AgSbS2 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(4) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal pyramidal geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(2) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(1) atom.
AgSbS2 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. The Ag(1)-S(1) bond length is 2.66 Å. The Ag(1)-S(2) bond length is 2.66 Å. The Ag(1)-S(3) bond length is 2.58 Å. The Ag(1)-S(4) bond length is 2.58 Å. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. The Ag(2)-S(1) bond length is 3.07 Å. The Ag(2)-S(2) bond length is 3.14 Å. The Ag(2)-S(3) bond length is 2.41 Å. The Ag(2)-S(4) bond length is 2.41 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(4) atom. The Sb(1)-S(1) bond length is 2.54 Å. The Sb(1)-S(2) bond length is 2.55 Å. The Sb(1)-S(4) bond length is 2.49 Å. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. The Sb(2)-S(1) bond length is 2.55 Å. The Sb(2)-S(2) bond length is 2.53 Å. The Sb(2)-S(3) bond length is 2.49 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal pyramidal geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(2) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(1) atom.