KAuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent Au(1)O6 octahedra. Au(1) is bonded to six equivalent O(1) atoms to form AuO6 octahedra that share corners with six equivalent Au(1)O6 octahedra and faces with eight equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent K(1) and two equivalent Au(1) atoms to form a mixture of corner, edge, and face-sharing OK4Au2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
KAuO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, and faces with eight equivalent Au(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.94 Å. Au(1) is bonded to six equivalent O(1) atoms to form AuO6 octahedra that share corners with six equivalent Au(1)O6 octahedra and faces with eight equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Au(1)-O(1) bond lengths are 2.08 Å. O(1) is bonded to four equivalent K(1) and two equivalent Au(1) atoms to form a mixture of corner, edge, and face-sharing OK4Au2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.