ZrSb3 crystallizes in the hexagonal P6_3/mmc space group. Zr(1) is bonded to twelve equivalent Sb(1) atoms to form a mixture of face and corner-sharing ZrSb12 cuboctahedra. Sb(1) is bonded in a 4-coordinate geometry to four equivalent Zr(1) atoms.
ZrSb3 crystallizes in the hexagonal P6_3/mmc space group. Zr(1) is bonded to twelve equivalent Sb(1) atoms to form a mixture of face and corner-sharing ZrSb12 cuboctahedra. There are six shorter (3.24 Å) and six longer (3.30 Å) Zr(1)-Sb(1) bond lengths. Sb(1) is bonded in a 4-coordinate geometry to four equivalent Zr(1) atoms.