NH4PHO3F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonium molecules and one PHO3F cluster. In the PHO3F cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one F(1) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one F(2) atom. There are two inequivalent H sites. In the first H site, H(9) is bonded in a linear geometry to one O(3) and one O(6) atom. In the second H site, H(10) is bonded in a linear geometry to one O(1) and one O(4) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(10) atom. In the second O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(6) is bonded in a bent 150 degrees geometry to one P(2) and one H(9) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one H(10) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(9) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(2) atom.
NH4PHO3F is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonium molecules and one PHO3F cluster. In the PHO3F cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one F(1) atom. The P(1)-O(3) bond length is 1.55 Å. The P(1)-O(4) bond length is 1.50 Å. The P(1)-O(5) bond length is 1.49 Å. The P(1)-F(1) bond length is 1.59 Å. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one F(2) atom. The P(2)-O(1) bond length is 1.55 Å. The P(2)-O(2) bond length is 1.49 Å. The P(2)-O(6) bond length is 1.49 Å. The P(2)-F(2) bond length is 1.58 Å. There are two inequivalent H sites. In the first H site, H(9) is bonded in a linear geometry to one O(3) and one O(6) atom. The H(9)-O(3) bond length is 1.02 Å. The H(9)-O(6) bond length is 1.48 Å. In the second H site, H(10) is bonded in a linear geometry to one O(1) and one O(4) atom. The H(10)-O(1) bond length is 1.02 Å. The H(10)-O(4) bond length is 1.51 Å. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(10) atom. In the second O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(6) is bonded in a bent 150 degrees geometry to one P(2) and one H(9) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one H(10) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(9) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(2) atom.