Li4Mn2Co3O10 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the second Li site, Li(2) is bonded to one O(3), one O(4), one O(6), one O(7), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the third Li site, Li(3) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(10) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(8), and two equivalent O(4) atoms to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. In the second Mn site, Mn(2) is bonded to one O(10), one O(5), one O(6), one O(9), and two equivalent O(7) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(5), one O(6), one O(8), and two equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the third Co site, Co(3) is bonded to two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. In the fourth Co site, Co(4) is bonded to one O(10), one O(3), one O(6), one O(8), and two equivalent O(9) atoms to form CoO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Mn(1), one Co(2), and two equivalent Co(1) atoms to form OLiMnCo3 square pyramids that share  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(1)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(5)Li2MnCo2 square pyramids, corners with two equivalent O(4)Li3Mn2 square pyramids, corners with two equivalent O(6)LiMnCo3 square pyramids, edges with two equivalent O(8)Li2MnCo3 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(1)LiMnCo3 square pyramid, and  an edgeedge with one O(6)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles are 6°. In the second O site, O(2) is bonded to one Li(1), one Li(3), two equivalent Li(2), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(2)Li4MnCo octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4Mn2 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, edges with two equivalent O(4)Li3Mn2 square pyramids, and edges with two equivalent O(1)LiMnCo3 square pyramids. The corner-sharing octahedral tilt angles range from 4-7°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Mn(1), one Co(2), and one Co(4) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(5)Li2MnCo2 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(9)LiMnCo3 square pyramid, edges with two equivalent O(4)Li3Mn2 square pyramids, edges with two equivalent O(1)LiMnCo3 square pyramids, and edges with two equivalent O(6)LiMnCo3 square pyramids. The corner-sharing octahedral tilt angles range from 0-8°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), and two equivalent Mn(1) atoms to form OLi3Mn2 square pyramids that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid, corners with two equivalent O(5)Li2MnCo2 square pyramids, corners with two equivalent O(1)LiMnCo3 square pyramids,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(4)Li3Mn2 square pyramid, and  an edgeedge with one O(10)Li3MnCo square pyramid. The corner-sharing octahedral tilt angles range from 5-6°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), one Mn(2), one Co(1), and one Co(3) atom to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(5)Li2MnCo2 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(4)Li3Mn2 square pyramids, corners with two equivalent O(10)Li3MnCo square pyramids, corners with two equivalent O(1)LiMnCo3 square pyramids,  an edgeedge with one O(2)Li4MnCo octahedra, edges with two equivalent O(8)Li2MnCo3 octahedra, edges with two equivalent O(7)Li4Mn2 octahedra,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles are 4°. In the sixth O site, O(6) is bonded to one Li(2), one Mn(2), one Co(1), one Co(2), and one Co(4) atom to form OLiMnCo3 square pyramids that share  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(10)Li3MnCo square pyramids, corners with two equivalent O(1)LiMnCo3 square pyramids,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4MnCo octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(1)LiMnCo3 square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles range from 0-9°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), and two equivalent Mn(2) atoms to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(1)LiMnCo3 square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid,  an edgeedge with one O(9)LiMnCo3 square pyramid, edges with two equivalent O(5)Li2MnCo2 square pyramids, and edges with two equivalent O(10)Li3MnCo square pyramids. The corner-sharing octahedral tilt angles are 8°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Mn(1), one Co(1), one Co(3), and one Co(4) atom to form OLi2MnCo3 octahedra that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4MnCo octahedra,  an edgeedge with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, edges with two equivalent O(5)Li2MnCo2 square pyramids, edges with two equivalent O(1)LiMnCo3 square pyramids, and edges with two equivalent O(9)LiMnCo3 square pyramids. The corner-sharing octahedral tilt angles range from 0-6°. In the ninth O site, O(9) is bonded to one Li(1), one Mn(2), one Co(3), and two equivalent Co(4) atoms to form OLiMnCo3 square pyramids that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(5)Li2MnCo2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(1)LiMnCo3 square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(8)Li2MnCo3 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles range from 1-6°. In the tenth O site, O(10) is bonded to one Li(3), two equivalent Li(4), one Mn(2), and one Co(4) atom to form OLi3MnCo square pyramids that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(5)Li2MnCo2 square pyramids, corners with two equivalent O(6)LiMnCo3 square pyramids,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4Mn2 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(10)Li3MnCo square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles range from 4-8°.
Li4Mn2Co3O10 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. The Li(1)-O(1) bond length is 2.18 Å. The Li(1)-O(2) bond length is 2.05 Å. The Li(1)-O(3) bond length is 2.10 Å. The Li(1)-O(7) bond length is 2.14 Å. The Li(1)-O(8) bond length is 2.21 Å. The Li(1)-O(9) bond length is 2.16 Å. In the second Li site, Li(2) is bonded to one O(3), one O(4), one O(6), one O(7), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. The Li(2)-O(3) bond length is 2.19 Å. The Li(2)-O(4) bond length is 2.05 Å. The Li(2)-O(6) bond length is 2.18 Å. The Li(2)-O(7) bond length is 2.12 Å. There is one shorter (2.15 Å) and one longer (2.16 Å) Li(2)-O(2) bond length. In the third Li site, Li(3) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. The Li(3)-O(10) bond length is 2.01 Å. The Li(3)-O(2) bond length is 2.04 Å. The Li(3)-O(3) bond length is 2.18 Å. The Li(3)-O(4) bond length is 2.05 Å. The Li(3)-O(5) bond length is 2.09 Å. The Li(3)-O(7) bond length is 2.12 Å. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(10) atoms to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. The Li(4)-O(4) bond length is 2.18 Å. The Li(4)-O(5) bond length is 2.17 Å. The Li(4)-O(7) bond length is 2.12 Å. The Li(4)-O(8) bond length is 2.28 Å. There is one shorter (2.05 Å) and one longer (2.09 Å) Li(4)-O(10) bond length. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(8), and two equivalent O(4) atoms to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. The Mn(1)-O(1) bond length is 1.97 Å. The Mn(1)-O(2) bond length is 1.91 Å. The Mn(1)-O(3) bond length is 1.98 Å. The Mn(1)-O(8) bond length is 2.00 Å. There is one shorter (1.89 Å) and one longer (1.92 Å) Mn(1)-O(4) bond length. In the second Mn site, Mn(2) is bonded to one O(10), one O(5), one O(6), one O(9), and two equivalent O(7) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. The Mn(2)-O(10) bond length is 1.89 Å. The Mn(2)-O(5) bond length is 1.95 Å. The Mn(2)-O(6) bond length is 1.98 Å. The Mn(2)-O(9) bond length is 1.94 Å. There is one shorter (1.93 Å) and one longer (1.95 Å) Mn(2)-O(7) bond length. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(5), one O(6), one O(8), and two equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. The Co(1)-O(2) bond length is 1.94 Å. The Co(1)-O(5) bond length is 1.92 Å. The Co(1)-O(6) bond length is 1.91 Å. The Co(1)-O(8) bond length is 1.96 Å. There is one shorter (1.93 Å) and one longer (1.96 Å) Co(1)-O(1) bond length. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. Both Co(2)-O(1) bond lengths are 2.12 Å. Both Co(2)-O(3) bond lengths are 2.00 Å. Both Co(2)-O(6) bond lengths are 2.12 Å. In the third Co site, Co(3) is bonded to two equivalent O(5), two equivalent O(8), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. Both Co(3)-O(5) bond lengths are 1.99 Å. Both Co(3)-O(8) bond lengths are 2.13 Å. Both Co(3)-O(9) bond lengths are 2.15 Å. In the fourth Co site, Co(4) is bonded to one O(10), one O(3), one O(6), one O(8), and two equivalent O(9) atoms to form CoO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. The Co(4)-O(10) bond length is 1.92 Å. The Co(4)-O(3) bond length is 1.94 Å. The Co(4)-O(6) bond length is 1.98 Å. The Co(4)-O(8) bond length is 1.95 Å. There is one shorter (1.95 Å) and one longer (1.96 Å) Co(4)-O(9) bond length. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Mn(1), one Co(2), and two equivalent Co(1) atoms to form OLiMnCo3 square pyramids that share  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(1)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(5)Li2MnCo2 square pyramids, corners with two equivalent O(4)Li3Mn2 square pyramids, corners with two equivalent O(6)LiMnCo3 square pyramids, edges with two equivalent O(8)Li2MnCo3 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(1)LiMnCo3 square pyramid, and  an edgeedge with one O(6)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles are 6°. In the second O site, O(2) is bonded to one Li(1), one Li(3), two equivalent Li(2), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(2)Li4MnCo octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4Mn2 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, edges with two equivalent O(4)Li3Mn2 square pyramids, and edges with two equivalent O(1)LiMnCo3 square pyramids. The corner-sharing octahedral tilt angles range from 4-7°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Mn(1), one Co(2), and one Co(4) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(5)Li2MnCo2 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(9)LiMnCo3 square pyramid, edges with two equivalent O(4)Li3Mn2 square pyramids, edges with two equivalent O(1)LiMnCo3 square pyramids, and edges with two equivalent O(6)LiMnCo3 square pyramids. The corner-sharing octahedral tilt angles range from 0-8°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), and two equivalent Mn(1) atoms to form OLi3Mn2 square pyramids that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid, corners with two equivalent O(5)Li2MnCo2 square pyramids, corners with two equivalent O(1)LiMnCo3 square pyramids,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(4)Li3Mn2 square pyramid, and  an edgeedge with one O(10)Li3MnCo square pyramid. The corner-sharing octahedral tilt angles range from 5-6°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), one Mn(2), one Co(1), and one Co(3) atom to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(5)Li2MnCo2 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(4)Li3Mn2 square pyramids, corners with two equivalent O(10)Li3MnCo square pyramids, corners with two equivalent O(1)LiMnCo3 square pyramids,  an edgeedge with one O(2)Li4MnCo octahedra, edges with two equivalent O(8)Li2MnCo3 octahedra, edges with two equivalent O(7)Li4Mn2 octahedra,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles are 4°. In the sixth O site, O(6) is bonded to one Li(2), one Mn(2), one Co(1), one Co(2), and one Co(4) atom to form OLiMnCo3 square pyramids that share  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(10)Li3MnCo square pyramids, corners with two equivalent O(1)LiMnCo3 square pyramids,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4MnCo octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(1)LiMnCo3 square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles range from 0-9°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), and two equivalent Mn(2) atoms to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(1)LiMnCo3 square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(2)Li4MnCo octahedra,  an edgeedge with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid,  an edgeedge with one O(9)LiMnCo3 square pyramid, edges with two equivalent O(5)Li2MnCo2 square pyramids, and edges with two equivalent O(10)Li3MnCo square pyramids. The corner-sharing octahedral tilt angles are 8°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Mn(1), one Co(1), one Co(3), and one Co(4) atom to form OLi2MnCo3 octahedra that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4MnCo octahedra,  an edgeedge with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, edges with two equivalent O(5)Li2MnCo2 square pyramids, edges with two equivalent O(1)LiMnCo3 square pyramids, and edges with two equivalent O(9)LiMnCo3 square pyramids. The corner-sharing octahedral tilt angles range from 0-6°. In the ninth O site, O(9) is bonded to one Li(1), one Mn(2), one Co(3), and two equivalent Co(4) atoms to form OLiMnCo3 square pyramids that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(5)Li2MnCo2 square pyramid,  a cornercorner with one O(10)Li3MnCo square pyramid,  a cornercorner with one O(1)LiMnCo3 square pyramid,  a cornercorner with one O(6)LiMnCo3 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4Mn2 octahedra, edges with two equivalent O(8)Li2MnCo3 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(10)Li3MnCo square pyramid,  an edgeedge with one O(6)LiMnCo3 square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles range from 1-6°. In the tenth O site, O(10) is bonded to one Li(3), two equivalent Li(4), one Mn(2), and one Co(4) atom to form OLi3MnCo square pyramids that share  a cornercorner with one O(8)Li2MnCo3 octahedra,  a cornercorner with one O(7)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4MnCo octahedra,  a cornercorner with one O(4)Li3Mn2 square pyramid,  a cornercorner with one O(9)LiMnCo3 square pyramid, corners with two equivalent O(5)Li2MnCo2 square pyramids, corners with two equivalent O(6)LiMnCo3 square pyramids,  an edgeedge with one O(8)Li2MnCo3 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4Mn2 octahedra,  an edgeedge with one O(5)Li2MnCo2 square pyramid,  an edgeedge with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(10)Li3MnCo square pyramid, and  an edgeedge with one O(9)LiMnCo3 square pyramid. The corner-sharing octahedral tilt angles range from 4-8°.