TiRhBi is half-Heusler structured and crystallizes in the cubic F-43m space group. Ti(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Bi(1) atoms. Rh(1) is bonded to four equivalent Ti(1) and six equivalent Bi(1) atoms to form distorted RhTi4Bi6 tetrahedra that share corners with four equivalent Bi(1)Ti4Rh6 tetrahedra, corners with six equivalent Rh(1)Ti4Bi6 tetrahedra, edges with six equivalent Bi(1)Ti4Rh6 tetrahedra, and faces with twelve equivalent Rh(1)Ti4Bi6 tetrahedra. Bi(1) is bonded to four equivalent Ti(1) and six equivalent Rh(1) atoms to form distorted BiTi4Rh6 tetrahedra that share corners with four equivalent Rh(1)Ti4Bi6 tetrahedra, corners with six equivalent Bi(1)Ti4Rh6 tetrahedra, edges with six equivalent Rh(1)Ti4Bi6 tetrahedra, and faces with twelve equivalent Bi(1)Ti4Rh6 tetrahedra.
TiRhBi is half-Heusler structured and crystallizes in the cubic F-43m space group. Ti(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Bi(1) atoms. All Ti(1)-Rh(1) bond lengths are 2.75 Å. All Ti(1)-Bi(1) bond lengths are 2.75 Å. Rh(1) is bonded to four equivalent Ti(1) and six equivalent Bi(1) atoms to form distorted RhTi4Bi6 tetrahedra that share corners with four equivalent Bi(1)Ti4Rh6 tetrahedra, corners with six equivalent Rh(1)Ti4Bi6 tetrahedra, edges with six equivalent Bi(1)Ti4Rh6 tetrahedra, and faces with twelve equivalent Rh(1)Ti4Bi6 tetrahedra. All Rh(1)-Bi(1) bond lengths are 3.17 Å. Bi(1) is bonded to four equivalent Ti(1) and six equivalent Rh(1) atoms to form distorted BiTi4Rh6 tetrahedra that share corners with four equivalent Rh(1)Ti4Bi6 tetrahedra, corners with six equivalent Bi(1)Ti4Rh6 tetrahedra, edges with six equivalent Rh(1)Ti4Bi6 tetrahedra, and faces with twelve equivalent Bi(1)Ti4Rh6 tetrahedra.