CaClF is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ca(1) is bonded in a 9-coordinate geometry to five equivalent Cl(1) and four equivalent F(1) atoms. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Ca(1) atoms. F(1) is bonded to four equivalent Ca(1) atoms to form a mixture of corner and edge-sharing FCa4 tetrahedra.
CaClF is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ca(1) is bonded in a 9-coordinate geometry to five equivalent Cl(1) and four equivalent F(1) atoms. There are four shorter (2.95 Å) and one longer (3.08 Å) Ca(1)-Cl(1) bond length. All Ca(1)-F(1) bond lengths are 2.35 Å. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Ca(1) atoms. F(1) is bonded to four equivalent Ca(1) atoms to form a mixture of corner and edge-sharing FCa4 tetrahedra.