InO2 is Marcasite structured and crystallizes in the orthorhombic Pnnm space group. In(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles are 60°. O(1) is bonded in a trigonal planar geometry to three equivalent In(1) atoms.
InO2 is Marcasite structured and crystallizes in the orthorhombic Pnnm space group. In(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles are 60°. There are two shorter (2.19 Å) and four longer (2.21 Å) In(1)-O(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent In(1) atoms.