Li2AgSb is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to six equivalent Ag(1) and four equivalent Sb(1) atoms to form distorted LiAg6Sb4 tetrahedra that share corners with six equivalent Li(1)Ag6Sb4 tetrahedra, edges with twelve equivalent Li(2)Ag4Sb6 tetrahedra, faces with four equivalent Li(2)Ag4Sb6 tetrahedra, and faces with twelve equivalent Li(1)Ag6Sb4 tetrahedra. In the second Li site, Li(2) is bonded to four equivalent Ag(1) and six equivalent Sb(1) atoms to form distorted LiAg4Sb6 tetrahedra that share corners with six equivalent Li(2)Ag4Sb6 tetrahedra, edges with twelve equivalent Li(1)Ag6Sb4 tetrahedra, faces with four equivalent Li(1)Ag6Sb4 tetrahedra, and faces with twelve equivalent Li(2)Ag4Sb6 tetrahedra. Ag(1) is bonded in a 14-coordinate geometry to four equivalent Li(2), six equivalent Li(1), and four equivalent Sb(1) atoms. Sb(1) is bonded in a 14-coordinate geometry to four equivalent Li(1), six equivalent Li(2), and four equivalent Ag(1) atoms.
Li2AgSb is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to six equivalent Ag(1) and four equivalent Sb(1) atoms to form distorted LiAg6Sb4 tetrahedra that share corners with six equivalent Li(1)Ag6Sb4 tetrahedra, edges with twelve equivalent Li(2)Ag4Sb6 tetrahedra, faces with four equivalent Li(2)Ag4Sb6 tetrahedra, and faces with twelve equivalent Li(1)Ag6Sb4 tetrahedra. All Li(1)-Ag(1) bond lengths are 3.30 Å. All Li(1)-Sb(1) bond lengths are 2.86 Å. In the second Li site, Li(2) is bonded to four equivalent Ag(1) and six equivalent Sb(1) atoms to form distorted LiAg4Sb6 tetrahedra that share corners with six equivalent Li(2)Ag4Sb6 tetrahedra, edges with twelve equivalent Li(1)Ag6Sb4 tetrahedra, faces with four equivalent Li(1)Ag6Sb4 tetrahedra, and faces with twelve equivalent Li(2)Ag4Sb6 tetrahedra. All Li(2)-Ag(1) bond lengths are 2.86 Å. All Li(2)-Sb(1) bond lengths are 3.30 Å. Ag(1) is bonded in a 14-coordinate geometry to four equivalent Li(2), six equivalent Li(1), and four equivalent Sb(1) atoms. All Ag(1)-Sb(1) bond lengths are 2.86 Å. Sb(1) is bonded in a 14-coordinate geometry to four equivalent Li(1), six equivalent Li(2), and four equivalent Ag(1) atoms.