AgPF6 crystallizes in the cubic Fm-3m space group. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent P(1)F6 octahedra. The corner-sharing octahedra are not tilted. P(1) is bonded to six equivalent F(1) atoms to form PF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted linear geometry to one Ag(1) and one P(1) atom.
AgPF6 crystallizes in the cubic Fm-3m space group. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent P(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Ag(1)-F(1) bond lengths are 2.43 Å. P(1) is bonded to six equivalent F(1) atoms to form PF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedra are not tilted. All P(1)-F(1) bond lengths are 1.62 Å. F(1) is bonded in a distorted linear geometry to one Ag(1) and one P(1) atom.