LiFeCdF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 49°. Cd(1) is bonded to six equivalent F(1) atoms to form CdF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Fe(1), and one Cd(1) atom.
LiFeCdF6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31c space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles are 54°. All Li(1)-F(1) bond lengths are 2.05 Å. Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Fe(1)-F(1) bond lengths are 1.96 Å. Cd(1) is bonded to six equivalent F(1) atoms to form CdF6 octahedra that share corners with six equivalent Li(1)F6 octahedra and corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. All Cd(1)-F(1) bond lengths are 2.28 Å. F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Fe(1), and one Cd(1) atom.