Li3V2P4(HO8)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(3), one O(5), and one O(9) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(5), one O(6), and one O(8) atom. In the third Li site, Li(3) is bonded to one O(1), one O(13), one O(17), one O(18), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(20), one O(26), and one O(32) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(19), one O(21), one O(25), one O(27), and one O(28) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(24), one O(28), and one O(30) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(17), one O(2), one O(3), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(10), one O(11), one O(13), one O(4), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. In the third V site, V(3) is bonded to one O(16), one O(19), one O(24), one O(25), one O(30), and one O(31) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. In the fourth V site, V(4) is bonded to one O(20), one O(22), one O(23), one O(26), one O(27), and one O(29) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(27), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 19-50°. In the second P site, P(2) is bonded to one O(31), one O(5), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-49°. In the third P site, P(3) is bonded to one O(10), one O(12), one O(16), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-51°. In the fourth P site, P(4) is bonded to one O(11), one O(15), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-51°. In the fifth P site, P(5) is bonded to one O(13), one O(14), one O(18), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 22-51°. In the sixth P site, P(6) is bonded to one O(17), one O(21), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 25-51°. In the seventh P site, P(7) is bonded to one O(2), one O(25), one O(26), and one O(28) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 22-49°. In the eighth P site, P(8) is bonded to one O(29), one O(30), one O(32), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 19-50°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(28) and one O(5) atom. In the second H site, H(2) is bonded in a linear geometry to one O(12) and one O(21) atom. In the third H site, H(3) is bonded in a linear geometry to one O(15) and one O(18) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(3), one P(1), and one H(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one P(7) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one V(2), and one P(8) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one V(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one Li(1), one V(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Li(1), one V(2), and one P(4) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one P(3), and one H(2) atom. In the thirteenth O site, O(13) is bonded in a T-shaped geometry to one Li(3), one V(2), and one P(5) atom. In the fourteenth O site, O(14) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one P(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one P(4), and one H(3) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Li(4), one V(3), and one P(3) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Li(3), one V(1), and one P(6) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Li(3), one P(5), and one H(3) atom. In the nineteenth O site, O(19) is bonded in a distorted T-shaped geometry to one Li(5), one V(3), and one P(4) atom. In the twentieth O site, O(20) is bonded in a T-shaped geometry to one Li(4), one V(4), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(5), one Li(6), one P(6), and one H(2) atom. In the twenty-second O site, O(22) is bonded in a trigonal planar geometry to one Li(6), one V(4), and one P(5) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one V(4) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted T-shaped geometry to one Li(6), one V(3), and one P(6) atom. In the twenty-fifth O site, O(25) is bonded in a T-shaped geometry to one Li(5), one V(3), and one P(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one V(4), and one P(7) atom. In the twenty-seventh O site, O(27) is bonded in a trigonal planar geometry to one Li(5), one V(4), and one P(1) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Li(5), one Li(6), one P(7), and one H(1) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one V(4) and one P(8) atom. In the thirtieth O site, O(30) is bonded in a distorted T-shaped geometry to one Li(6), one V(3), and one P(8) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one V(3) and one P(2) atom. In the thirty-second O site, O(32) is bonded in a distorted trigonal planar geometry to one Li(4), one P(8), and one H(4) atom.
Li3V2P4(HO8)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(3), one O(5), and one O(9) atom. The Li(1)-O(11) bond length is 2.00 Å. The Li(1)-O(12) bond length is 2.32 Å. The Li(1)-O(3) bond length is 2.06 Å. The Li(1)-O(5) bond length is 2.00 Å. The Li(1)-O(9) bond length is 2.00 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(5), one O(6), and one O(8) atom. The Li(2)-O(12) bond length is 1.97 Å. The Li(2)-O(14) bond length is 2.05 Å. The Li(2)-O(5) bond length is 2.39 Å. The Li(2)-O(6) bond length is 2.01 Å. The Li(2)-O(8) bond length is 1.99 Å. In the third Li site, Li(3) is bonded to one O(1), one O(13), one O(17), one O(18), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. The Li(3)-O(1) bond length is 1.97 Å. The Li(3)-O(13) bond length is 2.05 Å. The Li(3)-O(17) bond length is 2.01 Å. The Li(3)-O(18) bond length is 2.22 Å. The Li(3)-O(7) bond length is 2.11 Å. In the fourth Li site, Li(4) is bonded to one O(15), one O(16), one O(20), one O(26), and one O(32) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. The Li(4)-O(15) bond length is 2.18 Å. The Li(4)-O(16) bond length is 1.98 Å. The Li(4)-O(20) bond length is 2.07 Å. The Li(4)-O(26) bond length is 2.14 Å. The Li(4)-O(32) bond length is 2.01 Å. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(19), one O(21), one O(25), one O(27), and one O(28) atom. The Li(5)-O(19) bond length is 2.08 Å. The Li(5)-O(21) bond length is 2.01 Å. The Li(5)-O(25) bond length is 1.98 Å. The Li(5)-O(27) bond length is 2.00 Å. The Li(5)-O(28) bond length is 2.36 Å. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(24), one O(28), and one O(30) atom. The Li(6)-O(21) bond length is 2.35 Å. The Li(6)-O(22) bond length is 2.02 Å. The Li(6)-O(24) bond length is 2.01 Å. The Li(6)-O(28) bond length is 1.96 Å. The Li(6)-O(30) bond length is 2.04 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(17), one O(2), one O(3), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The V(1)-O(14) bond length is 2.09 Å. The V(1)-O(17) bond length is 2.10 Å. The V(1)-O(2) bond length is 1.98 Å. The V(1)-O(3) bond length is 2.11 Å. The V(1)-O(8) bond length is 2.00 Å. The V(1)-O(9) bond length is 1.98 Å. In the second V site, V(2) is bonded to one O(10), one O(11), one O(13), one O(4), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The V(2)-O(10) bond length is 1.93 Å. The V(2)-O(11) bond length is 2.02 Å. The V(2)-O(13) bond length is 1.96 Å. The V(2)-O(4) bond length is 1.84 Å. The V(2)-O(6) bond length is 2.07 Å. The V(2)-O(7) bond length is 2.07 Å. In the third V site, V(3) is bonded to one O(16), one O(19), one O(24), one O(25), one O(30), and one O(31) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The V(3)-O(16) bond length is 2.06 Å. The V(3)-O(19) bond length is 2.08 Å. The V(3)-O(24) bond length is 1.99 Å. The V(3)-O(25) bond length is 1.98 Å. The V(3)-O(30) bond length is 2.12 Å. The V(3)-O(31) bond length is 2.01 Å. In the fourth V site, V(4) is bonded to one O(20), one O(22), one O(23), one O(26), one O(27), and one O(29) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. The V(4)-O(20) bond length is 1.91 Å. The V(4)-O(22) bond length is 2.06 Å. The V(4)-O(23) bond length is 1.97 Å. The V(4)-O(26) bond length is 2.03 Å. The V(4)-O(27) bond length is 2.04 Å. The V(4)-O(29) bond length is 1.87 Å. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(27), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 19-50°. The P(1)-O(1) bond length is 1.52 Å. The P(1)-O(27) bond length is 1.57 Å. The P(1)-O(3) bond length is 1.54 Å. The P(1)-O(4) bond length is 1.59 Å. In the second P site, P(2) is bonded to one O(31), one O(5), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-49°. The P(2)-O(31) bond length is 1.52 Å. The P(2)-O(5) bond length is 1.58 Å. The P(2)-O(7) bond length is 1.55 Å. The P(2)-O(8) bond length is 1.55 Å. In the third P site, P(3) is bonded to one O(10), one O(12), one O(16), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-51°. The P(3)-O(10) bond length is 1.55 Å. The P(3)-O(12) bond length is 1.55 Å. The P(3)-O(16) bond length is 1.55 Å. The P(3)-O(9) bond length is 1.55 Å. In the fourth P site, P(4) is bonded to one O(11), one O(15), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-51°. The P(4)-O(11) bond length is 1.57 Å. The P(4)-O(15) bond length is 1.51 Å. The P(4)-O(19) bond length is 1.53 Å. The P(4)-O(20) bond length is 1.60 Å. In the fifth P site, P(5) is bonded to one O(13), one O(14), one O(18), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 22-51°. The P(5)-O(13) bond length is 1.57 Å. The P(5)-O(14) bond length is 1.53 Å. The P(5)-O(18) bond length is 1.55 Å. The P(5)-O(22) bond length is 1.56 Å. In the sixth P site, P(6) is bonded to one O(17), one O(21), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 25-51°. The P(6)-O(17) bond length is 1.54 Å. The P(6)-O(21) bond length is 1.58 Å. The P(6)-O(23) bond length is 1.53 Å. The P(6)-O(24) bond length is 1.54 Å. In the seventh P site, P(7) is bonded to one O(2), one O(25), one O(26), and one O(28) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 22-49°. The P(7)-O(2) bond length is 1.54 Å. The P(7)-O(25) bond length is 1.56 Å. The P(7)-O(26) bond length is 1.56 Å. The P(7)-O(28) bond length is 1.54 Å. In the eighth P site, P(8) is bonded to one O(29), one O(30), one O(32), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 19-50°. The P(8)-O(29) bond length is 1.57 Å. The P(8)-O(30) bond length is 1.53 Å. The P(8)-O(32) bond length is 1.56 Å. The P(8)-O(6) bond length is 1.55 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(28) and one O(5) atom. The H(1)-O(28) bond length is 1.40 Å. The H(1)-O(5) bond length is 1.08 Å. In the second H site, H(2) is bonded in a linear geometry to one O(12) and one O(21) atom. The H(2)-O(12) bond length is 1.38 Å. The H(2)-O(21) bond length is 1.08 Å. In the third H site, H(3) is bonded in a linear geometry to one O(15) and one O(18) atom. The H(3)-O(15) bond length is 1.40 Å. The H(3)-O(18) bond length is 1.08 Å. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. The H(4)-O(1) bond length is 1.40 Å. The H(4)-O(32) bond length is 1.08 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(3), one P(1), and one H(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one P(7) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one V(2), and one P(8) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one V(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one P(2) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one Li(1), one V(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Li(1), one V(2), and one P(4) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one P(3), and one H(2) atom. In the thirteenth O site, O(13) is bonded in a T-shaped geometry to one Li(3), one V(2), and one P(5) atom. In the fourteenth O site, O(14) is bonded in a distorted T-shaped geometry to one Li(2), one V(1), and one P(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one P(4), and one H(3) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Li(4), one V(3), and one P(3) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Li(3), one V(1), and one P(6) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Li(3), one P(5), and one H(3) atom. In the nineteenth O site, O(19) is bonded in a distorted T-shaped geometry to one Li(5), one V(3), and one P(4) atom. In the twentieth O site, O(20) is bonded in a T-shaped geometry to one Li(4), one V(4), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a 4-coordinate geometry to one Li(5), one Li(6), one P(6), and one H(2) atom. In the twenty-second O site, O(22) is bonded in a trigonal planar geometry to one Li(6), one V(4), and one P(5) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one V(4) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted T-shaped geometry to one Li(6), one V(3), and one P(6) atom. In the twenty-fifth O site, O(25) is bonded in a T-shaped geometry to one Li(5), one V(3), and one P(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one V(4), and one P(7) atom. In the twenty-seventh O site, O(27) is bonded in a trigonal planar geometry to one Li(5), one V(4), and one P(1) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one Li(5), one Li(6), one P(7), and one H(1) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one V(4) and one P(8) atom. In the thirtieth O site, O(30) is bonded in a distorted T-shaped geometry to one Li(6), one V(3), and one P(8) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one V(3) and one P(2) atom. In the thirty-second O site, O(32) is bonded in a distorted trigonal planar geometry to one Li(4), one P(8), and one H(4) atom.