TmPdGe crystallizes in the orthorhombic Imm2 space group. There are four inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 12-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), two equivalent Ge(3), and four equivalent Ge(1) atoms. In the second Tm site, Tm(2) is bonded in a 12-coordinate geometry to one Pd(1), two equivalent Pd(3), three equivalent Pd(2), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. In the third Tm site, Tm(3) is bonded in a 12-coordinate geometry to two equivalent Pd(1), four equivalent Pd(3), two equivalent Ge(1), and four equivalent Ge(3) atoms. In the fourth Tm site, Tm(4) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(2), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to one Tm(2), one Tm(3), two equivalent Tm(1), two equivalent Tm(4), one Pd(1), one Ge(1), and two equivalent Ge(3) atoms. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to three equivalent Tm(2), three equivalent Tm(4), one Ge(1), and three equivalent Ge(2) atoms. In the third Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Tm(1), one Tm(4), two equivalent Tm(2), two equivalent Tm(3), one Ge(2), one Ge(3), and two equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Tm(2), one Tm(3), two equivalent Tm(1), two equivalent Tm(4), one Pd(1), one Pd(2), and two equivalent Pd(3) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Tm(2), three equivalent Tm(4), one Pd(3), and three equivalent Pd(2) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Tm(1), one Tm(4), two equivalent Tm(2), two equivalent Tm(3), one Pd(3), two equivalent Pd(1), and one Ge(3) atom.
TmPdGe crystallizes in the orthorhombic Imm2 space group. There are four inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 12-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), two equivalent Ge(3), and four equivalent Ge(1) atoms. Both Tm(1)-Pd(3) bond lengths are 3.10 Å. All Tm(1)-Pd(1) bond lengths are 3.08 Å. Both Tm(1)-Ge(3) bond lengths are 3.18 Å. All Tm(1)-Ge(1) bond lengths are 3.03 Å. In the second Tm site, Tm(2) is bonded in a 12-coordinate geometry to one Pd(1), two equivalent Pd(3), three equivalent Pd(2), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. The Tm(2)-Pd(1) bond length is 2.92 Å. Both Tm(2)-Pd(3) bond lengths are 2.96 Å. There is one shorter (3.07 Å) and two longer (3.17 Å) Tm(2)-Pd(2) bond lengths. The Tm(2)-Ge(1) bond length is 3.25 Å. Both Tm(2)-Ge(3) bond lengths are 3.14 Å. There are two shorter (2.99 Å) and one longer (3.04 Å) Tm(2)-Ge(2) bond length. In the third Tm site, Tm(3) is bonded in a 12-coordinate geometry to two equivalent Pd(1), four equivalent Pd(3), two equivalent Ge(1), and four equivalent Ge(3) atoms. Both Tm(3)-Pd(1) bond lengths are 3.18 Å. All Tm(3)-Pd(3) bond lengths are 3.20 Å. Both Tm(3)-Ge(1) bond lengths are 2.94 Å. All Tm(3)-Ge(3) bond lengths are 2.97 Å. In the fourth Tm site, Tm(4) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(2), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. The Tm(4)-Pd(3) bond length is 3.06 Å. Both Tm(4)-Pd(1) bond lengths are 3.09 Å. There are two shorter (3.00 Å) and one longer (3.03 Å) Tm(4)-Pd(2) bond length. The Tm(4)-Ge(3) bond length is 3.12 Å. Both Tm(4)-Ge(1) bond lengths are 3.03 Å. There are two shorter (3.07 Å) and one longer (3.22 Å) Tm(4)-Ge(2) bond length. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to one Tm(2), one Tm(3), two equivalent Tm(1), two equivalent Tm(4), one Pd(1), one Ge(1), and two equivalent Ge(3) atoms. The Pd(1)-Pd(1) bond length is 2.99 Å. The Pd(1)-Ge(1) bond length is 2.54 Å. Both Pd(1)-Ge(3) bond lengths are 2.52 Å. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to three equivalent Tm(2), three equivalent Tm(4), one Ge(1), and three equivalent Ge(2) atoms. The Pd(2)-Ge(1) bond length is 2.87 Å. There are two shorter (2.53 Å) and one longer (2.56 Å) Pd(2)-Ge(2) bond length. In the third Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Tm(1), one Tm(4), two equivalent Tm(2), two equivalent Tm(3), one Ge(2), one Ge(3), and two equivalent Ge(1) atoms. The Pd(3)-Ge(2) bond length is 2.72 Å. The Pd(3)-Ge(3) bond length is 2.59 Å. Both Pd(3)-Ge(1) bond lengths are 2.54 Å. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Tm(2), one Tm(3), two equivalent Tm(1), two equivalent Tm(4), one Pd(1), one Pd(2), and two equivalent Pd(3) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Tm(2), three equivalent Tm(4), one Pd(3), and three equivalent Pd(2) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Tm(1), one Tm(4), two equivalent Tm(2), two equivalent Tm(3), one Pd(3), two equivalent Pd(1), and one Ge(3) atom. The Ge(3)-Ge(3) bond length is 2.69 Å.