Li4V2Cr3Mn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-63°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-63°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second V site, V(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Mn(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one Cr(1), and one Cr(2) atom to form OLiVCr2 tetrahedra that share  a cornercorner with one O(7)LiMnVCr tetrahedra,  a cornercorner with one O(8)LiMnVCr tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra,  a cornercorner with one O(13)LiMn2Cr trigonal pyramid,  an edgeedge with one O(7)LiMnVCr tetrahedra,  an edgeedge with one O(8)LiMnVCr tetrahedra, and  an edgeedge with one O(3)LiMnCr2 trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Cr(1), one Cr(2), and one Mn(1) atom to form distorted OLiMnCr2 trigonal pyramids that share  a cornercorner with one O(15)LiMn2V tetrahedra,  a cornercorner with one O(11)LiMnVCr tetrahedra,  a cornercorner with one O(12)LiMnVCr tetrahedra, corners with three equivalent O(4)LiMnCr2 tetrahedra,  an edgeedge with one O(7)LiMnVCr tetrahedra,  an edgeedge with one O(8)LiMnVCr tetrahedra, and  an edgeedge with one O(2)LiVCr2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Cr(1), one Cr(2), and one Mn(1) atom to form OLiMnCr2 tetrahedra that share corners with two equivalent O(7)LiMnVCr tetrahedra, corners with two equivalent O(8)LiMnVCr tetrahedra, corners with two equivalent O(2)LiVCr2 tetrahedra, and corners with three equivalent O(3)LiMnCr2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Cr(3), one Mn(2), and one Mn(3) atom to form OLiMn2Cr tetrahedra that share corners with two equivalent O(15)LiMn2V tetrahedra, corners with two equivalent O(11)LiMnVCr tetrahedra, corners with two equivalent O(12)LiMnVCr tetrahedra, and corners with three equivalent O(13)LiMn2Cr trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Cr(1), and one Mn(1) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(8)LiMnVCr tetrahedra,  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra,  a cornercorner with one O(13)LiMn2Cr trigonal pyramid,  an edgeedge with one O(8)LiMnVCr tetrahedra,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(3)LiMnCr2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Cr(2), and one Mn(1) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(7)LiMnVCr tetrahedra,  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra,  a cornercorner with one O(13)LiMn2Cr trigonal pyramid,  an edgeedge with one O(7)LiMnVCr tetrahedra,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(3)LiMnCr2 trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(1), and one Cr(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Cr(3), and one Mn(2) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(15)LiMn2V tetrahedra,  a cornercorner with one O(12)LiMnVCr tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(3)LiMnCr2 trigonal pyramid,  an edgeedge with one O(15)LiMn2V tetrahedra,  an edgeedge with one O(12)LiMnVCr tetrahedra, and  an edgeedge with one O(13)LiMn2Cr trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Cr(3), and one Mn(3) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(15)LiMn2V tetrahedra,  a cornercorner with one O(11)LiMnVCr tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(3)LiMnCr2 trigonal pyramid,  an edgeedge with one O(15)LiMn2V tetrahedra,  an edgeedge with one O(11)LiMnVCr tetrahedra, and  an edgeedge with one O(13)LiMn2Cr trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(4), one Cr(3), one Mn(2), and one Mn(3) atom to form distorted OLiMn2Cr trigonal pyramids that share  a cornercorner with one O(7)LiMnVCr tetrahedra,  a cornercorner with one O(8)LiMnVCr tetrahedra,  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with three equivalent O(5)LiMn2Cr tetrahedra,  an edgeedge with one O(15)LiMn2V tetrahedra,  an edgeedge with one O(11)LiMnVCr tetrahedra, and  an edgeedge with one O(12)LiMnVCr tetrahedra. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one Mn(2), and one Mn(3) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(11)LiMnVCr tetrahedra,  a cornercorner with one O(12)LiMnVCr tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(3)LiMnCr2 trigonal pyramid,  an edgeedge with one O(11)LiMnVCr tetrahedra,  an edgeedge with one O(12)LiMnVCr tetrahedra, and  an edgeedge with one O(13)LiMn2Cr trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(2), and one Mn(1) atom.
Li4V2Cr3Mn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. The Li(1)-O(11) bond length is 1.96 Å. The Li(1)-O(12) bond length is 1.96 Å. The Li(1)-O(15) bond length is 1.96 Å. The Li(1)-O(3) bond length is 1.96 Å. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-63°. The Li(2)-O(14) bond length is 1.95 Å. The Li(2)-O(16) bond length is 1.95 Å. The Li(2)-O(5) bond length is 1.77 Å. The Li(2)-O(9) bond length is 1.96 Å. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-63°. The Li(3)-O(1) bond length is 1.95 Å. The Li(3)-O(10) bond length is 1.94 Å. The Li(3)-O(4) bond length is 1.76 Å. The Li(3)-O(6) bond length is 1.95 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. The Li(4)-O(13) bond length is 2.01 Å. The Li(4)-O(2) bond length is 1.96 Å. The Li(4)-O(7) bond length is 1.96 Å. The Li(4)-O(8) bond length is 1.96 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. The V(1)-O(1) bond length is 1.93 Å. The V(1)-O(10) bond length is 1.97 Å. The V(1)-O(2) bond length is 1.99 Å. The V(1)-O(6) bond length is 1.93 Å. The V(1)-O(7) bond length is 2.09 Å. The V(1)-O(8) bond length is 2.08 Å. In the second V site, V(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. The V(2)-O(11) bond length is 2.01 Å. The V(2)-O(12) bond length is 2.02 Å. The V(2)-O(14) bond length is 1.94 Å. The V(2)-O(15) bond length is 2.13 Å. The V(2)-O(16) bond length is 1.94 Å. The V(2)-O(9) bond length is 1.94 Å. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. The Cr(1)-O(14) bond length is 2.04 Å. The Cr(1)-O(2) bond length is 1.98 Å. The Cr(1)-O(3) bond length is 1.95 Å. The Cr(1)-O(4) bond length is 1.94 Å. The Cr(1)-O(7) bond length is 1.97 Å. The Cr(1)-O(9) bond length is 2.00 Å. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. The Cr(2)-O(16) bond length is 2.04 Å. The Cr(2)-O(2) bond length is 1.98 Å. The Cr(2)-O(3) bond length is 1.95 Å. The Cr(2)-O(4) bond length is 1.94 Å. The Cr(2)-O(8) bond length is 1.98 Å. The Cr(2)-O(9) bond length is 2.00 Å. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. The Cr(3)-O(1) bond length is 2.01 Å. The Cr(3)-O(11) bond length is 1.98 Å. The Cr(3)-O(12) bond length is 1.98 Å. The Cr(3)-O(13) bond length is 1.96 Å. The Cr(3)-O(5) bond length is 1.95 Å. The Cr(3)-O(6) bond length is 2.01 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. The Mn(1)-O(14) bond length is 2.04 Å. The Mn(1)-O(16) bond length is 2.04 Å. The Mn(1)-O(3) bond length is 1.91 Å. The Mn(1)-O(4) bond length is 1.90 Å. The Mn(1)-O(7) bond length is 1.95 Å. The Mn(1)-O(8) bond length is 1.95 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Mn(2)-O(1) bond length is 2.07 Å. The Mn(2)-O(10) bond length is 2.02 Å. The Mn(2)-O(11) bond length is 2.00 Å. The Mn(2)-O(13) bond length is 1.92 Å. The Mn(2)-O(15) bond length is 1.96 Å. The Mn(2)-O(5) bond length is 1.92 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Mn(3)-O(10) bond length is 2.02 Å. The Mn(3)-O(12) bond length is 1.99 Å. The Mn(3)-O(13) bond length is 1.92 Å. The Mn(3)-O(15) bond length is 1.96 Å. The Mn(3)-O(5) bond length is 1.92 Å. The Mn(3)-O(6) bond length is 2.06 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Mn(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one Cr(1), and one Cr(2) atom to form OLiVCr2 tetrahedra that share  a cornercorner with one O(7)LiMnVCr tetrahedra,  a cornercorner with one O(8)LiMnVCr tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra,  a cornercorner with one O(13)LiMn2Cr trigonal pyramid,  an edgeedge with one O(7)LiMnVCr tetrahedra,  an edgeedge with one O(8)LiMnVCr tetrahedra, and  an edgeedge with one O(3)LiMnCr2 trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Cr(1), one Cr(2), and one Mn(1) atom to form distorted OLiMnCr2 trigonal pyramids that share  a cornercorner with one O(15)LiMn2V tetrahedra,  a cornercorner with one O(11)LiMnVCr tetrahedra,  a cornercorner with one O(12)LiMnVCr tetrahedra, corners with three equivalent O(4)LiMnCr2 tetrahedra,  an edgeedge with one O(7)LiMnVCr tetrahedra,  an edgeedge with one O(8)LiMnVCr tetrahedra, and  an edgeedge with one O(2)LiVCr2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Cr(1), one Cr(2), and one Mn(1) atom to form OLiMnCr2 tetrahedra that share corners with two equivalent O(7)LiMnVCr tetrahedra, corners with two equivalent O(8)LiMnVCr tetrahedra, corners with two equivalent O(2)LiVCr2 tetrahedra, and corners with three equivalent O(3)LiMnCr2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Cr(3), one Mn(2), and one Mn(3) atom to form OLiMn2Cr tetrahedra that share corners with two equivalent O(15)LiMn2V tetrahedra, corners with two equivalent O(11)LiMnVCr tetrahedra, corners with two equivalent O(12)LiMnVCr tetrahedra, and corners with three equivalent O(13)LiMn2Cr trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Cr(1), and one Mn(1) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(8)LiMnVCr tetrahedra,  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra,  a cornercorner with one O(13)LiMn2Cr trigonal pyramid,  an edgeedge with one O(8)LiMnVCr tetrahedra,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(3)LiMnCr2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Cr(2), and one Mn(1) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(7)LiMnVCr tetrahedra,  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with two equivalent O(4)LiMnCr2 tetrahedra,  a cornercorner with one O(13)LiMn2Cr trigonal pyramid,  an edgeedge with one O(7)LiMnVCr tetrahedra,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(3)LiMnCr2 trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(1), and one Cr(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Cr(3), and one Mn(2) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(15)LiMn2V tetrahedra,  a cornercorner with one O(12)LiMnVCr tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(3)LiMnCr2 trigonal pyramid,  an edgeedge with one O(15)LiMn2V tetrahedra,  an edgeedge with one O(12)LiMnVCr tetrahedra, and  an edgeedge with one O(13)LiMn2Cr trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Cr(3), and one Mn(3) atom to form distorted OLiMnVCr tetrahedra that share  a cornercorner with one O(15)LiMn2V tetrahedra,  a cornercorner with one O(11)LiMnVCr tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(3)LiMnCr2 trigonal pyramid,  an edgeedge with one O(15)LiMn2V tetrahedra,  an edgeedge with one O(11)LiMnVCr tetrahedra, and  an edgeedge with one O(13)LiMn2Cr trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(4), one Cr(3), one Mn(2), and one Mn(3) atom to form distorted OLiMn2Cr trigonal pyramids that share  a cornercorner with one O(7)LiMnVCr tetrahedra,  a cornercorner with one O(8)LiMnVCr tetrahedra,  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with three equivalent O(5)LiMn2Cr tetrahedra,  an edgeedge with one O(15)LiMn2V tetrahedra,  an edgeedge with one O(11)LiMnVCr tetrahedra, and  an edgeedge with one O(12)LiMnVCr tetrahedra. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one Mn(2), and one Mn(3) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(11)LiMnVCr tetrahedra,  a cornercorner with one O(12)LiMnVCr tetrahedra, corners with two equivalent O(5)LiMn2Cr tetrahedra,  a cornercorner with one O(3)LiMnCr2 trigonal pyramid,  an edgeedge with one O(11)LiMnVCr tetrahedra,  an edgeedge with one O(12)LiMnVCr tetrahedra, and  an edgeedge with one O(13)LiMn2Cr trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(2), and one Mn(1) atom.