KPuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent Pu(1)O6 octahedra. Pu(1) is bonded to six equivalent O(1) atoms to form PuO6 octahedra that share corners with six equivalent Pu(1)O6 octahedra and faces with eight equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent K(1) and two equivalent Pu(1) atoms.
KPuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent Pu(1)O6 octahedra. All K(1)-O(1) bond lengths are 3.00 Å. Pu(1) is bonded to six equivalent O(1) atoms to form PuO6 octahedra that share corners with six equivalent Pu(1)O6 octahedra and faces with eight equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Pu(1)-O(1) bond lengths are 2.12 Å. O(1) is bonded in a distorted linear geometry to four equivalent K(1) and two equivalent Pu(1) atoms.