NMnCl3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to two equivalent Cl(1) and four equivalent Cl(2) atoms to form corner-sharing MnCl6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. N(1) is bonded in a water-like geometry to two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one N(1) atom.
NMnCl3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to two equivalent Cl(1) and four equivalent Cl(2) atoms to form corner-sharing MnCl6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. Both Mn(1)-Cl(1) bond lengths are 2.35 Å. There are two shorter (2.69 Å) and two longer (2.77 Å) Mn(1)-Cl(2) bond lengths. N(1) is bonded in a water-like geometry to two equivalent Cl(2) atoms. Both N(1)-Cl(2) bond lengths are 1.76 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a trigonal planar geometry to two equivalent Mn(1) and one N(1) atom.