Zn(WO3)2 crystallizes in the orthorhombic Pmn2_1 space group. W(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 30-41°. Zn(1) is bonded in a trigonal non-coplanar geometry to one O(3) and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.
Zn(WO3)2 crystallizes in the orthorhombic Pmn2_1 space group. W(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 30-41°. The W(1)-O(3) bond length is 2.06 Å. The W(1)-O(4) bond length is 1.98 Å. There is one shorter (2.00 Å) and one longer (2.07 Å) W(1)-O(1) bond length. There is one shorter (1.95 Å) and one longer (1.99 Å) W(1)-O(2) bond length. Zn(1) is bonded in a trigonal non-coplanar geometry to one O(3) and two equivalent O(1) atoms. The Zn(1)-O(3) bond length is 1.96 Å. Both Zn(1)-O(1) bond lengths are 2.01 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.