(Mo2OCl9)2(N2)5 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of twenty ammonia atoms and four Mo2OCl9 clusters. In each Mo2OCl9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(3), one Cl(6), and two equivalent Cl(2) atoms to form corner-sharing MoCl5 square pyramids. In the second Mo site, Mo(2) is bonded to one Cl(4), one Cl(6), one Cl(7), and two equivalent Cl(5) atoms to form distorted corner-sharing MoCl5 trigonal bipyramids. O(1) is bonded in a single-bond geometry to one Cl(7) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Mo(2) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth Cl site, Cl(6) is bonded in a distorted linear geometry to one Mo(1) and one Mo(2) atom. In the fifth Cl site, Cl(7) is bonded in a bent 120 degrees geometry to one Mo(2) and one O(1) atom. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom.
(Mo2OCl9)2(N2)5 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of twenty ammonia atoms and four Mo2OCl9 clusters. In each Mo2OCl9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(3), one Cl(6), and two equivalent Cl(2) atoms to form corner-sharing MoCl5 square pyramids. The Mo(1)-Cl(1) bond length is 2.35 Å. The Mo(1)-Cl(3) bond length is 2.35 Å. The Mo(1)-Cl(6) bond length is 2.40 Å. Both Mo(1)-Cl(2) bond lengths are 2.35 Å. In the second Mo site, Mo(2) is bonded to one Cl(4), one Cl(6), one Cl(7), and two equivalent Cl(5) atoms to form distorted corner-sharing MoCl5 trigonal bipyramids. The Mo(2)-Cl(4) bond length is 2.27 Å. The Mo(2)-Cl(6) bond length is 2.71 Å. The Mo(2)-Cl(7) bond length is 2.38 Å. Both Mo(2)-Cl(5) bond lengths are 2.28 Å. O(1) is bonded in a single-bond geometry to one Cl(7) atom. The O(1)-Cl(7) bond length is 1.54 Å. There are seven inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Mo(2) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth Cl site, Cl(6) is bonded in a distorted linear geometry to one Mo(1) and one Mo(2) atom. In the fifth Cl site, Cl(7) is bonded in a bent 120 degrees geometry to one Mo(2) and one O(1) atom. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom.