MgO8(N3O4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dinitramide molecules and two MgO8 clusters. In each MgO8 cluster, Mg(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mg(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one O(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mg(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(2) atom.
MgO8(N3O4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dinitramide molecules and two MgO8 clusters. In each MgO8 cluster, Mg(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Mg(1)-O(1) bond lengths are 2.02 Å. Both Mg(1)-O(2) bond lengths are 2.48 Å. Both Mg(1)-O(3) bond lengths are 2.03 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mg(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one O(4) atom. The O(2)-O(4) bond length is 1.22 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Mg(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(2) atom.