LiAuS crystallizes in the orthorhombic Fddd space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent Au(1) and four equivalent S(1) atoms. Au(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent Au(1) atoms.
LiAuS crystallizes in the orthorhombic Fddd space group. Li(1) is bonded in a 6-coordinate geometry to two equivalent Au(1) and four equivalent S(1) atoms. Both Li(1)-Au(1) bond lengths are 2.99 Å. There are two shorter (2.53 Å) and two longer (2.55 Å) Li(1)-S(1) bond lengths. Au(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent S(1) atoms. Both Au(1)-S(1) bond lengths are 2.32 Å. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent Au(1) atoms.