CaMnSn is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ca(1) is bonded in a 9-coordinate geometry to four equivalent Mn(1) and five equivalent Sn(1) atoms. Mn(1) is bonded in a 8-coordinate geometry to four equivalent Ca(1) and four equivalent Sn(1) atoms. Sn(1) is bonded in a 9-coordinate geometry to five equivalent Ca(1) and four equivalent Mn(1) atoms.
CaMnSn is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Ca(1) is bonded in a 9-coordinate geometry to four equivalent Mn(1) and five equivalent Sn(1) atoms. All Ca(1)-Mn(1) bond lengths are 3.28 Å. There are four shorter (3.29 Å) and one longer (3.37 Å) Ca(1)-Sn(1) bond length. Mn(1) is bonded in a 8-coordinate geometry to four equivalent Ca(1) and four equivalent Sn(1) atoms. All Mn(1)-Sn(1) bond lengths are 2.78 Å. Sn(1) is bonded in a 9-coordinate geometry to five equivalent Ca(1) and four equivalent Mn(1) atoms.