(CNCl)3C3N3Cl3F2(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two 2,4,6-trichloro-1,3,5-triazin-1-ium molecules; four AsF6 clusters; and two C3N3Cl3F2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In each C3N3Cl3F2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one Cl(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one F(7) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(2) atom. F(7) is bonded in a single-bond geometry to one N(1) atom.
(CNCl)3C3N3Cl3F2(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two 2,4,6-trichloro-1,3,5-triazin-1-ium molecules; four AsF6 clusters; and two C3N3Cl3F2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.77 Å. The As(1)-F(2) bond length is 1.77 Å. The As(1)-F(3) bond length is 1.77 Å. The As(1)-F(4) bond length is 1.78 Å. The As(1)-F(5) bond length is 1.79 Å. The As(1)-F(6) bond length is 1.78 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In each C3N3Cl3F2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one Cl(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.32 Å. The C(1)-Cl(1) bond length is 1.64 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one Cl(2) atom. Both C(2)-N(1) bond lengths are 1.36 Å. The C(2)-Cl(2) bond length is 1.63 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one F(7) atom. The N(1)-F(7) bond length is 1.36 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(2) atom. F(7) is bonded in a single-bond geometry to one N(1) atom.