CsAuCdS2 crystallizes in the orthorhombic Cmme space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent Au(1) and eight equivalent S(1) atoms. Au(1) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent S(1) atoms. Cd(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing CdS4 tetrahedra. S(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Au(1), and two equivalent Cd(1) atoms.
CsAuCdS2 crystallizes in the orthorhombic Cmme space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent Au(1) and eight equivalent S(1) atoms. Both Cs(1)-Au(1) bond lengths are 3.83 Å. There are a spread of Cs(1)-S(1) bond distances ranging from 3.62-4.01 Å. Au(1) is bonded in a 4-coordinate geometry to two equivalent Cs(1) and two equivalent S(1) atoms. Both Au(1)-S(1) bond lengths are 2.34 Å. Cd(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing CdS4 tetrahedra. All Cd(1)-S(1) bond lengths are 2.62 Å. S(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Au(1), and two equivalent Cd(1) atoms.