LiMnPO4 crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Mn(1), and one P(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Li(1), one Mn(1), and one P(1) atom.
LiMnPO4 crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Both Li(1)-O(1) bond lengths are 2.38 Å. There are two shorter (2.09 Å) and two longer (2.35 Å) Li(1)-O(2) bond lengths. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. Both Mn(1)-O(2) bond lengths are 2.27 Å. There are two shorter (2.08 Å) and two longer (2.35 Å) Mn(1)-O(1) bond lengths. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both P(1)-O(1) bond lengths are 1.57 Å. Both P(1)-O(2) bond lengths are 1.55 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Mn(1), and one P(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Li(1), one Mn(1), and one P(1) atom.