LiAg2F4 crystallizes in the orthorhombic Cmce space group. Li(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form a mixture of corner and edge-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FLiAg4 square pyramids. In the second F site, F(2) is bonded in a T-shaped geometry to one Li(1) and two equivalent Ag(1) atoms.
LiAg2F4 crystallizes in the orthorhombic Cmce space group. Li(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Li(1)-F(1) bond lengths are 1.89 Å. Both Li(1)-F(2) bond lengths are 2.18 Å. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form a mixture of corner and edge-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 13-14°. Both Ag(1)-F(2) bond lengths are 2.19 Å. There are two shorter (2.41 Å) and two longer (2.46 Å) Ag(1)-F(1) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded to one Li(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FLiAg4 square pyramids. In the second F site, F(2) is bonded in a T-shaped geometry to one Li(1) and two equivalent Ag(1) atoms.