BaLaZnRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. Ru(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form RuO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-29°. Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-29°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one Ru(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom.
BaLaZnRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There is one shorter (2.80 Å) and one longer (2.94 Å) Ba(1)-O(1) bond length. There is one shorter (2.76 Å) and one longer (3.00 Å) Ba(1)-O(2) bond length. There is one shorter (2.90 Å) and one longer (2.92 Å) Ba(1)-O(3) bond length. There is one shorter (2.61 Å) and one longer (3.16 Å) Ba(1)-O(4) bond length. There is one shorter (2.72 Å) and one longer (3.03 Å) Ba(1)-O(5) bond length. There is one shorter (2.70 Å) and one longer (3.08 Å) Ba(1)-O(6) bond length. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. The La(1)-O(1) bond length is 2.47 Å. The La(1)-O(2) bond length is 2.45 Å. The La(1)-O(3) bond length is 2.45 Å. The La(1)-O(5) bond length is 2.56 Å. The La(1)-O(6) bond length is 2.54 Å. Ru(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form RuO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-29°. The Ru(1)-O(1) bond length is 2.00 Å. The Ru(1)-O(2) bond length is 2.01 Å. The Ru(1)-O(3) bond length is 2.02 Å. The Ru(1)-O(4) bond length is 1.95 Å. The Ru(1)-O(5) bond length is 1.98 Å. The Ru(1)-O(6) bond length is 2.00 Å. Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-29°. The Zn(1)-O(1) bond length is 2.14 Å. The Zn(1)-O(2) bond length is 2.11 Å. The Zn(1)-O(3) bond length is 2.12 Å. The Zn(1)-O(4) bond length is 2.13 Å. The Zn(1)-O(5) bond length is 2.16 Å. The Zn(1)-O(6) bond length is 2.11 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one Ru(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), one Ru(1), and one Zn(1) atom.