CN2S is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four aminothiocyanate molecules. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom.
CN2S is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four aminothiocyanate molecules. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(1)-N(2) bond length is 1.17 Å. The C(1)-S(1) bond length is 1.87 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. The N(1)-S(1) bond length is 1.48 Å. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom.