MgWTeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share edges with three equivalent W(1)O6 octahedra. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share edges with three equivalent Mg(1)O6 octahedra. Te(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Mg(1), one W(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Mg(1), one W(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Mg(1), one W(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Te(1) atom.
MgWTeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share edges with three equivalent W(1)O6 octahedra. The Mg(1)-O(1) bond length is 2.07 Å. The Mg(1)-O(2) bond length is 2.10 Å. The Mg(1)-O(3) bond length is 2.08 Å. The Mg(1)-O(4) bond length is 2.11 Å. The Mg(1)-O(5) bond length is 2.08 Å. The Mg(1)-O(6) bond length is 2.11 Å. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share edges with three equivalent Mg(1)O6 octahedra. The W(1)-O(1) bond length is 1.82 Å. The W(1)-O(2) bond length is 2.18 Å. The W(1)-O(3) bond length is 1.82 Å. The W(1)-O(4) bond length is 2.18 Å. The W(1)-O(5) bond length is 1.82 Å. The W(1)-O(6) bond length is 2.17 Å. Te(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Te(1)-O(1) bond length is 2.64 Å. The Te(1)-O(2) bond length is 1.96 Å. The Te(1)-O(3) bond length is 2.65 Å. The Te(1)-O(4) bond length is 1.96 Å. The Te(1)-O(5) bond length is 2.65 Å. The Te(1)-O(6) bond length is 1.97 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Mg(1), one W(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Mg(1), one W(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Mg(1), one W(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mg(1), one W(1), and one Te(1) atom.