NdH2O2Cl crystallizes in the monoclinic P2_1/m space group. Nd(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent Cl(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one H(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(1) atom. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Nd(1) atoms.
NdH2O2Cl crystallizes in the monoclinic P2_1/m space group. Nd(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent Cl(1) atoms. There is one shorter (2.47 Å) and two longer (2.49 Å) Nd(1)-O(1) bond lengths. There is one shorter (2.44 Å) and two longer (2.51 Å) Nd(1)-O(2) bond lengths. There are two shorter (3.02 Å) and one longer (3.16 Å) Nd(1)-Cl(1) bond length. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.98 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one H(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Nd(1) and one H(1) atom. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Nd(1) atoms.