(K)2TlAsBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlAsBr6 framework. In the TlAsBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Tl(1) and one As(1) atom.
(K)2TlAsBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlAsBr6 framework. In the TlAsBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 3.10 Å. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All As(1)-Br(1) bond lengths are 2.67 Å. Br(1) is bonded in a linear geometry to one Tl(1) and one As(1) atom.