TiFePbBiO6 crystallizes in the orthorhombic Imm2 space group. Ti(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Fe(1) is bonded in a distorted trigonal bipyramidal geometry to one O(3) and four equivalent O(1) atoms. Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ti(1), one Fe(1), one Pb(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ti(1) and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a single-bond geometry to one Fe(1) and two equivalent Pb(1) atoms.
TiFePbBiO6 crystallizes in the orthorhombic Imm2 space group. Ti(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. The Ti(1)-O(2) bond length is 1.76 Å. All Ti(1)-O(1) bond lengths are 1.98 Å. Fe(1) is bonded in a distorted trigonal bipyramidal geometry to one O(3) and four equivalent O(1) atoms. The Fe(1)-O(3) bond length is 1.85 Å. All Fe(1)-O(1) bond lengths are 2.03 Å. Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. Both Pb(1)-O(2) bond lengths are 2.82 Å. Both Pb(1)-O(3) bond lengths are 2.78 Å. All Pb(1)-O(1) bond lengths are 2.55 Å. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Bi(1)-O(1) bond lengths are 2.29 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ti(1), one Fe(1), one Pb(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ti(1) and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a single-bond geometry to one Fe(1) and two equivalent Pb(1) atoms.