Cs2PdBr6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent Br(1) atoms to form CsBr12 cuboctahedra that share corners with twelve equivalent Cs(1)Br12 cuboctahedra, faces with six equivalent Cs(1)Br12 cuboctahedra, and faces with four equivalent Pd(1)Br6 octahedra. Pd(1) is bonded to six equivalent Br(1) atoms to form PdBr6 octahedra that share faces with eight equivalent Cs(1)Br12 cuboctahedra. Br(1) is bonded to four equivalent Cs(1) and one Pd(1) atom to form a mixture of distorted corner, edge, and face-sharing BrCs4Pd square pyramids.
Cs2PdBr6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent Br(1) atoms to form CsBr12 cuboctahedra that share corners with twelve equivalent Cs(1)Br12 cuboctahedra, faces with six equivalent Cs(1)Br12 cuboctahedra, and faces with four equivalent Pd(1)Br6 octahedra. All Cs(1)-Br(1) bond lengths are 3.81 Å. Pd(1) is bonded to six equivalent Br(1) atoms to form PdBr6 octahedra that share faces with eight equivalent Cs(1)Br12 cuboctahedra. All Pd(1)-Br(1) bond lengths are 2.50 Å. Br(1) is bonded to four equivalent Cs(1) and one Pd(1) atom to form a mixture of distorted corner, edge, and face-sharing BrCs4Pd square pyramids.