HfN is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Hf(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing HfN6 pentagonal pyramids. N(1) is bonded to six equivalent Hf(1) atoms to form a mixture of corner, edge, and face-sharing NHf6 octahedra. The corner-sharing octahedral tilt angles are 47°.
HfN is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Hf(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing HfN6 pentagonal pyramids. All Hf(1)-N(1) bond lengths are 2.26 Å. N(1) is bonded to six equivalent Hf(1) atoms to form a mixture of corner, edge, and face-sharing NHf6 octahedra. The corner-sharing octahedral tilt angles are 47°.