Li3Ti2V3O10 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(7), and two equivalent O(9) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with four equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-17°. In the second Li site, Li(2) is bonded to two equivalent O(10), two equivalent O(4), and two equivalent O(8) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with four equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-17°. In the third Li site, Li(3) is bonded to one O(2), one O(3), one O(4), one O(7), and two equivalent O(9) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(8), and two equivalent O(10) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-17°. In the second Ti site, Ti(2) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-17°. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-18°. In the second V site, V(2) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. In the fourth V site, V(4) is bonded to one O(10), one O(5), one O(6), one O(8), and two equivalent O(1) atoms to form VO6 octahedra that share  a cornercorner with one V(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), one Ti(1), one V(1), and two equivalent V(4) atoms to form OLiTiV3 square pyramids that share  a cornercorner with one O(9)Li3TiV square pyramid,  a cornercorner with one O(1)LiTiV3 square pyramid, corners with two equivalent O(3)Li3Ti2 square pyramids, corners with two equivalent O(10)Li3TiV square pyramids,  an edgeedge with one O(4)Li3Ti2 square pyramid,  an edgeedge with one O(10)Li3TiV square pyramid,  an edgeedge with one O(1)LiTiV3 square pyramid, and edges with three equivalent O(8)Li2TiV2 square pyramids. In the second O site, O(2) is bonded to one Li(3), one Ti(2), one V(3), and two equivalent V(2) atoms to form OLiTiV3 square pyramids that share  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(2)LiTiV3 square pyramid, corners with two equivalent O(4)Li3Ti2 square pyramids, corners with two equivalent O(9)Li3TiV square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(9)Li3TiV square pyramid,  an edgeedge with one O(2)LiTiV3 square pyramid, and edges with three equivalent O(7)Li2TiV2 square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(4), one Ti(1), and one Ti(2) atom to form OLi3Ti2 square pyramids that share  a cornercorner with one O(3)Li3Ti2 square pyramid,  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(7)Li2TiV2 square pyramids, corners with two equivalent O(1)LiTiV3 square pyramids,  an edgeedge with one O(7)Li2TiV2 square pyramid,  an edgeedge with one O(8)Li2TiV2 square pyramid,  an edgeedge with one O(10)Li3TiV square pyramid,  an edgeedge with one O(2)LiTiV3 square pyramid, edges with two equivalent O(4)Li3Ti2 square pyramids, and edges with two equivalent O(9)Li3TiV square pyramids. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Ti(1), and one Ti(2) atom to form OLi3Ti2 square pyramids that share  a cornercorner with one O(4)Li3Ti2 square pyramid,  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(8)Li2TiV2 square pyramids, corners with two equivalent O(2)LiTiV3 square pyramids,  an edgeedge with one O(7)Li2TiV2 square pyramid,  an edgeedge with one O(8)Li2TiV2 square pyramid,  an edgeedge with one O(9)Li3TiV square pyramid,  an edgeedge with one O(1)LiTiV3 square pyramid, edges with two equivalent O(3)Li3Ti2 square pyramids, and edges with two equivalent O(10)Li3TiV square pyramids. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Ti(1), one V(1), one V(2), and one V(4) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Ti(2), one V(2), one V(3), and one V(4) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Ti(2), one V(2), and one V(3) atom to form OLi2TiV2 square pyramids that share  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(7)Li2TiV2 square pyramids, corners with two equivalent O(3)Li3Ti2 square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(4)Li3Ti2 square pyramid, edges with two equivalent O(9)Li3TiV square pyramids, and edges with three equivalent O(2)LiTiV3 square pyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one Ti(1), one V(1), and one V(4) atom to form distorted OLi2TiV2 square pyramids that share  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(8)Li2TiV2 square pyramids, corners with two equivalent O(4)Li3Ti2 square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(4)Li3Ti2 square pyramid, edges with two equivalent O(10)Li3TiV square pyramids, and edges with three equivalent O(1)LiTiV3 square pyramids. In the ninth O site, O(9) is bonded to one Li(1), two equivalent Li(3), one Ti(1), and one V(2) atom to form distorted OLi3TiV square pyramids that share  a cornercorner with one O(7)Li2TiV2 square pyramid,  a cornercorner with one O(8)Li2TiV2 square pyramid,  a cornercorner with one O(3)Li3Ti2 square pyramid,  a cornercorner with one O(4)Li3Ti2 square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid,  a cornercorner with one O(1)LiTiV3 square pyramid, corners with two equivalent O(2)LiTiV3 square pyramids,  an edgeedge with one O(4)Li3Ti2 square pyramid,  an edgeedge with one O(9)Li3TiV square pyramid,  an edgeedge with one O(2)LiTiV3 square pyramid, edges with two equivalent O(7)Li2TiV2 square pyramids, and edges with two equivalent O(3)Li3Ti2 square pyramids. In the tenth O site, O(10) is bonded to one Li(2), two equivalent Li(4), one Ti(2), and one V(4) atom to form distorted OLi3TiV square pyramids that share  a cornercorner with one O(7)Li2TiV2 square pyramid,  a cornercorner with one O(8)Li2TiV2 square pyramid,  a cornercorner with one O(3)Li3Ti2 square pyramid,  a cornercorner with one O(4)Li3Ti2 square pyramid,  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(2)LiTiV3 square pyramid, corners with two equivalent O(1)LiTiV3 square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(10)Li3TiV square pyramid,  an edgeedge with one O(1)LiTiV3 square pyramid, edges with two equivalent O(8)Li2TiV2 square pyramids, and edges with two equivalent O(4)Li3Ti2 square pyramids.
Li3Ti2V3O10 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(3), two equivalent O(7), and two equivalent O(9) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(3)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with four equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-17°. Both Li(1)-O(3) bond lengths are 2.15 Å. Both Li(1)-O(7) bond lengths are 2.47 Å. Both Li(1)-O(9) bond lengths are 1.94 Å. In the second Li site, Li(2) is bonded to two equivalent O(10), two equivalent O(4), and two equivalent O(8) atoms to form distorted LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with four equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-17°. Both Li(2)-O(10) bond lengths are 1.94 Å. Both Li(2)-O(4) bond lengths are 2.15 Å. Both Li(2)-O(8) bond lengths are 2.47 Å. In the third Li site, Li(3) is bonded to one O(2), one O(3), one O(4), one O(7), and two equivalent O(9) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. The Li(3)-O(2) bond length is 2.29 Å. The Li(3)-O(3) bond length is 2.18 Å. The Li(3)-O(4) bond length is 2.12 Å. The Li(3)-O(7) bond length is 2.09 Å. There is one shorter (2.06 Å) and one longer (2.48 Å) Li(3)-O(9) bond length. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(8), and two equivalent O(10) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. The Li(4)-O(1) bond length is 2.30 Å. The Li(4)-O(3) bond length is 2.12 Å. The Li(4)-O(4) bond length is 2.18 Å. The Li(4)-O(8) bond length is 2.09 Å. There is one shorter (2.07 Å) and one longer (2.48 Å) Li(4)-O(10) bond length. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-17°. The Ti(1)-O(1) bond length is 2.04 Å. The Ti(1)-O(3) bond length is 2.01 Å. The Ti(1)-O(4) bond length is 1.87 Å. The Ti(1)-O(5) bond length is 2.14 Å. The Ti(1)-O(8) bond length is 2.08 Å. The Ti(1)-O(9) bond length is 1.85 Å. In the second Ti site, Ti(2) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-17°. The Ti(2)-O(10) bond length is 1.85 Å. The Ti(2)-O(2) bond length is 2.05 Å. The Ti(2)-O(3) bond length is 1.87 Å. The Ti(2)-O(4) bond length is 2.01 Å. The Ti(2)-O(6) bond length is 2.14 Å. The Ti(2)-O(7) bond length is 2.08 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-18°. Both V(1)-O(1) bond lengths are 2.12 Å. Both V(1)-O(5) bond lengths are 2.03 Å. Both V(1)-O(8) bond lengths are 2.02 Å. In the second V site, V(2) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. The V(2)-O(5) bond length is 2.02 Å. The V(2)-O(6) bond length is 2.06 Å. The V(2)-O(7) bond length is 1.97 Å. The V(2)-O(9) bond length is 2.08 Å. There is one shorter (2.07 Å) and one longer (2.15 Å) V(2)-O(2) bond length. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. Both V(3)-O(2) bond lengths are 2.12 Å. Both V(3)-O(6) bond lengths are 2.03 Å. Both V(3)-O(7) bond lengths are 2.02 Å. In the fourth V site, V(4) is bonded to one O(10), one O(5), one O(6), one O(8), and two equivalent O(1) atoms to form VO6 octahedra that share  a cornercorner with one V(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-18°. The V(4)-O(10) bond length is 2.08 Å. The V(4)-O(5) bond length is 2.06 Å. The V(4)-O(6) bond length is 2.02 Å. The V(4)-O(8) bond length is 1.97 Å. There is one shorter (2.08 Å) and one longer (2.15 Å) V(4)-O(1) bond length. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), one Ti(1), one V(1), and two equivalent V(4) atoms to form OLiTiV3 square pyramids that share  a cornercorner with one O(9)Li3TiV square pyramid,  a cornercorner with one O(1)LiTiV3 square pyramid, corners with two equivalent O(3)Li3Ti2 square pyramids, corners with two equivalent O(10)Li3TiV square pyramids,  an edgeedge with one O(4)Li3Ti2 square pyramid,  an edgeedge with one O(10)Li3TiV square pyramid,  an edgeedge with one O(1)LiTiV3 square pyramid, and edges with three equivalent O(8)Li2TiV2 square pyramids. In the second O site, O(2) is bonded to one Li(3), one Ti(2), one V(3), and two equivalent V(2) atoms to form OLiTiV3 square pyramids that share  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(2)LiTiV3 square pyramid, corners with two equivalent O(4)Li3Ti2 square pyramids, corners with two equivalent O(9)Li3TiV square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(9)Li3TiV square pyramid,  an edgeedge with one O(2)LiTiV3 square pyramid, and edges with three equivalent O(7)Li2TiV2 square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Li(4), one Ti(1), and one Ti(2) atom to form OLi3Ti2 square pyramids that share  a cornercorner with one O(3)Li3Ti2 square pyramid,  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(7)Li2TiV2 square pyramids, corners with two equivalent O(1)LiTiV3 square pyramids,  an edgeedge with one O(7)Li2TiV2 square pyramid,  an edgeedge with one O(8)Li2TiV2 square pyramid,  an edgeedge with one O(10)Li3TiV square pyramid,  an edgeedge with one O(2)LiTiV3 square pyramid, edges with two equivalent O(4)Li3Ti2 square pyramids, and edges with two equivalent O(9)Li3TiV square pyramids. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Ti(1), and one Ti(2) atom to form OLi3Ti2 square pyramids that share  a cornercorner with one O(4)Li3Ti2 square pyramid,  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(8)Li2TiV2 square pyramids, corners with two equivalent O(2)LiTiV3 square pyramids,  an edgeedge with one O(7)Li2TiV2 square pyramid,  an edgeedge with one O(8)Li2TiV2 square pyramid,  an edgeedge with one O(9)Li3TiV square pyramid,  an edgeedge with one O(1)LiTiV3 square pyramid, edges with two equivalent O(3)Li3Ti2 square pyramids, and edges with two equivalent O(10)Li3TiV square pyramids. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Ti(1), one V(1), one V(2), and one V(4) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Ti(2), one V(2), one V(3), and one V(4) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Ti(2), one V(2), and one V(3) atom to form OLi2TiV2 square pyramids that share  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(7)Li2TiV2 square pyramids, corners with two equivalent O(3)Li3Ti2 square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(4)Li3Ti2 square pyramid, edges with two equivalent O(9)Li3TiV square pyramids, and edges with three equivalent O(2)LiTiV3 square pyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one Ti(1), one V(1), and one V(4) atom to form distorted OLi2TiV2 square pyramids that share  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid, corners with two equivalent O(8)Li2TiV2 square pyramids, corners with two equivalent O(4)Li3Ti2 square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(4)Li3Ti2 square pyramid, edges with two equivalent O(10)Li3TiV square pyramids, and edges with three equivalent O(1)LiTiV3 square pyramids. In the ninth O site, O(9) is bonded to one Li(1), two equivalent Li(3), one Ti(1), and one V(2) atom to form distorted OLi3TiV square pyramids that share  a cornercorner with one O(7)Li2TiV2 square pyramid,  a cornercorner with one O(8)Li2TiV2 square pyramid,  a cornercorner with one O(3)Li3Ti2 square pyramid,  a cornercorner with one O(4)Li3Ti2 square pyramid,  a cornercorner with one O(9)Li3TiV square pyramid,  a cornercorner with one O(1)LiTiV3 square pyramid, corners with two equivalent O(2)LiTiV3 square pyramids,  an edgeedge with one O(4)Li3Ti2 square pyramid,  an edgeedge with one O(9)Li3TiV square pyramid,  an edgeedge with one O(2)LiTiV3 square pyramid, edges with two equivalent O(7)Li2TiV2 square pyramids, and edges with two equivalent O(3)Li3Ti2 square pyramids. In the tenth O site, O(10) is bonded to one Li(2), two equivalent Li(4), one Ti(2), and one V(4) atom to form distorted OLi3TiV square pyramids that share  a cornercorner with one O(7)Li2TiV2 square pyramid,  a cornercorner with one O(8)Li2TiV2 square pyramid,  a cornercorner with one O(3)Li3Ti2 square pyramid,  a cornercorner with one O(4)Li3Ti2 square pyramid,  a cornercorner with one O(10)Li3TiV square pyramid,  a cornercorner with one O(2)LiTiV3 square pyramid, corners with two equivalent O(1)LiTiV3 square pyramids,  an edgeedge with one O(3)Li3Ti2 square pyramid,  an edgeedge with one O(10)Li3TiV square pyramid,  an edgeedge with one O(1)LiTiV3 square pyramid, edges with two equivalent O(8)Li2TiV2 square pyramids, and edges with two equivalent O(4)Li3Ti2 square pyramids.