Li3Cr(CoO3)2 is beta Polonium-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(9), two equivalent O(5), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the second Li site, Li(2) is bonded to one O(10), one O(11), two equivalent O(6), and two equivalent O(8) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the third Li site, Li(3) is bonded to one O(3), one O(6), two equivalent O(11), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(12) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the fifth Li site, Li(5) is bonded to one O(2), one O(7), two equivalent O(3), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the sixth Li site, Li(6) is bonded to one O(1), one O(8), two equivalent O(10), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(7) atoms to form CrO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the second Cr site, Cr(2) is bonded to one O(2), one O(4), two equivalent O(6), and two equivalent O(8) atoms to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(8), one O(9), two equivalent O(11), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the second Co site, Co(2) is bonded to one O(10), one O(7), two equivalent O(1), and two equivalent O(12) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the third Co site, Co(3) is bonded to one O(12), one O(6), two equivalent O(10), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with four equivalent Li(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the fourth Co site, Co(4) is bonded to one O(11), one O(5), two equivalent O(3), and two equivalent O(9) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with four equivalent Li(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(6), two equivalent Li(4), one Cr(1), and two equivalent Co(2) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(8)Li3Cr2Co octahedra,  a cornercorner with one O(3)Li3CrCo2 octahedra, corners with four equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to one Li(5), two equivalent Li(3), one Cr(2), and two equivalent Co(1) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(7)Li3Cr2Co octahedra,  a cornercorner with one O(4)Li3CrCo2 octahedra, corners with four equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third O site, O(3) is bonded to one Li(3), two equivalent Li(5), one Cr(1), and two equivalent Co(4) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(6)Li3Cr2Co octahedra,  a cornercorner with one O(1)Li3CrCo2 octahedra, corners with four equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth O site, O(4) is bonded to one Li(4), two equivalent Li(6), one Cr(2), and two equivalent Co(3) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(5)Li3Cr2Co octahedra,  a cornercorner with one O(2)Li3CrCo2 octahedra, corners with four equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth O site, O(5) is bonded to one Li(4), two equivalent Li(1), two equivalent Cr(1), and one Co(4) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(11)Li3Co3 octahedra,  a cornercorner with one O(4)Li3CrCo2 octahedra, corners with four equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth O site, O(6) is bonded to one Li(3), two equivalent Li(2), two equivalent Cr(2), and one Co(3) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(12)Li3Co3 octahedra,  a cornercorner with one O(3)Li3CrCo2 octahedra, corners with four equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh O site, O(7) is bonded to one Li(5), two equivalent Li(1), two equivalent Cr(1), and one Co(2) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(10)Li3Co3 octahedra,  a cornercorner with one O(2)Li3CrCo2 octahedra, corners with four equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the eighth O site, O(8) is bonded to one Li(6), two equivalent Li(2), two equivalent Cr(2), and one Co(1) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(9)Li3Co3 octahedra,  a cornercorner with one O(1)Li3CrCo2 octahedra, corners with four equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the ninth O site, O(9) is bonded to one Li(1), two equivalent Li(5), one Co(1), and two equivalent Co(4) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(12)Li3Co3 octahedra,  a cornercorner with one O(8)Li3Cr2Co octahedra, corners with four equivalent O(3)Li3CrCo2 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the tenth O site, O(10) is bonded to one Li(2), two equivalent Li(6), one Co(2), and two equivalent Co(3) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(11)Li3Co3 octahedra,  a cornercorner with one O(7)Li3Cr2Co octahedra, corners with four equivalent O(4)Li3CrCo2 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the eleventh O site, O(11) is bonded to one Li(2), two equivalent Li(3), one Co(4), and two equivalent Co(1) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(10)Li3Co3 octahedra,  a cornercorner with one O(5)Li3Cr2Co octahedra, corners with four equivalent O(2)Li3CrCo2 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the twelfth O site, O(12) is bonded to one Li(1), two equivalent Li(4), one Co(3), and two equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(9)Li3Co3 octahedra,  a cornercorner with one O(6)Li3Cr2Co octahedra, corners with four equivalent O(1)Li3CrCo2 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°.
Li3Cr(CoO3)2 is beta Polonium-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(9), two equivalent O(5), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. The Li(1)-O(12) bond length is 2.11 Å. The Li(1)-O(9) bond length is 2.12 Å. There is one shorter (2.11 Å) and one longer (2.25 Å) Li(1)-O(5) bond length. There is one shorter (2.11 Å) and one longer (2.23 Å) Li(1)-O(7) bond length. In the second Li site, Li(2) is bonded to one O(10), one O(11), two equivalent O(6), and two equivalent O(8) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. The Li(2)-O(10) bond length is 2.15 Å. The Li(2)-O(11) bond length is 2.17 Å. There is one shorter (2.11 Å) and one longer (2.23 Å) Li(2)-O(6) bond length. There is one shorter (2.10 Å) and one longer (2.24 Å) Li(2)-O(8) bond length. In the third Li site, Li(3) is bonded to one O(3), one O(6), two equivalent O(11), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. The Li(3)-O(3) bond length is 2.07 Å. The Li(3)-O(6) bond length is 2.18 Å. There is one shorter (2.10 Å) and one longer (2.22 Å) Li(3)-O(11) bond length. There is one shorter (2.14 Å) and one longer (2.16 Å) Li(3)-O(2) bond length. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(12) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Li(4)-O(4) bond length is 2.05 Å. The Li(4)-O(5) bond length is 2.22 Å. There is one shorter (2.10 Å) and one longer (2.22 Å) Li(4)-O(1) bond length. There is one shorter (2.10 Å) and one longer (2.19 Å) Li(4)-O(12) bond length. In the fifth Li site, Li(5) is bonded to one O(2), one O(7), two equivalent O(3), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. The Li(5)-O(2) bond length is 2.07 Å. The Li(5)-O(7) bond length is 2.23 Å. There is one shorter (2.10 Å) and one longer (2.21 Å) Li(5)-O(3) bond length. There is one shorter (2.13 Å) and one longer (2.19 Å) Li(5)-O(9) bond length. In the sixth Li site, Li(6) is bonded to one O(1), one O(8), two equivalent O(10), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. The Li(6)-O(1) bond length is 2.07 Å. The Li(6)-O(8) bond length is 2.17 Å. There is one shorter (2.08 Å) and one longer (2.23 Å) Li(6)-O(10) bond length. There is one shorter (2.12 Å) and one longer (2.17 Å) Li(6)-O(4) bond length. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(7) atoms to form CrO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. The Cr(1)-O(1) bond length is 2.00 Å. The Cr(1)-O(3) bond length is 2.01 Å. There is one shorter (2.02 Å) and one longer (2.03 Å) Cr(1)-O(5) bond length. There is one shorter (2.02 Å) and one longer (2.04 Å) Cr(1)-O(7) bond length. In the second Cr site, Cr(2) is bonded to one O(2), one O(4), two equivalent O(6), and two equivalent O(8) atoms to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. The Cr(2)-O(2) bond length is 2.01 Å. The Cr(2)-O(4) bond length is 2.01 Å. There is one shorter (2.03 Å) and one longer (2.04 Å) Cr(2)-O(6) bond length. There is one shorter (2.02 Å) and one longer (2.04 Å) Cr(2)-O(8) bond length. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(8), one O(9), two equivalent O(11), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. The Co(1)-O(8) bond length is 2.02 Å. The Co(1)-O(9) bond length is 1.98 Å. There is one shorter (2.00 Å) and one longer (2.09 Å) Co(1)-O(11) bond length. There is one shorter (2.02 Å) and one longer (2.07 Å) Co(1)-O(2) bond length. In the second Co site, Co(2) is bonded to one O(10), one O(7), two equivalent O(1), and two equivalent O(12) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Co(2)-O(10) bond length is 1.94 Å. The Co(2)-O(7) bond length is 1.96 Å. There is one shorter (1.91 Å) and one longer (2.17 Å) Co(2)-O(1) bond length. There is one shorter (1.93 Å) and one longer (2.19 Å) Co(2)-O(12) bond length. In the third Co site, Co(3) is bonded to one O(12), one O(6), two equivalent O(10), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with four equivalent Li(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. The Co(3)-O(12) bond length is 1.97 Å. The Co(3)-O(6) bond length is 2.01 Å. There is one shorter (2.03 Å) and one longer (2.07 Å) Co(3)-O(10) bond length. There is one shorter (2.03 Å) and one longer (2.06 Å) Co(3)-O(4) bond length. In the fourth Co site, Co(4) is bonded to one O(11), one O(5), two equivalent O(3), and two equivalent O(9) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with four equivalent Li(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. The Co(4)-O(11) bond length is 1.94 Å. The Co(4)-O(5) bond length is 1.96 Å. There is one shorter (1.92 Å) and one longer (2.16 Å) Co(4)-O(3) bond length. There is one shorter (1.93 Å) and one longer (2.16 Å) Co(4)-O(9) bond length. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(6), two equivalent Li(4), one Cr(1), and two equivalent Co(2) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(8)Li3Cr2Co octahedra,  a cornercorner with one O(3)Li3CrCo2 octahedra, corners with four equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to one Li(5), two equivalent Li(3), one Cr(2), and two equivalent Co(1) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(7)Li3Cr2Co octahedra,  a cornercorner with one O(4)Li3CrCo2 octahedra, corners with four equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third O site, O(3) is bonded to one Li(3), two equivalent Li(5), one Cr(1), and two equivalent Co(4) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(6)Li3Cr2Co octahedra,  a cornercorner with one O(1)Li3CrCo2 octahedra, corners with four equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth O site, O(4) is bonded to one Li(4), two equivalent Li(6), one Cr(2), and two equivalent Co(3) atoms to form OLi3CrCo2 octahedra that share  a cornercorner with one O(5)Li3Cr2Co octahedra,  a cornercorner with one O(2)Li3CrCo2 octahedra, corners with four equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth O site, O(5) is bonded to one Li(4), two equivalent Li(1), two equivalent Cr(1), and one Co(4) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(11)Li3Co3 octahedra,  a cornercorner with one O(4)Li3CrCo2 octahedra, corners with four equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth O site, O(6) is bonded to one Li(3), two equivalent Li(2), two equivalent Cr(2), and one Co(3) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(12)Li3Co3 octahedra,  a cornercorner with one O(3)Li3CrCo2 octahedra, corners with four equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh O site, O(7) is bonded to one Li(5), two equivalent Li(1), two equivalent Cr(1), and one Co(2) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(10)Li3Co3 octahedra,  a cornercorner with one O(2)Li3CrCo2 octahedra, corners with four equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the eighth O site, O(8) is bonded to one Li(6), two equivalent Li(2), two equivalent Cr(2), and one Co(1) atom to form OLi3Cr2Co octahedra that share  a cornercorner with one O(9)Li3Co3 octahedra,  a cornercorner with one O(1)Li3CrCo2 octahedra, corners with four equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the ninth O site, O(9) is bonded to one Li(1), two equivalent Li(5), one Co(1), and two equivalent Co(4) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(12)Li3Co3 octahedra,  a cornercorner with one O(8)Li3Cr2Co octahedra, corners with four equivalent O(3)Li3CrCo2 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the tenth O site, O(10) is bonded to one Li(2), two equivalent Li(6), one Co(2), and two equivalent Co(3) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(11)Li3Co3 octahedra,  a cornercorner with one O(7)Li3Cr2Co octahedra, corners with four equivalent O(4)Li3CrCo2 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the eleventh O site, O(11) is bonded to one Li(2), two equivalent Li(3), one Co(4), and two equivalent Co(1) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(10)Li3Co3 octahedra,  a cornercorner with one O(5)Li3Cr2Co octahedra, corners with four equivalent O(2)Li3CrCo2 octahedra, edges with two equivalent O(11)Li3Co3 octahedra, edges with two equivalent O(9)Li3Co3 octahedra, edges with two equivalent O(6)Li3Cr2Co octahedra, edges with two equivalent O(8)Li3Cr2Co octahedra, edges with two equivalent O(2)Li3CrCo2 octahedra, and edges with two equivalent O(3)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the twelfth O site, O(12) is bonded to one Li(1), two equivalent Li(4), one Co(3), and two equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(9)Li3Co3 octahedra,  a cornercorner with one O(6)Li3Cr2Co octahedra, corners with four equivalent O(1)Li3CrCo2 octahedra, edges with two equivalent O(10)Li3Co3 octahedra, edges with two equivalent O(12)Li3Co3 octahedra, edges with two equivalent O(5)Li3Cr2Co octahedra, edges with two equivalent O(7)Li3Cr2Co octahedra, edges with two equivalent O(1)Li3CrCo2 octahedra, and edges with two equivalent O(4)Li3CrCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°.