FeZnF6 crystallizes in the trigonal R-3 space group. Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. F(1) is bonded in a bent 150 degrees geometry to one Fe(1) and one Zn(1) atom.
FeZnF6 crystallizes in the trigonal R-3 space group. Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. All Fe(1)-F(1) bond lengths are 1.85 Å. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles are 27°. All Zn(1)-F(1) bond lengths are 1.98 Å. F(1) is bonded in a bent 150 degrees geometry to one Fe(1) and one Zn(1) atom.