CeSBr is Baddeleyite-derived structured and crystallizes in the orthorhombic Pbca space group. Ce(1) is bonded in a 7-coordinate geometry to four equivalent S(1) and three equivalent Br(1) atoms. S(1) is bonded to four equivalent Ce(1) atoms to form a mixture of corner and edge-sharing SCe4 tetrahedra. Br(1) is bonded in a distorted trigonal planar geometry to three equivalent Ce(1) atoms.
CeSBr is Baddeleyite-derived structured and crystallizes in the orthorhombic Pbca space group. Ce(1) is bonded in a 7-coordinate geometry to four equivalent S(1) and three equivalent Br(1) atoms. There are two shorter (2.82 Å) and two longer (2.83 Å) Ce(1)-S(1) bond lengths. There are a spread of Ce(1)-Br(1) bond distances ranging from 3.06-3.34 Å. S(1) is bonded to four equivalent Ce(1) atoms to form a mixture of corner and edge-sharing SCe4 tetrahedra. Br(1) is bonded in a distorted trigonal planar geometry to three equivalent Ce(1) atoms.