Ti(SnN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 3-coordinate geometry to one N(1) and two equivalent N(2) atoms. In the second Sn site, Sn(2) is bonded in a distorted T-shaped geometry to one N(2) and two equivalent N(3) atoms. In the third Sn site, Sn(3) is bonded in a distorted T-shaped geometry to one N(4) and two equivalent N(1) atoms. In the fourth Sn site, Sn(4) is bonded in a 3-coordinate geometry to one N(3) and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Ti(1), one Sn(1), and two equivalent Sn(3) atoms. In the second N site, N(2) is bonded in a distorted see-saw-like geometry to one Ti(1), one Sn(2), and two equivalent Sn(1) atoms. In the third N site, N(3) is bonded in a 4-coordinate geometry to one Ti(1), one Sn(4), and two equivalent Sn(2) atoms. In the fourth N site, N(4) is bonded in a distorted see-saw-like geometry to one Ti(1), one Sn(3), and two equivalent Sn(4) atoms.
Ti(SnN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ti(1)-N(1) bond length is 1.96 Å. The Ti(1)-N(2) bond length is 1.94 Å. The Ti(1)-N(3) bond length is 1.95 Å. The Ti(1)-N(4) bond length is 1.94 Å. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 3-coordinate geometry to one N(1) and two equivalent N(2) atoms. The Sn(1)-N(1) bond length is 2.36 Å. There is one shorter (2.28 Å) and one longer (2.33 Å) Sn(1)-N(2) bond length. In the second Sn site, Sn(2) is bonded in a distorted T-shaped geometry to one N(2) and two equivalent N(3) atoms. The Sn(2)-N(2) bond length is 2.24 Å. There is one shorter (2.26 Å) and one longer (2.40 Å) Sn(2)-N(3) bond length. In the third Sn site, Sn(3) is bonded in a distorted T-shaped geometry to one N(4) and two equivalent N(1) atoms. The Sn(3)-N(4) bond length is 2.24 Å. There is one shorter (2.26 Å) and one longer (2.40 Å) Sn(3)-N(1) bond length. In the fourth Sn site, Sn(4) is bonded in a 3-coordinate geometry to one N(3) and two equivalent N(4) atoms. The Sn(4)-N(3) bond length is 2.36 Å. There is one shorter (2.28 Å) and one longer (2.33 Å) Sn(4)-N(4) bond length. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Ti(1), one Sn(1), and two equivalent Sn(3) atoms. In the second N site, N(2) is bonded in a distorted see-saw-like geometry to one Ti(1), one Sn(2), and two equivalent Sn(1) atoms. In the third N site, N(3) is bonded in a 4-coordinate geometry to one Ti(1), one Sn(4), and two equivalent Sn(2) atoms. In the fourth N site, N(4) is bonded in a distorted see-saw-like geometry to one Ti(1), one Sn(3), and two equivalent Sn(4) atoms.