Li5V5O12 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(13), one O(17), one O(21), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-14°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(19), one O(22), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(13), one O(17), one O(22), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-13°. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(2), one O(23), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. In the fifth Li site, Li(5) is bonded to one O(11), one O(12), one O(13), one O(17), one O(21), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the sixth Li site, Li(6) is bonded to one O(14), one O(18), one O(20), one O(24), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the seventh Li site, Li(7) is bonded to one O(14), one O(18), one O(20), one O(24), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. In the eighth Li site, Li(8) is bonded to one O(1), one O(10), one O(19), one O(22), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the ninth Li site, Li(9) is bonded to one O(18), one O(2), one O(20), one O(23), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(10)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. In the tenth Li site, Li(10) is bonded to one O(15), one O(16), one O(2), one O(23), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. There are ten inequivalent V sites. In the first V site, V(1) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(5)O6 octahedra, and edges with three equivalent V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-8°. In the second V site, V(2) is bonded to one O(18), one O(2), one O(20), one O(23), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Li(9)O6 octahedra, and edges with three equivalent V(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(13), one O(17), one O(22), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(14), one O(21), one O(24), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(7)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the fifth V site, V(5) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the sixth V site, V(6) is bonded to one O(1), one O(10), one O(13), one O(17), one O(22), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. In the seventh V site, V(7) is bonded to one O(11), one O(12), one O(14), one O(21), one O(24), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. In the eighth V site, V(8) is bonded to one O(11), one O(12), one O(14), one O(21), one O(24), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with three equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. In the ninth V site, V(9) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. In the tenth V site, V(10) is bonded to one O(18), one O(2), one O(20), one O(23), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Li(9)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Li(8), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(7)Li2V3 square pyramids, corners with two equivalent O(8)Li2V3 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(10)Li3V2 square pyramids, and edges with two equivalent O(22)Li3V2 square pyramids. In the second O site, O(2) is bonded to one Li(10), one Li(4), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(16)Li2V3 square pyramids, corners with two equivalent O(4)Li2V3 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(23)Li3V2 square pyramids, and edges with two equivalent O(9)Li3V2 square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(5), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(21)Li2V3 square pyramids,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(13)Li3V2 square pyramids, and edges with two equivalent O(17)Li3V2 square pyramids. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(2)Li3V2 square pyramids, corners with two equivalent O(23)Li3V2 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(15)Li2V3 square pyramids, and edges with two equivalent O(16)Li2V3 square pyramids. In the fifth O site, O(5) is bonded to one Li(6), one Li(7), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid, corners with two equivalent O(20)Li3V2 square pyramids, corners with two equivalent O(6)Li3V2 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid, edges with two equivalent O(14)Li2V3 square pyramids, and edges with two equivalent O(24)Li2V3 square pyramids. In the sixth O site, O(6) is bonded to one Li(6), one Li(7), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(24)Li2V3 square pyramids, corners with two equivalent O(5)Li2V3 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(18)Li3V2 square pyramids, and edges with two equivalent O(20)Li3V2 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(8), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(1)Li3V2 square pyramids, corners with two equivalent O(10)Li3V2 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(19)Li2V3 square pyramids, and edges with two equivalent O(8)Li2V3 square pyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(8), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with two equivalent O(1)Li3V2 square pyramids, corners with two equivalent O(22)Li3V2 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid, edges with two equivalent O(19)Li2V3 square pyramids, and edges with two equivalent O(7)Li2V3 square pyramids. In the ninth O site, O(9) is bonded to one Li(10), one Li(4), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid, corners with two equivalent O(15)Li2V3 square pyramids, corners with two equivalent O(16)Li2V3 square pyramids,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(2)Li3V2 square pyramids, and edges with two equivalent O(23)Li3V2 square pyramids. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Li(8), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(19)Li2V3 square pyramids, corners with two equivalent O(7)Li2V3 square pyramids,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(1)Li3V2 square pyramids, and edges with two equivalent O(22)Li3V2 square pyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(5), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(17)Li3V2 square pyramids, corners with two equivalent O(3)Li3V2 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid, edges with two equivalent O(12)Li2V3 square pyramids, and edges with two equivalent O(21)Li2V3 square pyramids. In the twelfth O site, O(12) is bonded to one Li(1), one Li(5), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(13)Li3V2 square pyramids, corners with two equivalent O(17)Li3V2 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(11)Li2V3 square pyramids, and edges with two equivalent O(21)Li2V3 square pyramids. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(5), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(12)Li2V3 square pyramids, corners with two equivalent O(21)Li2V3 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(17)Li3V2 square pyramids, and edges with two equivalent O(3)Li3V2 square pyramids. In the fourteenth O site, O(14) is bonded to one Li(6), one Li(7), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(18)Li3V2 square pyramids, corners with two equivalent O(20)Li3V2 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(24)Li2V3 square pyramids, and edges with two equivalent O(5)Li2V3 square pyramids. In the fifteenth O site, O(15) is bonded to one Li(10), one Li(4), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(23)Li3V2 square pyramids, corners with two equivalent O(9)Li3V2 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid, edges with two equivalent O(16)Li2V3 square pyramids, and edges with two equivalent O(4)Li2V3 square pyramids. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(4), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(2)Li3V2 square pyramids, corners with two equivalent O(9)Li3V2 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid, edges with two equivalent O(15)Li2V3 square pyramids, and edges with two equivalent O(4)Li2V3 square pyramids. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(5), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(12)Li2V3 square pyramids,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(13)Li3V2 square pyramids, and edges with two equivalent O(3)Li3V2 square pyramids. In the eighteenth O site, O(18) is bonded to one Li(6), one Li(7), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(14)Li2V3 square pyramids, corners with two equivalent O(24)Li2V3 square pyramids,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(20)Li3V2 square pyramids, and edges with two equivalent O(6)Li3V2 square pyramids. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(8), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(10)Li3V2 square pyramids, corners with two equivalent O(22)Li3V2 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid, edges with two equivalent O(7)Li2V3 square pyramids, and edges with two equivalent O(8)Li2V3 square pyramids. In the twentieth O site, O(20) is bonded to one Li(6), one Li(7), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(14)Li2V3 square pyramids, corners with two equivalent O(5)Li2V3 square pyramids,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(18)Li3V2 square pyramids, and edges with two equivalent O(6)Li3V2 square pyramids. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(5), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(13)Li3V2 square pyramids, corners with two equivalent O(3)Li3V2 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid, edges with two equivalent O(11)Li2V3 square pyramids, and edges with two equivalent O(12)Li2V3 square pyramids. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(3), one Li(8), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(19)Li2V3 square pyramids, corners with two equivalent O(8)Li2V3 square pyramids,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(1)Li3V2 square pyramids, and edges with two equivalent O(10)Li3V2 square pyramids. In the twenty-third O site, O(23) is bonded to one Li(10), one Li(4), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(15)Li2V3 square pyramids, corners with two equivalent O(4)Li2V3 square pyramids,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(2)Li3V2 square pyramids, and edges with two equivalent O(9)Li3V2 square pyramids. In the twenty-fourth O site, O(24) is bonded to one Li(6), one Li(7), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(18)Li3V2 square pyramids, corners with two equivalent O(6)Li3V2 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid, edges with two equivalent O(14)Li2V3 square pyramids, and edges with two equivalent O(5)Li2V3 square pyramids.
Li5V5O12 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(13), one O(17), one O(21), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-14°. The Li(1)-O(11) bond length is 2.18 Å. The Li(1)-O(12) bond length is 2.21 Å. The Li(1)-O(13) bond length is 2.13 Å. The Li(1)-O(17) bond length is 2.12 Å. The Li(1)-O(21) bond length is 2.18 Å. The Li(1)-O(3) bond length is 2.29 Å. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(19), one O(22), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. The Li(2)-O(1) bond length is 2.20 Å. The Li(2)-O(10) bond length is 2.21 Å. The Li(2)-O(19) bond length is 2.20 Å. The Li(2)-O(22) bond length is 2.16 Å. The Li(2)-O(7) bond length is 2.25 Å. The Li(2)-O(8) bond length is 2.12 Å. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(13), one O(17), one O(22), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(3)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-13°. The Li(3)-O(1) bond length is 2.18 Å. The Li(3)-O(10) bond length is 2.12 Å. The Li(3)-O(13) bond length is 2.11 Å. The Li(3)-O(17) bond length is 2.16 Å. The Li(3)-O(22) bond length is 2.11 Å. The Li(3)-O(3) bond length is 2.10 Å. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(2), one O(23), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. The Li(4)-O(15) bond length is 2.16 Å. The Li(4)-O(16) bond length is 2.17 Å. The Li(4)-O(2) bond length is 2.25 Å. The Li(4)-O(23) bond length is 2.14 Å. The Li(4)-O(4) bond length is 2.23 Å. The Li(4)-O(9) bond length is 2.15 Å. In the fifth Li site, Li(5) is bonded to one O(11), one O(12), one O(13), one O(17), one O(21), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. The Li(5)-O(11) bond length is 2.24 Å. The Li(5)-O(12) bond length is 2.11 Å. The Li(5)-O(13) bond length is 2.13 Å. The Li(5)-O(17) bond length is 2.18 Å. The Li(5)-O(21) bond length is 2.21 Å. The Li(5)-O(3) bond length is 2.22 Å. In the sixth Li site, Li(6) is bonded to one O(14), one O(18), one O(20), one O(24), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. The Li(6)-O(14) bond length is 2.09 Å. The Li(6)-O(18) bond length is 2.09 Å. The Li(6)-O(20) bond length is 2.23 Å. The Li(6)-O(24) bond length is 2.20 Å. The Li(6)-O(5) bond length is 2.25 Å. The Li(6)-O(6) bond length is 2.17 Å. In the seventh Li site, Li(7) is bonded to one O(14), one O(18), one O(20), one O(24), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(7)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. The Li(7)-O(14) bond length is 2.16 Å. The Li(7)-O(18) bond length is 2.15 Å. The Li(7)-O(20) bond length is 2.16 Å. The Li(7)-O(24) bond length is 2.23 Å. The Li(7)-O(5) bond length is 2.16 Å. The Li(7)-O(6) bond length is 2.28 Å. In the eighth Li site, Li(8) is bonded to one O(1), one O(10), one O(19), one O(22), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. The Li(8)-O(1) bond length is 2.10 Å. The Li(8)-O(10) bond length is 2.29 Å. The Li(8)-O(19) bond length is 2.20 Å. The Li(8)-O(22) bond length is 2.17 Å. The Li(8)-O(7) bond length is 2.18 Å. The Li(8)-O(8) bond length is 2.18 Å. In the ninth Li site, Li(9) is bonded to one O(18), one O(2), one O(20), one O(23), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(10)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. The Li(9)-O(18) bond length is 2.17 Å. The Li(9)-O(2) bond length is 2.08 Å. The Li(9)-O(20) bond length is 2.09 Å. The Li(9)-O(23) bond length is 2.13 Å. The Li(9)-O(6) bond length is 2.11 Å. The Li(9)-O(9) bond length is 2.18 Å. In the tenth Li site, Li(10) is bonded to one O(15), one O(16), one O(2), one O(23), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. The Li(10)-O(15) bond length is 2.10 Å. The Li(10)-O(16) bond length is 2.29 Å. The Li(10)-O(2) bond length is 2.20 Å. The Li(10)-O(23) bond length is 2.21 Å. The Li(10)-O(4) bond length is 2.17 Å. The Li(10)-O(9) bond length is 2.06 Å. There are ten inequivalent V sites. In the first V site, V(1) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(5)O6 octahedra, and edges with three equivalent V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-8°. The V(1)-O(15) bond length is 1.93 Å. The V(1)-O(16) bond length is 2.02 Å. The V(1)-O(19) bond length is 1.92 Å. The V(1)-O(4) bond length is 2.01 Å. The V(1)-O(7) bond length is 2.00 Å. The V(1)-O(8) bond length is 2.03 Å. In the second V site, V(2) is bonded to one O(18), one O(2), one O(20), one O(23), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Li(9)O6 octahedra, and edges with three equivalent V(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. The V(2)-O(18) bond length is 1.87 Å. The V(2)-O(2) bond length is 1.89 Å. The V(2)-O(20) bond length is 2.00 Å. The V(2)-O(23) bond length is 1.97 Å. The V(2)-O(6) bond length is 1.92 Å. The V(2)-O(9) bond length is 1.85 Å. In the third V site, V(3) is bonded to one O(1), one O(10), one O(13), one O(17), one O(22), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. The V(3)-O(1) bond length is 1.91 Å. The V(3)-O(10) bond length is 1.86 Å. The V(3)-O(13) bond length is 1.88 Å. The V(3)-O(17) bond length is 2.03 Å. The V(3)-O(22) bond length is 1.92 Å. The V(3)-O(3) bond length is 1.92 Å. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(14), one O(21), one O(24), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(7)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. The V(4)-O(11) bond length is 2.04 Å. The V(4)-O(12) bond length is 2.01 Å. The V(4)-O(14) bond length is 2.03 Å. The V(4)-O(21) bond length is 2.09 Å. The V(4)-O(24) bond length is 2.06 Å. The V(4)-O(5) bond length is 2.03 Å. In the fifth V site, V(5) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. The V(5)-O(15) bond length is 2.06 Å. The V(5)-O(16) bond length is 2.04 Å. The V(5)-O(19) bond length is 2.07 Å. The V(5)-O(4) bond length is 2.00 Å. The V(5)-O(7) bond length is 2.05 Å. The V(5)-O(8) bond length is 2.01 Å. In the sixth V site, V(6) is bonded to one O(1), one O(10), one O(13), one O(17), one O(22), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. The V(6)-O(1) bond length is 1.98 Å. The V(6)-O(10) bond length is 2.02 Å. The V(6)-O(13) bond length is 2.01 Å. The V(6)-O(17) bond length is 1.88 Å. The V(6)-O(22) bond length is 1.96 Å. The V(6)-O(3) bond length is 1.98 Å. In the seventh V site, V(7) is bonded to one O(11), one O(12), one O(14), one O(21), one O(24), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with three equivalent V(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. The V(7)-O(11) bond length is 2.02 Å. The V(7)-O(12) bond length is 2.05 Å. The V(7)-O(14) bond length is 2.05 Å. The V(7)-O(21) bond length is 2.06 Å. The V(7)-O(24) bond length is 2.08 Å. The V(7)-O(5) bond length is 2.02 Å. In the eighth V site, V(8) is bonded to one O(11), one O(12), one O(14), one O(21), one O(24), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent V(4)O6 octahedra, and edges with three equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. The V(8)-O(11) bond length is 2.01 Å. The V(8)-O(12) bond length is 2.04 Å. The V(8)-O(14) bond length is 2.03 Å. The V(8)-O(21) bond length is 1.90 Å. The V(8)-O(24) bond length is 1.91 Å. The V(8)-O(5) bond length is 2.01 Å. In the ninth V site, V(9) is bonded to one O(15), one O(16), one O(19), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and edges with three equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. The V(9)-O(15) bond length is 2.08 Å. The V(9)-O(16) bond length is 2.00 Å. The V(9)-O(19) bond length is 2.06 Å. The V(9)-O(4) bond length is 2.04 Å. The V(9)-O(7) bond length is 2.01 Å. The V(9)-O(8) bond length is 2.05 Å. In the tenth V site, V(10) is bonded to one O(18), one O(2), one O(20), one O(23), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Li(9)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. The V(10)-O(18) bond length is 2.02 Å. The V(10)-O(2) bond length is 2.02 Å. The V(10)-O(20) bond length is 1.87 Å. The V(10)-O(23) bond length is 1.90 Å. The V(10)-O(6) bond length is 1.98 Å. The V(10)-O(9) bond length is 2.04 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Li(8), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(7)Li2V3 square pyramids, corners with two equivalent O(8)Li2V3 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(10)Li3V2 square pyramids, and edges with two equivalent O(22)Li3V2 square pyramids. In the second O site, O(2) is bonded to one Li(10), one Li(4), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(16)Li2V3 square pyramids, corners with two equivalent O(4)Li2V3 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(23)Li3V2 square pyramids, and edges with two equivalent O(9)Li3V2 square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(5), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(21)Li2V3 square pyramids,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(13)Li3V2 square pyramids, and edges with two equivalent O(17)Li3V2 square pyramids. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(2)Li3V2 square pyramids, corners with two equivalent O(23)Li3V2 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(15)Li2V3 square pyramids, and edges with two equivalent O(16)Li2V3 square pyramids. In the fifth O site, O(5) is bonded to one Li(6), one Li(7), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid, corners with two equivalent O(20)Li3V2 square pyramids, corners with two equivalent O(6)Li3V2 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid, edges with two equivalent O(14)Li2V3 square pyramids, and edges with two equivalent O(24)Li2V3 square pyramids. In the sixth O site, O(6) is bonded to one Li(6), one Li(7), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(24)Li2V3 square pyramids, corners with two equivalent O(5)Li2V3 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(18)Li3V2 square pyramids, and edges with two equivalent O(20)Li3V2 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(8), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(1)Li3V2 square pyramids, corners with two equivalent O(10)Li3V2 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(19)Li2V3 square pyramids, and edges with two equivalent O(8)Li2V3 square pyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(8), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with two equivalent O(1)Li3V2 square pyramids, corners with two equivalent O(22)Li3V2 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid, edges with two equivalent O(19)Li2V3 square pyramids, and edges with two equivalent O(7)Li2V3 square pyramids. In the ninth O site, O(9) is bonded to one Li(10), one Li(4), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid, corners with two equivalent O(15)Li2V3 square pyramids, corners with two equivalent O(16)Li2V3 square pyramids,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(2)Li3V2 square pyramids, and edges with two equivalent O(23)Li3V2 square pyramids. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Li(8), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(19)Li2V3 square pyramids, corners with two equivalent O(7)Li2V3 square pyramids,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(1)Li3V2 square pyramids, and edges with two equivalent O(22)Li3V2 square pyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(5), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(17)Li3V2 square pyramids, corners with two equivalent O(3)Li3V2 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid, edges with two equivalent O(12)Li2V3 square pyramids, and edges with two equivalent O(21)Li2V3 square pyramids. In the twelfth O site, O(12) is bonded to one Li(1), one Li(5), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(13)Li3V2 square pyramids, corners with two equivalent O(17)Li3V2 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(11)Li2V3 square pyramids, and edges with two equivalent O(21)Li2V3 square pyramids. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(5), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(12)Li2V3 square pyramids, corners with two equivalent O(21)Li2V3 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(17)Li3V2 square pyramids, and edges with two equivalent O(3)Li3V2 square pyramids. In the fourteenth O site, O(14) is bonded to one Li(6), one Li(7), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(18)Li3V2 square pyramids, corners with two equivalent O(20)Li3V2 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(24)Li2V3 square pyramids, and edges with two equivalent O(5)Li2V3 square pyramids. In the fifteenth O site, O(15) is bonded to one Li(10), one Li(4), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(23)Li3V2 square pyramids, corners with two equivalent O(9)Li3V2 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid, edges with two equivalent O(16)Li2V3 square pyramids, and edges with two equivalent O(4)Li2V3 square pyramids. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(4), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(19)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(2)Li3V2 square pyramids, corners with two equivalent O(9)Li3V2 square pyramids,  an edgeedge with one O(19)Li2V3 square pyramid,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(8)Li2V3 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid, edges with two equivalent O(15)Li2V3 square pyramids, and edges with two equivalent O(4)Li2V3 square pyramids. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(5), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(22)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(11)Li2V3 square pyramids, corners with two equivalent O(12)Li2V3 square pyramids,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid,  an edgeedge with one O(10)Li3V2 square pyramid,  an edgeedge with one O(22)Li3V2 square pyramid, edges with two equivalent O(13)Li3V2 square pyramids, and edges with two equivalent O(3)Li3V2 square pyramids. In the eighteenth O site, O(18) is bonded to one Li(6), one Li(7), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(14)Li2V3 square pyramids, corners with two equivalent O(24)Li2V3 square pyramids,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(20)Li3V2 square pyramids, and edges with two equivalent O(6)Li3V2 square pyramids. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(8), one V(1), one V(5), and one V(9) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(15)Li2V3 square pyramid,  a cornercorner with one O(16)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(8)Li2V3 square pyramid, corners with two equivalent O(10)Li3V2 square pyramids, corners with two equivalent O(22)Li3V2 square pyramids,  an edgeedge with one O(15)Li2V3 square pyramid,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid,  an edgeedge with one O(1)Li3V2 square pyramid, edges with two equivalent O(7)Li2V3 square pyramids, and edges with two equivalent O(8)Li2V3 square pyramids. In the twentieth O site, O(20) is bonded to one Li(6), one Li(7), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(23)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(14)Li2V3 square pyramids, corners with two equivalent O(5)Li2V3 square pyramids,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(2)Li3V2 square pyramid,  an edgeedge with one O(23)Li3V2 square pyramid,  an edgeedge with one O(9)Li3V2 square pyramid, edges with two equivalent O(18)Li3V2 square pyramids, and edges with two equivalent O(6)Li3V2 square pyramids. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(5), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(24)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(13)Li3V2 square pyramids, corners with two equivalent O(3)Li3V2 square pyramids,  an edgeedge with one O(14)Li2V3 square pyramid,  an edgeedge with one O(24)Li2V3 square pyramid,  an edgeedge with one O(5)Li2V3 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid, edges with two equivalent O(11)Li2V3 square pyramids, and edges with two equivalent O(12)Li2V3 square pyramids. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(3), one Li(8), one V(3), and one V(6) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(1)Li3V2 square pyramid,  a cornercorner with one O(10)Li3V2 square pyramid,  a cornercorner with one O(13)Li3V2 square pyramid,  a cornercorner with one O(17)Li3V2 square pyramid,  a cornercorner with one O(3)Li3V2 square pyramid, corners with two equivalent O(19)Li2V3 square pyramids, corners with two equivalent O(8)Li2V3 square pyramids,  an edgeedge with one O(7)Li2V3 square pyramid,  an edgeedge with one O(13)Li3V2 square pyramid,  an edgeedge with one O(17)Li3V2 square pyramid,  an edgeedge with one O(3)Li3V2 square pyramid, edges with two equivalent O(1)Li3V2 square pyramids, and edges with two equivalent O(10)Li3V2 square pyramids. In the twenty-third O site, O(23) is bonded to one Li(10), one Li(4), one Li(9), one V(10), and one V(2) atom to form OLi3V2 square pyramids that share  a cornercorner with one O(18)Li3V2 square pyramid,  a cornercorner with one O(2)Li3V2 square pyramid,  a cornercorner with one O(20)Li3V2 square pyramid,  a cornercorner with one O(6)Li3V2 square pyramid,  a cornercorner with one O(9)Li3V2 square pyramid, corners with two equivalent O(15)Li2V3 square pyramids, corners with two equivalent O(4)Li2V3 square pyramids,  an edgeedge with one O(16)Li2V3 square pyramid,  an edgeedge with one O(18)Li3V2 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid,  an edgeedge with one O(6)Li3V2 square pyramid, edges with two equivalent O(2)Li3V2 square pyramids, and edges with two equivalent O(9)Li3V2 square pyramids. In the twenty-fourth O site, O(24) is bonded to one Li(6), one Li(7), one V(4), one V(7), and one V(8) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(14)Li2V3 square pyramid,  a cornercorner with one O(21)Li2V3 square pyramid,  a cornercorner with one O(5)Li2V3 square pyramid, corners with two equivalent O(18)Li3V2 square pyramids, corners with two equivalent O(6)Li3V2 square pyramids,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid,  an edgeedge with one O(21)Li2V3 square pyramid,  an edgeedge with one O(20)Li3V2 square pyramid, edges with two equivalent O(14)Li2V3 square pyramids, and edges with two equivalent O(5)Li2V3 square pyramids.