CeGeO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. Ge(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Ce(1) and two equivalent Ge(1) atoms to form a mixture of distorted corner and edge-sharing OCe3Ge2 trigonal bipyramids.
CeGeO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. There are two shorter (2.37 Å) and four longer (2.40 Å) Ce(1)-O(1) bond lengths. Ge(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Ge(1)-O(1) bond lengths are 2.48 Å. O(1) is bonded to three equivalent Ce(1) and two equivalent Ge(1) atoms to form a mixture of distorted corner and edge-sharing OCe3Ge2 trigonal bipyramids.