ReP3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. Re(1) is bonded in a distorted body-centered cubic geometry to six equivalent P(2) and eight equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a body-centered cubic geometry to four equivalent Re(1) and four equivalent P(2) atoms. In the second P site, P(2) is bonded in a 14-coordinate geometry to six equivalent Re(1) and eight equivalent P(1) atoms.
ReP3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. Re(1) is bonded in a distorted body-centered cubic geometry to six equivalent P(2) and eight equivalent P(1) atoms. All Re(1)-P(2) bond lengths are 3.01 Å. All Re(1)-P(1) bond lengths are 2.60 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a body-centered cubic geometry to four equivalent Re(1) and four equivalent P(2) atoms. All P(1)-P(2) bond lengths are 2.60 Å. In the second P site, P(2) is bonded in a 14-coordinate geometry to six equivalent Re(1) and eight equivalent P(1) atoms.