K2Cu(BrF)2 crystallizes in the tetragonal P4/mmm space group. K(1) is bonded to two equivalent Br(1) and four equivalent F(1,2) atoms to form a mixture of distorted edge and corner-sharing KBr2F4 octahedra. The corner-sharing octahedra are not tilted. Cu(1) is bonded in a square co-planar geometry to four equivalent Br(1) atoms. Br(1) is bonded in a square co-planar geometry to two equivalent K(1) and two equivalent Cu(1) atoms. F(1,2) is bonded in a square co-planar geometry to four equivalent K(1) atoms.
K2Cu(BrF)2 crystallizes in the tetragonal P4/mmm space group. K(1) is bonded to two equivalent Br(1) and four equivalent F(1,2) atoms to form a mixture of distorted edge and corner-sharing KBr2F4 octahedra. The corner-sharing octahedra are not tilted. Both K(1)-Br(1) bond lengths are 3.32 Å. All K(1)-F(1,2) bond lengths are 2.51 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent Br(1) atoms. All Cu(1)-Br(1) bond lengths are 2.51 Å. Br(1) is bonded in a square co-planar geometry to two equivalent K(1) and two equivalent Cu(1) atoms. F(1,2) is bonded in a square co-planar geometry to four equivalent K(1) atoms.