Sb(MoS)2 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to two equivalent Sb(1), one S(2), and three equivalent S(1) atoms. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to three equivalent Sb(1) and three equivalent S(2) atoms. Sb(1) is bonded in a 5-coordinate geometry to two equivalent Mo(1) and three equivalent Mo(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to three equivalent Mo(1) atoms. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Mo(2) atoms.
Sb(MoS)2 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to two equivalent Sb(1), one S(2), and three equivalent S(1) atoms. Both Mo(1)-Sb(1) bond lengths are 2.90 Å. The Mo(1)-S(2) bond length is 2.64 Å. There is one shorter (2.35 Å) and two longer (2.37 Å) Mo(1)-S(1) bond lengths. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to three equivalent Sb(1) and three equivalent S(2) atoms. There is one shorter (2.88 Å) and two longer (2.91 Å) Mo(2)-Sb(1) bond lengths. There are two shorter (2.36 Å) and one longer (2.38 Å) Mo(2)-S(2) bond length. Sb(1) is bonded in a 5-coordinate geometry to two equivalent Mo(1) and three equivalent Mo(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to three equivalent Mo(1) atoms. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Mo(1) and three equivalent Mo(2) atoms.