Ag13OsO6 crystallizes in the cubic Fm-3c space group. Os(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a cuboctahedral geometry to twelve equivalent Ag(2) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one Ag(1) and two equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to one Os(1) and four equivalent Ag(2) atoms.
Ag13OsO6 crystallizes in the cubic Fm-3c space group. Os(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Os(1)-O(1) bond lengths are 1.92 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a cuboctahedral geometry to twelve equivalent Ag(2) atoms. All Ag(1)-Ag(2) bond lengths are 2.84 Å. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one Ag(1) and two equivalent O(1) atoms. Both Ag(2)-O(1) bond lengths are 2.51 Å. O(1) is bonded in a 5-coordinate geometry to one Os(1) and four equivalent Ag(2) atoms.