Ba2ZnAs2 crystallizes in the orthorhombic Ibam space group. Ba(1) is bonded in a 8-coordinate geometry to two equivalent Zn(1) and six equivalent As(1) atoms. Zn(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ba(1) and four equivalent As(1) atoms. As(1) is bonded in a 8-coordinate geometry to six equivalent Ba(1) and two equivalent Zn(1) atoms.
Ba2ZnAs2 crystallizes in the orthorhombic Ibam space group. Ba(1) is bonded in a 8-coordinate geometry to two equivalent Zn(1) and six equivalent As(1) atoms. Both Ba(1)-Zn(1) bond lengths are 3.28 Å. There are a spread of Ba(1)-As(1) bond distances ranging from 3.41-3.53 Å. Zn(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ba(1) and four equivalent As(1) atoms. All Zn(1)-As(1) bond lengths are 2.60 Å. As(1) is bonded in a 8-coordinate geometry to six equivalent Ba(1) and two equivalent Zn(1) atoms.