N3S4SeCl5 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N3S4 clusters and two SeCl5 clusters. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(4) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(3) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In each SeCl5 cluster, Se(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(5), and two equivalent Cl(4) atoms to form edge-sharing SeCl6 octahedra. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Se(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(1) atom.
N3S4SeCl5 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N3S4 clusters and two SeCl5 clusters. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(4) atom. The N(1)-S(2) bond length is 1.56 Å. The N(1)-S(4) bond length is 1.55 Å. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(3) atom. The N(2)-S(1) bond length is 1.57 Å. The N(2)-S(3) bond length is 1.55 Å. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. The N(3)-S(3) bond length is 1.58 Å. The N(3)-S(4) bond length is 1.58 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In each SeCl5 cluster, Se(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(5), and two equivalent Cl(4) atoms to form edge-sharing SeCl6 octahedra. The Se(1)-Cl(1) bond length is 2.43 Å. The Se(1)-Cl(2) bond length is 2.38 Å. The Se(1)-Cl(3) bond length is 2.25 Å. The Se(1)-Cl(5) bond length is 2.28 Å. There is one shorter (2.71 Å) and one longer (2.83 Å) Se(1)-Cl(4) bond length. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Se(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(1) atom.