Ag2ZnC4(NS)4 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one S(1), one S(4), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. In the second Ag site, Ag(2) is bonded to one S(1), one S(4), and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(3) and one S(4) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one N(2) and one S(3) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(4) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Zn(1) and one C(2) atom. There are four inequivalent S sites. In the first S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(1) atom. In the second S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(2) atom. In the third S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(2) and one C(3) atom. In the fourth S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(4) atom.
Ag2ZnC4(NS)4 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one S(1), one S(4), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. The Ag(1)-S(1) bond length is 2.58 Å. The Ag(1)-S(4) bond length is 2.57 Å. There is one shorter (2.65 Å) and one longer (2.74 Å) Ag(1)-S(3) bond length. In the second Ag site, Ag(2) is bonded to one S(1), one S(4), and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. The Ag(2)-S(1) bond length is 2.60 Å. The Ag(2)-S(4) bond length is 2.61 Å. There is one shorter (2.66 Å) and one longer (2.69 Å) Ag(2)-S(2) bond length. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Zn(1)-N(1) bond length is 1.99 Å. The Zn(1)-N(2) bond length is 1.99 Å. The Zn(1)-N(3) bond length is 1.98 Å. The Zn(1)-N(4) bond length is 1.97 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(3) and one S(4) atom. The C(1)-N(3) bond length is 1.18 Å. The C(1)-S(4) bond length is 1.64 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(4) and one S(1) atom. The C(2)-N(4) bond length is 1.18 Å. The C(2)-S(1) bond length is 1.64 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one N(1) and one S(2) atom. The C(3)-N(1) bond length is 1.18 Å. The C(3)-S(2) bond length is 1.64 Å. In the fourth C site, C(4) is bonded in a distorted linear geometry to one N(2) and one S(3) atom. The C(4)-N(2) bond length is 1.18 Å. The C(4)-S(3) bond length is 1.64 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(4) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Zn(1) and one C(2) atom. There are four inequivalent S sites. In the first S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(1) atom. In the second S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(2) atom. In the third S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(2) and one C(3) atom. In the fourth S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(4) atom.