Na3PO3S crystallizes in the trigonal R3c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. P(1) is bonded in a distorted tetrahedral geometry to one S(1) and three equivalent O(1) atoms. S(1) is bonded in a 7-coordinate geometry to six equivalent Na(1) and one P(1) atom. O(1) is bonded to four equivalent Na(1) and one P(1) atom to form a mixture of distorted corner and edge-sharing ONa4P trigonal bipyramids.
Na3PO3S crystallizes in the trigonal R3c space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent O(1) atoms. There is one shorter (2.95 Å) and one longer (3.03 Å) Na(1)-S(1) bond length. There are a spread of Na(1)-O(1) bond distances ranging from 2.38-2.59 Å. P(1) is bonded in a distorted tetrahedral geometry to one S(1) and three equivalent O(1) atoms. The P(1)-S(1) bond length is 2.10 Å. All P(1)-O(1) bond lengths are 1.55 Å. S(1) is bonded in a 7-coordinate geometry to six equivalent Na(1) and one P(1) atom. O(1) is bonded to four equivalent Na(1) and one P(1) atom to form a mixture of distorted corner and edge-sharing ONa4P trigonal bipyramids.