Na3N is Cementite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. In the second Na site, Na(2) is bonded in a distorted trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded in a 9-coordinate geometry to three equivalent Na(1) and six equivalent Na(2) atoms.
Na3N is Cementite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. There are a spread of Na(1)-N(1) bond distances ranging from 2.51-2.93 Å. In the second Na site, Na(2) is bonded in a distorted trigonal planar geometry to three equivalent N(1) atoms. There are a spread of Na(2)-N(1) bond distances ranging from 2.57-2.62 Å. N(1) is bonded in a 9-coordinate geometry to three equivalent Na(1) and six equivalent Na(2) atoms.