NaRh(NO2)6(NH4)2 crystallizes in the cubic Fm-3 space group. The structure consists of eight ammonium molecules inside a NaRh(NO2)6 framework. In the NaRh(NO2)6 framework, Na(1) is bonded in a cuboctahedral geometry to twelve equivalent O(1) atoms. Rh(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. N(1) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one Na(1) and one N(1) atom.
NaRh(NO2)6(NH4)2 crystallizes in the cubic Fm-3 space group. The structure consists of eight ammonium molecules inside a NaRh(NO2)6 framework. In the NaRh(NO2)6 framework, Na(1) is bonded in a cuboctahedral geometry to twelve equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.92 Å. Rh(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Rh(1)-N(1) bond lengths are 2.10 Å. N(1) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.25 Å. O(1) is bonded in a single-bond geometry to one Na(1) and one N(1) atom.