PdCl2PdCl4(RhN5OCl2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two palladium(ii) chloride molecules, two tetrachloropalladium molecules, and four RhN5OCl2 clusters. In each RhN5OCl2 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. In the second N site, N(2) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. In the third N site, N(3) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. In the fourth N site, N(4) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(5) atom. O(1) is bonded in a water-like geometry to one N(2) and one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(5) atom.
PdCl2PdCl4(RhN5OCl2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two palladium(ii) chloride molecules, two tetrachloropalladium molecules, and four RhN5OCl2 clusters. In each RhN5OCl2 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. The Rh(1)-N(1) bond length is 2.28 Å. The Rh(1)-N(2) bond length is 1.91 Å. The Rh(1)-N(3) bond length is 1.92 Å. The Rh(1)-N(4) bond length is 2.34 Å. The Rh(1)-N(5) bond length is 1.82 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. The N(1)-Cl(2) bond length is 1.53 Å. In the second N site, N(2) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. The N(2)-O(1) bond length is 1.37 Å. In the third N site, N(3) is bonded in an L-shaped geometry to one Rh(1) and one O(1) atom. The N(3)-O(1) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in an L-shaped geometry to one Rh(1) and one Cl(2) atom. The N(4)-Cl(2) bond length is 1.53 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cl(5) atom. The N(5)-Cl(5) bond length is 1.66 Å. O(1) is bonded in a water-like geometry to one N(2) and one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(4) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one N(5) atom.