(Rb)2CsBiF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsBiF6 framework. In the CsBiF6 framework, Cs(1) is bonded to six equivalent F(1) atoms to form CsF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Cs(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Cs(1) and one Bi(1) atom.
(Rb)2CsBiF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsBiF6 framework. In the CsBiF6 framework, Cs(1) is bonded to six equivalent F(1) atoms to form CsF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Cs(1)-F(1) bond lengths are 2.81 Å. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Cs(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-F(1) bond lengths are 2.27 Å. F(1) is bonded in a linear geometry to one Cs(1) and one Bi(1) atom.