MoZnN2 is Ilmenite-like structured and crystallizes in the hexagonal P6_3mc space group. Mo(1) is bonded in a 6-coordinate geometry to three equivalent N(1) and three equivalent N(2) atoms. Zn(1) is bonded in a rectangular see-saw-like geometry to one N(1) and three equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to three equivalent Mo(1) and one Zn(1) atom. In the second N site, N(2) is bonded to three equivalent Mo(1) and three equivalent Zn(1) atoms to form distorted edge-sharing NZn3Mo3 pentagonal pyramids.
MoZnN2 is Ilmenite-like structured and crystallizes in the hexagonal P6_3mc space group. Mo(1) is bonded in a 6-coordinate geometry to three equivalent N(1) and three equivalent N(2) atoms. All Mo(1)-N(1) bond lengths are 2.08 Å. All Mo(1)-N(2) bond lengths are 2.15 Å. Zn(1) is bonded in a rectangular see-saw-like geometry to one N(1) and three equivalent N(2) atoms. The Zn(1)-N(1) bond length is 1.88 Å. All Zn(1)-N(2) bond lengths are 2.12 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to three equivalent Mo(1) and one Zn(1) atom. In the second N site, N(2) is bonded to three equivalent Mo(1) and three equivalent Zn(1) atoms to form distorted edge-sharing NZn3Mo3 pentagonal pyramids.