LaTi2O6Ga crystallizes in the orthorhombic Cmmm space group. The structure consists of two 7440-55-3 atoms inside a LaTi2O6 framework. In the LaTi2O6 framework, La(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with eight equivalent Ti(1)O6 octahedra. Ti(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TiO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-18°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent La(1) and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent La(1) and two equivalent Ti(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent La(1) and two equivalent Ti(1) atoms.
LaTi2O6Ga crystallizes in the orthorhombic Cmmm space group. The structure consists of two 7440-55-3 atoms inside a LaTi2O6 framework. In the LaTi2O6 framework, La(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with eight equivalent Ti(1)O6 octahedra. All La(1)-O(1) bond lengths are 2.78 Å. All La(1)-O(2) bond lengths are 2.57 Å. All La(1)-O(3) bond lengths are 2.86 Å. Ti(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TiO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-18°. Both Ti(1)-O(1) bond lengths are 1.97 Å. Both Ti(1)-O(2) bond lengths are 1.99 Å. Both Ti(1)-O(3) bond lengths are 1.96 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent La(1) and two equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent La(1) and two equivalent Ti(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent La(1) and two equivalent Ti(1) atoms.