PrVSb3 crystallizes in the orthorhombic Pbcm space group. Pr(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent Sb(1), two equivalent Sb(2), and two equivalent Sb(3) atoms. V(1) is bonded in a distorted T-shaped geometry to two equivalent Pr(1), one Sb(1), and two equivalent Sb(3) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one V(1) atom. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to two equivalent Pr(1) atoms. In the third Sb site, Sb(3) is bonded in a 4-coordinate geometry to two equivalent Pr(1) and two equivalent V(1) atoms.
PrVSb3 crystallizes in the orthorhombic Pbcm space group. Pr(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent Sb(1), two equivalent Sb(2), and two equivalent Sb(3) atoms. Both Pr(1)-V(1) bond lengths are 3.71 Å. Both Pr(1)-Sb(1) bond lengths are 3.18 Å. There is one shorter (3.25 Å) and one longer (3.36 Å) Pr(1)-Sb(2) bond length. There is one shorter (3.15 Å) and one longer (3.20 Å) Pr(1)-Sb(3) bond length. V(1) is bonded in a distorted T-shaped geometry to two equivalent Pr(1), one Sb(1), and two equivalent Sb(3) atoms. The V(1)-Sb(1) bond length is 2.67 Å. Both V(1)-Sb(3) bond lengths are 2.70 Å. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one V(1) atom. In the second Sb site, Sb(2) is bonded in a 2-coordinate geometry to two equivalent Pr(1) atoms. In the third Sb site, Sb(3) is bonded in a 4-coordinate geometry to two equivalent Pr(1) and two equivalent V(1) atoms.