LiSnCl3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the triclinic P1 space group. Li(1) is bonded to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms to form corner-sharing LiCl6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. Sn(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one Sn(1) atom.
LiSnCl3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the triclinic P1 space group. Li(1) is bonded to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms to form corner-sharing LiCl6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. There is one shorter (2.46 Å) and one longer (2.63 Å) Li(1)-Cl(1) bond length. There is one shorter (2.46 Å) and one longer (2.64 Å) Li(1)-Cl(2) bond length. There is one shorter (2.47 Å) and one longer (2.62 Å) Li(1)-Cl(3) bond length. Sn(1) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(2), and one Cl(3) atom. The Sn(1)-Cl(1) bond length is 2.57 Å. The Sn(1)-Cl(2) bond length is 2.56 Å. The Sn(1)-Cl(3) bond length is 2.57 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one Sn(1) atom.