BNH2 is Indium-like structured and crystallizes in the tetragonal P4_32_12 space group. The structure is zero-dimensional and consists of four 1,3,5,2,4,6-triazatriborinane molecules. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one H(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(1), one B(2), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom.
BNH2 is Indium-like structured and crystallizes in the tetragonal P4_32_12 space group. The structure is zero-dimensional and consists of four 1,3,5,2,4,6-triazatriborinane molecules. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The B(1)-N(1) bond length is 1.43 Å. The B(1)-N(2) bond length is 1.43 Å. The B(1)-H(3) bond length is 1.20 Å. In the second B site, B(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one H(1) atom. Both B(2)-N(1) bond lengths are 1.43 Å. The B(2)-H(1) bond length is 1.20 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(1), one B(2), and one H(2) atom. The N(1)-H(2) bond length is 1.02 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(4) atom. The N(2)-H(4) bond length is 1.02 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom.