WMoRe2Si8 crystallizes in the tetragonal P4mm space group. W(1) is bonded in a distorted q6 geometry to one Si(1), one Si(6), four equivalent Si(2), and four equivalent Si(5) atoms. Mo(1) is bonded in a distorted q6 geometry to one Si(4), one Si(5), four equivalent Si(1), and four equivalent Si(8) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted q6 geometry to one Si(2), one Si(7), four equivalent Si(3), and four equivalent Si(6) atoms. In the second Re site, Re(2) is bonded in a distorted q6 geometry to one Si(3), one Si(8), four equivalent Si(4), and four equivalent Si(7) atoms. There are eight inequivalent Si sites. In the first Si site, Si(1) is bonded in a 10-coordinate geometry to one W(1), four equivalent Mo(1), one Si(8), and four equivalent Si(5) atoms. In the second Si site, Si(2) is bonded in a 10-coordinate geometry to four equivalent W(1), one Re(1), one Si(5), and four equivalent Si(6) atoms. In the third Si site, Si(3) is bonded in a distorted q6 geometry to one Re(2), four equivalent Re(1), one Si(6), and four equivalent Si(7) atoms. In the fourth Si site, Si(4) is bonded in a 10-coordinate geometry to one Mo(1), four equivalent Re(2), one Si(7), and four equivalent Si(8) atoms. In the fifth Si site, Si(5) is bonded in a 10-coordinate geometry to four equivalent W(1), one Mo(1), one Si(2), and four equivalent Si(1) atoms. In the sixth Si site, Si(6) is bonded in a 10-coordinate geometry to one W(1), four equivalent Re(1), one Si(3), and four equivalent Si(2) atoms. In the seventh Si site, Si(7) is bonded in a distorted q6 geometry to one Re(1), four equivalent Re(2), one Si(4), and four equivalent Si(3) atoms. In the eighth Si site, Si(8) is bonded in a 10-coordinate geometry to four equivalent Mo(1), one Re(2), one Si(1), and four equivalent Si(4) atoms.
WMoRe2Si8 crystallizes in the tetragonal P4mm space group. W(1) is bonded in a distorted q6 geometry to one Si(1), one Si(6), four equivalent Si(2), and four equivalent Si(5) atoms. The W(1)-Si(1) bond length is 2.65 Å. The W(1)-Si(6) bond length is 2.58 Å. All W(1)-Si(2) bond lengths are 2.61 Å. All W(1)-Si(5) bond lengths are 2.64 Å. Mo(1) is bonded in a distorted q6 geometry to one Si(4), one Si(5), four equivalent Si(1), and four equivalent Si(8) atoms. The Mo(1)-Si(4) bond length is 2.58 Å. The Mo(1)-Si(5) bond length is 2.64 Å. All Mo(1)-Si(1) bond lengths are 2.63 Å. All Mo(1)-Si(8) bond lengths are 2.60 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted q6 geometry to one Si(2), one Si(7), four equivalent Si(3), and four equivalent Si(6) atoms. The Re(1)-Si(2) bond length is 2.65 Å. The Re(1)-Si(7) bond length is 2.59 Å. All Re(1)-Si(3) bond lengths are 2.61 Å. All Re(1)-Si(6) bond lengths are 2.64 Å. In the second Re site, Re(2) is bonded in a distorted q6 geometry to one Si(3), one Si(8), four equivalent Si(4), and four equivalent Si(7) atoms. The Re(2)-Si(3) bond length is 2.59 Å. The Re(2)-Si(8) bond length is 2.66 Å. All Re(2)-Si(4) bond lengths are 2.65 Å. All Re(2)-Si(7) bond lengths are 2.61 Å. There are eight inequivalent Si sites. In the first Si site, Si(1) is bonded in a 10-coordinate geometry to one W(1), four equivalent Mo(1), one Si(8), and four equivalent Si(5) atoms. The Si(1)-Si(8) bond length is 2.62 Å. All Si(1)-Si(5) bond lengths are 2.62 Å. In the second Si site, Si(2) is bonded in a 10-coordinate geometry to four equivalent W(1), one Re(1), one Si(5), and four equivalent Si(6) atoms. The Si(2)-Si(5) bond length is 2.63 Å. All Si(2)-Si(6) bond lengths are 2.61 Å. In the third Si site, Si(3) is bonded in a distorted q6 geometry to one Re(2), four equivalent Re(1), one Si(6), and four equivalent Si(7) atoms. The Si(3)-Si(6) bond length is 2.66 Å. All Si(3)-Si(7) bond lengths are 2.61 Å. In the fourth Si site, Si(4) is bonded in a 10-coordinate geometry to one Mo(1), four equivalent Re(2), one Si(7), and four equivalent Si(8) atoms. The Si(4)-Si(7) bond length is 2.66 Å. All Si(4)-Si(8) bond lengths are 2.61 Å. In the fifth Si site, Si(5) is bonded in a 10-coordinate geometry to four equivalent W(1), one Mo(1), one Si(2), and four equivalent Si(1) atoms. In the sixth Si site, Si(6) is bonded in a 10-coordinate geometry to one W(1), four equivalent Re(1), one Si(3), and four equivalent Si(2) atoms. In the seventh Si site, Si(7) is bonded in a distorted q6 geometry to one Re(1), four equivalent Re(2), one Si(4), and four equivalent Si(3) atoms. In the eighth Si site, Si(8) is bonded in a 10-coordinate geometry to four equivalent Mo(1), one Re(2), one Si(1), and four equivalent Si(4) atoms.