PdNi2P crystallizes in the orthorhombic Cmcm space group. Pd(1) is bonded in a 13-coordinate geometry to ten equivalent Ni(1) and three equivalent P(1) atoms. Ni(1) is bonded in a 3-coordinate geometry to five equivalent Pd(1) and three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to three equivalent Pd(1) and six equivalent Ni(1) atoms.
PdNi2P crystallizes in the orthorhombic Cmcm space group. Pd(1) is bonded in a 13-coordinate geometry to ten equivalent Ni(1) and three equivalent P(1) atoms. There are eight shorter (2.74 Å) and two longer (2.82 Å) Pd(1)-Ni(1) bond lengths. There is one shorter (2.39 Å) and two longer (2.52 Å) Pd(1)-P(1) bond lengths. Ni(1) is bonded in a 3-coordinate geometry to five equivalent Pd(1) and three equivalent P(1) atoms. There is one shorter (2.22 Å) and two longer (2.26 Å) Ni(1)-P(1) bond lengths. P(1) is bonded in a 9-coordinate geometry to three equivalent Pd(1) and six equivalent Ni(1) atoms.