SrLaTiMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(10), two equivalent O(12), and two equivalent O(8) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(11), two equivalent O(7), and two equivalent O(9) atoms. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form TiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra and corners with three equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra and corners with three equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one Ti(2), and one Mn(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one Ti(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one Ti(2), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one Ti(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one Ti(2), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one Ti(1), and one Mn(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one Ti(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one Ti(2), and one Mn(1) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one Ti(1), and one Mn(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one Ti(2), and one Mn(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one Ti(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one Ti(2), and one Mn(1) atom.
SrLaTiMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. The Sr(1)-O(10) bond length is 2.83 Å. The Sr(1)-O(11) bond length is 2.94 Å. The Sr(1)-O(12) bond length is 2.90 Å. The Sr(1)-O(7) bond length is 2.71 Å. The Sr(1)-O(8) bond length is 2.68 Å. The Sr(1)-O(9) bond length is 2.85 Å. There is one shorter (2.55 Å) and one longer (3.07 Å) Sr(1)-O(2) bond length. There is one shorter (2.55 Å) and one longer (3.05 Å) Sr(1)-O(4) bond length. There is one shorter (2.51 Å) and one longer (3.17 Å) Sr(1)-O(6) bond length. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), one O(9), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. The Sr(2)-O(10) bond length is 2.85 Å. The Sr(2)-O(11) bond length is 2.66 Å. The Sr(2)-O(12) bond length is 2.75 Å. The Sr(2)-O(7) bond length is 2.99 Å. The Sr(2)-O(8) bond length is 2.88 Å. The Sr(2)-O(9) bond length is 2.79 Å. There is one shorter (2.50 Å) and one longer (3.13 Å) Sr(2)-O(1) bond length. There is one shorter (2.50 Å) and one longer (3.10 Å) Sr(2)-O(3) bond length. There is one shorter (2.59 Å) and one longer (3.09 Å) Sr(2)-O(5) bond length. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(10), two equivalent O(12), and two equivalent O(8) atoms. The La(1)-O(1) bond length is 2.93 Å. The La(1)-O(2) bond length is 2.98 Å. The La(1)-O(3) bond length is 2.61 Å. The La(1)-O(4) bond length is 2.72 Å. The La(1)-O(5) bond length is 2.75 Å. The La(1)-O(6) bond length is 2.85 Å. There is one shorter (2.42 Å) and one longer (3.26 Å) La(1)-O(10) bond length. There is one shorter (2.46 Å) and one longer (3.16 Å) La(1)-O(12) bond length. There is one shorter (2.43 Å) and one longer (3.17 Å) La(1)-O(8) bond length. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent O(11), two equivalent O(7), and two equivalent O(9) atoms. The La(2)-O(1) bond length is 2.65 Å. The La(2)-O(2) bond length is 2.64 Å. The La(2)-O(3) bond length is 3.08 Å. The La(2)-O(4) bond length is 2.81 Å. The La(2)-O(5) bond length is 2.88 Å. The La(2)-O(6) bond length is 2.80 Å. There is one shorter (2.40 Å) and one longer (3.23 Å) La(2)-O(11) bond length. There is one shorter (2.42 Å) and one longer (3.17 Å) La(2)-O(7) bond length. There is one shorter (2.49 Å) and one longer (3.20 Å) La(2)-O(9) bond length. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. The Ti(1)-O(11) bond length is 1.91 Å. The Ti(1)-O(2) bond length is 2.05 Å. The Ti(1)-O(4) bond length is 1.88 Å. The Ti(1)-O(6) bond length is 1.96 Å. The Ti(1)-O(7) bond length is 2.09 Å. The Ti(1)-O(9) bond length is 2.02 Å. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(8) atom to form TiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. The Ti(2)-O(1) bond length is 1.87 Å. The Ti(2)-O(10) bond length is 2.01 Å. The Ti(2)-O(12) bond length is 2.09 Å. The Ti(2)-O(3) bond length is 2.04 Å. The Ti(2)-O(5) bond length is 1.97 Å. The Ti(2)-O(8) bond length is 1.92 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra and corners with three equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. The Mn(1)-O(10) bond length is 1.98 Å. The Mn(1)-O(12) bond length is 1.95 Å. The Mn(1)-O(2) bond length is 1.95 Å. The Mn(1)-O(4) bond length is 2.19 Å. The Mn(1)-O(6) bond length is 1.98 Å. The Mn(1)-O(8) bond length is 2.21 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra and corners with three equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-25°. The Mn(2)-O(1) bond length is 2.20 Å. The Mn(2)-O(11) bond length is 2.21 Å. The Mn(2)-O(3) bond length is 1.96 Å. The Mn(2)-O(5) bond length is 1.96 Å. The Mn(2)-O(7) bond length is 1.96 Å. The Mn(2)-O(9) bond length is 1.97 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one Ti(2), and one Mn(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one Ti(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one Ti(2), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one Ti(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Sr(2), one La(1), one La(2), one Ti(2), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(1), one La(2), one Ti(1), and one Mn(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one Ti(1), and one Mn(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one Ti(2), and one Mn(1) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one Ti(1), and one Mn(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one Ti(2), and one Mn(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(2), one Ti(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(2), two equivalent La(1), one Ti(2), and one Mn(1) atom.