CrF2 crystallizes in the monoclinic P2_1/c space group. Cr(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing CrF6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Cr(1) atoms.
CrF2 crystallizes in the monoclinic P2_1/c space group. Cr(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing CrF6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. There are a spread of Cr(1)-F(1) bond distances ranging from 1.98-2.46 Å. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Cr(1) atoms.