URh2Ge2 crystallizes in the tetragonal I4/mmm space group. U(1) is bonded in a 16-coordinate geometry to eight equivalent Rh(1) and eight equivalent Ge(1) atoms. Rh(1) is bonded to four equivalent U(1) and four equivalent Ge(1) atoms to form a mixture of distorted face, corner, and edge-sharing RhU4Ge4 tetrahedra. Ge(1) is bonded in a 9-coordinate geometry to four equivalent U(1), four equivalent Rh(1), and one Ge(1) atom.
URh2Ge2 crystallizes in the tetragonal I4/mmm space group. U(1) is bonded in a 16-coordinate geometry to eight equivalent Rh(1) and eight equivalent Ge(1) atoms. All U(1)-Rh(1) bond lengths are 3.33 Å. All U(1)-Ge(1) bond lengths are 3.15 Å. Rh(1) is bonded to four equivalent U(1) and four equivalent Ge(1) atoms to form a mixture of distorted face, corner, and edge-sharing RhU4Ge4 tetrahedra. All Rh(1)-Ge(1) bond lengths are 2.48 Å. Ge(1) is bonded in a 9-coordinate geometry to four equivalent U(1), four equivalent Rh(1), and one Ge(1) atom. The Ge(1)-Ge(1) bond length is 2.47 Å.