(RhC3(NCl)3)2(N2)3 is Cyanogen Chloride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four ammonia atoms, and four RhC3(NCl)3 clusters. In each RhC3(NCl)3 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(5), one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one C(3) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. There are three inequivalent N sites. In the first N site, N(5) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(1) is bonded in a linear geometry to one Rh(1) and one C(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Rh(1) atom.
(RhC3(NCl)3)2(N2)3 is Cyanogen Chloride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four ammonia atoms, and four RhC3(NCl)3 clusters. In each RhC3(NCl)3 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(5), one Cl(1), one Cl(2), and one Cl(3) atom. The Rh(1)-N(1) bond length is 2.39 Å. The Rh(1)-N(5) bond length is 1.64 Å. The Rh(1)-Cl(1) bond length is 2.30 Å. The Rh(1)-Cl(2) bond length is 2.29 Å. The Rh(1)-Cl(3) bond length is 2.33 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. The C(1)-C(2) bond length is 1.32 Å. The C(1)-N(1) bond length is 1.19 Å. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one C(3) atom. The C(2)-C(3) bond length is 1.32 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. The C(3)-N(2) bond length is 1.20 Å. There are three inequivalent N sites. In the first N site, N(5) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(1) is bonded in a linear geometry to one Rh(1) and one C(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Rh(1) atom.