TiB12 crystallizes in the cubic Fm-3m space group. Ti(1) is bonded in a 24-coordinate geometry to twenty-four equivalent B(1) atoms. B(1) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and five equivalent B(1) atoms.
TiB12 crystallizes in the cubic Fm-3m space group. Ti(1) is bonded in a 24-coordinate geometry to twenty-four equivalent B(1) atoms. All Ti(1)-B(1) bond lengths are 2.73 Å. B(1) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and five equivalent B(1) atoms. There is one shorter (1.67 Å) and four longer (1.76 Å) B(1)-B(1) bond lengths.