K4MnCl6 crystallizes in the cubic Im-3m space group. K(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. Mn(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. Cl(1) is bonded to four equivalent K(1) and one Mn(1) atom to form a mixture of corner and face-sharing ClK4Mn square pyramids.
K4MnCl6 crystallizes in the cubic Im-3m space group. K(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. All K(1)-Cl(1) bond lengths are 3.19 Å. Mn(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. All Mn(1)-Cl(1) bond lengths are 2.57 Å. Cl(1) is bonded to four equivalent K(1) and one Mn(1) atom to form a mixture of corner and face-sharing ClK4Mn square pyramids.