AgZn crystallizes in the triclinic P1 space group. There are nine inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(8), and two equivalent Zn(4) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(8), one Zn(1), one Zn(8), and two equivalent Zn(3) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(9), and two equivalent Zn(4) atoms. In the fourth Ag site, Ag(4) is bonded in a 13-coordinate geometry to two equivalent Ag(3), two equivalent Ag(4), one Zn(4), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. In the fifth Ag site, Ag(5) is bonded in a 6-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(2), and two equivalent Zn(5) atoms. In the sixth Ag site, Ag(6) is bonded in a 8-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(1), two equivalent Zn(5), and two equivalent Zn(7) atoms. In the seventh Ag site, Ag(7) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(7), one Zn(4), two equivalent Zn(2), two equivalent Zn(6), and two equivalent Zn(9) atoms. In the eighth Ag site, Ag(8) is bonded in a 13-coordinate geometry to two equivalent Ag(2), two equivalent Ag(8), one Zn(3), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. In the ninth Ag site, Ag(9) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(9), one Zn(4), two equivalent Zn(2), two equivalent Zn(5), and two equivalent Zn(8) atoms. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 11-coordinate geometry to one Ag(2), two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(1) atoms. In the second Zn site, Zn(2) is bonded in a 11-coordinate geometry to one Ag(1), one Ag(3), two equivalent Ag(5), two equivalent Ag(7), two equivalent Ag(9), one Zn(5), and two equivalent Zn(2) atoms. In the third Zn site, Zn(3) is bonded in a 11-coordinate geometry to one Ag(5), one Ag(6), one Ag(8), two equivalent Ag(2), two equivalent Zn(3), two equivalent Zn(5), and two equivalent Zn(7) atoms. In the fourth Zn site, Zn(4) is bonded in a 11-coordinate geometry to one Ag(4), one Ag(7), one Ag(9), two equivalent Ag(1), two equivalent Ag(3), two equivalent Zn(4), and two equivalent Zn(6) atoms. In the fifth Zn site, Zn(5) is bonded to two equivalent Ag(5), two equivalent Ag(6), two equivalent Ag(9), one Zn(2), one Zn(8), two equivalent Zn(3), and two equivalent Zn(5) atoms to form a mixture of distorted edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. In the sixth Zn site, Zn(6) is bonded to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(4), and two equivalent Zn(6) atoms to form a mixture of face and corner-sharing ZnZn6Ag6 cuboctahedra. In the seventh Zn site, Zn(7) is bonded to two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(3), and two equivalent Zn(7) atoms to form a mixture of edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. In the eighth Zn site, Zn(8) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(5), one Ag(6), two equivalent Ag(9), and one Zn(5) atom. In the ninth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Ag(3), two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(9) atoms.
AgZn crystallizes in the triclinic P1 space group. There are nine inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(8), and two equivalent Zn(4) atoms. There is one shorter (3.01 Å) and one longer (3.04 Å) Ag(1)-Ag(7) bond length. There is one shorter (2.95 Å) and one longer (3.03 Å) Ag(1)-Ag(9) bond length. The Ag(1)-Zn(2) bond length is 2.71 Å. The Ag(1)-Zn(8) bond length is 2.68 Å. There is one shorter (2.75 Å) and one longer (2.78 Å) Ag(1)-Zn(4) bond length. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(8), one Zn(1), one Zn(8), and two equivalent Zn(3) atoms. There is one shorter (2.96 Å) and one longer (3.06 Å) Ag(2)-Ag(8) bond length. The Ag(2)-Zn(1) bond length is 2.68 Å. The Ag(2)-Zn(8) bond length is 2.65 Å. There is one shorter (2.76 Å) and one longer (2.77 Å) Ag(2)-Zn(3) bond length. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(9), and two equivalent Zn(4) atoms. There is one shorter (2.97 Å) and one longer (3.06 Å) Ag(3)-Ag(4) bond length. There is one shorter (2.95 Å) and one longer (3.04 Å) Ag(3)-Ag(7) bond length. There is one shorter (2.96 Å) and one longer (3.01 Å) Ag(3)-Ag(9) bond length. The Ag(3)-Zn(2) bond length is 2.73 Å. The Ag(3)-Zn(9) bond length is 2.65 Å. There is one shorter (2.75 Å) and one longer (2.76 Å) Ag(3)-Zn(4) bond length. In the fourth Ag site, Ag(4) is bonded in a 13-coordinate geometry to two equivalent Ag(3), two equivalent Ag(4), one Zn(4), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. Both Ag(4)-Ag(4) bond lengths are 2.90 Å. The Ag(4)-Zn(4) bond length is 2.76 Å. There is one shorter (2.76 Å) and one longer (2.78 Å) Ag(4)-Zn(1) bond length. There is one shorter (2.86 Å) and one longer (2.95 Å) Ag(4)-Zn(6) bond length. There is one shorter (2.89 Å) and one longer (2.92 Å) Ag(4)-Zn(7) bond length. There is one shorter (2.74 Å) and one longer (3.21 Å) Ag(4)-Zn(9) bond length. In the fifth Ag site, Ag(5) is bonded in a 6-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(2), and two equivalent Zn(5) atoms. The Ag(5)-Zn(3) bond length is 2.71 Å. The Ag(5)-Zn(8) bond length is 2.74 Å. There is one shorter (2.77 Å) and one longer (2.79 Å) Ag(5)-Zn(2) bond length. There is one shorter (2.83 Å) and one longer (2.90 Å) Ag(5)-Zn(5) bond length. In the sixth Ag site, Ag(6) is bonded in a 8-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(1), two equivalent Zn(5), and two equivalent Zn(7) atoms. The Ag(6)-Zn(3) bond length is 2.67 Å. The Ag(6)-Zn(8) bond length is 2.71 Å. There is one shorter (2.80 Å) and one longer (2.81 Å) Ag(6)-Zn(1) bond length. There is one shorter (2.89 Å) and one longer (2.90 Å) Ag(6)-Zn(5) bond length. There is one shorter (2.89 Å) and one longer (2.90 Å) Ag(6)-Zn(7) bond length. In the seventh Ag site, Ag(7) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(7), one Zn(4), two equivalent Zn(2), two equivalent Zn(6), and two equivalent Zn(9) atoms. Both Ag(7)-Ag(7) bond lengths are 2.90 Å. The Ag(7)-Zn(4) bond length is 2.70 Å. There is one shorter (2.80 Å) and one longer (2.83 Å) Ag(7)-Zn(2) bond length. There is one shorter (2.88 Å) and one longer (2.89 Å) Ag(7)-Zn(6) bond length. There is one shorter (2.71 Å) and one longer (3.18 Å) Ag(7)-Zn(9) bond length. In the eighth Ag site, Ag(8) is bonded in a 13-coordinate geometry to two equivalent Ag(2), two equivalent Ag(8), one Zn(3), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. Both Ag(8)-Ag(8) bond lengths are 2.90 Å. The Ag(8)-Zn(3) bond length is 2.75 Å. There is one shorter (2.79 Å) and one longer (2.81 Å) Ag(8)-Zn(1) bond length. There is one shorter (2.88 Å) and one longer (2.96 Å) Ag(8)-Zn(6) bond length. There is one shorter (2.90 Å) and one longer (3.00 Å) Ag(8)-Zn(7) bond length. There is one shorter (2.67 Å) and one longer (3.07 Å) Ag(8)-Zn(9) bond length. In the ninth Ag site, Ag(9) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(9), one Zn(4), two equivalent Zn(2), two equivalent Zn(5), and two equivalent Zn(8) atoms. Both Ag(9)-Ag(9) bond lengths are 2.90 Å. The Ag(9)-Zn(4) bond length is 2.85 Å. Both Ag(9)-Zn(2) bond lengths are 2.78 Å. There is one shorter (2.88 Å) and one longer (2.92 Å) Ag(9)-Zn(5) bond length. There is one shorter (2.68 Å) and one longer (3.26 Å) Ag(9)-Zn(8) bond length. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 11-coordinate geometry to one Ag(2), two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(1) atoms. The Zn(1)-Zn(6) bond length is 2.69 Å. The Zn(1)-Zn(7) bond length is 2.73 Å. Both Zn(1)-Zn(1) bond lengths are 2.90 Å. In the second Zn site, Zn(2) is bonded in a 11-coordinate geometry to one Ag(1), one Ag(3), two equivalent Ag(5), two equivalent Ag(7), two equivalent Ag(9), one Zn(5), and two equivalent Zn(2) atoms. The Zn(2)-Zn(5) bond length is 2.78 Å. Both Zn(2)-Zn(2) bond lengths are 2.90 Å. In the third Zn site, Zn(3) is bonded in a 11-coordinate geometry to one Ag(5), one Ag(6), one Ag(8), two equivalent Ag(2), two equivalent Zn(3), two equivalent Zn(5), and two equivalent Zn(7) atoms. Both Zn(3)-Zn(3) bond lengths are 2.90 Å. There is one shorter (2.80 Å) and one longer (2.81 Å) Zn(3)-Zn(5) bond length. There is one shorter (2.73 Å) and one longer (2.75 Å) Zn(3)-Zn(7) bond length. In the fourth Zn site, Zn(4) is bonded in a 11-coordinate geometry to one Ag(4), one Ag(7), one Ag(9), two equivalent Ag(1), two equivalent Ag(3), two equivalent Zn(4), and two equivalent Zn(6) atoms. Both Zn(4)-Zn(4) bond lengths are 2.90 Å. There is one shorter (2.77 Å) and one longer (2.79 Å) Zn(4)-Zn(6) bond length. In the fifth Zn site, Zn(5) is bonded to two equivalent Ag(5), two equivalent Ag(6), two equivalent Ag(9), one Zn(2), one Zn(8), two equivalent Zn(3), and two equivalent Zn(5) atoms to form a mixture of distorted edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. The Zn(5)-Zn(8) bond length is 2.70 Å. Both Zn(5)-Zn(5) bond lengths are 2.90 Å. In the sixth Zn site, Zn(6) is bonded to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(4), and two equivalent Zn(6) atoms to form a mixture of face and corner-sharing ZnZn6Ag6 cuboctahedra. The Zn(6)-Zn(9) bond length is 2.69 Å. Both Zn(6)-Zn(6) bond lengths are 2.90 Å. In the seventh Zn site, Zn(7) is bonded to two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(3), and two equivalent Zn(7) atoms to form a mixture of edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. The Zn(7)-Zn(9) bond length is 2.64 Å. Both Zn(7)-Zn(7) bond lengths are 2.90 Å. In the eighth Zn site, Zn(8) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(5), one Ag(6), two equivalent Ag(9), and one Zn(5) atom. In the ninth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Ag(3), two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(9) atoms. Both Zn(9)-Zn(9) bond lengths are 2.90 Å.