MnInCrS4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Cr(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form CrS6 octahedra that share corners with six equivalent Mn(1)S4 tetrahedra, edges with two equivalent Cr(1)S6 octahedra, and edges with four equivalent In(1)S6 octahedra. Mn(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form MnS4 tetrahedra that share corners with six equivalent Cr(1)S6 octahedra and corners with six equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. In(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Mn(1)S4 tetrahedra, edges with two equivalent In(1)S6 octahedra, and edges with four equivalent Cr(1)S6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to one Cr(1), one Mn(1), and two equivalent In(1) atoms. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cr(1), one Mn(1), and one In(1) atom.
MnInCrS4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Cr(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form CrS6 octahedra that share corners with six equivalent Mn(1)S4 tetrahedra, edges with two equivalent Cr(1)S6 octahedra, and edges with four equivalent In(1)S6 octahedra. Both Cr(1)-S(1) bond lengths are 2.45 Å. All Cr(1)-S(2) bond lengths are 2.47 Å. Mn(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form MnS4 tetrahedra that share corners with six equivalent Cr(1)S6 octahedra and corners with six equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. Both Mn(1)-S(1) bond lengths are 2.39 Å. Both Mn(1)-S(2) bond lengths are 2.43 Å. In(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Mn(1)S4 tetrahedra, edges with two equivalent In(1)S6 octahedra, and edges with four equivalent Cr(1)S6 octahedra. Both In(1)-S(2) bond lengths are 2.64 Å. All In(1)-S(1) bond lengths are 2.61 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to one Cr(1), one Mn(1), and two equivalent In(1) atoms. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cr(1), one Mn(1), and one In(1) atom.