LiAg2Si crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a body-centered cubic geometry to eight equivalent Ag(1) and four equivalent Si(1) atoms. Ag(1) is bonded in a distorted body-centered cubic geometry to four equivalent Li(1) and four equivalent Si(1) atoms. Si(1) is bonded to four equivalent Li(1) and eight equivalent Ag(1) atoms to form a mixture of distorted face and corner-sharing SiLi4Ag8 cuboctahedra.
LiAg2Si crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a body-centered cubic geometry to eight equivalent Ag(1) and four equivalent Si(1) atoms. All Li(1)-Ag(1) bond lengths are 2.74 Å. All Li(1)-Si(1) bond lengths are 3.11 Å. Ag(1) is bonded in a distorted body-centered cubic geometry to four equivalent Li(1) and four equivalent Si(1) atoms. All Ag(1)-Si(1) bond lengths are 2.74 Å. Si(1) is bonded to four equivalent Li(1) and eight equivalent Ag(1) atoms to form a mixture of distorted face and corner-sharing SiLi4Ag8 cuboctahedra.