WO2F is alpha Rhenium trioxide-derived structured and crystallizes in the monoclinic C2/c space group. W(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form corner-sharing WO4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. O(1) is bonded in a linear geometry to two equivalent W(1) atoms. F(1) is bonded in a linear geometry to two equivalent W(1) atoms.
WO2F is alpha Rhenium trioxide-derived structured and crystallizes in the monoclinic C2/c space group. W(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form corner-sharing WO4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. There are two shorter (1.87 Å) and two longer (2.02 Å) W(1)-O(1) bond lengths. Both W(1)-F(1) bond lengths are 2.08 Å. O(1) is bonded in a linear geometry to two equivalent W(1) atoms. F(1) is bonded in a linear geometry to two equivalent W(1) atoms.