LiAg4(RuO3)4 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to one O(2), one O(5), and four equivalent O(3) atoms to form LiO6 octahedra that share faces with two equivalent Ru(1)O6 octahedra and faces with two equivalent Ru(2)O6 octahedra. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(6), two equivalent O(1), and two equivalent O(3) atoms to form distorted RuO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra, corners with four equivalent Ru(2)O6 octahedra, and  a faceface with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-48°. In the second Ru site, Ru(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms to form distorted RuO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra, corners with four equivalent Ru(1)O6 octahedra, and  a faceface with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a hexagonal planar geometry to one O(2), one O(6), two equivalent O(1), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a hexagonal planar geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Ru(1), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Ru(2) and two equivalent Ag(2) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Ru(2), and two equivalent Ag(2) atoms. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ru(1) and two equivalent Ag(1) atoms.
LiAg4(RuO3)4 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to one O(2), one O(5), and four equivalent O(3) atoms to form LiO6 octahedra that share faces with two equivalent Ru(1)O6 octahedra and faces with two equivalent Ru(2)O6 octahedra. The Li(1)-O(2) bond length is 2.04 Å. The Li(1)-O(5) bond length is 2.03 Å. All Li(1)-O(3) bond lengths are 2.04 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(6), two equivalent O(1), and two equivalent O(3) atoms to form distorted RuO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra, corners with four equivalent Ru(2)O6 octahedra, and  a faceface with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-48°. The Ru(1)-O(2) bond length is 2.01 Å. The Ru(1)-O(6) bond length is 1.92 Å. Both Ru(1)-O(1) bond lengths are 1.92 Å. Both Ru(1)-O(3) bond lengths are 2.02 Å. In the second Ru site, Ru(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms to form distorted RuO6 octahedra that share corners with two equivalent Ru(2)O6 octahedra, corners with four equivalent Ru(1)O6 octahedra, and  a faceface with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. The Ru(2)-O(4) bond length is 1.92 Å. The Ru(2)-O(5) bond length is 2.02 Å. Both Ru(2)-O(1) bond lengths are 1.92 Å. Both Ru(2)-O(3) bond lengths are 2.02 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a hexagonal planar geometry to one O(2), one O(6), two equivalent O(1), and two equivalent O(3) atoms. The Ag(1)-O(2) bond length is 2.59 Å. The Ag(1)-O(6) bond length is 2.60 Å. Both Ag(1)-O(1) bond lengths are 2.59 Å. Both Ag(1)-O(3) bond lengths are 2.58 Å. In the second Ag site, Ag(2) is bonded in a hexagonal planar geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. The Ag(2)-O(4) bond length is 2.60 Å. The Ag(2)-O(5) bond length is 2.58 Å. Both Ag(2)-O(1) bond lengths are 2.60 Å. Both Ag(2)-O(3) bond lengths are 2.59 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Ru(1), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Ru(1), one Ru(2), one Ag(1), and one Ag(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Ru(2) and two equivalent Ag(2) atoms. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Ru(2), and two equivalent Ag(2) atoms. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ru(1) and two equivalent Ag(1) atoms.