NaBiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 pentagonal pyramids that share corners with nine equivalent Bi(1)O6 octahedra, edges with three equivalent Na(1)O6 pentagonal pyramids, and  a faceface with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-62°. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with nine equivalent Na(1)O6 pentagonal pyramids, edges with three equivalent Bi(1)O6 octahedra, and  a faceface with one Na(1)O6 pentagonal pyramid. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Na(1) and two equivalent Bi(1) atoms.
NaBiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 pentagonal pyramids that share corners with nine equivalent Bi(1)O6 octahedra, edges with three equivalent Na(1)O6 pentagonal pyramids, and  a faceface with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-62°. There are three shorter (2.34 Å) and three longer (2.53 Å) Na(1)-O(1) bond lengths. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with nine equivalent Na(1)O6 pentagonal pyramids, edges with three equivalent Bi(1)O6 octahedra, and  a faceface with one Na(1)O6 pentagonal pyramid. There are three shorter (2.11 Å) and three longer (2.16 Å) Bi(1)-O(1) bond lengths. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Na(1) and two equivalent Bi(1) atoms.