Pd3F is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to four equivalent Pd(2) and four equivalent F(1) atoms. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to eight equivalent Pd(1) atoms. F(1) is bonded in a body-centered cubic geometry to eight equivalent Pd(1) atoms.
Pd3F is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to four equivalent Pd(2) and four equivalent F(1) atoms. All Pd(1)-Pd(2) bond lengths are 2.68 Å. All Pd(1)-F(1) bond lengths are 2.68 Å. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to eight equivalent Pd(1) atoms. F(1) is bonded in a body-centered cubic geometry to eight equivalent Pd(1) atoms.