MgMoF6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent F(1) atoms to form MgF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedral tilt angles are 36°. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Mg(1)F6 octahedra. The corner-sharing octahedral tilt angles are 36°. F(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(1) atom.
MgMoF6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent F(1) atoms to form MgF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedral tilt angles are 36°. All Mg(1)-F(1) bond lengths are 1.98 Å. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Mg(1)F6 octahedra. The corner-sharing octahedral tilt angles are 36°. All Mo(1)-F(1) bond lengths are 1.96 Å. F(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(1) atom.