YbRhIn4 crystallizes in the orthorhombic Pmma space group. Yb(1) is bonded in a 13-coordinate geometry to one Rh(1), two equivalent In(2), two equivalent In(3), and eight equivalent In(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to one Yb(1), two equivalent In(2), two equivalent In(3), and four equivalent In(1) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 2-coordinate geometry to four equivalent Yb(1) and two equivalent Rh(1) atoms. In the second In site, In(2) is bonded in a linear geometry to two equivalent Yb(1) and two equivalent Rh(1) atoms. In the third In site, In(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Yb(1) and two equivalent Rh(1) atoms.
YbRhIn4 crystallizes in the orthorhombic Pmma space group. Yb(1) is bonded in a 13-coordinate geometry to one Rh(1), two equivalent In(2), two equivalent In(3), and eight equivalent In(1) atoms. The Yb(1)-Rh(1) bond length is 2.92 Å. Both Yb(1)-In(2) bond lengths are 3.67 Å. Both Yb(1)-In(3) bond lengths are 3.25 Å. There are four shorter (3.38 Å) and four longer (3.52 Å) Yb(1)-In(1) bond lengths. Rh(1) is bonded in a 9-coordinate geometry to one Yb(1), two equivalent In(2), two equivalent In(3), and four equivalent In(1) atoms. Both Rh(1)-In(2) bond lengths are 2.61 Å. Both Rh(1)-In(3) bond lengths are 2.91 Å. All Rh(1)-In(1) bond lengths are 2.81 Å. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 2-coordinate geometry to four equivalent Yb(1) and two equivalent Rh(1) atoms. In the second In site, In(2) is bonded in a linear geometry to two equivalent Yb(1) and two equivalent Rh(1) atoms. In the third In site, In(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Yb(1) and two equivalent Rh(1) atoms.