PrSO crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 4-coordinate geometry to three equivalent S(1) and four equivalent O(1) atoms. S(1) is bonded in a 4-coordinate geometry to three equivalent Pr(1) and one S(1) atom. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of corner and edge-sharing OPr4 tetrahedra.
PrSO crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 4-coordinate geometry to three equivalent S(1) and four equivalent O(1) atoms. There are two shorter (3.04 Å) and one longer (3.30 Å) Pr(1)-S(1) bond length. There are a spread of Pr(1)-O(1) bond distances ranging from 2.34-2.45 Å. S(1) is bonded in a 4-coordinate geometry to three equivalent Pr(1) and one S(1) atom. The S(1)-S(1) bond length is 2.10 Å. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of corner and edge-sharing OPr4 tetrahedra.