AuSbAsF9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuSbAsF9 clusters. Au(1) is bonded in a distorted linear geometry to one As(1) and one F(3) atom. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(7), and one F(8) atom. As(1) is bonded in a 3-coordinate geometry to one Au(1), one F(4), one F(6), and one F(9) atom. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one As(1) atom.
AuSbAsF9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuSbAsF9 clusters. Au(1) is bonded in a distorted linear geometry to one As(1) and one F(3) atom. The Au(1)-As(1) bond length is 2.32 Å. The Au(1)-F(3) bond length is 2.17 Å. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(7), and one F(8) atom. The Sb(1)-F(1) bond length is 1.91 Å. The Sb(1)-F(2) bond length is 1.92 Å. The Sb(1)-F(3) bond length is 2.00 Å. The Sb(1)-F(5) bond length is 1.90 Å. The Sb(1)-F(7) bond length is 1.92 Å. The Sb(1)-F(8) bond length is 1.92 Å. As(1) is bonded in a 3-coordinate geometry to one Au(1), one F(4), one F(6), and one F(9) atom. The As(1)-F(4) bond length is 1.73 Å. The As(1)-F(6) bond length is 1.73 Å. The As(1)-F(9) bond length is 1.72 Å. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one As(1) atom.