CsMn(CN)3 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded in a 24-coordinate geometry to twelve equivalent C(1) and twelve equivalent N(1) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. In the second Mn site, Mn(2) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to four equivalent Cs(1), one Mn(2), and one N(1) atom. N(1) is bonded in a linear geometry to four equivalent Cs(1), one Mn(1), and one C(1) atom.
CsMn(CN)3 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded in a 24-coordinate geometry to twelve equivalent C(1) and twelve equivalent N(1) atoms. All Cs(1)-C(1) bond lengths are 3.62 Å. All Cs(1)-N(1) bond lengths are 3.62 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Mn(1)-N(1) bond lengths are 1.95 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to six equivalent C(1) atoms. All Mn(2)-C(1) bond lengths are 1.92 Å. C(1) is bonded in a linear geometry to four equivalent Cs(1), one Mn(2), and one N(1) atom. The C(1)-N(1) bond length is 1.19 Å. N(1) is bonded in a linear geometry to four equivalent Cs(1), one Mn(1), and one C(1) atom.