CNSO3 is beta Polonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CNSO3 clusters. C(1) is bonded in a 2-coordinate geometry to one N(1) and one O(1) atom. N(1) is bonded in a water-like geometry to one C(1) and one S(1) atom. S(1) is bonded in a distorted tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom.
CNSO3 is beta Polonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CNSO3 clusters. C(1) is bonded in a 2-coordinate geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.29 Å. The C(1)-O(1) bond length is 1.31 Å. N(1) is bonded in a water-like geometry to one C(1) and one S(1) atom. The N(1)-S(1) bond length is 1.65 Å. S(1) is bonded in a distorted tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.84 Å. The S(1)-O(2) bond length is 1.43 Å. The S(1)-O(3) bond length is 1.42 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom.