(FeBr4)2FeC6(NBr)6(BrCN)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two cyanogen bromide molecules, two tetrabromoiron molecules, and one FeC6(NBr)6 cluster. In the FeC6(NBr)6 cluster, Fe(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent N(4) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(4) and one Br(3) atom. In the second C site, C(3) is bonded in a linear geometry to one N(2) and one Br(8) atom. In the third C site, C(4) is bonded in a linear geometry to one N(3) and one Br(2) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a linear geometry to one Fe(2) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Fe(2) and one C(3) atom. In the third N site, N(3) is bonded in a linear geometry to one Fe(2) and one C(4) atom. There are three inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one C(4) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one C(1) atom. In the third Br site, Br(8) is bonded in a single-bond geometry to one C(3) atom.
(FeBr4)2FeC6(NBr)6(BrCN)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two cyanogen bromide molecules, two tetrabromoiron molecules, and one FeC6(NBr)6 cluster. In the FeC6(NBr)6 cluster, Fe(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent N(4) atoms. Both Fe(2)-N(2) bond lengths are 1.94 Å. Both Fe(2)-N(3) bond lengths are 1.93 Å. Both Fe(2)-N(4) bond lengths are 1.95 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(4) and one Br(3) atom. The C(1)-N(4) bond length is 1.17 Å. The C(1)-Br(3) bond length is 1.79 Å. In the second C site, C(3) is bonded in a linear geometry to one N(2) and one Br(8) atom. The C(3)-N(2) bond length is 1.17 Å. The C(3)-Br(8) bond length is 1.79 Å. In the third C site, C(4) is bonded in a linear geometry to one N(3) and one Br(2) atom. The C(4)-N(3) bond length is 1.17 Å. The C(4)-Br(2) bond length is 1.79 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a linear geometry to one Fe(2) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Fe(2) and one C(3) atom. In the third N site, N(3) is bonded in a linear geometry to one Fe(2) and one C(4) atom. There are three inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one C(4) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one C(1) atom. In the third Br site, Br(8) is bonded in a single-bond geometry to one C(3) atom.