Li2RhIn crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent In(1) atoms to form distorted corner-sharing LiIn4 tetrahedra. In the second Li site, Li(2) is bonded to four equivalent Rh(1) atoms to form distorted corner-sharing LiRh4 tetrahedra. Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent Li(2) and four equivalent In(1) atoms. In(1) is bonded in a distorted body-centered cubic geometry to four equivalent Li(1) and four equivalent Rh(1) atoms.
Li2RhIn crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent In(1) atoms to form distorted corner-sharing LiIn4 tetrahedra. All Li(1)-In(1) bond lengths are 2.71 Å. In the second Li site, Li(2) is bonded to four equivalent Rh(1) atoms to form distorted corner-sharing LiRh4 tetrahedra. All Li(2)-Rh(1) bond lengths are 2.71 Å. Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent Li(2) and four equivalent In(1) atoms. All Rh(1)-In(1) bond lengths are 2.71 Å. In(1) is bonded in a distorted body-centered cubic geometry to four equivalent Li(1) and four equivalent Rh(1) atoms.