Mg(O6I)2(O2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and two Mg(O6I)2 clusters. In each Mg(O6I)2 cluster, Mg(1) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(7) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one I(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mg(1) and one I(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. In the sixth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one O(1) atom. I(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom.
Mg(O6I)2(O2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and two Mg(O6I)2 clusters. In each Mg(O6I)2 cluster, Mg(1) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(7) atoms. Both Mg(1)-O(4) bond lengths are 1.89 Å. Both Mg(1)-O(7) bond lengths are 2.30 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(7) atom. The O(1)-O(7) bond length is 1.23 Å. In the second O site, O(2) is bonded in a single-bond geometry to one I(1) atom. The O(2)-I(1) bond length is 1.79 Å. In the third O site, O(3) is bonded in a single-bond geometry to one I(1) atom. The O(3)-I(1) bond length is 1.79 Å. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mg(1) and one I(1) atom. The O(4)-I(1) bond length is 1.85 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. The O(5)-I(1) bond length is 1.78 Å. In the sixth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one O(1) atom. I(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom.