HfZrV4 is Hexagonal Laves-derived structured and crystallizes in the cubic F-43m space group. Hf(1) is bonded in a 16-coordinate geometry to four equivalent Zr(1) and twelve equivalent V(1) atoms. Zr(1) is bonded in a 16-coordinate geometry to four equivalent Hf(1) and twelve equivalent V(1) atoms. V(1) is bonded to three equivalent Hf(1), three equivalent Zr(1), and six equivalent V(1) atoms to form a mixture of corner, face, and edge-sharing VHf3Zr3V6 cuboctahedra.
HfZrV4 is Hexagonal Laves-derived structured and crystallizes in the cubic F-43m space group. Hf(1) is bonded in a 16-coordinate geometry to four equivalent Zr(1) and twelve equivalent V(1) atoms. All Hf(1)-Zr(1) bond lengths are 3.18 Å. All Hf(1)-V(1) bond lengths are 3.04 Å. Zr(1) is bonded in a 16-coordinate geometry to four equivalent Hf(1) and twelve equivalent V(1) atoms. All Zr(1)-V(1) bond lengths are 3.04 Å. V(1) is bonded to three equivalent Hf(1), three equivalent Zr(1), and six equivalent V(1) atoms to form a mixture of corner, face, and edge-sharing VHf3Zr3V6 cuboctahedra. There are three shorter (2.59 Å) and three longer (2.60 Å) V(1)-V(1) bond lengths.