VFe3 crystallizes in the orthorhombic Cmmm space group. V(1) is bonded in a 4-coordinate geometry to four equivalent Fe(1) atoms. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 2-coordinate geometry to two equivalent V(1) and two equivalent Fe(2) atoms. In the second Fe site, Fe(2) is bonded in a distorted body-centered cubic geometry to four equivalent Fe(1) and four equivalent Fe(2) atoms.
VFe3 crystallizes in the orthorhombic Cmmm space group. V(1) is bonded in a 4-coordinate geometry to four equivalent Fe(1) atoms. All V(1)-Fe(1) bond lengths are 2.50 Å. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 2-coordinate geometry to two equivalent V(1) and two equivalent Fe(2) atoms. Both Fe(1)-Fe(2) bond lengths are 2.46 Å. In the second Fe site, Fe(2) is bonded in a distorted body-centered cubic geometry to four equivalent Fe(1) and four equivalent Fe(2) atoms. All Fe(2)-Fe(2) bond lengths are 2.49 Å.