Mn(NO4)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and two Mn(NO4)2 clusters. In each Mn(NO4)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(4) and one O(5) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a 2-coordinate geometry to one Mn(1) and one O(6) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Mn(1) and one O(7) atom.
Mn(NO4)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and two Mn(NO4)2 clusters. In each Mn(NO4)2 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. Both Mn(1)-O(5) bond lengths are 2.20 Å. Both Mn(1)-O(6) bond lengths are 2.01 Å. Both Mn(1)-O(7) bond lengths are 1.99 Å. N(1) is bonded in a bent 120 degrees geometry to one O(4) and one O(5) atom. The N(1)-O(4) bond length is 1.22 Å. The N(1)-O(5) bond length is 1.26 Å. There are four inequivalent O sites. In the first O site, O(7) is bonded in a 2-coordinate geometry to one Mn(1) and one O(6) atom. The O(7)-O(6) bond length is 1.33 Å. In the second O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Mn(1) and one O(7) atom.