LiCoPO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent Co(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. Co(1) is bonded to four equivalent O(1) atoms to form CoO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Co(1)O4 tetrahedra. O(1) is bonded in a trigonal planar geometry to one Li(1), one Co(1), and one P(1) atom.
LiCoPO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent Co(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. All Li(1)-O(1) bond lengths are 2.03 Å. Co(1) is bonded to four equivalent O(1) atoms to form CoO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. All Co(1)-O(1) bond lengths are 2.00 Å. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Co(1)O4 tetrahedra. All P(1)-O(1) bond lengths are 1.56 Å. O(1) is bonded in a trigonal planar geometry to one Li(1), one Co(1), and one P(1) atom.