UCl6SCl3 is TlF-II structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four dtxsid201337604 molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(7), one Cl(8), and one Cl(9) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one S(1) atom.
UCl6SCl3 is TlF-II structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four dtxsid201337604 molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(7), one Cl(8), and one Cl(9) atom. The S(1)-Cl(7) bond length is 2.01 Å. The S(1)-Cl(8) bond length is 2.00 Å. The S(1)-Cl(9) bond length is 2.00 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one S(1) atom.