AlNSBr3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AlNSBr3 clusters. Al(1) is bonded in a tetrahedral geometry to one N(1), one Br(1), one Br(2), and one Br(3) atom. N(1) is bonded in a distorted trigonal planar geometry to one Al(1) and two equivalent S(1) atoms. S(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Al(1) atom.
AlNSBr3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AlNSBr3 clusters. Al(1) is bonded in a tetrahedral geometry to one N(1), one Br(1), one Br(2), and one Br(3) atom. The Al(1)-N(1) bond length is 1.96 Å. The Al(1)-Br(1) bond length is 2.30 Å. The Al(1)-Br(2) bond length is 2.33 Å. The Al(1)-Br(3) bond length is 2.27 Å. N(1) is bonded in a distorted trigonal planar geometry to one Al(1) and two equivalent S(1) atoms. There is one shorter (1.66 Å) and one longer (1.68 Å) N(1)-S(1) bond length. S(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Al(1) atom.