Cu(XeF2)6(SbF6)2 is Fluorite structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Cu(XeF2)6 clusters and six SbF6 clusters. In each Cu(XeF2)6 cluster, Xe(1) is bonded in a linear geometry to one F(3) and one F(4) atom. Cu(1) is bonded in an octahedral geometry to six equivalent F(3) atoms. There are two inequivalent F sites. In the first F site, F(3) is bonded in a bent 120 degrees geometry to one Xe(1) and one Cu(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom.
Cu(XeF2)6(SbF6)2 is Fluorite structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Cu(XeF2)6 clusters and six SbF6 clusters. In each Cu(XeF2)6 cluster, Xe(1) is bonded in a linear geometry to one F(3) and one F(4) atom. The Xe(1)-F(3) bond length is 2.17 Å. The Xe(1)-F(4) bond length is 2.03 Å. Cu(1) is bonded in an octahedral geometry to six equivalent F(3) atoms. All Cu(1)-F(3) bond lengths are 2.02 Å. There are two inequivalent F sites. In the first F site, F(3) is bonded in a bent 120 degrees geometry to one Xe(1) and one Cu(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. All Sb(1)-F(1) bond lengths are 1.93 Å. All Sb(1)-F(2) bond lengths are 1.92 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom.