NiRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Ni(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. Ni(1) is bonded to four equivalent S(1) atoms to form NiS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 57°. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rh(1) and one Ni(1) atom.
NiRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Ni(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. All Rh(1)-S(1) bond lengths are 2.38 Å. Ni(1) is bonded to four equivalent S(1) atoms to form NiS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Ni(1)-S(1) bond lengths are 2.20 Å. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rh(1) and one Ni(1) atom.