CaLaFeO6Bi crystallizes in the cubic F-43m space group. The structure consists of four 7440-69-9 atoms inside a CaLaFeO6 framework. In the CaLaFeO6 framework, Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with four equivalent La(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. La(1) is bonded to six equivalent O(1) atoms to form LaO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent La(1)O6 octahedra and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent Ca(1), one La(1), and one Fe(1) atom.
CaLaFeO6Bi crystallizes in the cubic F-43m space group. The structure consists of four 7440-69-9 atoms inside a CaLaFeO6 framework. In the CaLaFeO6 framework, Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with four equivalent La(1)O6 octahedra, and faces with four equivalent Fe(1)O6 octahedra. All Ca(1)-O(1) bond lengths are 2.96 Å. La(1) is bonded to six equivalent O(1) atoms to form LaO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All La(1)-O(1) bond lengths are 2.26 Å. Fe(1) is bonded to six equivalent O(1) atoms to form FeO6 octahedra that share corners with six equivalent La(1)O6 octahedra and faces with four equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Fe(1)-O(1) bond lengths are 1.92 Å. O(1) is bonded in a distorted linear geometry to two equivalent Ca(1), one La(1), and one Fe(1) atom.