(FeF3)6N2 crystallizes in the hexagonal P6/mmm space group. The structure consists of one ammonia atom inside a FeF3 framework. In the FeF3 framework, Fe(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing FeF6 octahedra. The corner-sharing octahedral tilt angles range from 0-32°. There are two inequivalent F sites. In the first F site, F(2) is bonded in a linear geometry to two equivalent Fe(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Fe(1) atoms.
(FeF3)6N2 crystallizes in the hexagonal P6/mmm space group. The structure consists of one ammonia atom inside a FeF3 framework. In the FeF3 framework, Fe(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing FeF6 octahedra. The corner-sharing octahedral tilt angles range from 0-32°. Both Fe(1)-F(2) bond lengths are 1.95 Å. All Fe(1)-F(1) bond lengths are 1.96 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a linear geometry to two equivalent Fe(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Fe(1) atoms.