Ag2SAg is Uranium Silicide-like structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to eight equivalent Ag(1) and four equivalent S(1) atoms to form distorted AgAg8S4 cuboctahedra that share corners with four equivalent S(1)Ag12 cuboctahedra; corners with fourteen equivalent Ag(1)Ag8S4 cuboctahedra; edges with six equivalent S(1)Ag12 cuboctahedra; edges with twelve equivalent Ag(1)Ag8S4 cuboctahedra; faces with four equivalent S(1)Ag12 cuboctahedra; and faces with sixteen Ag(1,1)Ag8S4 cuboctahedra. In the second Ag site, Ag(1) is bonded to eight equivalent Ag(1) and four equivalent S(1) atoms to form distorted AgAg8S4 cuboctahedra that share corners with four equivalent S(1)Ag12 cuboctahedra; corners with fourteen Ag(1,1)Ag8S4 cuboctahedra; edges with six equivalent S(1)Ag12 cuboctahedra; edges with twelve equivalent Ag(1)Ag8S4 cuboctahedra; faces with four equivalent S(1)Ag12 cuboctahedra; and faces with sixteen Ag(1,1)Ag8S4 cuboctahedra. S(1) is bonded to twelve Ag(1,1) atoms to form SAg12 cuboctahedra that share corners with six equivalent S(1)Ag12 cuboctahedra; corners with twelve Ag(1,1)Ag8S4 cuboctahedra; edges with eighteen Ag(1,1)Ag8S4 cuboctahedra; faces with eight equivalent S(1)Ag12 cuboctahedra; and faces with twelve Ag(1,1)Ag8S4 cuboctahedra.
Ag2SAg is Uranium Silicide-like structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to eight equivalent Ag(1) and four equivalent S(1) atoms to form distorted AgAg8S4 cuboctahedra that share corners with four equivalent S(1)Ag12 cuboctahedra; corners with fourteen equivalent Ag(1)Ag8S4 cuboctahedra; edges with six equivalent S(1)Ag12 cuboctahedra; edges with twelve equivalent Ag(1)Ag8S4 cuboctahedra; faces with four equivalent S(1)Ag12 cuboctahedra; and faces with sixteen Ag(1,1)Ag8S4 cuboctahedra. There are a spread of Ag(1)-Ag(1) bond distances ranging from 2.89-3.02 Å. There are two shorter (2.91 Å) and two longer (2.99 Å) Ag(1)-S(1) bond lengths. In the second Ag site, Ag(1) is bonded to eight equivalent Ag(1) and four equivalent S(1) atoms to form distorted AgAg8S4 cuboctahedra that share corners with four equivalent S(1)Ag12 cuboctahedra; corners with fourteen Ag(1,1)Ag8S4 cuboctahedra; edges with six equivalent S(1)Ag12 cuboctahedra; edges with twelve equivalent Ag(1)Ag8S4 cuboctahedra; faces with four equivalent S(1)Ag12 cuboctahedra; and faces with sixteen Ag(1,1)Ag8S4 cuboctahedra. There are a spread of Ag(1)-Ag(1) bond distances ranging from 2.89-3.02 Å. There are two shorter (2.91 Å) and two longer (2.99 Å) Ag(1)-S(1) bond lengths. S(1) is bonded to twelve Ag(1,1) atoms to form SAg12 cuboctahedra that share corners with six equivalent S(1)Ag12 cuboctahedra; corners with twelve Ag(1,1)Ag8S4 cuboctahedra; edges with eighteen Ag(1,1)Ag8S4 cuboctahedra; faces with eight equivalent S(1)Ag12 cuboctahedra; and faces with twelve Ag(1,1)Ag8S4 cuboctahedra.