Al3V is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Al(1) atoms to form VAl12 cuboctahedra that share corners with twelve equivalent V(1)Al12 cuboctahedra, edges with twenty-four equivalent Al(1)Al8V4 cuboctahedra, faces with six equivalent V(1)Al12 cuboctahedra, and faces with twelve equivalent Al(1)Al8V4 cuboctahedra. Al(1) is bonded to four equivalent V(1) and eight equivalent Al(1) atoms to form AlAl8V4 cuboctahedra that share corners with twelve equivalent Al(1)Al8V4 cuboctahedra, edges with eight equivalent V(1)Al12 cuboctahedra, edges with sixteen equivalent Al(1)Al8V4 cuboctahedra, faces with four equivalent V(1)Al12 cuboctahedra, and faces with fourteen equivalent Al(1)Al8V4 cuboctahedra.
Al3V is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Al(1) atoms to form VAl12 cuboctahedra that share corners with twelve equivalent V(1)Al12 cuboctahedra, edges with twenty-four equivalent Al(1)Al8V4 cuboctahedra, faces with six equivalent V(1)Al12 cuboctahedra, and faces with twelve equivalent Al(1)Al8V4 cuboctahedra. All V(1)-Al(1) bond lengths are 2.76 Å. Al(1) is bonded to four equivalent V(1) and eight equivalent Al(1) atoms to form AlAl8V4 cuboctahedra that share corners with twelve equivalent Al(1)Al8V4 cuboctahedra, edges with eight equivalent V(1)Al12 cuboctahedra, edges with sixteen equivalent Al(1)Al8V4 cuboctahedra, faces with four equivalent V(1)Al12 cuboctahedra, and faces with fourteen equivalent Al(1)Al8V4 cuboctahedra. All Al(1)-Al(1) bond lengths are 2.76 Å.