AgVO3 crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(3), and one O(7) atom. In the second V site, V(2) is bonded to one O(1), one O(4), one O(8), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(7), and two equivalent O(6) atoms. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(9), and two equivalent O(5) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(2)O4 tetrahedra and  an edgeedge with one V(4)O5 trigonal bipyramid. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to one O(1), one O(11), one O(12), and one O(2) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(10), one O(7), and one O(8) atom. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(4), and one O(9) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted tetrahedral geometry to one V(2), one V(4), one Ag(1), and one Ag(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Ag(3) atom. In the fifth O site, O(5) is bonded in a water-like geometry to two equivalent V(4) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent V(3) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one Ag(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(2) and one Ag(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(2), one V(4), and one Ag(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(3), and one Ag(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(3), one Ag(1), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one V(4), one Ag(1), and one Ag(4) atom.
AgVO3 crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(3), and one O(7) atom. The V(1)-O(10) bond length is 1.82 Å. The V(1)-O(2) bond length is 1.71 Å. The V(1)-O(3) bond length is 1.69 Å. The V(1)-O(7) bond length is 1.87 Å. In the second V site, V(2) is bonded to one O(1), one O(4), one O(8), and one O(9) atom to form corner-sharing VO4 tetrahedra. The V(2)-O(1) bond length is 1.85 Å. The V(2)-O(4) bond length is 1.70 Å. The V(2)-O(8) bond length is 1.69 Å. The V(2)-O(9) bond length is 1.82 Å. In the third V site, V(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(7), and two equivalent O(6) atoms. The V(3)-O(10) bond length is 1.91 Å. The V(3)-O(11) bond length is 1.69 Å. The V(3)-O(7) bond length is 1.87 Å. There is one shorter (1.69 Å) and one longer (2.39 Å) V(3)-O(6) bond length. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(9), and two equivalent O(5) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(2)O4 tetrahedra and  an edgeedge with one V(4)O5 trigonal bipyramid. The V(4)-O(1) bond length is 1.93 Å. The V(4)-O(12) bond length is 1.68 Å. The V(4)-O(9) bond length is 1.98 Å. There is one shorter (1.84 Å) and one longer (1.85 Å) V(4)-O(5) bond length. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to one O(1), one O(11), one O(12), and one O(2) atom. The Ag(1)-O(1) bond length is 2.39 Å. The Ag(1)-O(11) bond length is 2.47 Å. The Ag(1)-O(12) bond length is 2.36 Å. The Ag(1)-O(2) bond length is 2.38 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(10), one O(7), and one O(8) atom. The Ag(2)-O(10) bond length is 2.42 Å. The Ag(2)-O(7) bond length is 2.33 Å. The Ag(2)-O(8) bond length is 2.13 Å. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(4), and one O(9) atom. The Ag(3)-O(1) bond length is 2.58 Å. The Ag(3)-O(11) bond length is 2.30 Å. The Ag(3)-O(4) bond length is 2.31 Å. The Ag(3)-O(9) bond length is 2.45 Å. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(3) atom. The Ag(4)-O(12) bond length is 2.47 Å. The Ag(4)-O(2) bond length is 2.17 Å. The Ag(4)-O(3) bond length is 2.13 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted tetrahedral geometry to one V(2), one V(4), one Ag(1), and one Ag(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Ag(3) atom. In the fifth O site, O(5) is bonded in a water-like geometry to two equivalent V(4) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent V(3) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one Ag(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(2) and one Ag(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(2), one V(4), and one Ag(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one V(3), and one Ag(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one V(3), one Ag(1), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one V(4), one Ag(1), and one Ag(4) atom.