CeVO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Ce(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OCe3V2 trigonal bipyramids.
CeVO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. There are two shorter (2.43 Å) and four longer (2.45 Å) Ce(1)-O(1) bond lengths. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 2.19 Å. O(1) is bonded to three equivalent Ce(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OCe3V2 trigonal bipyramids.