(In2As4O13)2N2(NO)2 crystallizes in the triclinic P-1 space group. The structure consists of two ammonia atoms and two nitroxyl molecules inside a In2As4O13 framework. In the In2As4O13 framework, there are two inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(14), one O(2), one O(5), and one O(6) atom to form InO5 trigonal bipyramids that share  a cornercorner with one As(4)O4 tetrahedra, corners with two equivalent As(1)O4 tetrahedra, and corners with two equivalent As(2)O4 tetrahedra. In the second In site, In(2) is bonded to one O(12), one O(13), one O(3), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra, and corners with two equivalent As(4)O4 tetrahedra. There are four inequivalent As sites. In the first As site, As(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form AsO4 tetrahedra that share  a cornercorner with one In(2)O6 octahedra,  a cornercorner with one As(2)O4 tetrahedra, and corners with two equivalent In(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 60°. In the second As site, As(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form AsO4 tetrahedra that share  a cornercorner with one In(2)O6 octahedra,  a cornercorner with one As(1)O4 tetrahedra, and corners with two equivalent In(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 46°. In the third As site, As(3) is bonded in a trigonal planar geometry to one O(11), one O(8), and one O(9) atom. In the fourth As site, As(4) is bonded to one O(11), one O(12), one O(13), and one O(14) atom to form AsO4 tetrahedra that share corners with two equivalent In(2)O6 octahedra and  a cornercorner with one In(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-54°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one In(1) and one As(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one In(1) and one As(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one In(2) and one As(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one As(1) and one As(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one As(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one In(1) and one As(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one In(2) and one As(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one In(2) and one As(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one In(2) and one As(3) atom. In the tenth O site, O(11) is bonded in a bent 120 degrees geometry to one As(3) and one As(4) atom. In the eleventh O site, O(12) is bonded in a distorted bent 150 degrees geometry to one In(2) and one As(4) atom. In the twelfth O site, O(13) is bonded in a bent 120 degrees geometry to one In(2) and one As(4) atom. In the thirteenth O site, O(14) is bonded in a bent 150 degrees geometry to one In(1) and one As(4) atom.
(In2As4O13)2N2(NO)2 crystallizes in the triclinic P-1 space group. The structure consists of two ammonia atoms and two nitroxyl molecules inside a In2As4O13 framework. In the In2As4O13 framework, there are two inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(14), one O(2), one O(5), and one O(6) atom to form InO5 trigonal bipyramids that share  a cornercorner with one As(4)O4 tetrahedra, corners with two equivalent As(1)O4 tetrahedra, and corners with two equivalent As(2)O4 tetrahedra. The In(1)-O(1) bond length is 2.13 Å. The In(1)-O(14) bond length is 2.16 Å. The In(1)-O(2) bond length is 2.10 Å. The In(1)-O(5) bond length is 2.12 Å. The In(1)-O(6) bond length is 2.13 Å. In the second In site, In(2) is bonded to one O(12), one O(13), one O(3), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one As(1)O4 tetrahedra,  a cornercorner with one As(2)O4 tetrahedra, and corners with two equivalent As(4)O4 tetrahedra. The In(2)-O(12) bond length is 2.15 Å. The In(2)-O(13) bond length is 2.16 Å. The In(2)-O(3) bond length is 2.15 Å. The In(2)-O(7) bond length is 2.13 Å. The In(2)-O(8) bond length is 2.26 Å. The In(2)-O(9) bond length is 2.32 Å. There are four inequivalent As sites. In the first As site, As(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form AsO4 tetrahedra that share  a cornercorner with one In(2)O6 octahedra,  a cornercorner with one As(2)O4 tetrahedra, and corners with two equivalent In(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 60°. The As(1)-O(1) bond length is 1.71 Å. The As(1)-O(2) bond length is 1.70 Å. The As(1)-O(3) bond length is 1.71 Å. The As(1)-O(4) bond length is 1.79 Å. In the second As site, As(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form AsO4 tetrahedra that share  a cornercorner with one In(2)O6 octahedra,  a cornercorner with one As(1)O4 tetrahedra, and corners with two equivalent In(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 46°. The As(2)-O(4) bond length is 1.80 Å. The As(2)-O(5) bond length is 1.70 Å. The As(2)-O(6) bond length is 1.70 Å. The As(2)-O(7) bond length is 1.71 Å. In the third As site, As(3) is bonded in a trigonal planar geometry to one O(11), one O(8), and one O(9) atom. The As(3)-O(11) bond length is 1.75 Å. The As(3)-O(8) bond length is 1.66 Å. The As(3)-O(9) bond length is 1.68 Å. In the fourth As site, As(4) is bonded to one O(11), one O(12), one O(13), and one O(14) atom to form AsO4 tetrahedra that share corners with two equivalent In(2)O6 octahedra and  a cornercorner with one In(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 45-54°. The As(4)-O(11) bond length is 1.85 Å. The As(4)-O(12) bond length is 1.69 Å. The As(4)-O(13) bond length is 1.70 Å. The As(4)-O(14) bond length is 1.69 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one In(1) and one As(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one In(1) and one As(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one In(2) and one As(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one As(1) and one As(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one As(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one In(1) and one As(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one In(2) and one As(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one In(2) and one As(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one In(2) and one As(3) atom. In the tenth O site, O(11) is bonded in a bent 120 degrees geometry to one As(3) and one As(4) atom. In the eleventh O site, O(12) is bonded in a distorted bent 150 degrees geometry to one In(2) and one As(4) atom. In the twelfth O site, O(13) is bonded in a bent 120 degrees geometry to one In(2) and one As(4) atom. In the thirteenth O site, O(14) is bonded in a bent 150 degrees geometry to one In(1) and one As(4) atom.