CN2H4S is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four thiourea molecules. C(1) is bonded in a distorted trigonal planar geometry to two equivalent N(1) and one S(1) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom.
CN2H4S is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four thiourea molecules. C(1) is bonded in a distorted trigonal planar geometry to two equivalent N(1) and one S(1) atom. Both C(1)-N(1) bond lengths are 1.34 Å. The C(1)-S(1) bond length is 1.72 Å. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.02 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom.