PbFCl crystallizes in the monoclinic P2_1 space group. Pb(1) is bonded in a distorted linear geometry to four equivalent Cl(1) and two equivalent F(1) atoms. Cl(1) is bonded in a square co-planar geometry to four equivalent Pb(1) atoms. F(1) is bonded in a linear geometry to two equivalent Pb(1) atoms.
PbFCl crystallizes in the monoclinic P2_1 space group. Pb(1) is bonded in a distorted linear geometry to four equivalent Cl(1) and two equivalent F(1) atoms. There are a spread of Pb(1)-Cl(1) bond distances ranging from 2.95-3.01 Å. There is one shorter (2.34 Å) and one longer (2.41 Å) Pb(1)-F(1) bond length. Cl(1) is bonded in a square co-planar geometry to four equivalent Pb(1) atoms. F(1) is bonded in a linear geometry to two equivalent Pb(1) atoms.