MgTi4O8 crystallizes in the cubic F-43m space group. Mg(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. Ti(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted T-shaped geometry to three equivalent Ti(1) atoms. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Mg(1) and three equivalent Ti(1) atoms.
MgTi4O8 crystallizes in the cubic F-43m space group. Mg(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All Mg(1)-O(1) bond lengths are 1.78 Å. Ti(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. All Ti(1)-O(1) bond lengths are 2.40 Å. All Ti(1)-O(2) bond lengths are 1.95 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted T-shaped geometry to three equivalent Ti(1) atoms. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Mg(1) and three equivalent Ti(1) atoms.