Ba2ZnUO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent U(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent U(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent Ba(1), one U(1), and one Zn(1) atom.
Ba2ZnUO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent U(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. All Ba(1)-O(1) bond lengths are 3.01 Å. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All U(1)-O(1) bond lengths are 2.09 Å. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent U(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Zn(1)-O(1) bond lengths are 2.16 Å. O(1) is bonded in a distorted linear geometry to four equivalent Ba(1), one U(1), and one Zn(1) atom.