MoBiO2 crystallizes in the tetragonal I4_1/amd space group. Mo(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. O(1) is bonded in a 5-coordinate geometry to two equivalent Mo(1) and three equivalent Bi(1) atoms.
MoBiO2 crystallizes in the tetragonal I4_1/amd space group. Mo(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Mo(1)-O(1) bond lengths are 2.24 Å. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. There are two shorter (2.45 Å) and four longer (2.62 Å) Bi(1)-O(1) bond lengths. O(1) is bonded in a 5-coordinate geometry to two equivalent Mo(1) and three equivalent Bi(1) atoms.