TiMoAs2 crystallizes in the orthorhombic Pmc2_1 space group. Ti(1) is bonded in a 8-coordinate geometry to two equivalent Mo(1), two equivalent As(2), and four equivalent As(1) atoms. Mo(1) is bonded in a 8-coordinate geometry to two equivalent Ti(1), two equivalent As(1), and four equivalent As(2) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 6-coordinate geometry to four equivalent Ti(1) and two equivalent Mo(1) atoms. In the second As site, As(2) is bonded in a 6-coordinate geometry to two equivalent Ti(1) and four equivalent Mo(1) atoms.
TiMoAs2 crystallizes in the orthorhombic Pmc2_1 space group. Ti(1) is bonded in a 8-coordinate geometry to two equivalent Mo(1), two equivalent As(2), and four equivalent As(1) atoms. Both Ti(1)-Mo(1) bond lengths are 2.96 Å. There is one shorter (2.51 Å) and one longer (2.78 Å) Ti(1)-As(2) bond length. There are two shorter (2.61 Å) and two longer (2.63 Å) Ti(1)-As(1) bond lengths. Mo(1) is bonded in a 8-coordinate geometry to two equivalent Ti(1), two equivalent As(1), and four equivalent As(2) atoms. There is one shorter (2.53 Å) and one longer (2.71 Å) Mo(1)-As(1) bond length. There are two shorter (2.58 Å) and two longer (2.61 Å) Mo(1)-As(2) bond lengths. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 6-coordinate geometry to four equivalent Ti(1) and two equivalent Mo(1) atoms. In the second As site, As(2) is bonded in a 6-coordinate geometry to two equivalent Ti(1) and four equivalent Mo(1) atoms.