Pu2S3 is Corundum structured and crystallizes in the trigonal R-3c space group. Pu(1) is bonded to six equivalent S(1) atoms to form a mixture of edge, corner, and face-sharing PuS6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. S(1) is bonded to four equivalent Pu(1) atoms to form a mixture of distorted edge and corner-sharing SPu4 trigonal pyramids.
Pu2S3 is Corundum structured and crystallizes in the trigonal R-3c space group. Pu(1) is bonded to six equivalent S(1) atoms to form a mixture of edge, corner, and face-sharing PuS6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. There are three shorter (2.77 Å) and three longer (2.82 Å) Pu(1)-S(1) bond lengths. S(1) is bonded to four equivalent Pu(1) atoms to form a mixture of distorted edge and corner-sharing SPu4 trigonal pyramids.