Ag3CS(NO2)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to one N(2), one S(1), and one O(5) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(6) atoms. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(2), one S(1), one O(1), one O(2), and one O(3) atom. In the fourth Ag site, Ag(4) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(5) atoms. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(5), and one O(6) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one C(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. S(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(3) and one N(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ag(3) and one N(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(4), and one N(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(4), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Ag(2) and one N(1) atom.
Ag3CS(NO2)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to one N(2), one S(1), and one O(5) atom. The Ag(1)-N(2) bond length is 2.34 Å. The Ag(1)-S(1) bond length is 2.80 Å. The Ag(1)-O(5) bond length is 2.46 Å. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(6) atoms. Both Ag(2)-S(1) bond lengths are 2.76 Å. Both Ag(2)-O(4) bond lengths are 2.52 Å. Both Ag(2)-O(6) bond lengths are 2.86 Å. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(2), one S(1), one O(1), one O(2), and one O(3) atom. The Ag(3)-N(2) bond length is 2.25 Å. The Ag(3)-S(1) bond length is 2.94 Å. The Ag(3)-O(1) bond length is 2.78 Å. The Ag(3)-O(2) bond length is 2.40 Å. The Ag(3)-O(3) bond length is 2.52 Å. In the fourth Ag site, Ag(4) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(5) atoms. Both Ag(4)-S(1) bond lengths are 2.59 Å. Both Ag(4)-O(4) bond lengths are 2.77 Å. Both Ag(4)-O(5) bond lengths are 2.83 Å. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(1)-N(2) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.65 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(5), and one O(6) atom. The N(1)-O(2) bond length is 1.28 Å. The N(1)-O(5) bond length is 1.27 Å. The N(1)-O(6) bond length is 1.26 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one C(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. The N(3)-O(1) bond length is 1.27 Å. The N(3)-O(3) bond length is 1.26 Å. The N(3)-O(4) bond length is 1.29 Å. S(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(3) and one N(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ag(3) and one N(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(4), and one N(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(4), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Ag(2) and one N(1) atom.