Cr2CoP3 is Modderite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. In the second Cr site, Cr(2) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. In the third Cr site, Cr(3) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. In the fourth Cr site, Cr(4) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. In the fifth Cr site, Cr(5) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. In the sixth Cr site, Cr(6) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. In the seventh Cr site, Cr(7) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. In the eighth Cr site, Cr(8) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. In the third Co site, Co(3) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(3), two equivalent Cr(6), and one Co(3) atom. In the second P site, P(2) is bonded in a 6-coordinate geometry to two equivalent Cr(4), two equivalent Cr(7), one Co(1), and one Co(4) atom. In the third P site, P(3) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(5), two equivalent Cr(8), and one Co(2) atom. In the fourth P site, P(4) is bonded in a 6-coordinate geometry to two equivalent Cr(3), two equivalent Cr(6), one Co(1), and one Co(4) atom. In the fifth P site, P(5) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(4), two equivalent Cr(7), and one Co(2) atom. In the sixth P site, P(6) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(5), two equivalent Cr(8), and one Co(3) atom. In the seventh P site, P(7) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Co(1), and two equivalent Co(4) atoms. In the eighth P site, P(8) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(1), and two equivalent Co(2) atoms. In the ninth P site, P(9) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Cr(2), and two equivalent Co(3) atoms. In the tenth P site, P(10) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Co(1), and two equivalent Co(4) atoms. In the eleventh P site, P(11) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Cr(1), and two equivalent Co(2) atoms. In the twelfth P site, P(12) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(2), and two equivalent Co(3) atoms.
Cr2CoP3 is Modderite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. The Cr(1)-P(3) bond length is 2.26 Å. The Cr(1)-P(5) bond length is 2.37 Å. Both Cr(1)-P(11) bond lengths are 2.34 Å. Both Cr(1)-P(8) bond lengths are 2.35 Å. In the second Cr site, Cr(2) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. The Cr(2)-P(1) bond length is 2.26 Å. The Cr(2)-P(6) bond length is 2.38 Å. Both Cr(2)-P(12) bond lengths are 2.35 Å. Both Cr(2)-P(9) bond lengths are 2.35 Å. In the third Cr site, Cr(3) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. The Cr(3)-P(10) bond length is 2.30 Å. The Cr(3)-P(9) bond length is 2.39 Å. Both Cr(3)-P(1) bond lengths are 2.31 Å. Both Cr(3)-P(4) bond lengths are 2.38 Å. In the fourth Cr site, Cr(4) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. The Cr(4)-P(11) bond length is 2.32 Å. The Cr(4)-P(7) bond length is 2.39 Å. Both Cr(4)-P(2) bond lengths are 2.32 Å. Both Cr(4)-P(5) bond lengths are 2.41 Å. In the fifth Cr site, Cr(5) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. The Cr(5)-P(12) bond length is 2.31 Å. The Cr(5)-P(8) bond length is 2.38 Å. Both Cr(5)-P(3) bond lengths are 2.31 Å. Both Cr(5)-P(6) bond lengths are 2.40 Å. In the sixth Cr site, Cr(6) is bonded in a 6-coordinate geometry to one P(10), one P(9), two equivalent P(1), and two equivalent P(4) atoms. The Cr(6)-P(10) bond length is 2.40 Å. The Cr(6)-P(9) bond length is 2.32 Å. Both Cr(6)-P(1) bond lengths are 2.39 Å. Both Cr(6)-P(4) bond lengths are 2.33 Å. In the seventh Cr site, Cr(7) is bonded in a 6-coordinate geometry to one P(11), one P(7), two equivalent P(2), and two equivalent P(5) atoms. The Cr(7)-P(11) bond length is 2.43 Å. The Cr(7)-P(7) bond length is 2.31 Å. Both Cr(7)-P(2) bond lengths are 2.37 Å. Both Cr(7)-P(5) bond lengths are 2.33 Å. In the eighth Cr site, Cr(8) is bonded in a 6-coordinate geometry to one P(12), one P(8), two equivalent P(3), and two equivalent P(6) atoms. The Cr(8)-P(12) bond length is 2.42 Å. The Cr(8)-P(8) bond length is 2.32 Å. Both Cr(8)-P(3) bond lengths are 2.37 Å. Both Cr(8)-P(6) bond lengths are 2.33 Å. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. The Co(1)-P(2) bond length is 2.33 Å. The Co(1)-P(4) bond length is 2.24 Å. Both Co(1)-P(10) bond lengths are 2.37 Å. Both Co(1)-P(7) bond lengths are 2.26 Å. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one P(3), one P(5), two equivalent P(11), and two equivalent P(8) atoms. The Co(2)-P(3) bond length is 2.36 Å. The Co(2)-P(5) bond length is 2.28 Å. Both Co(2)-P(11) bond lengths are 2.34 Å. Both Co(2)-P(8) bond lengths are 2.28 Å. In the third Co site, Co(3) is bonded in a 6-coordinate geometry to one P(1), one P(6), two equivalent P(12), and two equivalent P(9) atoms. The Co(3)-P(1) bond length is 2.36 Å. The Co(3)-P(6) bond length is 2.28 Å. Both Co(3)-P(12) bond lengths are 2.35 Å. Both Co(3)-P(9) bond lengths are 2.29 Å. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one P(2), one P(4), two equivalent P(10), and two equivalent P(7) atoms. The Co(4)-P(2) bond length is 2.25 Å. The Co(4)-P(4) bond length is 2.32 Å. Both Co(4)-P(10) bond lengths are 2.26 Å. Both Co(4)-P(7) bond lengths are 2.37 Å. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(3), two equivalent Cr(6), and one Co(3) atom. In the second P site, P(2) is bonded in a 6-coordinate geometry to two equivalent Cr(4), two equivalent Cr(7), one Co(1), and one Co(4) atom. In the third P site, P(3) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(5), two equivalent Cr(8), and one Co(2) atom. In the fourth P site, P(4) is bonded in a 6-coordinate geometry to two equivalent Cr(3), two equivalent Cr(6), one Co(1), and one Co(4) atom. In the fifth P site, P(5) is bonded in a 6-coordinate geometry to one Cr(1), two equivalent Cr(4), two equivalent Cr(7), and one Co(2) atom. In the sixth P site, P(6) is bonded in a 6-coordinate geometry to one Cr(2), two equivalent Cr(5), two equivalent Cr(8), and one Co(3) atom. In the seventh P site, P(7) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Co(1), and two equivalent Co(4) atoms. In the eighth P site, P(8) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(1), and two equivalent Co(2) atoms. In the ninth P site, P(9) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Cr(2), and two equivalent Co(3) atoms. In the tenth P site, P(10) is bonded in a 6-coordinate geometry to one Cr(3), one Cr(6), two equivalent Co(1), and two equivalent Co(4) atoms. In the eleventh P site, P(11) is bonded in a 6-coordinate geometry to one Cr(4), one Cr(7), two equivalent Cr(1), and two equivalent Co(2) atoms. In the twelfth P site, P(12) is bonded in a 6-coordinate geometry to one Cr(5), one Cr(8), two equivalent Cr(2), and two equivalent Co(3) atoms.