Li4V3Sn3(SbO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, and corners with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-68°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-60°. In the third V site, V(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. In the second Sn site, Sn(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. In the third Sn site, Sn(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-60°. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Sn(3), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(4), one Sn(1), one Sn(2), and one Sb(1) atom to form distorted OLiSn2Sb tetrahedra that share  a cornercorner with one O(7)LiVSnSb tetrahedra,  a cornercorner with one O(8)LiVSnSb tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(7)LiVSnSb tetrahedra, and  an edgeedge with one O(8)LiVSnSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one Sn(1), and one Sn(2) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(2)LiSn2Sb tetrahedra, corners with two equivalent O(7)LiVSnSb tetrahedra, corners with two equivalent O(8)LiVSnSb tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid, and  an edgeedge with one O(16)LiVSnSb trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one V(2), one V(3), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share corners with two equivalent O(15)LiV2Sb tetrahedra, corners with two equivalent O(11)LiVSnSb tetrahedra, corners with two equivalent O(12)LiVSnSb tetrahedra,  a cornercorner with one O(16)LiVSnSb trigonal pyramid, and  an edgeedge with one O(10)LiV2Sb trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Sn(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Sn(1), and one Sb(1) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(8)LiVSnSb tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(2)LiSn2Sb tetrahedra, and  an edgeedge with one O(8)LiVSnSb tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Sn(2), and one Sb(1) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(7)LiVSnSb tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid, corners with two equivalent O(16)LiVSnSb trigonal pyramids,  an edgeedge with one O(2)LiSn2Sb tetrahedra, and  an edgeedge with one O(7)LiVSnSb tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Sn(1), one Sn(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one V(2), one V(3), and one Sb(1) atom to form distorted OLiV2Sb trigonal pyramids that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(4)LiVSn2 tetrahedra,  a cornercorner with one O(11)LiVSnSb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra,  a cornercorner with one O(7)LiVSnSb tetrahedra,  a cornercorner with one O(8)LiVSnSb tetrahedra, corners with two equivalent O(15)LiV2Sb tetrahedra, and  an edgeedge with one O(5)LiV2Sn tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Sn(3), and one Sb(2) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(15)LiV2Sb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(15)LiV2Sb tetrahedra, and  an edgeedge with one O(12)LiVSnSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one V(3), one Sn(3), and one Sb(2) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(15)LiV2Sb tetrahedra,  a cornercorner with one O(11)LiVSnSb tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(15)LiV2Sb tetrahedra, and  an edgeedge with one O(11)LiVSnSb tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Sn(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one V(3), and one Sb(2) atom to form distorted OLiV2Sb tetrahedra that share  a cornercorner with one O(11)LiVSnSb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(16)LiVSnSb trigonal pyramid, corners with two equivalent O(10)LiV2Sb trigonal pyramids,  an edgeedge with one O(11)LiVSnSb tetrahedra, and  an edgeedge with one O(12)LiVSnSb tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(2), one V(1), one Sn(2), and one Sb(2) atom to form distorted OLiVSnSb trigonal pyramids that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(15)LiV2Sb tetrahedra,  a cornercorner with one O(5)LiV2Sn tetrahedra,  a cornercorner with one O(11)LiVSnSb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra,  a cornercorner with one O(7)LiVSnSb tetrahedra, corners with two equivalent O(8)LiVSnSb tetrahedra, and  an edgeedge with one O(4)LiVSn2 tetrahedra.
Li4V3Sn3(SbO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. The Li(1)-O(11) bond length is 2.03 Å. The Li(1)-O(12) bond length is 2.07 Å. The Li(1)-O(15) bond length is 2.17 Å. The Li(1)-O(3) bond length is 2.18 Å. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. The Li(2)-O(14) bond length is 1.99 Å. The Li(2)-O(16) bond length is 1.98 Å. The Li(2)-O(5) bond length is 1.83 Å. The Li(2)-O(9) bond length is 2.05 Å. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. The Li(3)-O(1) bond length is 2.00 Å. The Li(3)-O(10) bond length is 1.94 Å. The Li(3)-O(4) bond length is 1.85 Å. The Li(3)-O(6) bond length is 1.98 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, and corners with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-68°. The Li(4)-O(13) bond length is 2.15 Å. The Li(4)-O(2) bond length is 2.10 Å. The Li(4)-O(7) bond length is 2.08 Å. The Li(4)-O(8) bond length is 2.08 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. The V(1)-O(14) bond length is 2.05 Å. The V(1)-O(16) bond length is 2.06 Å. The V(1)-O(3) bond length is 2.16 Å. The V(1)-O(4) bond length is 2.12 Å. The V(1)-O(7) bond length is 2.03 Å. The V(1)-O(8) bond length is 2.03 Å. In the second V site, V(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-60°. The V(2)-O(1) bond length is 2.05 Å. The V(2)-O(10) bond length is 2.04 Å. The V(2)-O(11) bond length is 2.03 Å. The V(2)-O(13) bond length is 2.16 Å. The V(2)-O(15) bond length is 2.09 Å. The V(2)-O(5) bond length is 2.13 Å. In the third V site, V(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. The V(3)-O(10) bond length is 1.91 Å. The V(3)-O(12) bond length is 2.02 Å. The V(3)-O(13) bond length is 2.03 Å. The V(3)-O(15) bond length is 1.94 Å. The V(3)-O(5) bond length is 2.07 Å. The V(3)-O(6) bond length is 2.07 Å. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. The Sn(1)-O(14) bond length is 2.10 Å. The Sn(1)-O(2) bond length is 2.15 Å. The Sn(1)-O(3) bond length is 2.10 Å. The Sn(1)-O(4) bond length is 2.09 Å. The Sn(1)-O(7) bond length is 2.09 Å. The Sn(1)-O(9) bond length is 2.12 Å. In the second Sn site, Sn(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. The Sn(2)-O(16) bond length is 2.10 Å. The Sn(2)-O(2) bond length is 2.15 Å. The Sn(2)-O(3) bond length is 2.10 Å. The Sn(2)-O(4) bond length is 2.10 Å. The Sn(2)-O(8) bond length is 2.09 Å. The Sn(2)-O(9) bond length is 2.11 Å. In the third Sn site, Sn(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. The Sn(3)-O(1) bond length is 2.14 Å. The Sn(3)-O(11) bond length is 2.11 Å. The Sn(3)-O(12) bond length is 2.14 Å. The Sn(3)-O(13) bond length is 2.10 Å. The Sn(3)-O(5) bond length is 2.07 Å. The Sn(3)-O(6) bond length is 2.14 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-60°. The Sb(1)-O(1) bond length is 2.20 Å. The Sb(1)-O(10) bond length is 2.43 Å. The Sb(1)-O(2) bond length is 2.27 Å. The Sb(1)-O(6) bond length is 2.21 Å. The Sb(1)-O(7) bond length is 2.40 Å. The Sb(1)-O(8) bond length is 2.42 Å. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. The Sb(2)-O(11) bond length is 2.34 Å. The Sb(2)-O(12) bond length is 2.33 Å. The Sb(2)-O(14) bond length is 2.29 Å. The Sb(2)-O(15) bond length is 2.36 Å. The Sb(2)-O(16) bond length is 2.27 Å. The Sb(2)-O(9) bond length is 2.27 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Sn(3), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(4), one Sn(1), one Sn(2), and one Sb(1) atom to form distorted OLiSn2Sb tetrahedra that share  a cornercorner with one O(7)LiVSnSb tetrahedra,  a cornercorner with one O(8)LiVSnSb tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(7)LiVSnSb tetrahedra, and  an edgeedge with one O(8)LiVSnSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one Sn(1), and one Sn(2) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(2)LiSn2Sb tetrahedra, corners with two equivalent O(7)LiVSnSb tetrahedra, corners with two equivalent O(8)LiVSnSb tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid, and  an edgeedge with one O(16)LiVSnSb trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one V(2), one V(3), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share corners with two equivalent O(15)LiV2Sb tetrahedra, corners with two equivalent O(11)LiVSnSb tetrahedra, corners with two equivalent O(12)LiVSnSb tetrahedra,  a cornercorner with one O(16)LiVSnSb trigonal pyramid, and  an edgeedge with one O(10)LiV2Sb trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Sn(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Sn(1), and one Sb(1) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(8)LiVSnSb tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(2)LiSn2Sb tetrahedra, and  an edgeedge with one O(8)LiVSnSb tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Sn(2), and one Sb(1) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(7)LiVSnSb tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid, corners with two equivalent O(16)LiVSnSb trigonal pyramids,  an edgeedge with one O(2)LiSn2Sb tetrahedra, and  an edgeedge with one O(7)LiVSnSb tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Sn(1), one Sn(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one V(2), one V(3), and one Sb(1) atom to form distorted OLiV2Sb trigonal pyramids that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(4)LiVSn2 tetrahedra,  a cornercorner with one O(11)LiVSnSb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra,  a cornercorner with one O(7)LiVSnSb tetrahedra,  a cornercorner with one O(8)LiVSnSb tetrahedra, corners with two equivalent O(15)LiV2Sb tetrahedra, and  an edgeedge with one O(5)LiV2Sn tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Sn(3), and one Sb(2) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(15)LiV2Sb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(15)LiV2Sb tetrahedra, and  an edgeedge with one O(12)LiVSnSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one V(3), one Sn(3), and one Sb(2) atom to form distorted OLiVSnSb tetrahedra that share  a cornercorner with one O(15)LiV2Sb tetrahedra,  a cornercorner with one O(11)LiVSnSb tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Sb trigonal pyramid,  a cornercorner with one O(16)LiVSnSb trigonal pyramid,  an edgeedge with one O(15)LiV2Sb tetrahedra, and  an edgeedge with one O(11)LiVSnSb tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Sn(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one V(3), and one Sb(2) atom to form distorted OLiV2Sb tetrahedra that share  a cornercorner with one O(11)LiVSnSb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(16)LiVSnSb trigonal pyramid, corners with two equivalent O(10)LiV2Sb trigonal pyramids,  an edgeedge with one O(11)LiVSnSb tetrahedra, and  an edgeedge with one O(12)LiVSnSb tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(2), one V(1), one Sn(2), and one Sb(2) atom to form distorted OLiVSnSb trigonal pyramids that share  a cornercorner with one O(2)LiSn2Sb tetrahedra,  a cornercorner with one O(15)LiV2Sb tetrahedra,  a cornercorner with one O(5)LiV2Sn tetrahedra,  a cornercorner with one O(11)LiVSnSb tetrahedra,  a cornercorner with one O(12)LiVSnSb tetrahedra,  a cornercorner with one O(7)LiVSnSb tetrahedra, corners with two equivalent O(8)LiVSnSb tetrahedra, and  an edgeedge with one O(4)LiVSn2 tetrahedra.