CsSO4 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 12-coordinate geometry to three equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent O(4) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom.
CsSO4 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 12-coordinate geometry to three equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent O(4) atoms. There are a spread of Cs(1)-O(1) bond distances ranging from 3.17-3.66 Å. There are a spread of Cs(1)-O(2) bond distances ranging from 3.21-3.64 Å. There are a spread of Cs(1)-O(3) bond distances ranging from 3.19-3.32 Å. There are a spread of Cs(1)-O(4) bond distances ranging from 3.15-3.66 Å. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.50 Å. The S(1)-O(2) bond length is 1.50 Å. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(4) bond length is 1.50 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom.