AgPO3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. P(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing PO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms.
AgPO3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. There are a spread of Ag(1)-O(1) bond distances ranging from 2.53-2.78 Å. There are a spread of Ag(1)-O(2) bond distances ranging from 2.58-2.74 Å. P(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing PO4 tetrahedra. The P(1)-O(1) bond length is 1.50 Å. The P(1)-O(2) bond length is 1.51 Å. There is one shorter (1.62 Å) and one longer (1.63 Å) P(1)-O(3) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms.