MgYbTiO3 crystallizes in the tetragonal P4/mmm space group. Mg(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Yb(1) is bonded in a distorted square co-planar geometry to four equivalent O(2) atoms. Ti(1) is bonded in a square co-planar geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to two equivalent Mg(1) and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded to four equivalent Yb(1) and two equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing OYb4Ti2 octahedra. The corner-sharing octahedra are not tilted.
MgYbTiO3 crystallizes in the tetragonal P4/mmm space group. Mg(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Mg(1)-O(1) bond lengths are 1.96 Å. Yb(1) is bonded in a distorted square co-planar geometry to four equivalent O(2) atoms. All Yb(1)-O(2) bond lengths are 2.77 Å. Ti(1) is bonded in a square co-planar geometry to two equivalent O(2) and four equivalent O(1) atoms. Both Ti(1)-O(2) bond lengths are 2.95 Å. All Ti(1)-O(1) bond lengths are 1.96 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to two equivalent Mg(1) and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded to four equivalent Yb(1) and two equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing OYb4Ti2 octahedra. The corner-sharing octahedra are not tilted.