V2NO4F3NF is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and two V2NO4F3 clusters. In each V2NO4F3 cluster, there are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(4), one F(1), and one F(3) atom to form distorted edge-sharing VO3F2 trigonal bipyramids. In the second V site, V(2) is bonded to one O(2), one O(3), one F(2), and one F(3) atom to form edge-sharing VO2F2 tetrahedra. N(1) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one V(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(2) atom. In the third F site, F(3) is bonded in an L-shaped geometry to one V(1) and one V(2) atom.
V2NO4F3NF is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and two V2NO4F3 clusters. In each V2NO4F3 cluster, there are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(4), one F(1), and one F(3) atom to form distorted edge-sharing VO3F2 trigonal bipyramids. The V(1)-O(1) bond length is 1.62 Å. The V(1)-O(3) bond length is 1.97 Å. The V(1)-O(4) bond length is 2.33 Å. The V(1)-F(1) bond length is 1.81 Å. The V(1)-F(3) bond length is 2.14 Å. In the second V site, V(2) is bonded to one O(2), one O(3), one F(2), and one F(3) atom to form edge-sharing VO2F2 tetrahedra. The V(2)-O(2) bond length is 1.61 Å. The V(2)-O(3) bond length is 1.73 Å. The V(2)-F(2) bond length is 1.77 Å. The V(2)-F(3) bond length is 1.88 Å. N(1) is bonded in a single-bond geometry to one O(4) atom. The N(1)-O(4) bond length is 1.17 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one V(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(2) atom. In the third F site, F(3) is bonded in an L-shaped geometry to one V(1) and one V(2) atom.