SbCl4F is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two SbCl4F clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent F(1) atoms to form corner-sharing SbCl4F2 octahedra. The corner-sharing octahedral tilt angles are 11°. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms.
SbCl4F is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two SbCl4F clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent F(1) atoms to form corner-sharing SbCl4F2 octahedra. The corner-sharing octahedral tilt angles are 11°. The Sb(1)-Cl(1) bond length is 2.31 Å. The Sb(1)-Cl(2) bond length is 2.30 Å. The Sb(1)-Cl(3) bond length is 2.31 Å. The Sb(1)-Cl(4) bond length is 2.32 Å. There is one shorter (2.10 Å) and one longer (2.11 Å) Sb(1)-F(1) bond length. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms.