K2PbO6 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. Pb(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pb(1), and one O(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pb(1), and one O(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Pb(1) atom.
K2PbO6 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(1), two equivalent O(2), and three equivalent O(3) atoms. There is one shorter (2.80 Å) and one longer (2.87 Å) K(1)-O(1) bond length. There is one shorter (2.80 Å) and one longer (3.24 Å) K(1)-O(2) bond length. There are a spread of K(1)-O(3) bond distances ranging from 2.70-3.00 Å. Pb(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Pb(1)-O(1) bond lengths are 2.57 Å. Both Pb(1)-O(2) bond lengths are 2.44 Å. Both Pb(1)-O(3) bond lengths are 2.00 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pb(1), and one O(1) atom. The O(1)-O(1) bond length is 1.35 Å. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Pb(1), and one O(2) atom. The O(2)-O(2) bond length is 1.35 Å. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Pb(1) atom.