C3NH10Br is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylazanium;hydrobromide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1) and three equivalent H(2,3) atoms to form corner-sharing CH3N tetrahedra. In the second C site, C(2) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. N(1) is bonded in a tetrahedral geometry to one C(1), two equivalent C(2), and one H(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. Br(1) is bonded in a single-bond geometry to one H(1) atom.
C3NH10Br is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylazanium;hydrobromide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1) and three equivalent H(2,3) atoms to form corner-sharing CH3N tetrahedra. The C(1)-N(1) bond length is 1.49 Å. There are two shorter (1.09 Å) and one longer (1.10 Å) C(1)-H(2,3) bond length. In the second C site, C(2) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(4) bond length is 1.09 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. N(1) is bonded in a tetrahedral geometry to one C(1), two equivalent C(2), and one H(1) atom. The N(1)-H(1) bond length is 1.07 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. The H(1)-Br(1) bond length is 2.15 Å. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. Br(1) is bonded in a single-bond geometry to one H(1) atom.