SbRe2O6 crystallizes in the monoclinic C2/c space group. Re(1) is bonded to one O(1), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 34-43°. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Re(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms.
SbRe2O6 crystallizes in the monoclinic C2/c space group. Re(1) is bonded to one O(1), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 34-43°. The Re(1)-O(1) bond length is 2.03 Å. There is one shorter (1.92 Å) and one longer (1.93 Å) Re(1)-O(2) bond length. There are a spread of Re(1)-O(3) bond distances ranging from 1.96-2.03 Å. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (2.02 Å) and two longer (2.19 Å) Sb(1)-O(1) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Re(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms.