Ag2Zn2(MoO4)3 crystallizes in the triclinic P1 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(11), one O(21), and one O(3) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, and  a cornercorner with one Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-60°. In the second Mo site, Mo(2) is bonded to one O(12), one O(2), one O(22), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, and  a cornercorner with one Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-60°. In the third Mo site, Mo(3) is bonded to one O(13), one O(18), one O(19), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra, and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-67°. In the fourth Mo site, Mo(4) is bonded to one O(14), one O(17), one O(20), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, and corners with two equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-67°. In the fifth Mo site, Mo(5) is bonded to one O(10), one O(16), one O(24), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-58°. In the sixth Mo site, Mo(6) is bonded to one O(15), one O(23), one O(5), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-58°. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(17), one O(19), one O(21), one O(3), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(10), one O(18), one O(20), one O(22), and one O(4) atom. In the third Ag site, Ag(3) is bonded to one O(11), one O(12), one O(15), one O(16), one O(19), and one O(20) atom to form AgO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, and  a cornercorner with one Mo(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 62°. In the fourth Ag site, Ag(4) is bonded in a distorted bent 150 degrees geometry to one O(15), one O(16), and one O(19) atom. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(12), one O(13), one O(3), one O(5), one O(6), and one O(9) atom to form ZnO6 octahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra, and  an edgeedge with one Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(14), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, corners with two equivalent Mo(5)O4 tetrahedra, and  an edgeedge with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. In the third Zn site, Zn(3) is bonded to one O(1), one O(18), one O(22), one O(23), one O(24), and one O(7) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, corners with two equivalent Mo(3)O4 tetrahedra, and  an edgeedge with one Zn(4)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(17), one O(2), one O(21), one O(23), one O(24), and one O(8) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, corners with two equivalent Mo(4)O4 tetrahedra, and  an edgeedge with one Zn(3)O6 octahedra. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Zn(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(2) and one Zn(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mo(1), one Ag(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mo(2), one Ag(2), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(6), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mo(5), one Zn(1), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(3) and one Zn(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mo(4) and one Zn(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Mo(6), one Ag(1), and one Zn(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Mo(5), one Ag(2), and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Ag(3), and one Zn(2) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mo(2), one Ag(3), and one Zn(1) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mo(3) and one Zn(1) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Mo(4) and one Zn(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Mo(6), one Ag(3), and one Ag(4) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Mo(5), one Ag(3), and one Ag(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(1), and one Zn(4) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Mo(3), one Ag(2), and one Zn(3) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Mo(3), one Ag(1), one Ag(3), and one Ag(4) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(2), and one Ag(3) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one Zn(4) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(2), and one Zn(3) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Mo(6), one Zn(3), and one Zn(4) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Mo(5), one Zn(3), and one Zn(4) atom.
Ag2Zn2(MoO4)3 crystallizes in the triclinic P1 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(11), one O(21), and one O(3) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, and  a cornercorner with one Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-60°. The Mo(1)-O(1) bond length is 1.79 Å. The Mo(1)-O(11) bond length is 1.82 Å. The Mo(1)-O(21) bond length is 1.82 Å. The Mo(1)-O(3) bond length is 1.80 Å. In the second Mo site, Mo(2) is bonded to one O(12), one O(2), one O(22), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra, and  a cornercorner with one Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-60°. The Mo(2)-O(12) bond length is 1.83 Å. The Mo(2)-O(2) bond length is 1.78 Å. The Mo(2)-O(22) bond length is 1.82 Å. The Mo(2)-O(4) bond length is 1.80 Å. In the third Mo site, Mo(3) is bonded to one O(13), one O(18), one O(19), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra, and corners with two equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-67°. The Mo(3)-O(13) bond length is 1.79 Å. The Mo(3)-O(18) bond length is 1.82 Å. The Mo(3)-O(19) bond length is 1.81 Å. The Mo(3)-O(7) bond length is 1.79 Å. In the fourth Mo site, Mo(4) is bonded to one O(14), one O(17), one O(20), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, and corners with two equivalent Zn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-67°. The Mo(4)-O(14) bond length is 1.79 Å. The Mo(4)-O(17) bond length is 1.83 Å. The Mo(4)-O(20) bond length is 1.79 Å. The Mo(4)-O(8) bond length is 1.79 Å. In the fifth Mo site, Mo(5) is bonded to one O(10), one O(16), one O(24), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-58°. The Mo(5)-O(10) bond length is 1.78 Å. The Mo(5)-O(16) bond length is 1.78 Å. The Mo(5)-O(24) bond length is 1.82 Å. The Mo(5)-O(6) bond length is 1.83 Å. In the sixth Mo site, Mo(6) is bonded to one O(15), one O(23), one O(5), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Zn(3)O6 octahedra,  a cornercorner with one Zn(4)O6 octahedra, and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-58°. The Mo(6)-O(15) bond length is 1.79 Å. The Mo(6)-O(23) bond length is 1.81 Å. The Mo(6)-O(5) bond length is 1.84 Å. The Mo(6)-O(9) bond length is 1.78 Å. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(17), one O(19), one O(21), one O(3), and one O(9) atom. The Ag(1)-O(17) bond length is 2.32 Å. The Ag(1)-O(19) bond length is 2.29 Å. The Ag(1)-O(21) bond length is 2.40 Å. The Ag(1)-O(3) bond length is 2.30 Å. The Ag(1)-O(9) bond length is 2.73 Å. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(10), one O(18), one O(20), one O(22), and one O(4) atom. The Ag(2)-O(10) bond length is 2.73 Å. The Ag(2)-O(18) bond length is 2.34 Å. The Ag(2)-O(20) bond length is 2.27 Å. The Ag(2)-O(22) bond length is 2.41 Å. The Ag(2)-O(4) bond length is 2.30 Å. In the third Ag site, Ag(3) is bonded to one O(11), one O(12), one O(15), one O(16), one O(19), and one O(20) atom to form AgO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, and  a cornercorner with one Mo(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 62°. The Ag(3)-O(11) bond length is 2.42 Å. The Ag(3)-O(12) bond length is 2.42 Å. The Ag(3)-O(15) bond length is 2.50 Å. The Ag(3)-O(16) bond length is 2.50 Å. The Ag(3)-O(19) bond length is 2.68 Å. The Ag(3)-O(20) bond length is 2.65 Å. In the fourth Ag site, Ag(4) is bonded in a distorted bent 150 degrees geometry to one O(15), one O(16), and one O(19) atom. The Ag(4)-O(15) bond length is 2.25 Å. The Ag(4)-O(16) bond length is 2.23 Å. The Ag(4)-O(19) bond length is 2.81 Å. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(12), one O(13), one O(3), one O(5), one O(6), and one O(9) atom to form ZnO6 octahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra, corners with two equivalent Mo(6)O4 tetrahedra, and  an edgeedge with one Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. The Zn(1)-O(12) bond length is 2.17 Å. The Zn(1)-O(13) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 2.16 Å. The Zn(1)-O(5) bond length is 2.20 Å. The Zn(1)-O(6) bond length is 2.14 Å. The Zn(1)-O(9) bond length is 2.07 Å. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(14), one O(4), one O(5), and one O(6) atom to form ZnO6 octahedra that share  a cornercorner with one Ag(3)O6 octahedra,  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, corners with two equivalent Mo(5)O4 tetrahedra, and  an edgeedge with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. The Zn(2)-O(10) bond length is 2.08 Å. The Zn(2)-O(11) bond length is 2.18 Å. The Zn(2)-O(14) bond length is 1.99 Å. The Zn(2)-O(4) bond length is 2.16 Å. The Zn(2)-O(5) bond length is 2.15 Å. The Zn(2)-O(6) bond length is 2.20 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(18), one O(22), one O(23), one O(24), and one O(7) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, corners with two equivalent Mo(3)O4 tetrahedra, and  an edgeedge with one Zn(4)O6 octahedra. The Zn(3)-O(1) bond length is 2.11 Å. The Zn(3)-O(18) bond length is 2.14 Å. The Zn(3)-O(22) bond length is 2.10 Å. The Zn(3)-O(23) bond length is 2.12 Å. The Zn(3)-O(24) bond length is 2.22 Å. The Zn(3)-O(7) bond length is 2.06 Å. In the fourth Zn site, Zn(4) is bonded to one O(17), one O(2), one O(21), one O(23), one O(24), and one O(8) atom to form ZnO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, corners with two equivalent Mo(4)O4 tetrahedra, and  an edgeedge with one Zn(3)O6 octahedra. The Zn(4)-O(17) bond length is 2.14 Å. The Zn(4)-O(2) bond length is 2.10 Å. The Zn(4)-O(21) bond length is 2.11 Å. The Zn(4)-O(23) bond length is 2.24 Å. The Zn(4)-O(24) bond length is 2.11 Å. The Zn(4)-O(8) bond length is 2.07 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Zn(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(2) and one Zn(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mo(1), one Ag(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mo(2), one Ag(2), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(6), one Zn(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mo(5), one Zn(1), and one Zn(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(3) and one Zn(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mo(4) and one Zn(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Mo(6), one Ag(1), and one Zn(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Mo(5), one Ag(2), and one Zn(2) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Ag(3), and one Zn(2) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mo(2), one Ag(3), and one Zn(1) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mo(3) and one Zn(1) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Mo(4) and one Zn(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Mo(6), one Ag(3), and one Ag(4) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Mo(5), one Ag(3), and one Ag(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(1), and one Zn(4) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Mo(3), one Ag(2), and one Zn(3) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Mo(3), one Ag(1), one Ag(3), and one Ag(4) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Mo(4), one Ag(2), and one Ag(3) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one Zn(4) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(2), and one Zn(3) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Mo(6), one Zn(3), and one Zn(4) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Mo(5), one Zn(3), and one Zn(4) atom.