Li2CrCSO7 crystallizes in the monoclinic P2_1/m space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. Cr(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), and two equivalent O(6) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. S(1) is bonded in a tetrahedral geometry to one O(4), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(1), one Cr(1), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Li(1), one Cr(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Li(1), one Cr(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cr(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Cr(1), and one S(1) atom.
Li2CrCSO7 crystallizes in the monoclinic P2_1/m space group. Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. The Li(1)-O(1) bond length is 2.00 Å. The Li(1)-O(2) bond length is 2.09 Å. The Li(1)-O(3) bond length is 2.07 Å. The Li(1)-O(4) bond length is 2.58 Å. The Li(1)-O(6) bond length is 2.55 Å. Cr(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), and two equivalent O(6) atoms. The Cr(1)-O(2) bond length is 2.10 Å. The Cr(1)-O(3) bond length is 2.50 Å. The Cr(1)-O(4) bond length is 2.40 Å. The Cr(1)-O(5) bond length is 2.10 Å. Both Cr(1)-O(6) bond lengths are 2.06 Å. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.33 Å. The C(1)-O(3) bond length is 1.30 Å. S(1) is bonded in a tetrahedral geometry to one O(4), one O(5), and two equivalent O(6) atoms. The S(1)-O(4) bond length is 1.49 Å. The S(1)-O(5) bond length is 1.50 Å. Both S(1)-O(6) bond lengths are 1.49 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Li(1), one Cr(1), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Li(1), one Cr(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Li(1), one Cr(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cr(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Cr(1), and one S(1) atom.