PtN3S4Cl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtN3S4Cl clusters. Pt(1) is bonded in a square co-planar geometry to one N(2), two equivalent S(1), and one Cl(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one N(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.
PtN3S4Cl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtN3S4Cl clusters. Pt(1) is bonded in a square co-planar geometry to one N(2), two equivalent S(1), and one Cl(1) atom. The Pt(1)-N(2) bond length is 1.99 Å. Both Pt(1)-S(1) bond lengths are 2.26 Å. The Pt(1)-Cl(1) bond length is 2.33 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.63 Å. The N(1)-S(2) bond length is 1.57 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent S(2) atoms. Both N(2)-S(2) bond lengths are 1.69 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one N(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.