Bi2O2S crystallizes in the orthorhombic Pnnm space group. Bi(1) is bonded in a 4-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. S(1) is bonded in a square co-planar geometry to four equivalent Bi(1) atoms. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OBi4 tetrahedra.
Bi2O2S crystallizes in the orthorhombic Pnnm space group. Bi(1) is bonded in a 4-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. Both Bi(1)-S(1) bond lengths are 3.05 Å. There are a spread of Bi(1)-O(1) bond distances ranging from 2.24-2.38 Å. S(1) is bonded in a square co-planar geometry to four equivalent Bi(1) atoms. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OBi4 tetrahedra.