MnAgO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with nine equivalent Ag(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-59°. Ag(1) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share corners with nine equivalent Mn(1)O6 octahedra, edges with three equivalent Ag(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-59°. O(1) is bonded in a 4-coordinate geometry to two equivalent Mn(1) and two equivalent Ag(1) atoms.
MnAgO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with nine equivalent Ag(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-59°. There are three shorter (1.93 Å) and three longer (1.94 Å) Mn(1)-O(1) bond lengths. Ag(1) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share corners with nine equivalent Mn(1)O6 octahedra, edges with three equivalent Ag(1)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-59°. There are three shorter (2.22 Å) and three longer (2.49 Å) Ag(1)-O(1) bond lengths. O(1) is bonded in a 4-coordinate geometry to two equivalent Mn(1) and two equivalent Ag(1) atoms.