CuPb2(OF)2 crystallizes in the tetragonal I4/mmm space group. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Pb(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded in a distorted linear geometry to two equivalent Cu(1) and four equivalent Pb(1) atoms. F(1) is bonded to four equivalent Pb(1) atoms to form a mixture of edge and corner-sharing FPb4 tetrahedra.
CuPb2(OF)2 crystallizes in the tetragonal I4/mmm space group. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Cu(1)-O(1) bond lengths are 2.02 Å. Pb(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. All Pb(1)-O(1) bond lengths are 2.70 Å. All Pb(1)-F(1) bond lengths are 2.57 Å. O(1) is bonded in a distorted linear geometry to two equivalent Cu(1) and four equivalent Pb(1) atoms. F(1) is bonded to four equivalent Pb(1) atoms to form a mixture of edge and corner-sharing FPb4 tetrahedra.