CrO2 is Hydrophilite-like structured and crystallizes in the cubic Pa-3 space group. Cr(1) is bonded to six equivalent O(1) atoms to form corner-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles are 61°. O(1) is bonded in a trigonal planar geometry to three equivalent Cr(1) atoms.
CrO2 is Hydrophilite-like structured and crystallizes in the cubic Pa-3 space group. Cr(1) is bonded to six equivalent O(1) atoms to form corner-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles are 61°. All Cr(1)-O(1) bond lengths are 1.99 Å. O(1) is bonded in a trigonal planar geometry to three equivalent Cr(1) atoms.