MnC4NO5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four MnC4NO5 clusters. Mn(1) is bonded in a trigonal bipyramidal geometry to two equivalent C(1), two equivalent C(2), and one N(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. N(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom.
MnC4NO5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four MnC4NO5 clusters. Mn(1) is bonded in a trigonal bipyramidal geometry to two equivalent C(1), two equivalent C(2), and one N(1) atom. Both Mn(1)-C(1) bond lengths are 1.86 Å. Both Mn(1)-C(2) bond lengths are 1.83 Å. The Mn(1)-N(1) bond length is 1.69 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(3) atom. The C(1)-O(3) bond length is 1.16 Å. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. The C(2)-O(2) bond length is 1.16 Å. N(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. The N(1)-O(1) bond length is 1.18 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom.