UOF4 crystallizes in the trigonal R3m space group. U(1) is bonded to one O(1), one F(2), one F(3), and four equivalent F(1) atoms to form corner-sharing UOF6 pentagonal bipyramids. O(1) is bonded in a single-bond geometry to one U(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent U(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one U(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one U(1) atom.
UOF4 crystallizes in the trigonal R3m space group. U(1) is bonded to one O(1), one F(2), one F(3), and four equivalent F(1) atoms to form corner-sharing UOF6 pentagonal bipyramids. The U(1)-O(1) bond length is 1.78 Å. The U(1)-F(2) bond length is 1.96 Å. The U(1)-F(3) bond length is 2.04 Å. All U(1)-F(1) bond lengths are 2.28 Å. O(1) is bonded in a single-bond geometry to one U(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent U(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one U(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one U(1) atom.