NbRh is Tetraauricupride-like structured and crystallizes in the orthorhombic Pmma space group. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a 8-coordinate geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. In the second Nb site, Nb(2) is bonded in a 8-coordinate geometry to two equivalent Rh(1) and six equivalent Rh(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded to two equivalent Nb(1) and six equivalent Nb(2) atoms to form a mixture of distorted face, corner, and edge-sharing RhNb8 cuboctahedra. In the second Rh site, Rh(1) is bonded in a 8-coordinate geometry to four equivalent Nb(1) and four equivalent Nb(2) atoms.
NbRh is Tetraauricupride-like structured and crystallizes in the orthorhombic Pmma space group. There are two inequivalent Nb sites. In the first Nb site, Nb(1) is bonded in a 8-coordinate geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. There are two shorter (2.76 Å) and two longer (2.86 Å) Nb(1)-Rh(1) bond lengths. All Nb(1)-Rh(2) bond lengths are 2.77 Å. In the second Nb site, Nb(2) is bonded in a 8-coordinate geometry to two equivalent Rh(1) and six equivalent Rh(2) atoms. Both Nb(2)-Rh(1) bond lengths are 2.76 Å. There are two shorter (2.80 Å) and four longer (2.82 Å) Nb(2)-Rh(2) bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded to two equivalent Nb(1) and six equivalent Nb(2) atoms to form a mixture of distorted face, corner, and edge-sharing RhNb8 cuboctahedra. In the second Rh site, Rh(1) is bonded in a 8-coordinate geometry to four equivalent Nb(1) and four equivalent Nb(2) atoms.