Cs2CrF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Cr(1)F6 octahedra. Cr(1) is bonded to six equivalent F(1) atoms to form CrF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Cr(1) atom.
Cs2CrF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Cr(1)F6 octahedra. All Cs(1)-F(1) bond lengths are 3.27 Å. Cr(1) is bonded to six equivalent F(1) atoms to form CrF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. All Cr(1)-F(1) bond lengths are 1.87 Å. F(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Cr(1) atom.