LiSbO3 is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Sb(1) is bonded to six equivalent O(1) atoms to form distorted corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 46°. O(1) is bonded to two equivalent Li(1) and two equivalent Sb(1) atoms to form a mixture of distorted corner and edge-sharing OLi2Sb2 trigonal pyramids.
LiSbO3 is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.03 Å) and three longer (2.22 Å) Li(1)-O(1) bond lengths. Sb(1) is bonded to six equivalent O(1) atoms to form distorted corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 46°. There are three shorter (2.02 Å) and three longer (2.03 Å) Sb(1)-O(1) bond lengths. O(1) is bonded to two equivalent Li(1) and two equivalent Sb(1) atoms to form a mixture of distorted corner and edge-sharing OLi2Sb2 trigonal pyramids.