(UH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two UH12(O3Cl)2 clusters. In each UH12(O3Cl)2 cluster, U(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one U(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(5), and one H(6) atom. Cl(1) is bonded in a 4-coordinate geometry to one U(1) atom.
(UH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two UH12(O3Cl)2 clusters. In each UH12(O3Cl)2 cluster, U(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. Both U(1)-O(1) bond lengths are 2.50 Å. Both U(1)-O(2) bond lengths are 2.50 Å. Both U(1)-O(3) bond lengths are 2.52 Å. Both U(1)-Cl(1) bond lengths are 2.92 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.99 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one U(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(5), and one H(6) atom. Cl(1) is bonded in a 4-coordinate geometry to one U(1) atom.