KGeCl3 crystallizes in the trigonal R3c space group. K(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. Ge(1) is bonded in a distorted T-shaped geometry to three equivalent Cl(1) atoms. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Ge(1) atom.
KGeCl3 crystallizes in the trigonal R3c space group. K(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. There are three shorter (3.18 Å) and three longer (3.28 Å) K(1)-Cl(1) bond lengths. Ge(1) is bonded in a distorted T-shaped geometry to three equivalent Cl(1) atoms. All Ge(1)-Cl(1) bond lengths are 2.38 Å. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Ge(1) atom.