S2C2N3H5 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two aminothiol molecules, two isothiocyanatocyanamide molecules, two methanimine molecules, and two CNH4S2 clusters. In each CNH4S2 cluster, C(4) is bonded in a distorted single-bond geometry to one H(2), one S(3), and one S(4) atom. N(5) is bonded in a bent 120 degrees geometry to one H(4) and one S(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one S(3) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(1), and one H(5) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one C(4) and one N(5) atom.
S2C2N3H5 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two aminothiol molecules, two isothiocyanatocyanamide molecules, two methanimine molecules, and two CNH4S2 clusters. In each CNH4S2 cluster, C(4) is bonded in a distorted single-bond geometry to one H(2), one S(3), and one S(4) atom. The C(4)-H(2) bond length is 1.09 Å. The C(4)-S(3) bond length is 1.72 Å. The C(4)-S(4) bond length is 1.68 Å. N(5) is bonded in a bent 120 degrees geometry to one H(4) and one S(4) atom. The N(5)-H(4) bond length is 1.03 Å. The N(5)-S(4) bond length is 1.55 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(3) atom. The H(1)-S(3) bond length is 1.38 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one S(3) atom. The H(5)-S(3) bond length is 1.38 Å. There are two inequivalent S sites. In the first S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(1), and one H(5) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one C(4) and one N(5) atom.