Nd2PbS4 crystallizes in the tetragonal I-42d space group. Nd(1) is bonded to eight equivalent S(1) atoms to form a mixture of distorted edge, face, and corner-sharing NdS8 hexagonal bipyramids. Pb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Nd(1) and two equivalent Pb(1) atoms.
Nd2PbS4 crystallizes in the tetragonal I-42d space group. Nd(1) is bonded to eight equivalent S(1) atoms to form a mixture of distorted edge, face, and corner-sharing NdS8 hexagonal bipyramids. There are a spread of Nd(1)-S(1) bond distances ranging from 2.86-3.09 Å. Pb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. There are four shorter (2.97 Å) and four longer (3.13 Å) Pb(1)-S(1) bond lengths. S(1) is bonded in a 6-coordinate geometry to four equivalent Nd(1) and two equivalent Pb(1) atoms.