V6GaSb crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Ga(1), and two equivalent Sb(1) atoms. Ga(1) is bonded to twelve equivalent V(1) atoms to form GaV12 cuboctahedra that share edges with six equivalent Ga(1)V12 cuboctahedra and faces with eight equivalent Sb(1)V12 cuboctahedra. Sb(1) is bonded to twelve equivalent V(1) atoms to form SbV12 cuboctahedra that share edges with six equivalent Sb(1)V12 cuboctahedra and faces with eight equivalent Ga(1)V12 cuboctahedra.
V6GaSb crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Ga(1), and two equivalent Sb(1) atoms. There is one shorter (2.37 Å) and one longer (2.50 Å) V(1)-V(1) bond length. Both V(1)-Ga(1) bond lengths are 2.71 Å. Both V(1)-Sb(1) bond lengths are 2.74 Å. Ga(1) is bonded to twelve equivalent V(1) atoms to form GaV12 cuboctahedra that share edges with six equivalent Ga(1)V12 cuboctahedra and faces with eight equivalent Sb(1)V12 cuboctahedra. Sb(1) is bonded to twelve equivalent V(1) atoms to form SbV12 cuboctahedra that share edges with six equivalent Sb(1)V12 cuboctahedra and faces with eight equivalent Ga(1)V12 cuboctahedra.