Sr2CuCd2(SO)2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Cu(1) is bonded in a square co-planar geometry to two equivalent S(1) and four equivalent O(1) atoms. Cd(1) is bonded in a 8-coordinate geometry to four equivalent Cd(1) and four equivalent S(1) atoms. S(1) is bonded in a 9-coordinate geometry to four equivalent Sr(1), one Cu(1), and four equivalent Cd(1) atoms. O(1) is bonded to four equivalent Sr(1) and two equivalent Cu(1) atoms to form a mixture of corner, edge, and face-sharing OSr4Cu2 octahedra. The corner-sharing octahedra are not tilted.
Sr2CuCd2(SO)2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. All Sr(1)-S(1) bond lengths are 3.19 Å. All Sr(1)-O(1) bond lengths are 2.61 Å. Cu(1) is bonded in a square co-planar geometry to two equivalent S(1) and four equivalent O(1) atoms. Both Cu(1)-S(1) bond lengths are 3.03 Å. All Cu(1)-O(1) bond lengths are 2.03 Å. Cd(1) is bonded in a 8-coordinate geometry to four equivalent Cd(1) and four equivalent S(1) atoms. All Cd(1)-Cd(1) bond lengths are 2.87 Å. All Cd(1)-S(1) bond lengths are 3.00 Å. S(1) is bonded in a 9-coordinate geometry to four equivalent Sr(1), one Cu(1), and four equivalent Cd(1) atoms. O(1) is bonded to four equivalent Sr(1) and two equivalent Cu(1) atoms to form a mixture of corner, edge, and face-sharing OSr4Cu2 octahedra. The corner-sharing octahedra are not tilted.