AgP(NO)2 crystallizes in the trigonal P3_121 space group. Ag(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. P(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent O(1) atoms. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one P(1), and one N(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one P(1) atom.
AgP(NO)2 crystallizes in the trigonal P3_121 space group. Ag(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Ag(1)-N(1) bond lengths are 2.22 Å. Both Ag(1)-O(1) bond lengths are 2.45 Å. P(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent O(1) atoms. Both P(1)-N(1) bond lengths are 1.72 Å. Both P(1)-O(1) bond lengths are 1.49 Å. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one P(1), and one N(1) atom. The N(1)-N(1) bond length is 1.32 Å. O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one P(1) atom.