Pd(PbO3)2 crystallizes in the tetragonal P4_2/ncm space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. Pb(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Pb(1) atoms to form edge-sharing OPb4 tetrahedra. In the second O site, O(2) is bonded in a distorted square co-planar geometry to four equivalent O(3) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Pd(1), two equivalent Pb(1), and one O(2) atom.
Pd(PbO3)2 crystallizes in the tetragonal P4_2/ncm space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. All Pd(1)-O(3) bond lengths are 2.02 Å. Pb(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(3) atoms. There is one shorter (2.20 Å) and one longer (2.35 Å) Pb(1)-O(1) bond length. There are two shorter (2.48 Å) and two longer (2.52 Å) Pb(1)-O(3) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Pb(1) atoms to form edge-sharing OPb4 tetrahedra. In the second O site, O(2) is bonded in a distorted square co-planar geometry to four equivalent O(3) atoms. All O(2)-O(3) bond lengths are 2.00 Å. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Pd(1), two equivalent Pb(1), and one O(2) atom.