Sr2ReZnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. Re(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-17°. Zn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ZnO6 octahedra that share corners with six equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-17°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to four equivalent Sr(1), one Re(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Sr(1), one Re(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one Re(1), and one Zn(1) atom.
Sr2ReZnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. There are a spread of Sr(1)-O(1) bond distances ranging from 2.59-3.18 Å. There are a spread of Sr(1)-O(2) bond distances ranging from 2.58-3.19 Å. There are a spread of Sr(1)-O(3) bond distances ranging from 2.56-3.12 Å. Re(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-17°. Both Re(1)-O(1) bond lengths are 1.94 Å. Both Re(1)-O(2) bond lengths are 1.95 Å. Both Re(1)-O(3) bond lengths are 1.95 Å. Zn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ZnO6 octahedra that share corners with six equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-17°. Both Zn(1)-O(1) bond lengths are 2.11 Å. Both Zn(1)-O(2) bond lengths are 2.11 Å. Both Zn(1)-O(3) bond lengths are 2.11 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to four equivalent Sr(1), one Re(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to four equivalent Sr(1), one Re(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one Re(1), and one Zn(1) atom.