SrCoO3 is (Cubic) Perovskite structured and crystallizes in the triclinic P1 space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(9), and four equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Co(3)O6 octahedra, and faces with four equivalent Co(4)O6 octahedra. In the second Sr site, Sr(2) is bonded to two equivalent O(10), two equivalent O(11), two equivalent O(6), two equivalent O(7), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Co(1)O6 octahedra, and faces with four equivalent Co(4)O6 octahedra. In the third Sr site, Sr(3) is bonded to two equivalent O(11), two equivalent O(12), two equivalent O(7), two equivalent O(8), and four equivalent O(3) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Co(1)O6 octahedra, and faces with four equivalent Co(2)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to two equivalent O(12), two equivalent O(5), two equivalent O(8), two equivalent O(9), and four equivalent O(4) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent Sr(4)O12 cuboctahedra, faces with four equivalent Co(2)O6 octahedra, and faces with four equivalent Co(3)O6 octahedra. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(3), two equivalent O(11), and two equivalent O(7) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with four equivalent Sr(2)O12 cuboctahedra, and faces with four equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Co site, Co(2) is bonded to one O(3), one O(4), two equivalent O(12), and two equivalent O(8) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, faces with four equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In the third Co site, Co(3) is bonded to one O(1), one O(4), two equivalent O(5), and two equivalent O(9) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), two equivalent O(10), and two equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to four equivalent Sr(1), one Co(3), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to four equivalent Sr(2), one Co(1), and one Co(4) atom. In the third O site, O(3) is bonded in a distorted linear geometry to four equivalent Sr(3), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to four equivalent Sr(4), one Co(2), and one Co(3) atom. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(4), and two equivalent Co(3) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Co(4) atoms to form a mixture of distorted corner and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the seventh O site, O(7) is bonded to two equivalent Sr(2), two equivalent Sr(3), and two equivalent Co(1) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the eighth O site, O(8) is bonded to two equivalent Sr(3), two equivalent Sr(4), and two equivalent Co(2) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(4), and two equivalent Co(3) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Co(4) atoms. In the eleventh O site, O(11) is bonded to two equivalent Sr(2), two equivalent Sr(3), and two equivalent Co(1) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the twelfth O site, O(12) is bonded to two equivalent Sr(3), two equivalent Sr(4), and two equivalent Co(2) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°.
SrCoO3 is (Cubic) Perovskite structured and crystallizes in the triclinic P1 space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(9), and four equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Co(3)O6 octahedra, and faces with four equivalent Co(4)O6 octahedra. Both Sr(1)-O(10) bond lengths are 2.76 Å. Both Sr(1)-O(5) bond lengths are 2.70 Å. There is one shorter (2.75 Å) and one longer (2.76 Å) Sr(1)-O(6) bond length. Both Sr(1)-O(9) bond lengths are 2.70 Å. There are two shorter (2.74 Å) and two longer (2.76 Å) Sr(1)-O(1) bond lengths. In the second Sr site, Sr(2) is bonded to two equivalent O(10), two equivalent O(11), two equivalent O(6), two equivalent O(7), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Co(1)O6 octahedra, and faces with four equivalent Co(4)O6 octahedra. Both Sr(2)-O(10) bond lengths are 2.77 Å. Both Sr(2)-O(11) bond lengths are 2.72 Å. There is one shorter (2.75 Å) and one longer (2.76 Å) Sr(2)-O(6) bond length. Both Sr(2)-O(7) bond lengths are 2.71 Å. There are a spread of Sr(2)-O(2) bond distances ranging from 2.73-2.76 Å. In the third Sr site, Sr(3) is bonded to two equivalent O(11), two equivalent O(12), two equivalent O(7), two equivalent O(8), and four equivalent O(3) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Co(1)O6 octahedra, and faces with four equivalent Co(2)O6 octahedra. There is one shorter (2.70 Å) and one longer (2.71 Å) Sr(3)-O(11) bond length. Both Sr(3)-O(12) bond lengths are 2.76 Å. Both Sr(3)-O(7) bond lengths are 2.70 Å. Both Sr(3)-O(8) bond lengths are 2.75 Å. There are two shorter (2.74 Å) and two longer (2.76 Å) Sr(3)-O(3) bond lengths. In the fourth Sr site, Sr(4) is bonded to two equivalent O(12), two equivalent O(5), two equivalent O(8), two equivalent O(9), and four equivalent O(4) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent Sr(4)O12 cuboctahedra, faces with four equivalent Co(2)O6 octahedra, and faces with four equivalent Co(3)O6 octahedra. Both Sr(4)-O(12) bond lengths are 2.76 Å. There is one shorter (2.70 Å) and one longer (2.71 Å) Sr(4)-O(5) bond length. There is one shorter (2.75 Å) and one longer (2.76 Å) Sr(4)-O(8) bond length. Both Sr(4)-O(9) bond lengths are 2.72 Å. There are a spread of Sr(4)-O(4) bond distances ranging from 2.74-2.76 Å. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(3), two equivalent O(11), and two equivalent O(7) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Co(1)O6 octahedra, faces with four equivalent Sr(2)O12 cuboctahedra, and faces with four equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. The Co(1)-O(2) bond length is 1.84 Å. The Co(1)-O(3) bond length is 1.87 Å. Both Co(1)-O(11) bond lengths are 1.94 Å. Both Co(1)-O(7) bond lengths are 1.95 Å. In the second Co site, Co(2) is bonded to one O(3), one O(4), two equivalent O(12), and two equivalent O(8) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, faces with four equivalent Sr(3)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedra are not tilted. The Co(2)-O(3) bond length is 1.98 Å. The Co(2)-O(4) bond length is 2.00 Å. Both Co(2)-O(12) bond lengths are 1.94 Å. Both Co(2)-O(8) bond lengths are 1.95 Å. In the third Co site, Co(3) is bonded to one O(1), one O(4), two equivalent O(5), and two equivalent O(9) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. The Co(3)-O(1) bond length is 1.87 Å. The Co(3)-O(4) bond length is 1.84 Å. Both Co(3)-O(5) bond lengths are 1.95 Å. Both Co(3)-O(9) bond lengths are 1.94 Å. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), two equivalent O(10), and two equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. The Co(4)-O(1) bond length is 1.98 Å. The Co(4)-O(2) bond length is 2.00 Å. There is one shorter (1.93 Å) and one longer (1.94 Å) Co(4)-O(10) bond length. Both Co(4)-O(6) bond lengths are 1.95 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to four equivalent Sr(1), one Co(3), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to four equivalent Sr(2), one Co(1), and one Co(4) atom. In the third O site, O(3) is bonded in a distorted linear geometry to four equivalent Sr(3), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to four equivalent Sr(4), one Co(2), and one Co(3) atom. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(4), and two equivalent Co(3) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the sixth O site, O(6) is bonded to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Co(4) atoms to form a mixture of distorted corner and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the seventh O site, O(7) is bonded to two equivalent Sr(2), two equivalent Sr(3), and two equivalent Co(1) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the eighth O site, O(8) is bonded to two equivalent Sr(3), two equivalent Sr(4), and two equivalent Co(2) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the ninth O site, O(9) is bonded to two equivalent Sr(1), two equivalent Sr(4), and two equivalent Co(3) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the tenth O site, O(10) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Sr(2), and two equivalent Co(4) atoms. In the eleventh O site, O(11) is bonded to two equivalent Sr(2), two equivalent Sr(3), and two equivalent Co(1) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the twelfth O site, O(12) is bonded to two equivalent Sr(3), two equivalent Sr(4), and two equivalent Co(2) atoms to form a mixture of distorted face, corner, and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°.