ZrIn crystallizes in the trigonal R-3m space group. Zr(1) is bonded to six equivalent Zr(1) and six equivalent In(1) atoms to form distorted ZrZr6In6 cuboctahedra that share corners with twelve equivalent Zr(1)Zr6In6 cuboctahedra, edges with twelve equivalent Zr(1)Zr6In6 cuboctahedra, edges with twelve equivalent In(1)Zr6In6 cuboctahedra, faces with six equivalent Zr(1)Zr6In6 cuboctahedra, and faces with twelve equivalent In(1)Zr6In6 cuboctahedra. In(1) is bonded to six equivalent Zr(1) and six equivalent In(1) atoms to form distorted InZr6In6 cuboctahedra that share corners with twelve equivalent In(1)Zr6In6 cuboctahedra, edges with twelve equivalent Zr(1)Zr6In6 cuboctahedra, edges with twelve equivalent In(1)Zr6In6 cuboctahedra, faces with six equivalent In(1)Zr6In6 cuboctahedra, and faces with twelve equivalent Zr(1)Zr6In6 cuboctahedra.
ZrIn crystallizes in the trigonal R-3m space group. Zr(1) is bonded to six equivalent Zr(1) and six equivalent In(1) atoms to form distorted ZrZr6In6 cuboctahedra that share corners with twelve equivalent Zr(1)Zr6In6 cuboctahedra, edges with twelve equivalent Zr(1)Zr6In6 cuboctahedra, edges with twelve equivalent In(1)Zr6In6 cuboctahedra, faces with six equivalent Zr(1)Zr6In6 cuboctahedra, and faces with twelve equivalent In(1)Zr6In6 cuboctahedra. All Zr(1)-Zr(1) bond lengths are 3.24 Å. All Zr(1)-In(1) bond lengths are 3.17 Å. In(1) is bonded to six equivalent Zr(1) and six equivalent In(1) atoms to form distorted InZr6In6 cuboctahedra that share corners with twelve equivalent In(1)Zr6In6 cuboctahedra, edges with twelve equivalent Zr(1)Zr6In6 cuboctahedra, edges with twelve equivalent In(1)Zr6In6 cuboctahedra, faces with six equivalent In(1)Zr6In6 cuboctahedra, and faces with twelve equivalent Zr(1)Zr6In6 cuboctahedra. All In(1)-In(1) bond lengths are 3.24 Å.