(Cs)2CsBiI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsBiI6 framework. In the CsBiI6 framework, Cs(2) is bonded to six equivalent I(1) atoms to form CsI6 octahedra that share corners with six equivalent Bi(1)I6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent I(1) atoms to form BiI6 octahedra that share corners with six equivalent Cs(2)I6 octahedra. The corner-sharing octahedra are not tilted. I(1) is bonded in a linear geometry to one Cs(2) and one Bi(1) atom.
(Cs)2CsBiI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsBiI6 framework. In the CsBiI6 framework, Cs(2) is bonded to six equivalent I(1) atoms to form CsI6 octahedra that share corners with six equivalent Bi(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Cs(2)-I(1) bond lengths are 3.63 Å. Bi(1) is bonded to six equivalent I(1) atoms to form BiI6 octahedra that share corners with six equivalent Cs(2)I6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-I(1) bond lengths are 3.09 Å. I(1) is bonded in a linear geometry to one Cs(2) and one Bi(1) atom.