(Rb)2RbScBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a RbScBr6 framework. In the RbScBr6 framework, Rb(2) is bonded to six equivalent Br(1) atoms to form RbBr6 octahedra that share corners with six equivalent Sc(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent Br(1) atoms to form ScBr6 octahedra that share corners with six equivalent Rb(2)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Rb(2) and one Sc(1) atom.
(Rb)2RbScBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a RbScBr6 framework. In the RbScBr6 framework, Rb(2) is bonded to six equivalent Br(1) atoms to form RbBr6 octahedra that share corners with six equivalent Sc(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Rb(2)-Br(1) bond lengths are 3.25 Å. Sc(1) is bonded to six equivalent Br(1) atoms to form ScBr6 octahedra that share corners with six equivalent Rb(2)Br6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-Br(1) bond lengths are 2.66 Å. Br(1) is bonded in a linear geometry to one Rb(2) and one Sc(1) atom.