ReVO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic P2_1/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms to form VO6 octahedra that share corners with four equivalent Re(1)O6 octahedra, corners with four equivalent Re(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-48°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms to form VO6 octahedra that share corners with four equivalent Re(1)O6 octahedra, corners with four equivalent Re(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-49°. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-49°. In the second Re site, Re(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2), one Re(1), and one Re(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Re(1), and one Re(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(1) atom.
ReVO4 is beta Vanadium nitride-derived structured and crystallizes in the monoclinic P2_1/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms to form VO6 octahedra that share corners with four equivalent Re(1)O6 octahedra, corners with four equivalent Re(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-48°. The V(1)-O(3) bond length is 1.98 Å. The V(1)-O(4) bond length is 1.96 Å. The V(1)-O(5) bond length is 1.97 Å. The V(1)-O(6) bond length is 1.96 Å. Both V(1)-O(2) bond lengths are 1.88 Å. In the second V site, V(2) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms to form VO6 octahedra that share corners with four equivalent Re(1)O6 octahedra, corners with four equivalent Re(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-49°. The V(2)-O(3) bond length is 1.94 Å. The V(2)-O(4) bond length is 1.96 Å. The V(2)-O(5) bond length is 1.95 Å. The V(2)-O(6) bond length is 1.96 Å. Both V(2)-O(1) bond lengths are 2.08 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-49°. The Re(1)-O(3) bond length is 1.93 Å. The Re(1)-O(6) bond length is 1.93 Å. Both Re(1)-O(1) bond lengths are 2.03 Å. Both Re(1)-O(2) bond lengths are 1.97 Å. In the second Re site, Re(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form ReO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra, and edges with two equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-49°. The Re(2)-O(4) bond length is 1.93 Å. The Re(2)-O(5) bond length is 1.93 Å. Both Re(2)-O(1) bond lengths are 2.03 Å. Both Re(2)-O(2) bond lengths are 1.97 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2), one Re(1), and one Re(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Re(1), and one Re(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one Re(1) atom.