Ni(HO)12(BrO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hypobromous acid molecules and one Ni(HO)12 cluster. In the Ni(HO)12 cluster, Ni(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one O(5) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(3) and one O(6) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(4) and one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. There are six inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one Ni(1) and one H(1) atom. In the second O site, O(3) is bonded in a water-like geometry to one Ni(1) and one H(2) atom. In the third O site, O(4) is bonded in a water-like geometry to one Ni(1) and one H(3) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one H(1) and one H(5) atom. In the fifth O site, O(6) is bonded in a water-like geometry to one H(2) and one H(6) atom. In the sixth O site, O(7) is bonded in a water-like geometry to one H(3) and one H(4) atom.
Ni(HO)12(BrO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hypobromous acid molecules and one Ni(HO)12 cluster. In the Ni(HO)12 cluster, Ni(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both Ni(1)-O(2) bond lengths are 1.83 Å. Both Ni(1)-O(3) bond lengths are 1.83 Å. Both Ni(1)-O(4) bond lengths are 1.84 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one O(5) atom. The H(1)-O(2) bond length is 1.67 Å. The H(1)-O(5) bond length is 1.01 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(3) and one O(6) atom. The H(2)-O(3) bond length is 1.66 Å. The H(2)-O(6) bond length is 1.01 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(4) and one O(7) atom. The H(3)-O(4) bond length is 1.67 Å. The H(3)-O(7) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. The H(4)-O(7) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. The H(5)-O(5) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. The H(6)-O(6) bond length is 0.98 Å. There are six inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one Ni(1) and one H(1) atom. In the second O site, O(3) is bonded in a water-like geometry to one Ni(1) and one H(2) atom. In the third O site, O(4) is bonded in a water-like geometry to one Ni(1) and one H(3) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one H(1) and one H(5) atom. In the fifth O site, O(6) is bonded in a water-like geometry to one H(2) and one H(6) atom. In the sixth O site, O(7) is bonded in a water-like geometry to one H(3) and one H(4) atom.