LiRh3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to four equivalent Rh(2) and eight equivalent Rh(1) atoms to form a mixture of corner, face, and edge-sharing LiRh12 cuboctahedra. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Li(1) atoms to form a mixture of distorted corner and edge-sharing RhLi4 cuboctahedra. In the second Rh site, Rh(2) is bonded in a distorted square co-planar geometry to four equivalent Li(1) atoms.
LiRh3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to four equivalent Rh(2) and eight equivalent Rh(1) atoms to form a mixture of corner, face, and edge-sharing LiRh12 cuboctahedra. All Li(1)-Rh(2) bond lengths are 2.67 Å. All Li(1)-Rh(1) bond lengths are 2.69 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Li(1) atoms to form a mixture of distorted corner and edge-sharing RhLi4 cuboctahedra. In the second Rh site, Rh(2) is bonded in a distorted square co-planar geometry to four equivalent Li(1) atoms.