PtC2(NO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two cis-(oxalatodiammine)platinum(ii) molecules. Pt(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. N(1) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom.
PtC2(NO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two cis-(oxalatodiammine)platinum(ii) molecules. Pt(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Pt(1)-N(1) bond lengths are 1.79 Å. Both Pt(1)-O(1) bond lengths are 2.10 Å. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.23 Å. N(1) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom.