CuCN4H3SClH2H2O(HCl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, four hydrochloric acid molecules, two water molecules, and two CuCN4H3SCl clusters. In each CuCN4H3SCl cluster, Cu(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one Cl(2) atom. C(1) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one N(2) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one N(1), one H(2), and one H(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one Cl(2) atom. S(1) is bonded in a distorted water-like geometry to one Cu(1) and one N(3) atom. Cl(2) is bonded in a distorted single-bond geometry to one Cu(1) and one H(5) atom.
CuCN4H3SClH2H2O(HCl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, four hydrochloric acid molecules, two water molecules, and two CuCN4H3SCl clusters. In each CuCN4H3SCl cluster, Cu(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one Cl(2) atom. The Cu(1)-N(1) bond length is 1.83 Å. The Cu(1)-S(1) bond length is 2.22 Å. The Cu(1)-Cl(2) bond length is 2.44 Å. C(1) is bonded in a linear geometry to one N(3) and one N(4) atom. The C(1)-N(3) bond length is 1.32 Å. The C(1)-N(4) bond length is 1.18 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one N(2) atom. The N(1)-N(2) bond length is 1.24 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one N(1), one H(2), and one H(3) atom. The N(2)-H(2) bond length is 1.04 Å. The N(2)-H(3) bond length is 1.04 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. The N(3)-S(1) bond length is 1.69 Å. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one Cl(2) atom. The H(5)-Cl(2) bond length is 1.34 Å. S(1) is bonded in a distorted water-like geometry to one Cu(1) and one N(3) atom. Cl(2) is bonded in a distorted single-bond geometry to one Cu(1) and one H(5) atom.