LiVSiO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent V(1)O4 tetrahedra. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom.
LiVSiO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. All Li(1)-O(1) bond lengths are 2.08 Å. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. All V(1)-O(1) bond lengths are 1.94 Å. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent V(1)O4 tetrahedra. All Si(1)-O(1) bond lengths are 1.65 Å. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom.