Ag3In is Titanium Disilicide-like structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 10-coordinate geometry to two equivalent Ag(2), six equivalent Ag(1), and two equivalent In(1) atoms. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to four equivalent Ag(1) and six equivalent Ag(2) atoms. In(1) is bonded in a 10-coordinate geometry to four equivalent Ag(1) and six equivalent In(1) atoms.
Ag3In is Titanium Disilicide-like structured and crystallizes in the orthorhombic Cmmm space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 10-coordinate geometry to two equivalent Ag(2), six equivalent Ag(1), and two equivalent In(1) atoms. Both Ag(1)-Ag(2) bond lengths are 2.85 Å. There are four shorter (3.02 Å) and two longer (3.10 Å) Ag(1)-Ag(1) bond lengths. Both Ag(1)-In(1) bond lengths are 2.97 Å. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to four equivalent Ag(1) and six equivalent Ag(2) atoms. There are four shorter (3.02 Å) and two longer (3.10 Å) Ag(2)-Ag(2) bond lengths. In(1) is bonded in a 10-coordinate geometry to four equivalent Ag(1) and six equivalent In(1) atoms. There are four shorter (3.02 Å) and two longer (3.10 Å) In(1)-In(1) bond lengths.