VOsCl is half-Heusler structured and crystallizes in the cubic F-43m space group. V(1) is bonded in a body-centered cubic geometry to four equivalent Os(1) and four equivalent Cl(1) atoms. Os(1) is bonded in a 10-coordinate geometry to four equivalent V(1) and six equivalent Cl(1) atoms. Cl(1) is bonded to four equivalent V(1) and six equivalent Os(1) atoms to form a mixture of distorted corner and face-sharing ClV4Os6 tetrahedra.
VOsCl is half-Heusler structured and crystallizes in the cubic F-43m space group. V(1) is bonded in a body-centered cubic geometry to four equivalent Os(1) and four equivalent Cl(1) atoms. All V(1)-Os(1) bond lengths are 2.53 Å. All V(1)-Cl(1) bond lengths are 2.53 Å. Os(1) is bonded in a 10-coordinate geometry to four equivalent V(1) and six equivalent Cl(1) atoms. All Os(1)-Cl(1) bond lengths are 2.92 Å. Cl(1) is bonded to four equivalent V(1) and six equivalent Os(1) atoms to form a mixture of distorted corner and face-sharing ClV4Os6 tetrahedra.