LiLu2W2(O4Cl)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(4), one O(6), one O(8), one Cl(1), and one Cl(2) atom. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(7), one O(8), one Cl(1), and one Cl(2) atom. In the second Lu site, Lu(2) is bonded in a 7-coordinate geometry to one O(2), one O(4), one O(6), one O(7), one O(8), one Cl(1), and one Cl(2) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(6), and one O(7) atom. In the second W site, W(2) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Lu(1) and one W(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Lu(2) and one W(2) atom. In the third O site, O(3) is bonded in a linear geometry to one Lu(1) and one W(2) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Li(1), one Lu(2), and one W(1) atom. In the fifth O site, O(5) is bonded in a linear geometry to one Lu(1) and one W(2) atom. In the sixth O site, O(6) is bonded in a T-shaped geometry to one Li(1), one Lu(2), and one W(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal pyramidal geometry to one Li(1), one Lu(1), one Lu(2), and one W(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Li(1), one Lu(1), and one Lu(2) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Li(1), one Lu(1), and one Lu(2) atom.
LiLu2W2(O4Cl)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(4), one O(6), one O(8), one Cl(1), and one Cl(2) atom. The Li(1)-O(4) bond length is 1.99 Å. The Li(1)-O(6) bond length is 1.95 Å. The Li(1)-O(8) bond length is 2.10 Å. The Li(1)-Cl(1) bond length is 2.37 Å. The Li(1)-Cl(2) bond length is 2.47 Å. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(7), one O(8), one Cl(1), and one Cl(2) atom. The Lu(1)-O(1) bond length is 2.15 Å. The Lu(1)-O(3) bond length is 2.22 Å. The Lu(1)-O(5) bond length is 2.18 Å. The Lu(1)-O(7) bond length is 2.29 Å. The Lu(1)-O(8) bond length is 2.28 Å. The Lu(1)-Cl(1) bond length is 2.92 Å. The Lu(1)-Cl(2) bond length is 2.85 Å. In the second Lu site, Lu(2) is bonded in a 7-coordinate geometry to one O(2), one O(4), one O(6), one O(7), one O(8), one Cl(1), and one Cl(2) atom. The Lu(2)-O(2) bond length is 2.20 Å. The Lu(2)-O(4) bond length is 2.14 Å. The Lu(2)-O(6) bond length is 2.17 Å. The Lu(2)-O(7) bond length is 2.27 Å. The Lu(2)-O(8) bond length is 2.48 Å. The Lu(2)-Cl(1) bond length is 2.90 Å. The Lu(2)-Cl(2) bond length is 2.85 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(6), and one O(7) atom. The W(1)-O(1) bond length is 1.83 Å. The W(1)-O(4) bond length is 1.93 Å. The W(1)-O(6) bond length is 1.93 Å. The W(1)-O(7) bond length is 1.90 Å. In the second W site, W(2) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(8) atom. The W(2)-O(2) bond length is 1.80 Å. The W(2)-O(3) bond length is 1.80 Å. The W(2)-O(5) bond length is 1.80 Å. The W(2)-O(8) bond length is 1.86 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Lu(1) and one W(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Lu(2) and one W(2) atom. In the third O site, O(3) is bonded in a linear geometry to one Lu(1) and one W(2) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Li(1), one Lu(2), and one W(1) atom. In the fifth O site, O(5) is bonded in a linear geometry to one Lu(1) and one W(2) atom. In the sixth O site, O(6) is bonded in a T-shaped geometry to one Li(1), one Lu(2), and one W(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal pyramidal geometry to one Li(1), one Lu(1), one Lu(2), and one W(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Li(1), one Lu(1), and one Lu(2) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Li(1), one Lu(1), and one Lu(2) atom.