ZrSn3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. Zr(1) is bonded in a distorted body-centered cubic geometry to six equivalent Sn(1) and eight equivalent Sn(2) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 14-coordinate geometry to six equivalent Zr(1) and eight equivalent Sn(2) atoms. In the second Sn site, Sn(2) is bonded in a distorted body-centered cubic geometry to four equivalent Zr(1) and four equivalent Sn(1) atoms.
ZrSn3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. Zr(1) is bonded in a distorted body-centered cubic geometry to six equivalent Sn(1) and eight equivalent Sn(2) atoms. All Zr(1)-Sn(1) bond lengths are 3.71 Å. All Zr(1)-Sn(2) bond lengths are 3.21 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 14-coordinate geometry to six equivalent Zr(1) and eight equivalent Sn(2) atoms. All Sn(1)-Sn(2) bond lengths are 3.21 Å. In the second Sn site, Sn(2) is bonded in a distorted body-centered cubic geometry to four equivalent Zr(1) and four equivalent Sn(1) atoms.