P2O5 is Indium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two P2O5 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(10), one O(18), and one O(6) atom. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(12), one O(17), and one O(18) atom. In the third P site, P(3) is bonded to one O(10), one O(16), one O(17), and one O(5) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form corner-sharing PO4 tetrahedra. There are ten inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one P(4) and one O(12) atom. In the second O site, O(5) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the third O site, O(6) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one P(4) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one P(4) atom. In the sixth O site, O(10) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the seventh O site, O(12) is bonded in a distorted single-bond geometry to one P(2) and one O(4) atom. In the eighth O site, O(16) is bonded in a single-bond geometry to one P(3) atom. In the ninth O site, O(17) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the tenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom.
P2O5 is Indium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two P2O5 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(10), one O(18), and one O(6) atom. The P(1)-O(10) bond length is 1.63 Å. The P(1)-O(18) bond length is 1.59 Å. The P(1)-O(6) bond length is 1.52 Å. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(12), one O(17), and one O(18) atom. The P(2)-O(12) bond length is 1.60 Å. The P(2)-O(17) bond length is 1.65 Å. The P(2)-O(18) bond length is 1.68 Å. In the third P site, P(3) is bonded to one O(10), one O(16), one O(17), and one O(5) atom to form corner-sharing PO4 tetrahedra. The P(3)-O(10) bond length is 1.62 Å. The P(3)-O(16) bond length is 1.46 Å. The P(3)-O(17) bond length is 1.60 Å. The P(3)-O(5) bond length is 1.60 Å. In the fourth P site, P(4) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form corner-sharing PO4 tetrahedra. The P(4)-O(4) bond length is 1.62 Å. The P(4)-O(5) bond length is 1.64 Å. The P(4)-O(8) bond length is 1.54 Å. The P(4)-O(9) bond length is 1.49 Å. There are ten inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one P(4) and one O(12) atom. The O(4)-O(12) bond length is 1.61 Å. In the second O site, O(5) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the third O site, O(6) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one P(4) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one P(4) atom. In the sixth O site, O(10) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the seventh O site, O(12) is bonded in a distorted single-bond geometry to one P(2) and one O(4) atom. In the eighth O site, O(16) is bonded in a single-bond geometry to one P(3) atom. In the ninth O site, O(17) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the tenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom.