GdCPH3O6H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a GdCPH3O6 framework. In the GdCPH3O6 framework, Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(5), one O(6), one O(7), two equivalent O(3), and two equivalent O(4) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(6) atom. P(1) is bonded in a distorted tetrahedral geometry to one H(5), one O(3), one O(4), and one O(7) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one P(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one C(1) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the fourth O site, O(5) is bonded in a distorted water-like geometry to one Gd(1), one H(2), and one H(4) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one Gd(1) and one C(1) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one P(1) atom.
GdCPH3O6H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a GdCPH3O6 framework. In the GdCPH3O6 framework, Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(5), one O(6), one O(7), two equivalent O(3), and two equivalent O(4) atoms. The Gd(1)-O(1) bond length is 2.44 Å. The Gd(1)-O(5) bond length is 2.38 Å. The Gd(1)-O(6) bond length is 2.47 Å. The Gd(1)-O(7) bond length is 2.33 Å. There is one shorter (2.41 Å) and one longer (2.49 Å) Gd(1)-O(3) bond length. There is one shorter (2.37 Å) and one longer (2.52 Å) Gd(1)-O(4) bond length. C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(6) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(6) bond length is 1.27 Å. P(1) is bonded in a distorted tetrahedral geometry to one H(5), one O(3), one O(4), and one O(7) atom. The P(1)-H(5) bond length is 1.41 Å. The P(1)-O(3) bond length is 1.56 Å. The P(1)-O(4) bond length is 1.55 Å. The P(1)-O(7) bond length is 1.53 Å. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 1.00 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. The H(4)-O(5) bond length is 0.99 Å. In the third H site, H(5) is bonded in a single-bond geometry to one P(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one C(1) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the fourth O site, O(5) is bonded in a distorted water-like geometry to one Gd(1), one H(2), and one H(4) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one Gd(1) and one C(1) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one P(1) atom.