CNH3SOF2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight CNH3SOF2 clusters. C(1) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one S(1)NOF2 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to one N(1), one O(1), one F(1), and one F(2) atom to form SNOF2 tetrahedra that share  a cornercorner with one C(1)H3N tetrahedra. O(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom.
CNH3SOF2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight CNH3SOF2 clusters. C(1) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one S(1)NOF2 tetrahedra. The C(1)-N(1) bond length is 1.47 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. The N(1)-S(1) bond length is 1.47 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to one N(1), one O(1), one F(1), and one F(2) atom to form SNOF2 tetrahedra that share  a cornercorner with one C(1)H3N tetrahedra. The S(1)-O(1) bond length is 1.42 Å. The S(1)-F(1) bond length is 1.61 Å. The S(1)-F(2) bond length is 1.61 Å. O(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom.