(Na)2HgAsBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a HgAsBr6 framework. In the HgAsBr6 framework, Hg(1) is bonded to six equivalent Br(1) atoms to form HgBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Hg(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Hg(1) and one As(1) atom.
(Na)2HgAsBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a HgAsBr6 framework. In the HgAsBr6 framework, Hg(1) is bonded to six equivalent Br(1) atoms to form HgBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Hg(1)-Br(1) bond lengths are 2.90 Å. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Hg(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All As(1)-Br(1) bond lengths are 2.67 Å. Br(1) is bonded in a linear geometry to one Hg(1) and one As(1) atom.