Pr6Pd13Cd4 crystallizes in the cubic Im-3m space group. Pr(1) is bonded in a 5-coordinate geometry to one Pd(2) and four equivalent Pd(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to two equivalent Pr(1) and two equivalent Cd(1) atoms. In the second Pd site, Pd(2) is bonded in an octahedral geometry to six equivalent Pr(1) atoms. Cd(1) is bonded in a distorted hexagonal planar geometry to six equivalent Pd(1) atoms.
Pr6Pd13Cd4 crystallizes in the cubic Im-3m space group. Pr(1) is bonded in a 5-coordinate geometry to one Pd(2) and four equivalent Pd(1) atoms. The Pr(1)-Pd(2) bond length is 2.98 Å. All Pr(1)-Pd(1) bond lengths are 2.95 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to two equivalent Pr(1) and two equivalent Cd(1) atoms. Both Pd(1)-Cd(1) bond lengths are 2.76 Å. In the second Pd site, Pd(2) is bonded in an octahedral geometry to six equivalent Pr(1) atoms. Cd(1) is bonded in a distorted hexagonal planar geometry to six equivalent Pd(1) atoms.