TlMo2O2Cl7 is Indium-derived structured and crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two Mo2O2Cl7 clusters. In each Mo2O2Cl7 cluster, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one Cl(2), two equivalent Cl(1), and two equivalent Cl(3) atoms. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to two equivalent Mo(1) atoms. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to two equivalent Mo(1) atoms. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom.
TlMo2O2Cl7 is Indium-derived structured and crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two Mo2O2Cl7 clusters. In each Mo2O2Cl7 cluster, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one Cl(2), two equivalent Cl(1), and two equivalent Cl(3) atoms. The Mo(1)-O(1) bond length is 1.70 Å. The Mo(1)-Cl(2) bond length is 2.69 Å. Both Mo(1)-Cl(1) bond lengths are 2.53 Å. Both Mo(1)-Cl(3) bond lengths are 2.35 Å. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to two equivalent Mo(1) atoms. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to two equivalent Mo(1) atoms. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom.