LiVOF3 crystallizes in the orthorhombic Pca2_1 space group. Li(1) is bonded to one O(1), one F(2), one F(3), and two equivalent F(1) atoms to form distorted corner-sharing LiOF4 square pyramids. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), and two equivalent F(3) atoms. O(1) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms.
LiVOF3 crystallizes in the orthorhombic Pca2_1 space group. Li(1) is bonded to one O(1), one F(2), one F(3), and two equivalent F(1) atoms to form distorted corner-sharing LiOF4 square pyramids. The Li(1)-O(1) bond length is 2.11 Å. The Li(1)-F(2) bond length is 1.90 Å. The Li(1)-F(3) bond length is 2.39 Å. There is one shorter (2.01 Å) and one longer (2.10 Å) Li(1)-F(1) bond length. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), and two equivalent F(3) atoms. The V(1)-O(1) bond length is 1.65 Å. The V(1)-F(1) bond length is 1.92 Å. The V(1)-F(2) bond length is 1.88 Å. There is one shorter (1.99 Å) and one longer (2.01 Å) V(1)-F(3) bond length. O(1) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms.