VOF is alpha bismuth trifluoride-derived structured and crystallizes in the trigonal R-3m space group. V(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent V(1) atoms to form OV4 tetrahedra that share corners with six equivalent O(1)V4 tetrahedra, corners with ten equivalent F(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra. F(1) is bonded to four equivalent V(1) atoms to form FV4 tetrahedra that share corners with six equivalent F(1)V4 tetrahedra, corners with ten equivalent O(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra.
VOF is alpha bismuth trifluoride-derived structured and crystallizes in the trigonal R-3m space group. V(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. There are three shorter (2.06 Å) and one longer (2.07 Å) V(1)-O(1) bond length. There are three shorter (2.21 Å) and one longer (2.42 Å) V(1)-F(1) bond length. O(1) is bonded to four equivalent V(1) atoms to form OV4 tetrahedra that share corners with six equivalent O(1)V4 tetrahedra, corners with ten equivalent F(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra. F(1) is bonded to four equivalent V(1) atoms to form FV4 tetrahedra that share corners with six equivalent F(1)V4 tetrahedra, corners with ten equivalent O(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra.