TeBr4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four TeBr4 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Br(1), one Br(2), one Br(4), one Br(5), and two equivalent Br(7) atoms to form edge-sharing TeBr6 octahedra. In the second Te site, Te(2) is bonded to one Br(3), one Br(6), one Br(7), one Br(8), and two equivalent Br(4) atoms to form edge-sharing TeBr6 octahedra. There are eight inequivalent Br sites. In the first Br site, Br(5) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(6) is bonded in a single-bond geometry to one Te(2) atom. In the third Br site, Br(7) is bonded in a distorted T-shaped geometry to one Te(2) and two equivalent Te(1) atoms. In the fourth Br site, Br(8) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Br site, Br(3) is bonded in a single-bond geometry to one Te(2) atom. In the eighth Br site, Br(4) is bonded in a distorted T-shaped geometry to one Te(1) and two equivalent Te(2) atoms.
TeBr4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four TeBr4 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Br(1), one Br(2), one Br(4), one Br(5), and two equivalent Br(7) atoms to form edge-sharing TeBr6 octahedra. The Te(1)-Br(1) bond length is 2.52 Å. The Te(1)-Br(2) bond length is 2.53 Å. The Te(1)-Br(4) bond length is 3.07 Å. The Te(1)-Br(5) bond length is 2.52 Å. There is one shorter (3.07 Å) and one longer (3.09 Å) Te(1)-Br(7) bond length. In the second Te site, Te(2) is bonded to one Br(3), one Br(6), one Br(7), one Br(8), and two equivalent Br(4) atoms to form edge-sharing TeBr6 octahedra. The Te(2)-Br(3) bond length is 2.54 Å. The Te(2)-Br(6) bond length is 2.53 Å. The Te(2)-Br(7) bond length is 3.05 Å. The Te(2)-Br(8) bond length is 2.52 Å. There is one shorter (3.04 Å) and one longer (3.07 Å) Te(2)-Br(4) bond length. There are eight inequivalent Br sites. In the first Br site, Br(5) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(6) is bonded in a single-bond geometry to one Te(2) atom. In the third Br site, Br(7) is bonded in a distorted T-shaped geometry to one Te(2) and two equivalent Te(1) atoms. In the fourth Br site, Br(8) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Br site, Br(3) is bonded in a single-bond geometry to one Te(2) atom. In the eighth Br site, Br(4) is bonded in a distorted T-shaped geometry to one Te(1) and two equivalent Te(2) atoms.