NaSbSn is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the hexagonal P6_3mc space group. Na(1) is bonded to three equivalent Sn(1) and three equivalent Sb(1) atoms to form distorted NaSn3Sb3 octahedra that share corners with six equivalent Sb(1)Na3Sn3 octahedra, edges with six equivalent Na(1)Sn3Sb3 octahedra, and  a faceface with one Sb(1)Na3Sn3 octahedra. The corner-sharing octahedral tilt angles are 49°. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent Sb(1) atoms. Sb(1) is bonded to three equivalent Na(1) and three equivalent Sn(1) atoms to form distorted SbNa3Sn3 octahedra that share corners with six equivalent Na(1)Sn3Sb3 octahedra, edges with six equivalent Sb(1)Na3Sn3 octahedra, and  a faceface with one Na(1)Sn3Sb3 octahedra. The corner-sharing octahedral tilt angles are 49°.
NaSbSn is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the hexagonal P6_3mc space group. Na(1) is bonded to three equivalent Sn(1) and three equivalent Sb(1) atoms to form distorted NaSn3Sb3 octahedra that share corners with six equivalent Sb(1)Na3Sn3 octahedra, edges with six equivalent Na(1)Sn3Sb3 octahedra, and  a faceface with one Sb(1)Na3Sn3 octahedra. The corner-sharing octahedral tilt angles are 49°. All Na(1)-Sn(1) bond lengths are 3.37 Å. All Na(1)-Sb(1) bond lengths are 3.30 Å. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent Sb(1) atoms. All Sn(1)-Sb(1) bond lengths are 2.90 Å. Sb(1) is bonded to three equivalent Na(1) and three equivalent Sn(1) atoms to form distorted SbNa3Sn3 octahedra that share corners with six equivalent Na(1)Sn3Sb3 octahedra, edges with six equivalent Sb(1)Na3Sn3 octahedra, and  a faceface with one Na(1)Sn3Sb3 octahedra. The corner-sharing octahedral tilt angles are 49°.