Re3S4O2F(O2)3 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, four trioxidane molecules, four water atoms, and two Re3S4O2F clusters. In each Re3S4O2F cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(4), and one F(1) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(3), and one O(7) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(8) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to one Re(3) and two equivalent Re(2) atoms. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Re(3) and two equivalent Re(1) atoms. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Re(3) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom.
Re3S4O2F(O2)3 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, four trioxidane molecules, four water atoms, and two Re3S4O2F clusters. In each Re3S4O2F cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(4), and one F(1) atom. The Re(1)-S(1) bond length is 2.41 Å. The Re(1)-S(2) bond length is 2.36 Å. There is one shorter (2.42 Å) and one longer (2.43 Å) Re(1)-S(4) bond length. The Re(1)-F(1) bond length is 1.97 Å. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one S(1), one S(2), two equivalent S(3), and one O(7) atom. The Re(2)-S(1) bond length is 2.40 Å. The Re(2)-S(2) bond length is 2.39 Å. There is one shorter (2.35 Å) and one longer (2.51 Å) Re(2)-S(3) bond length. The Re(2)-O(7) bond length is 1.72 Å. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one S(1), one S(2), one S(3), one S(4), and one O(8) atom. The Re(3)-S(1) bond length is 2.42 Å. The Re(3)-S(2) bond length is 2.45 Å. The Re(3)-S(3) bond length is 2.40 Å. The Re(3)-S(4) bond length is 2.40 Å. The Re(3)-O(8) bond length is 1.73 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a distorted T-shaped geometry to one Re(3) and two equivalent Re(2) atoms. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Re(3) and two equivalent Re(1) atoms. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Re(3) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom.