LiTbF2 crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. Tb(1) is bonded to six equivalent F(1) atoms to form distorted edge-sharing TbF6 octahedra. F(1) is bonded in a 5-coordinate geometry to two equivalent Li(1) and three equivalent Tb(1) atoms.
LiTbF2 crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All Li(1)-F(1) bond lengths are 2.50 Å. Tb(1) is bonded to six equivalent F(1) atoms to form distorted edge-sharing TbF6 octahedra. There are two shorter (2.37 Å) and four longer (2.39 Å) Tb(1)-F(1) bond lengths. F(1) is bonded in a 5-coordinate geometry to two equivalent Li(1) and three equivalent Tb(1) atoms.