NH3Te(OF)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NH3Te(OF)2 clusters. N(1) is bonded in a bent 120 degrees geometry to one H(1) and one H(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. Te(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one H(1) and one Te(1) atom.
NH3Te(OF)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NH3Te(OF)2 clusters. N(1) is bonded in a bent 120 degrees geometry to one H(1) and one H(2) atom. The N(1)-H(1) bond length is 1.06 Å. The N(1)-H(2) bond length is 1.06 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(1) atom. The H(1)-F(1) bond length is 1.57 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. The H(3)-O(1) bond length is 1.63 Å. The H(3)-O(2) bond length is 1.02 Å. Te(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. The Te(1)-O(1) bond length is 1.90 Å. The Te(1)-O(2) bond length is 1.94 Å. The Te(1)-F(1) bond length is 2.11 Å. The Te(1)-F(2) bond length is 2.00 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one H(1) and one Te(1) atom.