CuOHF crystallizes in the monoclinic P2_1/c space group. Cu(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form distorted edge-sharing CuO3F3 octahedra. H(1) is bonded in a distorted linear geometry to one O(1) and one F(1) atom. O(1) is bonded to three equivalent Cu(1) and one H(1) atom to form a mixture of distorted corner and edge-sharing OCu3H tetrahedra. F(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Cu(1) and one H(1) atom.
CuOHF crystallizes in the monoclinic P2_1/c space group. Cu(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form distorted edge-sharing CuO3F3 octahedra. There are two shorter (1.96 Å) and one longer (1.97 Å) Cu(1)-O(1) bond length. There are a spread of Cu(1)-F(1) bond distances ranging from 1.94-2.36 Å. H(1) is bonded in a distorted linear geometry to one O(1) and one F(1) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-F(1) bond length is 1.57 Å. O(1) is bonded to three equivalent Cu(1) and one H(1) atom to form a mixture of distorted corner and edge-sharing OCu3H tetrahedra. F(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Cu(1) and one H(1) atom.