Ba2YbBiO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. Yb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form YbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-25°. Bi(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form BiO6 octahedra that share corners with six equivalent Yb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-25°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Yb(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Yb(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to three equivalent Ba(1), one Yb(1), and one Bi(1) atom.
Ba2YbBiO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. There are a spread of Ba(1)-O(1) bond distances ranging from 2.75-3.09 Å. There are a spread of Ba(1)-O(2) bond distances ranging from 2.66-3.21 Å. There are a spread of Ba(1)-O(3) bond distances ranging from 2.75-3.11 Å. Yb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form YbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-25°. Both Yb(1)-O(1) bond lengths are 2.28 Å. Both Yb(1)-O(2) bond lengths are 2.33 Å. Both Yb(1)-O(3) bond lengths are 2.34 Å. Bi(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form BiO6 octahedra that share corners with six equivalent Yb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-25°. Both Bi(1)-O(1) bond lengths are 2.11 Å. Both Bi(1)-O(2) bond lengths are 2.15 Å. Both Bi(1)-O(3) bond lengths are 2.17 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Yb(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Yb(1), and one Bi(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to three equivalent Ba(1), one Yb(1), and one Bi(1) atom.