NaY(Pd3O4)2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1,1) atoms. Y(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1,1) atoms. Pd(1) is bonded in a square co-planar geometry to four O(1,1,1) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. In the second O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. In the third O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. In the fourth O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. In the fifth O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids.
NaY(Pd3O4)2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1,1) atoms. All Na(1)-O(1,1,1,1,1) bond lengths are 2.61 Å. Y(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1,1) atoms. All Y(1)-O(1,1,1,1,1) bond lengths are 2.44 Å. Pd(1) is bonded in a square co-planar geometry to four O(1,1,1) atoms. All Pd(1)-O(1,1,1) bond lengths are 2.06 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. In the second O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. All O(1)-Pd(1) bond lengths are 2.06 Å. In the third O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. All O(1)-Pd(1) bond lengths are 2.06 Å. In the fourth O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids. In the fifth O site, O(1) is bonded to one Na(1), one Y(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaYPd3 trigonal bipyramids.