Li3Mn3TeO8 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-87°. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), one O(7), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, corners with two equivalent Li(1)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-87°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Mn(2)O6 octahedra, corners with two equivalent Li(1)O5 square pyramids, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(2)O5 square pyramids. The corner-sharing octahedral tilt angles range from 13-16°. In the fourth Li site, Li(4) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Mn(2)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. The corner-sharing octahedral tilt angles range from 13-17°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with four equivalent Li(2)O5 square pyramids, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Te(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-17°. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(2)O5 square pyramids, corners with six equivalent Li(1)O5 square pyramids, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with four equivalent Li(1)O5 square pyramids, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(2)O5 square pyramids. In the fifth Mn site, Mn(5) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O5 square pyramids, corners with six equivalent Li(2)O5 square pyramids, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. Te(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O5 square pyramids, and edges with two equivalent Li(2)O5 square pyramids. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Mn(2), one Mn(4), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with three equivalent O(1)Li2Mn3 square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid, edges with two equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(7)Li2Mn2Te square pyramids, and edges with three equivalent O(4)Li2Mn2Te square pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(4), one Mn(1), one Mn(2), and one Mn(3) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with three equivalent O(2)Li2Mn3 square pyramids,  an edgeedge with one O(5)Li2Mn2Te square pyramid, edges with two equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(8)Li2Mn2Te square pyramids, and edges with three equivalent O(6)Li2Mn2Te square pyramids. In the third O site, O(3) is bonded to one Li(2), one Li(4), one Mn(1), one Mn(2), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(4)Li2Mn2Te square pyramids,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Mn(2), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(3)Li2Mn2Te square pyramids,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid, and edges with three equivalent O(1)Li2Mn3 square pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(6)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one Mn(2), one Mn(3), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(5)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid, and edges with three equivalent O(2)Li2Mn3 square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Mn(4), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(8)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Mn(1), one Mn(3), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(7)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids.
Li3Mn3TeO8 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-87°. The Li(1)-O(2) bond length is 2.07 Å. The Li(1)-O(5) bond length is 2.31 Å. The Li(1)-O(6) bond length is 2.09 Å. The Li(1)-O(7) bond length is 2.21 Å. The Li(1)-O(8) bond length is 2.17 Å. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), one O(7), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, corners with two equivalent Li(1)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-87°. The Li(2)-O(1) bond length is 2.07 Å. The Li(2)-O(3) bond length is 2.30 Å. The Li(2)-O(4) bond length is 2.10 Å. The Li(2)-O(7) bond length is 2.18 Å. The Li(2)-O(8) bond length is 2.19 Å. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Mn(2)O6 octahedra, corners with two equivalent Li(1)O5 square pyramids, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(2)O5 square pyramids. The corner-sharing octahedral tilt angles range from 13-16°. Both Li(3)-O(1) bond lengths are 2.22 Å. Both Li(3)-O(4) bond lengths are 2.21 Å. Both Li(3)-O(5) bond lengths are 2.19 Å. In the fourth Li site, Li(4) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Mn(2)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. The corner-sharing octahedral tilt angles range from 13-17°. Both Li(4)-O(2) bond lengths are 2.22 Å. Both Li(4)-O(3) bond lengths are 2.20 Å. Both Li(4)-O(6) bond lengths are 2.21 Å. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with four equivalent Li(2)O5 square pyramids, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. Both Mn(1)-O(2) bond lengths are 1.92 Å. Both Mn(1)-O(3) bond lengths are 2.14 Å. Both Mn(1)-O(8) bond lengths are 2.26 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Te(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-17°. The Mn(2)-O(1) bond length is 2.16 Å. The Mn(2)-O(2) bond length is 2.16 Å. The Mn(2)-O(3) bond length is 2.29 Å. The Mn(2)-O(4) bond length is 2.23 Å. The Mn(2)-O(5) bond length is 2.28 Å. The Mn(2)-O(6) bond length is 2.25 Å. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(2)O5 square pyramids, corners with six equivalent Li(1)O5 square pyramids, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. Both Mn(3)-O(2) bond lengths are 2.19 Å. Both Mn(3)-O(6) bond lengths are 2.23 Å. Both Mn(3)-O(8) bond lengths are 2.30 Å. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with four equivalent Li(1)O5 square pyramids, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Li(2)O5 square pyramids. Both Mn(4)-O(1) bond lengths are 1.92 Å. Both Mn(4)-O(5) bond lengths are 2.14 Å. Both Mn(4)-O(7) bond lengths are 2.26 Å. In the fifth Mn site, Mn(5) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O5 square pyramids, corners with six equivalent Li(2)O5 square pyramids, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. Both Mn(5)-O(1) bond lengths are 2.18 Å. Both Mn(5)-O(4) bond lengths are 2.23 Å. Both Mn(5)-O(7) bond lengths are 2.30 Å. Te(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O5 square pyramids, and edges with two equivalent Li(2)O5 square pyramids. The Te(1)-O(3) bond length is 1.97 Å. The Te(1)-O(4) bond length is 1.96 Å. The Te(1)-O(5) bond length is 1.97 Å. The Te(1)-O(6) bond length is 1.96 Å. The Te(1)-O(7) bond length is 1.95 Å. The Te(1)-O(8) bond length is 1.95 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Mn(2), one Mn(4), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with three equivalent O(1)Li2Mn3 square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid, edges with two equivalent O(5)Li2Mn2Te square pyramids, edges with two equivalent O(7)Li2Mn2Te square pyramids, and edges with three equivalent O(4)Li2Mn2Te square pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(4), one Mn(1), one Mn(2), and one Mn(3) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(3)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with three equivalent O(2)Li2Mn3 square pyramids,  an edgeedge with one O(5)Li2Mn2Te square pyramid, edges with two equivalent O(3)Li2Mn2Te square pyramids, edges with two equivalent O(8)Li2Mn2Te square pyramids, and edges with three equivalent O(6)Li2Mn2Te square pyramids. In the third O site, O(3) is bonded to one Li(2), one Li(4), one Mn(1), one Mn(2), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(4)Li2Mn2Te square pyramids,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Mn(2), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(3)Li2Mn2Te square pyramids,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid, and edges with three equivalent O(1)Li2Mn3 square pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(6)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one Mn(2), one Mn(3), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(5)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid, and edges with three equivalent O(2)Li2Mn3 square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Mn(4), one Mn(5), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(4)Li2Mn2Te square pyramids, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(8)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Mn(1), one Mn(3), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(3)Li2Mn2Te square pyramids, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(7)Li2Mn2Te square pyramids,  an edgeedge with one O(3)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids.