Li2V3SnO8 is Spinel-derived structured and crystallizes in the monoclinic Pc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form LiO4 tetrahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-65°. In the second Li site, Li(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. In the third V site, V(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. Sn(1) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form SnO4 tetrahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-62°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one V(3) atom. In the second O site, O(2) is bonded to one V(1), one V(2), one V(3), and one Sn(1) atom to form a mixture of distorted corner and edge-sharing OV3Sn trigonal pyramids. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one V(3) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(2), and one V(3) atom. In the sixth O site, O(6) is bonded to one Li(2), one V(2), one V(3), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(7)LiV2Sn tetrahedra,  a cornercorner with one O(8)LiV2Sn trigonal pyramid,  a cornercorner with one O(2)V3Sn trigonal pyramid,  an edgeedge with one O(7)LiV2Sn tetrahedra,  an edgeedge with one O(8)LiV2Sn trigonal pyramid, and  an edgeedge with one O(2)V3Sn trigonal pyramid. In the seventh O site, O(7) is bonded to one Li(2), one V(1), one V(2), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(6)LiV2Sn tetrahedra,  a cornercorner with one O(8)LiV2Sn trigonal pyramid,  a cornercorner with one O(2)V3Sn trigonal pyramid,  an edgeedge with one O(6)LiV2Sn tetrahedra,  an edgeedge with one O(8)LiV2Sn trigonal pyramid, and  an edgeedge with one O(2)V3Sn trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(2), one V(1), one V(3), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(6)LiV2Sn tetrahedra,  a cornercorner with one O(7)LiV2Sn tetrahedra,  a cornercorner with one O(2)V3Sn trigonal pyramid,  an edgeedge with one O(6)LiV2Sn tetrahedra,  an edgeedge with one O(7)LiV2Sn tetrahedra, and  an edgeedge with one O(2)V3Sn trigonal pyramid.
Li2V3SnO8 is Spinel-derived structured and crystallizes in the monoclinic Pc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form LiO4 tetrahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-65°. The Li(1)-O(1) bond length is 2.01 Å. The Li(1)-O(3) bond length is 1.99 Å. The Li(1)-O(4) bond length is 1.98 Å. The Li(1)-O(5) bond length is 2.06 Å. In the second Li site, Li(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The Li(2)-O(3) bond length is 2.15 Å. The Li(2)-O(4) bond length is 2.10 Å. The Li(2)-O(5) bond length is 2.22 Å. The Li(2)-O(6) bond length is 2.09 Å. The Li(2)-O(7) bond length is 2.08 Å. The Li(2)-O(8) bond length is 2.12 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The V(1)-O(1) bond length is 2.07 Å. The V(1)-O(2) bond length is 2.17 Å. The V(1)-O(3) bond length is 1.98 Å. The V(1)-O(4) bond length is 1.95 Å. The V(1)-O(7) bond length is 2.09 Å. The V(1)-O(8) bond length is 2.08 Å. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The V(2)-O(1) bond length is 1.94 Å. The V(2)-O(2) bond length is 2.13 Å. The V(2)-O(3) bond length is 1.88 Å. The V(2)-O(5) bond length is 1.81 Å. The V(2)-O(6) bond length is 2.13 Å. The V(2)-O(7) bond length is 2.10 Å. In the third V site, V(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The V(3)-O(1) bond length is 2.06 Å. The V(3)-O(2) bond length is 2.14 Å. The V(3)-O(4) bond length is 1.93 Å. The V(3)-O(5) bond length is 2.04 Å. The V(3)-O(6) bond length is 2.07 Å. The V(3)-O(8) bond length is 2.10 Å. Sn(1) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form SnO4 tetrahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-62°. The Sn(1)-O(2) bond length is 2.03 Å. The Sn(1)-O(6) bond length is 2.00 Å. The Sn(1)-O(7) bond length is 1.99 Å. The Sn(1)-O(8) bond length is 2.00 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one V(3) atom. In the second O site, O(2) is bonded to one V(1), one V(2), one V(3), and one Sn(1) atom to form a mixture of distorted corner and edge-sharing OV3Sn trigonal pyramids. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one V(3) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(2), and one V(3) atom. In the sixth O site, O(6) is bonded to one Li(2), one V(2), one V(3), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(7)LiV2Sn tetrahedra,  a cornercorner with one O(8)LiV2Sn trigonal pyramid,  a cornercorner with one O(2)V3Sn trigonal pyramid,  an edgeedge with one O(7)LiV2Sn tetrahedra,  an edgeedge with one O(8)LiV2Sn trigonal pyramid, and  an edgeedge with one O(2)V3Sn trigonal pyramid. In the seventh O site, O(7) is bonded to one Li(2), one V(1), one V(2), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(6)LiV2Sn tetrahedra,  a cornercorner with one O(8)LiV2Sn trigonal pyramid,  a cornercorner with one O(2)V3Sn trigonal pyramid,  an edgeedge with one O(6)LiV2Sn tetrahedra,  an edgeedge with one O(8)LiV2Sn trigonal pyramid, and  an edgeedge with one O(2)V3Sn trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(2), one V(1), one V(3), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(6)LiV2Sn tetrahedra,  a cornercorner with one O(7)LiV2Sn tetrahedra,  a cornercorner with one O(2)V3Sn trigonal pyramid,  an edgeedge with one O(6)LiV2Sn tetrahedra,  an edgeedge with one O(7)LiV2Sn tetrahedra, and  an edgeedge with one O(2)V3Sn trigonal pyramid.