K2PtCP4NSO11 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one N(1), one S(1), one O(10), one O(3), one O(5), one O(8), and one O(9) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one N(1), one O(11), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. Pt(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), one S(1), and one O(2) atom. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(1), one O(4), and one O(5) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(6), one O(7), and one O(8) atom. In the fourth P site, P(4) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(9) atom. N(1) is bonded in a distorted trigonal planar geometry to one K(1), one K(2), and one C(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one K(1), one Pt(1), and one C(1) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), one Pt(1), and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one K(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one K(1), one K(2), one P(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1) and one P(4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(2) and one O(11) atom.
K2PtCP4NSO11 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one N(1), one S(1), one O(10), one O(3), one O(5), one O(8), and one O(9) atom. The K(1)-N(1) bond length is 2.74 Å. The K(1)-S(1) bond length is 3.34 Å. The K(1)-O(10) bond length is 3.11 Å. The K(1)-O(3) bond length is 3.21 Å. The K(1)-O(5) bond length is 3.31 Å. The K(1)-O(8) bond length is 2.83 Å. The K(1)-O(9) bond length is 2.90 Å. In the second K site, K(2) is bonded in a 7-coordinate geometry to one N(1), one O(11), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. The K(2)-N(1) bond length is 2.84 Å. The K(2)-O(11) bond length is 3.09 Å. The K(2)-O(2) bond length is 3.05 Å. The K(2)-O(4) bond length is 2.62 Å. The K(2)-O(5) bond length is 2.98 Å. The K(2)-O(7) bond length is 2.72 Å. The K(2)-O(8) bond length is 2.75 Å. Pt(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), one S(1), and one O(2) atom. The Pt(1)-P(2) bond length is 2.23 Å. The Pt(1)-P(3) bond length is 2.32 Å. The Pt(1)-S(1) bond length is 2.42 Å. The Pt(1)-O(2) bond length is 2.23 Å. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.65 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(5) atom. The P(1)-O(1) bond length is 1.63 Å. The P(1)-O(2) bond length is 1.53 Å. The P(1)-O(3) bond length is 1.48 Å. The P(1)-O(5) bond length is 1.68 Å. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(1), one O(4), and one O(5) atom. The P(2)-O(1) bond length is 1.64 Å. The P(2)-O(4) bond length is 1.48 Å. The P(2)-O(5) bond length is 1.66 Å. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(6), one O(7), and one O(8) atom. The P(3)-O(6) bond length is 1.74 Å. The P(3)-O(7) bond length is 1.49 Å. The P(3)-O(8) bond length is 1.50 Å. In the fourth P site, P(4) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(9) atom. The P(4)-O(10) bond length is 1.47 Å. The P(4)-O(6) bond length is 1.56 Å. The P(4)-O(9) bond length is 1.47 Å. N(1) is bonded in a distorted trigonal planar geometry to one K(1), one K(2), and one C(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one K(1), one Pt(1), and one C(1) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), one Pt(1), and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one K(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one K(1), one K(2), one P(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1) and one P(4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(2) and one O(11) atom. The O(11)-O(11) bond length is 1.24 Å.