RbH2OF crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 13-coordinate geometry to six equivalent H(1), three equivalent O(1), and four equivalent F(1) atoms. H(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one O(1) atom. O(1) is bonded in a distorted water-like geometry to three equivalent Rb(1) and two equivalent H(1) atoms. F(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1) atoms.
RbH2OF crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 13-coordinate geometry to six equivalent H(1), three equivalent O(1), and four equivalent F(1) atoms. There are a spread of Rb(1)-H(1) bond distances ranging from 2.93-3.08 Å. There is one shorter (2.91 Å) and two longer (3.30 Å) Rb(1)-O(1) bond lengths. There are a spread of Rb(1)-F(1) bond distances ranging from 2.90-2.95 Å. H(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. O(1) is bonded in a distorted water-like geometry to three equivalent Rb(1) and two equivalent H(1) atoms. F(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1) atoms.