USbS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. U(1) is bonded in a 9-coordinate geometry to four equivalent Sb(1) and five equivalent S(1) atoms. Sb(1) is bonded to four equivalent U(1) and four equivalent Sb(1) atoms to form distorted SbU4Sb4 hexagonal bipyramids that share corners with four equivalent Sb(1)U4Sb4 hexagonal bipyramids, corners with twelve equivalent S(1)U5 square pyramids, edges with four equivalent Sb(1)U4Sb4 hexagonal bipyramids, edges with four equivalent S(1)U5 square pyramids, and faces with four equivalent Sb(1)U4Sb4 hexagonal bipyramids. S(1) is bonded to five equivalent U(1) atoms to form distorted SU5 square pyramids that share corners with twelve equivalent Sb(1)U4Sb4 hexagonal bipyramids, corners with four equivalent S(1)U5 square pyramids, edges with four equivalent Sb(1)U4Sb4 hexagonal bipyramids, and edges with eight equivalent S(1)U5 square pyramids.
USbS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. U(1) is bonded in a 9-coordinate geometry to four equivalent Sb(1) and five equivalent S(1) atoms. All U(1)-Sb(1) bond lengths are 3.33 Å. There is one shorter (2.83 Å) and four longer (2.98 Å) U(1)-S(1) bond lengths. Sb(1) is bonded to four equivalent U(1) and four equivalent Sb(1) atoms to form distorted SbU4Sb4 hexagonal bipyramids that share corners with four equivalent Sb(1)U4Sb4 hexagonal bipyramids, corners with twelve equivalent S(1)U5 square pyramids, edges with four equivalent Sb(1)U4Sb4 hexagonal bipyramids, edges with four equivalent S(1)U5 square pyramids, and faces with four equivalent Sb(1)U4Sb4 hexagonal bipyramids. All Sb(1)-Sb(1) bond lengths are 2.92 Å. S(1) is bonded to five equivalent U(1) atoms to form distorted SU5 square pyramids that share corners with twelve equivalent Sb(1)U4Sb4 hexagonal bipyramids, corners with four equivalent S(1)U5 square pyramids, edges with four equivalent Sb(1)U4Sb4 hexagonal bipyramids, and edges with eight equivalent S(1)U5 square pyramids.