Sr3CoZnO6 crystallizes in the triclinic P1 space group. There are twelve inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(15), one O(19), one O(23), one O(5), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(14), one O(16), one O(2), one O(20), one O(24), and one O(6) atom. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(15), one O(17), one O(19), one O(21), one O(3), and one O(7) atom. In the fourth Sr site, Sr(4) is bonded in a 8-coordinate geometry to one O(12), one O(16), one O(18), one O(2), one O(20), one O(22), one O(4), and one O(8) atom. In the fifth Sr site, Sr(5) is bonded in a 8-coordinate geometry to one O(10), one O(13), one O(17), one O(21), one O(24), one O(3), one O(6), and one O(7) atom. In the sixth Sr site, Sr(6) is bonded in a 8-coordinate geometry to one O(14), one O(18), one O(22), one O(23), one O(4), one O(5), one O(8), and one O(9) atom. In the seventh Sr site, Sr(7) is bonded in a 8-coordinate geometry to one O(13), one O(15), one O(19), one O(23), one O(3), one O(5), one O(7), and one O(9) atom. In the eighth Sr site, Sr(8) is bonded in a 8-coordinate geometry to one O(10), one O(14), one O(16), one O(20), one O(24), one O(4), one O(6), and one O(8) atom. In the ninth Sr site, Sr(9) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(15), one O(18), one O(19), one O(22), one O(5), and one O(9) atom. In the tenth Sr site, Sr(10) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(16), one O(17), one O(2), one O(20), one O(21), and one O(6) atom. In the eleventh Sr site, Sr(11) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(13), one O(17), one O(21), one O(24), one O(3), and one O(7) atom. In the twelfth Sr site, Sr(12) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(18), one O(2), one O(22), one O(23), one O(4), and one O(8) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one O(14), one O(16), one O(18), one O(2), one O(4), and one O(6) atom. In the second Co site, Co(2) is bonded in an octahedral geometry to one O(10), one O(11), one O(20), one O(21), one O(24), and one O(7) atom. In the third Co site, Co(3) is bonded in an octahedral geometry to one O(1), one O(13), one O(15), one O(17), one O(3), and one O(5) atom. In the fourth Co site, Co(4) is bonded in an octahedral geometry to one O(12), one O(19), one O(22), one O(23), one O(8), and one O(9) atom. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(1), one O(19), one O(22), one O(23), one O(3), and one O(5) atom. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(2), one O(20), one O(21), one O(24), one O(4), and one O(6) atom. In the third Zn site, Zn(3) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(15), one O(17), and one O(7) atom. In the fourth Zn site, Zn(4) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(16), one O(18), one O(8), and one O(9) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Sr(11), one Sr(3), one Sr(9), one Co(3), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the second O site, O(2) is bonded to one Sr(10), one Sr(12), one Sr(2), one Sr(4), one Co(1), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the third O site, O(3) is bonded to one Sr(11), one Sr(3), one Sr(5), one Sr(7), one Co(3), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the fourth O site, O(4) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(8), one Co(1), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(6), one Sr(7), one Sr(9), one Co(3), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the sixth O site, O(6) is bonded to one Sr(10), one Sr(2), one Sr(5), one Sr(8), one Co(1), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the seventh O site, O(7) is bonded to one Sr(11), one Sr(3), one Sr(5), one Sr(7), one Co(2), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the eighth O site, O(8) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(8), one Co(4), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(6), one Sr(7), one Sr(9), one Co(4), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the tenth O site, O(10) is bonded to one Sr(10), one Sr(2), one Sr(5), one Sr(8), one Co(2), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the eleventh O site, O(11) is bonded to one Sr(10), one Sr(11), one Sr(2), one Sr(3), one Co(2), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the twelfth O site, O(12) is bonded to one Sr(1), one Sr(12), one Sr(4), one Sr(9), one Co(4), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the thirteenth O site, O(13) is bonded to one Sr(1), one Sr(11), one Sr(5), one Sr(7), one Co(3), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the fourteenth O site, O(14) is bonded to one Sr(12), one Sr(2), one Sr(6), one Sr(8), one Co(1), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the fifteenth O site, O(15) is bonded to one Sr(1), one Sr(3), one Sr(7), one Sr(9), one Co(3), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the sixteenth O site, O(16) is bonded to one Sr(10), one Sr(2), one Sr(4), one Sr(8), one Co(1), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the seventeenth O site, O(17) is bonded to one Sr(10), one Sr(11), one Sr(3), one Sr(5), one Co(3), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the eighteenth O site, O(18) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(9), one Co(1), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the nineteenth O site, O(19) is bonded to one Sr(1), one Sr(3), one Sr(7), one Sr(9), one Co(4), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the twentieth O site, O(20) is bonded to one Sr(10), one Sr(2), one Sr(4), one Sr(8), one Co(2), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the twenty-first O site, O(21) is bonded to one Sr(10), one Sr(11), one Sr(3), one Sr(5), one Co(2), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the twenty-second O site, O(22) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(9), one Co(4), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the twenty-third O site, O(23) is bonded to one Sr(1), one Sr(12), one Sr(6), one Sr(7), one Co(4), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the twenty-fourth O site, O(24) is bonded to one Sr(11), one Sr(2), one Sr(5), one Sr(8), one Co(2), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°.
Sr3CoZnO6 crystallizes in the triclinic P1 space group. There are twelve inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(15), one O(19), one O(23), one O(5), and one O(9) atom. The Sr(1)-O(1) bond length is 2.57 Å. The Sr(1)-O(12) bond length is 2.63 Å. The Sr(1)-O(13) bond length is 2.63 Å. The Sr(1)-O(15) bond length is 2.72 Å. The Sr(1)-O(19) bond length is 2.61 Å. The Sr(1)-O(23) bond length is 2.57 Å. The Sr(1)-O(5) bond length is 2.61 Å. The Sr(1)-O(9) bond length is 2.73 Å. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(14), one O(16), one O(2), one O(20), one O(24), and one O(6) atom. The Sr(2)-O(10) bond length is 2.73 Å. The Sr(2)-O(11) bond length is 2.66 Å. The Sr(2)-O(14) bond length is 2.66 Å. The Sr(2)-O(16) bond length is 2.74 Å. The Sr(2)-O(2) bond length is 2.53 Å. The Sr(2)-O(20) bond length is 2.59 Å. The Sr(2)-O(24) bond length is 2.53 Å. The Sr(2)-O(6) bond length is 2.59 Å. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(15), one O(17), one O(19), one O(21), one O(3), and one O(7) atom. The Sr(3)-O(1) bond length is 2.63 Å. The Sr(3)-O(11) bond length is 2.71 Å. The Sr(3)-O(15) bond length is 2.65 Å. The Sr(3)-O(17) bond length is 2.73 Å. The Sr(3)-O(19) bond length is 2.48 Å. The Sr(3)-O(21) bond length is 2.60 Å. The Sr(3)-O(3) bond length is 2.57 Å. The Sr(3)-O(7) bond length is 2.66 Å. In the fourth Sr site, Sr(4) is bonded in a 8-coordinate geometry to one O(12), one O(16), one O(18), one O(2), one O(20), one O(22), one O(4), and one O(8) atom. The Sr(4)-O(12) bond length is 2.74 Å. The Sr(4)-O(16) bond length is 2.63 Å. The Sr(4)-O(18) bond length is 2.72 Å. The Sr(4)-O(2) bond length is 2.59 Å. The Sr(4)-O(20) bond length is 2.58 Å. The Sr(4)-O(22) bond length is 2.62 Å. The Sr(4)-O(4) bond length is 2.47 Å. The Sr(4)-O(8) bond length is 2.63 Å. In the fifth Sr site, Sr(5) is bonded in a 8-coordinate geometry to one O(10), one O(13), one O(17), one O(21), one O(24), one O(3), one O(6), and one O(7) atom. The Sr(5)-O(10) bond length is 2.63 Å. The Sr(5)-O(13) bond length is 2.74 Å. The Sr(5)-O(17) bond length is 2.62 Å. The Sr(5)-O(21) bond length is 2.47 Å. The Sr(5)-O(24) bond length is 2.59 Å. The Sr(5)-O(3) bond length is 2.62 Å. The Sr(5)-O(6) bond length is 2.58 Å. The Sr(5)-O(7) bond length is 2.72 Å. In the sixth Sr site, Sr(6) is bonded in a 8-coordinate geometry to one O(14), one O(18), one O(22), one O(23), one O(4), one O(5), one O(8), and one O(9) atom. The Sr(6)-O(14) bond length is 2.71 Å. The Sr(6)-O(18) bond length is 2.66 Å. The Sr(6)-O(22) bond length is 2.57 Å. The Sr(6)-O(23) bond length is 2.64 Å. The Sr(6)-O(4) bond length is 2.60 Å. The Sr(6)-O(5) bond length is 2.48 Å. The Sr(6)-O(8) bond length is 2.73 Å. The Sr(6)-O(9) bond length is 2.65 Å. In the seventh Sr site, Sr(7) is bonded in a 8-coordinate geometry to one O(13), one O(15), one O(19), one O(23), one O(3), one O(5), one O(7), and one O(9) atom. The Sr(7)-O(13) bond length is 2.59 Å. The Sr(7)-O(15) bond length is 2.56 Å. The Sr(7)-O(19) bond length is 2.62 Å. The Sr(7)-O(23) bond length is 2.73 Å. The Sr(7)-O(3) bond length is 2.64 Å. The Sr(7)-O(5) bond length is 2.76 Å. The Sr(7)-O(7) bond length is 2.57 Å. The Sr(7)-O(9) bond length is 2.61 Å. In the eighth Sr site, Sr(8) is bonded in a 8-coordinate geometry to one O(10), one O(14), one O(16), one O(20), one O(24), one O(4), one O(6), and one O(8) atom. The Sr(8)-O(10) bond length is 2.61 Å. The Sr(8)-O(14) bond length is 2.63 Å. The Sr(8)-O(16) bond length is 2.48 Å. The Sr(8)-O(20) bond length is 2.66 Å. The Sr(8)-O(24) bond length is 2.73 Å. The Sr(8)-O(4) bond length is 2.64 Å. The Sr(8)-O(6) bond length is 2.70 Å. The Sr(8)-O(8) bond length is 2.49 Å. In the ninth Sr site, Sr(9) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(15), one O(18), one O(19), one O(22), one O(5), and one O(9) atom. The Sr(9)-O(1) bond length is 2.72 Å. The Sr(9)-O(12) bond length is 2.59 Å. The Sr(9)-O(15) bond length is 2.61 Å. The Sr(9)-O(18) bond length is 2.57 Å. The Sr(9)-O(19) bond length is 2.75 Å. The Sr(9)-O(22) bond length is 2.64 Å. The Sr(9)-O(5) bond length is 2.62 Å. The Sr(9)-O(9) bond length is 2.56 Å. In the tenth Sr site, Sr(10) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(16), one O(17), one O(2), one O(20), one O(21), and one O(6) atom. The Sr(10)-O(10) bond length is 2.48 Å. The Sr(10)-O(11) bond length is 2.63 Å. The Sr(10)-O(16) bond length is 2.60 Å. The Sr(10)-O(17) bond length is 2.49 Å. The Sr(10)-O(2) bond length is 2.73 Å. The Sr(10)-O(20) bond length is 2.70 Å. The Sr(10)-O(21) bond length is 2.64 Å. The Sr(10)-O(6) bond length is 2.66 Å. In the eleventh Sr site, Sr(11) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(13), one O(17), one O(21), one O(24), one O(3), and one O(7) atom. The Sr(11)-O(1) bond length is 2.66 Å. The Sr(11)-O(11) bond length is 2.51 Å. The Sr(11)-O(13) bond length is 2.58 Å. The Sr(11)-O(17) bond length is 2.60 Å. The Sr(11)-O(21) bond length is 2.70 Å. The Sr(11)-O(24) bond length is 2.64 Å. The Sr(11)-O(3) bond length is 2.76 Å. The Sr(11)-O(7) bond length is 2.60 Å. In the twelfth Sr site, Sr(12) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(18), one O(2), one O(22), one O(23), one O(4), and one O(8) atom. The Sr(12)-O(12) bond length is 2.58 Å. The Sr(12)-O(14) bond length is 2.52 Å. The Sr(12)-O(18) bond length is 2.60 Å. The Sr(12)-O(2) bond length is 2.64 Å. The Sr(12)-O(22) bond length is 2.76 Å. The Sr(12)-O(23) bond length is 2.66 Å. The Sr(12)-O(4) bond length is 2.70 Å. The Sr(12)-O(8) bond length is 2.60 Å. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one O(14), one O(16), one O(18), one O(2), one O(4), and one O(6) atom. The Co(1)-O(14) bond length is 1.97 Å. The Co(1)-O(16) bond length is 2.02 Å. The Co(1)-O(18) bond length is 1.91 Å. The Co(1)-O(2) bond length is 1.96 Å. The Co(1)-O(4) bond length is 2.05 Å. The Co(1)-O(6) bond length is 1.90 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to one O(10), one O(11), one O(20), one O(21), one O(24), and one O(7) atom. The Co(2)-O(10) bond length is 2.01 Å. The Co(2)-O(11) bond length is 1.98 Å. The Co(2)-O(20) bond length is 1.90 Å. The Co(2)-O(21) bond length is 2.04 Å. The Co(2)-O(24) bond length is 1.98 Å. The Co(2)-O(7) bond length is 1.90 Å. In the third Co site, Co(3) is bonded in an octahedral geometry to one O(1), one O(13), one O(15), one O(17), one O(3), and one O(5) atom. The Co(3)-O(1) bond length is 1.93 Å. The Co(3)-O(13) bond length is 1.92 Å. The Co(3)-O(15) bond length is 1.96 Å. The Co(3)-O(17) bond length is 2.03 Å. The Co(3)-O(3) bond length is 1.94 Å. The Co(3)-O(5) bond length is 2.05 Å. In the fourth Co site, Co(4) is bonded in an octahedral geometry to one O(12), one O(19), one O(22), one O(23), one O(8), and one O(9) atom. The Co(4)-O(12) bond length is 1.94 Å. The Co(4)-O(19) bond length is 2.04 Å. The Co(4)-O(22) bond length is 1.93 Å. The Co(4)-O(23) bond length is 1.95 Å. The Co(4)-O(8) bond length is 2.03 Å. The Co(4)-O(9) bond length is 1.95 Å. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(1), one O(19), one O(22), one O(23), one O(3), and one O(5) atom. The Zn(1)-O(1) bond length is 2.22 Å. The Zn(1)-O(19) bond length is 2.23 Å. The Zn(1)-O(22) bond length is 2.20 Å. The Zn(1)-O(23) bond length is 2.20 Å. The Zn(1)-O(3) bond length is 2.18 Å. The Zn(1)-O(5) bond length is 2.22 Å. In the second Zn site, Zn(2) is bonded in a 6-coordinate geometry to one O(2), one O(20), one O(21), one O(24), one O(4), and one O(6) atom. The Zn(2)-O(2) bond length is 2.22 Å. The Zn(2)-O(20) bond length is 2.23 Å. The Zn(2)-O(21) bond length is 2.20 Å. The Zn(2)-O(24) bond length is 2.20 Å. The Zn(2)-O(4) bond length is 2.19 Å. The Zn(2)-O(6) bond length is 2.22 Å. In the third Zn site, Zn(3) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(15), one O(17), and one O(7) atom. The Zn(3)-O(10) bond length is 2.17 Å. The Zn(3)-O(11) bond length is 2.18 Å. The Zn(3)-O(13) bond length is 2.26 Å. The Zn(3)-O(15) bond length is 2.21 Å. The Zn(3)-O(17) bond length is 2.19 Å. The Zn(3)-O(7) bond length is 2.26 Å. In the fourth Zn site, Zn(4) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(16), one O(18), one O(8), and one O(9) atom. The Zn(4)-O(12) bond length is 2.24 Å. The Zn(4)-O(14) bond length is 2.19 Å. The Zn(4)-O(16) bond length is 2.17 Å. The Zn(4)-O(18) bond length is 2.25 Å. The Zn(4)-O(8) bond length is 2.20 Å. The Zn(4)-O(9) bond length is 2.22 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Sr(11), one Sr(3), one Sr(9), one Co(3), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the second O site, O(2) is bonded to one Sr(10), one Sr(12), one Sr(2), one Sr(4), one Co(1), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the third O site, O(3) is bonded to one Sr(11), one Sr(3), one Sr(5), one Sr(7), one Co(3), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the fourth O site, O(4) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(8), one Co(1), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(6), one Sr(7), one Sr(9), one Co(3), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the sixth O site, O(6) is bonded to one Sr(10), one Sr(2), one Sr(5), one Sr(8), one Co(1), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the seventh O site, O(7) is bonded to one Sr(11), one Sr(3), one Sr(5), one Sr(7), one Co(2), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the eighth O site, O(8) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(8), one Co(4), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(6), one Sr(7), one Sr(9), one Co(4), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the tenth O site, O(10) is bonded to one Sr(10), one Sr(2), one Sr(5), one Sr(8), one Co(2), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the eleventh O site, O(11) is bonded to one Sr(10), one Sr(11), one Sr(2), one Sr(3), one Co(2), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the twelfth O site, O(12) is bonded to one Sr(1), one Sr(12), one Sr(4), one Sr(9), one Co(4), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the thirteenth O site, O(13) is bonded to one Sr(1), one Sr(11), one Sr(5), one Sr(7), one Co(3), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-64°. In the fourteenth O site, O(14) is bonded to one Sr(12), one Sr(2), one Sr(6), one Sr(8), one Co(1), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the fifteenth O site, O(15) is bonded to one Sr(1), one Sr(3), one Sr(7), one Sr(9), one Co(3), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the sixteenth O site, O(16) is bonded to one Sr(10), one Sr(2), one Sr(4), one Sr(8), one Co(1), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the seventeenth O site, O(17) is bonded to one Sr(10), one Sr(11), one Sr(3), one Sr(5), one Co(3), and one Zn(3) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the eighteenth O site, O(18) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(9), one Co(1), and one Zn(4) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the nineteenth O site, O(19) is bonded to one Sr(1), one Sr(3), one Sr(7), one Sr(9), one Co(4), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the twentieth O site, O(20) is bonded to one Sr(10), one Sr(2), one Sr(4), one Sr(8), one Co(2), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°. In the twenty-first O site, O(21) is bonded to one Sr(10), one Sr(11), one Sr(3), one Sr(5), one Co(2), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the twenty-second O site, O(22) is bonded to one Sr(12), one Sr(4), one Sr(6), one Sr(9), one Co(4), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-64°. In the twenty-third O site, O(23) is bonded to one Sr(1), one Sr(12), one Sr(6), one Sr(7), one Co(4), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the twenty-fourth O site, O(24) is bonded to one Sr(11), one Sr(2), one Sr(5), one Sr(8), one Co(2), and one Zn(2) atom to form a mixture of distorted edge, face, and corner-sharing OSr4ZnCo octahedra. The corner-sharing octahedral tilt angles range from 0-63°.