PbSb2O6 crystallizes in the trigonal P-31m space group. Pb(1) is bonded to six equivalent O(1) atoms to form PbO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Pb(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. O(1) is bonded in a distorted trigonal planar geometry to one Pb(1) and two equivalent Sb(1) atoms.
PbSb2O6 crystallizes in the trigonal P-31m space group. Pb(1) is bonded to six equivalent O(1) atoms to form PbO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. All Pb(1)-O(1) bond lengths are 2.57 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Pb(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. All Sb(1)-O(1) bond lengths are 2.00 Å. O(1) is bonded in a distorted trigonal planar geometry to one Pb(1) and two equivalent Sb(1) atoms.