NaScF6N2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonia atoms inside a NaScF6 framework. In the NaScF6 framework, Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Sc(1)F6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent F(1) atoms to form ScF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Na(1) and one Sc(1) atom.
NaScF6N2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonia atoms inside a NaScF6 framework. In the NaScF6 framework, Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Sc(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-F(1) bond lengths are 2.27 Å. Sc(1) is bonded to six equivalent F(1) atoms to form ScF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-F(1) bond lengths are 2.03 Å. F(1) is bonded in a linear geometry to one Na(1) and one Sc(1) atom.