((CH3)2NH2)2SnH6(CCl2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylazanium molecules and one SnH6(CCl2)2 cluster. In the SnH6(CCl2)2 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent C(3), two equivalent Cl(1), and two equivalent Cl(2) atoms. C(3) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(4), one H(5), and one H(6) atom. There are three inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Sn(1) atom.
((CH3)2NH2)2SnH6(CCl2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylazanium molecules and one SnH6(CCl2)2 cluster. In the SnH6(CCl2)2 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent C(3), two equivalent Cl(1), and two equivalent Cl(2) atoms. Both Sn(1)-C(3) bond lengths are 2.15 Å. Both Sn(1)-Cl(1) bond lengths are 2.68 Å. Both Sn(1)-Cl(2) bond lengths are 2.66 Å. C(3) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(4), one H(5), and one H(6) atom. The C(3)-H(4) bond length is 1.09 Å. The C(3)-H(5) bond length is 1.09 Å. The C(3)-H(6) bond length is 1.09 Å. There are three inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Sn(1) atom.