TaBr5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four TaBr5 clusters. Ta(1) is bonded to one Br(1), one Br(2), one Br(3), one Br(4), one Br(5), and one Br(6) atom to form edge-sharing TaBr6 octahedra. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ta(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ta(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Ta(1) atom. In the fourth Br site, Br(4) is bonded in a water-like geometry to two equivalent Ta(1) atoms. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth Br site, Br(6) is bonded in a water-like geometry to two equivalent Ta(1) atoms.
TaBr5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four TaBr5 clusters. Ta(1) is bonded to one Br(1), one Br(2), one Br(3), one Br(4), one Br(5), and one Br(6) atom to form edge-sharing TaBr6 octahedra. The Ta(1)-Br(1) bond length is 2.48 Å. The Ta(1)-Br(2) bond length is 2.42 Å. The Ta(1)-Br(3) bond length is 2.42 Å. The Ta(1)-Br(4) bond length is 2.72 Å. The Ta(1)-Br(5) bond length is 2.48 Å. The Ta(1)-Br(6) bond length is 2.72 Å. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Ta(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ta(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Ta(1) atom. In the fourth Br site, Br(4) is bonded in a water-like geometry to two equivalent Ta(1) atoms. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth Br site, Br(6) is bonded in a water-like geometry to two equivalent Ta(1) atoms.