ZrOsGe crystallizes in the hexagonal P-62m space group. Zr(1) is bonded in a 11-coordinate geometry to six equivalent Os(1), one Ge(2), and four equivalent Ge(1) atoms. Os(1) is bonded in a 12-coordinate geometry to six equivalent Zr(1), two equivalent Os(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to six equivalent Zr(1) and three equivalent Os(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Zr(1) and six equivalent Os(1) atoms.
ZrOsGe crystallizes in the hexagonal P-62m space group. Zr(1) is bonded in a 11-coordinate geometry to six equivalent Os(1), one Ge(2), and four equivalent Ge(1) atoms. There are two shorter (2.97 Å) and four longer (3.10 Å) Zr(1)-Os(1) bond lengths. The Zr(1)-Ge(2) bond length is 2.81 Å. All Zr(1)-Ge(1) bond lengths are 2.78 Å. Os(1) is bonded in a 12-coordinate geometry to six equivalent Zr(1), two equivalent Os(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. Both Os(1)-Os(1) bond lengths are 2.86 Å. Both Os(1)-Ge(1) bond lengths are 2.60 Å. Both Os(1)-Ge(2) bond lengths are 2.52 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to six equivalent Zr(1) and three equivalent Os(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Zr(1) and six equivalent Os(1) atoms.