Pb2MnWO6 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the orthorhombic Pna2_1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the second O site, O(6) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the third O site, O(1) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fourth O site, O(2) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fifth O site, O(3) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the sixth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom.
Pb2MnWO6 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the orthorhombic Pna2_1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. The W(1)-O(1) bond length is 2.15 Å. The W(1)-O(2) bond length is 1.97 Å. The W(1)-O(3) bond length is 1.86 Å. The W(1)-O(4) bond length is 1.97 Å. The W(1)-O(5) bond length is 1.97 Å. The W(1)-O(6) bond length is 1.92 Å. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. The Mn(1)-O(1) bond length is 2.18 Å. The Mn(1)-O(2) bond length is 2.40 Å. The Mn(1)-O(3) bond length is 2.18 Å. The Mn(1)-O(4) bond length is 2.18 Å. The Mn(1)-O(5) bond length is 2.17 Å. The Mn(1)-O(6) bond length is 2.19 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. The Pb(1)-O(1) bond length is 2.47 Å. The Pb(1)-O(2) bond length is 2.61 Å. The Pb(1)-O(4) bond length is 2.55 Å. The Pb(1)-O(5) bond length is 2.47 Å. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. The Pb(2)-O(1) bond length is 2.43 Å. The Pb(2)-O(2) bond length is 2.51 Å. The Pb(2)-O(4) bond length is 2.57 Å. The Pb(2)-O(5) bond length is 2.61 Å. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the second O site, O(6) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the third O site, O(1) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fourth O site, O(2) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fifth O site, O(3) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the sixth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom.