Ti(MnN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one N(4), and two equivalent N(2) atoms. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form MnN4 trigonal pyramids that share  a cornercorner with one Mn(3)N5 square pyramid, corners with three equivalent Mn(4)N5 square pyramids, corners with four equivalent Mn(2)N4 trigonal pyramids,  an edgeedge with one Mn(4)N5 square pyramid, and edges with two equivalent Mn(3)N5 square pyramids. In the second Mn site, Mn(2) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form distorted MnN4 trigonal pyramids that share corners with two equivalent Mn(3)N5 square pyramids, corners with two equivalent Mn(4)N5 square pyramids, corners with four equivalent Mn(1)N4 trigonal pyramids, and edges with two equivalent Mn(2)N4 trigonal pyramids. In the third Mn site, Mn(3) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form MnN5 square pyramids that share corners with three equivalent Mn(4)N5 square pyramids,  a cornercorner with one Mn(1)N4 trigonal pyramid, corners with two equivalent Mn(2)N4 trigonal pyramids, edges with two equivalent Mn(3)N5 square pyramids, edges with three equivalent Mn(4)N5 square pyramids, and edges with two equivalent Mn(1)N4 trigonal pyramids. In the fourth Mn site, Mn(4) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form MnN5 square pyramids that share corners with three equivalent Mn(3)N5 square pyramids, corners with two equivalent Mn(2)N4 trigonal pyramids, corners with three equivalent Mn(1)N4 trigonal pyramids, edges with two equivalent Mn(4)N5 square pyramids, edges with three equivalent Mn(3)N5 square pyramids, and  an edgeedge with one Mn(1)N4 trigonal pyramid. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Ti(1), one Mn(1), two equivalent Mn(3), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing NTiMn5 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the second N site, N(2) is bonded in a 5-coordinate geometry to two equivalent Ti(1), one Mn(1), and two equivalent Mn(2) atoms. In the third N site, N(3) is bonded to one Ti(1), one Mn(1), one Mn(3), one Mn(4), and two equivalent Mn(2) atoms to form a mixture of corner and edge-sharing NTiMn5 octahedra. The corner-sharing octahedral tilt angles are 6°. In the fourth N site, N(4) is bonded to one Ti(1), one Mn(1), two equivalent Mn(3), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing NTiMn5 octahedra. The corner-sharing octahedral tilt angles range from 6-11°.
Ti(MnN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one N(4), and two equivalent N(2) atoms. The Ti(1)-N(1) bond length is 2.03 Å. The Ti(1)-N(3) bond length is 2.01 Å. The Ti(1)-N(4) bond length is 1.99 Å. There is one shorter (1.98 Å) and one longer (2.52 Å) Ti(1)-N(2) bond length. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form MnN4 trigonal pyramids that share  a cornercorner with one Mn(3)N5 square pyramid, corners with three equivalent Mn(4)N5 square pyramids, corners with four equivalent Mn(2)N4 trigonal pyramids,  an edgeedge with one Mn(4)N5 square pyramid, and edges with two equivalent Mn(3)N5 square pyramids. The Mn(1)-N(1) bond length is 2.02 Å. The Mn(1)-N(2) bond length is 1.85 Å. The Mn(1)-N(3) bond length is 1.95 Å. The Mn(1)-N(4) bond length is 2.00 Å. In the second Mn site, Mn(2) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form distorted MnN4 trigonal pyramids that share corners with two equivalent Mn(3)N5 square pyramids, corners with two equivalent Mn(4)N5 square pyramids, corners with four equivalent Mn(1)N4 trigonal pyramids, and edges with two equivalent Mn(2)N4 trigonal pyramids. There is one shorter (1.92 Å) and one longer (1.94 Å) Mn(2)-N(2) bond length. There is one shorter (2.01 Å) and one longer (2.06 Å) Mn(2)-N(3) bond length. In the third Mn site, Mn(3) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form MnN5 square pyramids that share corners with three equivalent Mn(4)N5 square pyramids,  a cornercorner with one Mn(1)N4 trigonal pyramid, corners with two equivalent Mn(2)N4 trigonal pyramids, edges with two equivalent Mn(3)N5 square pyramids, edges with three equivalent Mn(4)N5 square pyramids, and edges with two equivalent Mn(1)N4 trigonal pyramids. The Mn(3)-N(3) bond length is 2.23 Å. There is one shorter (1.96 Å) and one longer (2.08 Å) Mn(3)-N(1) bond length. There is one shorter (2.04 Å) and one longer (2.05 Å) Mn(3)-N(4) bond length. In the fourth Mn site, Mn(4) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form MnN5 square pyramids that share corners with three equivalent Mn(3)N5 square pyramids, corners with two equivalent Mn(2)N4 trigonal pyramids, corners with three equivalent Mn(1)N4 trigonal pyramids, edges with two equivalent Mn(4)N5 square pyramids, edges with three equivalent Mn(3)N5 square pyramids, and  an edgeedge with one Mn(1)N4 trigonal pyramid. The Mn(4)-N(3) bond length is 2.08 Å. There is one shorter (2.00 Å) and one longer (2.27 Å) Mn(4)-N(1) bond length. There is one shorter (2.05 Å) and one longer (2.34 Å) Mn(4)-N(4) bond length. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Ti(1), one Mn(1), two equivalent Mn(3), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing NTiMn5 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the second N site, N(2) is bonded in a 5-coordinate geometry to two equivalent Ti(1), one Mn(1), and two equivalent Mn(2) atoms. In the third N site, N(3) is bonded to one Ti(1), one Mn(1), one Mn(3), one Mn(4), and two equivalent Mn(2) atoms to form a mixture of corner and edge-sharing NTiMn5 octahedra. The corner-sharing octahedral tilt angles are 6°. In the fourth N site, N(4) is bonded to one Ti(1), one Mn(1), two equivalent Mn(3), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing NTiMn5 octahedra. The corner-sharing octahedral tilt angles range from 6-11°.