TiP2(S4Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two TiP2(S4Cl)2 clusters. Ti(1) is bonded to one S(2), one S(3), one S(7), one S(8), one Cl(1), and one Cl(2) atom to form distorted TiS4Cl2 octahedra that share  an edgeedge with one P(1)S4 tetrahedra and  an edgeedge with one P(2)S4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form PS4 tetrahedra that share  a cornercorner with one P(2)S4 tetrahedra and  an edgeedge with one Ti(1)S4Cl2 octahedra. In the second P site, P(2) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form PS4 tetrahedra that share  a cornercorner with one P(1)S4 tetrahedra and  an edgeedge with one Ti(1)S4Cl2 octahedra. There are eight inequivalent S sites. In the first S site, S(6) is bonded in a distorted water-like geometry to one P(2) and one S(5) atom. In the second S site, S(7) is bonded in an L-shaped geometry to one Ti(1) and one P(2) atom. In the third S site, S(8) is bonded in an L-shaped geometry to one Ti(1) and one P(2) atom. In the fourth S site, S(1) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fifth S site, S(2) is bonded in an L-shaped geometry to one Ti(1) and one P(1) atom. In the sixth S site, S(3) is bonded in an L-shaped geometry to one Ti(1) and one P(1) atom. In the seventh S site, S(4) is bonded in a distorted L-shaped geometry to one P(1) and one S(5) atom. In the eighth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ti(1) atom.
TiP2(S4Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two TiP2(S4Cl)2 clusters. Ti(1) is bonded to one S(2), one S(3), one S(7), one S(8), one Cl(1), and one Cl(2) atom to form distorted TiS4Cl2 octahedra that share  an edgeedge with one P(1)S4 tetrahedra and  an edgeedge with one P(2)S4 tetrahedra. The Ti(1)-S(2) bond length is 2.58 Å. The Ti(1)-S(3) bond length is 2.51 Å. The Ti(1)-S(7) bond length is 2.51 Å. The Ti(1)-S(8) bond length is 2.59 Å. The Ti(1)-Cl(1) bond length is 2.24 Å. The Ti(1)-Cl(2) bond length is 2.25 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(2), one S(3), and one S(4) atom to form PS4 tetrahedra that share  a cornercorner with one P(2)S4 tetrahedra and  an edgeedge with one Ti(1)S4Cl2 octahedra. The P(1)-S(1) bond length is 2.14 Å. The P(1)-S(2) bond length is 1.99 Å. The P(1)-S(3) bond length is 2.01 Å. The P(1)-S(4) bond length is 2.13 Å. In the second P site, P(2) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form PS4 tetrahedra that share  a cornercorner with one P(1)S4 tetrahedra and  an edgeedge with one Ti(1)S4Cl2 octahedra. The P(2)-S(1) bond length is 2.14 Å. The P(2)-S(6) bond length is 2.13 Å. The P(2)-S(7) bond length is 2.02 Å. The P(2)-S(8) bond length is 1.99 Å. There are eight inequivalent S sites. In the first S site, S(6) is bonded in a distorted water-like geometry to one P(2) and one S(5) atom. The S(6)-S(5) bond length is 2.06 Å. In the second S site, S(7) is bonded in an L-shaped geometry to one Ti(1) and one P(2) atom. In the third S site, S(8) is bonded in an L-shaped geometry to one Ti(1) and one P(2) atom. In the fourth S site, S(1) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fifth S site, S(2) is bonded in an L-shaped geometry to one Ti(1) and one P(1) atom. In the sixth S site, S(3) is bonded in an L-shaped geometry to one Ti(1) and one P(1) atom. In the seventh S site, S(4) is bonded in a distorted L-shaped geometry to one P(1) and one S(5) atom. The S(4)-S(5) bond length is 2.06 Å. In the eighth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ti(1) atom.