ZrRuSi crystallizes in the hexagonal P-62m space group. Zr(1) is bonded in a 11-coordinate geometry to six equivalent Ru(1), one Si(1), and four equivalent Si(2) atoms. Ru(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1), two equivalent Si(1), and two equivalent Si(2) atoms. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to three equivalent Zr(1) and six equivalent Ru(1) atoms. In the second Si site, Si(2) is bonded in a 9-coordinate geometry to six equivalent Zr(1) and three equivalent Ru(1) atoms.
ZrRuSi crystallizes in the hexagonal P-62m space group. Zr(1) is bonded in a 11-coordinate geometry to six equivalent Ru(1), one Si(1), and four equivalent Si(2) atoms. There are two shorter (2.93 Å) and four longer (3.04 Å) Zr(1)-Ru(1) bond lengths. The Zr(1)-Si(1) bond length is 2.78 Å. All Zr(1)-Si(2) bond lengths are 2.73 Å. Ru(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1), two equivalent Si(1), and two equivalent Si(2) atoms. Both Ru(1)-Si(1) bond lengths are 2.46 Å. Both Ru(1)-Si(2) bond lengths are 2.58 Å. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to three equivalent Zr(1) and six equivalent Ru(1) atoms. In the second Si site, Si(2) is bonded in a 9-coordinate geometry to six equivalent Zr(1) and three equivalent Ru(1) atoms.