MgTiVO4 crystallizes in the monoclinic P2 space group. Mg(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MgO6 octahedra that share corners with four equivalent V(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with four equivalent Ti(1)O6 octahedra, and faces with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-47°. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form TiO6 octahedra that share corners with eight equivalent V(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with four equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with four equivalent Mg(1)O6 octahedra, corners with eight equivalent Ti(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and faces with two equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), two equivalent Ti(1), and one V(1) atom. In the second O site, O(2) is bonded to two equivalent Mg(1), one Ti(1), and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OMg2TiV2 trigonal bipyramids.
MgTiVO4 crystallizes in the monoclinic P2 space group. Mg(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MgO6 octahedra that share corners with four equivalent V(1)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with four equivalent Ti(1)O6 octahedra, and faces with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-47°. Both Mg(1)-O(1) bond lengths are 1.98 Å. There are two shorter (2.08 Å) and two longer (2.10 Å) Mg(1)-O(2) bond lengths. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form TiO6 octahedra that share corners with eight equivalent V(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with four equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. Both Ti(1)-O(2) bond lengths are 2.05 Å. There are two shorter (1.90 Å) and two longer (2.11 Å) Ti(1)-O(1) bond lengths. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with four equivalent Mg(1)O6 octahedra, corners with eight equivalent Ti(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and faces with two equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. Both V(1)-O(1) bond lengths are 2.32 Å. All V(1)-O(2) bond lengths are 2.21 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), two equivalent Ti(1), and one V(1) atom. In the second O site, O(2) is bonded to two equivalent Mg(1), one Ti(1), and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OMg2TiV2 trigonal bipyramids.