TiN2H6F5NH4 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four ammonium molecules and four TiN2H6F5 clusters. In each TiN2H6F5 cluster, Ti(1) is bonded in a distorted octahedral geometry to one N(2), one H(10), one F(1), one F(3), one F(4), and one F(5) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ti(1) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) and one F(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a linear geometry to one F(2) and one F(3) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one Ti(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one H(5) atom. In the third F site, F(3) is bonded in an L-shaped geometry to one Ti(1) and one H(5) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ti(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one H(3) atom.
TiN2H6F5NH4 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four ammonium molecules and four TiN2H6F5 clusters. In each TiN2H6F5 cluster, Ti(1) is bonded in a distorted octahedral geometry to one N(2), one H(10), one F(1), one F(3), one F(4), and one F(5) atom. The Ti(1)-N(2) bond length is 2.01 Å. The Ti(1)-H(10) bond length is 1.79 Å. The Ti(1)-F(1) bond length is 1.92 Å. The Ti(1)-F(3) bond length is 2.11 Å. The Ti(1)-F(4) bond length is 1.82 Å. The Ti(1)-F(5) bond length is 1.96 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. The N(1)-H(1) bond length is 1.04 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.05 Å. The N(1)-H(4) bond length is 1.03 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Ti(1) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) and one F(5) atom. The H(3)-F(5) bond length is 1.65 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a linear geometry to one F(2) and one F(3) atom. The H(5)-F(2) bond length is 1.04 Å. The H(5)-F(3) bond length is 1.32 Å. In the sixth H site, H(10) is bonded in a single-bond geometry to one Ti(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one H(5) atom. In the third F site, F(3) is bonded in an L-shaped geometry to one Ti(1) and one H(5) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ti(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one H(3) atom.