CrO2 is trigonal omega-like structured and crystallizes in the cubic Fd-3m space group. Cr(1) is bonded to six equivalent O(1) atoms to form edge-sharing CrO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Cr(1) atoms.
CrO2 is trigonal omega-like structured and crystallizes in the cubic Fd-3m space group. Cr(1) is bonded to six equivalent O(1) atoms to form edge-sharing CrO6 octahedra. All Cr(1)-O(1) bond lengths are 1.95 Å. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Cr(1) atoms.