Li4V2Cr3Sb3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-69°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. In the second V site, V(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-50°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the third Sb site, Sb(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Sb(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one Cr(1), and one Cr(2) atom to form distorted OLiVCr2 tetrahedra that share  a cornercorner with one O(8)LiVCrSb tetrahedra, corners with two equivalent O(4)LiCr2Sb tetrahedra, corners with two equivalent O(9)LiVCr2 trigonal pyramids,  an edgeedge with one O(8)LiVCrSb tetrahedra, and  an edgeedge with one O(3)LiCr2Sb trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Cr(1), one Cr(2), and one Sb(1) atom to form distorted OLiCr2Sb trigonal pyramids that share  a cornercorner with one O(12)LiVCrSb tetrahedra, corners with three equivalent O(4)LiCr2Sb tetrahedra,  a cornercorner with one O(11)LiVCrSb trigonal pyramid, corners with two equivalent O(9)LiVCr2 trigonal pyramids,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(8)LiVCrSb tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Cr(1), one Cr(2), and one Sb(1) atom to form distorted OLiCr2Sb tetrahedra that share corners with two equivalent O(2)LiVCr2 tetrahedra, corners with two equivalent O(8)LiVCrSb tetrahedra, corners with three equivalent O(3)LiCr2Sb trigonal pyramids, and  an edgeedge with one O(9)LiVCr2 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Cr(3), one Sb(2), and one Sb(3) atom to form distorted OLiCrSb2 tetrahedra that share corners with two equivalent O(12)LiVCrSb tetrahedra,  a cornercorner with one O(9)LiVCr2 trigonal pyramid, and corners with two equivalent O(11)LiVCrSb trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Cr(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Cr(2), and one Sb(1) atom to form distorted OLiVCrSb tetrahedra that share  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with two equivalent O(4)LiCr2Sb tetrahedra,  a cornercorner with one O(9)LiVCr2 trigonal pyramid,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(3)LiCr2Sb trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(2), one V(2), one Cr(1), and one Cr(2) atom to form distorted OLiVCr2 trigonal pyramids that share  a cornercorner with one O(5)LiCrSb2 tetrahedra,  a cornercorner with one O(12)LiVCrSb tetrahedra,  a cornercorner with one O(8)LiVCrSb tetrahedra, corners with two equivalent O(2)LiVCr2 tetrahedra,  a cornercorner with one O(11)LiVCrSb trigonal pyramid, corners with two equivalent O(3)LiCr2Sb trigonal pyramids, and  an edgeedge with one O(4)LiCr2Sb tetrahedra. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Sb(2), and one Sb(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Cr(3), and one Sb(2) atom to form distorted OLiVCrSb trigonal pyramids that share  a cornercorner with one O(12)LiVCrSb tetrahedra, corners with two equivalent O(5)LiCrSb2 tetrahedra,  a cornercorner with one O(3)LiCr2Sb trigonal pyramid,  a cornercorner with one O(9)LiVCr2 trigonal pyramid, and  an edgeedge with one O(12)LiVCrSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Cr(3), and one Sb(3) atom to form distorted OLiVCrSb tetrahedra that share corners with two equivalent O(5)LiCrSb2 tetrahedra,  a cornercorner with one O(3)LiCr2Sb trigonal pyramid,  a cornercorner with one O(9)LiVCr2 trigonal pyramid,  a cornercorner with one O(11)LiVCrSb trigonal pyramid, and  an edgeedge with one O(11)LiVCrSb trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Cr(3), one Sb(2), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(1), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Sb(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(2), and one Sb(1) atom.
Li4V2Cr3Sb3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-69°. The Li(1)-O(11) bond length is 2.15 Å. The Li(1)-O(12) bond length is 2.03 Å. The Li(1)-O(15) bond length is 2.02 Å. The Li(1)-O(3) bond length is 2.00 Å. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. The Li(2)-O(14) bond length is 2.00 Å. The Li(2)-O(16) bond length is 2.06 Å. The Li(2)-O(5) bond length is 1.81 Å. The Li(2)-O(9) bond length is 1.91 Å. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. The Li(3)-O(1) bond length is 1.99 Å. The Li(3)-O(10) bond length is 2.09 Å. The Li(3)-O(4) bond length is 1.78 Å. The Li(3)-O(6) bond length is 1.94 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. The Li(4)-O(13) bond length is 2.10 Å. The Li(4)-O(2) bond length is 2.03 Å. The Li(4)-O(7) bond length is 2.08 Å. The Li(4)-O(8) bond length is 2.05 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with two equivalent Sb(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-58°. The V(1)-O(1) bond length is 2.24 Å. The V(1)-O(10) bond length is 2.17 Å. The V(1)-O(2) bond length is 2.06 Å. The V(1)-O(6) bond length is 1.99 Å. The V(1)-O(7) bond length is 2.14 Å. The V(1)-O(8) bond length is 2.10 Å. In the second V site, V(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. The V(2)-O(11) bond length is 2.18 Å. The V(2)-O(12) bond length is 2.02 Å. The V(2)-O(14) bond length is 2.19 Å. The V(2)-O(15) bond length is 2.09 Å. The V(2)-O(16) bond length is 2.23 Å. The V(2)-O(9) bond length is 2.01 Å. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. The Cr(1)-O(14) bond length is 2.09 Å. The Cr(1)-O(2) bond length is 2.04 Å. The Cr(1)-O(3) bond length is 2.06 Å. The Cr(1)-O(4) bond length is 2.04 Å. The Cr(1)-O(7) bond length is 2.06 Å. The Cr(1)-O(9) bond length is 2.07 Å. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. The Cr(2)-O(16) bond length is 2.07 Å. The Cr(2)-O(2) bond length is 2.04 Å. The Cr(2)-O(3) bond length is 2.04 Å. The Cr(2)-O(4) bond length is 2.03 Å. The Cr(2)-O(8) bond length is 2.04 Å. The Cr(2)-O(9) bond length is 2.08 Å. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-50°. The Cr(3)-O(1) bond length is 2.12 Å. The Cr(3)-O(11) bond length is 2.05 Å. The Cr(3)-O(12) bond length is 2.02 Å. The Cr(3)-O(13) bond length is 2.01 Å. The Cr(3)-O(5) bond length is 2.01 Å. The Cr(3)-O(6) bond length is 2.05 Å. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. The Sb(1)-O(14) bond length is 2.03 Å. The Sb(1)-O(16) bond length is 2.02 Å. The Sb(1)-O(3) bond length is 2.02 Å. The Sb(1)-O(4) bond length is 2.02 Å. The Sb(1)-O(7) bond length is 2.06 Å. The Sb(1)-O(8) bond length is 2.03 Å. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. The Sb(2)-O(1) bond length is 2.05 Å. The Sb(2)-O(10) bond length is 2.04 Å. The Sb(2)-O(11) bond length is 2.04 Å. The Sb(2)-O(13) bond length is 2.02 Å. The Sb(2)-O(15) bond length is 2.03 Å. The Sb(2)-O(5) bond length is 2.00 Å. In the third Sb site, Sb(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. The Sb(3)-O(10) bond length is 2.21 Å. The Sb(3)-O(12) bond length is 2.23 Å. The Sb(3)-O(13) bond length is 2.25 Å. The Sb(3)-O(15) bond length is 2.33 Å. The Sb(3)-O(5) bond length is 2.18 Å. The Sb(3)-O(6) bond length is 2.24 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Sb(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one Cr(1), and one Cr(2) atom to form distorted OLiVCr2 tetrahedra that share  a cornercorner with one O(8)LiVCrSb tetrahedra, corners with two equivalent O(4)LiCr2Sb tetrahedra, corners with two equivalent O(9)LiVCr2 trigonal pyramids,  an edgeedge with one O(8)LiVCrSb tetrahedra, and  an edgeedge with one O(3)LiCr2Sb trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Cr(1), one Cr(2), and one Sb(1) atom to form distorted OLiCr2Sb trigonal pyramids that share  a cornercorner with one O(12)LiVCrSb tetrahedra, corners with three equivalent O(4)LiCr2Sb tetrahedra,  a cornercorner with one O(11)LiVCrSb trigonal pyramid, corners with two equivalent O(9)LiVCr2 trigonal pyramids,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(8)LiVCrSb tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Cr(1), one Cr(2), and one Sb(1) atom to form distorted OLiCr2Sb tetrahedra that share corners with two equivalent O(2)LiVCr2 tetrahedra, corners with two equivalent O(8)LiVCrSb tetrahedra, corners with three equivalent O(3)LiCr2Sb trigonal pyramids, and  an edgeedge with one O(9)LiVCr2 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(2), one Cr(3), one Sb(2), and one Sb(3) atom to form distorted OLiCrSb2 tetrahedra that share corners with two equivalent O(12)LiVCrSb tetrahedra,  a cornercorner with one O(9)LiVCr2 trigonal pyramid, and corners with two equivalent O(11)LiVCrSb trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Cr(3), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Cr(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded to one Li(4), one V(1), one Cr(2), and one Sb(1) atom to form distorted OLiVCrSb tetrahedra that share  a cornercorner with one O(2)LiVCr2 tetrahedra, corners with two equivalent O(4)LiCr2Sb tetrahedra,  a cornercorner with one O(9)LiVCr2 trigonal pyramid,  an edgeedge with one O(2)LiVCr2 tetrahedra, and  an edgeedge with one O(3)LiCr2Sb trigonal pyramid. In the ninth O site, O(9) is bonded to one Li(2), one V(2), one Cr(1), and one Cr(2) atom to form distorted OLiVCr2 trigonal pyramids that share  a cornercorner with one O(5)LiCrSb2 tetrahedra,  a cornercorner with one O(12)LiVCrSb tetrahedra,  a cornercorner with one O(8)LiVCrSb tetrahedra, corners with two equivalent O(2)LiVCr2 tetrahedra,  a cornercorner with one O(11)LiVCrSb trigonal pyramid, corners with two equivalent O(3)LiCr2Sb trigonal pyramids, and  an edgeedge with one O(4)LiCr2Sb tetrahedra. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Sb(2), and one Sb(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Cr(3), and one Sb(2) atom to form distorted OLiVCrSb trigonal pyramids that share  a cornercorner with one O(12)LiVCrSb tetrahedra, corners with two equivalent O(5)LiCrSb2 tetrahedra,  a cornercorner with one O(3)LiCr2Sb trigonal pyramid,  a cornercorner with one O(9)LiVCr2 trigonal pyramid, and  an edgeedge with one O(12)LiVCrSb tetrahedra. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Cr(3), and one Sb(3) atom to form distorted OLiVCrSb tetrahedra that share corners with two equivalent O(5)LiCrSb2 tetrahedra,  a cornercorner with one O(3)LiCr2Sb trigonal pyramid,  a cornercorner with one O(9)LiVCr2 trigonal pyramid,  a cornercorner with one O(11)LiVCrSb trigonal pyramid, and  an edgeedge with one O(11)LiVCrSb trigonal pyramid. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Cr(3), one Sb(2), and one Sb(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(1), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Sb(2), and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Cr(2), and one Sb(1) atom.