(Li)2NaMoF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7439-93-2 atoms inside a NaMoF6 framework. In the NaMoF6 framework, Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedra are not tilted. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Na(1) and one Mo(1) atom.
(Li)2NaMoF6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7439-93-2 atoms inside a NaMoF6 framework. In the NaMoF6 framework, Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-F(1) bond lengths are 2.17 Å. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Mo(1)-F(1) bond lengths are 2.05 Å. F(1) is bonded in a linear geometry to one Na(1) and one Mo(1) atom.