Te(CF3)2(TeSO3)2 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four 13494-80-9 atoms, eight trifluoromethane molecules, and eight TeSO3 clusters. In four of the TeSO3 clusters, Te(1) is bonded in a 1-coordinate geometry to one O(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Te(1) and one S(1) atom. In four of the TeSO3 clusters, Te(3) is bonded in a distorted single-bond geometry to one O(4) atom. S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Te(3) and one S(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(2) atom.
Te(CF3)2(TeSO3)2 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four 13494-80-9 atoms, eight trifluoromethane molecules, and eight TeSO3 clusters. In four of the TeSO3 clusters, Te(1) is bonded in a 1-coordinate geometry to one O(2) atom. The Te(1)-O(2) bond length is 2.74 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.46 Å. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Te(1) and one S(1) atom. In four of the TeSO3 clusters, Te(3) is bonded in a distorted single-bond geometry to one O(4) atom. The Te(3)-O(4) bond length is 2.67 Å. S(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.48 Å. The S(2)-O(5) bond length is 1.45 Å. The S(2)-O(6) bond length is 1.47 Å. There are three inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Te(3) and one S(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(2) atom.