YbRh3B2 crystallizes in the hexagonal P6/mmm space group. Yb(1) is bonded in a 20-coordinate geometry to two equivalent Yb(1), twelve equivalent Rh(1), and six equivalent B(1) atoms. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Yb(1) and four equivalent B(1) atoms. B(1) is bonded in a 6-coordinate geometry to three equivalent Yb(1) and six equivalent Rh(1) atoms.
YbRh3B2 crystallizes in the hexagonal P6/mmm space group. Yb(1) is bonded in a 20-coordinate geometry to two equivalent Yb(1), twelve equivalent Rh(1), and six equivalent B(1) atoms. Both Yb(1)-Yb(1) bond lengths are 2.91 Å. All Yb(1)-Rh(1) bond lengths are 3.12 Å. All Yb(1)-B(1) bond lengths are 3.18 Å. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Yb(1) and four equivalent B(1) atoms. All Rh(1)-B(1) bond lengths are 2.16 Å. B(1) is bonded in a 6-coordinate geometry to three equivalent Yb(1) and six equivalent Rh(1) atoms.