BaMoZnF7 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. Mo(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form MoF6 octahedra that share corners with three equivalent Zn(1)F6 octahedra and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form ZnF6 octahedra that share corners with three equivalent Mo(1)F6 octahedra and  an edgeedge with one Mo(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Mo(1), and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Mo(1), and one Zn(1) atom. In the third F site, F(3) is bonded to two equivalent Ba(1), one Mo(1), and one Zn(1) atom to form distorted corner-sharing FBa2ZnMo trigonal pyramids. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Mo(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Mo(1), and one Zn(1) atom. In the sixth F site, F(6) is bonded in a distorted water-like geometry to two equivalent Ba(1), one Mo(1), and one Zn(1) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Zn(1) atom.
BaMoZnF7 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. The Ba(1)-F(1) bond length is 3.14 Å. The Ba(1)-F(2) bond length is 3.03 Å. There is one shorter (2.91 Å) and one longer (3.03 Å) Ba(1)-F(3) bond length. There is one shorter (2.73 Å) and one longer (2.78 Å) Ba(1)-F(4) bond length. There is one shorter (3.03 Å) and one longer (3.30 Å) Ba(1)-F(5) bond length. Both Ba(1)-F(6) bond lengths are 3.09 Å. There is one shorter (2.68 Å) and one longer (2.69 Å) Ba(1)-F(7) bond length. Mo(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form MoF6 octahedra that share corners with three equivalent Zn(1)F6 octahedra and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. The Mo(1)-F(1) bond length is 2.10 Å. The Mo(1)-F(2) bond length is 2.10 Å. The Mo(1)-F(3) bond length is 2.12 Å. The Mo(1)-F(4) bond length is 2.07 Å. The Mo(1)-F(5) bond length is 2.13 Å. The Mo(1)-F(6) bond length is 2.12 Å. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form ZnF6 octahedra that share corners with three equivalent Mo(1)F6 octahedra and  an edgeedge with one Mo(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. The Zn(1)-F(1) bond length is 2.02 Å. The Zn(1)-F(2) bond length is 2.05 Å. The Zn(1)-F(3) bond length is 2.25 Å. The Zn(1)-F(5) bond length is 2.08 Å. The Zn(1)-F(6) bond length is 2.13 Å. The Zn(1)-F(7) bond length is 1.96 Å. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Mo(1), and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Mo(1), and one Zn(1) atom. In the third F site, F(3) is bonded to two equivalent Ba(1), one Mo(1), and one Zn(1) atom to form distorted corner-sharing FBa2ZnMo trigonal pyramids. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Mo(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Mo(1), and one Zn(1) atom. In the sixth F site, F(6) is bonded in a distorted water-like geometry to two equivalent Ba(1), one Mo(1), and one Zn(1) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Zn(1) atom.