Ce2W4S3O14 crystallizes in the monoclinic C2/c space group. Ce(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and two equivalent O(7) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to one O(5), one O(6), and one O(7) atom. In the second W site, W(2) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(5) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ce(1), one W(2), and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ce(1), one W(2), and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(2) atom. In the fourth O site, O(7) is bonded in a trigonal non-coplanar geometry to two equivalent Ce(1) and one W(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one S(2) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Ce(1), one W(1), and one S(1) atom.
Ce2W4S3O14 crystallizes in the monoclinic C2/c space group. Ce(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and two equivalent O(7) atoms. The Ce(1)-O(1) bond length is 2.62 Å. The Ce(1)-O(2) bond length is 2.98 Å. The Ce(1)-O(3) bond length is 2.38 Å. The Ce(1)-O(4) bond length is 2.44 Å. The Ce(1)-O(6) bond length is 2.67 Å. There is one shorter (2.17 Å) and one longer (2.27 Å) Ce(1)-O(7) bond length. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to one O(5), one O(6), and one O(7) atom. The W(1)-O(5) bond length is 2.21 Å. The W(1)-O(6) bond length is 2.59 Å. The W(1)-O(7) bond length is 2.11 Å. In the second W site, W(2) is bonded in a linear geometry to one O(1) and one O(2) atom. The W(2)-O(1) bond length is 2.23 Å. The W(2)-O(2) bond length is 2.24 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. The S(1)-O(1) bond length is 1.52 Å. The S(1)-O(2) bond length is 1.50 Å. The S(1)-O(4) bond length is 1.46 Å. The S(1)-O(6) bond length is 1.48 Å. In the second S site, S(2) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(5) atoms. Both S(2)-O(3) bond lengths are 1.48 Å. Both S(2)-O(5) bond lengths are 1.49 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ce(1), one W(2), and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ce(1), one W(2), and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(2) atom. In the fourth O site, O(7) is bonded in a trigonal non-coplanar geometry to two equivalent Ce(1) and one W(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(1) and one S(2) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Ce(1), one W(1), and one S(1) atom.