LiCoCdF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Co(1)F6 octahedra. The corner-sharing octahedral tilt angles are 56°. Co(1) is bonded to six equivalent F(1) atoms to form CoF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 47°. Cd(1) is bonded to six equivalent F(1) atoms to form CdF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Co(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one Cd(1) atom.
LiCoCdF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Co(1)F6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Li(1)-F(1) bond lengths are 2.03 Å. Co(1) is bonded to six equivalent F(1) atoms to form CoF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 47°. All Co(1)-F(1) bond lengths are 1.87 Å. Cd(1) is bonded to six equivalent F(1) atoms to form CdF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Co(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. All Cd(1)-F(1) bond lengths are 2.28 Å. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one Cd(1) atom.