MoReN3 crystallizes in the triclinic P-1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted see-saw-like geometry to one N(2), one N(3), and two equivalent N(1) atoms. In the second Mo site, Mo(2) is bonded to one N(1), one N(2), one N(3), one N(5), and one N(6) atom to form distorted MoN5 trigonal bipyramids that share  a cornercorner with one Re(1)N4 tetrahedra and  an edgeedge with one Re(1)N4 tetrahedra. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one N(4), one N(5), and two equivalent N(6) atoms to form distorted ReN4 tetrahedra that share  a cornercorner with one Mo(2)N5 trigonal bipyramid,  an edgeedge with one Re(1)N4 tetrahedra, and  an edgeedge with one Mo(2)N5 trigonal bipyramid. In the second Re site, Re(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(3), and one N(4) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded to one Mo(2), two equivalent Mo(1), and one Re(2) atom to form distorted edge-sharing NReMo3 trigonal pyramids. In the second N site, N(2) is bonded in an L-shaped geometry to one Mo(1) and one Mo(2) atom. In the third N site, N(3) is bonded in a T-shaped geometry to one Mo(1), one Mo(2), and one Re(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom. In the fifth N site, N(5) is bonded in an L-shaped geometry to one Mo(2) and one Re(1) atom. In the sixth N site, N(6) is bonded in a T-shaped geometry to one Mo(2) and two equivalent Re(1) atoms.
MoReN3 crystallizes in the triclinic P-1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted see-saw-like geometry to one N(2), one N(3), and two equivalent N(1) atoms. The Mo(1)-N(2) bond length is 1.80 Å. The Mo(1)-N(3) bond length is 2.07 Å. There is one shorter (2.09 Å) and one longer (2.12 Å) Mo(1)-N(1) bond length. In the second Mo site, Mo(2) is bonded to one N(1), one N(2), one N(3), one N(5), and one N(6) atom to form distorted MoN5 trigonal bipyramids that share  a cornercorner with one Re(1)N4 tetrahedra and  an edgeedge with one Re(1)N4 tetrahedra. The Mo(2)-N(1) bond length is 2.01 Å. The Mo(2)-N(2) bond length is 1.96 Å. The Mo(2)-N(3) bond length is 1.97 Å. The Mo(2)-N(5) bond length is 2.32 Å. The Mo(2)-N(6) bond length is 2.01 Å. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one N(4), one N(5), and two equivalent N(6) atoms to form distorted ReN4 tetrahedra that share  a cornercorner with one Mo(2)N5 trigonal bipyramid,  an edgeedge with one Re(1)N4 tetrahedra, and  an edgeedge with one Mo(2)N5 trigonal bipyramid. The Re(1)-N(4) bond length is 1.89 Å. The Re(1)-N(5) bond length is 1.74 Å. There is one shorter (1.98 Å) and one longer (1.99 Å) Re(1)-N(6) bond length. In the second Re site, Re(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(3), and one N(4) atom. The Re(2)-N(1) bond length is 2.01 Å. The Re(2)-N(3) bond length is 1.93 Å. The Re(2)-N(4) bond length is 1.81 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded to one Mo(2), two equivalent Mo(1), and one Re(2) atom to form distorted edge-sharing NReMo3 trigonal pyramids. In the second N site, N(2) is bonded in an L-shaped geometry to one Mo(1) and one Mo(2) atom. In the third N site, N(3) is bonded in a T-shaped geometry to one Mo(1), one Mo(2), and one Re(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom. In the fifth N site, N(5) is bonded in an L-shaped geometry to one Mo(2) and one Re(1) atom. In the sixth N site, N(6) is bonded in a T-shaped geometry to one Mo(2) and two equivalent Re(1) atoms.