Re2Pb3N4 crystallizes in the orthorhombic Pnna space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted see-saw-like geometry to one Pb(2), two equivalent N(1), and two equivalent N(2) atoms. In the second Re site, Re(2) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in an L-shaped geometry to one N(1) and one N(2) atom. In the second Pb site, Pb(2) is bonded in a distorted trigonal planar geometry to one Re(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Pb(1) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Re(1), one Re(2), one Pb(1), and one Pb(2) atom.
Re2Pb3N4 crystallizes in the orthorhombic Pnna space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted see-saw-like geometry to one Pb(2), two equivalent N(1), and two equivalent N(2) atoms. The Re(1)-Pb(2) bond length is 3.02 Å. Both Re(1)-N(1) bond lengths are 2.06 Å. Both Re(1)-N(2) bond lengths are 1.92 Å. In the second Re site, Re(2) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Re(2)-N(1) bond lengths are 1.87 Å. Both Re(2)-N(2) bond lengths are 2.00 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in an L-shaped geometry to one N(1) and one N(2) atom. The Pb(1)-N(1) bond length is 2.39 Å. The Pb(1)-N(2) bond length is 2.50 Å. In the second Pb site, Pb(2) is bonded in a distorted trigonal planar geometry to one Re(1) and two equivalent N(2) atoms. Both Pb(2)-N(2) bond lengths are 2.70 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Pb(1) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Re(1), one Re(2), one Pb(1), and one Pb(2) atom.