CdSnO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Sn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 36-38°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Cd(1) and two equivalent Sn(1) atoms to form distorted corner-sharing OCd2Sn2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Cd(1) and two equivalent Sn(1) atoms.
CdSnO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. There is one shorter (2.25 Å) and one longer (2.36 Å) Cd(1)-O(1) bond length. There are two shorter (2.26 Å) and two longer (2.62 Å) Cd(1)-O(2) bond lengths. Sn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 36-38°. Both Sn(1)-O(1) bond lengths are 2.09 Å. All Sn(1)-O(2) bond lengths are 2.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Cd(1) and two equivalent Sn(1) atoms to form distorted corner-sharing OCd2Sn2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Cd(1) and two equivalent Sn(1) atoms.