TiMn3Te2(PO4)6 crystallizes in the trigonal R3 space group. Ti(1) is bonded to three equivalent O(4) and three equivalent O(6) atoms to form TiO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(5) atoms. In the second Mn site, Mn(2) is bonded to three equivalent O(1) and three equivalent O(3) atoms to form distorted MnO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form distorted MnO6 pentagonal pyramids that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 22-57°. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 34-42°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(7) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one P(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mn(2), one P(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(3), one P(2), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(1) atom.
TiMn3Te2(PO4)6 crystallizes in the trigonal R3 space group. Ti(1) is bonded to three equivalent O(4) and three equivalent O(6) atoms to form TiO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. All Ti(1)-O(4) bond lengths are 1.97 Å. All Ti(1)-O(6) bond lengths are 2.00 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(5) atoms. All Mn(1)-O(2) bond lengths are 2.35 Å. All Mn(1)-O(5) bond lengths are 2.00 Å. In the second Mn site, Mn(2) is bonded to three equivalent O(1) and three equivalent O(3) atoms to form distorted MnO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. All Mn(2)-O(1) bond lengths are 2.15 Å. All Mn(2)-O(3) bond lengths are 2.37 Å. In the third Mn site, Mn(3) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form distorted MnO6 pentagonal pyramids that share corners with three equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. All Mn(3)-O(7) bond lengths are 2.28 Å. All Mn(3)-O(8) bond lengths are 2.04 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 22-57°. The P(1)-O(2) bond length is 1.66 Å. The P(1)-O(3) bond length is 1.54 Å. The P(1)-O(4) bond length is 1.55 Å. The P(1)-O(8) bond length is 1.50 Å. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Mn(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 34-42°. The P(2)-O(1) bond length is 1.51 Å. The P(2)-O(5) bond length is 1.50 Å. The P(2)-O(6) bond length is 1.58 Å. The P(2)-O(7) bond length is 1.63 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. All Te(1)-O(2) bond lengths are 2.00 Å. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to three equivalent O(3) and three equivalent O(7) atoms. All Te(2)-O(3) bond lengths are 2.43 Å. All Te(2)-O(7) bond lengths are 2.07 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one P(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mn(2), one P(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(3), one P(2), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(1) atom.