(Hg)2AsF6 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight 7439-97-6 atoms and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four F(1,1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom.
(Hg)2AsF6 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight 7439-97-6 atoms and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(2) and four F(1,1) atoms. Both As(1)-F(2) bond lengths are 1.76 Å. All As(1)-F(1,1) bond lengths are 1.78 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom.