Ag2HgSI2 crystallizes in the orthorhombic Cmc2_1 space group. Ag(1) is bonded to one S(1) and three equivalent I(1) atoms to form corner-sharing AgSI3 tetrahedra. Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. S(1) is bonded to two equivalent Ag(1) and two equivalent Hg(1) atoms to form corner-sharing SAg2Hg2 trigonal pyramids. I(1) is bonded in a trigonal non-coplanar geometry to three equivalent Ag(1) atoms.
Ag2HgSI2 crystallizes in the orthorhombic Cmc2_1 space group. Ag(1) is bonded to one S(1) and three equivalent I(1) atoms to form corner-sharing AgSI3 tetrahedra. The Ag(1)-S(1) bond length is 2.60 Å. There are a spread of Ag(1)-I(1) bond distances ranging from 2.85-2.93 Å. Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. There is one shorter (2.41 Å) and one longer (2.42 Å) Hg(1)-S(1) bond length. S(1) is bonded to two equivalent Ag(1) and two equivalent Hg(1) atoms to form corner-sharing SAg2Hg2 trigonal pyramids. I(1) is bonded in a trigonal non-coplanar geometry to three equivalent Ag(1) atoms.