N4S5O3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N4S5O3 clusters. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one S(1), one S(4), and one S(5) atom. In the third N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(3) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(1) and one N(4) atom. In the fifth S site, S(5) is bonded in a distorted tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(5) atom.
N4S5O3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N4S5O3 clusters. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. The N(4)-S(3) bond length is 1.56 Å. The N(4)-S(4) bond length is 1.59 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one S(1), one S(4), and one S(5) atom. The N(1)-S(1) bond length is 1.67 Å. The N(1)-S(4) bond length is 1.67 Å. The N(1)-S(5) bond length is 1.83 Å. In the third N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.60 Å. The N(2)-S(2) bond length is 1.56 Å. In the fourth N site, N(3) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. The N(3)-S(2) bond length is 1.59 Å. The N(3)-S(3) bond length is 1.59 Å. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one N(1) and one N(4) atom. In the fifth S site, S(5) is bonded in a distorted tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. The S(5)-O(1) bond length is 1.46 Å. The S(5)-O(2) bond length is 1.46 Å. The S(5)-O(3) bond length is 1.45 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(5) atom.