NdMoO4F crystallizes in the monoclinic P2_1/c space group. Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), two equivalent O(4), and two equivalent F(1) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Nd(1) and one Mo(1) atom. F(1) is bonded in a distorted linear geometry to two equivalent Nd(1) atoms.
NdMoO4F crystallizes in the monoclinic P2_1/c space group. Nd(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), two equivalent O(3), two equivalent O(4), and two equivalent F(1) atoms. The Nd(1)-O(1) bond length is 2.46 Å. The Nd(1)-O(2) bond length is 2.43 Å. There is one shorter (2.54 Å) and one longer (2.56 Å) Nd(1)-O(3) bond length. There is one shorter (2.48 Å) and one longer (2.53 Å) Nd(1)-O(4) bond length. There is one shorter (2.36 Å) and one longer (2.38 Å) Nd(1)-F(1) bond length. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Mo(1)-O(1) bond length is 1.76 Å. The Mo(1)-O(2) bond length is 1.78 Å. The Mo(1)-O(3) bond length is 1.83 Å. The Mo(1)-O(4) bond length is 1.85 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Nd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Nd(1) and one Mo(1) atom. F(1) is bonded in a distorted linear geometry to two equivalent Nd(1) atoms.