CaPd3C is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ca(1) is bonded to twelve equivalent Pd(1) atoms to form CaPd12 cuboctahedra that share corners with twelve equivalent Ca(1)Pd12 cuboctahedra, faces with six equivalent Ca(1)Pd12 cuboctahedra, and faces with eight equivalent C(1)Pd6 octahedra. Pd(1) is bonded to four equivalent Ca(1) and two equivalent C(1) atoms to form a mixture of distorted corner, edge, and face-sharing PdCa4C2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. C(1) is bonded to six equivalent Pd(1) atoms to form CPd6 octahedra that share corners with six equivalent C(1)Pd6 octahedra and faces with eight equivalent Ca(1)Pd12 cuboctahedra. The corner-sharing octahedra are not tilted.
CaPd3C is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ca(1) is bonded to twelve equivalent Pd(1) atoms to form CaPd12 cuboctahedra that share corners with twelve equivalent Ca(1)Pd12 cuboctahedra, faces with six equivalent Ca(1)Pd12 cuboctahedra, and faces with eight equivalent C(1)Pd6 octahedra. All Ca(1)-Pd(1) bond lengths are 3.03 Å. Pd(1) is bonded to four equivalent Ca(1) and two equivalent C(1) atoms to form a mixture of distorted corner, edge, and face-sharing PdCa4C2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. Both Pd(1)-C(1) bond lengths are 2.14 Å. C(1) is bonded to six equivalent Pd(1) atoms to form CPd6 octahedra that share corners with six equivalent C(1)Pd6 octahedra and faces with eight equivalent Ca(1)Pd12 cuboctahedra. The corner-sharing octahedra are not tilted.