AsF6SOClF2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four SOClF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(11), one F(3), one F(5), one F(7), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In each SOClF2 cluster, S(1) is bonded in a distorted tetrahedral geometry to one O(1), one Cl(1), one F(14), and one F(16) atom. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent F sites. In the first F site, F(14) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(16) is bonded in a single-bond geometry to one S(1) atom.
AsF6SOClF2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four SOClF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(11), one F(3), one F(5), one F(7), and one F(9) atom. The As(1)-F(1) bond length is 1.77 Å. The As(1)-F(11) bond length is 1.77 Å. The As(1)-F(3) bond length is 1.80 Å. The As(1)-F(5) bond length is 1.78 Å. The As(1)-F(7) bond length is 1.77 Å. The As(1)-F(9) bond length is 1.78 Å. There are six inequivalent F sites. In the first F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In each SOClF2 cluster, S(1) is bonded in a distorted tetrahedral geometry to one O(1), one Cl(1), one F(14), and one F(16) atom. The S(1)-O(1) bond length is 1.40 Å. The S(1)-Cl(1) bond length is 1.91 Å. The S(1)-F(14) bond length is 1.53 Å. The S(1)-F(16) bond length is 1.53 Å. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent F sites. In the first F site, F(14) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(16) is bonded in a single-bond geometry to one S(1) atom.