C4TeS4(N2F)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C4TeS4(N2F)4 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(1) and one F(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one C(1), one Te(1), and one F(2) atom. In the second S site, S(2) is bonded in a distorted water-like geometry to one N(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom.
C4TeS4(N2F)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C4TeS4(N2F)4 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.29 Å. The C(1)-S(1) bond length is 1.85 Å. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. The C(2)-N(3) bond length is 1.32 Å. The C(2)-N(4) bond length is 1.18 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(1) and one F(1) atom. The N(1)-F(1) bond length is 1.39 Å. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. The N(3)-S(2) bond length is 1.63 Å. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. Both Te(1)-S(1) bond lengths are 2.77 Å. Both Te(1)-S(2) bond lengths are 2.56 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one C(1), one Te(1), and one F(2) atom. The S(1)-F(2) bond length is 1.63 Å. In the second S site, S(2) is bonded in a distorted water-like geometry to one N(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom.