SrLaTiMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(1), one O(12), one O(17), one O(20), one O(21), one O(24), one O(4), one O(9), two equivalent O(13), and two equivalent O(8) atoms. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(17), one O(18), one O(2), one O(21), one O(22), one O(9), two equivalent O(14), and two equivalent O(5) atoms. In the third Sr site, Sr(3) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(18), one O(19), one O(2), one O(22), one O(23), one O(3), two equivalent O(15), and two equivalent O(6) atoms. In the fourth Sr site, Sr(4) is bonded in a 12-coordinate geometry to one O(11), one O(12), one O(19), one O(20), one O(23), one O(24), one O(3), one O(4), two equivalent O(16), and two equivalent O(7) atoms. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 3-coordinate geometry to one O(14), one O(18), one O(21), and two equivalent O(5) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(18), one O(19), one O(2), one O(22), one O(23), one O(3), two equivalent O(15), and two equivalent O(6) atoms. In the third La site, La(3) is bonded in a 12-coordinate geometry to one O(11), one O(12), one O(19), one O(20), one O(23), one O(24), one O(3), one O(4), two equivalent O(16), and two equivalent O(7) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(17), one O(24), one O(4), one O(9), and two equivalent O(8) atoms. There are four inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(10), one O(15), one O(18), one O(2), one O(22), and one O(5) atom to form TiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-24°. In the second Ti site, Ti(2) is bonded to one O(11), one O(16), one O(19), one O(23), one O(3), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with four equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-24°. In the third Ti site, Ti(3) is bonded to one O(12), one O(13), one O(20), one O(24), one O(4), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and corners with four equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. In the fourth Ti site, Ti(4) is bonded to one O(1), one O(14), one O(17), one O(21), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-25°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(13), one O(17), one O(21), one O(5), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, and corners with four equivalent Ti(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-25°. In the second Mn site, Mn(2) is bonded to one O(10), one O(14), one O(18), one O(2), one O(22), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, and corners with four equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. In the third Mn site, Mn(3) is bonded to one O(11), one O(15), one O(19), one O(23), one O(3), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, and corners with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-24°. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(16), one O(20), one O(24), one O(4), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, and corners with four equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-24°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one La(4), one Ti(4), and one Mn(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(2), one Ti(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(4), one La(3), one La(4), one Ti(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to two equivalent Sr(2), two equivalent La(1), one Ti(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(2), one Ti(2), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(3), one Ti(3), and one Mn(3) atom. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(4), one Ti(4), and one Mn(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), one La(4), one Ti(4), and one Mn(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(2), one Ti(1), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(4), one La(3), one La(4), one Ti(3), and one Mn(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(4), one Ti(3), and one Mn(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to two equivalent Sr(2), one La(1), one Ti(4), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to two equivalent Sr(3), two equivalent La(2), one Ti(1), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to two equivalent Sr(4), two equivalent La(3), one Ti(2), and one Mn(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), one La(4), one Ti(4), and one Mn(1) atom. In the eighteenth O site, O(18) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(1), one La(2), one Ti(1), and one Mn(2) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(4), one La(3), one Ti(3), and one Mn(4) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), one La(1), one Ti(4), and one Mn(1) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(2), one Ti(1), and one Mn(2) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(4), one La(3), one La(4), one Ti(3), and one Mn(4) atom.
SrLaTiMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(1), one O(12), one O(17), one O(20), one O(21), one O(24), one O(4), one O(9), two equivalent O(13), and two equivalent O(8) atoms. The Sr(1)-O(1) bond length is 2.53 Å. The Sr(1)-O(12) bond length is 2.54 Å. The Sr(1)-O(17) bond length is 2.86 Å. The Sr(1)-O(20) bond length is 2.90 Å. The Sr(1)-O(21) bond length is 2.84 Å. The Sr(1)-O(24) bond length is 2.76 Å. The Sr(1)-O(4) bond length is 3.12 Å. The Sr(1)-O(9) bond length is 3.18 Å. There is one shorter (2.75 Å) and one longer (2.80 Å) Sr(1)-O(13) bond length. There is one shorter (2.52 Å) and one longer (3.01 Å) Sr(1)-O(8) bond length. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(17), one O(18), one O(2), one O(21), one O(22), one O(9), two equivalent O(14), and two equivalent O(5) atoms. The Sr(2)-O(1) bond length is 3.20 Å. The Sr(2)-O(10) bond length is 3.08 Å. The Sr(2)-O(17) bond length is 2.84 Å. The Sr(2)-O(18) bond length is 2.77 Å. The Sr(2)-O(2) bond length is 2.56 Å. The Sr(2)-O(21) bond length is 2.82 Å. The Sr(2)-O(22) bond length is 2.95 Å. The Sr(2)-O(9) bond length is 2.52 Å. There is one shorter (2.69 Å) and one longer (2.86 Å) Sr(2)-O(14) bond length. There is one shorter (2.50 Å) and one longer (3.03 Å) Sr(2)-O(5) bond length. In the third Sr site, Sr(3) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(18), one O(19), one O(2), one O(22), one O(23), one O(3), two equivalent O(15), and two equivalent O(6) atoms. The Sr(3)-O(10) bond length is 2.56 Å. The Sr(3)-O(11) bond length is 3.11 Å. The Sr(3)-O(18) bond length is 2.94 Å. The Sr(3)-O(19) bond length is 2.78 Å. The Sr(3)-O(2) bond length is 3.13 Å. The Sr(3)-O(22) bond length is 2.70 Å. The Sr(3)-O(23) bond length is 2.93 Å. The Sr(3)-O(3) bond length is 2.55 Å. There is one shorter (2.75 Å) and one longer (2.81 Å) Sr(3)-O(15) bond length. There is one shorter (2.49 Å) and one longer (3.04 Å) Sr(3)-O(6) bond length. In the fourth Sr site, Sr(4) is bonded in a 12-coordinate geometry to one O(11), one O(12), one O(19), one O(20), one O(23), one O(24), one O(3), one O(4), two equivalent O(16), and two equivalent O(7) atoms. The Sr(4)-O(11) bond length is 2.54 Å. The Sr(4)-O(12) bond length is 3.10 Å. The Sr(4)-O(19) bond length is 2.93 Å. The Sr(4)-O(20) bond length is 2.79 Å. The Sr(4)-O(23) bond length is 2.72 Å. The Sr(4)-O(24) bond length is 2.90 Å. The Sr(4)-O(3) bond length is 3.16 Å. The Sr(4)-O(4) bond length is 2.55 Å. There is one shorter (2.74 Å) and one longer (2.82 Å) Sr(4)-O(16) bond length. There is one shorter (2.50 Å) and one longer (3.03 Å) Sr(4)-O(7) bond length. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 3-coordinate geometry to one O(14), one O(18), one O(21), and two equivalent O(5) atoms. The La(1)-O(14) bond length is 2.38 Å. The La(1)-O(18) bond length is 2.48 Å. The La(1)-O(21) bond length is 2.45 Å. There is one shorter (2.67 Å) and one longer (2.86 Å) La(1)-O(5) bond length. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(18), one O(19), one O(2), one O(22), one O(23), one O(3), two equivalent O(15), and two equivalent O(6) atoms. The La(2)-O(10) bond length is 2.68 Å. The La(2)-O(11) bond length is 2.99 Å. The La(2)-O(18) bond length is 3.16 Å. The La(2)-O(19) bond length is 2.47 Å. The La(2)-O(2) bond length is 2.89 Å. The La(2)-O(22) bond length is 2.47 Å. The La(2)-O(23) bond length is 3.26 Å. The La(2)-O(3) bond length is 2.73 Å. There is one shorter (2.37 Å) and one longer (3.15 Å) La(2)-O(15) bond length. There is one shorter (2.73 Å) and one longer (2.80 Å) La(2)-O(6) bond length. In the third La site, La(3) is bonded in a 12-coordinate geometry to one O(11), one O(12), one O(19), one O(20), one O(23), one O(24), one O(3), one O(4), two equivalent O(16), and two equivalent O(7) atoms. The La(3)-O(11) bond length is 2.70 Å. The La(3)-O(12) bond length is 2.96 Å. The La(3)-O(19) bond length is 3.18 Å. The La(3)-O(20) bond length is 2.47 Å. The La(3)-O(23) bond length is 2.46 Å. The La(3)-O(24) bond length is 3.22 Å. The La(3)-O(3) bond length is 2.89 Å. The La(3)-O(4) bond length is 2.78 Å. There is one shorter (2.36 Å) and one longer (3.16 Å) La(3)-O(16) bond length. There is one shorter (2.71 Å) and one longer (2.81 Å) La(3)-O(7) bond length. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(17), one O(24), one O(4), one O(9), and two equivalent O(8) atoms. The La(4)-O(1) bond length is 2.90 Å. The La(4)-O(12) bond length is 2.76 Å. The La(4)-O(13) bond length is 2.37 Å. The La(4)-O(17) bond length is 2.44 Å. The La(4)-O(24) bond length is 2.46 Å. The La(4)-O(4) bond length is 2.86 Å. The La(4)-O(9) bond length is 2.84 Å. There is one shorter (2.70 Å) and one longer (2.82 Å) La(4)-O(8) bond length. There are four inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(10), one O(15), one O(18), one O(2), one O(22), and one O(5) atom to form TiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-24°. The Ti(1)-O(10) bond length is 1.96 Å. The Ti(1)-O(15) bond length is 1.98 Å. The Ti(1)-O(18) bond length is 2.01 Å. The Ti(1)-O(2) bond length is 1.95 Å. The Ti(1)-O(22) bond length is 2.02 Å. The Ti(1)-O(5) bond length is 1.93 Å. In the second Ti site, Ti(2) is bonded to one O(11), one O(16), one O(19), one O(23), one O(3), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with four equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-24°. The Ti(2)-O(11) bond length is 1.96 Å. The Ti(2)-O(16) bond length is 1.98 Å. The Ti(2)-O(19) bond length is 2.02 Å. The Ti(2)-O(23) bond length is 2.01 Å. The Ti(2)-O(3) bond length is 1.97 Å. The Ti(2)-O(6) bond length is 1.92 Å. In the third Ti site, Ti(3) is bonded to one O(12), one O(13), one O(20), one O(24), one O(4), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, and corners with four equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. The Ti(3)-O(12) bond length is 1.95 Å. The Ti(3)-O(13) bond length is 1.99 Å. The Ti(3)-O(20) bond length is 2.02 Å. The Ti(3)-O(24) bond length is 1.99 Å. The Ti(3)-O(4) bond length is 1.98 Å. The Ti(3)-O(7) bond length is 1.92 Å. In the fourth Ti site, Ti(4) is bonded to one O(1), one O(14), one O(17), one O(21), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, and corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-25°. The Ti(4)-O(1) bond length is 1.98 Å. The Ti(4)-O(14) bond length is 1.97 Å. The Ti(4)-O(17) bond length is 2.02 Å. The Ti(4)-O(21) bond length is 2.02 Å. The Ti(4)-O(8) bond length is 1.92 Å. The Ti(4)-O(9) bond length is 1.97 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(13), one O(17), one O(21), one O(5), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, and corners with four equivalent Ti(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-25°. The Mn(1)-O(1) bond length is 1.95 Å. The Mn(1)-O(13) bond length is 2.21 Å. The Mn(1)-O(17) bond length is 1.96 Å. The Mn(1)-O(21) bond length is 1.97 Å. The Mn(1)-O(5) bond length is 2.21 Å. The Mn(1)-O(9) bond length is 1.98 Å. In the second Mn site, Mn(2) is bonded to one O(10), one O(14), one O(18), one O(2), one O(22), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, and corners with four equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. The Mn(2)-O(10) bond length is 1.97 Å. The Mn(2)-O(14) bond length is 2.22 Å. The Mn(2)-O(18) bond length is 1.94 Å. The Mn(2)-O(2) bond length is 1.95 Å. The Mn(2)-O(22) bond length is 1.96 Å. The Mn(2)-O(6) bond length is 2.21 Å. In the third Mn site, Mn(3) is bonded to one O(11), one O(15), one O(19), one O(23), one O(3), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, and corners with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-24°. The Mn(3)-O(11) bond length is 1.96 Å. The Mn(3)-O(15) bond length is 2.22 Å. The Mn(3)-O(19) bond length is 1.95 Å. The Mn(3)-O(23) bond length is 1.96 Å. The Mn(3)-O(3) bond length is 1.95 Å. The Mn(3)-O(7) bond length is 2.21 Å. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(16), one O(20), one O(24), one O(4), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, and corners with four equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-24°. The Mn(4)-O(12) bond length is 1.96 Å. The Mn(4)-O(16) bond length is 2.22 Å. The Mn(4)-O(20) bond length is 1.95 Å. The Mn(4)-O(24) bond length is 1.96 Å. The Mn(4)-O(4) bond length is 1.95 Å. The Mn(4)-O(8) bond length is 2.21 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one La(4), one Ti(4), and one Mn(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(2), one Ti(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(4), one La(3), one La(4), one Ti(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to two equivalent Sr(2), two equivalent La(1), one Ti(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(3), two equivalent La(2), one Ti(2), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(3), one Ti(3), and one Mn(3) atom. In the eighth O site, O(8) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(4), one Ti(4), and one Mn(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), one La(4), one Ti(4), and one Mn(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(2), one Ti(1), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(4), one La(3), one La(4), one Ti(3), and one Mn(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(4), one Ti(3), and one Mn(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to two equivalent Sr(2), one La(1), one Ti(4), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to two equivalent Sr(3), two equivalent La(2), one Ti(1), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to two equivalent Sr(4), two equivalent La(3), one Ti(2), and one Mn(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), one La(4), one Ti(4), and one Mn(1) atom. In the eighteenth O site, O(18) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(1), one La(2), one Ti(1), and one Mn(2) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(4), one La(3), one Ti(3), and one Mn(4) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), one La(1), one Ti(4), and one Mn(1) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one La(2), one Ti(1), and one Mn(2) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one La(2), one La(3), one Ti(2), and one Mn(3) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(4), one La(3), one La(4), one Ti(3), and one Mn(4) atom.