KLiMnCPO7 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(6), one O(7), and two equivalent O(5) atoms. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. Mn(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. P(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one Li(1), one Mn(1), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one Li(1), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent K(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Mn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one Mn(1), and one P(1) atom.
KLiMnCPO7 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(6), one O(7), and two equivalent O(5) atoms. The K(1)-O(1) bond length is 2.69 Å. The K(1)-O(2) bond length is 2.83 Å. The K(1)-O(3) bond length is 2.74 Å. The K(1)-O(6) bond length is 2.92 Å. The K(1)-O(7) bond length is 2.70 Å. There is one shorter (2.75 Å) and one longer (3.09 Å) K(1)-O(5) bond length. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The Li(1)-O(1) bond length is 1.90 Å. The Li(1)-O(2) bond length is 1.94 Å. The Li(1)-O(3) bond length is 1.89 Å. Mn(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. The Mn(1)-O(2) bond length is 2.04 Å. The Mn(1)-O(3) bond length is 2.52 Å. The Mn(1)-O(4) bond length is 1.94 Å. The Mn(1)-O(5) bond length is 1.97 Å. The Mn(1)-O(6) bond length is 2.15 Å. The Mn(1)-O(7) bond length is 1.92 Å. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.33 Å. The C(1)-O(3) bond length is 1.29 Å. P(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom. The P(1)-O(4) bond length is 1.56 Å. The P(1)-O(5) bond length is 1.56 Å. The P(1)-O(6) bond length is 1.52 Å. The P(1)-O(7) bond length is 1.57 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Li(1), and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one Li(1), one Mn(1), and one C(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), one Li(1), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent K(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one K(1), one Mn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one Mn(1), and one P(1) atom.