CN2SC2TeS2(N2I)2CTeS(NI)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one C2TeS2(N2I)2 cluster, one CN2S cluster, and one CTeS(NI)2 cluster. In the C2TeS2(N2I)2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(5), and one S(1) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one N(2), one N(6), and one S(2) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(2) and one N(6) atom. In the third N site, N(5) is bonded in a single-bond geometry to one C(1) atom. In the fourth N site, N(6) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one I(1), and one I(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one Te(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Te(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Te(1) atom. In the CN2S cluster, C(3) is bonded in a 3-coordinate geometry to one N(3), one N(7), and one S(3) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to one C(3) and one N(7) atom. In the second N site, N(7) is bonded in a distorted single-bond geometry to one C(3) and one N(3) atom. S(3) is bonded in a single-bond geometry to one C(3) atom. In the CTeS(NI)2 cluster, C(4) is bonded in a linear geometry to one N(4) and one N(8) atom. There are two inequivalent N sites. In the first N site, N(4) is bonded in a distorted single-bond geometry to one C(4) and one I(3) atom. In the second N site, N(8) is bonded in a single-bond geometry to one C(4) atom. Te(2) is bonded in a 3-coordinate geometry to one S(4), one I(3), and one I(4) atom. S(4) is bonded in a single-bond geometry to one Te(2) atom. There are two inequivalent I sites. In the first I site, I(3) is bonded in a bent 150 degrees geometry to one N(4) and one Te(2) atom. In the second I site, I(4) is bonded in a single-bond geometry to one Te(2) atom.
CN2SC2TeS2(N2I)2CTeS(NI)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one C2TeS2(N2I)2 cluster, one CN2S cluster, and one CTeS(NI)2 cluster. In the C2TeS2(N2I)2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(5), and one S(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-N(5) bond length is 1.30 Å. The C(1)-S(1) bond length is 1.86 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one N(2), one N(6), and one S(2) atom. The C(2)-N(2) bond length is 1.39 Å. The C(2)-N(6) bond length is 1.40 Å. The C(2)-S(2) bond length is 1.59 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(2) and one N(6) atom. The N(2)-N(6) bond length is 1.31 Å. In the third N site, N(5) is bonded in a single-bond geometry to one C(1) atom. In the fourth N site, N(6) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one I(1), and one I(2) atom. The Te(1)-S(1) bond length is 2.58 Å. The Te(1)-S(2) bond length is 2.98 Å. The Te(1)-I(1) bond length is 2.78 Å. The Te(1)-I(2) bond length is 2.90 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one Te(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Te(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Te(1) atom. In the CN2S cluster, C(3) is bonded in a 3-coordinate geometry to one N(3), one N(7), and one S(3) atom. The C(3)-N(3) bond length is 1.39 Å. The C(3)-N(7) bond length is 1.40 Å. The C(3)-S(3) bond length is 1.59 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to one C(3) and one N(7) atom. The N(3)-N(7) bond length is 1.31 Å. In the second N site, N(7) is bonded in a distorted single-bond geometry to one C(3) and one N(3) atom. S(3) is bonded in a single-bond geometry to one C(3) atom. In the CTeS(NI)2 cluster, C(4) is bonded in a linear geometry to one N(4) and one N(8) atom. The C(4)-N(4) bond length is 1.25 Å. The C(4)-N(8) bond length is 1.22 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a distorted single-bond geometry to one C(4) and one I(3) atom. The N(4)-I(3) bond length is 2.76 Å. In the second N site, N(8) is bonded in a single-bond geometry to one C(4) atom. Te(2) is bonded in a 3-coordinate geometry to one S(4), one I(3), and one I(4) atom. The Te(2)-S(4) bond length is 2.24 Å. The Te(2)-I(3) bond length is 2.89 Å. The Te(2)-I(4) bond length is 2.85 Å. S(4) is bonded in a single-bond geometry to one Te(2) atom. There are two inequivalent I sites. In the first I site, I(3) is bonded in a bent 150 degrees geometry to one N(4) and one Te(2) atom. In the second I site, I(4) is bonded in a single-bond geometry to one Te(2) atom.