Mo3Te10I10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Mo3Te10I10 clusters. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 9-coordinate geometry to one Mo(2), one Mo(3), one Te(1), one Te(2), one Te(3), one Te(6), one Te(7), one Te(8), and one I(1) atom. In the second Mo site, Mo(2) is bonded in a 9-coordinate geometry to one Mo(1), one Mo(3), one Te(1), one Te(2), one Te(3), one Te(4), one Te(5), one Te(9), and one I(4) atom. In the third Mo site, Mo(3) is bonded in a 9-coordinate geometry to one Mo(1), one Mo(2), one Te(1), one Te(10), one Te(4), one Te(5), one Te(6), one Te(7), and one I(7) atom. There are ten inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one Mo(1), one Mo(2), one Te(3), and one I(10) atom. In the third Te site, Te(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Te(2) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one Mo(2), one Mo(3), one Te(5), and one I(10) atom. In the fifth Te site, Te(5) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(3), and one Te(4) atom. In the sixth Te site, Te(6) is bonded in a 4-coordinate geometry to one Mo(1), one Mo(3), one Te(7), and one I(10) atom. In the seventh Te site, Te(7) is bonded in a 4-coordinate geometry to one Mo(1), one Mo(3), one Te(6), and one Te(8) atom. In the eighth Te site, Te(8) is bonded in a 4-coordinate geometry to one Mo(1), one Te(7), one I(1), one I(2), and one I(3) atom. In the ninth Te site, Te(9) is bonded in a 4-coordinate geometry to one Mo(2), one I(4), one I(5), and one I(6) atom. In the tenth Te site, Te(10) is bonded in a 4-coordinate geometry to one Mo(3), one I(7), one I(8), and one I(9) atom. There are ten inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one Mo(1) and one Te(8) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Te(8) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Te(8) atom. In the fourth I site, I(4) is bonded in a 2-coordinate geometry to one Mo(2) and one Te(9) atom. In the fifth I site, I(5) is bonded in a single-bond geometry to one Te(9) atom. In the sixth I site, I(6) is bonded in a single-bond geometry to one Te(9) atom. In the seventh I site, I(7) is bonded in a 2-coordinate geometry to one Mo(3) and one Te(10) atom. In the eighth I site, I(8) is bonded in a single-bond geometry to one Te(10) atom. In the ninth I site, I(9) is bonded in a single-bond geometry to one Te(10) atom. In the tenth I site, I(10) is bonded in a 3-coordinate geometry to one Te(2), one Te(4), and one Te(6) atom.
Mo3Te10I10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Mo3Te10I10 clusters. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 9-coordinate geometry to one Mo(2), one Mo(3), one Te(1), one Te(2), one Te(3), one Te(6), one Te(7), one Te(8), and one I(1) atom. The Mo(1)-Mo(2) bond length is 2.83 Å. The Mo(1)-Mo(3) bond length is 2.83 Å. The Mo(1)-Te(1) bond length is 2.67 Å. The Mo(1)-Te(2) bond length is 2.77 Å. The Mo(1)-Te(3) bond length is 2.80 Å. The Mo(1)-Te(6) bond length is 2.75 Å. The Mo(1)-Te(7) bond length is 2.86 Å. The Mo(1)-Te(8) bond length is 2.81 Å. The Mo(1)-I(1) bond length is 2.92 Å. In the second Mo site, Mo(2) is bonded in a 9-coordinate geometry to one Mo(1), one Mo(3), one Te(1), one Te(2), one Te(3), one Te(4), one Te(5), one Te(9), and one I(4) atom. The Mo(2)-Mo(3) bond length is 2.83 Å. The Mo(2)-Te(1) bond length is 2.67 Å. The Mo(2)-Te(2) bond length is 2.75 Å. The Mo(2)-Te(3) bond length is 2.87 Å. The Mo(2)-Te(4) bond length is 2.77 Å. The Mo(2)-Te(5) bond length is 2.80 Å. The Mo(2)-Te(9) bond length is 2.80 Å. The Mo(2)-I(4) bond length is 2.93 Å. In the third Mo site, Mo(3) is bonded in a 9-coordinate geometry to one Mo(1), one Mo(2), one Te(1), one Te(10), one Te(4), one Te(5), one Te(6), one Te(7), and one I(7) atom. The Mo(3)-Te(1) bond length is 2.67 Å. The Mo(3)-Te(10) bond length is 2.81 Å. The Mo(3)-Te(4) bond length is 2.74 Å. The Mo(3)-Te(5) bond length is 2.87 Å. The Mo(3)-Te(6) bond length is 2.77 Å. The Mo(3)-Te(7) bond length is 2.80 Å. The Mo(3)-I(7) bond length is 2.92 Å. There are ten inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(3) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one Mo(1), one Mo(2), one Te(3), and one I(10) atom. The Te(2)-Te(3) bond length is 2.72 Å. The Te(2)-I(10) bond length is 3.29 Å. In the third Te site, Te(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Te(2) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one Mo(2), one Mo(3), one Te(5), and one I(10) atom. The Te(4)-Te(5) bond length is 2.73 Å. The Te(4)-I(10) bond length is 3.33 Å. In the fifth Te site, Te(5) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(3), and one Te(4) atom. In the sixth Te site, Te(6) is bonded in a 4-coordinate geometry to one Mo(1), one Mo(3), one Te(7), and one I(10) atom. The Te(6)-Te(7) bond length is 2.72 Å. The Te(6)-I(10) bond length is 3.34 Å. In the seventh Te site, Te(7) is bonded in a 4-coordinate geometry to one Mo(1), one Mo(3), one Te(6), and one Te(8) atom. The Te(7)-Te(8) bond length is 3.38 Å. In the eighth Te site, Te(8) is bonded in a 4-coordinate geometry to one Mo(1), one Te(7), one I(1), one I(2), and one I(3) atom. The Te(8)-I(1) bond length is 3.02 Å. The Te(8)-I(2) bond length is 2.78 Å. The Te(8)-I(3) bond length is 2.87 Å. In the ninth Te site, Te(9) is bonded in a 4-coordinate geometry to one Mo(2), one I(4), one I(5), and one I(6) atom. The Te(9)-I(4) bond length is 3.04 Å. The Te(9)-I(5) bond length is 2.79 Å. The Te(9)-I(6) bond length is 2.85 Å. In the tenth Te site, Te(10) is bonded in a 4-coordinate geometry to one Mo(3), one I(7), one I(8), and one I(9) atom. The Te(10)-I(7) bond length is 3.03 Å. The Te(10)-I(8) bond length is 2.79 Å. The Te(10)-I(9) bond length is 2.86 Å. There are ten inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one Mo(1) and one Te(8) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Te(8) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Te(8) atom. In the fourth I site, I(4) is bonded in a 2-coordinate geometry to one Mo(2) and one Te(9) atom. In the fifth I site, I(5) is bonded in a single-bond geometry to one Te(9) atom. In the sixth I site, I(6) is bonded in a single-bond geometry to one Te(9) atom. In the seventh I site, I(7) is bonded in a 2-coordinate geometry to one Mo(3) and one Te(10) atom. In the eighth I site, I(8) is bonded in a single-bond geometry to one Te(10) atom. In the ninth I site, I(9) is bonded in a single-bond geometry to one Te(10) atom. In the tenth I site, I(10) is bonded in a 3-coordinate geometry to one Te(2), one Te(4), and one Te(6) atom.