NaSbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 octahedra that share corners with nine equivalent Sb(1)O6 octahedra, edges with three equivalent Na(1)O6 octahedra, and  a faceface with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-60°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with nine equivalent Na(1)O6 octahedra, edges with three equivalent Sb(1)O6 octahedra, and  a faceface with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-60°. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Na(1) and two equivalent Sb(1) atoms.
NaSbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 octahedra that share corners with nine equivalent Sb(1)O6 octahedra, edges with three equivalent Na(1)O6 octahedra, and  a faceface with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-60°. There are three shorter (2.31 Å) and three longer (2.52 Å) Na(1)-O(1) bond lengths. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with nine equivalent Na(1)O6 octahedra, edges with three equivalent Sb(1)O6 octahedra, and  a faceface with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-60°. There are three shorter (1.98 Å) and three longer (2.02 Å) Sb(1)-O(1) bond lengths. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Na(1) and two equivalent Sb(1) atoms.