Ce3GaBr3 crystallizes in the cubic Pm-3m space group. Ce(1) is bonded to two equivalent Ga(1) and four equivalent Br(1) atoms to form a mixture of edge and corner-sharing CeGa2Br4 octahedra. The corner-sharing octahedra are not tilted. Ga(1) is bonded to six equivalent Ce(1) atoms to form corner-sharing GaCe6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a square co-planar geometry to four equivalent Ce(1) atoms.
Ce3GaBr3 crystallizes in the cubic Pm-3m space group. Ce(1) is bonded to two equivalent Ga(1) and four equivalent Br(1) atoms to form a mixture of edge and corner-sharing CeGa2Br4 octahedra. The corner-sharing octahedra are not tilted. Both Ce(1)-Ga(1) bond lengths are 3.04 Å. All Ce(1)-Br(1) bond lengths are 3.04 Å. Ga(1) is bonded to six equivalent Ce(1) atoms to form corner-sharing GaCe6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a square co-planar geometry to four equivalent Ce(1) atoms.