Cd(FeN)2 crystallizes in the monoclinic C2/m space group. Fe(1) is bonded to one Cd(1) and four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing FeCdN4 tetrahedra. Cd(1) is bonded in a 8-coordinate geometry to two equivalent Fe(1) and six equivalent Cd(1) atoms. N(1) is bonded to four equivalent Fe(1) atoms to form a mixture of distorted edge and corner-sharing NFe4 trigonal pyramids.
Cd(FeN)2 crystallizes in the monoclinic C2/m space group. Fe(1) is bonded to one Cd(1) and four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing FeCdN4 tetrahedra. The Fe(1)-Cd(1) bond length is 2.97 Å. There are a spread of Fe(1)-N(1) bond distances ranging from 1.83-2.02 Å. Cd(1) is bonded in a 8-coordinate geometry to two equivalent Fe(1) and six equivalent Cd(1) atoms. There are four shorter (3.10 Å) and two longer (3.17 Å) Cd(1)-Cd(1) bond lengths. N(1) is bonded to four equivalent Fe(1) atoms to form a mixture of distorted edge and corner-sharing NFe4 trigonal pyramids.