LaCrReO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 12-coordinate geometry to one Cr(1), one Re(1), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. Cr(1) is bonded in a linear geometry to one La(1), one O(1), one O(4), one O(5), and one O(6) atom. Re(1) is bonded in a distorted linear geometry to one La(1), one O(1), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent La(1), one Cr(1), and one Re(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent La(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent La(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent La(1), one Cr(1), and one Re(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent La(1), one Cr(1), and one Re(1) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Cr(1) and one Re(1) atom.
LaCrReO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 12-coordinate geometry to one Cr(1), one Re(1), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. The La(1)-Cr(1) bond length is 2.37 Å. The La(1)-Re(1) bond length is 2.38 Å. There is one shorter (2.45 Å) and one longer (3.05 Å) La(1)-O(1) bond length. There is one shorter (2.53 Å) and one longer (2.95 Å) La(1)-O(2) bond length. There is one shorter (2.55 Å) and one longer (2.94 Å) La(1)-O(3) bond length. There is one shorter (2.72 Å) and one longer (2.80 Å) La(1)-O(4) bond length. There is one shorter (2.72 Å) and one longer (2.78 Å) La(1)-O(5) bond length. Cr(1) is bonded in a linear geometry to one La(1), one O(1), one O(4), one O(5), and one O(6) atom. The Cr(1)-O(1) bond length is 2.59 Å. The Cr(1)-O(4) bond length is 1.46 Å. The Cr(1)-O(5) bond length is 1.42 Å. The Cr(1)-O(6) bond length is 2.56 Å. Re(1) is bonded in a distorted linear geometry to one La(1), one O(1), one O(4), one O(5), and one O(6) atom. The Re(1)-O(1) bond length is 2.18 Å. The Re(1)-O(4) bond length is 1.34 Å. The Re(1)-O(5) bond length is 1.35 Å. The Re(1)-O(6) bond length is 2.20 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent La(1), one Cr(1), and one Re(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent La(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent La(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent La(1), one Cr(1), and one Re(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to two equivalent La(1), one Cr(1), and one Re(1) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Cr(1) and one Re(1) atom.