VZnF6 crystallizes in the trigonal R-3 space group. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 28°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles are 28°. F(1) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(1) atom.
VZnF6 crystallizes in the trigonal R-3 space group. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 28°. All V(1)-F(1) bond lengths are 1.88 Å. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles are 28°. All Zn(1)-F(1) bond lengths are 2.05 Å. F(1) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(1) atom.