SmLa7Ti3V5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Sm(1) is bonded to one O(13), one O(9), two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the second La site, La(2) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(11), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the fourth La site, La(4) is bonded to one O(11), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the fifth La site, La(5) is bonded to one O(11), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(9), two equivalent O(3), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third V site, V(3) is bonded to one O(13), one O(14), two equivalent O(2), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth V site, V(4) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(1), and one Ti(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded to one La(1), one La(2), one La(3), one La(4), one V(2), and one V(4) atom to form distorted face-sharing OLa4V2 octahedra. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(1), and one Ti(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(2), and one V(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(1), and one V(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(2), and one V(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(1), and one V(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(2), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(1), and one V(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(2), and one V(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(3), and one V(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one V(3), and one V(4) atom.
SmLa7Ti3V5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Sm(1) is bonded to one O(13), one O(9), two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. The Sm(1)-O(13) bond length is 2.75 Å. The Sm(1)-O(9) bond length is 2.81 Å. Both Sm(1)-O(10) bond lengths are 2.77 Å. Both Sm(1)-O(5) bond lengths are 2.83 Å. Both Sm(1)-O(6) bond lengths are 2.80 Å. Both Sm(1)-O(7) bond lengths are 2.76 Å. Both Sm(1)-O(8) bond lengths are 2.71 Å. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. The La(1)-O(1) bond length is 2.83 Å. The La(1)-O(13) bond length is 2.77 Å. The La(1)-O(2) bond length is 2.81 Å. The La(1)-O(3) bond length is 2.79 Å. The La(1)-O(4) bond length is 2.77 Å. The La(1)-O(5) bond length is 2.84 Å. The La(1)-O(6) bond length is 2.81 Å. The La(1)-O(7) bond length is 2.78 Å. The La(1)-O(8) bond length is 2.77 Å. The La(1)-O(9) bond length is 2.82 Å. Both La(1)-O(10) bond lengths are 2.81 Å. In the second La site, La(2) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. The La(2)-O(13) bond length is 2.82 Å. The La(2)-O(9) bond length is 2.84 Å. Both La(2)-O(1) bond lengths are 2.82 Å. Both La(2)-O(10) bond lengths are 2.81 Å. Both La(2)-O(2) bond lengths are 2.81 Å. Both La(2)-O(3) bond lengths are 2.79 Å. Both La(2)-O(4) bond lengths are 2.77 Å. In the third La site, La(3) is bonded to one O(1), one O(11), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. The La(3)-O(1) bond length is 2.83 Å. The La(3)-O(11) bond length is 2.82 Å. The La(3)-O(14) bond length is 2.77 Å. The La(3)-O(2) bond length is 2.81 Å. The La(3)-O(3) bond length is 2.79 Å. The La(3)-O(4) bond length is 2.77 Å. The La(3)-O(5) bond length is 2.85 Å. The La(3)-O(6) bond length is 2.83 Å. The La(3)-O(7) bond length is 2.82 Å. The La(3)-O(8) bond length is 2.80 Å. Both La(3)-O(12) bond lengths are 2.81 Å. In the fourth La site, La(4) is bonded to one O(11), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. The La(4)-O(11) bond length is 2.82 Å. The La(4)-O(14) bond length is 2.79 Å. Both La(4)-O(1) bond lengths are 2.83 Å. Both La(4)-O(12) bond lengths are 2.80 Å. Both La(4)-O(2) bond lengths are 2.82 Å. Both La(4)-O(3) bond lengths are 2.79 Å. Both La(4)-O(4) bond lengths are 2.76 Å. In the fifth La site, La(5) is bonded to one O(11), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. The La(5)-O(11) bond length is 2.82 Å. The La(5)-O(14) bond length is 2.80 Å. Both La(5)-O(12) bond lengths are 2.79 Å. Both La(5)-O(5) bond lengths are 2.82 Å. Both La(5)-O(6) bond lengths are 2.81 Å. Both La(5)-O(7) bond lengths are 2.78 Å. Both La(5)-O(8) bond lengths are 2.77 Å. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. The Ti(1)-O(11) bond length is 1.93 Å. The Ti(1)-O(9) bond length is 1.92 Å. Both Ti(1)-O(1) bond lengths are 1.99 Å. Both Ti(1)-O(5) bond lengths are 1.98 Å. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. The Ti(2)-O(1) bond length is 1.98 Å. The Ti(2)-O(10) bond length is 1.93 Å. The Ti(2)-O(12) bond length is 1.94 Å. The Ti(2)-O(2) bond length is 1.94 Å. The Ti(2)-O(5) bond length is 1.97 Å. The Ti(2)-O(6) bond length is 1.94 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(9), two equivalent O(3), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. The V(1)-O(11) bond length is 2.03 Å. The V(1)-O(9) bond length is 2.03 Å. Both V(1)-O(3) bond lengths are 2.01 Å. Both V(1)-O(7) bond lengths are 2.01 Å. In the second V site, V(2) is bonded to one O(10), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. The V(2)-O(10) bond length is 2.02 Å. The V(2)-O(12) bond length is 2.02 Å. The V(2)-O(3) bond length is 1.95 Å. The V(2)-O(4) bond length is 1.97 Å. The V(2)-O(7) bond length is 1.95 Å. The V(2)-O(8) bond length is 1.97 Å. In the third V site, V(3) is bonded to one O(13), one O(14), two equivalent O(2), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. The V(3)-O(13) bond length is 2.01 Å. The V(3)-O(14) bond length is 2.01 Å. Both V(3)-O(2) bond lengths are 2.02 Å. Both V(3)-O(6) bond lengths are 2.02 Å. In the fourth V site, V(4) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. The V(4)-O(13) bond length is 1.94 Å. The V(4)-O(14) bond length is 1.95 Å. Both V(4)-O(4) bond lengths are 1.99 Å. Both V(4)-O(8) bond lengths are 1.99 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(1), and one Ti(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded to one La(1), one La(2), one La(3), one La(4), one V(2), and one V(4) atom to form distorted face-sharing OLa4V2 octahedra. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(1), and one Ti(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(2), and one V(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(1), and one V(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(2), and one V(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(1), and one V(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(2), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(1), and one V(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(2), and one V(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(3), and one V(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one V(3), and one V(4) atom.