Ti3Br is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded in a distorted see-saw-like geometry to four equivalent Br(1) atoms. Br(1) is bonded to twelve equivalent Ti(1) atoms to form a mixture of face and corner-sharing BrTi12 cuboctahedra.
Ti3Br is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded in a distorted see-saw-like geometry to four equivalent Br(1) atoms. There are two shorter (2.84 Å) and two longer (3.00 Å) Ti(1)-Br(1) bond lengths. Br(1) is bonded to twelve equivalent Ti(1) atoms to form a mixture of face and corner-sharing BrTi12 cuboctahedra.