Ba2Cr2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Cr(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form CrF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form CuF6 octahedra that share corners with four equivalent Cr(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. Zn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Cr(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one Cr(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a 2-coordinate geometry to one Ba(1), one Cr(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cr(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Cr(1), and one Cu(1) atom. In the sixth F site, F(3) is bonded in a 1-coordinate geometry to two equivalent Ba(1) and one Cr(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom.
Ba2Cr2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. The Ba(1)-F(1) bond length is 2.78 Å. The Ba(1)-F(4) bond length is 2.77 Å. The Ba(1)-F(6) bond length is 2.95 Å. The Ba(1)-F(7) bond length is 2.92 Å. There is one shorter (2.77 Å) and one longer (2.91 Å) Ba(1)-F(2) bond length. There is one shorter (2.72 Å) and one longer (2.96 Å) Ba(1)-F(3) bond length. There is one shorter (2.70 Å) and one longer (2.84 Å) Ba(1)-F(5) bond length. Cr(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form CrF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. The Cr(1)-F(1) bond length is 1.94 Å. The Cr(1)-F(2) bond length is 1.95 Å. The Cr(1)-F(3) bond length is 1.94 Å. The Cr(1)-F(5) bond length is 1.93 Å. The Cr(1)-F(6) bond length is 1.97 Å. The Cr(1)-F(7) bond length is 1.97 Å. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form CuF6 octahedra that share corners with four equivalent Cr(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. Both Cu(1)-F(2) bond lengths are 2.41 Å. Both Cu(1)-F(4) bond lengths are 1.93 Å. Both Cu(1)-F(7) bond lengths are 1.98 Å. Zn(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. Both Zn(1)-F(1) bond lengths are 2.20 Å. Both Zn(1)-F(4) bond lengths are 2.13 Å. Both Zn(1)-F(6) bond lengths are 2.18 Å. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Cr(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one Cr(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a 2-coordinate geometry to one Ba(1), one Cr(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cr(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Cr(1), and one Cu(1) atom. In the sixth F site, F(3) is bonded in a 1-coordinate geometry to two equivalent Ba(1) and one Cr(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom.