BN4S4F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four BN4S4F3 clusters. B(1) is bonded in a tetrahedral geometry to one N(4), one F(1), one F(2), and one F(3) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one B(1), one S(1), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(3) and one N(4) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom.
BN4S4F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four BN4S4F3 clusters. B(1) is bonded in a tetrahedral geometry to one N(4), one F(1), one F(2), and one F(3) atom. The B(1)-N(4) bond length is 1.60 Å. The B(1)-F(1) bond length is 1.41 Å. The B(1)-F(2) bond length is 1.40 Å. The B(1)-F(3) bond length is 1.41 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. The N(1)-S(2) bond length is 1.59 Å. The N(1)-S(3) bond length is 1.59 Å. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.60 Å. The N(2)-S(2) bond length is 1.56 Å. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. The N(3)-S(3) bond length is 1.56 Å. The N(3)-S(4) bond length is 1.60 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one B(1), one S(1), and one S(4) atom. The N(4)-S(1) bond length is 1.67 Å. The N(4)-S(4) bond length is 1.66 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(3) and one N(4) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom.