N2S3Cl is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight N2S3Cl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) and one Cl(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) and one Cl(1) atom. Cl(1) is bonded in a 2-coordinate geometry to one S(1) and one S(3) atom.
N2S3Cl is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight N2S3Cl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.62 Å. The N(1)-S(2) bond length is 1.58 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(2)-S(2) bond length is 1.58 Å. The N(2)-S(3) bond length is 1.62 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) and one Cl(1) atom. The S(1)-Cl(1) bond length is 2.85 Å. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) and one Cl(1) atom. The S(3)-Cl(1) bond length is 2.81 Å. Cl(1) is bonded in a 2-coordinate geometry to one S(1) and one S(3) atom.