BaNd(FeO3)2 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Nd(1)O12 cuboctahedra, and faces with eight equivalent Fe(1)O6 octahedra. Nd(1) is bonded to twelve equivalent O(1) atoms to form NdO12 cuboctahedra that share corners with twelve equivalent Nd(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, and faces with eight equivalent Fe(1)O6 octahedra. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent Ba(1), two equivalent Nd(1), and two equivalent Fe(1) atoms to form a mixture of distorted face, corner, and edge-sharing OBa2Nd2Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
BaNd(FeO3)2 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Nd(1)O12 cuboctahedra, and faces with eight equivalent Fe(1)O6 octahedra. All Ba(1)-O(1) bond lengths are 2.80 Å. Nd(1) is bonded to twelve equivalent O(1) atoms to form NdO12 cuboctahedra that share corners with twelve equivalent Nd(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, and faces with eight equivalent Fe(1)O6 octahedra. All Nd(1)-O(1) bond lengths are 2.80 Å. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Fe(1)-O(1) bond lengths are 1.98 Å. O(1) is bonded to two equivalent Ba(1), two equivalent Nd(1), and two equivalent Fe(1) atoms to form a mixture of distorted face, corner, and edge-sharing OBa2Nd2Fe2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.