LiVCrP2(HO5)2 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(5), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-59°. In the second Li site, Li(2) is bonded to one O(12), one O(14), one O(15), one O(17), and one O(18) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-59°. In the third Li site, Li(3) is bonded to one O(21), one O(23), one O(25), one O(26), and one O(29) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-59°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(3), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and corners with two equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 45-49°. In the second V site, V(2) is bonded to one O(13), one O(15), one O(16), one O(18), one O(22), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and corners with two equivalent Li(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 45-49°. In the third V site, V(3) is bonded to one O(20), one O(21), one O(24), one O(26), one O(27), and one O(28) atom to form VO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and corners with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 45-49°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(2), one O(26), one O(29), one O(30), and one O(5) atom to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra,  an edgeedge with one Li(1)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 49°. In the second Cr site, Cr(2) is bonded to one O(12), one O(13), one O(14), one O(6), one O(7), and one O(8) atom to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Li(1)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 45°. In the third Cr site, Cr(3) is bonded to one O(17), one O(18), one O(19), one O(23), one O(24), and one O(25) atom to form CrO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent P(4)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra,  an edgeedge with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-49°. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(28), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-52°. In the second P site, P(2) is bonded to one O(10), one O(6), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-52°. In the third P site, P(3) is bonded to one O(11), one O(12), one O(14), and one O(15) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-52°. In the fourth P site, P(4) is bonded to one O(16), one O(17), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. In the fifth P site, P(5) is bonded to one O(21), one O(22), one O(23), and one O(25) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-51°. In the sixth P site, P(6) is bonded to one O(27), one O(29), one O(3), and one O(30) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-52°. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(13) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(18) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(24) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(26) atom. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cr(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(6) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Cr(1), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Cr(2), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(1), one Cr(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(2), one Cr(2), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one V(2), one Cr(2), and one H(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(2), one Cr(2), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one V(2) and one P(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Li(2), one Cr(3), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Li(2), one V(2), one Cr(3), and one H(4) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Cr(3) and one P(4) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(3) and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(3), one V(3), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(5) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Li(3), one Cr(3), and one P(5) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one V(3), one Cr(3), and one H(5) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Li(3), one Cr(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Li(3), one V(3), one Cr(1), and one H(6) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one V(3) and one P(6) atom. In the twenty-eighth O site, O(28) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(1) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Li(3), one Cr(1), and one P(6) atom. In the thirtieth O site, O(30) is bonded in a bent 150 degrees geometry to one Cr(1) and one P(6) atom.
LiVCrP2(HO5)2 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(5), one O(6), and one O(8) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-59°. The Li(1)-O(10) bond length is 2.36 Å. The Li(1)-O(2) bond length is 2.00 Å. The Li(1)-O(5) bond length is 2.05 Å. The Li(1)-O(6) bond length is 1.97 Å. The Li(1)-O(8) bond length is 2.10 Å. In the second Li site, Li(2) is bonded to one O(12), one O(14), one O(15), one O(17), and one O(18) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-59°. The Li(2)-O(12) bond length is 2.09 Å. The Li(2)-O(14) bond length is 1.97 Å. The Li(2)-O(15) bond length is 2.36 Å. The Li(2)-O(17) bond length is 2.00 Å. The Li(2)-O(18) bond length is 2.05 Å. In the third Li site, Li(3) is bonded to one O(21), one O(23), one O(25), one O(26), and one O(29) atom to form distorted LiO5 trigonal bipyramids that share corners with two equivalent V(3)O6 octahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-59°. The Li(3)-O(21) bond length is 2.37 Å. The Li(3)-O(23) bond length is 2.08 Å. The Li(3)-O(25) bond length is 1.96 Å. The Li(3)-O(26) bond length is 2.05 Å. The Li(3)-O(29) bond length is 2.01 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(3), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and corners with two equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 45-49°. The V(1)-O(10) bond length is 1.99 Å. The V(1)-O(11) bond length is 2.00 Å. The V(1)-O(3) bond length is 1.97 Å. The V(1)-O(4) bond length is 1.89 Å. The V(1)-O(5) bond length is 2.03 Å. The V(1)-O(7) bond length is 1.94 Å. In the second V site, V(2) is bonded to one O(13), one O(15), one O(16), one O(18), one O(22), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and corners with two equivalent Li(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 45-49°. The V(2)-O(13) bond length is 1.94 Å. The V(2)-O(15) bond length is 1.98 Å. The V(2)-O(16) bond length is 1.89 Å. The V(2)-O(18) bond length is 2.04 Å. The V(2)-O(22) bond length is 1.99 Å. The V(2)-O(9) bond length is 1.99 Å. In the third V site, V(3) is bonded to one O(20), one O(21), one O(24), one O(26), one O(27), and one O(28) atom to form VO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and corners with two equivalent Li(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 45-49°. The V(3)-O(20) bond length is 1.98 Å. The V(3)-O(21) bond length is 1.98 Å. The V(3)-O(24) bond length is 1.94 Å. The V(3)-O(26) bond length is 2.03 Å. The V(3)-O(27) bond length is 1.89 Å. The V(3)-O(28) bond length is 1.98 Å. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(2), one O(26), one O(29), one O(30), and one O(5) atom to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra,  an edgeedge with one Li(1)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 49°. The Cr(1)-O(1) bond length is 1.97 Å. The Cr(1)-O(2) bond length is 2.00 Å. The Cr(1)-O(26) bond length is 2.05 Å. The Cr(1)-O(29) bond length is 2.00 Å. The Cr(1)-O(30) bond length is 1.97 Å. The Cr(1)-O(5) bond length is 2.05 Å. In the second Cr site, Cr(2) is bonded to one O(12), one O(13), one O(14), one O(6), one O(7), and one O(8) atom to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Li(1)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 45°. The Cr(2)-O(12) bond length is 1.99 Å. The Cr(2)-O(13) bond length is 2.01 Å. The Cr(2)-O(14) bond length is 2.01 Å. The Cr(2)-O(6) bond length is 2.01 Å. The Cr(2)-O(7) bond length is 2.01 Å. The Cr(2)-O(8) bond length is 1.99 Å. In the third Cr site, Cr(3) is bonded to one O(17), one O(18), one O(19), one O(23), one O(24), and one O(25) atom to form CrO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent P(4)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra,  an edgeedge with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-49°. The Cr(3)-O(17) bond length is 2.00 Å. The Cr(3)-O(18) bond length is 2.05 Å. The Cr(3)-O(19) bond length is 1.96 Å. The Cr(3)-O(23) bond length is 2.00 Å. The Cr(3)-O(24) bond length is 2.01 Å. The Cr(3)-O(25) bond length is 2.01 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(28), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-52°. The P(1)-O(1) bond length is 1.52 Å. The P(1)-O(2) bond length is 1.54 Å. The P(1)-O(28) bond length is 1.57 Å. The P(1)-O(4) bond length is 1.57 Å. In the second P site, P(2) is bonded to one O(10), one O(6), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-52°. The P(2)-O(10) bond length is 1.56 Å. The P(2)-O(6) bond length is 1.54 Å. The P(2)-O(8) bond length is 1.54 Å. The P(2)-O(9) bond length is 1.57 Å. In the third P site, P(3) is bonded to one O(11), one O(12), one O(14), and one O(15) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  a cornercorner with one Li(2)O5 trigonal bipyramid, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-52°. The P(3)-O(11) bond length is 1.57 Å. The P(3)-O(12) bond length is 1.54 Å. The P(3)-O(14) bond length is 1.54 Å. The P(3)-O(15) bond length is 1.56 Å. In the fourth P site, P(4) is bonded to one O(16), one O(17), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. The P(4)-O(16) bond length is 1.57 Å. The P(4)-O(17) bond length is 1.54 Å. The P(4)-O(19) bond length is 1.52 Å. The P(4)-O(20) bond length is 1.57 Å. In the fifth P site, P(5) is bonded to one O(21), one O(22), one O(23), and one O(25) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-51°. The P(5)-O(21) bond length is 1.56 Å. The P(5)-O(22) bond length is 1.57 Å. The P(5)-O(23) bond length is 1.54 Å. The P(5)-O(25) bond length is 1.54 Å. In the sixth P site, P(6) is bonded to one O(27), one O(29), one O(3), and one O(30) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-52°. The P(6)-O(27) bond length is 1.57 Å. The P(6)-O(29) bond length is 1.54 Å. The P(6)-O(3) bond length is 1.57 Å. The P(6)-O(30) bond length is 1.52 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. The H(2)-O(7) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(13) atom. The H(3)-O(13) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(18) atom. The H(4)-O(18) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(24) atom. The H(5)-O(24) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(26) atom. The H(6)-O(26) bond length is 0.99 Å. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cr(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(6) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Cr(1), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one V(1), one Cr(2), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(1), one Cr(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(2), one Cr(2), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one V(2), one Cr(2), and one H(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(2), one Cr(2), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(2), one V(2), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one V(2) and one P(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Li(2), one Cr(3), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Li(2), one V(2), one Cr(3), and one H(4) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Cr(3) and one P(4) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(3) and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(3), one V(3), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one V(2) and one P(5) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Li(3), one Cr(3), and one P(5) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one V(3), one Cr(3), and one H(5) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Li(3), one Cr(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Li(3), one V(3), one Cr(1), and one H(6) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one V(3) and one P(6) atom. In the twenty-eighth O site, O(28) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(1) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Li(3), one Cr(1), and one P(6) atom. In the thirtieth O site, O(30) is bonded in a bent 150 degrees geometry to one Cr(1) and one P(6) atom.