CrH10S2(NO2)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CrH10S2(NO2)4 cluster. Cr(1) is bonded in a 4-coordinate geometry to two equivalent N(2) and two equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one H(2), one H(3), and one H(5) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Cr(1), one H(1), and one H(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a 2-coordinate geometry to one N(1) and one O(3) atom. S(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cr(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one H(5) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom.
CrH10S2(NO2)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CrH10S2(NO2)4 cluster. Cr(1) is bonded in a 4-coordinate geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Cr(1)-N(2) bond lengths are 2.18 Å. Both Cr(1)-O(1) bond lengths are 2.15 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one H(2), one H(3), and one H(5) atom. The N(1)-H(2) bond length is 0.96 Å. The N(1)-H(3) bond length is 1.24 Å. The N(1)-H(5) bond length is 1.02 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Cr(1), one H(1), and one H(4) atom. The N(2)-H(1) bond length is 1.22 Å. The N(2)-H(4) bond length is 0.93 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a 2-coordinate geometry to one N(1) and one O(3) atom. The H(5)-O(3) bond length is 1.49 Å. S(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.41 Å. The S(1)-O(2) bond length is 1.52 Å. The S(1)-O(3) bond length is 1.58 Å. The S(1)-O(4) bond length is 1.79 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cr(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one H(5) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom.