WP2 crystallizes in the monoclinic C2/m space group. W(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent W(1) and three equivalent P(1) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent W(1) atoms.
WP2 crystallizes in the monoclinic C2/m space group. W(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There is one shorter (2.47 Å) and two longer (2.48 Å) W(1)-P(1) bond lengths. There are a spread of W(1)-P(2) bond distances ranging from 2.50-2.63 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent W(1) and three equivalent P(1) atoms. There is one shorter (2.18 Å) and two longer (2.64 Å) P(1)-P(1) bond lengths. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent W(1) atoms.