CCl2F2 is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two dichlorodifluoromethane molecules. C(1) is bonded in a distorted tetrahedral geometry to one Cl(1), one Cl(2), one F(1), and one F(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.
CCl2F2 is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two dichlorodifluoromethane molecules. C(1) is bonded in a distorted tetrahedral geometry to one Cl(1), one Cl(2), one F(1), and one F(2) atom. The C(1)-Cl(1) bond length is 1.73 Å. The C(1)-Cl(2) bond length is 1.79 Å. The C(1)-F(1) bond length is 1.38 Å. The C(1)-F(2) bond length is 1.38 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.