AgCd crystallizes in the orthorhombic Amm2 space group. Ag(1) is bonded to six equivalent Ag(1) and six equivalent Cd(1) atoms to form distorted AgCd6Ag6 cuboctahedra that share corners with eighteen equivalent Ag(1)Cd6Ag6 cuboctahedra, edges with six equivalent Ag(1)Cd6Ag6 cuboctahedra, edges with twelve equivalent Cd(1)Cd6Ag6 cuboctahedra, faces with eight equivalent Ag(1)Cd6Ag6 cuboctahedra, and faces with twelve equivalent Cd(1)Cd6Ag6 cuboctahedra. Cd(1) is bonded to six equivalent Ag(1) and six equivalent Cd(1) atoms to form distorted CdCd6Ag6 cuboctahedra that share corners with eighteen equivalent Cd(1)Cd6Ag6 cuboctahedra, edges with six equivalent Cd(1)Cd6Ag6 cuboctahedra, edges with twelve equivalent Ag(1)Cd6Ag6 cuboctahedra, faces with eight equivalent Cd(1)Cd6Ag6 cuboctahedra, and faces with twelve equivalent Ag(1)Cd6Ag6 cuboctahedra.
AgCd crystallizes in the orthorhombic Amm2 space group. Ag(1) is bonded to six equivalent Ag(1) and six equivalent Cd(1) atoms to form distorted AgCd6Ag6 cuboctahedra that share corners with eighteen equivalent Ag(1)Cd6Ag6 cuboctahedra, edges with six equivalent Ag(1)Cd6Ag6 cuboctahedra, edges with twelve equivalent Cd(1)Cd6Ag6 cuboctahedra, faces with eight equivalent Ag(1)Cd6Ag6 cuboctahedra, and faces with twelve equivalent Cd(1)Cd6Ag6 cuboctahedra. There are two shorter (2.95 Å) and four longer (3.08 Å) Ag(1)-Ag(1) bond lengths. There are two shorter (2.94 Å) and four longer (2.96 Å) Ag(1)-Cd(1) bond lengths. Cd(1) is bonded to six equivalent Ag(1) and six equivalent Cd(1) atoms to form distorted CdCd6Ag6 cuboctahedra that share corners with eighteen equivalent Cd(1)Cd6Ag6 cuboctahedra, edges with six equivalent Cd(1)Cd6Ag6 cuboctahedra, edges with twelve equivalent Ag(1)Cd6Ag6 cuboctahedra, faces with eight equivalent Cd(1)Cd6Ag6 cuboctahedra, and faces with twelve equivalent Ag(1)Cd6Ag6 cuboctahedra. There are two shorter (2.95 Å) and four longer (3.08 Å) Cd(1)-Cd(1) bond lengths.