LiAg(CO2)2 is Antimony trioxide-derived structured and crystallizes in the monoclinic Pc space group. Li(1) is bonded in a see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one C(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Li(1), two equivalent Ag(1), and one C(2) atom.
LiAg(CO2)2 is Antimony trioxide-derived structured and crystallizes in the monoclinic Pc space group. Li(1) is bonded in a see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Li(1)-O(1) bond length is 2.07 Å. The Li(1)-O(2) bond length is 1.96 Å. The Li(1)-O(3) bond length is 2.04 Å. The Li(1)-O(4) bond length is 2.02 Å. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. The Ag(1)-O(1) bond length is 2.43 Å. The Ag(1)-O(2) bond length is 2.30 Å. The Ag(1)-O(3) bond length is 2.43 Å. There is one shorter (2.70 Å) and one longer (2.80 Å) Ag(1)-O(4) bond length. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(2)-O(1) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one C(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ag(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Li(1), two equivalent Ag(1), and one C(2) atom.