LaBO3 crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. B(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent La(1) and one B(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent La(1) and one B(1) atom.
LaBO3 crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. There is one shorter (2.44 Å) and two longer (2.73 Å) La(1)-O(1) bond lengths. There are a spread of La(1)-O(2) bond distances ranging from 2.49-2.63 Å. B(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. The B(1)-O(1) bond length is 1.37 Å. Both B(1)-O(2) bond lengths are 1.38 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent La(1) and one B(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent La(1) and one B(1) atom.