LiCrN crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. Cr(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing CrN4 tetrahedra. N(1) is bonded in a 7-coordinate geometry to three equivalent Li(1) and four equivalent Cr(1) atoms.
LiCrN crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. There are two shorter (2.00 Å) and one longer (2.21 Å) Li(1)-N(1) bond length. Cr(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing CrN4 tetrahedra. There are a spread of Cr(1)-N(1) bond distances ranging from 1.97-2.01 Å. N(1) is bonded in a 7-coordinate geometry to three equivalent Li(1) and four equivalent Cr(1) atoms.