Ti4MnBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Mn(1) and four equivalent Bi(1) atoms. Mn(1) is bonded in a distorted q6 geometry to eight equivalent Ti(1) and two equivalent Mn(1) atoms. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms.
Ti4MnBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Mn(1) and four equivalent Bi(1) atoms. Both Ti(1)-Mn(1) bond lengths are 2.58 Å. There are a spread of Ti(1)-Bi(1) bond distances ranging from 2.92-3.11 Å. Mn(1) is bonded in a distorted q6 geometry to eight equivalent Ti(1) and two equivalent Mn(1) atoms. Both Mn(1)-Mn(1) bond lengths are 2.52 Å. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms.