(K)2NaCeBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaCeBr6 framework. In the NaCeBr6 framework, Na(1) is bonded to six equivalent Br(1) atoms to form NaBr6 octahedra that share corners with six equivalent Ce(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Ce(1) is bonded to six equivalent Br(1) atoms to form CeBr6 octahedra that share corners with six equivalent Na(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Na(1) and one Ce(1) atom.
(K)2NaCeBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaCeBr6 framework. In the NaCeBr6 framework, Na(1) is bonded to six equivalent Br(1) atoms to form NaBr6 octahedra that share corners with six equivalent Ce(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-Br(1) bond lengths are 2.90 Å. Ce(1) is bonded to six equivalent Br(1) atoms to form CeBr6 octahedra that share corners with six equivalent Na(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Ce(1)-Br(1) bond lengths are 2.89 Å. Br(1) is bonded in a linear geometry to one Na(1) and one Ce(1) atom.