SmV2O2 crystallizes in the tetragonal I4_1/amd space group. Sm(1) is bonded in a linear geometry to two equivalent O(1) atoms. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded to one Sm(1) and three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OSmV3 trigonal pyramids.
SmV2O2 crystallizes in the tetragonal I4_1/amd space group. Sm(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Sm(1)-O(1) bond lengths are 2.24 Å. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. There is one shorter (2.06 Å) and two longer (2.29 Å) V(1)-O(1) bond lengths. O(1) is bonded to one Sm(1) and three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OSmV3 trigonal pyramids.