ZrVW crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent V(1) and six equivalent W(1) atoms. V(1) is bonded to six equivalent Zr(1), two equivalent V(1), and four equivalent W(1) atoms to form distorted VZr6V2W4 cuboctahedra that share corners with eight equivalent W(1)Zr6V4W2 cuboctahedra, corners with ten equivalent V(1)Zr6V2W4 cuboctahedra, edges with six equivalent V(1)Zr6V2W4 cuboctahedra, faces with six equivalent V(1)Zr6V2W4 cuboctahedra, and faces with twelve equivalent W(1)Zr6V4W2 cuboctahedra. W(1) is bonded to six equivalent Zr(1), four equivalent V(1), and two equivalent W(1) atoms to form distorted WZr6V4W2 cuboctahedra that share corners with eight equivalent V(1)Zr6V2W4 cuboctahedra, corners with ten equivalent W(1)Zr6V4W2 cuboctahedra, edges with six equivalent W(1)Zr6V4W2 cuboctahedra, faces with six equivalent W(1)Zr6V4W2 cuboctahedra, and faces with twelve equivalent V(1)Zr6V2W4 cuboctahedra.
ZrVW crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent V(1) and six equivalent W(1) atoms. All Zr(1)-V(1) bond lengths are 3.10 Å. There are two shorter (3.09 Å) and four longer (3.11 Å) Zr(1)-W(1) bond lengths. V(1) is bonded to six equivalent Zr(1), two equivalent V(1), and four equivalent W(1) atoms to form distorted VZr6V2W4 cuboctahedra that share corners with eight equivalent W(1)Zr6V4W2 cuboctahedra, corners with ten equivalent V(1)Zr6V2W4 cuboctahedra, edges with six equivalent V(1)Zr6V2W4 cuboctahedra, faces with six equivalent V(1)Zr6V2W4 cuboctahedra, and faces with twelve equivalent W(1)Zr6V4W2 cuboctahedra. Both V(1)-V(1) bond lengths are 2.66 Å. All V(1)-W(1) bond lengths are 2.64 Å. W(1) is bonded to six equivalent Zr(1), four equivalent V(1), and two equivalent W(1) atoms to form distorted WZr6V4W2 cuboctahedra that share corners with eight equivalent V(1)Zr6V2W4 cuboctahedra, corners with ten equivalent W(1)Zr6V4W2 cuboctahedra, edges with six equivalent W(1)Zr6V4W2 cuboctahedra, faces with six equivalent W(1)Zr6V4W2 cuboctahedra, and faces with twelve equivalent V(1)Zr6V2W4 cuboctahedra. Both W(1)-W(1) bond lengths are 2.64 Å.