RbAg3Te2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 7-coordinate geometry to three equivalent Te(1) and four equivalent Te(2) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one Te(1) and two equivalent Te(2) atoms. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one Te(2) and two equivalent Te(1) atoms. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to one Te(2) and three equivalent Te(1) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 9-coordinate geometry to three equivalent Rb(1), one Ag(1), two equivalent Ag(2), and three equivalent Ag(3) atoms. In the second Te site, Te(2) is bonded in a 8-coordinate geometry to four equivalent Rb(1), one Ag(2), one Ag(3), and two equivalent Ag(1) atoms.
RbAg3Te2 crystallizes in the monoclinic C2/m space group. Rb(1) is bonded in a 7-coordinate geometry to three equivalent Te(1) and four equivalent Te(2) atoms. There are two shorter (3.73 Å) and one longer (3.86 Å) Rb(1)-Te(1) bond length. There are two shorter (3.74 Å) and two longer (3.81 Å) Rb(1)-Te(2) bond lengths. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one Te(1) and two equivalent Te(2) atoms. The Ag(1)-Te(1) bond length is 2.85 Å. Both Ag(1)-Te(2) bond lengths are 2.81 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one Te(2) and two equivalent Te(1) atoms. The Ag(2)-Te(2) bond length is 2.76 Å. Both Ag(2)-Te(1) bond lengths are 2.96 Å. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to one Te(2) and three equivalent Te(1) atoms. The Ag(3)-Te(2) bond length is 2.94 Å. There is one shorter (2.78 Å) and two longer (3.19 Å) Ag(3)-Te(1) bond lengths. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 9-coordinate geometry to three equivalent Rb(1), one Ag(1), two equivalent Ag(2), and three equivalent Ag(3) atoms. In the second Te site, Te(2) is bonded in a 8-coordinate geometry to four equivalent Rb(1), one Ag(2), one Ag(3), and two equivalent Ag(1) atoms.