Cr2SbAs is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the hexagonal P-6m2 space group. Cr(1) is bonded to three equivalent Sb(1) and three equivalent As(1) atoms to form a mixture of distorted corner, face, and edge-sharing CrSb3As3 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. Sb(1) is bonded to six equivalent Cr(1) atoms to form distorted edge-sharing SbCr6 pentagonal pyramids. As(1) is bonded in a 6-coordinate geometry to six equivalent Cr(1) atoms.
Cr2SbAs is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the hexagonal P-6m2 space group. Cr(1) is bonded to three equivalent Sb(1) and three equivalent As(1) atoms to form a mixture of distorted corner, face, and edge-sharing CrSb3As3 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. All Cr(1)-Sb(1) bond lengths are 2.70 Å. All Cr(1)-As(1) bond lengths are 2.59 Å. Sb(1) is bonded to six equivalent Cr(1) atoms to form distorted edge-sharing SbCr6 pentagonal pyramids. As(1) is bonded in a 6-coordinate geometry to six equivalent Cr(1) atoms.