CSb(OCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CSb(OCl2)2 clusters. In one of the CSb(OCl2)2 clusters, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. Sb(1) is bonded in an octahedral geometry to one O(2), one O(4), one Cl(1), one Cl(4), one Cl(5), and one Cl(8) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(1) atom. In one of the CSb(OCl2)2 clusters, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. Sb(2) is bonded in an octahedral geometry to one O(1), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom.
CSb(OCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CSb(OCl2)2 clusters. In one of the CSb(OCl2)2 clusters, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. Sb(1) is bonded in an octahedral geometry to one O(2), one O(4), one Cl(1), one Cl(4), one Cl(5), and one Cl(8) atom. The Sb(1)-O(2) bond length is 2.21 Å. The Sb(1)-O(4) bond length is 2.21 Å. The Sb(1)-Cl(1) bond length is 2.33 Å. The Sb(1)-Cl(4) bond length is 2.36 Å. The Sb(1)-Cl(5) bond length is 2.33 Å. The Sb(1)-Cl(8) bond length is 2.36 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(2) and one Sb(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(1) atom. In one of the CSb(OCl2)2 clusters, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. Sb(2) is bonded in an octahedral geometry to one O(1), one O(3), one Cl(2), one Cl(3), one Cl(6), and one Cl(7) atom. The Sb(2)-O(1) bond length is 2.21 Å. The Sb(2)-O(3) bond length is 2.21 Å. The Sb(2)-Cl(2) bond length is 2.34 Å. The Sb(2)-Cl(3) bond length is 2.36 Å. The Sb(2)-Cl(6) bond length is 2.36 Å. The Sb(2)-Cl(7) bond length is 2.33 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one C(1) and one Sb(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(2) atom.