PdMnGe crystallizes in the hexagonal P-62m space group. Mn(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1), one Ge(1), and four equivalent Ge(2) atoms. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Mn(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to three equivalent Mn(1) and six equivalent Pd(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to six equivalent Mn(1) and three equivalent Pd(1) atoms.
PdMnGe crystallizes in the hexagonal P-62m space group. Mn(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1), one Ge(1), and four equivalent Ge(2) atoms. There are two shorter (2.84 Å) and four longer (2.97 Å) Mn(1)-Pd(1) bond lengths. The Mn(1)-Ge(1) bond length is 2.69 Å. All Mn(1)-Ge(2) bond lengths are 2.70 Å. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Mn(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. Both Pd(1)-Ge(1) bond lengths are 2.51 Å. Both Pd(1)-Ge(2) bond lengths are 2.49 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to three equivalent Mn(1) and six equivalent Pd(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to six equivalent Mn(1) and three equivalent Pd(1) atoms.