Cr3Co3(TeO8)2 is Rutile-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Co(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(2), one Co(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Cr(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Cr(1) and one Co(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent Cr(1) and one Co(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(2) and two equivalent Co(2) atoms. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Cr(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to two equivalent Co(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Cr(2), one Co(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Cr(2) and two equivalent Co(2) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Cr(1), one Co(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to two equivalent Co(2) and one Te(2) atom.
Cr3Co3(TeO8)2 is Rutile-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Cr(1)-O(11) bond length is 2.04 Å. The Cr(1)-O(2) bond length is 1.97 Å. The Cr(1)-O(3) bond length is 1.93 Å. The Cr(1)-O(4) bond length is 1.89 Å. The Cr(1)-O(6) bond length is 2.01 Å. The Cr(1)-O(7) bond length is 2.04 Å. In the second Cr site, Cr(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CrO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. The Cr(2)-O(10) bond length is 1.92 Å. The Cr(2)-O(5) bond length is 1.88 Å. Both Cr(2)-O(1) bond lengths are 2.03 Å. Both Cr(2)-O(9) bond lengths are 1.98 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. The Co(1)-O(3) bond length is 1.87 Å. The Co(1)-O(4) bond length is 1.86 Å. Both Co(1)-O(11) bond lengths are 2.01 Å. Both Co(1)-O(6) bond lengths are 1.91 Å. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. The Co(2)-O(1) bond length is 2.00 Å. The Co(2)-O(10) bond length is 1.87 Å. The Co(2)-O(12) bond length is 1.93 Å. The Co(2)-O(5) bond length is 1.88 Å. The Co(2)-O(8) bond length is 2.00 Å. The Co(2)-O(9) bond length is 1.90 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Co(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. The Te(1)-O(2) bond length is 2.02 Å. The Te(1)-O(8) bond length is 1.95 Å. Both Te(1)-O(1) bond lengths are 1.93 Å. Both Te(1)-O(6) bond lengths are 2.02 Å. In the second Te site, Te(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Te(2)-O(12) bond length is 2.03 Å. The Te(2)-O(7) bond length is 1.92 Å. Both Te(2)-O(11) bond lengths are 1.93 Å. Both Te(2)-O(9) bond lengths are 2.03 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(2), one Co(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Cr(1) and one Te(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Cr(1) and one Co(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent Cr(1) and one Co(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(2) and two equivalent Co(2) atoms. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Cr(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to two equivalent Co(2) and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Cr(2), one Co(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Cr(2) and two equivalent Co(2) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Cr(1), one Co(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to two equivalent Co(2) and one Te(2) atom.