CeAg3 crystallizes in the hexagonal P6_3/mmc space group. Ce(1) is bonded to twelve equivalent Ag(1) atoms to form a mixture of distorted face and corner-sharing CeAg12 cuboctahedra. Ag(1) is bonded in a 10-coordinate geometry to four equivalent Ce(1) and six equivalent Ag(1) atoms.
CeAg3 crystallizes in the hexagonal P6_3/mmc space group. Ce(1) is bonded to twelve equivalent Ag(1) atoms to form a mixture of distorted face and corner-sharing CeAg12 cuboctahedra. There are six shorter (3.22 Å) and six longer (3.31 Å) Ce(1)-Ag(1) bond lengths. Ag(1) is bonded in a 10-coordinate geometry to four equivalent Ce(1) and six equivalent Ag(1) atoms. There are two shorter (2.89 Å) and four longer (2.93 Å) Ag(1)-Ag(1) bond lengths.