LiWAgZn2O6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 tetrahedra and corners with four equivalent Zn(2)O4 tetrahedra. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 28-62°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-57°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one W(1), one Ag(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one Ag(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a tetrahedral geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one W(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Li(1), one W(1), one Ag(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom.
LiWAgZn2O6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. The Li(1)-O(1) bond length is 2.11 Å. The Li(1)-O(3) bond length is 2.10 Å. The Li(1)-O(4) bond length is 2.03 Å. The Li(1)-O(5) bond length is 2.09 Å. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 tetrahedra and corners with four equivalent Zn(2)O4 tetrahedra. The W(1)-O(1) bond length is 1.99 Å. The W(1)-O(2) bond length is 1.92 Å. The W(1)-O(3) bond length is 2.04 Å. The W(1)-O(4) bond length is 1.92 Å. The W(1)-O(5) bond length is 1.95 Å. The W(1)-O(6) bond length is 1.97 Å. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(6) atom. The Ag(1)-O(1) bond length is 2.46 Å. The Ag(1)-O(2) bond length is 2.26 Å. The Ag(1)-O(5) bond length is 2.34 Å. The Ag(1)-O(6) bond length is 2.42 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 28-62°. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 1.96 Å. The Zn(1)-O(5) bond length is 1.92 Å. The Zn(1)-O(6) bond length is 2.05 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-57°. The Zn(2)-O(1) bond length is 1.98 Å. The Zn(2)-O(3) bond length is 2.02 Å. The Zn(2)-O(4) bond length is 1.92 Å. The Zn(2)-O(6) bond length is 2.12 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one W(1), one Ag(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one Ag(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a tetrahedral geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one W(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Li(1), one W(1), one Ag(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom.