NaHF2 crystallizes in the monoclinic C2 space group. Na(1) is bonded in a 10-coordinate geometry to two equivalent H(1) and eight equivalent F(1) atoms. H(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Na(1) and two equivalent F(1) atoms. F(1) is bonded in a 1-coordinate geometry to four equivalent Na(1) and one H(1) atom.
NaHF2 crystallizes in the monoclinic C2 space group. Na(1) is bonded in a 10-coordinate geometry to two equivalent H(1) and eight equivalent F(1) atoms. Both Na(1)-H(1) bond lengths are 2.24 Å. There are a spread of Na(1)-F(1) bond distances ranging from 2.08-2.81 Å. H(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Na(1) and two equivalent F(1) atoms. Both H(1)-F(1) bond lengths are 1.13 Å. F(1) is bonded in a 1-coordinate geometry to four equivalent Na(1) and one H(1) atom.