CePd2Si crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 11-coordinate geometry to eight equivalent Pd(1) and three equivalent Si(1) atoms. Pd(1) is bonded in a 6-coordinate geometry to four equivalent Ce(1) and three equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Pd(1) atoms.
CePd2Si crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 11-coordinate geometry to eight equivalent Pd(1) and three equivalent Si(1) atoms. There are a spread of Ce(1)-Pd(1) bond distances ranging from 3.00-3.36 Å. There are a spread of Ce(1)-Si(1) bond distances ranging from 3.02-3.14 Å. Pd(1) is bonded in a 6-coordinate geometry to four equivalent Ce(1) and three equivalent Si(1) atoms. There are two shorter (2.52 Å) and one longer (2.69 Å) Pd(1)-Si(1) bond length. Si(1) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Pd(1) atoms.