UPO5 crystallizes in the orthorhombic Cmce space group. U(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to two equivalent U(1) atoms. In the second O site, O(1) is bonded in a 2-coordinate geometry to one U(1) and one P(1) atom. In the third O site, O(2) is bonded in a linear geometry to one U(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a linear geometry to one U(1) and one P(1) atom.
UPO5 crystallizes in the orthorhombic Cmce space group. U(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. The U(1)-O(2) bond length is 2.23 Å. The U(1)-O(3) bond length is 2.23 Å. Both U(1)-O(1) bond lengths are 2.27 Å. There is one shorter (1.96 Å) and one longer (2.26 Å) U(1)-O(4) bond length. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. The P(1)-O(2) bond length is 1.53 Å. The P(1)-O(3) bond length is 1.54 Å. Both P(1)-O(1) bond lengths are 1.56 Å. There are four inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to two equivalent U(1) atoms. In the second O site, O(1) is bonded in a 2-coordinate geometry to one U(1) and one P(1) atom. In the third O site, O(2) is bonded in a linear geometry to one U(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a linear geometry to one U(1) and one P(1) atom.