AsF3AsSF8NS2F3NSOFNF2NOF crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one arsenic trifluoride molecule, one difluoroamine molecule, one n-hydroxyhypofluorous amide molecule, one AsSF8 cluster, one NS2F3 cluster, and one NSOF cluster. In the AsSF8 cluster, As(2) is bonded in a distorted rectangular see-saw-like geometry to one F(11), one F(18), one F(5), and one F(6) atom. S(3) is bonded in a square pyramidal geometry to one F(15), one F(5), one F(7), one F(8), and one F(9) atom. There are eight inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one As(2) and one S(3) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the third F site, F(7) is bonded in a single-bond geometry to one S(3) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one S(3) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one S(3) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(2) atom. In the seventh F site, F(15) is bonded in a single-bond geometry to one S(3) atom. In the eighth F site, F(18) is bonded in a single-bond geometry to one As(2) atom. In the NS2F3 cluster, N(3) is bonded in a single-bond geometry to one S(4) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 2-coordinate geometry to one F(12), one F(13), and one F(14) atom. In the second S site, S(4) is bonded in a water-like geometry to one N(3) and one F(13) atom. There are three inequivalent F sites. In the first F site, F(12) is bonded in a single-bond geometry to one S(2) atom. In the second F site, F(13) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the third F site, F(14) is bonded in a single-bond geometry to one S(2) atom. In the NSOF cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one N(2), one O(2), and one F(16) atom. O(2) is bonded in a single-bond geometry to one S(1) atom. F(16) is bonded in a single-bond geometry to one S(1) atom.
AsF3AsSF8NS2F3NSOFNF2NOF crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one arsenic trifluoride molecule, one difluoroamine molecule, one n-hydroxyhypofluorous amide molecule, one AsSF8 cluster, one NS2F3 cluster, and one NSOF cluster. In the AsSF8 cluster, As(2) is bonded in a distorted rectangular see-saw-like geometry to one F(11), one F(18), one F(5), and one F(6) atom. The As(2)-F(11) bond length is 1.82 Å. The As(2)-F(18) bond length is 1.76 Å. The As(2)-F(5) bond length is 2.39 Å. The As(2)-F(6) bond length is 1.76 Å. S(3) is bonded in a square pyramidal geometry to one F(15), one F(5), one F(7), one F(8), and one F(9) atom. The S(3)-F(15) bond length is 1.99 Å. The S(3)-F(5) bond length is 1.87 Å. The S(3)-F(7) bond length is 1.58 Å. The S(3)-F(8) bond length is 1.67 Å. The S(3)-F(9) bond length is 1.64 Å. There are eight inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one As(2) and one S(3) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the third F site, F(7) is bonded in a single-bond geometry to one S(3) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one S(3) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one S(3) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(2) atom. In the seventh F site, F(15) is bonded in a single-bond geometry to one S(3) atom. In the eighth F site, F(18) is bonded in a single-bond geometry to one As(2) atom. In the NS2F3 cluster, N(3) is bonded in a single-bond geometry to one S(4) atom. The N(3)-S(4) bond length is 1.43 Å. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 2-coordinate geometry to one F(12), one F(13), and one F(14) atom. The S(2)-F(12) bond length is 1.60 Å. The S(2)-F(13) bond length is 2.17 Å. The S(2)-F(14) bond length is 1.55 Å. In the second S site, S(4) is bonded in a water-like geometry to one N(3) and one F(13) atom. The S(4)-F(13) bond length is 1.86 Å. There are three inequivalent F sites. In the first F site, F(12) is bonded in a single-bond geometry to one S(2) atom. In the second F site, F(13) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the third F site, F(14) is bonded in a single-bond geometry to one S(2) atom. In the NSOF cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. The N(2)-S(1) bond length is 1.44 Å. S(1) is bonded in a distorted trigonal planar geometry to one N(2), one O(2), and one F(16) atom. The S(1)-O(2) bond length is 1.44 Å. The S(1)-F(16) bond length is 1.63 Å. O(2) is bonded in a single-bond geometry to one S(1) atom. F(16) is bonded in a single-bond geometry to one S(1) atom.