NaNdO2 crystallizes in the tetragonal I4_1/amd space group. Na(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Nd(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing NdO6 octahedra. The corner-sharing octahedral tilt angles are 16°. O(1) is bonded to two equivalent Na(1) and three equivalent Nd(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Nd3 square pyramids.
NaNdO2 crystallizes in the tetragonal I4_1/amd space group. Na(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.39 Å. Nd(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing NdO6 octahedra. The corner-sharing octahedral tilt angles are 16°. There are four shorter (2.39 Å) and two longer (2.41 Å) Nd(1)-O(1) bond lengths. O(1) is bonded to two equivalent Na(1) and three equivalent Nd(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Nd3 square pyramids.