Ag2HgO2 crystallizes in the tetragonal P4_32_12 space group. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Hg(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Ag(1) and two equivalent Hg(1) atoms to form corner-sharing OAg2Hg2 tetrahedra.
Ag2HgO2 crystallizes in the tetragonal P4_32_12 space group. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. There is one shorter (2.10 Å) and one longer (2.11 Å) Ag(1)-O(1) bond length. Hg(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are two shorter (2.07 Å) and two longer (2.57 Å) Hg(1)-O(1) bond lengths. O(1) is bonded to two equivalent Ag(1) and two equivalent Hg(1) atoms to form corner-sharing OAg2Hg2 tetrahedra.