POClF2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight chlorodifluorophosphorus oxide molecules. P(1) is bonded in a distorted tetrahedral geometry to one O(2), one Cl(1), and two equivalent F(1) atoms. O(2) is bonded in a single-bond geometry to one P(1) atom. Cl(1) is bonded in a single-bond geometry to one P(1) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.
POClF2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight chlorodifluorophosphorus oxide molecules. P(1) is bonded in a distorted tetrahedral geometry to one O(2), one Cl(1), and two equivalent F(1) atoms. The P(1)-O(2) bond length is 1.45 Å. The P(1)-Cl(1) bond length is 1.95 Å. Both P(1)-F(1) bond lengths are 1.54 Å. O(2) is bonded in a single-bond geometry to one P(1) atom. Cl(1) is bonded in a single-bond geometry to one P(1) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.