PN3S2(OCl2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PN3S2(OCl2)2 clusters. P(1) is bonded to one N(1), one N(2), one Cl(2), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one S(1)N2ClO tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one N(3), one O(2), and one Cl(1) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. In the second S site, S(2) is bonded to one N(2), one N(3), one O(1), and one Cl(3) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom.
PN3S2(OCl2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PN3S2(OCl2)2 clusters. P(1) is bonded to one N(1), one N(2), one Cl(2), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one S(1)N2ClO tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. The P(1)-N(1) bond length is 1.61 Å. The P(1)-N(2) bond length is 1.61 Å. The P(1)-Cl(2) bond length is 1.98 Å. The P(1)-Cl(4) bond length is 1.99 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. The N(1)-S(1) bond length is 1.55 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one S(2) atom. The N(2)-S(2) bond length is 1.56 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(3)-S(1) bond length is 1.59 Å. The N(3)-S(2) bond length is 1.60 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one N(3), one O(2), and one Cl(1) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. The S(1)-O(2) bond length is 1.43 Å. The S(1)-Cl(1) bond length is 2.07 Å. In the second S site, S(2) is bonded to one N(2), one N(3), one O(1), and one Cl(3) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. The S(2)-O(1) bond length is 1.43 Å. The S(2)-Cl(3) bond length is 2.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom.