UVAgO6 crystallizes in the monoclinic P2_1/c space group. U(1) is bonded to one O(1), one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent V(1)O5 trigonal bipyramids,  an edgeedge with one U(1)O7 pentagonal bipyramid, and edges with two equivalent V(1)O5 trigonal bipyramids. V(1) is bonded to one O(3), one O(5), one O(6), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, edges with two equivalent U(1)O7 pentagonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. Ag(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one U(1) and one Ag(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one U(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one U(1) and one Ag(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent U(1), one V(1), and one Ag(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom.
UVAgO6 crystallizes in the monoclinic P2_1/c space group. U(1) is bonded to one O(1), one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent V(1)O5 trigonal bipyramids,  an edgeedge with one U(1)O7 pentagonal bipyramid, and edges with two equivalent V(1)O5 trigonal bipyramids. The U(1)-O(1) bond length is 1.83 Å. The U(1)-O(2) bond length is 2.33 Å. The U(1)-O(4) bond length is 1.85 Å. There is one shorter (2.37 Å) and one longer (2.43 Å) U(1)-O(5) bond length. There is one shorter (2.32 Å) and one longer (2.35 Å) U(1)-O(6) bond length. V(1) is bonded to one O(3), one O(5), one O(6), and two equivalent O(2) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, edges with two equivalent U(1)O7 pentagonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. The V(1)-O(3) bond length is 1.65 Å. The V(1)-O(5) bond length is 1.86 Å. The V(1)-O(6) bond length is 1.82 Å. There is one shorter (1.93 Å) and one longer (1.97 Å) V(1)-O(2) bond length. Ag(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), one O(4), and one O(5) atom. The Ag(1)-O(1) bond length is 2.56 Å. The Ag(1)-O(3) bond length is 2.28 Å. The Ag(1)-O(4) bond length is 2.35 Å. The Ag(1)-O(5) bond length is 2.80 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one U(1) and one Ag(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one U(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one U(1) and one Ag(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent U(1), one V(1), and one Ag(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom.