Mn8O13F3 crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 4-coordinate geometry to one O(10), one O(2), one O(3), one O(6), and one F(1) atom. In the second Mn site, Mn(2) is bonded in a 4-coordinate geometry to one O(1), one O(12), one O(4), and one O(7) atom. In the third Mn site, Mn(3) is bonded in a 2-coordinate geometry to one O(1), one O(13), one O(2), one O(3), and one F(3) atom. In the fourth Mn site, Mn(4) is bonded in a distorted linear geometry to one O(12), one O(6), one O(7), one O(8), one O(9), and one F(1) atom. In the fifth Mn site, Mn(5) is bonded in a 2-coordinate geometry to one O(5), one O(8), one O(9), and one F(1) atom. In the sixth Mn site, Mn(6) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(2), one O(4), one F(2), and one F(3) atom. In the seventh Mn site, Mn(7) is bonded in a 4-coordinate geometry to one O(6), one O(8), one F(2), and one F(3) atom. In the eighth Mn site, Mn(8) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(5), and one O(9) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Mn(1) and one Mn(3) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Mn(2) and one Mn(6) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Mn(5) and one Mn(8) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Mn(2) and one Mn(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a distorted L-shaped geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Mn(1) atom. In the eleventh O site, O(11) is bonded in a 1-coordinate geometry to one Mn(8) atom. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Mn(2) and one Mn(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Mn(3), one Mn(6), and one Mn(8) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted L-shaped geometry to one Mn(6) and one Mn(7) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Mn(3), one Mn(6), and one Mn(7) atom.
Mn8O13F3 crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 4-coordinate geometry to one O(10), one O(2), one O(3), one O(6), and one F(1) atom. The Mn(1)-O(10) bond length is 1.85 Å. The Mn(1)-O(2) bond length is 1.59 Å. The Mn(1)-O(3) bond length is 1.83 Å. The Mn(1)-O(6) bond length is 2.54 Å. The Mn(1)-F(1) bond length is 2.06 Å. In the second Mn site, Mn(2) is bonded in a 4-coordinate geometry to one O(1), one O(12), one O(4), and one O(7) atom. The Mn(2)-O(1) bond length is 1.95 Å. The Mn(2)-O(12) bond length is 1.73 Å. The Mn(2)-O(4) bond length is 1.91 Å. The Mn(2)-O(7) bond length is 1.73 Å. In the third Mn site, Mn(3) is bonded in a 2-coordinate geometry to one O(1), one O(13), one O(2), one O(3), and one F(3) atom. The Mn(3)-O(1) bond length is 2.31 Å. The Mn(3)-O(13) bond length is 2.32 Å. The Mn(3)-O(2) bond length is 1.79 Å. The Mn(3)-O(3) bond length is 1.62 Å. The Mn(3)-F(3) bond length is 2.34 Å. In the fourth Mn site, Mn(4) is bonded in a distorted linear geometry to one O(12), one O(6), one O(7), one O(8), one O(9), and one F(1) atom. The Mn(4)-O(12) bond length is 1.76 Å. The Mn(4)-O(6) bond length is 2.26 Å. The Mn(4)-O(7) bond length is 1.69 Å. The Mn(4)-O(8) bond length is 2.36 Å. The Mn(4)-O(9) bond length is 2.31 Å. The Mn(4)-F(1) bond length is 2.48 Å. In the fifth Mn site, Mn(5) is bonded in a 2-coordinate geometry to one O(5), one O(8), one O(9), and one F(1) atom. The Mn(5)-O(5) bond length is 1.87 Å. The Mn(5)-O(8) bond length is 2.38 Å. The Mn(5)-O(9) bond length is 1.70 Å. The Mn(5)-F(1) bond length is 2.52 Å. In the sixth Mn site, Mn(6) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(2), one O(4), one F(2), and one F(3) atom. The Mn(6)-O(1) bond length is 2.36 Å. The Mn(6)-O(13) bond length is 2.37 Å. The Mn(6)-O(2) bond length is 2.36 Å. The Mn(6)-O(4) bond length is 2.39 Å. The Mn(6)-F(2) bond length is 2.05 Å. The Mn(6)-F(3) bond length is 1.86 Å. In the seventh Mn site, Mn(7) is bonded in a 4-coordinate geometry to one O(6), one O(8), one F(2), and one F(3) atom. The Mn(7)-O(6) bond length is 1.96 Å. The Mn(7)-O(8) bond length is 1.94 Å. The Mn(7)-F(2) bond length is 1.90 Å. The Mn(7)-F(3) bond length is 2.01 Å. In the eighth Mn site, Mn(8) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(5), and one O(9) atom. The Mn(8)-O(11) bond length is 1.91 Å. The Mn(8)-O(13) bond length is 2.00 Å. The Mn(8)-O(5) bond length is 1.74 Å. The Mn(8)-O(9) bond length is 1.78 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Mn(1) and one Mn(3) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Mn(2) and one Mn(6) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Mn(5) and one Mn(8) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Mn(2) and one Mn(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a distorted L-shaped geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Mn(1) atom. In the eleventh O site, O(11) is bonded in a 1-coordinate geometry to one Mn(8) atom. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Mn(2) and one Mn(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Mn(3), one Mn(6), and one Mn(8) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted L-shaped geometry to one Mn(6) and one Mn(7) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Mn(3), one Mn(6), and one Mn(7) atom.