N2S3SO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S3 clusters and four SO3F clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In each SO3F cluster, S(4) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(4) atom. F(1) is bonded in a single-bond geometry to one S(4) atom.
N2S3SO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S3 clusters and four SO3F clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(1)-S(2) bond length is 1.58 Å. The N(1)-S(3) bond length is 1.60 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.60 Å. The N(2)-S(2) bond length is 1.58 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In each SO3F cluster, S(4) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. The S(4)-O(1) bond length is 1.45 Å. The S(4)-O(2) bond length is 1.45 Å. The S(4)-O(3) bond length is 1.47 Å. The S(4)-F(1) bond length is 1.64 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(4) atom. F(1) is bonded in a single-bond geometry to one S(4) atom.