Ni(HO)6(SO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and one Ni(HO)6 cluster. In the Ni(HO)6 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ni(1) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ni(1), one H(2), and one H(3) atom.
Ni(HO)6(SO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and one Ni(HO)6 cluster. In the Ni(HO)6 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Ni(1)-O(1) bond lengths are 1.87 Å. Both Ni(1)-O(2) bond lengths are 1.76 Å. Both Ni(1)-O(3) bond lengths are 2.26 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 0.97 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ni(1) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ni(1), one H(2), and one H(3) atom.