Cu3Sb4(OF)6 crystallizes in the cubic I-43m space group. Cu(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form corner-sharing CuO2F4 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded in a distorted T-shaped geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent Sb(1) atoms. F(1) is bonded in a linear geometry to two equivalent Cu(1) atoms.
Cu3Sb4(OF)6 crystallizes in the cubic I-43m space group. Cu(1) is bonded to two equivalent O(1) and four equivalent F(1) atoms to form corner-sharing CuO2F4 octahedra. The corner-sharing octahedra are not tilted. Both Cu(1)-O(1) bond lengths are 2.01 Å. All Cu(1)-F(1) bond lengths are 2.04 Å. Sb(1) is bonded in a distorted T-shaped geometry to three equivalent O(1) atoms. All Sb(1)-O(1) bond lengths are 2.03 Å. O(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent Sb(1) atoms. F(1) is bonded in a linear geometry to two equivalent Cu(1) atoms.