B(CH)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one B(CH)2 cluster. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one C(1), one C(3), one H(2), and one H(3) atom. In the second B site, B(2) is bonded in a tetrahedral geometry to one C(2), one C(4), one H(4), and one H(5) atom. In the third B site, B(3) is bonded in a tetrahedral geometry to one C(5), one C(6), one H(1), and one H(6) atom. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one B(1) and one C(4) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one B(2) and one C(6) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one B(1) and one C(5) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one B(2) and one C(1) atom. In the fifth C site, C(5) is bonded in a distorted linear geometry to one B(3) and one C(3) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one B(3) and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one B(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one B(3) atom.
B(CH)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one B(CH)2 cluster. There are three inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one C(1), one C(3), one H(2), and one H(3) atom. The B(1)-C(1) bond length is 1.52 Å. The B(1)-C(3) bond length is 1.52 Å. The B(1)-H(2) bond length is 1.24 Å. The B(1)-H(3) bond length is 1.26 Å. In the second B site, B(2) is bonded in a tetrahedral geometry to one C(2), one C(4), one H(4), and one H(5) atom. The B(2)-C(2) bond length is 1.52 Å. The B(2)-C(4) bond length is 1.52 Å. The B(2)-H(4) bond length is 1.24 Å. The B(2)-H(5) bond length is 1.26 Å. In the third B site, B(3) is bonded in a tetrahedral geometry to one C(5), one C(6), one H(1), and one H(6) atom. The B(3)-C(5) bond length is 1.52 Å. The B(3)-C(6) bond length is 1.52 Å. The B(3)-H(1) bond length is 1.26 Å. The B(3)-H(6) bond length is 1.24 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one B(1) and one C(4) atom. The C(1)-C(4) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one B(2) and one C(6) atom. The C(2)-C(6) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one B(1) and one C(5) atom. The C(3)-C(5) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted linear geometry to one B(2) and one C(1) atom. In the fifth C site, C(5) is bonded in a distorted linear geometry to one B(3) and one C(3) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one B(3) and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one B(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one B(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one B(3) atom.