Li11V6O5F19 crystallizes in the triclinic P1 space group. There are eleven inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(14), one F(19), one F(6), and one F(9) atom to form distorted LiF4 tetrahedra that share  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent V(1)O2F4 octahedra, corners with two equivalent Li(7)F4 tetrahedra, and  an edgeedge with one V(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 50-75°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(5), one F(17), one F(5), and one F(8) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(16), one F(3), one F(6), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one F(15), one F(2), one F(3), one F(4), and one F(7) atom. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(3), one O(4), one F(2), one F(4), and one F(7) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(4), one F(12), one F(18), one F(5), and one F(8) atom. In the seventh Li site, Li(7) is bonded to one F(11), one F(14), one F(16), and one F(6) atom to form distorted LiF4 tetrahedra that share  a cornercorner with one V(6)OF5 octahedra, corners with two equivalent V(5)O2F4 octahedra, corners with two equivalent Li(1)F4 tetrahedra, and  an edgeedge with one V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-76°. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(10), one F(14), one F(16), and one F(9) atom. In the ninth Li site, Li(9) is bonded in a 5-coordinate geometry to one O(1), one O(5), one F(12), one F(17), and one F(8) atom. In the tenth Li site, Li(10) is bonded to one O(3), one F(13), one F(15), one F(2), and one F(7) atom to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(4)O2F4 octahedra,  a cornercorner with one V(6)OF5 octahedra,  an edgeedge with one V(3)O2F4 octahedra, and  an edgeedge with one V(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 37-68°. In the eleventh Li site, Li(11) is bonded in a 4-coordinate geometry to one O(4), one F(12), one F(17), and one F(18) atom. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(5), one F(11), one F(19), one F(6), and one F(8) atom to form VO2F4 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with two equivalent Li(1)F4 tetrahedra, and  an edgeedge with one Li(7)F4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-45°. In the second V site, V(2) is bonded to one O(2), one F(1), one F(10), one F(3), one F(4), and one F(9) atom to form VOF5 octahedra that share corners with four equivalent V(6)OF5 octahedra and  a cornercorner with one Li(1)F4 tetrahedra. The corner-sharing octahedral tilt angles range from 38-48°. In the third V site, V(3) is bonded to one O(3), one O(4), one F(13), one F(18), one F(2), and one F(5) atom to form VO2F4 octahedra that share corners with four equivalent V(4)O2F4 octahedra,  a cornercorner with one Li(10)OF4 trigonal bipyramid, and  an edgeedge with one Li(10)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. In the fourth V site, V(4) is bonded to one O(3), one O(4), one F(12), one F(18), one F(2), and one F(7) atom to form VO2F4 octahedra that share corners with four equivalent V(3)O2F4 octahedra,  a cornercorner with one Li(10)OF4 trigonal bipyramid, and  an edgeedge with one Li(10)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. In the fifth V site, V(5) is bonded to one O(1), one O(5), one F(11), one F(14), one F(17), and one F(19) atom to form VO2F4 octahedra that share corners with four equivalent V(1)O2F4 octahedra, corners with two equivalent Li(7)F4 tetrahedra, and  an edgeedge with one Li(1)F4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-45°. In the sixth V site, V(6) is bonded to one O(2), one F(1), one F(10), one F(15), one F(16), and one F(3) atom to form VOF5 octahedra that share corners with four equivalent V(2)OF5 octahedra,  a cornercorner with one Li(7)F4 tetrahedra, and  a cornercorner with one Li(10)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-48°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(9), one V(1), and one V(5) atom. In the second O site, O(2) is bonded to one Li(3), one Li(8), one V(2), and one V(6) atom to form distorted OLi2V2 trigonal pyramids that share  a cornercorner with one F(9)Li3V tetrahedra, corners with three equivalent F(16)Li3V tetrahedra,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  an edgeedge with one F(9)Li3V tetrahedra, and edges with two equivalent F(1)Li2V2 trigonal pyramids. In the third O site, O(3) is bonded to one Li(10), one Li(5), one V(3), and one V(4) atom to form distorted OLi2V2 tetrahedra that share  a cornercorner with one F(7)Li3V tetrahedra,  a cornercorner with one F(12)Li3V trigonal pyramid, corners with two equivalent F(18)Li2V2 trigonal pyramids, and  an edgeedge with one F(7)Li3V tetrahedra. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(11), one Li(5), one Li(6), one V(3), and one V(4) atom. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(9), one V(1), and one V(5) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded to one Li(3), one Li(8), one V(2), and one V(6) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(16)Li3V tetrahedra, corners with three equivalent F(9)Li3V tetrahedra,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  an edgeedge with one F(16)Li3V tetrahedra, and edges with two equivalent O(2)Li2V2 trigonal pyramids. In the second F site, F(2) is bonded in a 5-coordinate geometry to one Li(10), one Li(4), one Li(5), one V(3), and one V(4) atom. In the third F site, F(3) is bonded in a distorted see-saw-like geometry to one Li(3), one Li(4), one V(2), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(5), and one V(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(2), one Li(6), and one V(3) atom. In the sixth F site, F(6) is bonded to one Li(1), one Li(3), one Li(7), and one V(1) atom to form distorted FLi3V trigonal pyramids that share corners with two equivalent F(16)Li3V tetrahedra, corners with two equivalent F(9)Li3V tetrahedra,  a cornercorner with one O(2)Li2V2 trigonal pyramid,  a cornercorner with one F(1)Li2V2 trigonal pyramid, and corners with two equivalent F(14)Li3V trigonal pyramids. In the seventh F site, F(7) is bonded to one Li(10), one Li(4), one Li(5), and one V(4) atom to form FLi3V tetrahedra that share  a cornercorner with one O(3)Li2V2 tetrahedra,  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid, and  an edgeedge with one O(3)Li2V2 tetrahedra. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Li(2), one Li(6), one Li(9), and one V(1) atom. In the ninth F site, F(9) is bonded to one Li(1), one Li(3), one Li(8), and one V(2) atom to form FLi3V tetrahedra that share corners with two equivalent F(16)Li3V tetrahedra,  a cornercorner with one O(2)Li2V2 trigonal pyramid, corners with two equivalent F(14)Li3V trigonal pyramids, corners with two equivalent F(6)Li3V trigonal pyramids, corners with three equivalent F(1)Li2V2 trigonal pyramids, and  an edgeedge with one O(2)Li2V2 trigonal pyramid. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Li(8), one V(2), and one V(6) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Li(7), one V(1), and one V(5) atom. In the twelfth F site, F(12) is bonded to one Li(11), one Li(6), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(3)Li2V2 tetrahedra,  a cornercorner with one F(7)Li3V tetrahedra, corners with two equivalent F(17)Li3V trigonal pyramids, and corners with three equivalent F(18)Li2V2 trigonal pyramids. In the thirteenth F site, F(13) is bonded in a distorted water-like geometry to one Li(10) and one V(3) atom. In the fourteenth F site, F(14) is bonded to one Li(1), one Li(7), one Li(8), and one V(5) atom to form distorted FLi3V trigonal pyramids that share corners with two equivalent F(16)Li3V tetrahedra, corners with two equivalent F(9)Li3V tetrahedra,  a cornercorner with one O(2)Li2V2 trigonal pyramid,  a cornercorner with one F(1)Li2V2 trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid, and corners with two equivalent F(6)Li3V trigonal pyramids. In the fifteenth F site, F(15) is bonded in a T-shaped geometry to one Li(10), one Li(4), and one V(6) atom. In the sixteenth F site, F(16) is bonded to one Li(3), one Li(7), one Li(8), and one V(6) atom to form FLi3V tetrahedra that share corners with two equivalent F(9)Li3V tetrahedra,  a cornercorner with one F(1)Li2V2 trigonal pyramid, corners with two equivalent F(14)Li3V trigonal pyramids, corners with two equivalent F(6)Li3V trigonal pyramids, corners with three equivalent O(2)Li2V2 trigonal pyramids, and  an edgeedge with one F(1)Li2V2 trigonal pyramid. In the seventeenth F site, F(17) is bonded to one Li(11), one Li(2), one Li(9), and one V(5) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid, and corners with two equivalent F(12)Li3V trigonal pyramids. In the eighteenth F site, F(18) is bonded to one Li(11), one Li(6), one V(3), and one V(4) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(7)Li3V tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra,  a cornercorner with one F(17)Li3V trigonal pyramid, and corners with three equivalent F(12)Li3V trigonal pyramids. In the nineteenth F site, F(19) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one V(5) atom.
Li11V6O5F19 crystallizes in the triclinic P1 space group. There are eleven inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(14), one F(19), one F(6), and one F(9) atom to form distorted LiF4 tetrahedra that share  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent V(1)O2F4 octahedra, corners with two equivalent Li(7)F4 tetrahedra, and  an edgeedge with one V(5)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 50-75°. The Li(1)-F(14) bond length is 2.02 Å. The Li(1)-F(19) bond length is 1.88 Å. The Li(1)-F(6) bond length is 1.88 Å. The Li(1)-F(9) bond length is 1.94 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(5), one F(17), one F(5), and one F(8) atom. The Li(2)-O(1) bond length is 2.06 Å. The Li(2)-O(5) bond length is 2.18 Å. The Li(2)-F(17) bond length is 2.37 Å. The Li(2)-F(5) bond length is 1.92 Å. The Li(2)-F(8) bond length is 1.94 Å. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(16), one F(3), one F(6), and one F(9) atom. The Li(3)-O(2) bond length is 2.07 Å. The Li(3)-F(1) bond length is 2.37 Å. The Li(3)-F(16) bond length is 2.22 Å. The Li(3)-F(3) bond length is 2.28 Å. The Li(3)-F(6) bond length is 1.93 Å. The Li(3)-F(9) bond length is 1.93 Å. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one F(15), one F(2), one F(3), one F(4), and one F(7) atom. The Li(4)-F(15) bond length is 1.93 Å. The Li(4)-F(2) bond length is 2.45 Å. The Li(4)-F(3) bond length is 2.13 Å. The Li(4)-F(4) bond length is 1.94 Å. The Li(4)-F(7) bond length is 1.88 Å. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(3), one O(4), one F(2), one F(4), and one F(7) atom. The Li(5)-O(3) bond length is 2.00 Å. The Li(5)-O(4) bond length is 2.56 Å. The Li(5)-F(2) bond length is 2.18 Å. The Li(5)-F(4) bond length is 1.99 Å. The Li(5)-F(7) bond length is 1.92 Å. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(4), one F(12), one F(18), one F(5), and one F(8) atom. The Li(6)-O(4) bond length is 2.24 Å. The Li(6)-F(12) bond length is 2.15 Å. The Li(6)-F(18) bond length is 2.02 Å. The Li(6)-F(5) bond length is 1.95 Å. The Li(6)-F(8) bond length is 1.88 Å. In the seventh Li site, Li(7) is bonded to one F(11), one F(14), one F(16), and one F(6) atom to form distorted LiF4 tetrahedra that share  a cornercorner with one V(6)OF5 octahedra, corners with two equivalent V(5)O2F4 octahedra, corners with two equivalent Li(1)F4 tetrahedra, and  an edgeedge with one V(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 49-76°. The Li(7)-F(11) bond length is 1.88 Å. The Li(7)-F(14) bond length is 1.87 Å. The Li(7)-F(16) bond length is 1.96 Å. The Li(7)-F(6) bond length is 2.03 Å. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one O(2), one F(1), one F(10), one F(14), one F(16), and one F(9) atom. The Li(8)-O(2) bond length is 2.26 Å. The Li(8)-F(1) bond length is 2.12 Å. The Li(8)-F(10) bond length is 2.39 Å. The Li(8)-F(14) bond length is 1.92 Å. The Li(8)-F(16) bond length is 1.98 Å. The Li(8)-F(9) bond length is 2.08 Å. In the ninth Li site, Li(9) is bonded in a 5-coordinate geometry to one O(1), one O(5), one F(12), one F(17), and one F(8) atom. The Li(9)-O(1) bond length is 2.21 Å. The Li(9)-O(5) bond length is 2.02 Å. The Li(9)-F(12) bond length is 1.93 Å. The Li(9)-F(17) bond length is 1.94 Å. The Li(9)-F(8) bond length is 2.37 Å. In the tenth Li site, Li(10) is bonded to one O(3), one F(13), one F(15), one F(2), and one F(7) atom to form distorted LiOF4 trigonal bipyramids that share  a cornercorner with one V(3)O2F4 octahedra,  a cornercorner with one V(4)O2F4 octahedra,  a cornercorner with one V(6)OF5 octahedra,  an edgeedge with one V(3)O2F4 octahedra, and  an edgeedge with one V(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 37-68°. The Li(10)-O(3) bond length is 2.08 Å. The Li(10)-F(13) bond length is 1.95 Å. The Li(10)-F(15) bond length is 1.91 Å. The Li(10)-F(2) bond length is 2.19 Å. The Li(10)-F(7) bond length is 2.02 Å. In the eleventh Li site, Li(11) is bonded in a 4-coordinate geometry to one O(4), one F(12), one F(17), and one F(18) atom. The Li(11)-O(4) bond length is 2.00 Å. The Li(11)-F(12) bond length is 1.93 Å. The Li(11)-F(17) bond length is 1.93 Å. The Li(11)-F(18) bond length is 2.24 Å. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(5), one F(11), one F(19), one F(6), and one F(8) atom to form VO2F4 octahedra that share corners with four equivalent V(5)O2F4 octahedra, corners with two equivalent Li(1)F4 tetrahedra, and  an edgeedge with one Li(7)F4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-45°. The V(1)-O(1) bond length is 1.91 Å. The V(1)-O(5) bond length is 1.88 Å. The V(1)-F(11) bond length is 2.14 Å. The V(1)-F(19) bond length is 2.08 Å. The V(1)-F(6) bond length is 2.13 Å. The V(1)-F(8) bond length is 2.02 Å. In the second V site, V(2) is bonded to one O(2), one F(1), one F(10), one F(3), one F(4), and one F(9) atom to form VOF5 octahedra that share corners with four equivalent V(6)OF5 octahedra and  a cornercorner with one Li(1)F4 tetrahedra. The corner-sharing octahedral tilt angles range from 38-48°. The V(2)-O(2) bond length is 1.91 Å. The V(2)-F(1) bond length is 2.04 Å. The V(2)-F(10) bond length is 1.99 Å. The V(2)-F(3) bond length is 2.08 Å. The V(2)-F(4) bond length is 1.94 Å. The V(2)-F(9) bond length is 2.07 Å. In the third V site, V(3) is bonded to one O(3), one O(4), one F(13), one F(18), one F(2), and one F(5) atom to form VO2F4 octahedra that share corners with four equivalent V(4)O2F4 octahedra,  a cornercorner with one Li(10)OF4 trigonal bipyramid, and  an edgeedge with one Li(10)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. The V(3)-O(3) bond length is 1.98 Å. The V(3)-O(4) bond length is 1.97 Å. The V(3)-F(13) bond length is 1.96 Å. The V(3)-F(18) bond length is 2.08 Å. The V(3)-F(2) bond length is 2.10 Å. The V(3)-F(5) bond length is 2.03 Å. In the fourth V site, V(4) is bonded to one O(3), one O(4), one F(12), one F(18), one F(2), and one F(7) atom to form VO2F4 octahedra that share corners with four equivalent V(3)O2F4 octahedra,  a cornercorner with one Li(10)OF4 trigonal bipyramid, and  an edgeedge with one Li(10)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-53°. The V(4)-O(3) bond length is 1.97 Å. The V(4)-O(4) bond length is 1.95 Å. The V(4)-F(12) bond length is 2.01 Å. The V(4)-F(18) bond length is 2.07 Å. The V(4)-F(2) bond length is 2.08 Å. The V(4)-F(7) bond length is 2.06 Å. In the fifth V site, V(5) is bonded to one O(1), one O(5), one F(11), one F(14), one F(17), and one F(19) atom to form VO2F4 octahedra that share corners with four equivalent V(1)O2F4 octahedra, corners with two equivalent Li(7)F4 tetrahedra, and  an edgeedge with one Li(1)F4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-45°. The V(5)-O(1) bond length is 1.88 Å. The V(5)-O(5) bond length is 1.92 Å. The V(5)-F(11) bond length is 2.10 Å. The V(5)-F(14) bond length is 2.14 Å. The V(5)-F(17) bond length is 2.03 Å. The V(5)-F(19) bond length is 2.12 Å. In the sixth V site, V(6) is bonded to one O(2), one F(1), one F(10), one F(15), one F(16), and one F(3) atom to form VOF5 octahedra that share corners with four equivalent V(2)OF5 octahedra,  a cornercorner with one Li(7)F4 tetrahedra, and  a cornercorner with one Li(10)OF4 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-48°. The V(6)-O(2) bond length is 1.88 Å. The V(6)-F(1) bond length is 2.07 Å. The V(6)-F(10) bond length is 2.00 Å. The V(6)-F(15) bond length is 1.90 Å. The V(6)-F(16) bond length is 2.02 Å. The V(6)-F(3) bond length is 2.17 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(9), one V(1), and one V(5) atom. In the second O site, O(2) is bonded to one Li(3), one Li(8), one V(2), and one V(6) atom to form distorted OLi2V2 trigonal pyramids that share  a cornercorner with one F(9)Li3V tetrahedra, corners with three equivalent F(16)Li3V tetrahedra,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  an edgeedge with one F(9)Li3V tetrahedra, and edges with two equivalent F(1)Li2V2 trigonal pyramids. In the third O site, O(3) is bonded to one Li(10), one Li(5), one V(3), and one V(4) atom to form distorted OLi2V2 tetrahedra that share  a cornercorner with one F(7)Li3V tetrahedra,  a cornercorner with one F(12)Li3V trigonal pyramid, corners with two equivalent F(18)Li2V2 trigonal pyramids, and  an edgeedge with one F(7)Li3V tetrahedra. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(11), one Li(5), one Li(6), one V(3), and one V(4) atom. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(9), one V(1), and one V(5) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded to one Li(3), one Li(8), one V(2), and one V(6) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(16)Li3V tetrahedra, corners with three equivalent F(9)Li3V tetrahedra,  a cornercorner with one F(14)Li3V trigonal pyramid,  a cornercorner with one F(6)Li3V trigonal pyramid,  an edgeedge with one F(16)Li3V tetrahedra, and edges with two equivalent O(2)Li2V2 trigonal pyramids. In the second F site, F(2) is bonded in a 5-coordinate geometry to one Li(10), one Li(4), one Li(5), one V(3), and one V(4) atom. In the third F site, F(3) is bonded in a distorted see-saw-like geometry to one Li(3), one Li(4), one V(2), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(5), and one V(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(2), one Li(6), and one V(3) atom. In the sixth F site, F(6) is bonded to one Li(1), one Li(3), one Li(7), and one V(1) atom to form distorted FLi3V trigonal pyramids that share corners with two equivalent F(16)Li3V tetrahedra, corners with two equivalent F(9)Li3V tetrahedra,  a cornercorner with one O(2)Li2V2 trigonal pyramid,  a cornercorner with one F(1)Li2V2 trigonal pyramid, and corners with two equivalent F(14)Li3V trigonal pyramids. In the seventh F site, F(7) is bonded to one Li(10), one Li(4), one Li(5), and one V(4) atom to form FLi3V tetrahedra that share  a cornercorner with one O(3)Li2V2 tetrahedra,  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(12)Li3V trigonal pyramid, and  an edgeedge with one O(3)Li2V2 tetrahedra. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Li(2), one Li(6), one Li(9), and one V(1) atom. In the ninth F site, F(9) is bonded to one Li(1), one Li(3), one Li(8), and one V(2) atom to form FLi3V tetrahedra that share corners with two equivalent F(16)Li3V tetrahedra,  a cornercorner with one O(2)Li2V2 trigonal pyramid, corners with two equivalent F(14)Li3V trigonal pyramids, corners with two equivalent F(6)Li3V trigonal pyramids, corners with three equivalent F(1)Li2V2 trigonal pyramids, and  an edgeedge with one O(2)Li2V2 trigonal pyramid. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Li(8), one V(2), and one V(6) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Li(7), one V(1), and one V(5) atom. In the twelfth F site, F(12) is bonded to one Li(11), one Li(6), one Li(9), and one V(4) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one O(3)Li2V2 tetrahedra,  a cornercorner with one F(7)Li3V tetrahedra, corners with two equivalent F(17)Li3V trigonal pyramids, and corners with three equivalent F(18)Li2V2 trigonal pyramids. In the thirteenth F site, F(13) is bonded in a distorted water-like geometry to one Li(10) and one V(3) atom. In the fourteenth F site, F(14) is bonded to one Li(1), one Li(7), one Li(8), and one V(5) atom to form distorted FLi3V trigonal pyramids that share corners with two equivalent F(16)Li3V tetrahedra, corners with two equivalent F(9)Li3V tetrahedra,  a cornercorner with one O(2)Li2V2 trigonal pyramid,  a cornercorner with one F(1)Li2V2 trigonal pyramid,  a cornercorner with one F(17)Li3V trigonal pyramid, and corners with two equivalent F(6)Li3V trigonal pyramids. In the fifteenth F site, F(15) is bonded in a T-shaped geometry to one Li(10), one Li(4), and one V(6) atom. In the sixteenth F site, F(16) is bonded to one Li(3), one Li(7), one Li(8), and one V(6) atom to form FLi3V tetrahedra that share corners with two equivalent F(9)Li3V tetrahedra,  a cornercorner with one F(1)Li2V2 trigonal pyramid, corners with two equivalent F(14)Li3V trigonal pyramids, corners with two equivalent F(6)Li3V trigonal pyramids, corners with three equivalent O(2)Li2V2 trigonal pyramids, and  an edgeedge with one F(1)Li2V2 trigonal pyramid. In the seventeenth F site, F(17) is bonded to one Li(11), one Li(2), one Li(9), and one V(5) atom to form distorted FLi3V trigonal pyramids that share  a cornercorner with one F(18)Li2V2 trigonal pyramid,  a cornercorner with one F(14)Li3V trigonal pyramid, and corners with two equivalent F(12)Li3V trigonal pyramids. In the eighteenth F site, F(18) is bonded to one Li(11), one Li(6), one V(3), and one V(4) atom to form distorted FLi2V2 trigonal pyramids that share  a cornercorner with one F(7)Li3V tetrahedra, corners with two equivalent O(3)Li2V2 tetrahedra,  a cornercorner with one F(17)Li3V trigonal pyramid, and corners with three equivalent F(12)Li3V trigonal pyramids. In the nineteenth F site, F(19) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one V(5) atom.