(BeF2)2Ni(NF5)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four beryllium fluoride molecules and two Ni(NF5)2 clusters. In each Ni(NF5)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(5), and two equivalent F(6) atoms. N(1) is bonded in a trigonal non-coplanar geometry to one F(1), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Ni(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one N(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Ni(1) atom.
(BeF2)2Ni(NF5)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four beryllium fluoride molecules and two Ni(NF5)2 clusters. In each Ni(NF5)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(5), and two equivalent F(6) atoms. Both Ni(1)-F(3) bond lengths are 1.76 Å. Both Ni(1)-F(5) bond lengths are 2.26 Å. Both Ni(1)-F(6) bond lengths are 1.76 Å. N(1) is bonded in a trigonal non-coplanar geometry to one F(1), one F(4), and one F(5) atom. The N(1)-F(1) bond length is 1.39 Å. The N(1)-F(4) bond length is 1.39 Å. The N(1)-F(5) bond length is 1.50 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Ni(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one N(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Ni(1) atom.