CsAgO2 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Ag(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Cs(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing OCs3Ag2 trigonal bipyramids.
CsAgO2 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are two shorter (2.95 Å) and four longer (3.16 Å) Cs(1)-O(1) bond lengths. Ag(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. All Ag(1)-O(1) bond lengths are 2.00 Å. O(1) is bonded to three equivalent Cs(1) and two equivalent Ag(1) atoms to form a mixture of distorted edge, face, and corner-sharing OCs3Ag2 trigonal bipyramids.