AgLi2Sn is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to six equivalent Ag(1) and four equivalent Sn(1) atoms to form distorted LiAg6Sn4 tetrahedra that share corners with six equivalent Li(1)Ag6Sn4 tetrahedra, corners with twelve equivalent Li(2)Ag4 tetrahedra, corners with twelve equivalent Sn(1)Li4Ag4 tetrahedra, faces with four equivalent Li(2)Ag4 tetrahedra, faces with four equivalent Sn(1)Li4Ag4 tetrahedra, and faces with twelve equivalent Li(1)Ag6Sn4 tetrahedra. In the second Li site, Li(2) is bonded to four equivalent Ag(1) atoms to form distorted LiAg4 tetrahedra that share corners with four equivalent Sn(1)Li4Ag4 tetrahedra, corners with twelve equivalent Li(2)Ag4 tetrahedra, corners with twelve equivalent Li(1)Ag6Sn4 tetrahedra, edges with six equivalent Sn(1)Li4Ag4 tetrahedra, and faces with four equivalent Li(1)Ag6Sn4 tetrahedra. Ag(1) is bonded in a 14-coordinate geometry to four equivalent Li(2), six equivalent Li(1), and four equivalent Sn(1) atoms. Sn(1) is bonded to four equivalent Li(1) and four equivalent Ag(1) atoms to form distorted SnLi4Ag4 tetrahedra that share corners with four equivalent Li(2)Ag4 tetrahedra, corners with twelve equivalent Li(1)Ag6Sn4 tetrahedra, edges with six equivalent Li(2)Ag4 tetrahedra, edges with twelve equivalent Sn(1)Li4Ag4 tetrahedra, and faces with four equivalent Li(1)Ag6Sn4 tetrahedra.
AgLi2Sn is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to six equivalent Ag(1) and four equivalent Sn(1) atoms to form distorted LiAg6Sn4 tetrahedra that share corners with six equivalent Li(1)Ag6Sn4 tetrahedra, corners with twelve equivalent Li(2)Ag4 tetrahedra, corners with twelve equivalent Sn(1)Li4Ag4 tetrahedra, faces with four equivalent Li(2)Ag4 tetrahedra, faces with four equivalent Sn(1)Li4Ag4 tetrahedra, and faces with twelve equivalent Li(1)Ag6Sn4 tetrahedra. All Li(1)-Ag(1) bond lengths are 3.27 Å. All Li(1)-Sn(1) bond lengths are 2.83 Å. In the second Li site, Li(2) is bonded to four equivalent Ag(1) atoms to form distorted LiAg4 tetrahedra that share corners with four equivalent Sn(1)Li4Ag4 tetrahedra, corners with twelve equivalent Li(2)Ag4 tetrahedra, corners with twelve equivalent Li(1)Ag6Sn4 tetrahedra, edges with six equivalent Sn(1)Li4Ag4 tetrahedra, and faces with four equivalent Li(1)Ag6Sn4 tetrahedra. All Li(2)-Ag(1) bond lengths are 2.83 Å. Ag(1) is bonded in a 14-coordinate geometry to four equivalent Li(2), six equivalent Li(1), and four equivalent Sn(1) atoms. All Ag(1)-Sn(1) bond lengths are 2.83 Å. Sn(1) is bonded to four equivalent Li(1) and four equivalent Ag(1) atoms to form distorted SnLi4Ag4 tetrahedra that share corners with four equivalent Li(2)Ag4 tetrahedra, corners with twelve equivalent Li(1)Ag6Sn4 tetrahedra, edges with six equivalent Li(2)Ag4 tetrahedra, edges with twelve equivalent Sn(1)Li4Ag4 tetrahedra, and faces with four equivalent Li(1)Ag6Sn4 tetrahedra.