AgNTeO5 crystallizes in the orthorhombic Pbcn space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a trigonal planar geometry to one O(3) and two equivalent O(2) atoms. Te(1) is bonded in a distorted see-saw-like geometry to four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ag(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Ag(1) and one N(1) atom.
AgNTeO5 crystallizes in the orthorhombic Pbcn space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Ag(1)-O(1) bond lengths are 2.36 Å. Both Ag(1)-O(2) bond lengths are 2.67 Å. Both Ag(1)-O(3) bond lengths are 2.75 Å. N(1) is bonded in a trigonal planar geometry to one O(3) and two equivalent O(2) atoms. The N(1)-O(3) bond length is 1.29 Å. Both N(1)-O(2) bond lengths are 1.26 Å. Te(1) is bonded in a distorted see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (1.96 Å) and two longer (2.12 Å) Te(1)-O(1) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ag(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Ag(1) and one N(1) atom.