K2NaCo(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(1), and two equivalent N(3) atoms. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one K(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(3) atom.
K2NaCo(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(1), and two equivalent N(3) atoms. The K(1)-N(2) bond length is 3.04 Å. There is one shorter (2.95 Å) and one longer (3.09 Å) K(1)-N(1) bond length. There is one shorter (2.88 Å) and one longer (3.27 Å) K(1)-N(3) bond length. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Both Na(1)-N(1) bond lengths are 2.55 Å. Both Na(1)-N(2) bond lengths are 2.52 Å. Both Na(1)-N(3) bond lengths are 2.56 Å. Co(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. Both Co(1)-C(1) bond lengths are 1.87 Å. Both Co(1)-C(2) bond lengths are 1.88 Å. Both Co(1)-C(3) bond lengths are 1.88 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. The C(1)-N(1) bond length is 1.18 Å. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. The C(2)-N(2) bond length is 1.18 Å. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(3) atom. The C(3)-N(3) bond length is 1.18 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one K(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(3) atom.