Mo2Cu6H2Te2O15Cl4 crystallizes in the triclinic P1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(3), one O(7), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(11), one O(15), one O(4), one O(7), one O(8), and one O(9) atom. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(13), one O(2), one Cl(1), and one Cl(3) atom to form distorted edge-sharing CuCl2O3 square pyramids. In the second Cu site, Cu(2) is bonded to one O(1), one O(14), one O(2), one Cl(2), and one Cl(4) atom to form a mixture of distorted edge and corner-sharing CuCl2O3 square pyramids. In the third Cu site, Cu(3) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(5), one O(6), one O(9), and one Cl(3) atom. In the fourth Cu site, Cu(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(14), one O(5), one O(6), and one Cl(4) atom. In the fifth Cu site, Cu(5) is bonded in a 5-coordinate geometry to one O(11), one O(7), one O(9), one Cl(1), and one Cl(3) atom. In the sixth Cu site, Cu(6) is bonded to one O(10), one O(12), one O(8), one Cl(2), and one Cl(4) atom to form distorted corner-sharing CuCl2O3 square pyramids. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(15) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted T-shaped geometry to one O(14), one O(2), and one O(5) atom. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to one O(1), one O(13), and one O(6) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Cu(3), one Cu(4), and one Te(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Cu(3), one Cu(4), and one Te(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(6) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one Mo(2), one Cu(3), and one Cu(5) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Mo(1), one Cu(4), and one Cu(6) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(5) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mo(1) and one Cu(6) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Cu(1), one Cu(3), and one Te(2) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Cu(2), one Cu(4), and one Te(1) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one Mo(2), one H(1), and one H(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one Cu(5) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one Cu(6) atom. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), and one Cu(5) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(4), and one Cu(6) atom.
Mo2Cu6H2Te2O15Cl4 crystallizes in the triclinic P1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(3), one O(7), and one O(8) atom. The Mo(1)-O(10) bond length is 1.95 Å. The Mo(1)-O(12) bond length is 1.79 Å. The Mo(1)-O(3) bond length is 1.74 Å. The Mo(1)-O(7) bond length is 1.93 Å. The Mo(1)-O(8) bond length is 2.11 Å. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(11), one O(15), one O(4), one O(7), one O(8), and one O(9) atom. The Mo(2)-O(11) bond length is 1.78 Å. The Mo(2)-O(15) bond length is 2.47 Å. The Mo(2)-O(4) bond length is 1.74 Å. The Mo(2)-O(7) bond length is 2.14 Å. The Mo(2)-O(8) bond length is 1.96 Å. The Mo(2)-O(9) bond length is 1.95 Å. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(13), one O(2), one Cl(1), and one Cl(3) atom to form distorted edge-sharing CuCl2O3 square pyramids. The Cu(1)-O(1) bond length is 1.95 Å. The Cu(1)-O(13) bond length is 1.93 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-Cl(1) bond length is 2.23 Å. The Cu(1)-Cl(3) bond length is 2.79 Å. In the second Cu site, Cu(2) is bonded to one O(1), one O(14), one O(2), one Cl(2), and one Cl(4) atom to form a mixture of distorted edge and corner-sharing CuCl2O3 square pyramids. The Cu(2)-O(1) bond length is 1.99 Å. The Cu(2)-O(14) bond length is 1.93 Å. The Cu(2)-O(2) bond length is 1.95 Å. The Cu(2)-Cl(2) bond length is 2.22 Å. The Cu(2)-Cl(4) bond length is 2.80 Å. In the third Cu site, Cu(3) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(5), one O(6), one O(9), and one Cl(3) atom. The Cu(3)-O(13) bond length is 1.94 Å. The Cu(3)-O(5) bond length is 1.97 Å. The Cu(3)-O(6) bond length is 1.98 Å. The Cu(3)-O(9) bond length is 1.94 Å. The Cu(3)-Cl(3) bond length is 2.97 Å. In the fourth Cu site, Cu(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(14), one O(5), one O(6), and one Cl(4) atom. The Cu(4)-O(10) bond length is 1.93 Å. The Cu(4)-O(14) bond length is 1.95 Å. The Cu(4)-O(5) bond length is 1.98 Å. The Cu(4)-O(6) bond length is 1.96 Å. The Cu(4)-Cl(4) bond length is 3.00 Å. In the fifth Cu site, Cu(5) is bonded in a 5-coordinate geometry to one O(11), one O(7), one O(9), one Cl(1), and one Cl(3) atom. The Cu(5)-O(11) bond length is 1.89 Å. The Cu(5)-O(7) bond length is 1.94 Å. The Cu(5)-O(9) bond length is 1.98 Å. The Cu(5)-Cl(1) bond length is 2.83 Å. The Cu(5)-Cl(3) bond length is 2.23 Å. In the sixth Cu site, Cu(6) is bonded to one O(10), one O(12), one O(8), one Cl(2), and one Cl(4) atom to form distorted corner-sharing CuCl2O3 square pyramids. The Cu(6)-O(10) bond length is 2.01 Å. The Cu(6)-O(12) bond length is 1.94 Å. The Cu(6)-O(8) bond length is 1.93 Å. The Cu(6)-Cl(2) bond length is 2.77 Å. The Cu(6)-Cl(4) bond length is 2.22 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. The H(1)-O(15) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(15) atom. The H(2)-O(15) bond length is 0.98 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted T-shaped geometry to one O(14), one O(2), and one O(5) atom. The Te(1)-O(14) bond length is 1.94 Å. The Te(1)-O(2) bond length is 1.92 Å. The Te(1)-O(5) bond length is 1.94 Å. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to one O(1), one O(13), and one O(6) atom. The Te(2)-O(1) bond length is 1.92 Å. The Te(2)-O(13) bond length is 1.94 Å. The Te(2)-O(6) bond length is 1.94 Å. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Cu(3), one Cu(4), and one Te(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Cu(3), one Cu(4), and one Te(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(5) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(6) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one Mo(2), one Cu(3), and one Cu(5) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Mo(1), one Cu(4), and one Cu(6) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(5) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mo(1) and one Cu(6) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Cu(1), one Cu(3), and one Te(2) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Cu(2), one Cu(4), and one Te(1) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one Mo(2), one H(1), and one H(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one Cu(5) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one Cu(6) atom. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), and one Cu(5) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(4), and one Cu(6) atom.