OsOF5 is beta Np structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four OsOF5 clusters. Os(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. O(1) is bonded in a single-bond geometry to one Os(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Os(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Os(1) atom.
OsOF5 is beta Np structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four OsOF5 clusters. Os(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The Os(1)-O(1) bond length is 1.68 Å. The Os(1)-F(1) bond length is 1.87 Å. The Os(1)-F(2) bond length is 1.87 Å. The Os(1)-F(3) bond length is 1.87 Å. The Os(1)-F(4) bond length is 1.89 Å. The Os(1)-F(5) bond length is 1.87 Å. O(1) is bonded in a single-bond geometry to one Os(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Os(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Os(1) atom.