Ti4(FeO4)3 crystallizes in the cubic Im-3 space group. Ti(1) is bonded to six equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 35°. Fe(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to two equivalent Ti(1) and one Fe(1) atom.
Ti4(FeO4)3 crystallizes in the cubic Im-3 space group. Ti(1) is bonded to six equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 35°. All Ti(1)-O(1) bond lengths are 1.96 Å. Fe(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Fe(1)-O(1) bond lengths are 2.06 Å. O(1) is bonded in a 3-coordinate geometry to two equivalent Ti(1) and one Fe(1) atom.