Pb4(VO4)3 crystallizes in the cubic I-43d space group. V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. Pb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms.
Pb4(VO4)3 crystallizes in the cubic I-43d space group. V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 1.72 Å. Pb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.32 Å) and three longer (2.69 Å) Pb(1)-O(1) bond lengths. O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms.