VCrB4 is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6/mmm space group. V(1) is bonded to twelve equivalent B(1) atoms to form VB12 cuboctahedra that share edges with twelve equivalent Cr(1)B12 cuboctahedra, faces with two equivalent Cr(1)B12 cuboctahedra, and faces with six equivalent V(1)B12 cuboctahedra. Cr(1) is bonded to twelve equivalent B(1) atoms to form CrB12 cuboctahedra that share edges with twelve equivalent V(1)B12 cuboctahedra, faces with two equivalent V(1)B12 cuboctahedra, and faces with six equivalent Cr(1)B12 cuboctahedra. B(1) is bonded in a 9-coordinate geometry to three equivalent V(1), three equivalent Cr(1), and three equivalent B(1) atoms.
VCrB4 is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6/mmm space group. V(1) is bonded to twelve equivalent B(1) atoms to form VB12 cuboctahedra that share edges with twelve equivalent Cr(1)B12 cuboctahedra, faces with two equivalent Cr(1)B12 cuboctahedra, and faces with six equivalent V(1)B12 cuboctahedra. All V(1)-B(1) bond lengths are 2.29 Å. Cr(1) is bonded to twelve equivalent B(1) atoms to form CrB12 cuboctahedra that share edges with twelve equivalent V(1)B12 cuboctahedra, faces with two equivalent V(1)B12 cuboctahedra, and faces with six equivalent Cr(1)B12 cuboctahedra. All Cr(1)-B(1) bond lengths are 2.27 Å. B(1) is bonded in a 9-coordinate geometry to three equivalent V(1), three equivalent Cr(1), and three equivalent B(1) atoms. All B(1)-B(1) bond lengths are 1.73 Å.