CrNiF6Tl is Upper Bainite-derived structured and crystallizes in the orthorhombic Imma space group. The structure consists of four 7440-28-0 atoms inside a CrNiF6 framework. In the CrNiF6 framework, Cr(1) is bonded to two equivalent F(1) and four equivalent F(3) atoms to form CrF6 octahedra that share corners with two equivalent Cr(1)F6 octahedra and corners with four equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-45°. Ni(1) is bonded to two equivalent F(2) and four equivalent F(3) atoms to form NiF6 octahedra that share corners with two equivalent Ni(1)F6 octahedra and corners with four equivalent Cr(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Ni(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Cr(1) and one Ni(1) atom.
CrNiF6Tl is Upper Bainite-derived structured and crystallizes in the orthorhombic Imma space group. The structure consists of four 7440-28-0 atoms inside a CrNiF6 framework. In the CrNiF6 framework, Cr(1) is bonded to two equivalent F(1) and four equivalent F(3) atoms to form CrF6 octahedra that share corners with two equivalent Cr(1)F6 octahedra and corners with four equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-45°. Both Cr(1)-F(1) bond lengths are 1.97 Å. All Cr(1)-F(3) bond lengths are 1.93 Å. Ni(1) is bonded to two equivalent F(2) and four equivalent F(3) atoms to form NiF6 octahedra that share corners with two equivalent Ni(1)F6 octahedra and corners with four equivalent Cr(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-47°. Both Ni(1)-F(2) bond lengths are 1.99 Å. All Ni(1)-F(3) bond lengths are 2.03 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to two equivalent Ni(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Cr(1) and one Ni(1) atom.