LiAgO2 crystallizes in the monoclinic C2/m space group. Li(1) is bonded to six equivalent O(1) atoms to form edge-sharing LiO6 octahedra. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Li(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OLi3Ag2 trigonal bipyramids.
LiAgO2 crystallizes in the monoclinic C2/m space group. Li(1) is bonded to six equivalent O(1) atoms to form edge-sharing LiO6 octahedra. There are two shorter (2.10 Å) and four longer (2.27 Å) Li(1)-O(1) bond lengths. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Ag(1)-O(1) bond lengths are 2.05 Å. O(1) is bonded to three equivalent Li(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OLi3Ag2 trigonal bipyramids.