MgO6(H2)2(H2O)4(SO)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two sulfur monoxide molecules, four water molecules, and one MgO6 cluster. In the MgO6 cluster, Mg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom. In the second O site, O(3) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the third O site, O(1) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom.
MgO6(H2)2(H2O)4(SO)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two sulfur monoxide molecules, four water molecules, and one MgO6 cluster. In the MgO6 cluster, Mg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Mg(1)-O(1) bond lengths are 2.02 Å. Both Mg(1)-O(2) bond lengths are 2.04 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom. The O(2)-O(3) bond length is 1.40 Å. In the second O site, O(3) is bonded in a water-like geometry to one O(1) and one O(2) atom. The O(3)-O(1) bond length is 1.36 Å. In the third O site, O(1) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom.