AlSbI6 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two AlSbI6 clusters. Al(1) is bonded to one I(3), one I(4), and two equivalent I(2) atoms to form AlI4 tetrahedra that share corners with two equivalent Sb(1)I4 trigonal pyramids. Sb(1) is bonded to two equivalent I(1) and two equivalent I(2) atoms to form distorted SbI4 trigonal pyramids that share corners with two equivalent Al(1)I4 tetrahedra. There are four inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second I site, I(2) is bonded in an L-shaped geometry to one Al(1) and one Sb(1) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Al(1) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one Al(1) atom.
AlSbI6 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two AlSbI6 clusters. Al(1) is bonded to one I(3), one I(4), and two equivalent I(2) atoms to form AlI4 tetrahedra that share corners with two equivalent Sb(1)I4 trigonal pyramids. The Al(1)-I(3) bond length is 2.56 Å. The Al(1)-I(4) bond length is 2.48 Å. Both Al(1)-I(2) bond lengths are 2.60 Å. Sb(1) is bonded to two equivalent I(1) and two equivalent I(2) atoms to form distorted SbI4 trigonal pyramids that share corners with two equivalent Al(1)I4 tetrahedra. Both Sb(1)-I(1) bond lengths are 2.74 Å. Both Sb(1)-I(2) bond lengths are 3.15 Å. There are four inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second I site, I(2) is bonded in an L-shaped geometry to one Al(1) and one Sb(1) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Al(1) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one Al(1) atom.