Bi(TeO3)(NO3) crystallizes in the monoclinic P2_1/c space group. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. N(1) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Te(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Bi(1) and one Te(1) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Bi(1) and one Te(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one N(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Bi(1) and one N(1) atom.
Bi(TeO3)(NO3) crystallizes in the monoclinic P2_1/c space group. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. The Bi(1)-O(3) bond length is 2.21 Å. The Bi(1)-O(5) bond length is 2.77 Å. There is one shorter (2.32 Å) and one longer (2.41 Å) Bi(1)-O(1) bond length. There is one shorter (2.31 Å) and one longer (2.66 Å) Bi(1)-O(2) bond length. There is one shorter (2.63 Å) and one longer (2.79 Å) Bi(1)-O(4) bond length. N(1) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(1)-O(4) bond length is 1.28 Å. The N(1)-O(5) bond length is 1.25 Å. The N(1)-O(6) bond length is 1.25 Å. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. The Te(1)-O(1) bond length is 1.89 Å. The Te(1)-O(2) bond length is 1.91 Å. The Te(1)-O(3) bond length is 1.88 Å. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Te(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Bi(1) and one Te(1) atom. In the fourth O site, O(3) is bonded in a water-like geometry to one Bi(1) and one Te(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one N(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Bi(1) and one N(1) atom.