FeC4H12(N5S2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one FeC4H12(N5S2)2 cluster. Fe(1) is bonded in a distorted octahedral geometry to two equivalent N(2), two equivalent N(5), and two equivalent S(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(4), and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(5) and one S(2) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(1), one N(2), and one H(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one Fe(1), one N(1), one H(2), and one H(3) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one N(4) and two equivalent H(4,6) atoms. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(1), one N(3), and one H(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one Fe(1) and one C(2) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4,6) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Fe(1) and one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom.
FeC4H12(N5S2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one FeC4H12(N5S2)2 cluster. Fe(1) is bonded in a distorted octahedral geometry to two equivalent N(2), two equivalent N(5), and two equivalent S(1) atoms. Both Fe(1)-N(2) bond lengths are 2.24 Å. Both Fe(1)-N(5) bond lengths are 2.06 Å. Both Fe(1)-S(1) bond lengths are 2.54 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(4), and one S(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(4) bond length is 1.35 Å. The C(1)-S(1) bond length is 1.71 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(5) and one S(2) atom. The C(2)-N(5) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.62 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(1), one N(2), and one H(1) atom. The N(1)-N(2) bond length is 1.41 Å. The N(1)-H(1) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one Fe(1), one N(1), one H(2), and one H(3) atom. The N(2)-H(2) bond length is 1.03 Å. The N(2)-H(3) bond length is 1.03 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one N(4) and two equivalent H(4,6) atoms. The N(3)-N(4) bond length is 1.40 Å. There is one shorter (1.02 Å) and one longer (1.03 Å) N(3)-H(4,6) bond length. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(1), one N(3), and one H(5) atom. The N(4)-H(5) bond length is 1.02 Å. In the fifth N site, N(5) is bonded in a linear geometry to one Fe(1) and one C(2) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4,6) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Fe(1) and one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom.