SrPrMn2O6 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), four equivalent O(3), and four equivalent O(4) atoms. Pr(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms. Mn(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms.
SrPrMn2O6 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), four equivalent O(3), and four equivalent O(4) atoms. There is one shorter (2.70 Å) and one longer (2.89 Å) Sr(1)-O(1) bond length. There is one shorter (2.50 Å) and one longer (3.07 Å) Sr(1)-O(2) bond length. There are two shorter (2.70 Å) and two longer (2.79 Å) Sr(1)-O(3) bond lengths. There are two shorter (2.55 Å) and two longer (3.05 Å) Sr(1)-O(4) bond lengths. Pr(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms. The Pr(1)-O(1) bond length is 2.44 Å. The Pr(1)-O(2) bond length is 2.56 Å. Both Pr(1)-O(3) bond lengths are 2.47 Å. Both Pr(1)-O(4) bond lengths are 2.57 Å. Mn(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. The Mn(1)-O(1) bond length is 1.98 Å. The Mn(1)-O(2) bond length is 1.97 Å. There is one shorter (1.98 Å) and one longer (1.99 Å) Mn(1)-O(3) bond length. Both Mn(1)-O(4) bond lengths are 1.99 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one Pr(1), and two equivalent Mn(1) atoms.