Zr6BCl18(O2)12 is Indium-derived structured and crystallizes in the cubic Im-3m space group. The structure is zero-dimensional and consists of twenty-four hydrogen peroxide molecules and two Zr6BCl18 clusters. In each Zr6BCl18 cluster, Zr(1) is bonded to one B(1), one Cl(2), and four equivalent Cl(1) atoms to form a mixture of corner and edge-sharing ZrBCl5 octahedra. The corner-sharing octahedra are not tilted. B(1) is bonded in an octahedral geometry to six equivalent Zr(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Zr(1) atom. In the second Cl site, Cl(1) is bonded in an L-shaped geometry to two equivalent Zr(1) atoms.
Zr6BCl18(O2)12 is Indium-derived structured and crystallizes in the cubic Im-3m space group. The structure is zero-dimensional and consists of twenty-four hydrogen peroxide molecules and two Zr6BCl18 clusters. In each Zr6BCl18 cluster, Zr(1) is bonded to one B(1), one Cl(2), and four equivalent Cl(1) atoms to form a mixture of corner and edge-sharing ZrBCl5 octahedra. The corner-sharing octahedra are not tilted. The Zr(1)-B(1) bond length is 2.52 Å. The Zr(1)-Cl(2) bond length is 2.39 Å. All Zr(1)-Cl(1) bond lengths are 2.54 Å. B(1) is bonded in an octahedral geometry to six equivalent Zr(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Zr(1) atom. In the second Cl site, Cl(1) is bonded in an L-shaped geometry to two equivalent Zr(1) atoms.