Zn(Au4In)3 is beta Cu3Ti-derived structured and crystallizes in the orthorhombic Pmm2 space group. There are seven inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted see-saw-like geometry to four equivalent Au(4), four equivalent Au(6), two equivalent Zn(1), and two equivalent In(2) atoms. In the second Au site, Au(2) is bonded in a distorted see-saw-like geometry to four equivalent Au(5), four equivalent Au(7), two equivalent In(1), and two equivalent In(2) atoms. In the third Au site, Au(3) is bonded in a distorted see-saw-like geometry to two equivalent Au(4), two equivalent Au(5), two equivalent Au(6), two equivalent Au(7), one Zn(1), one In(1), and two equivalent In(2) atoms. In the fourth Au site, Au(4) is bonded to one Au(4), one Au(5), two equivalent Au(1), two equivalent Au(3), two equivalent Au(6), two equivalent Zn(1), and two equivalent In(2) atoms to form distorted AuZn2In2Au8 cuboctahedra that share corners with four equivalent Au(4)Zn2In2Au8 cuboctahedra, corners with four equivalent Zn(1)Au12 cuboctahedra, corners with six equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra,  a faceface with one Au(5)In4Au8 cuboctahedra, faces with two equivalent Au(7)In4Au8 cuboctahedra, faces with two equivalent Zn(1)Au12 cuboctahedra, faces with two equivalent In(2)Au12 cuboctahedra, and faces with three equivalent Au(4)Zn2In2Au8 cuboctahedra. In the fifth Au site, Au(5) is bonded to one Au(4), one Au(5), two equivalent Au(2), two equivalent Au(3), two equivalent Au(7), two equivalent In(1), and two equivalent In(2) atoms to form distorted AuIn4Au8 cuboctahedra that share corners with four equivalent Au(5)In4Au8 cuboctahedra, corners with four equivalent In(1)Au12 cuboctahedra, corners with six equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra,  a faceface with one Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, faces with two equivalent In(2)Au12 cuboctahedra, faces with three equivalent Au(5)In4Au8 cuboctahedra, and faces with six equivalent Au(7)In4Au8 cuboctahedra. In the sixth Au site, Au(6) is bonded in a 12-coordinate geometry to one Au(6), one Au(7), two equivalent Au(1), two equivalent Au(3), two equivalent Au(4), two equivalent Zn(1), and two equivalent In(2) atoms. In the seventh Au site, Au(7) is bonded to one Au(6), one Au(7), two equivalent Au(2), two equivalent Au(3), two equivalent Au(5), two equivalent In(1), and two equivalent In(2) atoms to form distorted AuIn4Au8 cuboctahedra that share corners with four equivalent Au(7)In4Au8 cuboctahedra, corners with four equivalent In(2)Au12 cuboctahedra, edges with two equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with two equivalent In(2)Au12 cuboctahedra, faces with two equivalent Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, faces with two equivalent In(2)Au12 cuboctahedra, faces with three equivalent Au(7)In4Au8 cuboctahedra, and faces with six equivalent Au(5)In4Au8 cuboctahedra. Zn(1) is bonded to two equivalent Au(1), two equivalent Au(3), four equivalent Au(4), and four equivalent Au(6) atoms to form ZnAu12 cuboctahedra that share corners with two equivalent In(1)Au12 cuboctahedra, corners with eight equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with four equivalent Au(5)In4Au8 cuboctahedra, edges with four equivalent Au(7)In4Au8 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra, faces with two equivalent Zn(1)Au12 cuboctahedra, faces with four equivalent Au(4)Zn2In2Au8 cuboctahedra, and faces with four equivalent In(2)Au12 cuboctahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent Au(2), two equivalent Au(3), four equivalent Au(5), and four equivalent Au(7) atoms to form InAu12 cuboctahedra that share corners with two equivalent Zn(1)Au12 cuboctahedra, corners with eight equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with four equivalent Au(7)In4Au8 cuboctahedra, edges with four equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, faces with four equivalent Au(5)In4Au8 cuboctahedra, faces with four equivalent Au(7)In4Au8 cuboctahedra, and faces with four equivalent In(2)Au12 cuboctahedra. In the second In site, In(2) is bonded to one Au(1), one Au(2), two equivalent Au(3), two equivalent Au(4), two equivalent Au(5), two equivalent Au(6), and two equivalent Au(7) atoms to form InAu12 cuboctahedra that share corners with two equivalent In(2)Au12 cuboctahedra, corners with four equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with two equivalent In(2)Au12 cuboctahedra, edges with four equivalent Au(5)In4Au8 cuboctahedra, edges with four equivalent Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent Au(5)In4Au8 cuboctahedra, faces with two equivalent Au(7)In4Au8 cuboctahedra, faces with two equivalent Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent Zn(1)Au12 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, and faces with two equivalent In(2)Au12 cuboctahedra.
Zn(Au4In)3 is beta Cu3Ti-derived structured and crystallizes in the orthorhombic Pmm2 space group. There are seven inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted see-saw-like geometry to four equivalent Au(4), four equivalent Au(6), two equivalent Zn(1), and two equivalent In(2) atoms. All Au(1)-Au(4) bond lengths are 2.95 Å. There are two shorter (2.95 Å) and two longer (3.10 Å) Au(1)-Au(6) bond lengths. Both Au(1)-Zn(1) bond lengths are 2.94 Å. Both Au(1)-In(2) bond lengths are 2.92 Å. In the second Au site, Au(2) is bonded in a distorted see-saw-like geometry to four equivalent Au(5), four equivalent Au(7), two equivalent In(1), and two equivalent In(2) atoms. All Au(2)-Au(5) bond lengths are 2.96 Å. All Au(2)-Au(7) bond lengths are 3.05 Å. Both Au(2)-In(1) bond lengths are 2.97 Å. Both Au(2)-In(2) bond lengths are 2.95 Å. In the third Au site, Au(3) is bonded in a distorted see-saw-like geometry to two equivalent Au(4), two equivalent Au(5), two equivalent Au(6), two equivalent Au(7), one Zn(1), one In(1), and two equivalent In(2) atoms. There is one shorter (3.02 Å) and one longer (3.03 Å) Au(3)-Au(4) bond length. There is one shorter (3.06 Å) and one longer (3.08 Å) Au(3)-Au(5) bond length. Both Au(3)-Au(6) bond lengths are 2.92 Å. Both Au(3)-Au(7) bond lengths are 2.97 Å. The Au(3)-Zn(1) bond length is 2.86 Å. The Au(3)-In(1) bond length is 3.00 Å. Both Au(3)-In(2) bond lengths are 2.97 Å. In the fourth Au site, Au(4) is bonded to one Au(4), one Au(5), two equivalent Au(1), two equivalent Au(3), two equivalent Au(6), two equivalent Zn(1), and two equivalent In(2) atoms to form distorted AuZn2In2Au8 cuboctahedra that share corners with four equivalent Au(4)Zn2In2Au8 cuboctahedra, corners with four equivalent Zn(1)Au12 cuboctahedra, corners with six equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra,  a faceface with one Au(5)In4Au8 cuboctahedra, faces with two equivalent Au(7)In4Au8 cuboctahedra, faces with two equivalent Zn(1)Au12 cuboctahedra, faces with two equivalent In(2)Au12 cuboctahedra, and faces with three equivalent Au(4)Zn2In2Au8 cuboctahedra. The Au(4)-Au(4) bond length is 2.88 Å. The Au(4)-Au(5) bond length is 2.94 Å. Both Au(4)-Au(6) bond lengths are 2.98 Å. There is one shorter (3.02 Å) and one longer (3.05 Å) Au(4)-Zn(1) bond length. Both Au(4)-In(2) bond lengths are 2.95 Å. In the fifth Au site, Au(5) is bonded to one Au(4), one Au(5), two equivalent Au(2), two equivalent Au(3), two equivalent Au(7), two equivalent In(1), and two equivalent In(2) atoms to form distorted AuIn4Au8 cuboctahedra that share corners with four equivalent Au(5)In4Au8 cuboctahedra, corners with four equivalent In(1)Au12 cuboctahedra, corners with six equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra,  a faceface with one Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, faces with two equivalent In(2)Au12 cuboctahedra, faces with three equivalent Au(5)In4Au8 cuboctahedra, and faces with six equivalent Au(7)In4Au8 cuboctahedra. The Au(5)-Au(5) bond length is 2.98 Å. Both Au(5)-Au(7) bond lengths are 2.96 Å. There is one shorter (3.05 Å) and one longer (3.07 Å) Au(5)-In(1) bond length. Both Au(5)-In(2) bond lengths are 2.94 Å. In the sixth Au site, Au(6) is bonded in a 12-coordinate geometry to one Au(6), one Au(7), two equivalent Au(1), two equivalent Au(3), two equivalent Au(4), two equivalent Zn(1), and two equivalent In(2) atoms. The Au(6)-Au(6) bond length is 2.82 Å. The Au(6)-Au(7) bond length is 2.98 Å. Both Au(6)-Zn(1) bond lengths are 2.90 Å. There is one shorter (3.05 Å) and one longer (3.08 Å) Au(6)-In(2) bond length. In the seventh Au site, Au(7) is bonded to one Au(6), one Au(7), two equivalent Au(2), two equivalent Au(3), two equivalent Au(5), two equivalent In(1), and two equivalent In(2) atoms to form distorted AuIn4Au8 cuboctahedra that share corners with four equivalent Au(7)In4Au8 cuboctahedra, corners with four equivalent In(2)Au12 cuboctahedra, edges with two equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with two equivalent In(2)Au12 cuboctahedra, faces with two equivalent Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, faces with two equivalent In(2)Au12 cuboctahedra, faces with three equivalent Au(7)In4Au8 cuboctahedra, and faces with six equivalent Au(5)In4Au8 cuboctahedra. The Au(7)-Au(7) bond length is 2.95 Å. Both Au(7)-In(1) bond lengths are 2.94 Å. There is one shorter (3.05 Å) and one longer (3.06 Å) Au(7)-In(2) bond length. Zn(1) is bonded to two equivalent Au(1), two equivalent Au(3), four equivalent Au(4), and four equivalent Au(6) atoms to form ZnAu12 cuboctahedra that share corners with two equivalent In(1)Au12 cuboctahedra, corners with eight equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with four equivalent Au(5)In4Au8 cuboctahedra, edges with four equivalent Au(7)In4Au8 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra, faces with two equivalent Zn(1)Au12 cuboctahedra, faces with four equivalent Au(4)Zn2In2Au8 cuboctahedra, and faces with four equivalent In(2)Au12 cuboctahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent Au(2), two equivalent Au(3), four equivalent Au(5), and four equivalent Au(7) atoms to form InAu12 cuboctahedra that share corners with two equivalent Zn(1)Au12 cuboctahedra, corners with eight equivalent Au(5)In4Au8 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with four equivalent Au(7)In4Au8 cuboctahedra, edges with four equivalent Au(4)Zn2In2Au8 cuboctahedra, edges with four equivalent In(2)Au12 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, faces with four equivalent Au(5)In4Au8 cuboctahedra, faces with four equivalent Au(7)In4Au8 cuboctahedra, and faces with four equivalent In(2)Au12 cuboctahedra. In the second In site, In(2) is bonded to one Au(1), one Au(2), two equivalent Au(3), two equivalent Au(4), two equivalent Au(5), two equivalent Au(6), and two equivalent Au(7) atoms to form InAu12 cuboctahedra that share corners with two equivalent In(2)Au12 cuboctahedra, corners with four equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Au(7)In4Au8 cuboctahedra, edges with two equivalent Zn(1)Au12 cuboctahedra, edges with two equivalent In(1)Au12 cuboctahedra, edges with two equivalent In(2)Au12 cuboctahedra, edges with four equivalent Au(5)In4Au8 cuboctahedra, edges with four equivalent Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent Au(5)In4Au8 cuboctahedra, faces with two equivalent Au(7)In4Au8 cuboctahedra, faces with two equivalent Au(4)Zn2In2Au8 cuboctahedra, faces with two equivalent Zn(1)Au12 cuboctahedra, faces with two equivalent In(1)Au12 cuboctahedra, and faces with two equivalent In(2)Au12 cuboctahedra.