NaLiO crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge, corner, and face-sharing NaO6 cuboctahedra. Li(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Li(1) atoms.
NaLiO crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge, corner, and face-sharing NaO6 cuboctahedra. All Na(1)-O(1) bond lengths are 2.57 Å. Li(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 1.94 Å. O(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Li(1) atoms.