PbP2H4O8 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PbP2H4O8 clusters. Pb(1) is bonded in a 3-coordinate geometry to one H(4), one O(3), and one O(4) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one O(4), one O(6), and one O(7) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Pb(1) and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one P(2) and one H(2) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one P(1) and one H(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one P(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one H(4) atom.
PbP2H4O8 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PbP2H4O8 clusters. Pb(1) is bonded in a 3-coordinate geometry to one H(4), one O(3), and one O(4) atom. The Pb(1)-H(4) bond length is 2.29 Å. The Pb(1)-O(3) bond length is 2.63 Å. The Pb(1)-O(4) bond length is 2.29 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one O(4), one O(6), and one O(7) atom. The P(1)-O(4) bond length is 1.31 Å. The P(1)-O(6) bond length is 1.62 Å. The P(1)-O(7) bond length is 2.01 Å. In the second P site, P(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. The P(2)-O(1) bond length is 1.58 Å. The P(2)-O(2) bond length is 2.09 Å. The P(2)-O(3) bond length is 1.47 Å. The P(2)-O(5) bond length is 1.72 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.36 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 0.88 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) atom. The H(3)-O(6) bond length is 1.35 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one Pb(1) and one O(8) atom. The H(4)-O(8) bond length is 0.71 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one P(2) and one H(2) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one P(1) and one H(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one P(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one H(4) atom.