V6O7F5 is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), two equivalent O(2), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with four equivalent V(4)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra,  an edgeedge with one V(2)O2F4 octahedra, and  an edgeedge with one V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-51°. In the second V site, V(2) is bonded to two equivalent O(3), two equivalent F(1), and two equivalent F(3) atoms to form VO2F4 octahedra that share corners with eight equivalent V(4)O4F2 octahedra and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the third V site, V(3) is bonded to one O(1), four equivalent O(2), and one F(2) atom to form VO5F octahedra that share corners with eight equivalent V(1)O3F3 octahedra and edges with two equivalent V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-49°. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(3), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with four equivalent V(2)O2F4 octahedra, corners with four equivalent V(1)O3F3 octahedra,  an edgeedge with one V(4)O4F2 octahedra, and  an edgeedge with one V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-51°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom.
V6O7F5 is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), two equivalent O(2), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with four equivalent V(4)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra,  an edgeedge with one V(2)O2F4 octahedra, and  an edgeedge with one V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-51°. The V(1)-O(1) bond length is 1.96 Å. Both V(1)-O(2) bond lengths are 1.96 Å. The V(1)-F(1) bond length is 2.07 Å. The V(1)-F(2) bond length is 2.06 Å. The V(1)-F(3) bond length is 2.12 Å. In the second V site, V(2) is bonded to two equivalent O(3), two equivalent F(1), and two equivalent F(3) atoms to form VO2F4 octahedra that share corners with eight equivalent V(4)O4F2 octahedra and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-50°. Both V(2)-O(3) bond lengths are 1.94 Å. Both V(2)-F(1) bond lengths are 2.06 Å. Both V(2)-F(3) bond lengths are 2.06 Å. In the third V site, V(3) is bonded to one O(1), four equivalent O(2), and one F(2) atom to form VO5F octahedra that share corners with eight equivalent V(1)O3F3 octahedra and edges with two equivalent V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-49°. The V(3)-O(1) bond length is 1.89 Å. All V(3)-O(2) bond lengths are 1.96 Å. The V(3)-F(2) bond length is 2.32 Å. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(3), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with four equivalent V(2)O2F4 octahedra, corners with four equivalent V(1)O3F3 octahedra,  an edgeedge with one V(4)O4F2 octahedra, and  an edgeedge with one V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-51°. Both V(4)-O(2) bond lengths are 2.02 Å. Both V(4)-O(3) bond lengths are 2.01 Å. The V(4)-F(1) bond length is 2.12 Å. The V(4)-F(3) bond length is 2.11 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(1) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom.