Mn12O7F17 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(7), one F(1), one F(13), one F(14), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(7)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(11)O2F4 octahedra,  an edgeedge with one Mn(5)O2F4 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the second Mn site, Mn(2) is bonded to one O(2), one F(1), one F(12), one F(14), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(11)O2F4 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the third Mn site, Mn(3) is bonded to one O(2), one O(6), one F(12), one F(15), one F(2), and one F(3) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(8)O2F4 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(10)O2F4 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. In the fourth Mn site, Mn(4) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(5), one F(11), one F(16), and one F(17) atom. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(3), one F(13), one F(17), one F(6), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(11)O2F4 octahedra, corners with two equivalent Mn(12)O2F4 octahedra, corners with four equivalent Mn(7)OF5 octahedra, and  an edgeedge with one Mn(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 41-60°. In the sixth Mn site, Mn(6) is bonded to one O(4), one F(10), one F(15), one F(16), one F(2), and one F(7) atom to form a mixture of edge and corner-sharing MnOF5 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the seventh Mn site, Mn(7) is bonded to one O(1), one F(11), one F(13), one F(5), one F(6), and one F(9) atom to form a mixture of distorted edge and corner-sharing MnOF5 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the eighth Mn site, Mn(8) is bonded to one O(5), one O(6), one F(10), one F(16), one F(2), and one F(7) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(12)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the ninth Mn site, Mn(9) is bonded to one O(7), one F(1), one F(12), one F(3), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(3)O2F4 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(11)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. In the tenth Mn site, Mn(10) is bonded to one O(2), one O(6), one F(15), one F(3), one F(7), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(3)O2F4 octahedra,  an edgeedge with one Mn(8)O2F4 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. In the eleventh Mn site, Mn(11) is bonded to one O(3), one O(7), one F(14), one F(4), one F(5), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with four equivalent Mn(1)O2F4 octahedra,  an edgeedge with one Mn(7)OF5 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the twelfth Mn site, Mn(12) is bonded to one O(4), one O(5), one F(10), one F(11), one F(17), and one F(6) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(8)O2F4 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 41-57°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. There are seventeen inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the fifteenth F site, F(15) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the sixteenth F site, F(16) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the seventeenth F site, F(17) is bonded in a 3-coordinate geometry to one Mn(12), one Mn(4), and one Mn(5) atom.
Mn12O7F17 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(7), one F(1), one F(13), one F(14), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(7)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(11)O2F4 octahedra,  an edgeedge with one Mn(5)O2F4 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. The Mn(1)-O(3) bond length is 1.99 Å. The Mn(1)-O(7) bond length is 1.95 Å. The Mn(1)-F(1) bond length is 2.04 Å. The Mn(1)-F(13) bond length is 2.03 Å. The Mn(1)-F(14) bond length is 2.21 Å. The Mn(1)-F(5) bond length is 2.12 Å. In the second Mn site, Mn(2) is bonded to one O(2), one F(1), one F(12), one F(14), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)O2F4 octahedra, corners with two equivalent Mn(11)O2F4 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(1)O2F4 octahedra, and  an edgeedge with one Mn(3)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. The Mn(2)-O(2) bond length is 2.02 Å. The Mn(2)-F(1) bond length is 2.21 Å. The Mn(2)-F(12) bond length is 2.13 Å. The Mn(2)-F(14) bond length is 2.17 Å. The Mn(2)-F(4) bond length is 2.05 Å. The Mn(2)-F(8) bond length is 2.12 Å. In the third Mn site, Mn(3) is bonded to one O(2), one O(6), one F(12), one F(15), one F(2), and one F(3) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(8)O2F4 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(10)O2F4 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. The Mn(3)-O(2) bond length is 2.03 Å. The Mn(3)-O(6) bond length is 2.02 Å. The Mn(3)-F(12) bond length is 2.07 Å. The Mn(3)-F(15) bond length is 2.22 Å. The Mn(3)-F(2) bond length is 2.07 Å. The Mn(3)-F(3) bond length is 2.19 Å. In the fourth Mn site, Mn(4) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(5), one F(11), one F(16), and one F(17) atom. The Mn(4)-O(1) bond length is 1.90 Å. The Mn(4)-O(4) bond length is 1.94 Å. The Mn(4)-O(5) bond length is 2.05 Å. The Mn(4)-F(11) bond length is 2.11 Å. The Mn(4)-F(16) bond length is 2.13 Å. The Mn(4)-F(17) bond length is 2.63 Å. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(3), one F(13), one F(17), one F(6), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(11)O2F4 octahedra, corners with two equivalent Mn(12)O2F4 octahedra, corners with four equivalent Mn(7)OF5 octahedra, and  an edgeedge with one Mn(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 41-60°. The Mn(5)-O(1) bond length is 1.96 Å. The Mn(5)-O(3) bond length is 2.03 Å. The Mn(5)-F(13) bond length is 2.15 Å. The Mn(5)-F(17) bond length is 2.15 Å. The Mn(5)-F(6) bond length is 2.08 Å. The Mn(5)-F(9) bond length is 2.08 Å. In the sixth Mn site, Mn(6) is bonded to one O(4), one F(10), one F(15), one F(16), one F(2), and one F(7) atom to form a mixture of edge and corner-sharing MnOF5 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. The Mn(6)-O(4) bond length is 2.01 Å. The Mn(6)-F(10) bond length is 2.05 Å. The Mn(6)-F(15) bond length is 2.11 Å. The Mn(6)-F(16) bond length is 2.11 Å. The Mn(6)-F(2) bond length is 2.18 Å. The Mn(6)-F(7) bond length is 2.05 Å. In the seventh Mn site, Mn(7) is bonded to one O(1), one F(11), one F(13), one F(5), one F(6), and one F(9) atom to form a mixture of distorted edge and corner-sharing MnOF5 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. The Mn(7)-O(1) bond length is 2.03 Å. The Mn(7)-F(11) bond length is 2.26 Å. The Mn(7)-F(13) bond length is 2.02 Å. The Mn(7)-F(5) bond length is 2.15 Å. The Mn(7)-F(6) bond length is 2.06 Å. The Mn(7)-F(9) bond length is 2.40 Å. In the eighth Mn site, Mn(8) is bonded to one O(5), one O(6), one F(10), one F(16), one F(2), and one F(7) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(12)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. The Mn(8)-O(5) bond length is 1.98 Å. The Mn(8)-O(6) bond length is 2.00 Å. The Mn(8)-F(10) bond length is 2.09 Å. The Mn(8)-F(16) bond length is 2.05 Å. The Mn(8)-F(2) bond length is 2.10 Å. The Mn(8)-F(7) bond length is 2.10 Å. In the ninth Mn site, Mn(9) is bonded to one O(7), one F(1), one F(12), one F(3), one F(4), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra, corners with two equivalent Mn(3)O2F4 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)O2F4 octahedra, and  an edgeedge with one Mn(11)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. The Mn(9)-O(7) bond length is 2.02 Å. The Mn(9)-F(1) bond length is 2.11 Å. The Mn(9)-F(12) bond length is 2.05 Å. The Mn(9)-F(3) bond length is 2.18 Å. The Mn(9)-F(4) bond length is 2.11 Å. The Mn(9)-F(8) bond length is 2.19 Å. In the tenth Mn site, Mn(10) is bonded to one O(2), one O(6), one F(15), one F(3), one F(7), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(3)O2F4 octahedra,  an edgeedge with one Mn(8)O2F4 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-59°. The Mn(10)-O(2) bond length is 1.96 Å. The Mn(10)-O(6) bond length is 2.01 Å. The Mn(10)-F(15) bond length is 2.17 Å. The Mn(10)-F(3) bond length is 2.21 Å. The Mn(10)-F(7) bond length is 2.04 Å. The Mn(10)-F(8) bond length is 2.05 Å. In the eleventh Mn site, Mn(11) is bonded to one O(3), one O(7), one F(14), one F(4), one F(5), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with four equivalent Mn(1)O2F4 octahedra,  an edgeedge with one Mn(7)OF5 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. The Mn(11)-O(3) bond length is 2.03 Å. The Mn(11)-O(7) bond length is 2.04 Å. The Mn(11)-F(14) bond length is 2.15 Å. The Mn(11)-F(4) bond length is 2.10 Å. The Mn(11)-F(5) bond length is 2.18 Å. The Mn(11)-F(9) bond length is 2.08 Å. In the twelfth Mn site, Mn(12) is bonded to one O(4), one O(5), one F(10), one F(11), one F(17), and one F(6) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)O2F4 octahedra, corners with two equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(8)O2F4 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 41-57°. The Mn(12)-O(4) bond length is 1.93 Å. The Mn(12)-O(5) bond length is 1.97 Å. The Mn(12)-F(10) bond length is 2.15 Å. The Mn(12)-F(11) bond length is 2.10 Å. The Mn(12)-F(17) bond length is 2.02 Å. The Mn(12)-F(6) bond length is 2.14 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. There are seventeen inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the fifteenth F site, F(15) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the sixteenth F site, F(16) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the seventeenth F site, F(17) is bonded in a 3-coordinate geometry to one Mn(12), one Mn(4), and one Mn(5) atom.