V2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with eight equivalent V(2)O5F octahedra and edges with two equivalent V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-50°. In the second V site, V(2) is bonded to one O(1), four equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with eight equivalent V(1)O4F2 octahedra and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-50°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms.
V2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with eight equivalent V(2)O5F octahedra and edges with two equivalent V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-50°. Both V(1)-O(1) bond lengths are 1.95 Å. Both V(1)-O(2) bond lengths are 1.98 Å. Both V(1)-F(1) bond lengths are 2.09 Å. In the second V site, V(2) is bonded to one O(1), four equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with eight equivalent V(1)O4F2 octahedra and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-50°. The V(2)-O(1) bond length is 1.88 Å. All V(2)-O(2) bond lengths are 1.97 Å. The V(2)-F(1) bond length is 2.20 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms.