Ti(VTe2)2 crystallizes in the monoclinic C2/m space group. Ti(1) is bonded to two equivalent V(1), two equivalent Te(1), and four equivalent Te(2) atoms to form distorted edge-sharing TiV2Te6 octahedra. V(1) is bonded in a 7-coordinate geometry to one Ti(1), three equivalent Te(1), and three equivalent Te(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and three equivalent V(1) atoms. In the second Te site, Te(1) is bonded in a rectangular see-saw-like geometry to one Ti(1) and three equivalent V(1) atoms.
Ti(VTe2)2 crystallizes in the monoclinic C2/m space group. Ti(1) is bonded to two equivalent V(1), two equivalent Te(1), and four equivalent Te(2) atoms to form distorted edge-sharing TiV2Te6 octahedra. Both Ti(1)-V(1) bond lengths are 2.94 Å. Both Ti(1)-Te(1) bond lengths are 2.79 Å. All Ti(1)-Te(2) bond lengths are 2.84 Å. V(1) is bonded in a 7-coordinate geometry to one Ti(1), three equivalent Te(1), and three equivalent Te(2) atoms. There is one shorter (2.70 Å) and two longer (2.76 Å) V(1)-Te(1) bond lengths. There are two shorter (2.79 Å) and one longer (2.92 Å) V(1)-Te(2) bond length. There are two inequivalent Te sites. In the first Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent Ti(1) and three equivalent V(1) atoms. In the second Te site, Te(1) is bonded in a rectangular see-saw-like geometry to one Ti(1) and three equivalent V(1) atoms.