TiCd crystallizes in the tetragonal P4/nmm space group. Ti(1) is bonded to eight equivalent Ti(1) and four equivalent Cd(1) atoms to form TiTi8Cd4 cuboctahedra that share corners with four equivalent Ti(1)Ti8Cd4 cuboctahedra, corners with eight equivalent Cd(1)Ti4Cd8 cuboctahedra, edges with eight equivalent Ti(1)Ti8Cd4 cuboctahedra, edges with sixteen equivalent Cd(1)Ti4Cd8 cuboctahedra, faces with six equivalent Cd(1)Ti4Cd8 cuboctahedra, and faces with twelve equivalent Ti(1)Ti8Cd4 cuboctahedra. Cd(1) is bonded to four equivalent Ti(1) and eight equivalent Cd(1) atoms to form CdTi4Cd8 cuboctahedra that share corners with four equivalent Cd(1)Ti4Cd8 cuboctahedra, corners with eight equivalent Ti(1)Ti8Cd4 cuboctahedra, edges with eight equivalent Cd(1)Ti4Cd8 cuboctahedra, edges with sixteen equivalent Ti(1)Ti8Cd4 cuboctahedra, faces with six equivalent Ti(1)Ti8Cd4 cuboctahedra, and faces with twelve equivalent Cd(1)Ti4Cd8 cuboctahedra.
TiCd crystallizes in the tetragonal P4/nmm space group. Ti(1) is bonded to eight equivalent Ti(1) and four equivalent Cd(1) atoms to form TiTi8Cd4 cuboctahedra that share corners with four equivalent Ti(1)Ti8Cd4 cuboctahedra, corners with eight equivalent Cd(1)Ti4Cd8 cuboctahedra, edges with eight equivalent Ti(1)Ti8Cd4 cuboctahedra, edges with sixteen equivalent Cd(1)Ti4Cd8 cuboctahedra, faces with six equivalent Cd(1)Ti4Cd8 cuboctahedra, and faces with twelve equivalent Ti(1)Ti8Cd4 cuboctahedra. There are four shorter (2.83 Å) and four longer (2.89 Å) Ti(1)-Ti(1) bond lengths. All Ti(1)-Cd(1) bond lengths are 3.09 Å. Cd(1) is bonded to four equivalent Ti(1) and eight equivalent Cd(1) atoms to form CdTi4Cd8 cuboctahedra that share corners with four equivalent Cd(1)Ti4Cd8 cuboctahedra, corners with eight equivalent Ti(1)Ti8Cd4 cuboctahedra, edges with eight equivalent Cd(1)Ti4Cd8 cuboctahedra, edges with sixteen equivalent Ti(1)Ti8Cd4 cuboctahedra, faces with six equivalent Ti(1)Ti8Cd4 cuboctahedra, and faces with twelve equivalent Cd(1)Ti4Cd8 cuboctahedra. There are four shorter (2.89 Å) and four longer (3.15 Å) Cd(1)-Cd(1) bond lengths.