(Li)2LiScCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7439-93-2 atoms inside a LiScCl6 framework. In the LiScCl6 framework, Li(2) is bonded to six equivalent Cl(1) atoms to form LiCl6 octahedra that share corners with six equivalent Sc(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent Cl(1) atoms to form ScCl6 octahedra that share corners with six equivalent Li(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Li(2) and one Sc(1) atom.
(Li)2LiScCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7439-93-2 atoms inside a LiScCl6 framework. In the LiScCl6 framework, Li(2) is bonded to six equivalent Cl(1) atoms to form LiCl6 octahedra that share corners with six equivalent Sc(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Li(2)-Cl(1) bond lengths are 2.49 Å. Sc(1) is bonded to six equivalent Cl(1) atoms to form ScCl6 octahedra that share corners with six equivalent Li(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-Cl(1) bond lengths are 2.47 Å. Cl(1) is bonded in a linear geometry to one Li(2) and one Sc(1) atom.