ReVO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Re(1)O6 octahedra, corners with two equivalent Re(3)O6 octahedra, corners with four equivalent Re(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Re(1)O6 octahedra, corners with two equivalent Re(3)O6 octahedra, corners with four equivalent Re(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(10), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. In the second Re site, Re(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(9) atom to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one Re(1)O6 octahedra, and  an edgeedge with one Re(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. In the third Re site, Re(3) is bonded to one O(7), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(2), one Re(2), and one Re(3) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(1), one Re(1), and one Re(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2), one Re(1), and one Re(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one Re(2), and one Re(3) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Re(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Re(3) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Re(3) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Re(1) atom.
ReVO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Re(1)O6 octahedra, corners with two equivalent Re(3)O6 octahedra, corners with four equivalent Re(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. The V(1)-O(10) bond length is 2.03 Å. The V(1)-O(2) bond length is 2.02 Å. The V(1)-O(4) bond length is 2.00 Å. The V(1)-O(6) bond length is 2.00 Å. The V(1)-O(7) bond length is 2.01 Å. The V(1)-O(9) bond length is 2.01 Å. In the second V site, V(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Re(1)O6 octahedra, corners with two equivalent Re(3)O6 octahedra, corners with four equivalent Re(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. The V(2)-O(1) bond length is 2.01 Å. The V(2)-O(3) bond length is 2.01 Å. The V(2)-O(5) bond length is 2.03 Å. The V(2)-O(6) bond length is 2.02 Å. The V(2)-O(8) bond length is 2.03 Å. The V(2)-O(9) bond length is 2.02 Å. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(10), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. The Re(1)-O(10) bond length is 1.91 Å. The Re(1)-O(5) bond length is 1.92 Å. Both Re(1)-O(2) bond lengths are 2.03 Å. Both Re(1)-O(3) bond lengths are 2.02 Å. In the second Re site, Re(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(9) atom to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one Re(1)O6 octahedra, and  an edgeedge with one Re(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. The Re(2)-O(1) bond length is 2.02 Å. The Re(2)-O(2) bond length is 2.02 Å. The Re(2)-O(3) bond length is 2.04 Å. The Re(2)-O(4) bond length is 2.03 Å. The Re(2)-O(6) bond length is 1.91 Å. The Re(2)-O(9) bond length is 1.91 Å. In the third Re site, Re(3) is bonded to one O(7), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. The Re(3)-O(7) bond length is 1.93 Å. The Re(3)-O(8) bond length is 1.92 Å. Both Re(3)-O(1) bond lengths are 2.04 Å. Both Re(3)-O(4) bond lengths are 2.03 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(2), one Re(2), and one Re(3) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(1), one Re(1), and one Re(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2), one Re(1), and one Re(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one Re(2), and one Re(3) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Re(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Re(3) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to two equivalent V(2) and one Re(3) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to two equivalent V(1) and one Re(1) atom.