IrN5Cl2AuCl4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four IrN5Cl2 clusters. In two of the AuCl4 clusters, Au(1) is bonded in a square co-planar geometry to two equivalent Cl(2) and two equivalent Cl(5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In two of the AuCl4 clusters, Au(2) is bonded in a square co-planar geometry to four equivalent Cl(1,4) atoms. Cl(1,4) is bonded in a single-bond geometry to one Au(2) atom. In each IrN5Cl2 cluster, Ir(1) is bonded in a distorted octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(6) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one N(2) atom.
IrN5Cl2AuCl4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four IrN5Cl2 clusters. In two of the AuCl4 clusters, Au(1) is bonded in a square co-planar geometry to two equivalent Cl(2) and two equivalent Cl(5) atoms. Both Au(1)-Cl(2) bond lengths are 2.32 Å. Both Au(1)-Cl(5) bond lengths are 2.31 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In two of the AuCl4 clusters, Au(2) is bonded in a square co-planar geometry to four equivalent Cl(1,4) atoms. All Au(2)-Cl(1,4) bond lengths are 2.31 Å. Cl(1,4) is bonded in a single-bond geometry to one Au(2) atom. In each IrN5Cl2 cluster, Ir(1) is bonded in a distorted octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(3) atom. The Ir(1)-N(2) bond length is 2.26 Å. Both Ir(1)-N(1) bond lengths are 1.75 Å. Both Ir(1)-N(3) bond lengths are 2.12 Å. The Ir(1)-Cl(3) bond length is 2.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(6) atom. The N(2)-Cl(6) bond length is 1.60 Å. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one N(2) atom.