AgClO3 crystallizes in the cubic P2_13 space group. Ag(1) is bonded to six equivalent O(1) atoms to form corner-sharing AgO6 octahedra. The corner-sharing octahedral tilt angles are 67°. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.
AgClO3 crystallizes in the cubic P2_13 space group. Ag(1) is bonded to six equivalent O(1) atoms to form corner-sharing AgO6 octahedra. The corner-sharing octahedral tilt angles are 67°. There are three shorter (2.44 Å) and three longer (2.54 Å) Ag(1)-O(1) bond lengths. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ag(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.50 Å. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.