Mn4O7F is Hydrophilite-derived structured and crystallizes in the monoclinic Cc space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(5), two equivalent O(1), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), two equivalent O(7), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. In the third Mn site, Mn(3) is bonded to one O(2), one O(4), one O(6), two equivalent O(5), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the fourth Mn site, Mn(4) is bonded to one O(2), one O(3), one O(4), one O(7), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-52°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(3) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(4) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(4) and two equivalent Mn(2) atoms. F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom.
Mn4O7F is Hydrophilite-derived structured and crystallizes in the monoclinic Cc space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(5), two equivalent O(1), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-55°. The Mn(1)-O(2) bond length is 1.95 Å. The Mn(1)-O(3) bond length is 1.97 Å. The Mn(1)-O(5) bond length is 1.92 Å. Both Mn(1)-O(1) bond lengths are 1.97 Å. The Mn(1)-F(1) bond length is 2.03 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), two equivalent O(7), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. The Mn(2)-O(1) bond length is 1.97 Å. The Mn(2)-O(3) bond length is 1.95 Å. The Mn(2)-O(4) bond length is 1.96 Å. There is one shorter (1.93 Å) and one longer (1.96 Å) Mn(2)-O(7) bond length. The Mn(2)-F(1) bond length is 2.16 Å. In the third Mn site, Mn(3) is bonded to one O(2), one O(4), one O(6), two equivalent O(5), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. The Mn(3)-O(2) bond length is 1.95 Å. The Mn(3)-O(4) bond length is 1.92 Å. The Mn(3)-O(6) bond length is 1.93 Å. There is one shorter (1.90 Å) and one longer (1.97 Å) Mn(3)-O(5) bond length. The Mn(3)-F(1) bond length is 2.01 Å. In the fourth Mn site, Mn(4) is bonded to one O(2), one O(3), one O(4), one O(7), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O6 octahedra,  an edgeedge with one Mn(2)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-52°. The Mn(4)-O(2) bond length is 2.01 Å. The Mn(4)-O(3) bond length is 1.96 Å. The Mn(4)-O(4) bond length is 1.94 Å. The Mn(4)-O(7) bond length is 1.92 Å. There is one shorter (1.96 Å) and one longer (2.01 Å) Mn(4)-O(6) bond length. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(3) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(4) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(4) and two equivalent Mn(2) atoms. F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom.