LaOsN3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 12-coordinate geometry to four equivalent N(2) and eight equivalent N(1) atoms. Os(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form corner-sharing OsN6 octahedra. The corner-sharing octahedral tilt angles range from 14-16°. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to four equivalent La(1) and two equivalent Os(1) atoms. In the second N site, N(2) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent Os(1) atoms.
LaOsN3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 12-coordinate geometry to four equivalent N(2) and eight equivalent N(1) atoms. There are a spread of La(1)-N(2) bond distances ranging from 2.55-3.03 Å. There are a spread of La(1)-N(1) bond distances ranging from 2.56-3.12 Å. Os(1) is bonded to two equivalent N(2) and four equivalent N(1) atoms to form corner-sharing OsN6 octahedra. The corner-sharing octahedral tilt angles range from 14-16°. Both Os(1)-N(2) bond lengths are 2.00 Å. All Os(1)-N(1) bond lengths are 1.99 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to four equivalent La(1) and two equivalent Os(1) atoms. In the second N site, N(2) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent Os(1) atoms.