Na2LiN crystallizes in the hexagonal P6/mmm space group. Na(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. Li(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to six equivalent Na(1) and two equivalent Li(1) atoms to form a mixture of distorted edge and corner-sharing NNa6Li2 hexagonal bipyramids.
Na2LiN crystallizes in the hexagonal P6/mmm space group. Na(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All Na(1)-N(1) bond lengths are 2.59 Å. Li(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Li(1)-N(1) bond lengths are 1.94 Å. N(1) is bonded to six equivalent Na(1) and two equivalent Li(1) atoms to form a mixture of distorted edge and corner-sharing NNa6Li2 hexagonal bipyramids.