GeO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Ge(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing GeO6 octahedra. The corner-sharing octahedral tilt angles are 50°. O(1) is bonded in a trigonal planar geometry to three equivalent Ge(1) atoms.
GeO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Ge(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing GeO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are four shorter (1.88 Å) and two longer (1.91 Å) Ge(1)-O(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent Ge(1) atoms.