MoCrAs2 crystallizes in the orthorhombic Pmc2_1 space group. Mo(1) is bonded in a 8-coordinate geometry to two equivalent Cr(1), two equivalent As(1), and four equivalent As(2) atoms. Cr(1) is bonded in a 6-coordinate geometry to two equivalent Mo(1), two equivalent As(2), and four equivalent As(1) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 4-coordinate geometry to two equivalent Mo(1) and four equivalent Cr(1) atoms. In the second As site, As(2) is bonded in a 6-coordinate geometry to four equivalent Mo(1) and two equivalent Cr(1) atoms.
MoCrAs2 crystallizes in the orthorhombic Pmc2_1 space group. Mo(1) is bonded in a 8-coordinate geometry to two equivalent Cr(1), two equivalent As(1), and four equivalent As(2) atoms. Both Mo(1)-Cr(1) bond lengths are 2.96 Å. There is one shorter (2.54 Å) and one longer (2.71 Å) Mo(1)-As(1) bond length. There are two shorter (2.59 Å) and two longer (2.60 Å) Mo(1)-As(2) bond lengths. Cr(1) is bonded in a 6-coordinate geometry to two equivalent Mo(1), two equivalent As(2), and four equivalent As(1) atoms. There is one shorter (2.43 Å) and one longer (2.64 Å) Cr(1)-As(2) bond length. There are two shorter (2.54 Å) and two longer (2.55 Å) Cr(1)-As(1) bond lengths. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 4-coordinate geometry to two equivalent Mo(1) and four equivalent Cr(1) atoms. In the second As site, As(2) is bonded in a 6-coordinate geometry to four equivalent Mo(1) and two equivalent Cr(1) atoms.