CaLa2BiO6 is Corundum-derived structured and crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 39°. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 39°. O(1) is bonded to one Ca(1), two equivalent La(1), and one Bi(1) atom to form a mixture of corner and edge-sharing OCaLa2Bi trigonal pyramids.
CaLa2BiO6 is Corundum-derived structured and crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Ca(1)-O(1) bond lengths are 2.37 Å. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.36 Å) and three longer (2.60 Å) La(1)-O(1) bond lengths. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Bi(1)-O(1) bond lengths are 2.28 Å. O(1) is bonded to one Ca(1), two equivalent La(1), and one Bi(1) atom to form a mixture of corner and edge-sharing OCaLa2Bi trigonal pyramids.