VTl3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Tl(1) atoms to form VTl12 cuboctahedra that share corners with twelve equivalent V(1)Tl12 cuboctahedra, edges with twenty-four equivalent Tl(1)Tl8V4 cuboctahedra, faces with six equivalent V(1)Tl12 cuboctahedra, and faces with twelve equivalent Tl(1)Tl8V4 cuboctahedra. Tl(1) is bonded to four equivalent V(1) and eight equivalent Tl(1) atoms to form TlTl8V4 cuboctahedra that share corners with twelve equivalent Tl(1)Tl8V4 cuboctahedra, edges with eight equivalent V(1)Tl12 cuboctahedra, edges with sixteen equivalent Tl(1)Tl8V4 cuboctahedra, faces with four equivalent V(1)Tl12 cuboctahedra, and faces with fourteen equivalent Tl(1)Tl8V4 cuboctahedra.
VTl3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Tl(1) atoms to form VTl12 cuboctahedra that share corners with twelve equivalent V(1)Tl12 cuboctahedra, edges with twenty-four equivalent Tl(1)Tl8V4 cuboctahedra, faces with six equivalent V(1)Tl12 cuboctahedra, and faces with twelve equivalent Tl(1)Tl8V4 cuboctahedra. All V(1)-Tl(1) bond lengths are 3.29 Å. Tl(1) is bonded to four equivalent V(1) and eight equivalent Tl(1) atoms to form TlTl8V4 cuboctahedra that share corners with twelve equivalent Tl(1)Tl8V4 cuboctahedra, edges with eight equivalent V(1)Tl12 cuboctahedra, edges with sixteen equivalent Tl(1)Tl8V4 cuboctahedra, faces with four equivalent V(1)Tl12 cuboctahedra, and faces with fourteen equivalent Tl(1)Tl8V4 cuboctahedra. All Tl(1)-Tl(1) bond lengths are 3.29 Å.