WTeBr9 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two WTeBr9 clusters. W(1) is bonded to one Br(2), one Br(4), two equivalent Br(1), and two equivalent Br(5) atoms to form WBr6 octahedra that share  a faceface with one Te(1)Br6 octahedra. Te(1) is bonded to one Br(3), one Br(4), two equivalent Br(1), and two equivalent Br(6) atoms to form distorted TeBr6 octahedra that share  a faceface with one W(1)Br6 octahedra. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom.
WTeBr9 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two WTeBr9 clusters. W(1) is bonded to one Br(2), one Br(4), two equivalent Br(1), and two equivalent Br(5) atoms to form WBr6 octahedra that share  a faceface with one Te(1)Br6 octahedra. The W(1)-Br(2) bond length is 2.44 Å. The W(1)-Br(4) bond length is 2.61 Å. Both W(1)-Br(1) bond lengths are 2.60 Å. Both W(1)-Br(5) bond lengths are 2.44 Å. Te(1) is bonded to one Br(3), one Br(4), two equivalent Br(1), and two equivalent Br(6) atoms to form distorted TeBr6 octahedra that share  a faceface with one W(1)Br6 octahedra. The Te(1)-Br(3) bond length is 2.56 Å. The Te(1)-Br(4) bond length is 3.03 Å. Both Te(1)-Br(1) bond lengths are 3.02 Å. Both Te(1)-Br(6) bond lengths are 2.55 Å. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in an L-shaped geometry to one W(1) and one Te(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom.