CsPdCl3 crystallizes in the orthorhombic Ibam space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms. Pd(1) is bonded in a rectangular see-saw-like geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted L-shaped geometry to two equivalent Cs(1) and two equivalent Pd(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Pd(1) atom. In the third Cl site, Cl(3) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pd(1) atom.
CsPdCl3 crystallizes in the orthorhombic Ibam space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms. Both Cs(1)-Cl(1) bond lengths are 3.78 Å. There are two shorter (3.60 Å) and two longer (3.68 Å) Cs(1)-Cl(2) bond lengths. There are two shorter (3.56 Å) and two longer (3.72 Å) Cs(1)-Cl(3) bond lengths. Pd(1) is bonded in a rectangular see-saw-like geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. The Pd(1)-Cl(2) bond length is 2.28 Å. The Pd(1)-Cl(3) bond length is 2.29 Å. There is one shorter (2.33 Å) and one longer (2.34 Å) Pd(1)-Cl(1) bond length. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted L-shaped geometry to two equivalent Cs(1) and two equivalent Pd(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Pd(1) atom. In the third Cl site, Cl(3) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pd(1) atom.