MnZnN2 is Enargite-like structured and crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form MnN4 tetrahedra that share corners with four equivalent Mn(1)N4 tetrahedra and corners with eight equivalent Zn(1)N4 tetrahedra. Zn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form ZnN4 tetrahedra that share corners with four equivalent Zn(1)N4 tetrahedra and corners with eight equivalent Mn(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Mn(1) and two equivalent Zn(1) atoms to form corner-sharing NMn2Zn2 tetrahedra. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Zn(1) atoms to form corner-sharing NMn2Zn2 tetrahedra.
MnZnN2 is Enargite-like structured and crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form MnN4 tetrahedra that share corners with four equivalent Mn(1)N4 tetrahedra and corners with eight equivalent Zn(1)N4 tetrahedra. Both Mn(1)-N(1) bond lengths are 1.83 Å. Both Mn(1)-N(2) bond lengths are 1.82 Å. Zn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form ZnN4 tetrahedra that share corners with four equivalent Zn(1)N4 tetrahedra and corners with eight equivalent Mn(1)N4 tetrahedra. Both Zn(1)-N(1) bond lengths are 2.05 Å. There is one shorter (2.06 Å) and one longer (2.07 Å) Zn(1)-N(2) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Mn(1) and two equivalent Zn(1) atoms to form corner-sharing NMn2Zn2 tetrahedra. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Zn(1) atoms to form corner-sharing NMn2Zn2 tetrahedra.