LiLa5Ti8O24 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(20), one O(5), and one O(7) atom. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(10), one O(12), one O(19), one O(2), one O(20), one O(22), one O(3), one O(4), one O(7), one O(9), and two equivalent O(1) atoms to form distorted LaO12 cuboctahedra that share corners with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra,  a faceface with one Ti(5)O6 octahedra,  a faceface with one Ti(6)O6 octahedra,  a faceface with one Ti(7)O6 octahedra,  a faceface with one Ti(8)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(10), one O(11), one O(12), one O(15), one O(17), one O(2), one O(21), one O(3), one O(8), and two equivalent O(4) atoms to form distorted LaO12 cuboctahedra that share corners with two equivalent La(2)O12 cuboctahedra, corners with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Ti(4)O6 octahedra, faces with two equivalent Ti(5)O6 octahedra, and faces with two equivalent Ti(7)O6 octahedra. In the third La site, La(3) is bonded in a 12-coordinate geometry to one O(11), one O(16), one O(17), one O(18), one O(21), one O(22), one O(23), one O(24), one O(4), one O(8), and two equivalent O(15) atoms. In the fourth La site, La(4) is bonded to one O(1), one O(15), one O(16), one O(18), one O(19), one O(20), one O(23), one O(24), one O(7), one O(9), and two equivalent O(22) atoms to form distorted LaO12 cuboctahedra that share corners with two equivalent La(2)O12 cuboctahedra, corners with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Ti(4)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, and faces with two equivalent Ti(8)O6 octahedra. In the fifth La site, La(5) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(13), one O(14), one O(16), one O(17), one O(19), one O(2), one O(24), one O(9), and two equivalent O(6) atoms. There are eight inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(15), one O(18), one O(21), one O(23), one O(5), and one O(8) atom to form distorted TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent Ti(5)O6 octahedra, corners with two equivalent Ti(6)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra, and  a faceface with one La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-33°. In the second Ti site, Ti(2) is bonded to one O(1), one O(12), one O(20), one O(3), one O(5), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, corners with two equivalent Ti(7)O6 octahedra, corners with two equivalent Ti(8)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-25°. In the third Ti site, Ti(3) is bonded to one O(11), one O(15), one O(16), one O(17), one O(24), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, corners with two equivalent Ti(7)O6 octahedra, corners with two equivalent Ti(8)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra, and  a faceface with one La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 8-24°. In the fourth Ti site, Ti(4) is bonded to one O(1), one O(10), one O(19), one O(2), one O(6), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent Ti(5)O6 octahedra, corners with two equivalent Ti(6)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 12-26°. In the fifth Ti site, Ti(5) is bonded to one O(10), one O(14), one O(2), one O(21), one O(4), and one O(8) atom to form distorted TiO6 octahedra that share  a cornercorner with one Ti(7)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 11-33°. In the sixth Ti site, Ti(6) is bonded to one O(13), one O(18), one O(19), one O(22), one O(23), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(7)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-26°. In the seventh Ti site, Ti(7) is bonded to one O(11), one O(12), one O(13), one O(17), one O(3), and one O(4) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(6)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-26°. In the eighth Ti site, Ti(8) is bonded to one O(14), one O(16), one O(20), one O(22), one O(24), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(6)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 8-24°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(2), one La(4), two equivalent La(1), one Ti(2), and one Ti(4) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one La(1), one La(2), one La(5), one Ti(4), and one Ti(5) atom. In the third O site, O(3) is bonded in a linear geometry to one La(1), one La(2), one Ti(2), and one Ti(7) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one La(1), one La(3), two equivalent La(2), one Ti(5), and one Ti(7) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one Ti(1), and one Ti(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to two equivalent La(5), one Ti(3), and one Ti(4) atom. In the seventh O site, O(7) is bonded to one Li(1), one La(1), one La(4), one Ti(2), and one Ti(8) atom to form distorted OLiLa2Ti2 square pyramids that share  a cornercorner with one O(10)La3Ti2 square pyramid,  a cornercorner with one O(12)LiLa2Ti2 square pyramid, corners with two equivalent O(24)La3Ti2 square pyramids,  a cornercorner with one O(23)La2Ti2 trigonal pyramid,  an edgeedge with one O(12)LiLa2Ti2 square pyramid,  an edgeedge with one O(20)LiLa2Ti2 square pyramid, and  a faceface with one O(20)LiLa2Ti2 square pyramid. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(2), one La(3), one Ti(1), and one Ti(5) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one La(1), one La(4), one La(5), one Ti(4), and one Ti(6) atom. In the tenth O site, O(10) is bonded to one La(1), one La(2), one La(5), one Ti(4), and one Ti(5) atom to form distorted OLa3Ti2 square pyramids that share  a cornercorner with one O(24)La3Ti2 square pyramid,  a cornercorner with one O(20)LiLa2Ti2 square pyramid,  a cornercorner with one O(7)LiLa2Ti2 square pyramid, corners with two equivalent O(11)La3Ti2 square pyramids,  an edgeedge with one O(12)LiLa2Ti2 square pyramid, and  an edgeedge with one O(21)La2Ti2 tetrahedra. In the eleventh O site, O(11) is bonded to one La(2), one La(3), one La(5), one Ti(3), and one Ti(7) atom to form distorted OLa3Ti2 square pyramids that share  a cornercorner with one O(24)La3Ti2 square pyramid, corners with two equivalent O(10)La3Ti2 square pyramids, corners with two equivalent O(12)LiLa2Ti2 square pyramids, corners with two equivalent O(21)La2Ti2 tetrahedra,  a cornercorner with one O(23)La2Ti2 trigonal pyramid, and  an edgeedge with one O(24)La3Ti2 square pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one La(1), one La(2), one Ti(2), and one Ti(7) atom to form distorted OLiLa2Ti2 square pyramids that share  a cornercorner with one O(7)LiLa2Ti2 square pyramid, corners with two equivalent O(11)La3Ti2 square pyramids,  a cornercorner with one O(21)La2Ti2 tetrahedra,  an edgeedge with one O(10)La3Ti2 square pyramid,  an edgeedge with one O(7)LiLa2Ti2 square pyramid, and  a faceface with one O(20)LiLa2Ti2 square pyramid. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(5), one Ti(6), and one Ti(7) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(1), one La(5), one Ti(5), and one Ti(8) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one La(2), one La(4), two equivalent La(3), one Ti(1), and one Ti(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one La(3), one La(4), one La(5), one Ti(3), and one Ti(8) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one La(2), one La(3), one La(5), one Ti(3), and one Ti(7) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one La(3), one La(4), one Ti(1), and one Ti(6) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one La(1), one La(4), one La(5), one Ti(4), and one Ti(6) atom. In the twentieth O site, O(20) is bonded to one Li(1), one La(1), one La(4), one Ti(2), and one Ti(8) atom to form distorted OLiLa2Ti2 square pyramids that share  a cornercorner with one O(10)La3Ti2 square pyramid,  a cornercorner with one O(23)La2Ti2 trigonal pyramid,  an edgeedge with one O(24)La3Ti2 square pyramid,  an edgeedge with one O(7)LiLa2Ti2 square pyramid,  a faceface with one O(12)LiLa2Ti2 square pyramid, and  a faceface with one O(7)LiLa2Ti2 square pyramid. In the twenty-first O site, O(21) is bonded to one La(2), one La(3), one Ti(1), and one Ti(5) atom to form distorted OLa2Ti2 tetrahedra that share  a cornercorner with one O(24)La3Ti2 square pyramid,  a cornercorner with one O(12)LiLa2Ti2 square pyramid, corners with two equivalent O(11)La3Ti2 square pyramids,  an edgeedge with one O(10)La3Ti2 square pyramid, and  an edgeedge with one O(23)La2Ti2 trigonal pyramid. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one La(1), one La(3), two equivalent La(4), one Ti(6), and one Ti(8) atom. In the twenty-third O site, O(23) is bonded to one La(3), one La(4), one Ti(1), and one Ti(6) atom to form distorted OLa2Ti2 trigonal pyramids that share  a cornercorner with one O(11)La3Ti2 square pyramid,  a cornercorner with one O(20)LiLa2Ti2 square pyramid,  a cornercorner with one O(7)LiLa2Ti2 square pyramid,  an edgeedge with one O(24)La3Ti2 square pyramid, and  an edgeedge with one O(21)La2Ti2 tetrahedra. In the twenty-fourth O site, O(24) is bonded to one La(3), one La(4), one La(5), one Ti(3), and one Ti(8) atom to form distorted OLa3Ti2 square pyramids that share  a cornercorner with one O(10)La3Ti2 square pyramid,  a cornercorner with one O(11)La3Ti2 square pyramid, corners with two equivalent O(7)LiLa2Ti2 square pyramids,  a cornercorner with one O(21)La2Ti2 tetrahedra,  an edgeedge with one O(11)La3Ti2 square pyramid,  an edgeedge with one O(20)LiLa2Ti2 square pyramid, and  an edgeedge with one O(23)La2Ti2 trigonal pyramid.
LiLa5Ti8O24 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(20), one O(5), and one O(7) atom. The Li(1)-O(12) bond length is 2.37 Å. The Li(1)-O(14) bond length is 2.39 Å. The Li(1)-O(20) bond length is 2.18 Å. The Li(1)-O(5) bond length is 2.09 Å. The Li(1)-O(7) bond length is 2.49 Å. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(10), one O(12), one O(19), one O(2), one O(20), one O(22), one O(3), one O(4), one O(7), one O(9), and two equivalent O(1) atoms to form distorted LaO12 cuboctahedra that share corners with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra,  a faceface with one Ti(5)O6 octahedra,  a faceface with one Ti(6)O6 octahedra,  a faceface with one Ti(7)O6 octahedra,  a faceface with one Ti(8)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. The La(1)-O(10) bond length is 2.61 Å. The La(1)-O(12) bond length is 2.63 Å. The La(1)-O(19) bond length is 2.54 Å. The La(1)-O(2) bond length is 2.75 Å. The La(1)-O(20) bond length is 2.57 Å. The La(1)-O(22) bond length is 2.99 Å. The La(1)-O(3) bond length is 2.84 Å. The La(1)-O(4) bond length is 2.53 Å. The La(1)-O(7) bond length is 2.67 Å. The La(1)-O(9) bond length is 2.62 Å. There is one shorter (2.55 Å) and one longer (2.97 Å) La(1)-O(1) bond length. In the second La site, La(2) is bonded to one O(1), one O(10), one O(11), one O(12), one O(15), one O(17), one O(2), one O(21), one O(3), one O(8), and two equivalent O(4) atoms to form distorted LaO12 cuboctahedra that share corners with two equivalent La(2)O12 cuboctahedra, corners with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Ti(4)O6 octahedra, faces with two equivalent Ti(5)O6 octahedra, and faces with two equivalent Ti(7)O6 octahedra. The La(2)-O(1) bond length is 2.53 Å. The La(2)-O(10) bond length is 2.73 Å. The La(2)-O(11) bond length is 2.74 Å. The La(2)-O(12) bond length is 2.71 Å. The La(2)-O(15) bond length is 2.99 Å. The La(2)-O(17) bond length is 2.54 Å. The La(2)-O(2) bond length is 2.99 Å. The La(2)-O(21) bond length is 2.51 Å. The La(2)-O(3) bond length is 2.89 Å. The La(2)-O(8) bond length is 2.61 Å. There is one shorter (2.52 Å) and one longer (3.00 Å) La(2)-O(4) bond length. In the third La site, La(3) is bonded in a 12-coordinate geometry to one O(11), one O(16), one O(17), one O(18), one O(21), one O(22), one O(23), one O(24), one O(4), one O(8), and two equivalent O(15) atoms. The La(3)-O(11) bond length is 2.66 Å. The La(3)-O(16) bond length is 2.85 Å. The La(3)-O(17) bond length is 2.59 Å. The La(3)-O(18) bond length is 2.75 Å. The La(3)-O(21) bond length is 2.51 Å. The La(3)-O(22) bond length is 2.56 Å. The La(3)-O(23) bond length is 2.59 Å. The La(3)-O(24) bond length is 2.68 Å. The La(3)-O(4) bond length is 2.97 Å. The La(3)-O(8) bond length is 2.60 Å. There is one shorter (2.53 Å) and one longer (3.00 Å) La(3)-O(15) bond length. In the fourth La site, La(4) is bonded to one O(1), one O(15), one O(16), one O(18), one O(19), one O(20), one O(23), one O(24), one O(7), one O(9), and two equivalent O(22) atoms to form distorted LaO12 cuboctahedra that share corners with two equivalent La(2)O12 cuboctahedra, corners with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Ti(4)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, and faces with two equivalent Ti(8)O6 octahedra. The La(4)-O(1) bond length is 3.00 Å. The La(4)-O(15) bond length is 2.53 Å. The La(4)-O(16) bond length is 3.04 Å. The La(4)-O(18) bond length is 2.80 Å. The La(4)-O(19) bond length is 2.50 Å. The La(4)-O(20) bond length is 2.60 Å. The La(4)-O(23) bond length is 2.56 Å. The La(4)-O(24) bond length is 2.77 Å. The La(4)-O(7) bond length is 2.74 Å. The La(4)-O(9) bond length is 2.70 Å. There is one shorter (2.53 Å) and one longer (2.99 Å) La(4)-O(22) bond length. In the fifth La site, La(5) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(13), one O(14), one O(16), one O(17), one O(19), one O(2), one O(24), one O(9), and two equivalent O(6) atoms. The La(5)-O(10) bond length is 2.79 Å. The La(5)-O(11) bond length is 2.79 Å. The La(5)-O(13) bond length is 2.50 Å. The La(5)-O(14) bond length is 2.84 Å. The La(5)-O(16) bond length is 2.47 Å. The La(5)-O(17) bond length is 3.09 Å. The La(5)-O(19) bond length is 3.07 Å. The La(5)-O(2) bond length is 2.51 Å. The La(5)-O(24) bond length is 2.77 Å. The La(5)-O(9) bond length is 2.81 Å. There is one shorter (2.57 Å) and one longer (2.95 Å) La(5)-O(6) bond length. There are eight inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(15), one O(18), one O(21), one O(23), one O(5), and one O(8) atom to form distorted TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent Ti(5)O6 octahedra, corners with two equivalent Ti(6)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra, and  a faceface with one La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-33°. The Ti(1)-O(15) bond length is 2.21 Å. The Ti(1)-O(18) bond length is 1.94 Å. The Ti(1)-O(21) bond length is 2.02 Å. The Ti(1)-O(23) bond length is 1.97 Å. The Ti(1)-O(5) bond length is 1.83 Å. The Ti(1)-O(8) bond length is 2.00 Å. In the second Ti site, Ti(2) is bonded to one O(1), one O(12), one O(20), one O(3), one O(5), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, corners with two equivalent Ti(7)O6 octahedra, corners with two equivalent Ti(8)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-25°. The Ti(2)-O(1) bond length is 2.08 Å. The Ti(2)-O(12) bond length is 2.01 Å. The Ti(2)-O(20) bond length is 2.05 Å. The Ti(2)-O(3) bond length is 1.88 Å. The Ti(2)-O(5) bond length is 1.90 Å. The Ti(2)-O(7) bond length is 1.92 Å. In the third Ti site, Ti(3) is bonded to one O(11), one O(15), one O(16), one O(17), one O(24), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, corners with two equivalent Ti(7)O6 octahedra, corners with two equivalent Ti(8)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra, and  a faceface with one La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 8-24°. The Ti(3)-O(11) bond length is 1.96 Å. The Ti(3)-O(15) bond length is 1.96 Å. The Ti(3)-O(16) bond length is 1.97 Å. The Ti(3)-O(17) bond length is 1.96 Å. The Ti(3)-O(24) bond length is 1.97 Å. The Ti(3)-O(6) bond length is 1.97 Å. In the fourth Ti site, Ti(4) is bonded to one O(1), one O(10), one O(19), one O(2), one O(6), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent Ti(5)O6 octahedra, corners with two equivalent Ti(6)O6 octahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 12-26°. The Ti(4)-O(1) bond length is 2.05 Å. The Ti(4)-O(10) bond length is 1.94 Å. The Ti(4)-O(19) bond length is 1.98 Å. The Ti(4)-O(2) bond length is 1.97 Å. The Ti(4)-O(6) bond length is 1.90 Å. The Ti(4)-O(9) bond length is 2.00 Å. In the fifth Ti site, Ti(5) is bonded to one O(10), one O(14), one O(2), one O(21), one O(4), and one O(8) atom to form distorted TiO6 octahedra that share  a cornercorner with one Ti(7)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 11-33°. The Ti(5)-O(10) bond length is 2.06 Å. The Ti(5)-O(14) bond length is 1.85 Å. The Ti(5)-O(2) bond length is 2.00 Å. The Ti(5)-O(21) bond length is 1.96 Å. The Ti(5)-O(4) bond length is 2.13 Å. The Ti(5)-O(8) bond length is 1.91 Å. In the sixth Ti site, Ti(6) is bonded to one O(13), one O(18), one O(19), one O(22), one O(23), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(7)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-26°. The Ti(6)-O(13) bond length is 1.87 Å. The Ti(6)-O(18) bond length is 1.89 Å. The Ti(6)-O(19) bond length is 2.07 Å. The Ti(6)-O(22) bond length is 2.14 Å. The Ti(6)-O(23) bond length is 1.96 Å. The Ti(6)-O(9) bond length is 1.99 Å. In the seventh Ti site, Ti(7) is bonded to one O(11), one O(12), one O(13), one O(17), one O(3), and one O(4) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(6)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-26°. The Ti(7)-O(11) bond length is 2.01 Å. The Ti(7)-O(12) bond length is 1.92 Å. The Ti(7)-O(13) bond length is 1.93 Å. The Ti(7)-O(17) bond length is 2.01 Å. The Ti(7)-O(3) bond length is 1.92 Å. The Ti(7)-O(4) bond length is 2.05 Å. In the eighth Ti site, Ti(8) is bonded to one O(14), one O(16), one O(20), one O(22), one O(24), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(6)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra,  a faceface with one La(1)O12 cuboctahedra, and faces with two equivalent La(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 8-24°. The Ti(8)-O(14) bond length is 1.94 Å. The Ti(8)-O(16) bond length is 1.97 Å. The Ti(8)-O(20) bond length is 1.96 Å. The Ti(8)-O(22) bond length is 1.99 Å. The Ti(8)-O(24) bond length is 1.97 Å. The Ti(8)-O(7) bond length is 1.96 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(2), one La(4), two equivalent La(1), one Ti(2), and one Ti(4) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one La(1), one La(2), one La(5), one Ti(4), and one Ti(5) atom. In the third O site, O(3) is bonded in a linear geometry to one La(1), one La(2), one Ti(2), and one Ti(7) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one La(1), one La(3), two equivalent La(2), one Ti(5), and one Ti(7) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one Ti(1), and one Ti(2) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to two equivalent La(5), one Ti(3), and one Ti(4) atom. In the seventh O site, O(7) is bonded to one Li(1), one La(1), one La(4), one Ti(2), and one Ti(8) atom to form distorted OLiLa2Ti2 square pyramids that share  a cornercorner with one O(10)La3Ti2 square pyramid,  a cornercorner with one O(12)LiLa2Ti2 square pyramid, corners with two equivalent O(24)La3Ti2 square pyramids,  a cornercorner with one O(23)La2Ti2 trigonal pyramid,  an edgeedge with one O(12)LiLa2Ti2 square pyramid,  an edgeedge with one O(20)LiLa2Ti2 square pyramid, and  a faceface with one O(20)LiLa2Ti2 square pyramid. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one La(2), one La(3), one Ti(1), and one Ti(5) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one La(1), one La(4), one La(5), one Ti(4), and one Ti(6) atom. In the tenth O site, O(10) is bonded to one La(1), one La(2), one La(5), one Ti(4), and one Ti(5) atom to form distorted OLa3Ti2 square pyramids that share  a cornercorner with one O(24)La3Ti2 square pyramid,  a cornercorner with one O(20)LiLa2Ti2 square pyramid,  a cornercorner with one O(7)LiLa2Ti2 square pyramid, corners with two equivalent O(11)La3Ti2 square pyramids,  an edgeedge with one O(12)LiLa2Ti2 square pyramid, and  an edgeedge with one O(21)La2Ti2 tetrahedra. In the eleventh O site, O(11) is bonded to one La(2), one La(3), one La(5), one Ti(3), and one Ti(7) atom to form distorted OLa3Ti2 square pyramids that share  a cornercorner with one O(24)La3Ti2 square pyramid, corners with two equivalent O(10)La3Ti2 square pyramids, corners with two equivalent O(12)LiLa2Ti2 square pyramids, corners with two equivalent O(21)La2Ti2 tetrahedra,  a cornercorner with one O(23)La2Ti2 trigonal pyramid, and  an edgeedge with one O(24)La3Ti2 square pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one La(1), one La(2), one Ti(2), and one Ti(7) atom to form distorted OLiLa2Ti2 square pyramids that share  a cornercorner with one O(7)LiLa2Ti2 square pyramid, corners with two equivalent O(11)La3Ti2 square pyramids,  a cornercorner with one O(21)La2Ti2 tetrahedra,  an edgeedge with one O(10)La3Ti2 square pyramid,  an edgeedge with one O(7)LiLa2Ti2 square pyramid, and  a faceface with one O(20)LiLa2Ti2 square pyramid. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one La(5), one Ti(6), and one Ti(7) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(1), one La(5), one Ti(5), and one Ti(8) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one La(2), one La(4), two equivalent La(3), one Ti(1), and one Ti(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one La(3), one La(4), one La(5), one Ti(3), and one Ti(8) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one La(2), one La(3), one La(5), one Ti(3), and one Ti(7) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one La(3), one La(4), one Ti(1), and one Ti(6) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one La(1), one La(4), one La(5), one Ti(4), and one Ti(6) atom. In the twentieth O site, O(20) is bonded to one Li(1), one La(1), one La(4), one Ti(2), and one Ti(8) atom to form distorted OLiLa2Ti2 square pyramids that share  a cornercorner with one O(10)La3Ti2 square pyramid,  a cornercorner with one O(23)La2Ti2 trigonal pyramid,  an edgeedge with one O(24)La3Ti2 square pyramid,  an edgeedge with one O(7)LiLa2Ti2 square pyramid,  a faceface with one O(12)LiLa2Ti2 square pyramid, and  a faceface with one O(7)LiLa2Ti2 square pyramid. In the twenty-first O site, O(21) is bonded to one La(2), one La(3), one Ti(1), and one Ti(5) atom to form distorted OLa2Ti2 tetrahedra that share  a cornercorner with one O(24)La3Ti2 square pyramid,  a cornercorner with one O(12)LiLa2Ti2 square pyramid, corners with two equivalent O(11)La3Ti2 square pyramids,  an edgeedge with one O(10)La3Ti2 square pyramid, and  an edgeedge with one O(23)La2Ti2 trigonal pyramid. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one La(1), one La(3), two equivalent La(4), one Ti(6), and one Ti(8) atom. In the twenty-third O site, O(23) is bonded to one La(3), one La(4), one Ti(1), and one Ti(6) atom to form distorted OLa2Ti2 trigonal pyramids that share  a cornercorner with one O(11)La3Ti2 square pyramid,  a cornercorner with one O(20)LiLa2Ti2 square pyramid,  a cornercorner with one O(7)LiLa2Ti2 square pyramid,  an edgeedge with one O(24)La3Ti2 square pyramid, and  an edgeedge with one O(21)La2Ti2 tetrahedra. In the twenty-fourth O site, O(24) is bonded to one La(3), one La(4), one La(5), one Ti(3), and one Ti(8) atom to form distorted OLa3Ti2 square pyramids that share  a cornercorner with one O(10)La3Ti2 square pyramid,  a cornercorner with one O(11)La3Ti2 square pyramid, corners with two equivalent O(7)LiLa2Ti2 square pyramids,  a cornercorner with one O(21)La2Ti2 tetrahedra,  an edgeedge with one O(11)La3Ti2 square pyramid,  an edgeedge with one O(20)LiLa2Ti2 square pyramid, and  an edgeedge with one O(23)La2Ti2 trigonal pyramid.