FeCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(6) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom.
FeCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(6) atom. The S(1)-Cl(1) bond length is 2.00 Å. The S(1)-Cl(2) bond length is 2.00 Å. The S(1)-Cl(6) bond length is 2.00 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom.