NiOF crystallizes in the tetragonal P4/mmm space group. Ni(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing NiO4F2 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a square co-planar geometry to four equivalent Ni(1) atoms. F(1) is bonded in a linear geometry to two equivalent Ni(1) atoms.
NiOF crystallizes in the tetragonal P4/mmm space group. Ni(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing NiO4F2 octahedra. The corner-sharing octahedra are not tilted. All Ni(1)-O(1) bond lengths are 2.04 Å. Both Ni(1)-F(1) bond lengths are 1.93 Å. O(1) is bonded in a square co-planar geometry to four equivalent Ni(1) atoms. F(1) is bonded in a linear geometry to two equivalent Ni(1) atoms.