AgV6O15 crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(13), one O(2), and one O(3) atom to form a mixture of distorted corner and edge-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(5), one O(7), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. In the third V site, V(3) is bonded to one O(3), one O(5), one O(6), and one O(8) atom to form corner-sharing VO4 tetrahedra. In the fourth V site, V(4) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the fifth V site, V(5) is bonded to one O(12), one O(14), and two equivalent O(11) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(13), and one O(15) atom to form a mixture of corner and edge-sharing VO4 tetrahedra. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(14), one O(2), one O(7), and one O(9) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one V(3) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(2) and one Ag(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one V(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(4) and one Ag(1) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one V(4) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to two equivalent V(5) atoms. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one V(5) and one V(6) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one V(1) and one V(6) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one V(5) and one Ag(1) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one V(6) atom.
AgV6O15 crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(13), one O(2), and one O(3) atom to form a mixture of distorted corner and edge-sharing VO4 tetrahedra. The V(1)-O(1) bond length is 2.02 Å. The V(1)-O(13) bond length is 1.93 Å. The V(1)-O(2) bond length is 1.66 Å. The V(1)-O(3) bond length is 1.86 Å. In the second V site, V(2) is bonded to one O(5), one O(7), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. The V(2)-O(5) bond length is 1.79 Å. The V(2)-O(7) bond length is 1.63 Å. Both V(2)-O(4) bond lengths are 1.82 Å. In the third V site, V(3) is bonded to one O(3), one O(5), one O(6), and one O(8) atom to form corner-sharing VO4 tetrahedra. The V(3)-O(3) bond length is 1.80 Å. The V(3)-O(5) bond length is 1.84 Å. The V(3)-O(6) bond length is 1.76 Å. The V(3)-O(8) bond length is 1.62 Å. In the fourth V site, V(4) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form corner-sharing VO4 tetrahedra. The V(4)-O(1) bond length is 1.94 Å. The V(4)-O(10) bond length is 1.62 Å. The V(4)-O(6) bond length is 1.85 Å. The V(4)-O(9) bond length is 1.69 Å. In the fifth V site, V(5) is bonded to one O(12), one O(14), and two equivalent O(11) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. The V(5)-O(12) bond length is 1.80 Å. The V(5)-O(14) bond length is 1.63 Å. There is one shorter (1.82 Å) and one longer (1.83 Å) V(5)-O(11) bond length. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(13), and one O(15) atom to form a mixture of corner and edge-sharing VO4 tetrahedra. The V(6)-O(1) bond length is 1.88 Å. The V(6)-O(12) bond length is 1.82 Å. The V(6)-O(13) bond length is 1.76 Å. The V(6)-O(15) bond length is 1.62 Å. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(14), one O(2), one O(7), and one O(9) atom. The Ag(1)-O(14) bond length is 2.55 Å. The Ag(1)-O(2) bond length is 2.18 Å. The Ag(1)-O(7) bond length is 2.47 Å. The Ag(1)-O(9) bond length is 2.16 Å. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one V(3) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(2) and one Ag(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one V(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(4) and one Ag(1) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one V(4) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to two equivalent V(5) atoms. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one V(5) and one V(6) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one V(1) and one V(6) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one V(5) and one Ag(1) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one V(6) atom.