AgZnF3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with nine equivalent Zn(1)F6 octahedra, edges with three equivalent Ag(1)F6 octahedra, and  a faceface with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with nine equivalent Ag(1)F6 octahedra, edges with three equivalent Zn(1)F6 octahedra, and  a faceface with one Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. F(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms.
AgZnF3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with nine equivalent Zn(1)F6 octahedra, edges with three equivalent Ag(1)F6 octahedra, and  a faceface with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. There are three shorter (2.39 Å) and three longer (2.56 Å) Ag(1)-F(1) bond lengths. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with nine equivalent Ag(1)F6 octahedra, edges with three equivalent Zn(1)F6 octahedra, and  a faceface with one Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. There are three shorter (2.01 Å) and three longer (2.07 Å) Zn(1)-F(1) bond lengths. F(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms.