TiPdGe crystallizes in the hexagonal P-62m space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1), one Ge(2), and four equivalent Ge(1) atoms. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Ti(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to six equivalent Ti(1) and three equivalent Pd(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Ti(1) and six equivalent Pd(1) atoms.
TiPdGe crystallizes in the hexagonal P-62m space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1), one Ge(2), and four equivalent Ge(1) atoms. There are two shorter (2.83 Å) and four longer (3.01 Å) Ti(1)-Pd(1) bond lengths. The Ti(1)-Ge(2) bond length is 2.70 Å. All Ti(1)-Ge(1) bond lengths are 2.71 Å. Pd(1) is bonded in a 10-coordinate geometry to six equivalent Ti(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. Both Pd(1)-Ge(1) bond lengths are 2.45 Å. Both Pd(1)-Ge(2) bond lengths are 2.52 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to six equivalent Ti(1) and three equivalent Pd(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Ti(1) and six equivalent Pd(1) atoms.