GdIr3B2 crystallizes in the hexagonal P6/mmm space group. Gd(1) is bonded in a 20-coordinate geometry to two equivalent Gd(1), twelve equivalent Ir(1), and six equivalent B(1) atoms. Ir(1) is bonded in a distorted square co-planar geometry to four equivalent Gd(1) and four equivalent B(1) atoms. B(1) is bonded in a 6-coordinate geometry to three equivalent Gd(1) and six equivalent Ir(1) atoms.
GdIr3B2 crystallizes in the hexagonal P6/mmm space group. Gd(1) is bonded in a 20-coordinate geometry to two equivalent Gd(1), twelve equivalent Ir(1), and six equivalent B(1) atoms. Both Gd(1)-Gd(1) bond lengths are 3.15 Å. All Gd(1)-Ir(1) bond lengths are 3.15 Å. All Gd(1)-B(1) bond lengths are 3.15 Å. Ir(1) is bonded in a distorted square co-planar geometry to four equivalent Gd(1) and four equivalent B(1) atoms. All Ir(1)-B(1) bond lengths are 2.23 Å. B(1) is bonded in a 6-coordinate geometry to three equivalent Gd(1) and six equivalent Ir(1) atoms.