Sb3O2F5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four Sb3O2F5 clusters. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(1), one F(2), and one F(3) atom. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to two equivalent O(1) and one F(1) atom. O(1) is bonded in a water-like geometry to one Sb(1) and one Sb(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.
Sb3O2F5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four Sb3O2F5 clusters. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(1), one F(2), and one F(3) atom. The Sb(1)-O(1) bond length is 2.02 Å. The Sb(1)-F(2) bond length is 2.02 Å. The Sb(1)-F(3) bond length is 2.02 Å. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to two equivalent O(1) and one F(1) atom. Both Sb(2)-O(1) bond lengths are 2.05 Å. The Sb(2)-F(1) bond length is 2.07 Å. O(1) is bonded in a water-like geometry to one Sb(1) and one Sb(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.