LiSrTiF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. Sr(1) is bonded to six equivalent F(1) atoms to form SrF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. Ti(1) is bonded to six equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 49°. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Sr(1), and one Ti(1) atom.
LiSrTiF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. All Li(1)-F(1) bond lengths are 2.08 Å. Sr(1) is bonded to six equivalent F(1) atoms to form SrF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. All Sr(1)-F(1) bond lengths are 2.46 Å. Ti(1) is bonded to six equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent Sr(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Ti(1)-F(1) bond lengths are 1.99 Å. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Sr(1), and one Ti(1) atom.