ZrBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight zirconium tetrabromide molecules. Zr(1) is bonded in a tetrahedral geometry to one Br(2) and three equivalent Br(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Zr(1) atom.
ZrBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight zirconium tetrabromide molecules. Zr(1) is bonded in a tetrahedral geometry to one Br(2) and three equivalent Br(1) atoms. The Zr(1)-Br(2) bond length is 2.47 Å. All Zr(1)-Br(1) bond lengths are 2.47 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Zr(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Zr(1) atom.