NaBF4 is Zircon-like structured and crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(2) atoms. B(1) is bonded in a tetrahedral geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one B(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one B(1) atom.
NaBF4 is Zircon-like structured and crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two shorter (2.26 Å) and two longer (2.46 Å) Na(1)-F(1) bond lengths. There are two shorter (2.36 Å) and two longer (2.50 Å) Na(1)-F(2) bond lengths. B(1) is bonded in a tetrahedral geometry to two equivalent F(1) and two equivalent F(2) atoms. Both B(1)-F(1) bond lengths are 1.41 Å. Both B(1)-F(2) bond lengths are 1.40 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one B(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one B(1) atom.