Os(S3Cl4)2(Cl2)8 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of sixteen 7782-50-5 molecules and two Os(S3Cl4)2 clusters. In each Os(S3Cl4)2 cluster, Os(1) is bonded in a distorted octahedral geometry to two equivalent S(1) and four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Os(1) and two equivalent Cl(3) atoms. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Os(1) and one S(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Cl(3) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) and one Cl(2) atom.
Os(S3Cl4)2(Cl2)8 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of sixteen 7782-50-5 molecules and two Os(S3Cl4)2 clusters. In each Os(S3Cl4)2 cluster, Os(1) is bonded in a distorted octahedral geometry to two equivalent S(1) and four equivalent S(2) atoms. Both Os(1)-S(1) bond lengths are 2.28 Å. All Os(1)-S(2) bond lengths are 2.39 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Os(1) and two equivalent Cl(3) atoms. Both S(1)-Cl(3) bond lengths are 2.32 Å. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Os(1) and one S(2) atom. The S(2)-S(2) bond length is 1.97 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Cl(3) atom. The Cl(2)-Cl(3) bond length is 2.23 Å. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) and one Cl(2) atom.