N2(SO3F)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four SO3F clusters. In each SO3F cluster, S(1) is bonded in a tetrahedral geometry to one O(1), two equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom.
N2(SO3F)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four SO3F clusters. In each SO3F cluster, S(1) is bonded in a tetrahedral geometry to one O(1), two equivalent O(2), and one F(1) atom. The S(1)-O(1) bond length is 1.45 Å. Both S(1)-O(2) bond lengths are 1.46 Å. The S(1)-F(1) bond length is 1.60 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom.