MnOF crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Mn(1) atoms.
MnOF crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. There are a spread of Mn(1)-O(1) bond distances ranging from 1.91-2.06 Å. There are a spread of Mn(1)-F(1) bond distances ranging from 2.04-2.42 Å. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Mn(1) atoms.