Sm2OCl2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Sm2OCl2 cluster. Sm(1) is bonded in a linear geometry to one O(1) and one Cl(1) atom. O(1) is bonded in a linear geometry to two equivalent Sm(1) atoms. Cl(1) is bonded in a single-bond geometry to one Sm(1) atom.
Sm2OCl2 crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Sm2OCl2 cluster. Sm(1) is bonded in a linear geometry to one O(1) and one Cl(1) atom. The Sm(1)-O(1) bond length is 2.13 Å. The Sm(1)-Cl(1) bond length is 2.52 Å. O(1) is bonded in a linear geometry to two equivalent Sm(1) atoms. Cl(1) is bonded in a single-bond geometry to one Sm(1) atom.