LiGeN crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. Ge(1) is bonded in a distorted water-like geometry to two equivalent N(1) atoms. N(1) is bonded to three equivalent Li(1) and two equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing NLi3Ge2 trigonal bipyramids.
LiGeN crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. There is one shorter (2.02 Å) and two longer (2.13 Å) Li(1)-N(1) bond lengths. Ge(1) is bonded in a distorted water-like geometry to two equivalent N(1) atoms. Both Ge(1)-N(1) bond lengths are 1.88 Å. N(1) is bonded to three equivalent Li(1) and two equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing NLi3Ge2 trigonal bipyramids.