(Tl)3Ga9S13O2 crystallizes in the hexagonal P-6 space group. The structure consists of three 7440-28-0 atoms inside a Ga9S13O2 framework. In the Ga9S13O2 framework, there are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one S(1), one S(2), one S(3), and one O(1) atom to form GaS3O tetrahedra that share corners with two equivalent Ga(2)S4 tetrahedra and corners with four equivalent Ga(1)S3O tetrahedra. In the second Ga site, Ga(2) is bonded to one S(3), one S(4), and two equivalent S(1) atoms to form GaS4 tetrahedra that share corners with two equivalent Ga(2)S4 tetrahedra and corners with four equivalent Ga(1)S3O tetrahedra. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Ga(1) and one Ga(2) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent Ga(1) atoms. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ga(2) and two equivalent Ga(1) atoms. In the fourth S site, S(4) is bonded in a trigonal planar geometry to three equivalent Ga(2) atoms. O(1) is bonded in a trigonal planar geometry to three equivalent Ga(1) atoms.
(Tl)3Ga9S13O2 crystallizes in the hexagonal P-6 space group. The structure consists of three 7440-28-0 atoms inside a Ga9S13O2 framework. In the Ga9S13O2 framework, there are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one S(1), one S(2), one S(3), and one O(1) atom to form GaS3O tetrahedra that share corners with two equivalent Ga(2)S4 tetrahedra and corners with four equivalent Ga(1)S3O tetrahedra. The Ga(1)-S(1) bond length is 2.26 Å. The Ga(1)-S(2) bond length is 2.27 Å. The Ga(1)-S(3) bond length is 2.37 Å. The Ga(1)-O(1) bond length is 1.91 Å. In the second Ga site, Ga(2) is bonded to one S(3), one S(4), and two equivalent S(1) atoms to form GaS4 tetrahedra that share corners with two equivalent Ga(2)S4 tetrahedra and corners with four equivalent Ga(1)S3O tetrahedra. The Ga(2)-S(3) bond length is 2.34 Å. The Ga(2)-S(4) bond length is 2.35 Å. Both Ga(2)-S(1) bond lengths are 2.25 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Ga(1) and one Ga(2) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent Ga(1) atoms. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ga(2) and two equivalent Ga(1) atoms. In the fourth S site, S(4) is bonded in a trigonal planar geometry to three equivalent Ga(2) atoms. O(1) is bonded in a trigonal planar geometry to three equivalent Ga(1) atoms.