Na2Al2Si3(HO3)4 crystallizes in the triclinic P1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(14), one O(15), one O(20), one O(24), one O(4), and one O(6) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra, edges with two equivalent Na(4)O6 pentagonal pyramids,  an edgeedge with one Si(4)O4 tetrahedra, and  an edgeedge with one Si(5)O4 tetrahedra. In the second Na site, Na(2) is bonded to one O(10), one O(11), one O(17), one O(19), one O(2), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, edges with two equivalent Na(3)O6 pentagonal pyramids,  an edgeedge with one Al(1)O4 tetrahedra, and  an edgeedge with one Al(4)O4 tetrahedra. In the third Na site, Na(3) is bonded to one O(10), one O(13), one O(18), one O(19), one O(2), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, edges with two equivalent Na(2)O6 pentagonal pyramids,  an edgeedge with one Si(2)O4 tetrahedra, and  an edgeedge with one Si(6)O4 tetrahedra. In the fourth Na site, Na(4) is bonded to one O(14), one O(15), one O(16), one O(22), one O(24), and one O(6) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, edges with two equivalent Na(1)O6 pentagonal pyramids,  an edgeedge with one Al(2)O4 tetrahedra, and  an edgeedge with one Al(3)O4 tetrahedra. There are four inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(1), one O(11), one O(2), and one O(4) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(2)O6 pentagonal pyramid. In the second Al site, Al(2) is bonded to one O(14), one O(16), one O(18), and one O(8) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(4)O6 pentagonal pyramid. In the third Al site, Al(3) is bonded to one O(11), one O(15), one O(22), and one O(23) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, and  an edgeedge with one Na(4)O6 pentagonal pyramid. In the fourth Al site, Al(4) is bonded to one O(16), one O(17), one O(19), and one O(3) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, and  an edgeedge with one Na(2)O6 pentagonal pyramid. There are six inequivalent Si sites. In the first Si site, Si(1) is bonded to one O(1), one O(12), one O(21), and one O(23) atom to form SiO4 tetrahedra that share  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. In the second Si site, Si(2) is bonded to one O(18), one O(2), one O(20), and one O(5) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra, and  an edgeedge with one Na(3)O6 pentagonal pyramid. In the third Si site, Si(3) is bonded to one O(3), one O(5), one O(8), and one O(9) atom to form SiO4 tetrahedra that share  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra, and  a cornercorner with one Si(5)O4 tetrahedra. In the fourth Si site, Si(4) is bonded to one O(13), one O(14), one O(21), and one O(4) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, and  an edgeedge with one Na(1)O6 pentagonal pyramid. In the fifth Si site, Si(5) is bonded to one O(15), one O(17), one O(20), and one O(9) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra, and  an edgeedge with one Na(1)O6 pentagonal pyramid. In the sixth Si site, Si(6) is bonded to one O(12), one O(13), one O(19), and one O(22) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(3)O6 pentagonal pyramid. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(24) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(24) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Al(1) and one Si(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Al(1), and one Si(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Al(4) and one Si(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one Al(1), and one Si(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Si(2) and one Si(3) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Na(1), one Na(4), one H(1), and one H(4) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(3), and one H(6) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Al(2) and one Si(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Si(3) and one Si(5) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(5), and one H(7) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Na(2), one Al(1), and one Al(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Si(1) and one Si(6) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(3), one Si(4), and one Si(6) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(1), one Na(4), one Al(2), and one Si(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Na(1), one Na(4), one Al(3), and one Si(5) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Na(4), one Al(2), and one Al(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Na(2), one Al(4), and one Si(5) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(3), one Al(2), and one Si(2) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Al(4), and one Si(6) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Na(1), one Si(2), and one Si(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Si(1) and one Si(4) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(4), one Al(3), and one Si(6) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Al(3) and one Si(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted water-like geometry to one Na(1), one Na(4), one H(2), and one H(8) atom.
Na2Al2Si3(HO3)4 crystallizes in the triclinic P1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(14), one O(15), one O(20), one O(24), one O(4), and one O(6) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra, edges with two equivalent Na(4)O6 pentagonal pyramids,  an edgeedge with one Si(4)O4 tetrahedra, and  an edgeedge with one Si(5)O4 tetrahedra. The Na(1)-O(14) bond length is 2.58 Å. The Na(1)-O(15) bond length is 2.54 Å. The Na(1)-O(20) bond length is 2.51 Å. The Na(1)-O(24) bond length is 2.42 Å. The Na(1)-O(4) bond length is 2.44 Å. The Na(1)-O(6) bond length is 2.42 Å. In the second Na site, Na(2) is bonded to one O(10), one O(11), one O(17), one O(19), one O(2), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, edges with two equivalent Na(3)O6 pentagonal pyramids,  an edgeedge with one Al(1)O4 tetrahedra, and  an edgeedge with one Al(4)O4 tetrahedra. The Na(2)-O(10) bond length is 2.47 Å. The Na(2)-O(11) bond length is 2.32 Å. The Na(2)-O(17) bond length is 2.46 Å. The Na(2)-O(19) bond length is 2.62 Å. The Na(2)-O(2) bond length is 2.62 Å. The Na(2)-O(7) bond length is 2.44 Å. In the third Na site, Na(3) is bonded to one O(10), one O(13), one O(18), one O(19), one O(2), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, edges with two equivalent Na(2)O6 pentagonal pyramids,  an edgeedge with one Si(2)O4 tetrahedra, and  an edgeedge with one Si(6)O4 tetrahedra. The Na(3)-O(10) bond length is 2.43 Å. The Na(3)-O(13) bond length is 2.53 Å. The Na(3)-O(18) bond length is 2.42 Å. The Na(3)-O(19) bond length is 2.54 Å. The Na(3)-O(2) bond length is 2.58 Å. The Na(3)-O(7) bond length is 2.43 Å. In the fourth Na site, Na(4) is bonded to one O(14), one O(15), one O(16), one O(22), one O(24), and one O(6) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, edges with two equivalent Na(1)O6 pentagonal pyramids,  an edgeedge with one Al(2)O4 tetrahedra, and  an edgeedge with one Al(3)O4 tetrahedra. The Na(4)-O(14) bond length is 2.62 Å. The Na(4)-O(15) bond length is 2.62 Å. The Na(4)-O(16) bond length is 2.32 Å. The Na(4)-O(22) bond length is 2.45 Å. The Na(4)-O(24) bond length is 2.47 Å. The Na(4)-O(6) bond length is 2.46 Å. There are four inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(1), one O(11), one O(2), and one O(4) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(2)O6 pentagonal pyramid. The Al(1)-O(1) bond length is 1.77 Å. The Al(1)-O(11) bond length is 1.73 Å. The Al(1)-O(2) bond length is 1.77 Å. The Al(1)-O(4) bond length is 1.76 Å. In the second Al site, Al(2) is bonded to one O(14), one O(16), one O(18), and one O(8) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(4)O6 pentagonal pyramid. The Al(2)-O(14) bond length is 1.77 Å. The Al(2)-O(16) bond length is 1.72 Å. The Al(2)-O(18) bond length is 1.76 Å. The Al(2)-O(8) bond length is 1.77 Å. In the third Al site, Al(3) is bonded to one O(11), one O(15), one O(22), and one O(23) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, and  an edgeedge with one Na(4)O6 pentagonal pyramid. The Al(3)-O(11) bond length is 1.72 Å. The Al(3)-O(15) bond length is 1.79 Å. The Al(3)-O(22) bond length is 1.78 Å. The Al(3)-O(23) bond length is 1.77 Å. In the fourth Al site, Al(4) is bonded to one O(16), one O(17), one O(19), and one O(3) atom to form AlO4 tetrahedra that share  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, and  an edgeedge with one Na(2)O6 pentagonal pyramid. The Al(4)-O(16) bond length is 1.72 Å. The Al(4)-O(17) bond length is 1.78 Å. The Al(4)-O(19) bond length is 1.79 Å. The Al(4)-O(3) bond length is 1.77 Å. There are six inequivalent Si sites. In the first Si site, Si(1) is bonded to one O(1), one O(12), one O(21), and one O(23) atom to form SiO4 tetrahedra that share  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. The Si(1)-O(1) bond length is 1.62 Å. The Si(1)-O(12) bond length is 1.66 Å. The Si(1)-O(21) bond length is 1.65 Å. The Si(1)-O(23) bond length is 1.62 Å. In the second Si site, Si(2) is bonded to one O(18), one O(2), one O(20), and one O(5) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra, and  an edgeedge with one Na(3)O6 pentagonal pyramid. The Si(2)-O(18) bond length is 1.62 Å. The Si(2)-O(2) bond length is 1.62 Å. The Si(2)-O(20) bond length is 1.66 Å. The Si(2)-O(5) bond length is 1.65 Å. In the third Si site, Si(3) is bonded to one O(3), one O(5), one O(8), and one O(9) atom to form SiO4 tetrahedra that share  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra, and  a cornercorner with one Si(5)O4 tetrahedra. The Si(3)-O(3) bond length is 1.62 Å. The Si(3)-O(5) bond length is 1.65 Å. The Si(3)-O(8) bond length is 1.62 Å. The Si(3)-O(9) bond length is 1.66 Å. In the fourth Si site, Si(4) is bonded to one O(13), one O(14), one O(21), and one O(4) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(3)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(1)O4 tetrahedra,  a cornercorner with one Al(2)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra, and  an edgeedge with one Na(1)O6 pentagonal pyramid. The Si(4)-O(13) bond length is 1.66 Å. The Si(4)-O(14) bond length is 1.62 Å. The Si(4)-O(21) bond length is 1.65 Å. The Si(4)-O(4) bond length is 1.62 Å. In the fifth Si site, Si(5) is bonded to one O(15), one O(17), one O(20), and one O(9) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra, and  an edgeedge with one Na(1)O6 pentagonal pyramid. The Si(5)-O(15) bond length is 1.63 Å. The Si(5)-O(17) bond length is 1.62 Å. The Si(5)-O(20) bond length is 1.66 Å. The Si(5)-O(9) bond length is 1.65 Å. In the sixth Si site, Si(6) is bonded to one O(12), one O(13), one O(19), and one O(22) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one Na(4)O6 pentagonal pyramid,  a cornercorner with one Al(3)O4 tetrahedra,  a cornercorner with one Al(4)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(3)O6 pentagonal pyramid. The Si(6)-O(12) bond length is 1.65 Å. The Si(6)-O(13) bond length is 1.66 Å. The Si(6)-O(19) bond length is 1.64 Å. The Si(6)-O(22) bond length is 1.62 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(24) atom. The H(2)-O(24) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. The H(4)-O(6) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(10) atom. The H(5)-O(10) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(7) atom. The H(6)-O(7) bond length is 0.98 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(10) atom. The H(7)-O(10) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(24) atom. The H(8)-O(24) bond length is 0.98 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Al(1) and one Si(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Al(1), and one Si(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Al(4) and one Si(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one Al(1), and one Si(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Si(2) and one Si(3) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Na(1), one Na(4), one H(1), and one H(4) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(3), and one H(6) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Al(2) and one Si(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Si(3) and one Si(5) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(5), and one H(7) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Na(2), one Al(1), and one Al(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Si(1) and one Si(6) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(3), one Si(4), and one Si(6) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(1), one Na(4), one Al(2), and one Si(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Na(1), one Na(4), one Al(3), and one Si(5) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Na(4), one Al(2), and one Al(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Na(2), one Al(4), and one Si(5) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(3), one Al(2), and one Si(2) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Al(4), and one Si(6) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Na(1), one Si(2), and one Si(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Si(1) and one Si(4) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(4), one Al(3), and one Si(6) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Al(3) and one Si(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted water-like geometry to one Na(1), one Na(4), one H(2), and one H(8) atom.