UPd2S4 crystallizes in the tetragonal I4_1/a space group. U(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded to two equivalent U(1) and two equivalent Pd(1) atoms to form a mixture of corner and edge-sharing SU2Pd2 tetrahedra.
UPd2S4 crystallizes in the tetragonal I4_1/a space group. U(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. There are four shorter (2.78 Å) and four longer (2.87 Å) U(1)-S(1) bond lengths. Pd(1) is bonded in a square co-planar geometry to four equivalent S(1) atoms. There are two shorter (2.35 Å) and two longer (2.37 Å) Pd(1)-S(1) bond lengths. S(1) is bonded to two equivalent U(1) and two equivalent Pd(1) atoms to form a mixture of corner and edge-sharing SU2Pd2 tetrahedra.