(Tl)2Ti(TeO4)3 crystallizes in the monoclinic C2 space group. The structure consists of four 7440-28-0 atoms inside a Ti(TeO4)3 framework. In the Ti(TeO4)3 framework, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-42°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form TeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, and corners with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-45°. In the second Te site, Te(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-45°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ti(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to two equivalent Te(1) atoms. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Ti(1) and one Te(2) atom.
(Tl)2Ti(TeO4)3 crystallizes in the monoclinic C2 space group. The structure consists of four 7440-28-0 atoms inside a Ti(TeO4)3 framework. In the Ti(TeO4)3 framework, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-42°. Both Ti(1)-O(1) bond lengths are 1.92 Å. Both Ti(1)-O(3) bond lengths are 1.96 Å. Both Ti(1)-O(6) bond lengths are 1.94 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form TeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, and corners with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-45°. The Te(1)-O(1) bond length is 1.87 Å. The Te(1)-O(2) bond length is 1.94 Å. The Te(1)-O(3) bond length is 1.87 Å. The Te(1)-O(4) bond length is 1.94 Å. Both Te(1)-O(5) bond lengths are 1.94 Å. In the second Te site, Te(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-45°. Both Te(2)-O(2) bond lengths are 1.94 Å. Both Te(2)-O(4) bond lengths are 1.94 Å. Both Te(2)-O(6) bond lengths are 1.87 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ti(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to two equivalent Te(1) atoms. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Ti(1) and one Te(2) atom.