AuCl4C5S4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two tetrakis(methylthio)tetrathiafulvalene molecules and four AuCl4 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom.
AuCl4C5S4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two tetrakis(methylthio)tetrathiafulvalene molecules and four AuCl4 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. The Au(1)-Cl(1) bond length is 2.31 Å. The Au(1)-Cl(3) bond length is 2.34 Å. Both Au(1)-Cl(2) bond lengths are 2.32 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom.