PbOCl crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and five equivalent Cl(1) atoms. O(1) is bonded in a trigonal non-coplanar geometry to three equivalent Pb(1) atoms. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms.
PbOCl crystallizes in the orthorhombic Pnma space group. Pb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and five equivalent Cl(1) atoms. There are two shorter (2.25 Å) and one longer (2.28 Å) Pb(1)-O(1) bond length. There are a spread of Pb(1)-Cl(1) bond distances ranging from 3.04-3.21 Å. O(1) is bonded in a trigonal non-coplanar geometry to three equivalent Pb(1) atoms. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms.