Li2PdO2 is Ilmenite-like structured and crystallizes in the orthorhombic Immm space group. Li(1) is bonded to four equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing LiO4 trigonal pyramids. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Li(1) and two equivalent Pd(1) atoms to form a mixture of corner and edge-sharing OLi4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-31°.
Li2PdO2 is Ilmenite-like structured and crystallizes in the orthorhombic Immm space group. Li(1) is bonded to four equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing LiO4 trigonal pyramids. There are two shorter (1.93 Å) and two longer (1.99 Å) Li(1)-O(1) bond lengths. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Pd(1)-O(1) bond lengths are 2.04 Å. O(1) is bonded to four equivalent Li(1) and two equivalent Pd(1) atoms to form a mixture of corner and edge-sharing OLi4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-31°.