WGeO4 crystallizes in the orthorhombic Pnna space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 32°. Ge(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.
WGeO4 crystallizes in the orthorhombic Pnna space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 32°. Both W(1)-O(1) bond lengths are 1.94 Å. There are two shorter (1.88 Å) and two longer (2.04 Å) W(1)-O(2) bond lengths. Ge(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (1.97 Å) and two longer (2.30 Å) Ge(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.