ZrRhSb is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Sb(1) atoms. Rh(1) is bonded to four equivalent Zr(1) atoms to form distorted RhZr4 tetrahedra that share corners with four equivalent Sb(1)Zr4 tetrahedra, corners with twelve equivalent Rh(1)Zr4 tetrahedra, and edges with six equivalent Sb(1)Zr4 tetrahedra. Sb(1) is bonded to four equivalent Zr(1) atoms to form distorted SbZr4 tetrahedra that share corners with four equivalent Rh(1)Zr4 tetrahedra, corners with twelve equivalent Sb(1)Zr4 tetrahedra, and edges with six equivalent Rh(1)Zr4 tetrahedra.
ZrRhSb is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Sb(1) atoms. All Zr(1)-Rh(1) bond lengths are 2.82 Å. All Zr(1)-Sb(1) bond lengths are 2.82 Å. Rh(1) is bonded to four equivalent Zr(1) atoms to form distorted RhZr4 tetrahedra that share corners with four equivalent Sb(1)Zr4 tetrahedra, corners with twelve equivalent Rh(1)Zr4 tetrahedra, and edges with six equivalent Sb(1)Zr4 tetrahedra. Sb(1) is bonded to four equivalent Zr(1) atoms to form distorted SbZr4 tetrahedra that share corners with four equivalent Rh(1)Zr4 tetrahedra, corners with twelve equivalent Sb(1)Zr4 tetrahedra, and edges with six equivalent Rh(1)Zr4 tetrahedra.