Li3Co5OF11 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(8), and one F(9) atom. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one O(1), one F(2), one F(7), and one F(9) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one F(10), one F(11), one F(3), and one F(8) atom. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a rectangular see-saw-like geometry to one O(1), one F(10), one F(2), and one F(5) atom. In the second Co site, Co(2) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(7), one F(8), and one F(9) atom. In the third Co site, Co(3) is bonded in a 4-coordinate geometry to one O(1), one F(10), one F(11), and one F(6) atom. In the fourth Co site, Co(4) is bonded in a 2-coordinate geometry to one O(1), one F(1), one F(11), and one F(9) atom. In the fifth Co site, Co(5) is bonded in a 2-coordinate geometry to one F(10), one F(6), one F(7), and one F(8) atom. O(1) is bonded in a 4-coordinate geometry to one Li(2), one Co(1), one Co(3), and one Co(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Co(2) and one Co(4) atom. In the second F site, F(2) is bonded in a water-like geometry to one Li(2) and one Co(1) atom. In the third F site, F(3) is bonded in a distorted water-like geometry to one Li(1) and one Li(3) atom. In the fourth F site, F(4) is bonded in a 1-coordinate geometry to one Li(1) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Co(1) atom. In the sixth F site, F(6) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one Co(5) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(2), and one Co(5) atom. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Co(2), and one Co(5) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Co(2), and one Co(4) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(3), one Co(1), one Co(3), and one Co(5) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Co(3), and one Co(4) atom.
Li3Co5OF11 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(8), and one F(9) atom. The Li(1)-F(3) bond length is 1.73 Å. The Li(1)-F(4) bond length is 2.01 Å. The Li(1)-F(8) bond length is 2.21 Å. The Li(1)-F(9) bond length is 1.91 Å. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one O(1), one F(2), one F(7), and one F(9) atom. The Li(2)-O(1) bond length is 2.36 Å. The Li(2)-F(2) bond length is 1.88 Å. The Li(2)-F(7) bond length is 2.44 Å. The Li(2)-F(9) bond length is 1.91 Å. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one F(10), one F(11), one F(3), and one F(8) atom. The Li(3)-F(10) bond length is 1.86 Å. The Li(3)-F(11) bond length is 2.43 Å. The Li(3)-F(3) bond length is 1.80 Å. The Li(3)-F(8) bond length is 2.31 Å. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a rectangular see-saw-like geometry to one O(1), one F(10), one F(2), and one F(5) atom. The Co(1)-O(1) bond length is 1.93 Å. The Co(1)-F(10) bond length is 1.93 Å. The Co(1)-F(2) bond length is 1.86 Å. The Co(1)-F(5) bond length is 2.07 Å. In the second Co site, Co(2) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(7), one F(8), and one F(9) atom. The Co(2)-F(1) bond length is 1.83 Å. The Co(2)-F(7) bond length is 2.04 Å. The Co(2)-F(8) bond length is 1.82 Å. The Co(2)-F(9) bond length is 2.05 Å. In the third Co site, Co(3) is bonded in a 4-coordinate geometry to one O(1), one F(10), one F(11), and one F(6) atom. The Co(3)-O(1) bond length is 1.84 Å. The Co(3)-F(10) bond length is 2.17 Å. The Co(3)-F(11) bond length is 2.09 Å. The Co(3)-F(6) bond length is 1.75 Å. In the fourth Co site, Co(4) is bonded in a 2-coordinate geometry to one O(1), one F(1), one F(11), and one F(9) atom. The Co(4)-O(1) bond length is 1.68 Å. The Co(4)-F(1) bond length is 1.87 Å. The Co(4)-F(11) bond length is 2.38 Å. The Co(4)-F(9) bond length is 2.35 Å. In the fifth Co site, Co(5) is bonded in a 2-coordinate geometry to one F(10), one F(6), one F(7), and one F(8) atom. The Co(5)-F(10) bond length is 2.39 Å. The Co(5)-F(6) bond length is 1.78 Å. The Co(5)-F(7) bond length is 2.18 Å. The Co(5)-F(8) bond length is 1.86 Å. O(1) is bonded in a 4-coordinate geometry to one Li(2), one Co(1), one Co(3), and one Co(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Co(2) and one Co(4) atom. In the second F site, F(2) is bonded in a water-like geometry to one Li(2) and one Co(1) atom. In the third F site, F(3) is bonded in a distorted water-like geometry to one Li(1) and one Li(3) atom. In the fourth F site, F(4) is bonded in a 1-coordinate geometry to one Li(1) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Co(1) atom. In the sixth F site, F(6) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one Co(5) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(2), and one Co(5) atom. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Co(2), and one Co(5) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Co(2), and one Co(4) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(3), one Co(1), one Co(3), and one Co(5) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Co(3), and one Co(4) atom.