CaP2(OBr3)2(POBr3)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two phosphorus oxybromide molecules and one CaP2(OBr3)2 cluster. In the CaP2(OBr3)2 cluster, Ca(1) is bonded to one O(1), one Br(4), one Br(8), and one Br(9) atom to form distorted CaBr3O tetrahedra that share  a cornercorner with one P(2)Br3O tetrahedra. There are two inequivalent P sites. In the first P site, P(2) is bonded to one O(1), one Br(1), one Br(6), and one Br(7) atom to form PBr3O tetrahedra that share  a cornercorner with one Ca(1)Br3O tetrahedra. In the second P site, P(3) is bonded in a distorted single-bond geometry to one O(2), one Br(4), and one Br(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Ca(1) and one P(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(3) atom. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in an L-shaped geometry to one Ca(1) and one P(3) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one P(2) atom. In the fourth Br site, Br(7) is bonded in a single-bond geometry to one P(2) atom. In the fifth Br site, Br(8) is bonded in an L-shaped geometry to one Ca(1) and one P(3) atom. In the sixth Br site, Br(9) is bonded in a single-bond geometry to one Ca(1) atom.
CaP2(OBr3)2(POBr3)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two phosphorus oxybromide molecules and one CaP2(OBr3)2 cluster. In the CaP2(OBr3)2 cluster, Ca(1) is bonded to one O(1), one Br(4), one Br(8), and one Br(9) atom to form distorted CaBr3O tetrahedra that share  a cornercorner with one P(2)Br3O tetrahedra. The Ca(1)-O(1) bond length is 2.26 Å. The Ca(1)-Br(4) bond length is 2.84 Å. The Ca(1)-Br(8) bond length is 2.84 Å. The Ca(1)-Br(9) bond length is 2.68 Å. There are two inequivalent P sites. In the first P site, P(2) is bonded to one O(1), one Br(1), one Br(6), and one Br(7) atom to form PBr3O tetrahedra that share  a cornercorner with one Ca(1)Br3O tetrahedra. The P(2)-O(1) bond length is 1.49 Å. The P(2)-Br(1) bond length is 2.17 Å. The P(2)-Br(6) bond length is 2.17 Å. The P(2)-Br(7) bond length is 2.18 Å. In the second P site, P(3) is bonded in a distorted single-bond geometry to one O(2), one Br(4), and one Br(8) atom. The P(3)-O(2) bond length is 1.49 Å. The P(3)-Br(4) bond length is 2.58 Å. The P(3)-Br(8) bond length is 2.53 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Ca(1) and one P(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(3) atom. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(2) atom. In the second Br site, Br(4) is bonded in an L-shaped geometry to one Ca(1) and one P(3) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one P(2) atom. In the fourth Br site, Br(7) is bonded in a single-bond geometry to one P(2) atom. In the fifth Br site, Br(8) is bonded in an L-shaped geometry to one Ca(1) and one P(3) atom. In the sixth Br site, Br(9) is bonded in a single-bond geometry to one Ca(1) atom.