LaTiO2N is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Imma space group. La(1) is bonded in a 12-coordinate geometry to four equivalent N(1) and eight equivalent O(1) atoms. Ti(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form corner-sharing TiN2O4 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. N(1) is bonded in a 3-coordinate geometry to four equivalent La(1) and two equivalent Ti(1) atoms. O(1) is bonded in a 2-coordinate geometry to four equivalent La(1) and two equivalent Ti(1) atoms.
LaTiO2N is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Imma space group. La(1) is bonded in a 12-coordinate geometry to four equivalent N(1) and eight equivalent O(1) atoms. There are a spread of La(1)-N(1) bond distances ranging from 2.43-3.19 Å. There are four shorter (2.62 Å) and four longer (3.02 Å) La(1)-O(1) bond lengths. Ti(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form corner-sharing TiN2O4 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. Both Ti(1)-N(1) bond lengths are 2.03 Å. All Ti(1)-O(1) bond lengths are 1.99 Å. N(1) is bonded in a 3-coordinate geometry to four equivalent La(1) and two equivalent Ti(1) atoms. O(1) is bonded in a 2-coordinate geometry to four equivalent La(1) and two equivalent Ti(1) atoms.