CsAgGaF6 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 7-coordinate geometry to one F(4), two equivalent F(1), and four equivalent F(3) atoms. Ag(1) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra and corners with four equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. Ga(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form GaF6 octahedra that share corners with two equivalent Ga(1)F6 octahedra and corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 21-61°. There are four inequivalent F sites. In the first F site, F(4) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Ag(1) atoms. In the second F site, F(1) is bonded in a 2-coordinate geometry to one Cs(1), one Ag(1), and one Ga(1) atom. In the third F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the fourth F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one Ag(1), and one Ga(1) atom.
CsAgGaF6 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 7-coordinate geometry to one F(4), two equivalent F(1), and four equivalent F(3) atoms. The Cs(1)-F(4) bond length is 3.26 Å. Both Cs(1)-F(1) bond lengths are 3.24 Å. There are two shorter (3.18 Å) and two longer (3.20 Å) Cs(1)-F(3) bond lengths. Ag(1) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra and corners with four equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. Both Ag(1)-F(1) bond lengths are 2.38 Å. Both Ag(1)-F(3) bond lengths are 2.35 Å. Both Ag(1)-F(4) bond lengths are 2.07 Å. Ga(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form GaF6 octahedra that share corners with two equivalent Ga(1)F6 octahedra and corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 21-61°. Both Ga(1)-F(1) bond lengths are 1.91 Å. Both Ga(1)-F(2) bond lengths are 1.96 Å. Both Ga(1)-F(3) bond lengths are 1.92 Å. There are four inequivalent F sites. In the first F site, F(4) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Ag(1) atoms. In the second F site, F(1) is bonded in a 2-coordinate geometry to one Cs(1), one Ag(1), and one Ga(1) atom. In the third F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the fourth F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one Ag(1), and one Ga(1) atom.