Li6Mn3CoO10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fourth Li site, Li(4) is bonded to one O(1), one O(4), one O(5), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the fifth Li site, Li(5) is bonded to one O(1), one O(10), one O(2), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the sixth Li site, Li(6) is bonded to one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(4), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. Co(1) is bonded to one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), one Li(5), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(7)Li4MnCo octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li4MnCo octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(5), one Mn(1), one Mn(3), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra, corners with two equivalent O(8)Li4MnCo octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, and edges with two equivalent O(3)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Li(6), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(9)Li4Mn2 octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Li(6), one Mn(2), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(10)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with two equivalent O(3)Li4MnCo octahedra, edges with two equivalent O(7)Li4MnCo octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), one Li(5), one Li(6), one Mn(2), and one Mn(3) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(6)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(3)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Mn(1), one Mn(3), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(5)Li4Mn2 octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, edges with two equivalent O(3)Li4MnCo octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one Li(6), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(1)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(3)Li4MnCo octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the eighth O site, O(8) is bonded to one Li(3), one Li(4), one Li(5), one Li(6), one Mn(2), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(2)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(3)Li4MnCo octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the ninth O site, O(9) is bonded to one Li(1), one Li(4), one Li(5), one Li(6), one Mn(2), and one Mn(3) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(3)Li4MnCo octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(5), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra, corners with two equivalent O(4)Li4MnCo octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(3)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°.
Li6Mn3CoO10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. The Li(1)-O(1) bond length is 2.28 Å. The Li(1)-O(10) bond length is 2.11 Å. The Li(1)-O(2) bond length is 2.19 Å. The Li(1)-O(3) bond length is 2.03 Å. The Li(1)-O(6) bond length is 2.11 Å. The Li(1)-O(9) bond length is 2.03 Å. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. The Li(2)-O(10) bond length is 2.19 Å. The Li(2)-O(2) bond length is 2.10 Å. The Li(2)-O(3) bond length is 2.16 Å. The Li(2)-O(4) bond length is 2.07 Å. The Li(2)-O(6) bond length is 2.21 Å. The Li(2)-O(7) bond length is 2.07 Å. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. The Li(3)-O(3) bond length is 2.33 Å. The Li(3)-O(4) bond length is 2.02 Å. The Li(3)-O(5) bond length is 2.11 Å. The Li(3)-O(6) bond length is 2.16 Å. The Li(3)-O(7) bond length is 2.12 Å. The Li(3)-O(8) bond length is 2.31 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(4), one O(5), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Li(4)-O(1) bond length is 2.18 Å. The Li(4)-O(4) bond length is 2.16 Å. The Li(4)-O(5) bond length is 2.16 Å. The Li(4)-O(7) bond length is 2.09 Å. The Li(4)-O(8) bond length is 2.07 Å. The Li(4)-O(9) bond length is 2.09 Å. In the fifth Li site, Li(5) is bonded to one O(1), one O(10), one O(2), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. The Li(5)-O(1) bond length is 2.15 Å. The Li(5)-O(10) bond length is 2.30 Å. The Li(5)-O(2) bond length is 2.20 Å. The Li(5)-O(5) bond length is 2.05 Å. The Li(5)-O(8) bond length is 2.11 Å. The Li(5)-O(9) bond length is 2.13 Å. In the sixth Li site, Li(6) is bonded to one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. The Li(6)-O(3) bond length is 2.07 Å. The Li(6)-O(4) bond length is 2.10 Å. The Li(6)-O(5) bond length is 2.16 Å. The Li(6)-O(7) bond length is 2.17 Å. The Li(6)-O(8) bond length is 2.08 Å. The Li(6)-O(9) bond length is 2.05 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. The Mn(1)-O(1) bond length is 1.99 Å. The Mn(1)-O(10) bond length is 2.02 Å. The Mn(1)-O(2) bond length is 1.93 Å. The Mn(1)-O(3) bond length is 1.90 Å. The Mn(1)-O(6) bond length is 1.94 Å. The Mn(1)-O(7) bond length is 1.90 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(4), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Mn(2)-O(1) bond length is 2.02 Å. The Mn(2)-O(10) bond length is 2.01 Å. The Mn(2)-O(4) bond length is 1.89 Å. The Mn(2)-O(5) bond length is 1.98 Å. The Mn(2)-O(8) bond length is 1.91 Å. The Mn(2)-O(9) bond length is 1.91 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. The Mn(3)-O(1) bond length is 2.03 Å. The Mn(3)-O(10) bond length is 2.01 Å. The Mn(3)-O(2) bond length is 2.22 Å. The Mn(3)-O(5) bond length is 1.92 Å. The Mn(3)-O(6) bond length is 1.97 Å. The Mn(3)-O(9) bond length is 2.11 Å. Co(1) is bonded to one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. The Co(1)-O(2) bond length is 1.94 Å. The Co(1)-O(3) bond length is 1.98 Å. The Co(1)-O(4) bond length is 2.03 Å. The Co(1)-O(6) bond length is 2.21 Å. The Co(1)-O(7) bond length is 1.97 Å. The Co(1)-O(8) bond length is 1.92 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), one Li(5), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(7)Li4MnCo octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li4MnCo octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(5), one Mn(1), one Mn(3), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra, corners with two equivalent O(8)Li4MnCo octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, and edges with two equivalent O(3)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Li(6), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(9)Li4Mn2 octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Li(6), one Mn(2), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(6)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(10)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with two equivalent O(3)Li4MnCo octahedra, edges with two equivalent O(7)Li4MnCo octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), one Li(5), one Li(6), one Mn(2), and one Mn(3) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(10)Li3Mn3 octahedra,  a cornercorner with one O(9)Li4Mn2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra,  a cornercorner with one O(8)Li4MnCo octahedra, corners with two equivalent O(6)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(3)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Mn(1), one Mn(3), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(5)Li4Mn2 octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, edges with two equivalent O(3)Li4MnCo octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one Li(6), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(1)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(9)Li4Mn2 octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(3)Li4MnCo octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the eighth O site, O(8) is bonded to one Li(3), one Li(4), one Li(5), one Li(6), one Mn(2), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(2)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3Mn3 octahedra,  an edgeedge with one O(3)Li4MnCo octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, edges with two equivalent O(9)Li4Mn2 octahedra, edges with two equivalent O(4)Li4MnCo octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the ninth O site, O(9) is bonded to one Li(1), one Li(4), one Li(5), one Li(6), one Mn(2), and one Mn(3) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(4)Li4MnCo octahedra, corners with two equivalent O(3)Li4MnCo octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(10)Li3Mn3 octahedra, edges with two equivalent O(5)Li4Mn2 octahedra, and edges with two equivalent O(8)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(5), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  a cornercorner with one O(3)Li4MnCo octahedra, corners with two equivalent O(4)Li4MnCo octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(3)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra,  an edgeedge with one O(8)Li4MnCo octahedra, edges with two equivalent O(2)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, and edges with two equivalent O(9)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°.