RbAgF3 crystallizes in the orthorhombic Cmmm space group. Rb(1) is bonded in a 2-coordinate geometry to two equivalent F(2) atoms. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted linear geometry to two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted square co-planar geometry to two equivalent Rb(1) and two equivalent Ag(1) atoms.
RbAgF3 crystallizes in the orthorhombic Cmmm space group. Rb(1) is bonded in a 2-coordinate geometry to two equivalent F(2) atoms. Both Rb(1)-F(2) bond lengths are 2.63 Å. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedra are not tilted. Both Ag(1)-F(2) bond lengths are 2.18 Å. All Ag(1)-F(1) bond lengths are 2.15 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted linear geometry to two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted square co-planar geometry to two equivalent Rb(1) and two equivalent Ag(1) atoms.