PdSCl is Copper structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PdSCl clusters. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a square co-planar geometry to one S(3), one S(4), one Cl(3), and one Cl(4) atom. In the second Pd site, Pd(2) is bonded in a rectangular see-saw-like geometry to one S(3), one S(4), one Cl(1), and one Cl(2) atom. In the third Pd site, Pd(3) is bonded in a rectangular see-saw-like geometry to one S(1), one S(2), one Cl(1), and one Cl(4) atom. In the fourth Pd site, Pd(4) is bonded in a square co-planar geometry to one S(1), one S(2), one Cl(2), and one Cl(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(3), one Pd(4), and one S(3) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Pd(3), one Pd(4), and one S(4) atom. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one Pd(2), and one S(1) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one Pd(2), and one S(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in an L-shaped geometry to one Pd(1) and one Pd(4) atom. In the second Cl site, Cl(1) is bonded in an L-shaped geometry to one Pd(2) and one Pd(3) atom. In the third Cl site, Cl(4) is bonded in an L-shaped geometry to one Pd(1) and one Pd(3) atom. In the fourth Cl site, Cl(2) is bonded in an L-shaped geometry to one Pd(2) and one Pd(4) atom.
PdSCl is Copper structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PdSCl clusters. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a square co-planar geometry to one S(3), one S(4), one Cl(3), and one Cl(4) atom. The Pd(1)-S(3) bond length is 2.29 Å. The Pd(1)-S(4) bond length is 2.28 Å. The Pd(1)-Cl(3) bond length is 2.38 Å. The Pd(1)-Cl(4) bond length is 2.37 Å. In the second Pd site, Pd(2) is bonded in a rectangular see-saw-like geometry to one S(3), one S(4), one Cl(1), and one Cl(2) atom. The Pd(2)-S(3) bond length is 2.28 Å. The Pd(2)-S(4) bond length is 2.28 Å. The Pd(2)-Cl(1) bond length is 2.37 Å. The Pd(2)-Cl(2) bond length is 2.38 Å. In the third Pd site, Pd(3) is bonded in a rectangular see-saw-like geometry to one S(1), one S(2), one Cl(1), and one Cl(4) atom. The Pd(3)-S(1) bond length is 2.28 Å. The Pd(3)-S(2) bond length is 2.28 Å. The Pd(3)-Cl(1) bond length is 2.37 Å. The Pd(3)-Cl(4) bond length is 2.37 Å. In the fourth Pd site, Pd(4) is bonded in a square co-planar geometry to one S(1), one S(2), one Cl(2), and one Cl(3) atom. The Pd(4)-S(1) bond length is 2.28 Å. The Pd(4)-S(2) bond length is 2.29 Å. The Pd(4)-Cl(2) bond length is 2.37 Å. The Pd(4)-Cl(3) bond length is 2.37 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(3), one Pd(4), and one S(3) atom. The S(1)-S(3) bond length is 2.11 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Pd(3), one Pd(4), and one S(4) atom. The S(2)-S(4) bond length is 2.11 Å. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one Pd(2), and one S(1) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one Pd(2), and one S(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in an L-shaped geometry to one Pd(1) and one Pd(4) atom. In the second Cl site, Cl(1) is bonded in an L-shaped geometry to one Pd(2) and one Pd(3) atom. In the third Cl site, Cl(4) is bonded in an L-shaped geometry to one Pd(1) and one Pd(3) atom. In the fourth Cl site, Cl(2) is bonded in an L-shaped geometry to one Pd(2) and one Pd(4) atom.