N2S3AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2S3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom.
N2S3AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2S3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.83 Å. The As(1)-F(2) bond length is 1.78 Å. The As(1)-F(3) bond length is 1.78 Å. The As(1)-F(4) bond length is 1.77 Å. The As(1)-F(5) bond length is 1.76 Å. The As(1)-F(6) bond length is 1.76 Å. There are six inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(1)-S(2) bond length is 1.58 Å. The N(1)-S(3) bond length is 1.60 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.60 Å. The N(2)-S(2) bond length is 1.58 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom.