NaSbO6 crystallizes in the tetragonal P4_2/nnm space group. Na(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one O(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom.
NaSbO6 crystallizes in the tetragonal P4_2/nnm space group. Na(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Both Na(1)-O(2) bond lengths are 2.22 Å. All Na(1)-O(1) bond lengths are 2.38 Å. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Both Sb(1)-O(2) bond lengths are 1.81 Å. All Sb(1)-O(1) bond lengths are 2.37 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one O(1) atom. The O(1)-O(1) bond length is 1.33 Å. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom.