BaWO2 crystallizes in the tetragonal I4_1/amd space group. Ba(1) is bonded to six equivalent O(1) atoms to form edge-sharing BaO6 octahedra. W(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Ba(1) and two equivalent W(1) atoms to form a mixture of distorted corner and edge-sharing OBa3W2 square pyramids.
BaWO2 crystallizes in the tetragonal I4_1/amd space group. Ba(1) is bonded to six equivalent O(1) atoms to form edge-sharing BaO6 octahedra. There are four shorter (2.72 Å) and two longer (2.78 Å) Ba(1)-O(1) bond lengths. W(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All W(1)-O(1) bond lengths are 2.24 Å. O(1) is bonded to three equivalent Ba(1) and two equivalent W(1) atoms to form a mixture of distorted corner and edge-sharing OBa3W2 square pyramids.