RuNOCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuNOCl5 clusters. In each RuNOCl5 cluster, Ru(1) is bonded in an octahedral geometry to one N(2), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. N(2) is bonded in a linear geometry to one Ru(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom.
RuNOCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuNOCl5 clusters. In each RuNOCl5 cluster, Ru(1) is bonded in an octahedral geometry to one N(2), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. The Ru(1)-N(2) bond length is 1.79 Å. The Ru(1)-Cl(1) bond length is 2.34 Å. The Ru(1)-Cl(3) bond length is 2.33 Å. The Ru(1)-Cl(4) bond length is 2.31 Å. Both Ru(1)-Cl(2) bond lengths are 2.34 Å. N(2) is bonded in a linear geometry to one Ru(1) and one O(1) atom. The N(2)-O(1) bond length is 1.15 Å. O(1) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom.