(Ag)2AgAlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-22-4 atoms inside a AgAlF6 framework. In the AgAlF6 framework, Ag(2) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent Ag(2)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Ag(2) and one Al(1) atom.
(Ag)2AgAlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-22-4 atoms inside a AgAlF6 framework. In the AgAlF6 framework, Ag(2) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Ag(2)-F(1) bond lengths are 2.37 Å. Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent Ag(2)F6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-F(1) bond lengths are 1.82 Å. F(1) is bonded in a linear geometry to one Ag(2) and one Al(1) atom.