(Mo3Cl7)4(N2)2O2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms, four water atoms, and four Mo3Cl7 clusters. In each Mo3Cl7 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(6) atom to form edge-sharing MoCl5 square pyramids. In the second Mo site, Mo(2) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(7) atom to form distorted edge-sharing MoCl5 square pyramids. In the third Mo site, Mo(3) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom to form distorted edge-sharing MoCl5 square pyramids. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(3) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(2) atom.
(Mo3Cl7)4(N2)2O2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms, four water atoms, and four Mo3Cl7 clusters. In each Mo3Cl7 cluster, there are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(6) atom to form edge-sharing MoCl5 square pyramids. The Mo(1)-Cl(1) bond length is 2.56 Å. The Mo(1)-Cl(2) bond length is 2.56 Å. The Mo(1)-Cl(3) bond length is 2.56 Å. The Mo(1)-Cl(4) bond length is 2.55 Å. The Mo(1)-Cl(6) bond length is 2.36 Å. In the second Mo site, Mo(2) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(7) atom to form distorted edge-sharing MoCl5 square pyramids. The Mo(2)-Cl(1) bond length is 2.57 Å. The Mo(2)-Cl(2) bond length is 2.57 Å. The Mo(2)-Cl(3) bond length is 2.57 Å. The Mo(2)-Cl(4) bond length is 2.56 Å. The Mo(2)-Cl(7) bond length is 2.40 Å. In the third Mo site, Mo(3) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom to form distorted edge-sharing MoCl5 square pyramids. The Mo(3)-Cl(1) bond length is 2.55 Å. The Mo(3)-Cl(2) bond length is 2.54 Å. The Mo(3)-Cl(3) bond length is 2.55 Å. The Mo(3)-Cl(4) bond length is 2.56 Å. The Mo(3)-Cl(5) bond length is 2.38 Å. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(3) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Mo(2) atom.