CaLaCrO6Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a CaLaCrO6 framework. In the CaLaCrO6 framework, Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. La(1) is bonded to twelve equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with four equivalent Ca(1)O6 octahedra, and faces with four equivalent Cr(1)O6 octahedra. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to one Ca(1), two equivalent La(1), and one Cr(1) atom.
CaLaCrO6Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a CaLaCrO6 framework. In the CaLaCrO6 framework, Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ca(1)-O(1) bond lengths are 2.18 Å. La(1) is bonded to twelve equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with four equivalent Ca(1)O6 octahedra, and faces with four equivalent Cr(1)O6 octahedra. All La(1)-O(1) bond lengths are 2.87 Å. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Cr(1)-O(1) bond lengths are 1.87 Å. O(1) is bonded in a distorted linear geometry to one Ca(1), two equivalent La(1), and one Cr(1) atom.