CoN2(OCl)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 7727-37-9 molecules and four CoN2(OCl)2 clusters. In each CoN2(OCl)2 cluster, Co(1) is bonded in a trigonal planar geometry to one N(2) and two equivalent Cl(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a linear geometry to one Co(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom.
CoN2(OCl)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 7727-37-9 molecules and four CoN2(OCl)2 clusters. In each CoN2(OCl)2 cluster, Co(1) is bonded in a trigonal planar geometry to one N(2) and two equivalent Cl(1) atoms. The Co(1)-N(2) bond length is 1.77 Å. Both Co(1)-Cl(1) bond lengths are 2.10 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent O(1) atoms. The N(1)-N(2) bond length is 1.28 Å. Both N(1)-O(1) bond lengths are 1.25 Å. In the second N site, N(2) is bonded in a linear geometry to one Co(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom.