SbP(OF3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbP(OF3)2 cluster. Sb(1) is bonded to one O(1), one O(2), one F(1), one F(4), one F(5), and one F(6) atom to form SbO2F4 octahedra that share corners with two equivalent P(1)O2F2 tetrahedra. P(1) is bonded to one O(1), one O(2), one F(2), and one F(3) atom to form PO2F2 tetrahedra that share corners with two equivalent Sb(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom.
SbP(OF3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbP(OF3)2 cluster. Sb(1) is bonded to one O(1), one O(2), one F(1), one F(4), one F(5), and one F(6) atom to form SbO2F4 octahedra that share corners with two equivalent P(1)O2F2 tetrahedra. The Sb(1)-O(1) bond length is 2.06 Å. The Sb(1)-O(2) bond length is 2.06 Å. The Sb(1)-F(1) bond length is 1.89 Å. The Sb(1)-F(4) bond length is 1.89 Å. The Sb(1)-F(5) bond length is 1.89 Å. The Sb(1)-F(6) bond length is 1.91 Å. P(1) is bonded to one O(1), one O(2), one F(2), and one F(3) atom to form PO2F2 tetrahedra that share corners with two equivalent Sb(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. The P(1)-O(1) bond length is 1.52 Å. The P(1)-O(2) bond length is 1.51 Å. The P(1)-F(2) bond length is 1.54 Å. The P(1)-F(3) bond length is 1.53 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom.