Ag3C(NO2)3 crystallizes in the monoclinic Pc space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one C(1), one O(1), one O(2), one O(4), and two equivalent O(6) atoms. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one N(3), one O(1), one O(2), one O(3), and two equivalent O(5) atoms. In the third Ag site, Ag(3) is bonded in a linear geometry to one C(1) and one N(3) atom. C(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Ag(2), one Ag(3), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Ag(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Ag(2) and one N(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(2) atom.
Ag3C(NO2)3 crystallizes in the monoclinic Pc space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one C(1), one O(1), one O(2), one O(4), and two equivalent O(6) atoms. The Ag(1)-C(1) bond length is 2.65 Å. The Ag(1)-O(1) bond length is 2.63 Å. The Ag(1)-O(2) bond length is 2.55 Å. The Ag(1)-O(4) bond length is 2.70 Å. There is one shorter (2.49 Å) and one longer (2.63 Å) Ag(1)-O(6) bond length. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one N(3), one O(1), one O(2), one O(3), and two equivalent O(5) atoms. The Ag(2)-N(3) bond length is 2.69 Å. The Ag(2)-O(1) bond length is 2.54 Å. The Ag(2)-O(2) bond length is 2.64 Å. The Ag(2)-O(3) bond length is 2.68 Å. There is one shorter (2.47 Å) and one longer (2.63 Å) Ag(2)-O(5) bond length. In the third Ag site, Ag(3) is bonded in a linear geometry to one C(1) and one N(3) atom. The Ag(3)-C(1) bond length is 2.05 Å. The Ag(3)-N(3) bond length is 2.10 Å. C(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one N(3) atom. The C(1)-N(3) bond length is 1.18 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. The N(1)-O(1) bond length is 1.28 Å. The N(1)-O(3) bond length is 1.26 Å. The N(1)-O(5) bond length is 1.27 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. The N(2)-O(2) bond length is 1.28 Å. The N(2)-O(4) bond length is 1.26 Å. The N(2)-O(6) bond length is 1.28 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Ag(2), one Ag(3), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Ag(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Ag(2) and one N(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(2) atom.