AuBr3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuBr3 clusters. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a rectangular see-saw-like geometry to one Br(1), one Br(2), one Br(3), and one Br(6) atom. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one Br(3), one Br(4), one Br(5), and one Br(6) atom. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Au(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Au(1) atom. In the third Br site, Br(3) is bonded in an L-shaped geometry to one Au(1) and one Au(2) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Au(2) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Au(2) atom. In the sixth Br site, Br(6) is bonded in an L-shaped geometry to one Au(1) and one Au(2) atom.
AuBr3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuBr3 clusters. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a rectangular see-saw-like geometry to one Br(1), one Br(2), one Br(3), and one Br(6) atom. The Au(1)-Br(1) bond length is 2.42 Å. The Au(1)-Br(2) bond length is 2.43 Å. The Au(1)-Br(3) bond length is 2.49 Å. The Au(1)-Br(6) bond length is 2.49 Å. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one Br(3), one Br(4), one Br(5), and one Br(6) atom. The Au(2)-Br(3) bond length is 2.50 Å. The Au(2)-Br(4) bond length is 2.42 Å. The Au(2)-Br(5) bond length is 2.42 Å. The Au(2)-Br(6) bond length is 2.51 Å. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Au(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Au(1) atom. In the third Br site, Br(3) is bonded in an L-shaped geometry to one Au(1) and one Au(2) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Au(2) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Au(2) atom. In the sixth Br site, Br(6) is bonded in an L-shaped geometry to one Au(1) and one Au(2) atom.