Zn(AgO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ag(1) is bonded to six equivalent O(1) atoms to form AgO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra and edges with six equivalent Ag(1)O6 octahedra. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. O(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(1) and one Zn(1) atom.
Zn(AgO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ag(1) is bonded to six equivalent O(1) atoms to form AgO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra and edges with six equivalent Ag(1)O6 octahedra. All Ag(1)-O(1) bond lengths are 2.22 Å. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Zn(1)-O(1) bond lengths are 2.01 Å. O(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(1) and one Zn(1) atom.