Pu2SbTe2 crystallizes in the tetragonal P-4m2 space group. Pu(1) is bonded to two equivalent Sb(1) and five equivalent Te(1) atoms to form a mixture of distorted edge, corner, and face-sharing PuSb2Te5 pentagonal bipyramids. Sb(1) is bonded in a 4-coordinate geometry to four equivalent Pu(1) atoms. Te(1) is bonded to five equivalent Pu(1) atoms to form a mixture of distorted edge and corner-sharing TePu5 trigonal bipyramids.
Pu2SbTe2 crystallizes in the tetragonal P-4m2 space group. Pu(1) is bonded to two equivalent Sb(1) and five equivalent Te(1) atoms to form a mixture of distorted edge, corner, and face-sharing PuSb2Te5 pentagonal bipyramids. Both Pu(1)-Sb(1) bond lengths are 3.25 Å. There are four shorter (3.10 Å) and one longer (3.19 Å) Pu(1)-Te(1) bond length. Sb(1) is bonded in a 4-coordinate geometry to four equivalent Pu(1) atoms. Te(1) is bonded to five equivalent Pu(1) atoms to form a mixture of distorted edge and corner-sharing TePu5 trigonal bipyramids.