NdLuO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Lu(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing LuO6 octahedra. The corner-sharing octahedral tilt angles range from 39-41°. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Lu(1) and three equivalent Nd(1) atoms. In the second O site, O(2) is bonded to two equivalent Lu(1) and two equivalent Nd(1) atoms to form distorted corner-sharing ONd2Lu2 trigonal pyramids.
NdLuO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Lu(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing LuO6 octahedra. The corner-sharing octahedral tilt angles range from 39-41°. Both Lu(1)-O(2) bond lengths are 2.22 Å. There are two shorter (2.19 Å) and two longer (2.21 Å) Lu(1)-O(1) bond lengths. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.33 Å) and one longer (2.47 Å) Nd(1)-O(2) bond length. There are a spread of Nd(1)-O(1) bond distances ranging from 2.35-2.98 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Lu(1) and three equivalent Nd(1) atoms. In the second O site, O(2) is bonded to two equivalent Lu(1) and two equivalent Nd(1) atoms to form distorted corner-sharing ONd2Lu2 trigonal pyramids.