LiPtF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Pt(1) atom.
LiPtF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Li(1)-F(1) bond lengths are 1.98 Å. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Pt(1)-F(1) bond lengths are 1.91 Å. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Pt(1) atom.