NHS3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 1,2,3,5,6,7,4,8-hexathiadiazocane molecules. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one H(1) and two equivalent S(1) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one H(2) and two equivalent S(3) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom.
NHS3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 1,2,3,5,6,7,4,8-hexathiadiazocane molecules. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one H(1) and two equivalent S(1) atoms. The N(1)-H(1) bond length is 1.03 Å. Both N(1)-S(1) bond lengths are 1.70 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one H(2) and two equivalent S(3) atoms. The N(2)-H(2) bond length is 1.03 Å. Both N(2)-S(3) bond lengths are 1.68 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. The S(1)-S(2) bond length is 2.06 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. The S(2)-S(3) bond length is 2.09 Å. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom.