RbPbCl3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-17-7 atoms inside a PbCl3 framework. In the PbCl3 framework, Pb(1) is bonded to two equivalent Cl(2) and four equivalent Cl(1) atoms to form corner-sharing PbCl6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a linear geometry to two equivalent Pb(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted linear geometry to two equivalent Pb(1) atoms.
RbPbCl3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-17-7 atoms inside a PbCl3 framework. In the PbCl3 framework, Pb(1) is bonded to two equivalent Cl(2) and four equivalent Cl(1) atoms to form corner-sharing PbCl6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. There is one shorter (2.85 Å) and one longer (2.86 Å) Pb(1)-Cl(2) bond length. All Pb(1)-Cl(1) bond lengths are 2.86 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a linear geometry to two equivalent Pb(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted linear geometry to two equivalent Pb(1) atoms.