RhSbS is Spinel-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form RhSb3S3 octahedra that share corners with twelve equivalent Rh(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Rh3S tetrahedra, and corners with three equivalent S(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 64°. Sb(1) is bonded to three equivalent Rh(1) and one S(1) atom to form SbRh3S tetrahedra that share corners with three equivalent Rh(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Rh3S tetrahedra, and corners with nine equivalent S(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 79°. S(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form SSbRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3S3 octahedra, corners with six equivalent S(1)SbRh3 tetrahedra, and corners with nine equivalent Sb(1)Rh3S tetrahedra. The corner-sharing octahedral tilt angles are 78°.
RhSbS is Spinel-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form RhSb3S3 octahedra that share corners with twelve equivalent Rh(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Rh3S tetrahedra, and corners with three equivalent S(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 64°. All Rh(1)-Sb(1) bond lengths are 2.59 Å. All Rh(1)-S(1) bond lengths are 2.47 Å. Sb(1) is bonded to three equivalent Rh(1) and one S(1) atom to form SbRh3S tetrahedra that share corners with three equivalent Rh(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Rh3S tetrahedra, and corners with nine equivalent S(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 79°. The Sb(1)-S(1) bond length is 2.50 Å. S(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form SSbRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3S3 octahedra, corners with six equivalent S(1)SbRh3 tetrahedra, and corners with nine equivalent Sb(1)Rh3S tetrahedra. The corner-sharing octahedral tilt angles are 78°.