La2BiO2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. La(1) is bonded in a 4-coordinate geometry to four equivalent Bi(1) and four equivalent O(1) atoms. Bi(1) is bonded in a body-centered cubic geometry to eight equivalent La(1) atoms. O(1) is bonded to four equivalent La(1) atoms to form a mixture of corner and edge-sharing OLa4 tetrahedra.
La2BiO2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. La(1) is bonded in a 4-coordinate geometry to four equivalent Bi(1) and four equivalent O(1) atoms. All La(1)-Bi(1) bond lengths are 3.71 Å. All La(1)-O(1) bond lengths are 2.37 Å. Bi(1) is bonded in a body-centered cubic geometry to eight equivalent La(1) atoms. O(1) is bonded to four equivalent La(1) atoms to form a mixture of corner and edge-sharing OLa4 tetrahedra.