SiBr3 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four tribromosilane molecules. Si(1) is bonded in a distorted trigonal non-coplanar geometry to one Br(1) and two equivalent Br(2) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Si(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Si(1) atom.
SiBr3 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four tribromosilane molecules. Si(1) is bonded in a distorted trigonal non-coplanar geometry to one Br(1) and two equivalent Br(2) atoms. The Si(1)-Br(1) bond length is 2.21 Å. Both Si(1)-Br(2) bond lengths are 2.20 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Si(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Si(1) atom.