CeAlO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ce(1) is bonded to twelve equivalent O(1) atoms to form CeO12 cuboctahedra that share corners with twelve equivalent Ce(1)O12 cuboctahedra, faces with six equivalent Ce(1)O12 cuboctahedra, and faces with eight equivalent Al(1)O6 octahedra. Al(1) is bonded to six equivalent O(1) atoms to form AlO6 octahedra that share corners with six equivalent Al(1)O6 octahedra and faces with eight equivalent Ce(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent Ce(1) and two equivalent Al(1) atoms.
CeAlO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ce(1) is bonded to twelve equivalent O(1) atoms to form CeO12 cuboctahedra that share corners with twelve equivalent Ce(1)O12 cuboctahedra, faces with six equivalent Ce(1)O12 cuboctahedra, and faces with eight equivalent Al(1)O6 octahedra. All Ce(1)-O(1) bond lengths are 2.66 Å. Al(1) is bonded to six equivalent O(1) atoms to form AlO6 octahedra that share corners with six equivalent Al(1)O6 octahedra and faces with eight equivalent Ce(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Al(1)-O(1) bond lengths are 1.88 Å. O(1) is bonded in a distorted linear geometry to four equivalent Ce(1) and two equivalent Al(1) atoms.