Li2CoN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to four equivalent N(1) atoms. Co(1) is bonded to six equivalent N(1) atoms to form distorted edge-sharing CoN6 octahedra. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Co(1) atoms.
Li2CoN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to four equivalent N(1) atoms. There are three shorter (1.92 Å) and one longer (2.36 Å) Li(1)-N(1) bond length. Co(1) is bonded to six equivalent N(1) atoms to form distorted edge-sharing CoN6 octahedra. All Co(1)-N(1) bond lengths are 2.01 Å. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Co(1) atoms.