Ti2AgBiO6 crystallizes in the tetragonal I-42m space group. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 0-26°. Ag(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ti(1), one Ag(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a linear geometry to two equivalent Ti(1), two equivalent Ag(1), and two equivalent Bi(1) atoms.
Ti2AgBiO6 crystallizes in the tetragonal I-42m space group. Ti(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 0-26°. Both Ti(1)-O(2) bond lengths are 1.98 Å. All Ti(1)-O(1) bond lengths are 1.98 Å. Ag(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Ag(1)-O(1) bond lengths are 2.56 Å. All Ag(1)-O(2) bond lengths are 2.74 Å. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Bi(1)-O(1) bond lengths are 2.41 Å. All Bi(1)-O(2) bond lengths are 2.74 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ti(1), one Ag(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a linear geometry to two equivalent Ti(1), two equivalent Ag(1), and two equivalent Bi(1) atoms.