PrPdSb2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal P4/nmm space group. Pr(1) is bonded to four equivalent Pd(1), four equivalent Sb(1), and four equivalent Sb(2) atoms to form a mixture of edge, corner, and face-sharing PrSb8Pd4 cuboctahedra. Pd(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Pd(1) atoms. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Sb(2) atoms.
PrPdSb2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal P4/nmm space group. Pr(1) is bonded to four equivalent Pd(1), four equivalent Sb(1), and four equivalent Sb(2) atoms to form a mixture of edge, corner, and face-sharing PrSb8Pd4 cuboctahedra. All Pr(1)-Pd(1) bond lengths are 3.36 Å. All Pr(1)-Sb(1) bond lengths are 3.35 Å. All Pr(1)-Sb(2) bond lengths are 3.37 Å. Pd(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Sb(1) atoms. All Pd(1)-Sb(1) bond lengths are 2.68 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Pd(1) atoms. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Sb(2) atoms. All Sb(2)-Sb(2) bond lengths are 3.19 Å.