V2MnO10 crystallizes in the monoclinic Cc space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(9), and two equivalent O(6) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(6), and two equivalent O(9) atoms. Mn(1) is bonded in a distorted octahedral geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(8) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(7) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the seventh O site, O(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(2) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one Mn(1) atom.
V2MnO10 crystallizes in the monoclinic Cc space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(9), and two equivalent O(6) atoms. The V(1)-O(3) bond length is 1.68 Å. The V(1)-O(5) bond length is 1.70 Å. The V(1)-O(9) bond length is 2.03 Å. There is one shorter (1.91 Å) and one longer (1.94 Å) V(1)-O(6) bond length. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(6), and two equivalent O(9) atoms. The V(2)-O(1) bond length is 1.68 Å. The V(2)-O(10) bond length is 1.70 Å. The V(2)-O(6) bond length is 2.03 Å. There is one shorter (1.91 Å) and one longer (1.95 Å) V(2)-O(9) bond length. Mn(1) is bonded in a distorted octahedral geometry to one O(1), one O(10), one O(3), one O(4), one O(5), and one O(8) atom. The Mn(1)-O(1) bond length is 2.11 Å. The Mn(1)-O(10) bond length is 2.03 Å. The Mn(1)-O(3) bond length is 2.12 Å. The Mn(1)-O(4) bond length is 2.70 Å. The Mn(1)-O(5) bond length is 2.03 Å. The Mn(1)-O(8) bond length is 2.30 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(8) atom. The O(2)-O(8) bond length is 1.24 Å. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(7) atom. The O(4)-O(7) bond length is 1.23 Å. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the seventh O site, O(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one O(2) atom. In the ninth O site, O(9) is bonded in a trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one Mn(1) atom.