CaUI6 is Upper Bainite-derived structured and crystallizes in the trigonal P-31c space group. Ca(1) is bonded to six equivalent I(1) atoms to form CaI6 octahedra that share corners with six equivalent U(1)I6 octahedra. The corner-sharing octahedral tilt angles are 48°. U(1) is bonded to six equivalent I(1) atoms to form UI6 octahedra that share corners with six equivalent Ca(1)I6 octahedra. The corner-sharing octahedral tilt angles are 48°. I(1) is bonded in a bent 120 degrees geometry to one Ca(1) and one U(1) atom.
CaUI6 is Upper Bainite-derived structured and crystallizes in the trigonal P-31c space group. Ca(1) is bonded to six equivalent I(1) atoms to form CaI6 octahedra that share corners with six equivalent U(1)I6 octahedra. The corner-sharing octahedral tilt angles are 48°. All Ca(1)-I(1) bond lengths are 3.17 Å. U(1) is bonded to six equivalent I(1) atoms to form UI6 octahedra that share corners with six equivalent Ca(1)I6 octahedra. The corner-sharing octahedral tilt angles are 48°. All U(1)-I(1) bond lengths are 3.02 Å. I(1) is bonded in a bent 120 degrees geometry to one Ca(1) and one U(1) atom.