V2OF5 crystallizes in the trigonal P312 space group. V(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing VOF5 octahedra. The corner-sharing octahedral tilt angles range from 35-47°. O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.
V2OF5 crystallizes in the trigonal P312 space group. V(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing VOF5 octahedra. The corner-sharing octahedral tilt angles range from 35-47°. The V(1)-O(1) bond length is 1.80 Å. The V(1)-F(1) bond length is 1.98 Å. The V(1)-F(2) bond length is 2.00 Å. The V(1)-F(3) bond length is 1.95 Å. The V(1)-F(4) bond length is 1.95 Å. The V(1)-F(5) bond length is 1.93 Å. O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.