ZnGeAsP is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Zn(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form ZnAs2P2 tetrahedra that share corners with four equivalent Zn(1)As2P2 tetrahedra and corners with eight equivalent Ge(1)As2P2 tetrahedra. Ge(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form GeAs2P2 tetrahedra that share corners with four equivalent Ge(1)As2P2 tetrahedra and corners with eight equivalent Zn(1)As2P2 tetrahedra. As(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form AsZn2Ge2 tetrahedra that share corners with four equivalent As(1)Zn2Ge2 tetrahedra and corners with eight equivalent P(1)Zn2Ge2 tetrahedra. P(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form PZn2Ge2 tetrahedra that share corners with four equivalent P(1)Zn2Ge2 tetrahedra and corners with eight equivalent As(1)Zn2Ge2 tetrahedra.
ZnGeAsP is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Zn(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form ZnAs2P2 tetrahedra that share corners with four equivalent Zn(1)As2P2 tetrahedra and corners with eight equivalent Ge(1)As2P2 tetrahedra. Both Zn(1)-As(1) bond lengths are 2.46 Å. Both Zn(1)-P(1) bond lengths are 2.41 Å. Ge(1) is bonded to two equivalent As(1) and two equivalent P(1) atoms to form GeAs2P2 tetrahedra that share corners with four equivalent Ge(1)As2P2 tetrahedra and corners with eight equivalent Zn(1)As2P2 tetrahedra. Both Ge(1)-As(1) bond lengths are 2.46 Å. Both Ge(1)-P(1) bond lengths are 2.38 Å. As(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form AsZn2Ge2 tetrahedra that share corners with four equivalent As(1)Zn2Ge2 tetrahedra and corners with eight equivalent P(1)Zn2Ge2 tetrahedra. P(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form PZn2Ge2 tetrahedra that share corners with four equivalent P(1)Zn2Ge2 tetrahedra and corners with eight equivalent As(1)Zn2Ge2 tetrahedra.