(K)2HgTlCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a HgTlCl6 framework. In the HgTlCl6 framework, Hg(1) is bonded to six equivalent Cl(1) atoms to form HgCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent Hg(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Hg(1) and one Tl(1) atom.
(K)2HgTlCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a HgTlCl6 framework. In the HgTlCl6 framework, Hg(1) is bonded to six equivalent Cl(1) atoms to form HgCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Hg(1)-Cl(1) bond lengths are 2.68 Å. Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent Hg(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Cl(1) bond lengths are 2.76 Å. Cl(1) is bonded in a linear geometry to one Hg(1) and one Tl(1) atom.