(Cs)2CsEuCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsEuCl6 framework. In the CsEuCl6 framework, Cs(2) is bonded to six equivalent Cl(1) atoms to form CsCl6 octahedra that share corners with six equivalent Eu(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Eu(1) is bonded to six equivalent Cl(1) atoms to form EuCl6 octahedra that share corners with six equivalent Cs(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Cs(2) and one Eu(1) atom.
(Cs)2CsEuCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsEuCl6 framework. In the CsEuCl6 framework, Cs(2) is bonded to six equivalent Cl(1) atoms to form CsCl6 octahedra that share corners with six equivalent Eu(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Cs(2)-Cl(1) bond lengths are 3.28 Å. Eu(1) is bonded to six equivalent Cl(1) atoms to form EuCl6 octahedra that share corners with six equivalent Cs(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Eu(1)-Cl(1) bond lengths are 2.71 Å. Cl(1) is bonded in a linear geometry to one Cs(2) and one Eu(1) atom.