KTaF6 crystallizes in the tetragonal P-4c2 space group. K(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(2) atoms. Ta(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Ta(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to two equivalent K(1) and one Ta(1) atom.
KTaF6 crystallizes in the tetragonal P-4c2 space group. K(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(2) atoms. All K(1)-F(1) bond lengths are 3.08 Å. All K(1)-F(2) bond lengths are 2.63 Å. Ta(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. Both Ta(1)-F(1) bond lengths are 1.93 Å. All Ta(1)-F(2) bond lengths are 1.93 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Ta(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to two equivalent K(1) and one Ta(1) atom.