Cr2TeO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form CrO6 octahedra that share corners with four equivalent Cr(2)O6 octahedra, corners with four equivalent Te(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second Cr site, Cr(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form CrO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form TeO6 octahedra that share corners with eight equivalent Cr(2)O6 octahedra and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Te site, Te(2) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form TeO6 octahedra that share corners with eight equivalent Cr(1)O6 octahedra and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cr(2) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cr(1), one Cr(2), and one Te(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Cr(1), one Cr(2), and one Te(1) atom.
Cr2TeO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form CrO6 octahedra that share corners with four equivalent Cr(2)O6 octahedra, corners with four equivalent Te(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. Both Cr(1)-O(2) bond lengths are 1.97 Å. Both Cr(1)-O(3) bond lengths are 1.98 Å. Both Cr(1)-O(4) bond lengths are 1.99 Å. In the second Cr site, Cr(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form CrO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. Both Cr(2)-O(1) bond lengths are 1.96 Å. Both Cr(2)-O(3) bond lengths are 1.99 Å. Both Cr(2)-O(4) bond lengths are 1.98 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form TeO6 octahedra that share corners with eight equivalent Cr(2)O6 octahedra and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. Both Te(1)-O(1) bond lengths are 1.93 Å. All Te(1)-O(4) bond lengths are 1.92 Å. In the second Te site, Te(2) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form TeO6 octahedra that share corners with eight equivalent Cr(1)O6 octahedra and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. Both Te(2)-O(2) bond lengths are 1.94 Å. All Te(2)-O(3) bond lengths are 1.93 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cr(2) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Cr(1) and one Te(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cr(1), one Cr(2), and one Te(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Cr(1), one Cr(2), and one Te(1) atom.