Tl3BS3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two Tl3BS3 clusters. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 2-coordinate geometry to two equivalent S(2) atoms. In the second Tl site, Tl(2) is bonded in a 2-coordinate geometry to one S(1) and one S(2) atom. B(1) is bonded in a trigonal planar geometry to one S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to two equivalent Tl(2) and one B(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one Tl(1), one Tl(2), and one B(1) atom.
Tl3BS3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two Tl3BS3 clusters. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 2-coordinate geometry to two equivalent S(2) atoms. Both Tl(1)-S(2) bond lengths are 2.97 Å. In the second Tl site, Tl(2) is bonded in a 2-coordinate geometry to one S(1) and one S(2) atom. The Tl(2)-S(1) bond length is 3.06 Å. The Tl(2)-S(2) bond length is 3.03 Å. B(1) is bonded in a trigonal planar geometry to one S(1) and two equivalent S(2) atoms. The B(1)-S(1) bond length is 1.82 Å. Both B(1)-S(2) bond lengths are 1.82 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to two equivalent Tl(2) and one B(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one Tl(1), one Tl(2), and one B(1) atom.