BNH2H2 is Cyanogen Chloride-like structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules and two BNH2 clusters. In each BNH2 cluster, B(1) is bonded in a linear geometry to one N(1) and one H(2) atom. N(1) is bonded in a linear geometry to one B(1) and one H(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one B(1) atom.
BNH2H2 is Cyanogen Chloride-like structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules and two BNH2 clusters. In each BNH2 cluster, B(1) is bonded in a linear geometry to one N(1) and one H(2) atom. The B(1)-N(1) bond length is 1.24 Å. The B(1)-H(2) bond length is 1.17 Å. N(1) is bonded in a linear geometry to one B(1) and one H(1) atom. The N(1)-H(1) bond length is 1.00 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one B(1) atom.