(FeCl4)2Fe(NCH)6 is Indium-like structured and crystallizes in the trigonal P-3 space group. The structure is zero-dimensional and consists of two tetrachloroferrat(iii) molecules and one Fe(NCH)6 cluster. In the Fe(NCH)6 cluster, Fe(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. C(1) is bonded in a linear geometry to one N(1) and one H(1) atom. N(1) is bonded in a linear geometry to one Fe(1) and one C(1) atom. H(1) is bonded in a single-bond geometry to one C(1) atom.
(FeCl4)2Fe(NCH)6 is Indium-like structured and crystallizes in the trigonal P-3 space group. The structure is zero-dimensional and consists of two tetrachloroferrat(iii) molecules and one Fe(NCH)6 cluster. In the Fe(NCH)6 cluster, Fe(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Fe(1)-N(1) bond lengths are 1.90 Å. C(1) is bonded in a linear geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.16 Å. The C(1)-H(1) bond length is 1.09 Å. N(1) is bonded in a linear geometry to one Fe(1) and one C(1) atom. H(1) is bonded in a single-bond geometry to one C(1) atom.