SmSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sm(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing SmS4Br3 pentagonal bipyramids. S(1) is bonded to four equivalent Sm(1) atoms to form a mixture of corner and edge-sharing SSm4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Sm(1) atoms.
SmSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sm(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing SmS4Br3 pentagonal bipyramids. There are a spread of Sm(1)-S(1) bond distances ranging from 2.78-2.80 Å. There are a spread of Sm(1)-Br(1) bond distances ranging from 2.99-3.13 Å. S(1) is bonded to four equivalent Sm(1) atoms to form a mixture of corner and edge-sharing SSm4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Sm(1) atoms.