LiScF2 crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. Sc(1) is bonded to six equivalent F(1) atoms to form distorted edge-sharing ScF6 octahedra. F(1) is bonded in a 5-coordinate geometry to two equivalent Li(1) and three equivalent Sc(1) atoms.
LiScF2 crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All Li(1)-F(1) bond lengths are 2.26 Å. Sc(1) is bonded to six equivalent F(1) atoms to form distorted edge-sharing ScF6 octahedra. There are four shorter (2.26 Å) and two longer (2.28 Å) Sc(1)-F(1) bond lengths. F(1) is bonded in a 5-coordinate geometry to two equivalent Li(1) and three equivalent Sc(1) atoms.