NaLi2(RuO2)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom to form distorted LiO6 pentagonal pyramids that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra, corners with three equivalent Ru(1)O6 octahedra, corners with three equivalent Ru(3)O6 octahedra, corners with three equivalent Ru(6)O6 octahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra, and  an edgeedge with one Ru(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-73°. There are six inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(10), one O(6), one O(7), one O(8), and two equivalent O(9) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra, corners with three equivalent Li(2)O6 pentagonal pyramids,  an edgeedge with one Ru(1)O6 octahedra, and edges with three equivalent Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the second Ru site, Ru(2) is bonded to one O(5), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra,  a cornercorner with one Li(2)O6 pentagonal pyramid,  an edgeedge with one Ru(2)O6 octahedra, edges with three equivalent Ru(1)O6 octahedra, and  an edgeedge with one Li(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 52-54°. In the third Ru site, Ru(3) is bonded to one O(11), one O(3), one O(4), one O(8), and two equivalent O(12) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra, corners with three equivalent Li(2)O6 pentagonal pyramids,  an edgeedge with one Ru(3)O6 octahedra, and edges with three equivalent Ru(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. In the fourth Ru site, Ru(4) is bonded to one O(12), one O(3), one O(4), one O(7), and two equivalent O(11) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra,  a cornercorner with one Li(2)O6 pentagonal pyramid,  an edgeedge with one Ru(4)O6 octahedra, edges with three equivalent Ru(3)O6 octahedra, and  an edgeedge with one Li(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 52-56°. In the fifth Ru site, Ru(5) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(2) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Li(2)O6 pentagonal pyramid,  an edgeedge with one Ru(5)O6 octahedra, edges with three equivalent Ru(6)O6 octahedra, and  an edgeedge with one Li(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 53-57°. In the sixth Ru site, Ru(6) is bonded to one O(2), one O(4), one O(5), one O(6), and two equivalent O(1) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra, corners with three equivalent Li(2)O6 pentagonal pyramids,  an edgeedge with one Ru(6)O6 octahedra, and edges with three equivalent Ru(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Ru(5), and two equivalent Ru(6) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(10)Li2Ru3 trigonal bipyramids, corners with two equivalent O(12)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(6)NaRu3 trigonal pyramid, corners with two equivalent O(4)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(11)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(9)Li2Ru3 trigonal bipyramid, edges with three equivalent O(2)Li2Ru3 trigonal bipyramids, and  an edgeedge with one O(6)NaRu3 trigonal pyramid. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ru(6), and two equivalent Ru(5) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(11)Li2Ru3 trigonal bipyramids, corners with two equivalent O(9)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(4)NaRu3 trigonal pyramid, corners with three equivalent O(6)NaRu3 trigonal pyramids,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(2)Li2Ru3 trigonal bipyramid, and edges with three equivalent O(1)Li2Ru3 trigonal bipyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Na(1), one Ru(3), one Ru(4), and one Ru(5) atom. In the fourth O site, O(4) is bonded to one Na(1), one Ru(3), one Ru(4), and one Ru(6) atom to form distorted ONaRu3 trigonal pyramids that share  a cornercorner with one O(12)Li2Ru3 trigonal bipyramid,  a cornercorner with one O(2)Li2Ru3 trigonal bipyramid, corners with two equivalent O(1)Li2Ru3 trigonal bipyramids, corners with three equivalent O(11)Li2Ru3 trigonal bipyramids,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(6)NaRu3 trigonal pyramid, and  an edgeedge with one O(7)NaRu3 trigonal pyramid. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Na(1), one Ru(2), one Ru(5), and one Ru(6) atom. In the sixth O site, O(6) is bonded to one Na(1), one Ru(1), one Ru(5), and one Ru(6) atom to form distorted ONaRu3 trigonal pyramids that share  a cornercorner with one O(1)Li2Ru3 trigonal bipyramid,  a cornercorner with one O(10)Li2Ru3 trigonal bipyramid, corners with two equivalent O(9)Li2Ru3 trigonal bipyramids, corners with three equivalent O(2)Li2Ru3 trigonal bipyramids, corners with two equivalent O(7)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid, and  an edgeedge with one O(4)NaRu3 trigonal pyramid. In the seventh O site, O(7) is bonded to one Na(1), one Ru(1), one Ru(2), and one Ru(4) atom to form distorted ONaRu3 trigonal pyramids that share  a cornercorner with one O(10)Li2Ru3 trigonal bipyramid,  a cornercorner with one O(12)Li2Ru3 trigonal bipyramid, corners with two equivalent O(11)Li2Ru3 trigonal bipyramids, corners with three equivalent O(9)Li2Ru3 trigonal bipyramids, corners with two equivalent O(6)NaRu3 trigonal pyramids,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid, and  an edgeedge with one O(4)NaRu3 trigonal pyramid. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(1), one Ru(1), one Ru(2), and one Ru(3) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Ru(2), and two equivalent Ru(1) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(12)Li2Ru3 trigonal bipyramids, corners with two equivalent O(2)Li2Ru3 trigonal bipyramids, corners with two equivalent O(6)NaRu3 trigonal pyramids, corners with three equivalent O(7)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(11)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(9)Li2Ru3 trigonal bipyramid, and edges with three equivalent O(10)Li2Ru3 trigonal bipyramids. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Ru(1), and two equivalent Ru(2) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(1)Li2Ru3 trigonal bipyramids, corners with two equivalent O(11)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(6)NaRu3 trigonal pyramid,  a cornercorner with one O(7)NaRu3 trigonal pyramid,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(2)Li2Ru3 trigonal bipyramid, edges with three equivalent O(9)Li2Ru3 trigonal bipyramids, and  an edgeedge with one O(7)NaRu3 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(1), one Li(2), one Ru(3), and two equivalent Ru(4) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(10)Li2Ru3 trigonal bipyramids, corners with two equivalent O(2)Li2Ru3 trigonal bipyramids, corners with two equivalent O(7)NaRu3 trigonal pyramids, corners with three equivalent O(4)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(11)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(9)Li2Ru3 trigonal bipyramid, and edges with three equivalent O(12)Li2Ru3 trigonal bipyramids. In the twelfth O site, O(12) is bonded to one Li(1), one Li(2), one Ru(4), and two equivalent Ru(3) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(1)Li2Ru3 trigonal bipyramids, corners with two equivalent O(9)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(4)NaRu3 trigonal pyramid,  a cornercorner with one O(7)NaRu3 trigonal pyramid,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(2)Li2Ru3 trigonal bipyramid, edges with three equivalent O(11)Li2Ru3 trigonal bipyramids, and  an edgeedge with one O(4)NaRu3 trigonal pyramid.
NaLi2(RuO2)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Na(1)-O(3) bond length is 2.50 Å. The Na(1)-O(4) bond length is 2.50 Å. The Na(1)-O(5) bond length is 2.45 Å. The Na(1)-O(6) bond length is 2.58 Å. The Na(1)-O(7) bond length is 2.50 Å. The Na(1)-O(8) bond length is 2.50 Å. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom. The Li(1)-O(1) bond length is 2.26 Å. The Li(1)-O(10) bond length is 2.30 Å. The Li(1)-O(11) bond length is 2.17 Å. The Li(1)-O(12) bond length is 2.29 Å. The Li(1)-O(2) bond length is 2.13 Å. The Li(1)-O(9) bond length is 2.09 Å. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(9) atom to form distorted LiO6 pentagonal pyramids that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra, corners with three equivalent Ru(1)O6 octahedra, corners with three equivalent Ru(3)O6 octahedra, corners with three equivalent Ru(6)O6 octahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra, and  an edgeedge with one Ru(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-73°. The Li(2)-O(1) bond length is 2.32 Å. The Li(2)-O(10) bond length is 2.16 Å. The Li(2)-O(11) bond length is 2.16 Å. The Li(2)-O(12) bond length is 2.16 Å. The Li(2)-O(2) bond length is 2.09 Å. The Li(2)-O(9) bond length is 2.21 Å. There are six inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(10), one O(6), one O(7), one O(8), and two equivalent O(9) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra, corners with three equivalent Li(2)O6 pentagonal pyramids,  an edgeedge with one Ru(1)O6 octahedra, and edges with three equivalent Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. The Ru(1)-O(10) bond length is 2.06 Å. The Ru(1)-O(6) bond length is 2.05 Å. The Ru(1)-O(7) bond length is 2.03 Å. The Ru(1)-O(8) bond length is 1.99 Å. There is one shorter (2.03 Å) and one longer (2.10 Å) Ru(1)-O(9) bond length. In the second Ru site, Ru(2) is bonded to one O(5), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra,  a cornercorner with one Li(2)O6 pentagonal pyramid,  an edgeedge with one Ru(2)O6 octahedra, edges with three equivalent Ru(1)O6 octahedra, and  an edgeedge with one Li(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 52-54°. The Ru(2)-O(5) bond length is 2.03 Å. The Ru(2)-O(7) bond length is 2.04 Å. The Ru(2)-O(8) bond length is 2.03 Å. The Ru(2)-O(9) bond length is 2.05 Å. There is one shorter (2.07 Å) and one longer (2.10 Å) Ru(2)-O(10) bond length. In the third Ru site, Ru(3) is bonded to one O(11), one O(3), one O(4), one O(8), and two equivalent O(12) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra, corners with three equivalent Li(2)O6 pentagonal pyramids,  an edgeedge with one Ru(3)O6 octahedra, and edges with three equivalent Ru(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. The Ru(3)-O(11) bond length is 2.05 Å. The Ru(3)-O(3) bond length is 2.01 Å. The Ru(3)-O(4) bond length is 2.04 Å. The Ru(3)-O(8) bond length is 2.02 Å. There is one shorter (2.07 Å) and one longer (2.11 Å) Ru(3)-O(12) bond length. In the fourth Ru site, Ru(4) is bonded to one O(12), one O(3), one O(4), one O(7), and two equivalent O(11) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(5)O6 octahedra,  a cornercorner with one Ru(6)O6 octahedra,  a cornercorner with one Li(2)O6 pentagonal pyramid,  an edgeedge with one Ru(4)O6 octahedra, edges with three equivalent Ru(3)O6 octahedra, and  an edgeedge with one Li(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 52-56°. The Ru(4)-O(12) bond length is 2.07 Å. The Ru(4)-O(3) bond length is 2.02 Å. The Ru(4)-O(4) bond length is 2.03 Å. The Ru(4)-O(7) bond length is 2.07 Å. There is one shorter (2.03 Å) and one longer (2.08 Å) Ru(4)-O(11) bond length. In the fifth Ru site, Ru(5) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(2) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Li(2)O6 pentagonal pyramid,  an edgeedge with one Ru(5)O6 octahedra, edges with three equivalent Ru(6)O6 octahedra, and  an edgeedge with one Li(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 53-57°. The Ru(5)-O(1) bond length is 2.07 Å. The Ru(5)-O(3) bond length is 2.02 Å. The Ru(5)-O(5) bond length is 2.02 Å. The Ru(5)-O(6) bond length is 2.02 Å. There is one shorter (2.04 Å) and one longer (2.10 Å) Ru(5)-O(2) bond length. In the sixth Ru site, Ru(6) is bonded to one O(2), one O(4), one O(5), one O(6), and two equivalent O(1) atoms to form RuO6 octahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra, corners with three equivalent Li(2)O6 pentagonal pyramids,  an edgeedge with one Ru(6)O6 octahedra, and edges with three equivalent Ru(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. The Ru(6)-O(2) bond length is 2.04 Å. The Ru(6)-O(4) bond length is 2.07 Å. The Ru(6)-O(5) bond length is 2.00 Å. The Ru(6)-O(6) bond length is 2.04 Å. There is one shorter (2.06 Å) and one longer (2.09 Å) Ru(6)-O(1) bond length. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Ru(5), and two equivalent Ru(6) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(10)Li2Ru3 trigonal bipyramids, corners with two equivalent O(12)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(6)NaRu3 trigonal pyramid, corners with two equivalent O(4)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(11)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(9)Li2Ru3 trigonal bipyramid, edges with three equivalent O(2)Li2Ru3 trigonal bipyramids, and  an edgeedge with one O(6)NaRu3 trigonal pyramid. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ru(6), and two equivalent Ru(5) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(11)Li2Ru3 trigonal bipyramids, corners with two equivalent O(9)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(4)NaRu3 trigonal pyramid, corners with three equivalent O(6)NaRu3 trigonal pyramids,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(2)Li2Ru3 trigonal bipyramid, and edges with three equivalent O(1)Li2Ru3 trigonal bipyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Na(1), one Ru(3), one Ru(4), and one Ru(5) atom. In the fourth O site, O(4) is bonded to one Na(1), one Ru(3), one Ru(4), and one Ru(6) atom to form distorted ONaRu3 trigonal pyramids that share  a cornercorner with one O(12)Li2Ru3 trigonal bipyramid,  a cornercorner with one O(2)Li2Ru3 trigonal bipyramid, corners with two equivalent O(1)Li2Ru3 trigonal bipyramids, corners with three equivalent O(11)Li2Ru3 trigonal bipyramids,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(6)NaRu3 trigonal pyramid, and  an edgeedge with one O(7)NaRu3 trigonal pyramid. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Na(1), one Ru(2), one Ru(5), and one Ru(6) atom. In the sixth O site, O(6) is bonded to one Na(1), one Ru(1), one Ru(5), and one Ru(6) atom to form distorted ONaRu3 trigonal pyramids that share  a cornercorner with one O(1)Li2Ru3 trigonal bipyramid,  a cornercorner with one O(10)Li2Ru3 trigonal bipyramid, corners with two equivalent O(9)Li2Ru3 trigonal bipyramids, corners with three equivalent O(2)Li2Ru3 trigonal bipyramids, corners with two equivalent O(7)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid, and  an edgeedge with one O(4)NaRu3 trigonal pyramid. In the seventh O site, O(7) is bonded to one Na(1), one Ru(1), one Ru(2), and one Ru(4) atom to form distorted ONaRu3 trigonal pyramids that share  a cornercorner with one O(10)Li2Ru3 trigonal bipyramid,  a cornercorner with one O(12)Li2Ru3 trigonal bipyramid, corners with two equivalent O(11)Li2Ru3 trigonal bipyramids, corners with three equivalent O(9)Li2Ru3 trigonal bipyramids, corners with two equivalent O(6)NaRu3 trigonal pyramids,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid, and  an edgeedge with one O(4)NaRu3 trigonal pyramid. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(1), one Ru(1), one Ru(2), and one Ru(3) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Ru(2), and two equivalent Ru(1) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(12)Li2Ru3 trigonal bipyramids, corners with two equivalent O(2)Li2Ru3 trigonal bipyramids, corners with two equivalent O(6)NaRu3 trigonal pyramids, corners with three equivalent O(7)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(11)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(9)Li2Ru3 trigonal bipyramid, and edges with three equivalent O(10)Li2Ru3 trigonal bipyramids. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Ru(1), and two equivalent Ru(2) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(1)Li2Ru3 trigonal bipyramids, corners with two equivalent O(11)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(6)NaRu3 trigonal pyramid,  a cornercorner with one O(7)NaRu3 trigonal pyramid,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(2)Li2Ru3 trigonal bipyramid, edges with three equivalent O(9)Li2Ru3 trigonal bipyramids, and  an edgeedge with one O(7)NaRu3 trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(1), one Li(2), one Ru(3), and two equivalent Ru(4) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(10)Li2Ru3 trigonal bipyramids, corners with two equivalent O(2)Li2Ru3 trigonal bipyramids, corners with two equivalent O(7)NaRu3 trigonal pyramids, corners with three equivalent O(4)NaRu3 trigonal pyramids,  an edgeedge with one O(1)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(11)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(9)Li2Ru3 trigonal bipyramid, and edges with three equivalent O(12)Li2Ru3 trigonal bipyramids. In the twelfth O site, O(12) is bonded to one Li(1), one Li(2), one Ru(4), and two equivalent Ru(3) atoms to form distorted OLi2Ru3 trigonal bipyramids that share corners with two equivalent O(1)Li2Ru3 trigonal bipyramids, corners with two equivalent O(9)Li2Ru3 trigonal bipyramids,  a cornercorner with one O(4)NaRu3 trigonal pyramid,  a cornercorner with one O(7)NaRu3 trigonal pyramid,  an edgeedge with one O(10)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(12)Li2Ru3 trigonal bipyramid,  an edgeedge with one O(2)Li2Ru3 trigonal bipyramid, edges with three equivalent O(11)Li2Ru3 trigonal bipyramids, and  an edgeedge with one O(4)NaRu3 trigonal pyramid.