Te(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with four equivalent Te(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted TeO6 octahedra that share corners with eight equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent W(1) atoms.
Te(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form distorted WO6 octahedra that share corners with four equivalent Te(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. The W(1)-O(1) bond length is 1.85 Å. The W(1)-O(3) bond length is 1.95 Å. There is one shorter (1.91 Å) and one longer (2.14 Å) W(1)-O(2) bond length. There is one shorter (1.93 Å) and one longer (2.03 Å) W(1)-O(4) bond length. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form distorted TeO6 octahedra that share corners with eight equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-58°. Both Te(1)-O(1) bond lengths are 2.16 Å. Both Te(1)-O(2) bond lengths are 2.61 Å. Both Te(1)-O(3) bond lengths are 1.94 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent W(1) atoms.