LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one N(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one N(1) and one H(1) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to two equivalent La(1) and one H(2) atom. In the fifth O site, O(1) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(2) and one S(1) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom.
LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(5), and two equivalent O(7) atoms. The La(1)-O(3) bond length is 2.59 Å. The La(1)-O(4) bond length is 2.48 Å. The La(1)-O(5) bond length is 2.66 Å. There is one shorter (2.36 Å) and one longer (2.41 Å) La(1)-O(7) bond length. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. The N(1)-O(5) bond length is 1.29 Å. The N(1)-O(6) bond length is 1.26 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. The H(1)-O(1) bond length is 1.01 Å. The H(1)-O(6) bond length is 1.66 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. The H(2)-O(2) bond length is 1.70 Å. The H(2)-O(7) bond length is 1.00 Å. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.61 Å. The S(1)-O(2) bond length is 1.45 Å. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(4) bond length is 1.48 Å. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one N(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one N(1) and one H(1) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to two equivalent La(1) and one H(2) atom. In the fifth O site, O(1) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(2) and one S(1) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom.