VSe is Caswellsilverite-derived structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent Se(1) atoms to form a mixture of corner, edge, and face-sharing VSe6 octahedra. The corner-sharing octahedral tilt angles are 49°. Se(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.
VSe is Caswellsilverite-derived structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent Se(1) atoms to form a mixture of corner, edge, and face-sharing VSe6 octahedra. The corner-sharing octahedral tilt angles are 49°. All V(1)-Se(1) bond lengths are 2.61 Å. Se(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.