FeAg3F6 crystallizes in the tetragonal I4/mmm space group. Fe(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Fe(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a linear geometry to one Fe(1) and one Ag(2) atom.
FeAg3F6 crystallizes in the tetragonal I4/mmm space group. Fe(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. Both Fe(1)-F(2) bond lengths are 1.96 Å. All Fe(1)-F(1) bond lengths are 1.95 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. All Ag(1)-F(1) bond lengths are 2.42 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent F(2) atoms. Both Ag(2)-F(2) bond lengths are 2.11 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Fe(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a linear geometry to one Fe(1) and one Ag(2) atom.