S2C2N3H5 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four S2C2N3H5 clusters. In two of the S2C2N3H5 clusters, there are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2), one S(1), and one S(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one H(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(2) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom. In two of the S2C2N3H5 clusters, there are two inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(5), and one N(6) atom. In the second C site, C(4) is bonded in a distorted trigonal planar geometry to one N(5), one S(3), and one S(4) atom. There are three inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one C(3), one H(6), and one H(7) atom. In the second N site, N(5) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one H(10) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one C(3), one H(8), and one H(9) atom. There are five inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(6) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one N(6) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a single-bond geometry to one C(4) atom. In the second S site, S(4) is bonded in a distorted single-bond geometry to one C(4) atom.
S2C2N3H5 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four S2C2N3H5 clusters. In two of the S2C2N3H5 clusters, there are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.37 Å. The C(1)-N(3) bond length is 1.33 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2), one S(1), and one S(2) atom. The C(2)-N(2) bond length is 1.40 Å. The C(2)-S(1) bond length is 1.71 Å. The C(2)-S(2) bond length is 1.68 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(2), and one H(5) atom. The N(2)-H(5) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. The N(3)-H(3) bond length is 1.03 Å. The N(3)-H(4) bond length is 1.02 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(2) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom. In two of the S2C2N3H5 clusters, there are two inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(5), and one N(6) atom. The C(3)-N(4) bond length is 1.33 Å. The C(3)-N(5) bond length is 1.37 Å. The C(3)-N(6) bond length is 1.33 Å. In the second C site, C(4) is bonded in a distorted trigonal planar geometry to one N(5), one S(3), and one S(4) atom. The C(4)-N(5) bond length is 1.40 Å. The C(4)-S(3) bond length is 1.71 Å. The C(4)-S(4) bond length is 1.68 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one C(3), one H(6), and one H(7) atom. The N(4)-H(6) bond length is 1.02 Å. The N(4)-H(7) bond length is 1.03 Å. In the second N site, N(5) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one H(10) atom. The N(5)-H(10) bond length is 1.03 Å. In the third N site, N(6) is bonded in a trigonal planar geometry to one C(3), one H(8), and one H(9) atom. The N(6)-H(8) bond length is 1.03 Å. The N(6)-H(9) bond length is 1.02 Å. There are five inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(6) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one N(6) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a single-bond geometry to one C(4) atom. In the second S site, S(4) is bonded in a distorted single-bond geometry to one C(4) atom.