PtF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtF6 clusters. Pt(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Pt(1) atom.
PtF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtF6 clusters. Pt(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. The Pt(1)-F(1) bond length is 1.87 Å. The Pt(1)-F(2) bond length is 1.88 Å. Both Pt(1)-F(3) bond lengths are 1.87 Å. Both Pt(1)-F(4) bond lengths are 1.87 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Pt(1) atom.