FeO2(FeF2)2FeOF crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two iron hydroxide (fe(oh)2) molecules, four iron(ii) fluoride molecules, and two FeOF clusters. In each FeOF cluster, Fe(1) is bonded in a linear geometry to one O(1) and one F(3) atom. O(1) is bonded in a distorted single-bond geometry to one Fe(1) atom. F(3) is bonded in a distorted single-bond geometry to one Fe(1) atom.
FeO2(FeF2)2FeOF crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two iron hydroxide (fe(oh)2) molecules, four iron(ii) fluoride molecules, and two FeOF clusters. In each FeOF cluster, Fe(1) is bonded in a linear geometry to one O(1) and one F(3) atom. The Fe(1)-O(1) bond length is 1.32 Å. The Fe(1)-F(3) bond length is 1.44 Å. O(1) is bonded in a distorted single-bond geometry to one Fe(1) atom. F(3) is bonded in a distorted single-bond geometry to one Fe(1) atom.