P2V crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent P(1) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms.
P2V crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent P(1) and five equivalent P(2) atoms. There are two shorter (2.42 Å) and one longer (2.44 Å) V(1)-P(1) bond length. There are two shorter (2.47 Å) and three longer (2.48 Å) V(1)-P(2) bond lengths. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent P(1) atoms. There is one shorter (2.21 Å) and two longer (2.58 Å) P(1)-P(1) bond lengths. In the second P site, P(2) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms.