Li5Cu(PO4)2 is beta beryllia-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(14), one O(2), one O(3), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent Li(9)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(11), one O(2), one O(5), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(10)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. In the third Li site, Li(3) is bonded to one O(4), one O(6), one O(7), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra, corners with two equivalent Cu(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. In the fourth Li site, Li(4) is bonded to one O(12), one O(3), one O(5), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(9)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the fifth Li site, Li(5) is bonded to one O(1), one O(10), one O(6), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, corners with two equivalent Cu(1)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. In the sixth Li site, Li(6) is bonded to one O(12), one O(16), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Cu(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. In the seventh Li site, Li(7) is bonded to one O(10), one O(11), one O(15), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(10)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. In the eighth Li site, Li(8) is bonded to one O(1), one O(10), one O(13), and one O(16) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Cu(1)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. In the ninth Li site, Li(9) is bonded to one O(12), one O(14), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the tenth Li site, Li(10) is bonded to one O(11), one O(13), one O(15), and one O(2) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(13), one O(4), and one O(8) atom to form CuO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. In the second Cu site, Cu(2) is bonded to one O(14), one O(16), one O(4), and one O(9) atom to form CuO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(16), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra, and corners with two equivalent Cu(2)O4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(15), one O(2), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra, corners with two equivalent Li(10)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, and corners with two equivalent Li(7)O4 tetrahedra. In the third P site, P(3) is bonded to one O(11), one O(12), one O(14), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, and corners with two equivalent Li(9)O4 tetrahedra. In the fourth P site, P(4) is bonded to one O(10), one O(13), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, and corners with two equivalent Cu(1)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(8), one Cu(1), and one P(2) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(13)Li2CuP tetrahedra, corners with two equivalent O(8)Li2CuP tetrahedra, and corners with two equivalent O(10)Li3P tetrahedra. In the second O site, O(2) is bonded to one Li(1), one Li(10), one Li(2), and one P(2) atom to form distorted OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(11)Li3P tetrahedra, corners with two equivalent O(15)Li3P tetrahedra, and corners with two equivalent O(5)Li3P tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Li(4), one Li(9), and one P(1) atom to form OLi3P tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(14)Li2CuP tetrahedra, corners with two equivalent O(12)Li3P tetrahedra, and corners with two equivalent O(7)Li3P tetrahedra. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cu(1), one Cu(2), and one P(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one Li(7), and one P(2) atom to form OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(11)Li3P tetrahedra, corners with two equivalent O(15)Li3P tetrahedra, and corners with two equivalent O(2)Li3P tetrahedra. In the sixth O site, O(6) is bonded to one Li(3), one Li(5), one Li(6), and one P(1) atom to form OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(16)Li2CuP tetrahedra, and corners with two equivalent O(9)Li2CuP tetrahedra. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Li(4), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(14)Li2CuP tetrahedra, corners with two equivalent O(12)Li3P tetrahedra, and corners with two equivalent O(3)Li3P tetrahedra. In the eighth O site, O(8) is bonded to one Li(2), one Li(5), one Cu(1), and one P(4) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(1)Li2CuP tetrahedra, corners with two equivalent O(13)Li2CuP tetrahedra, and corners with two equivalent O(10)Li3P tetrahedra. In the ninth O site, O(9) is bonded to one Li(3), one Li(6), one Cu(2), and one P(4) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(16)Li2CuP tetrahedra, and corners with two equivalent O(6)Li3P tetrahedra. In the tenth O site, O(10) is bonded to one Li(5), one Li(7), one Li(8), and one P(4) atom to form OLi3P tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(1)Li2CuP tetrahedra, corners with two equivalent O(13)Li2CuP tetrahedra, and corners with two equivalent O(8)Li2CuP tetrahedra. In the eleventh O site, O(11) is bonded to one Li(10), one Li(2), one Li(7), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(15)Li3P tetrahedra, corners with two equivalent O(2)Li3P tetrahedra, and corners with two equivalent O(5)Li3P tetrahedra. In the twelfth O site, O(12) is bonded to one Li(4), one Li(6), one Li(9), and one P(3) atom to form distorted OLi3P tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(14)Li2CuP tetrahedra, corners with two equivalent O(3)Li3P tetrahedra, and corners with two equivalent O(7)Li3P tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(10), one Li(8), one Cu(1), and one P(4) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra, corners with two equivalent O(1)Li2CuP tetrahedra, corners with two equivalent O(8)Li2CuP tetrahedra, and corners with two equivalent O(10)Li3P tetrahedra. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(9), one Cu(2), and one P(3) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra, corners with two equivalent O(12)Li3P tetrahedra, corners with two equivalent O(3)Li3P tetrahedra, and corners with two equivalent O(7)Li3P tetrahedra. In the fifteenth O site, O(15) is bonded to one Li(10), one Li(7), one Li(9), and one P(2) atom to form OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra, corners with two equivalent O(11)Li3P tetrahedra, corners with two equivalent O(2)Li3P tetrahedra, and corners with two equivalent O(5)Li3P tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(6), one Li(8), one Cu(2), and one P(1) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra, corners with two equivalent O(9)Li2CuP tetrahedra, and corners with two equivalent O(6)Li3P tetrahedra.
Li5Cu(PO4)2 is beta beryllia-derived structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(14), one O(2), one O(3), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, corners with two equivalent Li(9)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The Li(1)-O(14) bond length is 2.04 Å. The Li(1)-O(2) bond length is 2.05 Å. The Li(1)-O(3) bond length is 2.02 Å. The Li(1)-O(7) bond length is 2.07 Å. In the second Li site, Li(2) is bonded to one O(11), one O(2), one O(5), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(10)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The Li(2)-O(11) bond length is 1.95 Å. The Li(2)-O(2) bond length is 2.01 Å. The Li(2)-O(5) bond length is 2.00 Å. The Li(2)-O(8) bond length is 1.99 Å. In the third Li site, Li(3) is bonded to one O(4), one O(6), one O(7), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra, corners with two equivalent Cu(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The Li(3)-O(4) bond length is 1.93 Å. The Li(3)-O(6) bond length is 1.96 Å. The Li(3)-O(7) bond length is 2.03 Å. The Li(3)-O(9) bond length is 1.95 Å. In the fourth Li site, Li(4) is bonded to one O(12), one O(3), one O(5), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(9)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The Li(4)-O(12) bond length is 2.00 Å. The Li(4)-O(3) bond length is 1.95 Å. The Li(4)-O(5) bond length is 2.00 Å. The Li(4)-O(7) bond length is 2.00 Å. In the fifth Li site, Li(5) is bonded to one O(1), one O(10), one O(6), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, corners with two equivalent Cu(1)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The Li(5)-O(1) bond length is 1.94 Å. The Li(5)-O(10) bond length is 2.01 Å. The Li(5)-O(6) bond length is 2.04 Å. The Li(5)-O(8) bond length is 1.99 Å. In the sixth Li site, Li(6) is bonded to one O(12), one O(16), one O(6), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Cu(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The Li(6)-O(12) bond length is 2.05 Å. The Li(6)-O(16) bond length is 2.03 Å. The Li(6)-O(6) bond length is 2.08 Å. The Li(6)-O(9) bond length is 1.98 Å. In the seventh Li site, Li(7) is bonded to one O(10), one O(11), one O(15), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(10)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The Li(7)-O(10) bond length is 2.03 Å. The Li(7)-O(11) bond length is 1.97 Å. The Li(7)-O(15) bond length is 2.07 Å. The Li(7)-O(5) bond length is 2.07 Å. In the eighth Li site, Li(8) is bonded to one O(1), one O(10), one O(13), and one O(16) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Cu(1)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The Li(8)-O(1) bond length is 1.94 Å. The Li(8)-O(10) bond length is 2.02 Å. The Li(8)-O(13) bond length is 2.00 Å. The Li(8)-O(16) bond length is 2.01 Å. In the ninth Li site, Li(9) is bonded to one O(12), one O(14), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The Li(9)-O(12) bond length is 2.00 Å. The Li(9)-O(14) bond length is 1.98 Å. The Li(9)-O(15) bond length is 2.00 Å. The Li(9)-O(3) bond length is 1.95 Å. In the tenth Li site, Li(10) is bonded to one O(11), one O(13), one O(15), and one O(2) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The Li(10)-O(11) bond length is 1.98 Å. The Li(10)-O(13) bond length is 2.02 Å. The Li(10)-O(15) bond length is 2.00 Å. The Li(10)-O(2) bond length is 2.00 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(13), one O(4), and one O(8) atom to form CuO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The Cu(1)-O(1) bond length is 2.17 Å. The Cu(1)-O(13) bond length is 2.07 Å. The Cu(1)-O(4) bond length is 2.13 Å. The Cu(1)-O(8) bond length is 2.08 Å. In the second Cu site, Cu(2) is bonded to one O(14), one O(16), one O(4), and one O(9) atom to form CuO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The Cu(2)-O(14) bond length is 2.10 Å. The Cu(2)-O(16) bond length is 2.05 Å. The Cu(2)-O(4) bond length is 2.08 Å. The Cu(2)-O(9) bond length is 2.09 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(16), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra, and corners with two equivalent Cu(2)O4 tetrahedra. The P(1)-O(16) bond length is 1.57 Å. The P(1)-O(3) bond length is 1.55 Å. The P(1)-O(4) bond length is 1.56 Å. The P(1)-O(6) bond length is 1.56 Å. In the second P site, P(2) is bonded to one O(1), one O(15), one O(2), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one Cu(1)O4 tetrahedra, corners with two equivalent Li(10)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, and corners with two equivalent Li(7)O4 tetrahedra. The P(2)-O(1) bond length is 1.56 Å. The P(2)-O(15) bond length is 1.56 Å. The P(2)-O(2) bond length is 1.56 Å. The P(2)-O(5) bond length is 1.56 Å. In the third P site, P(3) is bonded to one O(11), one O(12), one O(14), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra, and corners with two equivalent Li(9)O4 tetrahedra. The P(3)-O(11) bond length is 1.56 Å. The P(3)-O(12) bond length is 1.56 Å. The P(3)-O(14) bond length is 1.57 Å. The P(3)-O(7) bond length is 1.56 Å. In the fourth P site, P(4) is bonded to one O(10), one O(13), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Cu(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, and corners with two equivalent Cu(1)O4 tetrahedra. The P(4)-O(10) bond length is 1.55 Å. The P(4)-O(13) bond length is 1.56 Å. The P(4)-O(8) bond length is 1.56 Å. The P(4)-O(9) bond length is 1.56 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(8), one Cu(1), and one P(2) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(13)Li2CuP tetrahedra, corners with two equivalent O(8)Li2CuP tetrahedra, and corners with two equivalent O(10)Li3P tetrahedra. In the second O site, O(2) is bonded to one Li(1), one Li(10), one Li(2), and one P(2) atom to form distorted OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(11)Li3P tetrahedra, corners with two equivalent O(15)Li3P tetrahedra, and corners with two equivalent O(5)Li3P tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Li(4), one Li(9), and one P(1) atom to form OLi3P tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(14)Li2CuP tetrahedra, corners with two equivalent O(12)Li3P tetrahedra, and corners with two equivalent O(7)Li3P tetrahedra. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Cu(1), one Cu(2), and one P(1) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one Li(7), and one P(2) atom to form OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(11)Li3P tetrahedra, corners with two equivalent O(15)Li3P tetrahedra, and corners with two equivalent O(2)Li3P tetrahedra. In the sixth O site, O(6) is bonded to one Li(3), one Li(5), one Li(6), and one P(1) atom to form OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(16)Li2CuP tetrahedra, and corners with two equivalent O(9)Li2CuP tetrahedra. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Li(4), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(14)Li2CuP tetrahedra, corners with two equivalent O(12)Li3P tetrahedra, and corners with two equivalent O(3)Li3P tetrahedra. In the eighth O site, O(8) is bonded to one Li(2), one Li(5), one Cu(1), and one P(4) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(1)Li2CuP tetrahedra, corners with two equivalent O(13)Li2CuP tetrahedra, and corners with two equivalent O(10)Li3P tetrahedra. In the ninth O site, O(9) is bonded to one Li(3), one Li(6), one Cu(2), and one P(4) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(16)Li2CuP tetrahedra, and corners with two equivalent O(6)Li3P tetrahedra. In the tenth O site, O(10) is bonded to one Li(5), one Li(7), one Li(8), and one P(4) atom to form OLi3P tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(1)Li2CuP tetrahedra, corners with two equivalent O(13)Li2CuP tetrahedra, and corners with two equivalent O(8)Li2CuP tetrahedra. In the eleventh O site, O(11) is bonded to one Li(10), one Li(2), one Li(7), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(8)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(7)Li3P tetrahedra, corners with two equivalent O(15)Li3P tetrahedra, corners with two equivalent O(2)Li3P tetrahedra, and corners with two equivalent O(5)Li3P tetrahedra. In the twelfth O site, O(12) is bonded to one Li(4), one Li(6), one Li(9), and one P(3) atom to form distorted OLi3P tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(6)Li3P tetrahedra, corners with two equivalent O(14)Li2CuP tetrahedra, corners with two equivalent O(3)Li3P tetrahedra, and corners with two equivalent O(7)Li3P tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(10), one Li(8), one Cu(1), and one P(4) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra, corners with two equivalent O(1)Li2CuP tetrahedra, corners with two equivalent O(8)Li2CuP tetrahedra, and corners with two equivalent O(10)Li3P tetrahedra. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(9), one Cu(2), and one P(3) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(16)Li2CuP tetrahedra,  a cornercorner with one O(9)Li2CuP tetrahedra,  a cornercorner with one O(11)Li3P tetrahedra,  a cornercorner with one O(15)Li3P tetrahedra,  a cornercorner with one O(2)Li3P tetrahedra, corners with two equivalent O(12)Li3P tetrahedra, corners with two equivalent O(3)Li3P tetrahedra, and corners with two equivalent O(7)Li3P tetrahedra. In the fifteenth O site, O(15) is bonded to one Li(10), one Li(7), one Li(9), and one P(2) atom to form OLi3P tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra, corners with two equivalent O(11)Li3P tetrahedra, corners with two equivalent O(2)Li3P tetrahedra, and corners with two equivalent O(5)Li3P tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(6), one Li(8), one Cu(2), and one P(1) atom to form distorted OLi2CuP tetrahedra that share  a cornercorner with one O(1)Li2CuP tetrahedra,  a cornercorner with one O(13)Li2CuP tetrahedra,  a cornercorner with one O(14)Li2CuP tetrahedra,  a cornercorner with one O(10)Li3P tetrahedra,  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(3)Li3P tetrahedra, corners with two equivalent O(9)Li2CuP tetrahedra, and corners with two equivalent O(6)Li3P tetrahedra.