CsN3 crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to two equivalent N(2) atoms. In the second N site, N(2) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one N(1) atom.
CsN3 crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent N(2) atoms. All Cs(1)-N(2) bond lengths are 3.35 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to two equivalent N(2) atoms. Both N(1)-N(2) bond lengths are 1.19 Å. In the second N site, N(2) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one N(1) atom.