LiB crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a trigonal planar geometry to three equivalent B(1) atoms. B(1) is bonded to three equivalent Li(1) and two equivalent B(1) atoms to form corner-sharing BLi3B2 trigonal bipyramids.
LiB crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a trigonal planar geometry to three equivalent B(1) atoms. All Li(1)-B(1) bond lengths are 2.32 Å. B(1) is bonded to three equivalent Li(1) and two equivalent B(1) atoms to form corner-sharing BLi3B2 trigonal bipyramids. Both B(1)-B(1) bond lengths are 1.55 Å.