Li4V3Sn3(TeO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(14), one O(2), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-64°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(15), one O(16), one O(4), and one O(5) atom. In the third Li site, Li(3) is bonded to one O(10), one O(3), one O(6), and one O(9) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with three equivalent Te(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(12), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-67°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(12), one O(15), one O(16), one O(2), and one O(3) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the second V site, V(2) is bonded to one O(13), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 50-53°. In the third V site, V(3) is bonded to one O(10), one O(14), one O(4), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 53-55°. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(10), one O(13), one O(14), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 53-55°. In the second Sn site, Sn(2) is bonded to one O(1), one O(11), one O(15), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the third Sn site, Sn(3) is bonded to one O(1), one O(12), one O(16), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(6), and one O(9) atom to form distorted TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Te site, Te(2) is bonded to one O(13), one O(14), one O(15), one O(16), one O(5), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(4), one Sn(2), one Sn(3), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(1), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 trigonal pyramids that share corners with three equivalent O(3)LiVSn2 tetrahedra,  a cornercorner with one O(8)LiV2Te trigonal pyramid, corners with two equivalent O(15)LiVSnTe trigonal pyramids,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(12)LiVSnTe tetrahedra. In the third O site, O(3) is bonded to one Li(3), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(11)LiVSnTe tetrahedra, corners with two equivalent O(12)LiVSnTe tetrahedra, corners with three equivalent O(2)LiVSn2 trigonal pyramids, and  an edgeedge with one O(15)LiVSnTe trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(2), one V(2), one V(3), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(15)LiVSnTe trigonal pyramid, corners with two equivalent O(8)LiV2Te trigonal pyramids, and corners with three equivalent O(7)LiV2Sn trigonal pyramids. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Sn(2), one Sn(3), and one Te(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one V(3), and one Te(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(2), one V(3), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(11)LiVSnTe tetrahedra,  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with three equivalent O(4)LiV2Sn tetrahedra, and  an edgeedge with one O(8)LiV2Te trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(1), one V(2), one V(3), and one Te(2) atom to form distorted OLiV2Te trigonal pyramids that share corners with two equivalent O(4)LiV2Sn tetrahedra,  a cornercorner with one O(2)LiVSn2 trigonal pyramid,  a cornercorner with one O(15)LiVSnTe trigonal pyramid, and  an edgeedge with one O(7)LiV2Sn trigonal pyramid. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one Sn(1), and one Te(1) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Sn(1), and one Te(1) atom. In the eleventh O site, O(11) is bonded to one Li(4), one V(1), one Sn(2), and one Te(1) atom to form distorted OLiVSnTe tetrahedra that share  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  a cornercorner with one O(7)LiV2Sn trigonal pyramid, corners with two equivalent O(15)LiVSnTe trigonal pyramids,  an edgeedge with one O(12)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one V(1), one Sn(3), and one Te(1) atom to form OLiVSnTe tetrahedra that share  a cornercorner with one O(11)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  a cornercorner with one O(7)LiV2Sn trigonal pyramid,  a cornercorner with one O(15)LiVSnTe trigonal pyramid,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Sn(1), and one Te(2) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Sn(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded to one Li(2), one V(1), one Sn(2), and one Te(2) atom to form distorted OLiVSnTe trigonal pyramids that share  a cornercorner with one O(4)LiV2Sn tetrahedra,  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with two equivalent O(11)LiVSnTe tetrahedra,  a cornercorner with one O(8)LiV2Te trigonal pyramid, corners with two equivalent O(2)LiVSn2 trigonal pyramids, and  an edgeedge with one O(3)LiVSn2 tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(3), and one Te(2) atom.
Li4V3Sn3(TeO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(14), one O(2), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-64°. The Li(1)-O(13) bond length is 2.16 Å. The Li(1)-O(14) bond length is 2.09 Å. The Li(1)-O(2) bond length is 2.03 Å. The Li(1)-O(8) bond length is 2.13 Å. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(15), one O(16), one O(4), and one O(5) atom. The Li(2)-O(15) bond length is 1.98 Å. The Li(2)-O(16) bond length is 1.97 Å. The Li(2)-O(4) bond length is 1.84 Å. The Li(2)-O(5) bond length is 2.04 Å. In the third Li site, Li(3) is bonded to one O(10), one O(3), one O(6), and one O(9) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with three equivalent Te(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. The Li(3)-O(10) bond length is 2.06 Å. The Li(3)-O(3) bond length is 1.83 Å. The Li(3)-O(6) bond length is 1.98 Å. The Li(3)-O(9) bond length is 2.04 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(12), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-67°. The Li(4)-O(1) bond length is 2.05 Å. The Li(4)-O(11) bond length is 2.11 Å. The Li(4)-O(12) bond length is 2.14 Å. The Li(4)-O(7) bond length is 2.12 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(12), one O(15), one O(16), one O(2), and one O(3) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. The V(1)-O(11) bond length is 2.05 Å. The V(1)-O(12) bond length is 2.11 Å. The V(1)-O(15) bond length is 2.03 Å. The V(1)-O(16) bond length is 2.02 Å. The V(1)-O(2) bond length is 2.14 Å. The V(1)-O(3) bond length is 2.12 Å. In the second V site, V(2) is bonded to one O(13), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 50-53°. The V(2)-O(13) bond length is 2.16 Å. The V(2)-O(4) bond length is 2.02 Å. The V(2)-O(6) bond length is 2.12 Å. The V(2)-O(7) bond length is 2.02 Å. The V(2)-O(8) bond length is 2.06 Å. The V(2)-O(9) bond length is 2.11 Å. In the third V site, V(3) is bonded to one O(10), one O(14), one O(4), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 53-55°. The V(3)-O(10) bond length is 2.20 Å. The V(3)-O(14) bond length is 2.20 Å. The V(3)-O(4) bond length is 2.14 Å. The V(3)-O(6) bond length is 2.24 Å. The V(3)-O(7) bond length is 2.16 Å. The V(3)-O(8) bond length is 2.23 Å. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(10), one O(13), one O(14), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 53-55°. The Sn(1)-O(10) bond length is 2.14 Å. The Sn(1)-O(13) bond length is 2.17 Å. The Sn(1)-O(14) bond length is 2.15 Å. The Sn(1)-O(4) bond length is 2.06 Å. The Sn(1)-O(7) bond length is 2.07 Å. The Sn(1)-O(9) bond length is 2.09 Å. In the second Sn site, Sn(2) is bonded to one O(1), one O(11), one O(15), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. The Sn(2)-O(1) bond length is 2.11 Å. The Sn(2)-O(11) bond length is 2.12 Å. The Sn(2)-O(15) bond length is 2.11 Å. The Sn(2)-O(2) bond length is 2.13 Å. The Sn(2)-O(3) bond length is 2.11 Å. The Sn(2)-O(5) bond length is 2.11 Å. In the third Sn site, Sn(3) is bonded to one O(1), one O(12), one O(16), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-57°. The Sn(3)-O(1) bond length is 2.10 Å. The Sn(3)-O(12) bond length is 2.15 Å. The Sn(3)-O(16) bond length is 2.10 Å. The Sn(3)-O(2) bond length is 2.10 Å. The Sn(3)-O(3) bond length is 2.09 Å. The Sn(3)-O(5) bond length is 2.10 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(6), and one O(9) atom to form distorted TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. The Te(1)-O(1) bond length is 2.48 Å. The Te(1)-O(10) bond length is 2.09 Å. The Te(1)-O(11) bond length is 2.39 Å. The Te(1)-O(12) bond length is 2.22 Å. The Te(1)-O(6) bond length is 2.03 Å. The Te(1)-O(9) bond length is 2.29 Å. In the second Te site, Te(2) is bonded to one O(13), one O(14), one O(15), one O(16), one O(5), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. The Te(2)-O(13) bond length is 2.11 Å. The Te(2)-O(14) bond length is 2.09 Å. The Te(2)-O(15) bond length is 2.35 Å. The Te(2)-O(16) bond length is 2.34 Å. The Te(2)-O(5) bond length is 2.38 Å. The Te(2)-O(8) bond length is 2.06 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(4), one Sn(2), one Sn(3), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(1), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 trigonal pyramids that share corners with three equivalent O(3)LiVSn2 tetrahedra,  a cornercorner with one O(8)LiV2Te trigonal pyramid, corners with two equivalent O(15)LiVSnTe trigonal pyramids,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(12)LiVSnTe tetrahedra. In the third O site, O(3) is bonded to one Li(3), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(11)LiVSnTe tetrahedra, corners with two equivalent O(12)LiVSnTe tetrahedra, corners with three equivalent O(2)LiVSn2 trigonal pyramids, and  an edgeedge with one O(15)LiVSnTe trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(2), one V(2), one V(3), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(15)LiVSnTe trigonal pyramid, corners with two equivalent O(8)LiV2Te trigonal pyramids, and corners with three equivalent O(7)LiV2Sn trigonal pyramids. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Sn(2), one Sn(3), and one Te(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one V(3), and one Te(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(2), one V(3), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(11)LiVSnTe tetrahedra,  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with three equivalent O(4)LiV2Sn tetrahedra, and  an edgeedge with one O(8)LiV2Te trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(1), one V(2), one V(3), and one Te(2) atom to form distorted OLiV2Te trigonal pyramids that share corners with two equivalent O(4)LiV2Sn tetrahedra,  a cornercorner with one O(2)LiVSn2 trigonal pyramid,  a cornercorner with one O(15)LiVSnTe trigonal pyramid, and  an edgeedge with one O(7)LiV2Sn trigonal pyramid. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one Sn(1), and one Te(1) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Sn(1), and one Te(1) atom. In the eleventh O site, O(11) is bonded to one Li(4), one V(1), one Sn(2), and one Te(1) atom to form distorted OLiVSnTe tetrahedra that share  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  a cornercorner with one O(7)LiV2Sn trigonal pyramid, corners with two equivalent O(15)LiVSnTe trigonal pyramids,  an edgeedge with one O(12)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one V(1), one Sn(3), and one Te(1) atom to form OLiVSnTe tetrahedra that share  a cornercorner with one O(11)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  a cornercorner with one O(7)LiV2Sn trigonal pyramid,  a cornercorner with one O(15)LiVSnTe trigonal pyramid,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Sn(1), and one Te(2) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Sn(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded to one Li(2), one V(1), one Sn(2), and one Te(2) atom to form distorted OLiVSnTe trigonal pyramids that share  a cornercorner with one O(4)LiV2Sn tetrahedra,  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with two equivalent O(11)LiVSnTe tetrahedra,  a cornercorner with one O(8)LiV2Te trigonal pyramid, corners with two equivalent O(2)LiVSn2 trigonal pyramids, and  an edgeedge with one O(3)LiVSn2 tetrahedra. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(3), and one Te(2) atom.