CsNO3 crystallizes in the triclinic P1 space group. There are nine inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one O(10), one O(12), one O(16), one O(17), one O(19), one O(2), one O(20), one O(25), one O(26), one O(4), and one O(6) atom. In the second Cs site, Cs(2) is bonded in a 12-coordinate geometry to one O(11), one O(14), one O(15), one O(17), one O(21), one O(22), one O(24), one O(25), one O(27), one O(3), one O(8), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 11-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(16), one O(24), one O(26), one O(4), one O(7), one O(8), and one O(9) atom. In the fourth Cs site, Cs(4) is bonded in a 12-coordinate geometry to one O(13), one O(15), one O(17), one O(18), one O(19), one O(2), one O(20), one O(24), one O(3), one O(6), one O(7), and one O(9) atom. In the fifth Cs site, Cs(5) is bonded in a 12-coordinate geometry to one O(1), one O(12), one O(13), one O(16), one O(18), one O(21), one O(23), one O(24), one O(27), one O(5), one O(6), and one O(7) atom. In the sixth Cs site, Cs(6) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(12), one O(14), one O(15), one O(18), one O(2), one O(21), one O(22), one O(26), one O(5), and one O(8) atom. In the seventh Cs site, Cs(7) is bonded in a 12-coordinate geometry to one O(1), one O(11), one O(12), one O(17), one O(19), one O(2), one O(23), one O(26), one O(27), one O(3), one O(5), and one O(9) atom. In the eighth Cs site, Cs(8) is bonded in a 12-coordinate geometry to one O(11), one O(13), one O(14), one O(18), one O(19), one O(20), one O(21), one O(22), one O(25), one O(4), one O(5), and one O(6) atom. In the ninth Cs site, Cs(9) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(11), one O(16), one O(22), one O(23), one O(25), one O(27), one O(3), one O(4), and one O(7) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(12), one O(14), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(17), one O(19), and one O(24) atom. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one O(2), one O(27), and one O(3) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(18) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one O(21), one O(22), and one O(6) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one O(23), one O(25), and one O(4) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one O(10), one O(20), and one O(26) atom. In the eighth N site, N(9) is bonded in a trigonal planar geometry to one O(16), one O(7), and one O(8) atom. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(9), and one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cs(1); one Cs(4); one Cs(6); one Cs(7); and one N(3,4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(2); one Cs(4); one Cs(7); one Cs(9); and one N(3,4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(8), one Cs(9), and one N(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(8), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(5), one Cs(8), and one N(6) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(9), and one N(9) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), and one N(9) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(7); and one N(3,4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(9), and one N(8) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cs(2); one Cs(7); one Cs(8); one Cs(9); and one N(3,4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cs(1), one Cs(5), one Cs(6), one Cs(7), and one N(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(8), and one N(5) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(8), and one N(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(6); and one N(3,4) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(5), one Cs(9), and one N(9) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Cs(1), one Cs(2), one Cs(4), one Cs(7), and one N(2) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one Cs(4), one Cs(5), one Cs(6), one Cs(8), and one N(5) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), one Cs(7), one Cs(8), and one N(2) atom. In the twentieth O site, O(20) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(8), and one N(8) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Cs(2), one Cs(5), one Cs(6), one Cs(8), and one N(6) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Cs(2), one Cs(6), one Cs(8), one Cs(9), and one N(6) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one Cs(5), one Cs(7), one Cs(9), and one N(7) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(5), and one N(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(8), one Cs(9), and one N(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(7), and one N(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(5); one Cs(7); one Cs(9); and one N(3,4) atom.
CsNO3 crystallizes in the triclinic P1 space group. There are nine inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one O(10), one O(12), one O(16), one O(17), one O(19), one O(2), one O(20), one O(25), one O(26), one O(4), and one O(6) atom. The Cs(1)-O(10) bond length is 3.17 Å. The Cs(1)-O(12) bond length is 3.16 Å. The Cs(1)-O(16) bond length is 3.24 Å. The Cs(1)-O(17) bond length is 3.18 Å. The Cs(1)-O(19) bond length is 3.45 Å. The Cs(1)-O(2) bond length is 3.24 Å. The Cs(1)-O(20) bond length is 3.55 Å. The Cs(1)-O(25) bond length is 3.34 Å. The Cs(1)-O(26) bond length is 3.25 Å. The Cs(1)-O(4) bond length is 3.21 Å. The Cs(1)-O(6) bond length is 3.15 Å. In the second Cs site, Cs(2) is bonded in a 12-coordinate geometry to one O(11), one O(14), one O(15), one O(17), one O(21), one O(22), one O(24), one O(25), one O(27), one O(3), one O(8), and one O(9) atom. The Cs(2)-O(11) bond length is 3.45 Å. The Cs(2)-O(14) bond length is 3.32 Å. The Cs(2)-O(15) bond length is 3.18 Å. The Cs(2)-O(17) bond length is 3.19 Å. The Cs(2)-O(21) bond length is 3.18 Å. The Cs(2)-O(22) bond length is 3.43 Å. The Cs(2)-O(24) bond length is 3.56 Å. The Cs(2)-O(25) bond length is 3.14 Å. The Cs(2)-O(27) bond length is 3.50 Å. The Cs(2)-O(3) bond length is 3.23 Å. The Cs(2)-O(8) bond length is 3.14 Å. The Cs(2)-O(9) bond length is 3.14 Å. In the third Cs site, Cs(3) is bonded in a 11-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(16), one O(24), one O(26), one O(4), one O(7), one O(8), and one O(9) atom. The Cs(3)-O(10) bond length is 3.22 Å. The Cs(3)-O(13) bond length is 3.16 Å. The Cs(3)-O(14) bond length is 3.14 Å. The Cs(3)-O(15) bond length is 3.46 Å. The Cs(3)-O(16) bond length is 3.17 Å. The Cs(3)-O(24) bond length is 3.23 Å. The Cs(3)-O(26) bond length is 3.34 Å. The Cs(3)-O(4) bond length is 3.24 Å. The Cs(3)-O(7) bond length is 3.25 Å. The Cs(3)-O(8) bond length is 3.55 Å. The Cs(3)-O(9) bond length is 3.18 Å. In the fourth Cs site, Cs(4) is bonded in a 12-coordinate geometry to one O(13), one O(15), one O(17), one O(18), one O(19), one O(2), one O(20), one O(24), one O(3), one O(6), one O(7), and one O(9) atom. The Cs(4)-O(13) bond length is 3.43 Å. The Cs(4)-O(15) bond length is 3.50 Å. The Cs(4)-O(17) bond length is 3.14 Å. The Cs(4)-O(18) bond length is 3.19 Å. The Cs(4)-O(19) bond length is 3.18 Å. The Cs(4)-O(2) bond length is 3.55 Å. The Cs(4)-O(20) bond length is 3.14 Å. The Cs(4)-O(24) bond length is 3.46 Å. The Cs(4)-O(3) bond length is 3.19 Å. The Cs(4)-O(6) bond length is 3.32 Å. The Cs(4)-O(7) bond length is 3.14 Å. The Cs(4)-O(9) bond length is 3.24 Å. In the fifth Cs site, Cs(5) is bonded in a 12-coordinate geometry to one O(1), one O(12), one O(13), one O(16), one O(18), one O(21), one O(23), one O(24), one O(27), one O(5), one O(6), and one O(7) atom. The Cs(5)-O(1) bond length is 3.45 Å. The Cs(5)-O(12) bond length is 3.60 Å. The Cs(5)-O(13) bond length is 3.20 Å. The Cs(5)-O(16) bond length is 3.18 Å. The Cs(5)-O(18) bond length is 3.19 Å. The Cs(5)-O(21) bond length is 3.20 Å. The Cs(5)-O(23) bond length is 3.19 Å. The Cs(5)-O(24) bond length is 3.16 Å. The Cs(5)-O(27) bond length is 3.13 Å. The Cs(5)-O(5) bond length is 3.18 Å. The Cs(5)-O(6) bond length is 3.46 Å. The Cs(5)-O(7) bond length is 3.41 Å. In the sixth Cs site, Cs(6) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(12), one O(14), one O(15), one O(18), one O(2), one O(21), one O(22), one O(26), one O(5), and one O(8) atom. The Cs(6)-O(1) bond length is 3.46 Å. The Cs(6)-O(10) bond length is 3.18 Å. The Cs(6)-O(12) bond length is 3.20 Å. The Cs(6)-O(14) bond length is 3.44 Å. The Cs(6)-O(15) bond length is 3.13 Å. The Cs(6)-O(18) bond length is 3.20 Å. The Cs(6)-O(2) bond length is 3.16 Å. The Cs(6)-O(21) bond length is 3.18 Å. The Cs(6)-O(22) bond length is 3.59 Å. The Cs(6)-O(26) bond length is 3.42 Å. The Cs(6)-O(5) bond length is 3.20 Å. The Cs(6)-O(8) bond length is 3.20 Å. In the seventh Cs site, Cs(7) is bonded in a 12-coordinate geometry to one O(1), one O(11), one O(12), one O(17), one O(19), one O(2), one O(23), one O(26), one O(27), one O(3), one O(5), and one O(9) atom. The Cs(7)-O(1) bond length is 3.31 Å. The Cs(7)-O(11) bond length is 3.55 Å. The Cs(7)-O(12) bond length is 3.43 Å. The Cs(7)-O(17) bond length is 3.24 Å. The Cs(7)-O(19) bond length is 3.49 Å. The Cs(7)-O(2) bond length is 3.45 Å. The Cs(7)-O(23) bond length is 3.14 Å. The Cs(7)-O(26) bond length is 3.14 Å. The Cs(7)-O(27) bond length is 3.17 Å. The Cs(7)-O(3) bond length is 3.14 Å. The Cs(7)-O(5) bond length is 3.18 Å. The Cs(7)-O(9) bond length is 3.19 Å. In the eighth Cs site, Cs(8) is bonded in a 12-coordinate geometry to one O(11), one O(13), one O(14), one O(18), one O(19), one O(20), one O(21), one O(22), one O(25), one O(4), one O(5), and one O(6) atom. The Cs(8)-O(11) bond length is 3.16 Å. The Cs(8)-O(13) bond length is 3.59 Å. The Cs(8)-O(14) bond length is 3.46 Å. The Cs(8)-O(18) bond length is 3.18 Å. The Cs(8)-O(19) bond length is 3.13 Å. The Cs(8)-O(20) bond length is 3.19 Å. The Cs(8)-O(21) bond length is 3.19 Å. The Cs(8)-O(22) bond length is 3.20 Å. The Cs(8)-O(25) bond length is 3.42 Å. The Cs(8)-O(4) bond length is 3.18 Å. The Cs(8)-O(5) bond length is 3.20 Å. The Cs(8)-O(6) bond length is 3.44 Å. In the ninth Cs site, Cs(9) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(11), one O(16), one O(22), one O(23), one O(25), one O(27), one O(3), one O(4), and one O(7) atom. The Cs(9)-O(1) bond length is 3.14 Å. The Cs(9)-O(10) bond length is 3.24 Å. The Cs(9)-O(11) bond length is 3.23 Å. The Cs(9)-O(16) bond length is 3.22 Å. The Cs(9)-O(22) bond length is 3.16 Å. The Cs(9)-O(23) bond length is 3.54 Å. The Cs(9)-O(25) bond length is 3.25 Å. The Cs(9)-O(27) bond length is 3.46 Å. The Cs(9)-O(3) bond length is 3.17 Å. The Cs(9)-O(4) bond length is 3.16 Å. The Cs(9)-O(7) bond length is 3.34 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(12), one O(14), and one O(5) atom. The N(1)-O(12) bond length is 1.26 Å. The N(1)-O(14) bond length is 1.26 Å. The N(1)-O(5) bond length is 1.27 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(17), one O(19), and one O(24) atom. The N(2)-O(17) bond length is 1.27 Å. The N(2)-O(19) bond length is 1.26 Å. The N(2)-O(24) bond length is 1.26 Å. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one O(2), one O(27), and one O(3) atom. The N(3,4)-O(2) bond length is 1.26 Å. The N(3,4)-O(27) bond length is 1.26 Å. The N(3,4)-O(3) bond length is 1.27 Å. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(18) atom. The N(5)-O(1) bond length is 1.26 Å. The N(5)-O(13) bond length is 1.26 Å. The N(5)-O(18) bond length is 1.27 Å. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one O(21), one O(22), and one O(6) atom. The N(6)-O(21) bond length is 1.27 Å. The N(6)-O(22) bond length is 1.26 Å. The N(6)-O(6) bond length is 1.26 Å. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one O(23), one O(25), and one O(4) atom. The N(7)-O(23) bond length is 1.25 Å. The N(7)-O(25) bond length is 1.26 Å. The N(7)-O(4) bond length is 1.27 Å. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one O(10), one O(20), and one O(26) atom. The N(8)-O(10) bond length is 1.27 Å. The N(8)-O(20) bond length is 1.25 Å. The N(8)-O(26) bond length is 1.26 Å. In the eighth N site, N(9) is bonded in a trigonal planar geometry to one O(16), one O(7), and one O(8) atom. The N(9)-O(16) bond length is 1.27 Å. The N(9)-O(7) bond length is 1.26 Å. The N(9)-O(8) bond length is 1.25 Å. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(9), and one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cs(1); one Cs(4); one Cs(6); one Cs(7); and one N(3,4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(2); one Cs(4); one Cs(7); one Cs(9); and one N(3,4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(8), one Cs(9), and one N(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(8), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(5), one Cs(8), and one N(6) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(9), and one N(9) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), and one N(9) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(7); and one N(3,4) atom. The O(9)-N(3,4) bond length is 1.27 Å. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(9), and one N(8) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cs(2); one Cs(7); one Cs(8); one Cs(9); and one N(3,4) atom. The O(11)-N(3,4) bond length is 1.26 Å. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cs(1), one Cs(5), one Cs(6), one Cs(7), and one N(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(8), and one N(5) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(8), and one N(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(6); and one N(3,4) atom. The O(15)-N(3,4) bond length is 1.26 Å. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(5), one Cs(9), and one N(9) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Cs(1), one Cs(2), one Cs(4), one Cs(7), and one N(2) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one Cs(4), one Cs(5), one Cs(6), one Cs(8), and one N(5) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), one Cs(7), one Cs(8), and one N(2) atom. In the twentieth O site, O(20) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(8), and one N(8) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Cs(2), one Cs(5), one Cs(6), one Cs(8), and one N(6) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Cs(2), one Cs(6), one Cs(8), one Cs(9), and one N(6) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one Cs(5), one Cs(7), one Cs(9), and one N(7) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(5), and one N(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(8), one Cs(9), and one N(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(7), and one N(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(5); one Cs(7); one Cs(9); and one N(3,4) atom.