(CoSiN2ClF6)2(N2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two triazane molecules and two CoSiN2ClF6 clusters. In each CoSiN2ClF6 cluster, Co(1) is bonded in a 3-coordinate geometry to two equivalent N(3), one Cl(1), and two equivalent F(3) atoms. Si(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. N(3) is bonded in a distorted L-shaped geometry to one Co(1) and one N(3) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Co(1) and one Si(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Si(1) atom.
(CoSiN2ClF6)2(N2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two triazane molecules and two CoSiN2ClF6 clusters. In each CoSiN2ClF6 cluster, Co(1) is bonded in a 3-coordinate geometry to two equivalent N(3), one Cl(1), and two equivalent F(3) atoms. Both Co(1)-N(3) bond lengths are 2.63 Å. The Co(1)-Cl(1) bond length is 2.14 Å. Both Co(1)-F(3) bond lengths are 1.91 Å. Si(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. The Si(1)-F(1) bond length is 1.65 Å. The Si(1)-F(2) bond length is 1.66 Å. Both Si(1)-F(3) bond lengths are 1.91 Å. Both Si(1)-F(4) bond lengths are 1.67 Å. N(3) is bonded in a distorted L-shaped geometry to one Co(1) and one N(3) atom. The N(3)-N(3) bond length is 1.12 Å. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Co(1) and one Si(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Si(1) atom.