Ag3AsS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent S(1) atoms. As(1) is bonded in a trigonal non-coplanar geometry to three equivalent S(1) atoms. S(1) is bonded to three equivalent Ag(1) and one As(1) atom to form distorted corner-sharing SAg3As tetrahedra.
Ag3AsS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent S(1) atoms. There are a spread of Ag(1)-S(1) bond distances ranging from 2.47-2.57 Å. As(1) is bonded in a trigonal non-coplanar geometry to three equivalent S(1) atoms. All As(1)-S(1) bond lengths are 2.31 Å. S(1) is bonded to three equivalent Ag(1) and one As(1) atom to form distorted corner-sharing SAg3As tetrahedra.