BaCdSbF is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Ba(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent F(1) atoms. Cd(1) is bonded to four equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing CdSb4 tetrahedra. Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Cd(1) atoms. F(1) is bonded to four equivalent Ba(1) atoms to form a mixture of edge and corner-sharing FBa4 tetrahedra.
BaCdSbF is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Ba(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent F(1) atoms. All Ba(1)-Sb(1) bond lengths are 3.70 Å. All Ba(1)-F(1) bond lengths are 2.70 Å. Cd(1) is bonded to four equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing CdSb4 tetrahedra. All Cd(1)-Sb(1) bond lengths are 2.94 Å. Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Cd(1) atoms. F(1) is bonded to four equivalent Ba(1) atoms to form a mixture of edge and corner-sharing FBa4 tetrahedra.