NiO6(SO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and one NiO6 cluster. In the NiO6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are three inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(6) atom. In the second O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom.
NiO6(SO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfur trioxide molecules and one NiO6 cluster. In the NiO6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Both Ni(1)-O(4) bond lengths are 1.92 Å. Both Ni(1)-O(5) bond lengths are 1.74 Å. Both Ni(1)-O(6) bond lengths are 1.93 Å. There are three inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one Ni(1) and one O(6) atom. The O(4)-O(6) bond length is 1.30 Å. In the second O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Ni(1) and one O(4) atom.