VOF is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(5), one O(6), two equivalent F(1), and two equivalent F(6) atoms to form VO2F4 octahedra that share corners with four equivalent V(5)O4F2 octahedra, corners with four equivalent V(7)O4F2 octahedra, and edges with two equivalent V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the second V site, V(2) is bonded to one O(3), two equivalent O(1), one F(4), and two equivalent F(5) atoms to form VO3F3 octahedra that share corners with four equivalent V(6)O3F3 octahedra, corners with four equivalent V(5)O4F2 octahedra, and edges with two equivalent V(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the third V site, V(3) is bonded to one O(4), one O(7), two equivalent F(2), and two equivalent F(7) atoms to form VO2F4 octahedra that share corners with four equivalent V(7)O4F2 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the fourth V site, V(4) is bonded to one O(2), one O(8), two equivalent F(3), and two equivalent F(8) atoms to form VO2F4 octahedra that share corners with four equivalent V(6)O3F3 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the fifth V site, V(5) is bonded to two equivalent O(3), two equivalent O(6), one F(1), and one F(5) atom to form VO4F2 octahedra that share corners with four equivalent V(1)O2F4 octahedra, corners with four equivalent V(2)O3F3 octahedra, and edges with two equivalent V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the sixth V site, V(6) is bonded to one O(1), two equivalent O(2), one F(8), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with four equivalent V(4)O2F4 octahedra, corners with four equivalent V(2)O3F3 octahedra, and edges with two equivalent V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the seventh V site, V(7) is bonded to two equivalent O(5), two equivalent O(7), one F(2), and one F(6) atom to form VO4F2 octahedra that share corners with four equivalent V(1)O2F4 octahedra, corners with four equivalent V(3)O2F4 octahedra, and edges with two equivalent V(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the eighth V site, V(8) is bonded to two equivalent O(4), two equivalent O(8), one F(3), and one F(7) atom to form VO4F2 octahedra that share corners with four equivalent V(3)O2F4 octahedra, corners with four equivalent V(4)O2F4 octahedra, and edges with two equivalent V(8)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(6) and two equivalent V(2) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(6) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(5) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(8) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(7) atoms. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(5) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(7) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(8) atoms. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(5) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(3) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(4) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(6) atoms. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one V(5) and two equivalent V(2) atoms. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(1) atoms. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(3) atoms. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one V(6) and two equivalent V(4) atoms.
VOF is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(5), one O(6), two equivalent F(1), and two equivalent F(6) atoms to form VO2F4 octahedra that share corners with four equivalent V(5)O4F2 octahedra, corners with four equivalent V(7)O4F2 octahedra, and edges with two equivalent V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. The V(1)-O(5) bond length is 1.94 Å. The V(1)-O(6) bond length is 1.93 Å. Both V(1)-F(1) bond lengths are 2.06 Å. Both V(1)-F(6) bond lengths are 2.07 Å. In the second V site, V(2) is bonded to one O(3), two equivalent O(1), one F(4), and two equivalent F(5) atoms to form VO3F3 octahedra that share corners with four equivalent V(6)O3F3 octahedra, corners with four equivalent V(5)O4F2 octahedra, and edges with two equivalent V(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. The V(2)-O(3) bond length is 1.89 Å. Both V(2)-O(1) bond lengths are 1.98 Å. The V(2)-F(4) bond length is 2.11 Å. Both V(2)-F(5) bond lengths are 2.13 Å. In the third V site, V(3) is bonded to one O(4), one O(7), two equivalent F(2), and two equivalent F(7) atoms to form VO2F4 octahedra that share corners with four equivalent V(7)O4F2 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. The V(3)-O(4) bond length is 1.94 Å. The V(3)-O(7) bond length is 1.93 Å. Both V(3)-F(2) bond lengths are 2.06 Å. Both V(3)-F(7) bond lengths are 2.06 Å. In the fourth V site, V(4) is bonded to one O(2), one O(8), two equivalent F(3), and two equivalent F(8) atoms to form VO2F4 octahedra that share corners with four equivalent V(6)O3F3 octahedra, corners with four equivalent V(8)O4F2 octahedra, and edges with two equivalent V(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. The V(4)-O(2) bond length is 1.94 Å. The V(4)-O(8) bond length is 1.92 Å. Both V(4)-F(3) bond lengths are 2.07 Å. Both V(4)-F(8) bond lengths are 2.08 Å. In the fifth V site, V(5) is bonded to two equivalent O(3), two equivalent O(6), one F(1), and one F(5) atom to form VO4F2 octahedra that share corners with four equivalent V(1)O2F4 octahedra, corners with four equivalent V(2)O3F3 octahedra, and edges with two equivalent V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. Both V(5)-O(3) bond lengths are 2.01 Å. Both V(5)-O(6) bond lengths are 2.01 Å. The V(5)-F(1) bond length is 2.14 Å. The V(5)-F(5) bond length is 2.12 Å. In the sixth V site, V(6) is bonded to one O(1), two equivalent O(2), one F(8), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with four equivalent V(4)O2F4 octahedra, corners with four equivalent V(2)O3F3 octahedra, and edges with two equivalent V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. The V(6)-O(1) bond length is 1.90 Å. Both V(6)-O(2) bond lengths are 1.97 Å. The V(6)-F(8) bond length is 2.22 Å. Both V(6)-F(4) bond lengths are 2.12 Å. In the seventh V site, V(7) is bonded to two equivalent O(5), two equivalent O(7), one F(2), and one F(6) atom to form VO4F2 octahedra that share corners with four equivalent V(1)O2F4 octahedra, corners with four equivalent V(3)O2F4 octahedra, and edges with two equivalent V(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. Both V(7)-O(5) bond lengths are 2.01 Å. Both V(7)-O(7) bond lengths are 2.02 Å. The V(7)-F(2) bond length is 2.12 Å. The V(7)-F(6) bond length is 2.12 Å. In the eighth V site, V(8) is bonded to two equivalent O(4), two equivalent O(8), one F(3), and one F(7) atom to form VO4F2 octahedra that share corners with four equivalent V(3)O2F4 octahedra, corners with four equivalent V(4)O2F4 octahedra, and edges with two equivalent V(8)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. Both V(8)-O(4) bond lengths are 2.01 Å. Both V(8)-O(8) bond lengths are 2.02 Å. The V(8)-F(3) bond length is 2.13 Å. The V(8)-F(7) bond length is 2.12 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(6) and two equivalent V(2) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(4) and two equivalent V(6) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(5) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(8) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(7) atoms. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(5) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(7) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(8) atoms. There are eight inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(5) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(3) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(4) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(6) atoms. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one V(5) and two equivalent V(2) atoms. In the sixth F site, F(6) is bonded in a distorted trigonal planar geometry to one V(7) and two equivalent V(1) atoms. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one V(8) and two equivalent V(3) atoms. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one V(6) and two equivalent V(4) atoms.