BiV is Modderite structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent Bi(1) atoms. Bi(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.
BiV is Modderite structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 8-coordinate geometry to two equivalent V(1) and six equivalent Bi(1) atoms. Both V(1)-V(1) bond lengths are 2.62 Å. There are a spread of V(1)-Bi(1) bond distances ranging from 2.74-3.19 Å. Bi(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.