(WTeO6)4(N2)2(O2)3 crystallizes in the orthorhombic Imm2 space group. The structure consists of four ammonia atoms and two trioxidane molecules inside a WTeO6 framework. In the WTeO6 framework, W(1) is bonded to one O(5), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-39°. Te(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-43°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fifth O site, O(6) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the sixth O site, O(8) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.
(WTeO6)4(N2)2(O2)3 crystallizes in the orthorhombic Imm2 space group. The structure consists of four ammonia atoms and two trioxidane molecules inside a WTeO6 framework. In the WTeO6 framework, W(1) is bonded to one O(5), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-39°. The W(1)-O(5) bond length is 1.93 Å. The W(1)-O(8) bond length is 1.93 Å. Both W(1)-O(3) bond lengths are 1.95 Å. Both W(1)-O(6) bond lengths are 1.95 Å. Te(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-43°. The Te(1)-O(1) bond length is 1.97 Å. The Te(1)-O(4) bond length is 1.97 Å. Both Te(1)-O(3) bond lengths are 1.95 Å. Both Te(1)-O(6) bond lengths are 1.94 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fifth O site, O(6) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the sixth O site, O(8) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.