(SmN2H3O9)2H2(NH2O3)2(H2O2)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two water atoms, two H2O2 clusters, two NH2O3 clusters, and one SmN2H3O9 cluster. In each H2O2 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a 2-coordinate geometry to one O(10) and one O(14) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(10) and one O(14) atom. There are two inequivalent O sites. In the first O site, O(14) is bonded in a distorted single-bond geometry to one H(1) and one H(2) atom. In the second O site, O(10) is bonded in a 2-coordinate geometry to one H(1) and one H(2) atom. In each NH2O3 cluster, N(3) is bonded in a distorted single-bond geometry to one O(15) and one O(9) atom. There are two inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(8) is bonded in a distorted single-bond geometry to one O(13) atom. There are three inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one N(3) and one O(15) atom. In the second O site, O(13) is bonded in a distorted single-bond geometry to one H(7), one H(8), and one O(15) atom. In the third O site, O(15) is bonded in a distorted bent 150 degrees geometry to one N(3), one O(13), and one O(9) atom. In the SmN2H3O9 cluster, Sm(1) is bonded in a distorted single-bond geometry to one H(4), one O(11), one O(6), one O(7), and one O(8) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one O(1) and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(4) is bonded in a distorted single-bond geometry to one Sm(1) and one O(11) atom. In the second H site, H(5) is bonded in a 3-coordinate geometry to one H(6), one O(12), and one O(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one H(5) and one O(12) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Sm(1), one N(2), and one H(5) atom. In the third O site, O(7) is bonded in an L-shaped geometry to one Sm(1) and one O(4) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Sm(1) and one O(2) atom. In the fifth O site, O(11) is bonded in a 2-coordinate geometry to one Sm(1) and one H(4) atom. In the sixth O site, O(12) is bonded in a distorted single-bond geometry to one H(5) and one H(6) atom. In the seventh O site, O(1) is bonded in a 1-coordinate geometry to one N(1) atom. In the eighth O site, O(2) is bonded in a single-bond geometry to one N(1) and one O(8) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one N(2) and one O(7) atom.
(SmN2H3O9)2H2(NH2O3)2(H2O2)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two water atoms, two H2O2 clusters, two NH2O3 clusters, and one SmN2H3O9 cluster. In each H2O2 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a 2-coordinate geometry to one O(10) and one O(14) atom. The H(1)-O(10) bond length is 1.35 Å. The H(1)-O(14) bond length is 1.49 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(10) and one O(14) atom. The H(2)-O(10) bond length is 1.50 Å. The H(2)-O(14) bond length is 1.68 Å. There are two inequivalent O sites. In the first O site, O(14) is bonded in a distorted single-bond geometry to one H(1) and one H(2) atom. In the second O site, O(10) is bonded in a 2-coordinate geometry to one H(1) and one H(2) atom. In each NH2O3 cluster, N(3) is bonded in a distorted single-bond geometry to one O(15) and one O(9) atom. The N(3)-O(15) bond length is 1.98 Å. The N(3)-O(9) bond length is 1.06 Å. There are two inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one O(13) atom. The H(7)-O(13) bond length is 1.10 Å. In the second H site, H(8) is bonded in a distorted single-bond geometry to one O(13) atom. The H(8)-O(13) bond length is 1.64 Å. There are three inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one N(3) and one O(15) atom. The O(9)-O(15) bond length is 1.44 Å. In the second O site, O(13) is bonded in a distorted single-bond geometry to one H(7), one H(8), and one O(15) atom. The O(13)-O(15) bond length is 1.51 Å. In the third O site, O(15) is bonded in a distorted bent 150 degrees geometry to one N(3), one O(13), and one O(9) atom. In the SmN2H3O9 cluster, Sm(1) is bonded in a distorted single-bond geometry to one H(4), one O(11), one O(6), one O(7), and one O(8) atom. The Sm(1)-H(4) bond length is 1.96 Å. The Sm(1)-O(11) bond length is 1.65 Å. The Sm(1)-O(6) bond length is 2.95 Å. The Sm(1)-O(7) bond length is 2.81 Å. The Sm(1)-O(8) bond length is 3.03 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one O(1) and one O(2) atom. The N(1)-O(1) bond length is 1.76 Å. The N(1)-O(2) bond length is 1.15 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(2)-O(4) bond length is 1.23 Å. The N(2)-O(5) bond length is 1.36 Å. The N(2)-O(6) bond length is 1.50 Å. There are three inequivalent H sites. In the first H site, H(4) is bonded in a distorted single-bond geometry to one Sm(1) and one O(11) atom. The H(4)-O(11) bond length is 1.52 Å. In the second H site, H(5) is bonded in a 3-coordinate geometry to one H(6), one O(12), and one O(6) atom. The H(5)-H(6) bond length is 0.90 Å. The H(5)-O(12) bond length is 0.89 Å. The H(5)-O(6) bond length is 1.67 Å. In the third H site, H(6) is bonded in a single-bond geometry to one H(5) and one O(12) atom. The H(6)-O(12) bond length is 0.59 Å. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Sm(1), one N(2), and one H(5) atom. In the third O site, O(7) is bonded in an L-shaped geometry to one Sm(1) and one O(4) atom. The O(7)-O(4) bond length is 1.43 Å. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Sm(1) and one O(2) atom. The O(8)-O(2) bond length is 1.90 Å. In the fifth O site, O(11) is bonded in a 2-coordinate geometry to one Sm(1) and one H(4) atom. In the sixth O site, O(12) is bonded in a distorted single-bond geometry to one H(5) and one H(6) atom. In the seventh O site, O(1) is bonded in a 1-coordinate geometry to one N(1) atom. In the eighth O site, O(2) is bonded in a single-bond geometry to one N(1) and one O(8) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one N(2) and one O(7) atom.