(CF)3C3H3SeO3F2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six fluoromethane molecules and two C3H3SeO3F2 clusters. In each C3H3SeO3F2 cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one Se(1) atom. In the second C site, C(2) is bonded in a single-bond geometry to one C(1) and one F(1) atom. In the third C site, C(6) is bonded in a single-bond geometry to one C(1) and one F(5) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. Se(1) is bonded in a distorted water-like geometry to one C(1), one O(1), and one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one H(1) and one Se(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Se(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. There are two inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one C(6) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(2) atom.
(CF)3C3H3SeO3F2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six fluoromethane molecules and two C3H3SeO3F2 clusters. In each C3H3SeO3F2 cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one Se(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-Se(1) bond length is 2.00 Å. In the second C site, C(2) is bonded in a single-bond geometry to one C(1) and one F(1) atom. The C(2)-F(1) bond length is 1.35 Å. In the third C site, C(6) is bonded in a single-bond geometry to one C(1) and one F(5) atom. The C(6)-F(5) bond length is 1.36 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. The H(1)-O(1) bond length is 1.03 Å. The H(1)-O(3) bond length is 1.61 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 0.99 Å. Se(1) is bonded in a distorted water-like geometry to one C(1), one O(1), and one O(2) atom. The Se(1)-O(1) bond length is 1.79 Å. The Se(1)-O(2) bond length is 1.67 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one H(1) and one Se(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Se(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. There are two inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one C(6) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(2) atom.