Gd(PdGe)2 crystallizes in the tetragonal I4/mmm space group. Gd(1) is bonded in a 16-coordinate geometry to eight equivalent Pd(1) and eight equivalent Ge(1) atoms. Pd(1) is bonded in a 4-coordinate geometry to four equivalent Gd(1) and four equivalent Ge(1) atoms. Ge(1) is bonded in a 9-coordinate geometry to four equivalent Gd(1), four equivalent Pd(1), and one Ge(1) atom.
Gd(PdGe)2 crystallizes in the tetragonal I4/mmm space group. Gd(1) is bonded in a 16-coordinate geometry to eight equivalent Pd(1) and eight equivalent Ge(1) atoms. All Gd(1)-Pd(1) bond lengths are 3.31 Å. All Gd(1)-Ge(1) bond lengths are 3.25 Å. Pd(1) is bonded in a 4-coordinate geometry to four equivalent Gd(1) and four equivalent Ge(1) atoms. All Pd(1)-Ge(1) bond lengths are 2.50 Å. Ge(1) is bonded in a 9-coordinate geometry to four equivalent Gd(1), four equivalent Pd(1), and one Ge(1) atom. The Ge(1)-Ge(1) bond length is 2.44 Å.