Na3Ga is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to four equivalent Na(2) and four equivalent Ga(1) atoms to form a mixture of distorted corner, face, and edge-sharing NaNa4Ga4 tetrahedra. In the second Na site, Na(2) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms. Ga(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms.
Na3Ga is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to four equivalent Na(2) and four equivalent Ga(1) atoms to form a mixture of distorted corner, face, and edge-sharing NaNa4Ga4 tetrahedra. All Na(1)-Na(2) bond lengths are 3.31 Å. All Na(1)-Ga(1) bond lengths are 3.31 Å. In the second Na site, Na(2) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms. Ga(1) is bonded in a body-centered cubic geometry to eight equivalent Na(1) atoms.