V2OF5 crystallizes in the monoclinic C2 space group. V(1) is bonded to one O(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing VOF5 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.
V2OF5 crystallizes in the monoclinic C2 space group. V(1) is bonded to one O(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing VOF5 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. The V(1)-O(1) bond length is 1.77 Å. The V(1)-F(1) bond length is 1.97 Å. There is one shorter (1.93 Å) and one longer (2.04 Å) V(1)-F(2) bond length. There is one shorter (1.95 Å) and one longer (1.98 Å) V(1)-F(3) bond length. O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.