RhBiTe is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Bi(1) and three equivalent Te(1) atoms to form RhBi3Te3 octahedra that share corners with twelve equivalent Rh(1)Bi3Te3 octahedra, corners with three equivalent Bi(1)TeRh3 trigonal pyramids, and corners with three equivalent Te(1)BiRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 62°. Bi(1) is bonded to three equivalent Rh(1) and one Te(1) atom to form distorted BiTeRh3 trigonal pyramids that share corners with three equivalent Rh(1)Bi3Te3 octahedra, corners with six equivalent Bi(1)TeRh3 trigonal pyramids, and corners with nine equivalent Te(1)BiRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°. Te(1) is bonded to three equivalent Rh(1) and one Bi(1) atom to form distorted TeBiRh3 trigonal pyramids that share corners with three equivalent Rh(1)Bi3Te3 octahedra, corners with six equivalent Te(1)BiRh3 trigonal pyramids, and corners with nine equivalent Bi(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.
RhBiTe is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Bi(1) and three equivalent Te(1) atoms to form RhBi3Te3 octahedra that share corners with twelve equivalent Rh(1)Bi3Te3 octahedra, corners with three equivalent Bi(1)TeRh3 trigonal pyramids, and corners with three equivalent Te(1)BiRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 62°. All Rh(1)-Bi(1) bond lengths are 2.75 Å. All Rh(1)-Te(1) bond lengths are 2.68 Å. Bi(1) is bonded to three equivalent Rh(1) and one Te(1) atom to form distorted BiTeRh3 trigonal pyramids that share corners with three equivalent Rh(1)Bi3Te3 octahedra, corners with six equivalent Bi(1)TeRh3 trigonal pyramids, and corners with nine equivalent Te(1)BiRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°. The Bi(1)-Te(1) bond length is 2.94 Å. Te(1) is bonded to three equivalent Rh(1) and one Bi(1) atom to form distorted TeBiRh3 trigonal pyramids that share corners with three equivalent Rh(1)Bi3Te3 octahedra, corners with six equivalent Te(1)BiRh3 trigonal pyramids, and corners with nine equivalent Bi(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.