LiCo15O16 is Caswellsilverite-like structured and crystallizes in the triclinic P-1 space group. Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Co(7)O6 octahedra, corners with four equivalent Co(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are nine inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form CoO6 octahedra that share corners with three equivalent Co(5)O6 octahedra, corners with three equivalent Co(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Co(6)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. In the third Co site, Co(3) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(8) atom to form CoO6 octahedra that share corners with three equivalent Co(4)O6 octahedra, corners with three equivalent Co(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the fourth Co site, Co(4) is bonded to one O(1), one O(4), one O(6), one O(8), and two equivalent O(5) atoms to form CoO6 octahedra that share  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the fifth Co site, Co(5) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth Co site, Co(6) is bonded to one O(3), one O(6), one O(7), one O(8), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(8)O6 octahedra, corners with three equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with three equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the seventh Co site, Co(7) is bonded to one O(2), one O(4), one O(7), one O(8), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Co(9)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the eighth Co site, Co(8) is bonded to two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the ninth Co site, Co(9) is bonded to two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 1°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(3), one Co(4), one Co(9), and two equivalent Co(5) atoms to form OCo6 octahedra that share  a cornercorner with one O(1)Co6 octahedra,  a cornercorner with one O(7)Co6 octahedra, corners with two equivalent O(3)LiCo5 octahedra, corners with two equivalent O(4)LiCo5 octahedra,  an edgeedge with one O(1)Co6 octahedra,  an edgeedge with one O(2)Co6 octahedra,  an edgeedge with one O(4)LiCo5 octahedra, edges with two equivalent O(7)Co6 octahedra, edges with two equivalent O(8)Co6 octahedra, edges with two equivalent O(6)LiCo5 octahedra, and edges with three equivalent O(5)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to one Co(1), one Co(2), one Co(3), one Co(7), and two equivalent Co(6) atoms to form OCo6 octahedra that share  a cornercorner with one O(2)Co6 octahedra,  a cornercorner with one O(6)LiCo5 octahedra, corners with two equivalent O(5)Co6 octahedra, corners with two equivalent O(8)Co6 octahedra,  an edgeedge with one O(1)Co6 octahedra,  an edgeedge with one O(2)Co6 octahedra,  an edgeedge with one O(8)Co6 octahedra, edges with two equivalent O(7)Co6 octahedra, edges with two equivalent O(4)LiCo5 octahedra, edges with two equivalent O(6)LiCo5 octahedra, and edges with three equivalent O(3)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third O site, O(3) is bonded to one Li(1), one Co(1), one Co(3), one Co(6), and two equivalent Co(7) atoms to form OLiCo5 octahedra that share  a cornercorner with one O(3)LiCo5 octahedra,  a cornercorner with one O(4)LiCo5 octahedra, corners with two equivalent O(1)Co6 octahedra, corners with two equivalent O(7)Co6 octahedra,  an edgeedge with one O(5)Co6 octahedra,  an edgeedge with one O(7)Co6 octahedra,  an edgeedge with one O(3)LiCo5 octahedra, edges with two equivalent O(8)Co6 octahedra, edges with two equivalent O(4)LiCo5 octahedra, edges with two equivalent O(6)LiCo5 octahedra, and edges with three equivalent O(2)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth O site, O(4) is bonded to one Li(1), one Co(1), one Co(2), one Co(4), one Co(5), and one Co(7) atom to form OLiCo5 octahedra that share  a cornercorner with one O(7)Co6 octahedra,  a cornercorner with one O(3)LiCo5 octahedra, corners with two equivalent O(1)Co6 octahedra, corners with two equivalent O(4)LiCo5 octahedra,  an edgeedge with one O(1)Co6 octahedra,  an edgeedge with one O(7)Co6 octahedra,  an edgeedge with one O(8)Co6 octahedra, edges with two equivalent O(2)Co6 octahedra, edges with two equivalent O(5)Co6 octahedra, edges with two equivalent O(3)LiCo5 octahedra, and edges with three equivalent O(6)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fifth O site, O(5) is bonded to one Co(1), one Co(3), one Co(5), one Co(8), and two equivalent Co(4) atoms to form OCo6 octahedra that share  a cornercorner with one O(5)Co6 octahedra,  a cornercorner with one O(8)Co6 octahedra, corners with two equivalent O(2)Co6 octahedra, corners with two equivalent O(6)LiCo5 octahedra,  an edgeedge with one O(5)Co6 octahedra,  an edgeedge with one O(3)LiCo5 octahedra,  an edgeedge with one O(6)LiCo5 octahedra, edges with two equivalent O(7)Co6 octahedra, edges with two equivalent O(8)Co6 octahedra, edges with two equivalent O(4)LiCo5 octahedra, and edges with three equivalent O(1)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the sixth O site, O(6) is bonded to one Li(1), one Co(2), one Co(3), one Co(4), one Co(5), and one Co(6) atom to form OLiCo5 octahedra that share  a cornercorner with one O(2)Co6 octahedra,  a cornercorner with one O(8)Co6 octahedra, corners with two equivalent O(5)Co6 octahedra, corners with two equivalent O(6)LiCo5 octahedra,  an edgeedge with one O(5)Co6 octahedra,  an edgeedge with one O(7)Co6 octahedra,  an edgeedge with one O(8)Co6 octahedra, edges with two equivalent O(1)Co6 octahedra, edges with two equivalent O(2)Co6 octahedra, edges with two equivalent O(3)LiCo5 octahedra, and edges with three equivalent O(4)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh O site, O(7) is bonded to one Co(1), one Co(5), one Co(6), one Co(7), one Co(8), and one Co(9) atom to form OCo6 octahedra that share  a cornercorner with one O(1)Co6 octahedra,  a cornercorner with one O(4)LiCo5 octahedra, corners with two equivalent O(7)Co6 octahedra, corners with two equivalent O(3)LiCo5 octahedra,  an edgeedge with one O(3)LiCo5 octahedra,  an edgeedge with one O(4)LiCo5 octahedra,  an edgeedge with one O(6)LiCo5 octahedra, edges with two equivalent O(1)Co6 octahedra, edges with two equivalent O(2)Co6 octahedra, edges with two equivalent O(5)Co6 octahedra, and edges with three equivalent O(8)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the eighth O site, O(8) is bonded to one Co(3), one Co(4), one Co(6), one Co(7), one Co(8), and one Co(9) atom to form OCo6 octahedra that share  a cornercorner with one O(5)Co6 octahedra,  a cornercorner with one O(6)LiCo5 octahedra, corners with two equivalent O(2)Co6 octahedra, corners with two equivalent O(8)Co6 octahedra,  an edgeedge with one O(2)Co6 octahedra,  an edgeedge with one O(4)LiCo5 octahedra,  an edgeedge with one O(6)LiCo5 octahedra, edges with two equivalent O(1)Co6 octahedra, edges with two equivalent O(5)Co6 octahedra, edges with two equivalent O(3)LiCo5 octahedra, and edges with three equivalent O(7)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°.
LiCo15O16 is Caswellsilverite-like structured and crystallizes in the triclinic P-1 space group. Li(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with two equivalent Co(7)O6 octahedra, corners with four equivalent Co(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. Both Li(1)-O(3) bond lengths are 2.21 Å. Both Li(1)-O(4) bond lengths are 2.16 Å. Both Li(1)-O(6) bond lengths are 2.16 Å. There are nine inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form CoO6 octahedra that share corners with three equivalent Co(5)O6 octahedra, corners with three equivalent Co(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Co(1)-O(1) bond length is 2.15 Å. The Co(1)-O(2) bond length is 2.11 Å. The Co(1)-O(3) bond length is 2.11 Å. The Co(1)-O(4) bond length is 2.13 Å. The Co(1)-O(5) bond length is 2.14 Å. The Co(1)-O(7) bond length is 2.17 Å. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent Co(6)O6 octahedra, corners with four equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. Both Co(2)-O(2) bond lengths are 2.14 Å. Both Co(2)-O(4) bond lengths are 2.13 Å. Both Co(2)-O(6) bond lengths are 2.08 Å. In the third Co site, Co(3) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(8) atom to form CoO6 octahedra that share corners with three equivalent Co(4)O6 octahedra, corners with three equivalent Co(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. The Co(3)-O(1) bond length is 2.16 Å. The Co(3)-O(2) bond length is 2.12 Å. The Co(3)-O(3) bond length is 2.13 Å. The Co(3)-O(5) bond length is 2.13 Å. The Co(3)-O(6) bond length is 2.13 Å. The Co(3)-O(8) bond length is 2.18 Å. In the fourth Co site, Co(4) is bonded to one O(1), one O(4), one O(6), one O(8), and two equivalent O(5) atoms to form CoO6 octahedra that share  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. The Co(4)-O(1) bond length is 2.16 Å. The Co(4)-O(4) bond length is 2.10 Å. The Co(4)-O(6) bond length is 2.12 Å. The Co(4)-O(8) bond length is 2.13 Å. There is one shorter (2.13 Å) and one longer (2.19 Å) Co(4)-O(5) bond length. In the fifth Co site, Co(5) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. The Co(5)-O(4) bond length is 2.09 Å. The Co(5)-O(5) bond length is 2.15 Å. The Co(5)-O(6) bond length is 2.09 Å. The Co(5)-O(7) bond length is 2.16 Å. There is one shorter (2.13 Å) and one longer (2.15 Å) Co(5)-O(1) bond length. In the sixth Co site, Co(6) is bonded to one O(3), one O(6), one O(7), one O(8), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(8)O6 octahedra, corners with three equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with three equivalent Co(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. The Co(6)-O(3) bond length is 2.11 Å. The Co(6)-O(6) bond length is 2.14 Å. The Co(6)-O(7) bond length is 2.15 Å. The Co(6)-O(8) bond length is 2.14 Å. There is one shorter (2.14 Å) and one longer (2.16 Å) Co(6)-O(2) bond length. In the seventh Co site, Co(7) is bonded to one O(2), one O(4), one O(7), one O(8), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Co(9)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. The Co(7)-O(2) bond length is 2.15 Å. The Co(7)-O(4) bond length is 2.12 Å. The Co(7)-O(7) bond length is 2.15 Å. The Co(7)-O(8) bond length is 2.16 Å. There is one shorter (2.09 Å) and one longer (2.12 Å) Co(7)-O(3) bond length. In the eighth Co site, Co(8) is bonded to two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. Both Co(8)-O(5) bond lengths are 2.16 Å. Both Co(8)-O(7) bond lengths are 2.15 Å. Both Co(8)-O(8) bond lengths are 2.13 Å. In the ninth Co site, Co(9) is bonded to two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 1°. Both Co(9)-O(1) bond lengths are 2.14 Å. Both Co(9)-O(7) bond lengths are 2.13 Å. Both Co(9)-O(8) bond lengths are 2.12 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(3), one Co(4), one Co(9), and two equivalent Co(5) atoms to form OCo6 octahedra that share  a cornercorner with one O(1)Co6 octahedra,  a cornercorner with one O(7)Co6 octahedra, corners with two equivalent O(3)LiCo5 octahedra, corners with two equivalent O(4)LiCo5 octahedra,  an edgeedge with one O(1)Co6 octahedra,  an edgeedge with one O(2)Co6 octahedra,  an edgeedge with one O(4)LiCo5 octahedra, edges with two equivalent O(7)Co6 octahedra, edges with two equivalent O(8)Co6 octahedra, edges with two equivalent O(6)LiCo5 octahedra, and edges with three equivalent O(5)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to one Co(1), one Co(2), one Co(3), one Co(7), and two equivalent Co(6) atoms to form OCo6 octahedra that share  a cornercorner with one O(2)Co6 octahedra,  a cornercorner with one O(6)LiCo5 octahedra, corners with two equivalent O(5)Co6 octahedra, corners with two equivalent O(8)Co6 octahedra,  an edgeedge with one O(1)Co6 octahedra,  an edgeedge with one O(2)Co6 octahedra,  an edgeedge with one O(8)Co6 octahedra, edges with two equivalent O(7)Co6 octahedra, edges with two equivalent O(4)LiCo5 octahedra, edges with two equivalent O(6)LiCo5 octahedra, and edges with three equivalent O(3)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third O site, O(3) is bonded to one Li(1), one Co(1), one Co(3), one Co(6), and two equivalent Co(7) atoms to form OLiCo5 octahedra that share  a cornercorner with one O(3)LiCo5 octahedra,  a cornercorner with one O(4)LiCo5 octahedra, corners with two equivalent O(1)Co6 octahedra, corners with two equivalent O(7)Co6 octahedra,  an edgeedge with one O(5)Co6 octahedra,  an edgeedge with one O(7)Co6 octahedra,  an edgeedge with one O(3)LiCo5 octahedra, edges with two equivalent O(8)Co6 octahedra, edges with two equivalent O(4)LiCo5 octahedra, edges with two equivalent O(6)LiCo5 octahedra, and edges with three equivalent O(2)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the fourth O site, O(4) is bonded to one Li(1), one Co(1), one Co(2), one Co(4), one Co(5), and one Co(7) atom to form OLiCo5 octahedra that share  a cornercorner with one O(7)Co6 octahedra,  a cornercorner with one O(3)LiCo5 octahedra, corners with two equivalent O(1)Co6 octahedra, corners with two equivalent O(4)LiCo5 octahedra,  an edgeedge with one O(1)Co6 octahedra,  an edgeedge with one O(7)Co6 octahedra,  an edgeedge with one O(8)Co6 octahedra, edges with two equivalent O(2)Co6 octahedra, edges with two equivalent O(5)Co6 octahedra, edges with two equivalent O(3)LiCo5 octahedra, and edges with three equivalent O(6)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fifth O site, O(5) is bonded to one Co(1), one Co(3), one Co(5), one Co(8), and two equivalent Co(4) atoms to form OCo6 octahedra that share  a cornercorner with one O(5)Co6 octahedra,  a cornercorner with one O(8)Co6 octahedra, corners with two equivalent O(2)Co6 octahedra, corners with two equivalent O(6)LiCo5 octahedra,  an edgeedge with one O(5)Co6 octahedra,  an edgeedge with one O(3)LiCo5 octahedra,  an edgeedge with one O(6)LiCo5 octahedra, edges with two equivalent O(7)Co6 octahedra, edges with two equivalent O(8)Co6 octahedra, edges with two equivalent O(4)LiCo5 octahedra, and edges with three equivalent O(1)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the sixth O site, O(6) is bonded to one Li(1), one Co(2), one Co(3), one Co(4), one Co(5), and one Co(6) atom to form OLiCo5 octahedra that share  a cornercorner with one O(2)Co6 octahedra,  a cornercorner with one O(8)Co6 octahedra, corners with two equivalent O(5)Co6 octahedra, corners with two equivalent O(6)LiCo5 octahedra,  an edgeedge with one O(5)Co6 octahedra,  an edgeedge with one O(7)Co6 octahedra,  an edgeedge with one O(8)Co6 octahedra, edges with two equivalent O(1)Co6 octahedra, edges with two equivalent O(2)Co6 octahedra, edges with two equivalent O(3)LiCo5 octahedra, and edges with three equivalent O(4)LiCo5 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the seventh O site, O(7) is bonded to one Co(1), one Co(5), one Co(6), one Co(7), one Co(8), and one Co(9) atom to form OCo6 octahedra that share  a cornercorner with one O(1)Co6 octahedra,  a cornercorner with one O(4)LiCo5 octahedra, corners with two equivalent O(7)Co6 octahedra, corners with two equivalent O(3)LiCo5 octahedra,  an edgeedge with one O(3)LiCo5 octahedra,  an edgeedge with one O(4)LiCo5 octahedra,  an edgeedge with one O(6)LiCo5 octahedra, edges with two equivalent O(1)Co6 octahedra, edges with two equivalent O(2)Co6 octahedra, edges with two equivalent O(5)Co6 octahedra, and edges with three equivalent O(8)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the eighth O site, O(8) is bonded to one Co(3), one Co(4), one Co(6), one Co(7), one Co(8), and one Co(9) atom to form OCo6 octahedra that share  a cornercorner with one O(5)Co6 octahedra,  a cornercorner with one O(6)LiCo5 octahedra, corners with two equivalent O(2)Co6 octahedra, corners with two equivalent O(8)Co6 octahedra,  an edgeedge with one O(2)Co6 octahedra,  an edgeedge with one O(4)LiCo5 octahedra,  an edgeedge with one O(6)LiCo5 octahedra, edges with two equivalent O(1)Co6 octahedra, edges with two equivalent O(5)Co6 octahedra, edges with two equivalent O(3)LiCo5 octahedra, and edges with three equivalent O(7)Co6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°.