NdMoO2 crystallizes in the tetragonal I4_1/amd space group. Nd(1) is bonded to six equivalent O(1) atoms to form edge-sharing NdO6 octahedra. Mo(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Nd(1) and two equivalent Mo(1) atoms to form a mixture of distorted edge and corner-sharing ONd3Mo2 trigonal bipyramids.
NdMoO2 crystallizes in the tetragonal I4_1/amd space group. Nd(1) is bonded to six equivalent O(1) atoms to form edge-sharing NdO6 octahedra. All Nd(1)-O(1) bond lengths are 2.48 Å. Mo(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Mo(1)-O(1) bond lengths are 2.24 Å. O(1) is bonded to three equivalent Nd(1) and two equivalent Mo(1) atoms to form a mixture of distorted edge and corner-sharing ONd3Mo2 trigonal bipyramids.