NaSbO5O2 crystallizes in the orthorhombic Cmc2_1 space group. The structure consists of four 7782-44-7 molecules inside a NaSbO5 framework. In the NaSbO5 framework, Na(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. Sb(1) is bonded in a square pyramidal geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sb(1) atom.
NaSbO5O2 crystallizes in the orthorhombic Cmc2_1 space group. The structure consists of four 7782-44-7 molecules inside a NaSbO5 framework. In the NaSbO5 framework, Na(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. The Na(1)-O(1) bond length is 2.48 Å. There are two shorter (2.37 Å) and two longer (2.75 Å) Na(1)-O(2) bond lengths. Sb(1) is bonded in a square pyramidal geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. The Sb(1)-O(1) bond length is 1.95 Å. Both Sb(1)-O(2) bond lengths are 1.98 Å. Both Sb(1)-O(3) bond lengths are 2.02 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sb(1) atom.