CeRhSb crystallizes in the monoclinic C2/m space group. Ce(1) is bonded in a 11-coordinate geometry to five equivalent Rh(1) and six equivalent Sb(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to five equivalent Ce(1), one Rh(1), and three equivalent Sb(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), three equivalent Rh(1), and one Sb(1) atom.
CeRhSb crystallizes in the monoclinic C2/m space group. Ce(1) is bonded in a 11-coordinate geometry to five equivalent Rh(1) and six equivalent Sb(1) atoms. There are a spread of Ce(1)-Rh(1) bond distances ranging from 3.04-3.23 Å. There are a spread of Ce(1)-Sb(1) bond distances ranging from 3.26-3.46 Å. Rh(1) is bonded in a 9-coordinate geometry to five equivalent Ce(1), one Rh(1), and three equivalent Sb(1) atoms. The Rh(1)-Rh(1) bond length is 2.81 Å. There are two shorter (2.66 Å) and one longer (2.81 Å) Rh(1)-Sb(1) bond length. Sb(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), three equivalent Rh(1), and one Sb(1) atom. The Sb(1)-Sb(1) bond length is 3.02 Å.