SrVTlO4 crystallizes in the orthorhombic P2_12_12_1 space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Tl(1) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Sr(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Sr(1), one V(1), and one Tl(1) atom.
SrVTlO4 crystallizes in the orthorhombic P2_12_12_1 space group. Sr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There is one shorter (2.63 Å) and one longer (2.69 Å) Sr(1)-O(1) bond length. There is one shorter (2.65 Å) and one longer (2.68 Å) Sr(1)-O(2) bond length. There is one shorter (2.60 Å) and one longer (2.70 Å) Sr(1)-O(3) bond length. There is one shorter (2.81 Å) and one longer (2.83 Å) Sr(1)-O(4) bond length. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The V(1)-O(1) bond length is 1.76 Å. The V(1)-O(2) bond length is 1.76 Å. The V(1)-O(3) bond length is 1.75 Å. The V(1)-O(4) bond length is 1.73 Å. Tl(1) is bonded in a single-bond geometry to one O(4) atom. The Tl(1)-O(4) bond length is 2.57 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Sr(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Sr(1), one V(1), and one Tl(1) atom.