ZnGa2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. Ga(1) is bonded to six equivalent O(1) atoms to form GaO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra and edges with six equivalent Ga(1)O6 octahedra. O(1) is bonded to one Zn(1) and three equivalent Ga(1) atoms to form a mixture of distorted corner and edge-sharing OZnGa3 trigonal pyramids.
ZnGa2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. All Zn(1)-O(1) bond lengths are 1.97 Å. Ga(1) is bonded to six equivalent O(1) atoms to form GaO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra and edges with six equivalent Ga(1)O6 octahedra. All Ga(1)-O(1) bond lengths are 1.99 Å. O(1) is bonded to one Zn(1) and three equivalent Ga(1) atoms to form a mixture of distorted corner and edge-sharing OZnGa3 trigonal pyramids.