VCoAs crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 11-coordinate geometry to six equivalent Co(1) and five equivalent As(1) atoms. Co(1) is bonded in a 4-coordinate geometry to six equivalent V(1) and four equivalent As(1) atoms. As(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Co(1) atoms.
VCoAs crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 11-coordinate geometry to six equivalent Co(1) and five equivalent As(1) atoms. There are a spread of V(1)-Co(1) bond distances ranging from 2.70-2.85 Å. There are a spread of V(1)-As(1) bond distances ranging from 2.50-2.64 Å. Co(1) is bonded in a 4-coordinate geometry to six equivalent V(1) and four equivalent As(1) atoms. There are a spread of Co(1)-As(1) bond distances ranging from 2.30-2.34 Å. As(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Co(1) atoms.