VF2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. V(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 51°. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms.
VF2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. V(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two shorter (2.07 Å) and four longer (2.09 Å) V(1)-F(1) bond lengths. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms.