(Ta2NCl10)2(N2)3 is Indium-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of six ammonia atoms and two Ta2NCl10 clusters. In each Ta2NCl10 cluster, Ta(1) is bonded to one N(1), one Cl(2), and four equivalent Cl(1) atoms to form corner-sharing TaNCl5 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a linear geometry to two equivalent Ta(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ta(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ta(1) atom.
(Ta2NCl10)2(N2)3 is Indium-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of six ammonia atoms and two Ta2NCl10 clusters. In each Ta2NCl10 cluster, Ta(1) is bonded to one N(1), one Cl(2), and four equivalent Cl(1) atoms to form corner-sharing TaNCl5 octahedra. The corner-sharing octahedra are not tilted. The Ta(1)-N(1) bond length is 2.14 Å. The Ta(1)-Cl(2) bond length is 2.32 Å. All Ta(1)-Cl(1) bond lengths are 2.35 Å. N(1) is bonded in a linear geometry to two equivalent Ta(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ta(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ta(1) atom.