BiO2 crystallizes in the cubic Fd-3m space group. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi(1) atoms.
BiO2 crystallizes in the cubic Fd-3m space group. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. All Bi(1)-O(1) bond lengths are 2.30 Å. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi(1) atoms.