Ag5PTeO4 crystallizes in the tetragonal P4/nmm space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Te(1) and two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. Te(1) is bonded in a 8-coordinate geometry to eight equivalent Ag(1) atoms. O(1) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one P(1) atom.
Ag5PTeO4 crystallizes in the tetragonal P4/nmm space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Te(1) and two equivalent O(1) atoms. There is one shorter (2.71 Å) and one longer (3.15 Å) Ag(1)-Te(1) bond length. Both Ag(1)-O(1) bond lengths are 2.38 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Ag(2)-O(1) bond lengths are 2.56 Å. P(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All P(1)-O(1) bond lengths are 1.56 Å. Te(1) is bonded in a 8-coordinate geometry to eight equivalent Ag(1) atoms. O(1) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one P(1) atom.