Os(OF)2 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os(OF)2 clusters. Os(1) is bonded in a distorted T-shaped geometry to one O(1), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Os(1) and one O(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one O(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Os(1) atom.
Os(OF)2 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os(OF)2 clusters. Os(1) is bonded in a distorted T-shaped geometry to one O(1), one F(1), and one F(2) atom. The Os(1)-O(1) bond length is 1.85 Å. The Os(1)-F(1) bond length is 1.87 Å. The Os(1)-F(2) bond length is 1.88 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Os(1) and one O(2) atom. The O(1)-O(2) bond length is 1.33 Å. In the second O site, O(2) is bonded in a distorted single-bond geometry to one O(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Os(1) atom.