C13Cl12 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 33500-13-9 molecules. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(4), and one Cl(10) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(8), and one Cl(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(10), one C(5), and one Cl(1) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(7) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(9), and one Cl(3) atom. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one Cl(12) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one Cl(2) atom. In the eighth C site, C(8) is bonded in a tetrahedral geometry to one C(12), one C(2), one Cl(7), and one Cl(8) atom. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(13), one C(5), and one Cl(5) atom. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(6) atom. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(13), and one Cl(9) atom. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(7), one C(8), and one Cl(11) atom. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(9), and one Cl(6) atom. There are twelve inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(7) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth Cl site, Cl(10) is bonded in a single-bond geometry to one C(1) atom. In the eleventh Cl site, Cl(11) is bonded in a single-bond geometry to one C(12) atom. In the twelfth Cl site, Cl(12) is bonded in a single-bond geometry to one C(6) atom.
C13Cl12 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 33500-13-9 molecules. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(4), and one Cl(10) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-C(4) bond length is 1.48 Å. The C(1)-Cl(10) bond length is 1.72 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(8), and one Cl(4) atom. The C(2)-C(8) bond length is 1.50 Å. The C(2)-Cl(4) bond length is 1.71 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(10), one C(5), and one Cl(1) atom. The C(3)-C(10) bond length is 1.41 Å. The C(3)-C(5) bond length is 1.40 Å. The C(3)-Cl(1) bond length is 1.71 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(7) atom. The C(4)-C(6) bond length is 1.37 Å. The C(4)-C(7) bond length is 1.48 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(9), and one Cl(3) atom. The C(5)-C(9) bond length is 1.41 Å. The C(5)-Cl(3) bond length is 1.71 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one Cl(12) atom. The C(6)-C(10) bond length is 1.49 Å. The C(6)-Cl(12) bond length is 1.73 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one Cl(2) atom. The C(7)-C(12) bond length is 1.36 Å. The C(7)-Cl(2) bond length is 1.72 Å. In the eighth C site, C(8) is bonded in a tetrahedral geometry to one C(12), one C(2), one Cl(7), and one Cl(8) atom. The C(8)-C(12) bond length is 1.50 Å. The C(8)-Cl(7) bond length is 1.84 Å. The C(8)-Cl(8) bond length is 1.80 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(13), one C(5), and one Cl(5) atom. The C(9)-C(13) bond length is 1.41 Å. The C(9)-Cl(5) bond length is 1.71 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(6) atom. The C(10)-C(11) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(13), and one Cl(9) atom. The C(11)-C(13) bond length is 1.41 Å. The C(11)-Cl(9) bond length is 1.72 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(7), one C(8), and one Cl(11) atom. The C(12)-Cl(11) bond length is 1.71 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(9), and one Cl(6) atom. The C(13)-Cl(6) bond length is 1.72 Å. There are twelve inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(7) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth Cl site, Cl(10) is bonded in a single-bond geometry to one C(1) atom. In the eleventh Cl site, Cl(11) is bonded in a single-bond geometry to one C(12) atom. In the twelfth Cl site, Cl(12) is bonded in a single-bond geometry to one C(6) atom.