ZnGaNO is Stannite-like structured and crystallizes in the orthorhombic Pmc2_1 space group. Zn(1) is bonded to two equivalent N(1) and two equivalent O(1) atoms to form ZnN2O2 tetrahedra that share corners with four equivalent Zn(1)N2O2 tetrahedra and corners with eight equivalent Ga(1)N2O2 tetrahedra. Ga(1) is bonded to two equivalent N(1) and two equivalent O(1) atoms to form GaN2O2 tetrahedra that share corners with four equivalent Ga(1)N2O2 tetrahedra and corners with eight equivalent Zn(1)N2O2 tetrahedra. N(1) is bonded to two equivalent Zn(1) and two equivalent Ga(1) atoms to form NZn2Ga2 tetrahedra that share corners with four equivalent N(1)Zn2Ga2 tetrahedra and corners with eight equivalent O(1)Zn2Ga2 tetrahedra. O(1) is bonded to two equivalent Zn(1) and two equivalent Ga(1) atoms to form OZn2Ga2 tetrahedra that share corners with four equivalent O(1)Zn2Ga2 tetrahedra and corners with eight equivalent N(1)Zn2Ga2 tetrahedra.
ZnGaNO is Stannite-like structured and crystallizes in the orthorhombic Pmc2_1 space group. Zn(1) is bonded to two equivalent N(1) and two equivalent O(1) atoms to form ZnN2O2 tetrahedra that share corners with four equivalent Zn(1)N2O2 tetrahedra and corners with eight equivalent Ga(1)N2O2 tetrahedra. Both Zn(1)-N(1) bond lengths are 1.98 Å. There is one shorter (2.08 Å) and one longer (2.12 Å) Zn(1)-O(1) bond length. Ga(1) is bonded to two equivalent N(1) and two equivalent O(1) atoms to form GaN2O2 tetrahedra that share corners with four equivalent Ga(1)N2O2 tetrahedra and corners with eight equivalent Zn(1)N2O2 tetrahedra. Both Ga(1)-N(1) bond lengths are 1.91 Å. Both Ga(1)-O(1) bond lengths are 1.99 Å. N(1) is bonded to two equivalent Zn(1) and two equivalent Ga(1) atoms to form NZn2Ga2 tetrahedra that share corners with four equivalent N(1)Zn2Ga2 tetrahedra and corners with eight equivalent O(1)Zn2Ga2 tetrahedra. O(1) is bonded to two equivalent Zn(1) and two equivalent Ga(1) atoms to form OZn2Ga2 tetrahedra that share corners with four equivalent O(1)Zn2Ga2 tetrahedra and corners with eight equivalent N(1)Zn2Ga2 tetrahedra.