NaNdWMnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Nd(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. Nd(1) is bonded to twelve equivalent O(1) atoms to form NdO12 cuboctahedra that share corners with twelve equivalent Nd(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, faces with four equivalent Na(1)O12 cuboctahedra, and faces with four equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent Na(1)O12 cuboctahedra, and faces with four equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent Na(1), two equivalent Nd(1), one W(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing ONa2Nd2MnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
NaNdWMnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Nd(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. All Na(1)-O(1) bond lengths are 2.85 Å. Nd(1) is bonded to twelve equivalent O(1) atoms to form NdO12 cuboctahedra that share corners with twelve equivalent Nd(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Mn(1)O6 octahedra. All Nd(1)-O(1) bond lengths are 2.85 Å. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, faces with four equivalent Na(1)O12 cuboctahedra, and faces with four equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All W(1)-O(1) bond lengths are 1.93 Å. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent Na(1)O12 cuboctahedra, and faces with four equivalent Nd(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Mn(1)-O(1) bond lengths are 2.09 Å. O(1) is bonded to two equivalent Na(1), two equivalent Nd(1), one W(1), and one Mn(1) atom to form a mixture of distorted corner, edge, and face-sharing ONa2Nd2MnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°.