RuAgF7 crystallizes in the monoclinic P2_1/c space group. Ru(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. Ag(1) is bonded in a 6-coordinate geometry to one F(3), one F(4), one F(5), one F(6), and two equivalent F(1) atoms. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Ru(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Ag(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Ag(1) atom. In the sixth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ru(1) and one Ag(1) atom. In the seventh F site, F(6) is bonded in a distorted single-bond geometry to one Ru(1) and one Ag(1) atom.
RuAgF7 crystallizes in the monoclinic P2_1/c space group. Ru(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. The Ru(1)-F(2) bond length is 1.84 Å. The Ru(1)-F(3) bond length is 1.93 Å. The Ru(1)-F(4) bond length is 1.92 Å. The Ru(1)-F(5) bond length is 1.87 Å. The Ru(1)-F(6) bond length is 1.86 Å. The Ru(1)-F(7) bond length is 1.84 Å. Ag(1) is bonded in a 6-coordinate geometry to one F(3), one F(4), one F(5), one F(6), and two equivalent F(1) atoms. The Ag(1)-F(3) bond length is 2.16 Å. The Ag(1)-F(4) bond length is 2.18 Å. The Ag(1)-F(5) bond length is 2.51 Å. The Ag(1)-F(6) bond length is 2.58 Å. There is one shorter (2.02 Å) and one longer (2.04 Å) Ag(1)-F(1) bond length. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Ru(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(2) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Ag(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Ag(1) atom. In the sixth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Ru(1) and one Ag(1) atom. In the seventh F site, F(6) is bonded in a distorted single-bond geometry to one Ru(1) and one Ag(1) atom.