CSbNOCl4 is Indium-like structured and crystallizes in the hexagonal P6_3/m space group. The structure is zero-dimensional and consists of two CSbNOCl4 clusters. C(1) is bonded in a trigonal planar geometry to two equivalent N(1) and one O(1) atom. Sb(1) is bonded in an octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. N(1) is bonded in a 3-coordinate geometry to two equivalent C(1) and one Sb(1) atom. O(1) is bonded in a distorted L-shaped geometry to one C(1) and one Sb(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom.
CSbNOCl4 is Indium-like structured and crystallizes in the hexagonal P6_3/m space group. The structure is zero-dimensional and consists of two CSbNOCl4 clusters. C(1) is bonded in a trigonal planar geometry to two equivalent N(1) and one O(1) atom. There is one shorter (1.34 Å) and one longer (1.37 Å) C(1)-N(1) bond length. The C(1)-O(1) bond length is 1.28 Å. Sb(1) is bonded in an octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. The Sb(1)-N(1) bond length is 2.30 Å. The Sb(1)-O(1) bond length is 2.21 Å. The Sb(1)-Cl(1) bond length is 2.33 Å. The Sb(1)-Cl(3) bond length is 2.34 Å. Both Sb(1)-Cl(2) bond lengths are 2.36 Å. N(1) is bonded in a 3-coordinate geometry to two equivalent C(1) and one Sb(1) atom. O(1) is bonded in a distorted L-shaped geometry to one C(1) and one Sb(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom.