CoSbS is Hausmannite-derived structured and crystallizes in the orthorhombic Pbca space group. Co(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form distorted CoSb3S3 octahedra that share corners with ten equivalent Co(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Co3S tetrahedra, corners with three equivalent S(1)Co3Sb tetrahedra, and  an edgeedge with one Co(1)Sb3S3 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. Sb(1) is bonded to three equivalent Co(1) and one S(1) atom to form distorted SbCo3S tetrahedra that share corners with three equivalent Co(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Co3S tetrahedra, and corners with nine equivalent S(1)Co3Sb tetrahedra. The corner-sharing octahedral tilt angles range from 72-81°. S(1) is bonded to three equivalent Co(1) and one Sb(1) atom to form SCo3Sb tetrahedra that share corners with three equivalent Co(1)Sb3S3 octahedra, corners with four equivalent S(1)Co3Sb tetrahedra, corners with nine equivalent Sb(1)Co3S tetrahedra, and  an edgeedge with one S(1)Co3Sb tetrahedra. The corner-sharing octahedral tilt angles range from 77-79°.
CoSbS is Hausmannite-derived structured and crystallizes in the orthorhombic Pbca space group. Co(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form distorted CoSb3S3 octahedra that share corners with ten equivalent Co(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Co3S tetrahedra, corners with three equivalent S(1)Co3Sb tetrahedra, and  an edgeedge with one Co(1)Sb3S3 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. There are a spread of Co(1)-Sb(1) bond distances ranging from 2.51-2.55 Å. There are a spread of Co(1)-S(1) bond distances ranging from 2.27-2.31 Å. Sb(1) is bonded to three equivalent Co(1) and one S(1) atom to form distorted SbCo3S tetrahedra that share corners with three equivalent Co(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Co3S tetrahedra, and corners with nine equivalent S(1)Co3Sb tetrahedra. The corner-sharing octahedral tilt angles range from 72-81°. The Sb(1)-S(1) bond length is 2.52 Å. S(1) is bonded to three equivalent Co(1) and one Sb(1) atom to form SCo3Sb tetrahedra that share corners with three equivalent Co(1)Sb3S3 octahedra, corners with four equivalent S(1)Co3Sb tetrahedra, corners with nine equivalent Sb(1)Co3S tetrahedra, and  an edgeedge with one S(1)Co3Sb tetrahedra. The corner-sharing octahedral tilt angles range from 77-79°.