CsCuF4 crystallizes in the tetragonal I4/mcm space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Cu(1) atom.
CsCuF4 crystallizes in the tetragonal I4/mcm space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. All Cs(1)-F(1) bond lengths are 2.99 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All Cu(1)-F(1) bond lengths are 1.75 Å. F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Cu(1) atom.