V2O5 crystallizes in the orthorhombic Fdd2 space group. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing VO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third O site, O(2) is bonded in a single-bond geometry to one V(1) atom.
V2O5 crystallizes in the orthorhombic Fdd2 space group. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing VO4 tetrahedra. The V(1)-O(1) bond length is 1.78 Å. The V(1)-O(2) bond length is 1.60 Å. There is one shorter (1.76 Å) and one longer (1.77 Å) V(1)-O(3) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third O site, O(2) is bonded in a single-bond geometry to one V(1) atom.