CrFeO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with nine equivalent Fe(1)O6 octahedra, edges with three equivalent Cr(1)O6 octahedra, and  a faceface with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. Fe(1) is bonded to six equivalent O(1) atoms to form distorted FeO6 octahedra that share corners with nine equivalent Cr(1)O6 octahedra, edges with three equivalent Fe(1)O6 octahedra, and  a faceface with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. O(1) is bonded to two equivalent Cr(1) and two equivalent Fe(1) atoms to form a mixture of distorted edge and corner-sharing OCr2Fe2 trigonal pyramids.
CrFeO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with nine equivalent Fe(1)O6 octahedra, edges with three equivalent Cr(1)O6 octahedra, and  a faceface with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. All Cr(1)-O(1) bond lengths are 2.00 Å. Fe(1) is bonded to six equivalent O(1) atoms to form distorted FeO6 octahedra that share corners with nine equivalent Cr(1)O6 octahedra, edges with three equivalent Fe(1)O6 octahedra, and  a faceface with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. There are three shorter (1.94 Å) and three longer (2.15 Å) Fe(1)-O(1) bond lengths. O(1) is bonded to two equivalent Cr(1) and two equivalent Fe(1) atoms to form a mixture of distorted edge and corner-sharing OCr2Fe2 trigonal pyramids.