VCr2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with twelve equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with six equivalent Cr(1)O6 octahedra. O(1) is bonded to one V(1) and three equivalent Cr(1) atoms to form a mixture of distorted corner and edge-sharing OVCr3 trigonal pyramids.
VCr2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with twelve equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 58°. All V(1)-O(1) bond lengths are 2.00 Å. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with six equivalent Cr(1)O6 octahedra. All Cr(1)-O(1) bond lengths are 2.06 Å. O(1) is bonded to one V(1) and three equivalent Cr(1) atoms to form a mixture of distorted corner and edge-sharing OVCr3 trigonal pyramids.