Ag2TeO6 crystallizes in the triclinic P1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(5), one O(7), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(10), one O(2), one O(6), and one O(8) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(11), one O(3), one O(5), and one O(7) atom. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one O(12), one O(4), one O(6), and one O(8) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(11), one O(12), one O(3), one O(4), one O(7), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ag(1) and one Te(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ag(2) and one Te(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ag(3) and one Te(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Ag(4) and one Te(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Ag(2), one Ag(4), and one Te(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Ag(2), one Ag(4), and one Te(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Ag(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ag(2) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Ag(3) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Ag(4) and one Te(2) atom.
Ag2TeO6 crystallizes in the triclinic P1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(5), one O(7), and one O(9) atom. The Ag(1)-O(1) bond length is 2.02 Å. The Ag(1)-O(5) bond length is 2.66 Å. The Ag(1)-O(7) bond length is 2.17 Å. The Ag(1)-O(9) bond length is 2.04 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(10), one O(2), one O(6), and one O(8) atom. The Ag(2)-O(10) bond length is 2.05 Å. The Ag(2)-O(2) bond length is 2.02 Å. The Ag(2)-O(6) bond length is 2.51 Å. The Ag(2)-O(8) bond length is 2.21 Å. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(11), one O(3), one O(5), and one O(7) atom. The Ag(3)-O(11) bond length is 2.04 Å. The Ag(3)-O(3) bond length is 2.02 Å. The Ag(3)-O(5) bond length is 2.19 Å. The Ag(3)-O(7) bond length is 2.68 Å. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one O(12), one O(4), one O(6), and one O(8) atom. The Ag(4)-O(12) bond length is 2.04 Å. The Ag(4)-O(4) bond length is 2.01 Å. The Ag(4)-O(6) bond length is 2.22 Å. The Ag(4)-O(8) bond length is 2.52 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom. The Te(1)-O(1) bond length is 1.99 Å. The Te(1)-O(10) bond length is 1.96 Å. The Te(1)-O(2) bond length is 1.97 Å. The Te(1)-O(5) bond length is 1.94 Å. The Te(1)-O(6) bond length is 1.96 Å. The Te(1)-O(9) bond length is 1.95 Å. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(11), one O(12), one O(3), one O(4), one O(7), and one O(8) atom. The Te(2)-O(11) bond length is 1.96 Å. The Te(2)-O(12) bond length is 1.97 Å. The Te(2)-O(3) bond length is 1.99 Å. The Te(2)-O(4) bond length is 1.98 Å. The Te(2)-O(7) bond length is 1.93 Å. The Te(2)-O(8) bond length is 1.94 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ag(1) and one Te(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ag(2) and one Te(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ag(3) and one Te(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Ag(4) and one Te(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Ag(2), one Ag(4), and one Te(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one Te(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Ag(2), one Ag(4), and one Te(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Ag(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ag(2) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Ag(3) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Ag(4) and one Te(2) atom.