CoN4ClN2SnCl4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four tin tetrachloride molecules, and four CoN4Cl clusters. In each CoN4Cl cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(5), and one N(6) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Co(1) and one Cl(5) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(6) is bonded in a single-bond geometry to one Co(1) atom. Cl(5) is bonded in a single-bond geometry to one N(1) atom.
CoN4ClN2SnCl4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four tin tetrachloride molecules, and four CoN4Cl clusters. In each CoN4Cl cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(5), and one N(6) atom. The Co(1)-N(1) bond length is 1.86 Å. The Co(1)-N(3) bond length is 1.66 Å. The Co(1)-N(5) bond length is 1.61 Å. The Co(1)-N(6) bond length is 1.61 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Co(1) and one Cl(5) atom. The N(1)-Cl(5) bond length is 1.64 Å. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(6) is bonded in a single-bond geometry to one Co(1) atom. Cl(5) is bonded in a single-bond geometry to one N(1) atom.