TmZnAl is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Tm(1) is bonded to six equivalent Zn(1) and six equivalent Al(1) atoms to form a mixture of face and edge-sharing TmAl6Zn6 cuboctahedra. Zn(1) is bonded in a 9-coordinate geometry to six equivalent Tm(1) and three equivalent Al(1) atoms. Al(1) is bonded in a 9-coordinate geometry to six equivalent Tm(1) and three equivalent Zn(1) atoms.
TmZnAl is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Tm(1) is bonded to six equivalent Zn(1) and six equivalent Al(1) atoms to form a mixture of face and edge-sharing TmAl6Zn6 cuboctahedra. All Tm(1)-Zn(1) bond lengths are 3.09 Å. All Tm(1)-Al(1) bond lengths are 3.09 Å. Zn(1) is bonded in a 9-coordinate geometry to six equivalent Tm(1) and three equivalent Al(1) atoms. All Zn(1)-Al(1) bond lengths are 2.55 Å. Al(1) is bonded in a 9-coordinate geometry to six equivalent Tm(1) and three equivalent Zn(1) atoms.