ZnH3(CO2)3N(CH3)2 crystallizes in the monoclinic Cc space group. The structure consists of four dimethylamine molecules inside a ZnH3(CO2)3 framework. In the ZnH3(CO2)3 framework, Zn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are three inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one H(7), one O(1), and one O(5) atom. In the second C site, C(4) is bonded in a trigonal planar geometry to one H(8), one O(2), and one O(4) atom. In the third C site, C(5) is bonded in a trigonal planar geometry to one H(9), one O(3), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom.
ZnH3(CO2)3N(CH3)2 crystallizes in the monoclinic Cc space group. The structure consists of four dimethylamine molecules inside a ZnH3(CO2)3 framework. In the ZnH3(CO2)3 framework, Zn(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.18 Å. The Zn(1)-O(2) bond length is 2.10 Å. The Zn(1)-O(3) bond length is 2.13 Å. The Zn(1)-O(4) bond length is 2.11 Å. The Zn(1)-O(5) bond length is 2.13 Å. The Zn(1)-O(6) bond length is 2.17 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one H(7), one O(1), and one O(5) atom. The C(3)-H(7) bond length is 1.11 Å. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(5) bond length is 1.27 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one H(8), one O(2), and one O(4) atom. The C(4)-H(8) bond length is 1.11 Å. The C(4)-O(2) bond length is 1.27 Å. The C(4)-O(4) bond length is 1.27 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one H(9), one O(3), and one O(6) atom. The C(5)-H(9) bond length is 1.11 Å. The C(5)-O(3) bond length is 1.27 Å. The C(5)-O(6) bond length is 1.27 Å. There are three inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom.