LiTiO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 2°. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 2°. O(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of corner and edge-sharing OLi3Ti3 octahedra. The corner-sharing octahedra are not tilted.
LiTiO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 2°. All Li(1)-O(1) bond lengths are 2.11 Å. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 2°. All Ti(1)-O(1) bond lengths are 2.04 Å. O(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of corner and edge-sharing OLi3Ti3 octahedra. The corner-sharing octahedra are not tilted.