NaUF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent U(1)F6 octahedra. The corner-sharing octahedra are not tilted. U(1) is bonded to six equivalent F(1) atoms to form UF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Na(1) and one U(1) atom.
NaUF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent U(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-F(1) bond lengths are 2.25 Å. U(1) is bonded to six equivalent F(1) atoms to form UF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. All U(1)-F(1) bond lengths are 2.08 Å. F(1) is bonded in a linear geometry to one Na(1) and one U(1) atom.