Ga2O3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ga(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge, corner, and face-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. O(1) is bonded to four equivalent Ga(1) atoms to form a mixture of distorted edge and corner-sharing OGa4 trigonal pyramids.
Ga2O3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ga(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge, corner, and face-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. There are three shorter (1.93 Å) and three longer (2.08 Å) Ga(1)-O(1) bond lengths. O(1) is bonded to four equivalent Ga(1) atoms to form a mixture of distorted edge and corner-sharing OGa4 trigonal pyramids.