AgSCN crystallizes in the orthorhombic Pnnm space group. Ag(1) is bonded to one N(1) and three equivalent S(1) atoms to form distorted corner-sharing AgS3N trigonal pyramids. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(1) atom. S(1) is bonded to three equivalent Ag(1) and one C(1) atom to form corner-sharing SAg3C trigonal pyramids.
AgSCN crystallizes in the orthorhombic Pnnm space group. Ag(1) is bonded to one N(1) and three equivalent S(1) atoms to form distorted corner-sharing AgS3N trigonal pyramids. The Ag(1)-N(1) bond length is 2.20 Å. There are two shorter (2.60 Å) and one longer (2.80 Å) Ag(1)-S(1) bond length. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.66 Å. N(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(1) atom. S(1) is bonded to three equivalent Ag(1) and one C(1) atom to form corner-sharing SAg3C trigonal pyramids.