PtN2H8(OCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two azane;dichloroplatinum(2+);dihydrate molecules. Pt(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent Cl(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(4) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.
PtN2H8(OCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two azane;dichloroplatinum(2+);dihydrate molecules. Pt(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent Cl(1) atoms. Both Pt(1)-N(1) bond lengths are 2.07 Å. Both Pt(1)-O(1) bond lengths are 2.05 Å. Both Pt(1)-Cl(1) bond lengths are 2.34 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.04 Å. The N(1)-H(3) bond length is 1.05 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. The H(4)-O(1) bond length is 0.98 Å. O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(4) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.