C3SbPOCl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four C3SbPOCl5 clusters. There are three inequivalent C sites. In the first C site, C(2) is bonded in a 2-coordinate geometry to one C(5) and one P(1) atom. In the second C site, C(5) is bonded in a 3-coordinate geometry to one C(11), one C(2), and one P(1) atom. In the third C site, C(11) is bonded in a 3-coordinate geometry to one C(5), one P(1), and one Cl(1) atom. Sb(1) is bonded in a distorted square pyramidal geometry to one O(1), one Cl(13), one Cl(19), one Cl(5), and one Cl(9) atom. P(1) is bonded in a distorted single-bond geometry to one C(11), one C(2), one C(5), and one O(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(19) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one C(11) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom.
C3SbPOCl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four C3SbPOCl5 clusters. There are three inequivalent C sites. In the first C site, C(2) is bonded in a 2-coordinate geometry to one C(5) and one P(1) atom. The C(2)-C(5) bond length is 1.33 Å. The C(2)-P(1) bond length is 2.00 Å. In the second C site, C(5) is bonded in a 3-coordinate geometry to one C(11), one C(2), and one P(1) atom. The C(5)-C(11) bond length is 1.36 Å. The C(5)-P(1) bond length is 2.02 Å. In the third C site, C(11) is bonded in a 3-coordinate geometry to one C(5), one P(1), and one Cl(1) atom. The C(11)-P(1) bond length is 1.90 Å. The C(11)-Cl(1) bond length is 1.67 Å. Sb(1) is bonded in a distorted square pyramidal geometry to one O(1), one Cl(13), one Cl(19), one Cl(5), and one Cl(9) atom. The Sb(1)-O(1) bond length is 2.09 Å. The Sb(1)-Cl(13) bond length is 2.40 Å. The Sb(1)-Cl(19) bond length is 2.41 Å. The Sb(1)-Cl(5) bond length is 2.32 Å. The Sb(1)-Cl(9) bond length is 2.40 Å. P(1) is bonded in a distorted single-bond geometry to one C(11), one C(2), one C(5), and one O(1) atom. The P(1)-O(1) bond length is 1.60 Å. O(1) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(19) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one C(11) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom.