(Rb)2CsScBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsScBr6 framework. In the CsScBr6 framework, Cs(1) is bonded to six equivalent Br(1) atoms to form CsBr6 octahedra that share corners with six equivalent Sc(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent Br(1) atoms to form ScBr6 octahedra that share corners with six equivalent Cs(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Cs(1) and one Sc(1) atom.
(Rb)2CsScBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsScBr6 framework. In the CsScBr6 framework, Cs(1) is bonded to six equivalent Br(1) atoms to form CsBr6 octahedra that share corners with six equivalent Sc(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Cs(1)-Br(1) bond lengths are 3.39 Å. Sc(1) is bonded to six equivalent Br(1) atoms to form ScBr6 octahedra that share corners with six equivalent Cs(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-Br(1) bond lengths are 2.66 Å. Br(1) is bonded in a linear geometry to one Cs(1) and one Sc(1) atom.