LiVTiO4 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-22°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-18°. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-17°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(6), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-12°. In the second Ti site, Ti(2) is bonded to one O(2), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-17°. In the third Ti site, Ti(3) is bonded to one O(10), one O(11), one O(4), one O(5), one O(6), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-16°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. In the third V site, V(3) is bonded to one O(10), one O(12), one O(3), one O(5), one O(6), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-18°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one V(1), and one V(2) atom. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ti(1), one Ti(2), and one V(1) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(11)Li2Ti2V square pyramid,  a cornercorner with one O(10)Li2TiV2 square pyramid,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(4)Li2Ti2V square pyramid,  an edgeedge with one O(6)Li2Ti2V square pyramid, edges with two equivalent O(7)Li2Ti2V square pyramids, and  an edgeedge with one O(8)LiTiV2 trigonal pyramid. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(2), one V(2), and one V(3) atom. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Ti(2), one Ti(3), and one V(2) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(7)Li2Ti2V square pyramid, corners with two equivalent O(11)Li2Ti2V square pyramids, corners with two equivalent O(8)LiTiV2 trigonal pyramids,  an edgeedge with one O(2)Li2Ti2V square pyramid,  an edgeedge with one O(6)Li2Ti2V square pyramid,  an edgeedge with one O(7)Li2Ti2V square pyramid, and edges with two equivalent O(10)Li2TiV2 square pyramids. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Ti(3), one V(1), and one V(3) atom. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Ti(1), one Ti(3), and one V(3) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(10)Li2TiV2 square pyramid, corners with two equivalent O(7)Li2Ti2V square pyramids,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(2)Li2Ti2V square pyramid,  an edgeedge with one O(4)Li2Ti2V square pyramid,  an edgeedge with one O(10)Li2TiV2 square pyramid, and edges with two equivalent O(11)Li2Ti2V square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Ti(1), one Ti(2), and one V(2) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(4)Li2Ti2V square pyramid, corners with two equivalent O(6)Li2Ti2V square pyramids,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(4)Li2Ti2V square pyramid,  an edgeedge with one O(10)Li2TiV2 square pyramid, edges with two equivalent O(2)Li2Ti2V square pyramids, and  an edgeedge with one O(8)LiTiV2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Ti(2), one V(1), and one V(2) atom to form OLiTiV2 trigonal pyramids that share  a cornercorner with one O(2)Li2Ti2V square pyramid,  a cornercorner with one O(6)Li2Ti2V square pyramid,  a cornercorner with one O(7)Li2Ti2V square pyramid,  a cornercorner with one O(10)Li2TiV2 square pyramid, corners with two equivalent O(4)Li2Ti2V square pyramids,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(2)Li2Ti2V square pyramid, and  an edgeedge with one O(7)Li2Ti2V square pyramid. In the ninth O site, O(9) is bonded in a see-saw-like geometry to one Li(2), one Ti(2), one Ti(3), and one V(3) atom. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Ti(3), one V(2), and one V(3) atom to form OLi2TiV2 square pyramids that share  a cornercorner with one O(2)Li2Ti2V square pyramid,  a cornercorner with one O(6)Li2Ti2V square pyramid,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(6)Li2Ti2V square pyramid,  an edgeedge with one O(7)Li2Ti2V square pyramid, and edges with two equivalent O(4)Li2Ti2V square pyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one Ti(1), one Ti(3), and one V(1) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(2)Li2Ti2V square pyramid, corners with two equivalent O(4)Li2Ti2V square pyramids,  an edgeedge with one O(2)Li2Ti2V square pyramid,  an edgeedge with one O(7)Li2Ti2V square pyramid,  an edgeedge with one O(10)Li2TiV2 square pyramid, edges with two equivalent O(6)Li2Ti2V square pyramids, and  an edgeedge with one O(8)LiTiV2 trigonal pyramid. In the twelfth O site, O(12) is bonded in a see-saw-like geometry to one Li(3), one Ti(1), one V(1), and one V(3) atom.
LiVTiO4 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-22°. The Li(1)-O(11) bond length is 2.32 Å. The Li(1)-O(2) bond length is 2.19 Å. The Li(1)-O(5) bond length is 2.23 Å. The Li(1)-O(6) bond length is 2.25 Å. The Li(1)-O(7) bond length is 2.21 Å. The Li(1)-O(8) bond length is 2.08 Å. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-18°. The Li(2)-O(1) bond length is 2.17 Å. The Li(2)-O(10) bond length is 2.20 Å. The Li(2)-O(2) bond length is 2.18 Å. The Li(2)-O(4) bond length is 2.26 Å. The Li(2)-O(7) bond length is 2.24 Å. The Li(2)-O(9) bond length is 2.18 Å. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-17°. The Li(3)-O(10) bond length is 2.15 Å. The Li(3)-O(11) bond length is 2.27 Å. The Li(3)-O(12) bond length is 2.19 Å. The Li(3)-O(3) bond length is 2.07 Å. The Li(3)-O(4) bond length is 2.32 Å. The Li(3)-O(6) bond length is 2.28 Å. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(6), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-12°. The Ti(1)-O(1) bond length is 1.91 Å. The Ti(1)-O(11) bond length is 2.03 Å. The Ti(1)-O(12) bond length is 1.89 Å. The Ti(1)-O(2) bond length is 2.06 Å. The Ti(1)-O(6) bond length is 2.16 Å. The Ti(1)-O(7) bond length is 1.93 Å. In the second Ti site, Ti(2) is bonded to one O(2), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-17°. The Ti(2)-O(2) bond length is 1.97 Å. The Ti(2)-O(3) bond length is 1.88 Å. The Ti(2)-O(4) bond length is 2.00 Å. The Ti(2)-O(7) bond length is 2.15 Å. The Ti(2)-O(8) bond length is 1.98 Å. The Ti(2)-O(9) bond length is 2.00 Å. In the third Ti site, Ti(3) is bonded to one O(10), one O(11), one O(4), one O(5), one O(6), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. The Ti(3)-O(10) bond length is 2.00 Å. The Ti(3)-O(11) bond length is 1.99 Å. The Ti(3)-O(4) bond length is 2.08 Å. The Ti(3)-O(5) bond length is 1.92 Å. The Ti(3)-O(6) bond length is 1.96 Å. The Ti(3)-O(9) bond length is 1.97 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-16°. The V(1)-O(1) bond length is 2.04 Å. The V(1)-O(11) bond length is 2.08 Å. The V(1)-O(12) bond length is 2.11 Å. The V(1)-O(2) bond length is 2.13 Å. The V(1)-O(5) bond length is 1.99 Å. The V(1)-O(8) bond length is 2.00 Å. In the second V site, V(2) is bonded to one O(1), one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-22°. The V(2)-O(1) bond length is 2.06 Å. The V(2)-O(10) bond length is 2.04 Å. The V(2)-O(3) bond length is 2.09 Å. The V(2)-O(4) bond length is 2.06 Å. The V(2)-O(7) bond length is 2.08 Å. The V(2)-O(8) bond length is 2.01 Å. In the third V site, V(3) is bonded to one O(10), one O(12), one O(3), one O(5), one O(6), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-18°. The V(3)-O(10) bond length is 2.10 Å. The V(3)-O(12) bond length is 2.00 Å. The V(3)-O(3) bond length is 2.03 Å. The V(3)-O(5) bond length is 2.09 Å. The V(3)-O(6) bond length is 2.07 Å. The V(3)-O(9) bond length is 2.06 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one V(1), and one V(2) atom. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ti(1), one Ti(2), and one V(1) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(11)Li2Ti2V square pyramid,  a cornercorner with one O(10)Li2TiV2 square pyramid,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(4)Li2Ti2V square pyramid,  an edgeedge with one O(6)Li2Ti2V square pyramid, edges with two equivalent O(7)Li2Ti2V square pyramids, and  an edgeedge with one O(8)LiTiV2 trigonal pyramid. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(2), one V(2), and one V(3) atom. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Ti(2), one Ti(3), and one V(2) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(7)Li2Ti2V square pyramid, corners with two equivalent O(11)Li2Ti2V square pyramids, corners with two equivalent O(8)LiTiV2 trigonal pyramids,  an edgeedge with one O(2)Li2Ti2V square pyramid,  an edgeedge with one O(6)Li2Ti2V square pyramid,  an edgeedge with one O(7)Li2Ti2V square pyramid, and edges with two equivalent O(10)Li2TiV2 square pyramids. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(1), one Ti(3), one V(1), and one V(3) atom. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Ti(1), one Ti(3), and one V(3) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(10)Li2TiV2 square pyramid, corners with two equivalent O(7)Li2Ti2V square pyramids,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(2)Li2Ti2V square pyramid,  an edgeedge with one O(4)Li2Ti2V square pyramid,  an edgeedge with one O(10)Li2TiV2 square pyramid, and edges with two equivalent O(11)Li2Ti2V square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Ti(1), one Ti(2), and one V(2) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(4)Li2Ti2V square pyramid, corners with two equivalent O(6)Li2Ti2V square pyramids,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(4)Li2Ti2V square pyramid,  an edgeedge with one O(10)Li2TiV2 square pyramid, edges with two equivalent O(2)Li2Ti2V square pyramids, and  an edgeedge with one O(8)LiTiV2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Ti(2), one V(1), and one V(2) atom to form OLiTiV2 trigonal pyramids that share  a cornercorner with one O(2)Li2Ti2V square pyramid,  a cornercorner with one O(6)Li2Ti2V square pyramid,  a cornercorner with one O(7)Li2Ti2V square pyramid,  a cornercorner with one O(10)Li2TiV2 square pyramid, corners with two equivalent O(4)Li2Ti2V square pyramids,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(2)Li2Ti2V square pyramid, and  an edgeedge with one O(7)Li2Ti2V square pyramid. In the ninth O site, O(9) is bonded in a see-saw-like geometry to one Li(2), one Ti(2), one Ti(3), and one V(3) atom. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Ti(3), one V(2), and one V(3) atom to form OLi2TiV2 square pyramids that share  a cornercorner with one O(2)Li2Ti2V square pyramid,  a cornercorner with one O(6)Li2Ti2V square pyramid,  a cornercorner with one O(8)LiTiV2 trigonal pyramid,  an edgeedge with one O(11)Li2Ti2V square pyramid,  an edgeedge with one O(6)Li2Ti2V square pyramid,  an edgeedge with one O(7)Li2Ti2V square pyramid, and edges with two equivalent O(4)Li2Ti2V square pyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one Ti(1), one Ti(3), and one V(1) atom to form OLi2Ti2V square pyramids that share  a cornercorner with one O(2)Li2Ti2V square pyramid, corners with two equivalent O(4)Li2Ti2V square pyramids,  an edgeedge with one O(2)Li2Ti2V square pyramid,  an edgeedge with one O(7)Li2Ti2V square pyramid,  an edgeedge with one O(10)Li2TiV2 square pyramid, edges with two equivalent O(6)Li2Ti2V square pyramids, and  an edgeedge with one O(8)LiTiV2 trigonal pyramid. In the twelfth O site, O(12) is bonded in a see-saw-like geometry to one Li(3), one Ti(1), one V(1), and one V(3) atom.