Rb3OCl is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Rb(1) is bonded in a linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. O(1) is bonded to six equivalent Rb(1) atoms to form ORb6 octahedra that share corners with six equivalent O(1)Rb6 octahedra and faces with eight equivalent Cl(1)Rb12 cuboctahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded to twelve equivalent Rb(1) atoms to form ClRb12 cuboctahedra that share corners with twelve equivalent Cl(1)Rb12 cuboctahedra, faces with six equivalent Cl(1)Rb12 cuboctahedra, and faces with eight equivalent O(1)Rb6 octahedra.
Rb3OCl is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Rb(1) is bonded in a linear geometry to two equivalent O(1) and four equivalent Cl(1) atoms. Both Rb(1)-O(1) bond lengths are 2.77 Å. All Rb(1)-Cl(1) bond lengths are 3.91 Å. O(1) is bonded to six equivalent Rb(1) atoms to form ORb6 octahedra that share corners with six equivalent O(1)Rb6 octahedra and faces with eight equivalent Cl(1)Rb12 cuboctahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded to twelve equivalent Rb(1) atoms to form ClRb12 cuboctahedra that share corners with twelve equivalent Cl(1)Rb12 cuboctahedra, faces with six equivalent Cl(1)Rb12 cuboctahedra, and faces with eight equivalent O(1)Rb6 octahedra.