Os3Pb2N5Pb crystallizes in the triclinic P-1 space group. The structure consists of two 7439-92-1 atoms inside a Os3Pb2N5 framework. In the Os3Pb2N5 framework, there are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(5), and two equivalent N(3) atoms. In the second Os site, Os(2) is bonded to one N(1), one N(2), and two equivalent N(4) atoms to form a mixture of distorted edge and corner-sharing OsN4 trigonal pyramids. In the third Os site, Os(3) is bonded to one N(1), one N(2), one N(4), and one N(5) atom to form a mixture of edge and corner-sharing OsN4 tetrahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted water-like geometry to one N(2) and one N(3) atom. In the second Pb site, Pb(3) is bonded in a single-bond geometry to one N(3) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Os(1), one Os(2), and one Os(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Os(2), one Os(3), and one Pb(1) atom. In the third N site, N(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Os(1), one Pb(1), and one Pb(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Os(3) and two equivalent Os(2) atoms. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Os(1) and one Os(3) atom.
Os3Pb2N5Pb crystallizes in the triclinic P-1 space group. The structure consists of two 7439-92-1 atoms inside a Os3Pb2N5 framework. In the Os3Pb2N5 framework, there are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(5), and two equivalent N(3) atoms. The Os(1)-N(1) bond length is 1.93 Å. The Os(1)-N(5) bond length is 1.88 Å. There is one shorter (2.03 Å) and one longer (2.08 Å) Os(1)-N(3) bond length. In the second Os site, Os(2) is bonded to one N(1), one N(2), and two equivalent N(4) atoms to form a mixture of distorted edge and corner-sharing OsN4 trigonal pyramids. The Os(2)-N(1) bond length is 1.98 Å. The Os(2)-N(2) bond length is 2.03 Å. There is one shorter (1.94 Å) and one longer (2.07 Å) Os(2)-N(4) bond length. In the third Os site, Os(3) is bonded to one N(1), one N(2), one N(4), and one N(5) atom to form a mixture of edge and corner-sharing OsN4 tetrahedra. The Os(3)-N(1) bond length is 2.01 Å. The Os(3)-N(2) bond length is 1.91 Å. The Os(3)-N(4) bond length is 1.94 Å. The Os(3)-N(5) bond length is 1.81 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted water-like geometry to one N(2) and one N(3) atom. The Pb(1)-N(2) bond length is 2.50 Å. The Pb(1)-N(3) bond length is 2.28 Å. In the second Pb site, Pb(3) is bonded in a single-bond geometry to one N(3) atom. The Pb(3)-N(3) bond length is 2.43 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Os(1), one Os(2), and one Os(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Os(2), one Os(3), and one Pb(1) atom. In the third N site, N(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Os(1), one Pb(1), and one Pb(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Os(3) and two equivalent Os(2) atoms. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Os(1) and one Os(3) atom.