C3NH10I is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylazanium;hydroiodide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(1), one H(3), and one H(6) atom to form corner-sharing CH3N tetrahedra. In the second C site, C(2) is bonded to one N(1), one H(4), and two equivalent H(2) atoms to form corner-sharing CH3N tetrahedra. N(1) is bonded in a tetrahedral geometry to one C(2), two equivalent C(1), and one H(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) and one I(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. I(1) is bonded in a distorted single-bond geometry to one H(5) atom.
C3NH10I is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylazanium;hydroiodide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(1), one H(3), and one H(6) atom to form corner-sharing CH3N tetrahedra. The C(1)-N(1) bond length is 1.49 Å. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(6) bond length is 1.10 Å. In the second C site, C(2) is bonded to one N(1), one H(4), and two equivalent H(2) atoms to form corner-sharing CH3N tetrahedra. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(4) bond length is 1.10 Å. Both C(2)-H(2) bond lengths are 1.10 Å. N(1) is bonded in a tetrahedral geometry to one C(2), two equivalent C(1), and one H(5) atom. The N(1)-H(5) bond length is 1.06 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) and one I(1) atom. The H(5)-I(1) bond length is 2.47 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. I(1) is bonded in a distorted single-bond geometry to one H(5) atom.