LiRhF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Rh(1) atom.
LiRhF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Li(1)-F(1) bond lengths are 1.99 Å. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Rh(1)-F(1) bond lengths are 1.87 Å. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Rh(1) atom.