POBr3 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four phosphorus oxybromide molecules. P(1) is bonded in a distorted tetrahedral geometry to one O(1), one Br(2), and two equivalent Br(1) atoms. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one P(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one P(1) atom.
POBr3 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four phosphorus oxybromide molecules. P(1) is bonded in a distorted tetrahedral geometry to one O(1), one Br(2), and two equivalent Br(1) atoms. The P(1)-O(1) bond length is 1.46 Å. The P(1)-Br(2) bond length is 2.17 Å. Both P(1)-Br(1) bond lengths are 2.18 Å. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one P(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one P(1) atom.