KAgCl3 crystallizes in the trigonal R3c space group. K(1) is bonded in a 9-coordinate geometry to nine equivalent Cl(1) atoms. Ag(1) is bonded to six equivalent Cl(1) atoms to form corner-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles are 14°. Cl(1) is bonded to three equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing ClK3Ag2 square pyramids.
KAgCl3 crystallizes in the trigonal R3c space group. K(1) is bonded in a 9-coordinate geometry to nine equivalent Cl(1) atoms. There are a spread of K(1)-Cl(1) bond distances ranging from 3.28-3.59 Å. Ag(1) is bonded to six equivalent Cl(1) atoms to form corner-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles are 14°. All Ag(1)-Cl(1) bond lengths are 2.54 Å. Cl(1) is bonded to three equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing ClK3Ag2 square pyramids.