ZrTi(PbO3)2 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the tetragonal P4mm space group. Zr(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form distorted corner-sharing ZrO6 octahedra. The corner-sharing octahedra are not tilted. Ti(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Pb(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Zr(1), one Ti(1), and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third O site, O(3) is bonded in a distorted linear geometry to two equivalent Zr(1) atoms.
ZrTi(PbO3)2 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the tetragonal P4mm space group. Zr(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form distorted corner-sharing ZrO6 octahedra. The corner-sharing octahedra are not tilted. There is one shorter (1.99 Å) and one longer (2.44 Å) Zr(1)-O(3) bond length. All Zr(1)-O(1) bond lengths are 2.12 Å. Ti(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. The Ti(1)-O(2) bond length is 1.75 Å. All Ti(1)-O(1) bond lengths are 1.99 Å. Pb(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Pb(1)-O(1) bond lengths are 2.54 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Zr(1), one Ti(1), and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third O site, O(3) is bonded in a distorted linear geometry to two equivalent Zr(1) atoms.