NbRh is Tetraauricupride-like structured and crystallizes in the monoclinic P2/m space group. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a 8-coordinate geometry to two equivalent Rh(1) and six equivalent Rh(2) atoms. In the second Nb site, Nb(2) is bonded in a 8-coordinate geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Nb(1) and four equivalent Nb(2) atoms to form a mixture of distorted edge, corner, and face-sharing RhNb8 cuboctahedra. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to two equivalent Nb(2) and six equivalent Nb(1) atoms.
NbRh is Tetraauricupride-like structured and crystallizes in the monoclinic P2/m space group. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a 8-coordinate geometry to two equivalent Rh(1) and six equivalent Rh(2) atoms. Both Nb(1)-Rh(1) bond lengths are 2.77 Å. There are a spread of Nb(1)-Rh(2) bond distances ranging from 2.74-2.88 Å. In the second Nb site, Nb(2) is bonded in a 8-coordinate geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. All Nb(2)-Rh(1) bond lengths are 2.83 Å. All Nb(2)-Rh(2) bond lengths are 2.77 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Nb(1) and four equivalent Nb(2) atoms to form a mixture of distorted edge, corner, and face-sharing RhNb8 cuboctahedra. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to two equivalent Nb(2) and six equivalent Nb(1) atoms.