TaFeO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ta(1) is bonded to six equivalent O(1) atoms to form TaO6 octahedra that share corners with six equivalent Ta(1)O6 octahedra and faces with eight equivalent Fe(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Fe(1) is bonded to twelve equivalent O(1) atoms to form FeO12 cuboctahedra that share corners with twelve equivalent Fe(1)O12 cuboctahedra, faces with six equivalent Fe(1)O12 cuboctahedra, and faces with eight equivalent Ta(1)O6 octahedra. O(1) is bonded in a linear geometry to two equivalent Ta(1) and four equivalent Fe(1) atoms.
TaFeO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ta(1) is bonded to six equivalent O(1) atoms to form TaO6 octahedra that share corners with six equivalent Ta(1)O6 octahedra and faces with eight equivalent Fe(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ta(1)-O(1) bond lengths are 1.99 Å. Fe(1) is bonded to twelve equivalent O(1) atoms to form FeO12 cuboctahedra that share corners with twelve equivalent Fe(1)O12 cuboctahedra, faces with six equivalent Fe(1)O12 cuboctahedra, and faces with eight equivalent Ta(1)O6 octahedra. All Fe(1)-O(1) bond lengths are 2.81 Å. O(1) is bonded in a linear geometry to two equivalent Ta(1) and four equivalent Fe(1) atoms.