PNF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PNF2 clusters. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one F(1), and one F(2) atom to form corner-sharing PN2F2 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one F(3), and one F(4) atom to form corner-sharing PN2F2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(2) atom.
PNF2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PNF2 clusters. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one F(1), and one F(2) atom to form corner-sharing PN2F2 tetrahedra. The P(1)-N(1) bond length is 1.56 Å. The P(1)-N(2) bond length is 1.56 Å. The P(1)-F(1) bond length is 1.56 Å. The P(1)-F(2) bond length is 1.56 Å. In the second P site, P(2) is bonded to one N(1), one N(2), one F(3), and one F(4) atom to form corner-sharing PN2F2 tetrahedra. The P(2)-N(1) bond length is 1.56 Å. The P(2)-N(2) bond length is 1.56 Å. The P(2)-F(3) bond length is 1.56 Å. The P(2)-F(4) bond length is 1.56 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(2) atom.