WAlB crystallizes in the orthorhombic Cmcm space group. W(1) is bonded in a 11-coordinate geometry to five equivalent Al(1) and six equivalent B(1) atoms. Al(1) is bonded in a 10-coordinate geometry to five equivalent W(1), four equivalent Al(1), and one B(1) atom. B(1) is bonded in a 9-coordinate geometry to six equivalent W(1), one Al(1), and two equivalent B(1) atoms.
WAlB crystallizes in the orthorhombic Cmcm space group. W(1) is bonded in a 11-coordinate geometry to five equivalent Al(1) and six equivalent B(1) atoms. There are four shorter (2.70 Å) and one longer (2.92 Å) W(1)-Al(1) bond length. All W(1)-B(1) bond lengths are 2.36 Å. Al(1) is bonded in a 10-coordinate geometry to five equivalent W(1), four equivalent Al(1), and one B(1) atom. All Al(1)-Al(1) bond lengths are 2.63 Å. The Al(1)-B(1) bond length is 2.30 Å. B(1) is bonded in a 9-coordinate geometry to six equivalent W(1), one Al(1), and two equivalent B(1) atoms. Both B(1)-B(1) bond lengths are 1.83 Å.