SrNiO3 is (Cubic) Perovskite structured and crystallizes in the monoclinic C2 space group. Sr(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. Ni(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-8°. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1) and two equivalent Ni(1) atoms to form a mixture of distorted face, edge, and corner-sharing OSr4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the second O site, O(2) is bonded to four equivalent Sr(1) and two equivalent Ni(1) atoms to form a mixture of distorted face, edge, and corner-sharing OSr4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°.
SrNiO3 is (Cubic) Perovskite structured and crystallizes in the monoclinic C2 space group. Sr(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. There are a spread of Sr(1)-O(2) bond distances ranging from 2.66-2.80 Å. There are four shorter (2.67 Å) and four longer (2.77 Å) Sr(1)-O(1) bond lengths. Ni(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-8°. Both Ni(1)-O(2) bond lengths are 1.92 Å. There are two shorter (1.87 Å) and two longer (1.99 Å) Ni(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1) and two equivalent Ni(1) atoms to form a mixture of distorted face, edge, and corner-sharing OSr4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the second O site, O(2) is bonded to four equivalent Sr(1) and two equivalent Ni(1) atoms to form a mixture of distorted face, edge, and corner-sharing OSr4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°.