CrHfSi crystallizes in the orthorhombic Pnma space group. Hf(1) is bonded in a 9-coordinate geometry to four equivalent Cr(1) and five equivalent Si(1) atoms. Cr(1) is bonded in a 4-coordinate geometry to four equivalent Hf(1) and four equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to five equivalent Hf(1) and four equivalent Cr(1) atoms.
CrHfSi crystallizes in the orthorhombic Pnma space group. Hf(1) is bonded in a 9-coordinate geometry to four equivalent Cr(1) and five equivalent Si(1) atoms. All Hf(1)-Cr(1) bond lengths are 2.95 Å. There are a spread of Hf(1)-Si(1) bond distances ranging from 2.68-2.79 Å. Cr(1) is bonded in a 4-coordinate geometry to four equivalent Hf(1) and four equivalent Si(1) atoms. There are a spread of Cr(1)-Si(1) bond distances ranging from 2.42-2.58 Å. Si(1) is bonded in a 9-coordinate geometry to five equivalent Hf(1) and four equivalent Cr(1) atoms.