WCrO6 crystallizes in the monoclinic Cm space group. W(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. Cr(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom.
WCrO6 crystallizes in the monoclinic Cm space group. W(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. The W(1)-O(1) bond length is 1.81 Å. The W(1)-O(2) bond length is 2.14 Å. Both W(1)-O(3) bond lengths are 1.79 Å. Both W(1)-O(4) bond lengths are 2.15 Å. Cr(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. The Cr(1)-O(1) bond length is 2.03 Å. The Cr(1)-O(2) bond length is 1.68 Å. Both Cr(1)-O(3) bond lengths are 2.06 Å. Both Cr(1)-O(4) bond lengths are 1.68 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom.