TbVO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Tb(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 35-37°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Tb(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded to two equivalent Tb(1) and two equivalent V(1) atoms to form distorted corner-sharing OTb2V2 trigonal pyramids.
TbVO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Tb(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.24 Å) and one longer (2.31 Å) Tb(1)-O(2) bond length. There are a spread of Tb(1)-O(1) bond distances ranging from 2.28-2.66 Å. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 35-37°. Both V(1)-O(2) bond lengths are 1.99 Å. There are two shorter (1.98 Å) and two longer (2.08 Å) V(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Tb(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded to two equivalent Tb(1) and two equivalent V(1) atoms to form distorted corner-sharing OTb2V2 trigonal pyramids.