Rh(N2O3)3 is Indium-like structured and crystallizes in the trigonal P31m space group. The structure is zero-dimensional and consists of one nsc241243 molecule. Rh(1) is bonded in a distorted octahedral geometry to three equivalent N(2) and three equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom.
Rh(N2O3)3 is Indium-like structured and crystallizes in the trigonal P31m space group. The structure is zero-dimensional and consists of one nsc241243 molecule. Rh(1) is bonded in a distorted octahedral geometry to three equivalent N(2) and three equivalent O(1) atoms. All Rh(1)-N(2) bond lengths are 1.82 Å. All Rh(1)-O(1) bond lengths are 2.21 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.34 Å. The N(1)-O(2) bond length is 1.25 Å. The N(1)-O(3) bond length is 1.23 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom.