K2TeBr6 crystallizes in the tetragonal P4/mnc space group. K(1) is bonded in a body-centered cubic geometry to four equivalent Br(1) and four equivalent Br(2) atoms. Te(1) is bonded in an octahedral geometry to two equivalent Br(2) and four equivalent Br(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded to four equivalent K(1) and one Te(1) atom to form a mixture of edge and corner-sharing BrK4Te square pyramids. In the second Br site, Br(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Te(1) atom.
K2TeBr6 crystallizes in the tetragonal P4/mnc space group. K(1) is bonded in a body-centered cubic geometry to four equivalent Br(1) and four equivalent Br(2) atoms. All K(1)-Br(1) bond lengths are 3.46 Å. All K(1)-Br(2) bond lengths are 3.73 Å. Te(1) is bonded in an octahedral geometry to two equivalent Br(2) and four equivalent Br(1) atoms. Both Te(1)-Br(2) bond lengths are 2.72 Å. All Te(1)-Br(1) bond lengths are 2.72 Å. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded to four equivalent K(1) and one Te(1) atom to form a mixture of edge and corner-sharing BrK4Te square pyramids. In the second Br site, Br(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Te(1) atom.