Li7Mn5O12 crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(17), one O(19), one O(23), and one O(9) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(13)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-90°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(18), one O(20), and one O(24) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-90°. In the third Li site, Li(3) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(11)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. In the fourth Li site, Li(4) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form LiO6 octahedra that share corners with three equivalent Mn(10)O6 octahedra, corners with three equivalent Mn(9)O6 octahedra,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(21), one O(23), one O(3), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(11)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. In the sixth Li site, Li(6) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(4) atom to form LiO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. In the seventh Li site, Li(7) is bonded to one O(1), one O(13), one O(15), one O(23), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(9)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. In the eighth Li site, Li(8) is bonded to one O(10), one O(14), one O(16), one O(2), one O(24), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  a cornercorner with one Li(12)O5 square pyramid,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid,  an edgeedge with one Li(13)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. In the ninth Li site, Li(9) is bonded to one O(11), one O(14), one O(16), one O(21), one O(3), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(10)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(12)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and  an edgeedge with one Li(13)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. In the tenth Li site, Li(10) is bonded to one O(12), one O(13), one O(15), one O(22), one O(4), and one O(5) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(9)O6 octahedra, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. In the eleventh Li site, Li(11) is bonded to one O(1), one O(19), one O(5), one O(7), and one O(9) atom to form LiO5 square pyramids that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 6-87°. In the twelfth Li site, Li(12) is bonded to one O(10), one O(2), one O(20), one O(6), and one O(8) atom to form LiO5 square pyramids that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(13)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-87°. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(14), one O(17), one O(6), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(12)O5 square pyramid. The corner-sharing octahedral tilt angles range from 6-90°. In the fourteenth Li site, Li(14) is bonded to one O(12), one O(13), one O(18), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 6-90°. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(17), one O(19), one O(3), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Li(13)O5 square pyramids, corners with three equivalent Li(11)O5 square pyramids,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. In the second Mn site, Mn(2) is bonded to one O(12), one O(15), one O(18), one O(22), one O(5), and one O(7) atom to form MnO6 octahedra that share corners with two equivalent Li(11)O5 square pyramids, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(9)O6 octahedra, and edges with two equivalent Li(14)O5 square pyramids. In the third Mn site, Mn(3) is bonded to one O(10), one O(14), one O(20), one O(24), one O(6), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(13)O5 square pyramids, corners with three equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, and edges with two equivalent Li(12)O5 square pyramids. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(16), one O(17), one O(21), one O(3), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(12)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and  an edgeedge with one Li(13)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(13), one O(15), one O(19), one O(23), and one O(5) atom to form MnO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. In the sixth Mn site, Mn(6) is bonded to one O(10), one O(12), one O(18), one O(2), one O(20), and one O(4) atom to form MnO6 octahedra that share corners with two equivalent Li(14)O5 square pyramids, corners with three equivalent Li(12)O5 square pyramids,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Li(2)O5 square pyramids. In the seventh Mn site, Mn(7) is bonded to one O(11), one O(16), one O(17), one O(21), one O(6), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Li(1)O5 square pyramids, corners with two equivalent Li(12)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Li(13)O5 square pyramids. In the eighth Mn site, Mn(8) is bonded to one O(13), one O(19), one O(23), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O5 square pyramids, corners with three equivalent Li(14)O5 square pyramids,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Li(11)O5 square pyramids. In the ninth Mn site, Mn(9) is bonded to one O(13), one O(15), one O(18), one O(22), one O(4), and one O(7) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(7)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. In the tenth Mn site, Mn(10) is bonded to one O(14), one O(16), one O(2), one O(20), one O(24), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  a cornercorner with one Li(12)O5 square pyramid,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid,  an edgeedge with one Li(13)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(11), one Li(3), one Li(5), one Li(7), one Mn(1), and one Mn(5) atom to form OLi4Mn2 octahedra that share corners with two equivalent O(15)Li2Mn3 square pyramids, corners with three equivalent O(3)Li3Mn2 square pyramids,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, edges with two equivalent O(23)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, and  an edgeedge with one O(21)Li3Mn2 square pyramid. In the second O site, O(2) is bonded to one Li(12), one Li(4), one Li(6), one Li(8), one Mn(10), and one Mn(6) atom to form OLi4Mn2 octahedra that share corners with two equivalent O(16)Li2Mn3 square pyramids, corners with three equivalent O(4)Li3Mn2 square pyramids,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(24)Li4Mn2 octahedra, and  an edgeedge with one O(22)Li3Mn2 square pyramid. In the third O site, O(3) is bonded to one Li(3), one Li(5), one Li(9), one Mn(1), and one Mn(4) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra, corners with two equivalent O(14)Li3Mn3 octahedra, corners with three equivalent O(1)Li4Mn2 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and edges with two equivalent O(21)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-82°. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one Li(6), one Mn(6), and one Mn(9) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(5)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra, corners with two equivalent O(13)Li3Mn3 octahedra, corners with three equivalent O(2)Li4Mn2 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and edges with two equivalent O(22)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-82°. In the fifth O site, O(5) is bonded to one Li(10), one Li(11), one Li(14), one Mn(2), one Mn(5), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(19)Li3Mn3 octahedra, corners with three equivalent O(12)Li4Mn2 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(7)Li3Mn3 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and  an edgeedge with one O(22)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-15°. In the sixth O site, O(6) is bonded to one Li(12), one Li(13), one Li(9), one Mn(10), one Mn(3), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(20)Li3Mn3 octahedra, corners with three equivalent O(11)Li4Mn2 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and  an edgeedge with one O(21)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-14°. In the seventh O site, O(7) is bonded to one Li(11), one Li(14), one Li(7), one Mn(2), one Mn(8), and one Mn(9) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(18)Li3Mn3 octahedra, corners with three equivalent O(9)Li4Mn2 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(5)Li3Mn3 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and  an edgeedge with one O(22)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the eighth O site, O(8) is bonded to one Li(12), one Li(13), one Li(8), one Mn(3), one Mn(4), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(17)Li3Mn3 octahedra, corners with three equivalent O(10)Li4Mn2 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and  an edgeedge with one O(21)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the ninth O site, O(9) is bonded to one Li(1), one Li(11), one Li(5), one Li(7), one Mn(1), and one Mn(8) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(7)Li3Mn3 octahedra, corners with three equivalent O(11)Li4Mn2 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(21)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(23)Li4Mn2 octahedra, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the tenth O site, O(10) is bonded to one Li(12), one Li(2), one Li(6), one Li(8), one Mn(3), and one Mn(6) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(8)Li3Mn3 octahedra, corners with three equivalent O(12)Li4Mn2 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(22)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra, edges with two equivalent O(24)Li4Mn2 octahedra, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Mn(1), and one Mn(7) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(6)Li3Mn3 octahedra, corners with three equivalent O(9)Li4Mn2 octahedra,  a cornercorner with one O(21)Li3Mn2 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra, edges with two equivalent O(17)Li3Mn3 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid,  an edgeedge with one O(21)Li3Mn2 square pyramid, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Mn(2), and one Mn(6) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(5)Li3Mn3 octahedra, corners with three equivalent O(10)Li4Mn2 octahedra,  a cornercorner with one O(22)Li3Mn2 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(18)Li3Mn3 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid,  an edgeedge with one O(22)Li3Mn2 square pyramid, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the thirteenth O site, O(13) is bonded to one Li(10), one Li(14), one Li(7), one Mn(5), one Mn(8), and one Mn(9) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(23)Li4Mn2 octahedra, corners with two equivalent O(4)Li3Mn2 square pyramids,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(5)Li3Mn3 octahedra, edges with two equivalent O(7)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn2 square pyramid, and edges with two equivalent O(15)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles are 4°. In the fourteenth O site, O(14) is bonded to one Li(13), one Li(8), one Li(9), one Mn(10), one Mn(3), and one Mn(4) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(24)Li4Mn2 octahedra, corners with two equivalent O(3)Li3Mn2 square pyramids,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn2 square pyramid, and edges with two equivalent O(16)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles are 4°. In the fifteenth O site, O(15) is bonded to one Li(10), one Li(7), one Mn(2), one Mn(5), and one Mn(9) atom to form OLi2Mn3 square pyramids that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(5)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra, corners with two equivalent O(1)Li4Mn2 octahedra, corners with three equivalent O(22)Li3Mn2 square pyramids,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 4-82°. In the sixteenth O site, O(16) is bonded to one Li(8), one Li(9), one Mn(10), one Mn(4), and one Mn(7) atom to form OLi2Mn3 square pyramids that share  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra, corners with two equivalent O(2)Li4Mn2 octahedra, corners with three equivalent O(21)Li3Mn2 square pyramids,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 4-82°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(13), one Li(3), one Mn(1), one Mn(4), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(19)Li3Mn3 octahedra, corners with three equivalent O(8)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn2 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid,  an edgeedge with one O(21)Li3Mn2 square pyramid, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the eighteenth O site, O(18) is bonded to one Li(14), one Li(2), one Li(4), one Mn(2), one Mn(6), and one Mn(9) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(20)Li3Mn3 octahedra, corners with three equivalent O(7)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn2 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(12)Li4Mn2 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid,  an edgeedge with one O(22)Li3Mn2 square pyramid, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(11), one Li(3), one Mn(1), one Mn(5), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(17)Li3Mn3 octahedra, corners with three equivalent O(5)Li3Mn3 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(21)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(23)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-15°. In the twentieth O site, O(20) is bonded to one Li(12), one Li(2), one Li(4), one Mn(10), one Mn(3), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(18)Li3Mn3 octahedra, corners with three equivalent O(6)Li3Mn3 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(22)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra, edges with two equivalent O(24)Li4Mn2 octahedra, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-14°. In the twenty-first O site, O(21) is bonded to one Li(3), one Li(5), one Li(9), one Mn(4), and one Mn(7) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra, corners with two equivalent O(23)Li4Mn2 octahedra, corners with three equivalent O(16)Li2Mn3 square pyramids,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, and edges with two equivalent O(3)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 5-83°. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(4), one Li(6), one Mn(2), and one Mn(9) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra, corners with two equivalent O(24)Li4Mn2 octahedra, corners with three equivalent O(15)Li2Mn3 square pyramids,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, and edges with two equivalent O(4)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 5-83°. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(5), and one Mn(8) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(13)Li3Mn3 octahedra, corners with two equivalent O(21)Li3Mn2 square pyramids,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles are 4°. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(10), and one Mn(3) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(14)Li3Mn3 octahedra, corners with two equivalent O(22)Li3Mn2 square pyramids,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles are 4°.
Li7Mn5O12 crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(17), one O(19), one O(23), and one O(9) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(13)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-90°. The Li(1)-O(11) bond length is 2.18 Å. The Li(1)-O(17) bond length is 2.12 Å. The Li(1)-O(19) bond length is 2.13 Å. The Li(1)-O(23) bond length is 2.00 Å. The Li(1)-O(9) bond length is 2.12 Å. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(18), one O(20), and one O(24) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-90°. The Li(2)-O(10) bond length is 2.12 Å. The Li(2)-O(12) bond length is 2.18 Å. The Li(2)-O(18) bond length is 2.12 Å. The Li(2)-O(20) bond length is 2.13 Å. The Li(2)-O(24) bond length is 2.00 Å. In the third Li site, Li(3) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(11)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. The Li(3)-O(1) bond length is 2.20 Å. The Li(3)-O(17) bond length is 2.10 Å. The Li(3)-O(19) bond length is 2.16 Å. The Li(3)-O(21) bond length is 2.15 Å. The Li(3)-O(23) bond length is 2.12 Å. The Li(3)-O(3) bond length is 2.13 Å. In the fourth Li site, Li(4) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form LiO6 octahedra that share corners with three equivalent Mn(10)O6 octahedra, corners with three equivalent Mn(9)O6 octahedra,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. The Li(4)-O(18) bond length is 2.11 Å. The Li(4)-O(2) bond length is 2.19 Å. The Li(4)-O(20) bond length is 2.16 Å. The Li(4)-O(22) bond length is 2.15 Å. The Li(4)-O(24) bond length is 2.13 Å. The Li(4)-O(4) bond length is 2.13 Å. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(21), one O(23), one O(3), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(11)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. The Li(5)-O(1) bond length is 2.07 Å. The Li(5)-O(11) bond length is 2.18 Å. The Li(5)-O(21) bond length is 2.08 Å. The Li(5)-O(23) bond length is 2.04 Å. The Li(5)-O(3) bond length is 2.05 Å. The Li(5)-O(9) bond length is 2.28 Å. In the sixth Li site, Li(6) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(4) atom to form LiO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. The Li(6)-O(10) bond length is 2.28 Å. The Li(6)-O(12) bond length is 2.18 Å. The Li(6)-O(2) bond length is 2.06 Å. The Li(6)-O(22) bond length is 2.08 Å. The Li(6)-O(24) bond length is 2.04 Å. The Li(6)-O(4) bond length is 2.05 Å. In the seventh Li site, Li(7) is bonded to one O(1), one O(13), one O(15), one O(23), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(9)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. The Li(7)-O(1) bond length is 2.04 Å. The Li(7)-O(13) bond length is 2.16 Å. The Li(7)-O(15) bond length is 2.12 Å. The Li(7)-O(23) bond length is 2.03 Å. The Li(7)-O(7) bond length is 2.29 Å. The Li(7)-O(9) bond length is 2.14 Å. In the eighth Li site, Li(8) is bonded to one O(10), one O(14), one O(16), one O(2), one O(24), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  a cornercorner with one Li(12)O5 square pyramid,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid,  an edgeedge with one Li(13)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. The Li(8)-O(10) bond length is 2.15 Å. The Li(8)-O(14) bond length is 2.16 Å. The Li(8)-O(16) bond length is 2.13 Å. The Li(8)-O(2) bond length is 2.04 Å. The Li(8)-O(24) bond length is 2.03 Å. The Li(8)-O(8) bond length is 2.29 Å. In the ninth Li site, Li(9) is bonded to one O(11), one O(14), one O(16), one O(21), one O(3), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(10)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(12)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and  an edgeedge with one Li(13)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. The Li(9)-O(11) bond length is 2.19 Å. The Li(9)-O(14) bond length is 2.12 Å. The Li(9)-O(16) bond length is 2.12 Å. The Li(9)-O(21) bond length is 2.06 Å. The Li(9)-O(3) bond length is 2.06 Å. The Li(9)-O(6) bond length is 2.22 Å. In the tenth Li site, Li(10) is bonded to one O(12), one O(13), one O(15), one O(22), one O(4), and one O(5) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(9)O6 octahedra, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-18°. The Li(10)-O(12) bond length is 2.19 Å. The Li(10)-O(13) bond length is 2.12 Å. The Li(10)-O(15) bond length is 2.12 Å. The Li(10)-O(22) bond length is 2.06 Å. The Li(10)-O(4) bond length is 2.06 Å. The Li(10)-O(5) bond length is 2.22 Å. In the eleventh Li site, Li(11) is bonded to one O(1), one O(19), one O(5), one O(7), and one O(9) atom to form LiO5 square pyramids that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 6-87°. The Li(11)-O(1) bond length is 2.17 Å. The Li(11)-O(19) bond length is 2.09 Å. The Li(11)-O(5) bond length is 2.20 Å. The Li(11)-O(7) bond length is 2.18 Å. The Li(11)-O(9) bond length is 2.09 Å. In the twelfth Li site, Li(12) is bonded to one O(10), one O(2), one O(20), one O(6), and one O(8) atom to form LiO5 square pyramids that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(13)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-87°. The Li(12)-O(10) bond length is 2.09 Å. The Li(12)-O(2) bond length is 2.18 Å. The Li(12)-O(20) bond length is 2.09 Å. The Li(12)-O(6) bond length is 2.20 Å. The Li(12)-O(8) bond length is 2.18 Å. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(14), one O(17), one O(6), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(12)O5 square pyramid. The corner-sharing octahedral tilt angles range from 6-90°. The Li(13)-O(11) bond length is 2.10 Å. The Li(13)-O(14) bond length is 2.10 Å. The Li(13)-O(17) bond length is 2.18 Å. The Li(13)-O(6) bond length is 2.12 Å. The Li(13)-O(8) bond length is 2.08 Å. In the fourteenth Li site, Li(14) is bonded to one O(12), one O(13), one O(18), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 6-90°. The Li(14)-O(12) bond length is 2.10 Å. The Li(14)-O(13) bond length is 2.10 Å. The Li(14)-O(18) bond length is 2.18 Å. The Li(14)-O(5) bond length is 2.12 Å. The Li(14)-O(7) bond length is 2.08 Å. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(17), one O(19), one O(3), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Li(13)O5 square pyramids, corners with three equivalent Li(11)O5 square pyramids,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. The Mn(1)-O(1) bond length is 1.98 Å. The Mn(1)-O(11) bond length is 1.96 Å. The Mn(1)-O(17) bond length is 1.95 Å. The Mn(1)-O(19) bond length is 1.95 Å. The Mn(1)-O(3) bond length is 1.95 Å. The Mn(1)-O(9) bond length is 1.94 Å. In the second Mn site, Mn(2) is bonded to one O(12), one O(15), one O(18), one O(22), one O(5), and one O(7) atom to form MnO6 octahedra that share corners with two equivalent Li(11)O5 square pyramids, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(9)O6 octahedra, and edges with two equivalent Li(14)O5 square pyramids. The Mn(2)-O(12) bond length is 1.93 Å. The Mn(2)-O(15) bond length is 2.02 Å. The Mn(2)-O(18) bond length is 1.95 Å. The Mn(2)-O(22) bond length is 1.91 Å. The Mn(2)-O(5) bond length is 1.97 Å. The Mn(2)-O(7) bond length is 1.94 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(14), one O(20), one O(24), one O(6), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(13)O5 square pyramids, corners with three equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, and edges with two equivalent Li(12)O5 square pyramids. The Mn(3)-O(10) bond length is 1.95 Å. The Mn(3)-O(14) bond length is 2.34 Å. The Mn(3)-O(20) bond length is 1.97 Å. The Mn(3)-O(24) bond length is 2.16 Å. The Mn(3)-O(6) bond length is 1.97 Å. The Mn(3)-O(8) bond length is 2.00 Å. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(16), one O(17), one O(21), one O(3), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(12)O5 square pyramid,  a cornercorner with one Li(13)O5 square pyramid,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and  an edgeedge with one Li(13)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. The Mn(4)-O(14) bond length is 1.95 Å. The Mn(4)-O(16) bond length is 1.99 Å. The Mn(4)-O(17) bond length is 2.30 Å. The Mn(4)-O(21) bond length is 1.95 Å. The Mn(4)-O(3) bond length is 1.93 Å. The Mn(4)-O(8) bond length is 2.27 Å. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(13), one O(15), one O(19), one O(23), and one O(5) atom to form MnO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(11)O5 square pyramid, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. The Mn(5)-O(1) bond length is 1.95 Å. The Mn(5)-O(13) bond length is 1.96 Å. The Mn(5)-O(15) bond length is 2.00 Å. The Mn(5)-O(19) bond length is 2.31 Å. The Mn(5)-O(23) bond length is 1.89 Å. The Mn(5)-O(5) bond length is 2.28 Å. In the sixth Mn site, Mn(6) is bonded to one O(10), one O(12), one O(18), one O(2), one O(20), and one O(4) atom to form MnO6 octahedra that share corners with two equivalent Li(14)O5 square pyramids, corners with three equivalent Li(12)O5 square pyramids,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Li(2)O5 square pyramids. The Mn(6)-O(10) bond length is 1.94 Å. The Mn(6)-O(12) bond length is 1.96 Å. The Mn(6)-O(18) bond length is 1.95 Å. The Mn(6)-O(2) bond length is 1.98 Å. The Mn(6)-O(20) bond length is 1.95 Å. The Mn(6)-O(4) bond length is 1.95 Å. In the seventh Mn site, Mn(7) is bonded to one O(11), one O(16), one O(17), one O(21), one O(6), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Li(1)O5 square pyramids, corners with two equivalent Li(12)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Li(13)O5 square pyramids. The Mn(7)-O(11) bond length is 1.93 Å. The Mn(7)-O(16) bond length is 2.02 Å. The Mn(7)-O(17) bond length is 1.96 Å. The Mn(7)-O(21) bond length is 1.91 Å. The Mn(7)-O(6) bond length is 1.97 Å. The Mn(7)-O(8) bond length is 1.94 Å. In the eighth Mn site, Mn(8) is bonded to one O(13), one O(19), one O(23), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O5 square pyramids, corners with three equivalent Li(14)O5 square pyramids,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Li(11)O5 square pyramids. The Mn(8)-O(13) bond length is 2.34 Å. The Mn(8)-O(19) bond length is 1.97 Å. The Mn(8)-O(23) bond length is 2.16 Å. The Mn(8)-O(5) bond length is 1.97 Å. The Mn(8)-O(7) bond length is 2.00 Å. The Mn(8)-O(9) bond length is 1.95 Å. In the ninth Mn site, Mn(9) is bonded to one O(13), one O(15), one O(18), one O(22), one O(4), and one O(7) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(7)O6 octahedra,  a cornercorner with one Li(11)O5 square pyramid,  a cornercorner with one Li(14)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(14)O5 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. The Mn(9)-O(13) bond length is 1.95 Å. The Mn(9)-O(15) bond length is 1.99 Å. The Mn(9)-O(18) bond length is 2.30 Å. The Mn(9)-O(22) bond length is 1.95 Å. The Mn(9)-O(4) bond length is 1.93 Å. The Mn(9)-O(7) bond length is 2.27 Å. In the tenth Mn site, Mn(10) is bonded to one O(14), one O(16), one O(2), one O(20), one O(24), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  a cornercorner with one Li(12)O5 square pyramid,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(12)O5 square pyramid,  an edgeedge with one Li(13)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 2-16°. The Mn(10)-O(14) bond length is 1.96 Å. The Mn(10)-O(16) bond length is 2.00 Å. The Mn(10)-O(2) bond length is 1.95 Å. The Mn(10)-O(20) bond length is 2.31 Å. The Mn(10)-O(24) bond length is 1.89 Å. The Mn(10)-O(6) bond length is 2.28 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(11), one Li(3), one Li(5), one Li(7), one Mn(1), and one Mn(5) atom to form OLi4Mn2 octahedra that share corners with two equivalent O(15)Li2Mn3 square pyramids, corners with three equivalent O(3)Li3Mn2 square pyramids,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, edges with two equivalent O(23)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, and  an edgeedge with one O(21)Li3Mn2 square pyramid. In the second O site, O(2) is bonded to one Li(12), one Li(4), one Li(6), one Li(8), one Mn(10), and one Mn(6) atom to form OLi4Mn2 octahedra that share corners with two equivalent O(16)Li2Mn3 square pyramids, corners with three equivalent O(4)Li3Mn2 square pyramids,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(24)Li4Mn2 octahedra, and  an edgeedge with one O(22)Li3Mn2 square pyramid. In the third O site, O(3) is bonded to one Li(3), one Li(5), one Li(9), one Mn(1), and one Mn(4) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra, corners with two equivalent O(14)Li3Mn3 octahedra, corners with three equivalent O(1)Li4Mn2 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and edges with two equivalent O(21)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-82°. In the fourth O site, O(4) is bonded to one Li(10), one Li(4), one Li(6), one Mn(6), and one Mn(9) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(5)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra, corners with two equivalent O(13)Li3Mn3 octahedra, corners with three equivalent O(2)Li4Mn2 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and edges with two equivalent O(22)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 0-82°. In the fifth O site, O(5) is bonded to one Li(10), one Li(11), one Li(14), one Mn(2), one Mn(5), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(19)Li3Mn3 octahedra, corners with three equivalent O(12)Li4Mn2 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(7)Li3Mn3 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and  an edgeedge with one O(22)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-15°. In the sixth O site, O(6) is bonded to one Li(12), one Li(13), one Li(9), one Mn(10), one Mn(3), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(20)Li3Mn3 octahedra, corners with three equivalent O(11)Li4Mn2 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and  an edgeedge with one O(21)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-14°. In the seventh O site, O(7) is bonded to one Li(11), one Li(14), one Li(7), one Mn(2), one Mn(8), and one Mn(9) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(18)Li3Mn3 octahedra, corners with three equivalent O(9)Li4Mn2 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(5)Li3Mn3 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and  an edgeedge with one O(22)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the eighth O site, O(8) is bonded to one Li(12), one Li(13), one Li(8), one Mn(3), one Mn(4), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(17)Li3Mn3 octahedra, corners with three equivalent O(10)Li4Mn2 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and  an edgeedge with one O(21)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the ninth O site, O(9) is bonded to one Li(1), one Li(11), one Li(5), one Li(7), one Mn(1), and one Mn(8) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(7)Li3Mn3 octahedra, corners with three equivalent O(11)Li4Mn2 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(21)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(23)Li4Mn2 octahedra, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the tenth O site, O(10) is bonded to one Li(12), one Li(2), one Li(6), one Li(8), one Mn(3), and one Mn(6) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(8)Li3Mn3 octahedra, corners with three equivalent O(12)Li4Mn2 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(22)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra, edges with two equivalent O(24)Li4Mn2 octahedra, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-16°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Mn(1), and one Mn(7) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(6)Li3Mn3 octahedra, corners with three equivalent O(9)Li4Mn2 octahedra,  a cornercorner with one O(21)Li3Mn2 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra, edges with two equivalent O(17)Li3Mn3 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid,  an edgeedge with one O(21)Li3Mn2 square pyramid, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Mn(2), and one Mn(6) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(5)Li3Mn3 octahedra, corners with three equivalent O(10)Li4Mn2 octahedra,  a cornercorner with one O(22)Li3Mn2 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(18)Li3Mn3 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid,  an edgeedge with one O(22)Li3Mn2 square pyramid, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the thirteenth O site, O(13) is bonded to one Li(10), one Li(14), one Li(7), one Mn(5), one Mn(8), and one Mn(9) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(23)Li4Mn2 octahedra, corners with two equivalent O(4)Li3Mn2 square pyramids,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(5)Li3Mn3 octahedra, edges with two equivalent O(7)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn2 square pyramid, and edges with two equivalent O(15)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles are 4°. In the fourteenth O site, O(14) is bonded to one Li(13), one Li(8), one Li(9), one Mn(10), one Mn(3), and one Mn(4) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(24)Li4Mn2 octahedra, corners with two equivalent O(3)Li3Mn2 square pyramids,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn2 square pyramid, and edges with two equivalent O(16)Li2Mn3 square pyramids. The corner-sharing octahedral tilt angles are 4°. In the fifteenth O site, O(15) is bonded to one Li(10), one Li(7), one Mn(2), one Mn(5), and one Mn(9) atom to form OLi2Mn3 square pyramids that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(5)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra, corners with two equivalent O(1)Li4Mn2 octahedra, corners with three equivalent O(22)Li3Mn2 square pyramids,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 4-82°. In the sixteenth O site, O(16) is bonded to one Li(8), one Li(9), one Mn(10), one Mn(4), and one Mn(7) atom to form OLi2Mn3 square pyramids that share  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra, corners with two equivalent O(2)Li4Mn2 octahedra, corners with three equivalent O(21)Li3Mn2 square pyramids,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 4-82°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(13), one Li(3), one Mn(1), one Mn(4), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(19)Li3Mn3 octahedra, corners with three equivalent O(8)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn2 square pyramid,  a cornercorner with one O(3)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(23)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(11)Li4Mn2 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid,  an edgeedge with one O(21)Li3Mn2 square pyramid, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the eighteenth O site, O(18) is bonded to one Li(14), one Li(2), one Li(4), one Mn(2), one Mn(6), and one Mn(9) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(20)Li3Mn3 octahedra, corners with three equivalent O(7)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn2 square pyramid,  a cornercorner with one O(4)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(10)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(24)Li4Mn2 octahedra, edges with two equivalent O(12)Li4Mn2 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid,  an edgeedge with one O(22)Li3Mn2 square pyramid, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-11°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(11), one Li(3), one Mn(1), one Mn(5), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(17)Li3Mn3 octahedra, corners with three equivalent O(5)Li3Mn3 octahedra,  a cornercorner with one O(15)Li2Mn3 square pyramid,  a cornercorner with one O(21)Li3Mn2 square pyramid,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(23)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-15°. In the twentieth O site, O(20) is bonded to one Li(12), one Li(2), one Li(4), one Mn(10), one Mn(3), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(18)Li3Mn3 octahedra, corners with three equivalent O(6)Li3Mn3 octahedra,  a cornercorner with one O(16)Li2Mn3 square pyramid,  a cornercorner with one O(22)Li3Mn2 square pyramid,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra, edges with two equivalent O(24)Li4Mn2 octahedra, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles range from 1-14°. In the twenty-first O site, O(21) is bonded to one Li(3), one Li(5), one Li(9), one Mn(4), and one Mn(7) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(11)Li4Mn2 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra, corners with two equivalent O(23)Li4Mn2 octahedra, corners with three equivalent O(16)Li2Mn3 square pyramids,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, and edges with two equivalent O(3)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 5-83°. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(4), one Li(6), one Mn(2), and one Mn(9) atom to form distorted OLi3Mn2 square pyramids that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(10)Li4Mn2 octahedra,  a cornercorner with one O(12)Li4Mn2 octahedra, corners with two equivalent O(24)Li4Mn2 octahedra, corners with three equivalent O(15)Li2Mn3 square pyramids,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, and edges with two equivalent O(4)Li3Mn2 square pyramids. The corner-sharing octahedral tilt angles range from 5-83°. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(5), and one Mn(8) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(13)Li3Mn3 octahedra, corners with two equivalent O(21)Li3Mn2 square pyramids,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(11)Li4Mn2 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra,  an edgeedge with one O(15)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles are 4°. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(10), and one Mn(3) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(14)Li3Mn3 octahedra, corners with two equivalent O(22)Li3Mn2 square pyramids,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(12)Li4Mn2 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, edges with two equivalent O(10)Li4Mn2 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra,  an edgeedge with one O(16)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li3Mn2 square pyramid. The corner-sharing octahedral tilt angles are 4°.