(CNH)2H2N2H4S2II is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four hydriodic acid atoms, eight methanimine molecules, and four N2H4S2I clusters. In each N2H4S2I cluster, N(2) is bonded in a distorted single-bond geometry to one H(4), one S(1), and one I(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one N(2) and one H(1) atom. I(2) is bonded in a bent 150 degrees geometry to two equivalent N(2) atoms.
(CNH)2H2N2H4S2II is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four hydriodic acid atoms, eight methanimine molecules, and four N2H4S2I clusters. In each N2H4S2I cluster, N(2) is bonded in a distorted single-bond geometry to one H(4), one S(1), and one I(2) atom. The N(2)-H(4) bond length is 1.04 Å. The N(2)-S(1) bond length is 1.65 Å. The N(2)-I(2) bond length is 2.26 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(1) atom. The H(1)-S(1) bond length is 1.37 Å. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one N(2) and one H(1) atom. I(2) is bonded in a bent 150 degrees geometry to two equivalent N(2) atoms.