AlNSCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AlNSCl3 clusters. Al(1) is bonded in a tetrahedral geometry to one N(1), one Cl(1), one Cl(2), and one Cl(3) atom. N(1) is bonded in a distorted trigonal planar geometry to one Al(1) and two equivalent S(1) atoms. S(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom.
AlNSCl3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AlNSCl3 clusters. Al(1) is bonded in a tetrahedral geometry to one N(1), one Cl(1), one Cl(2), and one Cl(3) atom. The Al(1)-N(1) bond length is 1.96 Å. The Al(1)-Cl(1) bond length is 2.14 Å. The Al(1)-Cl(2) bond length is 2.11 Å. The Al(1)-Cl(3) bond length is 2.15 Å. N(1) is bonded in a distorted trigonal planar geometry to one Al(1) and two equivalent S(1) atoms. Both N(1)-S(1) bond lengths are 1.66 Å. S(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom.