TiRhAs is half-Heusler structured and crystallizes in the cubic F-43m space group. Ti(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent As(1) atoms. Rh(1) is bonded to four equivalent Ti(1) atoms to form RhTi4 tetrahedra that share corners with four equivalent As(1)Ti4 tetrahedra, corners with twelve equivalent Rh(1)Ti4 tetrahedra, and edges with six equivalent As(1)Ti4 tetrahedra. As(1) is bonded to four equivalent Ti(1) atoms to form distorted AsTi4 tetrahedra that share corners with four equivalent Rh(1)Ti4 tetrahedra, corners with twelve equivalent As(1)Ti4 tetrahedra, and edges with six equivalent Rh(1)Ti4 tetrahedra.
TiRhAs is half-Heusler structured and crystallizes in the cubic F-43m space group. Ti(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent As(1) atoms. All Ti(1)-Rh(1) bond lengths are 2.58 Å. All Ti(1)-As(1) bond lengths are 2.58 Å. Rh(1) is bonded to four equivalent Ti(1) atoms to form RhTi4 tetrahedra that share corners with four equivalent As(1)Ti4 tetrahedra, corners with twelve equivalent Rh(1)Ti4 tetrahedra, and edges with six equivalent As(1)Ti4 tetrahedra. As(1) is bonded to four equivalent Ti(1) atoms to form distorted AsTi4 tetrahedra that share corners with four equivalent Rh(1)Ti4 tetrahedra, corners with twelve equivalent As(1)Ti4 tetrahedra, and edges with six equivalent Rh(1)Ti4 tetrahedra.