WCoB crystallizes in the orthorhombic Pnma space group. W(1) is bonded in a 11-coordinate geometry to six equivalent Co(1) and five equivalent B(1) atoms. Co(1) is bonded in a 12-coordinate geometry to six equivalent W(1), two equivalent Co(1), and four equivalent B(1) atoms. B(1) is bonded in a 9-coordinate geometry to five equivalent W(1) and four equivalent Co(1) atoms.
WCoB crystallizes in the orthorhombic Pnma space group. W(1) is bonded in a 11-coordinate geometry to six equivalent Co(1) and five equivalent B(1) atoms. There are a spread of W(1)-Co(1) bond distances ranging from 2.57-2.68 Å. There are a spread of W(1)-B(1) bond distances ranging from 2.37-2.41 Å. Co(1) is bonded in a 12-coordinate geometry to six equivalent W(1), two equivalent Co(1), and four equivalent B(1) atoms. Both Co(1)-Co(1) bond lengths are 2.42 Å. There are a spread of Co(1)-B(1) bond distances ranging from 2.08-2.21 Å. B(1) is bonded in a 9-coordinate geometry to five equivalent W(1) and four equivalent Co(1) atoms.