YTi(WO4)2 is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. Y(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form distorted YO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-61°. Ti(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted TiO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(6), two equivalent O(3), and two equivalent O(8) atoms to form WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. In the second W site, W(2) is bonded to one O(1), one O(5), two equivalent O(4), and two equivalent O(7) atoms to form WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-60°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Y(1), one Ti(1), and one W(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one Ti(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent W(2) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Y(1), one Ti(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Y(1), one Ti(1), and one W(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(2) atoms. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(1) atoms.
YTi(WO4)2 is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. Y(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form distorted YO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-61°. The Y(1)-O(1) bond length is 2.32 Å. The Y(1)-O(2) bond length is 2.29 Å. The Y(1)-O(5) bond length is 2.31 Å. The Y(1)-O(6) bond length is 2.29 Å. The Y(1)-O(7) bond length is 2.16 Å. The Y(1)-O(8) bond length is 2.21 Å. Ti(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted TiO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. The Ti(1)-O(1) bond length is 1.93 Å. The Ti(1)-O(2) bond length is 1.94 Å. The Ti(1)-O(3) bond length is 2.26 Å. The Ti(1)-O(4) bond length is 1.90 Å. The Ti(1)-O(5) bond length is 1.91 Å. The Ti(1)-O(6) bond length is 2.44 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(6), two equivalent O(3), and two equivalent O(8) atoms to form WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. The W(1)-O(2) bond length is 2.02 Å. The W(1)-O(6) bond length is 1.87 Å. There is one shorter (2.06 Å) and one longer (2.11 Å) W(1)-O(3) bond length. There is one shorter (2.03 Å) and one longer (2.07 Å) W(1)-O(8) bond length. In the second W site, W(2) is bonded to one O(1), one O(5), two equivalent O(4), and two equivalent O(7) atoms to form WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-60°. The W(2)-O(1) bond length is 2.03 Å. The W(2)-O(5) bond length is 2.08 Å. There is one shorter (2.14 Å) and one longer (2.22 Å) W(2)-O(4) bond length. There is one shorter (2.02 Å) and one longer (2.08 Å) W(2)-O(7) bond length. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Y(1), one Ti(1), and one W(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one Ti(1), and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent W(2) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Y(1), one Ti(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Y(1), one Ti(1), and one W(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(2) atoms. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(1) atoms.