Sn2TiO4 crystallizes in the tetragonal P4_2/mbc space group. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form edge-sharing TiO6 octahedra. Sn(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to one Ti(1) and two equivalent Sn(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one Sn(1) atom.
Sn2TiO4 crystallizes in the tetragonal P4_2/mbc space group. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form edge-sharing TiO6 octahedra. Both Ti(1)-O(2) bond lengths are 1.97 Å. All Ti(1)-O(1) bond lengths are 1.98 Å. Sn(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2) atoms. The Sn(1)-O(1) bond length is 2.21 Å. Both Sn(1)-O(2) bond lengths are 2.10 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to one Ti(1) and two equivalent Sn(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one Sn(1) atom.