KSO2F is Potassium chlorate-derived structured and crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent F(1) atoms. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. F(1) is bonded to three equivalent K(1) and one S(1) atom to form distorted corner-sharing FK3S tetrahedra.
KSO2F is Potassium chlorate-derived structured and crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent F(1) atoms. There are a spread of K(1)-O(1) bond distances ranging from 2.89-3.03 Å. There are a spread of K(1)-O(2) bond distances ranging from 2.97-3.25 Å. There are a spread of K(1)-F(1) bond distances ranging from 2.84-3.00 Å. S(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one F(1) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-F(1) bond length is 1.83 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. F(1) is bonded to three equivalent K(1) and one S(1) atom to form distorted corner-sharing FK3S tetrahedra.