Ba2YbO6Sb crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-36-0 atoms inside a Ba2YbO6 framework. In the Ba2YbO6 framework, Ba(1) is bonded to six equivalent O(1) atoms to form BaO6 octahedra that share corners with six equivalent Ba(1)O6 octahedra and faces with four equivalent Yb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Yb(1) is bonded to twelve equivalent O(1) atoms to form distorted YbO12 cuboctahedra that share corners with twelve equivalent Yb(1)O12 cuboctahedra and faces with eight equivalent Ba(1)O6 octahedra. O(1) is bonded in a linear geometry to two equivalent Ba(1) and two equivalent Yb(1) atoms.
Ba2YbO6Sb crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-36-0 atoms inside a Ba2YbO6 framework. In the Ba2YbO6 framework, Ba(1) is bonded to six equivalent O(1) atoms to form BaO6 octahedra that share corners with six equivalent Ba(1)O6 octahedra and faces with four equivalent Yb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ba(1)-O(1) bond lengths are 2.33 Å. Yb(1) is bonded to twelve equivalent O(1) atoms to form distorted YbO12 cuboctahedra that share corners with twelve equivalent Yb(1)O12 cuboctahedra and faces with eight equivalent Ba(1)O6 octahedra. All Yb(1)-O(1) bond lengths are 3.29 Å. O(1) is bonded in a linear geometry to two equivalent Ba(1) and two equivalent Yb(1) atoms.