V3O5F is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(6), one O(8), one O(9), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(3)O5F octahedra, corners with three equivalent V(6)O4F2 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 41-56°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(5)O5F octahedra,  an edgeedge with one V(6)O4F2 octahedra, and  an edgeedge with one V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 41-52°. In the third V site, V(3) is bonded to one O(10), one O(2), one O(4), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O5F octahedra, corners with three equivalent V(4)O5F octahedra, corners with three equivalent V(5)O5F octahedra,  an edgeedge with one V(6)O4F2 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. In the fourth V site, V(4) is bonded to one O(10), one O(2), one O(3), one O(7), one O(8), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(2)O6 octahedra, corners with three equivalent V(6)O4F2 octahedra, corners with three equivalent V(3)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 39-53°. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(2), one O(5), one O(9), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(6)O4F2 octahedra, corners with three equivalent V(3)O5F octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-53°. In the sixth V site, V(6) is bonded to one O(3), one O(5), one O(6), one O(8), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(5)O5F octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(2), one V(3), and one V(4) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(5) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one V(5) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom.
V3O5F is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(6), one O(8), one O(9), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(3)O5F octahedra, corners with three equivalent V(6)O4F2 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 41-56°. The V(1)-O(1) bond length is 1.85 Å. The V(1)-O(4) bond length is 1.97 Å. The V(1)-O(6) bond length is 2.08 Å. The V(1)-O(8) bond length is 1.99 Å. The V(1)-O(9) bond length is 1.87 Å. The V(1)-F(2) bond length is 2.12 Å. In the second V site, V(2) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(5)O5F octahedra,  an edgeedge with one V(6)O4F2 octahedra, and  an edgeedge with one V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 41-52°. The V(2)-O(1) bond length is 1.99 Å. The V(2)-O(3) bond length is 2.06 Å. The V(2)-O(4) bond length is 2.03 Å. The V(2)-O(5) bond length is 2.02 Å. The V(2)-O(7) bond length is 2.06 Å. The V(2)-O(9) bond length is 1.96 Å. In the third V site, V(3) is bonded to one O(10), one O(2), one O(4), one O(6), one O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O5F octahedra, corners with three equivalent V(4)O5F octahedra, corners with three equivalent V(5)O5F octahedra,  an edgeedge with one V(6)O4F2 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-53°. The V(3)-O(10) bond length is 1.97 Å. The V(3)-O(2) bond length is 1.97 Å. The V(3)-O(4) bond length is 1.89 Å. The V(3)-O(6) bond length is 2.00 Å. The V(3)-O(7) bond length is 1.84 Å. The V(3)-F(1) bond length is 2.12 Å. In the fourth V site, V(4) is bonded to one O(10), one O(2), one O(3), one O(7), one O(8), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(2)O6 octahedra, corners with three equivalent V(6)O4F2 octahedra, corners with three equivalent V(3)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 39-53°. The V(4)-O(10) bond length is 1.86 Å. The V(4)-O(2) bond length is 1.89 Å. The V(4)-O(3) bond length is 1.97 Å. The V(4)-O(7) bond length is 1.97 Å. The V(4)-O(8) bond length is 2.00 Å. The V(4)-F(2) bond length is 2.13 Å. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(2), one O(5), one O(9), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(6)O4F2 octahedra, corners with three equivalent V(3)O5F octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-53°. The V(5)-O(1) bond length is 2.04 Å. The V(5)-O(10) bond length is 2.03 Å. The V(5)-O(2) bond length is 2.02 Å. The V(5)-O(5) bond length is 1.89 Å. The V(5)-O(9) bond length is 2.00 Å. The V(5)-F(1) bond length is 2.10 Å. In the sixth V site, V(6) is bonded to one O(3), one O(5), one O(6), one O(8), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent V(5)O5F octahedra, corners with three equivalent V(1)O5F octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(3)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. The V(6)-O(3) bond length is 1.87 Å. The V(6)-O(5) bond length is 1.86 Å. The V(6)-O(6) bond length is 1.89 Å. The V(6)-O(8) bond length is 1.92 Å. The V(6)-F(1) bond length is 2.10 Å. The V(6)-F(2) bond length is 2.19 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(2), one V(3), and one V(4) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(5) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one V(5) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom.