NiNH12O9NO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two NiNH12O9 clusters. In each NiNH12O9 cluster, Ni(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. N(1) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one O(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ni(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ni(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ni(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Ni(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ni(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one N(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom.
NiNH12O9NO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two NiNH12O9 clusters. In each NiNH12O9 cluster, Ni(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Ni(1)-O(1) bond length is 2.10 Å. The Ni(1)-O(2) bond length is 2.10 Å. The Ni(1)-O(3) bond length is 2.06 Å. The Ni(1)-O(4) bond length is 2.09 Å. The Ni(1)-O(5) bond length is 2.13 Å. The Ni(1)-O(6) bond length is 2.04 Å. N(1) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. The N(1)-O(7) bond length is 1.26 Å. The N(1)-O(8) bond length is 1.28 Å. The N(1)-O(9) bond length is 1.26 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one O(9) atom. The H(4)-O(2) bond length is 1.00 Å. The H(4)-O(9) bond length is 1.72 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. The H(7)-O(4) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. The H(8)-O(4) bond length is 0.99 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. The H(9)-O(5) bond length is 0.99 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. The H(10)-O(5) bond length is 0.98 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. The H(11)-O(6) bond length is 0.99 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. The H(12)-O(6) bond length is 0.99 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Ni(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ni(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ni(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Ni(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ni(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one N(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one N(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom.