VO2 is trigonal omega-like structured and crystallizes in the tetragonal I4_1/a space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms.
VO2 is trigonal omega-like structured and crystallizes in the tetragonal I4_1/a space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. There are a spread of V(1)-O(1) bond distances ranging from 1.94-1.99 Å. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms.