PdBi2O4 crystallizes in the tetragonal P4/ncc space group. Pd(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. Bi(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to one Pd(1) and three equivalent Bi(1) atoms.
PdBi2O4 crystallizes in the tetragonal P4/ncc space group. Pd(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. All Pd(1)-O(1) bond lengths are 2.03 Å. Bi(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are a spread of Bi(1)-O(1) bond distances ranging from 2.18-2.75 Å. O(1) is bonded in a 4-coordinate geometry to one Pd(1) and three equivalent Bi(1) atoms.