SbSO2F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbSO2F5 clusters. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one S(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.
SbSO2F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbSO2F5 clusters. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The Sb(1)-O(2) bond length is 2.17 Å. The Sb(1)-F(1) bond length is 1.90 Å. The Sb(1)-F(2) bond length is 1.91 Å. The Sb(1)-F(3) bond length is 1.90 Å. The Sb(1)-F(4) bond length is 1.90 Å. The Sb(1)-F(5) bond length is 1.90 Å. S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The S(1)-O(1) bond length is 1.43 Å. The S(1)-O(2) bond length is 1.49 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one S(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.