Rb(RuAs)2 crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded in a body-centered cubic geometry to eight equivalent As(1) atoms. Ru(1) is bonded to four equivalent As(1) atoms to form a mixture of distorted edge and corner-sharing RuAs4 tetrahedra. As(1) is bonded in a 8-coordinate geometry to four equivalent Rb(1) and four equivalent Ru(1) atoms.
Rb(RuAs)2 crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded in a body-centered cubic geometry to eight equivalent As(1) atoms. All Rb(1)-As(1) bond lengths are 3.59 Å. Ru(1) is bonded to four equivalent As(1) atoms to form a mixture of distorted edge and corner-sharing RuAs4 tetrahedra. All Ru(1)-As(1) bond lengths are 2.42 Å. As(1) is bonded in a 8-coordinate geometry to four equivalent Rb(1) and four equivalent Ru(1) atoms.