Li10Ge(PO6)2 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are twenty inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(17), one O(18), one O(3), one O(4), and one O(9) atom. In the second Li site, Li(2) is bonded in a 3-coordinate geometry to one O(12), one O(19), one O(2), and one O(20) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(21), one O(22), one O(7), and one O(8) atom. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(23), one O(24), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(9)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Li(13)O4 tetrahedra,  an edgeedge with one Li(5)O4 tetrahedra,  an edgeedge with one Ge(2)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. In the fifth Li site, Li(5) is bonded to one O(20), one O(24), one O(6), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Ge(1)O4 tetrahedra. In the sixth Li site, Li(6) is bonded in a 3-coordinate geometry to one O(13), one O(19), and one O(23) atom. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(15), one O(17), one O(22), and one O(7) atom. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(10), one O(13), one O(2), one O(20), and one O(24) atom. In the ninth Li site, Li(9) is bonded to one O(1), one O(14), one O(19), and one O(23) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the tenth Li site, Li(10) is bonded to one O(11), one O(21), one O(22), one O(3), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent Ge(2)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the eleventh Li site, Li(11) is bonded in a 3-coordinate geometry to one O(1), one O(14), one O(20), and one O(24) atom. In the twelfth Li site, Li(12) is bonded in a 3-coordinate geometry to one O(16), one O(18), one O(4), and one O(9) atom. In the thirteenth Li site, Li(13) is bonded to one O(10), one O(15), one O(3), and one O(5) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the fourteenth Li site, Li(14) is bonded in a 3-coordinate geometry to one O(16), one O(23), one O(6), and one O(9) atom. In the fifteenth Li site, Li(15) is bonded to one O(12), one O(17), one O(22), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one P(3)O4 tetrahedra. In the sixteenth Li site, Li(16) is bonded in a distorted rectangular see-saw-like geometry to one O(15), one O(18), one O(3), and one O(9) atom. In the seventeenth Li site, Li(17) is bonded in a 4-coordinate geometry to one O(10), one O(16), one O(4), and one O(5) atom. In the eighteenth Li site, Li(18) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(2), and one O(7) atom. In the nineteenth Li site, Li(19) is bonded in a 4-coordinate geometry to one O(12), one O(18), one O(21), and one O(8) atom. In the twentieth Li site, Li(20) is bonded in a 4-coordinate geometry to one O(11), one O(18), one O(21), and one O(7) atom. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(10), one O(19), one O(20), and one O(9) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra, and  an edgeedge with one Li(5)O4 tetrahedra. In the second Ge site, Ge(2) is bonded to one O(15), one O(16), one O(21), and one O(22) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra, corners with two equivalent Li(10)O5 trigonal bipyramids, and  an edgeedge with one Li(4)O6 octahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(15)O4 tetrahedra and  a cornercorner with one Li(9)O4 tetrahedra. In the second P site, P(2) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Li(4)O6 octahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Li(13)O4 tetrahedra, and  an edgeedge with one Li(10)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 34-38°. In the third P site, P(3) is bonded to one O(11), one O(12), one O(17), and one O(18) atom to form PO4 tetrahedra that share  a cornercorner with one Li(10)O5 trigonal bipyramid and  an edgeedge with one Li(15)O4 tetrahedra. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Li(9)O4 tetrahedra. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(11), one Li(9), and one P(1) atom. In the second O site, O(2) is bonded to one Li(18), one Li(2), one Li(8), and one P(1) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(19)Li3Ge trigonal pyramid, and  an edgeedge with one O(13)Li4P trigonal bipyramid. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Li(10), one Li(13), one Li(16), and one P(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one Li(10), one Li(12), one Li(17), and one P(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(13), one Li(17), one Li(4), and one P(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(14), one Li(4), one Li(5), and one P(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(18), one Li(20), one Li(3), one Li(7), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(15), one Li(19), one Li(3), and one P(1) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Li(1), one Li(12), one Li(14), one Li(16), one Li(5), and one Ge(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one Li(13), one Li(17), one Li(8), and one Ge(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(10), one Li(18), one Li(20), and one P(3) atom. In the twelfth O site, O(12) is bonded to one Li(15), one Li(19), one Li(2), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(22)Li4Ge trigonal bipyramid,  a cornercorner with one O(19)Li3Ge trigonal pyramid,  a cornercorner with one O(2)Li3P trigonal pyramid, and  an edgeedge with one O(17)Li3P tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(18), one Li(3), one Li(6), one Li(8), and one P(4) atom to form distorted OLi4P trigonal bipyramids that share  a cornercorner with one O(22)Li4Ge trigonal bipyramid,  a cornercorner with one O(19)Li3Ge trigonal pyramid,  an edgeedge with one O(23)Li4P trigonal bipyramid,  an edgeedge with one O(14)Li3P trigonal pyramid, and  an edgeedge with one O(2)Li3P trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(11), one Li(3), one Li(9), and one P(4) atom to form OLi3P trigonal pyramids that share  a cornercorner with one O(22)Li4Ge trigonal bipyramid,  a cornercorner with one O(19)Li3Ge trigonal pyramid,  an edgeedge with one O(13)Li4P trigonal bipyramid, and  an edgeedge with one O(23)Li4P trigonal bipyramid. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(16), one Li(4), one Li(7), and one Ge(2) atom to form distorted OLi4Ge trigonal bipyramids that share  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(23)Li4P trigonal bipyramid, and  an edgeedge with one O(22)Li4Ge trigonal bipyramid. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Li(12), one Li(14), one Li(17), one Li(4), and one Ge(2) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(15), one Li(7), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(15)Li4Ge trigonal bipyramid, corners with two equivalent O(22)Li4Ge trigonal bipyramids, and  an edgeedge with one O(12)Li3P tetrahedra. In the eighteenth O site, O(18) is bonded in a 6-coordinate geometry to one Li(1), one Li(12), one Li(16), one Li(19), one Li(20), and one P(3) atom. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(6), one Li(9), and one Ge(1) atom to form distorted OLi3Ge trigonal pyramids that share  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(13)Li4P trigonal bipyramid, corners with two equivalent O(23)Li4P trigonal bipyramids,  a cornercorner with one O(14)Li3P trigonal pyramid, and  a cornercorner with one O(2)Li3P trigonal pyramid. In the twentieth O site, O(20) is bonded in a 5-coordinate geometry to one Li(11), one Li(2), one Li(5), one Li(8), and one Ge(1) atom. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to one Li(10), one Li(19), one Li(20), one Li(3), and one Ge(2) atom. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(15), one Li(3), one Li(7), and one Ge(2) atom to form distorted OLi4Ge trigonal bipyramids that share  a cornercorner with one O(12)Li3P tetrahedra, corners with two equivalent O(17)Li3P tetrahedra,  a cornercorner with one O(13)Li4P trigonal bipyramid,  a cornercorner with one O(14)Li3P trigonal pyramid, and  an edgeedge with one O(15)Li4Ge trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Li(14), one Li(4), one Li(6), one Li(9), and one P(4) atom to form distorted OLi4P trigonal bipyramids that share  a cornercorner with one O(15)Li4Ge trigonal bipyramid, corners with two equivalent O(19)Li3Ge trigonal pyramids,  an edgeedge with one O(13)Li4P trigonal bipyramid, and  an edgeedge with one O(14)Li3P trigonal pyramid. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Li(11), one Li(4), one Li(5), one Li(8), and one P(4) atom.
Li10Ge(PO6)2 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are twenty inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(17), one O(18), one O(3), one O(4), and one O(9) atom. The Li(1)-O(10) bond length is 2.01 Å. The Li(1)-O(17) bond length is 1.99 Å. The Li(1)-O(18) bond length is 2.36 Å. The Li(1)-O(3) bond length is 2.47 Å. The Li(1)-O(4) bond length is 2.13 Å. The Li(1)-O(9) bond length is 2.16 Å. In the second Li site, Li(2) is bonded in a 3-coordinate geometry to one O(12), one O(19), one O(2), and one O(20) atom. The Li(2)-O(12) bond length is 1.98 Å. The Li(2)-O(19) bond length is 1.98 Å. The Li(2)-O(2) bond length is 1.94 Å. The Li(2)-O(20) bond length is 2.40 Å. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(21), one O(22), one O(7), and one O(8) atom. The Li(3)-O(13) bond length is 2.13 Å. The Li(3)-O(14) bond length is 2.15 Å. The Li(3)-O(21) bond length is 2.38 Å. The Li(3)-O(22) bond length is 2.03 Å. The Li(3)-O(7) bond length is 2.57 Å. The Li(3)-O(8) bond length is 2.03 Å. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(23), one O(24), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(9)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Li(13)O4 tetrahedra,  an edgeedge with one Li(5)O4 tetrahedra,  an edgeedge with one Ge(2)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. The Li(4)-O(15) bond length is 2.28 Å. The Li(4)-O(16) bond length is 2.06 Å. The Li(4)-O(23) bond length is 2.32 Å. The Li(4)-O(24) bond length is 2.14 Å. The Li(4)-O(5) bond length is 2.08 Å. The Li(4)-O(6) bond length is 2.30 Å. In the fifth Li site, Li(5) is bonded to one O(20), one O(24), one O(6), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Ge(1)O4 tetrahedra. The Li(5)-O(20) bond length is 1.97 Å. The Li(5)-O(24) bond length is 1.91 Å. The Li(5)-O(6) bond length is 1.89 Å. The Li(5)-O(9) bond length is 2.24 Å. In the sixth Li site, Li(6) is bonded in a 3-coordinate geometry to one O(13), one O(19), and one O(23) atom. The Li(6)-O(13) bond length is 2.02 Å. The Li(6)-O(19) bond length is 1.88 Å. The Li(6)-O(23) bond length is 2.10 Å. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(15), one O(17), one O(22), and one O(7) atom. The Li(7)-O(15) bond length is 2.01 Å. The Li(7)-O(17) bond length is 1.87 Å. The Li(7)-O(22) bond length is 2.29 Å. The Li(7)-O(7) bond length is 1.93 Å. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(10), one O(13), one O(2), one O(20), and one O(24) atom. The Li(8)-O(10) bond length is 2.51 Å. The Li(8)-O(13) bond length is 2.32 Å. The Li(8)-O(2) bond length is 2.09 Å. The Li(8)-O(20) bond length is 2.00 Å. The Li(8)-O(24) bond length is 2.02 Å. In the ninth Li site, Li(9) is bonded to one O(1), one O(14), one O(19), and one O(23) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. The Li(9)-O(1) bond length is 1.96 Å. The Li(9)-O(14) bond length is 2.08 Å. The Li(9)-O(19) bond length is 1.90 Å. The Li(9)-O(23) bond length is 2.08 Å. In the tenth Li site, Li(10) is bonded to one O(11), one O(21), one O(22), one O(3), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent Ge(2)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The Li(10)-O(11) bond length is 2.36 Å. The Li(10)-O(21) bond length is 2.25 Å. The Li(10)-O(22) bond length is 2.06 Å. The Li(10)-O(3) bond length is 1.98 Å. The Li(10)-O(4) bond length is 2.45 Å. In the eleventh Li site, Li(11) is bonded in a 3-coordinate geometry to one O(1), one O(14), one O(20), and one O(24) atom. The Li(11)-O(1) bond length is 1.92 Å. The Li(11)-O(14) bond length is 2.02 Å. The Li(11)-O(20) bond length is 1.90 Å. The Li(11)-O(24) bond length is 2.50 Å. In the twelfth Li site, Li(12) is bonded in a 3-coordinate geometry to one O(16), one O(18), one O(4), and one O(9) atom. The Li(12)-O(16) bond length is 1.92 Å. The Li(12)-O(18) bond length is 2.00 Å. The Li(12)-O(4) bond length is 1.99 Å. The Li(12)-O(9) bond length is 2.46 Å. In the thirteenth Li site, Li(13) is bonded to one O(10), one O(15), one O(3), and one O(5) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Ge(1)O4 tetrahedra,  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The Li(13)-O(10) bond length is 1.95 Å. The Li(13)-O(15) bond length is 1.94 Å. The Li(13)-O(3) bond length is 2.13 Å. The Li(13)-O(5) bond length is 2.09 Å. In the fourteenth Li site, Li(14) is bonded in a 3-coordinate geometry to one O(16), one O(23), one O(6), and one O(9) atom. The Li(14)-O(16) bond length is 2.40 Å. The Li(14)-O(23) bond length is 2.01 Å. The Li(14)-O(6) bond length is 1.99 Å. The Li(14)-O(9) bond length is 2.00 Å. In the fifteenth Li site, Li(15) is bonded to one O(12), one O(17), one O(22), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Ge(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one Li(10)O5 trigonal bipyramid, and  an edgeedge with one P(3)O4 tetrahedra. The Li(15)-O(12) bond length is 2.07 Å. The Li(15)-O(17) bond length is 2.02 Å. The Li(15)-O(22) bond length is 1.94 Å. The Li(15)-O(8) bond length is 1.94 Å. In the sixteenth Li site, Li(16) is bonded in a distorted rectangular see-saw-like geometry to one O(15), one O(18), one O(3), and one O(9) atom. The Li(16)-O(15) bond length is 1.92 Å. The Li(16)-O(18) bond length is 2.02 Å. The Li(16)-O(3) bond length is 2.16 Å. The Li(16)-O(9) bond length is 2.01 Å. In the seventeenth Li site, Li(17) is bonded in a 4-coordinate geometry to one O(10), one O(16), one O(4), and one O(5) atom. The Li(17)-O(10) bond length is 1.96 Å. The Li(17)-O(16) bond length is 1.91 Å. The Li(17)-O(4) bond length is 2.19 Å. The Li(17)-O(5) bond length is 2.16 Å. In the eighteenth Li site, Li(18) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(2), and one O(7) atom. The Li(18)-O(11) bond length is 2.05 Å. The Li(18)-O(13) bond length is 2.01 Å. The Li(18)-O(2) bond length is 2.13 Å. The Li(18)-O(7) bond length is 2.13 Å. In the nineteenth Li site, Li(19) is bonded in a 4-coordinate geometry to one O(12), one O(18), one O(21), and one O(8) atom. The Li(19)-O(12) bond length is 1.96 Å. The Li(19)-O(18) bond length is 2.50 Å. The Li(19)-O(21) bond length is 1.92 Å. The Li(19)-O(8) bond length is 2.00 Å. In the twentieth Li site, Li(20) is bonded in a 4-coordinate geometry to one O(11), one O(18), one O(21), and one O(7) atom. The Li(20)-O(11) bond length is 1.98 Å. The Li(20)-O(18) bond length is 2.39 Å. The Li(20)-O(21) bond length is 1.94 Å. The Li(20)-O(7) bond length is 1.93 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(10), one O(19), one O(20), and one O(9) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra, and  an edgeedge with one Li(5)O4 tetrahedra. The Ge(1)-O(10) bond length is 1.78 Å. The Ge(1)-O(19) bond length is 1.77 Å. The Ge(1)-O(20) bond length is 1.78 Å. The Ge(1)-O(9) bond length is 1.80 Å. In the second Ge site, Ge(2) is bonded to one O(15), one O(16), one O(21), and one O(22) atom to form GeO4 tetrahedra that share  a cornercorner with one Li(13)O4 tetrahedra,  a cornercorner with one Li(15)O4 tetrahedra, corners with two equivalent Li(10)O5 trigonal bipyramids, and  an edgeedge with one Li(4)O6 octahedra. The Ge(2)-O(15) bond length is 1.79 Å. The Ge(2)-O(16) bond length is 1.77 Å. The Ge(2)-O(21) bond length is 1.80 Å. The Ge(2)-O(22) bond length is 1.80 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(15)O4 tetrahedra and  a cornercorner with one Li(9)O4 tetrahedra. The P(1)-O(1) bond length is 1.55 Å. The P(1)-O(2) bond length is 1.56 Å. The P(1)-O(7) bond length is 1.57 Å. The P(1)-O(8) bond length is 1.56 Å. In the second P site, P(2) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Li(4)O6 octahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Li(13)O4 tetrahedra, and  an edgeedge with one Li(10)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 34-38°. The P(2)-O(3) bond length is 1.57 Å. The P(2)-O(4) bond length is 1.57 Å. The P(2)-O(5) bond length is 1.56 Å. The P(2)-O(6) bond length is 1.55 Å. In the third P site, P(3) is bonded to one O(11), one O(12), one O(17), and one O(18) atom to form PO4 tetrahedra that share  a cornercorner with one Li(10)O5 trigonal bipyramid and  an edgeedge with one Li(15)O4 tetrahedra. The P(3)-O(11) bond length is 1.57 Å. The P(3)-O(12) bond length is 1.56 Å. The P(3)-O(17) bond length is 1.55 Å. The P(3)-O(18) bond length is 1.56 Å. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Li(9)O4 tetrahedra. The P(4)-O(13) bond length is 1.57 Å. The P(4)-O(14) bond length is 1.56 Å. The P(4)-O(23) bond length is 1.57 Å. The P(4)-O(24) bond length is 1.55 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(11), one Li(9), and one P(1) atom. In the second O site, O(2) is bonded to one Li(18), one Li(2), one Li(8), and one P(1) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(19)Li3Ge trigonal pyramid, and  an edgeedge with one O(13)Li4P trigonal bipyramid. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Li(10), one Li(13), one Li(16), and one P(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one Li(10), one Li(12), one Li(17), and one P(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(13), one Li(17), one Li(4), and one P(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(14), one Li(4), one Li(5), and one P(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(18), one Li(20), one Li(3), one Li(7), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(15), one Li(19), one Li(3), and one P(1) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Li(1), one Li(12), one Li(14), one Li(16), one Li(5), and one Ge(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one Li(13), one Li(17), one Li(8), and one Ge(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(10), one Li(18), one Li(20), and one P(3) atom. In the twelfth O site, O(12) is bonded to one Li(15), one Li(19), one Li(2), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(22)Li4Ge trigonal bipyramid,  a cornercorner with one O(19)Li3Ge trigonal pyramid,  a cornercorner with one O(2)Li3P trigonal pyramid, and  an edgeedge with one O(17)Li3P tetrahedra. In the thirteenth O site, O(13) is bonded to one Li(18), one Li(3), one Li(6), one Li(8), and one P(4) atom to form distorted OLi4P trigonal bipyramids that share  a cornercorner with one O(22)Li4Ge trigonal bipyramid,  a cornercorner with one O(19)Li3Ge trigonal pyramid,  an edgeedge with one O(23)Li4P trigonal bipyramid,  an edgeedge with one O(14)Li3P trigonal pyramid, and  an edgeedge with one O(2)Li3P trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(11), one Li(3), one Li(9), and one P(4) atom to form OLi3P trigonal pyramids that share  a cornercorner with one O(22)Li4Ge trigonal bipyramid,  a cornercorner with one O(19)Li3Ge trigonal pyramid,  an edgeedge with one O(13)Li4P trigonal bipyramid, and  an edgeedge with one O(23)Li4P trigonal bipyramid. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(16), one Li(4), one Li(7), and one Ge(2) atom to form distorted OLi4Ge trigonal bipyramids that share  a cornercorner with one O(17)Li3P tetrahedra,  a cornercorner with one O(23)Li4P trigonal bipyramid, and  an edgeedge with one O(22)Li4Ge trigonal bipyramid. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Li(12), one Li(14), one Li(17), one Li(4), and one Ge(2) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(15), one Li(7), and one P(3) atom to form OLi3P tetrahedra that share  a cornercorner with one O(15)Li4Ge trigonal bipyramid, corners with two equivalent O(22)Li4Ge trigonal bipyramids, and  an edgeedge with one O(12)Li3P tetrahedra. In the eighteenth O site, O(18) is bonded in a 6-coordinate geometry to one Li(1), one Li(12), one Li(16), one Li(19), one Li(20), and one P(3) atom. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(6), one Li(9), and one Ge(1) atom to form distorted OLi3Ge trigonal pyramids that share  a cornercorner with one O(12)Li3P tetrahedra,  a cornercorner with one O(13)Li4P trigonal bipyramid, corners with two equivalent O(23)Li4P trigonal bipyramids,  a cornercorner with one O(14)Li3P trigonal pyramid, and  a cornercorner with one O(2)Li3P trigonal pyramid. In the twentieth O site, O(20) is bonded in a 5-coordinate geometry to one Li(11), one Li(2), one Li(5), one Li(8), and one Ge(1) atom. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to one Li(10), one Li(19), one Li(20), one Li(3), and one Ge(2) atom. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(15), one Li(3), one Li(7), and one Ge(2) atom to form distorted OLi4Ge trigonal bipyramids that share  a cornercorner with one O(12)Li3P tetrahedra, corners with two equivalent O(17)Li3P tetrahedra,  a cornercorner with one O(13)Li4P trigonal bipyramid,  a cornercorner with one O(14)Li3P trigonal pyramid, and  an edgeedge with one O(15)Li4Ge trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Li(14), one Li(4), one Li(6), one Li(9), and one P(4) atom to form distorted OLi4P trigonal bipyramids that share  a cornercorner with one O(15)Li4Ge trigonal bipyramid, corners with two equivalent O(19)Li3Ge trigonal pyramids,  an edgeedge with one O(13)Li4P trigonal bipyramid, and  an edgeedge with one O(14)Li3P trigonal pyramid. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Li(11), one Li(4), one Li(5), one Li(8), and one P(4) atom.