(Tl)6H2 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure consists of four 1333-74-0 atoms inside a Tl framework. In the Tl framework, there are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to four equivalent Tl(2) atoms to form a mixture of distorted edge and corner-sharing TlTl4 tetrahedra. In the second Tl site, Tl(2) is bonded in a body-centered cubic geometry to eight equivalent Tl(1) atoms.
(Tl)6H2 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure consists of four 1333-74-0 atoms inside a Tl framework. In the Tl framework, there are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to four equivalent Tl(2) atoms to form a mixture of distorted edge and corner-sharing TlTl4 tetrahedra. All Tl(1)-Tl(2) bond lengths are 3.24 Å. In the second Tl site, Tl(2) is bonded in a body-centered cubic geometry to eight equivalent Tl(1) atoms.