NdAg3 crystallizes in the hexagonal P6_3/mmc space group. Nd(1) is bonded to twelve equivalent Ag(1) atoms to form a mixture of distorted corner and face-sharing NdAg12 cuboctahedra. Ag(1) is bonded in a 10-coordinate geometry to four equivalent Nd(1) and six equivalent Ag(1) atoms.
NdAg3 crystallizes in the hexagonal P6_3/mmc space group. Nd(1) is bonded to twelve equivalent Ag(1) atoms to form a mixture of distorted corner and face-sharing NdAg12 cuboctahedra. There are six shorter (3.18 Å) and six longer (3.27 Å) Nd(1)-Ag(1) bond lengths. Ag(1) is bonded in a 10-coordinate geometry to four equivalent Nd(1) and six equivalent Ag(1) atoms. There are two shorter (2.90 Å) and four longer (2.93 Å) Ag(1)-Ag(1) bond lengths.