C3H9(NS)2Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen bromide atoms and one C3H9(NS)2 cluster. In the C3H9(NS)2 cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(4), one H(9), and one S(2) atom. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(6), one H(7), and one S(2) atom. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one H(2), one H(5), one H(8), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one C(3), one N(1), and one N(2) atom. In the second S site, S(2) is bonded in a distorted tetrahedral geometry to one C(1), one C(2), one N(1), and one N(2) atom.
C3H9(NS)2Br is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrogen bromide atoms and one C3H9(NS)2 cluster. In the C3H9(NS)2 cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(4), one H(9), and one S(2) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-H(9) bond length is 1.10 Å. The C(1)-S(2) bond length is 1.77 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(6), one H(7), and one S(2) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-H(7) bond length is 1.10 Å. The C(2)-S(2) bond length is 1.77 Å. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one H(2), one H(5), one H(8), and one S(1) atom. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(5) bond length is 1.09 Å. The C(3)-H(8) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.78 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.68 Å. The N(2)-S(2) bond length is 1.58 Å. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.66 Å. The N(1)-S(2) bond length is 1.59 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one C(3), one N(1), and one N(2) atom. In the second S site, S(2) is bonded in a distorted tetrahedral geometry to one C(1), one C(2), one N(1), and one N(2) atom.