Rb3Mn3P3O10F7 crystallizes in the monoclinic Cc space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(2), one O(6), one O(8), one O(9), one F(1), one F(2), one F(3), and one F(5) atom. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(10), one O(2), one O(3), one O(5), one O(7), one O(8), one F(1), one F(4), one F(5), and one F(6) atom. In the third Rb site, Rb(3) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(5), one O(6), one O(7), one O(9), one F(1), one F(5), and one F(7) atom. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(5), one O(6), one F(1), one F(2), and one F(7) atom to form MnO3F3 octahedra that share  a cornercorner with one Mn(3)O3F3 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(2)O3F tetrahedra,  a cornercorner with one P(3)O3F tetrahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the second Mn site, Mn(2) is bonded to one O(10), one O(3), one O(4), one O(9), one F(2), and one F(4) atom to form MnO4F2 octahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra,  a cornercorner with one P(2)O3F tetrahedra,  a cornercorner with one P(3)O3F tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-44°. In the third Mn site, Mn(3) is bonded to one O(1), one O(7), one O(8), one F(4), one F(5), and one F(7) atom to form MnO3F3 octahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(2)O3F tetrahedra,  a cornercorner with one P(3)O3F tetrahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-44°. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra, and corners with two equivalent Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 26-51°. In the second P site, P(2) is bonded to one O(10), one O(6), one O(7), and one F(6) atom to form PO3F tetrahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra, and  a cornercorner with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 33-35°. In the third P site, P(3) is bonded to one O(5), one O(8), one O(9), and one F(3) atom to form PO3F tetrahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra, and  a cornercorner with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 33-35°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Rb(3), one Mn(3), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Rb(2), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one Rb(3), one Mn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Rb(2), one Rb(3), one Mn(1), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(3), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Rb(2), one Rb(3), one Mn(3), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mn(3), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(3), one Mn(2), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mn(2), and one P(2) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Mn(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Rb(1), one Mn(1), and one Mn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(1) and one P(3) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Rb(2), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Mn(3) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one Rb(2) and one P(2) atom. In the seventh F site, F(7) is bonded in a 3-coordinate geometry to one Rb(3), one Mn(1), and one Mn(3) atom.
Rb3Mn3P3O10F7 crystallizes in the monoclinic Cc space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(2), one O(6), one O(8), one O(9), one F(1), one F(2), one F(3), and one F(5) atom. The Rb(1)-O(1) bond length is 3.13 Å. The Rb(1)-O(10) bond length is 3.07 Å. The Rb(1)-O(2) bond length is 3.22 Å. The Rb(1)-O(6) bond length is 3.17 Å. The Rb(1)-O(8) bond length is 3.01 Å. The Rb(1)-O(9) bond length is 3.21 Å. The Rb(1)-F(1) bond length is 2.99 Å. The Rb(1)-F(2) bond length is 3.05 Å. The Rb(1)-F(3) bond length is 2.90 Å. The Rb(1)-F(5) bond length is 3.18 Å. In the second Rb site, Rb(2) is bonded in a 10-coordinate geometry to one O(10), one O(2), one O(3), one O(5), one O(7), one O(8), one F(1), one F(4), one F(5), and one F(6) atom. The Rb(2)-O(10) bond length is 3.11 Å. The Rb(2)-O(2) bond length is 3.20 Å. The Rb(2)-O(3) bond length is 3.21 Å. The Rb(2)-O(5) bond length is 3.11 Å. The Rb(2)-O(7) bond length is 3.02 Å. The Rb(2)-O(8) bond length is 3.25 Å. The Rb(2)-F(1) bond length is 3.11 Å. The Rb(2)-F(4) bond length is 2.99 Å. The Rb(2)-F(5) bond length is 3.06 Å. The Rb(2)-F(6) bond length is 2.91 Å. In the third Rb site, Rb(3) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(5), one O(6), one O(7), one O(9), one F(1), one F(5), and one F(7) atom. The Rb(3)-O(1) bond length is 3.19 Å. The Rb(3)-O(3) bond length is 3.22 Å. The Rb(3)-O(5) bond length is 3.13 Å. The Rb(3)-O(6) bond length is 2.97 Å. The Rb(3)-O(7) bond length is 3.07 Å. The Rb(3)-O(9) bond length is 3.04 Å. The Rb(3)-F(1) bond length is 3.05 Å. The Rb(3)-F(5) bond length is 3.01 Å. The Rb(3)-F(7) bond length is 2.79 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(5), one O(6), one F(1), one F(2), and one F(7) atom to form MnO3F3 octahedra that share  a cornercorner with one Mn(3)O3F3 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(2)O3F tetrahedra,  a cornercorner with one P(3)O3F tetrahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-43°. The Mn(1)-O(2) bond length is 1.94 Å. The Mn(1)-O(5) bond length is 2.06 Å. The Mn(1)-O(6) bond length is 2.08 Å. The Mn(1)-F(1) bond length is 1.86 Å. The Mn(1)-F(2) bond length is 2.17 Å. The Mn(1)-F(7) bond length is 1.98 Å. In the second Mn site, Mn(2) is bonded to one O(10), one O(3), one O(4), one O(9), one F(2), and one F(4) atom to form MnO4F2 octahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra,  a cornercorner with one P(2)O3F tetrahedra,  a cornercorner with one P(3)O3F tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-44°. The Mn(2)-O(10) bond length is 2.12 Å. The Mn(2)-O(3) bond length is 1.96 Å. The Mn(2)-O(4) bond length is 1.95 Å. The Mn(2)-O(9) bond length is 2.03 Å. The Mn(2)-F(2) bond length is 1.95 Å. The Mn(2)-F(4) bond length is 2.15 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(7), one O(8), one F(4), one F(5), and one F(7) atom to form MnO3F3 octahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(2)O3F tetrahedra,  a cornercorner with one P(3)O3F tetrahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-44°. The Mn(3)-O(1) bond length is 1.94 Å. The Mn(3)-O(7) bond length is 2.10 Å. The Mn(3)-O(8) bond length is 2.05 Å. The Mn(3)-F(4) bond length is 1.98 Å. The Mn(3)-F(5) bond length is 1.86 Å. The Mn(3)-F(7) bond length is 2.14 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra, and corners with two equivalent Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 26-51°. The P(1)-O(1) bond length is 1.56 Å. The P(1)-O(2) bond length is 1.56 Å. The P(1)-O(3) bond length is 1.56 Å. The P(1)-O(4) bond length is 1.53 Å. In the second P site, P(2) is bonded to one O(10), one O(6), one O(7), and one F(6) atom to form PO3F tetrahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra, and  a cornercorner with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 33-35°. The P(2)-O(10) bond length is 1.52 Å. The P(2)-O(6) bond length is 1.52 Å. The P(2)-O(7) bond length is 1.52 Å. The P(2)-F(6) bond length is 1.61 Å. In the third P site, P(3) is bonded to one O(5), one O(8), one O(9), and one F(3) atom to form PO3F tetrahedra that share  a cornercorner with one Mn(1)O3F3 octahedra,  a cornercorner with one Mn(3)O3F3 octahedra, and  a cornercorner with one Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 33-35°. The P(3)-O(5) bond length is 1.53 Å. The P(3)-O(8) bond length is 1.52 Å. The P(3)-O(9) bond length is 1.53 Å. The P(3)-F(3) bond length is 1.59 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Rb(3), one Mn(3), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Rb(2), one Mn(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one Rb(3), one Mn(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Rb(2), one Rb(3), one Mn(1), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(3), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Rb(2), one Rb(3), one Mn(3), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mn(3), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(3), one Mn(2), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mn(2), and one P(2) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Mn(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Rb(1), one Mn(1), and one Mn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(1) and one P(3) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Rb(2), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Mn(3) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one Rb(2) and one P(2) atom. In the seventh F site, F(7) is bonded in a 3-coordinate geometry to one Rb(3), one Mn(1), and one Mn(3) atom.