RhF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RhF5 clusters. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. In the second Rh site, Rh(2) is bonded to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Rh(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Rh(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Rh(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Rh(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Rh(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Rh(2) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Rh(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Rh(1) atom. In the ninth F site, F(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom. In the tenth F site, F(6) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom.
RhF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RhF5 clusters. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. The Rh(1)-F(1) bond length is 1.84 Å. The Rh(1)-F(2) bond length is 1.83 Å. The Rh(1)-F(3) bond length is 1.83 Å. The Rh(1)-F(4) bond length is 1.82 Å. The Rh(1)-F(5) bond length is 2.01 Å. The Rh(1)-F(6) bond length is 2.00 Å. In the second Rh site, Rh(2) is bonded to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. The Rh(2)-F(10) bond length is 1.82 Å. The Rh(2)-F(5) bond length is 2.01 Å. The Rh(2)-F(6) bond length is 2.01 Å. The Rh(2)-F(7) bond length is 1.84 Å. The Rh(2)-F(8) bond length is 1.82 Å. The Rh(2)-F(9) bond length is 1.84 Å. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Rh(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Rh(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Rh(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Rh(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Rh(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Rh(2) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Rh(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Rh(1) atom. In the ninth F site, F(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom. In the tenth F site, F(6) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom.