AgSbSeS is alpha Po-derived structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to four equivalent Se(1) and two equivalent S(1) atoms to form AgSe4S2 octahedra that share corners with six equivalent Ag(1)Se4S2 octahedra, edges with four equivalent Ag(1)Se4S2 octahedra, and edges with eight equivalent Sb(1)Se2S4 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to two equivalent Se(1) and four equivalent S(1) atoms to form SbSe2S4 octahedra that share corners with six equivalent Sb(1)Se2S4 octahedra, edges with four equivalent Sb(1)Se2S4 octahedra, and edges with eight equivalent Ag(1)Se4S2 octahedra. The corner-sharing octahedra are not tilted. Se(1) is bonded to four equivalent Ag(1) and two equivalent Sb(1) atoms to form SeAg4Sb2 octahedra that share corners with six equivalent Se(1)Ag4Sb2 octahedra, edges with four equivalent Se(1)Ag4Sb2 octahedra, and edges with eight equivalent S(1)Ag2Sb4 octahedra. The corner-sharing octahedra are not tilted. S(1) is bonded to two equivalent Ag(1) and four equivalent Sb(1) atoms to form SAg2Sb4 octahedra that share corners with six equivalent S(1)Ag2Sb4 octahedra, edges with four equivalent S(1)Ag2Sb4 octahedra, and edges with eight equivalent Se(1)Ag4Sb2 octahedra. The corner-sharing octahedra are not tilted.
AgSbSeS is alpha Po-derived structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to four equivalent Se(1) and two equivalent S(1) atoms to form AgSe4S2 octahedra that share corners with six equivalent Ag(1)Se4S2 octahedra, edges with four equivalent Ag(1)Se4S2 octahedra, and edges with eight equivalent Sb(1)Se2S4 octahedra. The corner-sharing octahedra are not tilted. All Ag(1)-Se(1) bond lengths are 2.80 Å. Both Ag(1)-S(1) bond lengths are 2.89 Å. Sb(1) is bonded to two equivalent Se(1) and four equivalent S(1) atoms to form SbSe2S4 octahedra that share corners with six equivalent Sb(1)Se2S4 octahedra, edges with four equivalent Sb(1)Se2S4 octahedra, and edges with eight equivalent Ag(1)Se4S2 octahedra. The corner-sharing octahedra are not tilted. Both Sb(1)-Se(1) bond lengths are 2.89 Å. All Sb(1)-S(1) bond lengths are 2.80 Å. Se(1) is bonded to four equivalent Ag(1) and two equivalent Sb(1) atoms to form SeAg4Sb2 octahedra that share corners with six equivalent Se(1)Ag4Sb2 octahedra, edges with four equivalent Se(1)Ag4Sb2 octahedra, and edges with eight equivalent S(1)Ag2Sb4 octahedra. The corner-sharing octahedra are not tilted. S(1) is bonded to two equivalent Ag(1) and four equivalent Sb(1) atoms to form SAg2Sb4 octahedra that share corners with six equivalent S(1)Ag2Sb4 octahedra, edges with four equivalent S(1)Ag2Sb4 octahedra, and edges with eight equivalent Se(1)Ag4Sb2 octahedra. The corner-sharing octahedra are not tilted.