BaLaMnRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), four equivalent O(3), and four equivalent O(4) atoms. La(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. Mn(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-31°. Ru(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form RuO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-31°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one Mn(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one La(1), one Mn(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), one Mn(1), and one Ru(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), one Mn(1), and one Ru(1) atom.
BaLaMnRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), four equivalent O(3), and four equivalent O(4) atoms. There is one shorter (2.61 Å) and one longer (3.18 Å) Ba(1)-O(1) bond length. Both Ba(1)-O(2) bond lengths are 2.94 Å. There are two shorter (2.75 Å) and two longer (3.07 Å) Ba(1)-O(3) bond lengths. There are two shorter (2.78 Å) and two longer (2.99 Å) Ba(1)-O(4) bond lengths. La(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. The La(1)-O(2) bond length is 2.44 Å. Both La(1)-O(3) bond lengths are 2.48 Å. Both La(1)-O(4) bond lengths are 2.50 Å. Mn(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-31°. The Mn(1)-O(1) bond length is 2.15 Å. The Mn(1)-O(2) bond length is 2.16 Å. Both Mn(1)-O(3) bond lengths are 2.14 Å. Both Mn(1)-O(4) bond lengths are 2.17 Å. Ru(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form RuO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-31°. The Ru(1)-O(1) bond length is 1.96 Å. The Ru(1)-O(2) bond length is 2.03 Å. Both Ru(1)-O(3) bond lengths are 2.01 Å. Both Ru(1)-O(4) bond lengths are 1.99 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one Mn(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Ba(1), one La(1), one Mn(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one La(1), one Mn(1), and one Ru(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one La(1), one Mn(1), and one Ru(1) atom.