VOF crystallizes in the orthorhombic Fddd space group. V(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F2 pentagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent V(1) atoms.
VOF crystallizes in the orthorhombic Fddd space group. V(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F2 pentagonal pyramids. There are two shorter (2.05 Å) and two longer (2.07 Å) V(1)-O(1) bond lengths. Both V(1)-F(1) bond lengths are 2.04 Å. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent V(1) atoms.