Ti3Hg4Zn is Tetraauricupride-derived structured and crystallizes in the tetragonal P4/mmm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted body-centered cubic geometry to four equivalent Hg(1) and four equivalent Hg(2) atoms. In the second Ti site, Ti(2) is bonded in a distorted body-centered cubic geometry to eight equivalent Hg(2) atoms. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ti(1) and four equivalent Zn(1) atoms. In the second Hg site, Hg(2) is bonded in a distorted body-centered cubic geometry to four equivalent Ti(1) and four equivalent Ti(2) atoms. Zn(1) is bonded in a distorted body-centered cubic geometry to eight equivalent Hg(1) atoms.
Ti3Hg4Zn is Tetraauricupride-derived structured and crystallizes in the tetragonal P4/mmm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a distorted body-centered cubic geometry to four equivalent Hg(1) and four equivalent Hg(2) atoms. All Ti(1)-Hg(1) bond lengths are 2.95 Å. All Ti(1)-Hg(2) bond lengths are 2.95 Å. In the second Ti site, Ti(2) is bonded in a distorted body-centered cubic geometry to eight equivalent Hg(2) atoms. All Ti(2)-Hg(2) bond lengths are 2.96 Å. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ti(1) and four equivalent Zn(1) atoms. All Hg(1)-Zn(1) bond lengths are 2.94 Å. In the second Hg site, Hg(2) is bonded in a distorted body-centered cubic geometry to four equivalent Ti(1) and four equivalent Ti(2) atoms. Zn(1) is bonded in a distorted body-centered cubic geometry to eight equivalent Hg(1) atoms.