TcB is alpha carbon monoxide-like structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of two TcB clusters. Tc(1) is bonded in a single-bond geometry to one B(1) atom. B(1) is bonded in a single-bond geometry to one Tc(1) atom.
TcB is alpha carbon monoxide-like structured and crystallizes in the hexagonal P6_3mc space group. The structure is zero-dimensional and consists of two TcB clusters. Tc(1) is bonded in a single-bond geometry to one B(1) atom. The Tc(1)-B(1) bond length is 1.77 Å. B(1) is bonded in a single-bond geometry to one Tc(1) atom.