LaVO4BiVO4 is Zircon-derived structured and crystallizes in the tetragonal I-4m2 space group. La(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1), one V(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one V(2), and one Bi(1) atom.
LaVO4BiVO4 is Zircon-derived structured and crystallizes in the tetragonal I-4m2 space group. La(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All La(1)-O(1) bond lengths are 2.56 Å. All La(1)-O(2) bond lengths are 2.45 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 1.74 Å. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. All V(2)-O(2) bond lengths are 1.74 Å. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Bi(1)-O(1) bond lengths are 2.44 Å. All Bi(1)-O(2) bond lengths are 2.54 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1), one V(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one V(2), and one Bi(1) atom.