WAgC5(NS2)2C4N is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two C4N clusters and two WAgC5(NS2)2 clusters. In each C4N cluster, there are four inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one N(3) atom. In the second C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one C(9), and one N(3) atom. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one N(3) atom. In the fourth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one C(7), and one N(3) atom. N(3) is bonded in a 4-coordinate geometry to one C(6), one C(7), one C(8), and one C(9) atom. In each WAgC5(NS2)2 cluster, W(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. Ag(1) is bonded in a 3-coordinate geometry to one C(1), one S(1), and one S(2) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one N(2) atom. In the third C site, C(3) is bonded in a 2-coordinate geometry to one C(2) and one N(2) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one C(5) and one N(2) atom. In the fifth C site, C(5) is bonded in a linear geometry to one C(4) and one S(4) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one C(2), one C(3), and one C(4) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one W(1) and one C(5) atom.
WAgC5(NS2)2C4N is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two C4N clusters and two WAgC5(NS2)2 clusters. In each C4N cluster, there are four inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one N(3) atom. The C(6)-C(9) bond length is 1.46 Å. The C(6)-N(3) bond length is 1.38 Å. In the second C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one C(9), and one N(3) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-C(9) bond length is 1.42 Å. The C(7)-N(3) bond length is 1.72 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one N(3) atom. The C(8)-N(3) bond length is 1.35 Å. In the fourth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one C(7), and one N(3) atom. The C(9)-N(3) bond length is 1.71 Å. N(3) is bonded in a 4-coordinate geometry to one C(6), one C(7), one C(8), and one C(9) atom. In each WAgC5(NS2)2 cluster, W(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. The W(1)-S(1) bond length is 2.20 Å. The W(1)-S(2) bond length is 2.21 Å. The W(1)-S(3) bond length is 2.14 Å. The W(1)-S(4) bond length is 2.41 Å. Ag(1) is bonded in a 3-coordinate geometry to one C(1), one S(1), and one S(2) atom. The Ag(1)-C(1) bond length is 2.06 Å. The Ag(1)-S(1) bond length is 2.51 Å. The Ag(1)-S(2) bond length is 2.49 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one N(2) atom. The C(2)-C(3) bond length is 1.45 Å. The C(2)-N(2) bond length is 1.40 Å. In the third C site, C(3) is bonded in a 2-coordinate geometry to one C(2) and one N(2) atom. The C(3)-N(2) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted linear geometry to one C(5) and one N(2) atom. The C(4)-C(5) bond length is 1.24 Å. The C(4)-N(2) bond length is 1.29 Å. In the fifth C site, C(5) is bonded in a linear geometry to one C(4) and one S(4) atom. The C(5)-S(4) bond length is 1.64 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one C(2), one C(3), and one C(4) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one W(1) and one C(5) atom.