(MoO3)12N2 crystallizes in the trigonal P3 space group. The structure consists of one ammonia atom inside a MoO3 framework. In the MoO3 framework, Mo(1,2) is bonded in a 6-coordinate geometry to one O(3), one O(5), two equivalent O(1), and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Mo(1,2) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Mo(1,2) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1,2) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1,2) atoms. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1,2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1,2) atom.
(MoO3)12N2 crystallizes in the trigonal P3 space group. The structure consists of one ammonia atom inside a MoO3 framework. In the MoO3 framework, Mo(1,2) is bonded in a 6-coordinate geometry to one O(3), one O(5), two equivalent O(1), and two equivalent O(4) atoms. The Mo(1,2)-O(3) bond length is 2.26 Å. The Mo(1,2)-O(5) bond length is 1.70 Å. There is one shorter (1.75 Å) and one longer (2.47 Å) Mo(1,2)-O(1) bond length. Both Mo(1,2)-O(4) bond lengths are 2.00 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Mo(1,2) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Mo(1,2) atoms. There is one shorter (1.75 Å) and one longer (2.47 Å) O(2)-Mo(1,2) bond length. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1,2) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1,2) atoms. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1,2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1,2) atom. The O(6)-Mo(1,2) bond length is 1.70 Å.