AsOCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AsOCl3 clusters. As(1) is bonded to two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing AsCl3O2 trigonal bipyramids. O(1) is bonded in a water-like geometry to two equivalent As(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom.
AsOCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AsOCl3 clusters. As(1) is bonded to two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing AsCl3O2 trigonal bipyramids. There is one shorter (1.74 Å) and one longer (1.90 Å) As(1)-O(1) bond length. The As(1)-Cl(1) bond length is 2.13 Å. The As(1)-Cl(2) bond length is 2.14 Å. The As(1)-Cl(3) bond length is 2.20 Å. O(1) is bonded in a water-like geometry to two equivalent As(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(1) atom.