CdC3N5S3 crystallizes in the orthorhombic P2_12_12_1 space group. Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one S(1), one S(2), and one S(3) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(3) and one S(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(4) and one S(3) atom. There are five inequivalent N sites. In the first N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second N site, N(3) is bonded in a linear geometry to one Cd(1) and one C(2) atom. In the third N site, N(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth N site, N(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth N site, N(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one N(5) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(2) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(3) atom.
CdC3N5S3 crystallizes in the orthorhombic P2_12_12_1 space group. Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one S(1), one S(2), and one S(3) atom. The Cd(1)-N(1) bond length is 2.64 Å. The Cd(1)-N(2) bond length is 2.25 Å. The Cd(1)-N(3) bond length is 2.27 Å. The Cd(1)-S(1) bond length is 3.01 Å. The Cd(1)-S(2) bond length is 2.64 Å. The Cd(1)-S(3) bond length is 2.81 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(1)-N(2) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.62 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(3) and one S(2) atom. The C(2)-N(3) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.64 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one N(4) and one S(3) atom. The C(3)-N(4) bond length is 1.19 Å. The C(3)-S(3) bond length is 1.64 Å. There are five inequivalent N sites. In the first N site, N(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second N site, N(3) is bonded in a linear geometry to one Cd(1) and one C(2) atom. In the third N site, N(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth N site, N(5) is bonded in a single-bond geometry to one N(1) atom. The N(5)-N(1) bond length is 1.12 Å. In the fifth N site, N(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one N(5) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Cd(1) and one C(2) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(3) atom.