Ag3CN(O5Cl)2 crystallizes in the monoclinic P2_1 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one O(3) atom. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one C(1), one O(6), one O(7), one O(8), and one O(9) atom. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(1), one O(10), one O(2), one O(3), and one O(4) atom. C(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(1) atom. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one C(1) atom. There are ten inequivalent O sites. In the first O site, O(10) is bonded in a bent 120 degrees geometry to one Ag(3) and one O(9) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one Cl(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(3), and one Cl(1) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Ag(3) and one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(2) atom. In the seventh O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one Cl(2) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Ag(2) and one Cl(2) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(2) and one Cl(2) atom. In the tenth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one O(10) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom.
Ag3CN(O5Cl)2 crystallizes in the monoclinic P2_1 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one O(3) atom. The Ag(1)-C(1) bond length is 2.08 Å. The Ag(1)-N(1) bond length is 2.14 Å. The Ag(1)-O(3) bond length is 2.75 Å. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one C(1), one O(6), one O(7), one O(8), and one O(9) atom. The Ag(2)-C(1) bond length is 2.23 Å. The Ag(2)-O(6) bond length is 2.69 Å. The Ag(2)-O(7) bond length is 2.43 Å. The Ag(2)-O(8) bond length is 2.74 Å. The Ag(2)-O(9) bond length is 2.82 Å. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(1), one O(10), one O(2), one O(3), and one O(4) atom. The Ag(3)-N(1) bond length is 2.38 Å. The Ag(3)-O(10) bond length is 2.61 Å. The Ag(3)-O(2) bond length is 2.46 Å. The Ag(3)-O(3) bond length is 2.69 Å. The Ag(3)-O(4) bond length is 2.56 Å. C(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(1) atom. The C(1)-N(1) bond length is 1.18 Å. N(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one C(1) atom. There are ten inequivalent O sites. In the first O site, O(10) is bonded in a bent 120 degrees geometry to one Ag(3) and one O(9) atom. The O(10)-O(9) bond length is 1.23 Å. In the second O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. The O(1)-Cl(1) bond length is 1.44 Å. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one Cl(1) atom. The O(2)-Cl(1) bond length is 1.48 Å. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(3), and one Cl(1) atom. The O(3)-Cl(1) bond length is 1.47 Å. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Ag(3) and one Cl(1) atom. The O(4)-Cl(1) bond length is 1.49 Å. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(2) atom. The O(5)-Cl(2) bond length is 1.44 Å. In the seventh O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one Cl(2) atom. The O(6)-Cl(2) bond length is 1.47 Å. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Ag(2) and one Cl(2) atom. The O(7)-Cl(2) bond length is 1.49 Å. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(2) and one Cl(2) atom. The O(8)-Cl(2) bond length is 1.47 Å. In the tenth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one O(10) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom.