NiAsO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent As(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. As(1) is bonded to twelve equivalent O(1) atoms to form distorted AsO12 cuboctahedra that share corners with twelve equivalent As(1)O12 cuboctahedra, faces with six equivalent As(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. O(1) is bonded in a linear geometry to two equivalent Ni(1) and four equivalent As(1) atoms.
NiAsO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent As(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ni(1)-O(1) bond lengths are 1.85 Å. As(1) is bonded to twelve equivalent O(1) atoms to form distorted AsO12 cuboctahedra that share corners with twelve equivalent As(1)O12 cuboctahedra, faces with six equivalent As(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. All As(1)-O(1) bond lengths are 2.61 Å. O(1) is bonded in a linear geometry to two equivalent Ni(1) and four equivalent As(1) atoms.