TlPd3O4 crystallizes in the cubic Fm-3m space group. Pd(1) is bonded in a square co-planar geometry to two equivalent Tl(1) and four equivalent O(1) atoms. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to twelve equivalent Pd(1) atoms to form TlPd12 cuboctahedra that share corners with twelve equivalent Tl(1)Pd12 cuboctahedra and edges with twenty-four equivalent O(1)TlPd3 tetrahedra. In the second Tl site, Tl(2) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. O(1) is bonded to three equivalent Pd(1) and one Tl(2) atom to form OTlPd3 tetrahedra that share corners with ten equivalent O(1)TlPd3 tetrahedra, edges with three equivalent Tl(1)Pd12 cuboctahedra, and edges with three equivalent O(1)TlPd3 tetrahedra.
TlPd3O4 crystallizes in the cubic Fm-3m space group. Pd(1) is bonded in a square co-planar geometry to two equivalent Tl(1) and four equivalent O(1) atoms. Both Pd(1)-Tl(1) bond lengths are 3.40 Å. All Pd(1)-O(1) bond lengths are 2.01 Å. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to twelve equivalent Pd(1) atoms to form TlPd12 cuboctahedra that share corners with twelve equivalent Tl(1)Pd12 cuboctahedra and edges with twenty-four equivalent O(1)TlPd3 tetrahedra. In the second Tl site, Tl(2) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Tl(2)-O(1) bond lengths are 2.37 Å. O(1) is bonded to three equivalent Pd(1) and one Tl(2) atom to form OTlPd3 tetrahedra that share corners with ten equivalent O(1)TlPd3 tetrahedra, edges with three equivalent Tl(1)Pd12 cuboctahedra, and edges with three equivalent O(1)TlPd3 tetrahedra.