AuPbO2 crystallizes in the hexagonal P6_3/mmc space group. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. O(1) is bonded to one Au(1) and three equivalent Pb(1) atoms to form a mixture of corner and edge-sharing OPb3Au tetrahedra.
AuPbO2 crystallizes in the hexagonal P6_3/mmc space group. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Au(1)-O(1) bond lengths are 2.01 Å. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. All Pb(1)-O(1) bond lengths are 2.44 Å. O(1) is bonded to one Au(1) and three equivalent Pb(1) atoms to form a mixture of corner and edge-sharing OPb3Au tetrahedra.