CN5S3Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CN5S3Cl clusters. C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(1) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one S(3) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(2), one N(4), and one N(5) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one N(1), one N(3), and one N(5) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom.
CN5S3Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CN5S3Cl clusters. C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(1) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.32 Å. The C(1)-Cl(1) bond length is 1.75 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(1)-S(2) bond length is 1.56 Å. The N(1)-S(3) bond length is 1.75 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. The N(2)-S(1) bond length is 1.64 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one S(3) atom. The N(3)-S(3) bond length is 1.64 Å. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(4)-S(1) bond length is 1.75 Å. The N(4)-S(2) bond length is 1.56 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. The N(5)-S(1) bond length is 1.64 Å. The N(5)-S(3) bond length is 1.64 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(2), one N(4), and one N(5) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one N(1), one N(3), and one N(5) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom.