CPH3S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CPH3S3 clusters. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(2) atom. P(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form edge-sharing PS4 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to two equivalent P(1) atoms.
CPH3S3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CPH3S3 clusters. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(2) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-S(2) bond length is 1.81 Å. P(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form edge-sharing PS4 tetrahedra. The P(1)-S(1) bond length is 1.93 Å. The P(1)-S(2) bond length is 2.08 Å. There is one shorter (2.14 Å) and one longer (2.15 Å) P(1)-S(3) bond length. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to two equivalent P(1) atoms.