MgTi4Zn2O10 crystallizes in the orthorhombic Pmm2 space group. Mg(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(6) atoms. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form distorted corner-sharing TiO5 trigonal bipyramids. In the second Ti site, Ti(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(6), and two equivalent O(4) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(5) atoms. In the second Zn site, Zn(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(1) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), two equivalent Ti(2), and two equivalent Zn(2) atoms. In the second O site, O(2) is bonded to two equivalent Ti(1) and two equivalent Zn(1) atoms to form corner-sharing OTi2Zn2 tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2) and two equivalent Ti(1) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Ti(1) and two equivalent Ti(2) atoms. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Ti(1) and two equivalent Zn(1) atoms. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mg(1) and one Ti(2) atom.
MgTi4Zn2O10 crystallizes in the orthorhombic Pmm2 space group. Mg(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent O(6) atoms. The Mg(1)-O(1) bond length is 1.95 Å. Both Mg(1)-O(6) bond lengths are 2.08 Å. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form distorted corner-sharing TiO5 trigonal bipyramids. The Ti(1)-O(2) bond length is 1.95 Å. The Ti(1)-O(4) bond length is 2.06 Å. The Ti(1)-O(5) bond length is 1.73 Å. Both Ti(1)-O(3) bond lengths are 1.95 Å. In the second Ti site, Ti(2) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(6), and two equivalent O(4) atoms. The Ti(2)-O(1) bond length is 2.30 Å. The Ti(2)-O(3) bond length is 2.01 Å. The Ti(2)-O(6) bond length is 1.70 Å. Both Ti(2)-O(4) bond lengths are 1.95 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(5) atoms. Both Zn(1)-O(2) bond lengths are 2.31 Å. All Zn(1)-O(5) bond lengths are 2.44 Å. In the second Zn site, Zn(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(1) atoms. Both Zn(2)-O(1) bond lengths are 2.13 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), two equivalent Ti(2), and two equivalent Zn(2) atoms. In the second O site, O(2) is bonded to two equivalent Ti(1) and two equivalent Zn(1) atoms to form corner-sharing OTi2Zn2 tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2) and two equivalent Ti(1) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Ti(1) and two equivalent Ti(2) atoms. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Ti(1) and two equivalent Zn(1) atoms. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mg(1) and one Ti(2) atom.