W(OF2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four ammonia atoms and two W(OF2)2 clusters. In each W(OF2)2 cluster, W(1) is bonded in a distorted pentagonal pyramidal geometry to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one W(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one W(1) and one O(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom.
W(OF2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four ammonia atoms and two W(OF2)2 clusters. In each W(OF2)2 cluster, W(1) is bonded in a distorted pentagonal pyramidal geometry to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. The W(1)-O(1) bond length is 1.91 Å. The W(1)-O(2) bond length is 1.91 Å. The W(1)-F(1) bond length is 1.89 Å. The W(1)-F(2) bond length is 1.89 Å. The W(1)-F(3) bond length is 1.89 Å. The W(1)-F(4) bond length is 1.89 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one W(1) and one O(2) atom. The O(1)-O(2) bond length is 1.51 Å. In the second O site, O(2) is bonded in a 2-coordinate geometry to one W(1) and one O(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom.