CNH3F3Sb2F11 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trifluoromethylazanium molecules and two Sb2F11 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(3), one F(7), one F(8), and two equivalent F(2) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the second Sb site, Sb(2) is bonded to one F(3), one F(4), two equivalent F(5), and two equivalent F(6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are eight inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom.
CNH3F3Sb2F11 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trifluoromethylazanium molecules and two Sb2F11 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(3), one F(7), one F(8), and two equivalent F(2) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. The Sb(1)-F(1) bond length is 1.90 Å. The Sb(1)-F(3) bond length is 2.09 Å. The Sb(1)-F(7) bond length is 1.90 Å. The Sb(1)-F(8) bond length is 1.90 Å. Both Sb(1)-F(2) bond lengths are 1.91 Å. In the second Sb site, Sb(2) is bonded to one F(3), one F(4), two equivalent F(5), and two equivalent F(6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. The Sb(2)-F(3) bond length is 2.06 Å. The Sb(2)-F(4) bond length is 1.90 Å. Both Sb(2)-F(5) bond lengths are 1.89 Å. Both Sb(2)-F(6) bond lengths are 1.92 Å. There are eight inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom.