Ge2C2(SeF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ge2C2(SeF2)3 clusters. Ge(1) is bonded to one C(1) and three equivalent Se(1) atoms to form corner-sharing GeCSe3 tetrahedra. C(1) is bonded in a distorted trigonal non-coplanar geometry to one Ge(1) and three equivalent F(1) atoms. Se(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. F(1) is bonded in a single-bond geometry to one C(1) atom.
Ge2C2(SeF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ge2C2(SeF2)3 clusters. Ge(1) is bonded to one C(1) and three equivalent Se(1) atoms to form corner-sharing GeCSe3 tetrahedra. The Ge(1)-C(1) bond length is 2.06 Å. All Ge(1)-Se(1) bond lengths are 2.38 Å. C(1) is bonded in a distorted trigonal non-coplanar geometry to one Ge(1) and three equivalent F(1) atoms. All C(1)-F(1) bond lengths are 1.36 Å. Se(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. F(1) is bonded in a single-bond geometry to one C(1) atom.