TiVN2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Ti(1) is bonded to six equivalent N(1) atoms to form TiN6 octahedra that share corners with six equivalent V(1)N6 octahedra, edges with six equivalent Ti(1)N6 octahedra, and edges with six equivalent V(1)N6 octahedra. The corner-sharing octahedral tilt angles are 1°. V(1) is bonded to six equivalent N(1) atoms to form VN6 octahedra that share corners with six equivalent Ti(1)N6 octahedra, edges with six equivalent Ti(1)N6 octahedra, and edges with six equivalent V(1)N6 octahedra. The corner-sharing octahedral tilt angles are 1°. N(1) is bonded to three equivalent Ti(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing NTi3V3 octahedra. The corner-sharing octahedra are not tilted.
TiVN2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Ti(1) is bonded to six equivalent N(1) atoms to form TiN6 octahedra that share corners with six equivalent V(1)N6 octahedra, edges with six equivalent Ti(1)N6 octahedra, and edges with six equivalent V(1)N6 octahedra. The corner-sharing octahedral tilt angles are 1°. All Ti(1)-N(1) bond lengths are 2.10 Å. V(1) is bonded to six equivalent N(1) atoms to form VN6 octahedra that share corners with six equivalent Ti(1)N6 octahedra, edges with six equivalent Ti(1)N6 octahedra, and edges with six equivalent V(1)N6 octahedra. The corner-sharing octahedral tilt angles are 1°. All V(1)-N(1) bond lengths are 2.08 Å. N(1) is bonded to three equivalent Ti(1) and three equivalent V(1) atoms to form a mixture of corner and edge-sharing NTi3V3 octahedra. The corner-sharing octahedra are not tilted.