AuPd crystallizes in the trigonal R-3m space group. Pd(1) is bonded to six equivalent Pd(1) and six equivalent Au(1) atoms to form PdPd6Au6 cuboctahedra that share corners with twelve equivalent Pd(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Au(1)Pd6Au6 cuboctahedra, faces with six equivalent Pd(1)Pd6Au6 cuboctahedra, and faces with twelve equivalent Au(1)Pd6Au6 cuboctahedra. Au(1) is bonded to six equivalent Pd(1) and six equivalent Au(1) atoms to form AuPd6Au6 cuboctahedra that share corners with twelve equivalent Au(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Au(1)Pd6Au6 cuboctahedra, faces with six equivalent Au(1)Pd6Au6 cuboctahedra, and faces with twelve equivalent Pd(1)Pd6Au6 cuboctahedra.
AuPd crystallizes in the trigonal R-3m space group. Pd(1) is bonded to six equivalent Pd(1) and six equivalent Au(1) atoms to form PdPd6Au6 cuboctahedra that share corners with twelve equivalent Pd(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Au(1)Pd6Au6 cuboctahedra, faces with six equivalent Pd(1)Pd6Au6 cuboctahedra, and faces with twelve equivalent Au(1)Pd6Au6 cuboctahedra. All Pd(1)-Pd(1) bond lengths are 2.85 Å. All Pd(1)-Au(1) bond lengths are 2.83 Å. Au(1) is bonded to six equivalent Pd(1) and six equivalent Au(1) atoms to form AuPd6Au6 cuboctahedra that share corners with twelve equivalent Au(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6Au6 cuboctahedra, edges with twelve equivalent Au(1)Pd6Au6 cuboctahedra, faces with six equivalent Au(1)Pd6Au6 cuboctahedra, and faces with twelve equivalent Pd(1)Pd6Au6 cuboctahedra. All Au(1)-Au(1) bond lengths are 2.85 Å.