SrLaMnWO6 crystallizes in the tetragonal I-4 space group. Sr(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. La(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-29°. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-29°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent La(1), one W(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), one W(1), and one Mn(1) atom.
SrLaMnWO6 crystallizes in the tetragonal I-4 space group. Sr(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Sr(1)-O(1) bond lengths are 2.90 Å. All Sr(1)-O(2) bond lengths are 2.63 Å. La(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All La(1)-O(1) bond lengths are 2.90 Å. All La(1)-O(2) bond lengths are 2.46 Å. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-29°. Both W(1)-O(1) bond lengths are 1.93 Å. All W(1)-O(2) bond lengths are 2.05 Å. Mn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-29°. Both Mn(1)-O(1) bond lengths are 2.12 Å. All Mn(1)-O(2) bond lengths are 2.18 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent La(1), one W(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(1), one La(1), one W(1), and one Mn(1) atom.