HoOF is Fluorite-derived structured and crystallizes in the trigonal R-3m space group. Ho(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Ho(1) atoms to form OHo4 tetrahedra that share corners with six equivalent O(1)Ho4 tetrahedra, corners with ten equivalent F(1)Ho4 tetrahedra, edges with three equivalent O(1)Ho4 tetrahedra, and edges with three equivalent F(1)Ho4 tetrahedra. F(1) is bonded to four equivalent Ho(1) atoms to form FHo4 tetrahedra that share corners with six equivalent F(1)Ho4 tetrahedra, corners with ten equivalent O(1)Ho4 tetrahedra, edges with three equivalent O(1)Ho4 tetrahedra, and edges with three equivalent F(1)Ho4 tetrahedra.
HoOF is Fluorite-derived structured and crystallizes in the trigonal R-3m space group. Ho(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. There are three shorter (2.24 Å) and one longer (2.25 Å) Ho(1)-O(1) bond length. All Ho(1)-F(1) bond lengths are 2.41 Å. O(1) is bonded to four equivalent Ho(1) atoms to form OHo4 tetrahedra that share corners with six equivalent O(1)Ho4 tetrahedra, corners with ten equivalent F(1)Ho4 tetrahedra, edges with three equivalent O(1)Ho4 tetrahedra, and edges with three equivalent F(1)Ho4 tetrahedra. F(1) is bonded to four equivalent Ho(1) atoms to form FHo4 tetrahedra that share corners with six equivalent F(1)Ho4 tetrahedra, corners with ten equivalent O(1)Ho4 tetrahedra, edges with three equivalent O(1)Ho4 tetrahedra, and edges with three equivalent F(1)Ho4 tetrahedra.