MgLa10(Ga3O10)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Mg(1) is bonded to two equivalent O(13), two equivalent O(14), and two equivalent O(15) atoms to form MgO6 octahedra that share corners with two equivalent Ga(3)O6 octahedra, corners with two equivalent Ga(4)O6 octahedra, and corners with two equivalent Ga(5)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(15), one O(2), one O(6), one O(9), and two equivalent O(5) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(8), two equivalent O(3), and two equivalent O(7) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(14), one O(2), one O(6), one O(7), one O(8), and two equivalent O(9) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(14), one O(15), one O(3), one O(4), one O(6), and two equivalent O(10) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(14), one O(15), one O(4), one O(8), and two equivalent O(11) atoms. There are five inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(3) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-24°. In the second Ga site, Ga(2) is bonded to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-24°. In the third Ga site, Ga(3) is bonded to one O(1), one O(10), one O(11), one O(13), one O(4), and one O(7) atom to form GaO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra, corners with two equivalent Ga(2)O6 octahedra, and corners with three equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-24°. In the fourth Ga site, Ga(4) is bonded to one O(15), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, and corners with three equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-24°. In the fifth Ga site, Ga(5) is bonded to two equivalent O(12), two equivalent O(14), and two equivalent O(6) atoms to form GaO6 octahedra that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, and corners with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one La(2), one La(5), one Ga(1), and one Ga(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one La(2), one La(3), one Ga(1), and one Ga(4) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(4), two equivalent La(2), one Ga(1), and one Ga(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(2), one La(4), one La(5), one Ga(2), and one Ga(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(2), two equivalent La(1), one Ga(2), and one Ga(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one La(3), one La(4), one Ga(2), and one Ga(5) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(3), two equivalent La(2), one Ga(2), and one Ga(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(2), one La(3), one La(5), one Ga(2), and one Ga(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one La(1), two equivalent La(3), one Ga(2), and one Ga(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(3), two equivalent La(4), one Ga(1), and one Ga(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(4), two equivalent La(5), one Ga(1), and one Ga(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(1), one La(4), one La(5), one Ga(1), and one Ga(5) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(3), one La(5), and one Ga(3) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Mg(1), one La(3), one La(4), one La(5), and one Ga(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mg(1), one La(1), one La(4), one La(5), and one Ga(4) atom.
MgLa10(Ga3O10)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Mg(1) is bonded to two equivalent O(13), two equivalent O(14), and two equivalent O(15) atoms to form MgO6 octahedra that share corners with two equivalent Ga(3)O6 octahedra, corners with two equivalent Ga(4)O6 octahedra, and corners with two equivalent Ga(5)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. Both Mg(1)-O(13) bond lengths are 2.07 Å. Both Mg(1)-O(14) bond lengths are 2.07 Å. Both Mg(1)-O(15) bond lengths are 2.06 Å. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(15), one O(2), one O(6), one O(9), and two equivalent O(5) atoms. The La(1)-O(1) bond length is 2.78 Å. The La(1)-O(12) bond length is 2.80 Å. The La(1)-O(13) bond length is 2.40 Å. The La(1)-O(15) bond length is 2.74 Å. The La(1)-O(2) bond length is 2.80 Å. The La(1)-O(6) bond length is 2.42 Å. The La(1)-O(9) bond length is 2.76 Å. There is one shorter (2.41 Å) and one longer (2.88 Å) La(1)-O(5) bond length. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(8), two equivalent O(3), and two equivalent O(7) atoms. The La(2)-O(1) bond length is 2.41 Å. The La(2)-O(2) bond length is 2.84 Å. The La(2)-O(4) bond length is 2.76 Å. The La(2)-O(5) bond length is 2.74 Å. The La(2)-O(8) bond length is 2.77 Å. There is one shorter (2.40 Å) and one longer (2.76 Å) La(2)-O(3) bond length. There is one shorter (2.40 Å) and one longer (2.75 Å) La(2)-O(7) bond length. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(14), one O(2), one O(6), one O(7), one O(8), and two equivalent O(9) atoms. The La(3)-O(10) bond length is 2.81 Å. The La(3)-O(13) bond length is 2.79 Å. The La(3)-O(14) bond length is 2.40 Å. The La(3)-O(2) bond length is 2.42 Å. The La(3)-O(6) bond length is 2.86 Å. The La(3)-O(7) bond length is 2.85 Å. The La(3)-O(8) bond length is 2.84 Å. There is one shorter (2.42 Å) and one longer (2.87 Å) La(3)-O(9) bond length. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(14), one O(15), one O(3), one O(4), one O(6), and two equivalent O(10) atoms. The La(4)-O(11) bond length is 2.75 Å. The La(4)-O(12) bond length is 2.81 Å. The La(4)-O(14) bond length is 2.80 Å. The La(4)-O(15) bond length is 2.40 Å. The La(4)-O(3) bond length is 2.84 Å. The La(4)-O(4) bond length is 2.42 Å. The La(4)-O(6) bond length is 2.75 Å. There is one shorter (2.43 Å) and one longer (2.79 Å) La(4)-O(10) bond length. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(1), one O(12), one O(13), one O(14), one O(15), one O(4), one O(8), and two equivalent O(11) atoms. The La(5)-O(1) bond length is 2.86 Å. The La(5)-O(12) bond length is 2.41 Å. The La(5)-O(13) bond length is 2.74 Å. The La(5)-O(14) bond length is 2.74 Å. The La(5)-O(15) bond length is 2.80 Å. The La(5)-O(4) bond length is 2.88 Å. The La(5)-O(8) bond length is 2.41 Å. There is one shorter (2.41 Å) and one longer (2.89 Å) La(5)-O(11) bond length. There are five inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(3) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-24°. The Ga(1)-O(1) bond length is 2.01 Å. The Ga(1)-O(10) bond length is 2.02 Å. The Ga(1)-O(11) bond length is 2.02 Å. The Ga(1)-O(12) bond length is 1.98 Å. The Ga(1)-O(2) bond length is 2.03 Å. The Ga(1)-O(3) bond length is 2.00 Å. In the second Ga site, Ga(2) is bonded to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 23-24°. The Ga(2)-O(4) bond length is 2.03 Å. The Ga(2)-O(5) bond length is 2.02 Å. The Ga(2)-O(6) bond length is 1.99 Å. The Ga(2)-O(7) bond length is 2.01 Å. The Ga(2)-O(8) bond length is 2.00 Å. The Ga(2)-O(9) bond length is 2.00 Å. In the third Ga site, Ga(3) is bonded to one O(1), one O(10), one O(11), one O(13), one O(4), and one O(7) atom to form GaO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra, corners with two equivalent Ga(2)O6 octahedra, and corners with three equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-24°. The Ga(3)-O(1) bond length is 2.01 Å. The Ga(3)-O(10) bond length is 2.01 Å. The Ga(3)-O(11) bond length is 2.01 Å. The Ga(3)-O(13) bond length is 1.95 Å. The Ga(3)-O(4) bond length is 1.99 Å. The Ga(3)-O(7) bond length is 2.01 Å. In the fourth Ga site, Ga(4) is bonded to one O(15), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form GaO6 octahedra that share  a cornercorner with one Mg(1)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, and corners with three equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-24°. The Ga(4)-O(15) bond length is 1.98 Å. The Ga(4)-O(2) bond length is 1.99 Å. The Ga(4)-O(3) bond length is 2.03 Å. The Ga(4)-O(5) bond length is 2.01 Å. The Ga(4)-O(8) bond length is 2.04 Å. The Ga(4)-O(9) bond length is 2.04 Å. In the fifth Ga site, Ga(5) is bonded to two equivalent O(12), two equivalent O(14), and two equivalent O(6) atoms to form GaO6 octahedra that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, and corners with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-23°. Both Ga(5)-O(12) bond lengths are 2.05 Å. Both Ga(5)-O(14) bond lengths are 1.95 Å. Both Ga(5)-O(6) bond lengths are 2.04 Å. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one La(2), one La(5), one Ga(1), and one Ga(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one La(2), one La(3), one Ga(1), and one Ga(4) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(4), two equivalent La(2), one Ga(1), and one Ga(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(2), one La(4), one La(5), one Ga(2), and one Ga(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(2), two equivalent La(1), one Ga(2), and one Ga(4) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one La(3), one La(4), one Ga(2), and one Ga(5) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(3), two equivalent La(2), one Ga(2), and one Ga(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one La(2), one La(3), one La(5), one Ga(2), and one Ga(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one La(1), two equivalent La(3), one Ga(2), and one Ga(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(3), two equivalent La(4), one Ga(1), and one Ga(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(4), two equivalent La(5), one Ga(1), and one Ga(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one La(1), one La(4), one La(5), one Ga(1), and one Ga(5) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(3), one La(5), and one Ga(3) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Mg(1), one La(3), one La(4), one La(5), and one Ga(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mg(1), one La(1), one La(4), one La(5), and one Ga(4) atom.