GeTi3 crystallizes in the tetragonal I-4 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted water-like geometry to two equivalent Ge(1) atoms. In the second Ti site, Ti(3) is bonded in a 3-coordinate geometry to three equivalent Ge(1) atoms. In the third Ti site, Ti(2) is bonded in a 4-coordinate geometry to four equivalent Ge(1) atoms. Ge(1) is bonded in a 9-coordinate geometry to two equivalent Ti(1), three equivalent Ti(3), and four equivalent Ti(2) atoms.
GeTi3 crystallizes in the tetragonal I-4 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted water-like geometry to two equivalent Ge(1) atoms. There is one shorter (2.62 Å) and one longer (2.77 Å) Ti(1)-Ge(1) bond length. In the second Ti site, Ti(3) is bonded in a 3-coordinate geometry to three equivalent Ge(1) atoms. There are a spread of Ti(3)-Ge(1) bond distances ranging from 2.58-2.77 Å. In the third Ti site, Ti(2) is bonded in a 4-coordinate geometry to four equivalent Ge(1) atoms. There are a spread of Ti(2)-Ge(1) bond distances ranging from 2.62-2.68 Å. Ge(1) is bonded in a 9-coordinate geometry to two equivalent Ti(1), three equivalent Ti(3), and four equivalent Ti(2) atoms.