Li5Cr2Mn3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the third Li site, Li(3) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fifth Li site, Li(5) is bonded to one O(10), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-15°. In the second Cr site, Cr(2) is bonded to one O(10), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(3), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(3), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one Cr(1), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra, corners with two equivalent O(6)Li4MnCr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, edges with two equivalent O(7)Li3Mn2Cr octahedra, and edges with two equivalent O(5)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Cr(1), and one Cr(2) atom to form OLi4Cr2 octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra, edges with two equivalent O(7)Li3Mn2Cr octahedra, edges with two equivalent O(9)Li4Cr2 octahedra, edges with two equivalent O(5)Li4MnCr octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the third O site, O(3) is bonded to one Li(2), one Li(5), one Cr(1), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(9)Li4Cr2 octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(5)Li4MnCr octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, and edges with two equivalent O(7)Li3Mn2Cr octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Li(5), one Cr(2), one Mn(1), and one Mn(3) atom to form OLi3Mn2Cr octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(5)Li4MnCr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, edges with two equivalent O(9)Li4Cr2 octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Cr(1), and one Mn(2) atom to form OLi4MnCr octahedra that share  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(7)Li3Mn2Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, and edges with two equivalent O(9)Li4Cr2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Cr(2), and one Mn(3) atom to form OLi4MnCr octahedra that share  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(5)Li4MnCr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(4)Li3Mn2Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, and edges with two equivalent O(9)Li4Cr2 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one Cr(1), one Mn(1), and one Mn(2) atom to form OLi3Mn2Cr octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, and edges with two equivalent O(5)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the eighth O site, O(8) is bonded to one Li(2), one Li(5), one Cr(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(2)Li4Cr2 octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra,  an edgeedge with one O(5)Li4MnCr octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, and edges with two equivalent O(4)Li3Mn2Cr octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Cr(1), and one Cr(2) atom to form OLi4Cr2 octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra, edges with two equivalent O(4)Li3Mn2Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, edges with two equivalent O(5)Li4MnCr octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the tenth O site, O(10) is bonded to one Li(1), one Li(5), one Cr(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra, corners with two equivalent O(5)Li4MnCr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, edges with two equivalent O(4)Li3Mn2Cr octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-13°.
Li5Cr2Mn3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. The Li(1)-O(10) bond length is 2.22 Å. The Li(1)-O(2) bond length is 2.10 Å. The Li(1)-O(4) bond length is 2.43 Å. The Li(1)-O(5) bond length is 2.16 Å. The Li(1)-O(6) bond length is 2.26 Å. The Li(1)-O(9) bond length is 2.06 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. The Li(2)-O(1) bond length is 2.08 Å. The Li(2)-O(2) bond length is 2.03 Å. The Li(2)-O(3) bond length is 2.41 Å. The Li(2)-O(5) bond length is 2.06 Å. The Li(2)-O(7) bond length is 2.22 Å. The Li(2)-O(8) bond length is 2.23 Å. In the third Li site, Li(3) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. The Li(3)-O(2) bond length is 2.17 Å. The Li(3)-O(4) bond length is 2.17 Å. The Li(3)-O(5) bond length is 2.11 Å. The Li(3)-O(6) bond length is 2.11 Å. The Li(3)-O(7) bond length is 2.17 Å. The Li(3)-O(9) bond length is 2.16 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. The Li(4)-O(1) bond length is 2.29 Å. The Li(4)-O(2) bond length is 2.13 Å. The Li(4)-O(5) bond length is 2.19 Å. The Li(4)-O(6) bond length is 2.09 Å. The Li(4)-O(7) bond length is 2.42 Å. The Li(4)-O(9) bond length is 2.12 Å. In the fifth Li site, Li(5) is bonded to one O(10), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. The Li(5)-O(10) bond length is 2.10 Å. The Li(5)-O(3) bond length is 2.20 Å. The Li(5)-O(4) bond length is 2.20 Å. The Li(5)-O(6) bond length is 2.07 Å. The Li(5)-O(8) bond length is 2.40 Å. The Li(5)-O(9) bond length is 2.04 Å. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-15°. The Cr(1)-O(1) bond length is 2.08 Å. The Cr(1)-O(2) bond length is 2.00 Å. The Cr(1)-O(3) bond length is 2.09 Å. The Cr(1)-O(5) bond length is 2.02 Å. The Cr(1)-O(7) bond length is 2.09 Å. The Cr(1)-O(9) bond length is 1.97 Å. In the second Cr site, Cr(2) is bonded to one O(10), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-14°. The Cr(2)-O(10) bond length is 2.08 Å. The Cr(2)-O(2) bond length is 1.97 Å. The Cr(2)-O(4) bond length is 2.09 Å. The Cr(2)-O(6) bond length is 2.02 Å. The Cr(2)-O(8) bond length is 2.08 Å. The Cr(2)-O(9) bond length is 2.00 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. The Mn(1)-O(1) bond length is 2.23 Å. The Mn(1)-O(10) bond length is 2.23 Å. The Mn(1)-O(3) bond length is 2.01 Å. The Mn(1)-O(4) bond length is 1.98 Å. The Mn(1)-O(7) bond length is 1.98 Å. The Mn(1)-O(8) bond length is 2.01 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(3), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. The Mn(2)-O(1) bond length is 2.19 Å. The Mn(2)-O(10) bond length is 2.00 Å. The Mn(2)-O(3) bond length is 2.24 Å. The Mn(2)-O(5) bond length is 1.92 Å. The Mn(2)-O(7) bond length is 1.98 Å. The Mn(2)-O(8) bond length is 2.02 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(3), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. The Mn(3)-O(1) bond length is 1.99 Å. The Mn(3)-O(10) bond length is 2.19 Å. The Mn(3)-O(3) bond length is 2.03 Å. The Mn(3)-O(4) bond length is 1.99 Å. The Mn(3)-O(6) bond length is 1.92 Å. The Mn(3)-O(8) bond length is 2.24 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one Cr(1), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra, corners with two equivalent O(6)Li4MnCr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, edges with two equivalent O(7)Li3Mn2Cr octahedra, and edges with two equivalent O(5)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Cr(1), and one Cr(2) atom to form OLi4Cr2 octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra, edges with two equivalent O(7)Li3Mn2Cr octahedra, edges with two equivalent O(9)Li4Cr2 octahedra, edges with two equivalent O(5)Li4MnCr octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the third O site, O(3) is bonded to one Li(2), one Li(5), one Cr(1), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(9)Li4Cr2 octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(5)Li4MnCr octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, and edges with two equivalent O(7)Li3Mn2Cr octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Li(5), one Cr(2), one Mn(1), and one Mn(3) atom to form OLi3Mn2Cr octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(5)Li4MnCr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, edges with two equivalent O(9)Li4Cr2 octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one Cr(1), and one Mn(2) atom to form OLi4MnCr octahedra that share  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(7)Li3Mn2Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, and edges with two equivalent O(9)Li4Cr2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Cr(2), and one Mn(3) atom to form OLi4MnCr octahedra that share  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(5)Li4MnCr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(4)Li3Mn2Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, and edges with two equivalent O(9)Li4Cr2 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one Cr(1), one Mn(1), and one Mn(2) atom to form OLi3Mn2Cr octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra,  a cornercorner with one O(5)Li4MnCr octahedra, corners with two equivalent O(4)Li3Mn2Cr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, and edges with two equivalent O(5)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-15°. In the eighth O site, O(8) is bonded to one Li(2), one Li(5), one Cr(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(3)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(2)Li4Cr2 octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra,  an edgeedge with one O(5)Li4MnCr octahedra,  an edgeedge with one O(6)Li4MnCr octahedra, edges with two equivalent O(1)Li2Mn3Cr octahedra, edges with two equivalent O(10)Li2Mn3Cr octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, and edges with two equivalent O(4)Li3Mn2Cr octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Cr(1), and one Cr(2) atom to form OLi4Cr2 octahedra that share  a cornercorner with one O(10)Li2Mn3Cr octahedra,  a cornercorner with one O(7)Li3Mn2Cr octahedra,  a cornercorner with one O(2)Li4Cr2 octahedra,  a cornercorner with one O(6)Li4MnCr octahedra, corners with two equivalent O(3)Li2Mn3Cr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(10)Li2Mn3Cr octahedra,  an edgeedge with one O(8)Li2Mn3Cr octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra, edges with two equivalent O(4)Li3Mn2Cr octahedra, edges with two equivalent O(2)Li4Cr2 octahedra, edges with two equivalent O(5)Li4MnCr octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the tenth O site, O(10) is bonded to one Li(1), one Li(5), one Cr(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2Mn3Cr octahedra that share  a cornercorner with one O(1)Li2Mn3Cr octahedra,  a cornercorner with one O(8)Li2Mn3Cr octahedra,  a cornercorner with one O(4)Li3Mn2Cr octahedra,  a cornercorner with one O(9)Li4Cr2 octahedra, corners with two equivalent O(5)Li4MnCr octahedra,  an edgeedge with one O(1)Li2Mn3Cr octahedra,  an edgeedge with one O(7)Li3Mn2Cr octahedra,  an edgeedge with one O(2)Li4Cr2 octahedra,  an edgeedge with one O(9)Li4Cr2 octahedra, edges with two equivalent O(3)Li2Mn3Cr octahedra, edges with two equivalent O(8)Li2Mn3Cr octahedra, edges with two equivalent O(4)Li3Mn2Cr octahedra, and edges with two equivalent O(6)Li4MnCr octahedra. The corner-sharing octahedral tilt angles range from 0-13°.