Zr10NiSnSb4 crystallizes in the tetragonal I422 space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to one Ni(1), one Sn(1), and four equivalent Sb(1) atoms. In the second Zr site, Zr(2) is bonded in a 6-coordinate geometry to two equivalent Zr(2) and four equivalent Sb(1) atoms. Ni(1) is bonded in a 10-coordinate geometry to eight equivalent Zr(1) and two equivalent Sn(1) atoms. Sn(1) is bonded in a 10-coordinate geometry to eight equivalent Zr(1) and two equivalent Ni(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to two equivalent Zr(2) and eight equivalent Zr(1) atoms.
Zr10NiSnSb4 crystallizes in the tetragonal I422 space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to one Ni(1), one Sn(1), and four equivalent Sb(1) atoms. The Zr(1)-Ni(1) bond length is 2.90 Å. The Zr(1)-Sn(1) bond length is 2.94 Å. There are a spread of Zr(1)-Sb(1) bond distances ranging from 2.96-3.28 Å. In the second Zr site, Zr(2) is bonded in a 6-coordinate geometry to two equivalent Zr(2) and four equivalent Sb(1) atoms. Both Zr(2)-Zr(2) bond lengths are 2.78 Å. All Zr(2)-Sb(1) bond lengths are 2.94 Å. Ni(1) is bonded in a 10-coordinate geometry to eight equivalent Zr(1) and two equivalent Sn(1) atoms. Both Ni(1)-Sn(1) bond lengths are 2.78 Å. Sn(1) is bonded in a 10-coordinate geometry to eight equivalent Zr(1) and two equivalent Ni(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to two equivalent Zr(2) and eight equivalent Zr(1) atoms.