KCeWMnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Ce(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. Ce(1) is bonded to twelve equivalent O(1) atoms to form CeO12 cuboctahedra that share corners with twelve equivalent Ce(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Ce(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Ce(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent K(1), two equivalent Ce(1), one W(1), and one Mn(1) atom to form a mixture of distorted edge, corner, and face-sharing OK2Ce2MnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
KCeWMnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Ce(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.87 Å. Ce(1) is bonded to twelve equivalent O(1) atoms to form CeO12 cuboctahedra that share corners with twelve equivalent Ce(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. All Ce(1)-O(1) bond lengths are 2.87 Å. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Ce(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All W(1)-O(1) bond lengths are 1.94 Å. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Ce(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Mn(1)-O(1) bond lengths are 2.12 Å. O(1) is bonded to two equivalent K(1), two equivalent Ce(1), one W(1), and one Mn(1) atom to form a mixture of distorted edge, corner, and face-sharing OK2Ce2MnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°.