ZnPbN2 is Lavarevi\'{c}ite-like structured and crystallizes in the orthorhombic Pna2_1 space group. Zn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form ZnN4 tetrahedra that share corners with four equivalent Zn(1)N4 tetrahedra and corners with eight equivalent Pb(1)N4 tetrahedra. Pb(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form PbN4 tetrahedra that share corners with four equivalent Pb(1)N4 tetrahedra and corners with eight equivalent Zn(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Zn(1) and two equivalent Pb(1) atoms to form corner-sharing NZn2Pb2 tetrahedra. In the second N site, N(2) is bonded to two equivalent Zn(1) and two equivalent Pb(1) atoms to form corner-sharing NZn2Pb2 tetrahedra.
ZnPbN2 is Lavarevi\'{c}ite-like structured and crystallizes in the orthorhombic Pna2_1 space group. Zn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form ZnN4 tetrahedra that share corners with four equivalent Zn(1)N4 tetrahedra and corners with eight equivalent Pb(1)N4 tetrahedra. There is one shorter (2.07 Å) and one longer (2.08 Å) Zn(1)-N(1) bond length. There is one shorter (2.06 Å) and one longer (2.07 Å) Zn(1)-N(2) bond length. Pb(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form PbN4 tetrahedra that share corners with four equivalent Pb(1)N4 tetrahedra and corners with eight equivalent Zn(1)N4 tetrahedra. Both Pb(1)-N(1) bond lengths are 2.23 Å. There is one shorter (2.21 Å) and one longer (2.22 Å) Pb(1)-N(2) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Zn(1) and two equivalent Pb(1) atoms to form corner-sharing NZn2Pb2 tetrahedra. In the second N site, N(2) is bonded to two equivalent Zn(1) and two equivalent Pb(1) atoms to form corner-sharing NZn2Pb2 tetrahedra.