NaMgN crystallizes in the hexagonal P6_3mc space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. Mg(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded in a 7-coordinate geometry to four equivalent Na(1) and three equivalent Mg(1) atoms.
NaMgN crystallizes in the hexagonal P6_3mc space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. There are three shorter (2.69 Å) and one longer (2.70 Å) Na(1)-N(1) bond length. Mg(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All Mg(1)-N(1) bond lengths are 2.07 Å. N(1) is bonded in a 7-coordinate geometry to four equivalent Na(1) and three equivalent Mg(1) atoms.