Cr(OF)3 is Protactinium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cr(OF)3 cluster. Cr(1) is bonded in a distorted single-bond geometry to one O(1), one O(2), one O(3), one F(1), and one F(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cr(1), one F(1), and one F(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cr(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Cr(1) and one O(2) atom. In the second F site, F(2) is bonded in a 1-coordinate geometry to one O(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom.
Cr(OF)3 is Protactinium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cr(OF)3 cluster. Cr(1) is bonded in a distorted single-bond geometry to one O(1), one O(2), one O(3), one F(1), and one F(3) atom. The Cr(1)-O(1) bond length is 2.06 Å. The Cr(1)-O(2) bond length is 2.41 Å. The Cr(1)-O(3) bond length is 1.14 Å. The Cr(1)-F(1) bond length is 2.08 Å. The Cr(1)-F(3) bond length is 2.51 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cr(1), one F(1), and one F(2) atom. The O(2)-F(1) bond length is 1.96 Å. The O(2)-F(2) bond length is 2.03 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Cr(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Cr(1) and one O(2) atom. In the second F site, F(2) is bonded in a 1-coordinate geometry to one O(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom.