FePNH5O4F is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two FePNH5O4F clusters. Fe(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(7), and one F(2) atom. P(2) is bonded in a distorted tetrahedral geometry to one H(1), one H(10), one H(9), and one O(7) atom. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(8) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one P(2) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one P(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Fe(1), one H(2), and one H(3) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Fe(1) and one N(1) atom. In the third O site, O(7) is bonded in a bent 150 degrees geometry to one Fe(1) and one P(2) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one N(1) atom. F(2) is bonded in a single-bond geometry to one Fe(1) atom.
FePNH5O4F is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two FePNH5O4F clusters. Fe(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(7), and one F(2) atom. The Fe(1)-O(1) bond length is 2.26 Å. The Fe(1)-O(3) bond length is 2.16 Å. The Fe(1)-O(7) bond length is 2.01 Å. The Fe(1)-F(2) bond length is 1.91 Å. P(2) is bonded in a distorted tetrahedral geometry to one H(1), one H(10), one H(9), and one O(7) atom. The P(2)-H(1) bond length is 1.41 Å. The P(2)-H(10) bond length is 1.40 Å. The P(2)-H(9) bond length is 1.41 Å. The P(2)-O(7) bond length is 1.52 Å. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(8) atom. The N(1)-O(3) bond length is 1.29 Å. The N(1)-O(8) bond length is 1.26 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 0.98 Å. In the fourth H site, H(9) is bonded in a single-bond geometry to one P(2) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one P(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Fe(1), one H(2), and one H(3) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Fe(1) and one N(1) atom. In the third O site, O(7) is bonded in a bent 150 degrees geometry to one Fe(1) and one P(2) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one N(1) atom. F(2) is bonded in a single-bond geometry to one Fe(1) atom.