BCNH2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one BCNH2 cluster. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one C(3), one N(2), one H(2), and one H(5) atom. In the second B site, B(2) is bonded in a tetrahedral geometry to one C(2), one N(1), one H(4), and one H(6) atom. In the third B site, B(3) is bonded in a tetrahedral geometry to one C(1), one N(3), one H(1), and one H(3) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one B(3) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one B(2) and one N(3) atom. In the third C site, C(3) is bonded in a linear geometry to one B(1) and one N(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one B(2) and one C(3) atom. In the second N site, N(2) is bonded in a linear geometry to one B(1) and one C(1) atom. In the third N site, N(3) is bonded in a linear geometry to one B(3) and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one B(2) atom.
BCNH2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one BCNH2 cluster. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one C(3), one N(2), one H(2), and one H(5) atom. The B(1)-C(3) bond length is 1.57 Å. The B(1)-N(2) bond length is 1.52 Å. The B(1)-H(2) bond length is 1.21 Å. The B(1)-H(5) bond length is 1.21 Å. In the second B site, B(2) is bonded in a tetrahedral geometry to one C(2), one N(1), one H(4), and one H(6) atom. The B(2)-C(2) bond length is 1.57 Å. The B(2)-N(1) bond length is 1.52 Å. The B(2)-H(4) bond length is 1.21 Å. The B(2)-H(6) bond length is 1.21 Å. In the third B site, B(3) is bonded in a tetrahedral geometry to one C(1), one N(3), one H(1), and one H(3) atom. The B(3)-C(1) bond length is 1.57 Å. The B(3)-N(3) bond length is 1.52 Å. The B(3)-H(1) bond length is 1.21 Å. The B(3)-H(3) bond length is 1.21 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one B(3) and one N(2) atom. The C(1)-N(2) bond length is 1.16 Å. In the second C site, C(2) is bonded in a linear geometry to one B(2) and one N(3) atom. The C(2)-N(3) bond length is 1.16 Å. In the third C site, C(3) is bonded in a linear geometry to one B(1) and one N(1) atom. The C(3)-N(1) bond length is 1.16 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one B(2) and one C(3) atom. In the second N site, N(2) is bonded in a linear geometry to one B(1) and one C(1) atom. In the third N site, N(3) is bonded in a linear geometry to one B(3) and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one B(2) atom.