(MnF3)2N2 is (Cubic) Perovskite structured and crystallizes in the orthorhombic Pnma space group. The structure consists of four ammonia atoms inside a MnF3 framework. In the MnF3 framework, Mn(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Mn(1) atoms.
(MnF3)2N2 is (Cubic) Perovskite structured and crystallizes in the orthorhombic Pnma space group. The structure consists of four ammonia atoms inside a MnF3 framework. In the MnF3 framework, Mn(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 3-4°. Both Mn(1)-F(2) bond lengths are 2.01 Å. There are two shorter (1.92 Å) and two longer (2.06 Å) Mn(1)-F(1) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Mn(1) atoms.