Re2Cl9NS2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four (chlorosulfanylamino) thiohypochlorite molecules and four Re2Cl9 clusters. In each Re2Cl9 cluster, Re(1) is bonded to one Cl(3), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(1) atoms to form face-sharing ReCl6 octahedra. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent Re(1) atoms. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(4) is bonded in a 2-coordinate geometry to two equivalent Re(1) atoms. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the fifth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom.
Re2Cl9NS2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four (chlorosulfanylamino) thiohypochlorite molecules and four Re2Cl9 clusters. In each Re2Cl9 cluster, Re(1) is bonded to one Cl(3), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(1) atoms to form face-sharing ReCl6 octahedra. The Re(1)-Cl(3) bond length is 2.32 Å. The Re(1)-Cl(4) bond length is 2.43 Å. The Re(1)-Cl(5) bond length is 2.32 Å. The Re(1)-Cl(6) bond length is 2.31 Å. Both Re(1)-Cl(1) bond lengths are 2.43 Å. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent Re(1) atoms. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(4) is bonded in a 2-coordinate geometry to two equivalent Re(1) atoms. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the fifth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom.