CaF3Tl crystallizes in the trigonal R3c space group. The structure consists of six 7440-28-0 atoms inside a CaF3 framework. In the CaF3 framework, Ca(1) is bonded to six equivalent F(1) atoms to form corner-sharing CaF6 octahedra. The corner-sharing octahedral tilt angles are 19°. F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Ca(1) atoms.
CaF3Tl crystallizes in the trigonal R3c space group. The structure consists of six 7440-28-0 atoms inside a CaF3 framework. In the CaF3 framework, Ca(1) is bonded to six equivalent F(1) atoms to form corner-sharing CaF6 octahedra. The corner-sharing octahedral tilt angles are 19°. There are three shorter (2.24 Å) and three longer (2.26 Å) Ca(1)-F(1) bond lengths. F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Ca(1) atoms.