CsNH2SO3 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1) and one S(1) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom.
CsNH2SO3 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. There is one shorter (3.07 Å) and two longer (3.52 Å) Cs(1)-O(1) bond lengths. All Cs(1)-O(2) bond lengths are 3.33 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1) and one S(1) atom. Both N(1)-H(1) bond lengths are 1.02 Å. The N(1)-S(1) bond length is 1.71 Å. H(1) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. The S(1)-O(1) bond length is 1.47 Å. Both S(1)-O(2) bond lengths are 1.47 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom.