Ti4CoBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Co(1) and four equivalent Bi(1) atoms. Co(1) is bonded in a 10-coordinate geometry to eight equivalent Ti(1) and two equivalent Co(1) atoms. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms.
Ti4CoBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Co(1) and four equivalent Bi(1) atoms. Both Ti(1)-Co(1) bond lengths are 2.52 Å. There are a spread of Ti(1)-Bi(1) bond distances ranging from 2.92-3.06 Å. Co(1) is bonded in a 10-coordinate geometry to eight equivalent Ti(1) and two equivalent Co(1) atoms. Both Co(1)-Co(1) bond lengths are 2.43 Å. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms.