LiMn2O4 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are eighteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(32), one O(47), one O(48), and one O(54) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the second Li site, Li(2) is bonded to one O(10), one O(34), one O(37), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the third Li site, Li(3) is bonded to one O(20), one O(41), one O(6), and one O(65) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, and  a cornercorner with one Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the fourth Li site, Li(4) is bonded to one O(1), one O(15), one O(16), and one O(29) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the fifth Li site, Li(5) is bonded to one O(14), one O(28), one O(49), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. In the sixth Li site, Li(6) is bonded to one O(18), one O(24), one O(31), and one O(52) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the seventh Li site, Li(7) is bonded to one O(27), one O(42), one O(69), and one O(72) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. In the eighth Li site, Li(8) is bonded to one O(22), one O(23), one O(43), and one O(66) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. In the ninth Li site, Li(9) is bonded to one O(26), one O(33), one O(36), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the tenth Li site, Li(10) is bonded to one O(19), one O(30), one O(56), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra, and  a cornercorner with one Mn(35)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. In the eleventh Li site, Li(11) is bonded to one O(13), one O(2), one O(3), and one O(51) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. In the twelfth Li site, Li(12) is bonded to one O(12), one O(21), one O(5), and one O(68) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(50), one O(55), and one O(59) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. In the fourteenth Li site, Li(14) is bonded to one O(44), one O(57), one O(70), and one O(71) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. In the fifteenth Li site, Li(15) is bonded to one O(39), one O(45), one O(53), and one O(58) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra, and  a cornercorner with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the sixteenth Li site, Li(16) is bonded to one O(17), one O(25), one O(35), and one O(67) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the seventeenth Li site, Li(17) is bonded to one O(38), one O(40), one O(46), and one O(62) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the eighteenth Li site, Li(18) is bonded to one O(60), one O(61), one O(63), and one O(64) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. There are thirty-six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(22), one O(25), one O(57), one O(59), one O(63), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra, and  an edgeedge with one Mn(35)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(16), one O(41), one O(42), one O(56), one O(7), and one O(70) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra,  an edgeedge with one Mn(36)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(31), one O(4), one O(48), one O(49), one O(51), and one O(61) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(24), one O(34), one O(39), one O(50), and one O(66) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to one O(16), one O(20), one O(21), one O(26), one O(42), and one O(43) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(20), one O(29), one O(4), one O(43), and one O(61) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. In the seventh Mn site, Mn(7) is bonded to one O(31), one O(34), one O(35), one O(50), one O(51), and one O(54) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the eighth Mn site, Mn(8) is bonded to one O(31), one O(35), one O(38), one O(47), one O(49), and one O(55) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(11), one O(13), one O(23), one O(44), and one O(64) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra, and  an edgeedge with one Mn(33)O6 octahedra. In the tenth Mn site, Mn(10) is bonded to one O(21), one O(33), one O(42), one O(53), one O(56), and one O(71) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. In the eleventh Mn site, Mn(11) is bonded to one O(29), one O(3), one O(4), one O(48), one O(52), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. In the twelfth Mn site, Mn(12) is bonded to one O(10), one O(15), one O(3), one O(45), one O(6), and one O(62) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. In the thirteenth Mn site, Mn(13) is bonded to one O(23), one O(27), one O(44), one O(59), one O(63), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the fourteenth Mn site, Mn(14) is bonded to one O(30), one O(33), one O(46), one O(5), one O(53), and one O(67) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra, and  an edgeedge with one Mn(35)O6 octahedra. In the fifteenth Mn site, Mn(15) is bonded to one O(1), one O(11), one O(24), one O(36), one O(66), and one O(68) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the sixteenth Mn site, Mn(16) is bonded to one O(16), one O(21), one O(36), one O(39), one O(56), and one O(66) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. In the seventeenth Mn site, Mn(17) is bonded to one O(32), one O(35), one O(40), one O(49), one O(51), and one O(60) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the eighteenth Mn site, Mn(18) is bonded to one O(18), one O(19), one O(25), one O(47), one O(55), and one O(57) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the nineteenth Mn site, Mn(19) is bonded to one O(12), one O(18), one O(22), one O(25), one O(50), and one O(54) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the twentieth Mn site, Mn(20) is bonded to one O(17), one O(19), one O(28), one O(38), one O(47), and one O(58) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the twenty-first Mn site, Mn(21) is bonded to one O(1), one O(2), one O(26), one O(43), one O(64), and one O(68) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the twenty-second Mn site, Mn(22) is bonded to one O(11), one O(18), one O(22), one O(57), one O(64), and one O(68) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the twenty-third Mn site, Mn(23) is bonded to one O(17), one O(28), one O(32), one O(40), one O(65), and one O(69) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra, and  an edgeedge with one Mn(30)O6 octahedra. In the twenty-fourth Mn site, Mn(24) is bonded to one O(24), one O(30), one O(36), one O(37), one O(39), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra, and  an edgeedge with one Mn(4)O6 octahedra. In the twenty-fifth Mn site, Mn(25) is bonded to one O(10), one O(28), one O(58), one O(62), one O(65), and one O(72) atom to form MnO6 octahedra that share  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. In the twenty-sixth Mn site, Mn(26) is bonded to one O(10), one O(15), one O(2), one O(20), one O(26), and one O(72) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(36)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. In the twenty-seventh Mn site, Mn(27) is bonded to one O(13), one O(32), one O(44), one O(60), one O(69), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the twenty-eighth Mn site, Mn(28) is bonded to one O(17), one O(30), one O(37), one O(46), one O(58), and one O(65) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra, and  an edgeedge with one Mn(32)O6 octahedra. In the twenty-ninth Mn site, Mn(29) is bonded to one O(19), one O(38), one O(53), one O(55), one O(67), and one O(71) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the thirtieth Mn site, Mn(30) is bonded to one O(14), one O(40), one O(41), one O(60), one O(69), and one O(70) atom to form MnO6 octahedra that share  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. In the thirty-first Mn site, Mn(31) is bonded to one O(12), one O(3), one O(34), one O(45), one O(52), and one O(54) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the thirty-second Mn site, Mn(32) is bonded to one O(37), one O(45), one O(46), one O(5), one O(52), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra, and  an edgeedge with one Mn(31)O6 octahedra. In the thirty-third Mn site, Mn(33) is bonded to one O(13), one O(23), one O(29), one O(48), one O(61), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the thirty-fourth Mn site, Mn(34) is bonded to one O(14), one O(27), one O(63), one O(7), one O(70), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. In the thirty-fifth Mn site, Mn(35) is bonded to one O(27), one O(33), one O(59), one O(67), one O(71), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra, and  an edgeedge with one Mn(34)O6 octahedra. In the thirty-sixth Mn site, Mn(36) is bonded to one O(14), one O(15), one O(41), one O(62), one O(7), and one O(72) atom to form MnO6 octahedra that share  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra, and  an edgeedge with one Mn(34)O6 octahedra. There are seventy-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(15), one Mn(21), and one Mn(9) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(11), one Mn(21), one Mn(26), and one Mn(6) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(11), one Mn(11), one Mn(12), and one Mn(31) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(11), one Mn(3), and one Mn(6) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(12), one Mn(14), one Mn(24), and one Mn(32) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Mn(11), one Mn(12), and one Mn(32) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(9), one Mn(2), one Mn(34), and one Mn(36) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(13), one Mn(27), and one Mn(33) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(1), one Mn(34), and one Mn(35) atom. In the tenth O site, O(10) is bonded to one Li(2), one Mn(12), one Mn(25), and one Mn(26) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(13), one Mn(15), one Mn(22), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twelfth O site, O(12) is bonded to one Li(12), one Mn(19), one Mn(31), and one Mn(4) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(11), one Mn(27), one Mn(33), and one Mn(9) atom. In the fourteenth O site, O(14) is bonded to one Li(5), one Mn(30), one Mn(34), and one Mn(36) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(12), one Mn(26), and one Mn(36) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(16), one Mn(2), and one Mn(5) atom. In the seventeenth O site, O(17) is bonded to one Li(16), one Mn(20), one Mn(23), and one Mn(28) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(18), one Mn(19), and one Mn(22) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(18), one Mn(20), and one Mn(29) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Mn(26), one Mn(5), and one Mn(6) atom. In the twenty-first O site, O(21) is bonded in a distorted rectangular see-saw-like geometry to one Li(12), one Mn(10), one Mn(16), and one Mn(5) atom. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Mn(1), one Mn(19), and one Mn(22) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Li(8), one Mn(13), one Mn(33), and one Mn(9) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(15), one Mn(24), and one Mn(4) atom. In the twenty-fifth O site, O(25) is bonded in a distorted rectangular see-saw-like geometry to one Li(16), one Mn(1), one Mn(18), and one Mn(19) atom. In the twenty-sixth O site, O(26) is bonded to one Li(9), one Mn(21), one Mn(26), and one Mn(5) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the twenty-seventh O site, O(27) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(13), one Mn(34), and one Mn(35) atom. In the twenty-eighth O site, O(28) is bonded to one Li(5), one Mn(20), one Mn(23), and one Mn(25) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-ninth O site, O(29) is bonded to one Li(4), one Mn(11), one Mn(33), and one Mn(6) atom to form distorted edge-sharing OLiMn3 tetrahedra. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(14), one Mn(24), and one Mn(28) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(3), one Mn(7), and one Mn(8) atom. In the thirty-second O site, O(32) is bonded to one Li(1), one Mn(17), one Mn(23), and one Mn(27) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-third O site, O(33) is bonded in a rectangular see-saw-like geometry to one Li(9), one Mn(10), one Mn(14), and one Mn(35) atom. In the thirty-fourth O site, O(34) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(31), one Mn(4), and one Mn(7) atom. In the thirty-fifth O site, O(35) is bonded in a distorted rectangular see-saw-like geometry to one Li(16), one Mn(17), one Mn(7), and one Mn(8) atom. In the thirty-sixth O site, O(36) is bonded to one Li(9), one Mn(15), one Mn(16), and one Mn(24) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-seventh O site, O(37) is bonded to one Li(2), one Mn(24), one Mn(28), and one Mn(32) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-eighth O site, O(38) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(20), one Mn(29), and one Mn(8) atom. In the thirty-ninth O site, O(39) is bonded in a distorted rectangular see-saw-like geometry to one Li(15), one Mn(16), one Mn(24), and one Mn(4) atom. In the fortieth O site, O(40) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(17), one Mn(23), and one Mn(30) atom. In the forty-first O site, O(41) is bonded to one Li(3), one Mn(2), one Mn(30), and one Mn(36) atom to form distorted edge-sharing OLiMn3 tetrahedra. In the forty-second O site, O(42) is bonded in a rectangular see-saw-like geometry to one Li(7), one Mn(10), one Mn(2), and one Mn(5) atom. In the forty-third O site, O(43) is bonded in a rectangular see-saw-like geometry to one Li(8), one Mn(21), one Mn(5), and one Mn(6) atom. In the forty-fourth O site, O(44) is bonded to one Li(14), one Mn(13), one Mn(27), and one Mn(9) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the forty-fifth O site, O(45) is bonded in a distorted rectangular see-saw-like geometry to one Li(15), one Mn(12), one Mn(31), and one Mn(32) atom. In the forty-sixth O site, O(46) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(14), one Mn(28), and one Mn(32) atom. In the forty-seventh O site, O(47) is bonded to one Li(1), one Mn(18), one Mn(20), and one Mn(8) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the forty-eighth O site, O(48) is bonded in a rectangular see-saw-like geometry to one Li(1), one Mn(11), one Mn(3), and one Mn(33) atom. In the forty-ninth O site, O(49) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(17), one Mn(3), and one Mn(8) atom. In the fiftieth O site, O(50) is bonded to one Li(13), one Mn(19), one Mn(4), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the fifty-first O site, O(51) is bonded in a rectangular see-saw-like geometry to one Li(11), one Mn(17), one Mn(3), and one Mn(7) atom. In the fifty-second O site, O(52) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(11), one Mn(31), and one Mn(32) atom. In the fifty-third O site, O(53) is bonded to one Li(15), one Mn(10), one Mn(14), and one Mn(29) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the fifty-fourth O site, O(54) is bonded in a rectangular see-saw-like geometry to one Li(1), one Mn(19), one Mn(31), and one Mn(7) atom. In the fifty-fifth O site, O(55) is bonded in a distorted rectangular see-saw-like geometry to one Li(13), one Mn(18), one Mn(29), and one Mn(8) atom. In the fifty-sixth O site, O(56) is bonded in a rectangular see-saw-like geometry to one Li(10), one Mn(10), one Mn(16), and one Mn(2) atom. In the fifty-seventh O site, O(57) is bonded to one Li(14), one Mn(1), one Mn(18), and one Mn(22) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the fifty-eighth O site, O(58) is bonded to one Li(15), one Mn(20), one Mn(25), and one Mn(28) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fifty-ninth O site, O(59) is bonded in a distorted rectangular see-saw-like geometry to one Li(13), one Mn(1), one Mn(13), and one Mn(35) atom. In the sixtieth O site, O(60) is bonded in a distorted rectangular see-saw-like geometry to one Li(18), one Mn(17), one Mn(27), and one Mn(30) atom. In the sixty-first O site, O(61) is bonded to one Li(18), one Mn(3), one Mn(33), and one Mn(6) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the sixty-second O site, O(62) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(12), one Mn(25), and one Mn(36) atom. In the sixty-third O site, O(63) is bonded in a distorted rectangular see-saw-like geometry to one Li(18), one Mn(1), one Mn(13), and one Mn(34) atom. In the sixty-fourth O site, O(64) is bonded to one Li(18), one Mn(21), one Mn(22), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixty-fifth O site, O(65) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(23), one Mn(25), and one Mn(28) atom. In the sixty-sixth O site, O(66) is bonded in a rectangular see-saw-like geometry to one Li(8), one Mn(15), one Mn(16), and one Mn(4) atom. In the sixty-seventh O site, O(67) is bonded to one Li(16), one Mn(14), one Mn(29), and one Mn(35) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the sixty-eighth O site, O(68) is bonded to one Li(12), one Mn(15), one Mn(21), and one Mn(22) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixty-ninth O site, O(69) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(23), one Mn(27), and one Mn(30) atom. In the seventieth O site, O(70) is bonded in a rectangular see-saw-like geometry to one Li(14), one Mn(2), one Mn(30), and one Mn(34) atom. In the seventy-first O site, O(71) is bonded in a rectangular see-saw-like geometry to one Li(14), one Mn(10), one Mn(29), and one Mn(35) atom. In the seventy-second O site, O(72) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(25), one Mn(26), and one Mn(36) atom.
LiMn2O4 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are eighteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(32), one O(47), one O(48), and one O(54) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. The Li(1)-O(32) bond length is 2.07 Å. The Li(1)-O(47) bond length is 2.07 Å. The Li(1)-O(48) bond length is 1.97 Å. The Li(1)-O(54) bond length is 1.97 Å. In the second Li site, Li(2) is bonded to one O(10), one O(34), one O(37), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. The Li(2)-O(10) bond length is 2.07 Å. The Li(2)-O(34) bond length is 1.98 Å. The Li(2)-O(37) bond length is 2.07 Å. The Li(2)-O(4) bond length is 1.98 Å. In the third Li site, Li(3) is bonded to one O(20), one O(41), one O(6), and one O(65) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, and  a cornercorner with one Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. The Li(3)-O(20) bond length is 1.99 Å. The Li(3)-O(41) bond length is 2.02 Å. The Li(3)-O(6) bond length is 2.00 Å. The Li(3)-O(65) bond length is 1.98 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(15), one O(16), and one O(29) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. The Li(4)-O(1) bond length is 1.98 Å. The Li(4)-O(15) bond length is 1.99 Å. The Li(4)-O(16) bond length is 2.00 Å. The Li(4)-O(29) bond length is 2.02 Å. In the fifth Li site, Li(5) is bonded to one O(14), one O(28), one O(49), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. The Li(5)-O(14) bond length is 2.02 Å. The Li(5)-O(28) bond length is 1.97 Å. The Li(5)-O(49) bond length is 2.00 Å. The Li(5)-O(8) bond length is 1.99 Å. In the sixth Li site, Li(6) is bonded to one O(18), one O(24), one O(31), and one O(52) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. The Li(6)-O(18) bond length is 2.08 Å. The Li(6)-O(24) bond length is 2.08 Å. The Li(6)-O(31) bond length is 2.01 Å. The Li(6)-O(52) bond length is 2.02 Å. In the seventh Li site, Li(7) is bonded to one O(27), one O(42), one O(69), and one O(72) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. The Li(7)-O(27) bond length is 2.00 Å. The Li(7)-O(42) bond length is 2.00 Å. The Li(7)-O(69) bond length is 2.08 Å. The Li(7)-O(72) bond length is 2.08 Å. In the eighth Li site, Li(8) is bonded to one O(22), one O(23), one O(43), and one O(66) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. The Li(8)-O(22) bond length is 1.97 Å. The Li(8)-O(23) bond length is 1.97 Å. The Li(8)-O(43) bond length is 1.98 Å. The Li(8)-O(66) bond length is 1.97 Å. In the ninth Li site, Li(9) is bonded to one O(26), one O(33), one O(36), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. The Li(9)-O(26) bond length is 2.07 Å. The Li(9)-O(33) bond length is 1.98 Å. The Li(9)-O(36) bond length is 2.08 Å. The Li(9)-O(7) bond length is 1.98 Å. In the tenth Li site, Li(10) is bonded to one O(19), one O(30), one O(56), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra, and  a cornercorner with one Mn(35)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. The Li(10)-O(19) bond length is 2.08 Å. The Li(10)-O(30) bond length is 2.08 Å. The Li(10)-O(56) bond length is 2.01 Å. The Li(10)-O(9) bond length is 2.00 Å. In the eleventh Li site, Li(11) is bonded to one O(13), one O(2), one O(3), and one O(51) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(26)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-64°. The Li(11)-O(13) bond length is 2.07 Å. The Li(11)-O(2) bond length is 2.08 Å. The Li(11)-O(3) bond length is 2.01 Å. The Li(11)-O(51) bond length is 2.01 Å. In the twelfth Li site, Li(12) is bonded to one O(12), one O(21), one O(5), and one O(68) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and  a cornercorner with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. The Li(12)-O(12) bond length is 2.02 Å. The Li(12)-O(21) bond length is 1.99 Å. The Li(12)-O(5) bond length is 2.00 Å. The Li(12)-O(68) bond length is 1.98 Å. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(50), one O(55), and one O(59) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. The Li(13)-O(11) bond length is 1.98 Å. The Li(13)-O(50) bond length is 2.02 Å. The Li(13)-O(55) bond length is 2.00 Å. The Li(13)-O(59) bond length is 2.00 Å. In the fourteenth Li site, Li(14) is bonded to one O(44), one O(57), one O(70), and one O(71) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. The Li(14)-O(44) bond length is 2.07 Å. The Li(14)-O(57) bond length is 2.07 Å. The Li(14)-O(70) bond length is 1.97 Å. The Li(14)-O(71) bond length is 1.97 Å. In the fifteenth Li site, Li(15) is bonded to one O(39), one O(45), one O(53), and one O(58) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(16)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(24)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(31)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra, and  a cornercorner with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. The Li(15)-O(39) bond length is 2.00 Å. The Li(15)-O(45) bond length is 1.99 Å. The Li(15)-O(53) bond length is 2.02 Å. The Li(15)-O(58) bond length is 1.98 Å. In the sixteenth Li site, Li(16) is bonded to one O(17), one O(25), one O(35), and one O(67) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(18)O6 octahedra,  a cornercorner with one Mn(19)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(35)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. The Li(16)-O(17) bond length is 1.98 Å. The Li(16)-O(25) bond length is 1.99 Å. The Li(16)-O(35) bond length is 2.00 Å. The Li(16)-O(67) bond length is 2.02 Å. In the seventeenth Li site, Li(17) is bonded to one O(38), one O(40), one O(46), and one O(62) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(20)O6 octahedra,  a cornercorner with one Mn(23)O6 octahedra,  a cornercorner with one Mn(25)O6 octahedra,  a cornercorner with one Mn(28)O6 octahedra,  a cornercorner with one Mn(29)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(32)O6 octahedra,  a cornercorner with one Mn(36)O6 octahedra, and  a cornercorner with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. The Li(17)-O(38) bond length is 1.97 Å. The Li(17)-O(40) bond length is 1.97 Å. The Li(17)-O(46) bond length is 1.97 Å. The Li(17)-O(62) bond length is 1.97 Å. In the eighteenth Li site, Li(18) is bonded to one O(60), one O(61), one O(63), and one O(64) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(17)O6 octahedra,  a cornercorner with one Mn(21)O6 octahedra,  a cornercorner with one Mn(22)O6 octahedra,  a cornercorner with one Mn(27)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(30)O6 octahedra,  a cornercorner with one Mn(33)O6 octahedra,  a cornercorner with one Mn(34)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra, and  a cornercorner with one Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. The Li(18)-O(60) bond length is 1.99 Å. The Li(18)-O(61) bond length is 2.02 Å. The Li(18)-O(63) bond length is 2.00 Å. The Li(18)-O(64) bond length is 1.98 Å. There are thirty-six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(22), one O(25), one O(57), one O(59), one O(63), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra, and  an edgeedge with one Mn(35)O6 octahedra. The Mn(1)-O(22) bond length is 1.93 Å. The Mn(1)-O(25) bond length is 1.93 Å. The Mn(1)-O(57) bond length is 1.98 Å. The Mn(1)-O(59) bond length is 1.96 Å. The Mn(1)-O(63) bond length is 1.96 Å. The Mn(1)-O(9) bond length is 1.94 Å. In the second Mn site, Mn(2) is bonded to one O(16), one O(41), one O(42), one O(56), one O(7), and one O(70) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra,  an edgeedge with one Mn(36)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The Mn(2)-O(16) bond length is 2.07 Å. The Mn(2)-O(41) bond length is 1.96 Å. The Mn(2)-O(42) bond length is 2.16 Å. The Mn(2)-O(56) bond length is 1.92 Å. The Mn(2)-O(7) bond length is 2.11 Å. The Mn(2)-O(70) bond length is 2.04 Å. In the third Mn site, Mn(3) is bonded to one O(31), one O(4), one O(48), one O(49), one O(51), and one O(61) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(3)-O(31) bond length is 1.92 Å. The Mn(3)-O(4) bond length is 2.04 Å. The Mn(3)-O(48) bond length is 2.10 Å. The Mn(3)-O(49) bond length is 2.06 Å. The Mn(3)-O(51) bond length is 2.16 Å. The Mn(3)-O(61) bond length is 1.96 Å. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(24), one O(34), one O(39), one O(50), and one O(66) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The Mn(4)-O(12) bond length is 1.99 Å. The Mn(4)-O(24) bond length is 1.96 Å. The Mn(4)-O(34) bond length is 1.91 Å. The Mn(4)-O(39) bond length is 1.92 Å. The Mn(4)-O(50) bond length is 1.97 Å. The Mn(4)-O(66) bond length is 1.93 Å. In the fifth Mn site, Mn(5) is bonded to one O(16), one O(20), one O(21), one O(26), one O(42), and one O(43) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. The Mn(5)-O(16) bond length is 1.95 Å. The Mn(5)-O(20) bond length is 1.93 Å. The Mn(5)-O(21) bond length is 1.95 Å. The Mn(5)-O(26) bond length is 1.98 Å. The Mn(5)-O(42) bond length is 1.94 Å. The Mn(5)-O(43) bond length is 1.93 Å. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(20), one O(29), one O(4), one O(43), and one O(61) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The Mn(6)-O(2) bond length is 1.97 Å. The Mn(6)-O(20) bond length is 1.92 Å. The Mn(6)-O(29) bond length is 1.99 Å. The Mn(6)-O(4) bond length is 1.91 Å. The Mn(6)-O(43) bond length is 1.94 Å. The Mn(6)-O(61) bond length is 1.97 Å. In the seventh Mn site, Mn(7) is bonded to one O(31), one O(34), one O(35), one O(50), one O(51), and one O(54) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(7)-O(31) bond length is 2.15 Å. The Mn(7)-O(34) bond length is 2.05 Å. The Mn(7)-O(35) bond length is 2.07 Å. The Mn(7)-O(50) bond length is 1.96 Å. The Mn(7)-O(51) bond length is 1.92 Å. The Mn(7)-O(54) bond length is 2.08 Å. In the eighth Mn site, Mn(8) is bonded to one O(31), one O(35), one O(38), one O(47), one O(49), and one O(55) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The Mn(8)-O(31) bond length is 1.94 Å. The Mn(8)-O(35) bond length is 1.95 Å. The Mn(8)-O(38) bond length is 1.93 Å. The Mn(8)-O(47) bond length is 1.99 Å. The Mn(8)-O(49) bond length is 1.95 Å. The Mn(8)-O(55) bond length is 1.93 Å. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(11), one O(13), one O(23), one O(44), and one O(64) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra, and  an edgeedge with one Mn(33)O6 octahedra. The Mn(9)-O(1) bond length is 1.93 Å. The Mn(9)-O(11) bond length is 1.99 Å. The Mn(9)-O(13) bond length is 2.04 Å. The Mn(9)-O(23) bond length is 2.14 Å. The Mn(9)-O(44) bond length is 1.97 Å. The Mn(9)-O(64) bond length is 2.13 Å. In the tenth Mn site, Mn(10) is bonded to one O(21), one O(33), one O(42), one O(53), one O(56), and one O(71) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The Mn(10)-O(21) bond length is 2.07 Å. The Mn(10)-O(33) bond length is 2.10 Å. The Mn(10)-O(42) bond length is 1.92 Å. The Mn(10)-O(53) bond length is 1.95 Å. The Mn(10)-O(56) bond length is 2.15 Å. The Mn(10)-O(71) bond length is 2.05 Å. In the eleventh Mn site, Mn(11) is bonded to one O(29), one O(3), one O(4), one O(48), one O(52), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. The Mn(11)-O(29) bond length is 1.96 Å. The Mn(11)-O(3) bond length is 2.15 Å. The Mn(11)-O(4) bond length is 2.10 Å. The Mn(11)-O(48) bond length is 2.05 Å. The Mn(11)-O(52) bond length is 1.92 Å. The Mn(11)-O(6) bond length is 2.08 Å. In the twelfth Mn site, Mn(12) is bonded to one O(10), one O(15), one O(3), one O(45), one O(6), and one O(62) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. The Mn(12)-O(10) bond length is 1.99 Å. The Mn(12)-O(15) bond length is 1.93 Å. The Mn(12)-O(3) bond length is 1.94 Å. The Mn(12)-O(45) bond length is 1.94 Å. The Mn(12)-O(6) bond length is 1.95 Å. The Mn(12)-O(62) bond length is 1.93 Å. In the thirteenth Mn site, Mn(13) is bonded to one O(23), one O(27), one O(44), one O(59), one O(63), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(13)-O(23) bond length is 1.93 Å. The Mn(13)-O(27) bond length is 1.94 Å. The Mn(13)-O(44) bond length is 1.98 Å. The Mn(13)-O(59) bond length is 1.96 Å. The Mn(13)-O(63) bond length is 1.96 Å. The Mn(13)-O(8) bond length is 1.93 Å. In the fourteenth Mn site, Mn(14) is bonded to one O(30), one O(33), one O(46), one O(5), one O(53), and one O(67) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra, and  an edgeedge with one Mn(35)O6 octahedra. The Mn(14)-O(30) bond length is 1.97 Å. The Mn(14)-O(33) bond length is 1.91 Å. The Mn(14)-O(46) bond length is 1.94 Å. The Mn(14)-O(5) bond length is 1.93 Å. The Mn(14)-O(53) bond length is 1.99 Å. The Mn(14)-O(67) bond length is 1.97 Å. In the fifteenth Mn site, Mn(15) is bonded to one O(1), one O(11), one O(24), one O(36), one O(66), and one O(68) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(15)-O(1) bond length is 2.00 Å. The Mn(15)-O(11) bond length is 1.92 Å. The Mn(15)-O(24) bond length is 2.05 Å. The Mn(15)-O(36) bond length is 1.97 Å. The Mn(15)-O(66) bond length is 2.15 Å. The Mn(15)-O(68) bond length is 2.15 Å. In the sixteenth Mn site, Mn(16) is bonded to one O(16), one O(21), one O(36), one O(39), one O(56), and one O(66) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The Mn(16)-O(16) bond length is 1.95 Å. The Mn(16)-O(21) bond length is 1.95 Å. The Mn(16)-O(36) bond length is 1.99 Å. The Mn(16)-O(39) bond length is 1.93 Å. The Mn(16)-O(56) bond length is 1.94 Å. The Mn(16)-O(66) bond length is 1.93 Å. In the seventeenth Mn site, Mn(17) is bonded to one O(32), one O(35), one O(40), one O(49), one O(51), and one O(60) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(17)-O(32) bond length is 1.98 Å. The Mn(17)-O(35) bond length is 1.95 Å. The Mn(17)-O(40) bond length is 1.93 Å. The Mn(17)-O(49) bond length is 1.95 Å. The Mn(17)-O(51) bond length is 1.94 Å. The Mn(17)-O(60) bond length is 1.93 Å. In the eighteenth Mn site, Mn(18) is bonded to one O(18), one O(19), one O(25), one O(47), one O(55), and one O(57) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(18)-O(18) bond length is 1.97 Å. The Mn(18)-O(19) bond length is 1.98 Å. The Mn(18)-O(25) bond length is 2.21 Å. The Mn(18)-O(47) bond length is 2.00 Å. The Mn(18)-O(55) bond length is 2.21 Å. The Mn(18)-O(57) bond length is 2.00 Å. In the nineteenth Mn site, Mn(19) is bonded to one O(12), one O(18), one O(22), one O(25), one O(50), and one O(54) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(31)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The Mn(19)-O(12) bond length is 1.97 Å. The Mn(19)-O(18) bond length is 1.96 Å. The Mn(19)-O(22) bond length is 1.94 Å. The Mn(19)-O(25) bond length is 1.92 Å. The Mn(19)-O(50) bond length is 1.99 Å. The Mn(19)-O(54) bond length is 1.91 Å. In the twentieth Mn site, Mn(20) is bonded to one O(17), one O(19), one O(28), one O(38), one O(47), and one O(58) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(20)-O(17) bond length is 2.13 Å. The Mn(20)-O(19) bond length is 2.04 Å. The Mn(20)-O(28) bond length is 1.99 Å. The Mn(20)-O(38) bond length is 2.13 Å. The Mn(20)-O(47) bond length is 1.97 Å. The Mn(20)-O(58) bond length is 1.92 Å. In the twenty-first Mn site, Mn(21) is bonded to one O(1), one O(2), one O(26), one O(43), one O(64), and one O(68) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(22)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(21)-O(1) bond length is 2.12 Å. The Mn(21)-O(2) bond length is 2.03 Å. The Mn(21)-O(26) bond length is 1.97 Å. The Mn(21)-O(43) bond length is 2.12 Å. The Mn(21)-O(64) bond length is 1.92 Å. The Mn(21)-O(68) bond length is 1.98 Å. In the twenty-second Mn site, Mn(22) is bonded to one O(11), one O(18), one O(22), one O(57), one O(64), and one O(68) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(22)-O(11) bond length is 2.14 Å. The Mn(22)-O(18) bond length is 2.05 Å. The Mn(22)-O(22) bond length is 2.14 Å. The Mn(22)-O(57) bond length is 1.97 Å. The Mn(22)-O(64) bond length is 2.00 Å. The Mn(22)-O(68) bond length is 1.92 Å. In the twenty-third Mn site, Mn(23) is bonded to one O(17), one O(28), one O(32), one O(40), one O(65), and one O(69) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra, and  an edgeedge with one Mn(30)O6 octahedra. The Mn(23)-O(17) bond length is 1.99 Å. The Mn(23)-O(28) bond length is 2.14 Å. The Mn(23)-O(32) bond length is 1.97 Å. The Mn(23)-O(40) bond length is 2.14 Å. The Mn(23)-O(65) bond length is 1.93 Å. The Mn(23)-O(69) bond length is 2.03 Å. In the twenty-fourth Mn site, Mn(24) is bonded to one O(24), one O(30), one O(36), one O(37), one O(39), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(16)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The Mn(24)-O(24) bond length is 1.98 Å. The Mn(24)-O(30) bond length is 1.98 Å. The Mn(24)-O(36) bond length is 2.00 Å. The Mn(24)-O(37) bond length is 2.00 Å. The Mn(24)-O(39) bond length is 2.22 Å. The Mn(24)-O(5) bond length is 2.22 Å. In the twenty-fifth Mn site, Mn(25) is bonded to one O(10), one O(28), one O(58), one O(62), one O(65), and one O(72) atom to form MnO6 octahedra that share  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. The Mn(25)-O(10) bond length is 1.97 Å. The Mn(25)-O(28) bond length is 1.92 Å. The Mn(25)-O(58) bond length is 1.98 Å. The Mn(25)-O(62) bond length is 2.12 Å. The Mn(25)-O(65) bond length is 2.12 Å. The Mn(25)-O(72) bond length is 2.03 Å. In the twenty-sixth Mn site, Mn(26) is bonded to one O(10), one O(15), one O(2), one O(20), one O(26), and one O(72) atom to form MnO6 octahedra that share  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(21)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(36)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. The Mn(26)-O(10) bond length is 2.00 Å. The Mn(26)-O(15) bond length is 2.21 Å. The Mn(26)-O(2) bond length is 1.98 Å. The Mn(26)-O(20) bond length is 2.21 Å. The Mn(26)-O(26) bond length is 2.00 Å. The Mn(26)-O(72) bond length is 1.98 Å. In the twenty-seventh Mn site, Mn(27) is bonded to one O(13), one O(32), one O(44), one O(60), one O(69), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(33)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(27)-O(13) bond length is 1.98 Å. The Mn(27)-O(32) bond length is 1.99 Å. The Mn(27)-O(44) bond length is 1.99 Å. The Mn(27)-O(60) bond length is 2.21 Å. The Mn(27)-O(69) bond length is 1.98 Å. The Mn(27)-O(8) bond length is 2.21 Å. In the twenty-eighth Mn site, Mn(28) is bonded to one O(17), one O(30), one O(37), one O(46), one O(58), and one O(65) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra, and  an edgeedge with one Mn(32)O6 octahedra. The Mn(28)-O(17) bond length is 1.92 Å. The Mn(28)-O(30) bond length is 2.04 Å. The Mn(28)-O(37) bond length is 1.97 Å. The Mn(28)-O(46) bond length is 2.14 Å. The Mn(28)-O(58) bond length is 2.15 Å. The Mn(28)-O(65) bond length is 2.00 Å. In the twenty-ninth Mn site, Mn(29) is bonded to one O(19), one O(38), one O(53), one O(55), one O(67), and one O(71) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(18)O6 octahedra,  an edgeedge with one Mn(20)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(29)-O(19) bond length is 1.97 Å. The Mn(29)-O(38) bond length is 1.94 Å. The Mn(29)-O(53) bond length is 1.97 Å. The Mn(29)-O(55) bond length is 1.93 Å. The Mn(29)-O(67) bond length is 1.99 Å. The Mn(29)-O(71) bond length is 1.91 Å. In the thirtieth Mn site, Mn(30) is bonded to one O(14), one O(40), one O(41), one O(60), one O(69), and one O(70) atom to form MnO6 octahedra that share  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(17)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(23)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(34)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. The Mn(30)-O(14) bond length is 1.99 Å. The Mn(30)-O(40) bond length is 1.94 Å. The Mn(30)-O(41) bond length is 1.97 Å. The Mn(30)-O(60) bond length is 1.92 Å. The Mn(30)-O(69) bond length is 1.97 Å. The Mn(30)-O(70) bond length is 1.91 Å. In the thirty-first Mn site, Mn(31) is bonded to one O(12), one O(3), one O(34), one O(45), one O(52), and one O(54) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(19)O6 octahedra,  an edgeedge with one Mn(32)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The Mn(31)-O(12) bond length is 1.95 Å. The Mn(31)-O(3) bond length is 1.92 Å. The Mn(31)-O(34) bond length is 2.08 Å. The Mn(31)-O(45) bond length is 2.09 Å. The Mn(31)-O(52) bond length is 2.14 Å. The Mn(31)-O(54) bond length is 2.07 Å. In the thirty-second Mn site, Mn(32) is bonded to one O(37), one O(45), one O(46), one O(5), one O(52), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(24)O6 octahedra,  an edgeedge with one Mn(28)O6 octahedra, and  an edgeedge with one Mn(31)O6 octahedra. The Mn(32)-O(37) bond length is 1.99 Å. The Mn(32)-O(45) bond length is 1.94 Å. The Mn(32)-O(46) bond length is 1.93 Å. The Mn(32)-O(5) bond length is 1.93 Å. The Mn(32)-O(52) bond length is 1.95 Å. The Mn(32)-O(6) bond length is 1.95 Å. In the thirty-third Mn site, Mn(33) is bonded to one O(13), one O(23), one O(29), one O(48), one O(61), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(11)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(27)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(33)-O(13) bond length is 1.96 Å. The Mn(33)-O(23) bond length is 1.94 Å. The Mn(33)-O(29) bond length is 1.98 Å. The Mn(33)-O(48) bond length is 1.91 Å. The Mn(33)-O(61) bond length is 1.99 Å. The Mn(33)-O(8) bond length is 1.92 Å. In the thirty-fourth Mn site, Mn(34) is bonded to one O(14), one O(27), one O(63), one O(7), one O(70), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(18)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra,  an edgeedge with one Mn(35)O6 octahedra, and  an edgeedge with one Mn(36)O6 octahedra. The Mn(34)-O(14) bond length is 1.96 Å. The Mn(34)-O(27) bond length is 2.16 Å. The Mn(34)-O(63) bond length is 2.05 Å. The Mn(34)-O(7) bond length is 2.02 Å. The Mn(34)-O(70) bond length is 2.11 Å. The Mn(34)-O(9) bond length is 1.93 Å. In the thirty-fifth Mn site, Mn(35) is bonded to one O(27), one O(33), one O(59), one O(67), one O(71), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(14)O4 tetrahedra,  a cornercorner with one Li(16)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(29)O6 octahedra, and  an edgeedge with one Mn(34)O6 octahedra. The Mn(35)-O(27) bond length is 1.93 Å. The Mn(35)-O(33) bond length is 2.02 Å. The Mn(35)-O(59) bond length is 2.05 Å. The Mn(35)-O(67) bond length is 1.96 Å. The Mn(35)-O(71) bond length is 2.11 Å. The Mn(35)-O(9) bond length is 2.16 Å. In the thirty-sixth Mn site, Mn(36) is bonded to one O(14), one O(15), one O(41), one O(62), one O(7), and one O(72) atom to form MnO6 octahedra that share  a cornercorner with one Li(17)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(25)O6 octahedra,  an edgeedge with one Mn(26)O6 octahedra,  an edgeedge with one Mn(30)O6 octahedra, and  an edgeedge with one Mn(34)O6 octahedra. The Mn(36)-O(14) bond length is 1.97 Å. The Mn(36)-O(15) bond length is 1.93 Å. The Mn(36)-O(41) bond length is 1.99 Å. The Mn(36)-O(62) bond length is 1.94 Å. The Mn(36)-O(7) bond length is 1.91 Å. The Mn(36)-O(72) bond length is 1.97 Å. There are seventy-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(15), one Mn(21), and one Mn(9) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(11), one Mn(21), one Mn(26), and one Mn(6) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(11), one Mn(11), one Mn(12), and one Mn(31) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(11), one Mn(3), and one Mn(6) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(12), one Mn(14), one Mn(24), and one Mn(32) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Mn(11), one Mn(12), and one Mn(32) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(9), one Mn(2), one Mn(34), and one Mn(36) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(13), one Mn(27), and one Mn(33) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(1), one Mn(34), and one Mn(35) atom. In the tenth O site, O(10) is bonded to one Li(2), one Mn(12), one Mn(25), and one Mn(26) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(13), one Mn(15), one Mn(22), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twelfth O site, O(12) is bonded to one Li(12), one Mn(19), one Mn(31), and one Mn(4) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(11), one Mn(27), one Mn(33), and one Mn(9) atom. In the fourteenth O site, O(14) is bonded to one Li(5), one Mn(30), one Mn(34), and one Mn(36) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(12), one Mn(26), and one Mn(36) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(16), one Mn(2), and one Mn(5) atom. In the seventeenth O site, O(17) is bonded to one Li(16), one Mn(20), one Mn(23), and one Mn(28) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(18), one Mn(19), and one Mn(22) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(18), one Mn(20), and one Mn(29) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Mn(26), one Mn(5), and one Mn(6) atom. In the twenty-first O site, O(21) is bonded in a distorted rectangular see-saw-like geometry to one Li(12), one Mn(10), one Mn(16), and one Mn(5) atom. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Mn(1), one Mn(19), and one Mn(22) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Li(8), one Mn(13), one Mn(33), and one Mn(9) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(15), one Mn(24), and one Mn(4) atom. In the twenty-fifth O site, O(25) is bonded in a distorted rectangular see-saw-like geometry to one Li(16), one Mn(1), one Mn(18), and one Mn(19) atom. In the twenty-sixth O site, O(26) is bonded to one Li(9), one Mn(21), one Mn(26), and one Mn(5) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the twenty-seventh O site, O(27) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(13), one Mn(34), and one Mn(35) atom. In the twenty-eighth O site, O(28) is bonded to one Li(5), one Mn(20), one Mn(23), and one Mn(25) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-ninth O site, O(29) is bonded to one Li(4), one Mn(11), one Mn(33), and one Mn(6) atom to form distorted edge-sharing OLiMn3 tetrahedra. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(14), one Mn(24), and one Mn(28) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(3), one Mn(7), and one Mn(8) atom. In the thirty-second O site, O(32) is bonded to one Li(1), one Mn(17), one Mn(23), and one Mn(27) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-third O site, O(33) is bonded in a rectangular see-saw-like geometry to one Li(9), one Mn(10), one Mn(14), and one Mn(35) atom. In the thirty-fourth O site, O(34) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(31), one Mn(4), and one Mn(7) atom. In the thirty-fifth O site, O(35) is bonded in a distorted rectangular see-saw-like geometry to one Li(16), one Mn(17), one Mn(7), and one Mn(8) atom. In the thirty-sixth O site, O(36) is bonded to one Li(9), one Mn(15), one Mn(16), and one Mn(24) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-seventh O site, O(37) is bonded to one Li(2), one Mn(24), one Mn(28), and one Mn(32) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-eighth O site, O(38) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(20), one Mn(29), and one Mn(8) atom. In the thirty-ninth O site, O(39) is bonded in a distorted rectangular see-saw-like geometry to one Li(15), one Mn(16), one Mn(24), and one Mn(4) atom. In the fortieth O site, O(40) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(17), one Mn(23), and one Mn(30) atom. In the forty-first O site, O(41) is bonded to one Li(3), one Mn(2), one Mn(30), and one Mn(36) atom to form distorted edge-sharing OLiMn3 tetrahedra. In the forty-second O site, O(42) is bonded in a rectangular see-saw-like geometry to one Li(7), one Mn(10), one Mn(2), and one Mn(5) atom. In the forty-third O site, O(43) is bonded in a rectangular see-saw-like geometry to one Li(8), one Mn(21), one Mn(5), and one Mn(6) atom. In the forty-fourth O site, O(44) is bonded to one Li(14), one Mn(13), one Mn(27), and one Mn(9) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the forty-fifth O site, O(45) is bonded in a distorted rectangular see-saw-like geometry to one Li(15), one Mn(12), one Mn(31), and one Mn(32) atom. In the forty-sixth O site, O(46) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(14), one Mn(28), and one Mn(32) atom. In the forty-seventh O site, O(47) is bonded to one Li(1), one Mn(18), one Mn(20), and one Mn(8) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the forty-eighth O site, O(48) is bonded in a rectangular see-saw-like geometry to one Li(1), one Mn(11), one Mn(3), and one Mn(33) atom. In the forty-ninth O site, O(49) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(17), one Mn(3), and one Mn(8) atom. In the fiftieth O site, O(50) is bonded to one Li(13), one Mn(19), one Mn(4), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the fifty-first O site, O(51) is bonded in a rectangular see-saw-like geometry to one Li(11), one Mn(17), one Mn(3), and one Mn(7) atom. In the fifty-second O site, O(52) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(11), one Mn(31), and one Mn(32) atom. In the fifty-third O site, O(53) is bonded to one Li(15), one Mn(10), one Mn(14), and one Mn(29) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the fifty-fourth O site, O(54) is bonded in a rectangular see-saw-like geometry to one Li(1), one Mn(19), one Mn(31), and one Mn(7) atom. In the fifty-fifth O site, O(55) is bonded in a distorted rectangular see-saw-like geometry to one Li(13), one Mn(18), one Mn(29), and one Mn(8) atom. In the fifty-sixth O site, O(56) is bonded in a rectangular see-saw-like geometry to one Li(10), one Mn(10), one Mn(16), and one Mn(2) atom. In the fifty-seventh O site, O(57) is bonded to one Li(14), one Mn(1), one Mn(18), and one Mn(22) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the fifty-eighth O site, O(58) is bonded to one Li(15), one Mn(20), one Mn(25), and one Mn(28) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fifty-ninth O site, O(59) is bonded in a distorted rectangular see-saw-like geometry to one Li(13), one Mn(1), one Mn(13), and one Mn(35) atom. In the sixtieth O site, O(60) is bonded in a distorted rectangular see-saw-like geometry to one Li(18), one Mn(17), one Mn(27), and one Mn(30) atom. In the sixty-first O site, O(61) is bonded to one Li(18), one Mn(3), one Mn(33), and one Mn(6) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the sixty-second O site, O(62) is bonded in a rectangular see-saw-like geometry to one Li(17), one Mn(12), one Mn(25), and one Mn(36) atom. In the sixty-third O site, O(63) is bonded in a distorted rectangular see-saw-like geometry to one Li(18), one Mn(1), one Mn(13), and one Mn(34) atom. In the sixty-fourth O site, O(64) is bonded to one Li(18), one Mn(21), one Mn(22), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixty-fifth O site, O(65) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(23), one Mn(25), and one Mn(28) atom. In the sixty-sixth O site, O(66) is bonded in a rectangular see-saw-like geometry to one Li(8), one Mn(15), one Mn(16), and one Mn(4) atom. In the sixty-seventh O site, O(67) is bonded to one Li(16), one Mn(14), one Mn(29), and one Mn(35) atom to form a mixture of distorted edge and corner-sharing OLiMn3 tetrahedra. In the sixty-eighth O site, O(68) is bonded to one Li(12), one Mn(15), one Mn(21), and one Mn(22) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixty-ninth O site, O(69) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(23), one Mn(27), and one Mn(30) atom. In the seventieth O site, O(70) is bonded in a rectangular see-saw-like geometry to one Li(14), one Mn(2), one Mn(30), and one Mn(34) atom. In the seventy-first O site, O(71) is bonded in a rectangular see-saw-like geometry to one Li(14), one Mn(10), one Mn(29), and one Mn(35) atom. In the seventy-second O site, O(72) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(25), one Mn(26), and one Mn(36) atom.