AuTeBr7Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 7726-95-6 molecule and one AuTeBr7 cluster. In the AuTeBr7 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Br(1), one Br(2), one Br(3), and one Br(4) atom. Te(1) is bonded in an octahedral geometry to one Br(1), one Br(2), one Br(3), one Br(5), one Br(6), and one Br(7) atom. There are seven inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one Au(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a water-like geometry to one Au(1) and one Te(1) atom. In the third Br site, Br(3) is bonded in an L-shaped geometry to one Au(1) and one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Au(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Br site, Br(7) is bonded in a single-bond geometry to one Te(1) atom.
AuTeBr7Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one 7726-95-6 molecule and one AuTeBr7 cluster. In the AuTeBr7 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Br(1), one Br(2), one Br(3), and one Br(4) atom. The Au(1)-Br(1) bond length is 2.47 Å. The Au(1)-Br(2) bond length is 2.47 Å. The Au(1)-Br(3) bond length is 2.46 Å. The Au(1)-Br(4) bond length is 2.43 Å. Te(1) is bonded in an octahedral geometry to one Br(1), one Br(2), one Br(3), one Br(5), one Br(6), and one Br(7) atom. The Te(1)-Br(1) bond length is 3.09 Å. The Te(1)-Br(2) bond length is 3.12 Å. The Te(1)-Br(3) bond length is 3.10 Å. The Te(1)-Br(5) bond length is 2.51 Å. The Te(1)-Br(6) bond length is 2.52 Å. The Te(1)-Br(7) bond length is 2.51 Å. There are seven inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one Au(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a water-like geometry to one Au(1) and one Te(1) atom. In the third Br site, Br(3) is bonded in an L-shaped geometry to one Au(1) and one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Au(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Br site, Br(7) is bonded in a single-bond geometry to one Te(1) atom.