Y4Rh6Pb19 crystallizes in the cubic I23 space group. Y(1) is bonded in a 10-coordinate geometry to one Pb(2), three equivalent Pb(1), and six equivalent Pb(3) atoms. Rh(1) is bonded in a 7-coordinate geometry to one Rh(1), two equivalent Pb(1), and four equivalent Pb(3) atoms. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent Y(1) and two equivalent Rh(1) atoms. In the second Pb site, Pb(2) is bonded in a distorted tetrahedral geometry to four equivalent Y(1) atoms. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to two equivalent Y(1) and two equivalent Rh(1) atoms.
Y4Rh6Pb19 crystallizes in the cubic I23 space group. Y(1) is bonded in a 10-coordinate geometry to one Pb(2), three equivalent Pb(1), and six equivalent Pb(3) atoms. The Y(1)-Pb(2) bond length is 3.56 Å. All Y(1)-Pb(1) bond lengths are 3.26 Å. There are three shorter (3.31 Å) and three longer (3.32 Å) Y(1)-Pb(3) bond lengths. Rh(1) is bonded in a 7-coordinate geometry to one Rh(1), two equivalent Pb(1), and four equivalent Pb(3) atoms. The Rh(1)-Rh(1) bond length is 2.81 Å. Both Rh(1)-Pb(1) bond lengths are 2.73 Å. There are two shorter (2.74 Å) and two longer (2.94 Å) Rh(1)-Pb(3) bond lengths. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent Y(1) and two equivalent Rh(1) atoms. In the second Pb site, Pb(2) is bonded in a distorted tetrahedral geometry to four equivalent Y(1) atoms. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to two equivalent Y(1) and two equivalent Rh(1) atoms.