VCrP2 is Modderite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent P(2) and four equivalent P(1) atoms. Cr(1) is bonded in a 6-coordinate geometry to two equivalent P(1) and four equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to four equivalent V(1) and two equivalent Cr(1) atoms. In the second P site, P(2) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Cr(1) atoms.
VCrP2 is Modderite-derived structured and crystallizes in the orthorhombic Pmc2_1 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent P(2) and four equivalent P(1) atoms. There is one shorter (2.36 Å) and one longer (2.49 Å) V(1)-P(2) bond length. There are two shorter (2.40 Å) and two longer (2.42 Å) V(1)-P(1) bond lengths. Cr(1) is bonded in a 6-coordinate geometry to two equivalent P(1) and four equivalent P(2) atoms. There is one shorter (2.32 Å) and one longer (2.46 Å) Cr(1)-P(1) bond length. There are two shorter (2.38 Å) and two longer (2.39 Å) Cr(1)-P(2) bond lengths. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to four equivalent V(1) and two equivalent Cr(1) atoms. In the second P site, P(2) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Cr(1) atoms.