NdV4Mn3O12 crystallizes in the cubic Im-3 space group. Nd(1) is bonded to twelve equivalent O(1) atoms to form NdO12 cuboctahedra that share faces with eight equivalent V(1)O6 octahedra. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent V(1)O6 octahedra and faces with two equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 34°. Mn(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Nd(1), two equivalent V(1), and one Mn(1) atom.
NdV4Mn3O12 crystallizes in the cubic Im-3 space group. Nd(1) is bonded to twelve equivalent O(1) atoms to form NdO12 cuboctahedra that share faces with eight equivalent V(1)O6 octahedra. All Nd(1)-O(1) bond lengths are 2.66 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent V(1)O6 octahedra and faces with two equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 34°. All V(1)-O(1) bond lengths are 1.98 Å. Mn(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Mn(1)-O(1) bond lengths are 2.10 Å. O(1) is bonded in a 3-coordinate geometry to one Nd(1), two equivalent V(1), and one Mn(1) atom.