ZrCuSiP is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 8-coordinate geometry to four equivalent Si(1) and four equivalent P(1) atoms. Cu(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. Si(1) is bonded to four equivalent Zr(1) and four equivalent Si(1) atoms to form a mixture of distorted corner, face, and edge-sharing SiZr4Si4 hexagonal bipyramids. P(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1) and four equivalent Cu(1) atoms.
ZrCuSiP is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 8-coordinate geometry to four equivalent Si(1) and four equivalent P(1) atoms. All Zr(1)-Si(1) bond lengths are 2.82 Å. All Zr(1)-P(1) bond lengths are 2.71 Å. Cu(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. All Cu(1)-P(1) bond lengths are 2.43 Å. Si(1) is bonded to four equivalent Zr(1) and four equivalent Si(1) atoms to form a mixture of distorted corner, face, and edge-sharing SiZr4Si4 hexagonal bipyramids. All Si(1)-Si(1) bond lengths are 2.54 Å. P(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1) and four equivalent Cu(1) atoms.