Rb2Li(OsO3)2 crystallizes in the trigonal R-3 space group. Rb(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. Li(1) is bonded in a distorted octahedral geometry to six equivalent O(1) atoms. Os(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to three equivalent Rb(1), one Li(1), and two equivalent Os(1) atoms.
Rb2Li(OsO3)2 crystallizes in the trigonal R-3 space group. Rb(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. There are a spread of Rb(1)-O(1) bond distances ranging from 2.70-3.22 Å. Li(1) is bonded in a distorted octahedral geometry to six equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.29 Å. Os(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.01 Å) and three longer (2.04 Å) Os(1)-O(1) bond lengths. O(1) is bonded in a 6-coordinate geometry to three equivalent Rb(1), one Li(1), and two equivalent Os(1) atoms.