CSbCl2CSbH4Cl(H2)4(CHCl)2CClCCl2SbHCl2SbCl2NHClNH2Cl(HCl)2Cl2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of five 1333-74-0 atoms, one 7782-50-5 molecule, one antimony dichloride molecule, one chloramine molecule, one chloramine molecule, one chloromethane molecule, two chloromethane molecules, one dichloromethane molecule, two hydrochloric acid molecules, one CSbCl2 cluster, one CSbH4Cl cluster, and one SbHCl2 cluster. In the CSbCl2 cluster, C(2) is bonded in a distorted bent 150 degrees geometry to one Sb(2) and one Cl(8) atom. Sb(2) is bonded in a distorted L-shaped geometry to one C(2) and one Cl(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(8) is bonded in a single-bond geometry to one C(2) atom. In the CSbH4Cl cluster, C(5) is bonded in a distorted tetrahedral geometry to one H(16), one H(18), one H(19), and one Cl(1) atom. Sb(1) is bonded in a distorted L-shaped geometry to one H(15) and one Cl(1) atom. There are four inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one Sb(1) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(5) atom. Cl(1) is bonded in a distorted water-like geometry to one C(5) and one Sb(1) atom. In the SbHCl2 cluster, Sb(4) is bonded in a distorted T-shaped geometry to one H(9), one Cl(14), and one Cl(16) atom. H(9) is bonded in a single-bond geometry to one Sb(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(4) atom. In the second Cl site, Cl(16) is bonded in a single-bond geometry to one Sb(4) atom.
CSbCl2CSbH4Cl(H2)4(CHCl)2CClCCl2SbHCl2SbCl2NHClNH2Cl(HCl)2Cl2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of five 1333-74-0 atoms, one 7782-50-5 molecule, one antimony dichloride molecule, one chloramine molecule, one chloramine molecule, one chloromethane molecule, two chloromethane molecules, one dichloromethane molecule, two hydrochloric acid molecules, one CSbCl2 cluster, one CSbH4Cl cluster, and one SbHCl2 cluster. In the CSbCl2 cluster, C(2) is bonded in a distorted bent 150 degrees geometry to one Sb(2) and one Cl(8) atom. The C(2)-Sb(2) bond length is 2.13 Å. The C(2)-Cl(8) bond length is 1.67 Å. Sb(2) is bonded in a distorted L-shaped geometry to one C(2) and one Cl(5) atom. The Sb(2)-Cl(5) bond length is 2.44 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(8) is bonded in a single-bond geometry to one C(2) atom. In the CSbH4Cl cluster, C(5) is bonded in a distorted tetrahedral geometry to one H(16), one H(18), one H(19), and one Cl(1) atom. The C(5)-H(16) bond length is 1.10 Å. The C(5)-H(18) bond length is 1.09 Å. The C(5)-H(19) bond length is 1.10 Å. The C(5)-Cl(1) bond length is 1.82 Å. Sb(1) is bonded in a distorted L-shaped geometry to one H(15) and one Cl(1) atom. The Sb(1)-H(15) bond length is 1.73 Å. The Sb(1)-Cl(1) bond length is 2.66 Å. There are four inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one Sb(1) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(5) atom. Cl(1) is bonded in a distorted water-like geometry to one C(5) and one Sb(1) atom. In the SbHCl2 cluster, Sb(4) is bonded in a distorted T-shaped geometry to one H(9), one Cl(14), and one Cl(16) atom. The Sb(4)-H(9) bond length is 1.82 Å. The Sb(4)-Cl(14) bond length is 2.50 Å. The Sb(4)-Cl(16) bond length is 2.86 Å. H(9) is bonded in a single-bond geometry to one Sb(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(4) atom. In the second Cl site, Cl(16) is bonded in a single-bond geometry to one Sb(4) atom.