Sc2(VSi)3 crystallizes in the hexagonal P6_3/mcm space group. Sc(1) is bonded in a 6-coordinate geometry to six equivalent Si(1) atoms. V(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to four equivalent Sc(1) and five equivalent V(1) atoms.
Sc2(VSi)3 crystallizes in the hexagonal P6_3/mcm space group. Sc(1) is bonded in a 6-coordinate geometry to six equivalent Si(1) atoms. All Sc(1)-Si(1) bond lengths are 2.69 Å. V(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. There are a spread of V(1)-Si(1) bond distances ranging from 2.45-2.86 Å. Si(1) is bonded in a 9-coordinate geometry to four equivalent Sc(1) and five equivalent V(1) atoms.