C2SbN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2SbN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(5) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(6) atom. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) and one Sb(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one C(1) atom.
C2SbN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2SbN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(5) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-O(2) bond length is 1.25 Å. The C(1)-F(5) bond length is 1.32 Å. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. The C(2)-N(1) bond length is 1.24 Å. The C(2)-O(1) bond length is 1.16 Å. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(6) atom. The Sb(1)-O(2) bond length is 2.16 Å. The Sb(1)-F(1) bond length is 1.91 Å. The Sb(1)-F(2) bond length is 1.90 Å. The Sb(1)-F(3) bond length is 1.90 Å. The Sb(1)-F(4) bond length is 1.91 Å. The Sb(1)-F(6) bond length is 1.90 Å. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) and one Sb(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one C(1) atom.