GdN3O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and two GdN3O11 clusters. In each GdN3O11 cluster, Gd(1) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(4), one O(7), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(11), one O(13), and one O(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(7) atom. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(14) is bonded in a single-bond geometry to one O(4) atom. In the third O site, O(1) is bonded in an L-shaped geometry to one Gd(1) and one N(3) atom. In the fourth O site, O(2) is bonded in an L-shaped geometry to one Gd(1) and one N(1) atom. In the fifth O site, O(4) is bonded in an L-shaped geometry to one Gd(1) and one O(14) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Gd(1) and one N(3) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Gd(1) and one N(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the tenth O site, O(10) is bonded in an L-shaped geometry to one Gd(1) and one N(1) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to one Gd(1) and one N(2) atom.
GdN3O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules and two GdN3O11 clusters. In each GdN3O11 cluster, Gd(1) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(4), one O(7), and one O(8) atom. The Gd(1)-O(1) bond length is 2.44 Å. The Gd(1)-O(10) bond length is 2.39 Å. The Gd(1)-O(11) bond length is 2.39 Å. The Gd(1)-O(2) bond length is 2.33 Å. The Gd(1)-O(4) bond length is 2.74 Å. The Gd(1)-O(7) bond length is 2.33 Å. The Gd(1)-O(8) bond length is 2.40 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(9) atom. The N(1)-O(10) bond length is 1.29 Å. The N(1)-O(2) bond length is 1.31 Å. The N(1)-O(9) bond length is 1.21 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(11), one O(13), and one O(8) atom. The N(2)-O(11) bond length is 1.31 Å. The N(2)-O(13) bond length is 1.21 Å. The N(2)-O(8) bond length is 1.31 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(7) atom. The N(3)-O(1) bond length is 1.29 Å. The N(3)-O(6) bond length is 1.22 Å. The N(3)-O(7) bond length is 1.31 Å. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(14) is bonded in a single-bond geometry to one O(4) atom. The O(14)-O(4) bond length is 1.25 Å. In the third O site, O(1) is bonded in an L-shaped geometry to one Gd(1) and one N(3) atom. In the fourth O site, O(2) is bonded in an L-shaped geometry to one Gd(1) and one N(1) atom. In the fifth O site, O(4) is bonded in an L-shaped geometry to one Gd(1) and one O(14) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Gd(1) and one N(3) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Gd(1) and one N(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the tenth O site, O(10) is bonded in an L-shaped geometry to one Gd(1) and one N(1) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to one Gd(1) and one N(2) atom.