TiCrS4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Ti(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form TiS6 octahedra that share edges with two equivalent Ti(1)S6 octahedra and edges with four equivalent Cr(1)S6 octahedra. Cr(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form CrS6 octahedra that share edges with two equivalent Cr(1)S6 octahedra and edges with four equivalent Ti(1)S6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to two equivalent Ti(1) and one Cr(1) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Ti(1) and two equivalent Cr(1) atoms.
TiCrS4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Ti(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form TiS6 octahedra that share edges with two equivalent Ti(1)S6 octahedra and edges with four equivalent Cr(1)S6 octahedra. Both Ti(1)-S(2) bond lengths are 2.42 Å. All Ti(1)-S(1) bond lengths are 2.43 Å. Cr(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form CrS6 octahedra that share edges with two equivalent Cr(1)S6 octahedra and edges with four equivalent Ti(1)S6 octahedra. Both Cr(1)-S(1) bond lengths are 2.37 Å. All Cr(1)-S(2) bond lengths are 2.37 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to two equivalent Ti(1) and one Cr(1) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Ti(1) and two equivalent Cr(1) atoms.