CdC2H8S2(NO)6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC2H8S2(NO)6 clusters. Cd(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(2) atoms. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cd(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom.
CdC2H8S2(NO)6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC2H8S2(NO)6 clusters. Cd(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(2) atoms. Both Cd(1)-S(1) bond lengths are 2.54 Å. Both Cd(1)-O(2) bond lengths are 2.48 Å. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.75 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(3)-O(1) bond length is 1.26 Å. The N(3)-O(2) bond length is 1.28 Å. The N(3)-O(3) bond length is 1.26 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.02 Å. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.02 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cd(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom.