K(IrP)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. Ir(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing IrP4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Ir(1) atoms.
K(IrP)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. All K(1)-P(1) bond lengths are 3.43 Å. Ir(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing IrP4 tetrahedra. All Ir(1)-P(1) bond lengths are 2.35 Å. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Ir(1) atoms.