KLiICl crystallizes in the tetragonal P4/mmm space group. K(1) is bonded to two equivalent I(1) and four equivalent Cl(1) atoms to form a mixture of corner and edge-sharing KI2Cl4 octahedra. The corner-sharing octahedra are not tilted. Li(1) is bonded in a square co-planar geometry to four equivalent I(1) atoms. I(1) is bonded to two equivalent K(1) and four equivalent Li(1) atoms to form a mixture of corner and edge-sharing IK2Li4 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a square co-planar geometry to four equivalent K(1) atoms.
KLiICl crystallizes in the tetragonal P4/mmm space group. K(1) is bonded to two equivalent I(1) and four equivalent Cl(1) atoms to form a mixture of corner and edge-sharing KI2Cl4 octahedra. The corner-sharing octahedra are not tilted. Both K(1)-I(1) bond lengths are 3.43 Å. All K(1)-Cl(1) bond lengths are 3.05 Å. Li(1) is bonded in a square co-planar geometry to four equivalent I(1) atoms. All Li(1)-I(1) bond lengths are 3.05 Å. I(1) is bonded to two equivalent K(1) and four equivalent Li(1) atoms to form a mixture of corner and edge-sharing IK2Li4 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a square co-planar geometry to four equivalent K(1) atoms.