Mn2Pd3CuIn2 is Tungsten-derived structured and crystallizes in the trigonal R3m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to one Pd(1), one Pd(3), three equivalent Pd(2), and three equivalent Cu(1) atoms. In the second Mn site, Mn(2) is bonded in a body-centered cubic geometry to one Pd(2), three equivalent Pd(1), three equivalent Pd(3), and one Cu(1) atom. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a body-centered cubic geometry to one Mn(1), three equivalent Mn(2), one In(1), and three equivalent In(2) atoms. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to one Mn(2), three equivalent Mn(1), one In(1), and three equivalent In(2) atoms. In the third Pd site, Pd(3) is bonded in a distorted body-centered cubic geometry to one Mn(1), three equivalent Mn(2), one In(2), and three equivalent In(1) atoms. Cu(1) is bonded in a distorted body-centered cubic geometry to one Mn(2), three equivalent Mn(1), one In(2), and three equivalent In(1) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted body-centered cubic geometry to one Pd(1), one Pd(2), three equivalent Pd(3), and three equivalent Cu(1) atoms. In the second In site, In(2) is bonded in a distorted body-centered cubic geometry to one Pd(3), three equivalent Pd(1), three equivalent Pd(2), and one Cu(1) atom.
Mn2Pd3CuIn2 is Tungsten-derived structured and crystallizes in the trigonal R3m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to one Pd(1), one Pd(3), three equivalent Pd(2), and three equivalent Cu(1) atoms. The Mn(1)-Pd(1) bond length is 2.79 Å. The Mn(1)-Pd(3) bond length is 2.75 Å. All Mn(1)-Pd(2) bond lengths are 2.76 Å. All Mn(1)-Cu(1) bond lengths are 2.75 Å. In the second Mn site, Mn(2) is bonded in a body-centered cubic geometry to one Pd(2), three equivalent Pd(1), three equivalent Pd(3), and one Cu(1) atom. The Mn(2)-Pd(2) bond length is 2.79 Å. All Mn(2)-Pd(1) bond lengths are 2.76 Å. All Mn(2)-Pd(3) bond lengths are 2.75 Å. The Mn(2)-Cu(1) bond length is 2.76 Å. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a body-centered cubic geometry to one Mn(1), three equivalent Mn(2), one In(1), and three equivalent In(2) atoms. The Pd(1)-In(1) bond length is 2.79 Å. All Pd(1)-In(2) bond lengths are 2.76 Å. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to one Mn(2), three equivalent Mn(1), one In(1), and three equivalent In(2) atoms. The Pd(2)-In(1) bond length is 2.75 Å. All Pd(2)-In(2) bond lengths are 2.75 Å. In the third Pd site, Pd(3) is bonded in a distorted body-centered cubic geometry to one Mn(1), three equivalent Mn(2), one In(2), and three equivalent In(1) atoms. The Pd(3)-In(2) bond length is 2.79 Å. All Pd(3)-In(1) bond lengths are 2.76 Å. Cu(1) is bonded in a distorted body-centered cubic geometry to one Mn(2), three equivalent Mn(1), one In(2), and three equivalent In(1) atoms. The Cu(1)-In(2) bond length is 2.76 Å. All Cu(1)-In(1) bond lengths are 2.75 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted body-centered cubic geometry to one Pd(1), one Pd(2), three equivalent Pd(3), and three equivalent Cu(1) atoms. In the second In site, In(2) is bonded in a distorted body-centered cubic geometry to one Pd(3), three equivalent Pd(1), three equivalent Pd(2), and one Cu(1) atom.