Na2U2CoH8(C3O7)4 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(13), one O(2), one O(4), and one O(9) atom. U(1) is bonded in a distorted q6 geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. Co(1) is bonded in an octahedral geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(7) atoms. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(13) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(14) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Na(1), one U(1), and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(1) and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(5) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one U(1) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(6) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one U(1) and one C(6) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Na(1), one Co(1), one H(1), and one H(2) atom. In the fourteenth O site, O(14) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom.
Na2U2CoH8(C3O7)4 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(13), one O(2), one O(4), and one O(9) atom. The Na(1)-O(11) bond length is 2.40 Å. The Na(1)-O(13) bond length is 2.46 Å. The Na(1)-O(2) bond length is 2.40 Å. The Na(1)-O(4) bond length is 2.44 Å. The Na(1)-O(9) bond length is 2.36 Å. U(1) is bonded in a distorted q6 geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(9) atom. The U(1)-O(1) bond length is 2.53 Å. The U(1)-O(10) bond length is 2.49 Å. The U(1)-O(11) bond length is 2.45 Å. The U(1)-O(12) bond length is 2.51 Å. The U(1)-O(2) bond length is 2.55 Å. The U(1)-O(3) bond length is 2.54 Å. The U(1)-O(4) bond length is 2.54 Å. The U(1)-O(5) bond length is 2.41 Å. The U(1)-O(6) bond length is 2.36 Å. The U(1)-O(9) bond length is 2.45 Å. Co(1) is bonded in an octahedral geometry to two equivalent O(13), two equivalent O(14), and two equivalent O(7) atoms. Both Co(1)-O(13) bond lengths are 2.16 Å. Both Co(1)-O(14) bond lengths are 2.11 Å. Both Co(1)-O(7) bond lengths are 2.05 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(3) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. The C(3)-O(5) bond length is 1.30 Å. The C(3)-O(8) bond length is 1.24 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(4)-O(6) bond length is 1.28 Å. The C(4)-O(7) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(5)-O(10) bond length is 1.26 Å. The C(5)-O(9) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(6)-O(11) bond length is 1.28 Å. The C(6)-O(12) bond length is 1.26 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. The H(1)-O(13) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(13) atom. The H(2)-O(13) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(14) atom. The H(3)-O(14) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(14) atom. The H(4)-O(14) bond length is 0.98 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one U(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Na(1), one U(1), and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(1) and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(3) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(5) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one U(1) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one C(6) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one U(1) and one C(6) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one Na(1), one Co(1), one H(1), and one H(2) atom. In the fourteenth O site, O(14) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom.