PdF2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Pd(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles are 52°. F(1) is bonded in a trigonal planar geometry to three equivalent Pd(1) atoms.
PdF2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Pd(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing PdF6 octahedra. The corner-sharing octahedral tilt angles are 52°. There are two shorter (2.16 Å) and four longer (2.18 Å) Pd(1)-F(1) bond lengths. F(1) is bonded in a trigonal planar geometry to three equivalent Pd(1) atoms.