CdGeAsP is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Cd(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form CdAs2P2 tetrahedra that share corners with four equivalent Cd(1)As2P2 tetrahedra and corners with eight equivalent Ge(1)As2P2 tetrahedra. Ge(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form GeAs2P2 tetrahedra that share corners with four equivalent Ge(1)As2P2 tetrahedra and corners with eight equivalent Cd(1)As2P2 tetrahedra. As(1) is bonded to two equivalent Cd(1) and two equivalent Ge(1) atoms to form AsCd2Ge2 tetrahedra that share corners with four equivalent As(1)Cd2Ge2 tetrahedra and corners with eight equivalent P(1)Cd2Ge2 tetrahedra. P(1) is bonded to two equivalent Cd(1) and two equivalent Ge(1) atoms to form PCd2Ge2 tetrahedra that share corners with four equivalent P(1)Cd2Ge2 tetrahedra and corners with eight equivalent As(1)Cd2Ge2 tetrahedra.
CdGeAsP is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Cd(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form CdAs2P2 tetrahedra that share corners with four equivalent Cd(1)As2P2 tetrahedra and corners with eight equivalent Ge(1)As2P2 tetrahedra. Both Cd(1)-As(1) bond lengths are 2.65 Å. Both Cd(1)-P(1) bond lengths are 2.61 Å. Ge(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form GeAs2P2 tetrahedra that share corners with four equivalent Ge(1)As2P2 tetrahedra and corners with eight equivalent Cd(1)As2P2 tetrahedra. Both Ge(1)-As(1) bond lengths are 2.47 Å. Both Ge(1)-P(1) bond lengths are 2.38 Å. As(1) is bonded to two equivalent Cd(1) and two equivalent Ge(1) atoms to form AsCd2Ge2 tetrahedra that share corners with four equivalent As(1)Cd2Ge2 tetrahedra and corners with eight equivalent P(1)Cd2Ge2 tetrahedra. P(1) is bonded to two equivalent Cd(1) and two equivalent Ge(1) atoms to form PCd2Ge2 tetrahedra that share corners with four equivalent P(1)Cd2Ge2 tetrahedra and corners with eight equivalent As(1)Cd2Ge2 tetrahedra.