LiReN2 is Enargite-like structured and crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form LiN4 tetrahedra that share corners with four equivalent Li(1)N4 tetrahedra and corners with eight equivalent Re(1)N4 tetrahedra. Re(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form ReN4 tetrahedra that share corners with four equivalent Re(1)N4 tetrahedra and corners with eight equivalent Li(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Li(1) and two equivalent Re(1) atoms to form corner-sharing NLi2Re2 tetrahedra. In the second N site, N(2) is bonded to two equivalent Li(1) and two equivalent Re(1) atoms to form corner-sharing NLi2Re2 tetrahedra.
LiReN2 is Enargite-like structured and crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form LiN4 tetrahedra that share corners with four equivalent Li(1)N4 tetrahedra and corners with eight equivalent Re(1)N4 tetrahedra. There is one shorter (2.12 Å) and one longer (2.21 Å) Li(1)-N(1) bond length. There is one shorter (2.15 Å) and one longer (2.19 Å) Li(1)-N(2) bond length. Re(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form ReN4 tetrahedra that share corners with four equivalent Re(1)N4 tetrahedra and corners with eight equivalent Li(1)N4 tetrahedra. There is one shorter (1.90 Å) and one longer (1.94 Å) Re(1)-N(1) bond length. There is one shorter (1.89 Å) and one longer (1.90 Å) Re(1)-N(2) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Li(1) and two equivalent Re(1) atoms to form corner-sharing NLi2Re2 tetrahedra. In the second N site, N(2) is bonded to two equivalent Li(1) and two equivalent Re(1) atoms to form corner-sharing NLi2Re2 tetrahedra.