(Na)2NaGaCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaGaCl6 framework. In the NaGaCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Ga(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Ga(1) is bonded to six equivalent Cl(1) atoms to form GaCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Na(2) and one Ga(1) atom.
(Na)2NaGaCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaGaCl6 framework. In the NaGaCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Ga(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-Cl(1) bond lengths are 2.69 Å. Ga(1) is bonded to six equivalent Cl(1) atoms to form GaCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Ga(1)-Cl(1) bond lengths are 2.38 Å. Cl(1) is bonded in a linear geometry to one Na(2) and one Ga(1) atom.