Pt3Cl3F crystallizes in the cubic Pm-3m space group. Pt(1) is bonded to four equivalent Cl(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing PtCl4F2 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a square co-planar geometry to four equivalent Pt(1) atoms. F(1) is bonded to six equivalent Pt(1) atoms to form corner-sharing FPt6 octahedra. The corner-sharing octahedra are not tilted.
Pt3Cl3F crystallizes in the cubic Pm-3m space group. Pt(1) is bonded to four equivalent Cl(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing PtCl4F2 octahedra. The corner-sharing octahedra are not tilted. All Pt(1)-Cl(1) bond lengths are 2.51 Å. Both Pt(1)-F(1) bond lengths are 2.51 Å. Cl(1) is bonded in a square co-planar geometry to four equivalent Pt(1) atoms. F(1) is bonded to six equivalent Pt(1) atoms to form corner-sharing FPt6 octahedra. The corner-sharing octahedra are not tilted.