RbVOF3 crystallizes in the orthorhombic Pbam space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), one F(3), two equivalent F(1), and four equivalent F(2) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one F(2), two equivalent F(1), and two equivalent F(3) atoms. O(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent V(1) atoms.
RbVOF3 crystallizes in the orthorhombic Pbam space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent O(1), one F(3), two equivalent F(1), and four equivalent F(2) atoms. Both Rb(1)-O(1) bond lengths are 2.92 Å. The Rb(1)-F(3) bond length is 3.05 Å. Both Rb(1)-F(1) bond lengths are 2.84 Å. There are two shorter (2.91 Å) and two longer (3.05 Å) Rb(1)-F(2) bond lengths. V(1) is bonded in a 6-coordinate geometry to one O(1), one F(2), two equivalent F(1), and two equivalent F(3) atoms. The V(1)-O(1) bond length is 1.61 Å. The V(1)-F(2) bond length is 1.89 Å. There is one shorter (1.95 Å) and one longer (2.19 Å) V(1)-F(1) bond length. Both V(1)-F(3) bond lengths are 1.96 Å. O(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent V(1) atoms.