VCrSe2 crystallizes in the trigonal P-3m1 space group. V(1) is bonded to six equivalent Se(1) atoms to form distorted VSe6 octahedra that share corners with twelve equivalent Cr(1)Se6 octahedra, edges with six equivalent V(1)Se6 octahedra, and faces with two equivalent Cr(1)Se6 octahedra. The corner-sharing octahedral tilt angles are 50°. Cr(1) is bonded to six equivalent Se(1) atoms to form CrSe6 octahedra that share corners with twelve equivalent V(1)Se6 octahedra, edges with six equivalent Cr(1)Se6 octahedra, and faces with two equivalent V(1)Se6 octahedra. The corner-sharing octahedral tilt angles are 50°. Se(1) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent Cr(1) atoms.
VCrSe2 crystallizes in the trigonal P-3m1 space group. V(1) is bonded to six equivalent Se(1) atoms to form distorted VSe6 octahedra that share corners with twelve equivalent Cr(1)Se6 octahedra, edges with six equivalent V(1)Se6 octahedra, and faces with two equivalent Cr(1)Se6 octahedra. The corner-sharing octahedral tilt angles are 50°. All V(1)-Se(1) bond lengths are 2.61 Å. Cr(1) is bonded to six equivalent Se(1) atoms to form CrSe6 octahedra that share corners with twelve equivalent V(1)Se6 octahedra, edges with six equivalent Cr(1)Se6 octahedra, and faces with two equivalent V(1)Se6 octahedra. The corner-sharing octahedral tilt angles are 50°. All Cr(1)-Se(1) bond lengths are 2.65 Å. Se(1) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent Cr(1) atoms.