NdBaInO4 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 10-coordinate geometry to one O(3), two equivalent O(4), three equivalent O(1), and four equivalent O(2) atoms. Nd(1) is bonded in a 7-coordinate geometry to one O(1), three equivalent O(3), and three equivalent O(4) atoms. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 14-20°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Nd(1), and two equivalent In(1) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to four equivalent Ba(1) and two equivalent In(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ba(1), three equivalent Nd(1), and one In(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to two equivalent Ba(1), three equivalent Nd(1), and one In(1) atom.
NdBaInO4 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 10-coordinate geometry to one O(3), two equivalent O(4), three equivalent O(1), and four equivalent O(2) atoms. The Ba(1)-O(3) bond length is 3.44 Å. There is one shorter (2.95 Å) and one longer (3.40 Å) Ba(1)-O(4) bond length. There are a spread of Ba(1)-O(1) bond distances ranging from 2.76-3.41 Å. There are a spread of Ba(1)-O(2) bond distances ranging from 2.71-3.19 Å. Nd(1) is bonded in a 7-coordinate geometry to one O(1), three equivalent O(3), and three equivalent O(4) atoms. The Nd(1)-O(1) bond length is 2.44 Å. There are a spread of Nd(1)-O(3) bond distances ranging from 2.33-2.60 Å. There are a spread of Nd(1)-O(4) bond distances ranging from 2.30-3.06 Å. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 14-20°. The In(1)-O(3) bond length is 2.36 Å. The In(1)-O(4) bond length is 2.27 Å. There is one shorter (2.12 Å) and one longer (2.13 Å) In(1)-O(1) bond length. There is one shorter (2.17 Å) and one longer (2.18 Å) In(1)-O(2) bond length. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Nd(1), and two equivalent In(1) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to four equivalent Ba(1) and two equivalent In(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ba(1), three equivalent Nd(1), and one In(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to two equivalent Ba(1), three equivalent Nd(1), and one In(1) atom.