GdVO3 is Orthorhombic Perovskite structured and crystallizes in the triclinic P-1 space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to two O(1,1); three O(2,2); and three O(3,3) atoms. In the second Gd site, Gd(1) is bonded in a 8-coordinate geometry to two O(1,1); three O(2,2); and three O(3,3) atoms. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1) and four O(2,2) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. In the second V site, V(1) is bonded to two equivalent O(1) and four O(2,2) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 33°. In the third V site, V(2) is bonded to two equivalent O(1) and four O(3,3) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. In the fourth V site, V(2) is bonded to two equivalent O(1) and four O(3,3) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 34°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two Gd(1,1); one V(1); and one V(2) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to two Gd(1,1); one V(1); and one V(2) atom. In the third O site, O(2) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(1,1) atoms. In the fourth O site, O(2) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(1,1) atoms. In the fifth O site, O(3) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(2,2) atoms. In the sixth O site, O(3) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(2,2) atoms.
GdVO3 is Orthorhombic Perovskite structured and crystallizes in the triclinic P-1 space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to two O(1,1); three O(2,2); and three O(3,3) atoms. There is one shorter (2.30 Å) and one longer (2.36 Å) Gd(1)-O(1,1) bond length. There are a spread of Gd(1)-O(2,2) bond distances ranging from 2.31-2.65 Å. There are a spread of Gd(1)-O(3,3) bond distances ranging from 2.31-2.66 Å. In the second Gd site, Gd(1) is bonded in a 8-coordinate geometry to two O(1,1); three O(2,2); and three O(3,3) atoms. There is one shorter (2.30 Å) and one longer (2.36 Å) Gd(1)-O(1,1) bond length. There are a spread of Gd(1)-O(2,2) bond distances ranging from 2.31-2.65 Å. There are a spread of Gd(1)-O(3,3) bond distances ranging from 2.31-2.66 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1) and four O(2,2) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. Both V(1)-O(1) bond lengths are 1.98 Å. There are two shorter (1.99 Å) and two longer (2.08 Å) V(1)-O(2,2) bond lengths. In the second V site, V(1) is bonded to two equivalent O(1) and four O(2,2) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 33°. Both V(1)-O(1) bond lengths are 1.98 Å. There are two shorter (1.99 Å) and two longer (2.08 Å) V(1)-O(2,2) bond lengths. In the third V site, V(2) is bonded to two equivalent O(1) and four O(3,3) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. Both V(2)-O(1) bond lengths are 1.97 Å. There are two shorter (2.01 Å) and two longer (2.07 Å) V(2)-O(3,3) bond lengths. In the fourth V site, V(2) is bonded to two equivalent O(1) and four O(3,3) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 34°. Both V(2)-O(1) bond lengths are 1.97 Å. There are two shorter (2.01 Å) and two longer (2.06 Å) V(2)-O(3,3) bond lengths. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two Gd(1,1); one V(1); and one V(2) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to two Gd(1,1); one V(1); and one V(2) atom. In the third O site, O(2) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(1,1) atoms. In the fourth O site, O(2) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(1,1) atoms. In the fifth O site, O(3) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(2,2) atoms. In the sixth O site, O(3) is bonded in a 5-coordinate geometry to three Gd(1,1) and two V(2,2) atoms.