Ag5Pb2O6 crystallizes in the trigonal P31m space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. Pb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing PbO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Ag(3), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra.
Ag5Pb2O6 crystallizes in the trigonal P31m space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. The Ag(1)-O(1) bond length is 2.15 Å. The Ag(1)-O(2) bond length is 2.15 Å. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All Ag(2)-O(1) bond lengths are 2.33 Å. In the third Ag site, Ag(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. All Ag(3)-O(2) bond lengths are 2.36 Å. Pb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing PbO6 octahedra. All Pb(1)-O(1) bond lengths are 2.28 Å. All Pb(1)-O(2) bond lengths are 2.28 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Ag(3), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra.