NiO4NiCl4NiO4ClO2ClO2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-44-7 molecule, one hydroxy hypochlorite molecule, one NiCl4 cluster, one NiO4 cluster, and one NiO4Cl cluster. In the NiCl4 cluster, Ni(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ni(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Ni(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Ni(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Ni(1) atom. In the NiO4 cluster, Ni(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(6) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one O(4) atom. In the second O site, O(4) is bonded in a single-bond geometry to one O(3) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Ni(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Ni(2) atom. In the NiO4Cl cluster, Ni(3) is bonded in a T-shaped geometry to one O(10), one O(2), and one O(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(3) and one O(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Ni(3) atom. In the fourth O site, O(10) is bonded in a bent 120 degrees geometry to one Ni(3) and one Cl(2) atom. Cl(2) is bonded in a single-bond geometry to one O(10) atom.
NiO4NiCl4NiO4ClO2ClO2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-44-7 molecule, one hydroxy hypochlorite molecule, one NiCl4 cluster, one NiO4 cluster, and one NiO4Cl cluster. In the NiCl4 cluster, Ni(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. The Ni(1)-Cl(3) bond length is 2.19 Å. The Ni(1)-Cl(4) bond length is 2.16 Å. The Ni(1)-Cl(5) bond length is 2.16 Å. The Ni(1)-Cl(6) bond length is 2.16 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ni(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Ni(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Ni(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Ni(1) atom. In the NiO4 cluster, Ni(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(6) atom. The Ni(2)-O(3) bond length is 1.95 Å. The Ni(2)-O(5) bond length is 1.60 Å. The Ni(2)-O(6) bond length is 1.60 Å. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one O(4) atom. The O(3)-O(4) bond length is 1.25 Å. In the second O site, O(4) is bonded in a single-bond geometry to one O(3) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Ni(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Ni(2) atom. In the NiO4Cl cluster, Ni(3) is bonded in a T-shaped geometry to one O(10), one O(2), and one O(9) atom. The Ni(3)-O(10) bond length is 1.81 Å. The Ni(3)-O(2) bond length is 2.04 Å. The Ni(3)-O(9) bond length is 1.76 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(2) atom. The O(1)-O(2) bond length is 1.24 Å. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(3) and one O(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Ni(3) atom. In the fourth O site, O(10) is bonded in a bent 120 degrees geometry to one Ni(3) and one Cl(2) atom. The O(10)-Cl(2) bond length is 1.62 Å. Cl(2) is bonded in a single-bond geometry to one O(10) atom.