Zn(AgO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form AgO4 tetrahedra that share corners with six equivalent Ag(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-77°. In the second Ag site, Ag(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form AgO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Ag(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Ag(2)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Zn(1) atoms to form OZn2Ag2 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(1)Zn2Ag2 trigonal pyramid, and edges with two equivalent O(2)ZnAg3 trigonal pyramids. In the second O site, O(2) is bonded to one Ag(1), two equivalent Ag(2), and one Zn(1) atom to form OZnAg3 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(2)ZnAg3 trigonal pyramid, and edges with two equivalent O(1)Zn2Ag2 trigonal pyramids.
Zn(AgO2)2 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form AgO4 tetrahedra that share corners with six equivalent Ag(2)O6 octahedra and corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-77°. Both Ag(1)-O(1) bond lengths are 2.18 Å. Both Ag(1)-O(2) bond lengths are 2.21 Å. In the second Ag site, Ag(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form AgO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Ag(2)O6 octahedra, and edges with four equivalent Zn(1)O6 octahedra. Both Ag(2)-O(1) bond lengths are 2.08 Å. All Ag(2)-O(2) bond lengths are 2.17 Å. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ag(1)O4 tetrahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Ag(2)O6 octahedra. Both Zn(1)-O(2) bond lengths are 2.16 Å. All Zn(1)-O(1) bond lengths are 2.11 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Zn(1) atoms to form OZn2Ag2 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(1)Zn2Ag2 trigonal pyramid, and edges with two equivalent O(2)ZnAg3 trigonal pyramids. In the second O site, O(2) is bonded to one Ag(1), two equivalent Ag(2), and one Zn(1) atom to form OZnAg3 trigonal pyramids that share corners with six equivalent O(1)Zn2Ag2 trigonal pyramids, corners with six equivalent O(2)ZnAg3 trigonal pyramids,  an edgeedge with one O(2)ZnAg3 trigonal pyramid, and edges with two equivalent O(1)Zn2Ag2 trigonal pyramids.