DySCl is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Dy(1) is bonded to four equivalent S(1) and three equivalent Cl(1) atoms to form a mixture of distorted edge and corner-sharing DyS4Cl3 pentagonal bipyramids. S(1) is bonded to four equivalent Dy(1) atoms to form a mixture of edge and corner-sharing SDy4 tetrahedra. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Dy(1) atoms.
DySCl is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Dy(1) is bonded to four equivalent S(1) and three equivalent Cl(1) atoms to form a mixture of distorted edge and corner-sharing DyS4Cl3 pentagonal bipyramids. There are three shorter (2.72 Å) and one longer (2.74 Å) Dy(1)-S(1) bond length. There are a spread of Dy(1)-Cl(1) bond distances ranging from 2.79-2.85 Å. S(1) is bonded to four equivalent Dy(1) atoms to form a mixture of edge and corner-sharing SDy4 tetrahedra. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Dy(1) atoms.