KLiAs crystallizes in the orthorhombic Pmma space group. The structure is zero-dimensional and consists of two KLiAs clusters. K(1) is bonded in a 2-coordinate geometry to one Li(1) and one As(1) atom. Li(1) is bonded in a 2-coordinate geometry to one K(1) and two equivalent As(1) atoms. As(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent Li(1), and one As(1) atom.
KLiAs crystallizes in the orthorhombic Pmma space group. The structure is zero-dimensional and consists of two KLiAs clusters. K(1) is bonded in a 2-coordinate geometry to one Li(1) and one As(1) atom. The K(1)-Li(1) bond length is 3.62 Å. The K(1)-As(1) bond length is 3.14 Å. Li(1) is bonded in a 2-coordinate geometry to one K(1) and two equivalent As(1) atoms. There is one shorter (2.43 Å) and one longer (2.49 Å) Li(1)-As(1) bond length. As(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent Li(1), and one As(1) atom. The As(1)-As(1) bond length is 2.36 Å.