Li5Mn3(SbO5)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(19), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Li(9)O5 square pyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 8-11°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and  an edgeedge with one Li(10)O5 square pyramid. The corner-sharing octahedral tilt angles range from 10-13°. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(12), one O(13), one O(17), one O(19), and one O(4) atom. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(14), one O(18), one O(20), and one O(3) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(15), one O(17), one O(19), and one O(2) atom. In the sixth Li site, Li(6) is bonded to one O(1), one O(12), one O(16), one O(18), one O(20), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(10)O5 square pyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-16°. In the seventh Li site, Li(7) is bonded to one O(1), one O(15), one O(17), one O(5), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-85°. In the eighth Li site, Li(8) is bonded to one O(10), one O(16), one O(18), one O(2), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-20°. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(19), one O(3), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-87°. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(20), one O(4), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and edges with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-85°. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(15), one O(2), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, and  an edgeedge with one Li(9)O5 square pyramid. The corner-sharing octahedral tilt angles range from 1-15°. In the second Mn site, Mn(2) is bonded to one O(1), one O(16), one O(18), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(10)O5 square pyramids,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-16°. In the third Mn site, Mn(3) is bonded to one O(1), one O(13), one O(19), one O(4), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  a cornercorner with one Li(9)O5 square pyramid, corners with two equivalent Li(7)O5 trigonal bipyramids,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and  an edgeedge with one Li(9)O5 square pyramid. The corner-sharing octahedral tilt angles range from 7-14°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(13), one O(16), one O(4), one O(5), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(10)O5 square pyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-15°. In the fifth Mn site, Mn(5) is bonded to one O(15), one O(17), one O(2), one O(3), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Li(9)O5 square pyramids,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 9-15°. In the sixth Mn site, Mn(6) is bonded to one O(14), one O(2), one O(20), one O(3), one O(6), and one O(8) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  a cornercorner with one Li(9)O5 square pyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(10)O5 square pyramid. The corner-sharing octahedral tilt angles range from 9-20°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(12), one O(16), one O(17), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Li(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the second Sb site, Sb(2) is bonded to one O(10), one O(11), one O(15), one O(18), one O(2), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and edges with two equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the third Sb site, Sb(3) is bonded to one O(10), one O(11), one O(14), one O(19), one O(3), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Li(9)O5 square pyramids. The corner-sharing octahedral tilt angles range from 1-10°. In the fourth Sb site, Sb(4) is bonded to one O(12), one O(13), one O(20), one O(4), one O(8), and one O(9) atom to form distorted SbO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with two equivalent Li(10)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-12°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(6), one Li(7), one Mn(2), one Mn(3), one Mn(4), and one Sb(1) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and edges with two equivalent O(5)LiMn3Sb square pyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the second O site, O(2) is bonded to one Li(5), one Li(8), one Mn(1), one Mn(5), one Mn(6), and one Sb(2) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(5)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(7)LiMn3Sb square pyramid, and edges with two equivalent O(6)LiMn3Sb square pyramids. The corner-sharing octahedral tilt angles range from 3-21°. In the third O site, O(3) is bonded to one Li(4), one Li(9), one Mn(1), one Mn(5), one Mn(6), and one Sb(3) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra,  a cornercorner with one O(5)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(6)LiMn3Sb square pyramid, and edges with two equivalent O(7)LiMn3Sb square pyramids. The corner-sharing octahedral tilt angles range from 1-20°. In the fourth O site, O(4) is bonded to one Li(10), one Li(3), one Mn(2), one Mn(3), one Mn(4), and one Sb(4) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(8)Li2Mn3Sb octahedra, edges with two equivalent O(13)Li3Mn2Sb octahedra, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-20°. In the fifth O site, O(5) is bonded to one Li(7), one Mn(3), one Mn(4), one Mn(5), and one Sb(1) atom to form OLiMn3Sb square pyramids that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra, edges with two equivalent O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-87°. In the sixth O site, O(6) is bonded to one Li(8), one Mn(1), one Mn(2), one Mn(6), and one Sb(2) atom to form OLiMn3Sb square pyramids that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and edges with two equivalent O(2)Li2Mn3Sb octahedra. The corner-sharing octahedral tilt angles range from 6-83°. In the seventh O site, O(7) is bonded to one Li(9), one Mn(1), one Mn(3), one Mn(5), and one Sb(3) atom to form OLiMn3Sb square pyramids that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Mn3Sb octahedra, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 8-83°. In the eighth O site, O(8) is bonded to one Li(10), one Li(8), one Mn(2), one Mn(4), one Mn(6), and one Sb(4) atom to form distorted OLi2Mn3Sb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Mn3Sb octahedra, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 4-24°. In the ninth O site, O(9) is bonded to one Li(1), one Li(6), one Li(7), one Sb(1), and one Sb(4) atom to form distorted OLi3Sb2 square pyramids that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 4-89°. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Li(5), one Li(8), one Sb(2), and one Sb(3) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra, edges with two equivalent O(18)Li4MnSb octahedra, edges with two equivalent O(11)Li4Sb2 octahedra, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-19°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Li(5), one Li(9), one Sb(2), and one Sb(3) atom to form distorted OLi4Sb2 octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra, edges with two equivalent O(19)Li4MnSb octahedra, edges with two equivalent O(10)Li4Sb2 octahedra, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-17°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(2), one Li(3), one Li(6), one Sb(1), and one Sb(4) atom to form distorted OLi4Sb2 octahedra that share  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra, edges with two equivalent O(20)Li4MnSb octahedra, and  an edgeedge with one O(9)Li3Sb2 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(9), one Mn(3), one Mn(4), and one Sb(4) atom to form distorted OLi3Mn2Sb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra, corners with two equivalent O(5)LiMn3Sb square pyramids,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Mn3Sb octahedra, edges with two equivalent O(19)Li4MnSb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-12°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(2), one Li(4), one Mn(1), one Mn(6), and one Sb(3) atom to form distorted OLi3Mn2Sb octahedra that share  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(6)LiMn3Sb square pyramids,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Mn3Sb octahedra, edges with two equivalent O(20)Li4MnSb octahedra, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-19°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Li(7), one Mn(1), one Mn(5), and one Sb(2) atom to form distorted OLi3Mn2Sb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(7)LiMn3Sb square pyramids,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(2)Li2Mn3Sb octahedra, edges with two equivalent O(17)Li4MnSb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid,  an edgeedge with one O(5)LiMn3Sb square pyramid, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-19°. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Li(8), one Mn(2), one Mn(4), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(1)Li2Mn3Sb octahedra, edges with two equivalent O(18)Li4MnSb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid,  an edgeedge with one O(5)LiMn3Sb square pyramid, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 2-17°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(5), and one Sb(1) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-20°. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(2), and one Sb(2) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(16)Li3Mn2Sb octahedra, edges with two equivalent O(10)Li4Sb2 octahedra, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 4-20°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(3), and one Sb(3) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, edges with two equivalent O(13)Li3Mn2Sb octahedra, edges with two equivalent O(11)Li4Sb2 octahedra, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-21°. In the twentieth O site, O(20) is bonded to one Li(10), one Li(2), one Li(4), one Li(6), one Mn(6), and one Sb(4) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, edges with two equivalent O(14)Li3Mn2Sb octahedra, edges with two equivalent O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li3Sb2 square pyramid. The corner-sharing octahedral tilt angles range from 3-24°.
Li5Mn3(SbO5)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(17), one O(19), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra,  an edgeedge with one Li(9)O5 square pyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 8-11°. The Li(1)-O(11) bond length is 2.19 Å. The Li(1)-O(13) bond length is 2.12 Å. The Li(1)-O(15) bond length is 2.44 Å. The Li(1)-O(17) bond length is 2.31 Å. The Li(1)-O(19) bond length is 2.30 Å. The Li(1)-O(9) bond length is 2.17 Å. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(18), and one O(20) atom to form LiO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and  an edgeedge with one Li(10)O5 square pyramid. The corner-sharing octahedral tilt angles range from 10-13°. The Li(2)-O(10) bond length is 2.20 Å. The Li(2)-O(12) bond length is 2.13 Å. The Li(2)-O(14) bond length is 2.38 Å. The Li(2)-O(16) bond length is 2.20 Å. The Li(2)-O(18) bond length is 2.20 Å. The Li(2)-O(20) bond length is 2.39 Å. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(12), one O(13), one O(17), one O(19), and one O(4) atom. The Li(3)-O(12) bond length is 2.45 Å. The Li(3)-O(13) bond length is 2.01 Å. The Li(3)-O(17) bond length is 2.15 Å. The Li(3)-O(19) bond length is 2.24 Å. The Li(3)-O(4) bond length is 2.23 Å. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(14), one O(18), one O(20), and one O(3) atom. The Li(4)-O(10) bond length is 2.56 Å. The Li(4)-O(11) bond length is 2.42 Å. The Li(4)-O(14) bond length is 2.10 Å. The Li(4)-O(18) bond length is 2.07 Å. The Li(4)-O(20) bond length is 2.01 Å. The Li(4)-O(3) bond length is 2.38 Å. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(15), one O(17), one O(19), and one O(2) atom. The Li(5)-O(10) bond length is 2.41 Å. The Li(5)-O(11) bond length is 2.60 Å. The Li(5)-O(15) bond length is 2.06 Å. The Li(5)-O(17) bond length is 2.14 Å. The Li(5)-O(19) bond length is 2.13 Å. The Li(5)-O(2) bond length is 2.25 Å. In the sixth Li site, Li(6) is bonded to one O(1), one O(12), one O(16), one O(18), one O(20), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(10)O5 square pyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-16°. The Li(6)-O(1) bond length is 2.43 Å. The Li(6)-O(12) bond length is 2.07 Å. The Li(6)-O(16) bond length is 2.22 Å. The Li(6)-O(18) bond length is 2.24 Å. The Li(6)-O(20) bond length is 2.12 Å. The Li(6)-O(9) bond length is 2.41 Å. In the seventh Li site, Li(7) is bonded to one O(1), one O(15), one O(17), one O(5), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-85°. The Li(7)-O(1) bond length is 2.12 Å. The Li(7)-O(15) bond length is 2.51 Å. The Li(7)-O(17) bond length is 2.09 Å. The Li(7)-O(5) bond length is 2.20 Å. The Li(7)-O(9) bond length is 2.00 Å. In the eighth Li site, Li(8) is bonded to one O(10), one O(16), one O(18), one O(2), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-20°. The Li(8)-O(10) bond length is 2.45 Å. The Li(8)-O(16) bond length is 2.39 Å. The Li(8)-O(18) bond length is 2.16 Å. The Li(8)-O(2) bond length is 2.25 Å. The Li(8)-O(6) bond length is 2.21 Å. The Li(8)-O(8) bond length is 2.02 Å. In the ninth Li site, Li(9) is bonded to one O(11), one O(13), one O(19), one O(3), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-87°. The Li(9)-O(11) bond length is 2.16 Å. The Li(9)-O(13) bond length is 1.97 Å. The Li(9)-O(19) bond length is 2.10 Å. The Li(9)-O(3) bond length is 2.26 Å. The Li(9)-O(7) bond length is 2.27 Å. In the tenth Li site, Li(10) is bonded to one O(12), one O(14), one O(20), one O(4), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and edges with two equivalent Sb(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-85°. The Li(10)-O(12) bond length is 2.10 Å. The Li(10)-O(14) bond length is 2.48 Å. The Li(10)-O(20) bond length is 2.09 Å. The Li(10)-O(4) bond length is 2.13 Å. The Li(10)-O(8) bond length is 2.31 Å. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(15), one O(2), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, and  an edgeedge with one Li(9)O5 square pyramid. The corner-sharing octahedral tilt angles range from 1-15°. The Mn(1)-O(14) bond length is 2.22 Å. The Mn(1)-O(15) bond length is 2.23 Å. The Mn(1)-O(2) bond length is 2.36 Å. The Mn(1)-O(3) bond length is 2.32 Å. The Mn(1)-O(6) bond length is 2.17 Å. The Mn(1)-O(7) bond length is 2.17 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(16), one O(18), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Li(10)O5 square pyramids,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-16°. The Mn(2)-O(1) bond length is 2.24 Å. The Mn(2)-O(16) bond length is 2.19 Å. The Mn(2)-O(18) bond length is 2.27 Å. The Mn(2)-O(4) bond length is 2.44 Å. The Mn(2)-O(6) bond length is 2.22 Å. The Mn(2)-O(8) bond length is 2.16 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(13), one O(19), one O(4), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  a cornercorner with one Li(9)O5 square pyramid, corners with two equivalent Li(7)O5 trigonal bipyramids,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and  an edgeedge with one Li(9)O5 square pyramid. The corner-sharing octahedral tilt angles range from 7-14°. The Mn(3)-O(1) bond length is 2.28 Å. The Mn(3)-O(13) bond length is 2.10 Å. The Mn(3)-O(19) bond length is 2.25 Å. The Mn(3)-O(4) bond length is 2.25 Å. The Mn(3)-O(5) bond length is 2.30 Å. The Mn(3)-O(7) bond length is 2.24 Å. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(13), one O(16), one O(4), one O(5), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(4)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(10)O5 square pyramid, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-15°. The Mn(4)-O(1) bond length is 2.29 Å. The Mn(4)-O(13) bond length is 2.20 Å. The Mn(4)-O(16) bond length is 2.30 Å. The Mn(4)-O(4) bond length is 2.19 Å. The Mn(4)-O(5) bond length is 2.27 Å. The Mn(4)-O(8) bond length is 2.21 Å. In the fifth Mn site, Mn(5) is bonded to one O(15), one O(17), one O(2), one O(3), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Li(9)O5 square pyramids,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(7)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 9-15°. The Mn(5)-O(15) bond length is 2.19 Å. The Mn(5)-O(17) bond length is 2.24 Å. The Mn(5)-O(2) bond length is 2.20 Å. The Mn(5)-O(3) bond length is 2.39 Å. The Mn(5)-O(5) bond length is 2.15 Å. The Mn(5)-O(7) bond length is 2.24 Å. In the sixth Mn site, Mn(6) is bonded to one O(14), one O(2), one O(20), one O(3), one O(6), and one O(8) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  a cornercorner with one Li(9)O5 square pyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(10)O5 square pyramid. The corner-sharing octahedral tilt angles range from 9-20°. The Mn(6)-O(14) bond length is 2.19 Å. The Mn(6)-O(2) bond length is 2.51 Å. The Mn(6)-O(20) bond length is 2.20 Å. The Mn(6)-O(3) bond length is 2.26 Å. The Mn(6)-O(6) bond length is 2.28 Å. The Mn(6)-O(8) bond length is 2.13 Å. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(12), one O(16), one O(17), one O(5), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Li(7)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. The Sb(1)-O(1) bond length is 2.03 Å. The Sb(1)-O(12) bond length is 1.98 Å. The Sb(1)-O(16) bond length is 2.04 Å. The Sb(1)-O(17) bond length is 2.03 Å. The Sb(1)-O(5) bond length is 2.04 Å. The Sb(1)-O(9) bond length is 2.05 Å. In the second Sb site, Sb(2) is bonded to one O(10), one O(11), one O(15), one O(18), one O(2), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(3)O6 octahedra, and edges with two equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. The Sb(2)-O(10) bond length is 2.09 Å. The Sb(2)-O(11) bond length is 2.05 Å. The Sb(2)-O(15) bond length is 2.03 Å. The Sb(2)-O(18) bond length is 1.98 Å. The Sb(2)-O(2) bond length is 2.02 Å. The Sb(2)-O(6) bond length is 2.03 Å. In the third Sb site, Sb(3) is bonded to one O(10), one O(11), one O(14), one O(19), one O(3), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Li(10)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Li(9)O5 square pyramids. The corner-sharing octahedral tilt angles range from 1-10°. The Sb(3)-O(10) bond length is 2.04 Å. The Sb(3)-O(11) bond length is 2.09 Å. The Sb(3)-O(14) bond length is 2.03 Å. The Sb(3)-O(19) bond length is 1.99 Å. The Sb(3)-O(3) bond length is 2.02 Å. The Sb(3)-O(7) bond length is 2.03 Å. In the fourth Sb site, Sb(4) is bonded to one O(12), one O(13), one O(20), one O(4), one O(8), and one O(9) atom to form distorted SbO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(9)O5 square pyramid,  a cornercorner with one Li(7)O5 trigonal bipyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with two equivalent Li(10)O5 square pyramids. The corner-sharing octahedral tilt angles range from 2-12°. The Sb(4)-O(12) bond length is 2.51 Å. The Sb(4)-O(13) bond length is 2.48 Å. The Sb(4)-O(20) bond length is 2.11 Å. The Sb(4)-O(4) bond length is 2.12 Å. The Sb(4)-O(8) bond length is 2.52 Å. The Sb(4)-O(9) bond length is 2.16 Å. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(6), one Li(7), one Mn(2), one Mn(3), one Mn(4), and one Sb(1) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and edges with two equivalent O(5)LiMn3Sb square pyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the second O site, O(2) is bonded to one Li(5), one Li(8), one Mn(1), one Mn(5), one Mn(6), and one Sb(2) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(5)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(7)LiMn3Sb square pyramid, and edges with two equivalent O(6)LiMn3Sb square pyramids. The corner-sharing octahedral tilt angles range from 3-21°. In the third O site, O(3) is bonded to one Li(4), one Li(9), one Mn(1), one Mn(5), one Mn(6), and one Sb(3) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra,  a cornercorner with one O(5)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(6)LiMn3Sb square pyramid, and edges with two equivalent O(7)LiMn3Sb square pyramids. The corner-sharing octahedral tilt angles range from 1-20°. In the fourth O site, O(4) is bonded to one Li(10), one Li(3), one Mn(2), one Mn(3), one Mn(4), and one Sb(4) atom to form OLi2Mn3Sb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(8)Li2Mn3Sb octahedra, edges with two equivalent O(13)Li3Mn2Sb octahedra, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-20°. In the fifth O site, O(5) is bonded to one Li(7), one Mn(3), one Mn(4), one Mn(5), and one Sb(1) atom to form OLiMn3Sb square pyramids that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra, corners with two equivalent O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra, edges with two equivalent O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-87°. In the sixth O site, O(6) is bonded to one Li(8), one Mn(1), one Mn(2), one Mn(6), and one Sb(2) atom to form OLiMn3Sb square pyramids that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, and edges with two equivalent O(2)Li2Mn3Sb octahedra. The corner-sharing octahedral tilt angles range from 6-83°. In the seventh O site, O(7) is bonded to one Li(9), one Mn(1), one Mn(3), one Mn(5), and one Sb(3) atom to form OLiMn3Sb square pyramids that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Mn3Sb octahedra, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 8-83°. In the eighth O site, O(8) is bonded to one Li(10), one Li(8), one Mn(2), one Mn(4), one Mn(6), and one Sb(4) atom to form distorted OLi2Mn3Sb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Mn3Sb octahedra, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 4-24°. In the ninth O site, O(9) is bonded to one Li(1), one Li(6), one Li(7), one Sb(1), and one Sb(4) atom to form distorted OLi3Sb2 square pyramids that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 4-89°. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Li(5), one Li(8), one Sb(2), and one Sb(3) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra, edges with two equivalent O(18)Li4MnSb octahedra, edges with two equivalent O(11)Li4Sb2 octahedra, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-19°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Li(5), one Li(9), one Sb(2), and one Sb(3) atom to form distorted OLi4Sb2 octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra, edges with two equivalent O(19)Li4MnSb octahedra, edges with two equivalent O(10)Li4Sb2 octahedra, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-17°. In the twelfth O site, O(12) is bonded to one Li(10), one Li(2), one Li(3), one Li(6), one Sb(1), and one Sb(4) atom to form distorted OLi4Sb2 octahedra that share  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra, edges with two equivalent O(20)Li4MnSb octahedra, and  an edgeedge with one O(9)Li3Sb2 square pyramid. The corner-sharing octahedral tilt angles range from 5-17°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(3), one Li(9), one Mn(3), one Mn(4), and one Sb(4) atom to form distorted OLi3Mn2Sb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra, corners with two equivalent O(5)LiMn3Sb square pyramids,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Mn3Sb octahedra, edges with two equivalent O(19)Li4MnSb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-12°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(2), one Li(4), one Mn(1), one Mn(6), and one Sb(3) atom to form distorted OLi3Mn2Sb octahedra that share  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra, corners with two equivalent O(6)LiMn3Sb square pyramids,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Mn3Sb octahedra, edges with two equivalent O(20)Li4MnSb octahedra, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-19°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(5), one Li(7), one Mn(1), one Mn(5), and one Sb(2) atom to form distorted OLi3Mn2Sb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra, corners with two equivalent O(7)LiMn3Sb square pyramids,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra, edges with two equivalent O(2)Li2Mn3Sb octahedra, edges with two equivalent O(17)Li4MnSb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid,  an edgeedge with one O(5)LiMn3Sb square pyramid, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 1-19°. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(6), one Li(8), one Mn(2), one Mn(4), and one Sb(1) atom to form OLi3Mn2Sb octahedra that share  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(1)Li2Mn3Sb octahedra, edges with two equivalent O(18)Li4MnSb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid,  an edgeedge with one O(5)LiMn3Sb square pyramid, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 2-17°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(3), one Li(5), one Li(7), one Mn(5), and one Sb(1) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(16)Li3Mn2Sb octahedra,  a cornercorner with one O(19)Li4MnSb octahedra,  a cornercorner with one O(10)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(13)Li3Mn2Sb octahedra,  an edgeedge with one O(19)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(9)Li3Sb2 square pyramid, and  an edgeedge with one O(5)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-20°. In the eighteenth O site, O(18) is bonded to one Li(2), one Li(4), one Li(6), one Li(8), one Mn(2), and one Sb(2) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(3)Li2Mn3Sb octahedra,  a cornercorner with one O(4)Li2Mn3Sb octahedra,  a cornercorner with one O(15)Li3Mn2Sb octahedra,  a cornercorner with one O(20)Li4MnSb octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(1)Li2Mn3Sb octahedra,  an edgeedge with one O(2)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(14)Li3Mn2Sb octahedra,  an edgeedge with one O(20)Li4MnSb octahedra,  an edgeedge with one O(11)Li4Sb2 octahedra,  an edgeedge with one O(12)Li4Sb2 octahedra, edges with two equivalent O(16)Li3Mn2Sb octahedra, edges with two equivalent O(10)Li4Sb2 octahedra, and  an edgeedge with one O(6)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 4-20°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(3), and one Sb(3) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(14)Li3Mn2Sb octahedra,  a cornercorner with one O(17)Li4MnSb octahedra,  a cornercorner with one O(12)Li4Sb2 octahedra,  a cornercorner with one O(9)Li3Sb2 square pyramid,  a cornercorner with one O(5)LiMn3Sb square pyramid,  a cornercorner with one O(7)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(15)Li3Mn2Sb octahedra,  an edgeedge with one O(17)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, edges with two equivalent O(13)Li3Mn2Sb octahedra, edges with two equivalent O(11)Li4Sb2 octahedra, and  an edgeedge with one O(7)LiMn3Sb square pyramid. The corner-sharing octahedral tilt angles range from 3-21°. In the twentieth O site, O(20) is bonded to one Li(10), one Li(2), one Li(4), one Li(6), one Mn(6), and one Sb(4) atom to form OLi4MnSb octahedra that share  a cornercorner with one O(1)Li2Mn3Sb octahedra,  a cornercorner with one O(2)Li2Mn3Sb octahedra,  a cornercorner with one O(8)Li2Mn3Sb octahedra,  a cornercorner with one O(13)Li3Mn2Sb octahedra,  a cornercorner with one O(18)Li4MnSb octahedra,  a cornercorner with one O(11)Li4Sb2 octahedra,  a cornercorner with one O(6)LiMn3Sb square pyramid,  an edgeedge with one O(3)Li2Mn3Sb octahedra,  an edgeedge with one O(4)Li2Mn3Sb octahedra,  an edgeedge with one O(8)Li2Mn3Sb octahedra,  an edgeedge with one O(16)Li3Mn2Sb octahedra,  an edgeedge with one O(18)Li4MnSb octahedra,  an edgeedge with one O(10)Li4Sb2 octahedra, edges with two equivalent O(14)Li3Mn2Sb octahedra, edges with two equivalent O(12)Li4Sb2 octahedra, and  an edgeedge with one O(9)Li3Sb2 square pyramid. The corner-sharing octahedral tilt angles range from 3-24°.