Li2TiN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. Ti(1) is bonded to six equivalent N(1) atoms to form edge-sharing TiN6 octahedra. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Ti(1) atoms.
Li2TiN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. There are three shorter (1.97 Å) and one longer (2.25 Å) Li(1)-N(1) bond length. Ti(1) is bonded to six equivalent N(1) atoms to form edge-sharing TiN6 octahedra. All Ti(1)-N(1) bond lengths are 2.11 Å. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Ti(1) atoms.