RhN3(NO2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve nitrous acid molecules and four RhN3 clusters. In each RhN3 cluster, Rh(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one N(3), and one N(6) atom. There are three inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom.
RhN3(NO2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve nitrous acid molecules and four RhN3 clusters. In each RhN3 cluster, Rh(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one N(3), and one N(6) atom. The Rh(1)-N(2) bond length is 1.75 Å. The Rh(1)-N(3) bond length is 1.78 Å. The Rh(1)-N(6) bond length is 1.74 Å. There are three inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom.