(K)2TlAlBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlAlBr6 framework. In the TlAlBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Al(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Al(1) is bonded to six equivalent Br(1) atoms to form AlBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Tl(1) and one Al(1) atom.
(K)2TlAlBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlAlBr6 framework. In the TlAlBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Al(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 3.15 Å. Al(1) is bonded to six equivalent Br(1) atoms to form AlBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-Br(1) bond lengths are 2.53 Å. Br(1) is bonded in a linear geometry to one Tl(1) and one Al(1) atom.