AlCl4NS2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four (chlorosulfanylamino) thiohypochlorite molecules and four AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(5), one Cl(8), and two equivalent Cl(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Al(1) atom.
AlCl4NS2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four (chlorosulfanylamino) thiohypochlorite molecules and four AlCl4 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(5), one Cl(8), and two equivalent Cl(2) atoms. The Al(1)-Cl(5) bond length is 2.18 Å. The Al(1)-Cl(8) bond length is 2.16 Å. Both Al(1)-Cl(2) bond lengths are 2.15 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Al(1) atom.