Rb3AuF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the third Rb site, Rb(3) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Au(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Au(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Rb(3) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one Au(1) atom.
Rb3AuF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Rb(1)-F(1) bond lengths are 3.04 Å. Both Rb(1)-F(2) bond lengths are 2.65 Å. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Rb(2)-F(1) bond lengths are 3.19 Å. Both Rb(2)-F(2) bond lengths are 2.70 Å. Both Rb(2)-F(3) bond lengths are 2.96 Å. In the third Rb site, Rb(3) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Rb(3)-F(1) bond lengths are 2.95 Å. Both Rb(3)-F(2) bond lengths are 2.70 Å. Both Rb(3)-F(3) bond lengths are 3.04 Å. Au(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. Both Au(1)-F(1) bond lengths are 1.99 Å. Both Au(1)-F(3) bond lengths are 1.98 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Au(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Rb(3) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one Au(1) atom.