Cs(CO)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom.
Cs(CO)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are a spread of Cs(1)-O(1) bond distances ranging from 3.10-3.62 Å. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.26 Å. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom.