TiHg2Zn is Tetraauricupride-derived structured and crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to eight equivalent Hg(1) and four equivalent Zn(1) atoms to form distorted TiZn4Hg8 cuboctahedra that share corners with twelve equivalent Ti(1)Zn4Hg8 cuboctahedra, edges with eight equivalent Zn(1)Ti4Hg8 cuboctahedra, faces with four equivalent Zn(1)Ti4Hg8 cuboctahedra, and faces with six equivalent Ti(1)Zn4Hg8 cuboctahedra. Hg(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ti(1) and four equivalent Zn(1) atoms. Zn(1) is bonded to four equivalent Ti(1) and eight equivalent Hg(1) atoms to form ZnTi4Hg8 cuboctahedra that share corners with twelve equivalent Zn(1)Ti4Hg8 cuboctahedra, edges with eight equivalent Ti(1)Zn4Hg8 cuboctahedra, faces with four equivalent Ti(1)Zn4Hg8 cuboctahedra, and faces with six equivalent Zn(1)Ti4Hg8 cuboctahedra.
TiHg2Zn is Tetraauricupride-derived structured and crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to eight equivalent Hg(1) and four equivalent Zn(1) atoms to form distorted TiZn4Hg8 cuboctahedra that share corners with twelve equivalent Ti(1)Zn4Hg8 cuboctahedra, edges with eight equivalent Zn(1)Ti4Hg8 cuboctahedra, faces with four equivalent Zn(1)Ti4Hg8 cuboctahedra, and faces with six equivalent Ti(1)Zn4Hg8 cuboctahedra. All Ti(1)-Hg(1) bond lengths are 2.94 Å. All Ti(1)-Zn(1) bond lengths are 3.13 Å. Hg(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ti(1) and four equivalent Zn(1) atoms. All Hg(1)-Zn(1) bond lengths are 2.94 Å. Zn(1) is bonded to four equivalent Ti(1) and eight equivalent Hg(1) atoms to form ZnTi4Hg8 cuboctahedra that share corners with twelve equivalent Zn(1)Ti4Hg8 cuboctahedra, edges with eight equivalent Ti(1)Zn4Hg8 cuboctahedra, faces with four equivalent Ti(1)Zn4Hg8 cuboctahedra, and faces with six equivalent Zn(1)Ti4Hg8 cuboctahedra.