CrZnF6 crystallizes in the trigonal R-3 space group. Cr(1) is bonded to six equivalent F(1) atoms to form CrF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Cr(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. F(1) is bonded in a bent 150 degrees geometry to one Cr(1) and one Zn(1) atom.
CrZnF6 crystallizes in the trigonal R-3 space group. Cr(1) is bonded to six equivalent F(1) atoms to form CrF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. All Cr(1)-F(1) bond lengths are 1.83 Å. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Cr(1)F6 octahedra. The corner-sharing octahedral tilt angles are 40°. All Zn(1)-F(1) bond lengths are 2.02 Å. F(1) is bonded in a bent 150 degrees geometry to one Cr(1) and one Zn(1) atom.