V2PbO2 crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one O(1) atom. Pb(1) is bonded in a 6-coordinate geometry to four equivalent V(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom.
V2PbO2 crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one O(1) atom. Both V(1)-Pb(1) bond lengths are 2.94 Å. The V(1)-O(1) bond length is 1.70 Å. Pb(1) is bonded in a 6-coordinate geometry to four equivalent V(1) and two equivalent O(1) atoms. Both Pb(1)-O(1) bond lengths are 2.46 Å. O(1) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom.