MoRe3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Mo(1) is bonded to twelve equivalent Re(1) atoms to form MoRe12 cuboctahedra that share corners with six equivalent Mo(1)Re12 cuboctahedra, corners with twelve equivalent Re(1)Re8Mo4 cuboctahedra, edges with eighteen equivalent Re(1)Re8Mo4 cuboctahedra, faces with eight equivalent Mo(1)Re12 cuboctahedra, and faces with twelve equivalent Re(1)Re8Mo4 cuboctahedra. Re(1) is bonded to four equivalent Mo(1) and eight equivalent Re(1) atoms to form ReRe8Mo4 cuboctahedra that share corners with four equivalent Mo(1)Re12 cuboctahedra, corners with fourteen equivalent Re(1)Re8Mo4 cuboctahedra, edges with six equivalent Mo(1)Re12 cuboctahedra, edges with twelve equivalent Re(1)Re8Mo4 cuboctahedra, faces with four equivalent Mo(1)Re12 cuboctahedra, and faces with sixteen equivalent Re(1)Re8Mo4 cuboctahedra.
MoRe3 is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Mo(1) is bonded to twelve equivalent Re(1) atoms to form MoRe12 cuboctahedra that share corners with six equivalent Mo(1)Re12 cuboctahedra, corners with twelve equivalent Re(1)Re8Mo4 cuboctahedra, edges with eighteen equivalent Re(1)Re8Mo4 cuboctahedra, faces with eight equivalent Mo(1)Re12 cuboctahedra, and faces with twelve equivalent Re(1)Re8Mo4 cuboctahedra. All Mo(1)-Re(1) bond lengths are 2.79 Å. Re(1) is bonded to four equivalent Mo(1) and eight equivalent Re(1) atoms to form ReRe8Mo4 cuboctahedra that share corners with four equivalent Mo(1)Re12 cuboctahedra, corners with fourteen equivalent Re(1)Re8Mo4 cuboctahedra, edges with six equivalent Mo(1)Re12 cuboctahedra, edges with twelve equivalent Re(1)Re8Mo4 cuboctahedra, faces with four equivalent Mo(1)Re12 cuboctahedra, and faces with sixteen equivalent Re(1)Re8Mo4 cuboctahedra. There are a spread of Re(1)-Re(1) bond distances ranging from 2.78-2.81 Å.