V3Al crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 14-coordinate geometry to ten equivalent V(1) and four equivalent Al(1) atoms. Al(1) is bonded to twelve equivalent V(1) atoms to form a mixture of edge and face-sharing AlV12 cuboctahedra.
V3Al crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 14-coordinate geometry to ten equivalent V(1) and four equivalent Al(1) atoms. There are two shorter (2.39 Å) and eight longer (2.93 Å) V(1)-V(1) bond lengths. All V(1)-Al(1) bond lengths are 2.68 Å. Al(1) is bonded to twelve equivalent V(1) atoms to form a mixture of edge and face-sharing AlV12 cuboctahedra.