KRhAs2 crystallizes in the tetragonal I-4m2 space group. K(1) is bonded in a distorted body-centered cubic geometry to eight equivalent As(1) atoms. Rh(1) is bonded to four equivalent As(1) atoms to form distorted corner-sharing RhAs4 tetrahedra. As(1) is bonded in a 6-coordinate geometry to four equivalent K(1) and two equivalent Rh(1) atoms.
KRhAs2 crystallizes in the tetragonal I-4m2 space group. K(1) is bonded in a distorted body-centered cubic geometry to eight equivalent As(1) atoms. All K(1)-As(1) bond lengths are 3.51 Å. Rh(1) is bonded to four equivalent As(1) atoms to form distorted corner-sharing RhAs4 tetrahedra. All Rh(1)-As(1) bond lengths are 2.36 Å. As(1) is bonded in a 6-coordinate geometry to four equivalent K(1) and two equivalent Rh(1) atoms.