CsGdO2 is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Gd(1) is bonded to six equivalent O(1) atoms to form edge-sharing GdO6 octahedra. O(1) is bonded to three equivalent Cs(1) and three equivalent Gd(1) atoms to form a mixture of distorted face, corner, and edge-sharing OCs3Gd3 octahedra. The corner-sharing octahedral tilt angles range from 0-39°.
CsGdO2 is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Cs(1)-O(1) bond lengths are 3.08 Å. Gd(1) is bonded to six equivalent O(1) atoms to form edge-sharing GdO6 octahedra. All Gd(1)-O(1) bond lengths are 2.37 Å. O(1) is bonded to three equivalent Cs(1) and three equivalent Gd(1) atoms to form a mixture of distorted face, corner, and edge-sharing OCs3Gd3 octahedra. The corner-sharing octahedral tilt angles range from 0-39°.