(Na)2VAuF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a VAuF6 framework. In the VAuF6 framework, V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedra are not tilted. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted linear geometry to one V(1) and one Au(1) atom.
(Na)2VAuF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a VAuF6 framework. In the VAuF6 framework, V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedra are not tilted. All V(1)-F(1) bond lengths are 1.94 Å. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Au(1)-F(1) bond lengths are 2.41 Å. F(1) is bonded in a distorted linear geometry to one V(1) and one Au(1) atom.