WPd3 is beta Cu3Ti-like structured and crystallizes in the tetragonal I4/mmm space group. W(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form WPd12 cuboctahedra that share corners with four equivalent W(1)Pd12 cuboctahedra, corners with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with six equivalent Pd(2)Pd8W4 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent W(1), four equivalent Pd(1), and four equivalent Pd(2) atoms to form PdPd8W4 cuboctahedra that share corners with twelve equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, and faces with ten equivalent Pd(1)Pd8W4 cuboctahedra. In the second Pd site, Pd(2) is bonded to four equivalent W(1) and eight equivalent Pd(1) atoms to form PdPd8W4 cuboctahedra that share corners with four equivalent Pd(2)Pd8W4 cuboctahedra, corners with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, faces with six equivalent W(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra.
WPd3 is beta Cu3Ti-like structured and crystallizes in the tetragonal I4/mmm space group. W(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form WPd12 cuboctahedra that share corners with four equivalent W(1)Pd12 cuboctahedra, corners with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with six equivalent Pd(2)Pd8W4 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra. All W(1)-Pd(2) bond lengths are 2.72 Å. All W(1)-Pd(1) bond lengths are 2.78 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent W(1), four equivalent Pd(1), and four equivalent Pd(2) atoms to form PdPd8W4 cuboctahedra that share corners with twelve equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(1)Pd8W4 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, faces with four equivalent W(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, and faces with ten equivalent Pd(1)Pd8W4 cuboctahedra. All Pd(1)-Pd(1) bond lengths are 2.72 Å. All Pd(1)-Pd(2) bond lengths are 2.78 Å. In the second Pd site, Pd(2) is bonded to four equivalent W(1) and eight equivalent Pd(1) atoms to form PdPd8W4 cuboctahedra that share corners with four equivalent Pd(2)Pd8W4 cuboctahedra, corners with eight equivalent W(1)Pd12 cuboctahedra, edges with eight equivalent Pd(2)Pd8W4 cuboctahedra, edges with sixteen equivalent Pd(1)Pd8W4 cuboctahedra, faces with four equivalent Pd(2)Pd8W4 cuboctahedra, faces with six equivalent W(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)Pd8W4 cuboctahedra.