Zr(TiGa2)2 crystallizes in the tetragonal I4/mmm space group. Zr(1) is bonded in a distorted square co-planar geometry to twelve Ga(1,1,1) atoms. Ti(1) is bonded in a 10-coordinate geometry to two equivalent Ti(1) and eight Ga(1,1,1) atoms. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 11-coordinate geometry to three equivalent Zr(1), four equivalent Ti(1), and four equivalent Ga(1) atoms. In the second Ga site, Ga(1) is bonded in a 11-coordinate geometry to three equivalent Zr(1); four equivalent Ti(1); and four Ga(1,1) atoms. In the third Ga site, Ga(1) is bonded in a 11-coordinate geometry to three equivalent Zr(1); four equivalent Ti(1); and four Ga(1,1) atoms.
Zr(TiGa2)2 crystallizes in the tetragonal I4/mmm space group. Zr(1) is bonded in a distorted square co-planar geometry to twelve Ga(1,1,1) atoms. There are four shorter (2.81 Å) and eight longer (3.26 Å) Zr(1)-Ga(1,1,1) bond lengths. Ti(1) is bonded in a 10-coordinate geometry to two equivalent Ti(1) and eight Ga(1,1,1) atoms. Both Ti(1)-Ti(1) bond lengths are 2.72 Å. All Ti(1)-Ga(1,1,1) bond lengths are 2.73 Å. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 11-coordinate geometry to three equivalent Zr(1), four equivalent Ti(1), and four equivalent Ga(1) atoms. There are two shorter (2.55 Å) and two longer (2.90 Å) Ga(1)-Ga(1) bond lengths. In the second Ga site, Ga(1) is bonded in a 11-coordinate geometry to three equivalent Zr(1); four equivalent Ti(1); and four Ga(1,1) atoms. There are two shorter (2.55 Å) and two longer (2.90 Å) Ga(1)-Ga(1,1) bond lengths. In the third Ga site, Ga(1) is bonded in a 11-coordinate geometry to three equivalent Zr(1); four equivalent Ti(1); and four Ga(1,1) atoms. There is one shorter (2.55 Å) and two longer (2.90 Å) Ga(1)-Ga(1) bond lengths.