PrBiO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Pr(1) is bonded to twelve equivalent O(1) atoms to form PrO12 cuboctahedra that share corners with twelve equivalent Pr(1)O12 cuboctahedra, faces with six equivalent Pr(1)O12 cuboctahedra, and faces with eight equivalent Bi(1)O6 octahedra. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra and faces with eight equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Pr(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge, face, and corner-sharing OPr4Bi2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
PrBiO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Pr(1) is bonded to twelve equivalent O(1) atoms to form PrO12 cuboctahedra that share corners with twelve equivalent Pr(1)O12 cuboctahedra, faces with six equivalent Pr(1)O12 cuboctahedra, and faces with eight equivalent Bi(1)O6 octahedra. All Pr(1)-O(1) bond lengths are 3.15 Å. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra and faces with eight equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Bi(1)-O(1) bond lengths are 2.22 Å. O(1) is bonded to four equivalent Pr(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge, face, and corner-sharing OPr4Bi2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.