Cd(C2N3)2 crystallizes in the orthorhombic Pnnm space group. Cd(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1) and two equivalent C(1) atoms. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(1) atom.
Cd(C2N3)2 crystallizes in the orthorhombic Pnnm space group. Cd(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. Both Cd(1)-N(1) bond lengths are 2.53 Å. All Cd(1)-N(2) bond lengths are 2.30 Å. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(2) bond length is 1.17 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1) and two equivalent C(1) atoms. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(1) atom.