XeO3 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four XeO3 clusters. Xe(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Xe(1) atom.
XeO3 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four XeO3 clusters. Xe(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. The Xe(1)-O(1) bond length is 1.88 Å. The Xe(1)-O(2) bond length is 1.92 Å. The Xe(1)-O(3) bond length is 1.90 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Xe(1) atom.