PdN3SO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and four PdN3 clusters. In each PdN3 cluster, Pd(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Pd(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pd(1) atom. In the third N site, N(1) is bonded in a single-bond geometry to one Pd(1) atom.
PdN3SO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and four PdN3 clusters. In each PdN3 cluster, Pd(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The Pd(1)-N(1) bond length is 1.88 Å. The Pd(1)-N(2) bond length is 1.77 Å. The Pd(1)-N(3) bond length is 1.83 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Pd(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pd(1) atom. In the third N site, N(1) is bonded in a single-bond geometry to one Pd(1) atom.