Li3V3(BO5)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(20), two equivalent O(16), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-62°. In the second Li site, Li(2) is bonded to one O(18), one O(3), two equivalent O(19), and two equivalent O(2) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(5)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-36°. In the third Li site, Li(3) is bonded to one O(10), one O(11), two equivalent O(15), and two equivalent O(6) atoms to form LiO6 octahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-68°. In the fourth Li site, Li(4) is bonded to one O(13), one O(8), two equivalent O(12), and two equivalent O(9) atoms to form LiO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. In the fifth Li site, Li(5) is bonded to one O(15), one O(17), two equivalent O(11), and two equivalent O(19) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-54°. In the sixth Li site, Li(6) is bonded to one O(2), one O(20), two equivalent O(18), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent V(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-67°. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(19), two equivalent O(17), and two equivalent O(3) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. In the second V site, V(2) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-56°. In the third V site, V(3) is bonded to one O(4), one O(6), two equivalent O(10), and two equivalent O(2) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-58°. In the fourth V site, V(4) is bonded to one O(10), one O(12), two equivalent O(14), and two equivalent O(8) atoms to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent V(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-68°. In the fifth V site, V(5) is bonded to one O(11), one O(9), two equivalent O(13), and two equivalent O(7) atoms to form distorted VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the sixth V site, V(6) is bonded to one O(14), one O(16), two equivalent O(12), and two equivalent O(20) atoms to form VO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-67°. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(8) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(3), one O(6), and one O(7) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(14), one O(15), and one O(18) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(13), one O(16), and one O(17) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), and two equivalent V(2) atoms. In the second O site, O(2) is bonded to one Li(6), two equivalent Li(2), and two equivalent V(3) atoms to form distorted OLi3V2 square pyramids that share  a cornercorner with one O(20)Li2V2 tetrahedra, corners with two equivalent O(10)LiV3 tetrahedra, edges with two equivalent O(2)Li3V2 square pyramids,  an edgeedge with one O(10)LiV3 tetrahedra, and edges with two equivalent O(18)Li3B trigonal pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), two equivalent V(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(6), one V(3), and one B(1) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one V(2), and one B(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(3), one V(3), and one B(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one V(2), two equivalent V(5), and one B(2) atom. In the eighth O site, O(8) is bonded to one Li(4), two equivalent V(4), and one B(1) atom to form distorted OLiV2B trigonal pyramids that share corners with two equivalent O(9)Li2V3 square pyramids, corners with two equivalent O(10)LiV3 tetrahedra, corners with two equivalent O(8)LiV2B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and  an edgeedge with one O(14)V3B trigonal pyramid. In the ninth O site, O(9) is bonded to two equivalent Li(4), one V(5), and two equivalent V(2) atoms to form OLi2V3 square pyramids that share corners with two equivalent O(12)Li2V3 square pyramids, corners with two equivalent O(8)LiV2B trigonal pyramids,  an edgeedge with one O(12)Li2V3 square pyramid, and edges with two equivalent O(9)Li2V3 square pyramids. In the tenth O site, O(10) is bonded to one Li(3), one V(4), and two equivalent V(3) atoms to form OLiV3 tetrahedra that share  a cornercorner with one O(12)Li2V3 square pyramid, corners with two equivalent O(2)Li3V2 square pyramids, corners with two equivalent O(10)LiV3 tetrahedra, corners with two equivalent O(8)LiV2B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, and  an edgeedge with one O(2)Li3V2 square pyramid. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), two equivalent Li(5), and one V(5) atom. In the twelfth O site, O(12) is bonded to two equivalent Li(4), one V(4), and two equivalent V(6) atoms to form OLi2V3 square pyramids that share corners with two equivalent O(9)Li2V3 square pyramids,  a cornercorner with one O(10)LiV3 tetrahedra, corners with two equivalent O(20)Li2V2 tetrahedra,  an edgeedge with one O(9)Li2V3 square pyramid, edges with two equivalent O(12)Li2V3 square pyramids,  an edgeedge with one O(20)Li2V2 tetrahedra, edges with two equivalent O(8)LiV2B trigonal pyramids, and edges with two equivalent O(14)V3B trigonal pyramids. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent V(5), and one B(4) atom. In the fourteenth O site, O(14) is bonded to one V(6), two equivalent V(4), and one B(3) atom to form distorted OV3B trigonal pyramids that share corners with two equivalent O(20)Li2V2 tetrahedra, corners with two equivalent O(10)LiV3 tetrahedra,  a cornercorner with one O(18)Li3B trigonal pyramid, corners with two equivalent O(8)LiV2B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and  an edgeedge with one O(8)LiV2B trigonal pyramid. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), two equivalent Li(3), and one B(3) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one V(6), and one B(4) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), two equivalent V(1), and one B(4) atom. In the eighteenth O site, O(18) is bonded to one Li(2), two equivalent Li(6), and one B(3) atom to form distorted OLi3B trigonal pyramids that share corners with two equivalent O(20)Li2V2 tetrahedra,  a cornercorner with one O(14)V3B trigonal pyramid, corners with two equivalent O(18)Li3B trigonal pyramids, and edges with two equivalent O(2)Li3V2 square pyramids. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to two equivalent Li(2), two equivalent Li(5), and one V(1) atom. In the twentieth O site, O(20) is bonded to one Li(1), one Li(6), and two equivalent V(6) atoms to form OLi2V2 tetrahedra that share  a cornercorner with one O(2)Li3V2 square pyramid, corners with two equivalent O(12)Li2V3 square pyramids, corners with two equivalent O(20)Li2V2 tetrahedra, corners with two equivalent O(18)Li3B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, and  an edgeedge with one O(12)Li2V3 square pyramid.
Li3V3(BO5)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(20), two equivalent O(16), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-62°. The Li(1)-O(1) bond length is 2.13 Å. The Li(1)-O(20) bond length is 2.10 Å. There is one shorter (2.17 Å) and one longer (2.22 Å) Li(1)-O(16) bond length. There is one shorter (2.12 Å) and one longer (2.13 Å) Li(1)-O(5) bond length. In the second Li site, Li(2) is bonded to one O(18), one O(3), two equivalent O(19), and two equivalent O(2) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(5)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-36°. The Li(2)-O(18) bond length is 1.92 Å. The Li(2)-O(3) bond length is 2.40 Å. There is one shorter (2.06 Å) and one longer (2.07 Å) Li(2)-O(19) bond length. There is one shorter (2.22 Å) and one longer (2.28 Å) Li(2)-O(2) bond length. In the third Li site, Li(3) is bonded to one O(10), one O(11), two equivalent O(15), and two equivalent O(6) atoms to form LiO6 octahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-68°. The Li(3)-O(10) bond length is 2.16 Å. The Li(3)-O(11) bond length is 2.14 Å. There is one shorter (1.98 Å) and one longer (1.99 Å) Li(3)-O(15) bond length. There is one shorter (2.30 Å) and one longer (2.34 Å) Li(3)-O(6) bond length. In the fourth Li site, Li(4) is bonded to one O(13), one O(8), two equivalent O(12), and two equivalent O(9) atoms to form LiO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. The Li(4)-O(13) bond length is 2.18 Å. The Li(4)-O(8) bond length is 2.07 Å. There is one shorter (2.13 Å) and one longer (2.15 Å) Li(4)-O(12) bond length. Both Li(4)-O(9) bond lengths are 2.12 Å. In the fifth Li site, Li(5) is bonded to one O(15), one O(17), two equivalent O(11), and two equivalent O(19) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-54°. The Li(5)-O(15) bond length is 1.93 Å. The Li(5)-O(17) bond length is 2.42 Å. There is one shorter (2.10 Å) and one longer (2.13 Å) Li(5)-O(11) bond length. There is one shorter (2.15 Å) and one longer (2.18 Å) Li(5)-O(19) bond length. In the sixth Li site, Li(6) is bonded to one O(2), one O(20), two equivalent O(18), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent V(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-67°. The Li(6)-O(2) bond length is 2.14 Å. The Li(6)-O(20) bond length is 2.03 Å. There is one shorter (2.00 Å) and one longer (2.01 Å) Li(6)-O(18) bond length. Both Li(6)-O(4) bond lengths are 2.28 Å. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(19), two equivalent O(17), and two equivalent O(3) atoms to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. The V(1)-O(1) bond length is 1.96 Å. The V(1)-O(19) bond length is 1.73 Å. There is one shorter (2.06 Å) and one longer (2.07 Å) V(1)-O(17) bond length. There is one shorter (2.06 Å) and one longer (2.07 Å) V(1)-O(3) bond length. In the second V site, V(2) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-56°. The V(2)-O(5) bond length is 2.00 Å. The V(2)-O(7) bond length is 2.20 Å. There is one shorter (2.02 Å) and one longer (2.04 Å) V(2)-O(1) bond length. There is one shorter (2.05 Å) and one longer (2.07 Å) V(2)-O(9) bond length. In the third V site, V(3) is bonded to one O(4), one O(6), two equivalent O(10), and two equivalent O(2) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-58°. The V(3)-O(4) bond length is 2.00 Å. The V(3)-O(6) bond length is 2.04 Å. There is one shorter (2.02 Å) and one longer (2.04 Å) V(3)-O(10) bond length. There is one shorter (1.81 Å) and one longer (2.02 Å) V(3)-O(2) bond length. In the fourth V site, V(4) is bonded to one O(10), one O(12), two equivalent O(14), and two equivalent O(8) atoms to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent V(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-68°. The V(4)-O(10) bond length is 1.94 Å. The V(4)-O(12) bond length is 2.03 Å. There is one shorter (2.09 Å) and one longer (2.11 Å) V(4)-O(14) bond length. There is one shorter (2.06 Å) and one longer (2.08 Å) V(4)-O(8) bond length. In the fifth V site, V(5) is bonded to one O(11), one O(9), two equivalent O(13), and two equivalent O(7) atoms to form distorted VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. The V(5)-O(11) bond length is 1.68 Å. The V(5)-O(9) bond length is 2.00 Å. Both V(5)-O(13) bond lengths are 2.06 Å. There is one shorter (2.12 Å) and one longer (2.13 Å) V(5)-O(7) bond length. In the sixth V site, V(6) is bonded to one O(14), one O(16), two equivalent O(12), and two equivalent O(20) atoms to form VO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-67°. The V(6)-O(14) bond length is 2.06 Å. The V(6)-O(16) bond length is 2.00 Å. There is one shorter (2.03 Å) and one longer (2.10 Å) V(6)-O(12) bond length. There is one shorter (1.77 Å) and one longer (2.01 Å) V(6)-O(20) bond length. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(8) atom. The B(1)-O(4) bond length is 1.36 Å. The B(1)-O(5) bond length is 1.38 Å. The B(1)-O(8) bond length is 1.42 Å. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(3), one O(6), and one O(7) atom. The B(2)-O(3) bond length is 1.41 Å. The B(2)-O(6) bond length is 1.33 Å. The B(2)-O(7) bond length is 1.44 Å. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(14), one O(15), and one O(18) atom. The B(3)-O(14) bond length is 1.53 Å. The B(3)-O(15) bond length is 1.33 Å. The B(3)-O(18) bond length is 1.34 Å. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(13), one O(16), and one O(17) atom. The B(4)-O(13) bond length is 1.42 Å. The B(4)-O(16) bond length is 1.35 Å. The B(4)-O(17) bond length is 1.40 Å. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), and two equivalent V(2) atoms. In the second O site, O(2) is bonded to one Li(6), two equivalent Li(2), and two equivalent V(3) atoms to form distorted OLi3V2 square pyramids that share  a cornercorner with one O(20)Li2V2 tetrahedra, corners with two equivalent O(10)LiV3 tetrahedra, edges with two equivalent O(2)Li3V2 square pyramids,  an edgeedge with one O(10)LiV3 tetrahedra, and edges with two equivalent O(18)Li3B trigonal pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), two equivalent V(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(6), one V(3), and one B(1) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one V(2), and one B(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(3), one V(3), and one B(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one V(2), two equivalent V(5), and one B(2) atom. In the eighth O site, O(8) is bonded to one Li(4), two equivalent V(4), and one B(1) atom to form distorted OLiV2B trigonal pyramids that share corners with two equivalent O(9)Li2V3 square pyramids, corners with two equivalent O(10)LiV3 tetrahedra, corners with two equivalent O(8)LiV2B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and  an edgeedge with one O(14)V3B trigonal pyramid. In the ninth O site, O(9) is bonded to two equivalent Li(4), one V(5), and two equivalent V(2) atoms to form OLi2V3 square pyramids that share corners with two equivalent O(12)Li2V3 square pyramids, corners with two equivalent O(8)LiV2B trigonal pyramids,  an edgeedge with one O(12)Li2V3 square pyramid, and edges with two equivalent O(9)Li2V3 square pyramids. In the tenth O site, O(10) is bonded to one Li(3), one V(4), and two equivalent V(3) atoms to form OLiV3 tetrahedra that share  a cornercorner with one O(12)Li2V3 square pyramid, corners with two equivalent O(2)Li3V2 square pyramids, corners with two equivalent O(10)LiV3 tetrahedra, corners with two equivalent O(8)LiV2B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, and  an edgeedge with one O(2)Li3V2 square pyramid. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), two equivalent Li(5), and one V(5) atom. In the twelfth O site, O(12) is bonded to two equivalent Li(4), one V(4), and two equivalent V(6) atoms to form OLi2V3 square pyramids that share corners with two equivalent O(9)Li2V3 square pyramids,  a cornercorner with one O(10)LiV3 tetrahedra, corners with two equivalent O(20)Li2V2 tetrahedra,  an edgeedge with one O(9)Li2V3 square pyramid, edges with two equivalent O(12)Li2V3 square pyramids,  an edgeedge with one O(20)Li2V2 tetrahedra, edges with two equivalent O(8)LiV2B trigonal pyramids, and edges with two equivalent O(14)V3B trigonal pyramids. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), two equivalent V(5), and one B(4) atom. In the fourteenth O site, O(14) is bonded to one V(6), two equivalent V(4), and one B(3) atom to form distorted OV3B trigonal pyramids that share corners with two equivalent O(20)Li2V2 tetrahedra, corners with two equivalent O(10)LiV3 tetrahedra,  a cornercorner with one O(18)Li3B trigonal pyramid, corners with two equivalent O(8)LiV2B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and  an edgeedge with one O(8)LiV2B trigonal pyramid. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), two equivalent Li(3), and one B(3) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1), one V(6), and one B(4) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), two equivalent V(1), and one B(4) atom. In the eighteenth O site, O(18) is bonded to one Li(2), two equivalent Li(6), and one B(3) atom to form distorted OLi3B trigonal pyramids that share corners with two equivalent O(20)Li2V2 tetrahedra,  a cornercorner with one O(14)V3B trigonal pyramid, corners with two equivalent O(18)Li3B trigonal pyramids, and edges with two equivalent O(2)Li3V2 square pyramids. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to two equivalent Li(2), two equivalent Li(5), and one V(1) atom. In the twentieth O site, O(20) is bonded to one Li(1), one Li(6), and two equivalent V(6) atoms to form OLi2V2 tetrahedra that share  a cornercorner with one O(2)Li3V2 square pyramid, corners with two equivalent O(12)Li2V3 square pyramids, corners with two equivalent O(20)Li2V2 tetrahedra, corners with two equivalent O(18)Li3B trigonal pyramids, corners with two equivalent O(14)V3B trigonal pyramids, and  an edgeedge with one O(12)Li2V3 square pyramid.