K3NaMnCl6 crystallizes in the trigonal R-3c space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. Na(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. Mn(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. Cl(1) is bonded to four equivalent K(1), one Na(1), and one Mn(1) atom to form a mixture of distorted face, corner, and edge-sharing ClK4NaMn octahedra. The corner-sharing octahedral tilt angles range from 0-64°.
K3NaMnCl6 crystallizes in the trigonal R-3c space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent Cl(1) atoms. There are a spread of K(1)-Cl(1) bond distances ranging from 3.23-3.37 Å. Na(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. All Na(1)-Cl(1) bond lengths are 2.86 Å. Mn(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. All Mn(1)-Cl(1) bond lengths are 2.56 Å. Cl(1) is bonded to four equivalent K(1), one Na(1), and one Mn(1) atom to form a mixture of distorted face, corner, and edge-sharing ClK4NaMn octahedra. The corner-sharing octahedral tilt angles range from 0-64°.