GaP is High Pressure Cadmuum Telluride structured and crystallizes in the tetragonal P4/mmm space group. Ga(1) is bonded to four equivalent Ga(1) and two equivalent P(1) atoms to form GaGa4P2 octahedra that share corners with six equivalent Ga(1)Ga4P2 octahedra, edges with four equivalent Ga(1)Ga4P2 octahedra, and edges with eight equivalent P(1)Ga2P4 octahedra. The corner-sharing octahedra are not tilted. P(1) is bonded to two equivalent Ga(1) and four equivalent P(1) atoms to form PGa2P4 octahedra that share corners with six equivalent P(1)Ga2P4 octahedra, edges with four equivalent P(1)Ga2P4 octahedra, and edges with eight equivalent Ga(1)Ga4P2 octahedra. The corner-sharing octahedra are not tilted.
GaP is High Pressure Cadmuum Telluride structured and crystallizes in the tetragonal P4/mmm space group. Ga(1) is bonded to four equivalent Ga(1) and two equivalent P(1) atoms to form GaGa4P2 octahedra that share corners with six equivalent Ga(1)Ga4P2 octahedra, edges with four equivalent Ga(1)Ga4P2 octahedra, and edges with eight equivalent P(1)Ga2P4 octahedra. The corner-sharing octahedra are not tilted. All Ga(1)-Ga(1) bond lengths are 2.57 Å. Both Ga(1)-P(1) bond lengths are 2.63 Å. P(1) is bonded to two equivalent Ga(1) and four equivalent P(1) atoms to form PGa2P4 octahedra that share corners with six equivalent P(1)Ga2P4 octahedra, edges with four equivalent P(1)Ga2P4 octahedra, and edges with eight equivalent Ga(1)Ga4P2 octahedra. The corner-sharing octahedra are not tilted. All P(1)-P(1) bond lengths are 2.57 Å.