NdNiSnH crystallizes in the orthorhombic Pnma space group. Nd(1) is bonded in a 3-coordinate geometry to six equivalent Sn(1) and three equivalent H(1) atoms. Ni(1) is bonded in a single-bond geometry to four equivalent Sn(1) and one H(1) atom. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1) and four equivalent Ni(1) atoms. H(1) is bonded to three equivalent Nd(1) and one Ni(1) atom to form a mixture of edge and corner-sharing HNd3Ni tetrahedra.
NdNiSnH crystallizes in the orthorhombic Pnma space group. Nd(1) is bonded in a 3-coordinate geometry to six equivalent Sn(1) and three equivalent H(1) atoms. There are a spread of Nd(1)-Sn(1) bond distances ranging from 3.25-3.39 Å. There is one shorter (2.31 Å) and two longer (2.43 Å) Nd(1)-H(1) bond lengths. Ni(1) is bonded in a single-bond geometry to four equivalent Sn(1) and one H(1) atom. There are a spread of Ni(1)-Sn(1) bond distances ranging from 2.65-2.94 Å. The Ni(1)-H(1) bond length is 1.60 Å. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1) and four equivalent Ni(1) atoms. H(1) is bonded to three equivalent Nd(1) and one Ni(1) atom to form a mixture of edge and corner-sharing HNd3Ni tetrahedra.