CsAgO crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent Cs(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing OCs4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 0-9°.
CsAgO crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (2.99 Å) and two longer (3.11 Å) Cs(1)-O(1) bond lengths. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.05 Å. O(1) is bonded to four equivalent Cs(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing OCs4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 0-9°.