BaBrCl crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 9-coordinate geometry to five equivalent Br(1) and four equivalent Cl(1) atoms. Br(1) is bonded to five equivalent Ba(1) atoms to form distorted BrBa5 trigonal bipyramids that share corners with eight equivalent Cl(1)Ba4 tetrahedra, corners with eight equivalent Br(1)Ba5 trigonal bipyramids, edges with six equivalent Cl(1)Ba4 tetrahedra, and edges with six equivalent Br(1)Ba5 trigonal bipyramids. Cl(1) is bonded to four equivalent Ba(1) atoms to form ClBa4 tetrahedra that share corners with eight equivalent Cl(1)Ba4 tetrahedra, corners with eight equivalent Br(1)Ba5 trigonal bipyramids, edges with two equivalent Cl(1)Ba4 tetrahedra, and edges with six equivalent Br(1)Ba5 trigonal bipyramids.
BaBrCl crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 9-coordinate geometry to five equivalent Br(1) and four equivalent Cl(1) atoms. There are a spread of Ba(1)-Br(1) bond distances ranging from 3.41-3.58 Å. There are a spread of Ba(1)-Cl(1) bond distances ranging from 3.12-3.17 Å. Br(1) is bonded to five equivalent Ba(1) atoms to form distorted BrBa5 trigonal bipyramids that share corners with eight equivalent Cl(1)Ba4 tetrahedra, corners with eight equivalent Br(1)Ba5 trigonal bipyramids, edges with six equivalent Cl(1)Ba4 tetrahedra, and edges with six equivalent Br(1)Ba5 trigonal bipyramids. Cl(1) is bonded to four equivalent Ba(1) atoms to form ClBa4 tetrahedra that share corners with eight equivalent Cl(1)Ba4 tetrahedra, corners with eight equivalent Br(1)Ba5 trigonal bipyramids, edges with two equivalent Cl(1)Ba4 tetrahedra, and edges with six equivalent Br(1)Ba5 trigonal bipyramids.