Ag3SbS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent S(1) atoms. Sb(1) is bonded in a trigonal non-coplanar geometry to three equivalent S(1) atoms. S(1) is bonded to three equivalent Ag(1) and one Sb(1) atom to form corner-sharing SAg3Sb tetrahedra.
Ag3SbS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent S(1) atoms. There are a spread of Ag(1)-S(1) bond distances ranging from 2.48-2.54 Å. Sb(1) is bonded in a trigonal non-coplanar geometry to three equivalent S(1) atoms. All Sb(1)-S(1) bond lengths are 2.49 Å. S(1) is bonded to three equivalent Ag(1) and one Sb(1) atom to form corner-sharing SAg3Sb tetrahedra.