NaZr2AgF11 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Zr(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. Ag(1) is bonded in a distorted square co-planar geometry to two equivalent F(3) and two equivalent F(4) atoms. There are six inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Na(1) and one Zr(1) atom. In the second F site, F(2) is bonded in a distorted water-like geometry to one Na(1) and one Zr(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Na(1), one Zr(1), and one Ag(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Zr(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Zr(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Zr(1) atoms.
NaZr2AgF11 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Na(1)-F(1) bond lengths are 2.79 Å. Both Na(1)-F(2) bond lengths are 2.34 Å. Both Na(1)-F(3) bond lengths are 2.34 Å. Zr(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Zr(1)-F(1) bond length is 2.54 Å. The Zr(1)-F(2) bond length is 1.67 Å. The Zr(1)-F(3) bond length is 2.42 Å. The Zr(1)-F(4) bond length is 1.85 Å. The Zr(1)-F(5) bond length is 2.61 Å. The Zr(1)-F(6) bond length is 2.17 Å. Ag(1) is bonded in a distorted square co-planar geometry to two equivalent F(3) and two equivalent F(4) atoms. Both Ag(1)-F(3) bond lengths are 2.51 Å. Both Ag(1)-F(4) bond lengths are 1.78 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Na(1) and one Zr(1) atom. In the second F site, F(2) is bonded in a distorted water-like geometry to one Na(1) and one Zr(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Na(1), one Zr(1), and one Ag(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Zr(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Zr(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Zr(1) atoms.