V3CrN3 crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded in a see-saw-like geometry to four equivalent N(1) atoms. Cr(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded to four equivalent V(1) and one Cr(1) atom to form a mixture of edge and corner-sharing NV4Cr trigonal bipyramids.
V3CrN3 crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded in a see-saw-like geometry to four equivalent N(1) atoms. There are two shorter (1.95 Å) and two longer (2.01 Å) V(1)-N(1) bond lengths. Cr(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All Cr(1)-N(1) bond lengths are 1.83 Å. N(1) is bonded to four equivalent V(1) and one Cr(1) atom to form a mixture of edge and corner-sharing NV4Cr trigonal bipyramids.