Sr2RuO6 crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. Ru(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Sr(1), one Ru(1), and one O(3) atom. In the second O site, O(2) is bonded in a T-shaped geometry to two equivalent Sr(1) and one Ru(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Sr(1) and one O(1) atom.
Sr2RuO6 crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. There is one shorter (2.49 Å) and one longer (2.50 Å) Sr(1)-O(1) bond length. There is one shorter (2.56 Å) and one longer (2.64 Å) Sr(1)-O(2) bond length. There are a spread of Sr(1)-O(3) bond distances ranging from 2.51-2.66 Å. Ru(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ru(1)-O(1) bond lengths are 2.04 Å. Both Ru(1)-O(2) bond lengths are 1.79 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Sr(1), one Ru(1), and one O(3) atom. The O(1)-O(3) bond length is 1.47 Å. In the second O site, O(2) is bonded in a T-shaped geometry to two equivalent Sr(1) and one Ru(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Sr(1) and one O(1) atom.