LiCo5O7F is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(14), one O(9), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Co(7)O5F octahedra,  a cornercorner with one Co(9)O5F octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(10)O5F octahedra, corners with two equivalent Co(8)O5F octahedra, corners with two equivalent Co(4)O6 octahedra, and corners with three equivalent Co(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 51-65°. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(13), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one Co(10)O5F octahedra,  a cornercorner with one Co(8)O5F octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(7)O5F octahedra, corners with two equivalent Co(9)O5F octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent Co(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-65°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(3), one O(5), and one O(8) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(10)O5F octahedra,  a cornercorner with one Co(8)O5F octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(7)O5F octahedra, corners with two equivalent Co(9)O5F octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent Co(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 54-62°. In the second Co site, Co(2) is bonded to one O(2), one O(4), one O(6), and one O(7) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(7)O5F octahedra,  a cornercorner with one Co(9)O5F octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(10)O5F octahedra, corners with two equivalent Co(8)O5F octahedra, corners with two equivalent Co(4)O6 octahedra, and corners with three equivalent Co(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 51-62°. In the third Co site, Co(3) is bonded to one O(11), one O(13), one O(3), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Co(2)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(7)O5F octahedra, and edges with two equivalent Co(9)O5F octahedra. In the fourth Co site, Co(4) is bonded to one O(10), one O(12), one O(14), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(10)O5F octahedra, and edges with two equivalent Co(8)O5F octahedra. In the fifth Co site, Co(5) is bonded to one O(11), one O(13), one O(2), one O(4), one O(6), and one F(1) atom to form CoO5F octahedra that share corners with three equivalent Li(2)O3F tetrahedra, corners with three equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(10)O5F octahedra,  an edgeedge with one Co(7)O5F octahedra,  an edgeedge with one Co(8)O5F octahedra,  an edgeedge with one Co(9)O5F octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(1), one O(12), one O(14), one O(3), one O(5), and one F(2) atom to form CoO5F octahedra that share corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(10)O5F octahedra,  an edgeedge with one Co(7)O5F octahedra,  an edgeedge with one Co(8)O5F octahedra,  an edgeedge with one Co(9)O5F octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. In the seventh Co site, Co(7) is bonded to one O(1), one O(13), one O(3), one O(7), one O(9), and one F(1) atom to form CoO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Co(2)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(9)O5F octahedra, and edges with two equivalent Co(3)O6 octahedra. In the eighth Co site, Co(8) is bonded to one O(10), one O(14), one O(2), one O(4), one O(8), and one F(2) atom to form CoO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(10)O5F octahedra, and edges with two equivalent Co(4)O6 octahedra. In the ninth Co site, Co(9) is bonded to one O(1), one O(11), one O(5), one O(7), one O(9), and one F(1) atom to form CoO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Co(2)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(7)O5F octahedra, and edges with two equivalent Co(3)O6 octahedra. In the tenth Co site, Co(10) is bonded to one O(10), one O(12), one O(2), one O(6), one O(8), and one F(2) atom to form CoO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(8)O5F octahedra, and edges with two equivalent Co(4)O6 octahedra. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(6), one Co(7), and one Co(9) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Co(10), one Co(2), one Co(5), and one Co(8) atom. In the third O site, O(3) is bonded to one Co(1), one Co(3), one Co(6), and one Co(7) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(13)LiCo3 tetrahedra, corners with two equivalent O(9)LiCo3 tetrahedra,  a cornercorner with one O(5)Co4 trigonal pyramid,  an edgeedge with one O(5)Co4 trigonal pyramid, and  an edgeedge with one O(7)Co4 trigonal pyramid. In the fourth O site, O(4) is bonded to one Co(2), one Co(4), one Co(5), and one Co(8) atom to form distorted OCo4 tetrahedra that share  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra, corners with two equivalent O(14)LiCo3 tetrahedra,  a cornercorner with one O(6)Co4 trigonal pyramid,  a cornercorner with one O(7)Co4 trigonal pyramid, corners with two equivalent O(10)LiCo3 trigonal pyramids, and  an edgeedge with one O(6)Co4 trigonal pyramid. In the fifth O site, O(5) is bonded to one Co(1), one Co(3), one Co(6), and one Co(9) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(11)LiCo3 tetrahedra, corners with two equivalent O(9)LiCo3 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  an edgeedge with one O(3)Co4 trigonal pyramid, and  an edgeedge with one O(7)Co4 trigonal pyramid. In the sixth O site, O(6) is bonded to one Co(10), one Co(2), one Co(4), and one Co(5) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(12)LiCo3 tetrahedra,  a cornercorner with one O(7)Co4 trigonal pyramid, corners with two equivalent O(10)LiCo3 trigonal pyramids, and  an edgeedge with one O(4)Co4 tetrahedra. In the seventh O site, O(7) is bonded to one Co(2), one Co(3), one Co(7), and one Co(9) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra, corners with two equivalent O(11)LiCo3 tetrahedra, corners with two equivalent O(13)LiCo3 tetrahedra, corners with three equivalent O(9)LiCo3 tetrahedra,  a cornercorner with one O(6)Co4 trigonal pyramid,  an edgeedge with one O(3)Co4 trigonal pyramid, and  an edgeedge with one O(5)Co4 trigonal pyramid. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(10), one Co(4), and one Co(8) atom. In the ninth O site, O(9) is bonded to one Li(1), one Co(3), one Co(7), and one Co(9) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(3)Co4 trigonal pyramids, corners with two equivalent O(5)Co4 trigonal pyramids, corners with three equivalent O(7)Co4 trigonal pyramids,  an edgeedge with one O(11)LiCo3 tetrahedra, and  an edgeedge with one O(13)LiCo3 tetrahedra. In the tenth O site, O(10) is bonded to one Li(2), one Co(10), one Co(4), and one Co(8) atom to form distorted OLiCo3 trigonal pyramids that share  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra, corners with two equivalent O(4)Co4 tetrahedra, corners with two equivalent O(6)Co4 trigonal pyramids,  an edgeedge with one O(12)LiCo3 tetrahedra, and  an edgeedge with one O(14)LiCo3 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(2), one Co(3), one Co(5), and one Co(9) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  a cornercorner with one O(6)Co4 trigonal pyramid,  a cornercorner with one O(10)LiCo3 trigonal pyramid, corners with two equivalent O(5)Co4 trigonal pyramids, corners with two equivalent O(7)Co4 trigonal pyramids,  an edgeedge with one O(13)LiCo3 tetrahedra, and  an edgeedge with one O(9)LiCo3 tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Co(10), one Co(4), and one Co(6) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra,  a cornercorner with one O(9)LiCo3 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  a cornercorner with one O(5)Co4 trigonal pyramid, corners with two equivalent O(6)Co4 trigonal pyramids,  an edgeedge with one O(14)LiCo3 tetrahedra, and  an edgeedge with one O(10)LiCo3 trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(2), one Co(3), one Co(5), and one Co(7) atom to form distorted OLiCo3 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(5)Co4 trigonal pyramid,  a cornercorner with one O(6)Co4 trigonal pyramid,  a cornercorner with one O(10)LiCo3 trigonal pyramid, corners with two equivalent O(3)Co4 trigonal pyramids, corners with two equivalent O(7)Co4 trigonal pyramids,  an edgeedge with one O(11)LiCo3 tetrahedra, and  an edgeedge with one O(9)LiCo3 tetrahedra. In the fourteenth O site, O(14) is bonded to one Li(1), one Co(4), one Co(6), and one Co(8) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(9)LiCo3 tetrahedra, corners with two equivalent O(4)Co4 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  a cornercorner with one O(5)Co4 trigonal pyramid,  a cornercorner with one O(6)Co4 trigonal pyramid,  an edgeedge with one O(12)LiCo3 tetrahedra, and  an edgeedge with one O(10)LiCo3 trigonal pyramid. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(5), one Co(7), and one Co(9) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(10), one Co(6), and one Co(8) atom.
LiCo5O7F is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(14), one O(9), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Co(7)O5F octahedra,  a cornercorner with one Co(9)O5F octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(10)O5F octahedra, corners with two equivalent Co(8)O5F octahedra, corners with two equivalent Co(4)O6 octahedra, and corners with three equivalent Co(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 51-65°. The Li(1)-O(12) bond length is 2.02 Å. The Li(1)-O(14) bond length is 2.01 Å. The Li(1)-O(9) bond length is 2.00 Å. The Li(1)-F(2) bond length is 1.84 Å. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(13), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one Co(10)O5F octahedra,  a cornercorner with one Co(8)O5F octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(7)O5F octahedra, corners with two equivalent Co(9)O5F octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent Co(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-65°. The Li(2)-O(10) bond length is 1.94 Å. The Li(2)-O(11) bond length is 1.99 Å. The Li(2)-O(13) bond length is 1.99 Å. The Li(2)-F(1) bond length is 1.90 Å. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(3), one O(5), and one O(8) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(10)O5F octahedra,  a cornercorner with one Co(8)O5F octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(7)O5F octahedra, corners with two equivalent Co(9)O5F octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with three equivalent Co(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 54-62°. The Co(1)-O(1) bond length is 1.87 Å. The Co(1)-O(3) bond length is 1.99 Å. The Co(1)-O(5) bond length is 1.99 Å. The Co(1)-O(8) bond length is 1.97 Å. In the second Co site, Co(2) is bonded to one O(2), one O(4), one O(6), and one O(7) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(7)O5F octahedra,  a cornercorner with one Co(9)O5F octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(10)O5F octahedra, corners with two equivalent Co(8)O5F octahedra, corners with two equivalent Co(4)O6 octahedra, and corners with three equivalent Co(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 51-62°. The Co(2)-O(2) bond length is 1.92 Å. The Co(2)-O(4) bond length is 2.00 Å. The Co(2)-O(6) bond length is 2.00 Å. The Co(2)-O(7) bond length is 1.98 Å. In the third Co site, Co(3) is bonded to one O(11), one O(13), one O(3), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Co(2)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(7)O5F octahedra, and edges with two equivalent Co(9)O5F octahedra. The Co(3)-O(11) bond length is 1.93 Å. The Co(3)-O(13) bond length is 1.93 Å. The Co(3)-O(3) bond length is 1.99 Å. The Co(3)-O(5) bond length is 1.99 Å. The Co(3)-O(7) bond length is 1.98 Å. The Co(3)-O(9) bond length is 1.96 Å. In the fourth Co site, Co(4) is bonded to one O(10), one O(12), one O(14), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(10)O5F octahedra, and edges with two equivalent Co(8)O5F octahedra. The Co(4)-O(10) bond length is 2.11 Å. The Co(4)-O(12) bond length is 1.95 Å. The Co(4)-O(14) bond length is 1.94 Å. The Co(4)-O(4) bond length is 1.95 Å. The Co(4)-O(6) bond length is 1.96 Å. The Co(4)-O(8) bond length is 2.14 Å. In the fifth Co site, Co(5) is bonded to one O(11), one O(13), one O(2), one O(4), one O(6), and one F(1) atom to form CoO5F octahedra that share corners with three equivalent Li(2)O3F tetrahedra, corners with three equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(10)O5F octahedra,  an edgeedge with one Co(7)O5F octahedra,  an edgeedge with one Co(8)O5F octahedra,  an edgeedge with one Co(9)O5F octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. The Co(5)-O(11) bond length is 1.91 Å. The Co(5)-O(13) bond length is 1.91 Å. The Co(5)-O(2) bond length is 1.88 Å. The Co(5)-O(4) bond length is 1.95 Å. The Co(5)-O(6) bond length is 1.95 Å. The Co(5)-F(1) bond length is 1.98 Å. In the sixth Co site, Co(6) is bonded to one O(1), one O(12), one O(14), one O(3), one O(5), and one F(2) atom to form CoO5F octahedra that share corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(10)O5F octahedra,  an edgeedge with one Co(7)O5F octahedra,  an edgeedge with one Co(8)O5F octahedra,  an edgeedge with one Co(9)O5F octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. The Co(6)-O(1) bond length is 2.03 Å. The Co(6)-O(12) bond length is 1.92 Å. The Co(6)-O(14) bond length is 1.92 Å. The Co(6)-O(3) bond length is 1.95 Å. The Co(6)-O(5) bond length is 1.95 Å. The Co(6)-F(2) bond length is 2.17 Å. In the seventh Co site, Co(7) is bonded to one O(1), one O(13), one O(3), one O(7), one O(9), and one F(1) atom to form CoO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Co(2)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(9)O5F octahedra, and edges with two equivalent Co(3)O6 octahedra. The Co(7)-O(1) bond length is 2.02 Å. The Co(7)-O(13) bond length is 1.90 Å. The Co(7)-O(3) bond length is 1.96 Å. The Co(7)-O(7) bond length is 1.95 Å. The Co(7)-O(9) bond length is 1.90 Å. The Co(7)-F(1) bond length is 2.23 Å. In the eighth Co site, Co(8) is bonded to one O(10), one O(14), one O(2), one O(4), one O(8), and one F(2) atom to form CoO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(10)O5F octahedra, and edges with two equivalent Co(4)O6 octahedra. The Co(8)-O(10) bond length is 1.88 Å. The Co(8)-O(14) bond length is 1.92 Å. The Co(8)-O(2) bond length is 2.07 Å. The Co(8)-O(4) bond length is 1.96 Å. The Co(8)-O(8) bond length is 1.91 Å. The Co(8)-F(2) bond length is 2.19 Å. In the ninth Co site, Co(9) is bonded to one O(1), one O(11), one O(5), one O(7), one O(9), and one F(1) atom to form CoO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Co(2)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent Co(1)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(7)O5F octahedra, and edges with two equivalent Co(3)O6 octahedra. The Co(9)-O(1) bond length is 2.02 Å. The Co(9)-O(11) bond length is 1.90 Å. The Co(9)-O(5) bond length is 1.96 Å. The Co(9)-O(7) bond length is 1.95 Å. The Co(9)-O(9) bond length is 1.90 Å. The Co(9)-F(1) bond length is 2.24 Å. In the tenth Co site, Co(10) is bonded to one O(10), one O(12), one O(2), one O(6), one O(8), and one F(2) atom to form CoO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent Co(2)O4 tetrahedra,  an edgeedge with one Co(5)O5F octahedra,  an edgeedge with one Co(6)O5F octahedra, edges with two equivalent Co(8)O5F octahedra, and edges with two equivalent Co(4)O6 octahedra. The Co(10)-O(10) bond length is 1.88 Å. The Co(10)-O(12) bond length is 1.92 Å. The Co(10)-O(2) bond length is 2.06 Å. The Co(10)-O(6) bond length is 1.96 Å. The Co(10)-O(8) bond length is 1.92 Å. The Co(10)-F(2) bond length is 2.18 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(6), one Co(7), and one Co(9) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Co(10), one Co(2), one Co(5), and one Co(8) atom. In the third O site, O(3) is bonded to one Co(1), one Co(3), one Co(6), and one Co(7) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(13)LiCo3 tetrahedra, corners with two equivalent O(9)LiCo3 tetrahedra,  a cornercorner with one O(5)Co4 trigonal pyramid,  an edgeedge with one O(5)Co4 trigonal pyramid, and  an edgeedge with one O(7)Co4 trigonal pyramid. In the fourth O site, O(4) is bonded to one Co(2), one Co(4), one Co(5), and one Co(8) atom to form distorted OCo4 tetrahedra that share  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra, corners with two equivalent O(14)LiCo3 tetrahedra,  a cornercorner with one O(6)Co4 trigonal pyramid,  a cornercorner with one O(7)Co4 trigonal pyramid, corners with two equivalent O(10)LiCo3 trigonal pyramids, and  an edgeedge with one O(6)Co4 trigonal pyramid. In the fifth O site, O(5) is bonded to one Co(1), one Co(3), one Co(6), and one Co(9) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(11)LiCo3 tetrahedra, corners with two equivalent O(9)LiCo3 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  an edgeedge with one O(3)Co4 trigonal pyramid, and  an edgeedge with one O(7)Co4 trigonal pyramid. In the sixth O site, O(6) is bonded to one Co(10), one Co(2), one Co(4), and one Co(5) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(12)LiCo3 tetrahedra,  a cornercorner with one O(7)Co4 trigonal pyramid, corners with two equivalent O(10)LiCo3 trigonal pyramids, and  an edgeedge with one O(4)Co4 tetrahedra. In the seventh O site, O(7) is bonded to one Co(2), one Co(3), one Co(7), and one Co(9) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(4)Co4 tetrahedra, corners with two equivalent O(11)LiCo3 tetrahedra, corners with two equivalent O(13)LiCo3 tetrahedra, corners with three equivalent O(9)LiCo3 tetrahedra,  a cornercorner with one O(6)Co4 trigonal pyramid,  an edgeedge with one O(3)Co4 trigonal pyramid, and  an edgeedge with one O(5)Co4 trigonal pyramid. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(10), one Co(4), and one Co(8) atom. In the ninth O site, O(9) is bonded to one Li(1), one Co(3), one Co(7), and one Co(9) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra, corners with two equivalent O(3)Co4 trigonal pyramids, corners with two equivalent O(5)Co4 trigonal pyramids, corners with three equivalent O(7)Co4 trigonal pyramids,  an edgeedge with one O(11)LiCo3 tetrahedra, and  an edgeedge with one O(13)LiCo3 tetrahedra. In the tenth O site, O(10) is bonded to one Li(2), one Co(10), one Co(4), and one Co(8) atom to form distorted OLiCo3 trigonal pyramids that share  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra, corners with two equivalent O(4)Co4 tetrahedra, corners with two equivalent O(6)Co4 trigonal pyramids,  an edgeedge with one O(12)LiCo3 tetrahedra, and  an edgeedge with one O(14)LiCo3 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(2), one Co(3), one Co(5), and one Co(9) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(13)LiCo3 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  a cornercorner with one O(6)Co4 trigonal pyramid,  a cornercorner with one O(10)LiCo3 trigonal pyramid, corners with two equivalent O(5)Co4 trigonal pyramids, corners with two equivalent O(7)Co4 trigonal pyramids,  an edgeedge with one O(13)LiCo3 tetrahedra, and  an edgeedge with one O(9)LiCo3 tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one Co(10), one Co(4), and one Co(6) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(14)LiCo3 tetrahedra,  a cornercorner with one O(9)LiCo3 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  a cornercorner with one O(5)Co4 trigonal pyramid, corners with two equivalent O(6)Co4 trigonal pyramids,  an edgeedge with one O(14)LiCo3 tetrahedra, and  an edgeedge with one O(10)LiCo3 trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(2), one Co(3), one Co(5), and one Co(7) atom to form distorted OLiCo3 tetrahedra that share  a cornercorner with one O(4)Co4 tetrahedra,  a cornercorner with one O(11)LiCo3 tetrahedra,  a cornercorner with one O(5)Co4 trigonal pyramid,  a cornercorner with one O(6)Co4 trigonal pyramid,  a cornercorner with one O(10)LiCo3 trigonal pyramid, corners with two equivalent O(3)Co4 trigonal pyramids, corners with two equivalent O(7)Co4 trigonal pyramids,  an edgeedge with one O(11)LiCo3 tetrahedra, and  an edgeedge with one O(9)LiCo3 tetrahedra. In the fourteenth O site, O(14) is bonded to one Li(1), one Co(4), one Co(6), and one Co(8) atom to form OLiCo3 tetrahedra that share  a cornercorner with one O(12)LiCo3 tetrahedra,  a cornercorner with one O(9)LiCo3 tetrahedra, corners with two equivalent O(4)Co4 tetrahedra,  a cornercorner with one O(3)Co4 trigonal pyramid,  a cornercorner with one O(5)Co4 trigonal pyramid,  a cornercorner with one O(6)Co4 trigonal pyramid,  an edgeedge with one O(12)LiCo3 tetrahedra, and  an edgeedge with one O(10)LiCo3 trigonal pyramid. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(5), one Co(7), and one Co(9) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(10), one Co(6), and one Co(8) atom.