NaN crystallizes in the orthorhombic Fddd space group. Na(1) is bonded in a distorted square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded to four equivalent Na(1) and one N(1) atom to form a mixture of distorted edge and corner-sharing NNa4N trigonal bipyramids.
NaN crystallizes in the orthorhombic Fddd space group. Na(1) is bonded in a distorted square co-planar geometry to four equivalent N(1) atoms. There are two shorter (2.53 Å) and two longer (2.57 Å) Na(1)-N(1) bond lengths. N(1) is bonded to four equivalent Na(1) and one N(1) atom to form a mixture of distorted edge and corner-sharing NNa4N trigonal bipyramids. The N(1)-N(1) bond length is 1.20 Å.