VAg2AsO6 crystallizes in the triclinic P-1 space group. V(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. As(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one As(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(1), one Ag(2), and one As(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one Ag(2), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one As(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(1), one Ag(1), and one Ag(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(1) atom.
VAg2AsO6 crystallizes in the triclinic P-1 space group. V(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms. The V(1)-O(2) bond length is 2.22 Å. The V(1)-O(3) bond length is 1.97 Å. The V(1)-O(4) bond length is 1.96 Å. The V(1)-O(6) bond length is 1.67 Å. There is one shorter (1.74 Å) and one longer (2.28 Å) V(1)-O(5) bond length. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. The Ag(1)-O(1) bond length is 2.24 Å. The Ag(1)-O(2) bond length is 2.35 Å. The Ag(1)-O(4) bond length is 2.56 Å. The Ag(1)-O(5) bond length is 2.58 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. The Ag(2)-O(1) bond length is 2.27 Å. The Ag(2)-O(2) bond length is 2.44 Å. The Ag(2)-O(3) bond length is 2.51 Å. The Ag(2)-O(5) bond length is 2.49 Å. As(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The As(1)-O(1) bond length is 1.71 Å. The As(1)-O(2) bond length is 1.74 Å. The As(1)-O(3) bond length is 1.73 Å. The As(1)-O(4) bond length is 1.72 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one As(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(1), one Ag(2), and one As(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one Ag(2), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one As(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(1), one Ag(1), and one Ag(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(1) atom.