KAgO crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of corner and edge-sharing OK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-11°.
KAgO crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (2.68 Å) and two longer (2.74 Å) K(1)-O(1) bond lengths. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.05 Å. O(1) is bonded to four equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of corner and edge-sharing OK4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-11°.