NaTiS2 crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a linear geometry to two equivalent S(1) atoms. Ti(1) is bonded to six equivalent S(1) atoms to form edge-sharing TiS6 octahedra. S(1) is bonded in a rectangular see-saw-like geometry to one Na(1) and three equivalent Ti(1) atoms.
NaTiS2 crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a linear geometry to two equivalent S(1) atoms. Both Na(1)-S(1) bond lengths are 2.66 Å. Ti(1) is bonded to six equivalent S(1) atoms to form edge-sharing TiS6 octahedra. All Ti(1)-S(1) bond lengths are 2.48 Å. S(1) is bonded in a rectangular see-saw-like geometry to one Na(1) and three equivalent Ti(1) atoms.