RhZn3F6 crystallizes in the triclinic P-1 space group. Rh(1) is bonded in a distorted linear geometry to two equivalent F(1) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Zn site, Zn(2) is bonded in a distorted linear geometry to two equivalent F(2) and two equivalent F(3) atoms. In the third Zn site, Zn(3) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in an L-shaped geometry to one Rh(1) and one Zn(3) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Zn(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom.
RhZn3F6 crystallizes in the triclinic P-1 space group. Rh(1) is bonded in a distorted linear geometry to two equivalent F(1) atoms. Both Rh(1)-F(1) bond lengths are 2.00 Å. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a linear geometry to two equivalent F(2) atoms. Both Zn(1)-F(2) bond lengths are 1.77 Å. In the second Zn site, Zn(2) is bonded in a distorted linear geometry to two equivalent F(2) and two equivalent F(3) atoms. Both Zn(2)-F(2) bond lengths are 2.44 Å. Both Zn(2)-F(3) bond lengths are 1.92 Å. In the third Zn site, Zn(3) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. Both Zn(3)-F(1) bond lengths are 2.08 Å. Both Zn(3)-F(3) bond lengths are 1.95 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in an L-shaped geometry to one Rh(1) and one Zn(3) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Zn(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom.