TlBr is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. Tl(1) is bonded to six equivalent Br(1) atoms to form a mixture of corner and edge-sharing TlBr6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded to six equivalent Tl(1) atoms to form a mixture of corner and edge-sharing BrTl6 octahedra. The corner-sharing octahedra are not tilted.
TlBr is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. Tl(1) is bonded to six equivalent Br(1) atoms to form a mixture of corner and edge-sharing TlBr6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 3.34 Å. Br(1) is bonded to six equivalent Tl(1) atoms to form a mixture of corner and edge-sharing BrTl6 octahedra. The corner-sharing octahedra are not tilted.