Ga4N2Te3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. In the second Ga site, Ga(2) is bonded in a distorted water-like geometry to two equivalent N(1) and two equivalent Te(1) atoms. In the third Ga site, Ga(3) is bonded in a distorted L-shaped geometry to two equivalent N(1) and two equivalent Te(2) atoms. N(1) is bonded to one Ga(1), one Ga(2), and two equivalent Ga(3) atoms to form distorted edge-sharing NGa4 tetrahedra. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted water-like geometry to two equivalent Ga(2) atoms. In the second Te site, Te(2) is bonded in a distorted L-shaped geometry to two equivalent Ga(3) atoms.
Ga4N2Te3 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. Both Ga(1)-N(1) bond lengths are 2.19 Å. In the second Ga site, Ga(2) is bonded in a distorted water-like geometry to two equivalent N(1) and two equivalent Te(1) atoms. Both Ga(2)-N(1) bond lengths are 1.92 Å. There is one shorter (2.75 Å) and one longer (2.77 Å) Ga(2)-Te(1) bond length. In the third Ga site, Ga(3) is bonded in a distorted L-shaped geometry to two equivalent N(1) and two equivalent Te(2) atoms. Both Ga(3)-N(1) bond lengths are 1.96 Å. There is one shorter (2.67 Å) and one longer (2.72 Å) Ga(3)-Te(2) bond length. N(1) is bonded to one Ga(1), one Ga(2), and two equivalent Ga(3) atoms to form distorted edge-sharing NGa4 tetrahedra. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted water-like geometry to two equivalent Ga(2) atoms. In the second Te site, Te(2) is bonded in a distorted L-shaped geometry to two equivalent Ga(3) atoms.