CsFeCl4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 10-coordinate geometry to one Cl(2), three equivalent Cl(3), and six equivalent Cl(1) atoms. Fe(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Fe(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(1) and one Fe(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Fe(1) atom.
CsFeCl4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 10-coordinate geometry to one Cl(2), three equivalent Cl(3), and six equivalent Cl(1) atoms. The Cs(1)-Cl(2) bond length is 3.57 Å. There is one shorter (3.65 Å) and two longer (3.94 Å) Cs(1)-Cl(3) bond lengths. There are a spread of Cs(1)-Cl(1) bond distances ranging from 3.60-3.80 Å. Fe(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. The Fe(1)-Cl(2) bond length is 2.19 Å. The Fe(1)-Cl(3) bond length is 2.19 Å. Both Fe(1)-Cl(1) bond lengths are 2.20 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Fe(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(1) and one Fe(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Fe(1) atom.