NaHgNaSn is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. The structure consists of one NaHg framework and one NaSn framework. In the NaHg framework, Na(2) is bonded to four equivalent Hg(1) atoms to form distorted corner-sharing NaHg4 tetrahedra. Hg(1) is bonded to four equivalent Na(2) atoms to form distorted corner-sharing HgNa4 tetrahedra. In the NaSn framework, Na(1) is bonded to four equivalent Sn(1) atoms to form distorted corner-sharing NaSn4 tetrahedra. Sn(1) is bonded in a 4-coordinate geometry to four equivalent Na(1) atoms.
NaHgNaSn is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. The structure consists of one NaHg framework and one NaSn framework. In the NaHg framework, Na(2) is bonded to four equivalent Hg(1) atoms to form distorted corner-sharing NaHg4 tetrahedra. All Na(2)-Hg(1) bond lengths are 3.20 Å. Hg(1) is bonded to four equivalent Na(2) atoms to form distorted corner-sharing HgNa4 tetrahedra. In the NaSn framework, Na(1) is bonded to four equivalent Sn(1) atoms to form distorted corner-sharing NaSn4 tetrahedra. All Na(1)-Sn(1) bond lengths are 3.20 Å. Sn(1) is bonded in a 4-coordinate geometry to four equivalent Na(1) atoms.