LuNdS3 crystallizes in the orthorhombic Cmcm space group. Lu(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Nd(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form a mixture of corner and edge-sharing NdS6 octahedra. The corner-sharing octahedral tilt angles are 58°. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Lu(1) and two equivalent Nd(1) atoms to form corner-sharing SNd2Lu2 tetrahedra. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Lu(1) and two equivalent Nd(1) atoms.
LuNdS3 crystallizes in the orthorhombic Cmcm space group. Lu(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Both Lu(1)-S(1) bond lengths are 2.66 Å. All Lu(1)-S(2) bond lengths are 2.81 Å. Nd(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form a mixture of corner and edge-sharing NdS6 octahedra. The corner-sharing octahedral tilt angles are 58°. Both Nd(1)-S(1) bond lengths are 2.82 Å. All Nd(1)-S(2) bond lengths are 2.80 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Lu(1) and two equivalent Nd(1) atoms to form corner-sharing SNd2Lu2 tetrahedra. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Lu(1) and two equivalent Nd(1) atoms.