Ga(NO3)4NO2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two Ga(NO3)4 clusters. In each Ga(NO3)4 cluster, Ga(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Ga(1) and one N(2) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Ga(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(2) atom.
Ga(NO3)4NO2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two Ga(NO3)4 clusters. In each Ga(NO3)4 cluster, Ga(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. Both Ga(1)-O(1) bond lengths are 1.91 Å. Both Ga(1)-O(4) bond lengths are 1.99 Å. Both Ga(1)-O(5) bond lengths are 2.16 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.33 Å. The N(1)-O(2) bond length is 1.23 Å. The N(1)-O(3) bond length is 1.23 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(2)-O(4) bond length is 1.31 Å. The N(2)-O(5) bond length is 1.27 Å. The N(2)-O(6) bond length is 1.21 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Ga(1) and one N(2) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Ga(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(2) atom.