V3O5F is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(5), two equivalent O(3), and one F(1) atom to form VO5F octahedra that share corners with four equivalent V(4)O5F octahedra, corners with four equivalent V(3)O6 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the third V site, V(3) is bonded to one O(1), one O(5), and four equivalent O(3) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the fourth V site, V(4) is bonded to one O(2), two equivalent O(3), two equivalent O(4), and one F(1) atom to form VO5F octahedra that share corners with four equivalent V(2)O4F2 octahedra, corners with four equivalent V(1)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. F(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(4) atom.
V3O5F is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(5), two equivalent O(3), and one F(1) atom to form VO5F octahedra that share corners with four equivalent V(4)O5F octahedra, corners with four equivalent V(3)O6 octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 43-54°. The V(1)-O(1) bond length is 1.86 Å. The V(1)-O(2) bond length is 1.96 Å. The V(1)-O(5) bond length is 1.92 Å. Both V(1)-O(3) bond lengths are 1.90 Å. The V(1)-F(1) bond length is 2.08 Å. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. Both V(2)-O(2) bond lengths are 1.88 Å. Both V(2)-O(4) bond lengths are 1.91 Å. Both V(2)-F(1) bond lengths are 2.05 Å. In the third V site, V(3) is bonded to one O(1), one O(5), and four equivalent O(3) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. The V(3)-O(1) bond length is 1.99 Å. The V(3)-O(5) bond length is 1.91 Å. All V(3)-O(3) bond lengths are 1.96 Å. In the fourth V site, V(4) is bonded to one O(2), two equivalent O(3), two equivalent O(4), and one F(1) atom to form VO5F octahedra that share corners with four equivalent V(2)O4F2 octahedra, corners with four equivalent V(1)O5F octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. The V(4)-O(2) bond length is 1.85 Å. Both V(4)-O(3) bond lengths are 1.90 Å. Both V(4)-O(4) bond lengths are 1.96 Å. The V(4)-F(1) bond length is 2.14 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. F(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(4) atom.