XeBiF9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two XeBiF9 clusters. Xe(1) is bonded in a rectangular see-saw-like geometry to one F(2), one F(3), one F(5), and one F(6) atom. Bi(1) is bonded in an octahedral geometry to one F(1), one F(4), one F(5), one F(7), one F(8), and one F(9) atom. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Xe(1) and one Bi(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Bi(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Bi(1) atom.
XeBiF9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two XeBiF9 clusters. Xe(1) is bonded in a rectangular see-saw-like geometry to one F(2), one F(3), one F(5), and one F(6) atom. The Xe(1)-F(2) bond length is 2.00 Å. The Xe(1)-F(3) bond length is 1.95 Å. The Xe(1)-F(5) bond length is 2.20 Å. The Xe(1)-F(6) bond length is 1.99 Å. Bi(1) is bonded in an octahedral geometry to one F(1), one F(4), one F(5), one F(7), one F(8), and one F(9) atom. The Bi(1)-F(1) bond length is 2.01 Å. The Bi(1)-F(4) bond length is 2.00 Å. The Bi(1)-F(5) bond length is 2.19 Å. The Bi(1)-F(7) bond length is 2.01 Å. The Bi(1)-F(8) bond length is 2.01 Å. The Bi(1)-F(9) bond length is 2.01 Å. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Xe(1) and one Bi(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Bi(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Bi(1) atom.