TiOF crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing TiO4F2 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a square co-planar geometry to four equivalent Ti(1) atoms. F(1) is bonded in a linear geometry to two equivalent Ti(1) atoms.
TiOF crystallizes in the tetragonal P4/mmm space group. Ti(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing TiO4F2 octahedra. The corner-sharing octahedra are not tilted. All Ti(1)-O(1) bond lengths are 2.02 Å. Both Ti(1)-F(1) bond lengths are 1.97 Å. O(1) is bonded in a square co-planar geometry to four equivalent Ti(1) atoms. F(1) is bonded in a linear geometry to two equivalent Ti(1) atoms.