Mn2FeC6(N3O2)2(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 7782-44-7 molecules inside a Mn2FeC6(N3O2)2 framework. In the Mn2FeC6(N3O2)2 framework, Mn(1) is bonded to one N(1), one N(2), one N(3), one O(1), and two equivalent O(2) atoms to form distorted edge-sharing MnN3O3 octahedra. Fe(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Mn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Mn(1) and one C(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to two equivalent Mn(1) atoms. In the second O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom.
Mn2FeC6(N3O2)2(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 7782-44-7 molecules inside a Mn2FeC6(N3O2)2 framework. In the Mn2FeC6(N3O2)2 framework, Mn(1) is bonded to one N(1), one N(2), one N(3), one O(1), and two equivalent O(2) atoms to form distorted edge-sharing MnN3O3 octahedra. The Mn(1)-N(1) bond length is 2.06 Å. The Mn(1)-N(2) bond length is 2.05 Å. The Mn(1)-N(3) bond length is 2.12 Å. The Mn(1)-O(1) bond length is 1.70 Å. There is one shorter (1.83 Å) and one longer (1.85 Å) Mn(1)-O(2) bond length. Fe(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. Both Fe(1)-C(1) bond lengths are 1.96 Å. Both Fe(1)-C(2) bond lengths are 1.95 Å. Both Fe(1)-C(3) bond lengths are 1.95 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. In the third C site, C(3) is bonded in a linear geometry to one Fe(1) and one N(3) atom. The C(3)-N(3) bond length is 1.17 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Mn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Mn(1) and one C(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to two equivalent Mn(1) atoms. In the second O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom.