(PuO4)2(NO3)4O2 is Cyanogen Chloride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four nitric acid molecules, two water atoms, and two PuO4 clusters. In one of the PuO4 clusters, Pu(1) is bonded in a square co-planar geometry to four equivalent O(1,5) atoms. O(1,5) is bonded in a single-bond geometry to one Pu(1) atom. In one of the PuO4 clusters, Pu(2) is bonded in a square co-planar geometry to four equivalent O(6,10) atoms. O(6,10) is bonded in a single-bond geometry to one Pu(2) atom.
(PuO4)2(NO3)4O2 is Cyanogen Chloride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four nitric acid molecules, two water atoms, and two PuO4 clusters. In one of the PuO4 clusters, Pu(1) is bonded in a square co-planar geometry to four equivalent O(1,5) atoms. There are two shorter (1.80 Å) and two longer (1.81 Å) Pu(1)-O(1,5) bond lengths. O(1,5) is bonded in a single-bond geometry to one Pu(1) atom. In one of the PuO4 clusters, Pu(2) is bonded in a square co-planar geometry to four equivalent O(6,10) atoms. There are two shorter (1.80 Å) and two longer (1.81 Å) Pu(2)-O(6,10) bond lengths. O(6,10) is bonded in a single-bond geometry to one Pu(2) atom.