AuI4InI4N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms, four AuI4 clusters, and four InI4 clusters. In each AuI4 cluster, Au(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent I(1) and two equivalent I(2) atoms. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted single-bond geometry to one Au(1) atom. In the second I site, I(2) is bonded in a distorted single-bond geometry to one Au(1) atom. In each InI4 cluster, In(1) is bonded in a tetrahedral geometry to one I(3), one I(4), and two equivalent I(5) atoms. There are three inequivalent I sites. In the first I site, I(3) is bonded in a single-bond geometry to one In(1) atom. In the second I site, I(5) is bonded in a single-bond geometry to one In(1) atom. In the third I site, I(4) is bonded in a single-bond geometry to one In(1) atom.
AuI4InI4N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms, four AuI4 clusters, and four InI4 clusters. In each AuI4 cluster, Au(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent I(1) and two equivalent I(2) atoms. Both Au(1)-I(1) bond lengths are 2.69 Å. Both Au(1)-I(2) bond lengths are 2.70 Å. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted single-bond geometry to one Au(1) atom. In the second I site, I(2) is bonded in a distorted single-bond geometry to one Au(1) atom. In each InI4 cluster, In(1) is bonded in a tetrahedral geometry to one I(3), one I(4), and two equivalent I(5) atoms. The In(1)-I(3) bond length is 2.72 Å. The In(1)-I(4) bond length is 2.71 Å. Both In(1)-I(5) bond lengths are 2.83 Å. There are three inequivalent I sites. In the first I site, I(3) is bonded in a single-bond geometry to one In(1) atom. In the second I site, I(5) is bonded in a single-bond geometry to one In(1) atom. In the third I site, I(4) is bonded in a single-bond geometry to one In(1) atom.