LaCrZnSbO6 crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-44°. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-44°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), one Cr(1), one Zn(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(1), one Cr(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one La(1), one Cr(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted tetrahedral geometry to one La(1), one Cr(1), one Zn(1), and one Sb(1) atom.
LaCrZnSbO6 crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. The La(1)-O(1) bond length is 2.39 Å. The La(1)-O(2) bond length is 2.37 Å. The La(1)-O(3) bond length is 2.35 Å. The La(1)-O(6) bond length is 2.51 Å. There is one shorter (2.67 Å) and one longer (2.85 Å) La(1)-O(4) bond length. There is one shorter (2.70 Å) and one longer (2.81 Å) La(1)-O(5) bond length. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-44°. The Cr(1)-O(1) bond length is 2.08 Å. The Cr(1)-O(2) bond length is 2.01 Å. The Cr(1)-O(3) bond length is 2.03 Å. The Cr(1)-O(4) bond length is 2.10 Å. The Cr(1)-O(5) bond length is 2.14 Å. The Cr(1)-O(6) bond length is 2.13 Å. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.51 Å. The Zn(1)-O(4) bond length is 2.10 Å. The Zn(1)-O(5) bond length is 2.12 Å. The Zn(1)-O(6) bond length is 2.04 Å. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-44°. The Sb(1)-O(1) bond length is 2.08 Å. The Sb(1)-O(2) bond length is 2.02 Å. The Sb(1)-O(3) bond length is 2.01 Å. The Sb(1)-O(4) bond length is 2.22 Å. The Sb(1)-O(5) bond length is 2.16 Å. The Sb(1)-O(6) bond length is 2.17 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), one Cr(1), one Zn(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(1), one Cr(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one La(1), one Cr(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent La(1), one Cr(1), one Zn(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted tetrahedral geometry to one La(1), one Cr(1), one Zn(1), and one Sb(1) atom.