GaCl4N2Se3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four GaCl4 clusters and four N2Se3Cl clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In each N2Se3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(3) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(1) atom. In the second Se site, Se(2) is bonded in a distorted water-like geometry to one N(2) and one Cl(5) atom. In the third Se site, Se(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(5) is bonded in a single-bond geometry to one Se(2) atom.
GaCl4N2Se3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four GaCl4 clusters and four N2Se3Cl clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Ga(1)-Cl(1) bond length is 2.23 Å. The Ga(1)-Cl(2) bond length is 2.20 Å. The Ga(1)-Cl(3) bond length is 2.21 Å. The Ga(1)-Cl(4) bond length is 2.19 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. In each N2Se3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(3) atom. The N(1)-Se(1) bond length is 1.76 Å. The N(1)-Se(3) bond length is 1.73 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(3) atom. The N(2)-Se(2) bond length is 1.75 Å. The N(2)-Se(3) bond length is 1.80 Å. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(1) atom. In the second Se site, Se(2) is bonded in a distorted water-like geometry to one N(2) and one Cl(5) atom. The Se(2)-Cl(5) bond length is 2.28 Å. In the third Se site, Se(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(5) is bonded in a single-bond geometry to one Se(2) atom.