Cs2NaAu3(CN)6 crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent N(1) atoms. Na(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. Au(1) is bonded in a linear geometry to two equivalent C(1) atoms. C(1) is bonded in a single-bond geometry to one Au(1) and one N(1) atom. N(1) is bonded in a 2-coordinate geometry to three equivalent Cs(1), one Na(1), and one C(1) atom.
Cs2NaAu3(CN)6 crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent N(1) atoms. There are three shorter (3.26 Å) and six longer (3.68 Å) Cs(1)-N(1) bond lengths. Na(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Na(1)-N(1) bond lengths are 2.52 Å. Au(1) is bonded in a linear geometry to two equivalent C(1) atoms. Both Au(1)-C(1) bond lengths are 1.99 Å. C(1) is bonded in a single-bond geometry to one Au(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. N(1) is bonded in a 2-coordinate geometry to three equivalent Cs(1), one Na(1), and one C(1) atom.