Cr2B is Khatyrkite structured and crystallizes in the tetragonal I4/mcm space group. Cr(1) is bonded in a 4-coordinate geometry to four equivalent B(1) atoms. B(1) is bonded in a 10-coordinate geometry to eight equivalent Cr(1) and two equivalent B(1) atoms.
Cr2B is Khatyrkite structured and crystallizes in the tetragonal I4/mcm space group. Cr(1) is bonded in a 4-coordinate geometry to four equivalent B(1) atoms. All Cr(1)-B(1) bond lengths are 2.18 Å. B(1) is bonded in a 10-coordinate geometry to eight equivalent Cr(1) and two equivalent B(1) atoms. Both B(1)-B(1) bond lengths are 2.12 Å.