GeS2 crystallizes in the tetragonal I-42d space group. Ge(1) is bonded to four equivalent S(1) atoms to form corner-sharing GeS4 tetrahedra. S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms.
GeS2 crystallizes in the tetragonal I-42d space group. Ge(1) is bonded to four equivalent S(1) atoms to form corner-sharing GeS4 tetrahedra. All Ge(1)-S(1) bond lengths are 2.23 Å. S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms.