MgVBiO4 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. V(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Bi(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom.
MgVBiO4 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Mg(1)-O(1) bond length is 2.01 Å. The Mg(1)-O(2) bond length is 1.98 Å. The Mg(1)-O(3) bond length is 1.98 Å. The Mg(1)-O(4) bond length is 2.01 Å. V(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The V(1)-O(1) bond length is 1.93 Å. The V(1)-O(2) bond length is 1.94 Å. The V(1)-O(3) bond length is 1.94 Å. The V(1)-O(4) bond length is 1.93 Å. Bi(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Bi(1)-O(1) bond length is 2.21 Å. The Bi(1)-O(2) bond length is 2.23 Å. The Bi(1)-O(3) bond length is 2.23 Å. The Bi(1)-O(4) bond length is 2.21 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Mg(1), one V(1), and one Bi(1) atom.