HgVO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent V(1)O6 octahedra and faces with eight equivalent Hg(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Hg(1) is bonded to twelve equivalent O(1) atoms to form HgO12 cuboctahedra that share corners with twelve equivalent Hg(1)O12 cuboctahedra, faces with six equivalent Hg(1)O12 cuboctahedra, and faces with eight equivalent V(1)O6 octahedra. O(1) is bonded in a linear geometry to two equivalent V(1) and four equivalent Hg(1) atoms.
HgVO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent V(1)O6 octahedra and faces with eight equivalent Hg(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All V(1)-O(1) bond lengths are 1.93 Å. Hg(1) is bonded to twelve equivalent O(1) atoms to form HgO12 cuboctahedra that share corners with twelve equivalent Hg(1)O12 cuboctahedra, faces with six equivalent Hg(1)O12 cuboctahedra, and faces with eight equivalent V(1)O6 octahedra. All Hg(1)-O(1) bond lengths are 2.73 Å. O(1) is bonded in a linear geometry to two equivalent V(1) and four equivalent Hg(1) atoms.