ZnC2H8(N3S)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ZnC2H8(N3S)2 clusters. Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. C(1) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a distorted linear geometry to one Zn(1) and one C(1) atom. In the second N site, N(1) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. In the third N site, N(2) is bonded in a water-like geometry to one Zn(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a single-bond geometry to one C(1) atom.
ZnC2H8(N3S)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ZnC2H8(N3S)2 clusters. Zn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Both Zn(1)-N(1) bond lengths are 2.18 Å. Both Zn(1)-N(2) bond lengths are 2.34 Å. Both Zn(1)-N(3) bond lengths are 2.13 Å. C(1) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. The C(1)-N(3) bond length is 1.19 Å. The C(1)-S(1) bond length is 1.62 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a distorted linear geometry to one Zn(1) and one C(1) atom. In the second N site, N(1) is bonded in a distorted water-like geometry to one Zn(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.03 Å. In the third N site, N(2) is bonded in a water-like geometry to one Zn(1), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.03 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a single-bond geometry to one C(1) atom.