(H3Te3OCl13)2SO2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two sulfur dioxide molecules and four H3Te3OCl13 clusters. In each H3Te3OCl13 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one Cl(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one Cl(9) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(10), one Cl(14), one Cl(2), one Cl(3), one Cl(8), and one Cl(9) atom to form edge-sharing TeCl6 octahedra. In the second Te site, Te(3) is bonded to one Cl(13), one Cl(14), two equivalent Cl(1), and two equivalent Cl(8) atoms to form edge-sharing TeCl6 octahedra. O(2) is bonded in a trigonal non-coplanar geometry to one H(2) and two equivalent H(1) atoms. There are eight inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one Te(1), and one Te(3) atom. In the second Cl site, Cl(9) is bonded in a distorted trigonal non-coplanar geometry to one H(2) and two equivalent Te(1) atoms. In the third Cl site, Cl(10) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(13) is bonded in a single-bond geometry to one Te(3) atom. In the fifth Cl site, Cl(14) is bonded in a distorted T-shaped geometry to one Te(3) and two equivalent Te(1) atoms. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Te(3) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(3) is bonded in a single-bond geometry to one Te(1) atom.
(H3Te3OCl13)2SO2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two sulfur dioxide molecules and four H3Te3OCl13 clusters. In each H3Te3OCl13 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one Cl(8) atom. The H(1)-O(2) bond length is 1.02 Å. The H(1)-Cl(8) bond length is 2.06 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one Cl(9) atom. The H(2)-O(2) bond length is 1.02 Å. The H(2)-Cl(9) bond length is 2.08 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(10), one Cl(14), one Cl(2), one Cl(3), one Cl(8), and one Cl(9) atom to form edge-sharing TeCl6 octahedra. The Te(1)-Cl(10) bond length is 2.37 Å. The Te(1)-Cl(14) bond length is 2.98 Å. The Te(1)-Cl(2) bond length is 2.37 Å. The Te(1)-Cl(3) bond length is 2.36 Å. The Te(1)-Cl(8) bond length is 2.94 Å. The Te(1)-Cl(9) bond length is 2.95 Å. In the second Te site, Te(3) is bonded to one Cl(13), one Cl(14), two equivalent Cl(1), and two equivalent Cl(8) atoms to form edge-sharing TeCl6 octahedra. The Te(3)-Cl(13) bond length is 2.36 Å. The Te(3)-Cl(14) bond length is 2.99 Å. Both Te(3)-Cl(1) bond lengths are 2.38 Å. Both Te(3)-Cl(8) bond lengths are 2.94 Å. O(2) is bonded in a trigonal non-coplanar geometry to one H(2) and two equivalent H(1) atoms. There are eight inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one Te(1), and one Te(3) atom. In the second Cl site, Cl(9) is bonded in a distorted trigonal non-coplanar geometry to one H(2) and two equivalent Te(1) atoms. In the third Cl site, Cl(10) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(13) is bonded in a single-bond geometry to one Te(3) atom. In the fifth Cl site, Cl(14) is bonded in a distorted T-shaped geometry to one Te(3) and two equivalent Te(1) atoms. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Te(3) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(3) is bonded in a single-bond geometry to one Te(1) atom.