HgN6 is Indium-like structured and crystallizes in the orthorhombic Iba2 space group. The structure is zero-dimensional and consists of eight HgN6 clusters. Hg(1) is bonded in a linear geometry to one N(1) and one N(4) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom.
HgN6 is Indium-like structured and crystallizes in the orthorhombic Iba2 space group. The structure is zero-dimensional and consists of eight HgN6 clusters. Hg(1) is bonded in a linear geometry to one N(1) and one N(4) atom. The Hg(1)-N(1) bond length is 2.10 Å. The Hg(1)-N(4) bond length is 2.09 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(2) atom. The N(1)-N(2) bond length is 1.23 Å. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. The N(2)-N(3) bond length is 1.15 Å. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one N(5) atom. The N(4)-N(5) bond length is 1.22 Å. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. The N(5)-N(6) bond length is 1.16 Å. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom.