PtCl6(RhN5Cl2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two PtCl6 clusters and four RhN5Cl2 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Pt(1) atom. In each RhN5Cl2 cluster, Rh(1) is bonded in a distorted octahedral geometry to one N(1), two equivalent N(2), two equivalent N(3), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(5) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Rh(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom.
PtCl6(RhN5Cl2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two PtCl6 clusters and four RhN5Cl2 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Both Pt(1)-Cl(2) bond lengths are 2.33 Å. Both Pt(1)-Cl(3) bond lengths are 2.33 Å. Both Pt(1)-Cl(4) bond lengths are 2.33 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Pt(1) atom. In each RhN5Cl2 cluster, Rh(1) is bonded in a distorted octahedral geometry to one N(1), two equivalent N(2), two equivalent N(3), and one Cl(1) atom. The Rh(1)-N(1) bond length is 1.92 Å. Both Rh(1)-N(2) bond lengths are 2.18 Å. Both Rh(1)-N(3) bond lengths are 1.85 Å. The Rh(1)-Cl(1) bond length is 2.35 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(5) atom. The N(1)-Cl(5) bond length is 1.59 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Rh(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom.