Na4NO is Fluorite-derived structured and crystallizes in the tetragonal P4/mmm space group. Na(1) is bonded to two equivalent N(1) and two equivalent O(1) atoms to form a mixture of corner and edge-sharing NaN2O2 tetrahedra. N(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms. O(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms.
Na4NO is Fluorite-derived structured and crystallizes in the tetragonal P4/mmm space group. Na(1) is bonded to two equivalent N(1) and two equivalent O(1) atoms to form a mixture of corner and edge-sharing NaN2O2 tetrahedra. Both Na(1)-N(1) bond lengths are 2.53 Å. Both Na(1)-O(1) bond lengths are 2.45 Å. N(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms. O(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms.