LiInW2O8 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted LiO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-53°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one In(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one In(1) atom.
LiInW2O8 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted LiO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. Both Li(1)-O(2) bond lengths are 2.39 Å. Both Li(1)-O(3) bond lengths are 2.15 Å. Both Li(1)-O(4) bond lengths are 2.17 Å. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. The W(1)-O(2) bond length is 1.84 Å. The W(1)-O(4) bond length is 1.83 Å. There is one shorter (2.00 Å) and one longer (2.17 Å) W(1)-O(1) bond length. There is one shorter (1.92 Å) and one longer (2.10 Å) W(1)-O(3) bond length. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-53°. Both In(1)-O(1) bond lengths are 2.17 Å. Both In(1)-O(2) bond lengths are 2.16 Å. Both In(1)-O(4) bond lengths are 2.22 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one In(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one In(1) atom.