AgTe crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), two equivalent Te(1), and two equivalent Te(3) atoms. In the second Ag site, Ag(2) is bonded in a 7-coordinate geometry to two equivalent Ag(1), one Te(3), two equivalent Te(1), and two equivalent Te(2) atoms. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent Te(1), and two equivalent Te(3) atoms. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Ag(2), one Ag(3), two equivalent Ag(1), and one Te(2) atom. In the second Te site, Te(2) is bonded in a 1-coordinate geometry to two equivalent Ag(2) and two equivalent Te(1) atoms. In the third Te site, Te(3) is bonded in a 6-coordinate geometry to one Ag(2), two equivalent Ag(3), and four equivalent Ag(1) atoms.
AgTe crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), two equivalent Te(1), and two equivalent Te(3) atoms. The Ag(1)-Ag(1) bond length is 2.97 Å. The Ag(1)-Ag(2) bond length is 2.87 Å. The Ag(1)-Ag(3) bond length is 2.88 Å. There is one shorter (2.80 Å) and one longer (3.10 Å) Ag(1)-Te(1) bond length. There is one shorter (2.80 Å) and one longer (2.97 Å) Ag(1)-Te(3) bond length. In the second Ag site, Ag(2) is bonded in a 7-coordinate geometry to two equivalent Ag(1), one Te(3), two equivalent Te(1), and two equivalent Te(2) atoms. The Ag(2)-Te(3) bond length is 3.43 Å. Both Ag(2)-Te(1) bond lengths are 2.92 Å. There is one shorter (2.80 Å) and one longer (3.52 Å) Ag(2)-Te(2) bond length. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent Te(1), and two equivalent Te(3) atoms. Both Ag(3)-Te(1) bond lengths are 2.96 Å. There is one shorter (2.82 Å) and one longer (2.90 Å) Ag(3)-Te(3) bond length. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Ag(2), one Ag(3), two equivalent Ag(1), and one Te(2) atom. The Te(1)-Te(2) bond length is 2.88 Å. In the second Te site, Te(2) is bonded in a 1-coordinate geometry to two equivalent Ag(2) and two equivalent Te(1) atoms. In the third Te site, Te(3) is bonded in a 6-coordinate geometry to one Ag(2), two equivalent Ag(3), and four equivalent Ag(1) atoms.