TiO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbca space group. Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 21-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a T-shaped geometry to three equivalent Ti(1) atoms.
TiO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbca space group. Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 21-56°. There are a spread of Ti(1)-O(1) bond distances ranging from 1.92-2.05 Å. There are a spread of Ti(1)-O(2) bond distances ranging from 1.87-2.00 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a T-shaped geometry to three equivalent Ti(1) atoms.