(GaF3)24O2 crystallizes in the orthorhombic Imm2 space group. The structure consists of two water atoms inside a GaF3 framework. In the GaF3 framework, there are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one F(1), one F(3), two equivalent F(4), and two equivalent F(6) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. In the second Ga site, Ga(2) is bonded to one F(2), one F(3), two equivalent F(5), and two equivalent F(7) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 27-36°. In the third Ga site, Ga(3) is bonded to one F(10), one F(12), one F(14), one F(5), one F(6), and one F(8) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. In the fourth Ga site, Ga(4) is bonded to one F(10), one F(11), one F(13), one F(4), one F(7), and one F(9) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. There are fourteen inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(3) atom. In the second F site, F(7) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the fifth F site, F(10) is bonded in a bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the sixth F site, F(11) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the seventh F site, F(12) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the eighth F site, F(13) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the ninth F site, F(14) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the tenth F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the eleventh F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(2) atoms. In the twelfth F site, F(3) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(2) atom. In the thirteenth F site, F(4) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(4) atom. In the fourteenth F site, F(5) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(3) atom.
(GaF3)24O2 crystallizes in the orthorhombic Imm2 space group. The structure consists of two water atoms inside a GaF3 framework. In the GaF3 framework, there are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one F(1), one F(3), two equivalent F(4), and two equivalent F(6) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. The Ga(1)-F(1) bond length is 1.93 Å. The Ga(1)-F(3) bond length is 1.92 Å. Both Ga(1)-F(4) bond lengths are 1.92 Å. Both Ga(1)-F(6) bond lengths are 1.92 Å. In the second Ga site, Ga(2) is bonded to one F(2), one F(3), two equivalent F(5), and two equivalent F(7) atoms to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 27-36°. The Ga(2)-F(2) bond length is 1.92 Å. The Ga(2)-F(3) bond length is 1.92 Å. Both Ga(2)-F(5) bond lengths are 1.92 Å. Both Ga(2)-F(7) bond lengths are 1.92 Å. In the third Ga site, Ga(3) is bonded to one F(10), one F(12), one F(14), one F(5), one F(6), and one F(8) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. The Ga(3)-F(10) bond length is 1.92 Å. The Ga(3)-F(12) bond length is 1.92 Å. The Ga(3)-F(14) bond length is 1.92 Å. The Ga(3)-F(5) bond length is 1.92 Å. The Ga(3)-F(6) bond length is 1.92 Å. The Ga(3)-F(8) bond length is 1.92 Å. In the fourth Ga site, Ga(4) is bonded to one F(10), one F(11), one F(13), one F(4), one F(7), and one F(9) atom to form corner-sharing GaF6 octahedra. The corner-sharing octahedral tilt angles range from 26-36°. The Ga(4)-F(10) bond length is 1.92 Å. The Ga(4)-F(11) bond length is 1.92 Å. The Ga(4)-F(13) bond length is 1.92 Å. The Ga(4)-F(4) bond length is 1.92 Å. The Ga(4)-F(7) bond length is 1.92 Å. The Ga(4)-F(9) bond length is 1.93 Å. There are fourteen inequivalent F sites. In the first F site, F(6) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(3) atom. In the second F site, F(7) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the third F site, F(8) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the fourth F site, F(9) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the fifth F site, F(10) is bonded in a bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the sixth F site, F(11) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the seventh F site, F(12) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the eighth F site, F(13) is bonded in a bent 150 degrees geometry to two equivalent Ga(4) atoms. In the ninth F site, F(14) is bonded in a bent 150 degrees geometry to two equivalent Ga(3) atoms. In the tenth F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the eleventh F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(2) atoms. In the twelfth F site, F(3) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(2) atom. In the thirteenth F site, F(4) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(4) atom. In the fourteenth F site, F(5) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(3) atom.