KTlBr3 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlBr3 framework. In the TlBr3 framework, there are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to six equivalent Br(1) atoms to form corner-sharing TlBr6 octahedra. The corner-sharing octahedra are not tilted. In the second Tl site, Tl(2) is bonded to six equivalent Br(1) atoms to form corner-sharing TlBr6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Tl(1) and one Tl(2) atom.
KTlBr3 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlBr3 framework. In the TlBr3 framework, there are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to six equivalent Br(1) atoms to form corner-sharing TlBr6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 3.07 Å. In the second Tl site, Tl(2) is bonded to six equivalent Br(1) atoms to form corner-sharing TlBr6 octahedra. The corner-sharing octahedra are not tilted. All Tl(2)-Br(1) bond lengths are 2.80 Å. Br(1) is bonded in a linear geometry to one Tl(1) and one Tl(2) atom.