CrFe3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. Cr(1) is bonded in a distorted body-centered cubic geometry to six equivalent Fe(2) and eight equivalent Fe(1) atoms. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a distorted body-centered cubic geometry to four equivalent Cr(1) and four equivalent Fe(2) atoms. In the second Fe site, Fe(2) is bonded in a 14-coordinate geometry to six equivalent Cr(1) and eight equivalent Fe(1) atoms.
CrFe3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. Cr(1) is bonded in a distorted body-centered cubic geometry to six equivalent Fe(2) and eight equivalent Fe(1) atoms. All Cr(1)-Fe(2) bond lengths are 2.88 Å. All Cr(1)-Fe(1) bond lengths are 2.49 Å. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a distorted body-centered cubic geometry to four equivalent Cr(1) and four equivalent Fe(2) atoms. All Fe(1)-Fe(2) bond lengths are 2.49 Å. In the second Fe site, Fe(2) is bonded in a 14-coordinate geometry to six equivalent Cr(1) and eight equivalent Fe(1) atoms.