AgPb2OCl3F crystallizes in the tetragonal I4_1md space group. Ag(1) is bonded to one Cl(1), one Cl(2), and four equivalent Cl(3) atoms to form corner-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 43-47°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent F(1) atoms. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to two equivalent O(1), one Cl(1), and one F(1) atom. O(1) is bonded in a trigonal non-coplanar geometry to one Pb(1) and two equivalent Pb(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Pb(2) atoms. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms. F(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(2) and two equivalent Pb(1) atoms.
AgPb2OCl3F crystallizes in the tetragonal I4_1md space group. Ag(1) is bonded to one Cl(1), one Cl(2), and four equivalent Cl(3) atoms to form corner-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 43-47°. The Ag(1)-Cl(1) bond length is 2.72 Å. The Ag(1)-Cl(2) bond length is 2.71 Å. There are two shorter (2.76 Å) and two longer (2.77 Å) Ag(1)-Cl(3) bond lengths. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 3-coordinate geometry to one O(1) and two equivalent F(1) atoms. The Pb(1)-O(1) bond length is 2.34 Å. Both Pb(1)-F(1) bond lengths are 2.40 Å. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to two equivalent O(1), one Cl(1), and one F(1) atom. Both Pb(2)-O(1) bond lengths are 2.31 Å. The Pb(2)-Cl(1) bond length is 3.16 Å. The Pb(2)-F(1) bond length is 2.59 Å. O(1) is bonded in a trigonal non-coplanar geometry to one Pb(1) and two equivalent Pb(2) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Pb(2) atoms. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms. F(1) is bonded in a distorted trigonal non-coplanar geometry to one Pb(2) and two equivalent Pb(1) atoms.