TlCdF3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the triclinic P1 space group. The structure consists of one 7440-28-0 atom inside a CdF3 framework. In the CdF3 framework, Cd(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing CdF6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Cd(1) atoms. In the second F site, F(2) is bonded in a distorted linear geometry to two equivalent Cd(1) atoms. In the third F site, F(3) is bonded in a linear geometry to two equivalent Cd(1) atoms.
TlCdF3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the triclinic P1 space group. The structure consists of one 7440-28-0 atom inside a CdF3 framework. In the CdF3 framework, Cd(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing CdF6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. There is one shorter (2.20 Å) and one longer (2.23 Å) Cd(1)-F(1) bond length. There is one shorter (2.20 Å) and one longer (2.23 Å) Cd(1)-F(2) bond length. There is one shorter (2.20 Å) and one longer (2.24 Å) Cd(1)-F(3) bond length. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Cd(1) atoms. In the second F site, F(2) is bonded in a distorted linear geometry to two equivalent Cd(1) atoms. In the third F site, F(3) is bonded in a linear geometry to two equivalent Cd(1) atoms.