CaSnO6 crystallizes in the cubic Pn-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. Sn(1) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. O(1) is bonded in a distorted trigonal planar geometry to one Ca(1), one Sn(1), and one O(1) atom.
CaSnO6 crystallizes in the cubic Pn-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. All Ca(1)-O(1) bond lengths are 2.31 Å. Sn(1) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. All Sn(1)-O(1) bond lengths are 2.21 Å. O(1) is bonded in a distorted trigonal planar geometry to one Ca(1), one Sn(1), and one O(1) atom. The O(1)-O(1) bond length is 1.46 Å.