Pb3O2(OH)2 is Indium structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two Pb3O2(OH)2 clusters. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. H(1) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1) and two equivalent Pb(2) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(1), two equivalent Pb(2), and one H(1) atom.
Pb3O2(OH)2 is Indium structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two Pb3O2(OH)2 clusters. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Pb(1)-O(1) bond lengths are 2.22 Å. Both Pb(1)-O(2) bond lengths are 2.46 Å. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Pb(2)-O(1) bond lengths are 2.21 Å. There is one shorter (2.45 Å) and one longer (2.52 Å) Pb(2)-O(2) bond length. H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(1) and two equivalent Pb(2) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Pb(1), two equivalent Pb(2), and one H(1) atom.