IrTeO6 crystallizes in the monoclinic P2_1/c space group. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-44°. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TeO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-44°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ir(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ir(1) and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Ir(1) and one Te(1) atom.
IrTeO6 crystallizes in the monoclinic P2_1/c space group. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-44°. Both Ir(1)-O(1) bond lengths are 1.93 Å. Both Ir(1)-O(2) bond lengths are 1.93 Å. Both Ir(1)-O(3) bond lengths are 1.94 Å. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TeO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-44°. Both Te(1)-O(1) bond lengths are 1.98 Å. Both Te(1)-O(2) bond lengths are 1.98 Å. Both Te(1)-O(3) bond lengths are 1.98 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ir(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ir(1) and one Te(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Ir(1) and one Te(1) atom.