NdO2ZrO12 crystallizes in the cubic Fd-3m space group. The structure consists of one NdO2 framework and one ZrO12 framework. In the NdO2 framework, Nd(1) is bonded to four equivalent O(1) atoms to form corner-sharing NdO4 tetrahedra. O(1) is bonded in a linear geometry to two equivalent Nd(1) atoms. In the ZrO12 framework, Zr(1) is bonded in a cuboctahedral geometry to twelve equivalent O(2) atoms. O(2) is bonded in a 3-coordinate geometry to one Zr(1) and two equivalent O(2) atoms.
NdO2ZrO12 crystallizes in the cubic Fd-3m space group. The structure consists of one NdO2 framework and one ZrO12 framework. In the NdO2 framework, Nd(1) is bonded to four equivalent O(1) atoms to form corner-sharing NdO4 tetrahedra. All Nd(1)-O(1) bond lengths are 2.36 Å. O(1) is bonded in a linear geometry to two equivalent Nd(1) atoms. In the ZrO12 framework, Zr(1) is bonded in a cuboctahedral geometry to twelve equivalent O(2) atoms. All Zr(1)-O(2) bond lengths are 2.40 Å. O(2) is bonded in a 3-coordinate geometry to one Zr(1) and two equivalent O(2) atoms. Both O(2)-O(2) bond lengths are 1.69 Å.