Cr3Mn3(WO8)2 is beta Vanadium nitride-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the second W site, W(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(3), and one Mn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cr(1), and one Cr(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(3), one Mn(2), and one Mn(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cr(1), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cr(2), and one Mn(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one W(2), one Cr(1), and one Cr(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one W(2), one Cr(3), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one W(2), one Cr(3), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Cr(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one W(2), one Cr(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one W(2), one Mn(2), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one W(2), one Cr(2), and one Mn(1) atom.
Cr3Mn3(WO8)2 is beta Vanadium nitride-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. The W(1)-O(1) bond length is 1.91 Å. The W(1)-O(10) bond length is 1.92 Å. The W(1)-O(2) bond length is 1.97 Å. The W(1)-O(6) bond length is 1.88 Å. The W(1)-O(7) bond length is 2.03 Å. The W(1)-O(8) bond length is 2.07 Å. In the second W site, W(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. The W(2)-O(11) bond length is 2.08 Å. The W(2)-O(12) bond length is 1.94 Å. The W(2)-O(14) bond length is 1.94 Å. The W(2)-O(15) bond length is 2.03 Å. The W(2)-O(16) bond length is 1.89 Å. The W(2)-O(9) bond length is 1.89 Å. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. The Cr(1)-O(14) bond length is 2.07 Å. The Cr(1)-O(2) bond length is 2.02 Å. The Cr(1)-O(3) bond length is 1.98 Å. The Cr(1)-O(4) bond length is 1.97 Å. The Cr(1)-O(7) bond length is 2.04 Å. The Cr(1)-O(9) bond length is 2.08 Å. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. The Cr(2)-O(16) bond length is 2.06 Å. The Cr(2)-O(2) bond length is 2.02 Å. The Cr(2)-O(3) bond length is 1.98 Å. The Cr(2)-O(4) bond length is 1.97 Å. The Cr(2)-O(8) bond length is 2.01 Å. The Cr(2)-O(9) bond length is 2.04 Å. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. The Cr(3)-O(1) bond length is 2.07 Å. The Cr(3)-O(11) bond length is 2.02 Å. The Cr(3)-O(12) bond length is 2.00 Å. The Cr(3)-O(13) bond length is 1.99 Å. The Cr(3)-O(5) bond length is 1.98 Å. The Cr(3)-O(6) bond length is 2.04 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. The Mn(1)-O(14) bond length is 2.02 Å. The Mn(1)-O(16) bond length is 2.09 Å. The Mn(1)-O(3) bond length is 1.90 Å. The Mn(1)-O(4) bond length is 1.91 Å. The Mn(1)-O(7) bond length is 1.96 Å. The Mn(1)-O(8) bond length is 1.93 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-50°. The Mn(2)-O(1) bond length is 2.07 Å. The Mn(2)-O(10) bond length is 2.04 Å. The Mn(2)-O(11) bond length is 1.92 Å. The Mn(2)-O(13) bond length is 1.92 Å. The Mn(2)-O(15) bond length is 1.92 Å. The Mn(2)-O(5) bond length is 1.93 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. The Mn(3)-O(10) bond length is 2.08 Å. The Mn(3)-O(12) bond length is 2.13 Å. The Mn(3)-O(13) bond length is 1.92 Å. The Mn(3)-O(15) bond length is 2.16 Å. The Mn(3)-O(5) bond length is 1.90 Å. The Mn(3)-O(6) bond length is 2.12 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(3), and one Mn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cr(1), and one Cr(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(3), one Mn(2), and one Mn(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Cr(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cr(1), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Cr(2), and one Mn(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one W(2), one Cr(1), and one Cr(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one W(2), one Cr(3), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one W(2), one Cr(3), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Cr(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one W(2), one Cr(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one W(2), one Mn(2), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one W(2), one Cr(2), and one Mn(1) atom.