Ba(OBr)2 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to four equivalent O(1) and six equivalent Br(1) atoms. O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and two equivalent Br(1) atoms. Br(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1) and two equivalent O(1) atoms.
Ba(OBr)2 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to four equivalent O(1) and six equivalent Br(1) atoms. There are two shorter (2.80 Å) and two longer (2.87 Å) Ba(1)-O(1) bond lengths. There are a spread of Ba(1)-Br(1) bond distances ranging from 3.37-3.48 Å. O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and two equivalent Br(1) atoms. Both O(1)-Br(1) bond lengths are 2.62 Å. Br(1) is bonded in a 5-coordinate geometry to three equivalent Ba(1) and two equivalent O(1) atoms.