(Rb)2CsScCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsScCl6 framework. In the CsScCl6 framework, Cs(1) is bonded to six equivalent Cl(1) atoms to form CsCl6 octahedra that share corners with six equivalent Sc(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent Cl(1) atoms to form ScCl6 octahedra that share corners with six equivalent Cs(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Cs(1) and one Sc(1) atom.
(Rb)2CsScCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsScCl6 framework. In the CsScCl6 framework, Cs(1) is bonded to six equivalent Cl(1) atoms to form CsCl6 octahedra that share corners with six equivalent Sc(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Cs(1)-Cl(1) bond lengths are 3.24 Å. Sc(1) is bonded to six equivalent Cl(1) atoms to form ScCl6 octahedra that share corners with six equivalent Cs(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-Cl(1) bond lengths are 2.50 Å. Cl(1) is bonded in a linear geometry to one Cs(1) and one Sc(1) atom.