BaBr3 crystallizes in the hexagonal P6_3/mmc space group. Ba(1) is bonded to twelve equivalent Br(1) atoms to form a mixture of face and corner-sharing BaBr12 cuboctahedra. Br(1) is bonded in a see-saw-like geometry to four equivalent Ba(1) atoms.
BaBr3 crystallizes in the hexagonal P6_3/mmc space group. Ba(1) is bonded to twelve equivalent Br(1) atoms to form a mixture of face and corner-sharing BaBr12 cuboctahedra. There are six shorter (3.46 Å) and six longer (3.68 Å) Ba(1)-Br(1) bond lengths. Br(1) is bonded in a see-saw-like geometry to four equivalent Ba(1) atoms.