NaClO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.
NaClO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.47 Å) and three longer (2.48 Å) Na(1)-O(1) bond lengths. O(1) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.51 Å. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.