Co(N3O)2CoI2(N3O)2(I)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7553-56-2 molecules, two Co(N3O)2 clusters, and four CoI2(N3O)2 clusters. In each Co(N3O)2 cluster, Co(2) is bonded in a 5-coordinate geometry to one N(6), two equivalent N(3), one O(1), and one O(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one N(3) atom. In the second N site, N(6) is bonded in a distorted linear geometry to one Co(2) and one N(6) atom. In the third N site, N(2) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Co(2) and one N(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In each CoI2(N3O)2 cluster, Co(1) is bonded in a distorted trigonal bipyramidal geometry to one N(8), two equivalent N(5), one O(3), and one O(4) atom. There are four inequivalent N sites. In the first N site, N(5) is bonded in a bent 120 degrees geometry to one Co(1) and one N(7) atom. In the second N site, N(7) is bonded in a single-bond geometry to one N(5) atom. In the third N site, N(8) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the fourth N site, N(1) is bonded in a water-like geometry to one O(3) and one O(4) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. In the second O site, O(4) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one N(8) and one I(3) atom. In the second I site, I(3) is bonded in a single-bond geometry to one I(1) atom.
Co(N3O)2CoI2(N3O)2(I)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7553-56-2 molecules, two Co(N3O)2 clusters, and four CoI2(N3O)2 clusters. In each Co(N3O)2 cluster, Co(2) is bonded in a 5-coordinate geometry to one N(6), two equivalent N(3), one O(1), and one O(2) atom. The Co(2)-N(6) bond length is 1.86 Å. Both Co(2)-N(3) bond lengths are 2.66 Å. The Co(2)-O(1) bond length is 2.08 Å. The Co(2)-O(2) bond length is 2.10 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one N(3) atom. The N(4)-N(3) bond length is 1.12 Å. In the second N site, N(6) is bonded in a distorted linear geometry to one Co(2) and one N(6) atom. The N(6)-N(6) bond length is 1.15 Å. In the third N site, N(2) is bonded in a water-like geometry to one O(1) and one O(2) atom. The N(2)-O(1) bond length is 1.28 Å. The N(2)-O(2) bond length is 1.28 Å. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Co(2) and one N(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Co(2) and one N(2) atom. In each CoI2(N3O)2 cluster, Co(1) is bonded in a distorted trigonal bipyramidal geometry to one N(8), two equivalent N(5), one O(3), and one O(4) atom. The Co(1)-N(8) bond length is 1.77 Å. Both Co(1)-N(5) bond lengths are 2.44 Å. The Co(1)-O(3) bond length is 2.11 Å. The Co(1)-O(4) bond length is 2.06 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a bent 120 degrees geometry to one Co(1) and one N(7) atom. The N(5)-N(7) bond length is 1.12 Å. In the second N site, N(7) is bonded in a single-bond geometry to one N(5) atom. In the third N site, N(8) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. The N(8)-I(1) bond length is 1.94 Å. In the fourth N site, N(1) is bonded in a water-like geometry to one O(3) and one O(4) atom. The N(1)-O(3) bond length is 1.27 Å. The N(1)-O(4) bond length is 1.29 Å. There are two inequivalent O sites. In the first O site, O(3) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. In the second O site, O(4) is bonded in an L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one N(8) and one I(3) atom. The I(1)-I(3) bond length is 2.85 Å. In the second I site, I(3) is bonded in a single-bond geometry to one I(1) atom.