KrSbF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrSbF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Kr(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Kr(1) and one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom.
KrSbF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrSbF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. The Kr(1)-F(3) bond length is 1.82 Å. The Kr(1)-F(4) bond length is 2.11 Å. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. The Sb(1)-F(1) bond length is 1.88 Å. The Sb(1)-F(2) bond length is 1.88 Å. The Sb(1)-F(4) bond length is 2.02 Å. The Sb(1)-F(5) bond length is 1.88 Å. The Sb(1)-F(6) bond length is 1.89 Å. The Sb(1)-F(7) bond length is 1.88 Å. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Kr(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Kr(1) and one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom.