WCO2 crystallizes in the tetragonal P4/mmm space group. W(1) is bonded to two equivalent C(1) and four equivalent O(1) atoms to form corner-sharing WC2O4 octahedra. The corner-sharing octahedra are not tilted. C(1) is bonded in a linear geometry to two equivalent W(1) atoms. O(1) is bonded in a linear geometry to two equivalent W(1) atoms.
WCO2 crystallizes in the tetragonal P4/mmm space group. W(1) is bonded to two equivalent C(1) and four equivalent O(1) atoms to form corner-sharing WC2O4 octahedra. The corner-sharing octahedra are not tilted. Both W(1)-C(1) bond lengths are 2.11 Å. All W(1)-O(1) bond lengths are 1.94 Å. C(1) is bonded in a linear geometry to two equivalent W(1) atoms. O(1) is bonded in a linear geometry to two equivalent W(1) atoms.