MoC4(NCl3)2C4N2Cl is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two C4N2Cl clusters and two MoC4(NCl3)2 clusters. In each C4N2Cl cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a single-bond geometry to one N(2) atom. In the second C site, C(4) is bonded in a bent 120 degrees geometry to one N(2) and one Cl(4) atom. N(2) is bonded in a linear geometry to one C(3) and one C(4) atom. Cl(4) is bonded in a linear geometry to two equivalent C(4) atoms. In each MoC4(NCl3)2 cluster, Mo(1) is bonded in a distorted octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a water-like geometry to one N(1) and one Cl(3) atom. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one C(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom.
MoC4(NCl3)2C4N2Cl is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two C4N2Cl clusters and two MoC4(NCl3)2 clusters. In each C4N2Cl cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a single-bond geometry to one N(2) atom. The C(3)-N(2) bond length is 1.23 Å. In the second C site, C(4) is bonded in a bent 120 degrees geometry to one N(2) and one Cl(4) atom. The C(4)-N(2) bond length is 1.29 Å. The C(4)-Cl(4) bond length is 1.98 Å. N(2) is bonded in a linear geometry to one C(3) and one C(4) atom. Cl(4) is bonded in a linear geometry to two equivalent C(4) atoms. In each MoC4(NCl3)2 cluster, Mo(1) is bonded in a distorted octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. Both Mo(1)-Cl(1) bond lengths are 2.26 Å. Both Mo(1)-Cl(2) bond lengths are 2.31 Å. Both Mo(1)-Cl(3) bond lengths are 2.80 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. The C(1)-N(1) bond length is 1.21 Å. In the second C site, C(2) is bonded in a water-like geometry to one N(1) and one Cl(3) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-Cl(3) bond length is 1.75 Å. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one C(2) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom.