(NH4)3WO3F3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one (NH4)3WO3F3 cluster. W(1) is bonded in a 5-coordinate geometry to one N(2), one O(1), one O(2), one O(3), and one F(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. In the second N site, N(2) is bonded in a water-like geometry to one W(1), one H(5), and one H(6) atom. In the third N site, N(3) is bonded in a tetrahedral geometry to one H(10), one H(11), one H(12), and one H(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one N(1) and one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a linear geometry to one O(2) and one F(3) atom. In the eighth H site, H(8) is bonded in a linear geometry to one F(1) and one F(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) and one O(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one H(9) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one H(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one H(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one H(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one H(7) and one H(8) atom.
(NH4)3WO3F3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one (NH4)3WO3F3 cluster. W(1) is bonded in a 5-coordinate geometry to one N(2), one O(1), one O(2), one O(3), and one F(2) atom. The W(1)-N(2) bond length is 2.17 Å. The W(1)-O(1) bond length is 1.80 Å. The W(1)-O(2) bond length is 1.81 Å. The W(1)-O(3) bond length is 1.81 Å. The W(1)-F(2) bond length is 2.04 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.04 Å. The N(1)-H(3) bond length is 1.08 Å. The N(1)-H(4) bond length is 1.02 Å. In the second N site, N(2) is bonded in a water-like geometry to one W(1), one H(5), and one H(6) atom. The N(2)-H(5) bond length is 1.02 Å. The N(2)-H(6) bond length is 1.03 Å. In the third N site, N(3) is bonded in a tetrahedral geometry to one H(10), one H(11), one H(12), and one H(9) atom. The N(3)-H(10) bond length is 1.03 Å. The N(3)-H(11) bond length is 1.03 Å. The N(3)-H(12) bond length is 1.04 Å. The N(3)-H(9) bond length is 1.06 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one N(1) and one O(3) atom. The H(3)-O(3) bond length is 1.55 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a linear geometry to one O(2) and one F(3) atom. The H(7)-O(2) bond length is 1.26 Å. The H(7)-F(3) bond length is 1.08 Å. In the eighth H site, H(8) is bonded in a linear geometry to one F(1) and one F(3) atom. The H(8)-F(1) bond length is 1.00 Å. The H(8)-F(3) bond length is 1.40 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) and one O(1) atom. The H(9)-O(1) bond length is 1.69 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one H(9) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one H(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one H(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one H(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one H(7) and one H(8) atom.