(Nb2NCl10)2(N2)3 is Indium-derived structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Nb2NCl10 clusters. In each Nb2NCl10 cluster, Nb(1) is bonded to one N(1), one Cl(2), and four equivalent Cl(1) atoms to form corner-sharing NbNCl5 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a linear geometry to two equivalent Nb(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom.
(Nb2NCl10)2(N2)3 is Indium-derived structured and crystallizes in the tetragonal P4/mnc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Nb2NCl10 clusters. In each Nb2NCl10 cluster, Nb(1) is bonded to one N(1), one Cl(2), and four equivalent Cl(1) atoms to form corner-sharing NbNCl5 octahedra. The corner-sharing octahedra are not tilted. The Nb(1)-N(1) bond length is 2.19 Å. The Nb(1)-Cl(2) bond length is 2.32 Å. All Nb(1)-Cl(1) bond lengths are 2.36 Å. N(1) is bonded in a linear geometry to two equivalent Nb(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom.