CaAgP crystallizes in the hexagonal P-62m space group. Ca(1) is bonded in a 11-coordinate geometry to six equivalent Ag(1), one P(1), and four equivalent P(2) atoms. Ag(1) is bonded in a 12-coordinate geometry to six equivalent Ca(1), two equivalent Ag(1), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to three equivalent Ca(1) and six equivalent Ag(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to six equivalent Ca(1) and three equivalent Ag(1) atoms.
CaAgP crystallizes in the hexagonal P-62m space group. Ca(1) is bonded in a 11-coordinate geometry to six equivalent Ag(1), one P(1), and four equivalent P(2) atoms. There are two shorter (3.16 Å) and four longer (3.28 Å) Ca(1)-Ag(1) bond lengths. The Ca(1)-P(1) bond length is 2.89 Å. All Ca(1)-P(2) bond lengths are 2.98 Å. Ag(1) is bonded in a 12-coordinate geometry to six equivalent Ca(1), two equivalent Ag(1), two equivalent P(1), and two equivalent P(2) atoms. Both Ag(1)-Ag(1) bond lengths are 3.07 Å. Both Ag(1)-P(1) bond lengths are 2.75 Å. Both Ag(1)-P(2) bond lengths are 2.67 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to three equivalent Ca(1) and six equivalent Ag(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to six equivalent Ca(1) and three equivalent Ag(1) atoms.