TiSnO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. Ti(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form TiO6 octahedra that share corners with eight equivalent Sn(1)O6 octahedra and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SnO6 octahedra that share corners with eight equivalent Ti(1)O6 octahedra and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Ti(1) and one Sn(1) atom.
TiSnO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. Ti(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form TiO6 octahedra that share corners with eight equivalent Sn(1)O6 octahedra and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. Both Ti(1)-O(1) bond lengths are 1.99 Å. All Ti(1)-O(2) bond lengths are 1.99 Å. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SnO6 octahedra that share corners with eight equivalent Ti(1)O6 octahedra and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. Both Sn(1)-O(2) bond lengths are 2.11 Å. All Sn(1)-O(1) bond lengths are 2.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Ti(1) and one Sn(1) atom.