VSO8O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four VSO8 clusters. In each VSO8 cluster, V(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one V(1)O5 trigonal bipyramid. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom.
VSO8O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four VSO8 clusters. In each VSO8 cluster, V(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra. The V(1)-O(1) bond length is 1.86 Å. The V(1)-O(2) bond length is 1.83 Å. The V(1)-O(4) bond length is 1.63 Å. The V(1)-O(5) bond length is 1.87 Å. The V(1)-O(6) bond length is 1.95 Å. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one V(1)O5 trigonal bipyramid. The S(1)-O(6) bond length is 1.53 Å. The S(1)-O(7) bond length is 1.48 Å. The S(1)-O(8) bond length is 1.48 Å. The S(1)-O(9) bond length is 1.47 Å. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom.