Ba2MnFe2CdF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(3), one F(6), one F(7), two equivalent F(1), two equivalent F(2), two equivalent F(5), and three equivalent F(4) atoms. Mn(1) is bonded to two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms to form MnF6 octahedra that share corners with four equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. Fe(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form FeF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. Cd(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(3) is bonded in a distorted trigonal planar geometry to one Ba(1), one Fe(1), and one Cd(1) atom. In the second F site, F(4) is bonded in a distorted single-bond geometry to three equivalent Ba(1) and one Fe(1) atom. In the third F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Mn(1), and one Fe(1) atom. In the fourth F site, F(6) is bonded in a trigonal planar geometry to one Ba(1), one Mn(1), and one Cd(1) atom. In the fifth F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Mn(1), and one Fe(1) atom. In the sixth F site, F(1) is bonded in a 2-coordinate geometry to two equivalent Ba(1), one Fe(1), and one Cd(1) atom. In the seventh F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Fe(1) atom.
Ba2MnFe2CdF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(3), one F(6), one F(7), two equivalent F(1), two equivalent F(2), two equivalent F(5), and three equivalent F(4) atoms. The Ba(1)-F(3) bond length is 2.75 Å. The Ba(1)-F(6) bond length is 2.73 Å. The Ba(1)-F(7) bond length is 2.82 Å. There is one shorter (3.12 Å) and one longer (3.18 Å) Ba(1)-F(1) bond length. There is one shorter (2.77 Å) and one longer (2.85 Å) Ba(1)-F(2) bond length. There is one shorter (2.92 Å) and one longer (3.03 Å) Ba(1)-F(5) bond length. There are a spread of Ba(1)-F(4) bond distances ranging from 2.82-3.35 Å. Mn(1) is bonded to two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms to form MnF6 octahedra that share corners with four equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. Both Mn(1)-F(5) bond lengths are 2.24 Å. Both Mn(1)-F(6) bond lengths are 2.09 Å. Both Mn(1)-F(7) bond lengths are 2.15 Å. Fe(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form FeF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. The Fe(1)-F(1) bond length is 1.94 Å. The Fe(1)-F(2) bond length is 1.98 Å. The Fe(1)-F(3) bond length is 1.94 Å. The Fe(1)-F(4) bond length is 1.93 Å. The Fe(1)-F(5) bond length is 2.00 Å. The Fe(1)-F(7) bond length is 1.96 Å. Cd(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. Both Cd(1)-F(1) bond lengths are 2.39 Å. Both Cd(1)-F(3) bond lengths are 2.35 Å. Both Cd(1)-F(6) bond lengths are 2.22 Å. There are seven inequivalent F sites. In the first F site, F(3) is bonded in a distorted trigonal planar geometry to one Ba(1), one Fe(1), and one Cd(1) atom. In the second F site, F(4) is bonded in a distorted single-bond geometry to three equivalent Ba(1) and one Fe(1) atom. In the third F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Mn(1), and one Fe(1) atom. In the fourth F site, F(6) is bonded in a trigonal planar geometry to one Ba(1), one Mn(1), and one Cd(1) atom. In the fifth F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Mn(1), and one Fe(1) atom. In the sixth F site, F(1) is bonded in a 2-coordinate geometry to two equivalent Ba(1), one Fe(1), and one Cd(1) atom. In the seventh F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Fe(1) atom.