SbF3 crystallizes in the orthorhombic Ama2 space group. Sb(1) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Sb(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms.
SbF3 crystallizes in the orthorhombic Ama2 space group. Sb(1) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(2) atoms. There is one shorter (1.97 Å) and one longer (2.49 Å) Sb(1)-F(1) bond length. There are two shorter (1.97 Å) and two longer (2.51 Å) Sb(1)-F(2) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Sb(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms.