CaFe2O4 crystallizes in the tetragonal P4/mmm space group. Ca(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Fe(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Ca(1) and two equivalent Fe(1) atoms.
CaFe2O4 crystallizes in the tetragonal P4/mmm space group. Ca(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Ca(1)-O(1) bond lengths are 2.47 Å. Fe(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Fe(1)-O(1) bond lengths are 1.92 Å. O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Ca(1) and two equivalent Fe(1) atoms.