LiVAlO4 crystallizes in the hexagonal P6_222 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Al(1)O4 tetrahedra. Al(1) is bonded to four equivalent O(1) atoms to form AlO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra. O(1) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one Al(1) atom.
LiVAlO4 crystallizes in the hexagonal P6_222 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.06 Å. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Al(1)O4 tetrahedra. All V(1)-O(1) bond lengths are 1.82 Å. Al(1) is bonded to four equivalent O(1) atoms to form AlO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra. All Al(1)-O(1) bond lengths are 1.77 Å. O(1) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one Al(1) atom.