Li4Co5Te3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Te(3)O6 octahedra, and corners with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-69°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-69°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Te(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, and corners with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-61°. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom. In the second Co site, Co(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the third Co site, Co(3) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted CoO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, corners with two equivalent Te(2)O6 octahedra, corners with three equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. In the fourth Co site, Co(4) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Te(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Te(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. In the second Te site, Te(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. In the third Te site, Te(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TeO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(4), and one Te(3) atom. In the second O site, O(2) is bonded to one Li(4), one Co(1), one Te(1), and one Te(2) atom to form distorted OLiCoTe2 tetrahedra that share  a cornercorner with one O(7)LiCo2Te tetrahedra,  a cornercorner with one O(8)LiCo2Te tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid,  a cornercorner with one O(16)LiCo2Te trigonal pyramid, corners with two equivalent O(4)LiCoTe2 trigonal pyramids,  an edgeedge with one O(7)LiCo2Te tetrahedra, and  an edgeedge with one O(8)LiCo2Te tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(2), one Te(1), and one Te(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one Co(2), one Te(1), and one Te(2) atom to form distorted OLiCoTe2 trigonal pyramids that share corners with two equivalent O(7)LiCo2Te tetrahedra, corners with two equivalent O(8)LiCo2Te tetrahedra, corners with two equivalent O(2)LiCoTe2 tetrahedra,  an edgeedge with one O(14)LiCo2Te trigonal pyramid, and  an edgeedge with one O(16)LiCo2Te trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Co(4), one Co(5), and one Te(3) atom to form distorted OLiCo2Te tetrahedra that share corners with two equivalent O(15)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid, and  a cornercorner with one O(16)LiCo2Te trigonal pyramid. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(5), and one Te(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Co(1), one Co(2), and one Te(1) atom to form distorted OLiCo2Te tetrahedra that share  a cornercorner with one O(8)LiCo2Te tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra,  a cornercorner with one O(16)LiCo2Te trigonal pyramid, corners with two equivalent O(14)LiCo2Te trigonal pyramids, corners with two equivalent O(4)LiCoTe2 trigonal pyramids,  an edgeedge with one O(8)LiCo2Te tetrahedra, and  an edgeedge with one O(2)LiCoTe2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Co(1), one Co(2), and one Te(2) atom to form distorted OLiCo2Te tetrahedra that share  a cornercorner with one O(7)LiCo2Te tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid, corners with two equivalent O(16)LiCo2Te trigonal pyramids, corners with two equivalent O(4)LiCoTe2 trigonal pyramids,  an edgeedge with one O(7)LiCo2Te tetrahedra, and  an edgeedge with one O(2)LiCoTe2 tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(3), one Te(1), and one Te(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(4), and one Co(5) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(3), one Co(4), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(3), one Co(5), and one Te(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(4), one Co(5), and one Te(3) atom. In the fourteenth O site, O(14) is bonded to one Li(2), one Co(2), one Co(3), and one Te(1) atom to form distorted OLiCo2Te trigonal pyramids that share  a cornercorner with one O(5)LiCo2Te tetrahedra,  a cornercorner with one O(8)LiCo2Te tetrahedra,  a cornercorner with one O(15)LiCo3 tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra, corners with two equivalent O(7)LiCo2Te tetrahedra,  a cornercorner with one O(16)LiCo2Te trigonal pyramid,  an edgeedge with one O(16)LiCo2Te trigonal pyramid, and  an edgeedge with one O(4)LiCoTe2 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(1), one Co(3), one Co(4), and one Co(5) atom to form distorted corner-sharing OLiCo3 tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(2), one Co(2), one Co(3), and one Te(2) atom to form distorted OLiCo2Te trigonal pyramids that share  a cornercorner with one O(5)LiCo2Te tetrahedra,  a cornercorner with one O(7)LiCo2Te tetrahedra,  a cornercorner with one O(15)LiCo3 tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra, corners with two equivalent O(8)LiCo2Te tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid,  an edgeedge with one O(14)LiCo2Te trigonal pyramid, and  an edgeedge with one O(4)LiCoTe2 trigonal pyramid.
Li4Co5Te3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Te(3)O6 octahedra, and corners with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-69°. The Li(1)-O(11) bond length is 2.02 Å. The Li(1)-O(12) bond length is 2.06 Å. The Li(1)-O(15) bond length is 1.96 Å. The Li(1)-O(3) bond length is 2.30 Å. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. The Li(2)-O(14) bond length is 1.97 Å. The Li(2)-O(16) bond length is 1.97 Å. The Li(2)-O(5) bond length is 1.79 Å. The Li(2)-O(9) bond length is 2.14 Å. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-69°. The Li(3)-O(1) bond length is 1.98 Å. The Li(3)-O(10) bond length is 1.89 Å. The Li(3)-O(4) bond length is 1.85 Å. The Li(3)-O(6) bond length is 1.98 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Te(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, and corners with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-61°. The Li(4)-O(13) bond length is 1.98 Å. The Li(4)-O(2) bond length is 2.19 Å. The Li(4)-O(7) bond length is 2.01 Å. The Li(4)-O(8) bond length is 2.06 Å. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom. The Co(1)-O(1) bond length is 2.07 Å. The Co(1)-O(10) bond length is 1.96 Å. The Co(1)-O(2) bond length is 2.50 Å. The Co(1)-O(6) bond length is 2.13 Å. The Co(1)-O(7) bond length is 2.43 Å. The Co(1)-O(8) bond length is 2.49 Å. In the second Co site, Co(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, edges with two equivalent Te(1)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. The Co(2)-O(14) bond length is 2.11 Å. The Co(2)-O(16) bond length is 2.13 Å. The Co(2)-O(3) bond length is 2.17 Å. The Co(2)-O(4) bond length is 2.14 Å. The Co(2)-O(7) bond length is 2.07 Å. The Co(2)-O(8) bond length is 2.09 Å. In the third Co site, Co(3) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted CoO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, corners with two equivalent Te(2)O6 octahedra, corners with three equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. The Co(3)-O(11) bond length is 2.13 Å. The Co(3)-O(12) bond length is 2.16 Å. The Co(3)-O(14) bond length is 2.17 Å. The Co(3)-O(15) bond length is 2.01 Å. The Co(3)-O(16) bond length is 2.25 Å. The Co(3)-O(9) bond length is 2.54 Å. In the fourth Co site, Co(4) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Te(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The Co(4)-O(1) bond length is 2.16 Å. The Co(4)-O(10) bond length is 2.15 Å. The Co(4)-O(11) bond length is 2.19 Å. The Co(4)-O(13) bond length is 2.12 Å. The Co(4)-O(15) bond length is 2.10 Å. The Co(4)-O(5) bond length is 2.10 Å. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Te(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The Co(5)-O(10) bond length is 1.93 Å. The Co(5)-O(12) bond length is 2.19 Å. The Co(5)-O(13) bond length is 2.13 Å. The Co(5)-O(15) bond length is 1.90 Å. The Co(5)-O(5) bond length is 2.09 Å. The Co(5)-O(6) bond length is 2.16 Å. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. The Te(1)-O(14) bond length is 2.03 Å. The Te(1)-O(2) bond length is 2.13 Å. The Te(1)-O(3) bond length is 2.11 Å. The Te(1)-O(4) bond length is 2.12 Å. The Te(1)-O(7) bond length is 1.98 Å. The Te(1)-O(9) bond length is 2.11 Å. In the second Te site, Te(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. The Te(2)-O(16) bond length is 1.95 Å. The Te(2)-O(2) bond length is 2.01 Å. The Te(2)-O(3) bond length is 2.01 Å. The Te(2)-O(4) bond length is 2.01 Å. The Te(2)-O(8) bond length is 1.93 Å. The Te(2)-O(9) bond length is 2.00 Å. In the third Te site, Te(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TeO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The Te(3)-O(1) bond length is 2.00 Å. The Te(3)-O(11) bond length is 1.97 Å. The Te(3)-O(12) bond length is 1.97 Å. The Te(3)-O(13) bond length is 1.97 Å. The Te(3)-O(5) bond length is 1.95 Å. The Te(3)-O(6) bond length is 2.01 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(4), and one Te(3) atom. In the second O site, O(2) is bonded to one Li(4), one Co(1), one Te(1), and one Te(2) atom to form distorted OLiCoTe2 tetrahedra that share  a cornercorner with one O(7)LiCo2Te tetrahedra,  a cornercorner with one O(8)LiCo2Te tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid,  a cornercorner with one O(16)LiCo2Te trigonal pyramid, corners with two equivalent O(4)LiCoTe2 trigonal pyramids,  an edgeedge with one O(7)LiCo2Te tetrahedra, and  an edgeedge with one O(8)LiCo2Te tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(2), one Te(1), and one Te(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one Co(2), one Te(1), and one Te(2) atom to form distorted OLiCoTe2 trigonal pyramids that share corners with two equivalent O(7)LiCo2Te tetrahedra, corners with two equivalent O(8)LiCo2Te tetrahedra, corners with two equivalent O(2)LiCoTe2 tetrahedra,  an edgeedge with one O(14)LiCo2Te trigonal pyramid, and  an edgeedge with one O(16)LiCo2Te trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Co(4), one Co(5), and one Te(3) atom to form distorted OLiCo2Te tetrahedra that share corners with two equivalent O(15)LiCo3 tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid, and  a cornercorner with one O(16)LiCo2Te trigonal pyramid. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(5), and one Te(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Co(1), one Co(2), and one Te(1) atom to form distorted OLiCo2Te tetrahedra that share  a cornercorner with one O(8)LiCo2Te tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra,  a cornercorner with one O(16)LiCo2Te trigonal pyramid, corners with two equivalent O(14)LiCo2Te trigonal pyramids, corners with two equivalent O(4)LiCoTe2 trigonal pyramids,  an edgeedge with one O(8)LiCo2Te tetrahedra, and  an edgeedge with one O(2)LiCoTe2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Co(1), one Co(2), and one Te(2) atom to form distorted OLiCo2Te tetrahedra that share  a cornercorner with one O(7)LiCo2Te tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid, corners with two equivalent O(16)LiCo2Te trigonal pyramids, corners with two equivalent O(4)LiCoTe2 trigonal pyramids,  an edgeedge with one O(7)LiCo2Te tetrahedra, and  an edgeedge with one O(2)LiCoTe2 tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(3), one Te(1), and one Te(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(1), one Co(4), and one Co(5) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(3), one Co(4), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(1), one Co(3), one Co(5), and one Te(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Co(4), one Co(5), and one Te(3) atom. In the fourteenth O site, O(14) is bonded to one Li(2), one Co(2), one Co(3), and one Te(1) atom to form distorted OLiCo2Te trigonal pyramids that share  a cornercorner with one O(5)LiCo2Te tetrahedra,  a cornercorner with one O(8)LiCo2Te tetrahedra,  a cornercorner with one O(15)LiCo3 tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra, corners with two equivalent O(7)LiCo2Te tetrahedra,  a cornercorner with one O(16)LiCo2Te trigonal pyramid,  an edgeedge with one O(16)LiCo2Te trigonal pyramid, and  an edgeedge with one O(4)LiCoTe2 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(1), one Co(3), one Co(4), and one Co(5) atom to form distorted corner-sharing OLiCo3 tetrahedra. In the sixteenth O site, O(16) is bonded to one Li(2), one Co(2), one Co(3), and one Te(2) atom to form distorted OLiCo2Te trigonal pyramids that share  a cornercorner with one O(5)LiCo2Te tetrahedra,  a cornercorner with one O(7)LiCo2Te tetrahedra,  a cornercorner with one O(15)LiCo3 tetrahedra,  a cornercorner with one O(2)LiCoTe2 tetrahedra, corners with two equivalent O(8)LiCo2Te tetrahedra,  a cornercorner with one O(14)LiCo2Te trigonal pyramid,  an edgeedge with one O(14)LiCo2Te trigonal pyramid, and  an edgeedge with one O(4)LiCoTe2 trigonal pyramid.