ReCoB crystallizes in the orthorhombic Pnma space group. Re(1) is bonded in a 5-coordinate geometry to five equivalent B(1) atoms. Co(1) is bonded to four equivalent B(1) atoms to form a mixture of distorted edge and corner-sharing CoB4 tetrahedra. B(1) is bonded in a 9-coordinate geometry to five equivalent Re(1) and four equivalent Co(1) atoms.
ReCoB crystallizes in the orthorhombic Pnma space group. Re(1) is bonded in a 5-coordinate geometry to five equivalent B(1) atoms. There are a spread of Re(1)-B(1) bond distances ranging from 2.35-2.40 Å. Co(1) is bonded to four equivalent B(1) atoms to form a mixture of distorted edge and corner-sharing CoB4 tetrahedra. There are a spread of Co(1)-B(1) bond distances ranging from 2.08-2.19 Å. B(1) is bonded in a 9-coordinate geometry to five equivalent Re(1) and four equivalent Co(1) atoms.