LaCrZnSnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-42°. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom. Sn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-42°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one La(1), one Cr(1), one Zn(1), and one Sn(1) atom to form distorted corner-sharing OLaZnCrSn tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sn(1) atom. In the sixth O site, O(6) is bonded to one La(1), one Cr(1), one Zn(1), and one Sn(1) atom to form distorted corner-sharing OLaZnCrSn tetrahedra.
LaCrZnSnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. The La(1)-O(1) bond length is 2.35 Å. The La(1)-O(2) bond length is 2.34 Å. The La(1)-O(3) bond length is 2.33 Å. The La(1)-O(6) bond length is 2.56 Å. There is one shorter (2.69 Å) and one longer (2.85 Å) La(1)-O(4) bond length. There is one shorter (2.69 Å) and one longer (2.84 Å) La(1)-O(5) bond length. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-42°. The Cr(1)-O(1) bond length is 2.03 Å. The Cr(1)-O(2) bond length is 1.97 Å. The Cr(1)-O(3) bond length is 1.98 Å. The Cr(1)-O(4) bond length is 2.07 Å. The Cr(1)-O(5) bond length is 2.08 Å. The Cr(1)-O(6) bond length is 2.11 Å. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.39 Å. The Zn(1)-O(4) bond length is 2.15 Å. The Zn(1)-O(5) bond length is 2.16 Å. The Zn(1)-O(6) bond length is 2.08 Å. Sn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-42°. The Sn(1)-O(1) bond length is 2.10 Å. The Sn(1)-O(2) bond length is 2.06 Å. The Sn(1)-O(3) bond length is 2.04 Å. The Sn(1)-O(4) bond length is 2.11 Å. The Sn(1)-O(5) bond length is 2.11 Å. The Sn(1)-O(6) bond length is 2.13 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded to one La(1), one Cr(1), one Zn(1), and one Sn(1) atom to form distorted corner-sharing OLaZnCrSn tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(1), one Cr(1), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sn(1) atom. In the sixth O site, O(6) is bonded to one La(1), one Cr(1), one Zn(1), and one Sn(1) atom to form distorted corner-sharing OLaZnCrSn tetrahedra.