ReNF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReNF6 clusters. Re(1) is bonded in an octahedral geometry to one N(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. N(1) is bonded in a linear geometry to one Re(1) and one F(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Re(1) atom.
ReNF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReNF6 clusters. Re(1) is bonded in an octahedral geometry to one N(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Re(1)-N(1) bond length is 1.74 Å. The Re(1)-F(2) bond length is 1.91 Å. The Re(1)-F(3) bond length is 1.88 Å. The Re(1)-F(4) bond length is 1.88 Å. The Re(1)-F(5) bond length is 1.88 Å. The Re(1)-F(6) bond length is 1.88 Å. N(1) is bonded in a linear geometry to one Re(1) and one F(1) atom. The N(1)-F(1) bond length is 1.29 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Re(1) atom.