NaSbO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 29°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Na(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded to two equivalent Na(1) and two equivalent Sb(1) atoms to form distorted corner-sharing ONa2Sb2 tetrahedra.
NaSbO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.32 Å) and one longer (2.48 Å) Na(1)-O(2) bond length. There are a spread of Na(1)-O(1) bond distances ranging from 2.34-2.74 Å. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 29°. Both Sb(1)-O(2) bond lengths are 2.01 Å. There are two shorter (2.01 Å) and two longer (2.02 Å) Sb(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Na(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded to two equivalent Na(1) and two equivalent Sb(1) atoms to form distorted corner-sharing ONa2Sb2 tetrahedra.