Li4Mn3Co3(SnO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(21), one O(24), one O(30), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, and corners with two equivalent Sn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-67°. In the second Li site, Li(2) is bonded to one O(22), one O(23), one O(29), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, and corners with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-66°. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(17), one O(27), one O(32), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(10), one O(18), one O(28), and one O(31) atom. In the fifth Li site, Li(5) is bonded in a rectangular see-saw-like geometry to one O(11), one O(19), one O(2), and one O(7) atom. In the sixth Li site, Li(6) is bonded in a rectangular see-saw-like geometry to one O(1), one O(12), one O(20), and one O(8) atom. In the seventh Li site, Li(7) is bonded to one O(14), one O(15), one O(25), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. In the eighth Li site, Li(8) is bonded to one O(13), one O(16), one O(26), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-64°. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(28), one O(31), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Mn site, Mn(2) is bonded to one O(19), one O(2), one O(21), one O(25), one O(29), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(20), one O(22), one O(26), and one O(30) atom to form MnO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the fourth Mn site, Mn(4) is bonded to one O(13), one O(15), one O(27), one O(32), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(12), one O(20), one O(23), one O(25), and one O(29) atom to form MnO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(7)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the sixth Mn site, Mn(6) is bonded to one O(11), one O(19), one O(24), one O(26), one O(30), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(8)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(13), one O(18), one O(28), one O(3), one O(5), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Sn(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. In the second Co site, Co(2) is bonded to one O(14), one O(17), one O(27), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent Sn(3)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the third Co site, Co(3) is bonded to one O(15), one O(17), one O(3), one O(32), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the fourth Co site, Co(4) is bonded to one O(16), one O(18), one O(31), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. In the fifth Co site, Co(5) is bonded to one O(11), one O(2), one O(21), one O(23), one O(25), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the sixth Co site, Co(6) is bonded to one O(1), one O(10), one O(12), one O(22), one O(24), and one O(26) atom to form CoO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(4)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(11), one O(13), one O(15), one O(19), and one O(3) atom to form SnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one Li(7)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the second Sn site, Sn(2) is bonded to one O(12), one O(14), one O(16), one O(2), one O(20), and one O(4) atom to form SnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(8)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the third Sn site, Sn(3) is bonded to one O(17), one O(21), one O(23), one O(27), one O(29), and one O(31) atom to form SnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the fourth Sn site, Sn(4) is bonded to one O(18), one O(22), one O(24), one O(28), one O(30), and one O(32) atom to form SnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(3), one Co(6), and one Sn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(5), one Mn(2), one Co(5), and one Sn(2) atom. In the third O site, O(3) is bonded to one Li(8), one Co(1), one Co(3), and one Sn(1) atom to form distorted OLiCo2Sn tetrahedra that share  a cornercorner with one O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra,  a cornercorner with one O(16)LiMnCoSn tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid,  an edgeedge with one O(13)LiMnCoSn tetrahedra,  an edgeedge with one O(15)LiMnCoSn tetrahedra, and  an edgeedge with one O(5)LiMnCo2 trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(7), one Co(2), one Co(4), and one Sn(2) atom to form distorted OLiCo2Sn tetrahedra that share  a cornercorner with one O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(15)LiMnCoSn tetrahedra,  a cornercorner with one O(25)LiMn2Co trigonal pyramid, and  an edgeedge with one O(16)LiMnCoSn tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Mn(4), one Co(1), and one Co(3) atom to form distorted OLiMnCo2 trigonal pyramids that share  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid,  an edgeedge with one O(3)LiCo2Sn tetrahedra,  an edgeedge with one O(13)LiMnCoSn tetrahedra, and  an edgeedge with one O(15)LiMnCoSn tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(1), one Co(2), and one Co(4) atom. In the seventh O site, O(7) is bonded to one Li(5), one Mn(4), one Co(2), and one Co(3) atom to form distorted OLiMnCo2 tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(4)LiCo2Sn tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra, corners with two equivalent O(15)LiMnCoSn tetrahedra, and corners with two equivalent O(5)LiMnCo2 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(6), one Mn(1), one Co(1), and one Co(4) atom to form distorted OLiMnCo2 tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(4)LiCo2Sn tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra, corners with two equivalent O(16)LiMnCoSn tetrahedra, and  a cornercorner with one O(5)LiMnCo2 trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(3), one Mn(2), one Mn(6), and one Co(5) atom to form OLiMn2Co tetrahedra that share  a cornercorner with one O(23)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid, and corners with two equivalent O(25)LiMn2Co trigonal pyramids. In the tenth O site, O(10) is bonded to one Li(4), one Mn(3), one Mn(5), and one Co(6) atom to form OLiMn2Co tetrahedra that share  a cornercorner with one O(23)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(22)LiMnCoSn tetrahedra,  a cornercorner with one O(25)LiMn2Co trigonal pyramid,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid, and corners with two equivalent O(26)LiMn2Co trigonal pyramids. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(5), one Mn(6), one Co(5), and one Sn(1) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(5), one Co(6), and one Sn(2) atom. In the thirteenth O site, O(13) is bonded to one Li(8), one Mn(4), one Co(1), and one Sn(1) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(16)LiMnCoSn tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid,  an edgeedge with one O(3)LiCo2Sn tetrahedra,  an edgeedge with one O(15)LiMnCoSn tetrahedra, and  an edgeedge with one O(5)LiMnCo2 trigonal pyramid. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(1), one Co(2), and one Sn(2) atom. In the fifteenth O site, O(15) is bonded to one Li(7), one Mn(4), one Co(3), and one Sn(1) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(4)LiCo2Sn tetrahedra, corners with two equivalent O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(25)LiMn2Co trigonal pyramid,  an edgeedge with one O(3)LiCo2Sn tetrahedra,  an edgeedge with one O(13)LiMnCoSn tetrahedra, and  an edgeedge with one O(5)LiMnCo2 trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(8), one Mn(1), one Co(4), and one Sn(2) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra, corners with two equivalent O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid, and  an edgeedge with one O(4)LiCo2Sn tetrahedra. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(2), one Co(3), and one Sn(3) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Co(4), and one Sn(4) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Li(5), one Mn(2), one Mn(6), and one Sn(1) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(3), one Mn(5), and one Sn(2) atom. In the twenty-first O site, O(21) is bonded to one Li(1), one Mn(2), one Co(5), and one Sn(3) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(9)LiMn2Co tetrahedra,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid,  a cornercorner with one O(5)LiMnCo2 trigonal pyramid,  an edgeedge with one O(23)LiMnCoSn tetrahedra,  an edgeedge with one O(25)LiMn2Co trigonal pyramid, and  an edgeedge with one O(29)LiMn2Sn trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Mn(3), one Co(6), and one Sn(4) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(23)LiMnCoSn tetrahedra, corners with two equivalent O(10)LiMn2Co tetrahedra,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  an edgeedge with one O(24)LiMnCoSn tetrahedra,  an edgeedge with one O(26)LiMn2Co trigonal pyramid, and  an edgeedge with one O(30)LiMn2Sn trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(2), one Mn(5), one Co(5), and one Sn(3) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(22)LiMnCoSn tetrahedra,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  an edgeedge with one O(21)LiMnCoSn tetrahedra,  an edgeedge with one O(25)LiMn2Co trigonal pyramid, and  an edgeedge with one O(29)LiMn2Sn trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(1), one Mn(6), one Co(6), and one Sn(4) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid,  a cornercorner with one O(5)LiMnCo2 trigonal pyramid,  an edgeedge with one O(22)LiMnCoSn tetrahedra,  an edgeedge with one O(26)LiMn2Co trigonal pyramid, and  an edgeedge with one O(30)LiMn2Sn trigonal pyramid. In the twenty-fifth O site, O(25) is bonded to one Li(7), one Mn(2), one Mn(5), and one Co(5) atom to form distorted OLiMn2Co trigonal pyramids that share  a cornercorner with one O(4)LiCo2Sn tetrahedra,  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(15)LiMnCoSn tetrahedra, corners with two equivalent O(9)LiMn2Co tetrahedra,  an edgeedge with one O(21)LiMnCoSn tetrahedra,  an edgeedge with one O(23)LiMnCoSn tetrahedra, and  an edgeedge with one O(29)LiMn2Sn trigonal pyramid. In the twenty-sixth O site, O(26) is bonded to one Li(8), one Mn(3), one Mn(6), and one Co(6) atom to form distorted OLiMn2Co trigonal pyramids that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra,  a cornercorner with one O(16)LiMnCoSn tetrahedra, corners with two equivalent O(10)LiMn2Co tetrahedra,  an edgeedge with one O(22)LiMnCoSn tetrahedra,  an edgeedge with one O(24)LiMnCoSn tetrahedra, and  an edgeedge with one O(30)LiMn2Sn trigonal pyramid. In the twenty-seventh O site, O(27) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(4), one Co(2), and one Sn(3) atom. In the twenty-eighth O site, O(28) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(1), one Co(1), and one Sn(4) atom. In the twenty-ninth O site, O(29) is bonded to one Li(2), one Mn(2), one Mn(5), and one Sn(3) atom to form distorted OLiMn2Sn trigonal pyramids that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(22)LiMnCoSn tetrahedra,  a cornercorner with one O(23)LiMnCoSn tetrahedra,  an edgeedge with one O(21)LiMnCoSn tetrahedra,  an edgeedge with one O(23)LiMnCoSn tetrahedra, and  an edgeedge with one O(25)LiMn2Co trigonal pyramid. In the thirtieth O site, O(30) is bonded to one Li(1), one Mn(3), one Mn(6), and one Sn(4) atom to form distorted OLiMn2Sn trigonal pyramids that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra,  a cornercorner with one O(5)LiMnCo2 trigonal pyramid,  an edgeedge with one O(22)LiMnCoSn tetrahedra,  an edgeedge with one O(24)LiMnCoSn tetrahedra, and  an edgeedge with one O(26)LiMn2Co trigonal pyramid. In the thirty-first O site, O(31) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(1), one Co(4), and one Sn(3) atom. In the thirty-second O site, O(32) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(4), one Co(3), and one Sn(4) atom.
Li4Mn3Co3(SnO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(21), one O(24), one O(30), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, and corners with two equivalent Sn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-67°. The Li(1)-O(21) bond length is 2.01 Å. The Li(1)-O(24) bond length is 1.94 Å. The Li(1)-O(30) bond length is 1.91 Å. The Li(1)-O(5) bond length is 2.06 Å. In the second Li site, Li(2) is bonded to one O(22), one O(23), one O(29), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, and corners with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-66°. The Li(2)-O(22) bond length is 2.01 Å. The Li(2)-O(23) bond length is 1.94 Å. The Li(2)-O(29) bond length is 1.93 Å. The Li(2)-O(6) bond length is 2.03 Å. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(17), one O(27), one O(32), and one O(9) atom. The Li(3)-O(17) bond length is 1.91 Å. The Li(3)-O(27) bond length is 1.93 Å. The Li(3)-O(32) bond length is 1.94 Å. The Li(3)-O(9) bond length is 1.82 Å. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(10), one O(18), one O(28), and one O(31) atom. The Li(4)-O(10) bond length is 1.82 Å. The Li(4)-O(18) bond length is 1.90 Å. The Li(4)-O(28) bond length is 1.92 Å. The Li(4)-O(31) bond length is 1.96 Å. In the fifth Li site, Li(5) is bonded in a rectangular see-saw-like geometry to one O(11), one O(19), one O(2), and one O(7) atom. The Li(5)-O(11) bond length is 1.91 Å. The Li(5)-O(19) bond length is 1.92 Å. The Li(5)-O(2) bond length is 1.93 Å. The Li(5)-O(7) bond length is 1.80 Å. In the sixth Li site, Li(6) is bonded in a rectangular see-saw-like geometry to one O(1), one O(12), one O(20), and one O(8) atom. The Li(6)-O(1) bond length is 1.93 Å. The Li(6)-O(12) bond length is 1.92 Å. The Li(6)-O(20) bond length is 1.92 Å. The Li(6)-O(8) bond length is 1.80 Å. In the seventh Li site, Li(7) is bonded to one O(14), one O(15), one O(25), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. The Li(7)-O(14) bond length is 1.96 Å. The Li(7)-O(15) bond length is 1.97 Å. The Li(7)-O(25) bond length is 2.11 Å. The Li(7)-O(4) bond length is 1.95 Å. In the eighth Li site, Li(8) is bonded to one O(13), one O(16), one O(26), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and corners with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-64°. The Li(8)-O(13) bond length is 1.98 Å. The Li(8)-O(16) bond length is 1.93 Å. The Li(8)-O(26) bond length is 2.14 Å. The Li(8)-O(3) bond length is 1.94 Å. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(28), one O(31), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Mn(1)-O(14) bond length is 1.95 Å. The Mn(1)-O(16) bond length is 1.93 Å. The Mn(1)-O(28) bond length is 1.97 Å. The Mn(1)-O(31) bond length is 1.99 Å. The Mn(1)-O(6) bond length is 1.90 Å. The Mn(1)-O(8) bond length is 1.91 Å. In the second Mn site, Mn(2) is bonded to one O(19), one O(2), one O(21), one O(25), one O(29), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. The Mn(2)-O(19) bond length is 1.95 Å. The Mn(2)-O(2) bond length is 1.99 Å. The Mn(2)-O(21) bond length is 1.95 Å. The Mn(2)-O(25) bond length is 1.94 Å. The Mn(2)-O(29) bond length is 1.92 Å. The Mn(2)-O(9) bond length is 1.94 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(20), one O(22), one O(26), and one O(30) atom to form MnO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. The Mn(3)-O(1) bond length is 1.98 Å. The Mn(3)-O(10) bond length is 1.94 Å. The Mn(3)-O(20) bond length is 1.93 Å. The Mn(3)-O(22) bond length is 1.96 Å. The Mn(3)-O(26) bond length is 1.94 Å. The Mn(3)-O(30) bond length is 1.91 Å. In the fourth Mn site, Mn(4) is bonded to one O(13), one O(15), one O(27), one O(32), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. The Mn(4)-O(13) bond length is 1.95 Å. The Mn(4)-O(15) bond length is 1.95 Å. The Mn(4)-O(27) bond length is 1.96 Å. The Mn(4)-O(32) bond length is 1.99 Å. The Mn(4)-O(5) bond length is 1.92 Å. The Mn(4)-O(7) bond length is 1.92 Å. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(12), one O(20), one O(23), one O(25), and one O(29) atom to form MnO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(7)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. The Mn(5)-O(10) bond length is 1.94 Å. The Mn(5)-O(12) bond length is 2.00 Å. The Mn(5)-O(20) bond length is 2.15 Å. The Mn(5)-O(23) bond length is 2.02 Å. The Mn(5)-O(25) bond length is 1.95 Å. The Mn(5)-O(29) bond length is 2.20 Å. In the sixth Mn site, Mn(6) is bonded to one O(11), one O(19), one O(24), one O(26), one O(30), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(8)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Sn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. The Mn(6)-O(11) bond length is 1.99 Å. The Mn(6)-O(19) bond length is 2.17 Å. The Mn(6)-O(24) bond length is 2.01 Å. The Mn(6)-O(26) bond length is 1.94 Å. The Mn(6)-O(30) bond length is 2.20 Å. The Mn(6)-O(9) bond length is 1.93 Å. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(13), one O(18), one O(28), one O(3), one O(5), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Sn(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. The Co(1)-O(13) bond length is 1.95 Å. The Co(1)-O(18) bond length is 2.00 Å. The Co(1)-O(28) bond length is 1.98 Å. The Co(1)-O(3) bond length is 1.93 Å. The Co(1)-O(5) bond length is 1.92 Å. The Co(1)-O(8) bond length is 1.92 Å. In the second Co site, Co(2) is bonded to one O(14), one O(17), one O(27), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share corners with two equivalent Sn(3)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. The Co(2)-O(14) bond length is 2.08 Å. The Co(2)-O(17) bond length is 1.98 Å. The Co(2)-O(27) bond length is 2.06 Å. The Co(2)-O(4) bond length is 1.99 Å. The Co(2)-O(6) bond length is 2.02 Å. The Co(2)-O(7) bond length is 2.01 Å. In the third Co site, Co(3) is bonded to one O(15), one O(17), one O(3), one O(32), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. The Co(3)-O(15) bond length is 1.94 Å. The Co(3)-O(17) bond length is 1.98 Å. The Co(3)-O(3) bond length is 1.94 Å. The Co(3)-O(32) bond length is 1.99 Å. The Co(3)-O(5) bond length is 1.93 Å. The Co(3)-O(7) bond length is 1.93 Å. In the fourth Co site, Co(4) is bonded to one O(16), one O(18), one O(31), one O(4), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Sn(4)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. The Co(4)-O(16) bond length is 2.04 Å. The Co(4)-O(18) bond length is 1.98 Å. The Co(4)-O(31) bond length is 2.04 Å. The Co(4)-O(4) bond length is 2.03 Å. The Co(4)-O(6) bond length is 2.02 Å. The Co(4)-O(8) bond length is 1.99 Å. In the fifth Co site, Co(5) is bonded to one O(11), one O(2), one O(21), one O(23), one O(25), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. The Co(5)-O(11) bond length is 1.98 Å. The Co(5)-O(2) bond length is 2.00 Å. The Co(5)-O(21) bond length is 1.95 Å. The Co(5)-O(23) bond length is 1.94 Å. The Co(5)-O(25) bond length is 1.94 Å. The Co(5)-O(9) bond length is 1.95 Å. In the sixth Co site, Co(6) is bonded to one O(1), one O(10), one O(12), one O(22), one O(24), and one O(26) atom to form CoO6 octahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sn(4)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. The Co(6)-O(1) bond length is 2.01 Å. The Co(6)-O(10) bond length is 1.94 Å. The Co(6)-O(12) bond length is 1.98 Å. The Co(6)-O(22) bond length is 1.95 Å. The Co(6)-O(24) bond length is 1.94 Å. The Co(6)-O(26) bond length is 1.94 Å. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(11), one O(13), one O(15), one O(19), and one O(3) atom to form SnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra,  a cornercorner with one Li(7)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. The Sn(1)-O(1) bond length is 2.11 Å. The Sn(1)-O(11) bond length is 2.05 Å. The Sn(1)-O(13) bond length is 2.17 Å. The Sn(1)-O(15) bond length is 2.17 Å. The Sn(1)-O(19) bond length is 2.05 Å. The Sn(1)-O(3) bond length is 2.15 Å. In the second Sn site, Sn(2) is bonded to one O(12), one O(14), one O(16), one O(2), one O(20), and one O(4) atom to form SnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(8)O4 tetrahedra, corners with two equivalent Li(7)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. The Sn(2)-O(12) bond length is 2.06 Å. The Sn(2)-O(14) bond length is 2.15 Å. The Sn(2)-O(16) bond length is 2.15 Å. The Sn(2)-O(2) bond length is 2.11 Å. The Sn(2)-O(20) bond length is 2.03 Å. The Sn(2)-O(4) bond length is 2.13 Å. In the third Sn site, Sn(3) is bonded to one O(17), one O(21), one O(23), one O(27), one O(29), and one O(31) atom to form SnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. The Sn(3)-O(17) bond length is 2.06 Å. The Sn(3)-O(21) bond length is 2.20 Å. The Sn(3)-O(23) bond length is 2.14 Å. The Sn(3)-O(27) bond length is 2.08 Å. The Sn(3)-O(29) bond length is 2.12 Å. The Sn(3)-O(31) bond length is 2.07 Å. In the fourth Sn site, Sn(4) is bonded to one O(18), one O(22), one O(24), one O(28), one O(30), and one O(32) atom to form SnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. The Sn(4)-O(18) bond length is 2.06 Å. The Sn(4)-O(22) bond length is 2.19 Å. The Sn(4)-O(24) bond length is 2.15 Å. The Sn(4)-O(28) bond length is 2.09 Å. The Sn(4)-O(30) bond length is 2.11 Å. The Sn(4)-O(32) bond length is 2.07 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(3), one Co(6), and one Sn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(5), one Mn(2), one Co(5), and one Sn(2) atom. In the third O site, O(3) is bonded to one Li(8), one Co(1), one Co(3), and one Sn(1) atom to form distorted OLiCo2Sn tetrahedra that share  a cornercorner with one O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra,  a cornercorner with one O(16)LiMnCoSn tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid,  an edgeedge with one O(13)LiMnCoSn tetrahedra,  an edgeedge with one O(15)LiMnCoSn tetrahedra, and  an edgeedge with one O(5)LiMnCo2 trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(7), one Co(2), one Co(4), and one Sn(2) atom to form distorted OLiCo2Sn tetrahedra that share  a cornercorner with one O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(15)LiMnCoSn tetrahedra,  a cornercorner with one O(25)LiMn2Co trigonal pyramid, and  an edgeedge with one O(16)LiMnCoSn tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Mn(4), one Co(1), and one Co(3) atom to form distorted OLiMnCo2 trigonal pyramids that share  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid,  an edgeedge with one O(3)LiCo2Sn tetrahedra,  an edgeedge with one O(13)LiMnCoSn tetrahedra, and  an edgeedge with one O(15)LiMnCoSn tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(2), one Mn(1), one Co(2), and one Co(4) atom. In the seventh O site, O(7) is bonded to one Li(5), one Mn(4), one Co(2), and one Co(3) atom to form distorted OLiMnCo2 tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(4)LiCo2Sn tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra, corners with two equivalent O(15)LiMnCoSn tetrahedra, and corners with two equivalent O(5)LiMnCo2 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(6), one Mn(1), one Co(1), and one Co(4) atom to form distorted OLiMnCo2 tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(4)LiCo2Sn tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra, corners with two equivalent O(16)LiMnCoSn tetrahedra, and  a cornercorner with one O(5)LiMnCo2 trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(3), one Mn(2), one Mn(6), and one Co(5) atom to form OLiMn2Co tetrahedra that share  a cornercorner with one O(23)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid, and corners with two equivalent O(25)LiMn2Co trigonal pyramids. In the tenth O site, O(10) is bonded to one Li(4), one Mn(3), one Mn(5), and one Co(6) atom to form OLiMn2Co tetrahedra that share  a cornercorner with one O(23)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(22)LiMnCoSn tetrahedra,  a cornercorner with one O(25)LiMn2Co trigonal pyramid,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid, and corners with two equivalent O(26)LiMn2Co trigonal pyramids. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(5), one Mn(6), one Co(5), and one Sn(1) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(5), one Co(6), and one Sn(2) atom. In the thirteenth O site, O(13) is bonded to one Li(8), one Mn(4), one Co(1), and one Sn(1) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(16)LiMnCoSn tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid,  an edgeedge with one O(3)LiCo2Sn tetrahedra,  an edgeedge with one O(15)LiMnCoSn tetrahedra, and  an edgeedge with one O(5)LiMnCo2 trigonal pyramid. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Mn(1), one Co(2), and one Sn(2) atom. In the fifteenth O site, O(15) is bonded to one Li(7), one Mn(4), one Co(3), and one Sn(1) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(4)LiCo2Sn tetrahedra, corners with two equivalent O(7)LiMnCo2 tetrahedra,  a cornercorner with one O(25)LiMn2Co trigonal pyramid,  an edgeedge with one O(3)LiCo2Sn tetrahedra,  an edgeedge with one O(13)LiMnCoSn tetrahedra, and  an edgeedge with one O(5)LiMnCo2 trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(8), one Mn(1), one Co(4), and one Sn(2) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra, corners with two equivalent O(8)LiMnCo2 tetrahedra,  a cornercorner with one O(26)LiMn2Co trigonal pyramid, and  an edgeedge with one O(4)LiCo2Sn tetrahedra. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(2), one Co(3), and one Sn(3) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(1), one Co(4), and one Sn(4) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Li(5), one Mn(2), one Mn(6), and one Sn(1) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(3), one Mn(5), and one Sn(2) atom. In the twenty-first O site, O(21) is bonded to one Li(1), one Mn(2), one Co(5), and one Sn(3) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(24)LiMnCoSn tetrahedra, corners with two equivalent O(9)LiMn2Co tetrahedra,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid,  a cornercorner with one O(5)LiMnCo2 trigonal pyramid,  an edgeedge with one O(23)LiMnCoSn tetrahedra,  an edgeedge with one O(25)LiMn2Co trigonal pyramid, and  an edgeedge with one O(29)LiMn2Sn trigonal pyramid. In the twenty-second O site, O(22) is bonded to one Li(2), one Mn(3), one Co(6), and one Sn(4) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(23)LiMnCoSn tetrahedra, corners with two equivalent O(10)LiMn2Co tetrahedra,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  an edgeedge with one O(24)LiMnCoSn tetrahedra,  an edgeedge with one O(26)LiMn2Co trigonal pyramid, and  an edgeedge with one O(30)LiMn2Sn trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(2), one Mn(5), one Co(5), and one Sn(3) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(22)LiMnCoSn tetrahedra,  a cornercorner with one O(29)LiMn2Sn trigonal pyramid,  an edgeedge with one O(21)LiMnCoSn tetrahedra,  an edgeedge with one O(25)LiMn2Co trigonal pyramid, and  an edgeedge with one O(29)LiMn2Sn trigonal pyramid. In the twenty-fourth O site, O(24) is bonded to one Li(1), one Mn(6), one Co(6), and one Sn(4) atom to form distorted OLiMnCoSn tetrahedra that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(30)LiMn2Sn trigonal pyramid,  a cornercorner with one O(5)LiMnCo2 trigonal pyramid,  an edgeedge with one O(22)LiMnCoSn tetrahedra,  an edgeedge with one O(26)LiMn2Co trigonal pyramid, and  an edgeedge with one O(30)LiMn2Sn trigonal pyramid. In the twenty-fifth O site, O(25) is bonded to one Li(7), one Mn(2), one Mn(5), and one Co(5) atom to form distorted OLiMn2Co trigonal pyramids that share  a cornercorner with one O(4)LiCo2Sn tetrahedra,  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(15)LiMnCoSn tetrahedra, corners with two equivalent O(9)LiMn2Co tetrahedra,  an edgeedge with one O(21)LiMnCoSn tetrahedra,  an edgeedge with one O(23)LiMnCoSn tetrahedra, and  an edgeedge with one O(29)LiMn2Sn trigonal pyramid. In the twenty-sixth O site, O(26) is bonded to one Li(8), one Mn(3), one Mn(6), and one Co(6) atom to form distorted OLiMn2Co trigonal pyramids that share  a cornercorner with one O(3)LiCo2Sn tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(13)LiMnCoSn tetrahedra,  a cornercorner with one O(16)LiMnCoSn tetrahedra, corners with two equivalent O(10)LiMn2Co tetrahedra,  an edgeedge with one O(22)LiMnCoSn tetrahedra,  an edgeedge with one O(24)LiMnCoSn tetrahedra, and  an edgeedge with one O(30)LiMn2Sn trigonal pyramid. In the twenty-seventh O site, O(27) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(4), one Co(2), and one Sn(3) atom. In the twenty-eighth O site, O(28) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(1), one Co(1), and one Sn(4) atom. In the twenty-ninth O site, O(29) is bonded to one Li(2), one Mn(2), one Mn(5), and one Sn(3) atom to form distorted OLiMn2Sn trigonal pyramids that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(22)LiMnCoSn tetrahedra,  a cornercorner with one O(23)LiMnCoSn tetrahedra,  an edgeedge with one O(21)LiMnCoSn tetrahedra,  an edgeedge with one O(23)LiMnCoSn tetrahedra, and  an edgeedge with one O(25)LiMn2Co trigonal pyramid. In the thirtieth O site, O(30) is bonded to one Li(1), one Mn(3), one Mn(6), and one Sn(4) atom to form distorted OLiMn2Sn trigonal pyramids that share  a cornercorner with one O(10)LiMn2Co tetrahedra,  a cornercorner with one O(9)LiMn2Co tetrahedra,  a cornercorner with one O(21)LiMnCoSn tetrahedra,  a cornercorner with one O(24)LiMnCoSn tetrahedra,  a cornercorner with one O(5)LiMnCo2 trigonal pyramid,  an edgeedge with one O(22)LiMnCoSn tetrahedra,  an edgeedge with one O(24)LiMnCoSn tetrahedra, and  an edgeedge with one O(26)LiMn2Co trigonal pyramid. In the thirty-first O site, O(31) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(1), one Co(4), and one Sn(3) atom. In the thirty-second O site, O(32) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(4), one Co(3), and one Sn(4) atom.