CoCN2 crystallizes in the hexagonal P6_3/mmc space group. Co(1) is bonded to six equivalent N(1) atoms to form edge-sharing CoN6 octahedra. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Co(1) and one C(1) atom.
CoCN2 crystallizes in the hexagonal P6_3/mmc space group. Co(1) is bonded to six equivalent N(1) atoms to form edge-sharing CoN6 octahedra. All Co(1)-N(1) bond lengths are 2.13 Å. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both C(1)-N(1) bond lengths are 1.24 Å. N(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Co(1) and one C(1) atom.