Li4V3Ni2Sn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, and corners with three equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form NiO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. In the second Ni site, Ni(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form NiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the second Sn site, Sn(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the third Sn site, Sn(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Ni(1), and one Sn(3) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Ni(1), one Sn(1), and one Sn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one Sn(1), and one Sn(2) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(7)LiVNiSn tetrahedra, corners with two equivalent O(8)LiVNiSn tetrahedra, and  a cornercorner with one O(10)LiV2Ni trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one V(2), one V(3), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share corners with two equivalent O(11)LiVNiSn tetrahedra, corners with two equivalent O(12)LiVNiSn tetrahedra, corners with two equivalent O(15)LiV2Ni trigonal pyramids, and  an edgeedge with one O(10)LiV2Ni trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Ni(1), and one Sn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Ni(1), and one Sn(1) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(8)LiVNiSn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid, and  an edgeedge with one O(8)LiVNiSn tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Ni(1), and one Sn(2) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(7)LiVNiSn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid, and  an edgeedge with one O(7)LiVNiSn tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ni(2), one Sn(1), and one Sn(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one V(2), one V(3), and one Ni(1) atom to form distorted OLiV2Ni trigonal pyramids that share  a cornercorner with one O(11)LiVNiSn tetrahedra,  a cornercorner with one O(12)LiVNiSn tetrahedra,  a cornercorner with one O(7)LiVNiSn tetrahedra,  a cornercorner with one O(8)LiVNiSn tetrahedra,  a cornercorner with one O(4)LiVSn2 tetrahedra, corners with two equivalent O(15)LiV2Ni trigonal pyramids, and  an edgeedge with one O(5)LiV2Sn tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one V(3), one Ni(2), and one Sn(3) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(12)LiVNiSn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid,  a cornercorner with one O(15)LiV2Ni trigonal pyramid,  an edgeedge with one O(12)LiVNiSn tetrahedra, and  an edgeedge with one O(15)LiV2Ni trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Ni(2), and one Sn(3) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(11)LiVNiSn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid,  a cornercorner with one O(15)LiV2Ni trigonal pyramid,  an edgeedge with one O(11)LiVNiSn tetrahedra, and  an edgeedge with one O(15)LiV2Ni trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Sn(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Ni(2), and one Sn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one V(3), and one Ni(2) atom to form distorted OLiV2Ni trigonal pyramids that share  a cornercorner with one O(11)LiVNiSn tetrahedra,  a cornercorner with one O(12)LiVNiSn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra, corners with two equivalent O(10)LiV2Ni trigonal pyramids,  an edgeedge with one O(11)LiVNiSn tetrahedra, and  an edgeedge with one O(12)LiVNiSn tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Ni(2), and one Sn(2) atom.
Li4V3Ni2Sn3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. The Li(1)-O(11) bond length is 2.00 Å. The Li(1)-O(12) bond length is 2.01 Å. The Li(1)-O(15) bond length is 2.08 Å. The Li(1)-O(3) bond length is 2.03 Å. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. The Li(2)-O(14) bond length is 1.96 Å. The Li(2)-O(16) bond length is 1.97 Å. The Li(2)-O(5) bond length is 1.78 Å. The Li(2)-O(9) bond length is 2.01 Å. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. The Li(3)-O(1) bond length is 2.00 Å. The Li(3)-O(10) bond length is 1.90 Å. The Li(3)-O(4) bond length is 1.78 Å. The Li(3)-O(6) bond length is 2.00 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, and corners with three equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. The Li(4)-O(13) bond length is 2.00 Å. The Li(4)-O(2) bond length is 1.98 Å. The Li(4)-O(7) bond length is 2.01 Å. The Li(4)-O(8) bond length is 2.04 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. The V(1)-O(14) bond length is 1.92 Å. The V(1)-O(16) bond length is 1.90 Å. The V(1)-O(3) bond length is 2.01 Å. The V(1)-O(4) bond length is 1.99 Å. The V(1)-O(7) bond length is 2.00 Å. The V(1)-O(8) bond length is 1.97 Å. In the second V site, V(2) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. The V(2)-O(10) bond length is 1.95 Å. The V(2)-O(12) bond length is 1.94 Å. The V(2)-O(13) bond length is 1.99 Å. The V(2)-O(15) bond length is 2.01 Å. The V(2)-O(5) bond length is 2.01 Å. The V(2)-O(6) bond length is 1.92 Å. In the third V site, V(3) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. The V(3)-O(1) bond length is 1.92 Å. The V(3)-O(10) bond length is 2.05 Å. The V(3)-O(11) bond length is 1.95 Å. The V(3)-O(13) bond length is 1.99 Å. The V(3)-O(15) bond length is 1.91 Å. The V(3)-O(5) bond length is 2.01 Å. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form NiO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. The Ni(1)-O(1) bond length is 2.13 Å. The Ni(1)-O(10) bond length is 2.24 Å. The Ni(1)-O(2) bond length is 2.13 Å. The Ni(1)-O(6) bond length is 2.14 Å. The Ni(1)-O(7) bond length is 2.10 Å. The Ni(1)-O(8) bond length is 2.12 Å. In the second Ni site, Ni(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form NiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. The Ni(2)-O(11) bond length is 2.11 Å. The Ni(2)-O(12) bond length is 2.10 Å. The Ni(2)-O(14) bond length is 2.14 Å. The Ni(2)-O(15) bond length is 2.14 Å. The Ni(2)-O(16) bond length is 2.16 Å. The Ni(2)-O(9) bond length is 2.14 Å. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. The Sn(1)-O(14) bond length is 2.14 Å. The Sn(1)-O(2) bond length is 2.07 Å. The Sn(1)-O(3) bond length is 2.09 Å. The Sn(1)-O(4) bond length is 2.07 Å. The Sn(1)-O(7) bond length is 2.08 Å. The Sn(1)-O(9) bond length is 2.07 Å. In the second Sn site, Sn(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. The Sn(2)-O(16) bond length is 2.15 Å. The Sn(2)-O(2) bond length is 2.06 Å. The Sn(2)-O(3) bond length is 2.08 Å. The Sn(2)-O(4) bond length is 2.07 Å. The Sn(2)-O(8) bond length is 2.09 Å. The Sn(2)-O(9) bond length is 2.07 Å. In the third Sn site, Sn(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SnO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. The Sn(3)-O(1) bond length is 2.12 Å. The Sn(3)-O(11) bond length is 2.07 Å. The Sn(3)-O(12) bond length is 2.09 Å. The Sn(3)-O(13) bond length is 2.10 Å. The Sn(3)-O(5) bond length is 2.06 Å. The Sn(3)-O(6) bond length is 2.12 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Ni(1), and one Sn(3) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Ni(1), one Sn(1), and one Sn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one Sn(1), and one Sn(2) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one Sn(1), and one Sn(2) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(7)LiVNiSn tetrahedra, corners with two equivalent O(8)LiVNiSn tetrahedra, and  a cornercorner with one O(10)LiV2Ni trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one V(2), one V(3), and one Sn(3) atom to form distorted OLiV2Sn tetrahedra that share corners with two equivalent O(11)LiVNiSn tetrahedra, corners with two equivalent O(12)LiVNiSn tetrahedra, corners with two equivalent O(15)LiV2Ni trigonal pyramids, and  an edgeedge with one O(10)LiV2Ni trigonal pyramid. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Ni(1), and one Sn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Ni(1), and one Sn(1) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(8)LiVNiSn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid, and  an edgeedge with one O(8)LiVNiSn tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Ni(1), and one Sn(2) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(7)LiVNiSn tetrahedra, corners with two equivalent O(4)LiVSn2 tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid, and  an edgeedge with one O(7)LiVNiSn tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ni(2), one Sn(1), and one Sn(2) atom. In the tenth O site, O(10) is bonded to one Li(3), one V(2), one V(3), and one Ni(1) atom to form distorted OLiV2Ni trigonal pyramids that share  a cornercorner with one O(11)LiVNiSn tetrahedra,  a cornercorner with one O(12)LiVNiSn tetrahedra,  a cornercorner with one O(7)LiVNiSn tetrahedra,  a cornercorner with one O(8)LiVNiSn tetrahedra,  a cornercorner with one O(4)LiVSn2 tetrahedra, corners with two equivalent O(15)LiV2Ni trigonal pyramids, and  an edgeedge with one O(5)LiV2Sn tetrahedra. In the eleventh O site, O(11) is bonded to one Li(1), one V(3), one Ni(2), and one Sn(3) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(12)LiVNiSn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid,  a cornercorner with one O(15)LiV2Ni trigonal pyramid,  an edgeedge with one O(12)LiVNiSn tetrahedra, and  an edgeedge with one O(15)LiV2Ni trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Ni(2), and one Sn(3) atom to form distorted OLiVNiSn tetrahedra that share  a cornercorner with one O(11)LiVNiSn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra,  a cornercorner with one O(10)LiV2Ni trigonal pyramid,  a cornercorner with one O(15)LiV2Ni trigonal pyramid,  an edgeedge with one O(11)LiVNiSn tetrahedra, and  an edgeedge with one O(15)LiV2Ni trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Sn(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Ni(2), and one Sn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one V(3), and one Ni(2) atom to form distorted OLiV2Ni trigonal pyramids that share  a cornercorner with one O(11)LiVNiSn tetrahedra,  a cornercorner with one O(12)LiVNiSn tetrahedra, corners with two equivalent O(5)LiV2Sn tetrahedra, corners with two equivalent O(10)LiV2Ni trigonal pyramids,  an edgeedge with one O(11)LiVNiSn tetrahedra, and  an edgeedge with one O(12)LiVNiSn tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Ni(2), and one Sn(2) atom.