and one C(15) atom. In the seventeenth N site, N(17) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one C(1), and one C(13) atom. In the eighteenth N site, N(18) is bonded in a distorted bent 120 degrees geometry to one Rb(7), one C(12), and one C(4) atom. In the nineteenth N site, N(19) is bonded in a distorted single-bond geometry to one Rb(4), one Rb(5), one Rb(8), and one C(11) atom. In the twentieth N site, N(20) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(7), and one C(2) atom. In the twenty-first N site, N(21) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one Rb(6), one C(14), and one C(5) atom. In the twenty-second N site, N(22) is bonded in a distorted bent 120 degrees geometry to one Rb(4), one C(2), and one C(6) atom. In the twenty-third N site, N(23) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(6), and one C(16) atom. In the twenty-fourth N site, N(24) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(5), one Rb(8), and one C(5) atom.
RbC2N3 crystallizes in the triclinic P1 space group. There are eight inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one N(12), one N(15), one N(20), one N(23), one N(4), one N(8), and one N(9) atom. The Rb(1)-N(12) bond length is 3.37 Å. The Rb(1)-N(15) bond length is 3.01 Å. The Rb(1)-N(20) bond length is 3.08 Å. The Rb(1)-N(23) bond length is 3.23 Å. The Rb(1)-N(4) bond length is 3.23 Å. The Rb(1)-N(8) bond length is 3.08 Å. The Rb(1)-N(9) bond length is 3.33 Å. In the second Rb site, Rb(2) is bonded in a 7-coordinate geometry to one N(13), one N(14), one N(17), one N(21), one N(23), one N(4), and one N(6) atom. The Rb(2)-N(13) bond length is 2.97 Å. The Rb(2)-N(14) bond length is 3.09 Å. The Rb(2)-N(17) bond length is 3.14 Å. The Rb(2)-N(21) bond length is 3.09 Å. The Rb(2)-N(23) bond length is 3.10 Å. The Rb(2)-N(4) bond length is 3.00 Å. The Rb(2)-N(6) bond length is 3.10 Å. In the third Rb site, Rb(3) is bonded in a 7-coordinate geometry to one N(11), one N(13), one N(16), one N(2), one N(24), one N(5), and one N(7) atom. The Rb(3)-N(11) bond length is 3.20 Å. The Rb(3)-N(13) bond length is 3.31 Å. The Rb(3)-N(16) bond length is 3.31 Å. The Rb(3)-N(2) bond length is 3.02 Å. The Rb(3)-N(24) bond length is 3.08 Å. The Rb(3)-N(5) bond length is 3.29 Å. The Rb(3)-N(7) bond length is 3.04 Å. In the fourth Rb site, Rb(4) is bonded in a 7-coordinate geometry to one N(10), one N(11), one N(16), one N(19), one N(22), one N(3), and one N(9) atom. The Rb(4)-N(10) bond length is 3.14 Å. The Rb(4)-N(11) bond length is 3.04 Å. The Rb(4)-N(16) bond length is 3.15 Å. The Rb(4)-N(19) bond length is 3.10 Å. The Rb(4)-N(22) bond length is 3.05 Å. The Rb(4)-N(3) bond length is 3.04 Å. The Rb(4)-N(9) bond length is 3.00 Å. In the fifth Rb site, Rb(5) is bonded in a 7-coordinate geometry to one N(10), one N(15), one N(16), one N(19), one N(24), one N(3), and one N(9) atom. The Rb(5)-N(10) bond length is 3.30 Å. The Rb(5)-N(15) bond length is 3.31 Å. The Rb(5)-N(16) bond length is 3.08 Å. The Rb(5)-N(19) bond length is 3.17 Å. The Rb(5)-N(24) bond length is 3.24 Å. The Rb(5)-N(3) bond length is 3.04 Å. The Rb(5)-N(9) bond length is 3.03 Å. In the sixth Rb site, Rb(6) is bonded in a 7-coordinate geometry to one N(13), one N(14), one N(2), one N(21), one N(23), one N(6), and one N(8) atom. The Rb(6)-N(13) bond length is 3.01 Å. The Rb(6)-N(14) bond length is 3.04 Å. The Rb(6)-N(2) bond length is 3.32 Å. The Rb(6)-N(21) bond length is 3.32 Å. The Rb(6)-N(23) bond length is 3.15 Å. The Rb(6)-N(6) bond length is 3.22 Å. The Rb(6)-N(8) bond length is 3.26 Å. In the seventh Rb site, Rb(7) is bonded in a 7-coordinate geometry to one N(12), one N(15), one N(18), one N(20), one N(4), one N(6), and one N(8) atom. The Rb(7)-N(12) bond length is 3.09 Å. The Rb(7)-N(15) bond length is 3.03 Å. The Rb(7)-N(18) bond length is 3.13 Å. The Rb(7)-N(20) bond length is 3.11 Å. The Rb(7)-N(4) bond length is 3.09 Å. The Rb(7)-N(6) bond length is 3.04 Å. The Rb(7)-N(8) bond length is 3.10 Å. In the eighth Rb site, Rb(8) is bonded in a 7-coordinate geometry to one N(1), one N(11), one N(19), one N(2), one N(24), one N(5), and one N(7) atom. The Rb(8)-N(1) bond length is 3.12 Å. The Rb(8)-N(11) bond length is 3.12 Å. The Rb(8)-N(19) bond length is 3.00 Å. The Rb(8)-N(2) bond length is 3.00 Å. The Rb(8)-N(24) bond length is 3.18 Å. The Rb(8)-N(5) bond length is 3.14 Å. The Rb(8)-N(7) bond length is 3.09 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(17) and one N(7) atom. The C(1)-N(17) bond length is 1.30 Å. The C(1)-N(7) bond length is 1.18 Å. In the second C site, C(2) is bonded in a linear geometry to one N(20) and one N(22) atom. The C(2)-N(20) bond length is 1.18 Å. The C(2)-N(22) bond length is 1.30 Å. In the third C site, C(3) is bonded in a linear geometry to one N(10) and one N(8) atom. The C(3)-N(10) bond length is 1.30 Å. The C(3)-N(8) bond length is 1.18 Å. In the fourth C site, C(4) is bonded in a linear geometry to one N(18) and one N(3) atom. The C(4)-N(18) bond length is 1.30 Å. The C(4)-N(3) bond length is 1.18 Å. In the fifth C site, C(5) is bonded in a linear geometry to one N(21) and one N(24) atom. The C(5)-N(21) bond length is 1.31 Å. The C(5)-N(24) bond length is 1.18 Å. In the sixth C site, C(6) is bonded in a linear geometry to one N(2) and one N(22) atom. The C(6)-N(2) bond length is 1.19 Å. The C(6)-N(22) bond length is 1.30 Å. In the seventh C site, C(7) is bonded in a linear geometry to one N(10) and one N(4) atom. The C(7)-N(10) bond length is 1.31 Å. The C(7)-N(4) bond length is 1.18 Å. In the eighth C site, C(8) is bonded in a linear geometry to one N(5) and one N(6) atom. The C(8)-N(5) bond length is 1.30 Å. The C(8)-N(6) bond length is 1.19 Å. In the ninth C site, C(9) is bonded in a linear geometry to one N(1) and one N(9) atom. The C(9)-N(1) bond length is 1.30 Å. The C(9)-N(9) bond length is 1.18 Å. In the tenth C site, C(10) is bonded in a linear geometry to one N(1) and one N(14) atom. The C(10)-N(1) bond length is 1.30 Å. The C(10)-N(14) bond length is 1.18 Å. In the eleventh C site, C(11) is bonded in a linear geometry to one N(12) and one N(19) atom. The C(11)-N(12) bond length is 1.30 Å. The C(11)-N(19) bond length is 1.18 Å. In the twelfth C site, C(12) is bonded in a linear geometry to one N(13) and one N(18) atom. The C(12)-N(13) bond length is 1.18 Å. The C(12)-N(18) bond length is 1.30 Å. In the thirteenth C site, C(13) is bonded in a linear geometry to one N(15) and one N(17) atom. The C(13)-N(15) bond length is 1.18 Å. The C(13)-N(17) bond length is 1.30 Å. In the fourteenth C site, C(14) is bonded in a linear geometry to one N(11) and one N(21) atom. The C(14)-N(11) bond length is 1.18 Å. The C(14)-N(21) bond length is 1.30 Å. In the fifteenth C site, C(15) is bonded in a linear geometry to one N(12) and one N(16) atom. The C(15)-N(12) bond length is 1.31 Å. The C(15)-N(16) bond length is 1.18 Å. In the sixteenth C site, C(16) is bonded in a linear geometry to one N(23) and one N(5) atom. The C(16)-N(23) bond length is 1.18 Å. The C(16)-N(5) bond length is 1.31 Å. There are twenty-four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Rb(8), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(6), one Rb(8), and one C(6) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Rb(4), one Rb(5), and one C(4) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(7), and one C(7) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Rb(3), one Rb(8), one C(16), and one C(8) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(6), one Rb(7), and one C(8) atom. In the seventh N site, N(7) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(8), and one C(1) atom. In the eighth N site, N(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(6), one Rb(7), and one C(3) atom. In the ninth N site, N(9) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(4), one Rb(5), and one C(9) atom. In the tenth N site, N(10) is bonded in a distorted bent 120 degrees geometry to one Rb(4), one Rb(5), one C(3), and one C(7) atom. In the eleventh N site, N(11) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(4), one Rb(8), and one C(14) atom. In the twelfth N site, N(12) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Rb(7), one C(11), and one C(15) atom. In the thirteenth N site, N(13) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), one Rb(6), and one C(12) atom. In the fourteenth N site, N(14) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(6), and one C(10) atom. In the fifteenth N site, N(15) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(5), one Rb(7), and one C(13) atom. In the sixteenth N site, N(16) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(4), one Rb(5), and one C(15) atom. In the seventeenth N site, N(17) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one C(1), and one C(13) atom. In the eighteenth N site, N(18) is bonded in a distorted bent 120 degrees geometry to one Rb(7), one C(12), and one C(4) atom. In the nineteenth N site, N(19) is bonded in a distorted single-bond geometry to one Rb(4), one Rb(5), one Rb(8), and one C(11) atom. In the twentieth N site, N(20) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(7), and one C(2) atom. In the twenty-first N site, N(21) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one Rb(6), one C(14), and one C(5) atom. In the twenty-second N site, N(22) is bonded in a distorted bent 120 degrees geometry to one Rb(4), one C(2), and one C(6) atom. In the twenty-third N site, N(23) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(6), and one C(16) atom. In the twenty-fourth N site, N(24) is bonded in a distorted single-bond geometry to one Rb(3), one Rb(5), one Rb(8), and one C(5) atom.