PdN4H12ZnH4(C2O5)2(H2O)2 is Indium-derived structured and crystallizes in the orthorhombic I222 space group. The structure is zero-dimensional and consists of four water molecules, two PdN4H12 clusters, and two ZnH4(C2O5)2 clusters. In each PdN4H12 cluster, Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each ZnH4(C2O5)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. H(4) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1) and two equivalent H(4) atoms. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom.
PdN4H12ZnH4(C2O5)2(H2O)2 is Indium-derived structured and crystallizes in the orthorhombic I222 space group. The structure is zero-dimensional and consists of four water molecules, two PdN4H12 clusters, and two ZnH4(C2O5)2 clusters. In each PdN4H12 cluster, Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Pd(1)-N(1) bond lengths are 2.07 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each ZnH4(C2O5)2 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent O(3) and four equivalent O(1) atoms. Both Zn(1)-O(3) bond lengths are 2.15 Å. All Zn(1)-O(1) bond lengths are 2.11 Å. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.25 Å. H(4) is bonded in a single-bond geometry to one O(3) atom. The H(4)-O(3) bond length is 0.99 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one C(1) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(1) and two equivalent H(4) atoms. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom.