AgS16SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgS16 clusters and four SbF6 clusters. In each AgS16 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(5) and two equivalent S(6) atoms. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(8) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(1) and one S(7) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(5) and one S(6) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(7) atom. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(8) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one S(2) and one S(6) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom.
AgS16SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgS16 clusters and four SbF6 clusters. In each AgS16 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(5) and two equivalent S(6) atoms. Both Ag(1)-S(5) bond lengths are 2.73 Å. Both Ag(1)-S(6) bond lengths are 2.81 Å. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(3) atom. The S(1)-S(2) bond length is 2.06 Å. The S(1)-S(3) bond length is 2.07 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(8) atom. The S(2)-S(8) bond length is 2.05 Å. In the third S site, S(3) is bonded in a water-like geometry to one S(1) and one S(7) atom. The S(3)-S(7) bond length is 2.05 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one S(5) and one S(6) atom. The S(4)-S(5) bond length is 2.06 Å. The S(4)-S(6) bond length is 2.07 Å. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(7) atom. The S(5)-S(7) bond length is 2.08 Å. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(4), and one S(8) atom. The S(6)-S(8) bond length is 2.07 Å. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one S(2) and one S(6) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. Both Sb(1)-F(2) bond lengths are 1.92 Å. There are two shorter (1.92 Å) and two longer (1.93 Å) Sb(1)-F(1,3) bond lengths. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom.