SmTiGe crystallizes in the tetragonal I4/mmm space group. Sm(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. Ti(1) is bonded in a distorted square co-planar geometry to four equivalent Ge(1) atoms. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Sm(1) and four equivalent Ti(1) atoms.
SmTiGe crystallizes in the tetragonal I4/mmm space group. Sm(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. There are four shorter (3.01 Å) and one longer (3.24 Å) Sm(1)-Ge(1) bond length. Ti(1) is bonded in a distorted square co-planar geometry to four equivalent Ge(1) atoms. All Ti(1)-Ge(1) bond lengths are 2.77 Å. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Sm(1) and four equivalent Ti(1) atoms.