C3PN6H15S is Indium-like structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of two C3PN6H15S clusters. C(1) is bonded to one N(2), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one P(1)SN3 tetrahedra. P(1) is bonded to three equivalent N(2) and one S(1) atom to form PSN3 tetrahedra that share corners with three equivalent C(1)H3N tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one N(2), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one P(1), and one N(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom.
C3PN6H15S is Indium-like structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of two C3PN6H15S clusters. C(1) is bonded to one N(2), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one P(1)SN3 tetrahedra. The C(1)-N(2) bond length is 1.46 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.11 Å. P(1) is bonded to three equivalent N(2) and one S(1) atom to form PSN3 tetrahedra that share corners with three equivalent C(1)H3N tetrahedra. All P(1)-N(2) bond lengths are 1.68 Å. The P(1)-S(1) bond length is 1.97 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one N(2), one H(4), and one H(5) atom. The N(1)-N(2) bond length is 1.42 Å. The N(1)-H(4) bond length is 1.03 Å. The N(1)-H(5) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one P(1), and one N(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom.