LiAl2O6Br crystallizes in the hexagonal P6_3/mcm space group. Li(1) is bonded in a body-centered cubic geometry to six equivalent O(1) and two equivalent Br(1) atoms. Al(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Al(1), and one O(1) atom. Br(1) is bonded in a linear geometry to two equivalent Li(1) atoms.
LiAl2O6Br crystallizes in the hexagonal P6_3/mcm space group. Li(1) is bonded in a body-centered cubic geometry to six equivalent O(1) and two equivalent Br(1) atoms. All Li(1)-O(1) bond lengths are 2.46 Å. Both Li(1)-Br(1) bond lengths are 2.61 Å. Al(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Al(1)-O(1) bond lengths are 1.85 Å. O(1) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Al(1), and one O(1) atom. The O(1)-O(1) bond length is 1.73 Å. Br(1) is bonded in a linear geometry to two equivalent Li(1) atoms.