Ag5Pb2O6 crystallizes in the trigonal P-31m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra.
Ag5Pb2O6 crystallizes in the trigonal P-31m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. All Ag(1)-O(1) bond lengths are 2.31 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(2)-O(1) bond lengths are 2.12 Å. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. All Pb(1)-O(1) bond lengths are 2.24 Å. O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra.