NbInS2 crystallizes in the hexagonal P-6m2 space group. Nb(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing NbS6 pentagonal pyramids. In(1) is bonded in a linear geometry to two equivalent S(1) atoms. S(1) is bonded in a rectangular see-saw-like geometry to three equivalent Nb(1) and one In(1) atom.
NbInS2 crystallizes in the hexagonal P-6m2 space group. Nb(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing NbS6 pentagonal pyramids. All Nb(1)-S(1) bond lengths are 2.48 Å. In(1) is bonded in a linear geometry to two equivalent S(1) atoms. Both In(1)-S(1) bond lengths are 2.81 Å. S(1) is bonded in a rectangular see-saw-like geometry to three equivalent Nb(1) and one In(1) atom.