ZnMoO4 crystallizes in the monoclinic P2/c space group. Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted edge-sharing ZnO6 octahedra. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Mo(1) and one Zn(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Zn(1) atoms.
ZnMoO4 crystallizes in the monoclinic P2/c space group. Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Both Mo(1)-O(1) bond lengths are 1.77 Å. There are two shorter (1.89 Å) and two longer (2.18 Å) Mo(1)-O(2) bond lengths. Zn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted edge-sharing ZnO6 octahedra. Both Zn(1)-O(2) bond lengths are 2.01 Å. There are two shorter (2.07 Å) and two longer (2.24 Å) Zn(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Mo(1) and one Zn(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Zn(1) atoms.