SrTcO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1) and eight equivalent O(2) atoms. Tc(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing TcO6 octahedra. The corner-sharing octahedral tilt angles range from 17-22°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to four equivalent Sr(1) and two equivalent Tc(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to four equivalent Sr(1) and two equivalent Tc(1) atoms.
SrTcO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1) and eight equivalent O(2) atoms. There are a spread of Sr(1)-O(1) bond distances ranging from 2.48-3.20 Å. There are four shorter (2.59 Å) and four longer (3.04 Å) Sr(1)-O(2) bond lengths. Tc(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing TcO6 octahedra. The corner-sharing octahedral tilt angles range from 17-22°. Both Tc(1)-O(1) bond lengths are 2.02 Å. All Tc(1)-O(2) bond lengths are 2.01 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to four equivalent Sr(1) and two equivalent Tc(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to four equivalent Sr(1) and two equivalent Tc(1) atoms.