MoNH5O5F2NHH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two ammonia molecules, and one MoNH5O5F2 cluster. In the MoNH5O5F2 cluster, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one F(1), and one F(2) atom. N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(4), and one O(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one O(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(7) is bonded in a linear geometry to one O(4) and one F(1) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one H(2), and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one O(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one H(8) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one N(1) and one H(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one H(7) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Mo(1) atom.
MoNH5O5F2NHH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two ammonia molecules, and one MoNH5O5F2 cluster. In the MoNH5O5F2 cluster, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one F(1), and one F(2) atom. The Mo(1)-O(1) bond length is 2.00 Å. The Mo(1)-O(2) bond length is 1.92 Å. The Mo(1)-O(3) bond length is 1.88 Å. The Mo(1)-O(5) bond length is 1.74 Å. The Mo(1)-F(1) bond length is 2.11 Å. The Mo(1)-F(2) bond length is 1.98 Å. N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(4), and one O(4) atom. The N(1)-H(1) bond length is 1.05 Å. The N(1)-H(2) bond length is 1.05 Å. The N(1)-H(4) bond length is 1.05 Å. The N(1)-O(4) bond length is 1.43 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) and one O(1) atom. The H(2)-O(1) bond length is 1.73 Å. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(7) is bonded in a linear geometry to one O(4) and one F(1) atom. The H(7)-O(4) bond length is 1.04 Å. The H(7)-F(1) bond length is 1.45 Å. In the fifth H site, H(8) is bonded in a single-bond geometry to one O(3) atom. The H(8)-O(3) bond length is 1.00 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one H(2), and one O(2) atom. The O(1)-O(2) bond length is 1.48 Å. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one O(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one H(8) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one N(1) and one H(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one H(7) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Mo(1) atom.