PHSF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PHSF2 clusters. P(1) is bonded in a 4-coordinate geometry to one H(1), one S(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.
PHSF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PHSF2 clusters. P(1) is bonded in a 4-coordinate geometry to one H(1), one S(1), one F(1), and one F(2) atom. The P(1)-H(1) bond length is 1.41 Å. The P(1)-S(1) bond length is 1.89 Å. The P(1)-F(1) bond length is 1.58 Å. The P(1)-F(2) bond length is 1.58 Å. H(1) is bonded in a single-bond geometry to one P(1) atom. S(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.