La5Mn7Co(PbO8)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(19), one O(20), one O(24), one O(4), one O(5), and two equivalent O(23) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(12), one O(14), one O(15), one O(16), one O(20), one O(21), one O(22), one O(23), one O(24), one O(8), and two equivalent O(19) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(17), one O(2), one O(3), one O(4), one O(9), and two equivalent O(6) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(17), one O(22), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. In the fifth La site, La(5) is bonded in a 12-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(2), one O(20), one O(21), one O(22), one O(24), one O(8), and two equivalent O(18) atoms. There are seven inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(14), one O(2), one O(20), one O(23), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-20°. In the second Mn site, Mn(2) is bonded to one O(11), one O(3), one O(5), one O(6), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 15-20°. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(17), one O(4), one O(6), and one O(7) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 14-20°. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(13), one O(15), one O(17), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(13), one O(16), one O(22), one O(3), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-20°. In the sixth Mn site, Mn(6) is bonded to one O(15), one O(18), one O(19), one O(21), one O(24), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-22°. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(2), one O(21), one O(23), one O(24), and one O(4) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 12-21°. Co(1) is bonded to one O(14), one O(16), one O(18), one O(19), one O(20), and one O(22) atom to form CoO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, and corners with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-19°. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(3), one O(4), one O(5), and two equivalent O(7) atoms. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(17), one O(18), and one O(9) atom. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to one O(20), one O(24), and one O(6) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), one Mn(7), and one Pb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(3), one La(5), one Mn(1), and one Mn(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(3), one Mn(2), one Mn(5), and one Pb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one La(1), one La(3), one Mn(3), one Mn(7), and one Pb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), one Mn(2), and one Pb(1) atom. In the sixth O site, O(6) is bonded to two equivalent La(3), one Mn(2), one Mn(3), and one Pb(3) atom to form distorted corner-sharing OLa2Mn2Pb square pyramids. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(4), one Mn(2), one Mn(3), and two equivalent Pb(1) atoms. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(2), one La(4), one La(5), one Mn(4), and one Mn(6) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one La(3), one La(4), one Mn(2), one Mn(5), and one Pb(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(3), one Mn(3), one Mn(4), and one Pb(1) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one La(1), one La(3), one Mn(1), one Mn(2), and one Pb(1) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one La(2), two equivalent La(4), one Mn(4), one Mn(5), and one Pb(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(5), one Mn(4), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Mn(1), and one Co(1) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one La(2), one La(4), one La(5), one Mn(4), and one Mn(6) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one La(2), one La(4), one La(5), one Mn(5), and one Co(1) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one La(3), one La(4), one Mn(3), one Mn(4), and one Pb(2) atom. In the eighteenth O site, O(18) is bonded in a 5-coordinate geometry to two equivalent La(5), one Mn(6), one Co(1), and one Pb(2) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one La(1), two equivalent La(2), one Mn(6), and one Co(1) atom. In the twentieth O site, O(20) is bonded in a distorted linear geometry to one La(1), one La(2), one La(5), one Mn(1), one Co(1), and one Pb(3) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Mn(6), and one Mn(7) atom. In the twenty-second O site, O(22) is bonded in a 5-coordinate geometry to one La(2), one La(4), one La(5), one Mn(5), and one Co(1) atom. In the twenty-third O site, O(23) is bonded to one La(2), two equivalent La(1), one Mn(1), and one Mn(7) atom to form distorted corner-sharing OLa3Mn2 square pyramids. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one La(1), one La(2), one La(5), one Mn(6), one Mn(7), and one Pb(3) atom.
La5Mn7Co(PbO8)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(19), one O(20), one O(24), one O(4), one O(5), and two equivalent O(23) atoms. The La(1)-O(1) bond length is 2.48 Å. The La(1)-O(11) bond length is 2.79 Å. The La(1)-O(19) bond length is 2.45 Å. The La(1)-O(20) bond length is 2.76 Å. The La(1)-O(24) bond length is 2.76 Å. The La(1)-O(4) bond length is 2.81 Å. The La(1)-O(5) bond length is 2.46 Å. Both La(1)-O(23) bond lengths are 2.77 Å. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(12), one O(14), one O(15), one O(16), one O(20), one O(21), one O(22), one O(23), one O(24), one O(8), and two equivalent O(19) atoms. The La(2)-O(12) bond length is 3.00 Å. The La(2)-O(14) bond length is 2.70 Å. The La(2)-O(15) bond length is 2.48 Å. The La(2)-O(16) bond length is 2.70 Å. The La(2)-O(20) bond length is 2.96 Å. The La(2)-O(21) bond length is 2.69 Å. The La(2)-O(22) bond length is 2.47 Å. The La(2)-O(23) bond length is 2.48 Å. The La(2)-O(24) bond length is 3.03 Å. The La(2)-O(8) bond length is 2.71 Å. There is one shorter (2.76 Å) and one longer (2.80 Å) La(2)-O(19) bond length. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(17), one O(2), one O(3), one O(4), one O(9), and two equivalent O(6) atoms. The La(3)-O(10) bond length is 2.46 Å. The La(3)-O(11) bond length is 2.78 Å. The La(3)-O(17) bond length is 2.80 Å. The La(3)-O(2) bond length is 2.49 Å. The La(3)-O(3) bond length is 2.46 Å. The La(3)-O(4) bond length is 2.78 Å. The La(3)-O(9) bond length is 2.80 Å. There is one shorter (2.76 Å) and one longer (2.78 Å) La(3)-O(6) bond length. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(17), one O(22), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. The La(4)-O(15) bond length is 2.78 Å. The La(4)-O(16) bond length is 2.46 Å. The La(4)-O(17) bond length is 2.80 Å. The La(4)-O(22) bond length is 2.74 Å. The La(4)-O(7) bond length is 2.46 Å. The La(4)-O(8) bond length is 2.46 Å. The La(4)-O(9) bond length is 2.78 Å. There is one shorter (2.75 Å) and one longer (2.78 Å) La(4)-O(12) bond length. In the fifth La site, La(5) is bonded in a 12-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(2), one O(20), one O(21), one O(22), one O(24), one O(8), and two equivalent O(18) atoms. The La(5)-O(13) bond length is 2.44 Å. The La(5)-O(14) bond length is 2.47 Å. The La(5)-O(15) bond length is 2.86 Å. The La(5)-O(16) bond length is 3.11 Å. The La(5)-O(2) bond length is 3.05 Å. The La(5)-O(20) bond length is 2.77 Å. The La(5)-O(21) bond length is 2.49 Å. The La(5)-O(22) bond length is 2.83 Å. The La(5)-O(24) bond length is 2.81 Å. The La(5)-O(8) bond length is 3.22 Å. There is one shorter (2.75 Å) and one longer (2.80 Å) La(5)-O(18) bond length. There are seven inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(14), one O(2), one O(20), one O(23), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-20°. The Mn(1)-O(11) bond length is 1.98 Å. The Mn(1)-O(14) bond length is 1.96 Å. The Mn(1)-O(2) bond length is 2.00 Å. The Mn(1)-O(20) bond length is 1.93 Å. The Mn(1)-O(23) bond length is 2.01 Å. The Mn(1)-O(5) bond length is 2.00 Å. In the second Mn site, Mn(2) is bonded to one O(11), one O(3), one O(5), one O(6), one O(7), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 15-20°. The Mn(2)-O(11) bond length is 1.97 Å. The Mn(2)-O(3) bond length is 1.99 Å. The Mn(2)-O(5) bond length is 1.98 Å. The Mn(2)-O(6) bond length is 2.00 Å. The Mn(2)-O(7) bond length is 2.01 Å. The Mn(2)-O(9) bond length is 1.97 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(17), one O(4), one O(6), and one O(7) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 14-20°. The Mn(3)-O(1) bond length is 2.00 Å. The Mn(3)-O(10) bond length is 2.01 Å. The Mn(3)-O(17) bond length is 1.98 Å. The Mn(3)-O(4) bond length is 1.99 Å. The Mn(3)-O(6) bond length is 2.01 Å. The Mn(3)-O(7) bond length is 2.02 Å. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(13), one O(15), one O(17), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. The Mn(4)-O(10) bond length is 1.97 Å. The Mn(4)-O(12) bond length is 2.01 Å. The Mn(4)-O(13) bond length is 2.03 Å. The Mn(4)-O(15) bond length is 2.00 Å. The Mn(4)-O(17) bond length is 1.97 Å. The Mn(4)-O(8) bond length is 2.01 Å. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(13), one O(16), one O(22), one O(3), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-20°. The Mn(5)-O(12) bond length is 1.99 Å. The Mn(5)-O(13) bond length is 2.02 Å. The Mn(5)-O(16) bond length is 1.95 Å. The Mn(5)-O(22) bond length is 1.95 Å. The Mn(5)-O(3) bond length is 1.99 Å. The Mn(5)-O(9) bond length is 1.99 Å. In the sixth Mn site, Mn(6) is bonded to one O(15), one O(18), one O(19), one O(21), one O(24), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, and corners with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-22°. The Mn(6)-O(15) bond length is 1.98 Å. The Mn(6)-O(18) bond length is 1.93 Å. The Mn(6)-O(19) bond length is 1.96 Å. The Mn(6)-O(21) bond length is 1.97 Å. The Mn(6)-O(24) bond length is 1.96 Å. The Mn(6)-O(8) bond length is 1.98 Å. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(2), one O(21), one O(23), one O(24), and one O(4) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 12-21°. The Mn(7)-O(1) bond length is 1.97 Å. The Mn(7)-O(2) bond length is 2.02 Å. The Mn(7)-O(21) bond length is 2.00 Å. The Mn(7)-O(23) bond length is 2.01 Å. The Mn(7)-O(24) bond length is 1.98 Å. The Mn(7)-O(4) bond length is 1.96 Å. Co(1) is bonded to one O(14), one O(16), one O(18), one O(19), one O(20), and one O(22) atom to form CoO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, and corners with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-19°. The Co(1)-O(14) bond length is 2.01 Å. The Co(1)-O(16) bond length is 2.02 Å. The Co(1)-O(18) bond length is 2.07 Å. The Co(1)-O(19) bond length is 2.07 Å. The Co(1)-O(20) bond length is 1.99 Å. The Co(1)-O(22) bond length is 2.02 Å. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(3), one O(4), one O(5), and two equivalent O(7) atoms. The Pb(1)-O(1) bond length is 2.81 Å. The Pb(1)-O(10) bond length is 2.81 Å. The Pb(1)-O(11) bond length is 2.55 Å. The Pb(1)-O(12) bond length is 2.55 Å. The Pb(1)-O(3) bond length is 2.81 Å. The Pb(1)-O(4) bond length is 2.55 Å. The Pb(1)-O(5) bond length is 2.81 Å. There is one shorter (2.76 Å) and one longer (2.79 Å) Pb(1)-O(7) bond length. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(17), one O(18), and one O(9) atom. The Pb(2)-O(17) bond length is 2.55 Å. The Pb(2)-O(18) bond length is 2.53 Å. The Pb(2)-O(9) bond length is 2.53 Å. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to one O(20), one O(24), and one O(6) atom. The Pb(3)-O(20) bond length is 2.64 Å. The Pb(3)-O(24) bond length is 2.59 Å. The Pb(3)-O(6) bond length is 2.53 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one Mn(3), one Mn(7), and one Pb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(3), one La(5), one Mn(1), and one Mn(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one La(3), one Mn(2), one Mn(5), and one Pb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one La(1), one La(3), one Mn(3), one Mn(7), and one Pb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), one Mn(2), and one Pb(1) atom. In the sixth O site, O(6) is bonded to two equivalent La(3), one Mn(2), one Mn(3), and one Pb(3) atom to form distorted corner-sharing OLa2Mn2Pb square pyramids. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one La(4), one Mn(2), one Mn(3), and two equivalent Pb(1) atoms. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(2), one La(4), one La(5), one Mn(4), and one Mn(6) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one La(3), one La(4), one Mn(2), one Mn(5), and one Pb(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one La(3), one Mn(3), one Mn(4), and one Pb(1) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one La(1), one La(3), one Mn(1), one Mn(2), and one Pb(1) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one La(2), two equivalent La(4), one Mn(4), one Mn(5), and one Pb(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(5), one Mn(4), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Mn(1), and one Co(1) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one La(2), one La(4), one La(5), one Mn(4), and one Mn(6) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one La(2), one La(4), one La(5), one Mn(5), and one Co(1) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one La(3), one La(4), one Mn(3), one Mn(4), and one Pb(2) atom. In the eighteenth O site, O(18) is bonded in a 5-coordinate geometry to two equivalent La(5), one Mn(6), one Co(1), and one Pb(2) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one La(1), two equivalent La(2), one Mn(6), and one Co(1) atom. In the twentieth O site, O(20) is bonded in a distorted linear geometry to one La(1), one La(2), one La(5), one Mn(1), one Co(1), and one Pb(3) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Mn(6), and one Mn(7) atom. In the twenty-second O site, O(22) is bonded in a 5-coordinate geometry to one La(2), one La(4), one La(5), one Mn(5), and one Co(1) atom. In the twenty-third O site, O(23) is bonded to one La(2), two equivalent La(1), one Mn(1), and one Mn(7) atom to form distorted corner-sharing OLa3Mn2 square pyramids. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one La(1), one La(2), one La(5), one Mn(6), one Mn(7), and one Pb(3) atom.