KZnSb crystallizes in the hexagonal P-6m2 space group. K(1) is bonded to six equivalent Zn(1) and six equivalent Sb(1) atoms to form a mixture of face and edge-sharing KZn6Sb6 cuboctahedra. Zn(1) is bonded in a distorted trigonal planar geometry to six equivalent K(1) and three equivalent Sb(1) atoms. Sb(1) is bonded in a distorted trigonal planar geometry to six equivalent K(1) and three equivalent Zn(1) atoms.
KZnSb crystallizes in the hexagonal P-6m2 space group. K(1) is bonded to six equivalent Zn(1) and six equivalent Sb(1) atoms to form a mixture of face and edge-sharing KZn6Sb6 cuboctahedra. All K(1)-Zn(1) bond lengths are 3.74 Å. All K(1)-Sb(1) bond lengths are 3.74 Å. Zn(1) is bonded in a distorted trigonal planar geometry to six equivalent K(1) and three equivalent Sb(1) atoms. All Zn(1)-Sb(1) bond lengths are 2.61 Å. Sb(1) is bonded in a distorted trigonal planar geometry to six equivalent K(1) and three equivalent Zn(1) atoms.