Li(SO2)4(BCl)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve chloroborane molecules and one Li(SO2)4 cluster. In the Li(SO2)4 cluster, Li(1) is bonded in a trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(5), and one O(7) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one O(7) and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Li(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one S(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Li(1) and one S(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(4) atom.
Li(SO2)4(BCl)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve chloroborane molecules and one Li(SO2)4 cluster. In the Li(SO2)4 cluster, Li(1) is bonded in a trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(5), and one O(7) atom. The Li(1)-O(1) bond length is 2.09 Å. The Li(1)-O(2) bond length is 2.28 Å. The Li(1)-O(3) bond length is 2.03 Å. The Li(1)-O(5) bond length is 2.17 Å. The Li(1)-O(7) bond length is 2.05 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The S(1)-O(1) bond length is 1.45 Å. The S(1)-O(2) bond length is 1.45 Å. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. The S(2)-O(3) bond length is 1.46 Å. The S(2)-O(4) bond length is 1.45 Å. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. The S(3)-O(5) bond length is 1.45 Å. The S(3)-O(6) bond length is 1.45 Å. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one O(7) and one O(8) atom. The S(4)-O(7) bond length is 1.45 Å. The S(4)-O(8) bond length is 1.45 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Li(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one S(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Li(1) and one S(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(4) atom.