Ag2MnSn3S8 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(3) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(4) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent S(2) and two equivalent S(3) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to one S(1), one S(3), two equivalent S(2), and two equivalent S(4) atoms. In the second Sn site, Sn(2) is bonded in a square co-planar geometry to two equivalent S(2) and two equivalent S(4) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1), one Ag(1), one Sn(1), and one S(3) atom. In the second S site, S(2) is bonded to one Ag(2), one Sn(2), and two equivalent Sn(1) atoms to form a mixture of corner and edge-sharing SAgSn3 trigonal pyramids. In the third S site, S(3) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1), one Ag(2), one Sn(1), and one S(1) atom. In the fourth S site, S(4) is bonded to one Ag(1), one Sn(2), and two equivalent Sn(1) atoms to form a mixture of corner and edge-sharing SAgSn3 trigonal pyramids.
Ag2MnSn3S8 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(3) atoms. Both Mn(1)-S(1) bond lengths are 2.26 Å. Both Mn(1)-S(3) bond lengths are 2.26 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(4) atoms. Both Ag(1)-S(1) bond lengths are 2.60 Å. Both Ag(1)-S(4) bond lengths are 2.52 Å. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent S(2) and two equivalent S(3) atoms. Both Ag(2)-S(2) bond lengths are 2.52 Å. Both Ag(2)-S(3) bond lengths are 2.59 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to one S(1), one S(3), two equivalent S(2), and two equivalent S(4) atoms. The Sn(1)-S(1) bond length is 3.13 Å. The Sn(1)-S(3) bond length is 3.12 Å. There is one shorter (2.71 Å) and one longer (2.83 Å) Sn(1)-S(2) bond length. There is one shorter (2.71 Å) and one longer (2.81 Å) Sn(1)-S(4) bond length. In the second Sn site, Sn(2) is bonded in a square co-planar geometry to two equivalent S(2) and two equivalent S(4) atoms. Both Sn(2)-S(2) bond lengths are 2.85 Å. Both Sn(2)-S(4) bond lengths are 2.84 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1), one Ag(1), one Sn(1), and one S(3) atom. The S(1)-S(3) bond length is 2.11 Å. In the second S site, S(2) is bonded to one Ag(2), one Sn(2), and two equivalent Sn(1) atoms to form a mixture of corner and edge-sharing SAgSn3 trigonal pyramids. In the third S site, S(3) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1), one Ag(2), one Sn(1), and one S(1) atom. In the fourth S site, S(4) is bonded to one Ag(1), one Sn(2), and two equivalent Sn(1) atoms to form a mixture of corner and edge-sharing SAgSn3 trigonal pyramids.