Be3Rh is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Be(1) is bonded in a 4-coordinate geometry to four equivalent Rh(1) atoms. Rh(1) is bonded to twelve equivalent Be(1) atoms to form a mixture of face and corner-sharing RhBe12 cuboctahedra.
Be3Rh is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Be(1) is bonded in a 4-coordinate geometry to four equivalent Rh(1) atoms. There are two shorter (2.36 Å) and two longer (2.41 Å) Be(1)-Rh(1) bond lengths. Rh(1) is bonded to twelve equivalent Be(1) atoms to form a mixture of face and corner-sharing RhBe12 cuboctahedra.