WSBr4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four WSBr4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Br(1), one Br(2), one Br(3), and one Br(4) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one W(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one W(1) atom.
WSBr4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four WSBr4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Br(1), one Br(2), one Br(3), and one Br(4) atom. The W(1)-S(1) bond length is 2.08 Å. The W(1)-Br(1) bond length is 2.45 Å. The W(1)-Br(2) bond length is 2.46 Å. The W(1)-Br(3) bond length is 2.48 Å. The W(1)-Br(4) bond length is 2.46 Å. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one W(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one W(1) atom.