NaSrGaF6 crystallizes in the orthorhombic P2_12_12_1 space group. Na(1) is bonded in a 6-coordinate geometry to one F(2), one F(4), one F(5), one F(6), and two equivalent F(1) atoms. Sr(1) is bonded in a 7-coordinate geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and two equivalent F(3) atoms. Ga(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one Ga(1) atom. In the second F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Sr(1), and one Ga(1) atom. In the third F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one Ga(1) atom. In the fourth F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Sr(1) and one Ga(1) atom. In the fifth F site, F(4) is bonded in a distorted trigonal planar geometry to one Na(1), one Sr(1), and one Ga(1) atom. In the sixth F site, F(5) is bonded in a trigonal planar geometry to one Na(1), one Sr(1), and one Ga(1) atom.
NaSrGaF6 crystallizes in the orthorhombic P2_12_12_1 space group. Na(1) is bonded in a 6-coordinate geometry to one F(2), one F(4), one F(5), one F(6), and two equivalent F(1) atoms. The Na(1)-F(2) bond length is 2.43 Å. The Na(1)-F(4) bond length is 2.35 Å. The Na(1)-F(5) bond length is 2.25 Å. The Na(1)-F(6) bond length is 2.32 Å. There is one shorter (2.26 Å) and one longer (2.39 Å) Na(1)-F(1) bond length. Sr(1) is bonded in a 7-coordinate geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and two equivalent F(3) atoms. The Sr(1)-F(1) bond length is 2.75 Å. The Sr(1)-F(2) bond length is 2.41 Å. The Sr(1)-F(4) bond length is 2.42 Å. The Sr(1)-F(5) bond length is 2.47 Å. The Sr(1)-F(6) bond length is 2.49 Å. There is one shorter (2.54 Å) and one longer (2.65 Å) Sr(1)-F(3) bond length. Ga(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Ga(1)-F(1) bond length is 1.95 Å. The Ga(1)-F(2) bond length is 1.92 Å. The Ga(1)-F(3) bond length is 1.94 Å. The Ga(1)-F(4) bond length is 1.93 Å. The Ga(1)-F(5) bond length is 1.91 Å. The Ga(1)-F(6) bond length is 1.92 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one Ga(1) atom. In the second F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Sr(1), and one Ga(1) atom. In the third F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one Ga(1) atom. In the fourth F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Sr(1) and one Ga(1) atom. In the fifth F site, F(4) is bonded in a distorted trigonal planar geometry to one Na(1), one Sr(1), and one Ga(1) atom. In the sixth F site, F(5) is bonded in a trigonal planar geometry to one Na(1), one Sr(1), and one Ga(1) atom.