ZnZn(WF4)2 crystallizes in the monoclinic C2 space group. The structure consists of two 7440-66-6 atoms inside a Zn(WF4)2 framework. In the Zn(WF4)2 framework, W(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(4) atom. Zn(2) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom.
ZnZn(WF4)2 crystallizes in the monoclinic C2 space group. The structure consists of two 7440-66-6 atoms inside a Zn(WF4)2 framework. In the Zn(WF4)2 framework, W(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(4) atom. The W(1)-F(1) bond length is 2.02 Å. The W(1)-F(2) bond length is 2.03 Å. The W(1)-F(3) bond length is 2.03 Å. The W(1)-F(4) bond length is 2.03 Å. Zn(2) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. Both Zn(2)-F(1) bond lengths are 2.52 Å. Both Zn(2)-F(2) bond lengths are 2.54 Å. Both Zn(2)-F(3) bond lengths are 2.53 Å. Both Zn(2)-F(4) bond lengths are 2.55 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom.