LiGaTe2 is Chalcopyrite structured and crystallizes in the tetragonal I-42d space group. Li(1) is bonded to four equivalent Te(1) atoms to form LiTe4 tetrahedra that share corners with four equivalent Li(1)Te4 tetrahedra and corners with eight equivalent Ga(1)Te4 tetrahedra. Ga(1) is bonded to four equivalent Te(1) atoms to form GaTe4 tetrahedra that share corners with four equivalent Ga(1)Te4 tetrahedra and corners with eight equivalent Li(1)Te4 tetrahedra. Te(1) is bonded to two equivalent Li(1) and two equivalent Ga(1) atoms to form corner-sharing TeLi2Ga2 tetrahedra.
LiGaTe2 is Chalcopyrite structured and crystallizes in the tetragonal I-42d space group. Li(1) is bonded to four equivalent Te(1) atoms to form LiTe4 tetrahedra that share corners with four equivalent Li(1)Te4 tetrahedra and corners with eight equivalent Ga(1)Te4 tetrahedra. All Li(1)-Te(1) bond lengths are 2.75 Å. Ga(1) is bonded to four equivalent Te(1) atoms to form GaTe4 tetrahedra that share corners with four equivalent Ga(1)Te4 tetrahedra and corners with eight equivalent Li(1)Te4 tetrahedra. All Ga(1)-Te(1) bond lengths are 2.63 Å. Te(1) is bonded to two equivalent Li(1) and two equivalent Ga(1) atoms to form corner-sharing TeLi2Ga2 tetrahedra.