(K)2CsTiF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a CsTiF6 framework. In the CsTiF6 framework, Cs(1) is bonded to six equivalent F(1) atoms to form CsF6 octahedra that share corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedra are not tilted. Ti(1) is bonded to six equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent Cs(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted linear geometry to one Cs(1) and one Ti(1) atom.
(K)2CsTiF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a CsTiF6 framework. In the CsTiF6 framework, Cs(1) is bonded to six equivalent F(1) atoms to form CsF6 octahedra that share corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Cs(1)-F(1) bond lengths are 2.78 Å. Ti(1) is bonded to six equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent Cs(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Ti(1)-F(1) bond lengths are 1.99 Å. F(1) is bonded in a distorted linear geometry to one Cs(1) and one Ti(1) atom.