Na2O2 is Tungsten Carbide-like structured and crystallizes in the orthorhombic Pbcm space group. Na(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted face, corner, and edge-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles range from 31-52°. O(1) is bonded to six equivalent Na(1) atoms to form a mixture of distorted corner and edge-sharing ONa6 pentagonal pyramids.
Na2O2 is Tungsten Carbide-like structured and crystallizes in the orthorhombic Pbcm space group. Na(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted face, corner, and edge-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles range from 31-52°. There are a spread of Na(1)-O(1) bond distances ranging from 2.40-2.43 Å. O(1) is bonded to six equivalent Na(1) atoms to form a mixture of distorted corner and edge-sharing ONa6 pentagonal pyramids.