XeF5SbF6 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four SbF6 clusters and four XeF5 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(4), one F(5), one F(6), one F(8), and two equivalent F(7) atoms. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom.
XeF5SbF6 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four SbF6 clusters and four XeF5 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(4), one F(5), one F(6), one F(8), and two equivalent F(7) atoms. The Sb(1)-F(4) bond length is 1.95 Å. The Sb(1)-F(5) bond length is 1.90 Å. The Sb(1)-F(6) bond length is 1.90 Å. The Sb(1)-F(8) bond length is 1.95 Å. Both Sb(1)-F(7) bond lengths are 1.92 Å. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. The Xe(1)-F(1) bond length is 1.97 Å. Both Xe(1)-F(2) bond lengths are 1.98 Å. Both Xe(1)-F(3) bond lengths are 1.97 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom.