LaRhP is hexagonal omega structure-derived structured and crystallizes in the tetragonal I4_1md space group. La(1) is bonded to six Rh(1,1) and six equivalent P(1) atoms to form a mixture of face and edge-sharing LaP6Rh6 cuboctahedra. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent P(1) atoms. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent P(1) atoms. In the third Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three Rh(1,1) atoms.
LaRhP is hexagonal omega structure-derived structured and crystallizes in the tetragonal I4_1md space group. La(1) is bonded to six Rh(1,1) and six equivalent P(1) atoms to form a mixture of face and edge-sharing LaP6Rh6 cuboctahedra. There are two shorter (3.12 Å) and four longer (3.18 Å) La(1)-Rh(1,1) bond lengths. There are four shorter (3.14 Å) and two longer (3.20 Å) La(1)-P(1) bond lengths. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent P(1) atoms. There are two shorter (2.39 Å) and one longer (2.40 Å) Rh(1)-P(1) bond length. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent P(1) atoms. There are two shorter (2.39 Å) and one longer (2.40 Å) Rh(1)-P(1) bond length. In the third Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three equivalent P(1) atoms. There are two shorter (3.12 Å) and four longer (3.18 Å) Rh(1)-La(1) bond lengths. There are two shorter (2.39 Å) and one longer (2.40 Å) Rh(1)-P(1) bond length. P(1) is bonded in a 9-coordinate geometry to six equivalent La(1) and three Rh(1,1) atoms.