Li4Co2Ni3Sn(PO4)6 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(14), one O(20), one O(3), one O(4), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(11), one O(15), one O(17), one O(21), and one O(5) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(15), one O(19), one O(22), and one O(23) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), and one O(24) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(14), one O(18), one O(22), one O(3), and one O(7) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one Ni(1)O6 octahedra, and  a faceface with one Sn(1)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(15), one O(17), one O(19), one O(6), and one O(8) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one Ni(2)O6 octahedra, and  a faceface with one Ni(3)O6 octahedra. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(12), one O(14), one O(20), one O(3), one O(7), and one O(9) atom to form distorted NiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(1)O6 octahedra. In the second Ni site, Ni(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(6), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(2)O6 octahedra. In the third Ni site, Ni(3) is bonded to one O(15), one O(17), one O(19), one O(21), one O(23), and one O(24) atom to form distorted NiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(2)O6 octahedra. Sn(1) is bonded to one O(11), one O(13), one O(16), one O(18), one O(22), and one O(5) atom to form distorted SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(1)O6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(15), one O(2), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-52°. In the second P site, P(2) is bonded to one O(12), one O(17), one O(18), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-50°. In the third P site, P(3) is bonded to one O(1), one O(19), one O(20), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-52°. In the fourth P site, P(4) is bonded to one O(24), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-51°. In the fifth P site, P(5) is bonded to one O(13), one O(21), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-50°. In the sixth P site, P(6) is bonded to one O(10), one O(14), one O(16), and one O(23) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-52°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ni(2) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ni(2) and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Ni(1), and one P(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Ni(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Li(2), one Sn(1), and one P(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Co(2), one Ni(2), and one P(4) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Co(1), one Ni(1), and one P(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(1), one Co(2), one Ni(2), and one P(5) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(2), one Ni(2), and one P(6) atom. In the eleventh O site, O(11) is bonded to one Li(2), one Co(1), one Sn(1), and one P(1) atom to form distorted OLiCoSnP trigonal pyramids that share  a cornercorner with one O(14)LiCoNiP trigonal pyramid,  an edgeedge with one O(15)Li2CoNiP square pyramid,  an edgeedge with one O(18)LiCoSnP trigonal pyramid, and  an edgeedge with one O(22)LiCoSnP trigonal pyramid. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(5) atom. In the fourteenth O site, O(14) is bonded to one Li(1), one Co(1), one Ni(1), and one P(6) atom to form distorted corner-sharing OLiCoNiP trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Li(2), one Li(3), one Co(2), one Ni(3), and one P(1) atom to form a mixture of distorted corner and edge-sharing OLi2CoNiP square pyramids. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(6) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one Li(2), one Li(4), one Co(2), one Ni(3), and one P(2) atom. In the eighteenth O site, O(18) is bonded to one Li(4), one Co(1), one Sn(1), and one P(2) atom to form distorted OLiCoSnP trigonal pyramids that share  a cornercorner with one O(14)LiCoNiP trigonal pyramid,  an edgeedge with one O(11)LiCoSnP trigonal pyramid, and  an edgeedge with one O(22)LiCoSnP trigonal pyramid. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Li(3), one Li(4), one Co(2), one Ni(3), and one P(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Li(1), one Ni(1), and one P(3) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(2), one Ni(3), and one P(5) atom. In the twenty-second O site, O(22) is bonded to one Li(3), one Co(1), one Sn(1), and one P(3) atom to form distorted OLiCoSnP trigonal pyramids that share  a cornercorner with one O(15)Li2CoNiP square pyramid,  a cornercorner with one O(14)LiCoNiP trigonal pyramid,  an edgeedge with one O(11)LiCoSnP trigonal pyramid, and  an edgeedge with one O(18)LiCoSnP trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(3), one Ni(3), and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(4), one Ni(3), and one P(4) atom.
Li4Co2Ni3Sn(PO4)6 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(14), one O(20), one O(3), one O(4), and one O(8) atom. The Li(1)-O(10) bond length is 2.07 Å. The Li(1)-O(14) bond length is 2.07 Å. The Li(1)-O(20) bond length is 2.13 Å. The Li(1)-O(3) bond length is 2.52 Å. The Li(1)-O(4) bond length is 2.10 Å. The Li(1)-O(8) bond length is 2.46 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(11), one O(15), one O(17), one O(21), and one O(5) atom. The Li(2)-O(11) bond length is 2.21 Å. The Li(2)-O(15) bond length is 2.04 Å. The Li(2)-O(17) bond length is 2.32 Å. The Li(2)-O(21) bond length is 1.99 Å. The Li(2)-O(5) bond length is 2.62 Å. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(15), one O(19), one O(22), and one O(23) atom. The Li(3)-O(15) bond length is 2.32 Å. The Li(3)-O(19) bond length is 2.03 Å. The Li(3)-O(22) bond length is 2.26 Å. The Li(3)-O(23) bond length is 2.00 Å. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), and one O(24) atom. The Li(4)-O(17) bond length is 2.06 Å. The Li(4)-O(18) bond length is 2.22 Å. The Li(4)-O(19) bond length is 2.34 Å. The Li(4)-O(24) bond length is 1.98 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(14), one O(18), one O(22), one O(3), and one O(7) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one Ni(1)O6 octahedra, and  a faceface with one Sn(1)O6 octahedra. The Co(1)-O(11) bond length is 2.23 Å. The Co(1)-O(14) bond length is 2.14 Å. The Co(1)-O(18) bond length is 2.28 Å. The Co(1)-O(22) bond length is 2.27 Å. The Co(1)-O(3) bond length is 2.11 Å. The Co(1)-O(7) bond length is 2.02 Å. In the second Co site, Co(2) is bonded to one O(10), one O(15), one O(17), one O(19), one O(6), and one O(8) atom to form distorted CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a faceface with one Ni(2)O6 octahedra, and  a faceface with one Ni(3)O6 octahedra. The Co(2)-O(10) bond length is 2.18 Å. The Co(2)-O(15) bond length is 2.21 Å. The Co(2)-O(17) bond length is 2.23 Å. The Co(2)-O(19) bond length is 2.23 Å. The Co(2)-O(6) bond length is 2.05 Å. The Co(2)-O(8) bond length is 2.15 Å. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(12), one O(14), one O(20), one O(3), one O(7), and one O(9) atom to form distorted NiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(1)O6 octahedra. The Ni(1)-O(12) bond length is 1.99 Å. The Ni(1)-O(14) bond length is 2.08 Å. The Ni(1)-O(20) bond length is 2.09 Å. The Ni(1)-O(3) bond length is 2.11 Å. The Ni(1)-O(7) bond length is 2.11 Å. The Ni(1)-O(9) bond length is 1.99 Å. In the second Ni site, Ni(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(6), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(2)O6 octahedra. The Ni(2)-O(1) bond length is 2.00 Å. The Ni(2)-O(10) bond length is 2.08 Å. The Ni(2)-O(2) bond length is 2.00 Å. The Ni(2)-O(4) bond length is 2.10 Å. The Ni(2)-O(6) bond length is 2.10 Å. The Ni(2)-O(8) bond length is 2.10 Å. In the third Ni site, Ni(3) is bonded to one O(15), one O(17), one O(19), one O(21), one O(23), and one O(24) atom to form distorted NiO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(2)O6 octahedra. The Ni(3)-O(15) bond length is 2.11 Å. The Ni(3)-O(17) bond length is 2.13 Å. The Ni(3)-O(19) bond length is 2.14 Å. The Ni(3)-O(21) bond length is 2.02 Å. The Ni(3)-O(23) bond length is 2.00 Å. The Ni(3)-O(24) bond length is 2.01 Å. Sn(1) is bonded to one O(11), one O(13), one O(16), one O(18), one O(22), and one O(5) atom to form distorted SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a faceface with one Co(1)O6 octahedra. The Sn(1)-O(11) bond length is 2.11 Å. The Sn(1)-O(13) bond length is 2.01 Å. The Sn(1)-O(16) bond length is 2.01 Å. The Sn(1)-O(18) bond length is 2.13 Å. The Sn(1)-O(22) bond length is 2.13 Å. The Sn(1)-O(5) bond length is 2.02 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(15), one O(2), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-52°. The P(1)-O(11) bond length is 1.63 Å. The P(1)-O(15) bond length is 1.59 Å. The P(1)-O(2) bond length is 1.50 Å. The P(1)-O(9) bond length is 1.50 Å. In the second P site, P(2) is bonded to one O(12), one O(17), one O(18), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-50°. The P(2)-O(12) bond length is 1.50 Å. The P(2)-O(17) bond length is 1.59 Å. The P(2)-O(18) bond length is 1.63 Å. The P(2)-O(4) bond length is 1.52 Å. In the third P site, P(3) is bonded to one O(1), one O(19), one O(20), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-52°. The P(3)-O(1) bond length is 1.50 Å. The P(3)-O(19) bond length is 1.58 Å. The P(3)-O(20) bond length is 1.52 Å. The P(3)-O(22) bond length is 1.63 Å. In the fourth P site, P(4) is bonded to one O(24), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-51°. The P(4)-O(24) bond length is 1.53 Å. The P(4)-O(3) bond length is 1.55 Å. The P(4)-O(5) bond length is 1.58 Å. The P(4)-O(6) bond length is 1.54 Å. In the fifth P site, P(5) is bonded to one O(13), one O(21), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-50°. The P(5)-O(13) bond length is 1.57 Å. The P(5)-O(21) bond length is 1.53 Å. The P(5)-O(7) bond length is 1.54 Å. The P(5)-O(8) bond length is 1.55 Å. In the sixth P site, P(6) is bonded to one O(10), one O(14), one O(16), and one O(23) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, and  a cornercorner with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-52°. The P(6)-O(10) bond length is 1.55 Å. The P(6)-O(14) bond length is 1.55 Å. The P(6)-O(16) bond length is 1.56 Å. The P(6)-O(23) bond length is 1.52 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ni(2) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ni(2) and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(1), one Co(1), one Ni(1), and one P(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Ni(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Li(2), one Sn(1), and one P(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Co(2), one Ni(2), and one P(4) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Co(1), one Ni(1), and one P(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(1), one Co(2), one Ni(2), and one P(5) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(2), one Ni(2), and one P(6) atom. In the eleventh O site, O(11) is bonded to one Li(2), one Co(1), one Sn(1), and one P(1) atom to form distorted OLiCoSnP trigonal pyramids that share  a cornercorner with one O(14)LiCoNiP trigonal pyramid,  an edgeedge with one O(15)Li2CoNiP square pyramid,  an edgeedge with one O(18)LiCoSnP trigonal pyramid, and  an edgeedge with one O(22)LiCoSnP trigonal pyramid. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(5) atom. In the fourteenth O site, O(14) is bonded to one Li(1), one Co(1), one Ni(1), and one P(6) atom to form distorted corner-sharing OLiCoNiP trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Li(2), one Li(3), one Co(2), one Ni(3), and one P(1) atom to form a mixture of distorted corner and edge-sharing OLi2CoNiP square pyramids. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(6) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one Li(2), one Li(4), one Co(2), one Ni(3), and one P(2) atom. In the eighteenth O site, O(18) is bonded to one Li(4), one Co(1), one Sn(1), and one P(2) atom to form distorted OLiCoSnP trigonal pyramids that share  a cornercorner with one O(14)LiCoNiP trigonal pyramid,  an edgeedge with one O(11)LiCoSnP trigonal pyramid, and  an edgeedge with one O(22)LiCoSnP trigonal pyramid. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Li(3), one Li(4), one Co(2), one Ni(3), and one P(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Li(1), one Ni(1), and one P(3) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Li(2), one Ni(3), and one P(5) atom. In the twenty-second O site, O(22) is bonded to one Li(3), one Co(1), one Sn(1), and one P(3) atom to form distorted OLiCoSnP trigonal pyramids that share  a cornercorner with one O(15)Li2CoNiP square pyramid,  a cornercorner with one O(14)LiCoNiP trigonal pyramid,  an edgeedge with one O(11)LiCoSnP trigonal pyramid, and  an edgeedge with one O(18)LiCoSnP trigonal pyramid. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(3), one Ni(3), and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(4), one Ni(3), and one P(4) atom.