Li11(NiO2)12 crystallizes in the monoclinic C2/m space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the third Li site, Li(3) is bonded to two equivalent O(2) and four equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with four equivalent Ni(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with four equivalent Li(2)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. In the fourth Li site, Li(4) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), two equivalent O(5), and two equivalent O(8) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the second Ni site, Ni(2) is bonded to one O(4), one O(7), two equivalent O(3), and two equivalent O(6) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with four equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the third Ni site, Ni(3) is bonded to one O(2), one O(4), one O(6), one O(8), and two equivalent O(5) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the fourth Ni site, Ni(4) is bonded to one O(1), one O(6), one O(7), one O(8), and two equivalent O(3) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(5), one Ni(1), and two equivalent Ni(4) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra, corners with two equivalent O(6)Li3Ni3 octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with four equivalent O(5)Li3Ni3 octahedra,  an edgeedge with one O(7)Li2Ni3 square pyramid, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(3), two equivalent Li(2), one Ni(1), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra, corners with two equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with four equivalent O(5)Li3Ni3 octahedra, edges with four equivalent O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li2Ni3 square pyramid, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(4), one Ni(2), and two equivalent Ni(4) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(8)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(5)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li2Ni3 square pyramids, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-5°. In the fourth O site, O(4) is bonded to one Li(1), two equivalent Li(4), one Ni(2), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra, corners with two equivalent O(5)Li3Ni3 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid, corners with two equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with four equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-3°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(5), one Ni(1), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(8)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(2)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-2°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(5), one Ni(2), one Ni(3), and one Ni(4) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(8)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with two equivalent O(2)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li2Ni3 square pyramid, and  an edgeedge with one O(8)Li2Ni3 square pyramid. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh O site, O(7) is bonded to two equivalent Li(2), one Ni(2), and two equivalent Ni(4) atoms to form OLi2Ni3 square pyramids that share  a cornercorner with one O(4)Li3Ni3 octahedra, corners with two equivalent O(5)Li3Ni3 octahedra, corners with two equivalent O(6)Li3Ni3 octahedra, corners with four equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, and edges with four equivalent O(3)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one Ni(1), one Ni(3), and one Ni(4) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra, corners with two equivalent O(7)Li2Ni3 square pyramids, corners with two equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(5)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 3-7°.
Li11(NiO2)12 crystallizes in the monoclinic C2/m space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. The Li(1)-O(1) bond length is 2.04 Å. The Li(1)-O(4) bond length is 2.14 Å. Both Li(1)-O(3) bond lengths are 2.17 Å. Both Li(1)-O(5) bond lengths are 2.11 Å. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. The Li(2)-O(2) bond length is 2.19 Å. The Li(2)-O(3) bond length is 2.16 Å. The Li(2)-O(5) bond length is 2.10 Å. The Li(2)-O(6) bond length is 2.17 Å. The Li(2)-O(7) bond length is 2.06 Å. The Li(2)-O(8) bond length is 2.12 Å. In the third Li site, Li(3) is bonded to two equivalent O(2) and four equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with four equivalent Ni(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with four equivalent Li(2)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. Both Li(3)-O(2) bond lengths are 2.06 Å. All Li(3)-O(6) bond lengths are 2.10 Å. In the fourth Li site, Li(4) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. Both Li(4)-O(3) bond lengths are 2.13 Å. Both Li(4)-O(4) bond lengths are 2.16 Å. Both Li(4)-O(8) bond lengths are 2.07 Å. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. Both Li(5)-O(1) bond lengths are 2.20 Å. Both Li(5)-O(5) bond lengths are 2.15 Å. Both Li(5)-O(6) bond lengths are 2.10 Å. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), two equivalent O(5), and two equivalent O(8) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. The Ni(1)-O(1) bond length is 2.02 Å. The Ni(1)-O(2) bond length is 2.02 Å. Both Ni(1)-O(5) bond lengths are 2.07 Å. Both Ni(1)-O(8) bond lengths are 2.06 Å. In the second Ni site, Ni(2) is bonded to one O(4), one O(7), two equivalent O(3), and two equivalent O(6) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and edges with four equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. The Ni(2)-O(4) bond length is 1.89 Å. The Ni(2)-O(7) bond length is 1.86 Å. Both Ni(2)-O(3) bond lengths are 2.01 Å. Both Ni(2)-O(6) bond lengths are 2.01 Å. In the third Ni site, Ni(3) is bonded to one O(2), one O(4), one O(6), one O(8), and two equivalent O(5) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. The Ni(3)-O(2) bond length is 1.93 Å. The Ni(3)-O(4) bond length is 2.03 Å. The Ni(3)-O(6) bond length is 1.91 Å. The Ni(3)-O(8) bond length is 1.90 Å. There is one shorter (1.92 Å) and one longer (2.03 Å) Ni(3)-O(5) bond length. In the fourth Ni site, Ni(4) is bonded to one O(1), one O(6), one O(7), one O(8), and two equivalent O(3) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. The Ni(4)-O(1) bond length is 1.96 Å. The Ni(4)-O(6) bond length is 2.05 Å. The Ni(4)-O(7) bond length is 2.06 Å. The Ni(4)-O(8) bond length is 1.91 Å. There is one shorter (1.92 Å) and one longer (1.97 Å) Ni(4)-O(3) bond length. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(5), one Ni(1), and two equivalent Ni(4) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra, corners with two equivalent O(6)Li3Ni3 octahedra,  an edgeedge with one O(1)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with four equivalent O(5)Li3Ni3 octahedra,  an edgeedge with one O(7)Li2Ni3 square pyramid, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(3), two equivalent Li(2), one Ni(1), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra, corners with two equivalent O(3)Li3Ni3 octahedra, corners with two equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with four equivalent O(5)Li3Ni3 octahedra, edges with four equivalent O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li2Ni3 square pyramid, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(4), one Ni(2), and two equivalent Ni(4) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(8)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(5)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(4)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li2Ni3 square pyramids, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-5°. In the fourth O site, O(4) is bonded to one Li(1), two equivalent Li(4), one Ni(2), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra, corners with two equivalent O(5)Li3Ni3 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid, corners with two equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with four equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-3°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(5), one Ni(1), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(8)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with two equivalent O(1)Li3Ni3 octahedra, edges with two equivalent O(2)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, and edges with two equivalent O(8)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-2°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(5), one Ni(2), one Ni(3), and one Ni(4) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(1)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(8)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra, edges with two equivalent O(2)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, edges with two equivalent O(5)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra,  an edgeedge with one O(7)Li2Ni3 square pyramid, and  an edgeedge with one O(8)Li2Ni3 square pyramid. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh O site, O(7) is bonded to two equivalent Li(2), one Ni(2), and two equivalent Ni(4) atoms to form OLi2Ni3 square pyramids that share  a cornercorner with one O(4)Li3Ni3 octahedra, corners with two equivalent O(5)Li3Ni3 octahedra, corners with two equivalent O(6)Li3Ni3 octahedra, corners with four equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, and edges with four equivalent O(3)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one Ni(1), one Ni(3), and one Ni(4) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(2)Li3Ni3 octahedra,  a cornercorner with one O(3)Li3Ni3 octahedra,  a cornercorner with one O(4)Li3Ni3 octahedra,  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(6)Li3Ni3 octahedra, corners with two equivalent O(7)Li2Ni3 square pyramids, corners with two equivalent O(8)Li2Ni3 square pyramids,  an edgeedge with one O(1)Li3Ni3 octahedra,  an edgeedge with one O(2)Li3Ni3 octahedra,  an edgeedge with one O(4)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra, edges with two equivalent O(3)Li3Ni3 octahedra, and edges with two equivalent O(5)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 3-7°.