(PtN2Cl5)2N2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitroxyl molecules, and four PtN2Cl5 clusters. In each PtN2Cl5 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one Cl(1), one Cl(2), and one Cl(3) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(2) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom.
(PtN2Cl5)2N2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitroxyl molecules, and four PtN2Cl5 clusters. In each PtN2Cl5 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one Cl(1), one Cl(2), and one Cl(3) atom. The Pt(1)-N(1) bond length is 1.92 Å. The Pt(1)-N(2) bond length is 1.93 Å. The Pt(1)-Cl(1) bond length is 2.34 Å. The Pt(1)-Cl(2) bond length is 2.34 Å. The Pt(1)-Cl(3) bond length is 2.38 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(4) atom. The N(1)-Cl(4) bond length is 1.63 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Cl(5) atom. The N(2)-Cl(5) bond length is 1.67 Å. There are five inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(2) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom.