KPdF3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent F(1) atoms to form KF12 cuboctahedra that share corners with twelve equivalent K(1)F12 cuboctahedra, faces with six equivalent K(1)F12 cuboctahedra, and faces with eight equivalent Pd(1)F6 octahedra. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Pd(1)F6 octahedra and faces with eight equivalent K(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded to four equivalent K(1) and two equivalent Pd(1) atoms to form a mixture of distorted corner, edge, and face-sharing FK4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
KPdF3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent F(1) atoms to form KF12 cuboctahedra that share corners with twelve equivalent K(1)F12 cuboctahedra, faces with six equivalent K(1)F12 cuboctahedra, and faces with eight equivalent Pd(1)F6 octahedra. All K(1)-F(1) bond lengths are 3.05 Å. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Pd(1)F6 octahedra and faces with eight equivalent K(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Pd(1)-F(1) bond lengths are 2.15 Å. F(1) is bonded to four equivalent K(1) and two equivalent Pd(1) atoms to form a mixture of distorted corner, edge, and face-sharing FK4Pd2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.