WZn2SnO6 crystallizes in the triclinic P1 space group. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(6) atom. In the second Zn site, Zn(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. Sn(1) is bonded in a 3-coordinate geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Zn(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one W(1), one Zn(2), and one Sn(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one Sn(1) atom.
WZn2SnO6 crystallizes in the triclinic P1 space group. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The W(1)-O(1) bond length is 1.97 Å. The W(1)-O(2) bond length is 1.98 Å. The W(1)-O(3) bond length is 1.76 Å. The W(1)-O(4) bond length is 1.91 Å. The W(1)-O(5) bond length is 1.95 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(6) atom. The Zn(1)-O(1) bond length is 2.12 Å. The Zn(1)-O(2) bond length is 1.88 Å. The Zn(1)-O(6) bond length is 1.91 Å. In the second Zn site, Zn(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. The Zn(2)-O(2) bond length is 2.15 Å. The Zn(2)-O(4) bond length is 1.89 Å. The Zn(2)-O(5) bond length is 2.06 Å. The Zn(2)-O(6) bond length is 1.99 Å. Sn(1) is bonded in a 3-coordinate geometry to one O(1), one O(5), and one O(6) atom. The Sn(1)-O(1) bond length is 2.21 Å. The Sn(1)-O(5) bond length is 2.46 Å. The Sn(1)-O(6) bond length is 2.11 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Zn(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one W(1), one Zn(2), and one Sn(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one Sn(1) atom.