(PtS2O9)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one PtS2O9 cluster. In the PtS2O9 cluster, Pt(1) is bonded to one O(1), one O(2), one O(7), one O(8), and one O(9) atom to form PtO5 square pyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent S(2)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Pt(1) atom.
(PtS2O9)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one PtS2O9 cluster. In the PtS2O9 cluster, Pt(1) is bonded to one O(1), one O(2), one O(7), one O(8), and one O(9) atom to form PtO5 square pyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent S(2)O4 tetrahedra. The Pt(1)-O(1) bond length is 2.01 Å. The Pt(1)-O(2) bond length is 2.02 Å. The Pt(1)-O(7) bond length is 2.01 Å. The Pt(1)-O(8) bond length is 2.01 Å. The Pt(1)-O(9) bond length is 1.98 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. The S(1)-O(1) bond length is 1.58 Å. The S(1)-O(2) bond length is 1.57 Å. The S(1)-O(3) bond length is 1.44 Å. The S(1)-O(4) bond length is 1.44 Å. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. The S(2)-O(5) bond length is 1.44 Å. The S(2)-O(6) bond length is 1.45 Å. The S(2)-O(7) bond length is 1.58 Å. The S(2)-O(8) bond length is 1.58 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Pt(1) atom.