UV2O6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P-31m space group. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent U(1)O6 octahedra and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. O(1) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent V(1) atoms.
UV2O6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P-31m space group. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. All U(1)-O(1) bond lengths are 2.16 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent U(1)O6 octahedra and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. All V(1)-O(1) bond lengths are 1.96 Å. O(1) is bonded in a distorted trigonal planar geometry to one U(1) and two equivalent V(1) atoms.