VN is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent N(1) atoms to form a mixture of edge, face, and corner-sharing VN6 octahedra. The corner-sharing octahedral tilt angles are 45°. N(1) is bonded to six equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing NV6 pentagonal pyramids.
VN is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent N(1) atoms to form a mixture of edge, face, and corner-sharing VN6 octahedra. The corner-sharing octahedral tilt angles are 45°. All V(1)-N(1) bond lengths are 2.07 Å. N(1) is bonded to six equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing NV6 pentagonal pyramids.