YH5S3O13 crystallizes in the triclinic P-1 space group. Y(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(5) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(11) and one O(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(11) and one O(13) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(5), and one O(7) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(10), one O(3), one O(6), and one O(8) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(13), one O(2), one O(4), and one O(9) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Y(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one H(1) and one S(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one H(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Y(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Y(1) and one S(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one H(2) and one S(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one H(2), one H(5), and one S(1) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Y(1), one H(3), and one H(4) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one H(5) and one S(3) atom.
YH5S3O13 crystallizes in the triclinic P-1 space group. Y(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. The Y(1)-O(1) bond length is 2.44 Å. The Y(1)-O(10) bond length is 2.38 Å. The Y(1)-O(12) bond length is 2.37 Å. The Y(1)-O(2) bond length is 2.40 Å. The Y(1)-O(3) bond length is 2.35 Å. The Y(1)-O(6) bond length is 2.31 Å. The Y(1)-O(7) bond length is 2.31 Å. The Y(1)-O(9) bond length is 2.36 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(5) atom. The H(1)-O(4) bond length is 1.60 Å. The H(1)-O(5) bond length is 1.02 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(11) and one O(8) atom. The H(2)-O(11) bond length is 1.69 Å. The H(2)-O(8) bond length is 1.01 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. The H(3)-O(12) bond length is 0.98 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. The H(4)-O(12) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(11) and one O(13) atom. The H(5)-O(11) bond length is 1.67 Å. The H(5)-O(13) bond length is 1.02 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(5), and one O(7) atom. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(11) bond length is 1.48 Å. The S(1)-O(5) bond length is 1.57 Å. The S(1)-O(7) bond length is 1.46 Å. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(10), one O(3), one O(6), and one O(8) atom. The S(2)-O(10) bond length is 1.46 Å. The S(2)-O(3) bond length is 1.46 Å. The S(2)-O(6) bond length is 1.46 Å. The S(2)-O(8) bond length is 1.57 Å. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(13), one O(2), one O(4), and one O(9) atom. The S(3)-O(13) bond length is 1.58 Å. The S(3)-O(2) bond length is 1.45 Å. The S(3)-O(4) bond length is 1.48 Å. The S(3)-O(9) bond length is 1.47 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Y(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one H(1) and one S(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one H(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Y(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Y(1) and one S(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one H(2) and one S(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one H(2), one H(5), and one S(1) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Y(1), one H(3), and one H(4) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one H(5) and one S(3) atom.