LiCuS2 crystallizes in the monoclinic C2/m space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. Cu(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded in a 5-coordinate geometry to three equivalent Li(1) and two equivalent Cu(1) atoms.
LiCuS2 crystallizes in the monoclinic C2/m space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. There are two shorter (2.56 Å) and four longer (2.68 Å) Li(1)-S(1) bond lengths. Cu(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. All Cu(1)-S(1) bond lengths are 2.24 Å. S(1) is bonded in a 5-coordinate geometry to three equivalent Li(1) and two equivalent Cu(1) atoms.