MnTiO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 36-37°. Mn(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ti(1) and two equivalent Mn(1) atoms to form distorted corner-sharing OTi2Mn2 tetrahedra. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and three equivalent Mn(1) atoms.
MnTiO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 36-37°. Both Ti(1)-O(1) bond lengths are 1.99 Å. All Ti(1)-O(2) bond lengths are 1.97 Å. Mn(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. There is one shorter (2.15 Å) and one longer (2.27 Å) Mn(1)-O(1) bond length. There are a spread of Mn(1)-O(2) bond distances ranging from 2.17-2.67 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ti(1) and two equivalent Mn(1) atoms to form distorted corner-sharing OTi2Mn2 tetrahedra. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and three equivalent Mn(1) atoms.