NaBiF6 crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Bi(1) atom.
NaBiF6 crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Na(1)-F(1) bond lengths are 2.26 Å. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Bi(1)-F(1) bond lengths are 2.02 Å. F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Bi(1) atom.