H5O2(H2O)4(HClO4)2H5O6ClClO4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one hypochlorous acid;trihydrate molecule, two hypochlorous acid;trihydrate molecules, one molecular hydrogen;dihydrate molecule, four water molecules, and one H5O6Cl cluster. In the H5O6Cl cluster, there are five inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one O(15) and one O(19) atom. In the second H site, H(12) is bonded in a linear geometry to one O(19) and one O(23) atom. In the third H site, H(11) is bonded in a single-bond geometry to one O(19) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one O(23) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one O(23) atom. There are six inequivalent O sites. In the first O site, O(9) is bonded in a distorted single-bond geometry to one Cl(1) atom. In the second O site, O(15) is bonded in a distorted bent 120 degrees geometry to one H(6) and one Cl(1) atom. In the third O site, O(19) is bonded in a trigonal non-coplanar geometry to one H(11), one H(12), and one H(6) atom. In the fourth O site, O(23) is bonded in a trigonal non-coplanar geometry to one H(12), one H(17), and one H(18) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(15), one O(5), and one O(9) atom.
H5O2(H2O)4(HClO4)2H5O6ClClO4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one hypochlorous acid;trihydrate molecule, two hypochlorous acid;trihydrate molecules, one molecular hydrogen;dihydrate molecule, four water molecules, and one H5O6Cl cluster. In the H5O6Cl cluster, there are five inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one O(15) and one O(19) atom. The H(6)-O(15) bond length is 1.71 Å. The H(6)-O(19) bond length is 1.00 Å. In the second H site, H(12) is bonded in a linear geometry to one O(19) and one O(23) atom. The H(12)-O(19) bond length is 1.20 Å. The H(12)-O(23) bond length is 1.24 Å. In the third H site, H(11) is bonded in a single-bond geometry to one O(19) atom. The H(11)-O(19) bond length is 0.99 Å. In the fourth H site, H(17) is bonded in a single-bond geometry to one O(23) atom. The H(17)-O(23) bond length is 0.99 Å. In the fifth H site, H(18) is bonded in a single-bond geometry to one O(23) atom. The H(18)-O(23) bond length is 0.98 Å. There are six inequivalent O sites. In the first O site, O(9) is bonded in a distorted single-bond geometry to one Cl(1) atom. The O(9)-Cl(1) bond length is 1.46 Å. In the second O site, O(15) is bonded in a distorted bent 120 degrees geometry to one H(6) and one Cl(1) atom. The O(15)-Cl(1) bond length is 1.47 Å. In the third O site, O(19) is bonded in a trigonal non-coplanar geometry to one H(11), one H(12), and one H(6) atom. In the fourth O site, O(23) is bonded in a trigonal non-coplanar geometry to one H(12), one H(17), and one H(18) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. The O(1)-Cl(1) bond length is 1.49 Å. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(1) atom. The O(5)-Cl(1) bond length is 1.45 Å. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(15), one O(5), and one O(9) atom.