MnIn2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mn(1) is bonded to four equivalent O(1) atoms to form MnO4 tetrahedra that share corners with twelve equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Mn(1)O4 tetrahedra and edges with six equivalent In(1)O6 octahedra. O(1) is bonded to one Mn(1) and three equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing OMnIn3 trigonal pyramids.
MnIn2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mn(1) is bonded to four equivalent O(1) atoms to form MnO4 tetrahedra that share corners with twelve equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Mn(1)-O(1) bond lengths are 2.09 Å. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Mn(1)O4 tetrahedra and edges with six equivalent In(1)O6 octahedra. All In(1)-O(1) bond lengths are 2.19 Å. O(1) is bonded to one Mn(1) and three equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing OMnIn3 trigonal pyramids.