CdIn4As4Te is alpha Po-derived structured and crystallizes in the tetragonal I4/mmm space group. Cd(1) is bonded to two As(1,1) and four equivalent Te(1) atoms to form CdTe4As2 octahedra that share corners with two equivalent In(2)As6 octahedra, corners with four equivalent Cd(1)Te4As2 octahedra, edges with four equivalent Cd(1)Te4As2 octahedra, and edges with eight equivalent In(1)TeAs5 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent In sites. In the first In site, In(1) is bonded to one As(2), four equivalent As(1), and one Te(1) atom to form InTeAs5 octahedra that share  a cornercorner with one In(2)As6 octahedra, corners with five equivalent In(1)TeAs5 octahedra, edges with four equivalent Cd(1)Te4As2 octahedra, edges with four equivalent In(2)As6 octahedra, and edges with four equivalent In(1)TeAs5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second In site, In(2) is bonded to one As(1) and five equivalent As(2) atoms to form InAs6 octahedra that share  a cornercorner with one Cd(1)Te4As2 octahedra,  a cornercorner with one In(1)TeAs5 octahedra, corners with four equivalent In(2)As6 octahedra, edges with four equivalent In(1)TeAs5 octahedra, and edges with eight equivalent In(2)As6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. There are three inequivalent As sites. In the first As site, As(1) is bonded to one Cd(1), one In(2), and four equivalent In(1) atoms to form AsCdIn5 octahedra that share  a cornercorner with one As(2)In6 octahedra, corners with five equivalent As(1)CdIn5 octahedra, edges with four equivalent As(1)CdIn5 octahedra, edges with four equivalent As(2)In6 octahedra, and edges with four equivalent Te(1)Cd4In2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second As site, As(2) is bonded to one In(1) and five equivalent In(2) atoms to form AsIn6 octahedra that share  a cornercorner with one As(1)CdIn5 octahedra,  a cornercorner with one Te(1)Cd4In2 octahedra, corners with four equivalent As(2)In6 octahedra, edges with four equivalent As(1)CdIn5 octahedra, and edges with eight equivalent As(2)In6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third As site, As(1) is bonded to one Cd(1), one In(2), and four equivalent In(1) atoms to form AsCdIn5 octahedra that share  a cornercorner with one As(2)In6 octahedra; corners with five As(1,1)CdIn5 octahedra; edges with four equivalent As(1)CdIn5 octahedra; edges with four equivalent As(2)In6 octahedra; and edges with four equivalent Te(1)Cd4In2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. Te(1) is bonded to four equivalent Cd(1) and two equivalent In(1) atoms to form TeCd4In2 octahedra that share corners with two equivalent As(2)In6 octahedra; corners with four equivalent Te(1)Cd4In2 octahedra; edges with four equivalent Te(1)Cd4In2 octahedra; and edges with eight As(1,1)CdIn5 octahedra. The corner-sharing octahedra are not tilted.
CdIn4As4Te is alpha Po-derived structured and crystallizes in the tetragonal I4/mmm space group. Cd(1) is bonded to two As(1,1) and four equivalent Te(1) atoms to form CdTe4As2 octahedra that share corners with two equivalent In(2)As6 octahedra, corners with four equivalent Cd(1)Te4As2 octahedra, edges with four equivalent Cd(1)Te4As2 octahedra, and edges with eight equivalent In(1)TeAs5 octahedra. The corner-sharing octahedra are not tilted. Both Cd(1)-As(1,1) bond lengths are 2.95 Å. All Cd(1)-Te(1) bond lengths are 2.93 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded to one As(2), four equivalent As(1), and one Te(1) atom to form InTeAs5 octahedra that share  a cornercorner with one In(2)As6 octahedra, corners with five equivalent In(1)TeAs5 octahedra, edges with four equivalent Cd(1)Te4As2 octahedra, edges with four equivalent In(2)As6 octahedra, and edges with four equivalent In(1)TeAs5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The In(1)-As(2) bond length is 2.80 Å. All In(1)-As(1) bond lengths are 2.93 Å. The In(1)-Te(1) bond length is 3.07 Å. In the second In site, In(2) is bonded to one As(1) and five equivalent As(2) atoms to form InAs6 octahedra that share  a cornercorner with one Cd(1)Te4As2 octahedra,  a cornercorner with one In(1)TeAs5 octahedra, corners with four equivalent In(2)As6 octahedra, edges with four equivalent In(1)TeAs5 octahedra, and edges with eight equivalent In(2)As6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The In(2)-As(1) bond length is 2.81 Å. There is one shorter (2.83 Å) and four longer (2.93 Å) In(2)-As(2) bond lengths. There are three inequivalent As sites. In the first As site, As(1) is bonded to one Cd(1), one In(2), and four equivalent In(1) atoms to form AsCdIn5 octahedra that share  a cornercorner with one As(2)In6 octahedra, corners with five equivalent As(1)CdIn5 octahedra, edges with four equivalent As(1)CdIn5 octahedra, edges with four equivalent As(2)In6 octahedra, and edges with four equivalent Te(1)Cd4In2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second As site, As(2) is bonded to one In(1) and five equivalent In(2) atoms to form AsIn6 octahedra that share  a cornercorner with one As(1)CdIn5 octahedra,  a cornercorner with one Te(1)Cd4In2 octahedra, corners with four equivalent As(2)In6 octahedra, edges with four equivalent As(1)CdIn5 octahedra, and edges with eight equivalent As(2)In6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third As site, As(1) is bonded to one Cd(1), one In(2), and four equivalent In(1) atoms to form AsCdIn5 octahedra that share  a cornercorner with one As(2)In6 octahedra; corners with five As(1,1)CdIn5 octahedra; edges with four equivalent As(1)CdIn5 octahedra; edges with four equivalent As(2)In6 octahedra; and edges with four equivalent Te(1)Cd4In2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The As(1)-In(2) bond length is 2.81 Å. All As(1)-In(1) bond lengths are 2.93 Å. Te(1) is bonded to four equivalent Cd(1) and two equivalent In(1) atoms to form TeCd4In2 octahedra that share corners with two equivalent As(2)In6 octahedra; corners with four equivalent Te(1)Cd4In2 octahedra; edges with four equivalent Te(1)Cd4In2 octahedra; and edges with eight As(1,1)CdIn5 octahedra. The corner-sharing octahedra are not tilted.