K2VCo6Cu2As5O24 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(5), and one O(6) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(16), one O(7), one O(8), and one O(9) atom. V(1) is bonded to one O(15), one O(22), one O(3), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 36-62°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(16), one O(17), one O(3), one O(5), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra, corners with two equivalent As(4)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(5)O6 pentagonal pyramid. In the second Co site, Co(2) is bonded to one O(10), one O(15), one O(18), one O(2), one O(4), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra, corners with two equivalent As(5)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(5)O6 pentagonal pyramid. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(14), one O(19), one O(3), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(6)O6 pentagonal pyramid. In the fourth Co site, Co(4) is bonded to one O(12), one O(13), one O(2), one O(20), one O(4), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent As(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(6)O6 pentagonal pyramid. In the fifth Co site, Co(5) is bonded to one O(10), one O(21), one O(22), one O(5), one O(6), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent As(1)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(11), one O(12), one O(23), one O(24), one O(7), and one O(8) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent As(2)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one O(17), one O(18), one O(21), and one O(22) atom. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to one O(19), one O(20), one O(23), and one O(24) atom. There are five inequivalent As sites. In the first As site, As(1) is bonded to one O(10), one O(19), one O(20), and one O(9) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, and corners with two equivalent Co(5)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 60-62°. In the second As site, As(2) is bonded to one O(11), one O(12), one O(17), and one O(18) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, and corners with two equivalent Co(6)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 60-62°. In the third As site, As(3) is bonded to one O(16), one O(21), one O(4), and one O(8) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 38-61°. In the fourth As site, As(4) is bonded to one O(1), one O(13), one O(24), and one O(5) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 38-61°. In the fifth As site, As(5) is bonded to one O(14), one O(2), one O(23), and one O(6) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 38-61°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(3), and one As(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(4), and one As(5) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one Co(1), and one Co(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(4), and one As(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Co(1), one Co(5), and one As(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one K(1), one Co(2), one Co(5), and one As(5) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(2), one V(1), one Co(3), and one Co(6) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(2), one Co(4), one Co(6), and one As(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one K(2), one Co(1), one Co(5), and one As(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one K(2), one Co(2), one Co(5), and one As(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one K(1), one Co(3), one Co(6), and one As(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one K(1), one Co(4), one Co(6), and one As(2) atom. In the thirteenth O site, O(13) is bonded to one K(1), one K(2), one Co(4), and one As(4) atom to form distorted corner-sharing OK2CoAs trigonal pyramids. In the fourteenth O site, O(14) is bonded to one K(1), one K(2), one Co(3), and one As(5) atom to form a mixture of distorted corner and edge-sharing OK2CoAs trigonal pyramids. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one K(1), one K(2), one V(1), and one Co(2) atom. In the sixteenth O site, O(16) is bonded to one K(1), one K(2), one Co(1), and one As(3) atom to form a mixture of distorted corner and edge-sharing OK2CoAs trigonal pyramids. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Co(1), one Cu(1), and one As(2) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Co(2), one Cu(1), and one As(2) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Co(3), one Cu(2), and one As(1) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Co(4), one Cu(2), and one As(1) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Co(5), one Cu(1), and one As(3) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one V(1), one Co(5), and one Cu(1) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Co(6), one Cu(2), and one As(5) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Co(6), one Cu(2), and one As(4) atom.
K2VCo6Cu2As5O24 crystallizes in the triclinic P1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(5), and one O(6) atom. The K(1)-O(11) bond length is 2.93 Å. The K(1)-O(12) bond length is 2.93 Å. The K(1)-O(13) bond length is 2.67 Å. The K(1)-O(14) bond length is 2.67 Å. The K(1)-O(15) bond length is 2.72 Å. The K(1)-O(16) bond length is 2.69 Å. The K(1)-O(5) bond length is 3.00 Å. The K(1)-O(6) bond length is 2.99 Å. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(16), one O(7), one O(8), and one O(9) atom. The K(2)-O(10) bond length is 2.94 Å. The K(2)-O(13) bond length is 2.70 Å. The K(2)-O(14) bond length is 2.69 Å. The K(2)-O(15) bond length is 2.67 Å. The K(2)-O(16) bond length is 2.67 Å. The K(2)-O(7) bond length is 2.97 Å. The K(2)-O(8) bond length is 2.99 Å. The K(2)-O(9) bond length is 2.94 Å. V(1) is bonded to one O(15), one O(22), one O(3), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 36-62°. The V(1)-O(15) bond length is 1.72 Å. The V(1)-O(22) bond length is 1.76 Å. The V(1)-O(3) bond length is 1.76 Å. The V(1)-O(7) bond length is 1.76 Å. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(16), one O(17), one O(3), one O(5), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra, corners with two equivalent As(4)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(5)O6 pentagonal pyramid. The Co(1)-O(1) bond length is 2.18 Å. The Co(1)-O(16) bond length is 2.04 Å. The Co(1)-O(17) bond length is 2.07 Å. The Co(1)-O(3) bond length is 2.09 Å. The Co(1)-O(5) bond length is 2.16 Å. The Co(1)-O(9) bond length is 2.18 Å. In the second Co site, Co(2) is bonded to one O(10), one O(15), one O(18), one O(2), one O(4), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra, corners with two equivalent As(5)O4 tetrahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(5)O6 pentagonal pyramid. The Co(2)-O(10) bond length is 2.17 Å. The Co(2)-O(15) bond length is 2.03 Å. The Co(2)-O(18) bond length is 2.08 Å. The Co(2)-O(2) bond length is 2.19 Å. The Co(2)-O(4) bond length is 2.09 Å. The Co(2)-O(6) bond length is 2.14 Å. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(14), one O(19), one O(3), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(6)O6 pentagonal pyramid. The Co(3)-O(1) bond length is 2.10 Å. The Co(3)-O(11) bond length is 2.17 Å. The Co(3)-O(14) bond length is 2.04 Å. The Co(3)-O(19) bond length is 2.08 Å. The Co(3)-O(3) bond length is 2.15 Å. The Co(3)-O(7) bond length is 2.14 Å. In the fourth Co site, Co(4) is bonded to one O(12), one O(13), one O(2), one O(20), one O(4), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent As(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(6)O6 pentagonal pyramid. The Co(4)-O(12) bond length is 2.17 Å. The Co(4)-O(13) bond length is 2.05 Å. The Co(4)-O(2) bond length is 2.09 Å. The Co(4)-O(20) bond length is 2.08 Å. The Co(4)-O(4) bond length is 2.18 Å. The Co(4)-O(8) bond length is 2.15 Å. In the fifth Co site, Co(5) is bonded to one O(10), one O(21), one O(22), one O(5), one O(6), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent As(1)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The Co(5)-O(10) bond length is 2.21 Å. The Co(5)-O(21) bond length is 2.12 Å. The Co(5)-O(22) bond length is 2.12 Å. The Co(5)-O(5) bond length is 2.14 Å. The Co(5)-O(6) bond length is 2.13 Å. The Co(5)-O(9) bond length is 2.21 Å. In the sixth Co site, Co(6) is bonded to one O(11), one O(12), one O(23), one O(24), one O(7), and one O(8) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one As(3)O4 tetrahedra,  a cornercorner with one As(4)O4 tetrahedra,  a cornercorner with one As(5)O4 tetrahedra, corners with two equivalent As(2)O4 tetrahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. The Co(6)-O(11) bond length is 2.21 Å. The Co(6)-O(12) bond length is 2.23 Å. The Co(6)-O(23) bond length is 2.10 Å. The Co(6)-O(24) bond length is 2.10 Å. The Co(6)-O(7) bond length is 2.12 Å. The Co(6)-O(8) bond length is 2.16 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one O(17), one O(18), one O(21), and one O(22) atom. The Cu(1)-O(17) bond length is 1.96 Å. The Cu(1)-O(18) bond length is 1.97 Å. The Cu(1)-O(21) bond length is 1.95 Å. The Cu(1)-O(22) bond length is 1.92 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to one O(19), one O(20), one O(23), and one O(24) atom. The Cu(2)-O(19) bond length is 1.96 Å. The Cu(2)-O(20) bond length is 1.96 Å. The Cu(2)-O(23) bond length is 1.95 Å. The Cu(2)-O(24) bond length is 1.95 Å. There are five inequivalent As sites. In the first As site, As(1) is bonded to one O(10), one O(19), one O(20), and one O(9) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, and corners with two equivalent Co(5)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 60-62°. The As(1)-O(10) bond length is 1.73 Å. The As(1)-O(19) bond length is 1.75 Å. The As(1)-O(20) bond length is 1.75 Å. The As(1)-O(9) bond length is 1.73 Å. In the second As site, As(2) is bonded to one O(11), one O(12), one O(17), and one O(18) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, and corners with two equivalent Co(6)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 60-62°. The As(2)-O(11) bond length is 1.73 Å. The As(2)-O(12) bond length is 1.73 Å. The As(2)-O(17) bond length is 1.75 Å. The As(2)-O(18) bond length is 1.75 Å. In the third As site, As(3) is bonded to one O(16), one O(21), one O(4), and one O(8) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 38-61°. The As(3)-O(16) bond length is 1.71 Å. The As(3)-O(21) bond length is 1.74 Å. The As(3)-O(4) bond length is 1.73 Å. The As(3)-O(8) bond length is 1.74 Å. In the fourth As site, As(4) is bonded to one O(1), one O(13), one O(24), and one O(5) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 38-61°. The As(4)-O(1) bond length is 1.73 Å. The As(4)-O(13) bond length is 1.70 Å. The As(4)-O(24) bond length is 1.74 Å. The As(4)-O(5) bond length is 1.74 Å. In the fifth As site, As(5) is bonded to one O(14), one O(2), one O(23), and one O(6) atom to form AsO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 pentagonal pyramid, and  a cornercorner with one Co(6)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 38-61°. The As(5)-O(14) bond length is 1.71 Å. The As(5)-O(2) bond length is 1.73 Å. The As(5)-O(23) bond length is 1.74 Å. The As(5)-O(6) bond length is 1.74 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(3), and one As(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(4), and one As(5) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one Co(1), and one Co(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(4), and one As(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Co(1), one Co(5), and one As(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one K(1), one Co(2), one Co(5), and one As(5) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(2), one V(1), one Co(3), and one Co(6) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(2), one Co(4), one Co(6), and one As(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one K(2), one Co(1), one Co(5), and one As(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one K(2), one Co(2), one Co(5), and one As(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one K(1), one Co(3), one Co(6), and one As(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one K(1), one Co(4), one Co(6), and one As(2) atom. In the thirteenth O site, O(13) is bonded to one K(1), one K(2), one Co(4), and one As(4) atom to form distorted corner-sharing OK2CoAs trigonal pyramids. In the fourteenth O site, O(14) is bonded to one K(1), one K(2), one Co(3), and one As(5) atom to form a mixture of distorted corner and edge-sharing OK2CoAs trigonal pyramids. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one K(1), one K(2), one V(1), and one Co(2) atom. In the sixteenth O site, O(16) is bonded to one K(1), one K(2), one Co(1), and one As(3) atom to form a mixture of distorted corner and edge-sharing OK2CoAs trigonal pyramids. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Co(1), one Cu(1), and one As(2) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Co(2), one Cu(1), and one As(2) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Co(3), one Cu(2), and one As(1) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Co(4), one Cu(2), and one As(1) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Co(5), one Cu(1), and one As(3) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one V(1), one Co(5), and one Cu(1) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Co(6), one Cu(2), and one As(5) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Co(6), one Cu(2), and one As(4) atom.