SO2Cl2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfuryl chloride molecules. S(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent Cl(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom.
SO2Cl2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfuryl chloride molecules. S(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent Cl(1) atoms. Both S(1)-O(1) bond lengths are 1.42 Å. Both S(1)-Cl(1) bond lengths are 2.01 Å. O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom.