AgPbSbS3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a rectangular see-saw-like geometry to one S(1), one S(3), and two equivalent S(2) atoms. Pb(1) is bonded in a 6-coordinate geometry to one S(2), two equivalent S(3), and three equivalent S(1) atoms. Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to one Ag(1), three equivalent Pb(1), and one Sb(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1), one Pb(1), and one Sb(1) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Pb(1), and one Sb(1) atom.
AgPbSbS3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a rectangular see-saw-like geometry to one S(1), one S(3), and two equivalent S(2) atoms. The Ag(1)-S(1) bond length is 2.95 Å. The Ag(1)-S(3) bond length is 2.67 Å. There is one shorter (2.54 Å) and one longer (2.58 Å) Ag(1)-S(2) bond length. Pb(1) is bonded in a 6-coordinate geometry to one S(2), two equivalent S(3), and three equivalent S(1) atoms. The Pb(1)-S(2) bond length is 3.27 Å. There is one shorter (2.87 Å) and one longer (3.06 Å) Pb(1)-S(3) bond length. There are a spread of Pb(1)-S(1) bond distances ranging from 2.92-3.18 Å. Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. The Sb(1)-S(1) bond length is 2.51 Å. The Sb(1)-S(2) bond length is 2.48 Å. The Sb(1)-S(3) bond length is 2.49 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to one Ag(1), three equivalent Pb(1), and one Sb(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1), one Pb(1), and one Sb(1) atom. In the third S site, S(3) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Pb(1), and one Sb(1) atom.