TlZnF3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Pm space group. The structure consists of one 7440-28-0 atom inside a ZnF3 framework. In the ZnF3 framework, Zn(1) is bonded to two equivalent F(1) and four F(2,2) atoms to form corner-sharing ZnF6 octahedra. The corner-sharing octahedra are not tilted. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Zn(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Zn(1) atoms. In the third F site, F(2) is bonded in a linear geometry to two equivalent Zn(1) atoms.
TlZnF3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Pm space group. The structure consists of one 7440-28-0 atom inside a ZnF3 framework. In the ZnF3 framework, Zn(1) is bonded to two equivalent F(1) and four F(2,2) atoms to form corner-sharing ZnF6 octahedra. The corner-sharing octahedra are not tilted. Both Zn(1)-F(1) bond lengths are 2.06 Å. All Zn(1)-F(2,2) bond lengths are 2.06 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Zn(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Zn(1) atoms. In the third F site, F(2) is bonded in a linear geometry to two equivalent Zn(1) atoms.