ZnSnO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Zn(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Sn(1) is bonded to six equivalent O(1) atoms to form edge-sharing SnO6 octahedra. O(1) is bonded to two equivalent Zn(1) and two equivalent Sn(1) atoms to form a mixture of distorted edge and corner-sharing OZn2Sn2 trigonal pyramids.
ZnSnO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Zn(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.06 Å) and three longer (2.34 Å) Zn(1)-O(1) bond lengths. Sn(1) is bonded to six equivalent O(1) atoms to form edge-sharing SnO6 octahedra. There are three shorter (2.07 Å) and three longer (2.15 Å) Sn(1)-O(1) bond lengths. O(1) is bonded to two equivalent Zn(1) and two equivalent Sn(1) atoms to form a mixture of distorted edge and corner-sharing OZn2Sn2 trigonal pyramids.