ZnSbF5 crystallizes in the monoclinic Cc space group. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted ZnF5 trigonal bipyramids that share corners with five equivalent Sb(1)F5 square pyramids. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form SbF5 square pyramids that share corners with five equivalent Zn(1)F5 trigonal bipyramids. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom.
ZnSbF5 crystallizes in the monoclinic Cc space group. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted ZnF5 trigonal bipyramids that share corners with five equivalent Sb(1)F5 square pyramids. The Zn(1)-F(1) bond length is 2.38 Å. The Zn(1)-F(2) bond length is 1.92 Å. The Zn(1)-F(3) bond length is 1.95 Å. The Zn(1)-F(4) bond length is 1.97 Å. The Zn(1)-F(5) bond length is 2.08 Å. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form SbF5 square pyramids that share corners with five equivalent Zn(1)F5 trigonal bipyramids. The Sb(1)-F(1) bond length is 2.01 Å. The Sb(1)-F(2) bond length is 2.15 Å. The Sb(1)-F(3) bond length is 2.18 Å. The Sb(1)-F(4) bond length is 2.16 Å. The Sb(1)-F(5) bond length is 2.13 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom.