BaCaGe crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. Ca(1) is bonded to four equivalent Ge(1) atoms to form a mixture of distorted corner and edge-sharing CaGe4 tetrahedra. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Ba(1) and four equivalent Ca(1) atoms.
BaCaGe crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. There are a spread of Ba(1)-Ge(1) bond distances ranging from 3.41-3.74 Å. Ca(1) is bonded to four equivalent Ge(1) atoms to form a mixture of distorted corner and edge-sharing CaGe4 tetrahedra. There are a spread of Ca(1)-Ge(1) bond distances ranging from 3.11-3.16 Å. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Ba(1) and four equivalent Ca(1) atoms.