TaCl6PCl4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two TaCl6 clusters. In one of the TaCl6 clusters, Ta(1) is bonded in an octahedral geometry to two equivalent Cl(2,5); two equivalent Cl(4); and two equivalent Cl(6) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ta(1) atom. In the second Cl site, Cl(2,5) is bonded in a single-bond geometry to one Ta(2) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Ta(1) atom. In one of the TaCl6 clusters, Ta(2) is bonded in an octahedral geometry to two equivalent Cl(1); two equivalent Cl(2,5); and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ta(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ta(2) atom. In the third Cl site, Cl(2,5) is bonded in a single-bond geometry to one Ta(2) atom.
TaCl6PCl4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two TaCl6 clusters. In one of the TaCl6 clusters, Ta(1) is bonded in an octahedral geometry to two equivalent Cl(2,5); two equivalent Cl(4); and two equivalent Cl(6) atoms. Both Ta(1)-Cl(2,5) bond lengths are 2.37 Å. Both Ta(1)-Cl(4) bond lengths are 2.36 Å. Both Ta(1)-Cl(6) bond lengths are 2.35 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ta(1) atom. In the second Cl site, Cl(2,5) is bonded in a single-bond geometry to one Ta(2) atom. The Cl(2,5)-Ta(2) bond length is 2.37 Å. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Ta(1) atom. In one of the TaCl6 clusters, Ta(2) is bonded in an octahedral geometry to two equivalent Cl(1); two equivalent Cl(2,5); and two equivalent Cl(3) atoms. Both Ta(2)-Cl(1) bond lengths are 2.35 Å. Both Ta(2)-Cl(3) bond lengths are 2.36 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ta(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ta(2) atom. In the third Cl site, Cl(2,5) is bonded in a single-bond geometry to one Ta(2) atom.