XeO3AsF6 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four XeO3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In each XeO3 cluster, Xe(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2,3) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second O site, O(2,3) is bonded in a single-bond geometry to one Xe(1) atom.
XeO3AsF6 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four XeO3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.75 Å. The As(1)-F(2) bond length is 1.77 Å. The As(1)-F(3) bond length is 1.79 Å. The As(1)-F(4) bond length is 1.81 Å. The As(1)-F(5) bond length is 1.80 Å. The As(1)-F(6) bond length is 1.74 Å. There are six inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In each XeO3 cluster, Xe(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(2,3) atoms. The Xe(1)-O(1) bond length is 1.86 Å. Both Xe(1)-O(2,3) bond lengths are 1.93 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second O site, O(2,3) is bonded in a single-bond geometry to one Xe(1) atom.