NaCdSb crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 11-coordinate geometry to six equivalent Cd(1) and five equivalent Sb(1) atoms. Cd(1) is bonded in a 10-coordinate geometry to six equivalent Na(1) and four equivalent Sb(1) atoms. Sb(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Cd(1) atoms.
NaCdSb crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 11-coordinate geometry to six equivalent Cd(1) and five equivalent Sb(1) atoms. There are a spread of Na(1)-Cd(1) bond distances ranging from 3.42-3.69 Å. There are a spread of Na(1)-Sb(1) bond distances ranging from 3.21-3.43 Å. Cd(1) is bonded in a 10-coordinate geometry to six equivalent Na(1) and four equivalent Sb(1) atoms. There are a spread of Cd(1)-Sb(1) bond distances ranging from 2.89-3.00 Å. Sb(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Cd(1) atoms.