(CH3NH3)2SiF6 is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of four methylammonium molecules and two SiF6 clusters. In each SiF6 cluster, Si(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom.
(CH3NH3)2SiF6 is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of four methylammonium molecules and two SiF6 clusters. In each SiF6 cluster, Si(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. Both Si(1)-F(1) bond lengths are 1.72 Å. All Si(1)-F(2) bond lengths are 1.72 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom.