ClC1C2N is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two ClC1C2N clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(2) and one Cl(1) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one N(1) atom. N(1) is bonded in a 2-coordinate geometry to two equivalent C(2) atoms. Cl(1) is bonded in a single-bond geometry to one C(1) atom.
ClC1C2N is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two ClC1C2N clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(2) and one Cl(1) atom. Both C(1)-C(2) bond lengths are 1.41 Å. The C(1)-Cl(1) bond length is 1.67 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one N(1) atom. The C(2)-C(2) bond length is 1.51 Å. The C(2)-N(1) bond length is 1.39 Å. N(1) is bonded in a 2-coordinate geometry to two equivalent C(2) atoms. Cl(1) is bonded in a single-bond geometry to one C(1) atom.