WSeS2Cl5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four WSeS2Cl5 clusters. W(1) is bonded in a 8-coordinate geometry to one Se(1), two equivalent S(1), two equivalent S(2), one Cl(3), one Cl(4), and one Cl(5) atom. Se(1) is bonded in a 5-coordinate geometry to one W(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom.
WSeS2Cl5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four WSeS2Cl5 clusters. W(1) is bonded in a 8-coordinate geometry to one Se(1), two equivalent S(1), two equivalent S(2), one Cl(3), one Cl(4), and one Cl(5) atom. The W(1)-Se(1) bond length is 2.72 Å. There is one shorter (2.44 Å) and one longer (2.46 Å) W(1)-S(1) bond length. There is one shorter (2.44 Å) and one longer (2.46 Å) W(1)-S(2) bond length. The W(1)-Cl(3) bond length is 2.46 Å. The W(1)-Cl(4) bond length is 2.47 Å. The W(1)-Cl(5) bond length is 2.39 Å. Se(1) is bonded in a 5-coordinate geometry to one W(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Se(1)-Cl(1) bond length is 2.24 Å. The Se(1)-Cl(2) bond length is 2.23 Å. The Se(1)-Cl(3) bond length is 2.66 Å. The Se(1)-Cl(4) bond length is 2.69 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(2) atom. The S(1)-S(2) bond length is 2.03 Å. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom.