LiSrU2O6 crystallizes in the orthorhombic Immm space group. Li(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. Sr(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. U(1) is bonded in a body-centered cubic geometry to two equivalent O(2) and six equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), and three equivalent U(1) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Sr(1), and two equivalent U(1) atoms.
LiSrU2O6 crystallizes in the orthorhombic Immm space group. Li(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. All Li(1)-O(1) bond lengths are 2.39 Å. All Li(1)-O(2) bond lengths are 2.29 Å. Sr(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. All Sr(1)-O(1) bond lengths are 2.53 Å. All Sr(1)-O(2) bond lengths are 2.55 Å. U(1) is bonded in a body-centered cubic geometry to two equivalent O(2) and six equivalent O(1) atoms. Both U(1)-O(2) bond lengths are 2.35 Å. There are two shorter (2.31 Å) and four longer (2.35 Å) U(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), and three equivalent U(1) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Sr(1), and two equivalent U(1) atoms.