(K)2ScTlBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a ScTlBr6 framework. In the ScTlBr6 framework, Sc(1) is bonded to six equivalent Br(1) atoms to form ScBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Sc(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Sc(1) and one Tl(1) atom.
(K)2ScTlBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a ScTlBr6 framework. In the ScTlBr6 framework, Sc(1) is bonded to six equivalent Br(1) atoms to form ScBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-Br(1) bond lengths are 2.66 Å. Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Sc(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 3.16 Å. Br(1) is bonded in a linear geometry to one Sc(1) and one Tl(1) atom.