CeIr2RhB2 crystallizes in the orthorhombic Cmmm space group. Ce(1) is bonded in a 20-coordinate geometry to two equivalent Ce(1), eight equivalent Ir(1), four equivalent Rh(1), and six equivalent B(1) atoms. Ir(1) is bonded in a distorted square co-planar geometry to four equivalent Ce(1) and four equivalent B(1) atoms. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Ce(1) and four equivalent B(1) atoms. B(1) is bonded in a 6-coordinate geometry to three equivalent Ce(1), four equivalent Ir(1), and two equivalent Rh(1) atoms.
CeIr2RhB2 crystallizes in the orthorhombic Cmmm space group. Ce(1) is bonded in a 20-coordinate geometry to two equivalent Ce(1), eight equivalent Ir(1), four equivalent Rh(1), and six equivalent B(1) atoms. Both Ce(1)-Ce(1) bond lengths are 3.13 Å. All Ce(1)-Ir(1) bond lengths are 3.17 Å. All Ce(1)-Rh(1) bond lengths are 3.18 Å. All Ce(1)-B(1) bond lengths are 3.19 Å. Ir(1) is bonded in a distorted square co-planar geometry to four equivalent Ce(1) and four equivalent B(1) atoms. All Ir(1)-B(1) bond lengths are 2.23 Å. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Ce(1) and four equivalent B(1) atoms. All Rh(1)-B(1) bond lengths are 2.24 Å. B(1) is bonded in a 6-coordinate geometry to three equivalent Ce(1), four equivalent Ir(1), and two equivalent Rh(1) atoms.