Zr2Mo3Co is Hexagonal Laves-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Zr(1) is bonded in a 12-coordinate geometry to nine equivalent Mo(1) and three equivalent Co(1) atoms. Mo(1) is bonded to six equivalent Zr(1), four equivalent Mo(1), and two equivalent Co(1) atoms to form MoZr6Co2Mo4 cuboctahedra that share corners with four equivalent Co(1)Zr6Mo6 cuboctahedra, corners with fourteen equivalent Mo(1)Zr6Co2Mo4 cuboctahedra, edges with six equivalent Mo(1)Zr6Co2Mo4 cuboctahedra, faces with six equivalent Co(1)Zr6Mo6 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6Co2Mo4 cuboctahedra. Co(1) is bonded to six equivalent Zr(1) and six equivalent Mo(1) atoms to form CoZr6Mo6 cuboctahedra that share corners with twelve equivalent Mo(1)Zr6Co2Mo4 cuboctahedra, edges with six equivalent Co(1)Zr6Mo6 cuboctahedra, faces with two equivalent Co(1)Zr6Mo6 cuboctahedra, and faces with eighteen equivalent Mo(1)Zr6Co2Mo4 cuboctahedra.
Zr2Mo3Co is Hexagonal Laves-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Zr(1) is bonded in a 12-coordinate geometry to nine equivalent Mo(1) and three equivalent Co(1) atoms. There are three shorter (3.09 Å) and six longer (3.11 Å) Zr(1)-Mo(1) bond lengths. All Zr(1)-Co(1) bond lengths are 3.08 Å. Mo(1) is bonded to six equivalent Zr(1), four equivalent Mo(1), and two equivalent Co(1) atoms to form MoZr6Co2Mo4 cuboctahedra that share corners with four equivalent Co(1)Zr6Mo6 cuboctahedra, corners with fourteen equivalent Mo(1)Zr6Co2Mo4 cuboctahedra, edges with six equivalent Mo(1)Zr6Co2Mo4 cuboctahedra, faces with six equivalent Co(1)Zr6Mo6 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6Co2Mo4 cuboctahedra. There are two shorter (2.60 Å) and two longer (2.65 Å) Mo(1)-Mo(1) bond lengths. Both Mo(1)-Co(1) bond lengths are 2.67 Å. Co(1) is bonded to six equivalent Zr(1) and six equivalent Mo(1) atoms to form CoZr6Mo6 cuboctahedra that share corners with twelve equivalent Mo(1)Zr6Co2Mo4 cuboctahedra, edges with six equivalent Co(1)Zr6Mo6 cuboctahedra, faces with two equivalent Co(1)Zr6Mo6 cuboctahedra, and faces with eighteen equivalent Mo(1)Zr6Co2Mo4 cuboctahedra.