Ti(O4Cl)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Ti(O4Cl)4 clusters. Ti(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Cl(2) atom. In the second O site, O(6) is bonded in a water-like geometry to one Ti(1) and one Cl(2) atom. In the third O site, O(7) is bonded in a single-bond geometry to one Cl(2) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one Cl(1) atom. In the fifth O site, O(1) is bonded in a water-like geometry to one Ti(1) and one Cl(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. In the seventh O site, O(3) is bonded in a water-like geometry to one Ti(1) and one Cl(1) atom. In the eighth O site, O(4) is bonded in a water-like geometry to one Ti(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(8) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom.
Ti(O4Cl)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Ti(O4Cl)4 clusters. Ti(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. Both Ti(1)-O(1) bond lengths are 2.06 Å. Both Ti(1)-O(3) bond lengths are 2.12 Å. Both Ti(1)-O(4) bond lengths are 2.07 Å. Both Ti(1)-O(6) bond lengths are 2.10 Å. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Cl(2) atom. The O(5)-Cl(2) bond length is 1.40 Å. In the second O site, O(6) is bonded in a water-like geometry to one Ti(1) and one Cl(2) atom. The O(6)-Cl(2) bond length is 1.50 Å. In the third O site, O(7) is bonded in a single-bond geometry to one Cl(2) atom. The O(7)-Cl(2) bond length is 1.40 Å. In the fourth O site, O(8) is bonded in a single-bond geometry to one Cl(1) atom. The O(8)-Cl(1) bond length is 1.40 Å. In the fifth O site, O(1) is bonded in a water-like geometry to one Ti(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.53 Å. In the sixth O site, O(2) is bonded in a single-bond geometry to one Cl(1) atom. The O(2)-Cl(1) bond length is 1.40 Å. In the seventh O site, O(3) is bonded in a water-like geometry to one Ti(1) and one Cl(1) atom. The O(3)-Cl(1) bond length is 1.50 Å. In the eighth O site, O(4) is bonded in a water-like geometry to one Ti(1) and one Cl(2) atom. The O(4)-Cl(2) bond length is 1.52 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(8) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom.