C3SbPOCl5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four C3SbPOCl5 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(2) and one P(1) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one P(1) atom. Sb(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms. P(1) is bonded in a distorted single-bond geometry to one C(1), two equivalent C(2), and one O(1) atom. O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one P(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom.
C3SbPOCl5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four C3SbPOCl5 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(2) and one P(1) atom. Both C(1)-C(2) bond lengths are 1.63 Å. The C(1)-P(1) bond length is 1.71 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one P(1) atom. The C(2)-C(2) bond length is 1.42 Å. The C(2)-P(1) bond length is 1.84 Å. Sb(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms. The Sb(1)-O(1) bond length is 2.39 Å. The Sb(1)-Cl(1) bond length is 2.40 Å. The Sb(1)-Cl(2) bond length is 2.38 Å. The Sb(1)-Cl(3) bond length is 2.33 Å. Both Sb(1)-Cl(4) bond lengths are 2.38 Å. P(1) is bonded in a distorted single-bond geometry to one C(1), two equivalent C(2), and one O(1) atom. The P(1)-O(1) bond length is 1.50 Å. O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one P(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom.