Ag2PO2 crystallizes in the orthorhombic Fddd space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent P(1), and two equivalent O(1) atoms. P(1) is bonded in a linear geometry to four equivalent Ag(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(1) atom.
Ag2PO2 crystallizes in the orthorhombic Fddd space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent P(1), and two equivalent O(1) atoms. There is one shorter (2.78 Å) and one longer (2.79 Å) Ag(1)-Ag(1) bond length. There is one shorter (2.67 Å) and one longer (2.78 Å) Ag(1)-P(1) bond length. There is one shorter (2.53 Å) and one longer (2.66 Å) Ag(1)-O(1) bond length. P(1) is bonded in a linear geometry to four equivalent Ag(1) and two equivalent O(1) atoms. Both P(1)-O(1) bond lengths are 1.53 Å. O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(1) atom.