KTeO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent Te(1)O6 octahedra. Te(1) is bonded to six equivalent O(1) atoms to form TeO6 octahedra that share corners with six equivalent Te(1)O6 octahedra and faces with eight equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent K(1) and two equivalent Te(1) atoms to form a mixture of distorted corner, face, and edge-sharing OK4Te2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
KTeO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent Te(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.91 Å. Te(1) is bonded to six equivalent O(1) atoms to form TeO6 octahedra that share corners with six equivalent Te(1)O6 octahedra and faces with eight equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Te(1)-O(1) bond lengths are 2.06 Å. O(1) is bonded to four equivalent K(1) and two equivalent Te(1) atoms to form a mixture of distorted corner, face, and edge-sharing OK4Te2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.