(Na)2LiBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a LiBiBr6 framework. In the LiBiBr6 framework, Li(1) is bonded to six equivalent Br(1) atoms to form LiBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Li(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Li(1) and one Bi(1) atom.
(Na)2LiBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a LiBiBr6 framework. In the LiBiBr6 framework, Li(1) is bonded to six equivalent Br(1) atoms to form LiBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Li(1)-Br(1) bond lengths are 2.69 Å. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Li(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-Br(1) bond lengths are 2.85 Å. Br(1) is bonded in a linear geometry to one Li(1) and one Bi(1) atom.