NaAg(NO2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(1), one O(3), one O(6), and one O(7) atom. In the second Na site, Na(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Na(1), one O(2), and one O(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Na(1), one O(4), and one O(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one O(3), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(2), one Ag(1), and one N(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(1) atom.
NaAg(NO2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(1), one O(3), one O(6), and one O(7) atom. The Na(1)-N(1) bond length is 2.47 Å. The Na(1)-N(2) bond length is 2.52 Å. The Na(1)-O(1) bond length is 2.43 Å. The Na(1)-O(3) bond length is 2.53 Å. The Na(1)-O(6) bond length is 2.42 Å. The Na(1)-O(7) bond length is 2.45 Å. In the second Na site, Na(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Na(2)-O(1) bond length is 2.82 Å. The Na(2)-O(2) bond length is 2.60 Å. The Na(2)-O(3) bond length is 2.71 Å. The Na(2)-O(4) bond length is 2.56 Å. The Na(2)-O(5) bond length is 2.59 Å. The Na(2)-O(6) bond length is 2.76 Å. The Na(2)-O(7) bond length is 2.72 Å. The Na(2)-O(8) bond length is 2.49 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one O(8) atom. The Ag(1)-O(2) bond length is 2.39 Å. The Ag(1)-O(4) bond length is 2.44 Å. The Ag(1)-O(5) bond length is 2.51 Å. The Ag(1)-O(8) bond length is 2.44 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to one N(3) and one N(4) atom. The Ag(2)-N(3) bond length is 2.20 Å. The Ag(2)-N(4) bond length is 2.14 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Na(1), one O(2), and one O(8) atom. The N(1)-O(2) bond length is 1.22 Å. The N(1)-O(8) bond length is 1.29 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Na(1), one O(4), and one O(5) atom. The N(2)-O(4) bond length is 1.31 Å. The N(2)-O(5) bond length is 1.18 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(6) atom. The N(3)-O(1) bond length is 1.30 Å. The N(3)-O(6) bond length is 1.24 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one O(3), and one O(7) atom. The N(4)-O(3) bond length is 1.27 Å. The N(4)-O(7) bond length is 1.21 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(2), one Ag(1), and one N(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(1) atom.