Ba2Ag2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form AgF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Zn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Ag(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded to two equivalent Ba(1), one Ag(1), and one Cu(1) atom to form a mixture of distorted corner and edge-sharing FBa2CuAg tetrahedra. In the sixth F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Ag(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom.
Ba2Ag2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. The Ba(1)-F(1) bond length is 2.82 Å. The Ba(1)-F(4) bond length is 2.75 Å. The Ba(1)-F(6) bond length is 2.98 Å. The Ba(1)-F(7) bond length is 3.07 Å. There is one shorter (2.82 Å) and one longer (2.92 Å) Ba(1)-F(2) bond length. There is one shorter (2.71 Å) and one longer (3.04 Å) Ba(1)-F(3) bond length. There is one shorter (2.73 Å) and one longer (2.77 Å) Ba(1)-F(5) bond length. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form AgF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. The Ag(1)-F(1) bond length is 2.13 Å. The Ag(1)-F(2) bond length is 2.15 Å. The Ag(1)-F(3) bond length is 2.09 Å. The Ag(1)-F(5) bond length is 2.17 Å. The Ag(1)-F(6) bond length is 2.20 Å. The Ag(1)-F(7) bond length is 2.19 Å. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form distorted CuF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Both Cu(1)-F(2) bond lengths are 2.48 Å. Both Cu(1)-F(4) bond lengths are 1.88 Å. Both Cu(1)-F(7) bond lengths are 1.88 Å. Zn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. Both Zn(1)-F(1) bond lengths are 2.10 Å. Both Zn(1)-F(4) bond lengths are 2.38 Å. Both Zn(1)-F(6) bond lengths are 2.04 Å. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Ag(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded to two equivalent Ba(1), one Ag(1), and one Cu(1) atom to form a mixture of distorted corner and edge-sharing FBa2CuAg tetrahedra. In the sixth F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Ag(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom.