AgCN2H3 crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four AgCN2H3 clusters. Ag(1) is bonded in a linear geometry to one C(1) and one N(2) atom. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(2), and two equivalent H(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom.
AgCN2H3 crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four AgCN2H3 clusters. Ag(1) is bonded in a linear geometry to one C(1) and one N(2) atom. The Ag(1)-C(1) bond length is 2.03 Å. The Ag(1)-N(2) bond length is 2.14 Å. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(2), and two equivalent H(1) atoms. The N(2)-H(2) bond length is 1.03 Å. Both N(2)-H(1) bond lengths are 1.02 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom.