Mn2Pd4SnSb is Tungsten-derived structured and crystallizes in the trigonal R-3m space group. Mn(1) is bonded in a body-centered cubic geometry to four equivalent Pd(1), four equivalent Pd(2), and three equivalent Sb(1) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a body-centered cubic geometry to four equivalent Mn(1), one Sn(1), and three equivalent Sb(1) atoms. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to four equivalent Mn(1), three equivalent Sn(1), and one Sb(1) atom. In the third Pd site, Pd(2) is bonded in a body-centered cubic geometry to four equivalent Mn(1), three equivalent Sn(1), and one Sb(1) atom. In the fourth Pd site, Pd(2) is bonded in a body-centered cubic geometry to four equivalent Mn(1), three equivalent Sn(1), and one Sb(1) atom. Sn(1) is bonded in a distorted body-centered cubic geometry to two equivalent Pd(1) and six equivalent Pd(2) atoms. Sb(1) is bonded in a distorted body-centered cubic geometry to six equivalent Mn(1); two Pd(2,2); and six equivalent Pd(1) atoms.
Mn2Pd4SnSb is Tungsten-derived structured and crystallizes in the trigonal R-3m space group. Mn(1) is bonded in a body-centered cubic geometry to four equivalent Pd(1), four equivalent Pd(2), and three equivalent Sb(1) atoms. There are three shorter (2.80 Å) and one longer (2.81 Å) Mn(1)-Pd(1) bond length. There is one shorter (2.77 Å) and three longer (2.79 Å) Mn(1)-Pd(2) bond lengths. All Mn(1)-Sb(1) bond lengths are 3.23 Å. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a body-centered cubic geometry to four equivalent Mn(1), one Sn(1), and three equivalent Sb(1) atoms. The Pd(1)-Sn(1) bond length is 2.78 Å. All Pd(1)-Sb(1) bond lengths are 2.80 Å. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to four equivalent Mn(1), three equivalent Sn(1), and one Sb(1) atom. All Pd(2)-Sn(1) bond lengths are 2.79 Å. The Pd(2)-Sb(1) bond length is 2.79 Å. In the third Pd site, Pd(2) is bonded in a body-centered cubic geometry to four equivalent Mn(1), three equivalent Sn(1), and one Sb(1) atom. There is one shorter (2.77 Å) and three longer (2.79 Å) Pd(2)-Mn(1) bond lengths. All Pd(2)-Sn(1) bond lengths are 2.79 Å. The Pd(2)-Sb(1) bond length is 2.79 Å. In the fourth Pd site, Pd(2) is bonded in a body-centered cubic geometry to four equivalent Mn(1), three equivalent Sn(1), and one Sb(1) atom. There is one shorter (2.77 Å) and three longer (2.79 Å) Pd(2)-Mn(1) bond lengths. All Pd(2)-Sn(1) bond lengths are 2.79 Å. The Pd(2)-Sb(1) bond length is 2.79 Å. Sn(1) is bonded in a distorted body-centered cubic geometry to two equivalent Pd(1) and six equivalent Pd(2) atoms. Sb(1) is bonded in a distorted body-centered cubic geometry to six equivalent Mn(1); two Pd(2,2); and six equivalent Pd(1) atoms.