N2H6SO4 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four ammonia molecules, and four NH3SO4 clusters. In each NH3SO4 cluster, N(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one H(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) atom. In the second H site, H(3) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one H(3) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom.
N2H6SO4 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four ammonia molecules, and four NH3SO4 clusters. In each NH3SO4 cluster, N(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one H(6) atom. The N(1)-H(3) bond length is 1.07 Å. The N(1)-H(6) bond length is 1.04 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) atom. The H(1)-O(4) bond length is 0.98 Å. In the second H site, H(3) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. The H(3)-O(1) bond length is 1.71 Å. In the third H site, H(6) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(4) bond length is 1.62 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one H(3) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom.