CsCdInTe3 crystallizes in the monoclinic C2/c space group. Cs(1,2) is bonded in a 6-coordinate geometry to one Te(1), one Te(2), one Te(3), one Te(4), one Te(5), and one Te(6) atom. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent Te(2) and two equivalent Te(6) atoms to form CdTe4 tetrahedra that share corners with two equivalent In(1)Te4 tetrahedra, corners with two equivalent In(2)Te4 tetrahedra, and corners with four equivalent Cd(3)Te4 tetrahedra. In the second Cd site, Cd(2) is bonded to two equivalent Te(4) and two equivalent Te(5) atoms to form CdTe4 tetrahedra that share corners with two equivalent In(1)Te4 tetrahedra, corners with two equivalent In(2)Te4 tetrahedra, and corners with four equivalent Cd(3)Te4 tetrahedra. In the third Cd site, Cd(3) is bonded to one Te(2), one Te(4), one Te(5), and one Te(6) atom to form CdTe4 tetrahedra that share corners with two equivalent Cd(1)Te4 tetrahedra, corners with two equivalent Cd(2)Te4 tetrahedra, corners with two equivalent In(1)Te4 tetrahedra, and corners with two equivalent In(2)Te4 tetrahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to one Te(1), one Te(3), one Te(4), and one Te(6) atom to form InTe4 tetrahedra that share  a cornercorner with one Cd(1)Te4 tetrahedra,  a cornercorner with one Cd(2)Te4 tetrahedra, corners with two equivalent Cd(3)Te4 tetrahedra, and corners with two equivalent In(2)Te4 tetrahedra. In the second In site, In(2) is bonded to one Te(1), one Te(2), one Te(3), and one Te(5) atom to form InTe4 tetrahedra that share  a cornercorner with one Cd(1)Te4 tetrahedra,  a cornercorner with one Cd(2)Te4 tetrahedra, corners with two equivalent Cd(3)Te4 tetrahedra, and corners with two equivalent In(1)Te4 tetrahedra. There are six inequivalent Te sites. In the first Te site, Te(5) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(2); one Cd(3); and one In(2) atom. In the second Te site, Te(6) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(1); one Cd(3); and one In(1) atom. In the third Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cs(1,2); one In(1); and one In(2) atom. In the fourth Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(1); one Cd(3); and one In(2) atom. In the fifth Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cs(1,2); one In(1); and one In(2) atom. In the sixth Te site, Te(4) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(2); one Cd(3); and one In(1) atom.
CsCdInTe3 crystallizes in the monoclinic C2/c space group. Cs(1,2) is bonded in a 6-coordinate geometry to one Te(1), one Te(2), one Te(3), one Te(4), one Te(5), and one Te(6) atom. The Cs(1,2)-Te(1) bond length is 3.91 Å. The Cs(1,2)-Te(2) bond length is 4.02 Å. The Cs(1,2)-Te(3) bond length is 3.91 Å. The Cs(1,2)-Te(4) bond length is 4.02 Å. The Cs(1,2)-Te(5) bond length is 4.02 Å. The Cs(1,2)-Te(6) bond length is 4.02 Å. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to two equivalent Te(2) and two equivalent Te(6) atoms to form CdTe4 tetrahedra that share corners with two equivalent In(1)Te4 tetrahedra, corners with two equivalent In(2)Te4 tetrahedra, and corners with four equivalent Cd(3)Te4 tetrahedra. Both Cd(1)-Te(2) bond lengths are 2.89 Å. Both Cd(1)-Te(6) bond lengths are 2.86 Å. In the second Cd site, Cd(2) is bonded to two equivalent Te(4) and two equivalent Te(5) atoms to form CdTe4 tetrahedra that share corners with two equivalent In(1)Te4 tetrahedra, corners with two equivalent In(2)Te4 tetrahedra, and corners with four equivalent Cd(3)Te4 tetrahedra. Both Cd(2)-Te(4) bond lengths are 2.86 Å. Both Cd(2)-Te(5) bond lengths are 2.88 Å. In the third Cd site, Cd(3) is bonded to one Te(2), one Te(4), one Te(5), and one Te(6) atom to form CdTe4 tetrahedra that share corners with two equivalent Cd(1)Te4 tetrahedra, corners with two equivalent Cd(2)Te4 tetrahedra, corners with two equivalent In(1)Te4 tetrahedra, and corners with two equivalent In(2)Te4 tetrahedra. The Cd(3)-Te(2) bond length is 2.88 Å. The Cd(3)-Te(4) bond length is 2.86 Å. The Cd(3)-Te(5) bond length is 2.88 Å. The Cd(3)-Te(6) bond length is 2.86 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded to one Te(1), one Te(3), one Te(4), and one Te(6) atom to form InTe4 tetrahedra that share  a cornercorner with one Cd(1)Te4 tetrahedra,  a cornercorner with one Cd(2)Te4 tetrahedra, corners with two equivalent Cd(3)Te4 tetrahedra, and corners with two equivalent In(2)Te4 tetrahedra. The In(1)-Te(1) bond length is 2.86 Å. The In(1)-Te(3) bond length is 2.86 Å. The In(1)-Te(4) bond length is 2.82 Å. The In(1)-Te(6) bond length is 2.82 Å. In the second In site, In(2) is bonded to one Te(1), one Te(2), one Te(3), and one Te(5) atom to form InTe4 tetrahedra that share  a cornercorner with one Cd(1)Te4 tetrahedra,  a cornercorner with one Cd(2)Te4 tetrahedra, corners with two equivalent Cd(3)Te4 tetrahedra, and corners with two equivalent In(1)Te4 tetrahedra. The In(2)-Te(1) bond length is 2.86 Å. The In(2)-Te(2) bond length is 2.82 Å. The In(2)-Te(3) bond length is 2.86 Å. The In(2)-Te(5) bond length is 2.82 Å. There are six inequivalent Te sites. In the first Te site, Te(5) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(2); one Cd(3); and one In(2) atom. In the second Te site, Te(6) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(1); one Cd(3); and one In(1) atom. In the third Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cs(1,2); one In(1); and one In(2) atom. In the fourth Te site, Te(2) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(1); one Cd(3); and one In(2) atom. In the fifth Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Cs(1,2); one In(1); and one In(2) atom. In the sixth Te site, Te(4) is bonded in a 5-coordinate geometry to two equivalent Cs(1,2); one Cd(2); one Cd(3); and one In(1) atom.