TlCoTl2Cl5 crystallizes in the tetragonal I4/mcm space group. The structure consists of four 7440-28-0 atoms inside a CoTl2Cl5 framework. In the CoTl2Cl5 framework, Co(1) is bonded in a tetrahedral geometry to four equivalent Cl(2) atoms. Tl(2) is bonded in a 4-coordinate geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a square co-planar geometry to four equivalent Tl(2) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Co(1) and one Tl(2) atom.
TlCoTl2Cl5 crystallizes in the tetragonal I4/mcm space group. The structure consists of four 7440-28-0 atoms inside a CoTl2Cl5 framework. In the CoTl2Cl5 framework, Co(1) is bonded in a tetrahedral geometry to four equivalent Cl(2) atoms. All Co(1)-Cl(2) bond lengths are 2.25 Å. Tl(2) is bonded in a 4-coordinate geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. Both Tl(2)-Cl(1) bond lengths are 3.16 Å. Both Tl(2)-Cl(2) bond lengths are 3.18 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a square co-planar geometry to four equivalent Tl(2) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Co(1) and one Tl(2) atom.