SO2F2 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of four sulfuryl fluoride molecules. S(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent F(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom.
SO2F2 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of four sulfuryl fluoride molecules. S(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent F(1) atoms. Both S(1)-O(1) bond lengths are 1.40 Å. Both S(1)-F(1) bond lengths are 1.55 Å. O(1) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom.