XeBiF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeBiF7 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(3) atom. Bi(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Xe(1) and one Bi(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Bi(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Bi(1) atom.
XeBiF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeBiF7 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(3) atom. The Xe(1)-F(1) bond length is 2.21 Å. The Xe(1)-F(3) bond length is 1.98 Å. Bi(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. The Bi(1)-F(1) bond length is 2.16 Å. The Bi(1)-F(2) bond length is 2.01 Å. The Bi(1)-F(4) bond length is 2.01 Å. The Bi(1)-F(5) bond length is 2.01 Å. The Bi(1)-F(6) bond length is 2.00 Å. The Bi(1)-F(7) bond length is 2.00 Å. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Xe(1) and one Bi(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Bi(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Bi(1) atom.