Cs2MnCl6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent Cl(1) atoms to form CsCl12 cuboctahedra that share corners with twelve equivalent Cs(1)Cl12 cuboctahedra, faces with six equivalent Cs(1)Cl12 cuboctahedra, and faces with four equivalent Mn(1)Cl6 octahedra. Mn(1) is bonded to six equivalent Cl(1) atoms to form MnCl6 octahedra that share faces with eight equivalent Cs(1)Cl12 cuboctahedra. Cl(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mn(1) atom.
Cs2MnCl6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent Cl(1) atoms to form CsCl12 cuboctahedra that share corners with twelve equivalent Cs(1)Cl12 cuboctahedra, faces with six equivalent Cs(1)Cl12 cuboctahedra, and faces with four equivalent Mn(1)Cl6 octahedra. All Cs(1)-Cl(1) bond lengths are 3.64 Å. Mn(1) is bonded to six equivalent Cl(1) atoms to form MnCl6 octahedra that share faces with eight equivalent Cs(1)Cl12 cuboctahedra. All Mn(1)-Cl(1) bond lengths are 2.29 Å. Cl(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mn(1) atom.