LiSnPHO5 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one Sn(2), one O(1), one O(3), one O(4), and one O(5) atom. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in an octahedral geometry to two equivalent H(1), two equivalent O(1), and two equivalent O(2) atoms. In the second Sn site, Sn(2) is bonded in a 10-coordinate geometry to two equivalent Li(1), two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. P(1) is bonded in a 2-coordinate geometry to one O(2), one O(3), and one O(5) atom. H(1) is bonded in a single-bond geometry to one Sn(1) and one O(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(1), one Sn(1), one Sn(2), and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Sn(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Li(1) and one Sn(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one Sn(2), and one P(1) atom.
LiSnPHO5 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one Sn(2), one O(1), one O(3), one O(4), and one O(5) atom. The Li(1)-Sn(2) bond length is 2.93 Å. The Li(1)-O(1) bond length is 2.25 Å. The Li(1)-O(3) bond length is 2.54 Å. The Li(1)-O(4) bond length is 2.18 Å. The Li(1)-O(5) bond length is 2.46 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in an octahedral geometry to two equivalent H(1), two equivalent O(1), and two equivalent O(2) atoms. Both Sn(1)-H(1) bond lengths are 2.09 Å. Both Sn(1)-O(1) bond lengths are 2.26 Å. Both Sn(1)-O(2) bond lengths are 2.50 Å. In the second Sn site, Sn(2) is bonded in a 10-coordinate geometry to two equivalent Li(1), two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. Both Sn(2)-O(1) bond lengths are 2.29 Å. Both Sn(2)-O(3) bond lengths are 2.74 Å. Both Sn(2)-O(4) bond lengths are 2.43 Å. Both Sn(2)-O(5) bond lengths are 2.63 Å. P(1) is bonded in a 2-coordinate geometry to one O(2), one O(3), and one O(5) atom. The P(1)-O(2) bond length is 1.16 Å. The P(1)-O(3) bond length is 1.96 Å. The P(1)-O(5) bond length is 1.29 Å. H(1) is bonded in a single-bond geometry to one Sn(1) and one O(1) atom. The H(1)-O(1) bond length is 1.42 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(1), one Sn(1), one Sn(2), and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Sn(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Li(1) and one Sn(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one Sn(2), and one P(1) atom.