MnF3 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 24-25°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms.
MnF3 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 24-25°. Both Mn(1)-F(1) bond lengths are 1.95 Å. There are two shorter (1.86 Å) and two longer (2.09 Å) Mn(1)-F(2) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms.