MgTiS2 crystallizes in the monoclinic Cm space group. Mg(1) is bonded in a rectangular see-saw-like geometry to one S(1) and three equivalent S(2) atoms. Ti(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing TiS6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to one Mg(1) and three equivalent Ti(1) atoms. In the second S site, S(2) is bonded to three equivalent Mg(1) and three equivalent Ti(1) atoms to form edge-sharing SMg3Ti3 octahedra.
MgTiS2 crystallizes in the monoclinic Cm space group. Mg(1) is bonded in a rectangular see-saw-like geometry to one S(1) and three equivalent S(2) atoms. The Mg(1)-S(1) bond length is 2.41 Å. All Mg(1)-S(2) bond lengths are 2.47 Å. Ti(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing TiS6 octahedra. All Ti(1)-S(1) bond lengths are 2.47 Å. All Ti(1)-S(2) bond lengths are 2.60 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to one Mg(1) and three equivalent Ti(1) atoms. In the second S site, S(2) is bonded to three equivalent Mg(1) and three equivalent Ti(1) atoms to form edge-sharing SMg3Ti3 octahedra.