TaWO6Tl crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a TaWO6 framework. In the TaWO6 framework, Ta(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form TaO6 octahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-40°. W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Ta(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-39°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Ta(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Ta(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ta(1) and one W(1) atom.
TaWO6Tl crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a TaWO6 framework. In the TaWO6 framework, Ta(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form TaO6 octahedra that share corners with two equivalent Ta(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-40°. Both Ta(1)-O(2) bond lengths are 1.98 Å. Both Ta(1)-O(3) bond lengths are 1.98 Å. Both Ta(1)-O(4) bond lengths are 2.01 Å. W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Ta(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-39°. There is one shorter (1.93 Å) and one longer (1.97 Å) W(1)-O(1) bond length. Both W(1)-O(3) bond lengths are 1.94 Å. Both W(1)-O(4) bond lengths are 1.94 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Ta(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Ta(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ta(1) and one W(1) atom.