TiCoN2 is Caswellsilverite-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent N(1) atoms to form distorted TiN6 pentagonal pyramids that share corners with six equivalent Co(1)N6 octahedra, edges with six equivalent Co(1)N6 octahedra, and edges with six equivalent Ti(1)N6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 4°. Co(1) is bonded to six equivalent N(1) atoms to form CoN6 octahedra that share corners with six equivalent Ti(1)N6 pentagonal pyramids, edges with six equivalent Co(1)N6 octahedra, and edges with six equivalent Ti(1)N6 pentagonal pyramids. N(1) is bonded to three equivalent Ti(1) and three equivalent Co(1) atoms to form a mixture of corner, edge, and face-sharing NTi3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-47°.
TiCoN2 is Caswellsilverite-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent N(1) atoms to form distorted TiN6 pentagonal pyramids that share corners with six equivalent Co(1)N6 octahedra, edges with six equivalent Co(1)N6 octahedra, and edges with six equivalent Ti(1)N6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 4°. All Ti(1)-N(1) bond lengths are 2.11 Å. Co(1) is bonded to six equivalent N(1) atoms to form CoN6 octahedra that share corners with six equivalent Ti(1)N6 pentagonal pyramids, edges with six equivalent Co(1)N6 octahedra, and edges with six equivalent Ti(1)N6 pentagonal pyramids. All Co(1)-N(1) bond lengths are 2.03 Å. N(1) is bonded to three equivalent Ti(1) and three equivalent Co(1) atoms to form a mixture of corner, edge, and face-sharing NTi3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-47°.