CdH8(CO3)2(CO)2(H(CO)2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two formaldehyde molecules, two methanol with formaldehyde molecules, and one CdH8(CO3)2 cluster. In the CdH8(CO3)2 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(5) is bonded in a water-like geometry to one Cd(1), one H(3), and one H(4) atom. In the third O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one H(5), and one H(6) atom.
CdH8(CO3)2(CO)2(H(CO)2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two formaldehyde molecules, two methanol with formaldehyde molecules, and one CdH8(CO3)2 cluster. In the CdH8(CO3)2 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(6) atoms. Both Cd(1)-O(1) bond lengths are 2.27 Å. Both Cd(1)-O(5) bond lengths are 2.45 Å. Both Cd(1)-O(6) bond lengths are 2.25 Å. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.25 Å. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(5) atom. The H(3)-O(5) bond length is 0.99 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. The H(4)-O(5) bond length is 1.00 Å. In the third H site, H(5) is bonded in a single-bond geometry to one O(6) atom. The H(5)-O(6) bond length is 0.99 Å. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. The H(6)-O(6) bond length is 0.99 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(5) is bonded in a water-like geometry to one Cd(1), one H(3), and one H(4) atom. In the third O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one H(5), and one H(6) atom.