K2AgInBr6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. K(1) is bonded to twelve equivalent Br(1) atoms to form KBr12 cuboctahedra that share corners with twelve equivalent K(1)Br12 cuboctahedra, faces with six equivalent K(1)Br12 cuboctahedra, faces with four equivalent Ag(1)Br6 octahedra, and faces with four equivalent In(1)Br6 octahedra. Ag(1) is bonded to six equivalent Br(1) atoms to form AgBr6 octahedra that share corners with six equivalent In(1)Br6 octahedra and faces with eight equivalent K(1)Br12 cuboctahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to six equivalent Br(1) atoms to form InBr6 octahedra that share corners with six equivalent Ag(1)Br6 octahedra and faces with eight equivalent K(1)Br12 cuboctahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to four equivalent K(1), one Ag(1), and one In(1) atom.
K2AgInBr6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. K(1) is bonded to twelve equivalent Br(1) atoms to form KBr12 cuboctahedra that share corners with twelve equivalent K(1)Br12 cuboctahedra, faces with six equivalent K(1)Br12 cuboctahedra, faces with four equivalent Ag(1)Br6 octahedra, and faces with four equivalent In(1)Br6 octahedra. All K(1)-Br(1) bond lengths are 3.92 Å. Ag(1) is bonded to six equivalent Br(1) atoms to form AgBr6 octahedra that share corners with six equivalent In(1)Br6 octahedra and faces with eight equivalent K(1)Br12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ag(1)-Br(1) bond lengths are 2.83 Å. In(1) is bonded to six equivalent Br(1) atoms to form InBr6 octahedra that share corners with six equivalent Ag(1)Br6 octahedra and faces with eight equivalent K(1)Br12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-Br(1) bond lengths are 2.72 Å. Br(1) is bonded in a linear geometry to four equivalent K(1), one Ag(1), and one In(1) atom.