CsAuNH3 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 9-coordinate geometry to six equivalent Au(1), one N(1), one H(2), and one H(3) atom. Au(1) is bonded in a 8-coordinate geometry to six equivalent Cs(1) and two equivalent Au(1) atoms. N(1) is bonded in a trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom.
CsAuNH3 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 9-coordinate geometry to six equivalent Au(1), one N(1), one H(2), and one H(3) atom. There are a spread of Cs(1)-Au(1) bond distances ranging from 3.67-3.90 Å. The Cs(1)-N(1) bond length is 3.31 Å. The Cs(1)-H(2) bond length is 3.45 Å. The Cs(1)-H(3) bond length is 3.25 Å. Au(1) is bonded in a 8-coordinate geometry to six equivalent Cs(1) and two equivalent Au(1) atoms. There is one shorter (3.12 Å) and one longer (3.24 Å) Au(1)-Au(1) bond length. N(1) is bonded in a trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.02 Å. The N(1)-H(3) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom.