KNaPtC4N4H6O3 crystallizes in the monoclinic Cc space group. K(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(2), and one O(3) atom. Na(1) is bonded in a 5-coordinate geometry to one N(1), one N(4), one O(2), and two equivalent O(1) atoms. Pt(1) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Pt(1) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Pt(1) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(4) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one K(1), one Na(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one K(1), one H(5), and one H(6) atom.
KNaPtC4N4H6O3 crystallizes in the monoclinic Cc space group. K(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(2), and one O(3) atom. The K(1)-N(1) bond length is 2.91 Å. The K(1)-N(2) bond length is 2.91 Å. The K(1)-N(3) bond length is 2.87 Å. The K(1)-N(4) bond length is 2.92 Å. The K(1)-O(2) bond length is 2.77 Å. The K(1)-O(3) bond length is 3.08 Å. Na(1) is bonded in a 5-coordinate geometry to one N(1), one N(4), one O(2), and two equivalent O(1) atoms. The Na(1)-N(1) bond length is 2.54 Å. The Na(1)-N(4) bond length is 2.41 Å. The Na(1)-O(2) bond length is 2.40 Å. Both Na(1)-O(1) bond lengths are 2.45 Å. Pt(1) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), one C(3), and one C(4) atom. The Pt(1)-C(1) bond length is 1.99 Å. The Pt(1)-C(2) bond length is 1.99 Å. The Pt(1)-C(3) bond length is 1.99 Å. The Pt(1)-C(4) bond length is 1.99 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. The C(2)-N(2) bond length is 1.18 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one Pt(1) and one N(3) atom. The C(3)-N(3) bond length is 1.17 Å. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Pt(1) and one N(4) atom. The C(4)-N(4) bond length is 1.17 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(4) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.98 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one K(1), one Na(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one K(1), one H(5), and one H(6) atom.