LiSrN crystallizes in the tetragonal P4_2/mmc space group. Li(1) is bonded in a linear geometry to two equivalent N(1) atoms. Sr(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing SrN4 tetrahedra. N(1) is bonded to two equivalent Li(1) and four equivalent Sr(1) atoms to form a mixture of corner and edge-sharing NSr4Li2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°.
LiSrN crystallizes in the tetragonal P4_2/mmc space group. Li(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Li(1)-N(1) bond lengths are 1.96 Å. Sr(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing SrN4 tetrahedra. All Sr(1)-N(1) bond lengths are 2.64 Å. N(1) is bonded to two equivalent Li(1) and four equivalent Sr(1) atoms to form a mixture of corner and edge-sharing NSr4Li2 octahedra. The corner-sharing octahedral tilt angles range from 0-63°.