(Tl)2FeTlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-28-0 atoms inside a FeTlF6 framework. In the FeTlF6 framework, Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Tl(2)F6 octahedra. The corner-sharing octahedra are not tilted. Tl(2) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Fe(1) and one Tl(2) atom.
(Tl)2FeTlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-28-0 atoms inside a FeTlF6 framework. In the FeTlF6 framework, Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Tl(2)F6 octahedra. The corner-sharing octahedra are not tilted. All Fe(1)-F(1) bond lengths are 1.93 Å. Tl(2) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Tl(2)-F(1) bond lengths are 2.58 Å. F(1) is bonded in a linear geometry to one Fe(1) and one Tl(2) atom.