Tm(PO)2 is Indium-like structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tm(PO)2 clusters. Tm(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one Tm(1) and one P(1) atom.
Tm(PO)2 is Indium-like structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tm(PO)2 clusters. Tm(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. Both Tm(1)-O(1) bond lengths are 2.17 Å. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. The P(1)-O(1) bond length is 1.58 Å. O(1) is bonded in a water-like geometry to one Tm(1) and one P(1) atom.