Sb3O4Cl crystallizes in the monoclinic P2/c space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(1), two equivalent O(2), and one Cl(1) atom. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. Cl(1) is bonded in an L-shaped geometry to two equivalent Sb(1) atoms.
Sb3O4Cl crystallizes in the monoclinic P2/c space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(1), two equivalent O(2), and one Cl(1) atom. The Sb(1)-O(1) bond length is 2.09 Å. There is one shorter (1.97 Å) and one longer (1.98 Å) Sb(1)-O(2) bond length. The Sb(1)-Cl(1) bond length is 2.97 Å. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (2.04 Å) and two longer (2.25 Å) Sb(2)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. Cl(1) is bonded in an L-shaped geometry to two equivalent Sb(1) atoms.