Hg(ReO3)3 crystallizes in the hexagonal P6mm space group. The structure consists of one 7439-97-6 atom inside a ReO3 framework. In the ReO3 framework, Re(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 0-29°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to two equivalent Re(1) atoms. In the second O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Re(1) atoms.
Hg(ReO3)3 crystallizes in the hexagonal P6mm space group. The structure consists of one 7439-97-6 atom inside a ReO3 framework. In the ReO3 framework, Re(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 0-29°. There is one shorter (1.89 Å) and one longer (1.90 Å) Re(1)-O(2) bond length. All Re(1)-O(1) bond lengths are 1.92 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to two equivalent Re(1) atoms. In the second O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Re(1) atoms.