NaAg3O2 crystallizes in the orthorhombic Ibam space group. Na(1) is bonded to four equivalent O(1) atoms to form distorted edge-sharing NaO4 tetrahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to two equivalent Na(1), one Ag(2), and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Ag3 trigonal bipyramids.
NaAg3O2 crystallizes in the orthorhombic Ibam space group. Na(1) is bonded to four equivalent O(1) atoms to form distorted edge-sharing NaO4 tetrahedra. All Na(1)-O(1) bond lengths are 2.28 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.10 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(2)-O(1) bond lengths are 2.11 Å. O(1) is bonded to two equivalent Na(1), one Ag(2), and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Ag3 trigonal bipyramids.