C4TeS2(N4Cl)2(SO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur monoxide molecules and two C4TeS2(N4Cl)2 clusters. In each C4TeS2(N4Cl)2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Cl(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one N(3) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one N(2) atom.
C4TeS2(N4Cl)2(SO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur monoxide molecules and two C4TeS2(N4Cl)2 clusters. In each C4TeS2(N4Cl)2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(2) bond length is 1.31 Å. In the second C site, C(2) is bonded in a linear geometry to one N(3) and one N(4) atom. The C(2)-N(3) bond length is 1.31 Å. The C(2)-N(4) bond length is 1.18 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. The N(1)-Te(1) bond length is 2.05 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Cl(1) atom. The N(2)-Cl(1) bond length is 1.70 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(2) and one S(2) atom. The N(3)-S(2) bond length is 1.59 Å. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(2) atom. Te(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent S(2) atoms. Both Te(1)-S(2) bond lengths are 2.68 Å. S(2) is bonded in a distorted single-bond geometry to one N(3) and one Te(1) atom. Cl(1) is bonded in a single-bond geometry to one N(2) atom.