CdZnSeS is Stannite-like structured and crystallizes in the trigonal P3m1 space group. Cd(1) is bonded to three equivalent Se(1) and one S(1) atom to form CdSe3S tetrahedra that share corners with six equivalent Cd(1)Se3S tetrahedra and corners with six equivalent Zn(1)SeS3 tetrahedra. Zn(1) is bonded to one Se(1) and three equivalent S(1) atoms to form ZnSeS3 tetrahedra that share corners with six equivalent Cd(1)Se3S tetrahedra and corners with six equivalent Zn(1)SeS3 tetrahedra. Se(1) is bonded to three equivalent Cd(1) and one Zn(1) atom to form SeZnCd3 tetrahedra that share corners with six equivalent Se(1)ZnCd3 tetrahedra and corners with six equivalent S(1)Zn3Cd tetrahedra. S(1) is bonded to one Cd(1) and three equivalent Zn(1) atoms to form SZn3Cd tetrahedra that share corners with six equivalent Se(1)ZnCd3 tetrahedra and corners with six equivalent S(1)Zn3Cd tetrahedra.
CdZnSeS is Stannite-like structured and crystallizes in the trigonal P3m1 space group. Cd(1) is bonded to three equivalent Se(1) and one S(1) atom to form CdSe3S tetrahedra that share corners with six equivalent Cd(1)Se3S tetrahedra and corners with six equivalent Zn(1)SeS3 tetrahedra. All Cd(1)-Se(1) bond lengths are 2.62 Å. The Cd(1)-S(1) bond length is 2.56 Å. Zn(1) is bonded to one Se(1) and three equivalent S(1) atoms to form ZnSeS3 tetrahedra that share corners with six equivalent Cd(1)Se3S tetrahedra and corners with six equivalent Zn(1)SeS3 tetrahedra. The Zn(1)-Se(1) bond length is 2.49 Å. All Zn(1)-S(1) bond lengths are 2.46 Å. Se(1) is bonded to three equivalent Cd(1) and one Zn(1) atom to form SeZnCd3 tetrahedra that share corners with six equivalent Se(1)ZnCd3 tetrahedra and corners with six equivalent S(1)Zn3Cd tetrahedra. S(1) is bonded to one Cd(1) and three equivalent Zn(1) atoms to form SZn3Cd tetrahedra that share corners with six equivalent Se(1)ZnCd3 tetrahedra and corners with six equivalent S(1)Zn3Cd tetrahedra.