PtO2 is Hydrophilite structured and crystallizes in the tetragonal P4_2/mnm space group. Pt(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing PtO6 octahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a trigonal planar geometry to three equivalent Pt(1) atoms.
PtO2 is Hydrophilite structured and crystallizes in the tetragonal P4_2/mnm space group. Pt(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing PtO6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two shorter (2.01 Å) and four longer (2.04 Å) Pt(1)-O(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent Pt(1) atoms.