Cs2Li4UO6 crystallizes in the trigonal P-3m1 space group. Cs(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. U(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to one Cs(1), one Li(2), two equivalent Li(1), and one U(1) atom.
Cs2Li4UO6 crystallizes in the trigonal P-3m1 space group. Cs(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. All Cs(1)-O(1) bond lengths are 2.87 Å. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.17 Å. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Li(2)-O(1) bond lengths are 2.50 Å. U(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All U(1)-O(1) bond lengths are 2.09 Å. O(1) is bonded in a 5-coordinate geometry to one Cs(1), one Li(2), two equivalent Li(1), and one U(1) atom.