Rb2MnS2 crystallizes in the orthorhombic Ibam space group. Rb(1) is bonded in a 5-coordinate geometry to six equivalent S(1) atoms. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. S(1) is bonded in a 8-coordinate geometry to six equivalent Rb(1) and two equivalent Mn(1) atoms.
Rb2MnS2 crystallizes in the orthorhombic Ibam space group. Rb(1) is bonded in a 5-coordinate geometry to six equivalent S(1) atoms. There are a spread of Rb(1)-S(1) bond distances ranging from 3.35-3.77 Å. Mn(1) is bonded to four equivalent S(1) atoms to form distorted edge-sharing MnS4 tetrahedra. All Mn(1)-S(1) bond lengths are 2.45 Å. S(1) is bonded in a 8-coordinate geometry to six equivalent Rb(1) and two equivalent Mn(1) atoms.