MnZn3F6 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the second Zn site, Zn(2) is bonded in a distorted square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. In the third Zn site, Zn(3) is bonded in a linear geometry to two equivalent F(2) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Zn(1), and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Zn(1), and one Zn(3) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Zn(1), and one Zn(2) atom.
MnZn3F6 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Mn(1)-F(1) bond lengths are 2.39 Å. Both Mn(1)-F(2) bond lengths are 2.19 Å. Both Mn(1)-F(3) bond lengths are 2.13 Å. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Zn(1)-F(1) bond lengths are 2.19 Å. Both Zn(1)-F(2) bond lengths are 1.95 Å. Both Zn(1)-F(3) bond lengths are 2.25 Å. In the second Zn site, Zn(2) is bonded in a distorted square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. Both Zn(2)-F(1) bond lengths are 1.95 Å. Both Zn(2)-F(3) bond lengths are 2.19 Å. In the third Zn site, Zn(3) is bonded in a linear geometry to two equivalent F(2) atoms. Both Zn(3)-F(2) bond lengths are 2.32 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Zn(1), and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Zn(1), and one Zn(3) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Zn(1), and one Zn(2) atom.