VH10S2(NO4)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(4) atoms. N(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(4) atom. In the fourth H site, H(4) is bonded in a bent 150 degrees geometry to one O(2) and one O(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one S(1) atom. In the second O site, O(4) is bonded in a 4-coordinate geometry to one V(1), one H(1), one H(3), and one H(4) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one H(1), one H(4), and one H(5) atom.
VH10S2(NO4)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(4) atoms. Both V(1)-N(1) bond lengths are 1.90 Å. Both V(1)-O(1) bond lengths are 2.13 Å. Both V(1)-O(4) bond lengths are 2.02 Å. N(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. The N(1)-S(1) bond length is 1.54 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. The H(1)-O(2) bond length is 0.99 Å. The H(1)-O(4) bond length is 1.58 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 0.98 Å. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(4) atom. The H(3)-O(3) bond length is 1.50 Å. The H(3)-O(4) bond length is 1.03 Å. In the fourth H site, H(4) is bonded in a bent 150 degrees geometry to one O(2) and one O(4) atom. The H(4)-O(2) bond length is 1.54 Å. The H(4)-O(4) bond length is 1.03 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. The H(5)-O(2) bond length is 0.99 Å. S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(3) atom. The S(1)-O(1) bond length is 1.56 Å. The S(1)-O(3) bond length is 1.79 Å. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one S(1) atom. In the second O site, O(4) is bonded in a 4-coordinate geometry to one V(1), one H(1), one H(3), and one H(4) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one H(1), one H(4), and one H(5) atom.