ZnSbF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom.
ZnSbF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. All Zn(1)-F(1) bond lengths are 2.06 Å. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. All Sb(1)-F(1) bond lengths are 2.06 Å. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom.