Tl6TeO6 crystallizes in the trigonal R-3 space group. Tl(1) is bonded in a 2-coordinate geometry to two equivalent O(1) atoms. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Tl(1) and one Te(1) atom.
Tl6TeO6 crystallizes in the trigonal R-3 space group. Tl(1) is bonded in a 2-coordinate geometry to two equivalent O(1) atoms. There is one shorter (2.37 Å) and one longer (2.39 Å) Tl(1)-O(1) bond length. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Te(1)-O(1) bond lengths are 1.94 Å. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Tl(1) and one Te(1) atom.