AlC2H6TeBr3 is Indium-like structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four AlC2H6TeBr3 clusters. Al(1) is bonded in a tetrahedral geometry to one Te(1), one Br(1), and two equivalent Br(2) atoms. C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one Te(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one Al(1) and two equivalent C(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Al(1) atom.
AlC2H6TeBr3 is Indium-like structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four AlC2H6TeBr3 clusters. Al(1) is bonded in a tetrahedral geometry to one Te(1), one Br(1), and two equivalent Br(2) atoms. The Al(1)-Te(1) bond length is 2.75 Å. The Al(1)-Br(1) bond length is 2.32 Å. Both Al(1)-Br(2) bond lengths are 2.31 Å. C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one Te(1) atom. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.09 Å. The C(1)-Te(1) bond length is 2.15 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one Al(1) and two equivalent C(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Al(1) atom.