CaCrF4 crystallizes in the tetragonal I4/mcm space group. Ca(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. Cr(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to two equivalent Ca(1) and one Cr(1) atom.
CaCrF4 crystallizes in the tetragonal I4/mcm space group. Ca(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. All Ca(1)-F(1) bond lengths are 2.36 Å. Cr(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All Cr(1)-F(1) bond lengths are 1.97 Å. F(1) is bonded in a distorted trigonal planar geometry to two equivalent Ca(1) and one Cr(1) atom.