Rb2CoPb(NO2)6 crystallizes in the cubic Fm-3 space group. Rb(1) is bonded to twelve equivalent O(1) atoms to form RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra and faces with four equivalent Pb(1)O12 cuboctahedra. Co(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. Pb(1) is bonded to twelve equivalent O(1) atoms to form distorted PbO12 cuboctahedra that share faces with eight equivalent Rb(1)O12 cuboctahedra. N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(1) atom.
Rb2CoPb(NO2)6 crystallizes in the cubic Fm-3 space group. Rb(1) is bonded to twelve equivalent O(1) atoms to form RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra and faces with four equivalent Pb(1)O12 cuboctahedra. All Rb(1)-O(1) bond lengths are 3.12 Å. Co(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Co(1)-N(1) bond lengths are 2.03 Å. Pb(1) is bonded to twelve equivalent O(1) atoms to form distorted PbO12 cuboctahedra that share faces with eight equivalent Rb(1)O12 cuboctahedra. All Pb(1)-O(1) bond lengths are 2.87 Å. N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.26 Å. O(1) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(1) atom.