U(NO6)2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two U(NO6)2 clusters. In each U(NO6)2 cluster, U(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a water-like geometry to one O(4) and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(6) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one U(1) and one O(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one N(1) and one O(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one O(2) atom.
U(NO6)2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two U(NO6)2 clusters. In each U(NO6)2 cluster, U(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both U(1)-O(1) bond lengths are 1.81 Å. Both U(1)-O(2) bond lengths are 2.53 Å. Both U(1)-O(3) bond lengths are 2.24 Å. N(1) is bonded in a water-like geometry to one O(4) and one O(5) atom. The N(1)-O(4) bond length is 1.19 Å. The N(1)-O(5) bond length is 1.49 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(6) atom. The O(2)-O(6) bond length is 1.27 Å. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one U(1) and one O(5) atom. The O(3)-O(5) bond length is 1.40 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one N(1) and one O(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one O(2) atom.