Zr3S2 is Ilmenite-derived structured and crystallizes in the trigonal R32 space group. Zr(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded to six equivalent Zr(1) atoms to form a mixture of distorted edge, face, and corner-sharing SZr6 pentagonal pyramids.
Zr3S2 is Ilmenite-derived structured and crystallizes in the trigonal R32 space group. Zr(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. There are two shorter (2.61 Å) and two longer (2.62 Å) Zr(1)-S(1) bond lengths. S(1) is bonded to six equivalent Zr(1) atoms to form a mixture of distorted edge, face, and corner-sharing SZr6 pentagonal pyramids.