Cr2O5F2 is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of four Cr2O5F2 clusters. Cr(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form corner-sharing CrO3F tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Cr(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cr(1) atom. F(1) is bonded in a single-bond geometry to one Cr(1) atom.
Cr2O5F2 is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of four Cr2O5F2 clusters. Cr(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form corner-sharing CrO3F tetrahedra. The Cr(1)-O(1) bond length is 1.78 Å. The Cr(1)-O(2) bond length is 1.60 Å. The Cr(1)-O(3) bond length is 1.58 Å. The Cr(1)-F(1) bond length is 1.73 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Cr(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cr(1) atom. F(1) is bonded in a single-bond geometry to one Cr(1) atom.