NdLa(CoO3)2 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. La(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(4), and four equivalent O(2) atoms. Co(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 20-23°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Nd(1), one La(1), and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Co(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Nd(1) and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent La(1) and two equivalent Co(1) atoms.
NdLa(CoO3)2 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. Both Nd(1)-O(2) bond lengths are 2.66 Å. There is one shorter (2.40 Å) and one longer (2.50 Å) Nd(1)-O(3) bond length. There are two shorter (2.43 Å) and two longer (2.62 Å) Nd(1)-O(1) bond lengths. La(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(4), and four equivalent O(2) atoms. Both La(1)-O(1) bond lengths are 2.74 Å. There is one shorter (2.42 Å) and one longer (2.57 Å) La(1)-O(4) bond length. There are two shorter (2.43 Å) and two longer (2.72 Å) La(1)-O(2) bond lengths. Co(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 20-23°. The Co(1)-O(3) bond length is 1.97 Å. The Co(1)-O(4) bond length is 1.99 Å. Both Co(1)-O(1) bond lengths are 1.98 Å. There is one shorter (1.97 Å) and one longer (1.98 Å) Co(1)-O(2) bond length. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Nd(1), one La(1), and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Nd(1), two equivalent La(1), and two equivalent Co(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Nd(1) and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent La(1) and two equivalent Co(1) atoms.