ThV2PbO8 is Zircon-derived structured and crystallizes in the tetragonal I-4 space group. Th(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Th(1), one V(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Th(1), one V(2), and one Pb(1) atom.
ThV2PbO8 is Zircon-derived structured and crystallizes in the tetragonal I-4 space group. Th(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Th(1)-O(1) bond lengths are 2.47 Å. All Th(1)-O(2) bond lengths are 2.44 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 1.76 Å. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. All V(2)-O(2) bond lengths are 1.75 Å. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Pb(1)-O(1) bond lengths are 2.61 Å. All Pb(1)-O(2) bond lengths are 2.61 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Th(1), one V(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Th(1), one V(2), and one Pb(1) atom.