Nb3Bi crystallizes in the cubic Pm-3n space group. Nb(1) is bonded in a 6-coordinate geometry to two equivalent Nb(1) and four equivalent Bi(1) atoms. Bi(1) is bonded to twelve equivalent Nb(1) atoms to form a mixture of edge and face-sharing BiNb12 cuboctahedra.
Nb3Bi crystallizes in the cubic Pm-3n space group. Nb(1) is bonded in a 6-coordinate geometry to two equivalent Nb(1) and four equivalent Bi(1) atoms. Both Nb(1)-Nb(1) bond lengths are 2.69 Å. All Nb(1)-Bi(1) bond lengths are 3.01 Å. Bi(1) is bonded to twelve equivalent Nb(1) atoms to form a mixture of edge and face-sharing BiNb12 cuboctahedra.