AgBiO2 crystallizes in the monoclinic P2_1/m space group. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. Bi(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(1) and three equivalent Bi(1) atoms. In the second O site, O(2) is bonded to one Ag(1) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OAgBi3 tetrahedra.
AgBiO2 crystallizes in the monoclinic P2_1/m space group. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. The Ag(1)-O(1) bond length is 2.07 Å. The Ag(1)-O(2) bond length is 2.07 Å. Bi(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two shorter (2.26 Å) and one longer (2.76 Å) Bi(1)-O(1) bond length. There is one shorter (2.17 Å) and two longer (2.46 Å) Bi(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(1) and three equivalent Bi(1) atoms. In the second O site, O(2) is bonded to one Ag(1) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OAgBi3 tetrahedra.