(Ag)2VAgF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-22-4 atoms inside a VAgF6 framework. In the VAgF6 framework, V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Ag(2)F6 octahedra. The corner-sharing octahedra are not tilted. Ag(2) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one V(1) and one Ag(2) atom.
(Ag)2VAgF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-22-4 atoms inside a VAgF6 framework. In the VAgF6 framework, V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Ag(2)F6 octahedra. The corner-sharing octahedra are not tilted. All V(1)-F(1) bond lengths are 1.95 Å. Ag(2) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Ag(2)-F(1) bond lengths are 2.36 Å. F(1) is bonded in a linear geometry to one V(1) and one Ag(2) atom.