LiAg2F4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent F(1) atoms to form LiF4 tetrahedra that share corners with twelve equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Li(1)F4 tetrahedra and edges with six equivalent Ag(1)F6 octahedra. F(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Ag(1) atoms.
LiAg2F4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent F(1) atoms to form LiF4 tetrahedra that share corners with twelve equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. All Li(1)-F(1) bond lengths are 1.97 Å. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Li(1)F4 tetrahedra and edges with six equivalent Ag(1)F6 octahedra. All Ag(1)-F(1) bond lengths are 2.37 Å. F(1) is bonded in a rectangular see-saw-like geometry to one Li(1) and three equivalent Ag(1) atoms.