Na2BNH4 crystallizes in the tetragonal P-42m space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent N(1) and four equivalent H(1) atoms. B(1) is bonded in a tetrahedral geometry to four equivalent H(1) atoms. N(1) is bonded in a square co-planar geometry to four equivalent Na(1) atoms. H(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one B(1) atom.
Na2BNH4 crystallizes in the tetragonal P-42m space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent N(1) and four equivalent H(1) atoms. Both Na(1)-N(1) bond lengths are 2.44 Å. All Na(1)-H(1) bond lengths are 2.38 Å. B(1) is bonded in a tetrahedral geometry to four equivalent H(1) atoms. All B(1)-H(1) bond lengths are 1.23 Å. N(1) is bonded in a square co-planar geometry to four equivalent Na(1) atoms. H(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one B(1) atom.