(BiN3O11)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of three hydrogen peroxide molecules and one BiN3O11 cluster. In the BiN3O11 cluster, Bi(1) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one O(12) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(2) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(1) atom. In the fourth O site, O(3) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(6) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one N(3) atom. In the ninth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Bi(1) and one N(3) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one Bi(1) and one N(3) atom. In the eleventh O site, O(12) is bonded in a bent 120 degrees geometry to one Bi(1) and one O(13) atom.
(BiN3O11)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of three hydrogen peroxide molecules and one BiN3O11 cluster. In the BiN3O11 cluster, Bi(1) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom. The Bi(1)-O(12) bond length is 2.60 Å. The Bi(1)-O(2) bond length is 2.42 Å. The Bi(1)-O(3) bond length is 2.42 Å. The Bi(1)-O(4) bond length is 2.38 Å. The Bi(1)-O(6) bond length is 2.38 Å. The Bi(1)-O(8) bond length is 2.44 Å. The Bi(1)-O(9) bond length is 2.81 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.21 Å. The N(1)-O(2) bond length is 1.31 Å. The N(1)-O(3) bond length is 1.30 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(2)-O(4) bond length is 1.31 Å. The N(2)-O(5) bond length is 1.21 Å. The N(2)-O(6) bond length is 1.31 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. The N(3)-O(7) bond length is 1.24 Å. The N(3)-O(8) bond length is 1.31 Å. The N(3)-O(9) bond length is 1.26 Å. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in a single-bond geometry to one O(12) atom. The O(13)-O(12) bond length is 1.24 Å. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(2) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(1) atom. In the fourth O site, O(3) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(6) is bonded in a distorted L-shaped geometry to one Bi(1) and one N(2) atom. In the eighth O site, O(7) is bonded in a single-bond geometry to one N(3) atom. In the ninth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Bi(1) and one N(3) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one Bi(1) and one N(3) atom. In the eleventh O site, O(12) is bonded in a bent 120 degrees geometry to one Bi(1) and one O(13) atom.