P2O3F4 is Indium-like structured and crystallizes in the orthorhombic Pcca space group. The structure is zero-dimensional and consists of four pyrophosphoryl tetrafluoride molecules. P(1) is bonded to one O(1), one O(2), one F(1), and one F(2) atom to form corner-sharing PO2F2 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.
P2O3F4 is Indium-like structured and crystallizes in the orthorhombic Pcca space group. The structure is zero-dimensional and consists of four pyrophosphoryl tetrafluoride molecules. P(1) is bonded to one O(1), one O(2), one F(1), and one F(2) atom to form corner-sharing PO2F2 tetrahedra. The P(1)-O(1) bond length is 1.44 Å. The P(1)-O(2) bond length is 1.57 Å. The P(1)-F(1) bond length is 1.53 Å. The P(1)-F(2) bond length is 1.53 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.