TlInF6 crystallizes in the trigonal R-3 space group. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent In(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. F(1) is bonded in a bent 150 degrees geometry to one Tl(1) and one In(1) atom.
TlInF6 crystallizes in the trigonal R-3 space group. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent In(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Tl(1)-F(1) bond lengths are 2.17 Å. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. All In(1)-F(1) bond lengths are 2.08 Å. F(1) is bonded in a bent 150 degrees geometry to one Tl(1) and one In(1) atom.