CaSbO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ca(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 35-37°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ca(1) and two equivalent Sb(1) atoms to form distorted corner-sharing OCa2Sb2 tetrahedra. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Ca(1) and two equivalent Sb(1) atoms.
CaSbO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ca(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. There is one shorter (2.36 Å) and one longer (2.45 Å) Ca(1)-O(1) bond length. There are a spread of Ca(1)-O(2) bond distances ranging from 2.39-2.89 Å. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 35-37°. Both Sb(1)-O(1) bond lengths are 2.16 Å. All Sb(1)-O(2) bond lengths are 2.15 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ca(1) and two equivalent Sb(1) atoms to form distorted corner-sharing OCa2Sb2 tetrahedra. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Ca(1) and two equivalent Sb(1) atoms.