NHS7 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four heptathiazocine molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1) and two equivalent S(4) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom.
NHS7 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four heptathiazocine molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1) and two equivalent S(4) atoms. The N(1)-H(1) bond length is 1.03 Å. Both N(1)-S(4) bond lengths are 1.68 Å. H(1) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(4) atom. The S(1)-S(2) bond length is 2.06 Å. The S(1)-S(4) bond length is 2.11 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. The S(2)-S(3) bond length is 2.06 Å. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom.