TiSi2 is Zirconium Disilicide structured and crystallizes in the orthorhombic Cmcm space group. Ti(1) is bonded in a 10-coordinate geometry to four equivalent Si(2) and six equivalent Si(1) atoms. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a 8-coordinate geometry to six equivalent Ti(1) and two equivalent Si(1) atoms. In the second Si site, Si(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent Si(2) atoms.
TiSi2 is Zirconium Disilicide structured and crystallizes in the orthorhombic Cmcm space group. Ti(1) is bonded in a 10-coordinate geometry to four equivalent Si(2) and six equivalent Si(1) atoms. There are two shorter (2.66 Å) and two longer (2.67 Å) Ti(1)-Si(2) bond lengths. There are four shorter (2.58 Å) and two longer (2.81 Å) Ti(1)-Si(1) bond lengths. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a 8-coordinate geometry to six equivalent Ti(1) and two equivalent Si(1) atoms. Both Si(1)-Si(1) bond lengths are 2.38 Å. In the second Si site, Si(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent Si(2) atoms. All Si(2)-Si(2) bond lengths are 2.51 Å.