Sr2GdVO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Sr(1) is bonded to twelve equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Gd(1)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. Gd(1) is bonded to six equivalent O(1) atoms to form GdO6 octahedra that share corners with six equivalent V(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent Sr(1), one Gd(1), and one V(1) atom.
Sr2GdVO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Sr(1) is bonded to twelve equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Gd(1)O6 octahedra, and faces with four equivalent V(1)O6 octahedra. All Sr(1)-O(1) bond lengths are 2.93 Å. Gd(1) is bonded to six equivalent O(1) atoms to form GdO6 octahedra that share corners with six equivalent V(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Gd(1)-O(1) bond lengths are 2.23 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All V(1)-O(1) bond lengths are 1.90 Å. O(1) is bonded in a distorted linear geometry to four equivalent Sr(1), one Gd(1), and one V(1) atom.