MgTi2 crystallizes in the orthorhombic Cmcm space group. Mg(1) is bonded to two equivalent Mg(1) and ten equivalent Ti(1) atoms to form a mixture of distorted edge and face-sharing MgMg2Ti10 cuboctahedra. Ti(1) is bonded in a 11-coordinate geometry to five equivalent Mg(1) and six equivalent Ti(1) atoms.
MgTi2 crystallizes in the orthorhombic Cmcm space group. Mg(1) is bonded to two equivalent Mg(1) and ten equivalent Ti(1) atoms to form a mixture of distorted edge and face-sharing MgMg2Ti10 cuboctahedra. Both Mg(1)-Mg(1) bond lengths are 3.02 Å. There are a spread of Mg(1)-Ti(1) bond distances ranging from 2.95-3.19 Å. Ti(1) is bonded in a 11-coordinate geometry to five equivalent Mg(1) and six equivalent Ti(1) atoms. There are a spread of Ti(1)-Ti(1) bond distances ranging from 2.81-2.97 Å.