ReO2Cl3CN2S is Modderite structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules and four ReO2Cl3 clusters. In each ReO2Cl3 cluster, Re(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom.
ReO2Cl3CN2S is Modderite structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules and four ReO2Cl3 clusters. In each ReO2Cl3 cluster, Re(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one Cl(1), one Cl(2), and one Cl(3) atom. The Re(1)-O(1) bond length is 1.72 Å. The Re(1)-O(2) bond length is 1.73 Å. The Re(1)-Cl(1) bond length is 2.28 Å. The Re(1)-Cl(2) bond length is 2.33 Å. The Re(1)-Cl(3) bond length is 2.32 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom.