Li2AgBi is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent Bi(1) atoms to form distorted LiBi4 tetrahedra that share corners with twelve equivalent Li(2)Ag4Bi6 tetrahedra, corners with twelve equivalent Li(1)Bi4 tetrahedra, and faces with four equivalent Li(2)Ag4Bi6 tetrahedra. In the second Li site, Li(2) is bonded to four equivalent Ag(1) and six equivalent Bi(1) atoms to form distorted LiAg4Bi6 tetrahedra that share corners with six equivalent Li(2)Ag4Bi6 tetrahedra, corners with twelve equivalent Li(1)Bi4 tetrahedra, faces with four equivalent Li(1)Bi4 tetrahedra, and faces with twelve equivalent Li(2)Ag4Bi6 tetrahedra. Ag(1) is bonded in a 8-coordinate geometry to four equivalent Li(2) and four equivalent Bi(1) atoms. Bi(1) is bonded in a 14-coordinate geometry to four equivalent Li(1), six equivalent Li(2), and four equivalent Ag(1) atoms.
Li2AgBi is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent Bi(1) atoms to form distorted LiBi4 tetrahedra that share corners with twelve equivalent Li(2)Ag4Bi6 tetrahedra, corners with twelve equivalent Li(1)Bi4 tetrahedra, and faces with four equivalent Li(2)Ag4Bi6 tetrahedra. All Li(1)-Bi(1) bond lengths are 2.94 Å. In the second Li site, Li(2) is bonded to four equivalent Ag(1) and six equivalent Bi(1) atoms to form distorted LiAg4Bi6 tetrahedra that share corners with six equivalent Li(2)Ag4Bi6 tetrahedra, corners with twelve equivalent Li(1)Bi4 tetrahedra, faces with four equivalent Li(1)Bi4 tetrahedra, and faces with twelve equivalent Li(2)Ag4Bi6 tetrahedra. All Li(2)-Ag(1) bond lengths are 2.94 Å. All Li(2)-Bi(1) bond lengths are 3.39 Å. Ag(1) is bonded in a 8-coordinate geometry to four equivalent Li(2) and four equivalent Bi(1) atoms. All Ag(1)-Bi(1) bond lengths are 2.94 Å. Bi(1) is bonded in a 14-coordinate geometry to four equivalent Li(1), six equivalent Li(2), and four equivalent Ag(1) atoms.