PdW crystallizes in the trigonal R-3m space group. W(1) is bonded to six equivalent W(1) and six equivalent Pd(1) atoms to form WPd6W6 cuboctahedra that share corners with twelve equivalent W(1)Pd6W6 cuboctahedra, edges with twelve equivalent W(1)Pd6W6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6W6 cuboctahedra, faces with six equivalent W(1)Pd6W6 cuboctahedra, and faces with twelve equivalent Pd(1)Pd6W6 cuboctahedra. Pd(1) is bonded to six equivalent W(1) and six equivalent Pd(1) atoms to form PdPd6W6 cuboctahedra that share corners with twelve equivalent Pd(1)Pd6W6 cuboctahedra, edges with twelve equivalent W(1)Pd6W6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6W6 cuboctahedra, faces with six equivalent Pd(1)Pd6W6 cuboctahedra, and faces with twelve equivalent W(1)Pd6W6 cuboctahedra.
PdW crystallizes in the trigonal R-3m space group. W(1) is bonded to six equivalent W(1) and six equivalent Pd(1) atoms to form WPd6W6 cuboctahedra that share corners with twelve equivalent W(1)Pd6W6 cuboctahedra, edges with twelve equivalent W(1)Pd6W6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6W6 cuboctahedra, faces with six equivalent W(1)Pd6W6 cuboctahedra, and faces with twelve equivalent Pd(1)Pd6W6 cuboctahedra. All W(1)-W(1) bond lengths are 2.79 Å. All W(1)-Pd(1) bond lengths are 2.82 Å. Pd(1) is bonded to six equivalent W(1) and six equivalent Pd(1) atoms to form PdPd6W6 cuboctahedra that share corners with twelve equivalent Pd(1)Pd6W6 cuboctahedra, edges with twelve equivalent W(1)Pd6W6 cuboctahedra, edges with twelve equivalent Pd(1)Pd6W6 cuboctahedra, faces with six equivalent Pd(1)Pd6W6 cuboctahedra, and faces with twelve equivalent W(1)Pd6W6 cuboctahedra. All Pd(1)-Pd(1) bond lengths are 2.79 Å.