DyCrO2 crystallizes in the tetragonal I4_1/amd space group. Dy(1) is bonded to six equivalent O(1) atoms to form edge-sharing DyO6 octahedra. Cr(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Dy(1) and two equivalent Cr(1) atoms to form a mixture of distorted corner and edge-sharing ODy3Cr2 trigonal bipyramids.
DyCrO2 crystallizes in the tetragonal I4_1/amd space group. Dy(1) is bonded to six equivalent O(1) atoms to form edge-sharing DyO6 octahedra. There are four shorter (2.35 Å) and two longer (2.38 Å) Dy(1)-O(1) bond lengths. Cr(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Cr(1)-O(1) bond lengths are 2.12 Å. O(1) is bonded to three equivalent Dy(1) and two equivalent Cr(1) atoms to form a mixture of distorted corner and edge-sharing ODy3Cr2 trigonal bipyramids.