KMgN crystallizes in the hexagonal P-6m2 space group. K(1) is bonded to six equivalent Mg(1) and six equivalent N(1) atoms to form a mixture of distorted face and edge-sharing KMg6N6 cuboctahedra. Mg(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent N(1) atoms. N(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent Mg(1) atoms.
KMgN crystallizes in the hexagonal P-6m2 space group. K(1) is bonded to six equivalent Mg(1) and six equivalent N(1) atoms to form a mixture of distorted face and edge-sharing KMg6N6 cuboctahedra. All K(1)-Mg(1) bond lengths are 3.26 Å. All K(1)-N(1) bond lengths are 3.26 Å. Mg(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent N(1) atoms. All Mg(1)-N(1) bond lengths are 2.08 Å. N(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent Mg(1) atoms.