Pd3In crystallizes in the tetragonal P4/mmm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to four equivalent Pd(2) and four equivalent In(1) atoms. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to eight equivalent Pd(1) and two equivalent In(1) atoms. In(1) is bonded in a 10-coordinate geometry to two equivalent Pd(2) and eight equivalent Pd(1) atoms.
Pd3In crystallizes in the tetragonal P4/mmm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to four equivalent Pd(2) and four equivalent In(1) atoms. All Pd(1)-Pd(2) bond lengths are 2.80 Å. All Pd(1)-In(1) bond lengths are 2.80 Å. In the second Pd site, Pd(2) is bonded in a 10-coordinate geometry to eight equivalent Pd(1) and two equivalent In(1) atoms. Both Pd(2)-In(1) bond lengths are 2.95 Å. In(1) is bonded in a 10-coordinate geometry to two equivalent Pd(2) and eight equivalent Pd(1) atoms.