(Li2V4P8H3O32)2H2 crystallizes in the triclinic P1 space group. The structure consists of one 1333-74-0 atom inside a Li2V4P8H3O32 framework. In the Li2V4P8H3O32 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one P(1), one P(3), one O(22), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 1-coordinate geometry to one P(2), one O(14), one O(27), one O(29), and one O(8) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(2), one O(4), and one O(7) atom. In the second V site, V(2) is bonded in a linear geometry to one O(16) and one O(17) atom. In the third V site, V(3) is bonded in a linear geometry to one O(15) and one O(18) atom. In the fourth V site, V(4) is bonded in a distorted rectangular see-saw-like geometry to one O(22), one O(26), one O(29), and one O(31) atom. There are eight inequivalent P sites. In the first P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one O(21), one O(30), and one O(7) atom. In the second P site, P(2) is bonded in a 3-coordinate geometry to one Li(2), one O(20), and one O(29) atom. In the third P site, P(3) is bonded in a 3-coordinate geometry to one Li(1), one O(14), and one O(22) atom. In the fourth P site, P(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the fifth P site, P(5) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(19) atom. In the sixth P site, P(6) is bonded in a distorted bent 120 degrees geometry to one O(31) and one O(32) atom. In the seventh P site, P(7) is bonded in a 3-coordinate geometry to one O(13), one O(26), and one O(3) atom. In the eighth P site, P(8) is bonded in a 3-coordinate geometry to one O(12), one O(25), and one O(4) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(23) and one O(9) atom. In the second H site, H(2) is bonded in a linear geometry to one O(10) and one O(24) atom. In the third H site, H(4) is bonded in a 2-coordinate geometry to one O(12) and one O(20) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(4) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one P(4), and one O(7) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one P(7) and one O(10) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(1), one P(8), one O(11), and one O(18) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(20) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one O(21) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one V(1), one P(1), one O(16), and one O(2) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Li(1) and one Li(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one H(1), one O(20), and one O(25) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one H(2) and one O(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(1), one P(5), and one O(4) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one P(8), one H(4), and one O(28) atom. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one P(7) and one O(27) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Li(2) and one P(3) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one V(3) and one O(29) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one V(2) and one O(7) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one V(2) and one O(26) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one V(3) and one O(4) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one P(5) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one P(2), one H(4), one O(5), and one O(9) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one P(1) and one O(6) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(1), one V(4), one P(3), and one O(29) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one H(1) and one O(30) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one H(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one P(8) and one O(9) atom. In the twenty-sixth O site, O(26) is bonded in a 4-coordinate geometry to one V(4), one P(7), one O(17), and one O(31) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Li(2) and one O(13) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one O(12) atom. In the twenty-ninth O site, O(29) is bonded in a 5-coordinate geometry to one Li(2), one V(4), one P(2), one O(15), and one O(22) atom. In the thirtieth O site, O(30) is bonded in a 2-coordinate geometry to one P(1) and one O(23) atom. In the thirty-first O site, O(31) is bonded in a 3-coordinate geometry to one V(4), one P(6), and one O(26) atom. In the thirty-second O site, O(32) is bonded in a single-bond geometry to one P(6) atom.
(Li2V4P8H3O32)2H2 crystallizes in the triclinic P1 space group. The structure consists of one 1333-74-0 atom inside a Li2V4P8H3O32 framework. In the Li2V4P8H3O32 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one P(1), one P(3), one O(22), one O(7), and one O(8) atom. The Li(1)-P(1) bond length is 2.05 Å. The Li(1)-P(3) bond length is 1.64 Å. The Li(1)-O(22) bond length is 1.82 Å. The Li(1)-O(7) bond length is 2.41 Å. The Li(1)-O(8) bond length is 1.52 Å. In the second Li site, Li(2) is bonded in a 1-coordinate geometry to one P(2), one O(14), one O(27), one O(29), and one O(8) atom. The Li(2)-P(2) bond length is 1.72 Å. The Li(2)-O(14) bond length is 1.37 Å. The Li(2)-O(27) bond length is 2.45 Å. The Li(2)-O(29) bond length is 1.98 Å. The Li(2)-O(8) bond length is 1.80 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(2), one O(4), and one O(7) atom. The V(1)-O(11) bond length is 1.54 Å. The V(1)-O(2) bond length is 1.48 Å. The V(1)-O(4) bond length is 1.66 Å. The V(1)-O(7) bond length is 1.50 Å. In the second V site, V(2) is bonded in a linear geometry to one O(16) and one O(17) atom. The V(2)-O(16) bond length is 1.19 Å. The V(2)-O(17) bond length is 0.98 Å. In the third V site, V(3) is bonded in a linear geometry to one O(15) and one O(18) atom. The V(3)-O(15) bond length is 1.01 Å. The V(3)-O(18) bond length is 1.04 Å. In the fourth V site, V(4) is bonded in a distorted rectangular see-saw-like geometry to one O(22), one O(26), one O(29), and one O(31) atom. The V(4)-O(22) bond length is 1.55 Å. The V(4)-O(26) bond length is 1.61 Å. The V(4)-O(29) bond length is 1.81 Å. The V(4)-O(31) bond length is 1.40 Å. There are eight inequivalent P sites. In the first P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one O(21), one O(30), and one O(7) atom. The P(1)-O(21) bond length is 2.22 Å. The P(1)-O(30) bond length is 2.35 Å. The P(1)-O(7) bond length is 1.90 Å. In the second P site, P(2) is bonded in a 3-coordinate geometry to one Li(2), one O(20), and one O(29) atom. The P(2)-O(20) bond length is 2.23 Å. The P(2)-O(29) bond length is 1.87 Å. In the third P site, P(3) is bonded in a 3-coordinate geometry to one Li(1), one O(14), and one O(22) atom. The P(3)-O(14) bond length is 1.81 Å. The P(3)-O(22) bond length is 1.12 Å. In the fourth P site, P(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The P(4)-O(1) bond length is 1.72 Å. The P(4)-O(2) bond length is 1.18 Å. In the fifth P site, P(5) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(19) atom. The P(5)-O(11) bond length is 1.10 Å. The P(5)-O(19) bond length is 1.74 Å. In the sixth P site, P(6) is bonded in a distorted bent 120 degrees geometry to one O(31) and one O(32) atom. The P(6)-O(31) bond length is 1.21 Å. The P(6)-O(32) bond length is 1.72 Å. In the seventh P site, P(7) is bonded in a 3-coordinate geometry to one O(13), one O(26), and one O(3) atom. The P(7)-O(13) bond length is 2.19 Å. The P(7)-O(26) bond length is 1.91 Å. The P(7)-O(3) bond length is 2.34 Å. In the eighth P site, P(8) is bonded in a 3-coordinate geometry to one O(12), one O(25), and one O(4) atom. The P(8)-O(12) bond length is 2.40 Å. The P(8)-O(25) bond length is 2.32 Å. The P(8)-O(4) bond length is 1.89 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(23) and one O(9) atom. The H(1)-O(23) bond length is 0.85 Å. The H(1)-O(9) bond length is 1.17 Å. In the second H site, H(2) is bonded in a linear geometry to one O(10) and one O(24) atom. The H(2)-O(10) bond length is 0.81 Å. The H(2)-O(24) bond length is 0.95 Å. In the third H site, H(4) is bonded in a 2-coordinate geometry to one O(12) and one O(20) atom. The H(4)-O(12) bond length is 1.72 Å. The H(4)-O(20) bond length is 1.78 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(4) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one P(4), and one O(7) atom. The O(2)-O(7) bond length is 1.07 Å. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one P(7) and one O(10) atom. The O(3)-O(10) bond length is 1.61 Å. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(1), one P(8), one O(11), and one O(18) atom. The O(4)-O(11) bond length is 1.09 Å. The O(4)-O(18) bond length is 1.77 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(20) atom. The O(5)-O(20) bond length is 1.56 Å. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one O(21) atom. The O(6)-O(21) bond length is 1.64 Å. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Li(1), one V(1), one P(1), one O(16), and one O(2) atom. The O(7)-O(16) bond length is 1.88 Å. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Li(1) and one Li(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one H(1), one O(20), and one O(25) atom. The O(9)-O(20) bond length is 1.91 Å. The O(9)-O(25) bond length is 1.68 Å. In the tenth O site, O(10) is bonded in a single-bond geometry to one H(2) and one O(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(1), one P(5), and one O(4) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one P(8), one H(4), and one O(28) atom. The O(12)-O(28) bond length is 1.47 Å. In the thirteenth O site, O(13) is bonded in a 1-coordinate geometry to one P(7) and one O(27) atom. The O(13)-O(27) bond length is 1.63 Å. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Li(2) and one P(3) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one V(3) and one O(29) atom. The O(15)-O(29) bond length is 1.76 Å. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one V(2) and one O(7) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one V(2) and one O(26) atom. The O(17)-O(26) bond length is 1.76 Å. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one V(3) and one O(4) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one P(5) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one P(2), one H(4), one O(5), and one O(9) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one P(1) and one O(6) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Li(1), one V(4), one P(3), and one O(29) atom. The O(22)-O(29) bond length is 1.15 Å. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one H(1) and one O(30) atom. The O(23)-O(30) bond length is 1.62 Å. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one H(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one P(8) and one O(9) atom. In the twenty-sixth O site, O(26) is bonded in a 4-coordinate geometry to one V(4), one P(7), one O(17), and one O(31) atom. The O(26)-O(31) bond length is 1.14 Å. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Li(2) and one O(13) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one O(12) atom. In the twenty-ninth O site, O(29) is bonded in a 5-coordinate geometry to one Li(2), one V(4), one P(2), one O(15), and one O(22) atom. In the thirtieth O site, O(30) is bonded in a 2-coordinate geometry to one P(1) and one O(23) atom. In the thirty-first O site, O(31) is bonded in a 3-coordinate geometry to one V(4), one P(6), and one O(26) atom. In the thirty-second O site, O(32) is bonded in a single-bond geometry to one P(6) atom.