CuTlO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Cu(1) is bonded to six equivalent O(1) atoms to form CuO6 octahedra that share corners with six equivalent Cu(1)O6 octahedra and faces with eight equivalent Tl(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to twelve equivalent O(1) atoms to form TlO12 cuboctahedra that share corners with twelve equivalent Tl(1)O12 cuboctahedra, faces with six equivalent Tl(1)O12 cuboctahedra, and faces with eight equivalent Cu(1)O6 octahedra. O(1) is bonded in a distorted linear geometry to two equivalent Cu(1) and four equivalent Tl(1) atoms.
CuTlO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Cu(1) is bonded to six equivalent O(1) atoms to form CuO6 octahedra that share corners with six equivalent Cu(1)O6 octahedra and faces with eight equivalent Tl(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Cu(1)-O(1) bond lengths are 1.92 Å. Tl(1) is bonded to twelve equivalent O(1) atoms to form TlO12 cuboctahedra that share corners with twelve equivalent Tl(1)O12 cuboctahedra, faces with six equivalent Tl(1)O12 cuboctahedra, and faces with eight equivalent Cu(1)O6 octahedra. All Tl(1)-O(1) bond lengths are 2.72 Å. O(1) is bonded in a distorted linear geometry to two equivalent Cu(1) and four equivalent Tl(1) atoms.