LiVSiO4 crystallizes in the cubic P2_13 space group. Li(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. V(1) is bonded to one O(2) and three equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Si(1)O4 tetrahedra. Si(1) is bonded to one O(2) and three equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom. In the second O site, O(2) is bonded in a linear geometry to one V(1) and one Si(1) atom.
LiVSiO4 crystallizes in the cubic P2_13 space group. Li(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 1.98 Å. V(1) is bonded to one O(2) and three equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Si(1)O4 tetrahedra. The V(1)-O(2) bond length is 1.87 Å. All V(1)-O(1) bond lengths are 1.95 Å. Si(1) is bonded to one O(2) and three equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra. The Si(1)-O(2) bond length is 1.61 Å. All Si(1)-O(1) bond lengths are 1.66 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom. In the second O site, O(2) is bonded in a linear geometry to one V(1) and one Si(1) atom.