LiBaTi2Bi2O crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded to four equivalent Ti(1) and two equivalent Bi(1) atoms to form corner-sharing LiTi4Bi2 octahedra. The corner-sharing octahedra are not tilted. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent Bi(1) atoms. Ti(1) is bonded in a square co-planar geometry to two equivalent Li(1) and two equivalent O(1) atoms. Bi(1) is bonded in a distorted single-bond geometry to one Li(1) and four equivalent Ba(1) atoms. O(1) is bonded in a square co-planar geometry to four equivalent Ti(1) atoms.
LiBaTi2Bi2O crystallizes in the tetragonal P4/mmm space group. Li(1) is bonded to four equivalent Ti(1) and two equivalent Bi(1) atoms to form corner-sharing LiTi4Bi2 octahedra. The corner-sharing octahedra are not tilted. All Li(1)-Ti(1) bond lengths are 2.18 Å. Both Li(1)-Bi(1) bond lengths are 2.36 Å. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent Bi(1) atoms. All Ba(1)-Bi(1) bond lengths are 3.69 Å. Ti(1) is bonded in a square co-planar geometry to two equivalent Li(1) and two equivalent O(1) atoms. Both Ti(1)-O(1) bond lengths are 2.18 Å. Bi(1) is bonded in a distorted single-bond geometry to one Li(1) and four equivalent Ba(1) atoms. O(1) is bonded in a square co-planar geometry to four equivalent Ti(1) atoms.