LiPr2Ge6 crystallizes in the orthorhombic Cmmm space group. Li(1) is bonded in a body-centered cubic geometry to four equivalent Ge(2) and four equivalent Ge(3) atoms. Pr(1) is bonded in a 10-coordinate geometry to two equivalent Ge(2), two equivalent Ge(3), and six equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to six equivalent Pr(1) and two equivalent Ge(1) atoms. In the second Ge site, Ge(2) is bonded in a 2-coordinate geometry to two equivalent Li(1) and two equivalent Pr(1) atoms. In the third Ge site, Ge(3) is bonded in a 2-coordinate geometry to two equivalent Li(1) and two equivalent Pr(1) atoms.
LiPr2Ge6 crystallizes in the orthorhombic Cmmm space group. Li(1) is bonded in a body-centered cubic geometry to four equivalent Ge(2) and four equivalent Ge(3) atoms. All Li(1)-Ge(2) bond lengths are 2.46 Å. All Li(1)-Ge(3) bond lengths are 2.53 Å. Pr(1) is bonded in a 10-coordinate geometry to two equivalent Ge(2), two equivalent Ge(3), and six equivalent Ge(1) atoms. Both Pr(1)-Ge(2) bond lengths are 3.08 Å. Both Pr(1)-Ge(3) bond lengths are 3.13 Å. There are four shorter (3.15 Å) and two longer (3.39 Å) Pr(1)-Ge(1) bond lengths. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to six equivalent Pr(1) and two equivalent Ge(1) atoms. Both Ge(1)-Ge(1) bond lengths are 2.63 Å. In the second Ge site, Ge(2) is bonded in a 2-coordinate geometry to two equivalent Li(1) and two equivalent Pr(1) atoms. In the third Ge site, Ge(3) is bonded in a 2-coordinate geometry to two equivalent Li(1) and two equivalent Pr(1) atoms.