NaInSn4 crystallizes in the tetragonal I422 space group. Na(1) is bonded in a distorted q6 geometry to two equivalent In(1) and eight equivalent Sn(1) atoms. In(1) is bonded in a 10-coordinate geometry to two equivalent Na(1) and eight equivalent Sn(1) atoms. Sn(1) is bonded in a 5-coordinate geometry to two equivalent Na(1), two equivalent In(1), and one Sn(1) atom.
NaInSn4 crystallizes in the tetragonal I422 space group. Na(1) is bonded in a distorted q6 geometry to two equivalent In(1) and eight equivalent Sn(1) atoms. Both Na(1)-In(1) bond lengths are 3.08 Å. All Na(1)-Sn(1) bond lengths are 3.21 Å. In(1) is bonded in a 10-coordinate geometry to two equivalent Na(1) and eight equivalent Sn(1) atoms. All In(1)-Sn(1) bond lengths are 3.21 Å. Sn(1) is bonded in a 5-coordinate geometry to two equivalent Na(1), two equivalent In(1), and one Sn(1) atom. The Sn(1)-Sn(1) bond length is 3.12 Å.