Cs2NaMn(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 4-coordinate geometry to one N(2), one N(3), and two equivalent N(1) atoms. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Mn(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one N(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one N(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Cs(1), one Na(1), and one C(3) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Cs(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Na(1), and one C(1) atom.
Cs2NaMn(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 4-coordinate geometry to one N(2), one N(3), and two equivalent N(1) atoms. The Cs(1)-N(2) bond length is 3.31 Å. The Cs(1)-N(3) bond length is 3.44 Å. There is one shorter (3.40 Å) and one longer (3.49 Å) Cs(1)-N(1) bond length. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Both Na(1)-N(1) bond lengths are 2.51 Å. Both Na(1)-N(2) bond lengths are 2.55 Å. Both Na(1)-N(3) bond lengths are 2.54 Å. Mn(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. Both Mn(1)-C(1) bond lengths are 1.97 Å. Both Mn(1)-C(2) bond lengths are 1.97 Å. Both Mn(1)-C(3) bond lengths are 1.96 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one N(3) atom. The C(1)-N(3) bond length is 1.18 Å. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one N(2) atom. The C(2)-N(2) bond length is 1.18 Å. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one N(1) atom. The C(3)-N(1) bond length is 1.18 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Cs(1), one Na(1), and one C(3) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Cs(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Na(1), and one C(1) atom.