Dy12Ge5S28 crystallizes in the triclinic P1 space group. There are twelve inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one S(1), one S(13), one S(15), one S(18), one S(20), one S(25), one S(5), and one S(6) atom. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one S(14), one S(16), one S(17), one S(19), one S(2), one S(26), one S(5), and one S(6) atom. In the third Dy site, Dy(3) is bonded in a 8-coordinate geometry to one S(1), one S(11), one S(16), one S(20), one S(22), one S(28), one S(7), and one S(8) atom. In the fourth Dy site, Dy(4) is bonded in a 8-coordinate geometry to one S(12), one S(15), one S(19), one S(2), one S(21), one S(27), one S(7), and one S(8) atom. In the fifth Dy site, Dy(5) is bonded in a 8-coordinate geometry to one S(1), one S(10), one S(11), one S(14), one S(18), one S(22), one S(23), and one S(9) atom. In the sixth Dy site, Dy(6) is bonded in a 8-coordinate geometry to one S(10), one S(12), one S(13), one S(17), one S(2), one S(21), one S(24), and one S(9) atom. In the seventh Dy site, Dy(7) is bonded in a 8-coordinate geometry to one S(11), one S(12), one S(19), one S(23), one S(25), one S(3), one S(7), and one S(9) atom. In the eighth Dy site, Dy(8) is bonded in a 8-coordinate geometry to one S(10), one S(11), one S(12), one S(20), one S(24), one S(26), one S(4), and one S(8) atom. In the ninth Dy site, Dy(9) is bonded in a 8-coordinate geometry to one S(10), one S(13), one S(14), one S(22), one S(25), one S(27), one S(3), and one S(5) atom. In the tenth Dy site, Dy(10) is bonded in a 8-coordinate geometry to one S(13), one S(14), one S(21), one S(26), one S(28), one S(4), one S(6), and one S(9) atom. In the eleventh Dy site, Dy(11) is bonded in a 8-coordinate geometry to one S(15), one S(16), one S(17), one S(23), one S(27), one S(3), one S(5), and one S(8) atom. In the twelfth Dy site, Dy(12) is bonded in a 8-coordinate geometry to one S(15), one S(16), one S(18), one S(24), one S(28), one S(4), one S(6), and one S(7) atom. There are five inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a tetrahedral geometry to one S(1), one S(17), one S(19), and one S(21) atom. In the second Ge site, Ge(2) is bonded in a tetrahedral geometry to one S(18), one S(2), one S(20), and one S(22) atom. In the third Ge site, Ge(3) is bonded in a tetrahedral geometry to one S(23), one S(25), one S(27), and one S(4) atom. In the fourth Ge site, Ge(4) is bonded in a tetrahedral geometry to one S(24), one S(26), one S(28), and one S(3) atom. In the fifth Ge site, Ge(5) is bonded in an octahedral geometry to one S(10), one S(12), one S(13), one S(15), one S(5), and one S(8) atom. There are twenty-eight inequivalent S sites. In the first S site, S(1) is bonded to one Dy(1), one Dy(3), one Dy(5), and one Ge(1) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(11)Dy4 trigonal pyramids, and  an edgeedge with one S(18)Dy3Ge trigonal pyramid. In the second S site, S(2) is bonded to one Dy(2), one Dy(4), one Dy(6), and one Ge(2) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid, corners with two equivalent S(12)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid, and  a cornercorner with one S(9)Dy4 trigonal pyramid. In the third S site, S(3) is bonded to one Dy(11), one Dy(7), one Dy(9), and one Ge(4) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(12)Dy4Ge trigonal bipyramid,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid, and  a cornercorner with one S(9)Dy4 trigonal pyramid. In the fourth S site, S(4) is bonded to one Dy(10), one Dy(12), one Dy(8), and one Ge(3) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(12)Dy4Ge trigonal bipyramid,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(6)Dy4 trigonal pyramids, and  an edgeedge with one S(28)Dy3Ge trigonal pyramid. In the fifth S site, S(5) is bonded in a 5-coordinate geometry to one Dy(1), one Dy(11), one Dy(2), one Dy(9), and one Ge(5) atom. In the sixth S site, S(6) is bonded to one Dy(1), one Dy(10), one Dy(12), and one Dy(2) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra, corners with two equivalent S(4)Dy3Ge tetrahedra,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(28)Dy3Ge trigonal pyramids,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(18)Dy3Ge trigonal pyramid,  an edgeedge with one S(14)Dy4 trigonal pyramid, and  an edgeedge with one S(16)Dy4 trigonal pyramid. In the seventh S site, S(7) is bonded to one Dy(12), one Dy(3), one Dy(4), and one Dy(7) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(28)Dy3Ge trigonal pyramid,  an edgeedge with one S(11)Dy4 trigonal pyramid, and  an edgeedge with one S(16)Dy4 trigonal pyramid. In the eighth S site, S(8) is bonded in a 5-coordinate geometry to one Dy(11), one Dy(3), one Dy(4), one Dy(8), and one Ge(5) atom. In the ninth S site, S(9) is bonded to one Dy(10), one Dy(5), one Dy(6), and one Dy(7) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(11)Dy4 trigonal pyramid, and  an edgeedge with one S(14)Dy4 trigonal pyramid. In the tenth S site, S(10) is bonded in a 5-coordinate geometry to one Dy(5), one Dy(6), one Dy(8), one Dy(9), and one Ge(5) atom. In the eleventh S site, S(11) is bonded to one Dy(3), one Dy(5), one Dy(7), and one Dy(8) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(1)Dy3Ge tetrahedra, corners with two equivalent S(12)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  an edgeedge with one S(7)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the twelfth S site, S(12) is bonded to one Dy(4), one Dy(6), one Dy(7), one Dy(8), and one Ge(5) atom to form distorted SDy4Ge trigonal bipyramids that share  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(2)Dy3Ge tetrahedra, corners with two equivalent S(11)Dy4 trigonal pyramids,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(7)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the thirteenth S site, S(13) is bonded to one Dy(1), one Dy(10), one Dy(6), one Dy(9), and one Ge(5) atom to form distorted SDy4Ge trigonal bipyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid, corners with two equivalent S(14)Dy4 trigonal pyramids,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the fourteenth S site, S(14) is bonded to one Dy(10), one Dy(2), one Dy(5), and one Dy(9) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(13)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the fifteenth S site, S(15) is bonded to one Dy(1), one Dy(11), one Dy(12), one Dy(4), and one Ge(5) atom to form distorted SDy4Ge trigonal bipyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(28)Dy3Ge trigonal pyramid, corners with two equivalent S(16)Dy4 trigonal pyramids,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(18)Dy3Ge trigonal pyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(7)Dy4 trigonal pyramid. In the sixteenth S site, S(16) is bonded to one Dy(11), one Dy(12), one Dy(2), and one Dy(3) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(15)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  an edgeedge with one S(28)Dy3Ge trigonal pyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(7)Dy4 trigonal pyramid. In the seventeenth S site, S(17) is bonded in a distorted rectangular see-saw-like geometry to one Dy(11), one Dy(2), one Dy(6), and one Ge(1) atom. In the eighteenth S site, S(18) is bonded to one Dy(1), one Dy(12), one Dy(5), and one Ge(2) atom to form distorted SDy3Ge trigonal pyramids that share  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid,  an edgeedge with one S(1)Dy3Ge tetrahedra,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid, and  an edgeedge with one S(6)Dy4 trigonal pyramid. In the nineteenth S site, S(19) is bonded in a distorted rectangular see-saw-like geometry to one Dy(2), one Dy(4), one Dy(7), and one Ge(1) atom. In the twentieth S site, S(20) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one Dy(3), one Dy(8), and one Ge(2) atom. In the twenty-first S site, S(21) is bonded in a distorted rectangular see-saw-like geometry to one Dy(10), one Dy(4), one Dy(6), and one Ge(1) atom. In the twenty-second S site, S(22) is bonded in a distorted rectangular see-saw-like geometry to one Dy(3), one Dy(5), one Dy(9), and one Ge(2) atom. In the twenty-third S site, S(23) is bonded in a distorted rectangular see-saw-like geometry to one Dy(11), one Dy(5), one Dy(7), and one Ge(3) atom. In the twenty-fourth S site, S(24) is bonded in a distorted rectangular see-saw-like geometry to one Dy(12), one Dy(6), one Dy(8), and one Ge(4) atom. In the twenty-fifth S site, S(25) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one Dy(7), one Dy(9), and one Ge(3) atom. In the twenty-sixth S site, S(26) is bonded in a distorted rectangular see-saw-like geometry to one Dy(10), one Dy(2), one Dy(8), and one Ge(4) atom. In the twenty-seventh S site, S(27) is bonded in a rectangular see-saw-like geometry to one Dy(11), one Dy(4), one Dy(9), and one Ge(3) atom. In the twenty-eighth S site, S(28) is bonded to one Dy(10), one Dy(12), one Dy(3), and one Ge(4) atom to form distorted SDy3Ge trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(6)Dy4 trigonal pyramids,  an edgeedge with one S(4)Dy3Ge tetrahedra,  an edgeedge with one S(16)Dy4 trigonal pyramid, and  an edgeedge with one S(7)Dy4 trigonal pyramid.
Dy12Ge5S28 crystallizes in the triclinic P1 space group. There are twelve inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one S(1), one S(13), one S(15), one S(18), one S(20), one S(25), one S(5), and one S(6) atom. The Dy(1)-S(1) bond length is 2.92 Å. The Dy(1)-S(13) bond length is 2.80 Å. The Dy(1)-S(15) bond length is 2.78 Å. The Dy(1)-S(18) bond length is 2.90 Å. The Dy(1)-S(20) bond length is 2.77 Å. The Dy(1)-S(25) bond length is 2.95 Å. The Dy(1)-S(5) bond length is 2.88 Å. The Dy(1)-S(6) bond length is 2.96 Å. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one S(14), one S(16), one S(17), one S(19), one S(2), one S(26), one S(5), and one S(6) atom. The Dy(2)-S(14) bond length is 2.70 Å. The Dy(2)-S(16) bond length is 2.74 Å. The Dy(2)-S(17) bond length is 2.90 Å. The Dy(2)-S(19) bond length is 2.89 Å. The Dy(2)-S(2) bond length is 2.96 Å. The Dy(2)-S(26) bond length is 2.92 Å. The Dy(2)-S(5) bond length is 3.44 Å. The Dy(2)-S(6) bond length is 2.76 Å. In the third Dy site, Dy(3) is bonded in a 8-coordinate geometry to one S(1), one S(11), one S(16), one S(20), one S(22), one S(28), one S(7), and one S(8) atom. The Dy(3)-S(1) bond length is 2.96 Å. The Dy(3)-S(11) bond length is 2.74 Å. The Dy(3)-S(16) bond length is 2.70 Å. The Dy(3)-S(20) bond length is 2.90 Å. The Dy(3)-S(22) bond length is 2.92 Å. The Dy(3)-S(28) bond length is 2.91 Å. The Dy(3)-S(7) bond length is 2.76 Å. The Dy(3)-S(8) bond length is 3.44 Å. In the fourth Dy site, Dy(4) is bonded in a 8-coordinate geometry to one S(12), one S(15), one S(19), one S(2), one S(21), one S(27), one S(7), and one S(8) atom. The Dy(4)-S(12) bond length is 2.77 Å. The Dy(4)-S(15) bond length is 2.79 Å. The Dy(4)-S(19) bond length is 2.89 Å. The Dy(4)-S(2) bond length is 2.93 Å. The Dy(4)-S(21) bond length is 2.74 Å. The Dy(4)-S(27) bond length is 2.96 Å. The Dy(4)-S(7) bond length is 2.97 Å. The Dy(4)-S(8) bond length is 2.87 Å. In the fifth Dy site, Dy(5) is bonded in a 8-coordinate geometry to one S(1), one S(10), one S(11), one S(14), one S(18), one S(22), one S(23), and one S(9) atom. The Dy(5)-S(1) bond length is 2.96 Å. The Dy(5)-S(10) bond length is 3.42 Å. The Dy(5)-S(11) bond length is 2.71 Å. The Dy(5)-S(14) bond length is 2.72 Å. The Dy(5)-S(18) bond length is 2.88 Å. The Dy(5)-S(22) bond length is 2.99 Å. The Dy(5)-S(23) bond length is 2.93 Å. The Dy(5)-S(9) bond length is 2.75 Å. In the sixth Dy site, Dy(6) is bonded in a 8-coordinate geometry to one S(10), one S(12), one S(13), one S(17), one S(2), one S(21), one S(24), and one S(9) atom. The Dy(6)-S(10) bond length is 2.88 Å. The Dy(6)-S(12) bond length is 2.78 Å. The Dy(6)-S(13) bond length is 2.79 Å. The Dy(6)-S(17) bond length is 2.78 Å. The Dy(6)-S(2) bond length is 2.93 Å. The Dy(6)-S(21) bond length is 2.83 Å. The Dy(6)-S(24) bond length is 2.93 Å. The Dy(6)-S(9) bond length is 2.98 Å. In the seventh Dy site, Dy(7) is bonded in a 8-coordinate geometry to one S(11), one S(12), one S(19), one S(23), one S(25), one S(3), one S(7), and one S(9) atom. The Dy(7)-S(11) bond length is 2.97 Å. The Dy(7)-S(12) bond length is 3.08 Å. The Dy(7)-S(19) bond length is 3.02 Å. The Dy(7)-S(23) bond length is 2.91 Å. The Dy(7)-S(25) bond length is 2.84 Å. The Dy(7)-S(3) bond length is 3.00 Å. The Dy(7)-S(7) bond length is 2.68 Å. The Dy(7)-S(9) bond length is 2.70 Å. In the eighth Dy site, Dy(8) is bonded in a 8-coordinate geometry to one S(10), one S(11), one S(12), one S(20), one S(24), one S(26), one S(4), and one S(8) atom. The Dy(8)-S(10) bond length is 2.84 Å. The Dy(8)-S(11) bond length is 2.80 Å. The Dy(8)-S(12) bond length is 3.16 Å. The Dy(8)-S(20) bond length is 2.87 Å. The Dy(8)-S(24) bond length is 2.87 Å. The Dy(8)-S(26) bond length is 2.78 Å. The Dy(8)-S(4) bond length is 2.90 Å. The Dy(8)-S(8) bond length is 2.80 Å. In the ninth Dy site, Dy(9) is bonded in a 8-coordinate geometry to one S(10), one S(13), one S(14), one S(22), one S(25), one S(27), one S(3), and one S(5) atom. The Dy(9)-S(10) bond length is 2.78 Å. The Dy(9)-S(13) bond length is 3.16 Å. The Dy(9)-S(14) bond length is 2.80 Å. The Dy(9)-S(22) bond length is 2.88 Å. The Dy(9)-S(25) bond length is 2.88 Å. The Dy(9)-S(27) bond length is 2.80 Å. The Dy(9)-S(3) bond length is 2.89 Å. The Dy(9)-S(5) bond length is 2.85 Å. In the tenth Dy site, Dy(10) is bonded in a 8-coordinate geometry to one S(13), one S(14), one S(21), one S(26), one S(28), one S(4), one S(6), and one S(9) atom. The Dy(10)-S(13) bond length is 3.08 Å. The Dy(10)-S(14) bond length is 2.97 Å. The Dy(10)-S(21) bond length is 2.98 Å. The Dy(10)-S(26) bond length is 2.90 Å. The Dy(10)-S(28) bond length is 2.82 Å. The Dy(10)-S(4) bond length is 3.03 Å. The Dy(10)-S(6) bond length is 2.72 Å. The Dy(10)-S(9) bond length is 2.69 Å. In the eleventh Dy site, Dy(11) is bonded in a 8-coordinate geometry to one S(15), one S(16), one S(17), one S(23), one S(27), one S(3), one S(5), and one S(8) atom. The Dy(11)-S(15) bond length is 3.15 Å. The Dy(11)-S(16) bond length is 2.80 Å. The Dy(11)-S(17) bond length is 2.85 Å. The Dy(11)-S(23) bond length is 2.79 Å. The Dy(11)-S(27) bond length is 2.88 Å. The Dy(11)-S(3) bond length is 2.88 Å. The Dy(11)-S(5) bond length is 2.79 Å. The Dy(11)-S(8) bond length is 2.83 Å. In the twelfth Dy site, Dy(12) is bonded in a 8-coordinate geometry to one S(15), one S(16), one S(18), one S(24), one S(28), one S(4), one S(6), and one S(7) atom. The Dy(12)-S(15) bond length is 3.07 Å. The Dy(12)-S(16) bond length is 2.98 Å. The Dy(12)-S(18) bond length is 3.03 Å. The Dy(12)-S(24) bond length is 2.82 Å. The Dy(12)-S(28) bond length is 2.89 Å. The Dy(12)-S(4) bond length is 3.04 Å. The Dy(12)-S(6) bond length is 2.69 Å. The Dy(12)-S(7) bond length is 2.72 Å. There are five inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a tetrahedral geometry to one S(1), one S(17), one S(19), and one S(21) atom. The Ge(1)-S(1) bond length is 2.18 Å. The Ge(1)-S(17) bond length is 2.24 Å. The Ge(1)-S(19) bond length is 2.24 Å. The Ge(1)-S(21) bond length is 2.26 Å. In the second Ge site, Ge(2) is bonded in a tetrahedral geometry to one S(18), one S(2), one S(20), and one S(22) atom. The Ge(2)-S(18) bond length is 2.24 Å. The Ge(2)-S(2) bond length is 2.19 Å. The Ge(2)-S(20) bond length is 2.24 Å. The Ge(2)-S(22) bond length is 2.23 Å. In the third Ge site, Ge(3) is bonded in a tetrahedral geometry to one S(23), one S(25), one S(27), and one S(4) atom. The Ge(3)-S(23) bond length is 2.23 Å. The Ge(3)-S(25) bond length is 2.24 Å. The Ge(3)-S(27) bond length is 2.25 Å. The Ge(3)-S(4) bond length is 2.19 Å. In the fourth Ge site, Ge(4) is bonded in a tetrahedral geometry to one S(24), one S(26), one S(28), and one S(3) atom. The Ge(4)-S(24) bond length is 2.24 Å. The Ge(4)-S(26) bond length is 2.24 Å. The Ge(4)-S(28) bond length is 2.23 Å. The Ge(4)-S(3) bond length is 2.20 Å. In the fifth Ge site, Ge(5) is bonded in an octahedral geometry to one S(10), one S(12), one S(13), one S(15), one S(5), and one S(8) atom. The Ge(5)-S(10) bond length is 2.43 Å. The Ge(5)-S(12) bond length is 2.48 Å. The Ge(5)-S(13) bond length is 2.47 Å. The Ge(5)-S(15) bond length is 2.49 Å. The Ge(5)-S(5) bond length is 2.41 Å. The Ge(5)-S(8) bond length is 2.42 Å. There are twenty-eight inequivalent S sites. In the first S site, S(1) is bonded to one Dy(1), one Dy(3), one Dy(5), and one Ge(1) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(11)Dy4 trigonal pyramids, and  an edgeedge with one S(18)Dy3Ge trigonal pyramid. In the second S site, S(2) is bonded to one Dy(2), one Dy(4), one Dy(6), and one Ge(2) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid, corners with two equivalent S(12)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid, and  a cornercorner with one S(9)Dy4 trigonal pyramid. In the third S site, S(3) is bonded to one Dy(11), one Dy(7), one Dy(9), and one Ge(4) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(12)Dy4Ge trigonal bipyramid,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid, and  a cornercorner with one S(9)Dy4 trigonal pyramid. In the fourth S site, S(4) is bonded to one Dy(10), one Dy(12), one Dy(8), and one Ge(3) atom to form SDy3Ge tetrahedra that share  a cornercorner with one S(12)Dy4Ge trigonal bipyramid,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(6)Dy4 trigonal pyramids, and  an edgeedge with one S(28)Dy3Ge trigonal pyramid. In the fifth S site, S(5) is bonded in a 5-coordinate geometry to one Dy(1), one Dy(11), one Dy(2), one Dy(9), and one Ge(5) atom. In the sixth S site, S(6) is bonded to one Dy(1), one Dy(10), one Dy(12), and one Dy(2) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra, corners with two equivalent S(4)Dy3Ge tetrahedra,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(28)Dy3Ge trigonal pyramids,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(18)Dy3Ge trigonal pyramid,  an edgeedge with one S(14)Dy4 trigonal pyramid, and  an edgeedge with one S(16)Dy4 trigonal pyramid. In the seventh S site, S(7) is bonded to one Dy(12), one Dy(3), one Dy(4), and one Dy(7) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(28)Dy3Ge trigonal pyramid,  an edgeedge with one S(11)Dy4 trigonal pyramid, and  an edgeedge with one S(16)Dy4 trigonal pyramid. In the eighth S site, S(8) is bonded in a 5-coordinate geometry to one Dy(11), one Dy(3), one Dy(4), one Dy(8), and one Ge(5) atom. In the ninth S site, S(9) is bonded to one Dy(10), one Dy(5), one Dy(6), and one Dy(7) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(6)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(11)Dy4 trigonal pyramid, and  an edgeedge with one S(14)Dy4 trigonal pyramid. In the tenth S site, S(10) is bonded in a 5-coordinate geometry to one Dy(5), one Dy(6), one Dy(8), one Dy(9), and one Ge(5) atom. In the eleventh S site, S(11) is bonded to one Dy(3), one Dy(5), one Dy(7), and one Dy(8) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(1)Dy3Ge tetrahedra, corners with two equivalent S(12)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  an edgeedge with one S(7)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the twelfth S site, S(12) is bonded to one Dy(4), one Dy(6), one Dy(7), one Dy(8), and one Ge(5) atom to form distorted SDy4Ge trigonal bipyramids that share  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(2)Dy3Ge tetrahedra, corners with two equivalent S(11)Dy4 trigonal pyramids,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(7)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the thirteenth S site, S(13) is bonded to one Dy(1), one Dy(10), one Dy(6), one Dy(9), and one Ge(5) atom to form distorted SDy4Ge trigonal bipyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid, corners with two equivalent S(14)Dy4 trigonal pyramids,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the fourteenth S site, S(14) is bonded to one Dy(10), one Dy(2), one Dy(5), and one Dy(9) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(13)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(9)Dy4 trigonal pyramid. In the fifteenth S site, S(15) is bonded to one Dy(1), one Dy(11), one Dy(12), one Dy(4), and one Ge(5) atom to form distorted SDy4Ge trigonal bipyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(28)Dy3Ge trigonal pyramid, corners with two equivalent S(16)Dy4 trigonal pyramids,  an edgeedge with one S(12)Dy4Ge trigonal bipyramid,  an edgeedge with one S(13)Dy4Ge trigonal bipyramid,  an edgeedge with one S(18)Dy3Ge trigonal pyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(7)Dy4 trigonal pyramid. In the sixteenth S site, S(16) is bonded to one Dy(11), one Dy(12), one Dy(2), and one Dy(3) atom to form distorted SDy4 trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra, corners with two equivalent S(15)Dy4Ge trigonal bipyramids,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  an edgeedge with one S(28)Dy3Ge trigonal pyramid,  an edgeedge with one S(6)Dy4 trigonal pyramid, and  an edgeedge with one S(7)Dy4 trigonal pyramid. In the seventeenth S site, S(17) is bonded in a distorted rectangular see-saw-like geometry to one Dy(11), one Dy(2), one Dy(6), and one Ge(1) atom. In the eighteenth S site, S(18) is bonded to one Dy(1), one Dy(12), one Dy(5), and one Ge(2) atom to form distorted SDy3Ge trigonal pyramids that share  a cornercorner with one S(2)Dy3Ge tetrahedra,  a cornercorner with one S(4)Dy3Ge tetrahedra,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(28)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(16)Dy4 trigonal pyramid,  a cornercorner with one S(7)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid,  an edgeedge with one S(1)Dy3Ge tetrahedra,  an edgeedge with one S(15)Dy4Ge trigonal bipyramid, and  an edgeedge with one S(6)Dy4 trigonal pyramid. In the nineteenth S site, S(19) is bonded in a distorted rectangular see-saw-like geometry to one Dy(2), one Dy(4), one Dy(7), and one Ge(1) atom. In the twentieth S site, S(20) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one Dy(3), one Dy(8), and one Ge(2) atom. In the twenty-first S site, S(21) is bonded in a distorted rectangular see-saw-like geometry to one Dy(10), one Dy(4), one Dy(6), and one Ge(1) atom. In the twenty-second S site, S(22) is bonded in a distorted rectangular see-saw-like geometry to one Dy(3), one Dy(5), one Dy(9), and one Ge(2) atom. In the twenty-third S site, S(23) is bonded in a distorted rectangular see-saw-like geometry to one Dy(11), one Dy(5), one Dy(7), and one Ge(3) atom. In the twenty-fourth S site, S(24) is bonded in a distorted rectangular see-saw-like geometry to one Dy(12), one Dy(6), one Dy(8), and one Ge(4) atom. In the twenty-fifth S site, S(25) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one Dy(7), one Dy(9), and one Ge(3) atom. In the twenty-sixth S site, S(26) is bonded in a distorted rectangular see-saw-like geometry to one Dy(10), one Dy(2), one Dy(8), and one Ge(4) atom. In the twenty-seventh S site, S(27) is bonded in a rectangular see-saw-like geometry to one Dy(11), one Dy(4), one Dy(9), and one Ge(3) atom. In the twenty-eighth S site, S(28) is bonded to one Dy(10), one Dy(12), one Dy(3), and one Ge(4) atom to form distorted SDy3Ge trigonal pyramids that share  a cornercorner with one S(1)Dy3Ge tetrahedra,  a cornercorner with one S(3)Dy3Ge tetrahedra,  a cornercorner with one S(13)Dy4Ge trigonal bipyramid,  a cornercorner with one S(15)Dy4Ge trigonal bipyramid,  a cornercorner with one S(18)Dy3Ge trigonal pyramid,  a cornercorner with one S(11)Dy4 trigonal pyramid,  a cornercorner with one S(14)Dy4 trigonal pyramid,  a cornercorner with one S(9)Dy4 trigonal pyramid, corners with two equivalent S(6)Dy4 trigonal pyramids,  an edgeedge with one S(4)Dy3Ge tetrahedra,  an edgeedge with one S(16)Dy4 trigonal pyramid, and  an edgeedge with one S(7)Dy4 trigonal pyramid.