Tl3TaS4Tl3VS4 crystallizes in the cubic P-43m space group. The structure consists of one Tl3TaS4 framework and one Tl3VS4 framework. In the Tl3TaS4 framework, Ta(1) is bonded in a tetrahedral geometry to four equivalent S(2) atoms. Tl(1) is bonded in a 4-coordinate geometry to four equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one Ta(1) and three equivalent Tl(1) atoms. In the Tl3VS4 framework, V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Tl(2) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a distorted single-bond geometry to one V(1) and three equivalent Tl(2) atoms.
Tl3TaS4Tl3VS4 crystallizes in the cubic P-43m space group. The structure consists of one Tl3TaS4 framework and one Tl3VS4 framework. In the Tl3TaS4 framework, Ta(1) is bonded in a tetrahedral geometry to four equivalent S(2) atoms. All Ta(1)-S(2) bond lengths are 2.29 Å. Tl(1) is bonded in a 4-coordinate geometry to four equivalent S(2) atoms. All Tl(1)-S(2) bond lengths are 3.17 Å. S(2) is bonded in a distorted single-bond geometry to one Ta(1) and three equivalent Tl(1) atoms. In the Tl3VS4 framework, V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All V(1)-S(1) bond lengths are 2.17 Å. Tl(2) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All Tl(2)-S(1) bond lengths are 3.17 Å. S(1) is bonded in a distorted single-bond geometry to one V(1) and three equivalent Tl(2) atoms.