Li(WO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with twelve equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra and edges with six equivalent W(1)O6 octahedra. O(1) is bonded to one Li(1) and three equivalent W(1) atoms to form a mixture of distorted edge and corner-sharing OLiW3 trigonal pyramids.
Li(WO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with twelve equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. All Li(1)-O(1) bond lengths are 2.14 Å. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra and edges with six equivalent W(1)O6 octahedra. All W(1)-O(1) bond lengths are 2.15 Å. O(1) is bonded to one Li(1) and three equivalent W(1) atoms to form a mixture of distorted edge and corner-sharing OLiW3 trigonal pyramids.