(Mo2Cl9)2(N2)3 is Indium-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Mo2Cl9 clusters. In each Mo2Cl9 cluster, Mo(1) is bonded to three equivalent Cl(1) and three equivalent Cl(2) atoms to form face-sharing MoCl6 octahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms.
(Mo2Cl9)2(N2)3 is Indium-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Mo2Cl9 clusters. In each Mo2Cl9 cluster, Mo(1) is bonded to three equivalent Cl(1) and three equivalent Cl(2) atoms to form face-sharing MoCl6 octahedra. All Mo(1)-Cl(1) bond lengths are 2.48 Å. All Mo(1)-Cl(2) bond lengths are 2.29 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms.