ScTiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Sc(1) is bonded to six equivalent O(1) atoms to form distorted ScO6 octahedra that share corners with nine equivalent Ti(1)O6 octahedra, edges with three equivalent Sc(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with nine equivalent Sc(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Sc(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. O(1) is bonded to two equivalent Sc(1) and two equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing OSc2Ti2 trigonal pyramids.
ScTiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Sc(1) is bonded to six equivalent O(1) atoms to form distorted ScO6 octahedra that share corners with nine equivalent Ti(1)O6 octahedra, edges with three equivalent Sc(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. There are three shorter (2.07 Å) and three longer (2.21 Å) Sc(1)-O(1) bond lengths. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with nine equivalent Sc(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Sc(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. There are three shorter (2.03 Å) and three longer (2.11 Å) Ti(1)-O(1) bond lengths. O(1) is bonded to two equivalent Sc(1) and two equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing OSc2Ti2 trigonal pyramids.