NaZnAs is half-Heusler structured and crystallizes in the cubic F-43m space group. Na(1) is bonded to six equivalent Zn(1) and four equivalent As(1) atoms to form a mixture of distorted corner and face-sharing NaZn6As4 tetrahedra. Zn(1) is bonded in a 10-coordinate geometry to six equivalent Na(1) and four equivalent As(1) atoms. As(1) is bonded in a body-centered cubic geometry to four equivalent Na(1) and four equivalent Zn(1) atoms.
NaZnAs is half-Heusler structured and crystallizes in the cubic F-43m space group. Na(1) is bonded to six equivalent Zn(1) and four equivalent As(1) atoms to form a mixture of distorted corner and face-sharing NaZn6As4 tetrahedra. All Na(1)-Zn(1) bond lengths are 3.18 Å. All Na(1)-As(1) bond lengths are 2.75 Å. Zn(1) is bonded in a 10-coordinate geometry to six equivalent Na(1) and four equivalent As(1) atoms. All Zn(1)-As(1) bond lengths are 2.75 Å. As(1) is bonded in a body-centered cubic geometry to four equivalent Na(1) and four equivalent Zn(1) atoms.