NaMnP is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Na(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Mn(1) is bonded to four equivalent P(1) atoms to form a mixture of edge and corner-sharing MnP4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Mn(1) atoms.
NaMnP is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Na(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. There are four shorter (2.90 Å) and one longer (3.18 Å) Na(1)-P(1) bond length. Mn(1) is bonded to four equivalent P(1) atoms to form a mixture of edge and corner-sharing MnP4 tetrahedra. All Mn(1)-P(1) bond lengths are 2.35 Å. P(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Mn(1) atoms.