Li3V3CrO8 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(16), one O(3), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(2), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the third Li site, Li(3) is bonded to one O(11), one O(14), one O(15), one O(2), one O(3), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the fourth Li site, Li(4) is bonded to one O(12), one O(15), one O(16), one O(3), one O(4), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the fifth Li site, Li(5) is bonded to one O(13), one O(16), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(6)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the sixth Li site, Li(6) is bonded to one O(1), one O(10), one O(14), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(15), one O(16), one O(2), one O(3), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the second V site, V(2) is bonded to one O(12), one O(16), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(13), one O(4), one O(5), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fourth V site, V(4) is bonded to one O(10), one O(11), one O(14), one O(2), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the fifth V site, V(5) is bonded to one O(11), one O(12), one O(15), one O(3), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the sixth V site, V(6) is bonded to one O(12), one O(13), one O(16), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(13), one O(14), one O(5), one O(8), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the second Cr site, Cr(2) is bonded to one O(1), one O(10), one O(14), one O(15), one O(2), and one O(6) atom to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(6), one V(3), one Cr(1), and one Cr(2) atom to form OLi2VCr2 square pyramids that share corners with two equivalent O(14)Li3VCr2 octahedra,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid, corners with three equivalent O(13)Li2V2Cr square pyramids,  an edgeedge with one O(14)Li3VCr2 octahedra, edges with two equivalent O(5)Li3V2Cr octahedra,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid, and edges with two equivalent O(10)Li2V2Cr square pyramids. The corner-sharing octahedral tilt angles are 3°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one V(1), one V(4), and one Cr(2) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(16)Li3V3 octahedra, corners with two equivalent O(14)Li3VCr2 octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid, and  an edgeedge with one O(1)Li2VCr2 square pyramid. The corner-sharing octahedral tilt angles range from 2-6°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(4), one V(1), one V(2), and one V(5) atom to form OLi3V3 octahedra that share  a cornercorner with one O(14)Li3VCr2 octahedra, corners with two equivalent O(16)Li3V3 octahedra,  a cornercorner with one O(9)Li2V2Cr square pyramid, corners with two equivalent O(15)Li2V2Cr square pyramids,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, edges with two equivalent O(11)Li2V3 square pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and edges with two equivalent O(7)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 1-3°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one V(3), and one V(6) atom to form OLi2V3 square pyramids that share corners with two equivalent O(16)Li3V3 octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 3-4°. In the fifth O site, O(5) is bonded to one Li(2), one Li(5), one Li(6), one V(3), one V(4), and one Cr(1) atom to form OLi3V2Cr octahedra that share  a cornercorner with one O(16)Li3V3 octahedra,  a cornercorner with one O(11)Li2V3 square pyramid, corners with two equivalent O(10)Li2V2Cr square pyramids, corners with two equivalent O(9)Li2V2Cr square pyramids, edges with two equivalent O(14)Li3VCr2 octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, edges with two equivalent O(13)Li2V2Cr square pyramids, and edges with two equivalent O(1)Li2VCr2 square pyramids. The corner-sharing octahedral tilt angles are 4°. In the sixth O site, O(6) is bonded to one Li(3), one Li(6), one V(4), one V(5), and one Cr(2) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with three equivalent O(10)Li2V2Cr square pyramids,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(3)Li3V3 octahedra, edges with two equivalent O(14)Li3VCr2 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid, and  an edgeedge with one O(1)Li2VCr2 square pyramid. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one V(1), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid, corners with two equivalent O(12)Li2V3 square pyramids, corners with three equivalent O(11)Li2V3 square pyramids, edges with two equivalent O(16)Li3V3 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid, and  an edgeedge with one O(4)Li2V3 square pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(5), one V(2), one V(6), and one Cr(1) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(14)Li3VCr2 octahedra,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid, corners with three equivalent O(12)Li2V3 square pyramids,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(3)Li3V3 octahedra, edges with two equivalent O(16)Li3V3 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. The corner-sharing octahedral tilt angles are 4°. In the ninth O site, O(9) is bonded to one Li(5), one Li(6), one V(2), one V(3), and one Cr(1) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra, corners with two equivalent O(5)Li3V2Cr octahedra,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, and  an edgeedge with one O(1)Li2VCr2 square pyramid. The corner-sharing octahedral tilt angles range from 3-7°. In the tenth O site, O(10) is bonded to one Li(2), one Li(6), one V(3), one V(4), and one Cr(2) atom to form OLi2V2Cr square pyramids that share corners with two equivalent O(5)Li3V2Cr octahedra,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid, corners with three equivalent O(6)Li2V2Cr square pyramids,  an edgeedge with one O(5)Li3V2Cr octahedra, edges with two equivalent O(14)Li3VCr2 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid, and edges with two equivalent O(1)Li2VCr2 square pyramids. The corner-sharing octahedral tilt angles range from 3-4°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one V(1), one V(4), and one V(5) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(5)Li3V2Cr octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid, corners with three equivalent O(7)Li2V3 square pyramids,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid, and  an edgeedge with one O(12)Li2V3 square pyramid. The corner-sharing octahedral tilt angles are 2°. In the twelfth O site, O(12) is bonded to one Li(1), one Li(4), one V(2), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid, corners with two equivalent O(7)Li2V3 square pyramids, corners with three equivalent O(8)Li2V2Cr square pyramids, edges with two equivalent O(16)Li3V3 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. In the thirteenth O site, O(13) is bonded to one Li(2), one Li(5), one V(3), one V(6), and one Cr(1) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with three equivalent O(1)Li2VCr2 square pyramids,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra, edges with two equivalent O(5)Li3V2Cr octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid, and  an edgeedge with one O(4)Li2V3 square pyramid. In the fourteenth O site, O(14) is bonded to one Li(2), one Li(3), one Li(6), one V(4), one Cr(1), and one Cr(2) atom to form OLi3VCr2 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(8)Li2V2Cr square pyramid, corners with two equivalent O(2)Li2V2Cr square pyramids, corners with two equivalent O(1)Li2VCr2 square pyramids, edges with two equivalent O(5)Li3V2Cr octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(1)Li2VCr2 square pyramid, edges with two equivalent O(10)Li2V2Cr square pyramids, and edges with two equivalent O(6)Li2V2Cr square pyramids. The corner-sharing octahedral tilt angles are 3°. In the fifteenth O site, O(15) is bonded to one Li(3), one Li(4), one V(1), one V(5), and one Cr(2) atom to form OLi2V2Cr square pyramids that share corners with two equivalent O(3)Li3V3 octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 3-4°. In the sixteenth O site, O(16) is bonded to one Li(1), one Li(4), one Li(5), one V(1), one V(2), and one V(6) atom to form OLi3V3 octahedra that share  a cornercorner with one O(5)Li3V2Cr octahedra, corners with two equivalent O(3)Li3V3 octahedra,  a cornercorner with one O(2)Li2V2Cr square pyramid, corners with two equivalent O(4)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, edges with two equivalent O(8)Li2V2Cr square pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and edges with two equivalent O(7)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 1-4°.
Li3V3CrO8 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(16), one O(3), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra, corners with two equivalent V(5)O6 octahedra, corners with two equivalent V(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. The Li(1)-O(11) bond length is 2.32 Å. The Li(1)-O(12) bond length is 2.19 Å. The Li(1)-O(16) bond length is 2.13 Å. The Li(1)-O(3) bond length is 2.16 Å. The Li(1)-O(7) bond length is 2.13 Å. The Li(1)-O(8) bond length is 2.17 Å. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(2), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. The Li(2)-O(1) bond length is 2.13 Å. The Li(2)-O(10) bond length is 2.19 Å. The Li(2)-O(13) bond length is 2.11 Å. The Li(2)-O(14) bond length is 2.25 Å. The Li(2)-O(2) bond length is 2.14 Å. The Li(2)-O(5) bond length is 2.21 Å. In the third Li site, Li(3) is bonded to one O(11), one O(14), one O(15), one O(2), one O(3), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. The Li(3)-O(11) bond length is 2.19 Å. The Li(3)-O(14) bond length is 2.13 Å. The Li(3)-O(15) bond length is 2.20 Å. The Li(3)-O(2) bond length is 2.24 Å. The Li(3)-O(3) bond length is 2.16 Å. The Li(3)-O(6) bond length is 2.19 Å. In the fourth Li site, Li(4) is bonded to one O(12), one O(15), one O(16), one O(3), one O(4), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The Li(4)-O(12) bond length is 2.22 Å. The Li(4)-O(15) bond length is 2.18 Å. The Li(4)-O(16) bond length is 2.15 Å. The Li(4)-O(3) bond length is 2.20 Å. The Li(4)-O(4) bond length is 2.29 Å. The Li(4)-O(7) bond length is 2.22 Å. In the fifth Li site, Li(5) is bonded to one O(13), one O(16), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(6)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. The Li(5)-O(13) bond length is 2.28 Å. The Li(5)-O(16) bond length is 2.15 Å. The Li(5)-O(4) bond length is 2.21 Å. The Li(5)-O(5) bond length is 2.22 Å. The Li(5)-O(8) bond length is 2.19 Å. The Li(5)-O(9) bond length is 2.18 Å. In the sixth Li site, Li(6) is bonded to one O(1), one O(10), one O(14), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. The Li(6)-O(1) bond length is 2.18 Å. The Li(6)-O(10) bond length is 2.16 Å. The Li(6)-O(14) bond length is 2.28 Å. The Li(6)-O(5) bond length is 2.25 Å. The Li(6)-O(6) bond length is 2.12 Å. The Li(6)-O(9) bond length is 2.15 Å. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(15), one O(16), one O(2), one O(3), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The V(1)-O(11) bond length is 2.10 Å. The V(1)-O(15) bond length is 2.00 Å. The V(1)-O(16) bond length is 2.09 Å. The V(1)-O(2) bond length is 2.08 Å. The V(1)-O(3) bond length is 2.06 Å. The V(1)-O(7) bond length is 2.03 Å. In the second V site, V(2) is bonded to one O(12), one O(16), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The V(2)-O(12) bond length is 2.04 Å. The V(2)-O(16) bond length is 2.05 Å. The V(2)-O(3) bond length is 2.10 Å. The V(2)-O(4) bond length is 2.09 Å. The V(2)-O(8) bond length is 2.02 Å. The V(2)-O(9) bond length is 2.07 Å. In the third V site, V(3) is bonded to one O(1), one O(10), one O(13), one O(4), one O(5), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. The V(3)-O(1) bond length is 2.01 Å. The V(3)-O(10) bond length is 1.98 Å. The V(3)-O(13) bond length is 2.02 Å. The V(3)-O(4) bond length is 1.88 Å. The V(3)-O(5) bond length is 2.06 Å. The V(3)-O(9) bond length is 1.98 Å. In the fourth V site, V(4) is bonded to one O(10), one O(11), one O(14), one O(2), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. The V(4)-O(10) bond length is 2.02 Å. The V(4)-O(11) bond length is 1.87 Å. The V(4)-O(14) bond length is 2.02 Å. The V(4)-O(2) bond length is 1.95 Å. The V(4)-O(5) bond length is 2.06 Å. The V(4)-O(6) bond length is 1.98 Å. In the fifth V site, V(5) is bonded to one O(11), one O(12), one O(15), one O(3), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. The V(5)-O(11) bond length is 2.10 Å. The V(5)-O(12) bond length is 2.03 Å. The V(5)-O(15) bond length is 2.01 Å. The V(5)-O(3) bond length is 2.05 Å. The V(5)-O(6) bond length is 2.06 Å. The V(5)-O(7) bond length is 2.03 Å. In the sixth V site, V(6) is bonded to one O(12), one O(13), one O(16), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. The V(6)-O(12) bond length is 2.01 Å. The V(6)-O(13) bond length is 2.03 Å. The V(6)-O(16) bond length is 2.07 Å. The V(6)-O(4) bond length is 2.09 Å. The V(6)-O(7) bond length is 2.02 Å. The V(6)-O(8) bond length is 2.02 Å. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(13), one O(14), one O(5), one O(8), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Cr(1)-O(1) bond length is 2.02 Å. The Cr(1)-O(13) bond length is 2.01 Å. The Cr(1)-O(14) bond length is 2.06 Å. The Cr(1)-O(5) bond length is 2.03 Å. The Cr(1)-O(8) bond length is 2.01 Å. The Cr(1)-O(9) bond length is 2.00 Å. In the second Cr site, Cr(2) is bonded to one O(1), one O(10), one O(14), one O(15), one O(2), and one O(6) atom to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. The Cr(2)-O(1) bond length is 1.99 Å. The Cr(2)-O(10) bond length is 2.05 Å. The Cr(2)-O(14) bond length is 2.04 Å. The Cr(2)-O(15) bond length is 2.02 Å. The Cr(2)-O(2) bond length is 2.02 Å. The Cr(2)-O(6) bond length is 2.05 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(6), one V(3), one Cr(1), and one Cr(2) atom to form OLi2VCr2 square pyramids that share corners with two equivalent O(14)Li3VCr2 octahedra,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid, corners with three equivalent O(13)Li2V2Cr square pyramids,  an edgeedge with one O(14)Li3VCr2 octahedra, edges with two equivalent O(5)Li3V2Cr octahedra,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid, and edges with two equivalent O(10)Li2V2Cr square pyramids. The corner-sharing octahedral tilt angles are 3°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one V(1), one V(4), and one Cr(2) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(16)Li3V3 octahedra, corners with two equivalent O(14)Li3VCr2 octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid, and  an edgeedge with one O(1)Li2VCr2 square pyramid. The corner-sharing octahedral tilt angles range from 2-6°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(4), one V(1), one V(2), and one V(5) atom to form OLi3V3 octahedra that share  a cornercorner with one O(14)Li3VCr2 octahedra, corners with two equivalent O(16)Li3V3 octahedra,  a cornercorner with one O(9)Li2V2Cr square pyramid, corners with two equivalent O(15)Li2V2Cr square pyramids,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, edges with two equivalent O(11)Li2V3 square pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and edges with two equivalent O(7)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 1-3°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one V(3), and one V(6) atom to form OLi2V3 square pyramids that share corners with two equivalent O(16)Li3V3 octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 3-4°. In the fifth O site, O(5) is bonded to one Li(2), one Li(5), one Li(6), one V(3), one V(4), and one Cr(1) atom to form OLi3V2Cr octahedra that share  a cornercorner with one O(16)Li3V3 octahedra,  a cornercorner with one O(11)Li2V3 square pyramid, corners with two equivalent O(10)Li2V2Cr square pyramids, corners with two equivalent O(9)Li2V2Cr square pyramids, edges with two equivalent O(14)Li3VCr2 octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, edges with two equivalent O(13)Li2V2Cr square pyramids, and edges with two equivalent O(1)Li2VCr2 square pyramids. The corner-sharing octahedral tilt angles are 4°. In the sixth O site, O(6) is bonded to one Li(3), one Li(6), one V(4), one V(5), and one Cr(2) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with three equivalent O(10)Li2V2Cr square pyramids,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(3)Li3V3 octahedra, edges with two equivalent O(14)Li3VCr2 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid, and  an edgeedge with one O(1)Li2VCr2 square pyramid. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one V(1), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid, corners with two equivalent O(12)Li2V3 square pyramids, corners with three equivalent O(11)Li2V3 square pyramids, edges with two equivalent O(16)Li3V3 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid, and  an edgeedge with one O(4)Li2V3 square pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(5), one V(2), one V(6), and one Cr(1) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(14)Li3VCr2 octahedra,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid, corners with three equivalent O(12)Li2V3 square pyramids,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(3)Li3V3 octahedra, edges with two equivalent O(16)Li3V3 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. The corner-sharing octahedral tilt angles are 4°. In the ninth O site, O(9) is bonded to one Li(5), one Li(6), one V(2), one V(3), and one Cr(1) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(3)Li3V3 octahedra, corners with two equivalent O(5)Li3V2Cr octahedra,  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid,  an edgeedge with one O(5)Li3V2Cr octahedra,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, and  an edgeedge with one O(1)Li2VCr2 square pyramid. The corner-sharing octahedral tilt angles range from 3-7°. In the tenth O site, O(10) is bonded to one Li(2), one Li(6), one V(3), one V(4), and one Cr(2) atom to form OLi2V2Cr square pyramids that share corners with two equivalent O(5)Li3V2Cr octahedra,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid, corners with three equivalent O(6)Li2V2Cr square pyramids,  an edgeedge with one O(5)Li3V2Cr octahedra, edges with two equivalent O(14)Li3VCr2 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid, and edges with two equivalent O(1)Li2VCr2 square pyramids. The corner-sharing octahedral tilt angles range from 3-4°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one V(1), one V(4), and one V(5) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(5)Li3V2Cr octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(15)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid, corners with three equivalent O(7)Li2V3 square pyramids,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid, and  an edgeedge with one O(12)Li2V3 square pyramid. The corner-sharing octahedral tilt angles are 2°. In the twelfth O site, O(12) is bonded to one Li(1), one Li(4), one V(2), one V(5), and one V(6) atom to form OLi2V3 square pyramids that share  a cornercorner with one O(13)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid, corners with two equivalent O(7)Li2V3 square pyramids, corners with three equivalent O(8)Li2V2Cr square pyramids, edges with two equivalent O(16)Li3V3 octahedra, edges with two equivalent O(3)Li3V3 octahedra,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. In the thirteenth O site, O(13) is bonded to one Li(2), one Li(5), one V(3), one V(6), and one Cr(1) atom to form OLi2V2Cr square pyramids that share  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(8)Li2V2Cr square pyramid,  a cornercorner with one O(9)Li2V2Cr square pyramid,  a cornercorner with one O(12)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid, corners with three equivalent O(1)Li2VCr2 square pyramids,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra, edges with two equivalent O(5)Li3V2Cr octahedra,  an edgeedge with one O(10)Li2V2Cr square pyramid,  an edgeedge with one O(8)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid, and  an edgeedge with one O(4)Li2V3 square pyramid. In the fourteenth O site, O(14) is bonded to one Li(2), one Li(3), one Li(6), one V(4), one Cr(1), and one Cr(2) atom to form OLi3VCr2 octahedra that share  a cornercorner with one O(3)Li3V3 octahedra,  a cornercorner with one O(8)Li2V2Cr square pyramid, corners with two equivalent O(2)Li2V2Cr square pyramids, corners with two equivalent O(1)Li2VCr2 square pyramids, edges with two equivalent O(5)Li3V2Cr octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(1)Li2VCr2 square pyramid, edges with two equivalent O(10)Li2V2Cr square pyramids, and edges with two equivalent O(6)Li2V2Cr square pyramids. The corner-sharing octahedral tilt angles are 3°. In the fifteenth O site, O(15) is bonded to one Li(3), one Li(4), one V(1), one V(5), and one Cr(2) atom to form OLi2V2Cr square pyramids that share corners with two equivalent O(3)Li3V3 octahedra,  a cornercorner with one O(10)Li2V2Cr square pyramid,  a cornercorner with one O(2)Li2V2Cr square pyramid,  a cornercorner with one O(6)Li2V2Cr square pyramid,  a cornercorner with one O(11)Li2V3 square pyramid,  a cornercorner with one O(4)Li2V3 square pyramid,  a cornercorner with one O(7)Li2V3 square pyramid,  a cornercorner with one O(1)Li2VCr2 square pyramid,  an edgeedge with one O(16)Li3V3 octahedra,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(14)Li3VCr2 octahedra,  an edgeedge with one O(2)Li2V2Cr square pyramid,  an edgeedge with one O(6)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(12)Li2V3 square pyramid, and  an edgeedge with one O(7)Li2V3 square pyramid. The corner-sharing octahedral tilt angles range from 3-4°. In the sixteenth O site, O(16) is bonded to one Li(1), one Li(4), one Li(5), one V(1), one V(2), and one V(6) atom to form OLi3V3 octahedra that share  a cornercorner with one O(5)Li3V2Cr octahedra, corners with two equivalent O(3)Li3V3 octahedra,  a cornercorner with one O(2)Li2V2Cr square pyramid, corners with two equivalent O(4)Li2V3 square pyramids,  an edgeedge with one O(3)Li3V3 octahedra,  an edgeedge with one O(13)Li2V2Cr square pyramid,  an edgeedge with one O(15)Li2V2Cr square pyramid,  an edgeedge with one O(9)Li2V2Cr square pyramid,  an edgeedge with one O(11)Li2V3 square pyramid,  an edgeedge with one O(4)Li2V3 square pyramid, edges with two equivalent O(8)Li2V2Cr square pyramids, edges with two equivalent O(12)Li2V3 square pyramids, and edges with two equivalent O(7)Li2V3 square pyramids. The corner-sharing octahedral tilt angles range from 1-4°.