Ag3Br crystallizes in the hexagonal P6_3/mmc space group. Ag(1) is bonded in a 10-coordinate geometry to six equivalent Ag(1) and four equivalent Br(1) atoms. Br(1) is bonded to twelve equivalent Ag(1) atoms to form a mixture of distorted face and corner-sharing BrAg12 cuboctahedra.
Ag3Br crystallizes in the hexagonal P6_3/mmc space group. Ag(1) is bonded in a 10-coordinate geometry to six equivalent Ag(1) and four equivalent Br(1) atoms. All Ag(1)-Ag(1) bond lengths are 2.89 Å. There are two shorter (3.17 Å) and two longer (3.28 Å) Ag(1)-Br(1) bond lengths. Br(1) is bonded to twelve equivalent Ag(1) atoms to form a mixture of distorted face and corner-sharing BrAg12 cuboctahedra.