Cs2Pd3S4 crystallizes in the orthorhombic Fmmm space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Pd(1), and two equivalent Pd(2) atoms.
Cs2Pd3S4 crystallizes in the orthorhombic Fmmm space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. There are a spread of Cs(1)-S(1) bond distances ranging from 3.64-3.82 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. All Pd(1)-S(1) bond lengths are 2.36 Å. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. All Pd(2)-S(1) bond lengths are 2.36 Å. S(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Pd(1), and two equivalent Pd(2) atoms.