ScPt3B is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Sc(1) is bonded to twelve equivalent Pt(1) atoms to form ScPt12 cuboctahedra that share corners with twelve equivalent Sc(1)Pt12 cuboctahedra, faces with six equivalent Sc(1)Pt12 cuboctahedra, and faces with eight equivalent B(1)Pt6 octahedra. Pt(1) is bonded to four equivalent Sc(1) and two equivalent B(1) atoms to form a mixture of distorted corner, edge, and face-sharing PtSc4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. B(1) is bonded to six equivalent Pt(1) atoms to form BPt6 octahedra that share corners with six equivalent B(1)Pt6 octahedra and faces with eight equivalent Sc(1)Pt12 cuboctahedra. The corner-sharing octahedra are not tilted.
ScPt3B is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Sc(1) is bonded to twelve equivalent Pt(1) atoms to form ScPt12 cuboctahedra that share corners with twelve equivalent Sc(1)Pt12 cuboctahedra, faces with six equivalent Sc(1)Pt12 cuboctahedra, and faces with eight equivalent B(1)Pt6 octahedra. All Sc(1)-Pt(1) bond lengths are 3.01 Å. Pt(1) is bonded to four equivalent Sc(1) and two equivalent B(1) atoms to form a mixture of distorted corner, edge, and face-sharing PtSc4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. Both Pt(1)-B(1) bond lengths are 2.13 Å. B(1) is bonded to six equivalent Pt(1) atoms to form BPt6 octahedra that share corners with six equivalent B(1)Pt6 octahedra and faces with eight equivalent Sc(1)Pt12 cuboctahedra. The corner-sharing octahedra are not tilted.