VOF3 is Cubic alpha N2-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four VOF3 clusters. V(1) is bonded in a distorted tetrahedral geometry to one O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a distorted single-bond geometry to one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom.
VOF3 is Cubic alpha N2-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four VOF3 clusters. V(1) is bonded in a distorted tetrahedral geometry to one O(1), one F(1), one F(2), and one F(3) atom. The V(1)-O(1) bond length is 1.64 Å. The V(1)-F(1) bond length is 1.76 Å. The V(1)-F(2) bond length is 1.75 Å. The V(1)-F(3) bond length is 1.76 Å. O(1) is bonded in a distorted single-bond geometry to one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom.