CoBr(N2O)2NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitrous acid molecules and four CoBr(N2O)2 clusters. In each CoBr(N2O)2 cluster, Co(1) is bonded in a 5-coordinate geometry to one N(2), one N(3), one N(4), one N(5), and one Br(1) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one O(3), and one O(4) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. Br(1) is bonded in a single-bond geometry to one Co(1) atom.
CoBr(N2O)2NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitrous acid molecules and four CoBr(N2O)2 clusters. In each CoBr(N2O)2 cluster, Co(1) is bonded in a 5-coordinate geometry to one N(2), one N(3), one N(4), one N(5), and one Br(1) atom. The Co(1)-N(2) bond length is 2.11 Å. The Co(1)-N(3) bond length is 1.53 Å. The Co(1)-N(4) bond length is 1.81 Å. The Co(1)-N(5) bond length is 1.80 Å. The Co(1)-Br(1) bond length is 2.31 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one O(3), and one O(4) atom. The N(2)-O(3) bond length is 1.22 Å. The N(2)-O(4) bond length is 1.22 Å. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. Br(1) is bonded in a single-bond geometry to one Co(1) atom.