VW3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. V(1) is bonded in a distorted body-centered cubic geometry to six equivalent W(2) and eight equivalent W(1) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded to four equivalent V(1) and four equivalent W(2) atoms to form a mixture of distorted face, corner, and edge-sharing WV4W4 tetrahedra. In the second W site, W(2) is bonded in a 14-coordinate geometry to six equivalent V(1) and eight equivalent W(1) atoms.
VW3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. V(1) is bonded in a distorted body-centered cubic geometry to six equivalent W(2) and eight equivalent W(1) atoms. All V(1)-W(2) bond lengths are 3.13 Å. All V(1)-W(1) bond lengths are 2.71 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to four equivalent V(1) and four equivalent W(2) atoms to form a mixture of distorted face, corner, and edge-sharing WV4W4 tetrahedra. All W(1)-W(2) bond lengths are 2.71 Å. In the second W site, W(2) is bonded in a 14-coordinate geometry to six equivalent V(1) and eight equivalent W(1) atoms.