Fe(CN)3O2 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic F-43m space group. The structure consists of four h20 trihydrate molecules inside a Fe(CN)3 framework. In the Fe(CN)3 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. In the second Fe site, Fe(2) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Fe(2) and one N(1) atom. N(1) is bonded in a linear geometry to one Fe(1) and one C(1) atom.
Fe(CN)3O2 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic F-43m space group. The structure consists of four h20 trihydrate molecules inside a Fe(CN)3 framework. In the Fe(CN)3 framework, there are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Fe(1)-N(1) bond lengths are 2.09 Å. In the second Fe site, Fe(2) is bonded in an octahedral geometry to six equivalent C(1) atoms. All Fe(2)-C(1) bond lengths are 2.20 Å. C(1) is bonded in a linear geometry to one Fe(2) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. N(1) is bonded in a linear geometry to one Fe(1) and one C(1) atom.