C2SbN2F5 is Indium-like structured and crystallizes in the orthorhombic C222_1 space group. The structure is zero-dimensional and consists of four C2SbN2F5 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(2) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one C(1) and one N(1) atom. Sb(1) is bonded in a distorted octahedral geometry to one N(1), one F(3), two equivalent F(1), and two equivalent F(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one C(2) and one Sb(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.
C2SbN2F5 is Indium-like structured and crystallizes in the orthorhombic C222_1 space group. The structure is zero-dimensional and consists of four C2SbN2F5 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(2) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-N(2) bond length is 1.17 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one C(1) and one N(1) atom. The C(2)-N(1) bond length is 1.16 Å. Sb(1) is bonded in a distorted octahedral geometry to one N(1), one F(3), two equivalent F(1), and two equivalent F(2) atoms. The Sb(1)-N(1) bond length is 2.26 Å. The Sb(1)-F(3) bond length is 1.88 Å. Both Sb(1)-F(1) bond lengths are 1.90 Å. Both Sb(1)-F(2) bond lengths are 1.90 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one C(2) and one Sb(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom.