Pt(SCl4)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Pt(SCl4)2 clusters. Pt(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent Cl(1), and two equivalent Cl(4) atoms. S(1) is bonded in a trigonal non-coplanar geometry to one Pt(1), one Cl(2), and one Cl(3) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom.
Pt(SCl4)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Pt(SCl4)2 clusters. Pt(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent Cl(1), and two equivalent Cl(4) atoms. Both Pt(1)-S(1) bond lengths are 2.36 Å. Both Pt(1)-Cl(1) bond lengths are 2.34 Å. Both Pt(1)-Cl(4) bond lengths are 2.33 Å. S(1) is bonded in a trigonal non-coplanar geometry to one Pt(1), one Cl(2), and one Cl(3) atom. The S(1)-Cl(2) bond length is 2.00 Å. The S(1)-Cl(3) bond length is 2.00 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom.