TbAg3C6H6(N2O)3 crystallizes in the hexagonal P6_3/mcm space group. Tb(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(1) atoms. Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. N(1) is bonded in a distorted linear geometry to one Tb(1) and one C(1) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one Tb(1) and two equivalent H(1) atoms.
TbAg3C6H6(N2O)3 crystallizes in the hexagonal P6_3/mcm space group. Tb(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(1) atoms. All Tb(1)-N(1) bond lengths are 2.52 Å. All Tb(1)-O(1) bond lengths are 2.44 Å. Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. Both Ag(1)-C(1) bond lengths are 2.06 Å. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. N(1) is bonded in a distorted linear geometry to one Tb(1) and one C(1) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. O(1) is bonded in a water-like geometry to one Tb(1) and two equivalent H(1) atoms.