LiSbF4 crystallizes in the cubic P2_13 space group. Li(1) is bonded in a tetrahedral geometry to one F(2) and three equivalent F(1) atoms. Sb(1) is bonded in a 6-coordinate geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Li(1) and three equivalent Sb(1) atoms.
LiSbF4 crystallizes in the cubic P2_13 space group. Li(1) is bonded in a tetrahedral geometry to one F(2) and three equivalent F(1) atoms. The Li(1)-F(2) bond length is 1.85 Å. All Li(1)-F(1) bond lengths are 1.83 Å. Sb(1) is bonded in a 6-coordinate geometry to three equivalent F(1) and three equivalent F(2) atoms. All Sb(1)-F(1) bond lengths are 1.98 Å. All Sb(1)-F(2) bond lengths are 2.52 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Li(1) and three equivalent Sb(1) atoms.