Ga2(TeO3)3 crystallizes in the hexagonal P6_3/m space group. Ga(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form face-sharing GaO6 octahedra. Te(1) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Ga(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ga(1) and one Te(1) atom.
Ga2(TeO3)3 crystallizes in the hexagonal P6_3/m space group. Ga(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form face-sharing GaO6 octahedra. All Ga(1)-O(1) bond lengths are 2.05 Å. All Ga(1)-O(2) bond lengths are 1.93 Å. Te(1) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(2) atoms. The Te(1)-O(1) bond length is 1.91 Å. Both Te(1)-O(2) bond lengths are 1.89 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Ga(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ga(1) and one Te(1) atom.