ErCo(CN)6 is alpha Rhenium trioxide-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Er(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent N(1) atoms. Co(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. N(1) is bonded in a linear geometry to one Er(1) and one C(1) atom.
ErCo(CN)6 is alpha Rhenium trioxide-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Er(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent N(1) atoms. All Er(1)-N(1) bond lengths are 2.33 Å. Co(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. All Co(1)-C(1) bond lengths are 1.87 Å. C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. N(1) is bonded in a linear geometry to one Er(1) and one C(1) atom.