ZrCo4Al is Hexagonal Laves-derived structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded in a 16-coordinate geometry to twelve equivalent Co(1) and four equivalent Al(1) atoms. Co(1) is bonded to three equivalent Zr(1), six equivalent Co(1), and three equivalent Al(1) atoms to form a mixture of face, corner, and edge-sharing CoZr3Al3Co6 cuboctahedra. Al(1) is bonded in a 16-coordinate geometry to four equivalent Zr(1) and twelve equivalent Co(1) atoms.
ZrCo4Al is Hexagonal Laves-derived structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded in a 16-coordinate geometry to twelve equivalent Co(1) and four equivalent Al(1) atoms. All Zr(1)-Co(1) bond lengths are 2.80 Å. All Zr(1)-Al(1) bond lengths are 2.93 Å. Co(1) is bonded to three equivalent Zr(1), six equivalent Co(1), and three equivalent Al(1) atoms to form a mixture of face, corner, and edge-sharing CoZr3Al3Co6 cuboctahedra. There are three shorter (2.36 Å) and three longer (2.42 Å) Co(1)-Co(1) bond lengths. All Co(1)-Al(1) bond lengths are 2.80 Å. Al(1) is bonded in a 16-coordinate geometry to four equivalent Zr(1) and twelve equivalent Co(1) atoms.