TiOsGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Os(2), two equivalent Ge(1), and four equivalent Ge(2) atoms. In the second Ti site, Ti(2) is bonded in a 9-coordinate geometry to two equivalent Os(1), two equivalent Os(2), one Ge(1), and four equivalent Ge(2) atoms. In the third Ti site, Ti(3) is bonded in a 11-coordinate geometry to two equivalent Os(1), four equivalent Os(2), one Ge(1), and four equivalent Ge(2) atoms. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 8-coordinate geometry to two equivalent Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the second Os site, Os(2) is bonded in a 8-coordinate geometry to one Ti(1), one Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Os(1), and four equivalent Os(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Os(1), and two equivalent Os(2) atoms.
TiOsGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Os(2), two equivalent Ge(1), and four equivalent Ge(2) atoms. Both Ti(1)-Os(2) bond lengths are 2.82 Å. There is one shorter (2.70 Å) and one longer (3.14 Å) Ti(1)-Ge(1) bond length. There are two shorter (2.64 Å) and two longer (2.68 Å) Ti(1)-Ge(2) bond lengths. In the second Ti site, Ti(2) is bonded in a 9-coordinate geometry to two equivalent Os(1), two equivalent Os(2), one Ge(1), and four equivalent Ge(2) atoms. Both Ti(2)-Os(1) bond lengths are 2.82 Å. Both Ti(2)-Os(2) bond lengths are 2.84 Å. The Ti(2)-Ge(1) bond length is 2.74 Å. There are two shorter (2.65 Å) and two longer (2.70 Å) Ti(2)-Ge(2) bond lengths. In the third Ti site, Ti(3) is bonded in a 11-coordinate geometry to two equivalent Os(1), four equivalent Os(2), one Ge(1), and four equivalent Ge(2) atoms. Both Ti(3)-Os(1) bond lengths are 2.88 Å. There are two shorter (2.74 Å) and two longer (2.77 Å) Ti(3)-Os(2) bond lengths. The Ti(3)-Ge(1) bond length is 2.98 Å. There are two shorter (2.67 Å) and two longer (2.70 Å) Ti(3)-Ge(2) bond lengths. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 8-coordinate geometry to two equivalent Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. Both Os(1)-Ge(1) bond lengths are 2.53 Å. Both Os(1)-Ge(2) bond lengths are 2.51 Å. In the second Os site, Os(2) is bonded in a 8-coordinate geometry to one Ti(1), one Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There is one shorter (2.46 Å) and one longer (2.53 Å) Os(2)-Ge(1) bond length. Both Os(2)-Ge(2) bond lengths are 2.50 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Os(1), and four equivalent Os(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Os(1), and two equivalent Os(2) atoms.