(NO)2NO2(SeO2)2SeO4 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two nitrous acid molecules, four nitroxyl molecules, four SeO2 clusters, and two SeO4 clusters. In each SeO2 cluster, Se(1) is bonded in a bent 120 degrees geometry to two equivalent O(3,4) atoms. O(3,4) is bonded in a single-bond geometry to one Se(1) atom. In each SeO4 cluster, Se(2) is bonded in a tetrahedral geometry to two equivalent O(5) and two equivalent O(6) atoms. There are two inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Se(2) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Se(2) atom.
(NO)2NO2(SeO2)2SeO4 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two nitrous acid molecules, four nitroxyl molecules, four SeO2 clusters, and two SeO4 clusters. In each SeO2 cluster, Se(1) is bonded in a bent 120 degrees geometry to two equivalent O(3,4) atoms. Both Se(1)-O(3,4) bond lengths are 1.64 Å. O(3,4) is bonded in a single-bond geometry to one Se(1) atom. In each SeO4 cluster, Se(2) is bonded in a tetrahedral geometry to two equivalent O(5) and two equivalent O(6) atoms. Both Se(2)-O(5) bond lengths are 1.69 Å. Both Se(2)-O(6) bond lengths are 1.69 Å. There are two inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Se(2) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Se(2) atom.