Rb2AgC3(NS)3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one N(1), two equivalent N(2), two equivalent N(3), one S(2), and one S(3) atom. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to one N(2), one N(3), two equivalent N(1), one S(2), and one S(3) atom. Ag(1) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form corner-sharing AgS4 tetrahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(3) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one C(3) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one Ag(1), and one C(2) atom. In the third S site, S(3) is bonded in a distorted tetrahedral geometry to one Rb(1), one Rb(2), one Ag(1), and one C(1) atom.
Rb2AgC3(NS)3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one N(1), two equivalent N(2), two equivalent N(3), one S(2), and one S(3) atom. The Rb(1)-N(1) bond length is 3.19 Å. There is one shorter (3.01 Å) and one longer (3.21 Å) Rb(1)-N(2) bond length. There is one shorter (3.09 Å) and one longer (3.16 Å) Rb(1)-N(3) bond length. The Rb(1)-S(2) bond length is 3.81 Å. The Rb(1)-S(3) bond length is 3.70 Å. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to one N(2), one N(3), two equivalent N(1), one S(2), and one S(3) atom. The Rb(2)-N(2) bond length is 3.06 Å. The Rb(2)-N(3) bond length is 3.12 Å. There is one shorter (3.04 Å) and one longer (3.18 Å) Rb(2)-N(1) bond length. The Rb(2)-S(2) bond length is 3.54 Å. The Rb(2)-S(3) bond length is 3.72 Å. Ag(1) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form corner-sharing AgS4 tetrahedra. The Ag(1)-S(2) bond length is 2.58 Å. The Ag(1)-S(3) bond length is 2.55 Å. There is one shorter (2.67 Å) and one longer (2.70 Å) Ag(1)-S(1) bond length. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(3) atom. The C(1)-N(1) bond length is 1.19 Å. The C(1)-S(3) bond length is 1.65 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.64 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. The C(3)-N(3) bond length is 1.19 Å. The C(3)-S(1) bond length is 1.65 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one C(3) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one Ag(1), and one C(2) atom. In the third S site, S(3) is bonded in a distorted tetrahedral geometry to one Rb(1), one Rb(2), one Ag(1), and one C(1) atom.