CoN5SOClSO3 is Iron Boride structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and four CoN5SOCl clusters. In each CoN5SOCl cluster, Co(1) is bonded in a 5-coordinate geometry to one N(1), two equivalent N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Co(1) atom. In the second N site, N(2) is bonded in a distorted L-shaped geometry to one Co(1) and one Cl(1) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Co(1), one N(3), and one S(1) atom. S(1) is bonded in a 3-coordinate geometry to two equivalent N(3) and one O(3) atom. O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in an L-shaped geometry to two equivalent N(2) atoms.
CoN5SOClSO3 is Iron Boride structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and four CoN5SOCl clusters. In each CoN5SOCl cluster, Co(1) is bonded in a 5-coordinate geometry to one N(1), two equivalent N(2), and two equivalent N(3) atoms. The Co(1)-N(1) bond length is 1.55 Å. Both Co(1)-N(2) bond lengths are 1.80 Å. Both Co(1)-N(3) bond lengths are 1.97 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Co(1) atom. In the second N site, N(2) is bonded in a distorted L-shaped geometry to one Co(1) and one Cl(1) atom. The N(2)-Cl(1) bond length is 1.77 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Co(1), one N(3), and one S(1) atom. The N(3)-N(3) bond length is 1.33 Å. The N(3)-S(1) bond length is 1.83 Å. S(1) is bonded in a 3-coordinate geometry to two equivalent N(3) and one O(3) atom. The S(1)-O(3) bond length is 1.46 Å. O(3) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in an L-shaped geometry to two equivalent N(2) atoms.