InTe2O5F crystallizes in the orthorhombic C222_1 space group. In(1) is bonded to one O(1), one O(2), one O(3), one O(5), one F(1), and one F(2) atom to form corner-sharing InO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(4), and one O(5) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one In(1) and one Te(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one In(1) and one Te(1) atom. In the fourth O site, O(1) is bonded in a distorted trigonal planar geometry to one In(1), one Te(1), and one Te(2) atom. In the fifth O site, O(2) is bonded in a 2-coordinate geometry to one In(1) and one Te(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent In(1) atoms. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to two equivalent In(1) atoms.
InTe2O5F crystallizes in the orthorhombic C222_1 space group. In(1) is bonded to one O(1), one O(2), one O(3), one O(5), one F(1), and one F(2) atom to form corner-sharing InO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. The In(1)-O(1) bond length is 2.15 Å. The In(1)-O(2) bond length is 2.13 Å. The In(1)-O(3) bond length is 2.15 Å. The In(1)-O(5) bond length is 2.11 Å. The In(1)-F(1) bond length is 2.14 Å. The In(1)-F(2) bond length is 2.17 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(4), and one O(5) atom. The Te(1)-O(1) bond length is 2.35 Å. The Te(1)-O(3) bond length is 1.88 Å. The Te(1)-O(4) bond length is 2.00 Å. The Te(1)-O(5) bond length is 1.86 Å. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. The Te(2)-O(1) bond length is 1.91 Å. The Te(2)-O(2) bond length is 1.87 Å. The Te(2)-O(4) bond length is 1.91 Å. There are five inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one In(1) and one Te(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one In(1) and one Te(1) atom. In the fourth O site, O(1) is bonded in a distorted trigonal planar geometry to one In(1), one Te(1), and one Te(2) atom. In the fifth O site, O(2) is bonded in a 2-coordinate geometry to one In(1) and one Te(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to two equivalent In(1) atoms. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to two equivalent In(1) atoms.