Zn(AgO2)2 crystallizes in the triclinic P-1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(5), and two equivalent O(7) atoms. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(6), and two equivalent O(8) atoms. In the third Ag site, Ag(3) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. In the fifth Ag site, Ag(5) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms. In the sixth Ag site, Ag(6) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(3), one O(4), one O(5), one O(6), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Ag(1), one Ag(3), one Ag(5), and one Zn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ag(2), one Ag(4), one Ag(6), and one Zn(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(3), one Ag(5), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ag(2), one Ag(4), one Ag(6), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Ag(2), one Zn(1), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Ag(5), two equivalent Ag(1), one Zn(1), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Ag(6), two equivalent Ag(2), and one Zn(1) atom.
Zn(AgO2)2 crystallizes in the triclinic P-1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(5), and two equivalent O(7) atoms. The Ag(1)-O(1) bond length is 2.19 Å. The Ag(1)-O(3) bond length is 2.06 Å. The Ag(1)-O(5) bond length is 2.01 Å. There is one shorter (2.06 Å) and one longer (2.78 Å) Ag(1)-O(7) bond length. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(6), and two equivalent O(8) atoms. The Ag(2)-O(2) bond length is 2.18 Å. The Ag(2)-O(4) bond length is 2.07 Å. The Ag(2)-O(6) bond length is 2.02 Å. There is one shorter (2.07 Å) and one longer (2.73 Å) Ag(2)-O(8) bond length. In the third Ag site, Ag(3) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(3) atoms. Both Ag(3)-O(1) bond lengths are 2.11 Å. Both Ag(3)-O(3) bond lengths are 2.12 Å. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. Both Ag(4)-O(2) bond lengths are 2.09 Å. Both Ag(4)-O(4) bond lengths are 2.12 Å. In the fifth Ag site, Ag(5) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms. Both Ag(5)-O(1) bond lengths are 2.09 Å. Both Ag(5)-O(3) bond lengths are 2.65 Å. Both Ag(5)-O(7) bond lengths are 2.03 Å. In the sixth Ag site, Ag(6) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms. Both Ag(6)-O(2) bond lengths are 2.09 Å. Both Ag(6)-O(4) bond lengths are 2.62 Å. Both Ag(6)-O(8) bond lengths are 2.02 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom. The Zn(1)-O(1) bond length is 2.20 Å. The Zn(1)-O(2) bond length is 2.34 Å. The Zn(1)-O(5) bond length is 2.00 Å. The Zn(1)-O(6) bond length is 1.99 Å. The Zn(1)-O(7) bond length is 2.32 Å. The Zn(1)-O(8) bond length is 2.23 Å. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(3), one O(4), one O(5), one O(6), and one O(7) atom. The Zn(2)-O(3) bond length is 2.22 Å. The Zn(2)-O(4) bond length is 2.15 Å. The Zn(2)-O(5) bond length is 1.99 Å. The Zn(2)-O(6) bond length is 2.01 Å. The Zn(2)-O(7) bond length is 2.50 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Ag(1), one Ag(3), one Ag(5), and one Zn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ag(2), one Ag(4), one Ag(6), and one Zn(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(3), one Ag(5), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ag(2), one Ag(4), one Ag(6), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Ag(2), one Zn(1), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Ag(5), two equivalent Ag(1), one Zn(1), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Ag(6), two equivalent Ag(2), and one Zn(1) atom.