HgHOF crystallizes in the orthorhombic P2_12_12_1 space group. Hg(1) is bonded to two equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing HgO2F3 square pyramids. H(1) is bonded in a linear geometry to one O(1) and one F(1) atom. O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Hg(1) and one H(1) atom. F(1) is bonded in a distorted single-bond geometry to three equivalent Hg(1) and one H(1) atom.
HgHOF crystallizes in the orthorhombic P2_12_12_1 space group. Hg(1) is bonded to two equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing HgO2F3 square pyramids. Both Hg(1)-O(1) bond lengths are 2.14 Å. There are a spread of Hg(1)-F(1) bond distances ranging from 2.55-2.57 Å. H(1) is bonded in a linear geometry to one O(1) and one F(1) atom. The H(1)-O(1) bond length is 1.03 Å. The H(1)-F(1) bond length is 1.48 Å. O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Hg(1) and one H(1) atom. F(1) is bonded in a distorted single-bond geometry to three equivalent Hg(1) and one H(1) atom.