CePdIn4 crystallizes in the orthorhombic Cmcm space group. Ce(1) is bonded in a 15-coordinate geometry to two equivalent Pd(1), three equivalent In(3), four equivalent In(1), and six equivalent In(2) atoms. Pd(1) is bonded in a 7-coordinate geometry to two equivalent Ce(1), one In(3), and six equivalent In(2) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a distorted q6 geometry to four equivalent Ce(1), two equivalent In(2), and four equivalent In(3) atoms. In the second In site, In(2) is bonded in a 5-coordinate geometry to three equivalent Ce(1), three equivalent Pd(1), and one In(1) atom. In the third In site, In(3) is bonded in a distorted linear geometry to three equivalent Ce(1), one Pd(1), and four equivalent In(1) atoms.
CePdIn4 crystallizes in the orthorhombic Cmcm space group. Ce(1) is bonded in a 15-coordinate geometry to two equivalent Pd(1), three equivalent In(3), four equivalent In(1), and six equivalent In(2) atoms. Both Ce(1)-Pd(1) bond lengths are 3.55 Å. There is one shorter (3.18 Å) and two longer (3.77 Å) Ce(1)-In(3) bond lengths. All Ce(1)-In(1) bond lengths are 3.57 Å. There are four shorter (3.36 Å) and two longer (3.73 Å) Ce(1)-In(2) bond lengths. Pd(1) is bonded in a 7-coordinate geometry to two equivalent Ce(1), one In(3), and six equivalent In(2) atoms. The Pd(1)-In(3) bond length is 2.68 Å. There are two shorter (2.70 Å) and four longer (2.84 Å) Pd(1)-In(2) bond lengths. There are three inequivalent In sites. In the first In site, In(1) is bonded in a distorted q6 geometry to four equivalent Ce(1), two equivalent In(2), and four equivalent In(3) atoms. Both In(1)-In(2) bond lengths are 3.15 Å. All In(1)-In(3) bond lengths are 3.17 Å. In the second In site, In(2) is bonded in a 5-coordinate geometry to three equivalent Ce(1), three equivalent Pd(1), and one In(1) atom. In the third In site, In(3) is bonded in a distorted linear geometry to three equivalent Ce(1), one Pd(1), and four equivalent In(1) atoms.