Li(O2Cl)2 is Indium-like structured and crystallizes in the tetragonal P4_2/mmc space group. The structure is zero-dimensional and consists of two Li(O2Cl)2 clusters. Li(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in an L-shaped geometry to one Li(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms.
Li(O2Cl)2 is Indium-like structured and crystallizes in the tetragonal P4_2/mmc space group. The structure is zero-dimensional and consists of two Li(O2Cl)2 clusters. Li(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.08 Å. O(1) is bonded in an L-shaped geometry to one Li(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.54 Å. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms.