Mo5NO16N2NO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia atoms, two nitroxyl molecules, and one Mo5NO16 cluster. In the Mo5NO16 cluster, there are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(4), one O(8), and one O(9) atom. In the third Mo site, Mo(3) is bonded to one O(1), one O(10), one O(12), and one O(7) atom to form corner-sharing MoO4 tetrahedra. In the fourth Mo site, Mo(4) is bonded to one O(11), one O(13), one O(14), one O(3), and one O(7) atom to form distorted corner-sharing MoO5 trigonal bipyramids. In the fifth Mo site, Mo(5) is bonded to one O(13), one O(16), one O(17), and one O(2) atom to form corner-sharing MoO4 tetrahedra. N(4) is bonded in a water-like geometry to one O(4) and one O(5) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one N(4) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Mo(1) and one N(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(3) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(4) and one Mo(5) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(4) atom. In the fifteenth O site, O(16) is bonded in a single-bond geometry to one Mo(5) atom. In the sixteenth O site, O(17) is bonded in a single-bond geometry to one Mo(5) atom.
Mo5NO16N2NO is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia atoms, two nitroxyl molecules, and one Mo5NO16 cluster. In the Mo5NO16 cluster, there are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Mo(1)-O(1) bond length is 2.06 Å. The Mo(1)-O(2) bond length is 1.96 Å. The Mo(1)-O(3) bond length is 2.20 Å. The Mo(1)-O(4) bond length is 2.24 Å. The Mo(1)-O(5) bond length is 2.22 Å. The Mo(1)-O(6) bond length is 1.70 Å. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(4), one O(8), and one O(9) atom. The Mo(2)-O(10) bond length is 2.09 Å. The Mo(2)-O(11) bond length is 1.92 Å. The Mo(2)-O(4) bond length is 2.26 Å. The Mo(2)-O(8) bond length is 1.71 Å. The Mo(2)-O(9) bond length is 1.72 Å. In the third Mo site, Mo(3) is bonded to one O(1), one O(10), one O(12), and one O(7) atom to form corner-sharing MoO4 tetrahedra. The Mo(3)-O(1) bond length is 1.85 Å. The Mo(3)-O(10) bond length is 1.81 Å. The Mo(3)-O(12) bond length is 1.71 Å. The Mo(3)-O(7) bond length is 1.85 Å. In the fourth Mo site, Mo(4) is bonded to one O(11), one O(13), one O(14), one O(3), and one O(7) atom to form distorted corner-sharing MoO5 trigonal bipyramids. The Mo(4)-O(11) bond length is 1.95 Å. The Mo(4)-O(13) bond length is 1.92 Å. The Mo(4)-O(14) bond length is 1.70 Å. The Mo(4)-O(3) bond length is 1.82 Å. The Mo(4)-O(7) bond length is 2.16 Å. In the fifth Mo site, Mo(5) is bonded to one O(13), one O(16), one O(17), and one O(2) atom to form corner-sharing MoO4 tetrahedra. The Mo(5)-O(13) bond length is 1.93 Å. The Mo(5)-O(16) bond length is 1.72 Å. The Mo(5)-O(17) bond length is 1.72 Å. The Mo(5)-O(2) bond length is 1.88 Å. N(4) is bonded in a water-like geometry to one O(4) and one O(5) atom. The N(4)-O(4) bond length is 1.34 Å. The N(4)-O(5) bond length is 1.26 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one N(4) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Mo(1) and one N(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one Mo(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Mo(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Mo(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(3) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(4) and one Mo(5) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Mo(4) atom. In the fifteenth O site, O(16) is bonded in a single-bond geometry to one Mo(5) atom. In the sixteenth O site, O(17) is bonded in a single-bond geometry to one Mo(5) atom.