Ag2CdZn crystallizes in the orthorhombic Cmm2 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to two equivalent Ag(2) and two equivalent Zn(1) atoms. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to two equivalent Ag(1), six equivalent Ag(2), and two equivalent Cd(1) atoms. Cd(1) is bonded in a 10-coordinate geometry to two equivalent Ag(2), six equivalent Cd(1), and two equivalent Zn(1) atoms. Zn(1) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and two equivalent Cd(1) atoms.
Ag2CdZn crystallizes in the orthorhombic Cmm2 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to two equivalent Ag(2) and two equivalent Zn(1) atoms. Both Ag(1)-Ag(2) bond lengths are 2.85 Å. Both Ag(1)-Zn(1) bond lengths are 2.68 Å. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to two equivalent Ag(1), six equivalent Ag(2), and two equivalent Cd(1) atoms. There are four shorter (2.96 Å) and two longer (3.07 Å) Ag(2)-Ag(2) bond lengths. Both Ag(2)-Cd(1) bond lengths are 2.97 Å. Cd(1) is bonded in a 10-coordinate geometry to two equivalent Ag(2), six equivalent Cd(1), and two equivalent Zn(1) atoms. There are four shorter (2.96 Å) and two longer (3.07 Å) Cd(1)-Cd(1) bond lengths. Both Cd(1)-Zn(1) bond lengths are 2.87 Å. Zn(1) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and two equivalent Cd(1) atoms.