CuZn3InS5 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the second Cu site, Cu(2) is bonded to one S(2), one S(3), one S(4), and one S(9) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(3), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(10), one S(4), one S(6), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the third Zn site, Zn(3) is bonded to one S(10), one S(5), one S(6), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the fourth Zn site, Zn(4) is bonded to one S(1), one S(2), one S(5), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(6)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the fifth Zn site, Zn(5) is bonded to one S(1), one S(2), one S(3), and one S(8) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(6)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one S(10), one S(3), one S(4), and one S(5) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to one S(2), one S(7), one S(8), and one S(9) atom to form InS4 tetrahedra that share  a cornercorner with one Zn(2)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(5)S4 tetrahedra. In the second In site, In(2) is bonded to one S(1), one S(4), one S(5), and one S(6) atom to form InS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(6)S4 tetrahedra. There are ten inequivalent S sites. In the first S site, S(1) is bonded to one Cu(1), one Zn(4), one Zn(5), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the second S site, S(2) is bonded to one Cu(2), one Zn(4), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the third S site, S(3) is bonded to one Cu(2), one Zn(1), one Zn(5), and one Zn(6) atom to form SZn3Cu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fourth S site, S(4) is bonded to one Cu(2), one Zn(2), one Zn(6), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fifth S site, S(5) is bonded to one Zn(3), one Zn(4), one Zn(6), and one In(2) atom to form SZn3In tetrahedra that share  a cornercorner with one S(2)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the sixth S site, S(6) is bonded to one Cu(1), one Zn(2), one Zn(3), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(8)Zn2InCu tetrahedra,  a cornercorner with one S(9)Zn2InCu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the seventh S site, S(7) is bonded to one Cu(1), one Zn(3), one Zn(4), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(9)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the eighth S site, S(8) is bonded to one Cu(1), one Zn(1), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the ninth S site, S(9) is bonded to one Cu(2), one Zn(1), one Zn(2), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(7)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the tenth S site, S(10) is bonded to one Zn(1), one Zn(2), one Zn(3), and one Zn(6) atom to form SZn4 tetrahedra that share  a cornercorner with one S(7)Zn2InCu tetrahedra,  a cornercorner with one S(8)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra.
CuZn3InS5 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. The Cu(1)-S(1) bond length is 2.32 Å. The Cu(1)-S(6) bond length is 2.32 Å. The Cu(1)-S(7) bond length is 2.32 Å. The Cu(1)-S(8) bond length is 2.32 Å. In the second Cu site, Cu(2) is bonded to one S(2), one S(3), one S(4), and one S(9) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. The Cu(2)-S(2) bond length is 2.33 Å. The Cu(2)-S(3) bond length is 2.34 Å. The Cu(2)-S(4) bond length is 2.33 Å. The Cu(2)-S(9) bond length is 2.33 Å. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(3), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. The Zn(1)-S(10) bond length is 2.39 Å. The Zn(1)-S(3) bond length is 2.34 Å. The Zn(1)-S(8) bond length is 2.37 Å. The Zn(1)-S(9) bond length is 2.37 Å. In the second Zn site, Zn(2) is bonded to one S(10), one S(4), one S(6), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. The Zn(2)-S(10) bond length is 2.36 Å. The Zn(2)-S(4) bond length is 2.37 Å. The Zn(2)-S(6) bond length is 2.37 Å. The Zn(2)-S(9) bond length is 2.36 Å. In the third Zn site, Zn(3) is bonded to one S(10), one S(5), one S(6), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. The Zn(3)-S(10) bond length is 2.35 Å. The Zn(3)-S(5) bond length is 2.39 Å. The Zn(3)-S(6) bond length is 2.35 Å. The Zn(3)-S(7) bond length is 2.35 Å. In the fourth Zn site, Zn(4) is bonded to one S(1), one S(2), one S(5), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(6)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. The Zn(4)-S(1) bond length is 2.35 Å. The Zn(4)-S(2) bond length is 2.34 Å. The Zn(4)-S(5) bond length is 2.38 Å. The Zn(4)-S(7) bond length is 2.35 Å. In the fifth Zn site, Zn(5) is bonded to one S(1), one S(2), one S(3), and one S(8) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(6)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. The Zn(5)-S(1) bond length is 2.38 Å. The Zn(5)-S(2) bond length is 2.37 Å. The Zn(5)-S(3) bond length is 2.34 Å. The Zn(5)-S(8) bond length is 2.37 Å. In the sixth Zn site, Zn(6) is bonded to one S(10), one S(3), one S(4), and one S(5) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. The Zn(6)-S(10) bond length is 2.37 Å. The Zn(6)-S(3) bond length is 2.33 Å. The Zn(6)-S(4) bond length is 2.36 Å. The Zn(6)-S(5) bond length is 2.40 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded to one S(2), one S(7), one S(8), and one S(9) atom to form InS4 tetrahedra that share  a cornercorner with one Zn(2)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(5)S4 tetrahedra. The In(1)-S(2) bond length is 2.50 Å. The In(1)-S(7) bond length is 2.50 Å. The In(1)-S(8) bond length is 2.49 Å. The In(1)-S(9) bond length is 2.49 Å. In the second In site, In(2) is bonded to one S(1), one S(4), one S(5), and one S(6) atom to form InS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(6)S4 tetrahedra. The In(2)-S(1) bond length is 2.48 Å. The In(2)-S(4) bond length is 2.48 Å. The In(2)-S(5) bond length is 2.51 Å. The In(2)-S(6) bond length is 2.49 Å. There are ten inequivalent S sites. In the first S site, S(1) is bonded to one Cu(1), one Zn(4), one Zn(5), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the second S site, S(2) is bonded to one Cu(2), one Zn(4), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the third S site, S(3) is bonded to one Cu(2), one Zn(1), one Zn(5), and one Zn(6) atom to form SZn3Cu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fourth S site, S(4) is bonded to one Cu(2), one Zn(2), one Zn(6), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fifth S site, S(5) is bonded to one Zn(3), one Zn(4), one Zn(6), and one In(2) atom to form SZn3In tetrahedra that share  a cornercorner with one S(2)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the sixth S site, S(6) is bonded to one Cu(1), one Zn(2), one Zn(3), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(8)Zn2InCu tetrahedra,  a cornercorner with one S(9)Zn2InCu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the seventh S site, S(7) is bonded to one Cu(1), one Zn(3), one Zn(4), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(9)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the eighth S site, S(8) is bonded to one Cu(1), one Zn(1), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the ninth S site, S(9) is bonded to one Cu(2), one Zn(1), one Zn(2), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(7)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the tenth S site, S(10) is bonded to one Zn(1), one Zn(2), one Zn(3), and one Zn(6) atom to form SZn4 tetrahedra that share  a cornercorner with one S(7)Zn2InCu tetrahedra,  a cornercorner with one S(8)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra.