CSCl(OF)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CSCl(OF)3 clusters. C(1) is bonded to one O(2), one F(1), one F(2), and one F(3) atom to form COF3 tetrahedra that share  a cornercorner with one S(1)ClO3 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form distorted SClO3 tetrahedra that share  a cornercorner with one C(1)OF3 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(1) atom.
CSCl(OF)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CSCl(OF)3 clusters. C(1) is bonded to one O(2), one F(1), one F(2), and one F(3) atom to form COF3 tetrahedra that share  a cornercorner with one S(1)ClO3 tetrahedra. The C(1)-O(2) bond length is 1.40 Å. The C(1)-F(1) bond length is 1.34 Å. The C(1)-F(2) bond length is 1.35 Å. The C(1)-F(3) bond length is 1.35 Å. S(1) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form distorted SClO3 tetrahedra that share  a cornercorner with one C(1)OF3 tetrahedra. The S(1)-O(1) bond length is 1.43 Å. The S(1)-O(2) bond length is 1.65 Å. The S(1)-O(3) bond length is 1.42 Å. The S(1)-Cl(1) bond length is 2.01 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(1) atom.