MnIn2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mn(1) is bonded to four equivalent S(1) atoms to form MnS4 tetrahedra that share corners with twelve equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles are 57°. In(1) is bonded to six equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Mn(1)S4 tetrahedra and edges with six equivalent In(1)S6 octahedra. S(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1) and three equivalent In(1) atoms.
MnIn2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mn(1) is bonded to four equivalent S(1) atoms to form MnS4 tetrahedra that share corners with twelve equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Mn(1)-S(1) bond lengths are 2.43 Å. In(1) is bonded to six equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Mn(1)S4 tetrahedra and edges with six equivalent In(1)S6 octahedra. All In(1)-S(1) bond lengths are 2.63 Å. S(1) is bonded in a distorted rectangular see-saw-like geometry to one Mn(1) and three equivalent In(1) atoms.