SV1 is beta Sn-derived structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of edge, corner, and face-sharing VS6 octahedra. The corner-sharing octahedral tilt angles are 50°. S(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.
SV1 is beta Sn-derived structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of edge, corner, and face-sharing VS6 octahedra. The corner-sharing octahedral tilt angles are 50°. All V(1)-S(1) bond lengths are 2.50 Å. S(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.