Ni(NO4)2(PO2F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four fluoro(hydroxy)oxophosphanium molecules and two Ni(NO4)2 clusters. In each Ni(NO4)2 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(6) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(5) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Ni(1) and one N(1) atom.
Ni(NO4)2(PO2F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four fluoro(hydroxy)oxophosphanium molecules and two Ni(NO4)2 clusters. In each Ni(NO4)2 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Both Ni(1)-O(4) bond lengths are 1.85 Å. Both Ni(1)-O(5) bond lengths are 1.86 Å. Both Ni(1)-O(6) bond lengths are 2.59 Å. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(6) atom. The N(1)-O(3) bond length is 1.22 Å. The N(1)-O(6) bond length is 1.22 Å. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(5) atom. The O(4)-O(5) bond length is 1.33 Å. In the third O site, O(5) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Ni(1) and one N(1) atom.