LiAgF3 is Calcite structured and crystallizes in the trigonal R3c space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to six equivalent F(1) atoms. Ag(1) is bonded to six equivalent F(1) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 51°. F(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms.
LiAgF3 is Calcite structured and crystallizes in the trigonal R3c space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to six equivalent F(1) atoms. There are three shorter (1.95 Å) and three longer (2.48 Å) Li(1)-F(1) bond lengths. Ag(1) is bonded to six equivalent F(1) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are three shorter (2.23 Å) and three longer (2.24 Å) Ag(1)-F(1) bond lengths. F(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms.