Nd2PdO4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Nd(1) is bonded to six equivalent O(1) atoms to form NdO6 octahedra that share corners with six equivalent Pd(1)O4 tetrahedra and edges with six equivalent Nd(1)O6 octahedra. Pd(1) is bonded to four equivalent O(1) atoms to form PdO4 tetrahedra that share corners with twelve equivalent Nd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. O(1) is bonded to three equivalent Nd(1) and one Pd(1) atom to form a mixture of distorted corner and edge-sharing ONd3Pd trigonal pyramids.
Nd2PdO4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Nd(1) is bonded to six equivalent O(1) atoms to form NdO6 octahedra that share corners with six equivalent Pd(1)O4 tetrahedra and edges with six equivalent Nd(1)O6 octahedra. All Nd(1)-O(1) bond lengths are 2.39 Å. Pd(1) is bonded to four equivalent O(1) atoms to form PdO4 tetrahedra that share corners with twelve equivalent Nd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Pd(1)-O(1) bond lengths are 2.31 Å. O(1) is bonded to three equivalent Nd(1) and one Pd(1) atom to form a mixture of distorted corner and edge-sharing ONd3Pd trigonal pyramids.