Y(TiS2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Y(1) is bonded to four equivalent S(1) atoms to form YS4 tetrahedra that share corners with twelve equivalent Ti(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. Ti(1) is bonded to six equivalent S(1) atoms to form TiS6 octahedra that share corners with six equivalent Y(1)S4 tetrahedra and edges with six equivalent Ti(1)S6 octahedra. S(1) is bonded in a rectangular see-saw-like geometry to one Y(1) and three equivalent Ti(1) atoms.
Y(TiS2)2 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Y(1) is bonded to four equivalent S(1) atoms to form YS4 tetrahedra that share corners with twelve equivalent Ti(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 54-62°. All Y(1)-S(1) bond lengths are 2.59 Å. Ti(1) is bonded to six equivalent S(1) atoms to form TiS6 octahedra that share corners with six equivalent Y(1)S4 tetrahedra and edges with six equivalent Ti(1)S6 octahedra. There are four shorter (2.54 Å) and two longer (2.55 Å) Ti(1)-S(1) bond lengths. S(1) is bonded in a rectangular see-saw-like geometry to one Y(1) and three equivalent Ti(1) atoms.