C2NS2Cl3 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four C2NS2Cl3 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one S(2), and one Cl(3) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one Cl(1) atom. N(1) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one C(1), one S(1), and one Cl(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(2) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one S(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom.
C2NS2Cl3 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four C2NS2Cl3 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one S(2), and one Cl(3) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-S(2) bond length is 1.70 Å. The C(1)-Cl(3) bond length is 1.69 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one Cl(1) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-Cl(1) bond length is 1.71 Å. N(1) is bonded in a bent 120 degrees geometry to one C(2) and one S(1) atom. The N(1)-S(1) bond length is 1.61 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. The S(1)-S(2) bond length is 2.05 Å. In the second S site, S(2) is bonded in a 3-coordinate geometry to one C(1), one S(1), and one Cl(2) atom. The S(2)-Cl(2) bond length is 2.82 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(2) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one S(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(1) atom.