Ti2MnZnO6 is Ilmenite-derived structured and crystallizes in the trigonal R3 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted TiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with six equivalent Zn(1)O6 pentagonal pyramids, edges with three equivalent Ti(2)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. In the second Ti site, Ti(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted TiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with three equivalent Zn(1)O6 pentagonal pyramids, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Zn(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 45-54°. Mn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted MnO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra, corners with six equivalent Ti(2)O6 octahedra, edges with three equivalent Zn(1)O6 pentagonal pyramids, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. Zn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted ZnO6 pentagonal pyramids that share corners with three equivalent Ti(2)O6 octahedra, corners with six equivalent Ti(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ti(1), one Ti(2), one Mn(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OTi2MnZn trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Ti(1), one Ti(2), one Mn(1), and one Zn(1) atom.
Ti2MnZnO6 is Ilmenite-derived structured and crystallizes in the trigonal R3 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted TiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with six equivalent Zn(1)O6 pentagonal pyramids, edges with three equivalent Ti(2)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. All Ti(1)-O(1) bond lengths are 2.13 Å. All Ti(1)-O(2) bond lengths are 1.88 Å. In the second Ti site, Ti(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted TiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with three equivalent Zn(1)O6 pentagonal pyramids, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Zn(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 45-54°. All Ti(2)-O(1) bond lengths are 1.90 Å. All Ti(2)-O(2) bond lengths are 2.10 Å. Mn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted MnO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra, corners with six equivalent Ti(2)O6 octahedra, edges with three equivalent Zn(1)O6 pentagonal pyramids, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. All Mn(1)-O(1) bond lengths are 2.28 Å. All Mn(1)-O(2) bond lengths are 2.12 Å. Zn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted ZnO6 pentagonal pyramids that share corners with three equivalent Ti(2)O6 octahedra, corners with six equivalent Ti(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. All Zn(1)-O(1) bond lengths are 2.05 Å. All Zn(1)-O(2) bond lengths are 2.29 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ti(1), one Ti(2), one Mn(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OTi2MnZn trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Ti(1), one Ti(2), one Mn(1), and one Zn(1) atom.