Li4Mn3(PO4)4 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(14), one O(15), one O(25), one O(3), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-72°. In the second Li site, Li(2) is bonded to one O(12), one O(13), one O(18), one O(2), one O(20), and one O(30) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-67°. In the third Li site, Li(3) is bonded to one O(11), one O(14), one O(16), one O(17), one O(3), and one O(31) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(4)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-72°. In the fourth Li site, Li(4) is bonded to one O(21), one O(23), one O(26), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 57-68°. In the fifth Li site, Li(5) is bonded to one O(10), one O(21), one O(24), one O(27), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-66°. In the sixth Li site, Li(6) is bonded to one O(10), one O(22), one O(27), one O(28), one O(29), and one O(4) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-72°. In the seventh Li site, Li(7) is bonded to one O(1), one O(13), one O(20), one O(23), one O(24), and one O(28) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-66°. In the eighth Li site, Li(8) is bonded to one O(1), one O(11), one O(12), one O(16), one O(20), and one O(32) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-69°. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(14), one O(2), one O(24), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the second Mn site, Mn(2) is bonded to one O(11), one O(17), one O(27), one O(32), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-68°. In the third Mn site, Mn(3) is bonded to one O(13), one O(15), one O(16), one O(23), one O(25), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-65°. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(17), one O(19), one O(21), one O(6), and one O(8) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-72°. In the fifth Mn site, Mn(5) is bonded to one O(18), one O(19), one O(26), one O(29), one O(30), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-66°. In the sixth Mn site, Mn(6) is bonded to one O(18), one O(22), one O(29), one O(31), one O(32), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-69°. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(12), one O(13), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. In the second P site, P(2) is bonded to one O(24), one O(27), one O(4), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-60°. In the third P site, P(3) is bonded to one O(22), one O(5), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the fourth P site, P(4) is bonded to one O(14), one O(15), one O(20), and one O(31) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, and  an edgeedge with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-61°. In the fifth P site, P(5) is bonded to one O(11), one O(18), one O(19), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-59°. In the sixth P site, P(6) is bonded to one O(10), one O(23), one O(25), and one O(26) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. In the seventh P site, P(7) is bonded to one O(21), one O(28), one O(29), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-60°. In the eighth P site, P(8) is bonded to one O(16), one O(17), one O(30), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(7), one Li(8), one Mn(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(1), and one P(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(3), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(6), one Mn(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one Li(5), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(4), one Mn(5), and one P(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(6), and one P(7) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(2), one Mn(4), and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(4), one Mn(3), and one P(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one Mn(1), and one P(6) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(8), one Mn(2), and one P(5) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(8), one Mn(4), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(7), one Mn(3), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one Mn(3), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(8), one Mn(3), and one P(8) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Mn(2), one Mn(4), and one P(8) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Mn(5), one Mn(6), and one P(5) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one P(5) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(7), one Li(8), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(4), one Li(5), one Mn(4), and one P(7) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(6), and one P(3) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(7), one Mn(3), and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(7), one Mn(1), and one P(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(3), and one P(6) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(5), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one Mn(2), and one P(2) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one Li(6), one Li(7), and one P(7) atom. In the twenty-ninth O site, O(29) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(5), one Mn(6), and one P(7) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(5), and one P(8) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(6), and one P(4) atom. In the thirty-second O site, O(32) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Mn(2), one Mn(6), and one P(8) atom.
Li4Mn3(PO4)4 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(14), one O(15), one O(25), one O(3), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-72°. The Li(1)-O(14) bond length is 2.33 Å. The Li(1)-O(15) bond length is 2.36 Å. The Li(1)-O(25) bond length is 2.13 Å. The Li(1)-O(3) bond length is 2.07 Å. The Li(1)-O(4) bond length is 2.15 Å. The Li(1)-O(5) bond length is 2.18 Å. In the second Li site, Li(2) is bonded to one O(12), one O(13), one O(18), one O(2), one O(20), and one O(30) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-67°. The Li(2)-O(12) bond length is 2.25 Å. The Li(2)-O(13) bond length is 2.05 Å. The Li(2)-O(18) bond length is 2.37 Å. The Li(2)-O(2) bond length is 2.04 Å. The Li(2)-O(20) bond length is 2.10 Å. The Li(2)-O(30) bond length is 2.24 Å. In the third Li site, Li(3) is bonded to one O(11), one O(14), one O(16), one O(17), one O(3), and one O(31) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(4)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-72°. The Li(3)-O(11) bond length is 2.38 Å. The Li(3)-O(14) bond length is 2.14 Å. The Li(3)-O(16) bond length is 2.17 Å. The Li(3)-O(17) bond length is 2.29 Å. The Li(3)-O(3) bond length is 1.97 Å. The Li(3)-O(31) bond length is 2.13 Å. In the fourth Li site, Li(4) is bonded to one O(21), one O(23), one O(26), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 57-68°. The Li(4)-O(21) bond length is 2.34 Å. The Li(4)-O(23) bond length is 2.19 Å. The Li(4)-O(26) bond length is 2.14 Å. The Li(4)-O(5) bond length is 2.19 Å. The Li(4)-O(8) bond length is 2.18 Å. The Li(4)-O(9) bond length is 2.11 Å. In the fifth Li site, Li(5) is bonded to one O(10), one O(21), one O(24), one O(27), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-66°. The Li(5)-O(10) bond length is 2.20 Å. The Li(5)-O(21) bond length is 2.30 Å. The Li(5)-O(24) bond length is 2.18 Å. The Li(5)-O(27) bond length is 2.15 Å. The Li(5)-O(5) bond length is 2.08 Å. The Li(5)-O(6) bond length is 2.25 Å. In the sixth Li site, Li(6) is bonded to one O(10), one O(22), one O(27), one O(28), one O(29), and one O(4) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-72°. The Li(6)-O(10) bond length is 2.32 Å. The Li(6)-O(22) bond length is 2.18 Å. The Li(6)-O(27) bond length is 2.28 Å. The Li(6)-O(28) bond length is 2.06 Å. The Li(6)-O(29) bond length is 2.30 Å. The Li(6)-O(4) bond length is 2.13 Å. In the seventh Li site, Li(7) is bonded to one O(1), one O(13), one O(20), one O(23), one O(24), and one O(28) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-66°. The Li(7)-O(1) bond length is 2.31 Å. The Li(7)-O(13) bond length is 2.31 Å. The Li(7)-O(20) bond length is 2.20 Å. The Li(7)-O(23) bond length is 2.14 Å. The Li(7)-O(24) bond length is 2.12 Å. The Li(7)-O(28) bond length is 2.04 Å. In the eighth Li site, Li(8) is bonded to one O(1), one O(11), one O(12), one O(16), one O(20), and one O(32) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 54-69°. The Li(8)-O(1) bond length is 2.08 Å. The Li(8)-O(11) bond length is 2.33 Å. The Li(8)-O(12) bond length is 2.15 Å. The Li(8)-O(16) bond length is 2.06 Å. The Li(8)-O(20) bond length is 2.04 Å. The Li(8)-O(32) bond length is 2.36 Å. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(14), one O(2), one O(24), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-63°. The Mn(1)-O(1) bond length is 2.13 Å. The Mn(1)-O(10) bond length is 2.21 Å. The Mn(1)-O(14) bond length is 2.01 Å. The Mn(1)-O(2) bond length is 2.11 Å. The Mn(1)-O(24) bond length is 2.06 Å. The Mn(1)-O(4) bond length is 2.02 Å. In the second Mn site, Mn(2) is bonded to one O(11), one O(17), one O(27), one O(32), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-68°. The Mn(2)-O(11) bond length is 2.22 Å. The Mn(2)-O(17) bond length is 2.13 Å. The Mn(2)-O(27) bond length is 2.17 Å. The Mn(2)-O(32) bond length is 2.17 Å. The Mn(2)-O(7) bond length is 2.06 Å. The Mn(2)-O(8) bond length is 2.09 Å. In the third Mn site, Mn(3) is bonded to one O(13), one O(15), one O(16), one O(23), one O(25), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(7)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-65°. The Mn(3)-O(13) bond length is 2.07 Å. The Mn(3)-O(15) bond length is 2.03 Å. The Mn(3)-O(16) bond length is 2.19 Å. The Mn(3)-O(23) bond length is 2.01 Å. The Mn(3)-O(25) bond length is 2.00 Å. The Mn(3)-O(9) bond length is 2.20 Å. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(17), one O(19), one O(21), one O(6), and one O(8) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-72°. The Mn(4)-O(12) bond length is 2.05 Å. The Mn(4)-O(17) bond length is 2.08 Å. The Mn(4)-O(19) bond length is 2.06 Å. The Mn(4)-O(21) bond length is 2.13 Å. The Mn(4)-O(6) bond length is 2.26 Å. The Mn(4)-O(8) bond length is 2.24 Å. In the fifth Mn site, Mn(5) is bonded to one O(18), one O(19), one O(26), one O(29), one O(30), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-66°. The Mn(5)-O(18) bond length is 2.12 Å. The Mn(5)-O(19) bond length is 2.12 Å. The Mn(5)-O(26) bond length is 2.13 Å. The Mn(5)-O(29) bond length is 2.07 Å. The Mn(5)-O(30) bond length is 2.20 Å. The Mn(5)-O(6) bond length is 2.13 Å. In the sixth Mn site, Mn(6) is bonded to one O(18), one O(22), one O(29), one O(31), one O(32), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-69°. The Mn(6)-O(18) bond length is 2.10 Å. The Mn(6)-O(22) bond length is 2.11 Å. The Mn(6)-O(29) bond length is 2.22 Å. The Mn(6)-O(31) bond length is 2.03 Å. The Mn(6)-O(32) bond length is 2.11 Å. The Mn(6)-O(7) bond length is 2.21 Å. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(12), one O(13), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, and  an edgeedge with one Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. The P(1)-O(1) bond length is 1.57 Å. The P(1)-O(12) bond length is 1.59 Å. The P(1)-O(13) bond length is 1.59 Å. The P(1)-O(3) bond length is 1.51 Å. In the second P site, P(2) is bonded to one O(24), one O(27), one O(4), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-60°. The P(2)-O(24) bond length is 1.58 Å. The P(2)-O(27) bond length is 1.55 Å. The P(2)-O(4) bond length is 1.60 Å. The P(2)-O(9) bond length is 1.51 Å. In the third P site, P(3) is bonded to one O(22), one O(5), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-57°. The P(3)-O(22) bond length is 1.53 Å. The P(3)-O(5) bond length is 1.53 Å. The P(3)-O(6) bond length is 1.59 Å. The P(3)-O(8) bond length is 1.59 Å. In the fourth P site, P(4) is bonded to one O(14), one O(15), one O(20), and one O(31) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, and  an edgeedge with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-61°. The P(4)-O(14) bond length is 1.60 Å. The P(4)-O(15) bond length is 1.56 Å. The P(4)-O(20) bond length is 1.53 Å. The P(4)-O(31) bond length is 1.56 Å. In the fifth P site, P(5) is bonded to one O(11), one O(18), one O(19), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-59°. The P(5)-O(11) bond length is 1.53 Å. The P(5)-O(18) bond length is 1.60 Å. The P(5)-O(19) bond length is 1.58 Å. The P(5)-O(2) bond length is 1.52 Å. In the sixth P site, P(6) is bonded to one O(10), one O(23), one O(25), and one O(26) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. The P(6)-O(10) bond length is 1.54 Å. The P(6)-O(23) bond length is 1.60 Å. The P(6)-O(25) bond length is 1.57 Å. The P(6)-O(26) bond length is 1.53 Å. In the seventh P site, P(7) is bonded to one O(21), one O(28), one O(29), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra, and  an edgeedge with one Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-60°. The P(7)-O(21) bond length is 1.55 Å. The P(7)-O(28) bond length is 1.51 Å. The P(7)-O(29) bond length is 1.60 Å. The P(7)-O(7) bond length is 1.58 Å. In the eighth P site, P(8) is bonded to one O(16), one O(17), one O(30), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. The P(8)-O(16) bond length is 1.54 Å. The P(8)-O(17) bond length is 1.59 Å. The P(8)-O(30) bond length is 1.51 Å. The P(8)-O(32) bond length is 1.59 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(7), one Li(8), one Mn(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(1), and one P(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(3), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(6), one Mn(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one Li(5), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(4), one Mn(5), and one P(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(6), and one P(7) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(2), one Mn(4), and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(4), one Mn(3), and one P(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one Mn(1), and one P(6) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(8), one Mn(2), and one P(5) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(8), one Mn(4), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(7), one Mn(3), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one Mn(3), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(8), one Mn(3), and one P(8) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Mn(2), one Mn(4), and one P(8) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Mn(5), one Mn(6), and one P(5) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one P(5) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(7), one Li(8), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(4), one Li(5), one Mn(4), and one P(7) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(6), and one P(3) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Li(4), one Li(7), one Mn(3), and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(7), one Mn(1), and one P(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(3), and one P(6) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(5), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a rectangular see-saw-like geometry to one Li(5), one Li(6), one Mn(2), and one P(2) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one Li(6), one Li(7), and one P(7) atom. In the twenty-ninth O site, O(29) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(5), one Mn(6), and one P(7) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(5), and one P(8) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(6), and one P(4) atom. In the thirty-second O site, O(32) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Mn(2), one Mn(6), and one P(8) atom.