MgCrF4 crystallizes in the orthorhombic Ibam space group. Mg(1) is bonded in a distorted body-centered cubic geometry to eight equivalent F(1) atoms. Cr(1) is bonded in a distorted square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a 3-coordinate geometry to two equivalent Mg(1) and one Cr(1) atom.
MgCrF4 crystallizes in the orthorhombic Ibam space group. Mg(1) is bonded in a distorted body-centered cubic geometry to eight equivalent F(1) atoms. There are four shorter (2.14 Å) and four longer (2.26 Å) Mg(1)-F(1) bond lengths. Cr(1) is bonded in a distorted square co-planar geometry to four equivalent F(1) atoms. All Cr(1)-F(1) bond lengths are 2.03 Å. F(1) is bonded in a 3-coordinate geometry to two equivalent Mg(1) and one Cr(1) atom.