SbF6ClO2 is beta-prime cadmium gold structured and crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two hydroxychloride hydrate molecules and two SbF6 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom.
SbF6ClO2 is beta-prime cadmium gold structured and crystallizes in the orthorhombic Pmmn space group. The structure is zero-dimensional and consists of two hydroxychloride hydrate molecules and two SbF6 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Sb(1)-F(1) bond lengths are 1.91 Å. Both Sb(1)-F(2) bond lengths are 1.95 Å. Both Sb(1)-F(3) bond lengths are 1.91 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom.