BaSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Ba(1) is bonded to six equivalent O(1) atoms to form BaO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ba(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a distorted trigonal planar geometry to one Ba(1) and two equivalent Sb(1) atoms.
BaSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Ba(1) is bonded to six equivalent O(1) atoms to form BaO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Ba(1)-O(1) bond lengths are 2.72 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ba(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Sb(1)-O(1) bond lengths are 2.00 Å. O(1) is bonded in a distorted trigonal planar geometry to one Ba(1) and two equivalent Sb(1) atoms.