Mg(Tl)2(Pb2OBr2)8(Br)2 is Indium-derived structured and crystallizes in the tetragonal P4 space group. The structure is zero-dimensional and consists of one 7439-95-4 atom, two 7440-28-0 atoms, two hydrogen bromide atoms, and two Pb2OBr2 clusters. In each Pb2OBr2 cluster, there are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted single-bond geometry to one O(1), one Br(1), and one Br(3) atom. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2) atoms. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to one O(2), one Br(2), and one Br(4) atom. In the fourth Pb site, Pb(4) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Pb(1), one Pb(2), and two equivalent Pb(4) atoms to form edge-sharing OPb4 tetrahedra. In the second O site, O(2) is bonded to one Pb(3), one Pb(4), and two equivalent Pb(2) atoms to form edge-sharing OPb4 tetrahedra. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Pb(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Pb(3) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one Pb(1) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one Pb(3) atom.
Mg(Tl)2(Pb2OBr2)8(Br)2 is Indium-derived structured and crystallizes in the tetragonal P4 space group. The structure is zero-dimensional and consists of one 7439-95-4 atom, two 7440-28-0 atoms, two hydrogen bromide atoms, and two Pb2OBr2 clusters. In each Pb2OBr2 cluster, there are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted single-bond geometry to one O(1), one Br(1), and one Br(3) atom. The Pb(1)-O(1) bond length is 2.31 Å. The Pb(1)-Br(1) bond length is 2.98 Å. The Pb(1)-Br(3) bond length is 2.93 Å. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2) atoms. The Pb(2)-O(1) bond length is 2.34 Å. There is one shorter (2.36 Å) and one longer (2.40 Å) Pb(2)-O(2) bond length. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to one O(2), one Br(2), and one Br(4) atom. The Pb(3)-O(2) bond length is 2.32 Å. The Pb(3)-Br(2) bond length is 2.99 Å. The Pb(3)-Br(4) bond length is 2.95 Å. In the fourth Pb site, Pb(4) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. The Pb(4)-O(2) bond length is 2.34 Å. There is one shorter (2.36 Å) and one longer (2.40 Å) Pb(4)-O(1) bond length. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Pb(1), one Pb(2), and two equivalent Pb(4) atoms to form edge-sharing OPb4 tetrahedra. In the second O site, O(2) is bonded to one Pb(3), one Pb(4), and two equivalent Pb(2) atoms to form edge-sharing OPb4 tetrahedra. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Pb(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Pb(3) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one Pb(1) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one Pb(3) atom.