(Nb(SCl2)2)4(O2)5Cl2 is Indium-derived structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms, ten water atoms, and two Nb(SCl2)2 clusters. In each Nb(SCl2)2 cluster, Nb(1) is bonded in a 8-coordinate geometry to four equivalent S(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. S(1) is bonded in a 4-coordinate geometry to two equivalent Nb(1) and two equivalent S(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom.
(Nb(SCl2)2)4(O2)5Cl2 is Indium-derived structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms, ten water atoms, and two Nb(SCl2)2 clusters. In each Nb(SCl2)2 cluster, Nb(1) is bonded in a 8-coordinate geometry to four equivalent S(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. All Nb(1)-S(1) bond lengths are 2.66 Å. Both Nb(1)-Cl(1) bond lengths are 2.37 Å. Both Nb(1)-Cl(2) bond lengths are 2.35 Å. S(1) is bonded in a 4-coordinate geometry to two equivalent Nb(1) and two equivalent S(1) atoms. There is one shorter (2.00 Å) and one longer (2.69 Å) S(1)-S(1) bond length. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Nb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Nb(1) atom.