NaMgN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. Mg(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing MgN4 tetrahedra. N(1) is bonded in a 7-coordinate geometry to three equivalent Na(1) and four equivalent Mg(1) atoms.
NaMgN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. There is one shorter (2.44 Å) and two longer (2.55 Å) Na(1)-N(1) bond lengths. Mg(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing MgN4 tetrahedra. There are two shorter (2.20 Å) and two longer (2.25 Å) Mg(1)-N(1) bond lengths. N(1) is bonded in a 7-coordinate geometry to three equivalent Na(1) and four equivalent Mg(1) atoms.