LiWAgZn2O6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 trigonal pyramids and corners with four equivalent Zn(2)O4 trigonal pyramids. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-67°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-69°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(2) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(1) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom.
LiWAgZn2O6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. The Li(1)-O(1) bond length is 1.95 Å. The Li(1)-O(2) bond length is 1.95 Å. The Li(1)-O(3) bond length is 2.05 Å. The Li(1)-O(6) bond length is 2.09 Å. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 trigonal pyramids and corners with four equivalent Zn(2)O4 trigonal pyramids. The W(1)-O(1) bond length is 2.00 Å. The W(1)-O(2) bond length is 2.01 Å. The W(1)-O(3) bond length is 2.01 Å. The W(1)-O(4) bond length is 1.88 Å. The W(1)-O(5) bond length is 1.88 Å. The W(1)-O(6) bond length is 1.99 Å. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. The Ag(1)-O(1) bond length is 2.17 Å. The Ag(1)-O(2) bond length is 2.17 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-67°. The Zn(1)-O(2) bond length is 2.01 Å. The Zn(1)-O(3) bond length is 2.13 Å. The Zn(1)-O(5) bond length is 1.88 Å. The Zn(1)-O(6) bond length is 2.00 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-69°. The Zn(2)-O(1) bond length is 2.01 Å. The Zn(2)-O(3) bond length is 1.97 Å. The Zn(2)-O(4) bond length is 1.88 Å. The Zn(2)-O(6) bond length is 2.20 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(2) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(1) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom.