WCrO6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Cr(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom.
WCrO6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. The W(1)-O(1) bond length is 1.81 Å. The W(1)-O(2) bond length is 2.14 Å. The W(1)-O(3) bond length is 1.80 Å. The W(1)-O(4) bond length is 1.80 Å. The W(1)-O(5) bond length is 2.15 Å. The W(1)-O(6) bond length is 2.15 Å. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. The Cr(1)-O(1) bond length is 2.03 Å. The Cr(1)-O(2) bond length is 1.68 Å. The Cr(1)-O(3) bond length is 2.06 Å. The Cr(1)-O(4) bond length is 2.05 Å. The Cr(1)-O(5) bond length is 1.68 Å. The Cr(1)-O(6) bond length is 1.67 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Cr(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one W(1) and one Cr(1) atom.