Tl2SO4 is Iron carbide-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four thallium(i) sulfate, >=99.9% trace metals basis molecules. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 1-coordinate geometry to one O(2) atom. In the second Tl site, Tl(2) is bonded in a distorted single-bond geometry to one O(3) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Tl(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Tl(2) and one S(1) atom.
Tl2SO4 is Iron carbide-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four thallium(i) sulfate, >=99.9% trace metals basis molecules. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 1-coordinate geometry to one O(2) atom. The Tl(1)-O(2) bond length is 2.76 Å. In the second Tl site, Tl(2) is bonded in a distorted single-bond geometry to one O(3) atom. The Tl(2)-O(3) bond length is 2.84 Å. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. The S(1)-O(2) bond length is 1.49 Å. The S(1)-O(3) bond length is 1.48 Å. Both S(1)-O(1) bond lengths are 1.48 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Tl(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Tl(2) and one S(1) atom.