K(WO3)3 crystallizes in the hexagonal P6_3mc space group. K(1) is bonded in a 12-coordinate geometry to six equivalent O(2) and six equivalent O(3) atoms. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-31°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent K(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1) and two equivalent W(1) atoms.
K(WO3)3 crystallizes in the hexagonal P6_3mc space group. K(1) is bonded in a 12-coordinate geometry to six equivalent O(2) and six equivalent O(3) atoms. There are three shorter (3.26 Å) and three longer (3.34 Å) K(1)-O(2) bond lengths. There are three shorter (3.19 Å) and three longer (3.42 Å) K(1)-O(3) bond lengths. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-31°. Both W(1)-O(1) bond lengths are 1.91 Å. Both W(1)-O(2) bond lengths are 1.92 Å. Both W(1)-O(3) bond lengths are 1.92 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent K(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1) and two equivalent W(1) atoms.