CaLa2SbO6 is Ilmenite-derived structured and crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. O(1) is bonded to one Ca(1), two equivalent La(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCaLa2Sb trigonal pyramids.
CaLa2SbO6 is Ilmenite-derived structured and crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. All Ca(1)-O(1) bond lengths are 2.35 Å. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.36 Å) and three longer (2.71 Å) La(1)-O(1) bond lengths. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. All Sb(1)-O(1) bond lengths are 2.16 Å. O(1) is bonded to one Ca(1), two equivalent La(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCaLa2Sb trigonal pyramids.