PrSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted edge and corner-sharing PrS4Br3 pentagonal bipyramids. S(1) is bonded to four equivalent Pr(1) atoms to form a mixture of edge and corner-sharing SPr4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Pr(1) atoms.
PrSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted edge and corner-sharing PrS4Br3 pentagonal bipyramids. There are two shorter (2.84 Å) and two longer (2.85 Å) Pr(1)-S(1) bond lengths. There are a spread of Pr(1)-Br(1) bond distances ranging from 3.05-3.19 Å. S(1) is bonded to four equivalent Pr(1) atoms to form a mixture of edge and corner-sharing SPr4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Pr(1) atoms.