Na2MgPb crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a 11-coordinate geometry to four equivalent Na(1), three equivalent Mg(1), and four equivalent Pb(1) atoms. Mg(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Pb(1) atoms. Pb(1) is bonded in a 11-coordinate geometry to eight equivalent Na(1) and three equivalent Mg(1) atoms.
Na2MgPb crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a 11-coordinate geometry to four equivalent Na(1), three equivalent Mg(1), and four equivalent Pb(1) atoms. There are three shorter (3.35 Å) and one longer (3.43 Å) Na(1)-Na(1) bond length. All Na(1)-Mg(1) bond lengths are 3.40 Å. There is one shorter (3.34 Å) and three longer (3.40 Å) Na(1)-Pb(1) bond lengths. Mg(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Pb(1) atoms. All Mg(1)-Pb(1) bond lengths are 2.94 Å. Pb(1) is bonded in a 11-coordinate geometry to eight equivalent Na(1) and three equivalent Mg(1) atoms.