LaRhSn crystallizes in the hexagonal P-62m space group. La(1) is bonded in a 11-coordinate geometry to one Rh(2), four equivalent Rh(1), and six equivalent Sn(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 9-coordinate geometry to three equivalent La(1) and six equivalent Sn(1) atoms. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent Sn(1) atoms. Sn(1) is bonded in a 12-coordinate geometry to six equivalent La(1), two equivalent Rh(1), two equivalent Rh(2), and two equivalent Sn(1) atoms.
LaRhSn crystallizes in the hexagonal P-62m space group. La(1) is bonded in a 11-coordinate geometry to one Rh(2), four equivalent Rh(1), and six equivalent Sn(1) atoms. The La(1)-Rh(2) bond length is 3.13 Å. All La(1)-Rh(1) bond lengths are 3.10 Å. There are two shorter (3.31 Å) and four longer (3.45 Å) La(1)-Sn(1) bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 9-coordinate geometry to three equivalent La(1) and six equivalent Sn(1) atoms. All Rh(2)-Sn(1) bond lengths are 2.81 Å. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent Sn(1) atoms. All Rh(1)-Sn(1) bond lengths are 2.89 Å. Sn(1) is bonded in a 12-coordinate geometry to six equivalent La(1), two equivalent Rh(1), two equivalent Rh(2), and two equivalent Sn(1) atoms. Both Sn(1)-Sn(1) bond lengths are 3.19 Å.