SOBr2 is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of eight thionyl bromide molecules. S(1,2) is bonded in a distorted single-bond geometry to one O(1), one Br(1), and one Br(2) atom. O(1) is bonded in a single-bond geometry to one S(1,2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one S(1,2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one S(1,2) atom.
SOBr2 is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of eight thionyl bromide molecules. S(1,2) is bonded in a distorted single-bond geometry to one O(1), one Br(1), and one Br(2) atom. The S(1,2)-O(1) bond length is 1.44 Å. The S(1,2)-Br(1) bond length is 2.30 Å. The S(1,2)-Br(2) bond length is 2.26 Å. O(1) is bonded in a single-bond geometry to one S(1,2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one S(1,2) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one S(1,2) atom.