PdN4(Pd(N2O)2)2(NO3)4 is Indium-derived structured and crystallizes in the tetragonal I-42m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, eight nitric acid molecules, and four Pd(N2O)2 clusters. In each Pd(N2O)2 cluster, Pd(2) is bonded in a square co-planar geometry to one N(1), one N(4), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pd(2) and two equivalent O(1) atoms. In the second N site, N(3) is bonded in a single-bond geometry to one Pd(2) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Pd(2) atom. O(1) is bonded in a single-bond geometry to one N(1) atom.
PdN4(Pd(N2O)2)2(NO3)4 is Indium-derived structured and crystallizes in the tetragonal I-42m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, eight nitric acid molecules, and four Pd(N2O)2 clusters. In each Pd(N2O)2 cluster, Pd(2) is bonded in a square co-planar geometry to one N(1), one N(4), and two equivalent N(3) atoms. The Pd(2)-N(1) bond length is 2.19 Å. The Pd(2)-N(4) bond length is 1.93 Å. Both Pd(2)-N(3) bond lengths are 2.03 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pd(2) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.24 Å. In the second N site, N(3) is bonded in a single-bond geometry to one Pd(2) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Pd(2) atom. O(1) is bonded in a single-bond geometry to one N(1) atom.