CrZrF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Cr(1)F6 octahedra. The corner-sharing octahedra are not tilted. Cr(1) is bonded to six equivalent F(1) atoms to form CrF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Zr(1) and one Cr(1) atom.
CrZrF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Cr(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Zr(1)-F(1) bond lengths are 2.04 Å. Cr(1) is bonded to six equivalent F(1) atoms to form CrF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Cr(1)-F(1) bond lengths are 2.12 Å. F(1) is bonded in a linear geometry to one Zr(1) and one Cr(1) atom.