ZrAlW is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded to four equivalent W(1) atoms to form distorted ZrW4 tetrahedra that share corners with four equivalent Al(1)W4 tetrahedra, corners with twelve equivalent Zr(1)W4 tetrahedra, and edges with six equivalent Al(1)W4 tetrahedra. W(1) is bonded in a body-centered cubic geometry to four equivalent Zr(1) and four equivalent Al(1) atoms. Al(1) is bonded to four equivalent W(1) atoms to form distorted AlW4 tetrahedra that share corners with four equivalent Zr(1)W4 tetrahedra, corners with twelve equivalent Al(1)W4 tetrahedra, and edges with six equivalent Zr(1)W4 tetrahedra.
ZrAlW is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded to four equivalent W(1) atoms to form distorted ZrW4 tetrahedra that share corners with four equivalent Al(1)W4 tetrahedra, corners with twelve equivalent Zr(1)W4 tetrahedra, and edges with six equivalent Al(1)W4 tetrahedra. All Zr(1)-W(1) bond lengths are 2.76 Å. W(1) is bonded in a body-centered cubic geometry to four equivalent Zr(1) and four equivalent Al(1) atoms. All W(1)-Al(1) bond lengths are 2.76 Å. Al(1) is bonded to four equivalent W(1) atoms to form distorted AlW4 tetrahedra that share corners with four equivalent Zr(1)W4 tetrahedra, corners with twelve equivalent Al(1)W4 tetrahedra, and edges with six equivalent Zr(1)W4 tetrahedra.