CH3Cl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four chloromethane molecules. C(1) is bonded in a tetrahedral geometry to one H(1), two equivalent H(2), and one Cl(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom.
CH3Cl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four chloromethane molecules. C(1) is bonded in a tetrahedral geometry to one H(1), two equivalent H(2), and one Cl(1) atom. The C(1)-H(1) bond length is 1.10 Å. Both C(1)-H(2) bond lengths are 1.10 Å. The C(1)-Cl(1) bond length is 1.79 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom.