Rb2PdAgF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with twelve equivalent Rb(1)F12 cuboctahedra, faces with six equivalent Rb(1)F12 cuboctahedra, faces with four equivalent Pd(1)F6 octahedra, and faces with four equivalent Ag(1)F6 octahedra. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Pd(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded to four equivalent Rb(1), one Pd(1), and one Ag(1) atom to form a mixture of distorted face, corner, and edge-sharing FRb4AgPd octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
Rb2PdAgF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with twelve equivalent Rb(1)F12 cuboctahedra, faces with six equivalent Rb(1)F12 cuboctahedra, faces with four equivalent Pd(1)F6 octahedra, and faces with four equivalent Ag(1)F6 octahedra. All Rb(1)-F(1) bond lengths are 3.07 Å. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Pd(1)-F(1) bond lengths are 2.07 Å. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Pd(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ag(1)-F(1) bond lengths are 2.26 Å. F(1) is bonded to four equivalent Rb(1), one Pd(1), and one Ag(1) atom to form a mixture of distorted face, corner, and edge-sharing FRb4AgPd octahedra. The corner-sharing octahedral tilt angles range from 0-60°.