Zr(InBr3)2 crystallizes in the tetragonal P4/mnc space group. Zr(1) is bonded in an octahedral geometry to two equivalent Br(2) and four Br(1,1,1) atoms. In(1) is bonded in a 4-coordinate geometry to four Br(1,1) atoms. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms. In the second Br site, Br(2) is bonded in a single-bond geometry to one Zr(1) atom. In the third Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms. In the fourth Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms. In the fifth Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms.
Zr(InBr3)2 crystallizes in the tetragonal P4/mnc space group. Zr(1) is bonded in an octahedral geometry to two equivalent Br(2) and four Br(1,1,1) atoms. Both Zr(1)-Br(2) bond lengths are 2.64 Å. All Zr(1)-Br(1,1,1) bond lengths are 2.63 Å. In(1) is bonded in a 4-coordinate geometry to four Br(1,1) atoms. All In(1)-Br(1,1) bond lengths are 3.40 Å. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms. In the second Br site, Br(2) is bonded in a single-bond geometry to one Zr(1) atom. In the third Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms. In the fourth Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms. The Br(1)-Zr(1) bond length is 2.63 Å. Both Br(1)-In(1) bond lengths are 3.40 Å. In the fifth Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) and two equivalent In(1) atoms. Both Br(1)-In(1) bond lengths are 3.40 Å.