VP1 is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent P(1) atoms to form a mixture of corner, edge, and face-sharing VP6 octahedra. The corner-sharing octahedral tilt angles are 45°. P(1) is bonded to six equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing PV6 pentagonal pyramids.
VP1 is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent P(1) atoms to form a mixture of corner, edge, and face-sharing VP6 octahedra. The corner-sharing octahedral tilt angles are 45°. All V(1)-P(1) bond lengths are 2.39 Å. P(1) is bonded to six equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing PV6 pentagonal pyramids.