Tl3BO3 crystallizes in the hexagonal P6_3/m space group. Tl(1) is bonded in a distorted T-shaped geometry to three equivalent O(1) atoms. B(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Tl(1) and one B(1) atom.
Tl3BO3 crystallizes in the hexagonal P6_3/m space group. Tl(1) is bonded in a distorted T-shaped geometry to three equivalent O(1) atoms. There is one shorter (2.45 Å) and two longer (2.56 Å) Tl(1)-O(1) bond lengths. B(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All B(1)-O(1) bond lengths are 1.39 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent Tl(1) and one B(1) atom.