(Na)2LiBiF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a LiBiF6 framework. In the LiBiF6 framework, Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Li(1) and one Bi(1) atom.
(Na)2LiBiF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a LiBiF6 framework. In the LiBiF6 framework, Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Li(1)-F(1) bond lengths are 2.03 Å. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-F(1) bond lengths are 2.25 Å. F(1) is bonded in a linear geometry to one Li(1) and one Bi(1) atom.