TbPdGe crystallizes in the orthorhombic Imm2 space group. There are four inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 12-coordinate geometry to two equivalent Pd(1), four equivalent Pd(3), two equivalent Ge(1), and four equivalent Ge(3) atoms. In the second Tb site, Tb(2) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(2), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. In the third Tb site, Tb(3) is bonded in a 12-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), two equivalent Ge(3), and four equivalent Ge(1) atoms. In the fourth Tb site, Tb(4) is bonded in a 12-coordinate geometry to one Pd(1), two equivalent Pd(3), three equivalent Pd(2), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to one Tb(1), one Tb(4), two equivalent Tb(2), two equivalent Tb(3), one Ge(1), one Ge(2), and two equivalent Ge(3) atoms. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to three equivalent Tb(2), three equivalent Tb(4), one Ge(3), and three equivalent Ge(2) atoms. In the third Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Tb(2), one Tb(3), two equivalent Tb(1), two equivalent Tb(4), one Pd(3), one Ge(3), and two equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Tb(1), one Tb(4), two equivalent Tb(2), two equivalent Tb(3), one Pd(1), two equivalent Pd(3), and one Ge(1) atom. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Tb(2), three equivalent Tb(4), one Pd(1), and three equivalent Pd(2) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Tb(2), one Tb(3), two equivalent Tb(1), two equivalent Tb(4), one Pd(2), one Pd(3), and two equivalent Pd(1) atoms.
TbPdGe crystallizes in the orthorhombic Imm2 space group. There are four inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 12-coordinate geometry to two equivalent Pd(1), four equivalent Pd(3), two equivalent Ge(1), and four equivalent Ge(3) atoms. Both Tb(1)-Pd(1) bond lengths are 3.13 Å. All Tb(1)-Pd(3) bond lengths are 3.13 Å. Both Tb(1)-Ge(1) bond lengths are 3.22 Å. All Tb(1)-Ge(3) bond lengths are 3.12 Å. In the second Tb site, Tb(2) is bonded in a 12-coordinate geometry to one Pd(3), two equivalent Pd(1), three equivalent Pd(2), one Ge(3), two equivalent Ge(1), and three equivalent Ge(2) atoms. The Tb(2)-Pd(3) bond length is 2.98 Å. Both Tb(2)-Pd(1) bond lengths are 3.03 Å. There is one shorter (3.17 Å) and two longer (3.22 Å) Tb(2)-Pd(2) bond lengths. The Tb(2)-Ge(3) bond length is 3.28 Å. Both Tb(2)-Ge(1) bond lengths are 3.22 Å. There are two shorter (3.06 Å) and one longer (3.11 Å) Tb(2)-Ge(2) bond length. In the third Tb site, Tb(3) is bonded in a 12-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), two equivalent Ge(3), and four equivalent Ge(1) atoms. Both Tb(3)-Pd(3) bond lengths are 3.22 Å. All Tb(3)-Pd(1) bond lengths are 3.27 Å. Both Tb(3)-Ge(3) bond lengths are 3.02 Å. All Tb(3)-Ge(1) bond lengths are 3.03 Å. In the fourth Tb site, Tb(4) is bonded in a 12-coordinate geometry to one Pd(1), two equivalent Pd(3), three equivalent Pd(2), one Ge(1), two equivalent Ge(3), and three equivalent Ge(2) atoms. The Tb(4)-Pd(1) bond length is 3.12 Å. Both Tb(4)-Pd(3) bond lengths are 3.17 Å. There are two shorter (3.06 Å) and one longer (3.07 Å) Tb(4)-Pd(2) bond length. The Tb(4)-Ge(1) bond length is 3.18 Å. Both Tb(4)-Ge(3) bond lengths are 3.09 Å. There are two shorter (3.17 Å) and one longer (3.22 Å) Tb(4)-Ge(2) bond length. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 10-coordinate geometry to one Tb(1), one Tb(4), two equivalent Tb(2), two equivalent Tb(3), one Ge(1), one Ge(2), and two equivalent Ge(3) atoms. The Pd(1)-Ge(1) bond length is 2.64 Å. The Pd(1)-Ge(2) bond length is 2.77 Å. Both Pd(1)-Ge(3) bond lengths are 2.58 Å. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to three equivalent Tb(2), three equivalent Tb(4), one Ge(3), and three equivalent Ge(2) atoms. The Pd(2)-Ge(3) bond length is 2.96 Å. There are two shorter (2.57 Å) and one longer (2.61 Å) Pd(2)-Ge(2) bond length. In the third Pd site, Pd(3) is bonded in a 10-coordinate geometry to one Tb(2), one Tb(3), two equivalent Tb(1), two equivalent Tb(4), one Pd(3), one Ge(3), and two equivalent Ge(1) atoms. The Pd(3)-Pd(3) bond length is 3.04 Å. The Pd(3)-Ge(3) bond length is 2.58 Å. Both Pd(3)-Ge(1) bond lengths are 2.57 Å. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Tb(1), one Tb(4), two equivalent Tb(2), two equivalent Tb(3), one Pd(1), two equivalent Pd(3), and one Ge(1) atom. The Ge(1)-Ge(1) bond length is 2.74 Å. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to three equivalent Tb(2), three equivalent Tb(4), one Pd(1), and three equivalent Pd(2) atoms. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Tb(2), one Tb(3), two equivalent Tb(1), two equivalent Tb(4), one Pd(2), one Pd(3), and two equivalent Pd(1) atoms.