RbNa2AuO2 crystallizes in the orthorhombic Pnnm space group. Rb(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Na(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to two equivalent Rb(1), three equivalent Na(1), and one Au(1) atom.
RbNa2AuO2 crystallizes in the orthorhombic Pnnm space group. Rb(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Rb(1)-O(1) bond lengths are 3.03 Å. Na(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. There is one shorter (2.29 Å) and two longer (2.35 Å) Na(1)-O(1) bond lengths. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Au(1)-O(1) bond lengths are 2.04 Å. O(1) is bonded in a 6-coordinate geometry to two equivalent Rb(1), three equivalent Na(1), and one Au(1) atom.