KInBr4 is Zircon-like structured and crystallizes in the orthorhombic Pnna space group. K(1) is bonded in a 8-coordinate geometry to four equivalent Br(1) and four equivalent Br(2) atoms. In(1) is bonded in a tetrahedral geometry to two equivalent Br(1) and two equivalent Br(2) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one In(1) atom. In the second Br site, Br(2) is bonded in a distorted T-shaped geometry to two equivalent K(1) and one In(1) atom.
KInBr4 is Zircon-like structured and crystallizes in the orthorhombic Pnna space group. K(1) is bonded in a 8-coordinate geometry to four equivalent Br(1) and four equivalent Br(2) atoms. All K(1)-Br(1) bond lengths are 3.46 Å. There are two shorter (3.40 Å) and two longer (3.44 Å) K(1)-Br(2) bond lengths. In(1) is bonded in a tetrahedral geometry to two equivalent Br(1) and two equivalent Br(2) atoms. Both In(1)-Br(1) bond lengths are 2.53 Å. Both In(1)-Br(2) bond lengths are 2.53 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one In(1) atom. In the second Br site, Br(2) is bonded in a distorted T-shaped geometry to two equivalent K(1) and one In(1) atom.