Cu3(WO3)4Zn crystallizes in the triclinic P-1 space group. The structure consists of one 7440-66-6 atom inside a Cu3(WO3)4 framework. In the Cu3(WO3)4 framework, there are four inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 34-38°. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. In the third W site, W(3) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 34-39°. In the fourth W site, W(4) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 35-41°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to two equivalent O(3) and two equivalent O(6) atoms. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(2), one W(4), and one Cu(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one W(3), and one Cu(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(2), one W(3), and one Cu(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one W(3), one W(4), and one Cu(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Cu(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one W(1), one W(4), and one Cu(1) atom.
Cu3(WO3)4Zn crystallizes in the triclinic P-1 space group. The structure consists of one 7440-66-6 atom inside a Cu3(WO3)4 framework. In the Cu3(WO3)4 framework, there are four inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 34-38°. Both W(1)-O(2) bond lengths are 1.95 Å. Both W(1)-O(5) bond lengths are 2.04 Å. Both W(1)-O(6) bond lengths are 2.07 Å. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. Both W(2)-O(1) bond lengths are 2.06 Å. Both W(2)-O(3) bond lengths are 1.96 Å. Both W(2)-O(5) bond lengths are 2.05 Å. In the third W site, W(3) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 34-39°. Both W(3)-O(2) bond lengths are 2.06 Å. Both W(3)-O(3) bond lengths are 2.12 Å. Both W(3)-O(4) bond lengths are 2.04 Å. In the fourth W site, W(4) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 35-41°. Both W(4)-O(1) bond lengths are 2.05 Å. Both W(4)-O(4) bond lengths are 2.05 Å. Both W(4)-O(6) bond lengths are 1.98 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to two equivalent O(3) and two equivalent O(6) atoms. Both Cu(1)-O(3) bond lengths are 2.07 Å. Both Cu(1)-O(6) bond lengths are 2.13 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Cu(2)-O(1) bond lengths are 2.02 Å. Both Cu(2)-O(2) bond lengths are 2.16 Å. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(5) atoms. Both Cu(3)-O(4) bond lengths are 2.09 Å. Both Cu(3)-O(5) bond lengths are 2.06 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(2), one W(4), and one Cu(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one W(3), and one Cu(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(2), one W(3), and one Cu(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one W(3), one W(4), and one Cu(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Cu(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one W(1), one W(4), and one Cu(1) atom.