(BeF4)2NiO4(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four BeF4 clusters, and two NiO4 clusters. In each BeF4 cluster, Be(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Be(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Be(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Be(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Be(1) atom. In each NiO4 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ni(1) atom.
(BeF4)2NiO4(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four BeF4 clusters, and two NiO4 clusters. In each BeF4 cluster, Be(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. The Be(1)-F(1) bond length is 1.57 Å. The Be(1)-F(2) bond length is 1.59 Å. The Be(1)-F(3) bond length is 1.57 Å. The Be(1)-F(4) bond length is 1.56 Å. There are four inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Be(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Be(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Be(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Be(1) atom. In each NiO4 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ni(1)-O(1) bond lengths are 1.77 Å. Both Ni(1)-O(2) bond lengths are 1.80 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ni(1) atom.