LiMn2O4 is Spinel structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(14), one O(20), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(11)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. In the second Li site, Li(2) is bonded to one O(10), one O(21), one O(4), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, and corners with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. In the third Li site, Li(3) is bonded to one O(15), one O(18), one O(22), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(12)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. In the fourth Li site, Li(4) is bonded to one O(13), one O(17), one O(23), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(11)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. In the fifth Li site, Li(5) is bonded to one O(12), one O(19), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, and corners with two equivalent Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. In the sixth Li site, Li(6) is bonded to one O(11), one O(16), one O(24), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(12)O6 octahedra, and corners with two equivalent Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(13), one O(21), one O(22), one O(3), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(14), one O(20), one O(22), one O(3), one O(4), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(14), one O(15), one O(16), one O(19), one O(23), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(17), one O(18), one O(21), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to one O(15), one O(16), one O(2), one O(20), one O(23), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. In the sixth Mn site, Mn(6) is bonded to one O(15), one O(19), one O(2), one O(21), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(10), one O(12), one O(17), one O(18), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(10)O6 octahedra. In the eighth Mn site, Mn(8) is bonded to one O(11), one O(13), one O(3), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(19), one O(2), one O(23), one O(24), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the tenth Mn site, Mn(10) is bonded to one O(1), one O(10), one O(12), one O(18), one O(24), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. In the eleventh Mn site, Mn(11) is bonded to one O(12), one O(14), one O(16), one O(17), one O(20), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the twelfth Mn site, Mn(12) is bonded to one O(10), one O(13), one O(22), one O(24), one O(5), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Mn(10), one Mn(7), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the second O site, O(2) is bonded to one Li(5), one Mn(5), one Mn(6), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the third O site, O(3) is bonded to one Li(5), one Mn(1), one Mn(2), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(2), one Mn(2), one Mn(3), and one Mn(5) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(6), one Mn(12), one Mn(7), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(3), one Mn(12), one Mn(2), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the seventh O site, O(7) is bonded to one Li(4), one Mn(10), one Mn(11), and one Mn(4) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Mn(1), one Mn(6), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(2), one Mn(4), one Mn(6), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the tenth O site, O(10) is bonded to one Li(2), one Mn(10), one Mn(12), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eleventh O site, O(11) is bonded to one Li(6), one Mn(1), one Mn(4), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twelfth O site, O(12) is bonded to one Li(5), one Mn(10), one Mn(11), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the thirteenth O site, O(13) is bonded to one Li(4), one Mn(1), one Mn(12), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fourteenth O site, O(14) is bonded to one Li(1), one Mn(11), one Mn(2), and one Mn(3) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Li(3), one Mn(3), one Mn(5), and one Mn(6) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixteenth O site, O(16) is bonded to one Li(6), one Mn(11), one Mn(3), and one Mn(5) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the seventeenth O site, O(17) is bonded to one Li(4), one Mn(11), one Mn(4), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Li(3), one Mn(10), one Mn(4), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the nineteenth O site, O(19) is bonded to one Li(5), one Mn(3), one Mn(6), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twentieth O site, O(20) is bonded to one Li(1), one Mn(11), one Mn(2), and one Mn(5) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-first O site, O(21) is bonded to one Li(2), one Mn(1), one Mn(4), and one Mn(6) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-second O site, O(22) is bonded to one Li(3), one Mn(1), one Mn(12), and one Mn(2) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-third O site, O(23) is bonded to one Li(4), one Mn(3), one Mn(5), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-fourth O site, O(24) is bonded to one Li(6), one Mn(10), one Mn(12), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids.
LiMn2O4 is Spinel structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(14), one O(20), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(11)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Li(1)-O(1) bond length is 1.92 Å. The Li(1)-O(14) bond length is 1.92 Å. The Li(1)-O(20) bond length is 1.92 Å. The Li(1)-O(8) bond length is 1.92 Å. In the second Li site, Li(2) is bonded to one O(10), one O(21), one O(4), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, and corners with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Li(2)-O(10) bond length is 1.92 Å. The Li(2)-O(21) bond length is 1.93 Å. The Li(2)-O(4) bond length is 1.92 Å. The Li(2)-O(9) bond length is 1.92 Å. In the third Li site, Li(3) is bonded to one O(15), one O(18), one O(22), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(12)O6 octahedra, and corners with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Li(3)-O(15) bond length is 1.92 Å. The Li(3)-O(18) bond length is 1.92 Å. The Li(3)-O(22) bond length is 1.92 Å. The Li(3)-O(6) bond length is 1.92 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(17), one O(23), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(11)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Li(4)-O(13) bond length is 1.92 Å. The Li(4)-O(17) bond length is 1.92 Å. The Li(4)-O(23) bond length is 1.93 Å. The Li(4)-O(7) bond length is 1.92 Å. In the fifth Li site, Li(5) is bonded to one O(12), one O(19), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, and corners with two equivalent Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Li(5)-O(12) bond length is 1.92 Å. The Li(5)-O(19) bond length is 1.93 Å. The Li(5)-O(2) bond length is 1.92 Å. The Li(5)-O(3) bond length is 1.92 Å. In the sixth Li site, Li(6) is bonded to one O(11), one O(16), one O(24), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(11)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(12)O6 octahedra, and corners with two equivalent Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. The Li(6)-O(11) bond length is 1.92 Å. The Li(6)-O(16) bond length is 1.92 Å. The Li(6)-O(24) bond length is 1.92 Å. The Li(6)-O(5) bond length is 1.92 Å. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(13), one O(21), one O(22), one O(3), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The Mn(1)-O(11) bond length is 1.92 Å. The Mn(1)-O(13) bond length is 1.92 Å. The Mn(1)-O(21) bond length is 1.92 Å. The Mn(1)-O(22) bond length is 1.92 Å. The Mn(1)-O(3) bond length is 1.92 Å. The Mn(1)-O(8) bond length is 1.92 Å. In the second Mn site, Mn(2) is bonded to one O(14), one O(20), one O(22), one O(3), one O(4), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(2)-O(14) bond length is 1.92 Å. The Mn(2)-O(20) bond length is 1.92 Å. The Mn(2)-O(22) bond length is 1.92 Å. The Mn(2)-O(3) bond length is 1.92 Å. The Mn(2)-O(4) bond length is 1.92 Å. The Mn(2)-O(6) bond length is 1.92 Å. In the third Mn site, Mn(3) is bonded to one O(14), one O(15), one O(16), one O(19), one O(23), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. The Mn(3)-O(14) bond length is 1.92 Å. The Mn(3)-O(15) bond length is 1.92 Å. The Mn(3)-O(16) bond length is 1.92 Å. The Mn(3)-O(19) bond length is 1.92 Å. The Mn(3)-O(23) bond length is 1.92 Å. The Mn(3)-O(4) bond length is 1.92 Å. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(17), one O(18), one O(21), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The Mn(4)-O(11) bond length is 1.92 Å. The Mn(4)-O(17) bond length is 1.92 Å. The Mn(4)-O(18) bond length is 1.92 Å. The Mn(4)-O(21) bond length is 1.92 Å. The Mn(4)-O(7) bond length is 1.92 Å. The Mn(4)-O(9) bond length is 1.92 Å. In the fifth Mn site, Mn(5) is bonded to one O(15), one O(16), one O(2), one O(20), one O(23), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The Mn(5)-O(15) bond length is 1.92 Å. The Mn(5)-O(16) bond length is 1.92 Å. The Mn(5)-O(2) bond length is 1.92 Å. The Mn(5)-O(20) bond length is 1.92 Å. The Mn(5)-O(23) bond length is 1.92 Å. The Mn(5)-O(4) bond length is 1.92 Å. In the sixth Mn site, Mn(6) is bonded to one O(15), one O(19), one O(2), one O(21), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(6)-O(15) bond length is 1.92 Å. The Mn(6)-O(19) bond length is 1.92 Å. The Mn(6)-O(2) bond length is 1.92 Å. The Mn(6)-O(21) bond length is 1.92 Å. The Mn(6)-O(8) bond length is 1.92 Å. The Mn(6)-O(9) bond length is 1.92 Å. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(10), one O(12), one O(17), one O(18), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(10)O6 octahedra. The Mn(7)-O(1) bond length is 1.92 Å. The Mn(7)-O(10) bond length is 1.92 Å. The Mn(7)-O(12) bond length is 1.92 Å. The Mn(7)-O(17) bond length is 1.92 Å. The Mn(7)-O(18) bond length is 1.92 Å. The Mn(7)-O(5) bond length is 1.92 Å. In the eighth Mn site, Mn(8) is bonded to one O(11), one O(13), one O(3), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The Mn(8)-O(11) bond length is 1.92 Å. The Mn(8)-O(13) bond length is 1.92 Å. The Mn(8)-O(3) bond length is 1.92 Å. The Mn(8)-O(6) bond length is 1.92 Å. The Mn(8)-O(8) bond length is 1.92 Å. The Mn(8)-O(9) bond length is 1.92 Å. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(19), one O(2), one O(23), one O(24), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The Mn(9)-O(1) bond length is 1.92 Å. The Mn(9)-O(19) bond length is 1.92 Å. The Mn(9)-O(2) bond length is 1.92 Å. The Mn(9)-O(23) bond length is 1.92 Å. The Mn(9)-O(24) bond length is 1.92 Å. The Mn(9)-O(5) bond length is 1.92 Å. In the tenth Mn site, Mn(10) is bonded to one O(1), one O(10), one O(12), one O(18), one O(24), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. The Mn(10)-O(1) bond length is 1.92 Å. The Mn(10)-O(10) bond length is 1.92 Å. The Mn(10)-O(12) bond length is 1.92 Å. The Mn(10)-O(18) bond length is 1.92 Å. The Mn(10)-O(24) bond length is 1.92 Å. The Mn(10)-O(7) bond length is 1.92 Å. In the eleventh Mn site, Mn(11) is bonded to one O(12), one O(14), one O(16), one O(17), one O(20), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The Mn(11)-O(12) bond length is 1.92 Å. The Mn(11)-O(14) bond length is 1.92 Å. The Mn(11)-O(16) bond length is 1.92 Å. The Mn(11)-O(17) bond length is 1.92 Å. The Mn(11)-O(20) bond length is 1.92 Å. The Mn(11)-O(7) bond length is 1.92 Å. In the twelfth Mn site, Mn(12) is bonded to one O(10), one O(13), one O(22), one O(24), one O(5), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. The Mn(12)-O(10) bond length is 1.92 Å. The Mn(12)-O(13) bond length is 1.92 Å. The Mn(12)-O(22) bond length is 1.92 Å. The Mn(12)-O(24) bond length is 1.92 Å. The Mn(12)-O(5) bond length is 1.92 Å. The Mn(12)-O(6) bond length is 1.92 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Mn(10), one Mn(7), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the second O site, O(2) is bonded to one Li(5), one Mn(5), one Mn(6), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the third O site, O(3) is bonded to one Li(5), one Mn(1), one Mn(2), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(2), one Mn(2), one Mn(3), and one Mn(5) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(6), one Mn(12), one Mn(7), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(3), one Mn(12), one Mn(2), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the seventh O site, O(7) is bonded to one Li(4), one Mn(10), one Mn(11), and one Mn(4) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Mn(1), one Mn(6), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(2), one Mn(4), one Mn(6), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the tenth O site, O(10) is bonded to one Li(2), one Mn(10), one Mn(12), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eleventh O site, O(11) is bonded to one Li(6), one Mn(1), one Mn(4), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twelfth O site, O(12) is bonded to one Li(5), one Mn(10), one Mn(11), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the thirteenth O site, O(13) is bonded to one Li(4), one Mn(1), one Mn(12), and one Mn(8) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fourteenth O site, O(14) is bonded to one Li(1), one Mn(11), one Mn(2), and one Mn(3) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Li(3), one Mn(3), one Mn(5), and one Mn(6) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the sixteenth O site, O(16) is bonded to one Li(6), one Mn(11), one Mn(3), and one Mn(5) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the seventeenth O site, O(17) is bonded to one Li(4), one Mn(11), one Mn(4), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Li(3), one Mn(10), one Mn(4), and one Mn(7) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the nineteenth O site, O(19) is bonded to one Li(5), one Mn(3), one Mn(6), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twentieth O site, O(20) is bonded to one Li(1), one Mn(11), one Mn(2), and one Mn(5) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-first O site, O(21) is bonded to one Li(2), one Mn(1), one Mn(4), and one Mn(6) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-second O site, O(22) is bonded to one Li(3), one Mn(1), one Mn(12), and one Mn(2) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-third O site, O(23) is bonded to one Li(4), one Mn(3), one Mn(5), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids. In the twenty-fourth O site, O(24) is bonded to one Li(6), one Mn(10), one Mn(12), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLiMn3 trigonal pyramids.