Li10Zn(PS4)4 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one S(1), one S(10), one S(6), and one S(8) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(3)S4 tetrahedra, corners with two equivalent Li(8)S4 tetrahedra, and corners with two equivalent P(4)S4 tetrahedra. In the second Li site, Li(2) is bonded to one S(11), one S(3), one S(5), and one S(7) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(9)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, and corners with two equivalent P(1)S4 tetrahedra. In the third Li site, Li(3) is bonded to one S(12), one S(4), one S(6), and one S(8) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(1)S4 tetrahedra, corners with two equivalent Li(10)S4 tetrahedra, and corners with two equivalent P(2)S4 tetrahedra. In the fourth Li site, Li(4) is bonded to one S(11), one S(13), one S(15), and one S(4) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(6)S4 tetrahedra, corners with two equivalent Li(9)S4 tetrahedra, and corners with two equivalent P(2)S4 tetrahedra. In the fifth Li site, Li(5) is bonded to one S(12), one S(14), one S(16), and one S(3) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(10)S4 tetrahedra, corners with two equivalent Li(7)S4 tetrahedra, and corners with two equivalent P(1)S4 tetrahedra. In the sixth Li site, Li(6) is bonded to one S(1), one S(13), one S(15), and one S(9) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(4)S4 tetrahedra, corners with two equivalent Li(8)S4 tetrahedra, and corners with two equivalent P(3)S4 tetrahedra. In the seventh Li site, Li(7) is bonded to one S(10), one S(14), one S(16), and one S(2) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra, and corners with two equivalent P(4)S4 tetrahedra. In the eighth Li site, Li(8) is bonded to one S(1), one S(13), one S(3), and one S(8) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(1)S4 tetrahedra, corners with two equivalent Li(6)S4 tetrahedra, and corners with two equivalent P(1)S4 tetrahedra. In the ninth Li site, Li(9) is bonded to one S(10), one S(11), one S(15), and one S(5) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(2)S4 tetrahedra, corners with two equivalent Li(4)S4 tetrahedra, and corners with two equivalent P(4)S4 tetrahedra. In the tenth Li site, Li(10) is bonded to one S(12), one S(16), one S(6), and one S(9) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(3)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra, and corners with two equivalent P(3)S4 tetrahedra. Zn(1) is bonded to one S(2), one S(5), one S(7), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(2)S4 tetrahedra, and corners with two equivalent P(3)S4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(16), one S(3), and one S(5) atom to form PS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, corners with two equivalent Li(2)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra, and corners with two equivalent Li(8)S4 tetrahedra. In the second P site, P(2) is bonded to one S(15), one S(2), one S(4), and one S(6) atom to form PS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, corners with two equivalent Li(3)S4 tetrahedra, and corners with two equivalent Li(4)S4 tetrahedra. In the third P site, P(3) is bonded to one S(12), one S(13), one S(7), and one S(9) atom to form PS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra, corners with two equivalent Li(10)S4 tetrahedra, corners with two equivalent Li(6)S4 tetrahedra, and corners with two equivalent Zn(1)S4 tetrahedra. In the fourth P site, P(4) is bonded to one S(10), one S(11), one S(14), and one S(8) atom to form PS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra, corners with two equivalent Li(1)S4 tetrahedra, corners with two equivalent Li(7)S4 tetrahedra, and corners with two equivalent Li(9)S4 tetrahedra. There are sixteen inequivalent S sites. In the first S site, S(1) is bonded to one Li(1), one Li(6), one Li(8), and one P(1) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(13)Li3P tetrahedra, corners with two equivalent S(3)Li3P tetrahedra, and corners with two equivalent S(8)Li3P tetrahedra. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Li(7), one Zn(1), and one P(2) atom. In the third S site, S(3) is bonded to one Li(2), one Li(5), one Li(8), and one P(1) atom to form SLi3P tetrahedra that share  a cornercorner with one S(11)Li3P tetrahedra,  a cornercorner with one S(12)Li3P tetrahedra,  a cornercorner with one S(13)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(5)Li2ZnP tetrahedra, corners with two equivalent S(1)Li3P tetrahedra, and corners with two equivalent S(16)Li3P tetrahedra. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Li(3), one Li(4), and one P(2) atom. In the fifth S site, S(5) is bonded to one Li(2), one Li(9), one Zn(1), and one P(1) atom to form SLi2ZnP tetrahedra that share  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra, corners with two equivalent S(11)Li3P tetrahedra, and corners with two equivalent S(3)Li3P tetrahedra. In the sixth S site, S(6) is bonded to one Li(1), one Li(10), one Li(3), and one P(2) atom to form SLi3P tetrahedra that share  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra, corners with two equivalent S(12)Li3P tetrahedra, and corners with two equivalent S(8)Li3P tetrahedra. In the seventh S site, S(7) is bonded in a trigonal non-coplanar geometry to one Li(2), one Zn(1), and one P(3) atom. In the eighth S site, S(8) is bonded to one Li(1), one Li(3), one Li(8), and one P(4) atom to form corner-sharing SLi3P tetrahedra. In the ninth S site, S(9) is bonded to one Li(10), one Li(6), one Zn(1), and one P(3) atom to form SLi2ZnP tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(12)Li3P tetrahedra, and corners with two equivalent S(13)Li3P tetrahedra. In the tenth S site, S(10) is bonded to one Li(1), one Li(7), one Li(9), and one P(4) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(11)Li3P tetrahedra, and corners with two equivalent S(8)Li3P tetrahedra. In the eleventh S site, S(11) is bonded to one Li(2), one Li(4), one Li(9), and one P(4) atom to form SLi3P tetrahedra that share  a cornercorner with one S(13)Li3P tetrahedra,  a cornercorner with one S(3)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(5)Li2ZnP tetrahedra, corners with two equivalent S(10)Li3P tetrahedra, and corners with two equivalent S(15)Li3P tetrahedra. In the twelfth S site, S(12) is bonded to one Li(10), one Li(3), one Li(5), and one P(3) atom to form SLi3P tetrahedra that share  a cornercorner with one S(13)Li3P tetrahedra,  a cornercorner with one S(3)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(9)Li2ZnP tetrahedra, corners with two equivalent S(16)Li3P tetrahedra, and corners with two equivalent S(6)Li3P tetrahedra. In the thirteenth S site, S(13) is bonded to one Li(4), one Li(6), one Li(8), and one P(3) atom to form SLi3P tetrahedra that share  a cornercorner with one S(11)Li3P tetrahedra,  a cornercorner with one S(12)Li3P tetrahedra,  a cornercorner with one S(3)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(9)Li2ZnP tetrahedra, corners with two equivalent S(1)Li3P tetrahedra, and corners with two equivalent S(15)Li3P tetrahedra. In the fourteenth S site, S(14) is bonded in a trigonal non-coplanar geometry to one Li(5), one Li(7), and one P(4) atom. In the fifteenth S site, S(15) is bonded to one Li(4), one Li(6), one Li(9), and one P(2) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(11)Li3P tetrahedra, and corners with two equivalent S(13)Li3P tetrahedra. In the sixteenth S site, S(16) is bonded to one Li(10), one Li(5), one Li(7), and one P(1) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(12)Li3P tetrahedra, and corners with two equivalent S(3)Li3P tetrahedra.
Li10Zn(PS4)4 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one S(1), one S(10), one S(6), and one S(8) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(3)S4 tetrahedra, corners with two equivalent Li(8)S4 tetrahedra, and corners with two equivalent P(4)S4 tetrahedra. The Li(1)-S(1) bond length is 2.47 Å. The Li(1)-S(10) bond length is 2.39 Å. The Li(1)-S(6) bond length is 2.45 Å. The Li(1)-S(8) bond length is 2.44 Å. In the second Li site, Li(2) is bonded to one S(11), one S(3), one S(5), and one S(7) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(9)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, and corners with two equivalent P(1)S4 tetrahedra. The Li(2)-S(11) bond length is 2.38 Å. The Li(2)-S(3) bond length is 2.39 Å. The Li(2)-S(5) bond length is 2.48 Å. The Li(2)-S(7) bond length is 2.45 Å. In the third Li site, Li(3) is bonded to one S(12), one S(4), one S(6), and one S(8) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(1)S4 tetrahedra, corners with two equivalent Li(10)S4 tetrahedra, and corners with two equivalent P(2)S4 tetrahedra. The Li(3)-S(12) bond length is 2.48 Å. The Li(3)-S(4) bond length is 2.38 Å. The Li(3)-S(6) bond length is 2.47 Å. The Li(3)-S(8) bond length is 2.48 Å. In the fourth Li site, Li(4) is bonded to one S(11), one S(13), one S(15), and one S(4) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(6)S4 tetrahedra, corners with two equivalent Li(9)S4 tetrahedra, and corners with two equivalent P(2)S4 tetrahedra. The Li(4)-S(11) bond length is 2.43 Å. The Li(4)-S(13) bond length is 2.57 Å. The Li(4)-S(15) bond length is 2.47 Å. The Li(4)-S(4) bond length is 2.39 Å. In the fifth Li site, Li(5) is bonded to one S(12), one S(14), one S(16), and one S(3) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(10)S4 tetrahedra, corners with two equivalent Li(7)S4 tetrahedra, and corners with two equivalent P(1)S4 tetrahedra. The Li(5)-S(12) bond length is 2.43 Å. The Li(5)-S(14) bond length is 2.40 Å. The Li(5)-S(16) bond length is 2.45 Å. The Li(5)-S(3) bond length is 2.40 Å. In the sixth Li site, Li(6) is bonded to one S(1), one S(13), one S(15), and one S(9) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(4)S4 tetrahedra, corners with two equivalent Li(8)S4 tetrahedra, and corners with two equivalent P(3)S4 tetrahedra. The Li(6)-S(1) bond length is 2.46 Å. The Li(6)-S(13) bond length is 2.48 Å. The Li(6)-S(15) bond length is 2.45 Å. The Li(6)-S(9) bond length is 2.47 Å. In the seventh Li site, Li(7) is bonded to one S(10), one S(14), one S(16), and one S(2) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra, and corners with two equivalent P(4)S4 tetrahedra. The Li(7)-S(10) bond length is 2.41 Å. The Li(7)-S(14) bond length is 2.45 Å. The Li(7)-S(16) bond length is 2.48 Å. The Li(7)-S(2) bond length is 2.44 Å. In the eighth Li site, Li(8) is bonded to one S(1), one S(13), one S(3), and one S(8) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one P(3)S4 tetrahedra,  a cornercorner with one P(4)S4 tetrahedra, corners with two equivalent Li(1)S4 tetrahedra, corners with two equivalent Li(6)S4 tetrahedra, and corners with two equivalent P(1)S4 tetrahedra. The Li(8)-S(1) bond length is 2.50 Å. The Li(8)-S(13) bond length is 2.59 Å. The Li(8)-S(3) bond length is 2.43 Å. The Li(8)-S(8) bond length is 2.50 Å. In the ninth Li site, Li(9) is bonded to one S(10), one S(11), one S(15), and one S(5) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(2)S4 tetrahedra, corners with two equivalent Li(4)S4 tetrahedra, and corners with two equivalent P(4)S4 tetrahedra. The Li(9)-S(10) bond length is 2.42 Å. The Li(9)-S(11) bond length is 2.48 Å. The Li(9)-S(15) bond length is 2.58 Å. The Li(9)-S(5) bond length is 2.77 Å. In the tenth Li site, Li(10) is bonded to one S(12), one S(16), one S(6), and one S(9) atom to form LiS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(3)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra, and corners with two equivalent P(3)S4 tetrahedra. The Li(10)-S(12) bond length is 2.50 Å. The Li(10)-S(16) bond length is 2.60 Å. The Li(10)-S(6) bond length is 2.54 Å. The Li(10)-S(9) bond length is 2.52 Å. Zn(1) is bonded to one S(2), one S(5), one S(7), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one P(1)S4 tetrahedra,  a cornercorner with one P(2)S4 tetrahedra, corners with two equivalent Li(2)S4 tetrahedra, and corners with two equivalent P(3)S4 tetrahedra. The Zn(1)-S(2) bond length is 2.32 Å. The Zn(1)-S(5) bond length is 2.42 Å. The Zn(1)-S(7) bond length is 2.40 Å. The Zn(1)-S(9) bond length is 2.41 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(16), one S(3), and one S(5) atom to form PS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, corners with two equivalent Li(2)S4 tetrahedra, corners with two equivalent Li(5)S4 tetrahedra, and corners with two equivalent Li(8)S4 tetrahedra. The P(1)-S(1) bond length is 2.05 Å. The P(1)-S(16) bond length is 2.05 Å. The P(1)-S(3) bond length is 2.05 Å. The P(1)-S(5) bond length is 2.11 Å. In the second P site, P(2) is bonded to one S(15), one S(2), one S(4), and one S(6) atom to form PS4 tetrahedra that share  a cornercorner with one Li(1)S4 tetrahedra,  a cornercorner with one Li(10)S4 tetrahedra,  a cornercorner with one Li(6)S4 tetrahedra,  a cornercorner with one Li(7)S4 tetrahedra,  a cornercorner with one Li(9)S4 tetrahedra,  a cornercorner with one Zn(1)S4 tetrahedra, corners with two equivalent Li(3)S4 tetrahedra, and corners with two equivalent Li(4)S4 tetrahedra. The P(2)-S(15) bond length is 2.08 Å. The P(2)-S(2) bond length is 2.09 Å. The P(2)-S(4) bond length is 2.01 Å. The P(2)-S(6) bond length is 2.07 Å. In the third P site, P(3) is bonded to one S(12), one S(13), one S(7), and one S(9) atom to form PS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra, corners with two equivalent Li(10)S4 tetrahedra, corners with two equivalent Li(6)S4 tetrahedra, and corners with two equivalent Zn(1)S4 tetrahedra. The P(3)-S(12) bond length is 2.04 Å. The P(3)-S(13) bond length is 2.05 Å. The P(3)-S(7) bond length is 2.06 Å. The P(3)-S(9) bond length is 2.12 Å. In the fourth P site, P(4) is bonded to one S(10), one S(11), one S(14), and one S(8) atom to form PS4 tetrahedra that share  a cornercorner with one Li(2)S4 tetrahedra,  a cornercorner with one Li(3)S4 tetrahedra,  a cornercorner with one Li(4)S4 tetrahedra,  a cornercorner with one Li(5)S4 tetrahedra,  a cornercorner with one Li(8)S4 tetrahedra, corners with two equivalent Li(1)S4 tetrahedra, corners with two equivalent Li(7)S4 tetrahedra, and corners with two equivalent Li(9)S4 tetrahedra. The P(4)-S(10) bond length is 2.07 Å. The P(4)-S(11) bond length is 2.07 Å. The P(4)-S(14) bond length is 2.02 Å. The P(4)-S(8) bond length is 2.07 Å. There are sixteen inequivalent S sites. In the first S site, S(1) is bonded to one Li(1), one Li(6), one Li(8), and one P(1) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(13)Li3P tetrahedra, corners with two equivalent S(3)Li3P tetrahedra, and corners with two equivalent S(8)Li3P tetrahedra. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Li(7), one Zn(1), and one P(2) atom. In the third S site, S(3) is bonded to one Li(2), one Li(5), one Li(8), and one P(1) atom to form SLi3P tetrahedra that share  a cornercorner with one S(11)Li3P tetrahedra,  a cornercorner with one S(12)Li3P tetrahedra,  a cornercorner with one S(13)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(5)Li2ZnP tetrahedra, corners with two equivalent S(1)Li3P tetrahedra, and corners with two equivalent S(16)Li3P tetrahedra. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Li(3), one Li(4), and one P(2) atom. In the fifth S site, S(5) is bonded to one Li(2), one Li(9), one Zn(1), and one P(1) atom to form SLi2ZnP tetrahedra that share  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra, corners with two equivalent S(11)Li3P tetrahedra, and corners with two equivalent S(3)Li3P tetrahedra. In the sixth S site, S(6) is bonded to one Li(1), one Li(10), one Li(3), and one P(2) atom to form SLi3P tetrahedra that share  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra, corners with two equivalent S(12)Li3P tetrahedra, and corners with two equivalent S(8)Li3P tetrahedra. In the seventh S site, S(7) is bonded in a trigonal non-coplanar geometry to one Li(2), one Zn(1), and one P(3) atom. In the eighth S site, S(8) is bonded to one Li(1), one Li(3), one Li(8), and one P(4) atom to form corner-sharing SLi3P tetrahedra. In the ninth S site, S(9) is bonded to one Li(10), one Li(6), one Zn(1), and one P(3) atom to form SLi2ZnP tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(12)Li3P tetrahedra, and corners with two equivalent S(13)Li3P tetrahedra. In the tenth S site, S(10) is bonded to one Li(1), one Li(7), one Li(9), and one P(4) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(15)Li3P tetrahedra,  a cornercorner with one S(16)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(11)Li3P tetrahedra, and corners with two equivalent S(8)Li3P tetrahedra. In the eleventh S site, S(11) is bonded to one Li(2), one Li(4), one Li(9), and one P(4) atom to form SLi3P tetrahedra that share  a cornercorner with one S(13)Li3P tetrahedra,  a cornercorner with one S(3)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(5)Li2ZnP tetrahedra, corners with two equivalent S(10)Li3P tetrahedra, and corners with two equivalent S(15)Li3P tetrahedra. In the twelfth S site, S(12) is bonded to one Li(10), one Li(3), one Li(5), and one P(3) atom to form SLi3P tetrahedra that share  a cornercorner with one S(13)Li3P tetrahedra,  a cornercorner with one S(3)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(9)Li2ZnP tetrahedra, corners with two equivalent S(16)Li3P tetrahedra, and corners with two equivalent S(6)Li3P tetrahedra. In the thirteenth S site, S(13) is bonded to one Li(4), one Li(6), one Li(8), and one P(3) atom to form SLi3P tetrahedra that share  a cornercorner with one S(11)Li3P tetrahedra,  a cornercorner with one S(12)Li3P tetrahedra,  a cornercorner with one S(3)Li3P tetrahedra,  a cornercorner with one S(8)Li3P tetrahedra, corners with two equivalent S(9)Li2ZnP tetrahedra, corners with two equivalent S(1)Li3P tetrahedra, and corners with two equivalent S(15)Li3P tetrahedra. In the fourteenth S site, S(14) is bonded in a trigonal non-coplanar geometry to one Li(5), one Li(7), and one P(4) atom. In the fifteenth S site, S(15) is bonded to one Li(4), one Li(6), one Li(9), and one P(2) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(11)Li3P tetrahedra, and corners with two equivalent S(13)Li3P tetrahedra. In the sixteenth S site, S(16) is bonded to one Li(10), one Li(5), one Li(7), and one P(1) atom to form SLi3P tetrahedra that share  a cornercorner with one S(5)Li2ZnP tetrahedra,  a cornercorner with one S(9)Li2ZnP tetrahedra,  a cornercorner with one S(1)Li3P tetrahedra,  a cornercorner with one S(10)Li3P tetrahedra,  a cornercorner with one S(6)Li3P tetrahedra, corners with two equivalent S(12)Li3P tetrahedra, and corners with two equivalent S(3)Li3P tetrahedra.