PdCr crystallizes in the trigonal R-3m space group. Cr(1) is bonded to six equivalent Cr(1) and six equivalent Pd(1) atoms to form distorted CrCr6Pd6 cuboctahedra that share corners with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra, faces with six equivalent Cr(1)Cr6Pd6 cuboctahedra, and faces with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra. Pd(1) is bonded to six equivalent Cr(1) and six equivalent Pd(1) atoms to form distorted PdCr6Pd6 cuboctahedra that share corners with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra, faces with six equivalent Pd(1)Cr6Pd6 cuboctahedra, and faces with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra.
PdCr crystallizes in the trigonal R-3m space group. Cr(1) is bonded to six equivalent Cr(1) and six equivalent Pd(1) atoms to form distorted CrCr6Pd6 cuboctahedra that share corners with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra, faces with six equivalent Cr(1)Cr6Pd6 cuboctahedra, and faces with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra. All Cr(1)-Cr(1) bond lengths are 2.68 Å. All Cr(1)-Pd(1) bond lengths are 2.68 Å. Pd(1) is bonded to six equivalent Cr(1) and six equivalent Pd(1) atoms to form distorted PdCr6Pd6 cuboctahedra that share corners with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cr6Pd6 cuboctahedra, faces with six equivalent Pd(1)Cr6Pd6 cuboctahedra, and faces with twelve equivalent Cr(1)Cr6Pd6 cuboctahedra. All Pd(1)-Pd(1) bond lengths are 2.68 Å.