EuFeO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Eu(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 22-28°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Eu(1) and two equivalent Fe(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Eu(1) and two equivalent Fe(1) atoms.
EuFeO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Eu(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. The Eu(1)-O(2) bond length is 2.36 Å. All Eu(1)-O(1) bond lengths are 2.48 Å. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 22-28°. Both Fe(1)-O(2) bond lengths are 2.01 Å. All Fe(1)-O(1) bond lengths are 1.99 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Eu(1) and two equivalent Fe(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Eu(1) and two equivalent Fe(1) atoms.