CsScAgF6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one F(2) and four equivalent F(3) atoms to form distorted CsF5 square pyramids that share corners with four equivalent Sc(1)F6 octahedra and corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 64-70°. Sc(1) is bonded to two equivalent F(1) and four equivalent F(3) atoms to form ScF6 octahedra that share corners with two equivalent Sc(1)F6 octahedra, corners with four equivalent Ag(1)F6 octahedra, and corners with four equivalent Cs(1)F5 square pyramids. The corner-sharing octahedral tilt angles range from 32-46°. Ag(1) is bonded to two equivalent F(2) and four equivalent F(3) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra, corners with four equivalent Sc(1)F6 octahedra, and corners with six equivalent Cs(1)F5 square pyramids. The corner-sharing octahedral tilt angles range from 41-46°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Sc(1) atoms. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent Ag(1) atoms. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Cs(1), one Sc(1), and one Ag(1) atom.
CsScAgF6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one F(2) and four equivalent F(3) atoms to form distorted CsF5 square pyramids that share corners with four equivalent Sc(1)F6 octahedra and corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 64-70°. The Cs(1)-F(2) bond length is 3.58 Å. All Cs(1)-F(3) bond lengths are 3.30 Å. Sc(1) is bonded to two equivalent F(1) and four equivalent F(3) atoms to form ScF6 octahedra that share corners with two equivalent Sc(1)F6 octahedra, corners with four equivalent Ag(1)F6 octahedra, and corners with four equivalent Cs(1)F5 square pyramids. The corner-sharing octahedral tilt angles range from 32-46°. Both Sc(1)-F(1) bond lengths are 2.05 Å. All Sc(1)-F(3) bond lengths are 2.02 Å. Ag(1) is bonded to two equivalent F(2) and four equivalent F(3) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra, corners with four equivalent Sc(1)F6 octahedra, and corners with six equivalent Cs(1)F5 square pyramids. The corner-sharing octahedral tilt angles range from 41-46°. Both Ag(1)-F(2) bond lengths are 2.07 Å. All Ag(1)-F(3) bond lengths are 2.32 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Sc(1) atoms. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent Ag(1) atoms. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Cs(1), one Sc(1), and one Ag(1) atom.