LiAgF3 crystallizes in the orthorhombic Cmmm space group. Li(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form a mixture of corner and edge-sharing LiF6 octahedra. The corner-sharing octahedral tilt angles are 59°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Li(1) and two equivalent Ag(1) atoms to form a mixture of corner and edge-sharing FLi2Ag2 tetrahedra. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(2) atom.
LiAgF3 crystallizes in the orthorhombic Cmmm space group. Li(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form a mixture of corner and edge-sharing LiF6 octahedra. The corner-sharing octahedral tilt angles are 59°. Both Li(1)-F(1) bond lengths are 2.26 Å. All Li(1)-F(2) bond lengths are 2.04 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All Ag(1)-F(1) bond lengths are 2.19 Å. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to four equivalent F(2) atoms. All Ag(2)-F(2) bond lengths are 2.07 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Li(1) and two equivalent Ag(1) atoms to form a mixture of corner and edge-sharing FLi2Ag2 tetrahedra. In the second F site, F(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(2) atom.