TiVCN is alpha Po-derived structured and crystallizes in the trigonal R3m space group. Ti(1) is bonded to three equivalent C(1) and three equivalent N(1) atoms to form TiC3N3 octahedra that share corners with six equivalent V(1)C3N3 octahedra, edges with six equivalent Ti(1)C3N3 octahedra, and edges with six equivalent V(1)C3N3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. V(1) is bonded to three equivalent C(1) and three equivalent N(1) atoms to form VC3N3 octahedra that share corners with six equivalent Ti(1)C3N3 octahedra, edges with six equivalent Ti(1)C3N3 octahedra, and edges with six equivalent V(1)C3N3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. C(1) is bonded to three equivalent Ti(1) and three equivalent V(1) atoms to form CTi3V3 octahedra that share corners with six equivalent N(1)Ti3V3 octahedra, edges with six equivalent C(1)Ti3V3 octahedra, and edges with six equivalent N(1)Ti3V3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. N(1) is bonded to three equivalent Ti(1) and three equivalent V(1) atoms to form NTi3V3 octahedra that share corners with six equivalent C(1)Ti3V3 octahedra, edges with six equivalent C(1)Ti3V3 octahedra, and edges with six equivalent N(1)Ti3V3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°.
TiVCN is alpha Po-derived structured and crystallizes in the trigonal R3m space group. Ti(1) is bonded to three equivalent C(1) and three equivalent N(1) atoms to form TiC3N3 octahedra that share corners with six equivalent V(1)C3N3 octahedra, edges with six equivalent Ti(1)C3N3 octahedra, and edges with six equivalent V(1)C3N3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. All Ti(1)-C(1) bond lengths are 2.12 Å. All Ti(1)-N(1) bond lengths are 2.14 Å. V(1) is bonded to three equivalent C(1) and three equivalent N(1) atoms to form VC3N3 octahedra that share corners with six equivalent Ti(1)C3N3 octahedra, edges with six equivalent Ti(1)C3N3 octahedra, and edges with six equivalent V(1)C3N3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. All V(1)-C(1) bond lengths are 2.07 Å. All V(1)-N(1) bond lengths are 2.12 Å. C(1) is bonded to three equivalent Ti(1) and three equivalent V(1) atoms to form CTi3V3 octahedra that share corners with six equivalent N(1)Ti3V3 octahedra, edges with six equivalent C(1)Ti3V3 octahedra, and edges with six equivalent N(1)Ti3V3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. N(1) is bonded to three equivalent Ti(1) and three equivalent V(1) atoms to form NTi3V3 octahedra that share corners with six equivalent C(1)Ti3V3 octahedra, edges with six equivalent C(1)Ti3V3 octahedra, and edges with six equivalent N(1)Ti3V3 octahedra. The corner-sharing octahedral tilt angles range from 1-2°.