AgS16AsF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgS16 clusters and four AsF6 clusters. In each AgS16 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(2) and two equivalent S(8) atoms. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(3), and one S(7) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(8) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(1) and one S(8) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(6) and one S(7) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(1) and one S(5) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(2) and one S(5) atom. In the eighth S site, S(8) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(3), and one S(4) atom. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom.
AgS16AsF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgS16 clusters and four AsF6 clusters. In each AgS16 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(2) and two equivalent S(8) atoms. Both Ag(1)-S(2) bond lengths are 2.72 Å. Both Ag(1)-S(8) bond lengths are 2.81 Å. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(6) atom. The S(1)-S(4) bond length is 2.05 Å. The S(1)-S(6) bond length is 2.06 Å. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(3), and one S(7) atom. The S(2)-S(3) bond length is 2.06 Å. The S(2)-S(7) bond length is 2.08 Å. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(8) atom. The S(3)-S(8) bond length is 2.07 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one S(1) and one S(8) atom. The S(4)-S(8) bond length is 2.07 Å. In the fifth S site, S(5) is bonded in a water-like geometry to one S(6) and one S(7) atom. The S(5)-S(6) bond length is 2.07 Å. The S(5)-S(7) bond length is 2.05 Å. In the sixth S site, S(6) is bonded in a water-like geometry to one S(1) and one S(5) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(2) and one S(5) atom. In the eighth S site, S(8) is bonded in a trigonal non-coplanar geometry to one Ag(1), one S(3), and one S(4) atom. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1,3) atoms. Both As(1)-F(2) bond lengths are 1.77 Å. There are two shorter (1.78 Å) and two longer (1.79 Å) As(1)-F(1,3) bond lengths. There are two inequivalent F sites. In the first F site, F(1,3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom.