AsPHOCl3F6 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AsPHOCl3F6 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one Cl(1), and two equivalent Cl(2) atoms. H(1) is bonded in a linear geometry to one O(1) and one F(2) atom. O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a bent 120 degrees geometry to one As(1) and one H(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom.
AsPHOCl3F6 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AsPHOCl3F6 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms. The As(1)-F(1) bond length is 1.77 Å. The As(1)-F(2) bond length is 1.85 Å. The As(1)-F(3) bond length is 1.76 Å. The As(1)-F(4) bond length is 1.76 Å. Both As(1)-F(5) bond lengths are 1.77 Å. P(1) is bonded in a tetrahedral geometry to one O(1), one Cl(1), and two equivalent Cl(2) atoms. The P(1)-O(1) bond length is 1.52 Å. The P(1)-Cl(1) bond length is 1.97 Å. Both P(1)-Cl(2) bond lengths are 1.97 Å. H(1) is bonded in a linear geometry to one O(1) and one F(2) atom. The H(1)-O(1) bond length is 1.05 Å. The H(1)-F(2) bond length is 1.40 Å. O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a bent 120 degrees geometry to one As(1) and one H(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom.