(Rb)2KGdCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a KGdCl6 framework. In the KGdCl6 framework, K(1) is bonded to six equivalent Cl(1) atoms to form KCl6 octahedra that share corners with six equivalent Gd(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Gd(1) is bonded to six equivalent Cl(1) atoms to form GdCl6 octahedra that share corners with six equivalent K(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one K(1) and one Gd(1) atom.
(Rb)2KGdCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a KGdCl6 framework. In the KGdCl6 framework, K(1) is bonded to six equivalent Cl(1) atoms to form KCl6 octahedra that share corners with six equivalent Gd(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All K(1)-Cl(1) bond lengths are 3.00 Å. Gd(1) is bonded to six equivalent Cl(1) atoms to form GdCl6 octahedra that share corners with six equivalent K(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Gd(1)-Cl(1) bond lengths are 2.67 Å. Cl(1) is bonded in a linear geometry to one K(1) and one Gd(1) atom.