LiIO crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a linear geometry to two equivalent O(1) and four equivalent I(1) atoms. O(1) is bonded in a linear geometry to two equivalent Li(1) atoms. I(1) is bonded in a square co-planar geometry to four equivalent Li(1) atoms.
LiIO crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded in a linear geometry to two equivalent O(1) and four equivalent I(1) atoms. Both Li(1)-O(1) bond lengths are 1.76 Å. All Li(1)-I(1) bond lengths are 2.89 Å. O(1) is bonded in a linear geometry to two equivalent Li(1) atoms. I(1) is bonded in a square co-planar geometry to four equivalent Li(1) atoms.