Cs2PtF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Pt(1)F6 octahedra. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Pt(1) atom.
Cs2PtF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Pt(1)F6 octahedra. All Cs(1)-F(1) bond lengths are 3.19 Å. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. All Pt(1)-F(1) bond lengths are 1.96 Å. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Pt(1) atom.