Rb2Pd3S4 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(2), four equivalent Pd(1), and eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pd(2), and two equivalent Pd(1) atoms.
Rb2Pd3S4 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(2), four equivalent Pd(1), and eight equivalent S(1) atoms. Both Rb(1)-Pd(2) bond lengths are 3.80 Å. All Rb(1)-Pd(1) bond lengths are 3.75 Å. There are a spread of Rb(1)-S(1) bond distances ranging from 3.56-3.66 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. All Pd(1)-S(1) bond lengths are 2.36 Å. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. All Pd(2)-S(1) bond lengths are 2.35 Å. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pd(2), and two equivalent Pd(1) atoms.