SbCl6AsCl3PCl4 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules, four arsenic trichloride molecules, and four SbCl6 clusters. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(7), one Cl(9), two equivalent Cl(1), and two equivalent Cl(6) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(1) atom.
SbCl6AsCl3PCl4 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules, four arsenic trichloride molecules, and four SbCl6 clusters. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(7), one Cl(9), two equivalent Cl(1), and two equivalent Cl(6) atoms. The Sb(1)-Cl(7) bond length is 2.42 Å. The Sb(1)-Cl(9) bond length is 2.41 Å. Both Sb(1)-Cl(1) bond lengths are 2.41 Å. Both Sb(1)-Cl(6) bond lengths are 2.43 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(1) atom.