Zn(MoO2)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(4), and one O(6) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra, corners with two equivalent Mo(9)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 trigonal pyramid,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Mo(4)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the second Mo site, Mo(2) is bonded to one O(11), one O(2), one O(5), and one O(9) atom to form distorted MoO4 trigonal pyramids that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(7)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, and corners with three equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-72°. In the third Mo site, Mo(3) is bonded to one O(1), one O(21), one O(22), one O(24), one O(3), and one O(4) atom to form MoO6 octahedra that share corners with three equivalent Mo(12)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra,  an edgeedge with one Mo(8)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, and  an edgeedge with one Zn(6)O6 octahedra. In the fourth Mo site, Mo(4) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra, corners with two equivalent Mo(9)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 trigonal pyramid,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the fifth Mo site, Mo(5) is bonded to one O(11), one O(14), one O(18), one O(20), one O(5), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(6)O4 tetrahedra,  a cornercorner with one Mo(9)O4 tetrahedra, corners with two equivalent Mo(11)O4 tetrahedra, corners with two equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(7)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. In the sixth Mo site, Mo(6) is bonded to one O(13), one O(16), one O(19), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(7)O6 octahedra,  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, and corners with three equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-66°. In the seventh Mo site, Mo(7) is bonded to one O(11), one O(14), one O(15), one O(18), one O(7), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(6)O4 tetrahedra,  a cornercorner with one Mo(9)O4 tetrahedra, corners with two equivalent Mo(11)O4 tetrahedra, corners with two equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(5)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. In the eighth Mo site, Mo(8) is bonded to one O(13), one O(17), one O(19), one O(21), one O(23), and one O(24) atom to form MoO6 octahedra that share  a cornercorner with one Mo(11)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. In the ninth Mo site, Mo(9) is bonded to one O(12), one O(18), one O(6), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(7)O6 octahedra,  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, and corners with three equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the tenth Mo site, Mo(10) is bonded to one O(16), one O(17), one O(19), one O(21), one O(22), and one O(23) atom to form MoO6 octahedra that share  a cornercorner with one Mo(11)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(8)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. In the eleventh Mo site, Mo(11) is bonded to one O(14), one O(15), one O(20), and one O(23) atom to form distorted MoO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra,  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(7)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, and corners with three equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-71°. In the twelfth Mo site, Mo(12) is bonded to one O(10), one O(21), one O(22), and one O(24) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, and corners with three equivalent Mo(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-67°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(17), one O(3), and one O(4) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra,  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, and corners with three equivalent Mo(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-62°. In the second Zn site, Zn(2) is bonded to one O(11), one O(12), one O(5), one O(6), one O(8), and one O(9) atom to form ZnO6 octahedra that share corners with three equivalent Mo(9)O4 tetrahedra, corners with three equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra,  an edgeedge with one Mo(7)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, and  an edgeedge with one Zn(5)O6 octahedra. In the third Zn site, Zn(3) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(8) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra, corners with two equivalent Mo(9)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 trigonal pyramid,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(4)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(13), one O(14), one O(15), one O(16), one O(19), and one O(20) atom to form ZnO6 octahedra that share corners with three equivalent Mo(11)O4 tetrahedra, corners with three equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra,  an edgeedge with one Mo(7)O6 octahedra,  an edgeedge with one Mo(8)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, and  an edgeedge with one Zn(6)O6 octahedra. In the fifth Zn site, Zn(5) is bonded to one O(15), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form distorted ZnO6 octahedra that share  a cornercorner with one Mo(6)O4 tetrahedra,  a cornercorner with one Mo(9)O4 tetrahedra, corners with two equivalent Mo(11)O4 tetrahedra, corners with two equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(5)O6 octahedra, and edges with two equivalent Mo(7)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(13), one O(16), one O(17), one O(22), one O(23), and one O(24) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(11)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Mo(8)O6 octahedra. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(3), one Zn(1), and one Zn(3) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Mo(4), and one Zn(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(4), one Zn(1), and one Zn(3) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(3), one Mo(4), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(5), one Zn(2), and one Zn(5) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(4), one Mo(9), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(6), one Mo(7), and one Zn(5) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Mo(4), one Mo(9), one Zn(2), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(7), one Zn(2), and one Zn(5) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(12), one Mo(4), and one Zn(3) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(5), one Mo(7), and one Zn(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(9), one Zn(2), and one Zn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Mo(6), one Mo(8), one Zn(4), and one Zn(6) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(5), one Mo(7), and one Zn(4) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(7), one Zn(4), and one Zn(5) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(6), one Zn(4), and one Zn(6) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(8), one Zn(1), and one Zn(6) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(7), one Mo(9), and one Zn(5) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(6), one Mo(8), and one Zn(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(5), one Zn(4), and one Zn(5) atom. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(12), one Mo(3), and one Mo(8) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(12), one Mo(3), and one Zn(6) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(8), and one Zn(6) atom. In the twenty-fourth O site, O(24) is bonded in a rectangular see-saw-like geometry to one Mo(12), one Mo(3), one Mo(8), and one Zn(6) atom.
Zn(MoO2)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(4), and one O(6) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra, corners with two equivalent Mo(9)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 trigonal pyramid,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Mo(4)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. The Mo(1)-O(1) bond length is 2.15 Å. The Mo(1)-O(10) bond length is 2.19 Å. The Mo(1)-O(12) bond length is 2.19 Å. The Mo(1)-O(2) bond length is 2.16 Å. The Mo(1)-O(4) bond length is 2.20 Å. The Mo(1)-O(6) bond length is 2.22 Å. In the second Mo site, Mo(2) is bonded to one O(11), one O(2), one O(5), and one O(9) atom to form distorted MoO4 trigonal pyramids that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(7)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, and corners with three equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-72°. The Mo(2)-O(11) bond length is 2.12 Å. The Mo(2)-O(2) bond length is 2.32 Å. The Mo(2)-O(5) bond length is 2.07 Å. The Mo(2)-O(9) bond length is 2.14 Å. In the third Mo site, Mo(3) is bonded to one O(1), one O(21), one O(22), one O(24), one O(3), and one O(4) atom to form MoO6 octahedra that share corners with three equivalent Mo(12)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra,  an edgeedge with one Mo(8)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, and  an edgeedge with one Zn(6)O6 octahedra. The Mo(3)-O(1) bond length is 2.20 Å. The Mo(3)-O(21) bond length is 2.19 Å. The Mo(3)-O(22) bond length is 2.19 Å. The Mo(3)-O(24) bond length is 2.12 Å. The Mo(3)-O(3) bond length is 2.17 Å. The Mo(3)-O(4) bond length is 2.19 Å. In the fourth Mo site, Mo(4) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra, corners with two equivalent Mo(9)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 trigonal pyramid,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. The Mo(4)-O(10) bond length is 2.18 Å. The Mo(4)-O(2) bond length is 2.17 Å. The Mo(4)-O(3) bond length is 2.16 Å. The Mo(4)-O(4) bond length is 2.17 Å. The Mo(4)-O(6) bond length is 2.18 Å. The Mo(4)-O(8) bond length is 2.17 Å. In the fifth Mo site, Mo(5) is bonded to one O(11), one O(14), one O(18), one O(20), one O(5), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(6)O4 tetrahedra,  a cornercorner with one Mo(9)O4 tetrahedra, corners with two equivalent Mo(11)O4 tetrahedra, corners with two equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(7)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. The Mo(5)-O(11) bond length is 2.14 Å. The Mo(5)-O(14) bond length is 2.14 Å. The Mo(5)-O(18) bond length is 2.19 Å. The Mo(5)-O(20) bond length is 2.17 Å. The Mo(5)-O(5) bond length is 2.16 Å. The Mo(5)-O(7) bond length is 2.18 Å. In the sixth Mo site, Mo(6) is bonded to one O(13), one O(16), one O(19), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(7)O6 octahedra,  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, and corners with three equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-66°. The Mo(6)-O(13) bond length is 2.09 Å. The Mo(6)-O(16) bond length is 2.07 Å. The Mo(6)-O(19) bond length is 2.10 Å. The Mo(6)-O(7) bond length is 2.10 Å. In the seventh Mo site, Mo(7) is bonded to one O(11), one O(14), one O(15), one O(18), one O(7), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(6)O4 tetrahedra,  a cornercorner with one Mo(9)O4 tetrahedra, corners with two equivalent Mo(11)O4 tetrahedra, corners with two equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(5)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. The Mo(7)-O(11) bond length is 2.18 Å. The Mo(7)-O(14) bond length is 2.18 Å. The Mo(7)-O(15) bond length is 2.18 Å. The Mo(7)-O(18) bond length is 2.21 Å. The Mo(7)-O(7) bond length is 2.14 Å. The Mo(7)-O(9) bond length is 2.19 Å. In the eighth Mo site, Mo(8) is bonded to one O(13), one O(17), one O(19), one O(21), one O(23), and one O(24) atom to form MoO6 octahedra that share  a cornercorner with one Mo(11)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. The Mo(8)-O(13) bond length is 2.17 Å. The Mo(8)-O(17) bond length is 2.18 Å. The Mo(8)-O(19) bond length is 2.14 Å. The Mo(8)-O(21) bond length is 2.19 Å. The Mo(8)-O(23) bond length is 2.18 Å. The Mo(8)-O(24) bond length is 2.20 Å. In the ninth Mo site, Mo(9) is bonded to one O(12), one O(18), one O(6), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(7)O6 octahedra,  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, and corners with three equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. The Mo(9)-O(12) bond length is 2.02 Å. The Mo(9)-O(18) bond length is 1.98 Å. The Mo(9)-O(6) bond length is 2.01 Å. The Mo(9)-O(8) bond length is 1.97 Å. In the tenth Mo site, Mo(10) is bonded to one O(16), one O(17), one O(19), one O(21), one O(22), and one O(23) atom to form MoO6 octahedra that share  a cornercorner with one Mo(11)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(8)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. The Mo(10)-O(16) bond length is 2.16 Å. The Mo(10)-O(17) bond length is 2.20 Å. The Mo(10)-O(19) bond length is 2.16 Å. The Mo(10)-O(21) bond length is 2.22 Å. The Mo(10)-O(22) bond length is 2.21 Å. The Mo(10)-O(23) bond length is 2.18 Å. In the eleventh Mo site, Mo(11) is bonded to one O(14), one O(15), one O(20), and one O(23) atom to form distorted MoO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra,  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(7)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, and corners with three equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-71°. The Mo(11)-O(14) bond length is 2.12 Å. The Mo(11)-O(15) bond length is 2.14 Å. The Mo(11)-O(20) bond length is 2.09 Å. The Mo(11)-O(23) bond length is 2.26 Å. In the twelfth Mo site, Mo(12) is bonded to one O(10), one O(21), one O(22), and one O(24) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, and corners with three equivalent Mo(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-67°. The Mo(12)-O(10) bond length is 2.14 Å. The Mo(12)-O(21) bond length is 2.13 Å. The Mo(12)-O(22) bond length is 2.12 Å. The Mo(12)-O(24) bond length is 2.07 Å. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(17), one O(3), and one O(4) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra,  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, and corners with three equivalent Mo(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-62°. The Zn(1)-O(1) bond length is 2.10 Å. The Zn(1)-O(17) bond length is 2.01 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.12 Å. In the second Zn site, Zn(2) is bonded to one O(11), one O(12), one O(5), one O(6), one O(8), and one O(9) atom to form ZnO6 octahedra that share corners with three equivalent Mo(9)O4 tetrahedra, corners with three equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra,  an edgeedge with one Mo(7)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, and  an edgeedge with one Zn(5)O6 octahedra. The Zn(2)-O(11) bond length is 2.11 Å. The Zn(2)-O(12) bond length is 2.26 Å. The Zn(2)-O(5) bond length is 2.06 Å. The Zn(2)-O(6) bond length is 2.26 Å. The Zn(2)-O(8) bond length is 2.20 Å. The Zn(2)-O(9) bond length is 2.08 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(8) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra, corners with two equivalent Mo(9)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 trigonal pyramid,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(4)O6 octahedra. The Zn(3)-O(1) bond length is 2.12 Å. The Zn(3)-O(10) bond length is 2.19 Å. The Zn(3)-O(12) bond length is 2.17 Å. The Zn(3)-O(2) bond length is 2.18 Å. The Zn(3)-O(3) bond length is 2.19 Å. The Zn(3)-O(8) bond length is 2.34 Å. In the fourth Zn site, Zn(4) is bonded to one O(13), one O(14), one O(15), one O(16), one O(19), and one O(20) atom to form ZnO6 octahedra that share corners with three equivalent Mo(11)O4 tetrahedra, corners with three equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra,  an edgeedge with one Mo(7)O6 octahedra,  an edgeedge with one Mo(8)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, and  an edgeedge with one Zn(6)O6 octahedra. The Zn(4)-O(13) bond length is 2.07 Å. The Zn(4)-O(14) bond length is 2.16 Å. The Zn(4)-O(15) bond length is 2.12 Å. The Zn(4)-O(16) bond length is 2.22 Å. The Zn(4)-O(19) bond length is 2.30 Å. The Zn(4)-O(20) bond length is 2.08 Å. In the fifth Zn site, Zn(5) is bonded to one O(15), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form distorted ZnO6 octahedra that share  a cornercorner with one Mo(6)O4 tetrahedra,  a cornercorner with one Mo(9)O4 tetrahedra, corners with two equivalent Mo(11)O4 tetrahedra, corners with two equivalent Mo(2)O4 trigonal pyramids,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(5)O6 octahedra, and edges with two equivalent Mo(7)O6 octahedra. The Zn(5)-O(15) bond length is 2.04 Å. The Zn(5)-O(18) bond length is 2.48 Å. The Zn(5)-O(20) bond length is 2.12 Å. The Zn(5)-O(5) bond length is 2.15 Å. The Zn(5)-O(7) bond length is 2.22 Å. The Zn(5)-O(9) bond length is 2.08 Å. In the sixth Zn site, Zn(6) is bonded to one O(13), one O(16), one O(17), one O(22), one O(23), and one O(24) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(11)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Mo(8)O6 octahedra. The Zn(6)-O(13) bond length is 2.13 Å. The Zn(6)-O(16) bond length is 2.08 Å. The Zn(6)-O(17) bond length is 2.22 Å. The Zn(6)-O(22) bond length is 2.14 Å. The Zn(6)-O(23) bond length is 2.22 Å. The Zn(6)-O(24) bond length is 2.24 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(3), one Zn(1), and one Zn(3) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Mo(4), and one Zn(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(4), one Zn(1), and one Zn(3) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(3), one Mo(4), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(5), one Zn(2), and one Zn(5) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(4), one Mo(9), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(6), one Mo(7), and one Zn(5) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Mo(4), one Mo(9), one Zn(2), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(7), one Zn(2), and one Zn(5) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(12), one Mo(4), and one Zn(3) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(5), one Mo(7), and one Zn(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(9), one Zn(2), and one Zn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Mo(6), one Mo(8), one Zn(4), and one Zn(6) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(5), one Mo(7), and one Zn(4) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(7), one Zn(4), and one Zn(5) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(6), one Zn(4), and one Zn(6) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(8), one Zn(1), and one Zn(6) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(7), one Mo(9), and one Zn(5) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(6), one Mo(8), and one Zn(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(5), one Zn(4), and one Zn(5) atom. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(12), one Mo(3), and one Mo(8) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(12), one Mo(3), and one Zn(6) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(8), and one Zn(6) atom. In the twenty-fourth O site, O(24) is bonded in a rectangular see-saw-like geometry to one Mo(12), one Mo(3), one Mo(8), and one Zn(6) atom.