Na2Pt(OCl)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom. Pt(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one O(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one O(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Pt(1) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Na(1) and one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Na(1) and one Pt(1) atom.
Na2Pt(OCl)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom. The Na(1)-O(1) bond length is 2.65 Å. The Na(1)-O(2) bond length is 2.82 Å. The Na(1)-O(3) bond length is 2.72 Å. The Na(1)-Cl(1) bond length is 2.91 Å. The Na(1)-Cl(2) bond length is 2.95 Å. The Na(1)-Cl(3) bond length is 2.71 Å. Pt(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. Both Pt(1)-Cl(1) bond lengths are 2.36 Å. Both Pt(1)-Cl(2) bond lengths are 2.35 Å. Both Pt(1)-Cl(3) bond lengths are 2.35 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(1) atom. The O(1)-O(1) bond length is 1.23 Å. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one O(3) atom. The O(2)-O(3) bond length is 1.24 Å. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one O(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Pt(1) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Na(1) and one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Na(1) and one Pt(1) atom.