GaF3 crystallizes in the trigonal R-3c space group. Ga(1) is bonded to six equivalent F(1) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles are 38°. F(1) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms.
GaF3 crystallizes in the trigonal R-3c space group. Ga(1) is bonded to six equivalent F(1) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles are 38°. All Ga(1)-F(1) bond lengths are 1.90 Å. F(1) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms.