ZrGeO2 crystallizes in the tetragonal I4_1/amd space group. Zr(1) is bonded to six equivalent O(1) atoms to form distorted edge-sharing ZrO6 octahedra. Ge(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Zr(1) and two equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing OZr3Ge2 trigonal bipyramids.
ZrGeO2 crystallizes in the tetragonal I4_1/amd space group. Zr(1) is bonded to six equivalent O(1) atoms to form distorted edge-sharing ZrO6 octahedra. There are two shorter (2.21 Å) and four longer (2.25 Å) Zr(1)-O(1) bond lengths. Ge(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Ge(1)-O(1) bond lengths are 2.45 Å. O(1) is bonded to three equivalent Zr(1) and two equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing OZr3Ge2 trigonal bipyramids.