Cs2Na(C2N3)3 crystallizes in the hexagonal P6_3/m space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. Na(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms.
Cs2Na(C2N3)3 crystallizes in the hexagonal P6_3/m space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. There are three shorter (3.28 Å) and three longer (3.43 Å) Cs(1)-N(1) bond lengths. Na(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Na(1)-N(1) bond lengths are 2.52 Å. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-N(2) bond length is 1.30 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms.