KLaMoO5 crystallizes in the tetragonal P4/nmm space group. K(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a body-centered cubic geometry to eight equivalent O(2) atoms. In the second La site, La(1) is bonded in a body-centered cubic geometry to eight equivalent O(2) atoms. Mo(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two La(1,1) and one Mo(1) atom.
KLaMoO5 crystallizes in the tetragonal P4/nmm space group. K(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All K(1)-O(1) bond lengths are 2.95 Å. There are two inequivalent La sites. In the first La site, La(1) is bonded in a body-centered cubic geometry to eight equivalent O(2) atoms. All La(1)-O(2) bond lengths are 2.52 Å. In the second La site, La(1) is bonded in a body-centered cubic geometry to eight equivalent O(2) atoms. All La(1)-O(2) bond lengths are 2.52 Å. Mo(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1) and four equivalent O(2) atoms. The Mo(1)-O(1) bond length is 1.79 Å. All Mo(1)-O(2) bond lengths are 1.91 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two La(1,1) and one Mo(1) atom.