RbInCl3 is (Cubic) Perovskite-like structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent Cl(1) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, faces with four equivalent In(1)Cl6 octahedra, and faces with four equivalent In(2)Cl6 octahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to six equivalent Cl(1) atoms to form InCl6 octahedra that share corners with six equivalent In(2)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second In site, In(2) is bonded to six equivalent Cl(1) atoms to form InCl6 octahedra that share corners with six equivalent In(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a distorted linear geometry to four equivalent Rb(1), one In(1), and one In(2) atom.
RbInCl3 is (Cubic) Perovskite-like structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent Cl(1) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, faces with four equivalent In(1)Cl6 octahedra, and faces with four equivalent In(2)Cl6 octahedra. All Rb(1)-Cl(1) bond lengths are 3.87 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded to six equivalent Cl(1) atoms to form InCl6 octahedra that share corners with six equivalent In(2)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-Cl(1) bond lengths are 2.94 Å. In the second In site, In(2) is bonded to six equivalent Cl(1) atoms to form InCl6 octahedra that share corners with six equivalent In(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(2)-Cl(1) bond lengths are 2.53 Å. Cl(1) is bonded in a distorted linear geometry to four equivalent Rb(1), one In(1), and one In(2) atom.