V2CdO8O2 crystallizes in the monoclinic Cc space group. The structure consists of four 7782-44-7 molecules inside a V2CdO8 framework. In the V2CdO8 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(3) atoms. Cd(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Cd(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(9) atom. In the eighth O site, O(9) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(7) atom.
V2CdO8O2 crystallizes in the monoclinic Cc space group. The structure consists of four 7782-44-7 molecules inside a V2CdO8 framework. In the V2CdO8 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. The V(1)-O(1) bond length is 1.68 Å. The V(1)-O(2) bond length is 1.70 Å. The V(1)-O(3) bond length is 2.03 Å. There is one shorter (1.91 Å) and one longer (1.94 Å) V(1)-O(4) bond length. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(3) atoms. The V(2)-O(4) bond length is 2.03 Å. The V(2)-O(5) bond length is 1.70 Å. The V(2)-O(6) bond length is 1.68 Å. There is one shorter (1.91 Å) and one longer (1.93 Å) V(2)-O(3) bond length. Cd(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(9) atom. The Cd(1)-O(1) bond length is 2.26 Å. The Cd(1)-O(2) bond length is 2.17 Å. The Cd(1)-O(5) bond length is 2.17 Å. The Cd(1)-O(6) bond length is 2.26 Å. The Cd(1)-O(7) bond length is 2.74 Å. The Cd(1)-O(9) bond length is 2.71 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Cd(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(9) atom. The O(7)-O(9) bond length is 1.24 Å. In the eighth O site, O(9) is bonded in a bent 150 degrees geometry to one Cd(1) and one O(7) atom.