C2TeS2(N2I)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2TeS2(N2I)2 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the second N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent I(1) atoms. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. I(1) is bonded in a single-bond geometry to one Te(1) atom.
C2TeS2(N2I)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2TeS2(N2I)2 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.60 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. The N(2)-N(1) bond length is 1.32 Å. In the second N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent I(1) atoms. Both Te(1)-S(1) bond lengths are 3.00 Å. Both Te(1)-I(1) bond lengths are 2.81 Å. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. I(1) is bonded in a single-bond geometry to one Te(1) atom.