In6WO12 crystallizes in the trigonal R-3 space group. W(1) is bonded in an octahedral geometry to six equivalent O(2) atoms. In(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent In(1) atoms. In the second O site, O(1) is bonded to four equivalent In(1) atoms to form a mixture of corner and edge-sharing OIn4 tetrahedra.
In6WO12 crystallizes in the trigonal R-3 space group. W(1) is bonded in an octahedral geometry to six equivalent O(2) atoms. All W(1)-O(2) bond lengths are 1.93 Å. In(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There is one shorter (2.22 Å) and one longer (2.29 Å) In(1)-O(2) bond length. There are a spread of In(1)-O(1) bond distances ranging from 2.08-2.26 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent In(1) atoms. In the second O site, O(1) is bonded to four equivalent In(1) atoms to form a mixture of corner and edge-sharing OIn4 tetrahedra.