Li2U(MoO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(5) atoms. U(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(4) atoms. Mo(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Li(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Li(1) and one U(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one U(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one Mo(1) atom.
Li2U(MoO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(5) atoms. The Li(1)-O(2) bond length is 2.64 Å. The Li(1)-O(3) bond length is 2.61 Å. There is one shorter (2.13 Å) and one longer (2.49 Å) Li(1)-O(1) bond length. There is one shorter (2.21 Å) and one longer (2.44 Å) Li(1)-O(5) bond length. U(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(4) atoms. Both U(1)-O(3) bond lengths are 1.76 Å. Both U(1)-O(4) bond lengths are 2.19 Å. Mo(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. The Mo(1)-O(1) bond length is 1.27 Å. The Mo(1)-O(2) bond length is 2.41 Å. The Mo(1)-O(4) bond length is 1.79 Å. The Mo(1)-O(5) bond length is 2.48 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Li(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Li(1) and one U(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one U(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one Mo(1) atom.