Li3Bi(PO4)2 crystallizes in the triclinic P1 space group. There are nine inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(21), one O(4), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 67°. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(24), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 65°. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(17), one O(18), one O(21), one O(23), and one O(24) atom. In the fourth Li site, Li(4) is bonded to one O(1), one O(17), one O(21), and one O(22) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 66°. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(12), one O(19), one O(22), one O(3), one O(4), and one O(9) atom. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(14), one O(6), one O(7), and one O(8) atom. In the seventh Li site, Li(7) is bonded to one O(10), one O(14), one O(18), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 66°. In the eighth Li site, Li(8) is bonded to one O(1), one O(19), one O(24), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 66°. In the ninth Li site, Li(9) is bonded to one O(12), one O(18), one O(23), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 67°. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(11), one O(16), one O(17), one O(2), one O(20), and one O(23) atom to form distorted BiO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the second Bi site, Bi(2) is bonded to one O(13), one O(14), one O(15), one O(5), one O(7), and one O(8) atom to form distorted BiO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third Bi site, Bi(3) is bonded in a 9-coordinate geometry to one O(12), one O(15), one O(19), one O(2), one O(20), one O(22), one O(3), one O(4), and one O(9) atom. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(15), one O(23), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-58°. In the second P site, P(2) is bonded to one O(16), one O(18), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the third P site, P(3) is bonded to one O(14), one O(19), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra, and  a cornercorner with one Li(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-60°. In the fourth P site, P(4) is bonded to one O(11), one O(22), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-61°. In the fifth P site, P(5) is bonded to one O(2), one O(24), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra, and  a cornercorner with one Li(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-58°. In the sixth P site, P(6) is bonded to one O(10), one O(12), one O(13), and one O(17) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-59°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), one Li(6), one Li(8), and one P(1) atom to form distorted corner-sharing OLi3P tetrahedra. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(3), and one P(5) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(5), one Bi(3), and one P(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Bi(3), and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Bi(2) and one P(4) atom. In the sixth O site, O(6) is bonded to one Li(1), one Li(6), one Li(9), and one P(4) atom to form distorted corner-sharing OLi3P tetrahedra. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one Bi(2), and one P(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one Bi(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(5), one Li(7), one Bi(3), and one P(5) atom. In the tenth O site, O(10) is bonded to one Li(2), one Li(6), one Li(7), and one P(6) atom to form distorted corner-sharing OLi3P tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Bi(1), and one P(4) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Li(5), one Li(9), one Bi(3), and one P(6) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Bi(2) and one P(6) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(6), one Li(7), one Bi(2), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Bi(2), one Bi(3), and one P(1) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Bi(1) and one P(2) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Bi(1), and one P(6) atom. In the eighteenth O site, O(18) is bonded to one Li(3), one Li(7), one Li(9), and one P(2) atom to form distorted corner-sharing OLi3P tetrahedra. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Li(5), one Li(8), one Bi(3), and one P(3) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(3), and one P(3) atom. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(3), one Li(4), and one P(3) atom to form distorted corner-sharing OLi3P tetrahedra. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Li(4), one Li(5), one Bi(3), and one P(4) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(3), one Li(9), one Bi(1), and one P(1) atom. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(3), one Li(8), and one P(5) atom to form distorted corner-sharing OLi3P tetrahedra.
Li3Bi(PO4)2 crystallizes in the triclinic P1 space group. There are nine inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(21), one O(4), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 67°. The Li(1)-O(21) bond length is 2.06 Å. The Li(1)-O(4) bond length is 1.94 Å. The Li(1)-O(6) bond length is 2.03 Å. The Li(1)-O(7) bond length is 1.98 Å. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(24), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 65°. The Li(2)-O(10) bond length is 2.05 Å. The Li(2)-O(11) bond length is 1.95 Å. The Li(2)-O(24) bond length is 2.05 Å. The Li(2)-O(3) bond length is 1.93 Å. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(11), one O(17), one O(18), one O(21), one O(23), and one O(24) atom. The Li(3)-O(11) bond length is 2.49 Å. The Li(3)-O(17) bond length is 2.51 Å. The Li(3)-O(18) bond length is 2.03 Å. The Li(3)-O(21) bond length is 2.01 Å. The Li(3)-O(23) bond length is 2.58 Å. The Li(3)-O(24) bond length is 2.00 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(17), one O(21), and one O(22) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 66°. The Li(4)-O(1) bond length is 2.07 Å. The Li(4)-O(17) bond length is 1.97 Å. The Li(4)-O(21) bond length is 2.03 Å. The Li(4)-O(22) bond length is 1.95 Å. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one O(12), one O(19), one O(22), one O(3), one O(4), and one O(9) atom. The Li(5)-O(12) bond length is 2.44 Å. The Li(5)-O(19) bond length is 2.34 Å. The Li(5)-O(22) bond length is 2.57 Å. The Li(5)-O(3) bond length is 2.41 Å. The Li(5)-O(4) bond length is 2.35 Å. The Li(5)-O(9) bond length is 2.21 Å. In the sixth Li site, Li(6) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(14), one O(6), one O(7), and one O(8) atom. The Li(6)-O(1) bond length is 2.01 Å. The Li(6)-O(10) bond length is 2.02 Å. The Li(6)-O(14) bond length is 2.53 Å. The Li(6)-O(6) bond length is 2.03 Å. The Li(6)-O(7) bond length is 2.56 Å. The Li(6)-O(8) bond length is 2.48 Å. In the seventh Li site, Li(7) is bonded to one O(10), one O(14), one O(18), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 66°. The Li(7)-O(10) bond length is 2.04 Å. The Li(7)-O(14) bond length is 1.96 Å. The Li(7)-O(18) bond length is 2.05 Å. The Li(7)-O(9) bond length is 1.92 Å. In the eighth Li site, Li(8) is bonded to one O(1), one O(19), one O(24), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 66°. The Li(8)-O(1) bond length is 2.06 Å. The Li(8)-O(19) bond length is 1.93 Å. The Li(8)-O(24) bond length is 2.06 Å. The Li(8)-O(8) bond length is 1.95 Å. In the ninth Li site, Li(9) is bonded to one O(12), one O(18), one O(23), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 67°. The Li(9)-O(12) bond length is 1.93 Å. The Li(9)-O(18) bond length is 2.03 Å. The Li(9)-O(23) bond length is 1.98 Å. The Li(9)-O(6) bond length is 2.06 Å. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(11), one O(16), one O(17), one O(2), one O(20), and one O(23) atom to form distorted BiO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(9)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The Bi(1)-O(11) bond length is 2.40 Å. The Bi(1)-O(16) bond length is 2.32 Å. The Bi(1)-O(17) bond length is 2.37 Å. The Bi(1)-O(2) bond length is 2.42 Å. The Bi(1)-O(20) bond length is 2.43 Å. The Bi(1)-O(23) bond length is 2.38 Å. In the second Bi site, Bi(2) is bonded to one O(13), one O(14), one O(15), one O(5), one O(7), and one O(8) atom to form distorted BiO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The Bi(2)-O(13) bond length is 2.34 Å. The Bi(2)-O(14) bond length is 2.39 Å. The Bi(2)-O(15) bond length is 2.49 Å. The Bi(2)-O(5) bond length is 2.35 Å. The Bi(2)-O(7) bond length is 2.35 Å. The Bi(2)-O(8) bond length is 2.39 Å. In the third Bi site, Bi(3) is bonded in a 9-coordinate geometry to one O(12), one O(15), one O(19), one O(2), one O(20), one O(22), one O(3), one O(4), and one O(9) atom. The Bi(3)-O(12) bond length is 2.67 Å. The Bi(3)-O(15) bond length is 2.56 Å. The Bi(3)-O(19) bond length is 2.54 Å. The Bi(3)-O(2) bond length is 2.80 Å. The Bi(3)-O(20) bond length is 2.74 Å. The Bi(3)-O(22) bond length is 2.46 Å. The Bi(3)-O(3) bond length is 2.53 Å. The Bi(3)-O(4) bond length is 2.68 Å. The Bi(3)-O(9) bond length is 2.74 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(15), one O(23), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-58°. The P(1)-O(1) bond length is 1.54 Å. The P(1)-O(15) bond length is 1.57 Å. The P(1)-O(23) bond length is 1.57 Å. The P(1)-O(3) bond length is 1.55 Å. In the second P site, P(2) is bonded to one O(16), one O(18), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-60°. The P(2)-O(16) bond length is 1.55 Å. The P(2)-O(18) bond length is 1.55 Å. The P(2)-O(4) bond length is 1.55 Å. The P(2)-O(8) bond length is 1.58 Å. In the third P site, P(3) is bonded to one O(14), one O(19), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra, and  a cornercorner with one Li(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-60°. The P(3)-O(14) bond length is 1.57 Å. The P(3)-O(19) bond length is 1.55 Å. The P(3)-O(20) bond length is 1.56 Å. The P(3)-O(21) bond length is 1.54 Å. In the fourth P site, P(4) is bonded to one O(11), one O(22), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-61°. The P(4)-O(11) bond length is 1.57 Å. The P(4)-O(22) bond length is 1.56 Å. The P(4)-O(5) bond length is 1.55 Å. The P(4)-O(6) bond length is 1.55 Å. In the fifth P site, P(5) is bonded to one O(2), one O(24), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra, and  a cornercorner with one Li(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-58°. The P(5)-O(2) bond length is 1.56 Å. The P(5)-O(24) bond length is 1.55 Å. The P(5)-O(7) bond length is 1.58 Å. The P(5)-O(9) bond length is 1.54 Å. In the sixth P site, P(6) is bonded to one O(10), one O(12), one O(13), and one O(17) atom to form PO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra,  a cornercorner with one Bi(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra, and  a cornercorner with one Li(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-59°. The P(6)-O(10) bond length is 1.55 Å. The P(6)-O(12) bond length is 1.55 Å. The P(6)-O(13) bond length is 1.55 Å. The P(6)-O(17) bond length is 1.58 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), one Li(6), one Li(8), and one P(1) atom to form distorted corner-sharing OLi3P tetrahedra. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(3), and one P(5) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(5), one Bi(3), and one P(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Bi(3), and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Bi(2) and one P(4) atom. In the sixth O site, O(6) is bonded to one Li(1), one Li(6), one Li(9), and one P(4) atom to form distorted corner-sharing OLi3P tetrahedra. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one Bi(2), and one P(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(6), one Li(8), one Bi(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(5), one Li(7), one Bi(3), and one P(5) atom. In the tenth O site, O(10) is bonded to one Li(2), one Li(6), one Li(7), and one P(6) atom to form distorted corner-sharing OLi3P tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Bi(1), and one P(4) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Li(5), one Li(9), one Bi(3), and one P(6) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Bi(2) and one P(6) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(6), one Li(7), one Bi(2), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Bi(2), one Bi(3), and one P(1) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Bi(1) and one P(2) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Bi(1), and one P(6) atom. In the eighteenth O site, O(18) is bonded to one Li(3), one Li(7), one Li(9), and one P(2) atom to form distorted corner-sharing OLi3P tetrahedra. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Li(5), one Li(8), one Bi(3), and one P(3) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one Bi(1), one Bi(3), and one P(3) atom. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(3), one Li(4), and one P(3) atom to form distorted corner-sharing OLi3P tetrahedra. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Li(4), one Li(5), one Bi(3), and one P(4) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(3), one Li(9), one Bi(1), and one P(1) atom. In the twenty-fourth O site, O(24) is bonded to one Li(2), one Li(3), one Li(8), and one P(5) atom to form distorted corner-sharing OLi3P tetrahedra.