PdAg(O3I)3 crystallizes in the triclinic P-1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(4) atoms. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(7) atoms. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(6), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Pd(1), one Ag(1), and one I(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(2) and one I(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one I(1) and one I(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Pd(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Ag(1) and one I(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Pd(2) and one I(3) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Ag(1) and one I(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one I(3) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(3), one O(7), one O(8), and one O(9) atom.
PdAg(O3I)3 crystallizes in the triclinic P-1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(4) atoms. Both Pd(1)-O(1) bond lengths are 2.03 Å. Both Pd(1)-O(4) bond lengths are 2.04 Å. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(7) atoms. Both Pd(2)-O(2) bond lengths are 2.02 Å. Both Pd(2)-O(7) bond lengths are 2.05 Å. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(6), one O(8), and one O(9) atom. The Ag(1)-O(1) bond length is 2.69 Å. The Ag(1)-O(6) bond length is 2.52 Å. The Ag(1)-O(8) bond length is 2.49 Å. The Ag(1)-O(9) bond length is 2.35 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Pd(1), one Ag(1), and one I(1) atom. The O(1)-I(1) bond length is 1.88 Å. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(2) and one I(1) atom. The O(2)-I(1) bond length is 1.89 Å. In the third O site, O(3) is bonded in a distorted single-bond geometry to one I(1) and one I(3) atom. The O(3)-I(1) bond length is 1.80 Å. The O(3)-I(3) bond length is 2.52 Å. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Pd(1) and one I(2) atom. The O(4)-I(2) bond length is 1.92 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(2) atom. The O(5)-I(2) bond length is 1.81 Å. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Ag(1) and one I(2) atom. The O(6)-I(2) bond length is 1.84 Å. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Pd(2) and one I(3) atom. The O(7)-I(3) bond length is 1.89 Å. In the eighth O site, O(8) is bonded in a water-like geometry to one Ag(1) and one I(3) atom. The O(8)-I(3) bond length is 1.84 Å. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one I(3) atom. The O(9)-I(3) bond length is 1.84 Å. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(3), one O(7), one O(8), and one O(9) atom.