NaRh(NO2)6N2 crystallizes in the monoclinic Cm space group. The structure consists of four ammonia atoms inside a NaRh(NO2)6 framework. In the NaRh(NO2)6 framework, Na(1) is bonded in a cuboctahedral geometry to one O(3), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. Rh(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(4), one N(5), and two equivalent N(3) atoms. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Rh(1), one O(3), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent O(1) atoms. In the third N site, N(3) is bonded in a trigonal planar geometry to one Rh(1), one O(2), and one O(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Rh(1), one O(6), and one O(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent O(4) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Na(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Na(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Na(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Na(1) and one N(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Na(1) and one N(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Na(1) and one N(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(1) and one N(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Na(1) and one N(4) atom.
NaRh(NO2)6N2 crystallizes in the monoclinic Cm space group. The structure consists of four ammonia atoms inside a NaRh(NO2)6 framework. In the NaRh(NO2)6 framework, Na(1) is bonded in a cuboctahedral geometry to one O(3), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. The Na(1)-O(3) bond length is 2.93 Å. The Na(1)-O(6) bond length is 2.93 Å. The Na(1)-O(7) bond length is 2.88 Å. The Na(1)-O(8) bond length is 2.88 Å. Both Na(1)-O(1) bond lengths are 2.90 Å. Both Na(1)-O(2) bond lengths are 2.90 Å. Both Na(1)-O(4) bond lengths are 2.90 Å. Both Na(1)-O(5) bond lengths are 2.90 Å. Rh(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(4), one N(5), and two equivalent N(3) atoms. The Rh(1)-N(1) bond length is 2.12 Å. The Rh(1)-N(2) bond length is 2.12 Å. The Rh(1)-N(4) bond length is 2.13 Å. The Rh(1)-N(5) bond length is 2.13 Å. Both Rh(1)-N(3) bond lengths are 2.13 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Rh(1), one O(3), and one O(7) atom. The N(1)-O(3) bond length is 1.23 Å. The N(1)-O(7) bond length is 1.23 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent O(1) atoms. Both N(2)-O(1) bond lengths are 1.23 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Rh(1), one O(2), and one O(5) atom. The N(3)-O(2) bond length is 1.23 Å. The N(3)-O(5) bond length is 1.23 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Rh(1), one O(6), and one O(8) atom. The N(4)-O(6) bond length is 1.23 Å. The N(4)-O(8) bond length is 1.23 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Rh(1) and two equivalent O(4) atoms. Both N(5)-O(4) bond lengths are 1.23 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Na(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Na(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Na(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Na(1) and one N(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Na(1) and one N(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Na(1) and one N(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(1) and one N(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Na(1) and one N(4) atom.