TbPdZn crystallizes in the hexagonal P-62m space group. Tb(1) is bonded in a 11-coordinate geometry to one Pd(1), four equivalent Pd(2), and six equivalent Zn(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to three equivalent Tb(1) and six equivalent Zn(1) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Tb(1) and three equivalent Zn(1) atoms. Zn(1) is bonded in a 10-coordinate geometry to six equivalent Tb(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.
TbPdZn crystallizes in the hexagonal P-62m space group. Tb(1) is bonded in a 11-coordinate geometry to one Pd(1), four equivalent Pd(2), and six equivalent Zn(1) atoms. The Tb(1)-Pd(1) bond length is 2.93 Å. All Tb(1)-Pd(2) bond lengths are 2.93 Å. There are two shorter (3.17 Å) and four longer (3.21 Å) Tb(1)-Zn(1) bond lengths. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to three equivalent Tb(1) and six equivalent Zn(1) atoms. All Pd(1)-Zn(1) bond lengths are 2.64 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Tb(1) and three equivalent Zn(1) atoms. All Pd(2)-Zn(1) bond lengths are 2.77 Å. Zn(1) is bonded in a 10-coordinate geometry to six equivalent Tb(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.