(Na)2HgAlBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a HgAlBr6 framework. In the HgAlBr6 framework, Hg(1) is bonded to six equivalent Br(1) atoms to form HgBr6 octahedra that share corners with six equivalent Al(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Al(1) is bonded to six equivalent Br(1) atoms to form AlBr6 octahedra that share corners with six equivalent Hg(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Hg(1) and one Al(1) atom.
(Na)2HgAlBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a HgAlBr6 framework. In the HgAlBr6 framework, Hg(1) is bonded to six equivalent Br(1) atoms to form HgBr6 octahedra that share corners with six equivalent Al(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Hg(1)-Br(1) bond lengths are 2.94 Å. Al(1) is bonded to six equivalent Br(1) atoms to form AlBr6 octahedra that share corners with six equivalent Hg(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-Br(1) bond lengths are 2.54 Å. Br(1) is bonded in a linear geometry to one Hg(1) and one Al(1) atom.