NiC2N6H16S2(O2Cl)2(CNH4SO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two methanesulfonamide molecules and one NiC2N6H16S2(O2Cl)2 cluster. In the NiC2N6H16S2(O2Cl)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(4), and two equivalent Cl(1) atoms. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one S(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one Ni(1), one N(1), one H(5), and one H(6) atom. In the third N site, N(4) is bonded in a distorted water-like geometry to one Ni(1), one H(11), and one H(12) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one N(4) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one Ni(1) atom.
NiC2N6H16S2(O2Cl)2(CNH4SO2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two methanesulfonamide molecules and one NiC2N6H16S2(O2Cl)2 cluster. In the NiC2N6H16S2(O2Cl)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(4), and two equivalent Cl(1) atoms. Both Ni(1)-N(2) bond lengths are 2.20 Å. Both Ni(1)-N(4) bond lengths are 2.20 Å. Both Ni(1)-Cl(1) bond lengths are 2.42 Å. C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.09 Å. The C(1)-S(1) bond length is 1.77 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one S(1) atom. The N(1)-N(2) bond length is 1.43 Å. The N(1)-H(4) bond length is 1.03 Å. The N(1)-S(1) bond length is 1.69 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one Ni(1), one N(1), one H(5), and one H(6) atom. The N(2)-H(5) bond length is 1.03 Å. The N(2)-H(6) bond length is 1.02 Å. In the third N site, N(4) is bonded in a distorted water-like geometry to one Ni(1), one H(11), and one H(12) atom. The N(4)-H(11) bond length is 1.03 Å. The N(4)-H(12) bond length is 1.02 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one N(4) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(1), one N(1), one O(1), and one O(2) atom. The S(1)-O(1) bond length is 1.45 Å. The S(1)-O(2) bond length is 1.45 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one Ni(1) atom.