HoV2ZnO6 crystallizes in the monoclinic Pc space group. Ho(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 36-42°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 36-42°. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ho(1), one V(1), one V(2), and one Zn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ho(1), one V(1), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Ho(1), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ho(1), one V(1), one V(2), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Ho(1), one V(1), one V(2), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a tetrahedral geometry to one Ho(1), one V(1), one V(2), and one Zn(1) atom.
HoV2ZnO6 crystallizes in the monoclinic Pc space group. Ho(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. The Ho(1)-O(1) bond length is 2.23 Å. The Ho(1)-O(2) bond length is 2.22 Å. The Ho(1)-O(3) bond length is 2.25 Å. The Ho(1)-O(6) bond length is 2.27 Å. There is one shorter (2.51 Å) and one longer (2.65 Å) Ho(1)-O(4) bond length. There is one shorter (2.49 Å) and one longer (2.71 Å) Ho(1)-O(5) bond length. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 36-42°. The V(1)-O(1) bond length is 2.00 Å. The V(1)-O(2) bond length is 1.96 Å. The V(1)-O(3) bond length is 2.05 Å. The V(1)-O(4) bond length is 2.12 Å. The V(1)-O(5) bond length is 2.06 Å. The V(1)-O(6) bond length is 2.06 Å. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 36-42°. The V(2)-O(1) bond length is 1.98 Å. The V(2)-O(2) bond length is 1.93 Å. The V(2)-O(3) bond length is 1.83 Å. The V(2)-O(4) bond length is 2.00 Å. The V(2)-O(5) bond length is 2.06 Å. The V(2)-O(6) bond length is 2.05 Å. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.42 Å. The Zn(1)-O(4) bond length is 2.09 Å. The Zn(1)-O(5) bond length is 2.07 Å. The Zn(1)-O(6) bond length is 2.00 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ho(1), one V(1), one V(2), and one Zn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ho(1), one V(1), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Ho(1), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ho(1), one V(1), one V(2), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Ho(1), one V(1), one V(2), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a tetrahedral geometry to one Ho(1), one V(1), one V(2), and one Zn(1) atom.