WH3 crystallizes in the monoclinic P2_1/m space group. W(1) is bonded in a 8-coordinate geometry to two equivalent H(2), three equivalent H(1), and three equivalent H(3) atoms. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted trigonal planar geometry to three equivalent W(1) atoms. In the second H site, H(2) is bonded in a bent 120 degrees geometry to two equivalent W(1) atoms. In the third H site, H(3) is bonded in a trigonal non-coplanar geometry to three equivalent W(1) atoms.
WH3 crystallizes in the monoclinic P2_1/m space group. W(1) is bonded in a 8-coordinate geometry to two equivalent H(2), three equivalent H(1), and three equivalent H(3) atoms. There is one shorter (1.81 Å) and one longer (1.87 Å) W(1)-H(2) bond length. There are two shorter (1.93 Å) and one longer (2.11 Å) W(1)-H(1) bond length. There is one shorter (1.85 Å) and two longer (1.92 Å) W(1)-H(3) bond lengths. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted trigonal planar geometry to three equivalent W(1) atoms. In the second H site, H(2) is bonded in a bent 120 degrees geometry to two equivalent W(1) atoms. In the third H site, H(3) is bonded in a trigonal non-coplanar geometry to three equivalent W(1) atoms.