MnSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms.
MnSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Mn(1)-O(1) bond lengths are 2.23 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. All Sb(1)-O(1) bond lengths are 1.99 Å. O(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms.