Li4Co2Ni3O10 crystallizes in the monoclinic P2/m space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-13°. In the second Li site, Li(2) is bonded to one O(2), one O(6), two equivalent O(1), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with four equivalent Ni(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. In the third Li site, Li(3) is bonded to one O(1), one O(8), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. In the fourth Li site, Li(4) is bonded to one O(10), one O(7), two equivalent O(8), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with five equivalent Ni(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the fifth Li site, Li(5) is bonded to two equivalent O(9) and four equivalent O(10) atoms to form LiO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with four equivalent Li(4)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. In the second Co site, Co(2) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-13°. In the third Co site, Co(3) is bonded to two equivalent O(8) and four equivalent O(10) atoms to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with four equivalent Li(5)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with four equivalent Li(4)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(3), one O(7), two equivalent O(1), and two equivalent O(5) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. In the second Ni site, Ni(2) is bonded to one O(5), one O(9), two equivalent O(6), and two equivalent O(7) atoms to form NiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. In the third Ni site, Ni(3) is bonded to one O(10), one O(6), two equivalent O(8), and two equivalent O(9) atoms to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with five equivalent Li(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), two equivalent Li(2), one Co(1), and two equivalent Ni(1) atoms to form OLi3CoNi2 octahedra that share  a cornercorner with one O(8)Li3CoNi2 octahedra,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with four equivalent O(5)Li2Ni3 square pyramids, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), and two equivalent Co(1) atoms. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Co(1), and one Ni(1) atom. In the fourth O site, O(4) is bonded to two equivalent Li(1), one Co(1), and two equivalent Co(2) atoms to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li3CoNi2 octahedra, corners with four equivalent O(4)Li2Co3 square pyramids, and edges with four equivalent O(4)Li2Co3 square pyramids. The corner-sharing octahedral tilt angles are 2°. In the fifth O site, O(5) is bonded to two equivalent Li(2), one Ni(2), and two equivalent Ni(1) atoms to form OLi2Ni3 square pyramids that share  a cornercorner with one O(9)Li3Ni3 octahedra, corners with four equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-8°. In the sixth O site, O(6) is bonded to one Li(2), two equivalent Li(3), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(10)Li3Co2Ni octahedra, corners with four equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded to one Li(4), two equivalent Li(3), one Ni(1), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(10)Li3Co2Ni octahedra, corners with four equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-2°. In the eighth O site, O(8) is bonded to one Li(3), two equivalent Li(4), one Co(3), and two equivalent Ni(3) atoms to form OLi3CoNi2 octahedra that share  a cornercorner with one O(1)Li3CoNi2 octahedra,  a cornercorner with one O(8)Li3CoNi2 octahedra, corners with four equivalent O(9)Li3Ni3 octahedra, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with four equivalent O(10)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the ninth O site, O(9) is bonded to one Li(5), two equivalent Li(4), one Ni(2), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(9)Li3Ni3 octahedra, corners with four equivalent O(8)Li3CoNi2 octahedra,  a cornercorner with one O(5)Li2Ni3 square pyramid, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with four equivalent O(10)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Li(5), two equivalent Co(3), and one Ni(3) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra, corners with four equivalent O(10)Li3Co2Ni octahedra, edges with four equivalent O(10)Li3Co2Ni octahedra, edges with four equivalent O(8)Li3CoNi2 octahedra, and edges with four equivalent O(9)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°.
Li4Co2Ni3O10 crystallizes in the monoclinic P2/m space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-13°. Both Li(1)-O(3) bond lengths are 2.04 Å. All Li(1)-O(4) bond lengths are 2.16 Å. In the second Li site, Li(2) is bonded to one O(2), one O(6), two equivalent O(1), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with four equivalent Ni(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. The Li(2)-O(2) bond length is 2.06 Å. The Li(2)-O(6) bond length is 2.17 Å. Both Li(2)-O(1) bond lengths are 2.16 Å. Both Li(2)-O(5) bond lengths are 2.07 Å. In the third Li site, Li(3) is bonded to one O(1), one O(8), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. The Li(3)-O(1) bond length is 2.18 Å. The Li(3)-O(8) bond length is 2.25 Å. Both Li(3)-O(6) bond lengths are 2.11 Å. Both Li(3)-O(7) bond lengths are 2.11 Å. In the fourth Li site, Li(4) is bonded to one O(10), one O(7), two equivalent O(8), and two equivalent O(9) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with five equivalent Ni(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. The Li(4)-O(10) bond length is 2.07 Å. The Li(4)-O(7) bond length is 2.04 Å. Both Li(4)-O(8) bond lengths are 2.11 Å. Both Li(4)-O(9) bond lengths are 2.11 Å. In the fifth Li site, Li(5) is bonded to two equivalent O(9) and four equivalent O(10) atoms to form LiO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra, corners with four equivalent Co(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with four equivalent Li(4)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. Both Li(5)-O(9) bond lengths are 2.19 Å. All Li(5)-O(10) bond lengths are 2.14 Å. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. The Co(1)-O(1) bond length is 1.91 Å. The Co(1)-O(4) bond length is 1.88 Å. Both Co(1)-O(2) bond lengths are 1.91 Å. Both Co(1)-O(3) bond lengths are 1.89 Å. In the second Co site, Co(2) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-13°. Both Co(2)-O(2) bond lengths are 1.93 Å. All Co(2)-O(4) bond lengths are 1.93 Å. In the third Co site, Co(3) is bonded to two equivalent O(8) and four equivalent O(10) atoms to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with four equivalent Li(5)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with four equivalent Li(4)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles are 5°. Both Co(3)-O(8) bond lengths are 1.91 Å. All Co(3)-O(10) bond lengths are 1.95 Å. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(3), one O(7), two equivalent O(1), and two equivalent O(5) atoms to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. The Ni(1)-O(3) bond length is 2.04 Å. The Ni(1)-O(7) bond length is 2.10 Å. Both Ni(1)-O(1) bond lengths are 2.00 Å. Both Ni(1)-O(5) bond lengths are 1.98 Å. In the second Ni site, Ni(2) is bonded to one O(5), one O(9), two equivalent O(6), and two equivalent O(7) atoms to form NiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. The Ni(2)-O(5) bond length is 1.86 Å. The Ni(2)-O(9) bond length is 1.92 Å. Both Ni(2)-O(6) bond lengths are 1.98 Å. Both Ni(2)-O(7) bond lengths are 1.98 Å. In the third Ni site, Ni(3) is bonded to one O(10), one O(6), two equivalent O(8), and two equivalent O(9) atoms to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with five equivalent Li(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Ni(3)-O(10) bond length is 2.07 Å. The Ni(3)-O(6) bond length is 2.06 Å. Both Ni(3)-O(8) bond lengths are 1.98 Å. Both Ni(3)-O(9) bond lengths are 1.98 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), two equivalent Li(2), one Co(1), and two equivalent Ni(1) atoms to form OLi3CoNi2 octahedra that share  a cornercorner with one O(8)Li3CoNi2 octahedra,  a cornercorner with one O(4)Li2Co3 square pyramid, corners with four equivalent O(5)Li2Ni3 square pyramids, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), and two equivalent Co(1) atoms. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), two equivalent Co(1), and one Ni(1) atom. In the fourth O site, O(4) is bonded to two equivalent Li(1), one Co(1), and two equivalent Co(2) atoms to form OLi2Co3 square pyramids that share  a cornercorner with one O(1)Li3CoNi2 octahedra, corners with four equivalent O(4)Li2Co3 square pyramids, and edges with four equivalent O(4)Li2Co3 square pyramids. The corner-sharing octahedral tilt angles are 2°. In the fifth O site, O(5) is bonded to two equivalent Li(2), one Ni(2), and two equivalent Ni(1) atoms to form OLi2Ni3 square pyramids that share  a cornercorner with one O(9)Li3Ni3 octahedra, corners with four equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 1-8°. In the sixth O site, O(6) is bonded to one Li(2), two equivalent Li(3), one Ni(3), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(10)Li3Co2Ni octahedra, corners with four equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded to one Li(4), two equivalent Li(3), one Ni(1), and two equivalent Ni(2) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(10)Li3Co2Ni octahedra, corners with four equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(1)Li3CoNi2 octahedra, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with two equivalent O(5)Li2Ni3 square pyramids. The corner-sharing octahedral tilt angles range from 0-2°. In the eighth O site, O(8) is bonded to one Li(3), two equivalent Li(4), one Co(3), and two equivalent Ni(3) atoms to form OLi3CoNi2 octahedra that share  a cornercorner with one O(1)Li3CoNi2 octahedra,  a cornercorner with one O(8)Li3CoNi2 octahedra, corners with four equivalent O(9)Li3Ni3 octahedra, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with four equivalent O(10)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the ninth O site, O(9) is bonded to one Li(5), two equivalent Li(4), one Ni(2), and two equivalent Ni(3) atoms to form OLi3Ni3 octahedra that share  a cornercorner with one O(9)Li3Ni3 octahedra, corners with four equivalent O(8)Li3CoNi2 octahedra,  a cornercorner with one O(5)Li2Ni3 square pyramid, edges with two equivalent O(8)Li3CoNi2 octahedra, edges with two equivalent O(6)Li3Ni3 octahedra, edges with two equivalent O(7)Li3Ni3 octahedra, edges with two equivalent O(9)Li3Ni3 octahedra, and edges with four equivalent O(10)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Li(5), two equivalent Co(3), and one Ni(3) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(7)Li3Ni3 octahedra, corners with four equivalent O(10)Li3Co2Ni octahedra, edges with four equivalent O(10)Li3Co2Ni octahedra, edges with four equivalent O(8)Li3CoNi2 octahedra, and edges with four equivalent O(9)Li3Ni3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°.