TiAu4 crystallizes in the tetragonal I4/m space group. Ti(1) is bonded to twelve equivalent Au(1) atoms to form a mixture of edge and face-sharing TiAu12 cuboctahedra. Au(1) is bonded in a 3-coordinate geometry to three equivalent Ti(1) atoms.
TiAu4 crystallizes in the tetragonal I4/m space group. Ti(1) is bonded to twelve equivalent Au(1) atoms to form a mixture of edge and face-sharing TiAu12 cuboctahedra. There are eight shorter (2.84 Å) and four longer (2.92 Å) Ti(1)-Au(1) bond lengths. Au(1) is bonded in a 3-coordinate geometry to three equivalent Ti(1) atoms.