OsF6 is beta Np structured and crystallizes in the orthorhombic Pmc2_1 space group. The structure is zero-dimensional and consists of four osmium hexafluoride molecules. Os(1,2) is bonded in an octahedral geometry to one F(3), one F(7), two equivalent F(2), and two equivalent F(5) atoms. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Os(1,2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Os(1,2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Os(1,2) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Os(1,2) atom.
OsF6 is beta Np structured and crystallizes in the orthorhombic Pmc2_1 space group. The structure is zero-dimensional and consists of four osmium hexafluoride molecules. Os(1,2) is bonded in an octahedral geometry to one F(3), one F(7), two equivalent F(2), and two equivalent F(5) atoms. The Os(1,2)-F(3) bond length is 1.87 Å. The Os(1,2)-F(7) bond length is 1.86 Å. Both Os(1,2)-F(2) bond lengths are 1.85 Å. Both Os(1,2)-F(5) bond lengths are 1.85 Å. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Os(1,2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Os(1,2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Os(1,2) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Os(1,2) atom.