Al3Li is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. Li(1) is bonded to twelve equivalent Al(1) atoms to form LiAl12 cuboctahedra that share corners with twelve equivalent Li(1)Al12 cuboctahedra, edges with twenty-four equivalent Al(1)Li4Al8 cuboctahedra, faces with six equivalent Li(1)Al12 cuboctahedra, and faces with twelve equivalent Al(1)Li4Al8 cuboctahedra. Al(1) is bonded to four equivalent Li(1) and eight equivalent Al(1) atoms to form distorted AlLi4Al8 cuboctahedra that share corners with twelve equivalent Al(1)Li4Al8 cuboctahedra, edges with eight equivalent Li(1)Al12 cuboctahedra, edges with sixteen equivalent Al(1)Li4Al8 cuboctahedra, faces with four equivalent Li(1)Al12 cuboctahedra, and faces with fourteen equivalent Al(1)Li4Al8 cuboctahedra.
Al3Li is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. Li(1) is bonded to twelve equivalent Al(1) atoms to form LiAl12 cuboctahedra that share corners with twelve equivalent Li(1)Al12 cuboctahedra, edges with twenty-four equivalent Al(1)Li4Al8 cuboctahedra, faces with six equivalent Li(1)Al12 cuboctahedra, and faces with twelve equivalent Al(1)Li4Al8 cuboctahedra. All Li(1)-Al(1) bond lengths are 2.83 Å. Al(1) is bonded to four equivalent Li(1) and eight equivalent Al(1) atoms to form distorted AlLi4Al8 cuboctahedra that share corners with twelve equivalent Al(1)Li4Al8 cuboctahedra, edges with eight equivalent Li(1)Al12 cuboctahedra, edges with sixteen equivalent Al(1)Li4Al8 cuboctahedra, faces with four equivalent Li(1)Al12 cuboctahedra, and faces with fourteen equivalent Al(1)Li4Al8 cuboctahedra. All Al(1)-Al(1) bond lengths are 2.83 Å.