AgFAsF6 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded to one F(3), two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent As(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one As(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 32-40°. As(1) is bonded to one F(3), one F(4), two equivalent F(1), and two equivalent F(5) atoms to form AsF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a distorted water-like geometry to one Ag(1) and one As(1) atom.
AgFAsF6 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded to one F(3), two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent As(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one As(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 32-40°. The Ag(1)-F(3) bond length is 2.41 Å. Both Ag(1)-F(1) bond lengths are 2.36 Å. Both Ag(1)-F(2) bond lengths are 2.01 Å. Both Ag(1)-F(5) bond lengths are 2.42 Å. As(1) is bonded to one F(3), one F(4), two equivalent F(1), and two equivalent F(5) atoms to form AsF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. The As(1)-F(3) bond length is 1.76 Å. The As(1)-F(4) bond length is 1.71 Å. Both As(1)-F(1) bond lengths are 1.75 Å. Both As(1)-F(5) bond lengths are 1.76 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a distorted water-like geometry to one Ag(1) and one As(1) atom.