(Na)2NaSbCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaSbCl6 framework. In the NaSbCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Sb(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent Cl(1) atoms to form SbCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Na(2) and one Sb(1) atom.
(Na)2NaSbCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaSbCl6 framework. In the NaSbCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Sb(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-Cl(1) bond lengths are 2.70 Å. Sb(1) is bonded to six equivalent Cl(1) atoms to form SbCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Sb(1)-Cl(1) bond lengths are 2.64 Å. Cl(1) is bonded in a linear geometry to one Na(2) and one Sb(1) atom.