LiCe(MoO4)2 is Zircon-derived structured and crystallizes in the tetragonal I-4 space group. Li(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Ce(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Ce(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ce(1), and one Mo(2) atom.
LiCe(MoO4)2 is Zircon-derived structured and crystallizes in the tetragonal I-4 space group. Li(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Li(1)-O(1) bond lengths are 2.53 Å. All Li(1)-O(2) bond lengths are 2.47 Å. Ce(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Ce(1)-O(1) bond lengths are 2.44 Å. All Ce(1)-O(2) bond lengths are 2.47 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All Mo(1)-O(1) bond lengths are 1.81 Å. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. All Mo(2)-O(2) bond lengths are 1.82 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Ce(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ce(1), and one Mo(2) atom.