Yb2Pd6In13 crystallizes in the monoclinic C2/m space group. Yb(1) is bonded in a 15-coordinate geometry to two equivalent Pd(1), two equivalent Pd(3), one In(2), one In(3), one In(6), one In(7), two equivalent In(4), two equivalent In(5), and three equivalent In(1) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(2) is bonded in a 9-coordinate geometry to one In(2), one In(7), two equivalent In(4), two equivalent In(5), and three equivalent In(3) atoms. In the second Pd site, Pd(3) is bonded in a 9-coordinate geometry to two equivalent Yb(1), one In(4), one In(6), two equivalent In(2), and three equivalent In(1) atoms. In the third Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Yb(1), one In(1), one In(2), one In(5), two equivalent In(3), and two equivalent In(6) atoms. There are seven inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to three equivalent Yb(1), one Pd(1), three equivalent Pd(3), one In(2), two equivalent In(1), and two equivalent In(6) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Yb(1), one Pd(1), one Pd(2), two equivalent Pd(3), and one In(1) atom. In the third In site, In(3) is bonded in a 5-coordinate geometry to one Yb(1), two equivalent Pd(1), and three equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to two equivalent Yb(1), one Pd(3), and two equivalent Pd(2) atoms. In the fifth In site, In(5) is bonded in a 5-coordinate geometry to two equivalent Yb(1), one Pd(1), and two equivalent Pd(2) atoms. In the sixth In site, In(6) is bonded in a distorted trigonal non-coplanar geometry to one Yb(1), one Pd(3), two equivalent Pd(1), and two equivalent In(1) atoms. In the seventh In site, In(7) is bonded in a distorted linear geometry to two equivalent Yb(1) and two equivalent Pd(2) atoms.
Yb2Pd6In13 crystallizes in the monoclinic C2/m space group. Yb(1) is bonded in a 15-coordinate geometry to two equivalent Pd(1), two equivalent Pd(3), one In(2), one In(3), one In(6), one In(7), two equivalent In(4), two equivalent In(5), and three equivalent In(1) atoms. Both Yb(1)-Pd(1) bond lengths are 3.31 Å. Both Yb(1)-Pd(3) bond lengths are 3.35 Å. The Yb(1)-In(2) bond length is 3.48 Å. The Yb(1)-In(3) bond length is 3.52 Å. The Yb(1)-In(6) bond length is 3.43 Å. The Yb(1)-In(7) bond length is 3.51 Å. Both Yb(1)-In(4) bond lengths are 3.35 Å. Both Yb(1)-In(5) bond lengths are 3.35 Å. There are two shorter (3.25 Å) and one longer (3.46 Å) Yb(1)-In(1) bond length. There are three inequivalent Pd sites. In the first Pd site, Pd(2) is bonded in a 9-coordinate geometry to one In(2), one In(7), two equivalent In(4), two equivalent In(5), and three equivalent In(3) atoms. The Pd(2)-In(2) bond length is 2.97 Å. The Pd(2)-In(7) bond length is 2.70 Å. Both Pd(2)-In(4) bond lengths are 2.93 Å. Both Pd(2)-In(5) bond lengths are 2.95 Å. There are two shorter (2.85 Å) and one longer (3.05 Å) Pd(2)-In(3) bond length. In the second Pd site, Pd(3) is bonded in a 9-coordinate geometry to two equivalent Yb(1), one In(4), one In(6), two equivalent In(2), and three equivalent In(1) atoms. The Pd(3)-In(4) bond length is 2.78 Å. The Pd(3)-In(6) bond length is 2.83 Å. Both Pd(3)-In(2) bond lengths are 2.80 Å. There are two shorter (2.83 Å) and one longer (2.87 Å) Pd(3)-In(1) bond length. In the third Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Yb(1), one In(1), one In(2), one In(5), two equivalent In(3), and two equivalent In(6) atoms. The Pd(1)-In(1) bond length is 2.85 Å. The Pd(1)-In(2) bond length is 2.78 Å. The Pd(1)-In(5) bond length is 2.76 Å. Both Pd(1)-In(3) bond lengths are 2.84 Å. Both Pd(1)-In(6) bond lengths are 2.83 Å. There are seven inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to three equivalent Yb(1), one Pd(1), three equivalent Pd(3), one In(2), two equivalent In(1), and two equivalent In(6) atoms. The In(1)-In(2) bond length is 3.29 Å. Both In(1)-In(1) bond lengths are 3.24 Å. Both In(1)-In(6) bond lengths are 3.24 Å. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Yb(1), one Pd(1), one Pd(2), two equivalent Pd(3), and one In(1) atom. In the third In site, In(3) is bonded in a 5-coordinate geometry to one Yb(1), two equivalent Pd(1), and three equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to two equivalent Yb(1), one Pd(3), and two equivalent Pd(2) atoms. In the fifth In site, In(5) is bonded in a 5-coordinate geometry to two equivalent Yb(1), one Pd(1), and two equivalent Pd(2) atoms. In the sixth In site, In(6) is bonded in a distorted trigonal non-coplanar geometry to one Yb(1), one Pd(3), two equivalent Pd(1), and two equivalent In(1) atoms. In the seventh In site, In(7) is bonded in a distorted linear geometry to two equivalent Yb(1) and two equivalent Pd(2) atoms.