BP(IBr)3 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BP(IBr)3 clusters. B(1) is bonded in a tetrahedral geometry to one P(1), one Br(2), and two equivalent Br(1) atoms. P(1) is bonded in a tetrahedral geometry to one B(1) and three equivalent I(1,2) atoms. I(1,2) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one B(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one B(1) atom.
BP(IBr)3 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BP(IBr)3 clusters. B(1) is bonded in a tetrahedral geometry to one P(1), one Br(2), and two equivalent Br(1) atoms. The B(1)-P(1) bond length is 2.05 Å. The B(1)-Br(2) bond length is 2.00 Å. Both B(1)-Br(1) bond lengths are 1.99 Å. P(1) is bonded in a tetrahedral geometry to one B(1) and three equivalent I(1,2) atoms. There is one shorter (2.43 Å) and two longer (2.44 Å) P(1)-I(1,2) bond lengths. I(1,2) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one B(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one B(1) atom.