NiCl6 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two NiCl4 clusters. In each NiCl4 cluster, Ni(1) is bonded in a square co-planar geometry to four equivalent Cl(2) atoms. Cl(2) is bonded in a single-bond geometry to one Ni(1) atom.
NiCl6 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two NiCl4 clusters. In each NiCl4 cluster, Ni(1) is bonded in a square co-planar geometry to four equivalent Cl(2) atoms. All Ni(1)-Cl(2) bond lengths are 2.11 Å. Cl(2) is bonded in a single-bond geometry to one Ni(1) atom.