Mg(AgO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/a space group. Mg(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. Ag(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Mg(1) and two equivalent Ag(1) atoms.
Mg(AgO2)2 is Spinel structured and crystallizes in the tetragonal I4_1/a space group. Mg(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All Mg(1)-O(1) bond lengths are 2.05 Å. Ag(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. There are two shorter (2.04 Å) and two longer (2.05 Å) Ag(1)-O(1) bond lengths. O(1) is bonded in a 3-coordinate geometry to one Mg(1) and two equivalent Ag(1) atoms.