(Rb)2CsAsBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsAsBr6 framework. In the CsAsBr6 framework, Cs(1) is bonded to six equivalent Br(1) atoms to form CsBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Cs(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Cs(1) and one As(1) atom.
(Rb)2CsAsBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a CsAsBr6 framework. In the CsAsBr6 framework, Cs(1) is bonded to six equivalent Br(1) atoms to form CsBr6 octahedra that share corners with six equivalent As(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Cs(1)-Br(1) bond lengths are 3.38 Å. As(1) is bonded to six equivalent Br(1) atoms to form AsBr6 octahedra that share corners with six equivalent Cs(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All As(1)-Br(1) bond lengths are 2.67 Å. Br(1) is bonded in a linear geometry to one Cs(1) and one As(1) atom.