LiV2O2F3 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a distorted linear geometry to two equivalent F(1) and two equivalent F(2) atoms. V(1) is bonded to three equivalent O(1), one F(1), and two equivalent F(2) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Li(1) and two equivalent V(1) atoms to form distorted corner-sharing FLi2V2 tetrahedra. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent V(1) atoms.
LiV2O2F3 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a distorted linear geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Li(1)-F(1) bond lengths are 2.44 Å. Both Li(1)-F(2) bond lengths are 1.78 Å. V(1) is bonded to three equivalent O(1), one F(1), and two equivalent F(2) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are a spread of V(1)-O(1) bond distances ranging from 1.95-2.03 Å. The V(1)-F(1) bond length is 2.12 Å. There is one shorter (2.03 Å) and one longer (2.11 Å) V(1)-F(2) bond length. O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Li(1) and two equivalent V(1) atoms to form distorted corner-sharing FLi2V2 tetrahedra. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent V(1) atoms.