DyRhBi crystallizes in the hexagonal P-62m space group. Dy(1) is bonded in a 11-coordinate geometry to one Rh(2), four equivalent Rh(1), and six equivalent Bi(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent Dy(1) and three equivalent Bi(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to three equivalent Dy(1) and six equivalent Bi(1) atoms. Bi(1) is bonded in a 10-coordinate geometry to six equivalent Dy(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.
DyRhBi crystallizes in the hexagonal P-62m space group. Dy(1) is bonded in a 11-coordinate geometry to one Rh(2), four equivalent Rh(1), and six equivalent Bi(1) atoms. The Dy(1)-Rh(2) bond length is 3.04 Å. All Dy(1)-Rh(1) bond lengths are 3.06 Å. There are two shorter (3.23 Å) and four longer (3.34 Å) Dy(1)-Bi(1) bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent Dy(1) and three equivalent Bi(1) atoms. All Rh(1)-Bi(1) bond lengths are 2.83 Å. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to three equivalent Dy(1) and six equivalent Bi(1) atoms. All Rh(2)-Bi(1) bond lengths are 2.84 Å. Bi(1) is bonded in a 10-coordinate geometry to six equivalent Dy(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.