PdAs2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Pd(1) is bonded to six equivalent O(1) atoms to form PdO6 octahedra that share corners with twelve equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. As(1) is bonded to six equivalent O(1) atoms to form AsO6 octahedra that share corners with six equivalent Pd(1)O6 octahedra and edges with three equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a distorted trigonal planar geometry to one Pd(1) and two equivalent As(1) atoms.
PdAs2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Pd(1) is bonded to six equivalent O(1) atoms to form PdO6 octahedra that share corners with twelve equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Pd(1)-O(1) bond lengths are 2.24 Å. As(1) is bonded to six equivalent O(1) atoms to form AsO6 octahedra that share corners with six equivalent Pd(1)O6 octahedra and edges with three equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. All As(1)-O(1) bond lengths are 1.84 Å. O(1) is bonded in a distorted trigonal planar geometry to one Pd(1) and two equivalent As(1) atoms.