Ti2ZnS4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ti(1) is bonded to six equivalent S(1) atoms to form TiS6 octahedra that share corners with six equivalent Zn(1)S4 tetrahedra and edges with six equivalent Ti(1)S6 octahedra. Zn(1) is bonded to four equivalent S(1) atoms to form ZnS4 tetrahedra that share corners with twelve equivalent Ti(1)S6 octahedra. The corner-sharing octahedral tilt angles are 57°. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ti(1) and one Zn(1) atom.
Ti2ZnS4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ti(1) is bonded to six equivalent S(1) atoms to form TiS6 octahedra that share corners with six equivalent Zn(1)S4 tetrahedra and edges with six equivalent Ti(1)S6 octahedra. All Ti(1)-S(1) bond lengths are 2.47 Å. Zn(1) is bonded to four equivalent S(1) atoms to form ZnS4 tetrahedra that share corners with twelve equivalent Ti(1)S6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Zn(1)-S(1) bond lengths are 2.32 Å. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ti(1) and one Zn(1) atom.