V2MnAl is Tungsten-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Mn(1) atoms. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to four equivalent V(1), six equivalent Mn(1), and four equivalent Al(1) atoms. Mn(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(1), six equivalent V(2), and four equivalent Al(1) atoms. Al(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Mn(1) atoms.
V2MnAl is Tungsten-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Mn(1) atoms. All V(1)-V(2) bond lengths are 2.58 Å. All V(1)-Mn(1) bond lengths are 2.58 Å. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to four equivalent V(1), six equivalent Mn(1), and four equivalent Al(1) atoms. All V(2)-Mn(1) bond lengths are 2.97 Å. All V(2)-Al(1) bond lengths are 2.58 Å. Mn(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(1), six equivalent V(2), and four equivalent Al(1) atoms. All Mn(1)-Al(1) bond lengths are 2.58 Å. Al(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(2) and four equivalent Mn(1) atoms.