Li2FeTiO4 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(7), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(6), one O(8), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with two equivalent Li(4)O5 square pyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the third Li site, Li(3) is bonded to one O(3), one O(5), one O(6), and two equivalent O(7) atoms to form distorted LiO5 square pyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, corners with two equivalent Li(4)O5 square pyramids,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-81°. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(6), and two equivalent O(8) atoms to form distorted LiO5 square pyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, corners with two equivalent Li(4)O5 square pyramids,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-81°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(3), one O(7), one O(8), and two equivalent O(5) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, edges with three equivalent Fe(2)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(4)O5 square pyramids. The corner-sharing octahedral tilt angles range from 3-12°. In the second Ti site, Ti(2) is bonded to one O(2), one O(4), one O(7), one O(8), and two equivalent O(6) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(4)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, edges with three equivalent Fe(1)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(4)O5 square pyramids. The corner-sharing octahedral tilt angles range from 3-12°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(3), one O(4), one O(6), one O(7), and two equivalent O(2) atoms to form distorted FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one Li(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 1-23°. In the second Fe site, Fe(2) is bonded to one O(3), one O(4), one O(5), one O(8), and two equivalent O(1) atoms to form distorted FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Li(4)O5 square pyramids,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one Li(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 1-23°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Ti(1), and two equivalent Fe(2) atoms to form OLi2TiFe2 trigonal bipyramids that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(3)Li3TiFe2 octahedra, corners with two equivalent O(8)Li3Ti2Fe octahedra, corners with two equivalent O(1)Li2TiFe2 trigonal bipyramids, corners with two equivalent O(2)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(7)Li3Ti2Fe octahedra,  an edgeedge with one O(8)Li3Ti2Fe octahedra, edges with two equivalent O(5)Li3Ti2Fe octahedra, edges with two equivalent O(3)Li3TiFe2 octahedra, and edges with two equivalent O(4)Li3TiFe2 octahedra. The corner-sharing octahedral tilt angles range from 16-81°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), and two equivalent Fe(1) atoms to form OLi2TiFe2 trigonal bipyramids that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(4)Li3TiFe2 octahedra, corners with two equivalent O(7)Li3Ti2Fe octahedra, corners with two equivalent O(1)Li2TiFe2 trigonal bipyramids, corners with two equivalent O(2)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(7)Li3Ti2Fe octahedra,  an edgeedge with one O(8)Li3Ti2Fe octahedra, edges with two equivalent O(6)Li3Ti2Fe octahedra, edges with two equivalent O(3)Li3TiFe2 octahedra, and edges with two equivalent O(4)Li3TiFe2 octahedra. The corner-sharing octahedral tilt angles range from 16-81°. In the third O site, O(3) is bonded to one Li(3), two equivalent Li(1), one Ti(1), one Fe(1), and one Fe(2) atom to form OLi3TiFe2 octahedra that share corners with two equivalent O(3)Li3TiFe2 octahedra, corners with two equivalent O(4)Li3TiFe2 octahedra,  a cornercorner with one O(1)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(6)Li3Ti2Fe octahedra,  an edgeedge with one O(8)Li3Ti2Fe octahedra, edges with three equivalent O(5)Li3Ti2Fe octahedra, edges with three equivalent O(7)Li3Ti2Fe octahedra, edges with two equivalent O(1)Li2TiFe2 trigonal bipyramids, and edges with two equivalent O(2)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 10-14°. In the fourth O site, O(4) is bonded to one Li(4), two equivalent Li(2), one Ti(2), one Fe(1), and one Fe(2) atom to form OLi3TiFe2 octahedra that share corners with two equivalent O(3)Li3TiFe2 octahedra, corners with two equivalent O(4)Li3TiFe2 octahedra,  a cornercorner with one O(2)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(5)Li3Ti2Fe octahedra,  an edgeedge with one O(7)Li3Ti2Fe octahedra, edges with three equivalent O(6)Li3Ti2Fe octahedra, edges with three equivalent O(8)Li3Ti2Fe octahedra, edges with two equivalent O(1)Li2TiFe2 trigonal bipyramids, and edges with two equivalent O(2)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 10-14°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(4), two equivalent Ti(1), and one Fe(2) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(7)Li3Ti2Fe octahedra,  a cornercorner with one O(8)Li3Ti2Fe octahedra, corners with two equivalent O(5)Li3Ti2Fe octahedra, corners with two equivalent O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(1)Li2TiFe2 trigonal bipyramid,  a cornercorner with one O(2)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(4)Li3TiFe2 octahedra, edges with two equivalent O(7)Li3Ti2Fe octahedra, edges with two equivalent O(8)Li3Ti2Fe octahedra, edges with three equivalent O(3)Li3TiFe2 octahedra, and edges with two equivalent O(1)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(4), two equivalent Ti(2), and one Fe(1) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(7)Li3Ti2Fe octahedra,  a cornercorner with one O(8)Li3Ti2Fe octahedra, corners with two equivalent O(5)Li3Ti2Fe octahedra, corners with two equivalent O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(1)Li2TiFe2 trigonal bipyramid,  a cornercorner with one O(2)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(3)Li3TiFe2 octahedra, edges with two equivalent O(7)Li3Ti2Fe octahedra, edges with two equivalent O(8)Li3Ti2Fe octahedra, edges with three equivalent O(4)Li3TiFe2 octahedra, and edges with two equivalent O(2)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the seventh O site, O(7) is bonded to one Li(1), two equivalent Li(3), one Ti(1), one Ti(2), and one Fe(1) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra, corners with two equivalent O(7)Li3Ti2Fe octahedra, corners with two equivalent O(8)Li3Ti2Fe octahedra, corners with two equivalent O(2)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(4)Li3TiFe2 octahedra, edges with two equivalent O(5)Li3Ti2Fe octahedra, edges with two equivalent O(6)Li3Ti2Fe octahedra, edges with three equivalent O(3)Li3TiFe2 octahedra,  an edgeedge with one O(1)Li2TiFe2 trigonal bipyramid, and  an edgeedge with one O(2)Li2TiFe2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-22°. In the eighth O site, O(8) is bonded to one Li(2), two equivalent Li(4), one Ti(1), one Ti(2), and one Fe(2) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra, corners with two equivalent O(7)Li3Ti2Fe octahedra, corners with two equivalent O(8)Li3Ti2Fe octahedra, corners with two equivalent O(1)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(3)Li3TiFe2 octahedra, edges with two equivalent O(5)Li3Ti2Fe octahedra, edges with two equivalent O(6)Li3Ti2Fe octahedra, edges with three equivalent O(4)Li3TiFe2 octahedra,  an edgeedge with one O(1)Li2TiFe2 trigonal bipyramid, and  an edgeedge with one O(2)Li2TiFe2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-22°.
Li2FeTiO4 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(7), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles range from 1-19°. The Li(1)-O(1) bond length is 2.13 Å. The Li(1)-O(2) bond length is 2.23 Å. The Li(1)-O(5) bond length is 2.21 Å. The Li(1)-O(7) bond length is 2.24 Å. There is one shorter (2.02 Å) and one longer (2.04 Å) Li(1)-O(3) bond length. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(6), one O(8), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  a cornercorner with one Li(4)O5 square pyramid,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with two equivalent Li(4)O5 square pyramids. The corner-sharing octahedral tilt angles range from 1-19°. The Li(2)-O(1) bond length is 2.23 Å. The Li(2)-O(2) bond length is 2.13 Å. The Li(2)-O(6) bond length is 2.21 Å. The Li(2)-O(8) bond length is 2.24 Å. There is one shorter (2.01 Å) and one longer (2.04 Å) Li(2)-O(4) bond length. In the third Li site, Li(3) is bonded to one O(3), one O(5), one O(6), and two equivalent O(7) atoms to form distorted LiO5 square pyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, corners with two equivalent Li(4)O5 square pyramids,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-81°. The Li(3)-O(3) bond length is 2.15 Å. The Li(3)-O(5) bond length is 2.10 Å. The Li(3)-O(6) bond length is 2.26 Å. Both Li(3)-O(7) bond lengths are 2.05 Å. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(6), and two equivalent O(8) atoms to form distorted LiO5 square pyramids that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids, corners with two equivalent Li(4)O5 square pyramids,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-81°. The Li(4)-O(4) bond length is 2.14 Å. The Li(4)-O(5) bond length is 2.26 Å. The Li(4)-O(6) bond length is 2.10 Å. Both Li(4)-O(8) bond lengths are 2.05 Å. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(3), one O(7), one O(8), and two equivalent O(5) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, edges with three equivalent Fe(2)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(4)O5 square pyramids. The corner-sharing octahedral tilt angles range from 3-12°. The Ti(1)-O(1) bond length is 1.96 Å. The Ti(1)-O(3) bond length is 1.94 Å. The Ti(1)-O(7) bond length is 2.46 Å. The Ti(1)-O(8) bond length is 1.85 Å. There is one shorter (1.94 Å) and one longer (2.11 Å) Ti(1)-O(5) bond length. In the second Ti site, Ti(2) is bonded to one O(2), one O(4), one O(7), one O(8), and two equivalent O(6) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(4)O5 square pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, edges with three equivalent Fe(1)O6 octahedra, edges with two equivalent Li(3)O5 square pyramids, and edges with two equivalent Li(4)O5 square pyramids. The corner-sharing octahedral tilt angles range from 3-12°. The Ti(2)-O(2) bond length is 1.97 Å. The Ti(2)-O(4) bond length is 1.94 Å. The Ti(2)-O(7) bond length is 1.85 Å. The Ti(2)-O(8) bond length is 2.45 Å. There is one shorter (1.94 Å) and one longer (2.11 Å) Ti(2)-O(6) bond length. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(3), one O(4), one O(6), one O(7), and two equivalent O(2) atoms to form distorted FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Li(3)O5 square pyramids,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one Li(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 1-23°. The Fe(1)-O(3) bond length is 2.14 Å. The Fe(1)-O(4) bond length is 2.18 Å. The Fe(1)-O(6) bond length is 2.30 Å. The Fe(1)-O(7) bond length is 2.18 Å. There is one shorter (2.04 Å) and one longer (2.06 Å) Fe(1)-O(2) bond length. In the second Fe site, Fe(2) is bonded to one O(3), one O(4), one O(5), one O(8), and two equivalent O(1) atoms to form distorted FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Li(4)O5 square pyramids,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra,  an edgeedge with one Li(3)O5 square pyramid, and  an edgeedge with one Li(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 1-23°. The Fe(2)-O(3) bond length is 2.18 Å. The Fe(2)-O(4) bond length is 2.14 Å. The Fe(2)-O(5) bond length is 2.30 Å. The Fe(2)-O(8) bond length is 2.18 Å. There is one shorter (2.04 Å) and one longer (2.06 Å) Fe(2)-O(1) bond length. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Ti(1), and two equivalent Fe(2) atoms to form OLi2TiFe2 trigonal bipyramids that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(3)Li3TiFe2 octahedra, corners with two equivalent O(8)Li3Ti2Fe octahedra, corners with two equivalent O(1)Li2TiFe2 trigonal bipyramids, corners with two equivalent O(2)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(7)Li3Ti2Fe octahedra,  an edgeedge with one O(8)Li3Ti2Fe octahedra, edges with two equivalent O(5)Li3Ti2Fe octahedra, edges with two equivalent O(3)Li3TiFe2 octahedra, and edges with two equivalent O(4)Li3TiFe2 octahedra. The corner-sharing octahedral tilt angles range from 16-81°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), and two equivalent Fe(1) atoms to form OLi2TiFe2 trigonal bipyramids that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(4)Li3TiFe2 octahedra, corners with two equivalent O(7)Li3Ti2Fe octahedra, corners with two equivalent O(1)Li2TiFe2 trigonal bipyramids, corners with two equivalent O(2)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(7)Li3Ti2Fe octahedra,  an edgeedge with one O(8)Li3Ti2Fe octahedra, edges with two equivalent O(6)Li3Ti2Fe octahedra, edges with two equivalent O(3)Li3TiFe2 octahedra, and edges with two equivalent O(4)Li3TiFe2 octahedra. The corner-sharing octahedral tilt angles range from 16-81°. In the third O site, O(3) is bonded to one Li(3), two equivalent Li(1), one Ti(1), one Fe(1), and one Fe(2) atom to form OLi3TiFe2 octahedra that share corners with two equivalent O(3)Li3TiFe2 octahedra, corners with two equivalent O(4)Li3TiFe2 octahedra,  a cornercorner with one O(1)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(6)Li3Ti2Fe octahedra,  an edgeedge with one O(8)Li3Ti2Fe octahedra, edges with three equivalent O(5)Li3Ti2Fe octahedra, edges with three equivalent O(7)Li3Ti2Fe octahedra, edges with two equivalent O(1)Li2TiFe2 trigonal bipyramids, and edges with two equivalent O(2)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 10-14°. In the fourth O site, O(4) is bonded to one Li(4), two equivalent Li(2), one Ti(2), one Fe(1), and one Fe(2) atom to form OLi3TiFe2 octahedra that share corners with two equivalent O(3)Li3TiFe2 octahedra, corners with two equivalent O(4)Li3TiFe2 octahedra,  a cornercorner with one O(2)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(5)Li3Ti2Fe octahedra,  an edgeedge with one O(7)Li3Ti2Fe octahedra, edges with three equivalent O(6)Li3Ti2Fe octahedra, edges with three equivalent O(8)Li3Ti2Fe octahedra, edges with two equivalent O(1)Li2TiFe2 trigonal bipyramids, and edges with two equivalent O(2)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 10-14°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(4), two equivalent Ti(1), and one Fe(2) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(7)Li3Ti2Fe octahedra,  a cornercorner with one O(8)Li3Ti2Fe octahedra, corners with two equivalent O(5)Li3Ti2Fe octahedra, corners with two equivalent O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(1)Li2TiFe2 trigonal bipyramid,  a cornercorner with one O(2)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(4)Li3TiFe2 octahedra, edges with two equivalent O(7)Li3Ti2Fe octahedra, edges with two equivalent O(8)Li3Ti2Fe octahedra, edges with three equivalent O(3)Li3TiFe2 octahedra, and edges with two equivalent O(1)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(4), two equivalent Ti(2), and one Fe(1) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(7)Li3Ti2Fe octahedra,  a cornercorner with one O(8)Li3Ti2Fe octahedra, corners with two equivalent O(5)Li3Ti2Fe octahedra, corners with two equivalent O(6)Li3Ti2Fe octahedra,  a cornercorner with one O(1)Li2TiFe2 trigonal bipyramid,  a cornercorner with one O(2)Li2TiFe2 trigonal bipyramid,  an edgeedge with one O(3)Li3TiFe2 octahedra, edges with two equivalent O(7)Li3Ti2Fe octahedra, edges with two equivalent O(8)Li3Ti2Fe octahedra, edges with three equivalent O(4)Li3TiFe2 octahedra, and edges with two equivalent O(2)Li2TiFe2 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-19°. In the seventh O site, O(7) is bonded to one Li(1), two equivalent Li(3), one Ti(1), one Ti(2), and one Fe(1) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra, corners with two equivalent O(7)Li3Ti2Fe octahedra, corners with two equivalent O(8)Li3Ti2Fe octahedra, corners with two equivalent O(2)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(4)Li3TiFe2 octahedra, edges with two equivalent O(5)Li3Ti2Fe octahedra, edges with two equivalent O(6)Li3Ti2Fe octahedra, edges with three equivalent O(3)Li3TiFe2 octahedra,  an edgeedge with one O(1)Li2TiFe2 trigonal bipyramid, and  an edgeedge with one O(2)Li2TiFe2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-22°. In the eighth O site, O(8) is bonded to one Li(2), two equivalent Li(4), one Ti(1), one Ti(2), and one Fe(2) atom to form distorted OLi3Ti2Fe octahedra that share  a cornercorner with one O(5)Li3Ti2Fe octahedra,  a cornercorner with one O(6)Li3Ti2Fe octahedra, corners with two equivalent O(7)Li3Ti2Fe octahedra, corners with two equivalent O(8)Li3Ti2Fe octahedra, corners with two equivalent O(1)Li2TiFe2 trigonal bipyramids,  an edgeedge with one O(3)Li3TiFe2 octahedra, edges with two equivalent O(5)Li3Ti2Fe octahedra, edges with two equivalent O(6)Li3Ti2Fe octahedra, edges with three equivalent O(4)Li3TiFe2 octahedra,  an edgeedge with one O(1)Li2TiFe2 trigonal bipyramid, and  an edgeedge with one O(2)Li2TiFe2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-22°.