RbAg(NO3)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to one O(5), one O(6), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Ag(1) is bonded in a 4-coordinate geometry to one O(2), one O(6), and two equivalent O(5) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Ag(1), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Ag(1), and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one Ag(1), and one N(1) atom.
RbAg(NO3)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to one O(5), one O(6), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. The Rb(1)-O(5) bond length is 3.25 Å. The Rb(1)-O(6) bond length is 3.11 Å. There is one shorter (2.99 Å) and one longer (3.22 Å) Rb(1)-O(1) bond length. There is one shorter (2.98 Å) and one longer (3.29 Å) Rb(1)-O(2) bond length. There is one shorter (2.99 Å) and one longer (3.22 Å) Rb(1)-O(3) bond length. There is one shorter (3.03 Å) and one longer (3.07 Å) Rb(1)-O(4) bond length. Ag(1) is bonded in a 4-coordinate geometry to one O(2), one O(6), and two equivalent O(5) atoms. The Ag(1)-O(2) bond length is 2.35 Å. The Ag(1)-O(6) bond length is 2.62 Å. There is one shorter (2.39 Å) and one longer (2.52 Å) Ag(1)-O(5) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(6) atom. The N(1)-O(2) bond length is 1.29 Å. The N(1)-O(3) bond length is 1.26 Å. The N(1)-O(6) bond length is 1.27 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. The N(2)-O(1) bond length is 1.26 Å. The N(2)-O(4) bond length is 1.26 Å. The N(2)-O(5) bond length is 1.29 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Ag(1), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Ag(1), and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one Ag(1), and one N(1) atom.