GeCNH3O is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four germane, isocyanato- molecules. Ge(1) is bonded in a tetrahedral geometry to one N(1), one H(1), and two equivalent H(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one O(1) atom. N(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Ge(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom.
GeCNH3O is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four germane, isocyanato- molecules. Ge(1) is bonded in a tetrahedral geometry to one N(1), one H(1), and two equivalent H(2) atoms. The Ge(1)-N(1) bond length is 1.86 Å. The Ge(1)-H(1) bond length is 1.52 Å. Both Ge(1)-H(2) bond lengths are 1.53 Å. C(1) is bonded in a linear geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.21 Å. The C(1)-O(1) bond length is 1.19 Å. N(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Ge(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom.