SbF6ClF4 is Indium-derived structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four ClF4 clusters and four SbF6 clusters. In each ClF4 cluster, Cl(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(7,8) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(7,8) is bonded in a single-bond geometry to one Cl(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(6), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.
SbF6ClF4 is Indium-derived structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four ClF4 clusters and four SbF6 clusters. In each ClF4 cluster, Cl(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(7,8) atoms. Both Cl(1)-F(1) bond lengths are 1.66 Å. Both Cl(1)-F(7,8) bond lengths are 1.56 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(7,8) is bonded in a single-bond geometry to one Cl(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(6), and two equivalent F(5) atoms. The Sb(1)-F(2) bond length is 1.93 Å. The Sb(1)-F(3) bond length is 1.88 Å. The Sb(1)-F(4) bond length is 1.93 Å. The Sb(1)-F(6) bond length is 1.88 Å. Both Sb(1)-F(5) bond lengths are 1.88 Å. There are five inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.