AgCrO2 crystallizes in the monoclinic Cc space group. Cr(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing CrO6 octahedra. Ag(1) is bonded in a 4-coordinate geometry to one O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Cr(1) and one Ag(1) atom to form distorted corner-sharing OCr3Ag tetrahedra. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent Cr(1) and three equivalent Ag(1) atoms.
AgCrO2 crystallizes in the monoclinic Cc space group. Cr(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing CrO6 octahedra. There are two shorter (2.01 Å) and one longer (2.02 Å) Cr(1)-O(1) bond length. All Cr(1)-O(2) bond lengths are 2.05 Å. Ag(1) is bonded in a 4-coordinate geometry to one O(1) and three equivalent O(2) atoms. The Ag(1)-O(1) bond length is 2.18 Å. There is one shorter (2.59 Å) and two longer (2.60 Å) Ag(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Cr(1) and one Ag(1) atom to form distorted corner-sharing OCr3Ag tetrahedra. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent Cr(1) and three equivalent Ag(1) atoms.