MgPtZnC4H16(N2O5)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules and one MgPtZnC4H16(N2O5)2 cluster. In the MgPtZnC4H16(N2O5)2 cluster, Mg(1) is bonded in a distorted trigonal bipyramidal geometry to one Pt(1), one N(3), one N(4), one O(7), and one O(8) atom. Pt(1) is bonded in a T-shaped geometry to one Mg(1), one N(1), and one N(2) atom. Zn(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(9) atom. There are two inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. In the second C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(11), one H(3), and one H(7) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1); one H(8); and two equivalent H(4,12) atoms. There are eleven inequivalent H sites. In the first H site, H(1,2,9,10) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(4,12) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one O(10) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1,2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(1,2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Zn(1), one H(13), and one H(16) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Zn(1), one H(14), and one H(15) atom.
MgPtZnC4H16(N2O5)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules and one MgPtZnC4H16(N2O5)2 cluster. In the MgPtZnC4H16(N2O5)2 cluster, Mg(1) is bonded in a distorted trigonal bipyramidal geometry to one Pt(1), one N(3), one N(4), one O(7), and one O(8) atom. The Mg(1)-Pt(1) bond length is 2.59 Å. The Mg(1)-N(3) bond length is 2.20 Å. The Mg(1)-N(4) bond length is 2.20 Å. The Mg(1)-O(7) bond length is 2.17 Å. The Mg(1)-O(8) bond length is 2.17 Å. Pt(1) is bonded in a T-shaped geometry to one Mg(1), one N(1), and one N(2) atom. The Pt(1)-N(1) bond length is 2.05 Å. The Pt(1)-N(2) bond length is 2.05 Å. Zn(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(9) atom. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(10) bond length is 2.16 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 2.14 Å. The Zn(1)-O(4) bond length is 2.14 Å. The Zn(1)-O(9) bond length is 2.16 Å. There are two inequivalent C sites. In the first C site, C(1,2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(1,2)-O(1) bond length is 1.29 Å. The C(1,2)-O(5) bond length is 1.25 Å. In the second C site, C(3,4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(7) atom. The C(3,4)-O(3) bond length is 1.27 Å. The C(3,4)-O(7) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. The N(1)-H(5,6) bond length is 1.03 Å. Both N(1)-H(1,2,9,10) bond lengths are 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1); one H(5,6); and two equivalent H(1,2,9,10) atoms. The N(2)-H(5,6) bond length is 1.03 Å. Both N(2)-H(1,2,9,10) bond lengths are 1.03 Å. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(11), one H(3), and one H(7) atom. The N(3)-H(11) bond length is 1.03 Å. The N(3)-H(3) bond length is 1.03 Å. The N(3)-H(7) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1); one H(8); and two equivalent H(4,12) atoms. The N(4)-H(8) bond length is 1.02 Å. Both N(4)-H(4,12) bond lengths are 1.03 Å. There are eleven inequivalent H sites. In the first H site, H(1,2,9,10) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(4,12) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one O(9) atom. The H(13)-O(9) bond length is 0.99 Å. In the ninth H site, H(14) is bonded in a single-bond geometry to one O(10) atom. The H(14)-O(10) bond length is 0.99 Å. In the tenth H site, H(15) is bonded in a single-bond geometry to one O(10) atom. The H(15)-O(10) bond length is 0.99 Å. In the eleventh H site, H(16) is bonded in a single-bond geometry to one O(9) atom. The H(16)-O(9) bond length is 0.99 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1,2) atom. The O(2)-C(1,2) bond length is 1.29 Å. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3,4) atom. The O(4)-C(3,4) bond length is 1.27 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1,2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(1,2) atom. The O(6)-C(1,2) bond length is 1.25 Å. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Mg(1) and one C(3,4) atom. The O(8)-C(3,4) bond length is 1.27 Å. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Zn(1), one H(13), and one H(16) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Zn(1), one H(14), and one H(15) atom.