Tc2C6NO8C2N is beta-prime cadmium gold structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two aziridine molecules and two Tc2C6NO8 clusters. In each Tc2C6NO8 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(2) atom. In the second C site, C(2) is bonded in a water-like geometry to one C(1) and one C(2) atom. In the third C site, C(4) is bonded in a distorted single-bond geometry to one O(4) atom. N(1) is bonded in a water-like geometry to two equivalent C(1) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(4) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(1) atom.
Tc2C6NO8C2N is beta-prime cadmium gold structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two aziridine molecules and two Tc2C6NO8 clusters. In each Tc2C6NO8 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Tc(1)-O(1) bond length is 1.71 Å. The Tc(1)-O(2) bond length is 1.97 Å. The Tc(1)-O(3) bond length is 1.70 Å. The Tc(1)-O(4) bond length is 2.07 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(1) and one C(2) atom. The C(2)-C(2) bond length is 1.27 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one O(4) atom. The C(4)-O(4) bond length is 1.24 Å. N(1) is bonded in a water-like geometry to two equivalent C(1) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(4) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(1) atom.