SrLa(RuO3)2 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. Sr(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(2), and four equivalent O(1) atoms. La(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(1), and four equivalent O(2) atoms. Ru(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), and two equivalent Ru(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Sr(1), two equivalent La(1), and two equivalent Ru(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), and two equivalent Ru(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), and two equivalent Ru(1) atoms.
SrLa(RuO3)2 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. Sr(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(2), and four equivalent O(1) atoms. The Sr(1)-O(3) bond length is 2.62 Å. The Sr(1)-O(4) bond length is 2.46 Å. Both Sr(1)-O(2) bond lengths are 2.48 Å. There are two shorter (2.75 Å) and two longer (2.79 Å) Sr(1)-O(1) bond lengths. La(1) is bonded in a 8-coordinate geometry to one O(3), one O(4), two equivalent O(1), and four equivalent O(2) atoms. The La(1)-O(3) bond length is 2.38 Å. The La(1)-O(4) bond length is 2.56 Å. Both La(1)-O(1) bond lengths are 2.41 Å. There are two shorter (2.69 Å) and two longer (2.80 Å) La(1)-O(2) bond lengths. Ru(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. The Ru(1)-O(3) bond length is 2.06 Å. The Ru(1)-O(4) bond length is 2.03 Å. There is one shorter (2.05 Å) and one longer (2.06 Å) Ru(1)-O(1) bond length. There is one shorter (2.04 Å) and one longer (2.05 Å) Ru(1)-O(2) bond length. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), and two equivalent Ru(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Sr(1), two equivalent La(1), and two equivalent Ru(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), and two equivalent Ru(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), and two equivalent Ru(1) atoms.