Li2MnF6 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(12), one F(13), one F(3), one F(34), one F(6), and one F(7) atom to form distorted LiF6 octahedra that share  a cornercorner with one Mn(2)F6 octahedra,  a cornercorner with one Mn(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Mn(1)F6 octahedra,  an edgeedge with one Mn(3)F6 octahedra, and  an edgeedge with one Li(3)F5 square pyramid. The corner-sharing octahedral tilt angles range from 17-47°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(10), one F(14), one F(16), one F(21), and one F(9) atom. In the third Li site, Li(3) is bonded to one F(13), one F(17), one F(19), one F(24), and one F(7) atom to form distorted LiF5 square pyramids that share  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra,  a cornercorner with one Mn(6)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Mn(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 41-64°. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one F(1), one F(14), one F(19), one F(26), one F(4), and one F(8) atom. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one F(11), one F(18), one F(23), one F(29), one F(33), and one F(36) atom. In the sixth Li site, Li(6) is bonded to one F(1), one F(15), one F(20), one F(25), one F(27), and one F(35) atom to form LiF6 octahedra that share  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra,  a cornercorner with one Li(10)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-66°. In the seventh Li site, Li(7) is bonded to one F(16), one F(21), one F(23), one F(27), and one F(28) atom to form distorted LiF5 trigonal bipyramids that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Mn(3)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra,  a cornercorner with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-78°. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one F(11), one F(14), one F(21), one F(22), one F(26), and one F(33) atom. In the ninth Li site, Li(9) is bonded to one F(24), one F(25), one F(3), one F(30), one F(31), and one F(34) atom to form distorted LiF6 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(2)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra,  an edgeedge with one Li(1)F6 octahedra,  an edgeedge with one Mn(5)F6 octahedra, and  an edgeedge with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 19-66°. In the tenth Li site, Li(10) is bonded to one F(20), one F(29), one F(31), and one F(8) atom to form LiF4 tetrahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(2)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra, and  a cornercorner with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-66°. In the eleventh Li site, Li(11) is bonded in a 4-coordinate geometry to one F(2), one F(28), one F(30), one F(34), and one F(6) atom. In the twelfth Li site, Li(12) is bonded to one F(10), one F(32), one F(33), and one F(5) atom to form LiF4 tetrahedra that share  a cornercorner with one Mn(3)F6 octahedra,  a cornercorner with one Mn(4)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra, and  a cornercorner with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one F(13), one F(15), one F(3), one F(4), one F(8), and one F(9) atom to form MnF6 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra, and  an edgeedge with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 19-42°. In the second Mn site, Mn(2) is bonded to one F(1), one F(17), one F(20), one F(30), one F(36), and one F(7) atom to form MnF6 octahedra that share  a cornercorner with one Li(1)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Li(10)F4 tetrahedra,  an edgeedge with one Li(6)F6 octahedra, and  an edgeedge with one Li(3)F5 square pyramid. The corner-sharing octahedral tilt angles range from 47-53°. In the third Mn site, Mn(3) is bonded to one F(11), one F(12), one F(16), one F(18), one F(5), and one F(6) atom to form MnF6 octahedra that share  a cornercorner with one Li(12)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid, and  an edgeedge with one Li(1)F6 octahedra. In the fourth Mn site, Mn(4) is bonded to one F(10), one F(14), one F(2), one F(23), one F(27), and one F(35) atom to form MnF6 octahedra that share  a cornercorner with one Li(12)F4 tetrahedra,  an edgeedge with one Li(6)F6 octahedra, and  an edgeedge with one Li(7)F5 trigonal bipyramid. In the fifth Mn site, Mn(5) is bonded to one F(19), one F(21), one F(25), one F(26), one F(31), and one F(32) atom to form MnF6 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra,  a cornercorner with one Li(12)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid, and  an edgeedge with one Li(9)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. In the sixth Mn site, Mn(6) is bonded to one F(22), one F(24), one F(28), one F(29), one F(33), and one F(34) atom to form MnF6 octahedra that share  a cornercorner with one Li(1)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra,  a cornercorner with one Li(12)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid, and  an edgeedge with one Li(9)F6 octahedra. The corner-sharing octahedral tilt angles are 17°. There are thirty-six inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(6), and one Mn(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Li(11) and one Mn(4) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(1), one Li(9), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a water-like geometry to one Li(4) and one Mn(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Li(12) and one Mn(3) atom. In the sixth F site, F(6) is bonded in a trigonal non-coplanar geometry to one Li(1), one Li(11), and one Mn(3) atom. In the seventh F site, F(7) is bonded in a distorted T-shaped geometry to one Li(1), one Li(3), and one Mn(2) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(10), one Li(4), and one Mn(1) atom. In the ninth F site, F(9) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one Mn(1) atom. In the tenth F site, F(10) is bonded in a trigonal non-coplanar geometry to one Li(12), one Li(2), and one Mn(4) atom. In the eleventh F site, F(11) is bonded in a distorted T-shaped geometry to one Li(5), one Li(8), and one Mn(3) atom. In the twelfth F site, F(12) is bonded in a water-like geometry to one Li(1) and one Mn(3) atom. In the thirteenth F site, F(13) is bonded in a T-shaped geometry to one Li(1), one Li(3), and one Mn(1) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal pyramidal geometry to one Li(2), one Li(4), one Li(8), and one Mn(4) atom. In the fifteenth F site, F(15) is bonded in a bent 150 degrees geometry to one Li(6) and one Mn(1) atom. In the sixteenth F site, F(16) is bonded in a distorted T-shaped geometry to one Li(2), one Li(7), and one Mn(3) atom. In the seventeenth F site, F(17) is bonded in a water-like geometry to one Li(3) and one Mn(2) atom. In the eighteenth F site, F(18) is bonded in a water-like geometry to one Li(5) and one Mn(3) atom. In the nineteenth F site, F(19) is bonded in a trigonal planar geometry to one Li(3), one Li(4), and one Mn(5) atom. In the twentieth F site, F(20) is bonded in a trigonal non-coplanar geometry to one Li(10), one Li(6), and one Mn(2) atom. In the twenty-first F site, F(21) is bonded in a 4-coordinate geometry to one Li(2), one Li(7), one Li(8), and one Mn(5) atom. In the twenty-second F site, F(22) is bonded in a water-like geometry to one Li(8) and one Mn(6) atom. In the twenty-third F site, F(23) is bonded in a distorted trigonal planar geometry to one Li(5), one Li(7), and one Mn(4) atom. In the twenty-fourth F site, F(24) is bonded in a 3-coordinate geometry to one Li(3), one Li(9), and one Mn(6) atom. In the twenty-fifth F site, F(25) is bonded in a trigonal planar geometry to one Li(6), one Li(9), and one Mn(5) atom. In the twenty-sixth F site, F(26) is bonded in a 3-coordinate geometry to one Li(4), one Li(8), and one Mn(5) atom. In the twenty-seventh F site, F(27) is bonded in a distorted trigonal non-coplanar geometry to one Li(6), one Li(7), and one Mn(4) atom. In the twenty-eighth F site, F(28) is bonded in a trigonal planar geometry to one Li(11), one Li(7), and one Mn(6) atom. In the twenty-ninth F site, F(29) is bonded in a 2-coordinate geometry to one Li(10), one Li(5), and one Mn(6) atom. In the thirtieth F site, F(30) is bonded in a trigonal planar geometry to one Li(11), one Li(9), and one Mn(2) atom. In the thirty-first F site, F(31) is bonded in a distorted trigonal planar geometry to one Li(10), one Li(9), and one Mn(5) atom. In the thirty-second F site, F(32) is bonded in a distorted bent 150 degrees geometry to one Li(12) and one Mn(5) atom. In the thirty-third F site, F(33) is bonded in a distorted rectangular see-saw-like geometry to one Li(12), one Li(5), one Li(8), and one Mn(6) atom. In the thirty-fourth F site, F(34) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(11), one Li(9), and one Mn(6) atom. In the thirty-fifth F site, F(35) is bonded in a water-like geometry to one Li(6) and one Mn(4) atom. In the thirty-sixth F site, F(36) is bonded in a bent 150 degrees geometry to one Li(5) and one Mn(2) atom.
Li2MnF6 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(12), one F(13), one F(3), one F(34), one F(6), and one F(7) atom to form distorted LiF6 octahedra that share  a cornercorner with one Mn(2)F6 octahedra,  a cornercorner with one Mn(6)F6 octahedra,  an edgeedge with one Li(9)F6 octahedra,  an edgeedge with one Mn(1)F6 octahedra,  an edgeedge with one Mn(3)F6 octahedra, and  an edgeedge with one Li(3)F5 square pyramid. The corner-sharing octahedral tilt angles range from 17-47°. The Li(1)-F(12) bond length is 1.97 Å. The Li(1)-F(13) bond length is 2.13 Å. The Li(1)-F(3) bond length is 1.98 Å. The Li(1)-F(34) bond length is 2.06 Å. The Li(1)-F(6) bond length is 2.23 Å. The Li(1)-F(7) bond length is 2.05 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one F(10), one F(14), one F(16), one F(21), and one F(9) atom. The Li(2)-F(10) bond length is 1.99 Å. The Li(2)-F(14) bond length is 2.29 Å. The Li(2)-F(16) bond length is 1.95 Å. The Li(2)-F(21) bond length is 2.14 Å. The Li(2)-F(9) bond length is 1.85 Å. In the third Li site, Li(3) is bonded to one F(13), one F(17), one F(19), one F(24), and one F(7) atom to form distorted LiF5 square pyramids that share  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra,  a cornercorner with one Mn(6)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Mn(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 41-64°. The Li(3)-F(13) bond length is 1.98 Å. The Li(3)-F(17) bond length is 2.05 Å. The Li(3)-F(19) bond length is 1.97 Å. The Li(3)-F(24) bond length is 1.99 Å. The Li(3)-F(7) bond length is 2.23 Å. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one F(1), one F(14), one F(19), one F(26), one F(4), and one F(8) atom. The Li(4)-F(1) bond length is 1.93 Å. The Li(4)-F(14) bond length is 2.08 Å. The Li(4)-F(19) bond length is 2.03 Å. The Li(4)-F(26) bond length is 2.40 Å. The Li(4)-F(4) bond length is 1.93 Å. The Li(4)-F(8) bond length is 2.42 Å. In the fifth Li site, Li(5) is bonded in a 6-coordinate geometry to one F(11), one F(18), one F(23), one F(29), one F(33), and one F(36) atom. The Li(5)-F(11) bond length is 2.31 Å. The Li(5)-F(18) bond length is 1.90 Å. The Li(5)-F(23) bond length is 1.98 Å. The Li(5)-F(29) bond length is 2.49 Å. The Li(5)-F(33) bond length is 2.07 Å. The Li(5)-F(36) bond length is 1.91 Å. In the sixth Li site, Li(6) is bonded to one F(1), one F(15), one F(20), one F(25), one F(27), and one F(35) atom to form LiF6 octahedra that share  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra,  a cornercorner with one Li(10)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid,  an edgeedge with one Mn(2)F6 octahedra, and  an edgeedge with one Mn(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-66°. The Li(6)-F(1) bond length is 2.17 Å. The Li(6)-F(15) bond length is 1.98 Å. The Li(6)-F(20) bond length is 2.01 Å. The Li(6)-F(25) bond length is 2.05 Å. The Li(6)-F(27) bond length is 2.12 Å. The Li(6)-F(35) bond length is 2.10 Å. In the seventh Li site, Li(7) is bonded to one F(16), one F(21), one F(23), one F(27), and one F(28) atom to form distorted LiF5 trigonal bipyramids that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Mn(3)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra,  a cornercorner with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-78°. The Li(7)-F(16) bond length is 1.99 Å. The Li(7)-F(21) bond length is 2.07 Å. The Li(7)-F(23) bond length is 2.15 Å. The Li(7)-F(27) bond length is 2.04 Å. The Li(7)-F(28) bond length is 1.99 Å. In the eighth Li site, Li(8) is bonded in a 6-coordinate geometry to one F(11), one F(14), one F(21), one F(22), one F(26), and one F(33) atom. The Li(8)-F(11) bond length is 1.87 Å. The Li(8)-F(14) bond length is 2.05 Å. The Li(8)-F(21) bond length is 2.48 Å. The Li(8)-F(22) bond length is 2.00 Å. The Li(8)-F(26) bond length is 2.02 Å. The Li(8)-F(33) bond length is 2.34 Å. In the ninth Li site, Li(9) is bonded to one F(24), one F(25), one F(3), one F(30), one F(31), and one F(34) atom to form distorted LiF6 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(2)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra,  an edgeedge with one Li(1)F6 octahedra,  an edgeedge with one Mn(5)F6 octahedra, and  an edgeedge with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 19-66°. The Li(9)-F(24) bond length is 2.35 Å. The Li(9)-F(25) bond length is 1.96 Å. The Li(9)-F(3) bond length is 1.94 Å. The Li(9)-F(30) bond length is 2.03 Å. The Li(9)-F(31) bond length is 2.32 Å. The Li(9)-F(34) bond length is 2.08 Å. In the tenth Li site, Li(10) is bonded to one F(20), one F(29), one F(31), and one F(8) atom to form LiF4 tetrahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Mn(1)F6 octahedra,  a cornercorner with one Mn(2)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra, and  a cornercorner with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-66°. The Li(10)-F(20) bond length is 1.89 Å. The Li(10)-F(29) bond length is 1.93 Å. The Li(10)-F(31) bond length is 1.95 Å. The Li(10)-F(8) bond length is 1.86 Å. In the eleventh Li site, Li(11) is bonded in a 4-coordinate geometry to one F(2), one F(28), one F(30), one F(34), and one F(6) atom. The Li(11)-F(2) bond length is 1.88 Å. The Li(11)-F(28) bond length is 2.04 Å. The Li(11)-F(30) bond length is 1.96 Å. The Li(11)-F(34) bond length is 2.47 Å. The Li(11)-F(6) bond length is 1.96 Å. In the twelfth Li site, Li(12) is bonded to one F(10), one F(32), one F(33), and one F(5) atom to form LiF4 tetrahedra that share  a cornercorner with one Mn(3)F6 octahedra,  a cornercorner with one Mn(4)F6 octahedra,  a cornercorner with one Mn(5)F6 octahedra, and  a cornercorner with one Mn(6)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. The Li(12)-F(10) bond length is 1.90 Å. The Li(12)-F(32) bond length is 1.87 Å. The Li(12)-F(33) bond length is 1.95 Å. The Li(12)-F(5) bond length is 1.85 Å. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one F(13), one F(15), one F(3), one F(4), one F(8), and one F(9) atom to form MnF6 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra, and  an edgeedge with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 19-42°. The Mn(1)-F(13) bond length is 1.87 Å. The Mn(1)-F(15) bond length is 1.84 Å. The Mn(1)-F(3) bond length is 1.88 Å. The Mn(1)-F(4) bond length is 1.82 Å. The Mn(1)-F(8) bond length is 1.85 Å. The Mn(1)-F(9) bond length is 1.82 Å. In the second Mn site, Mn(2) is bonded to one F(1), one F(17), one F(20), one F(30), one F(36), and one F(7) atom to form MnF6 octahedra that share  a cornercorner with one Li(1)F6 octahedra,  a cornercorner with one Li(9)F6 octahedra,  a cornercorner with one Li(10)F4 tetrahedra,  an edgeedge with one Li(6)F6 octahedra, and  an edgeedge with one Li(3)F5 square pyramid. The corner-sharing octahedral tilt angles range from 47-53°. The Mn(2)-F(1) bond length is 1.86 Å. The Mn(2)-F(17) bond length is 1.81 Å. The Mn(2)-F(20) bond length is 1.87 Å. The Mn(2)-F(30) bond length is 1.87 Å. The Mn(2)-F(36) bond length is 1.82 Å. The Mn(2)-F(7) bond length is 1.84 Å. In the third Mn site, Mn(3) is bonded to one F(11), one F(12), one F(16), one F(18), one F(5), and one F(6) atom to form MnF6 octahedra that share  a cornercorner with one Li(12)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid, and  an edgeedge with one Li(1)F6 octahedra. The Mn(3)-F(11) bond length is 1.85 Å. The Mn(3)-F(12) bond length is 1.83 Å. The Mn(3)-F(16) bond length is 1.89 Å. The Mn(3)-F(18) bond length is 1.82 Å. The Mn(3)-F(5) bond length is 1.85 Å. The Mn(3)-F(6) bond length is 1.84 Å. In the fourth Mn site, Mn(4) is bonded to one F(10), one F(14), one F(2), one F(23), one F(27), and one F(35) atom to form MnF6 octahedra that share  a cornercorner with one Li(12)F4 tetrahedra,  an edgeedge with one Li(6)F6 octahedra, and  an edgeedge with one Li(7)F5 trigonal bipyramid. The Mn(4)-F(10) bond length is 1.86 Å. The Mn(4)-F(14) bond length is 1.89 Å. The Mn(4)-F(2) bond length is 1.82 Å. The Mn(4)-F(23) bond length is 1.85 Å. The Mn(4)-F(27) bond length is 1.84 Å. The Mn(4)-F(35) bond length is 1.81 Å. In the fifth Mn site, Mn(5) is bonded to one F(19), one F(21), one F(25), one F(26), one F(31), and one F(32) atom to form MnF6 octahedra that share  a cornercorner with one Li(6)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra,  a cornercorner with one Li(12)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid, and  an edgeedge with one Li(9)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. The Mn(5)-F(19) bond length is 1.87 Å. The Mn(5)-F(21) bond length is 1.89 Å. The Mn(5)-F(25) bond length is 1.86 Å. The Mn(5)-F(26) bond length is 1.83 Å. The Mn(5)-F(31) bond length is 1.84 Å. The Mn(5)-F(32) bond length is 1.80 Å. In the sixth Mn site, Mn(6) is bonded to one F(22), one F(24), one F(28), one F(29), one F(33), and one F(34) atom to form MnF6 octahedra that share  a cornercorner with one Li(1)F6 octahedra,  a cornercorner with one Li(3)F5 square pyramid,  a cornercorner with one Li(10)F4 tetrahedra,  a cornercorner with one Li(12)F4 tetrahedra,  a cornercorner with one Li(7)F5 trigonal bipyramid, and  an edgeedge with one Li(9)F6 octahedra. The corner-sharing octahedral tilt angles are 17°. The Mn(6)-F(22) bond length is 1.81 Å. The Mn(6)-F(24) bond length is 1.83 Å. The Mn(6)-F(28) bond length is 1.87 Å. The Mn(6)-F(29) bond length is 1.83 Å. The Mn(6)-F(33) bond length is 1.89 Å. The Mn(6)-F(34) bond length is 1.88 Å. There are thirty-six inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(6), and one Mn(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Li(11) and one Mn(4) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(1), one Li(9), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a water-like geometry to one Li(4) and one Mn(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one Li(12) and one Mn(3) atom. In the sixth F site, F(6) is bonded in a trigonal non-coplanar geometry to one Li(1), one Li(11), and one Mn(3) atom. In the seventh F site, F(7) is bonded in a distorted T-shaped geometry to one Li(1), one Li(3), and one Mn(2) atom. In the eighth F site, F(8) is bonded in a 3-coordinate geometry to one Li(10), one Li(4), and one Mn(1) atom. In the ninth F site, F(9) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one Mn(1) atom. In the tenth F site, F(10) is bonded in a trigonal non-coplanar geometry to one Li(12), one Li(2), and one Mn(4) atom. In the eleventh F site, F(11) is bonded in a distorted T-shaped geometry to one Li(5), one Li(8), and one Mn(3) atom. In the twelfth F site, F(12) is bonded in a water-like geometry to one Li(1) and one Mn(3) atom. In the thirteenth F site, F(13) is bonded in a T-shaped geometry to one Li(1), one Li(3), and one Mn(1) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal pyramidal geometry to one Li(2), one Li(4), one Li(8), and one Mn(4) atom. In the fifteenth F site, F(15) is bonded in a bent 150 degrees geometry to one Li(6) and one Mn(1) atom. In the sixteenth F site, F(16) is bonded in a distorted T-shaped geometry to one Li(2), one Li(7), and one Mn(3) atom. In the seventeenth F site, F(17) is bonded in a water-like geometry to one Li(3) and one Mn(2) atom. In the eighteenth F site, F(18) is bonded in a water-like geometry to one Li(5) and one Mn(3) atom. In the nineteenth F site, F(19) is bonded in a trigonal planar geometry to one Li(3), one Li(4), and one Mn(5) atom. In the twentieth F site, F(20) is bonded in a trigonal non-coplanar geometry to one Li(10), one Li(6), and one Mn(2) atom. In the twenty-first F site, F(21) is bonded in a 4-coordinate geometry to one Li(2), one Li(7), one Li(8), and one Mn(5) atom. In the twenty-second F site, F(22) is bonded in a water-like geometry to one Li(8) and one Mn(6) atom. In the twenty-third F site, F(23) is bonded in a distorted trigonal planar geometry to one Li(5), one Li(7), and one Mn(4) atom. In the twenty-fourth F site, F(24) is bonded in a 3-coordinate geometry to one Li(3), one Li(9), and one Mn(6) atom. In the twenty-fifth F site, F(25) is bonded in a trigonal planar geometry to one Li(6), one Li(9), and one Mn(5) atom. In the twenty-sixth F site, F(26) is bonded in a 3-coordinate geometry to one Li(4), one Li(8), and one Mn(5) atom. In the twenty-seventh F site, F(27) is bonded in a distorted trigonal non-coplanar geometry to one Li(6), one Li(7), and one Mn(4) atom. In the twenty-eighth F site, F(28) is bonded in a trigonal planar geometry to one Li(11), one Li(7), and one Mn(6) atom. In the twenty-ninth F site, F(29) is bonded in a 2-coordinate geometry to one Li(10), one Li(5), and one Mn(6) atom. In the thirtieth F site, F(30) is bonded in a trigonal planar geometry to one Li(11), one Li(9), and one Mn(2) atom. In the thirty-first F site, F(31) is bonded in a distorted trigonal planar geometry to one Li(10), one Li(9), and one Mn(5) atom. In the thirty-second F site, F(32) is bonded in a distorted bent 150 degrees geometry to one Li(12) and one Mn(5) atom. In the thirty-third F site, F(33) is bonded in a distorted rectangular see-saw-like geometry to one Li(12), one Li(5), one Li(8), and one Mn(6) atom. In the thirty-fourth F site, F(34) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(11), one Li(9), and one Mn(6) atom. In the thirty-fifth F site, F(35) is bonded in a water-like geometry to one Li(6) and one Mn(4) atom. In the thirty-sixth F site, F(36) is bonded in a bent 150 degrees geometry to one Li(5) and one Mn(2) atom.