CdNF3 crystallizes in the orthorhombic Pnma space group. Cd(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing CdF6 octahedra. The corner-sharing octahedral tilt angles range from 24-42°. N(1) is bonded in a bent 150 degrees geometry to two equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one N(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Cd(1) atoms.
CdNF3 crystallizes in the orthorhombic Pnma space group. Cd(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing CdF6 octahedra. The corner-sharing octahedral tilt angles range from 24-42°. Both Cd(1)-F(2) bond lengths are 2.16 Å. All Cd(1)-F(1) bond lengths are 2.37 Å. N(1) is bonded in a bent 150 degrees geometry to two equivalent F(1) atoms. Both N(1)-F(1) bond lengths are 1.76 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one N(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Cd(1) atoms.