La3Mn3O10 is Orthorhombic Perovskite-like structured and crystallizes in the triclinic P1 space group. There are nine inequivalent La sites. In the first La site, La(1) is bonded in a 3-coordinate geometry to one O(12), one O(26), one O(29), one O(7), and two equivalent O(17) atoms. In the second La site, La(2) is bonded in a 1-coordinate geometry to one O(10), one O(14), one O(15), one O(20), two equivalent O(23), and two equivalent O(5) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(1), one O(13), one O(14), one O(22), one O(4), two equivalent O(19), and two equivalent O(24) atoms. In the fourth La site, La(4) is bonded in a 8-coordinate geometry to one O(16), one O(28), one O(5), one O(6), two equivalent O(15), and two equivalent O(25) atoms. In the fifth La site, La(5) is bonded in a 3-coordinate geometry to one O(15), one O(25), one O(26), one O(3), and two equivalent O(16) atoms. In the sixth La site, La(6) is bonded in a 1-coordinate geometry to one O(11), one O(16), one O(17), two equivalent O(26), and two equivalent O(7) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(17), one O(18), one O(27), one O(30), one O(9), two equivalent O(12), and two equivalent O(8) atoms. In the eighth La site, La(8) is bonded in a 1-coordinate geometry to one O(1), one O(12), two equivalent O(30), and two equivalent O(9) atoms. In the ninth La site, La(9) is bonded in a 3-coordinate geometry to one O(19), one O(2), one O(23), one O(5), two equivalent O(10), and two equivalent O(14) atoms. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(16), one O(26), one O(3), one O(6), and one O(7) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 19-25°. In the second Mn site, Mn(2) is bonded to one O(12), one O(18), one O(27), one O(30), one O(8), and one O(9) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 2-26°. In the third Mn site, Mn(3) is bonded to one O(10), one O(14), one O(19), one O(2), one O(24), and one O(4) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 4-23°. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(14), one O(2), one O(20), one O(23), and one O(5) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 17-25°. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(17), one O(21), one O(26), one O(29), and one O(7) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-25°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(13), one O(18), one O(22), one O(30), and one O(9) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 2-26°. In the seventh Mn site, Mn(7) is bonded to one O(12), one O(17), one O(21), one O(27), one O(29), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(13), one O(19), one O(22), one O(24), and one O(4) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 4-23°. In the ninth Mn site, Mn(9) is bonded to one O(15), one O(20), one O(23), one O(25), one O(28), and one O(5) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 19-25°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to one La(3), one La(8), one Mn(6), and one Mn(8) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(9), one Mn(3), and one Mn(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(5) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(3), one Mn(3), and one Mn(8) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one La(4), one La(9), two equivalent La(2), one Mn(4), and one Mn(9) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to one La(4) and one Mn(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one La(1), two equivalent La(6), one Mn(1), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to two equivalent La(7), one Mn(2), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one La(7), two equivalent La(8), one Mn(2), and one Mn(6) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(2), two equivalent La(9), one Mn(3), and one Mn(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(6), one Mn(1), and one Mn(5) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one La(1), one La(8), two equivalent La(7), one Mn(2), and one Mn(7) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one La(3), one Mn(6), and one Mn(8) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(2), one La(3), two equivalent La(9), one Mn(3), and one Mn(4) atom. In the fifteenth O site, O(15) is bonded to one La(2), one La(5), two equivalent La(4), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLa4Mn square pyramids. In the sixteenth O site, O(16) is bonded to one La(4), one La(6), two equivalent La(5), and one Mn(1) atom to form a mixture of distorted edge and corner-sharing OLa4Mn square pyramids. In the seventeenth O site, O(17) is bonded in a 6-coordinate geometry to one La(6), one La(7), two equivalent La(1), one Mn(5), and one Mn(7) atom. In the eighteenth O site, O(18) is bonded in a 2-coordinate geometry to one La(7), one Mn(2), and one Mn(6) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one La(9), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one La(2), one Mn(4), and one Mn(9) atom. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one Mn(5) and one Mn(7) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one La(3), one Mn(6), and one Mn(8) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one La(9), two equivalent La(2), one Mn(4), and one Mn(9) atom. In the twenty-fourth O site, O(24) is bonded in a distorted linear geometry to two equivalent La(3), one Mn(3), and one Mn(8) atom. In the twenty-fifth O site, O(25) is bonded in a 1-coordinate geometry to one La(5), two equivalent La(4), and one Mn(9) atom. In the twenty-sixth O site, O(26) is bonded in a 6-coordinate geometry to one La(1), one La(5), two equivalent La(6), one Mn(1), and one Mn(5) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one La(7), one Mn(2), and one Mn(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one La(4) and one Mn(9) atom. In the twenty-ninth O site, O(29) is bonded in a 3-coordinate geometry to one La(1), one Mn(5), and one Mn(7) atom. In the thirtieth O site, O(30) is bonded to one La(7), two equivalent La(8), one Mn(2), and one Mn(6) atom to form distorted corner-sharing OLa3Mn2 square pyramids.
La3Mn3O10 is Orthorhombic Perovskite-like structured and crystallizes in the triclinic P1 space group. There are nine inequivalent La sites. In the first La site, La(1) is bonded in a 3-coordinate geometry to one O(12), one O(26), one O(29), one O(7), and two equivalent O(17) atoms. The La(1)-O(12) bond length is 2.23 Å. The La(1)-O(26) bond length is 2.93 Å. The La(1)-O(29) bond length is 2.43 Å. The La(1)-O(7) bond length is 2.45 Å. There is one shorter (2.69 Å) and one longer (2.80 Å) La(1)-O(17) bond length. In the second La site, La(2) is bonded in a 1-coordinate geometry to one O(10), one O(14), one O(15), one O(20), two equivalent O(23), and two equivalent O(5) atoms. The La(2)-O(10) bond length is 2.58 Å. The La(2)-O(14) bond length is 3.03 Å. The La(2)-O(15) bond length is 2.16 Å. The La(2)-O(20) bond length is 2.40 Å. There is one shorter (2.65 Å) and one longer (2.91 Å) La(2)-O(23) bond length. There is one shorter (2.72 Å) and one longer (2.76 Å) La(2)-O(5) bond length. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(1), one O(13), one O(14), one O(22), one O(4), two equivalent O(19), and two equivalent O(24) atoms. The La(3)-O(1) bond length is 2.58 Å. The La(3)-O(13) bond length is 2.85 Å. The La(3)-O(14) bond length is 2.37 Å. The La(3)-O(22) bond length is 2.42 Å. The La(3)-O(4) bond length is 2.54 Å. There is one shorter (2.72 Å) and one longer (2.82 Å) La(3)-O(19) bond length. There is one shorter (2.68 Å) and one longer (2.79 Å) La(3)-O(24) bond length. In the fourth La site, La(4) is bonded in a 8-coordinate geometry to one O(16), one O(28), one O(5), one O(6), two equivalent O(15), and two equivalent O(25) atoms. The La(4)-O(16) bond length is 2.69 Å. The La(4)-O(28) bond length is 2.49 Å. The La(4)-O(5) bond length is 2.33 Å. The La(4)-O(6) bond length is 2.47 Å. There is one shorter (2.72 Å) and one longer (2.81 Å) La(4)-O(15) bond length. There is one shorter (2.72 Å) and one longer (2.76 Å) La(4)-O(25) bond length. In the fifth La site, La(5) is bonded in a 3-coordinate geometry to one O(15), one O(25), one O(26), one O(3), and two equivalent O(16) atoms. The La(5)-O(15) bond length is 2.67 Å. The La(5)-O(25) bond length is 2.44 Å. The La(5)-O(26) bond length is 2.35 Å. The La(5)-O(3) bond length is 2.49 Å. There is one shorter (2.72 Å) and one longer (2.82 Å) La(5)-O(16) bond length. In the sixth La site, La(6) is bonded in a 1-coordinate geometry to one O(11), one O(16), one O(17), two equivalent O(26), and two equivalent O(7) atoms. The La(6)-O(11) bond length is 2.39 Å. The La(6)-O(16) bond length is 2.14 Å. The La(6)-O(17) bond length is 3.06 Å. There is one shorter (2.73 Å) and one longer (2.75 Å) La(6)-O(26) bond length. There is one shorter (2.65 Å) and one longer (2.93 Å) La(6)-O(7) bond length. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(17), one O(18), one O(27), one O(30), one O(9), two equivalent O(12), and two equivalent O(8) atoms. The La(7)-O(17) bond length is 2.31 Å. The La(7)-O(18) bond length is 2.78 Å. The La(7)-O(27) bond length is 2.49 Å. The La(7)-O(30) bond length is 2.53 Å. The La(7)-O(9) bond length is 2.44 Å. There is one shorter (2.71 Å) and one longer (2.80 Å) La(7)-O(12) bond length. There is one shorter (2.71 Å) and one longer (2.77 Å) La(7)-O(8) bond length. In the eighth La site, La(8) is bonded in a 1-coordinate geometry to one O(1), one O(12), two equivalent O(30), and two equivalent O(9) atoms. The La(8)-O(1) bond length is 2.16 Å. The La(8)-O(12) bond length is 3.02 Å. There is one shorter (2.68 Å) and one longer (2.79 Å) La(8)-O(30) bond length. There is one shorter (2.67 Å) and one longer (2.88 Å) La(8)-O(9) bond length. In the ninth La site, La(9) is bonded in a 3-coordinate geometry to one O(19), one O(2), one O(23), one O(5), two equivalent O(10), and two equivalent O(14) atoms. The La(9)-O(19) bond length is 2.21 Å. The La(9)-O(2) bond length is 2.42 Å. The La(9)-O(23) bond length is 2.50 Å. The La(9)-O(5) bond length is 2.94 Å. There is one shorter (2.68 Å) and one longer (2.85 Å) La(9)-O(10) bond length. There is one shorter (2.69 Å) and one longer (2.80 Å) La(9)-O(14) bond length. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(16), one O(26), one O(3), one O(6), and one O(7) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 19-25°. The Mn(1)-O(11) bond length is 1.84 Å. The Mn(1)-O(16) bond length is 2.00 Å. The Mn(1)-O(26) bond length is 2.20 Å. The Mn(1)-O(3) bond length is 1.70 Å. The Mn(1)-O(6) bond length is 1.88 Å. The Mn(1)-O(7) bond length is 2.02 Å. In the second Mn site, Mn(2) is bonded to one O(12), one O(18), one O(27), one O(30), one O(8), and one O(9) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 2-26°. The Mn(2)-O(12) bond length is 2.31 Å. The Mn(2)-O(18) bond length is 1.73 Å. The Mn(2)-O(27) bond length is 1.80 Å. The Mn(2)-O(30) bond length is 2.10 Å. The Mn(2)-O(8) bond length is 1.99 Å. The Mn(2)-O(9) bond length is 1.95 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(14), one O(19), one O(2), one O(24), and one O(4) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 4-23°. The Mn(3)-O(10) bond length is 2.12 Å. The Mn(3)-O(14) bond length is 2.20 Å. The Mn(3)-O(19) bond length is 2.08 Å. The Mn(3)-O(2) bond length is 1.84 Å. The Mn(3)-O(24) bond length is 1.94 Å. The Mn(3)-O(4) bond length is 1.77 Å. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(14), one O(2), one O(20), one O(23), and one O(5) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 17-25°. The Mn(4)-O(10) bond length is 1.94 Å. The Mn(4)-O(14) bond length is 2.17 Å. The Mn(4)-O(2) bond length is 1.74 Å. The Mn(4)-O(20) bond length is 1.74 Å. The Mn(4)-O(23) bond length is 1.98 Å. The Mn(4)-O(5) bond length is 2.17 Å. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(17), one O(21), one O(26), one O(29), and one O(7) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-25°. The Mn(5)-O(11) bond length is 1.74 Å. The Mn(5)-O(17) bond length is 2.19 Å. The Mn(5)-O(21) bond length is 1.95 Å. The Mn(5)-O(26) bond length is 2.16 Å. The Mn(5)-O(29) bond length is 1.75 Å. The Mn(5)-O(7) bond length is 1.99 Å. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(13), one O(18), one O(22), one O(30), and one O(9) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 2-26°. The Mn(6)-O(1) bond length is 2.12 Å. The Mn(6)-O(13) bond length is 1.78 Å. The Mn(6)-O(18) bond length is 1.84 Å. The Mn(6)-O(22) bond length is 1.92 Å. The Mn(6)-O(30) bond length is 2.16 Å. The Mn(6)-O(9) bond length is 2.07 Å. In the seventh Mn site, Mn(7) is bonded to one O(12), one O(17), one O(21), one O(27), one O(29), and one O(8) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. The Mn(7)-O(12) bond length is 2.11 Å. The Mn(7)-O(17) bond length is 2.15 Å. The Mn(7)-O(21) bond length is 2.06 Å. The Mn(7)-O(27) bond length is 1.81 Å. The Mn(7)-O(29) bond length is 1.83 Å. The Mn(7)-O(8) bond length is 2.03 Å. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(13), one O(19), one O(22), one O(24), and one O(4) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 4-23°. The Mn(8)-O(1) bond length is 2.12 Å. The Mn(8)-O(13) bond length is 1.74 Å. The Mn(8)-O(19) bond length is 2.28 Å. The Mn(8)-O(22) bond length is 1.99 Å. The Mn(8)-O(24) bond length is 1.98 Å. The Mn(8)-O(4) bond length is 1.80 Å. In the ninth Mn site, Mn(9) is bonded to one O(15), one O(20), one O(23), one O(25), one O(28), and one O(5) atom to form distorted corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 19-25°. The Mn(9)-O(15) bond length is 2.00 Å. The Mn(9)-O(20) bond length is 1.85 Å. The Mn(9)-O(23) bond length is 2.01 Å. The Mn(9)-O(25) bond length is 1.88 Å. The Mn(9)-O(28) bond length is 1.70 Å. The Mn(9)-O(5) bond length is 2.21 Å. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a square co-planar geometry to one La(3), one La(8), one Mn(6), and one Mn(8) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(9), one Mn(3), and one Mn(4) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(5) and one Mn(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(3), one Mn(3), and one Mn(8) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one La(4), one La(9), two equivalent La(2), one Mn(4), and one Mn(9) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to one La(4) and one Mn(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one La(1), two equivalent La(6), one Mn(1), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to two equivalent La(7), one Mn(2), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one La(7), two equivalent La(8), one Mn(2), and one Mn(6) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(2), two equivalent La(9), one Mn(3), and one Mn(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(6), one Mn(1), and one Mn(5) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one La(1), one La(8), two equivalent La(7), one Mn(2), and one Mn(7) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one La(3), one Mn(6), and one Mn(8) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(2), one La(3), two equivalent La(9), one Mn(3), and one Mn(4) atom. In the fifteenth O site, O(15) is bonded to one La(2), one La(5), two equivalent La(4), and one Mn(9) atom to form a mixture of distorted edge and corner-sharing OLa4Mn square pyramids. In the sixteenth O site, O(16) is bonded to one La(4), one La(6), two equivalent La(5), and one Mn(1) atom to form a mixture of distorted edge and corner-sharing OLa4Mn square pyramids. In the seventeenth O site, O(17) is bonded in a 6-coordinate geometry to one La(6), one La(7), two equivalent La(1), one Mn(5), and one Mn(7) atom. In the eighteenth O site, O(18) is bonded in a 2-coordinate geometry to one La(7), one Mn(2), and one Mn(6) atom. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one La(9), two equivalent La(3), one Mn(3), and one Mn(8) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one La(2), one Mn(4), and one Mn(9) atom. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one Mn(5) and one Mn(7) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one La(3), one Mn(6), and one Mn(8) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one La(9), two equivalent La(2), one Mn(4), and one Mn(9) atom. In the twenty-fourth O site, O(24) is bonded in a distorted linear geometry to two equivalent La(3), one Mn(3), and one Mn(8) atom. In the twenty-fifth O site, O(25) is bonded in a 1-coordinate geometry to one La(5), two equivalent La(4), and one Mn(9) atom. In the twenty-sixth O site, O(26) is bonded in a 6-coordinate geometry to one La(1), one La(5), two equivalent La(6), one Mn(1), and one Mn(5) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one La(7), one Mn(2), and one Mn(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one La(4) and one Mn(9) atom. In the twenty-ninth O site, O(29) is bonded in a 3-coordinate geometry to one La(1), one Mn(5), and one Mn(7) atom. In the thirtieth O site, O(30) is bonded to one La(7), two equivalent La(8), one Mn(2), and one Mn(6) atom to form distorted corner-sharing OLa3Mn2 square pyramids.