Cs2InH6Tl crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-28-0 atoms inside a Cs2InH6 framework. In the Cs2InH6 framework, Cs(1) is bonded to twelve equivalent H(1) atoms to form CsH12 cuboctahedra that share corners with twelve equivalent Cs(1)H12 cuboctahedra, faces with six equivalent Cs(1)H12 cuboctahedra, and faces with four equivalent In(1)H6 octahedra. In(1) is bonded to six equivalent H(1) atoms to form InH6 octahedra that share faces with eight equivalent Cs(1)H12 cuboctahedra. H(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one In(1) atom.
Cs2InH6Tl crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-28-0 atoms inside a Cs2InH6 framework. In the Cs2InH6 framework, Cs(1) is bonded to twelve equivalent H(1) atoms to form CsH12 cuboctahedra that share corners with twelve equivalent Cs(1)H12 cuboctahedra, faces with six equivalent Cs(1)H12 cuboctahedra, and faces with four equivalent In(1)H6 octahedra. All Cs(1)-H(1) bond lengths are 3.26 Å. In(1) is bonded to six equivalent H(1) atoms to form InH6 octahedra that share faces with eight equivalent Cs(1)H12 cuboctahedra. All In(1)-H(1) bond lengths are 1.98 Å. H(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one In(1) atom.