Zr2Ni2In crystallizes in the tetragonal P4_2/mnm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. In the second Zr site, Zr(2) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. Ni(1) is bonded in a 9-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), one Ni(1), and two equivalent In(1) atoms. In(1) is bonded in a 14-coordinate geometry to four equivalent Zr(1), four equivalent Zr(2), four equivalent Ni(1), and two equivalent In(1) atoms.
Zr2Ni2In crystallizes in the tetragonal P4_2/mnm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. There are two shorter (2.68 Å) and four longer (2.76 Å) Zr(1)-Ni(1) bond lengths. All Zr(1)-In(1) bond lengths are 3.19 Å. In the second Zr site, Zr(2) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. There are four shorter (2.70 Å) and two longer (2.71 Å) Zr(2)-Ni(1) bond lengths. All Zr(2)-In(1) bond lengths are 3.14 Å. Ni(1) is bonded in a 9-coordinate geometry to three equivalent Zr(1), three equivalent Zr(2), one Ni(1), and two equivalent In(1) atoms. The Ni(1)-Ni(1) bond length is 2.55 Å. Both Ni(1)-In(1) bond lengths are 2.87 Å. In(1) is bonded in a 14-coordinate geometry to four equivalent Zr(1), four equivalent Zr(2), four equivalent Ni(1), and two equivalent In(1) atoms. Both In(1)-In(1) bond lengths are 3.34 Å.