LiRuRhO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Ru(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-60°. Ru(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Ru(1)O6 octahedra, and edges with four equivalent Rh(1)O6 octahedra. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Rh(1)O6 octahedra, and edges with four equivalent Ru(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Ru(1), and one Rh(1) atom to form distorted OLiRu2Rh trigonal pyramids that share corners with six equivalent O(1)LiRu2Rh trigonal pyramids, corners with six equivalent O(2)LiRuRh2 trigonal pyramids,  an edgeedge with one O(1)LiRu2Rh trigonal pyramid, and edges with two equivalent O(2)LiRuRh2 trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one Ru(1), and two equivalent Rh(1) atoms to form distorted OLiRuRh2 trigonal pyramids that share corners with six equivalent O(1)LiRu2Rh trigonal pyramids, corners with six equivalent O(2)LiRuRh2 trigonal pyramids,  an edgeedge with one O(2)LiRuRh2 trigonal pyramid, and edges with two equivalent O(1)LiRu2Rh trigonal pyramids.
LiRuRhO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Ru(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-60°. Both Li(1)-O(1) bond lengths are 2.02 Å. Both Li(1)-O(2) bond lengths are 2.00 Å. Ru(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Ru(1)O6 octahedra, and edges with four equivalent Rh(1)O6 octahedra. Both Ru(1)-O(2) bond lengths are 2.03 Å. All Ru(1)-O(1) bond lengths are 2.05 Å. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Rh(1)O6 octahedra, and edges with four equivalent Ru(1)O6 octahedra. Both Rh(1)-O(1) bond lengths are 2.08 Å. All Rh(1)-O(2) bond lengths are 2.07 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Ru(1), and one Rh(1) atom to form distorted OLiRu2Rh trigonal pyramids that share corners with six equivalent O(1)LiRu2Rh trigonal pyramids, corners with six equivalent O(2)LiRuRh2 trigonal pyramids,  an edgeedge with one O(1)LiRu2Rh trigonal pyramid, and edges with two equivalent O(2)LiRuRh2 trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one Ru(1), and two equivalent Rh(1) atoms to form distorted OLiRuRh2 trigonal pyramids that share corners with six equivalent O(1)LiRu2Rh trigonal pyramids, corners with six equivalent O(2)LiRuRh2 trigonal pyramids,  an edgeedge with one O(2)LiRuRh2 trigonal pyramid, and edges with two equivalent O(1)LiRu2Rh trigonal pyramids.