LiTaF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Ta(1)F6 octahedra. The corner-sharing octahedra are not tilted. Ta(1) is bonded to six equivalent F(1) atoms to form TaF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Li(1) and one Ta(1) atom.
LiTaF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Ta(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Li(1)-F(1) bond lengths are 1.98 Å. Ta(1) is bonded to six equivalent F(1) atoms to form TaF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Ta(1)-F(1) bond lengths are 1.91 Å. F(1) is bonded in a linear geometry to one Li(1) and one Ta(1) atom.