Cr3Co3(SbO8)2 is Rutile-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(3), one Co(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Cr(1), one Cr(2), and one Co(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Co(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(3), one Co(2), and one Co(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Cr(3), one Co(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one Co(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Cr(2), one Co(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Cr(1), one Cr(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Co(2), one Co(3), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Cr(3), one Co(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Cr(3), one Co(3), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Cr(3), one Co(2), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Cr(1), one Co(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one Sb(2) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Cr(2), one Co(1), and one Sb(2) atom.
Cr3Co3(SbO8)2 is Rutile-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Cr(1)-O(14) bond length is 1.86 Å. The Cr(1)-O(2) bond length is 1.93 Å. The Cr(1)-O(3) bond length is 1.92 Å. The Cr(1)-O(4) bond length is 1.91 Å. The Cr(1)-O(7) bond length is 1.97 Å. The Cr(1)-O(9) bond length is 1.88 Å. In the second Cr site, Cr(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. The Cr(2)-O(16) bond length is 1.99 Å. The Cr(2)-O(2) bond length is 1.90 Å. The Cr(2)-O(3) bond length is 1.89 Å. The Cr(2)-O(4) bond length is 1.82 Å. The Cr(2)-O(8) bond length is 1.91 Å. The Cr(2)-O(9) bond length is 2.01 Å. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. The Cr(3)-O(1) bond length is 1.87 Å. The Cr(3)-O(11) bond length is 1.95 Å. The Cr(3)-O(12) bond length is 1.94 Å. The Cr(3)-O(13) bond length is 1.92 Å. The Cr(3)-O(5) bond length is 1.89 Å. The Cr(3)-O(6) bond length is 1.87 Å. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with two equivalent Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. The Co(1)-O(14) bond length is 1.94 Å. The Co(1)-O(16) bond length is 1.93 Å. The Co(1)-O(3) bond length is 1.89 Å. The Co(1)-O(4) bond length is 1.87 Å. The Co(1)-O(7) bond length is 1.89 Å. The Co(1)-O(8) bond length is 1.90 Å. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. The Co(2)-O(1) bond length is 1.95 Å. The Co(2)-O(10) bond length is 1.93 Å. The Co(2)-O(11) bond length is 1.88 Å. The Co(2)-O(13) bond length is 1.86 Å. The Co(2)-O(15) bond length is 1.88 Å. The Co(2)-O(5) bond length is 1.85 Å. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. The Co(3)-O(10) bond length is 1.93 Å. The Co(3)-O(12) bond length is 1.88 Å. The Co(3)-O(13) bond length is 1.86 Å. The Co(3)-O(15) bond length is 1.89 Å. The Co(3)-O(5) bond length is 1.85 Å. The Co(3)-O(6) bond length is 1.94 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. The Sb(1)-O(1) bond length is 1.98 Å. The Sb(1)-O(10) bond length is 1.94 Å. The Sb(1)-O(2) bond length is 2.06 Å. The Sb(1)-O(6) bond length is 1.98 Å. The Sb(1)-O(7) bond length is 2.01 Å. The Sb(1)-O(8) bond length is 2.03 Å. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. The Sb(2)-O(11) bond length is 2.04 Å. The Sb(2)-O(12) bond length is 2.03 Å. The Sb(2)-O(14) bond length is 1.99 Å. The Sb(2)-O(15) bond length is 2.02 Å. The Sb(2)-O(16) bond length is 1.94 Å. The Sb(2)-O(9) bond length is 1.97 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(3), one Co(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Cr(1), one Cr(2), and one Co(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Cr(1), one Cr(2), and one Co(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Cr(3), one Co(2), and one Co(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Cr(3), one Co(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one Co(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Cr(2), one Co(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Cr(1), one Cr(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Co(2), one Co(3), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Cr(3), one Co(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Cr(3), one Co(3), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Cr(3), one Co(2), and one Co(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Cr(1), one Co(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one Sb(2) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Cr(2), one Co(1), and one Sb(2) atom.