RhN3 is Skutterudite structured and crystallizes in the cubic Im-3 space group. Rh(1) is bonded to six equivalent N(1) atoms to form RhN6 octahedra that share corners with six equivalent Rh(1)N6 octahedra and corners with twelve equivalent N(1)Rh2N2 tetrahedra. The corner-sharing octahedral tilt angles are 75°. N(1) is bonded to two equivalent Rh(1) and two equivalent N(1) atoms to form NRh2N2 tetrahedra that share corners with four equivalent Rh(1)N6 octahedra, corners with ten equivalent N(1)Rh2N2 tetrahedra, and  an edgeedge with one N(1)Rh2N2 tetrahedra. The corner-sharing octahedral tilt angles range from 64-65°.
RhN3 is Skutterudite structured and crystallizes in the cubic Im-3 space group. Rh(1) is bonded to six equivalent N(1) atoms to form RhN6 octahedra that share corners with six equivalent Rh(1)N6 octahedra and corners with twelve equivalent N(1)Rh2N2 tetrahedra. The corner-sharing octahedral tilt angles are 75°. All Rh(1)-N(1) bond lengths are 2.09 Å. N(1) is bonded to two equivalent Rh(1) and two equivalent N(1) atoms to form NRh2N2 tetrahedra that share corners with four equivalent Rh(1)N6 octahedra, corners with ten equivalent N(1)Rh2N2 tetrahedra, and  an edgeedge with one N(1)Rh2N2 tetrahedra. The corner-sharing octahedral tilt angles range from 64-65°. There is one shorter (1.47 Å) and one longer (1.54 Å) N(1)-N(1) bond length.