KVO3 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing VO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to four equivalent K(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1) and two equivalent V(1) atoms.
KVO3 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. There is one shorter (2.70 Å) and one longer (3.14 Å) K(1)-O(1) bond length. Both K(1)-O(3) bond lengths are 2.78 Å. There are a spread of K(1)-O(2) bond distances ranging from 2.75-3.08 Å. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing VO4 tetrahedra. The V(1)-O(1) bond length is 1.65 Å. The V(1)-O(2) bond length is 1.66 Å. Both V(1)-O(3) bond lengths are 1.81 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to four equivalent K(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1) and two equivalent V(1) atoms.