Zn(WO2)4 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. The structure consists of one 7440-66-6 atom inside a WO2 framework. In the WO2 framework, there are four inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the second W site, W(2) is bonded to one O(4), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the third W site, W(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the fourth W site, W(4) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(7) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(3) and two equivalent W(4) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1) and two equivalent W(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one W(4) and two equivalent W(2) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one W(2) and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one W(4) and two equivalent W(1) atoms. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(3) and two equivalent W(2) atoms. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one W(1) and two equivalent W(4) atoms. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one W(2) and two equivalent W(3) atoms.
Zn(WO2)4 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. The structure consists of one 7440-66-6 atom inside a WO2 framework. In the WO2 framework, there are four inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. The W(1)-O(2) bond length is 2.06 Å. The W(1)-O(7) bond length is 2.07 Å. There is one shorter (2.06 Å) and one longer (2.18 Å) W(1)-O(4) bond length. There is one shorter (2.10 Å) and one longer (2.14 Å) W(1)-O(5) bond length. In the second W site, W(2) is bonded to one O(4), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. The W(2)-O(4) bond length is 2.06 Å. The W(2)-O(8) bond length is 2.08 Å. There is one shorter (2.07 Å) and one longer (2.17 Å) W(2)-O(3) bond length. There is one shorter (2.10 Å) and one longer (2.15 Å) W(2)-O(6) bond length. In the third W site, W(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. The W(3)-O(1) bond length is 2.06 Å. The W(3)-O(6) bond length is 2.07 Å. There is one shorter (2.06 Å) and one longer (2.18 Å) W(3)-O(2) bond length. There is one shorter (2.10 Å) and one longer (2.15 Å) W(3)-O(8) bond length. In the fourth W site, W(4) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(7) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. The W(4)-O(3) bond length is 2.06 Å. The W(4)-O(5) bond length is 2.08 Å. There is one shorter (2.06 Å) and one longer (2.17 Å) W(4)-O(1) bond length. There is one shorter (2.10 Å) and one longer (2.14 Å) W(4)-O(7) bond length. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(3) and two equivalent W(4) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1) and two equivalent W(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one W(4) and two equivalent W(2) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one W(2) and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one W(4) and two equivalent W(1) atoms. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(3) and two equivalent W(2) atoms. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one W(1) and two equivalent W(4) atoms. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one W(2) and two equivalent W(3) atoms.