TeO3 crystallizes in the trigonal R-3c space group. Te(1) is bonded to six equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 41°. O(1) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms.
TeO3 crystallizes in the trigonal R-3c space group. Te(1) is bonded to six equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Te(1)-O(1) bond lengths are 1.91 Å. O(1) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms.