BaAgCu5P2 crystallizes in the tetragonal P4/mmm space group. Ba(1) is bonded in a 16-coordinate geometry to eight equivalent Cu(1) and eight equivalent P(1) atoms. Ag(1) is bonded to four equivalent Cu(2) and eight equivalent Cu(1) atoms to form a mixture of face and corner-sharing AgCu12 cuboctahedra. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), two equivalent Ag(1), two equivalent Cu(2), and two equivalent P(1) atoms. In the second Cu site, Cu(2) is bonded in a 14-coordinate geometry to four equivalent Ag(1), eight equivalent Cu(1), and two equivalent P(1) atoms. P(1) is bonded in a 4-coordinate geometry to four equivalent Ba(1), one Cu(2), and four equivalent Cu(1) atoms.
BaAgCu5P2 crystallizes in the tetragonal P4/mmm space group. Ba(1) is bonded in a 16-coordinate geometry to eight equivalent Cu(1) and eight equivalent P(1) atoms. All Ba(1)-Cu(1) bond lengths are 3.53 Å. All Ba(1)-P(1) bond lengths are 3.45 Å. Ag(1) is bonded to four equivalent Cu(2) and eight equivalent Cu(1) atoms to form a mixture of face and corner-sharing AgCu12 cuboctahedra. All Ag(1)-Cu(2) bond lengths are 2.91 Å. All Ag(1)-Cu(1) bond lengths are 2.69 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), two equivalent Ag(1), two equivalent Cu(2), and two equivalent P(1) atoms. Both Cu(1)-Cu(2) bond lengths are 2.69 Å. Both Cu(1)-P(1) bond lengths are 2.29 Å. In the second Cu site, Cu(2) is bonded in a 14-coordinate geometry to four equivalent Ag(1), eight equivalent Cu(1), and two equivalent P(1) atoms. Both Cu(2)-P(1) bond lengths are 2.75 Å. P(1) is bonded in a 4-coordinate geometry to four equivalent Ba(1), one Cu(2), and four equivalent Cu(1) atoms.