(Na)2AgAsBr6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a AgAsBr6 framework. In the AgAsBr6 framework, Ag(1) is bonded to six equivalent Br(1) atoms to form AgBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Ag(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Ag(1) and one As(1) atom.
(Na)2AgAsBr6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a AgAsBr6 framework. In the AgAsBr6 framework, Ag(1) is bonded to six equivalent Br(1) atoms to form AgBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Ag(1)-Br(1) bond lengths are 2.78 Å. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Ag(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All As(1)-Br(1) bond lengths are 2.66 Å. Br(1) is bonded in a linear geometry to one Ag(1) and one As(1) atom.