AsF6SeCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four SeCl3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each SeCl3 cluster, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom.
AsF6SeCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four SeCl3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.79 Å. The As(1)-F(2) bond length is 1.80 Å. The As(1)-F(3) bond length is 1.77 Å. The As(1)-F(4) bond length is 1.76 Å. The As(1)-F(5) bond length is 1.76 Å. The As(1)-F(6) bond length is 1.78 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each SeCl3 cluster, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. The Se(1)-Cl(1) bond length is 2.14 Å. The Se(1)-Cl(2) bond length is 2.14 Å. The Se(1)-Cl(3) bond length is 2.15 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom.