PrTiGe is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Pr(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. Ti(1) is bonded to four equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing TiGe4 tetrahedra. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Pr(1) and four equivalent Ti(1) atoms.
PrTiGe is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Pr(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. There are four shorter (3.10 Å) and one longer (3.48 Å) Pr(1)-Ge(1) bond length. Ti(1) is bonded to four equivalent Ge(1) atoms to form a mixture of distorted edge and corner-sharing TiGe4 tetrahedra. All Ti(1)-Ge(1) bond lengths are 2.74 Å. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Pr(1) and four equivalent Ti(1) atoms.