TcZn2Tl crystallizes in the cubic F-43m space group. Tc(1) is bonded in a distorted body-centered cubic geometry to four equivalent Zn(2), six equivalent Zn(1), and four equivalent Tl(1) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 14-coordinate geometry to six equivalent Tc(1), four equivalent Zn(2), and four equivalent Tl(1) atoms. In the second Zn site, Zn(2) is bonded in a 8-coordinate geometry to four equivalent Tc(1) and four equivalent Zn(1) atoms. Tl(1) is bonded in a distorted body-centered cubic geometry to four equivalent Tc(1) and four equivalent Zn(1) atoms.
TcZn2Tl crystallizes in the cubic F-43m space group. Tc(1) is bonded in a distorted body-centered cubic geometry to four equivalent Zn(2), six equivalent Zn(1), and four equivalent Tl(1) atoms. All Tc(1)-Zn(2) bond lengths are 2.77 Å. All Tc(1)-Zn(1) bond lengths are 3.20 Å. All Tc(1)-Tl(1) bond lengths are 2.77 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 14-coordinate geometry to six equivalent Tc(1), four equivalent Zn(2), and four equivalent Tl(1) atoms. All Zn(1)-Zn(2) bond lengths are 2.77 Å. All Zn(1)-Tl(1) bond lengths are 2.77 Å. In the second Zn site, Zn(2) is bonded in a 8-coordinate geometry to four equivalent Tc(1) and four equivalent Zn(1) atoms. Tl(1) is bonded in a distorted body-centered cubic geometry to four equivalent Tc(1) and four equivalent Zn(1) atoms.