(SnH5(OCl)3)2H2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four water molecules and four SnH5(OCl)3 clusters. In each SnH5(OCl)3 cluster, Sn(1) is bonded to one O(2), two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing SnCl3O3 octahedra. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sn(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sn(1), one H(2), and one H(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(3), one H(4), and one H(5) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom.
(SnH5(OCl)3)2H2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four water molecules and four SnH5(OCl)3 clusters. In each SnH5(OCl)3 cluster, Sn(1) is bonded to one O(2), two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing SnCl3O3 octahedra. The Sn(1)-O(2) bond length is 2.18 Å. Both Sn(1)-O(1) bond lengths are 2.12 Å. The Sn(1)-Cl(1) bond length is 2.45 Å. The Sn(1)-Cl(2) bond length is 2.39 Å. The Sn(1)-Cl(3) bond length is 2.41 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.99 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. The H(3)-O(2) bond length is 1.01 Å. The H(3)-O(3) bond length is 1.62 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. The H(4)-O(3) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.98 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sn(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sn(1), one H(2), and one H(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(3), one H(4), and one H(5) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom.