SrHBr is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Sr(1) is bonded in a 9-coordinate geometry to four equivalent H(1) and five equivalent Br(1) atoms. H(1) is bonded to four equivalent Sr(1) atoms to form a mixture of edge and corner-sharing HSr4 tetrahedra. Br(1) is bonded in a 5-coordinate geometry to five equivalent Sr(1) atoms.
SrHBr is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Sr(1) is bonded in a 9-coordinate geometry to four equivalent H(1) and five equivalent Br(1) atoms. All Sr(1)-H(1) bond lengths are 2.52 Å. There are four shorter (3.22 Å) and one longer (3.40 Å) Sr(1)-Br(1) bond length. H(1) is bonded to four equivalent Sr(1) atoms to form a mixture of edge and corner-sharing HSr4 tetrahedra. Br(1) is bonded in a 5-coordinate geometry to five equivalent Sr(1) atoms.