GdCoO3 is (Cubic) Perovskite structured and crystallizes in the tetragonal P4/mmm space group. Gd(1) is bonded to four equivalent O(1) and eight equivalent O(2) atoms to form GdO12 cuboctahedra that share corners with twelve equivalent Gd(1)O12 cuboctahedra, faces with six equivalent Gd(1)O12 cuboctahedra, and faces with eight equivalent Co(1)O6 octahedra. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and faces with eight equivalent Gd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Gd(1) and two equivalent Co(1) atoms to form a mixture of distorted corner and edge-sharing OGd4Co2 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded in a distorted linear geometry to four equivalent Gd(1) and two equivalent Co(1) atoms.
GdCoO3 is (Cubic) Perovskite structured and crystallizes in the tetragonal P4/mmm space group. Gd(1) is bonded to four equivalent O(1) and eight equivalent O(2) atoms to form GdO12 cuboctahedra that share corners with twelve equivalent Gd(1)O12 cuboctahedra, faces with six equivalent Gd(1)O12 cuboctahedra, and faces with eight equivalent Co(1)O6 octahedra. All Gd(1)-O(1) bond lengths are 2.67 Å. All Gd(1)-O(2) bond lengths are 2.70 Å. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and faces with eight equivalent Gd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Both Co(1)-O(1) bond lengths are 1.93 Å. All Co(1)-O(2) bond lengths are 1.89 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Gd(1) and two equivalent Co(1) atoms to form a mixture of distorted corner and edge-sharing OGd4Co2 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded in a distorted linear geometry to four equivalent Gd(1) and two equivalent Co(1) atoms.