In(OH)3 crystallizes in the triclinic P1 space group. There are four inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. In the second In site, In(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(4), and one O(9) atom to form distorted corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-54°. In the third In site, In(3) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. In the fourth In site, In(4) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-56°. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(7) atom. In the sixth H site, H(6) is bonded in a linear geometry to one O(4) and one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(2) atom. In the eleventh H site, H(11) is bonded in a linear geometry to one O(12) and one O(7) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one In(1), one In(2), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(10) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one In(2), one In(4), and one H(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one In(3), one In(4), and one H(4) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one In(3), one In(4), one H(11), and one H(5) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one In(2), one In(4), and one H(7) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(9) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(8) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one In(1), one In(2), one H(11), and one H(12) atom.
In(OH)3 crystallizes in the triclinic P1 space group. There are four inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. The In(1)-O(1) bond length is 2.17 Å. The In(1)-O(11) bond length is 2.17 Å. The In(1)-O(12) bond length is 2.32 Å. The In(1)-O(2) bond length is 2.20 Å. The In(1)-O(5) bond length is 2.21 Å. The In(1)-O(8) bond length is 2.15 Å. In the second In site, In(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(4), and one O(9) atom to form distorted corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-54°. The In(2)-O(1) bond length is 2.21 Å. The In(2)-O(10) bond length is 2.24 Å. The In(2)-O(12) bond length is 2.42 Å. The In(2)-O(3) bond length is 2.19 Å. The In(2)-O(4) bond length is 2.07 Å. The In(2)-O(9) bond length is 2.20 Å. In the third In site, In(3) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. The In(3)-O(10) bond length is 2.19 Å. The In(3)-O(3) bond length is 2.21 Å. The In(3)-O(5) bond length is 2.20 Å. The In(3)-O(6) bond length is 2.25 Å. The In(3)-O(7) bond length is 2.27 Å. The In(3)-O(8) bond length is 2.14 Å. In the fourth In site, In(4) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-56°. The In(4)-O(11) bond length is 2.23 Å. The In(4)-O(2) bond length is 2.19 Å. The In(4)-O(4) bond length is 2.09 Å. The In(4)-O(6) bond length is 2.27 Å. The In(4)-O(7) bond length is 2.30 Å. The In(4)-O(9) bond length is 2.25 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 1.00 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(5) atom. The H(3)-O(5) bond length is 1.00 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. The H(4)-O(6) bond length is 0.97 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(7) atom. The H(5)-O(7) bond length is 1.02 Å. In the sixth H site, H(6) is bonded in a linear geometry to one O(4) and one O(8) atom. The H(6)-O(4) bond length is 1.52 Å. The H(6)-O(8) bond length is 1.05 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. The H(7)-O(9) bond length is 1.00 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(11) atom. The H(8)-O(11) bond length is 1.00 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. The H(9)-O(10) bond length is 1.00 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(2) atom. The H(10)-O(2) bond length is 1.01 Å. In the eleventh H site, H(11) is bonded in a linear geometry to one O(12) and one O(7) atom. The H(11)-O(12) bond length is 1.14 Å. The H(11)-O(7) bond length is 1.34 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(12) atom. The H(12)-O(12) bond length is 0.97 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one In(1), one In(2), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(10) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one In(2), one In(4), and one H(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one In(3), one In(4), and one H(4) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one In(3), one In(4), one H(11), and one H(5) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one In(2), one In(4), and one H(7) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(9) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(8) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one In(1), one In(2), one H(11), and one H(12) atom.