PbO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Pb(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing PbO6 octahedra. The corner-sharing octahedral tilt angles are 51°. O(1) is bonded in a trigonal planar geometry to three equivalent Pb(1) atoms.
PbO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Pb(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing PbO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two shorter (2.17 Å) and four longer (2.18 Å) Pb(1)-O(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent Pb(1) atoms.