W(CO)6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four W(CO)6 clusters. W(1) is bonded in an octahedral geometry to one C(3), one C(4), two equivalent C(1), and two equivalent C(2) atoms. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(1) and one O(1,4) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one W(1) and one O(1,4) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one W(1) and one O(2) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(2) is bonded in a single-bond geometry to one C(4) atom.
W(CO)6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four W(CO)6 clusters. W(1) is bonded in an octahedral geometry to one C(3), one C(4), two equivalent C(1), and two equivalent C(2) atoms. The W(1)-C(3) bond length is 2.08 Å. The W(1)-C(4) bond length is 2.08 Å. Both W(1)-C(1) bond lengths are 2.09 Å. Both W(1)-C(2) bond lengths are 2.08 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(1) and one O(1,4) atom. The C(1)-O(1,4) bond length is 1.16 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one W(1) and one O(1,4) atom. The C(2)-O(1,4) bond length is 1.16 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one W(1) and one O(3) atom. The C(3)-O(3) bond length is 1.16 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one W(1) and one O(2) atom. The C(4)-O(2) bond length is 1.16 Å. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(2) is bonded in a single-bond geometry to one C(4) atom.