Rh2TeO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Rh(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. Te(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form TeO6 octahedra that share corners with eight equivalent Rh(1)O6 octahedra and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom.
Rh2TeO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Rh(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. Both Rh(1)-O(1) bond lengths are 2.04 Å. There are two shorter (2.02 Å) and two longer (2.04 Å) Rh(1)-O(2) bond lengths. Te(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form TeO6 octahedra that share corners with eight equivalent Rh(1)O6 octahedra and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. Both Te(1)-O(1) bond lengths are 2.05 Å. All Te(1)-O(2) bond lengths are 2.05 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom.