NaPO crystallizes in the orthorhombic Imma space group. Na(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(1) and two equivalent P(1) atoms.
NaPO crystallizes in the orthorhombic Imma space group. Na(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. Both Na(1)-O(1) bond lengths are 2.31 Å. P(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both P(1)-O(1) bond lengths are 1.83 Å. O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(1) and two equivalent P(1) atoms.