CsLu(MoO4)2 crystallizes in the orthorhombic Pccm space group. Cs(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(3) atoms. Lu(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Lu(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Lu(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom.
CsLu(MoO4)2 crystallizes in the orthorhombic Pccm space group. Cs(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(3) atoms. All Cs(1)-O(2) bond lengths are 3.40 Å. All Cs(1)-O(3) bond lengths are 3.13 Å. Lu(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Lu(1)-O(1) bond lengths are 2.43 Å. All Lu(1)-O(2) bond lengths are 2.25 Å. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. The Mo(1)-O(1) bond length is 1.87 Å. The Mo(1)-O(3) bond length is 1.75 Å. Both Mo(1)-O(2) bond lengths are 1.81 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Lu(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Lu(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom.