FeNF6N2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonia atoms inside a FeNF6 framework. In the FeNF6 framework, Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent N(1)F6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to six equivalent F(1) atoms to form NF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom.
FeNF6N2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonia atoms inside a FeNF6 framework. In the FeNF6 framework, Fe(1) is bonded to six equivalent F(1) atoms to form FeF6 octahedra that share corners with six equivalent N(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Fe(1)-F(1) bond lengths are 1.99 Å. N(1) is bonded to six equivalent F(1) atoms to form NF6 octahedra that share corners with six equivalent Fe(1)F6 octahedra. The corner-sharing octahedra are not tilted. All N(1)-F(1) bond lengths are 1.87 Å. F(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom.