WPO2 crystallizes in the tetragonal I4_1/amd space group. The structure consists of a WPO2 framework. W(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. P(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one P(1) atom.
WPO2 crystallizes in the tetragonal I4_1/amd space group. The structure consists of a WPO2 framework. W(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. All W(1)-O(1) bond lengths are 2.19 Å. P(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both P(1)-O(1) bond lengths are 1.83 Å. O(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one P(1) atom.