CdSn2H12(OF)6 crystallizes in the triclinic P-1 space group. Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Sn(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one F(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) and one F(2) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one F(2) atom. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(3) and one F(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(5), and one H(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Sn(1), one H(1), and one H(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Sn(1), one H(3), and one H(5) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Sn(1), one H(4), and one H(6) atom.
CdSn2H12(OF)6 crystallizes in the triclinic P-1 space group. Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Cd(1)-O(1) bond lengths are 2.34 Å. Both Cd(1)-O(2) bond lengths are 2.31 Å. Both Cd(1)-O(3) bond lengths are 2.41 Å. Sn(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. The Sn(1)-F(1) bond length is 2.15 Å. The Sn(1)-F(2) bond length is 2.17 Å. The Sn(1)-F(3) bond length is 2.12 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(1) atom. The H(1)-O(2) bond length is 0.99 Å. The H(1)-F(1) bond length is 1.63 Å. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one F(1) atom. The H(2)-O(1) bond length is 0.99 Å. The H(2)-F(1) bond length is 1.63 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) and one F(2) atom. The H(3)-O(1) bond length is 0.99 Å. The H(3)-F(2) bond length is 1.65 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. The H(4)-O(2) bond length is 0.99 Å. The H(4)-F(3) bond length is 1.64 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one F(2) atom. The H(5)-O(3) bond length is 1.00 Å. The H(5)-F(2) bond length is 1.66 Å. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(3) and one F(3) atom. The H(6)-O(3) bond length is 1.00 Å. The H(6)-F(3) bond length is 1.62 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(5), and one H(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Sn(1), one H(1), and one H(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Sn(1), one H(3), and one H(5) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Sn(1), one H(4), and one H(6) atom.