CsLi(NH2)2 crystallizes in the hexagonal P6_222 space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent H(1) atoms. Li(1) is bonded to four equivalent N(1) atoms to form distorted edge-sharing LiN4 trigonal pyramids. N(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom.
CsLi(NH2)2 crystallizes in the hexagonal P6_222 space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent H(1) atoms. All Cs(1)-H(1) bond lengths are 3.40 Å. Li(1) is bonded to four equivalent N(1) atoms to form distorted edge-sharing LiN4 trigonal pyramids. All Li(1)-N(1) bond lengths are 2.13 Å. N(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent H(1) atoms. Both N(1)-H(1) bond lengths are 1.03 Å. H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom.