Na2O2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted body-centered cubic geometry to six equivalent Na(1) atoms.
Na2O2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.43 Å. O(1) is bonded in a distorted body-centered cubic geometry to six equivalent Na(1) atoms.