XeSbF9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeSbF9 clusters. Xe(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(7), one F(8), and one F(9) atom. There are nine inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Xe(1) and one Sb(1) atom. In the seventh F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the eighth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the ninth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom.
XeSbF9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeSbF9 clusters. Xe(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. The Xe(1)-F(3) bond length is 2.42 Å. The Xe(1)-F(4) bond length is 2.00 Å. The Xe(1)-F(5) bond length is 1.97 Å. The Xe(1)-F(6) bond length is 2.01 Å. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(7), one F(8), and one F(9) atom. The Sb(1)-F(1) bond length is 1.89 Å. The Sb(1)-F(2) bond length is 1.91 Å. The Sb(1)-F(3) bond length is 2.01 Å. The Sb(1)-F(7) bond length is 1.91 Å. The Sb(1)-F(8) bond length is 1.91 Å. The Sb(1)-F(9) bond length is 1.93 Å. There are nine inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Xe(1) and one Sb(1) atom. In the seventh F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In the eighth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the ninth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom.