Hg3(AsF6)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7439-97-6 atoms and four HgAsF6 clusters. In each HgAsF6 cluster, Hg(1) is bonded in a single-bond geometry to one F(1) atom. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom.
Hg3(AsF6)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7439-97-6 atoms and four HgAsF6 clusters. In each HgAsF6 cluster, Hg(1) is bonded in a single-bond geometry to one F(1) atom. The Hg(1)-F(1) bond length is 2.40 Å. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.78 Å. The As(1)-F(2) bond length is 1.75 Å. The As(1)-F(3) bond length is 1.74 Å. The As(1)-F(4) bond length is 1.73 Å. The As(1)-F(5) bond length is 1.75 Å. The As(1)-F(6) bond length is 1.74 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom.