Pb2TcReO6 crystallizes in the cubic Fm-3m space group. Re(1) is bonded to six equivalent O(1) atoms to form ReO6 octahedra that share corners with six equivalent Tc(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Tc(1) is bonded to six equivalent O(1) atoms to form TcO6 octahedra that share corners with six equivalent Re(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Pb(1) is bonded to twelve equivalent O(1) atoms to form PbO12 cuboctahedra that share corners with twelve equivalent Pb(1)O12 cuboctahedra, faces with six equivalent Pb(1)O12 cuboctahedra, faces with four equivalent Re(1)O6 octahedra, and faces with four equivalent Tc(1)O6 octahedra. O(1) is bonded in a linear geometry to one Re(1), one Tc(1), and four equivalent Pb(1) atoms.
Pb2TcReO6 crystallizes in the cubic Fm-3m space group. Re(1) is bonded to six equivalent O(1) atoms to form ReO6 octahedra that share corners with six equivalent Tc(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Re(1)-O(1) bond lengths are 1.98 Å. Tc(1) is bonded to six equivalent O(1) atoms to form TcO6 octahedra that share corners with six equivalent Re(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Tc(1)-O(1) bond lengths are 2.04 Å. Pb(1) is bonded to twelve equivalent O(1) atoms to form PbO12 cuboctahedra that share corners with twelve equivalent Pb(1)O12 cuboctahedra, faces with six equivalent Pb(1)O12 cuboctahedra, faces with four equivalent Re(1)O6 octahedra, and faces with four equivalent Tc(1)O6 octahedra. All Pb(1)-O(1) bond lengths are 2.84 Å. O(1) is bonded in a linear geometry to one Re(1), one Tc(1), and four equivalent Pb(1) atoms.