(K)2AuInI6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a AuInI6 framework. In the AuInI6 framework, Au(1) is bonded to six equivalent I(1) atoms to form AuI6 octahedra that share corners with six equivalent In(1)I6 octahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to six equivalent I(1) atoms to form InI6 octahedra that share corners with six equivalent Au(1)I6 octahedra. The corner-sharing octahedra are not tilted. I(1) is bonded in a distorted linear geometry to one Au(1) and one In(1) atom.
(K)2AuInI6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a AuInI6 framework. In the AuInI6 framework, Au(1) is bonded to six equivalent I(1) atoms to form AuI6 octahedra that share corners with six equivalent In(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Au(1)-I(1) bond lengths are 2.95 Å. In(1) is bonded to six equivalent I(1) atoms to form InI6 octahedra that share corners with six equivalent Au(1)I6 octahedra. The corner-sharing octahedra are not tilted. All In(1)-I(1) bond lengths are 3.00 Å. I(1) is bonded in a distorted linear geometry to one Au(1) and one In(1) atom.