P3N4Cl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two P3N4Cl5 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(3), one Cl(1), and one Cl(2) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one Cl(3), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. In the third P site, P(3) is bonded to one N(2), one N(3), one N(4), and one Cl(5) atom to form corner-sharing PN3Cl tetrahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one P(3) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(3) atom.
P3N4Cl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two P3N4Cl5 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(3), one Cl(1), and one Cl(2) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. The P(1)-N(1) bond length is 1.59 Å. The P(1)-N(3) bond length is 1.60 Å. The P(1)-Cl(1) bond length is 2.02 Å. The P(1)-Cl(2) bond length is 2.02 Å. In the second P site, P(2) is bonded to one N(1), one N(2), one Cl(3), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. The P(2)-N(1) bond length is 1.60 Å. The P(2)-N(2) bond length is 1.60 Å. The P(2)-Cl(3) bond length is 2.02 Å. The P(2)-Cl(4) bond length is 2.01 Å. In the third P site, P(3) is bonded to one N(2), one N(3), one N(4), and one Cl(5) atom to form corner-sharing PN3Cl tetrahedra. The P(3)-N(2) bond length is 1.60 Å. The P(3)-N(3) bond length is 1.61 Å. The P(3)-N(4) bond length is 1.69 Å. The P(3)-Cl(5) bond length is 2.02 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one P(3) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(3) atom.