NaV2O4 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Na(1) is bonded to four equivalent O(1) atoms to form NaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Na(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. O(1) is bonded to one Na(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing ONaV3 tetrahedra.
NaV2O4 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Na(1) is bonded to four equivalent O(1) atoms to form NaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. All Na(1)-O(1) bond lengths are 2.18 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Na(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. There are four shorter (2.00 Å) and two longer (2.08 Å) V(1)-O(1) bond lengths. O(1) is bonded to one Na(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing ONaV3 tetrahedra.