(WO3)6Tl crystallizes in the trigonal P31m space group. The structure consists of one 7440-28-0 atom inside a WO3 framework. In the WO3 framework, there are two inequivalent W sites. In the first W site, W(1) is bonded to one O(3), one O(4), and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-29°. In the second W site, W(2) is bonded to one O(3), one O(4), and four equivalent O(1) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-29°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(2) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one W(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one W(2) atom.
(WO3)6Tl crystallizes in the trigonal P31m space group. The structure consists of one 7440-28-0 atom inside a WO3 framework. In the WO3 framework, there are two inequivalent W sites. In the first W site, W(1) is bonded to one O(3), one O(4), and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-29°. The W(1)-O(3) bond length is 1.92 Å. The W(1)-O(4) bond length is 1.92 Å. There are two shorter (1.84 Å) and two longer (2.05 Å) W(1)-O(2) bond lengths. In the second W site, W(2) is bonded to one O(3), one O(4), and four equivalent O(1) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-29°. The W(2)-O(3) bond length is 1.93 Å. The W(2)-O(4) bond length is 1.90 Å. There are two shorter (1.84 Å) and two longer (2.05 Å) W(2)-O(1) bond lengths. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(2) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one W(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one W(2) atom.