KNdWO6Sn crystallizes in the tetragonal P4_2/mmc space group. The structure consists of two 7440-31-5 atoms inside a KNdWO6 framework. In the KNdWO6 framework, K(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form KO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with four equivalent Nd(1)O6 octahedra, and faces with four equivalent W(1)O6 octahedra. Nd(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NdO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Nd(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Nd(1), and one W(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent K(1), one Nd(1), and one W(1) atom.
KNdWO6Sn crystallizes in the tetragonal P4_2/mmc space group. The structure consists of two 7440-31-5 atoms inside a KNdWO6 framework. In the KNdWO6 framework, K(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form KO12 cuboctahedra that share corners with four equivalent K(1)O12 cuboctahedra, faces with two equivalent K(1)O12 cuboctahedra, faces with four equivalent Nd(1)O6 octahedra, and faces with four equivalent W(1)O6 octahedra. All K(1)-O(2) bond lengths are 3.04 Å. All K(1)-O(1) bond lengths are 3.07 Å. Nd(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NdO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. Both Nd(1)-O(2) bond lengths are 2.33 Å. All Nd(1)-O(1) bond lengths are 2.33 Å. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Nd(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-3°. Both W(1)-O(2) bond lengths are 1.95 Å. All W(1)-O(1) bond lengths are 1.96 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Nd(1), and one W(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent K(1), one Nd(1), and one W(1) atom.