AgTeO3 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(3) and two equivalent O(1) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form distorted corner-sharing TeO5 square pyramids. The corner-sharing octahedral tilt angles range from 62-65°. In the second Te site, Te(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form TeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O5 square pyramids. The corner-sharing octahedral tilt angles are 38°. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom to form distorted OAg2Te2 tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and  an edgeedge with one O(3)Ag3Te tetrahedra. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(1), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form distorted OAg3Te tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and edges with two equivalent O(1)Ag2Te2 tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(2) atoms.
AgTeO3 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Ag(1)-O(1) bond lengths are 2.35 Å. Both Ag(1)-O(2) bond lengths are 2.64 Å. Both Ag(1)-O(3) bond lengths are 2.59 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(3) and two equivalent O(1) atoms. The Ag(2)-O(3) bond length is 2.23 Å. Both Ag(2)-O(1) bond lengths are 2.40 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form distorted corner-sharing TeO5 square pyramids. The corner-sharing octahedral tilt angles range from 62-65°. The Te(1)-O(3) bond length is 1.85 Å. Both Te(1)-O(1) bond lengths are 2.39 Å. Both Te(1)-O(2) bond lengths are 2.03 Å. In the second Te site, Te(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form TeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O5 square pyramids. The corner-sharing octahedral tilt angles are 38°. Both Te(2)-O(1) bond lengths are 1.91 Å. Both Te(2)-O(2) bond lengths are 1.95 Å. Both Te(2)-O(4) bond lengths are 1.95 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom to form distorted OAg2Te2 tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and  an edgeedge with one O(3)Ag3Te tetrahedra. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(1), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form distorted OAg3Te tetrahedra that share corners with two equivalent O(3)Ag3Te tetrahedra, corners with four equivalent O(1)Ag2Te2 tetrahedra, and edges with two equivalent O(1)Ag2Te2 tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(2) atoms.