VP1 is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing VP6 pentagonal pyramids. P(1) is bonded to six equivalent V(1) atoms to form a mixture of face, corner, and edge-sharing PV6 octahedra. The corner-sharing octahedral tilt angles are 47°.
VP1 is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing VP6 pentagonal pyramids. All V(1)-P(1) bond lengths are 2.41 Å. P(1) is bonded to six equivalent V(1) atoms to form a mixture of face, corner, and edge-sharing PV6 octahedra. The corner-sharing octahedral tilt angles are 47°.