LiPdN crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a linear geometry to two equivalent N(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded to two equivalent Li(1) and four equivalent Pd(1) atoms to form a mixture of edge and corner-sharing NLi2Pd4 octahedra. The corner-sharing octahedra are not tilted.
LiPdN crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Li(1)-N(1) bond lengths are 2.00 Å. Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Pd(1)-N(1) bond lengths are 2.13 Å. N(1) is bonded to two equivalent Li(1) and four equivalent Pd(1) atoms to form a mixture of edge and corner-sharing NLi2Pd4 octahedra. The corner-sharing octahedra are not tilted.