CsCHO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 13-coordinate geometry to one C(1), two equivalent H(1), three equivalent O(2), three equivalent O(3), and four equivalent O(1) atoms. C(1) is bonded in a trigonal planar geometry to one Cs(1), one O(1), one O(2), and one O(3) atom. H(1) is bonded in a distorted linear geometry to two equivalent Cs(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to three equivalent Cs(1), one C(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to three equivalent Cs(1), one C(1), and one H(1) atom.
CsCHO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 13-coordinate geometry to one C(1), two equivalent H(1), three equivalent O(2), three equivalent O(3), and four equivalent O(1) atoms. The Cs(1)-C(1) bond length is 3.56 Å. There is one shorter (3.22 Å) and one longer (3.49 Å) Cs(1)-H(1) bond length. There are a spread of Cs(1)-O(2) bond distances ranging from 3.19-3.53 Å. There are a spread of Cs(1)-O(3) bond distances ranging from 3.14-3.65 Å. There are a spread of Cs(1)-O(1) bond distances ranging from 3.11-3.36 Å. C(1) is bonded in a trigonal planar geometry to one Cs(1), one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.38 Å. H(1) is bonded in a distorted linear geometry to two equivalent Cs(1), one O(2), and one O(3) atom. The H(1)-O(2) bond length is 1.59 Å. The H(1)-O(3) bond length is 1.03 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to three equivalent Cs(1), one C(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to three equivalent Cs(1), one C(1), and one H(1) atom.