PrPd2P2 crystallizes in the tetragonal I4/mmm space group. Pr(1) is bonded in a 16-coordinate geometry to eight equivalent Pd(1) and eight equivalent P(1) atoms. Pd(1) is bonded to four equivalent Pr(1) and four equivalent P(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdPr4P4 cuboctahedra. P(1) is bonded in a 9-coordinate geometry to four equivalent Pr(1), four equivalent Pd(1), and one P(1) atom.
PrPd2P2 crystallizes in the tetragonal I4/mmm space group. Pr(1) is bonded in a 16-coordinate geometry to eight equivalent Pd(1) and eight equivalent P(1) atoms. All Pr(1)-Pd(1) bond lengths are 3.24 Å. All Pr(1)-P(1) bond lengths are 3.16 Å. Pd(1) is bonded to four equivalent Pr(1) and four equivalent P(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdPr4P4 cuboctahedra. All Pd(1)-P(1) bond lengths are 2.49 Å. P(1) is bonded in a 9-coordinate geometry to four equivalent Pr(1), four equivalent Pd(1), and one P(1) atom. The P(1)-P(1) bond length is 2.24 Å.