BaPtC4H8(NO)4 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent O(2), and four equivalent O(1) atoms. Pt(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ba(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Ba(1) and one C(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Ba(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ba(1), one H(3), and one H(4) atom.
BaPtC4H8(NO)4 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent O(2), and four equivalent O(1) atoms. Both Ba(1)-N(1) bond lengths are 3.05 Å. Both Ba(1)-N(2) bond lengths are 2.95 Å. Both Ba(1)-O(2) bond lengths are 2.89 Å. There are two shorter (2.87 Å) and two longer (2.93 Å) Ba(1)-O(1) bond lengths. Pt(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. Both Pt(1)-C(1) bond lengths are 1.99 Å. Both Pt(1)-C(2) bond lengths are 1.99 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. The C(2)-N(2) bond length is 1.18 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ba(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Ba(1) and one C(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.98 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Ba(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ba(1), one H(3), and one H(4) atom.