Li4VO3F2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li4VO3F2 cluster. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted linear geometry to one O(3) and one F(4) atom. In the second Li site, Li(2) is bonded in a distorted bent 150 degrees geometry to one O(2) and one O(5) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one O(1) and one O(6) atom. In the fourth Li site, Li(4) is bonded in a distorted bent 150 degrees geometry to one O(1) and one F(2) atom. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to one O(2) and one F(3) atom. In the sixth Li site, Li(6) is bonded in a distorted single-bond geometry to one O(3) atom. In the seventh Li site, Li(7) is bonded in a distorted linear geometry to one O(4) and one O(6) atom. In the eighth Li site, Li(8) is bonded in a distorted linear geometry to one F(1) and one F(3) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted linear geometry to one O(4) and one F(1) atom. In the second V site, V(2) is bonded in a linear geometry to one F(2) and one F(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Li(3) and one Li(4) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Li(2) and one Li(5) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one Li(6) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Li(7) and one V(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Li(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Li(3) and one Li(7) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted linear geometry to one Li(8) and one V(1) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Li(4) and one V(2) atom. In the third F site, F(3) is bonded in a 2-coordinate geometry to one Li(5) and one Li(8) atom. In the fourth F site, F(4) is bonded in a distorted linear geometry to one Li(1) and one V(2) atom.
Li4VO3F2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Li4VO3F2 cluster. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted linear geometry to one O(3) and one F(4) atom. The Li(1)-O(3) bond length is 1.76 Å. The Li(1)-F(4) bond length is 1.58 Å. In the second Li site, Li(2) is bonded in a distorted bent 150 degrees geometry to one O(2) and one O(5) atom. The Li(2)-O(2) bond length is 1.14 Å. The Li(2)-O(5) bond length is 1.31 Å. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one O(1) and one O(6) atom. The Li(3)-O(1) bond length is 1.49 Å. The Li(3)-O(6) bond length is 1.80 Å. In the fourth Li site, Li(4) is bonded in a distorted bent 150 degrees geometry to one O(1) and one F(2) atom. The Li(4)-O(1) bond length is 1.42 Å. The Li(4)-F(2) bond length is 1.48 Å. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to one O(2) and one F(3) atom. The Li(5)-O(2) bond length is 1.88 Å. The Li(5)-F(3) bond length is 1.43 Å. In the sixth Li site, Li(6) is bonded in a distorted single-bond geometry to one O(3) atom. The Li(6)-O(3) bond length is 1.24 Å. In the seventh Li site, Li(7) is bonded in a distorted linear geometry to one O(4) and one O(6) atom. The Li(7)-O(4) bond length is 1.45 Å. The Li(7)-O(6) bond length is 1.51 Å. In the eighth Li site, Li(8) is bonded in a distorted linear geometry to one F(1) and one F(3) atom. The Li(8)-F(1) bond length is 1.41 Å. The Li(8)-F(3) bond length is 1.65 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted linear geometry to one O(4) and one F(1) atom. The V(1)-O(4) bond length is 1.35 Å. The V(1)-F(1) bond length is 1.62 Å. In the second V site, V(2) is bonded in a linear geometry to one F(2) and one F(4) atom. The V(2)-F(2) bond length is 1.31 Å. The V(2)-F(4) bond length is 1.54 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Li(3) and one Li(4) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Li(2) and one Li(5) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one Li(6) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Li(7) and one V(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Li(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Li(3) and one Li(7) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted linear geometry to one Li(8) and one V(1) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Li(4) and one V(2) atom. In the third F site, F(3) is bonded in a 2-coordinate geometry to one Li(5) and one Li(8) atom. In the fourth F site, F(4) is bonded in a distorted linear geometry to one Li(1) and one V(2) atom.