(CH3)2(C2N2H6SeS)2Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two hydrochloric acid atoms, and one C2N2H6SeS cluster. In the C2N2H6SeS cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(3), one H(6), one H(7), and one S(1) atom. In the second C site, C(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(8), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. Se(1) is bonded in a distorted water-like geometry to one N(1) and one N(2) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(2), one C(3), one N(1), and one N(2) atom.
(CH3)2(C2N2H6SeS)2Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two hydrochloric acid atoms, and one C2N2H6SeS cluster. In the C2N2H6SeS cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(3), one H(6), one H(7), and one S(1) atom. The C(2)-H(3) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-H(7) bond length is 1.10 Å. The C(2)-S(1) bond length is 1.79 Å. In the second C site, C(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(8), and one S(1) atom. The C(3)-H(1) bond length is 1.10 Å. The C(3)-H(2) bond length is 1.10 Å. The C(3)-H(8) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.79 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. The N(1)-Se(1) bond length is 1.90 Å. The N(1)-S(1) bond length is 1.57 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. The N(2)-Se(1) bond length is 1.84 Å. The N(2)-S(1) bond length is 1.59 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. Se(1) is bonded in a distorted water-like geometry to one N(1) and one N(2) atom. S(1) is bonded in a distorted tetrahedral geometry to one C(2), one C(3), one N(1), and one N(2) atom.