URhS3 crystallizes in the orthorhombic Pnma space group. U(1) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. Rh(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form corner-sharing RhS6 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent U(1) and two equivalent Rh(1) atoms to form a mixture of distorted corner and edge-sharing SU3Rh2 trigonal bipyramids. In the second S site, S(2) is bonded in a see-saw-like geometry to two equivalent U(1) and two equivalent Rh(1) atoms.
URhS3 crystallizes in the orthorhombic Pnma space group. U(1) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. There is one shorter (2.66 Å) and one longer (2.76 Å) U(1)-S(2) bond length. There are a spread of U(1)-S(1) bond distances ranging from 2.74-2.93 Å. Rh(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form corner-sharing RhS6 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. Both Rh(1)-S(2) bond lengths are 2.37 Å. There are two shorter (2.49 Å) and two longer (2.51 Å) Rh(1)-S(1) bond lengths. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent U(1) and two equivalent Rh(1) atoms to form a mixture of distorted corner and edge-sharing SU3Rh2 trigonal bipyramids. In the second S site, S(2) is bonded in a see-saw-like geometry to two equivalent U(1) and two equivalent Rh(1) atoms.