Na2AgAs crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Ag(1) and four equivalent As(1) atoms. Ag(1) is bonded to eight equivalent Na(1), two equivalent Ag(1), and two equivalent As(1) atoms to form a mixture of distorted face, corner, and edge-sharing AgNa8Ag2As2 cuboctahedra. As(1) is bonded in a 10-coordinate geometry to eight equivalent Na(1) and two equivalent Ag(1) atoms.
Na2AgAs crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Ag(1) and four equivalent As(1) atoms. There are two shorter (3.34 Å) and two longer (3.35 Å) Na(1)-Ag(1) bond lengths. There are a spread of Na(1)-As(1) bond distances ranging from 3.02-3.24 Å. Ag(1) is bonded to eight equivalent Na(1), two equivalent Ag(1), and two equivalent As(1) atoms to form a mixture of distorted face, corner, and edge-sharing AgNa8Ag2As2 cuboctahedra. Both Ag(1)-Ag(1) bond lengths are 2.80 Å. Both Ag(1)-As(1) bond lengths are 2.54 Å. As(1) is bonded in a 10-coordinate geometry to eight equivalent Na(1) and two equivalent Ag(1) atoms.