CoO6AlF6 is Tetraauricupride structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four cobalt;hexahydrate molecules and four AlF6 clusters. In each AlF6 cluster, Al(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Al(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Al(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Al(1) atom.
CoO6AlF6 is Tetraauricupride structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four cobalt;hexahydrate molecules and four AlF6 clusters. In each AlF6 cluster, Al(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Al(1)-F(1) bond lengths are 1.83 Å. Both Al(1)-F(2) bond lengths are 1.82 Å. Both Al(1)-F(3) bond lengths are 1.84 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Al(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Al(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Al(1) atom.