Li6WO6 crystallizes in the trigonal R-3 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. W(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one W(1) atom.
Li6WO6 crystallizes in the trigonal R-3 space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are a spread of Li(1)-O(1) bond distances ranging from 1.89-2.03 Å. W(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All W(1)-O(1) bond lengths are 1.93 Å. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one W(1) atom.