AgC6(N2O)2SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgC6(N2O)2 clusters and four SbF6 clusters. In each AgC6(N2O)2 cluster, Ag(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one C(2) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to one Ag(1) and one C(3) atom. In the second N site, N(1) is bonded in a distorted linear geometry to one Ag(1) and one C(1) atom. O(1) is bonded in a single-bond geometry to one C(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.
AgC6(N2O)2SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgC6(N2O)2 clusters and four SbF6 clusters. In each AgC6(N2O)2 cluster, Ag(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ag(1)-N(1) bond lengths are 2.32 Å. Both Ag(1)-N(2) bond lengths are 2.27 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) atom. The C(1)-N(1) bond length is 1.16 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. The C(2)-C(3) bond length is 1.47 Å. The C(2)-O(1) bond length is 1.22 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one C(2) and one N(2) atom. The C(3)-N(2) bond length is 1.16 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to one Ag(1) and one C(3) atom. In the second N site, N(1) is bonded in a distorted linear geometry to one Ag(1) and one C(1) atom. O(1) is bonded in a single-bond geometry to one C(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Sb(1)-F(1) bond lengths are 1.93 Å. Both Sb(1)-F(2) bond lengths are 1.92 Å. Both Sb(1)-F(3) bond lengths are 1.92 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.