CeFe2P2 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to eight equivalent Fe(1) and eight equivalent P(1) atoms. Fe(1) is bonded to four equivalent Ce(1) and four equivalent P(1) atoms to form a mixture of distorted edge, face, and corner-sharing FeCe4P4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Fe(1) atoms.
CeFe2P2 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to eight equivalent Fe(1) and eight equivalent P(1) atoms. All Ce(1)-Fe(1) bond lengths are 3.20 Å. All Ce(1)-P(1) bond lengths are 3.07 Å. Fe(1) is bonded to four equivalent Ce(1) and four equivalent P(1) atoms to form a mixture of distorted edge, face, and corner-sharing FeCe4P4 tetrahedra. All Fe(1)-P(1) bond lengths are 2.18 Å. P(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Fe(1) atoms.