Ti3S2 is Ilmenite-derived structured and crystallizes in the trigonal R32 space group. Ti(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted face, corner, and edge-sharing STi6 pentagonal pyramids.
Ti3S2 is Ilmenite-derived structured and crystallizes in the trigonal R32 space group. Ti(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. There are two shorter (2.42 Å) and two longer (2.44 Å) Ti(1)-S(1) bond lengths. S(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted face, corner, and edge-sharing STi6 pentagonal pyramids.