AgTlS crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded in a distorted trigonal planar geometry to four equivalent Tl(1) and three equivalent S(1) atoms. Tl(1) is bonded in a 6-coordinate geometry to four equivalent Ag(1) and two equivalent S(1) atoms. S(1) is bonded in a 3-coordinate geometry to three equivalent Ag(1) and two equivalent Tl(1) atoms.
AgTlS crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded in a distorted trigonal planar geometry to four equivalent Tl(1) and three equivalent S(1) atoms. There are a spread of Ag(1)-Tl(1) bond distances ranging from 3.25-3.41 Å. There is one shorter (2.58 Å) and two longer (2.61 Å) Ag(1)-S(1) bond lengths. Tl(1) is bonded in a 6-coordinate geometry to four equivalent Ag(1) and two equivalent S(1) atoms. Both Tl(1)-S(1) bond lengths are 3.12 Å. S(1) is bonded in a 3-coordinate geometry to three equivalent Ag(1) and two equivalent Tl(1) atoms.