CaSb2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ca(1) is bonded to four equivalent O(1) atoms to form CaO4 tetrahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ca(1)O4 tetrahedra and edges with six equivalent Sb(1)O6 octahedra. O(1) is bonded to one Ca(1) and three equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing OCaSb3 trigonal pyramids.
CaSb2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ca(1) is bonded to four equivalent O(1) atoms to form CaO4 tetrahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Ca(1)-O(1) bond lengths are 2.29 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Ca(1)O4 tetrahedra and edges with six equivalent Sb(1)O6 octahedra. All Sb(1)-O(1) bond lengths are 2.37 Å. O(1) is bonded to one Ca(1) and three equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing OCaSb3 trigonal pyramids.