Pt3V is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Pt(1) atoms to form VPt12 cuboctahedra that share corners with twelve equivalent V(1)Pt12 cuboctahedra, edges with twenty-four equivalent Pt(1)V4Pt8 cuboctahedra, faces with six equivalent V(1)Pt12 cuboctahedra, and faces with twelve equivalent Pt(1)V4Pt8 cuboctahedra. Pt(1) is bonded to four equivalent V(1) and eight equivalent Pt(1) atoms to form distorted PtV4Pt8 cuboctahedra that share corners with twelve equivalent Pt(1)V4Pt8 cuboctahedra, edges with eight equivalent V(1)Pt12 cuboctahedra, edges with sixteen equivalent Pt(1)V4Pt8 cuboctahedra, faces with four equivalent V(1)Pt12 cuboctahedra, and faces with fourteen equivalent Pt(1)V4Pt8 cuboctahedra.
Pt3V is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Pt(1) atoms to form VPt12 cuboctahedra that share corners with twelve equivalent V(1)Pt12 cuboctahedra, edges with twenty-four equivalent Pt(1)V4Pt8 cuboctahedra, faces with six equivalent V(1)Pt12 cuboctahedra, and faces with twelve equivalent Pt(1)V4Pt8 cuboctahedra. All V(1)-Pt(1) bond lengths are 2.76 Å. Pt(1) is bonded to four equivalent V(1) and eight equivalent Pt(1) atoms to form distorted PtV4Pt8 cuboctahedra that share corners with twelve equivalent Pt(1)V4Pt8 cuboctahedra, edges with eight equivalent V(1)Pt12 cuboctahedra, edges with sixteen equivalent Pt(1)V4Pt8 cuboctahedra, faces with four equivalent V(1)Pt12 cuboctahedra, and faces with fourteen equivalent Pt(1)V4Pt8 cuboctahedra. All Pt(1)-Pt(1) bond lengths are 2.76 Å.