Cs2MnS2 crystallizes in the orthorhombic Ibam space group. Cs(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. S(1) is bonded in a 2-coordinate geometry to five equivalent Cs(1) and two equivalent Mn(1) atoms.
Cs2MnS2 crystallizes in the orthorhombic Ibam space group. Cs(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. There are a spread of Cs(1)-S(1) bond distances ranging from 3.56-3.66 Å. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. All Mn(1)-S(1) bond lengths are 2.46 Å. S(1) is bonded in a 2-coordinate geometry to five equivalent Cs(1) and two equivalent Mn(1) atoms.