Co7(RuO6)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(20), one O(22), one O(23), one O(3), and one O(5) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. In the second Ru site, Ru(2) is bonded to one O(12), one O(2), one O(22), one O(24), one O(4), and one O(9) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. In the third Ru site, Ru(3) is bonded to one O(13), one O(14), one O(15), one O(16), one O(18), and one O(19) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. In the fourth Ru site, Ru(4) is bonded to one O(10), one O(15), one O(17), one O(19), one O(7), and one O(8) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. There are fourteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(16), one O(2), and one O(5) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. In the second Co site, Co(2) is bonded to one O(1), one O(13), one O(14), one O(17), one O(18), and one O(19) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Ru(3)O6 octahedra. In the third Co site, Co(3) is bonded to one O(2), one O(20), one O(21), one O(23), one O(4), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Ru(1)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(11), one O(22), one O(4), and one O(7) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, and corners with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the fifth Co site, Co(5) is bonded to one O(22), one O(24), one O(4), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(2)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(10), one O(11), one O(12), one O(24), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. In the seventh Co site, Co(7) is bonded to one O(10), one O(14), one O(18), and one O(8) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-60°. In the eighth Co site, Co(8) is bonded to one O(11), one O(12), one O(6), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. In the ninth Co site, Co(9) is bonded to one O(10), one O(11), one O(13), one O(15), one O(17), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(4)O6 octahedra. In the tenth Co site, Co(10) is bonded to one O(12), one O(15), one O(17), and one O(6) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, corners with two equivalent Co(8)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the eleventh Co site, Co(11) is bonded to one O(1), one O(16), one O(18), one O(20), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(13)O6 octahedra. In the twelfth Co site, Co(12) is bonded to one O(13), one O(19), one O(21), and one O(3) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(14), one O(16), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(11)O6 octahedra. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(23), one O(24), and one O(9) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(11), one Co(13), and one Co(2) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(1), and one Co(3) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Ru(1), one Co(11), one Co(12), and one Co(13) atom. In the fourth O site, O(4) is bonded to one Ru(2), one Co(3), one Co(4), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the fifth O site, O(5) is bonded to one Ru(1), one Co(1), one Co(3), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Co(10), one Co(5), one Co(6), and one Co(8) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Ru(4), one Co(4), one Co(6), and one Co(8) atom. In the eighth O site, O(8) is bonded to one Ru(4), one Co(7), one Co(8), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the ninth O site, O(9) is bonded to one Ru(2), one Co(14), one Co(5), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the tenth O site, O(10) is bonded to one Ru(4), one Co(6), one Co(7), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(4), one Co(6), one Co(8), and one Co(9) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Ru(2), one Co(10), one Co(6), and one Co(8) atom. In the thirteenth O site, O(13) is bonded to one Ru(3), one Co(12), one Co(2), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the fourteenth O site, O(14) is bonded to one Ru(3), one Co(13), one Co(2), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(10), and one Co(9) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Ru(3), one Co(1), one Co(11), and one Co(13) atom. In the seventeenth O site, O(17) is bonded to one Ru(4), one Co(10), one Co(2), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Ru(3), one Co(11), one Co(2), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(12), and one Co(2) atom. In the twentieth O site, O(20) is bonded to one Ru(1), one Co(11), one Co(14), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Co(11), one Co(12), one Co(13), and one Co(3) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(4), and one Co(5) atom. In the twenty-third O site, O(23) is bonded to one Ru(1), one Co(13), one Co(14), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the twenty-fourth O site, O(24) is bonded to one Ru(2), one Co(14), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids.
Co7(RuO6)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(20), one O(22), one O(23), one O(3), and one O(5) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The Ru(1)-O(2) bond length is 2.04 Å. The Ru(1)-O(20) bond length is 2.08 Å. The Ru(1)-O(22) bond length is 2.04 Å. The Ru(1)-O(23) bond length is 2.05 Å. The Ru(1)-O(3) bond length is 2.04 Å. The Ru(1)-O(5) bond length is 2.07 Å. In the second Ru site, Ru(2) is bonded to one O(12), one O(2), one O(22), one O(24), one O(4), and one O(9) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The Ru(2)-O(12) bond length is 2.04 Å. The Ru(2)-O(2) bond length is 2.04 Å. The Ru(2)-O(22) bond length is 2.04 Å. The Ru(2)-O(24) bond length is 2.08 Å. The Ru(2)-O(4) bond length is 2.07 Å. The Ru(2)-O(9) bond length is 2.05 Å. In the third Ru site, Ru(3) is bonded to one O(13), one O(14), one O(15), one O(16), one O(18), and one O(19) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The Ru(3)-O(13) bond length is 2.07 Å. The Ru(3)-O(14) bond length is 2.05 Å. The Ru(3)-O(15) bond length is 2.04 Å. The Ru(3)-O(16) bond length is 2.04 Å. The Ru(3)-O(18) bond length is 2.07 Å. The Ru(3)-O(19) bond length is 2.04 Å. In the fourth Ru site, Ru(4) is bonded to one O(10), one O(15), one O(17), one O(19), one O(7), and one O(8) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The Ru(4)-O(10) bond length is 2.07 Å. The Ru(4)-O(15) bond length is 2.04 Å. The Ru(4)-O(17) bond length is 2.07 Å. The Ru(4)-O(19) bond length is 2.04 Å. The Ru(4)-O(7) bond length is 2.04 Å. The Ru(4)-O(8) bond length is 2.05 Å. There are fourteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(16), one O(2), and one O(5) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. The Co(1)-O(1) bond length is 1.93 Å. The Co(1)-O(16) bond length is 1.95 Å. The Co(1)-O(2) bond length is 1.96 Å. The Co(1)-O(5) bond length is 1.94 Å. In the second Co site, Co(2) is bonded to one O(1), one O(13), one O(14), one O(17), one O(18), and one O(19) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Ru(3)O6 octahedra. The Co(2)-O(1) bond length is 1.94 Å. The Co(2)-O(13) bond length is 1.96 Å. The Co(2)-O(14) bond length is 1.93 Å. The Co(2)-O(17) bond length is 1.96 Å. The Co(2)-O(18) bond length is 1.95 Å. The Co(2)-O(19) bond length is 1.97 Å. In the third Co site, Co(3) is bonded to one O(2), one O(20), one O(21), one O(23), one O(4), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Ru(1)O6 octahedra. The Co(3)-O(2) bond length is 1.96 Å. The Co(3)-O(20) bond length is 1.95 Å. The Co(3)-O(21) bond length is 1.95 Å. The Co(3)-O(23) bond length is 1.94 Å. The Co(3)-O(4) bond length is 1.97 Å. The Co(3)-O(5) bond length is 1.96 Å. In the fourth Co site, Co(4) is bonded to one O(11), one O(22), one O(4), and one O(7) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, and corners with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. The Co(4)-O(11) bond length is 1.93 Å. The Co(4)-O(22) bond length is 1.96 Å. The Co(4)-O(4) bond length is 1.94 Å. The Co(4)-O(7) bond length is 1.95 Å. In the fifth Co site, Co(5) is bonded to one O(22), one O(24), one O(4), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(2)O6 octahedra. The Co(5)-O(22) bond length is 1.96 Å. The Co(5)-O(24) bond length is 1.95 Å. The Co(5)-O(4) bond length is 1.96 Å. The Co(5)-O(5) bond length is 1.96 Å. The Co(5)-O(6) bond length is 1.94 Å. The Co(5)-O(9) bond length is 1.94 Å. In the sixth Co site, Co(6) is bonded to one O(10), one O(11), one O(12), one O(24), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The Co(6)-O(10) bond length is 1.95 Å. The Co(6)-O(11) bond length is 1.96 Å. The Co(6)-O(12) bond length is 1.97 Å. The Co(6)-O(24) bond length is 1.95 Å. The Co(6)-O(6) bond length is 1.96 Å. The Co(6)-O(7) bond length is 1.97 Å. In the seventh Co site, Co(7) is bonded to one O(10), one O(14), one O(18), and one O(8) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-60°. The Co(7)-O(10) bond length is 1.93 Å. The Co(7)-O(14) bond length is 1.95 Å. The Co(7)-O(18) bond length is 1.93 Å. The Co(7)-O(8) bond length is 1.96 Å. In the eighth Co site, Co(8) is bonded to one O(11), one O(12), one O(6), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The Co(8)-O(11) bond length is 1.96 Å. The Co(8)-O(12) bond length is 1.96 Å. The Co(8)-O(6) bond length is 1.96 Å. The Co(8)-O(7) bond length is 1.96 Å. The Co(8)-O(8) bond length is 1.97 Å. The Co(8)-O(9) bond length is 1.97 Å. In the ninth Co site, Co(9) is bonded to one O(10), one O(11), one O(13), one O(15), one O(17), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(4)O6 octahedra. The Co(9)-O(10) bond length is 1.95 Å. The Co(9)-O(11) bond length is 1.95 Å. The Co(9)-O(13) bond length is 1.96 Å. The Co(9)-O(15) bond length is 1.97 Å. The Co(9)-O(17) bond length is 1.96 Å. The Co(9)-O(8) bond length is 1.93 Å. In the tenth Co site, Co(10) is bonded to one O(12), one O(15), one O(17), and one O(6) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, corners with two equivalent Co(8)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. The Co(10)-O(12) bond length is 1.95 Å. The Co(10)-O(15) bond length is 1.96 Å. The Co(10)-O(17) bond length is 1.93 Å. The Co(10)-O(6) bond length is 1.93 Å. In the eleventh Co site, Co(11) is bonded to one O(1), one O(16), one O(18), one O(20), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(13)O6 octahedra. The Co(11)-O(1) bond length is 1.96 Å. The Co(11)-O(16) bond length is 1.98 Å. The Co(11)-O(18) bond length is 1.95 Å. The Co(11)-O(20) bond length is 1.95 Å. The Co(11)-O(21) bond length is 1.96 Å. The Co(11)-O(3) bond length is 1.98 Å. In the twelfth Co site, Co(12) is bonded to one O(13), one O(19), one O(21), and one O(3) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. The Co(12)-O(13) bond length is 1.93 Å. The Co(12)-O(19) bond length is 1.96 Å. The Co(12)-O(21) bond length is 1.93 Å. The Co(12)-O(3) bond length is 1.95 Å. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(14), one O(16), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(11)O6 octahedra. The Co(13)-O(1) bond length is 1.96 Å. The Co(13)-O(14) bond length is 1.97 Å. The Co(13)-O(16) bond length is 1.96 Å. The Co(13)-O(21) bond length is 1.96 Å. The Co(13)-O(23) bond length is 1.97 Å. The Co(13)-O(3) bond length is 1.96 Å. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(23), one O(24), and one O(9) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. The Co(14)-O(20) bond length is 1.93 Å. The Co(14)-O(23) bond length is 1.96 Å. The Co(14)-O(24) bond length is 1.93 Å. The Co(14)-O(9) bond length is 1.96 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(11), one Co(13), and one Co(2) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(1), and one Co(3) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Ru(1), one Co(11), one Co(12), and one Co(13) atom. In the fourth O site, O(4) is bonded to one Ru(2), one Co(3), one Co(4), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the fifth O site, O(5) is bonded to one Ru(1), one Co(1), one Co(3), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Co(10), one Co(5), one Co(6), and one Co(8) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Ru(4), one Co(4), one Co(6), and one Co(8) atom. In the eighth O site, O(8) is bonded to one Ru(4), one Co(7), one Co(8), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the ninth O site, O(9) is bonded to one Ru(2), one Co(14), one Co(5), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the tenth O site, O(10) is bonded to one Ru(4), one Co(6), one Co(7), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(4), one Co(6), one Co(8), and one Co(9) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Ru(2), one Co(10), one Co(6), and one Co(8) atom. In the thirteenth O site, O(13) is bonded to one Ru(3), one Co(12), one Co(2), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the fourteenth O site, O(14) is bonded to one Ru(3), one Co(13), one Co(2), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(10), and one Co(9) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Ru(3), one Co(1), one Co(11), and one Co(13) atom. In the seventeenth O site, O(17) is bonded to one Ru(4), one Co(10), one Co(2), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the eighteenth O site, O(18) is bonded to one Ru(3), one Co(11), one Co(2), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(12), and one Co(2) atom. In the twentieth O site, O(20) is bonded to one Ru(1), one Co(11), one Co(14), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Co(11), one Co(12), one Co(13), and one Co(3) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(4), and one Co(5) atom. In the twenty-third O site, O(23) is bonded to one Ru(1), one Co(13), one Co(14), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids. In the twenty-fourth O site, O(24) is bonded to one Ru(2), one Co(14), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OCo3Ru trigonal pyramids.