TiIrGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 11-coordinate geometry to two equivalent Ir(2), four equivalent Ir(1), one Ge(2), and four equivalent Ge(1) atoms. In the second Ti site, Ti(2) is bonded in a 8-coordinate geometry to two equivalent Ir(1), two equivalent Ge(2), and four equivalent Ge(1) atoms. In the third Ti site, Ti(3) is bonded in a 9-coordinate geometry to two equivalent Ir(1), two equivalent Ir(2), one Ge(2), and four equivalent Ge(1) atoms. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 8-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to two equivalent Ti(1), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Ir(2), and two equivalent Ir(1) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one Ti(1), one Ti(3), two equivalent Ti(2), two equivalent Ir(2), and four equivalent Ir(1) atoms.
TiIrGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 11-coordinate geometry to two equivalent Ir(2), four equivalent Ir(1), one Ge(2), and four equivalent Ge(1) atoms. Both Ti(1)-Ir(2) bond lengths are 2.85 Å. There are two shorter (2.73 Å) and two longer (2.74 Å) Ti(1)-Ir(1) bond lengths. The Ti(1)-Ge(2) bond length is 2.96 Å. There are two shorter (2.67 Å) and two longer (2.70 Å) Ti(1)-Ge(1) bond lengths. In the second Ti site, Ti(2) is bonded in a 8-coordinate geometry to two equivalent Ir(1), two equivalent Ge(2), and four equivalent Ge(1) atoms. Both Ti(2)-Ir(1) bond lengths are 2.83 Å. There is one shorter (2.61 Å) and one longer (2.89 Å) Ti(2)-Ge(2) bond length. There are two shorter (2.59 Å) and two longer (2.71 Å) Ti(2)-Ge(1) bond lengths. In the third Ti site, Ti(3) is bonded in a 9-coordinate geometry to two equivalent Ir(1), two equivalent Ir(2), one Ge(2), and four equivalent Ge(1) atoms. Both Ti(3)-Ir(1) bond lengths are 2.75 Å. Both Ti(3)-Ir(2) bond lengths are 2.82 Å. The Ti(3)-Ge(2) bond length is 2.80 Å. There are two shorter (2.65 Å) and two longer (2.70 Å) Ti(3)-Ge(1) bond lengths. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 8-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. There is one shorter (2.46 Å) and one longer (2.49 Å) Ir(1)-Ge(1) bond length. There is one shorter (2.52 Å) and one longer (2.54 Å) Ir(1)-Ge(2) bond length. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to two equivalent Ti(1), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. Both Ir(2)-Ge(1) bond lengths are 2.46 Å. Both Ir(2)-Ge(2) bond lengths are 2.50 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Ir(2), and two equivalent Ir(1) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one Ti(1), one Ti(3), two equivalent Ti(2), two equivalent Ir(2), and four equivalent Ir(1) atoms.