BaGdCrO6Fe crystallizes in the cubic F-43m space group. The structure consists of four 7439-89-6 atoms inside a BaGdCrO6 framework. In the BaGdCrO6 framework, Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Gd(1)O6 octahedra, and faces with four equivalent Cr(1)O6 octahedra. Gd(1) is bonded to six equivalent O(1) atoms to form GdO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent Ba(1), one Gd(1), and one Cr(1) atom.
BaGdCrO6Fe crystallizes in the cubic F-43m space group. The structure consists of four 7439-89-6 atoms inside a BaGdCrO6 framework. In the BaGdCrO6 framework, Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Gd(1)O6 octahedra, and faces with four equivalent Cr(1)O6 octahedra. All Ba(1)-O(1) bond lengths are 2.93 Å. Gd(1) is bonded to six equivalent O(1) atoms to form GdO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Gd(1)-O(1) bond lengths are 2.16 Å. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra and faces with four equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Cr(1)-O(1) bond lengths are 1.99 Å. O(1) is bonded in a distorted linear geometry to two equivalent Ba(1), one Gd(1), and one Cr(1) atom.