ReP(OCl2)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReP(OCl2)3 clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(2), one Cl(5), and one Cl(6) atom. P(1) is bonded in a tetrahedral geometry to one O(2), one Cl(1), one Cl(3), and one Cl(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom.
ReP(OCl2)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReP(OCl2)3 clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(2), one Cl(5), and one Cl(6) atom. The Re(1)-O(1) bond length is 1.73 Å. The Re(1)-O(2) bond length is 2.43 Å. The Re(1)-O(3) bond length is 1.71 Å. The Re(1)-Cl(2) bond length is 2.32 Å. The Re(1)-Cl(5) bond length is 2.39 Å. The Re(1)-Cl(6) bond length is 2.30 Å. P(1) is bonded in a tetrahedral geometry to one O(2), one Cl(1), one Cl(3), and one Cl(4) atom. The P(1)-O(2) bond length is 1.48 Å. The P(1)-Cl(1) bond length is 1.99 Å. The P(1)-Cl(3) bond length is 1.99 Å. The P(1)-Cl(4) bond length is 1.99 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom.