TbSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing TbS4Br3 pentagonal bipyramids. S(1) is bonded to four equivalent Tb(1) atoms to form a mixture of corner and edge-sharing STb4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Tb(1) atoms.
TbSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing TbS4Br3 pentagonal bipyramids. There are a spread of Tb(1)-S(1) bond distances ranging from 2.73-2.75 Å. There are a spread of Tb(1)-Br(1) bond distances ranging from 2.94-3.07 Å. S(1) is bonded to four equivalent Tb(1) atoms to form a mixture of corner and edge-sharing STb4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Tb(1) atoms.