CsTh(MoO4)2Cl crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), and four equivalent Cl(1) atoms. Th(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fourth O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fifth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one Mo(2) atom. In the sixth O site, O(1) is bonded in a distorted linear geometry to one Th(1) and one Mo(1) atom. In the seventh O site, O(2) is bonded in a linear geometry to one Th(1) and one Mo(1) atom. In the eighth O site, O(3) is bonded in a bent 150 degrees geometry to one Th(1) and one Mo(2) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Th(1) atom.
CsTh(MoO4)2Cl crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 9-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), and four equivalent Cl(1) atoms. The Cs(1)-O(4) bond length is 3.67 Å. The Cs(1)-O(5) bond length is 3.13 Å. The Cs(1)-O(6) bond length is 3.48 Å. The Cs(1)-O(7) bond length is 3.28 Å. The Cs(1)-O(8) bond length is 3.28 Å. There are a spread of Cs(1)-Cl(1) bond distances ranging from 3.53-3.71 Å. Th(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. The Th(1)-O(1) bond length is 2.45 Å. The Th(1)-O(2) bond length is 2.40 Å. The Th(1)-O(3) bond length is 2.40 Å. The Th(1)-O(4) bond length is 2.43 Å. The Th(1)-O(5) bond length is 2.44 Å. The Th(1)-O(6) bond length is 2.40 Å. The Th(1)-O(7) bond length is 2.42 Å. The Th(1)-Cl(1) bond length is 2.84 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. The Mo(1)-O(1) bond length is 1.79 Å. The Mo(1)-O(2) bond length is 1.80 Å. The Mo(1)-O(4) bond length is 1.80 Å. The Mo(1)-O(5) bond length is 1.81 Å. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. The Mo(2)-O(3) bond length is 1.80 Å. The Mo(2)-O(6) bond length is 1.82 Å. The Mo(2)-O(7) bond length is 1.83 Å. The Mo(2)-O(8) bond length is 1.74 Å. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fourth O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one Th(1), and one Mo(2) atom. In the fifth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one Mo(2) atom. In the sixth O site, O(1) is bonded in a distorted linear geometry to one Th(1) and one Mo(1) atom. In the seventh O site, O(2) is bonded in a linear geometry to one Th(1) and one Mo(1) atom. In the eighth O site, O(3) is bonded in a bent 150 degrees geometry to one Th(1) and one Mo(2) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Th(1) atom.