PdP2O6 crystallizes in the orthorhombic Pmna space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one P(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms.
PdP2O6 crystallizes in the orthorhombic Pmna space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. All Pd(1)-O(2) bond lengths are 2.00 Å. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. Both P(1)-O(1) bond lengths are 1.59 Å. Both P(1)-O(2) bond lengths are 1.49 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one P(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms.