Pr5AgSn3 crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 7-coordinate geometry to two equivalent Ag(1) and five equivalent Sn(1) atoms. In the second Pr site, Pr(2) is bonded in a 6-coordinate geometry to six equivalent Sn(1) atoms. Ag(1) is bonded to six equivalent Pr(1) atoms to form face-sharing AgPr6 octahedra. Sn(1) is bonded in a 9-coordinate geometry to four equivalent Pr(2) and five equivalent Pr(1) atoms.
Pr5AgSn3 crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 7-coordinate geometry to two equivalent Ag(1) and five equivalent Sn(1) atoms. Both Pr(1)-Ag(1) bond lengths are 3.15 Å. There are a spread of Pr(1)-Sn(1) bond distances ranging from 3.26-3.58 Å. In the second Pr site, Pr(2) is bonded in a 6-coordinate geometry to six equivalent Sn(1) atoms. All Pr(2)-Sn(1) bond lengths are 3.46 Å. Ag(1) is bonded to six equivalent Pr(1) atoms to form face-sharing AgPr6 octahedra. Sn(1) is bonded in a 9-coordinate geometry to four equivalent Pr(2) and five equivalent Pr(1) atoms.