Li3Mn(SbO3)4 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. In the second Sb site, Sb(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 37-43°. In the third Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. In the fourth Sb site, Sb(4) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 37-43°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(3), one Mn(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Sb(1), and one Sb(3) atom to form distorted OLi2Sb2 trigonal pyramids that share  a cornercorner with one O(4)LiMnSb2 trigonal pyramid, corners with two equivalent O(6)Li2Sb2 trigonal pyramids, corners with three equivalent O(5)Li2Sb2 trigonal pyramids, and  an edgeedge with one O(3)Li2Sb2 trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Sb(1), and one Sb(4) atom to form distorted OLi2Sb2 trigonal pyramids that share  a cornercorner with one O(5)Li2Sb2 trigonal pyramid,  a cornercorner with one O(4)LiMnSb2 trigonal pyramid,  an edgeedge with one O(2)Li2Sb2 trigonal pyramid,  an edgeedge with one O(5)Li2Sb2 trigonal pyramid, and  an edgeedge with one O(6)Li2Sb2 trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), one Sb(2), and one Sb(3) atom to form distorted corner-sharing OLiMnSb2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Sb(1), and one Sb(4) atom to form a mixture of distorted edge and corner-sharing OLi2Sb2 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Sb(2), and one Sb(4) atom to form distorted OLi2Sb2 trigonal pyramids that share  a cornercorner with one O(5)Li2Sb2 trigonal pyramid,  a cornercorner with one O(4)LiMnSb2 trigonal pyramid, corners with two equivalent O(2)Li2Sb2 trigonal pyramids,  an edgeedge with one O(3)Li2Sb2 trigonal pyramid, and  an edgeedge with one O(5)Li2Sb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Li(3), one Mn(1), one Sb(2), and one Sb(4) atom. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Li(2), one Mn(1), one Sb(1), and one Sb(4) atom. In the ninth O site, O(9) is bonded in a distorted see-saw-like geometry to one Li(2), one Mn(1), one Sb(2), and one Sb(3) atom. In the tenth O site, O(10) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(2), one Sb(1), and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a distorted see-saw-like geometry to one Li(3), one Mn(1), one Sb(1), and one Sb(3) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one Sb(2), and one Sb(3) atom.
Li3Mn(SbO3)4 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. The Li(1)-O(10) bond length is 2.05 Å. The Li(1)-O(12) bond length is 2.07 Å. The Li(1)-O(2) bond length is 2.04 Å. The Li(1)-O(3) bond length is 2.37 Å. The Li(1)-O(5) bond length is 2.37 Å. The Li(1)-O(6) bond length is 2.38 Å. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. The Li(2)-O(10) bond length is 2.30 Å. The Li(2)-O(2) bond length is 2.32 Å. The Li(2)-O(5) bond length is 2.05 Å. The Li(2)-O(6) bond length is 2.05 Å. The Li(2)-O(8) bond length is 2.30 Å. The Li(2)-O(9) bond length is 2.08 Å. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. The Li(3)-O(1) bond length is 2.11 Å. The Li(3)-O(11) bond length is 2.10 Å. The Li(3)-O(12) bond length is 2.35 Å. The Li(3)-O(3) bond length is 2.07 Å. The Li(3)-O(4) bond length is 2.34 Å. The Li(3)-O(7) bond length is 2.32 Å. Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. The Mn(1)-O(1) bond length is 2.33 Å. The Mn(1)-O(11) bond length is 2.32 Å. The Mn(1)-O(4) bond length is 2.11 Å. The Mn(1)-O(7) bond length is 2.11 Å. The Mn(1)-O(8) bond length is 2.09 Å. The Mn(1)-O(9) bond length is 2.35 Å. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. The Sb(1)-O(10) bond length is 2.08 Å. The Sb(1)-O(11) bond length is 2.05 Å. The Sb(1)-O(2) bond length is 2.05 Å. The Sb(1)-O(3) bond length is 2.02 Å. The Sb(1)-O(5) bond length is 2.01 Å. The Sb(1)-O(8) bond length is 2.10 Å. In the second Sb site, Sb(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 37-43°. The Sb(2)-O(1) bond length is 2.03 Å. The Sb(2)-O(12) bond length is 2.06 Å. The Sb(2)-O(4) bond length is 2.08 Å. The Sb(2)-O(6) bond length is 2.00 Å. The Sb(2)-O(7) bond length is 2.13 Å. The Sb(2)-O(9) bond length is 2.02 Å. In the third Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 38-42°. The Sb(3)-O(1) bond length is 2.10 Å. The Sb(3)-O(11) bond length is 2.12 Å. The Sb(3)-O(12) bond length is 2.01 Å. The Sb(3)-O(2) bond length is 2.00 Å. The Sb(3)-O(4) bond length is 2.02 Å. The Sb(3)-O(9) bond length is 2.08 Å. In the fourth Sb site, Sb(4) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 37-43°. The Sb(4)-O(10) bond length is 2.02 Å. The Sb(4)-O(3) bond length is 2.06 Å. The Sb(4)-O(5) bond length is 2.05 Å. The Sb(4)-O(6) bond length is 2.04 Å. The Sb(4)-O(7) bond length is 2.05 Å. The Sb(4)-O(8) bond length is 2.03 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(3), one Mn(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Sb(1), and one Sb(3) atom to form distorted OLi2Sb2 trigonal pyramids that share  a cornercorner with one O(4)LiMnSb2 trigonal pyramid, corners with two equivalent O(6)Li2Sb2 trigonal pyramids, corners with three equivalent O(5)Li2Sb2 trigonal pyramids, and  an edgeedge with one O(3)Li2Sb2 trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Sb(1), and one Sb(4) atom to form distorted OLi2Sb2 trigonal pyramids that share  a cornercorner with one O(5)Li2Sb2 trigonal pyramid,  a cornercorner with one O(4)LiMnSb2 trigonal pyramid,  an edgeedge with one O(2)Li2Sb2 trigonal pyramid,  an edgeedge with one O(5)Li2Sb2 trigonal pyramid, and  an edgeedge with one O(6)Li2Sb2 trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), one Sb(2), and one Sb(3) atom to form distorted corner-sharing OLiMnSb2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Sb(1), and one Sb(4) atom to form a mixture of distorted edge and corner-sharing OLi2Sb2 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Sb(2), and one Sb(4) atom to form distorted OLi2Sb2 trigonal pyramids that share  a cornercorner with one O(5)Li2Sb2 trigonal pyramid,  a cornercorner with one O(4)LiMnSb2 trigonal pyramid, corners with two equivalent O(2)Li2Sb2 trigonal pyramids,  an edgeedge with one O(3)Li2Sb2 trigonal pyramid, and  an edgeedge with one O(5)Li2Sb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a distorted see-saw-like geometry to one Li(3), one Mn(1), one Sb(2), and one Sb(4) atom. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Li(2), one Mn(1), one Sb(1), and one Sb(4) atom. In the ninth O site, O(9) is bonded in a distorted see-saw-like geometry to one Li(2), one Mn(1), one Sb(2), and one Sb(3) atom. In the tenth O site, O(10) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(2), one Sb(1), and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a distorted see-saw-like geometry to one Li(3), one Mn(1), one Sb(1), and one Sb(3) atom. In the twelfth O site, O(12) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one Sb(2), and one Sb(3) atom.