P2Te(NO6)2(NO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitroxyl molecules and one P2Te(NO6)2 cluster. In the P2Te(NO6)2 cluster, P(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. N(1) is bonded in a bent 120 degrees geometry to one O(2) and one O(5) atom. Te(1) is bonded in a square co-planar geometry to two equivalent O(5) and two equivalent O(7) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one N(1) and one Te(1) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one P(1) and one O(7) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Te(1) and one O(6) atom.
P2Te(NO6)2(NO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitroxyl molecules and one P2Te(NO6)2 cluster. In the P2Te(NO6)2 cluster, P(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. The P(1)-O(1) bond length is 1.47 Å. The P(1)-O(3) bond length is 1.47 Å. The P(1)-O(6) bond length is 1.60 Å. N(1) is bonded in a bent 120 degrees geometry to one O(2) and one O(5) atom. The N(1)-O(2) bond length is 1.22 Å. The N(1)-O(5) bond length is 1.26 Å. Te(1) is bonded in a square co-planar geometry to two equivalent O(5) and two equivalent O(7) atoms. Both Te(1)-O(5) bond lengths are 2.36 Å. Both Te(1)-O(7) bond lengths are 2.10 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one N(1) and one Te(1) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one P(1) and one O(7) atom. The O(6)-O(7) bond length is 1.56 Å. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Te(1) and one O(6) atom.