Ti4CrBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Bi(1) atoms. Cr(1) is bonded in a 10-coordinate geometry to eight equivalent Ti(1) and two equivalent Cr(1) atoms. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms.
Ti4CrBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Bi(1) atoms. Both Ti(1)-Cr(1) bond lengths are 2.53 Å. There are a spread of Ti(1)-Bi(1) bond distances ranging from 2.91-3.16 Å. Cr(1) is bonded in a 10-coordinate geometry to eight equivalent Ti(1) and two equivalent Cr(1) atoms. Both Cr(1)-Cr(1) bond lengths are 2.55 Å. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms.