Li3VOF5 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(2), one F(1), one F(18), one F(4), and one F(7) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one F(19), one F(2), one F(20), one F(5), and one F(6) atom. In the third Li site, Li(3) is bonded to one O(1), one F(1), one F(2), one F(20), one F(3), and one F(5) atom to form distorted LiOF5 octahedra that share  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(10)OF5 octahedra, and edges with two equivalent V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(3), one F(10), one F(4), one F(6), one F(7), and one F(9) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(4), one F(10), one F(3), one F(4), and one F(7) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(3), one F(11), one F(2), one F(5), one F(6), and one F(8) atom. In the seventh Li site, Li(7) is bonded in a 6-coordinate geometry to one O(4), one F(11), one F(13), one F(14), one F(17), and one F(8) atom. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(3), one F(12), one F(15), one F(16), and one F(9) atom. In the ninth Li site, Li(9) is bonded to one O(4), one F(10), one F(12), one F(13), one F(15), and one F(9) atom to form distorted LiOF5 octahedra that share  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, and edges with two equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. In the tenth Li site, Li(10) is bonded to one O(1), one F(14), one F(16), one F(17), one F(19), and one F(20) atom to form distorted LiOF5 octahedra that share  a cornercorner with one V(1)O2F4 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(3)OF5 octahedra, and edges with two equivalent V(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. In the eleventh Li site, Li(11) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(13), one F(14), and one F(17) atom. In the twelfth Li site, Li(12) is bonded in a 5-coordinate geometry to one O(2), one F(12), one F(15), one F(18), and one F(19) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(10)OF5 octahedra and edges with two equivalent Li(3)OF5 octahedra. The corner-sharing octahedral tilt angles are 50°. In the second V site, V(2) is bonded to one O(3), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form VOF5 octahedra that share  a cornercorner with one Li(3)OF5 octahedra and  a cornercorner with one Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. In the third V site, V(3) is bonded to one O(4), one F(10), one F(11), one F(12), one F(13), and one F(14) atom to form VOF5 octahedra that share  a cornercorner with one Li(10)OF5 octahedra and edges with two equivalent Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles are 52°. In the fourth V site, V(4) is bonded to one F(15), one F(16), one F(17), one F(18), one F(19), and one F(20) atom to form VF6 octahedra that share  a cornercorner with one Li(3)OF5 octahedra,  a cornercorner with one Li(9)OF5 octahedra, and edges with two equivalent Li(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 53-56°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(10), one Li(11), one Li(2), one Li(3), and one V(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one Li(12), and one V(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(4), one Li(6), one Li(8), and one V(2) atom. In the fourth O site, O(4) is bonded to one Li(5), one Li(7), one Li(9), and one V(3) atom to form distorted OLi3V trigonal pyramids that share  a cornercorner with one F(15)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid, and  an edgeedge with one F(14)Li3V trigonal pyramid. There are twenty inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(11), one Li(3), and one V(1) atom to form a mixture of distorted corner and edge-sharing FLi3V trigonal pyramids. In the second F site, F(2) is bonded to one Li(2), one Li(3), one Li(6), and one V(1) atom to form a mixture of corner and edge-sharing FLi3V trigonal pyramids. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one V(1) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(4), one Li(5), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  an edgeedge with one F(1)Li3V trigonal pyramid, and  an edgeedge with one F(7)Li3V trigonal pyramid. In the fifth F site, F(5) is bonded to one Li(2), one Li(3), one Li(6), and one V(2) atom to form a mixture of distorted corner and edge-sharing FLi3V trigonal pyramids. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), one Li(6), and one V(2) atom. In the seventh F site, F(7) is bonded to one Li(1), one Li(4), one Li(5), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid,  a cornercorner with one F(5)Li3V trigonal pyramid, and  an edgeedge with one F(4)Li3V trigonal pyramid. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Li(6), one Li(7), and one V(2) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(4), one Li(8), one Li(9), and one V(2) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(4), one Li(5), one Li(9), and one V(3) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Li(6), one Li(7), and one V(3) atom. In the twelfth F site, F(12) is bonded to one Li(12), one Li(8), one Li(9), and one V(3) atom to form FLi3V trigonal pyramids that share  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(15)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  an edgeedge with one O(4)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li3V trigonal pyramid. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Li(11), one Li(7), one Li(9), and one V(3) atom. In the fourteenth F site, F(14) is bonded to one Li(10), one Li(11), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  an edgeedge with one O(4)Li3V trigonal pyramid, and  an edgeedge with one F(17)Li3V trigonal pyramid. In the fifteenth F site, F(15) is bonded to one Li(12), one Li(8), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid, and  an edgeedge with one F(19)Li3V trigonal pyramid. In the sixteenth F site, F(16) is bonded in a 3-coordinate geometry to one Li(10), one Li(8), and one V(4) atom. In the seventeenth F site, F(17) is bonded to one Li(10), one Li(11), one Li(7), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(15)Li3V trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and  an edgeedge with one F(19)Li3V trigonal pyramid. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Li(1), one Li(12), and one V(4) atom. In the nineteenth F site, F(19) is bonded to one Li(10), one Li(12), one Li(2), and one V(4) atom to form a mixture of distorted corner and edge-sharing FLi3V trigonal pyramids. In the twentieth F site, F(20) is bonded in a 4-coordinate geometry to one Li(10), one Li(2), one Li(3), and one V(4) atom.
Li3VOF5 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(2), one F(1), one F(18), one F(4), and one F(7) atom. The Li(1)-O(2) bond length is 2.08 Å. The Li(1)-F(1) bond length is 2.21 Å. The Li(1)-F(18) bond length is 1.88 Å. The Li(1)-F(4) bond length is 2.16 Å. The Li(1)-F(7) bond length is 1.97 Å. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one F(19), one F(2), one F(20), one F(5), and one F(6) atom. The Li(2)-O(1) bond length is 2.53 Å. The Li(2)-F(19) bond length is 1.93 Å. The Li(2)-F(2) bond length is 2.18 Å. The Li(2)-F(20) bond length is 2.13 Å. The Li(2)-F(5) bond length is 2.09 Å. The Li(2)-F(6) bond length is 1.93 Å. In the third Li site, Li(3) is bonded to one O(1), one F(1), one F(2), one F(20), one F(3), and one F(5) atom to form distorted LiOF5 octahedra that share  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent Li(10)OF5 octahedra, and edges with two equivalent V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. The Li(3)-O(1) bond length is 2.22 Å. The Li(3)-F(1) bond length is 2.28 Å. The Li(3)-F(2) bond length is 1.92 Å. The Li(3)-F(20) bond length is 2.09 Å. The Li(3)-F(3) bond length is 2.12 Å. The Li(3)-F(5) bond length is 1.92 Å. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(3), one F(10), one F(4), one F(6), one F(7), and one F(9) atom. The Li(4)-O(3) bond length is 2.37 Å. The Li(4)-F(10) bond length is 2.19 Å. The Li(4)-F(4) bond length is 1.95 Å. The Li(4)-F(6) bond length is 2.06 Å. The Li(4)-F(7) bond length is 2.00 Å. The Li(4)-F(9) bond length is 2.12 Å. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(4), one F(10), one F(3), one F(4), and one F(7) atom. The Li(5)-O(4) bond length is 1.98 Å. The Li(5)-F(10) bond length is 2.16 Å. The Li(5)-F(3) bond length is 1.92 Å. The Li(5)-F(4) bond length is 2.04 Å. The Li(5)-F(7) bond length is 2.17 Å. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(3), one F(11), one F(2), one F(5), one F(6), and one F(8) atom. The Li(6)-O(3) bond length is 2.29 Å. The Li(6)-F(11) bond length is 1.92 Å. The Li(6)-F(2) bond length is 1.99 Å. The Li(6)-F(5) bond length is 2.24 Å. The Li(6)-F(6) bond length is 2.51 Å. The Li(6)-F(8) bond length is 1.94 Å. In the seventh Li site, Li(7) is bonded in a 6-coordinate geometry to one O(4), one F(11), one F(13), one F(14), one F(17), and one F(8) atom. The Li(7)-O(4) bond length is 2.24 Å. The Li(7)-F(11) bond length is 1.93 Å. The Li(7)-F(13) bond length is 2.50 Å. The Li(7)-F(14) bond length is 2.25 Å. The Li(7)-F(17) bond length is 2.01 Å. The Li(7)-F(8) bond length is 1.91 Å. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(3), one F(12), one F(15), one F(16), and one F(9) atom. The Li(8)-O(3) bond length is 1.97 Å. The Li(8)-F(12) bond length is 2.18 Å. The Li(8)-F(15) bond length is 2.07 Å. The Li(8)-F(16) bond length is 1.89 Å. The Li(8)-F(9) bond length is 2.13 Å. In the ninth Li site, Li(9) is bonded to one O(4), one F(10), one F(12), one F(13), one F(15), and one F(9) atom to form distorted LiOF5 octahedra that share  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, and edges with two equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. The Li(9)-O(4) bond length is 2.30 Å. The Li(9)-F(10) bond length is 2.11 Å. The Li(9)-F(12) bond length is 2.00 Å. The Li(9)-F(13) bond length is 2.05 Å. The Li(9)-F(15) bond length is 1.92 Å. The Li(9)-F(9) bond length is 2.17 Å. In the tenth Li site, Li(10) is bonded to one O(1), one F(14), one F(16), one F(17), one F(19), and one F(20) atom to form distorted LiOF5 octahedra that share  a cornercorner with one V(1)O2F4 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent Li(3)OF5 octahedra, and edges with two equivalent V(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. The Li(10)-O(1) bond length is 2.17 Å. The Li(10)-F(14) bond length is 1.93 Å. The Li(10)-F(16) bond length is 2.04 Å. The Li(10)-F(17) bond length is 1.96 Å. The Li(10)-F(19) bond length is 2.29 Å. The Li(10)-F(20) bond length is 2.12 Å. In the eleventh Li site, Li(11) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(13), one F(14), and one F(17) atom. The Li(11)-O(1) bond length is 2.18 Å. The Li(11)-F(1) bond length is 1.97 Å. The Li(11)-F(13) bond length is 1.91 Å. The Li(11)-F(14) bond length is 2.08 Å. The Li(11)-F(17) bond length is 2.15 Å. In the twelfth Li site, Li(12) is bonded in a 5-coordinate geometry to one O(2), one F(12), one F(15), one F(18), and one F(19) atom. The Li(12)-O(2) bond length is 1.98 Å. The Li(12)-F(12) bond length is 2.01 Å. The Li(12)-F(15) bond length is 2.19 Å. The Li(12)-F(18) bond length is 1.96 Å. The Li(12)-F(19) bond length is 2.15 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom to form distorted VO2F4 octahedra that share  a cornercorner with one Li(10)OF5 octahedra and edges with two equivalent Li(3)OF5 octahedra. The corner-sharing octahedral tilt angles are 50°. The V(1)-O(1) bond length is 1.70 Å. The V(1)-O(2) bond length is 1.67 Å. The V(1)-F(1) bond length is 1.93 Å. The V(1)-F(2) bond length is 2.12 Å. The V(1)-F(3) bond length is 1.92 Å. The V(1)-F(4) bond length is 2.11 Å. In the second V site, V(2) is bonded to one O(3), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form VOF5 octahedra that share  a cornercorner with one Li(3)OF5 octahedra and  a cornercorner with one Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. The V(2)-O(3) bond length is 1.67 Å. The V(2)-F(5) bond length is 1.99 Å. The V(2)-F(6) bond length is 2.03 Å. The V(2)-F(7) bond length is 2.00 Å. The V(2)-F(8) bond length is 1.95 Å. The V(2)-F(9) bond length is 1.99 Å. In the third V site, V(3) is bonded to one O(4), one F(10), one F(11), one F(12), one F(13), and one F(14) atom to form VOF5 octahedra that share  a cornercorner with one Li(10)OF5 octahedra and edges with two equivalent Li(9)OF5 octahedra. The corner-sharing octahedral tilt angles are 52°. The V(3)-O(4) bond length is 1.67 Å. The V(3)-F(10) bond length is 1.99 Å. The V(3)-F(11) bond length is 1.95 Å. The V(3)-F(12) bond length is 1.99 Å. The V(3)-F(13) bond length is 2.03 Å. The V(3)-F(14) bond length is 1.99 Å. In the fourth V site, V(4) is bonded to one F(15), one F(16), one F(17), one F(18), one F(19), and one F(20) atom to form VF6 octahedra that share  a cornercorner with one Li(3)OF5 octahedra,  a cornercorner with one Li(9)OF5 octahedra, and edges with two equivalent Li(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 53-56°. The V(4)-F(15) bond length is 1.99 Å. The V(4)-F(16) bond length is 1.96 Å. The V(4)-F(17) bond length is 1.99 Å. The V(4)-F(18) bond length is 1.96 Å. The V(4)-F(19) bond length is 1.97 Å. The V(4)-F(20) bond length is 2.00 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(10), one Li(11), one Li(2), one Li(3), and one V(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one Li(12), and one V(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(4), one Li(6), one Li(8), and one V(2) atom. In the fourth O site, O(4) is bonded to one Li(5), one Li(7), one Li(9), and one V(3) atom to form distorted OLi3V trigonal pyramids that share  a cornercorner with one F(15)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid, and  an edgeedge with one F(14)Li3V trigonal pyramid. There are twenty inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(11), one Li(3), and one V(1) atom to form a mixture of distorted corner and edge-sharing FLi3V trigonal pyramids. In the second F site, F(2) is bonded to one Li(2), one Li(3), one Li(6), and one V(1) atom to form a mixture of corner and edge-sharing FLi3V trigonal pyramids. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one V(1) atom. In the fourth F site, F(4) is bonded to one Li(1), one Li(4), one Li(5), and one V(1) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(2)Li3V trigonal pyramid,  a cornercorner with one F(7)Li3V trigonal pyramid,  an edgeedge with one F(1)Li3V trigonal pyramid, and  an edgeedge with one F(7)Li3V trigonal pyramid. In the fifth F site, F(5) is bonded to one Li(2), one Li(3), one Li(6), and one V(2) atom to form a mixture of distorted corner and edge-sharing FLi3V trigonal pyramids. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), one Li(6), and one V(2) atom. In the seventh F site, F(7) is bonded to one Li(1), one Li(4), one Li(5), and one V(2) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(4)Li3V trigonal pyramid,  a cornercorner with one F(5)Li3V trigonal pyramid, and  an edgeedge with one F(4)Li3V trigonal pyramid. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Li(6), one Li(7), and one V(2) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(4), one Li(8), one Li(9), and one V(2) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(4), one Li(5), one Li(9), and one V(3) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Li(6), one Li(7), and one V(3) atom. In the twelfth F site, F(12) is bonded to one Li(12), one Li(8), one Li(9), and one V(3) atom to form FLi3V trigonal pyramids that share  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(15)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  an edgeedge with one O(4)Li3V trigonal pyramid, and  an edgeedge with one F(15)Li3V trigonal pyramid. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Li(11), one Li(7), one Li(9), and one V(3) atom. In the fourteenth F site, F(14) is bonded to one Li(10), one Li(11), one Li(7), and one V(3) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  a cornercorner with one F(19)Li3V trigonal pyramid,  an edgeedge with one O(4)Li3V trigonal pyramid, and  an edgeedge with one F(17)Li3V trigonal pyramid. In the fifteenth F site, F(15) is bonded to one Li(12), one Li(8), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid,  an edgeedge with one F(12)Li3V trigonal pyramid, and  an edgeedge with one F(19)Li3V trigonal pyramid. In the sixteenth F site, F(16) is bonded in a 3-coordinate geometry to one Li(10), one Li(8), and one V(4) atom. In the seventeenth F site, F(17) is bonded to one Li(10), one Li(11), one Li(7), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(4)Li3V trigonal pyramid,  a cornercorner with one F(1)Li3V trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(15)Li3V trigonal pyramid,  an edgeedge with one F(14)Li3V trigonal pyramid, and  an edgeedge with one F(19)Li3V trigonal pyramid. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Li(1), one Li(12), and one V(4) atom. In the nineteenth F site, F(19) is bonded to one Li(10), one Li(12), one Li(2), and one V(4) atom to form a mixture of distorted corner and edge-sharing FLi3V trigonal pyramids. In the twentieth F site, F(20) is bonded in a 4-coordinate geometry to one Li(10), one Li(2), one Li(3), and one V(4) atom.