NiP2N2(O6F)2 is Hg_xSn structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NiP2N2(O6F)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. N(1) is bonded in a single-bond geometry to one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one P(1) and one O(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ni(1) and one O(6) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Ni(1) and one O(5) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.
NiP2N2(O6F)2 is Hg_xSn structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NiP2N2(O6F)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Both Ni(1)-O(4) bond lengths are 2.00 Å. Both Ni(1)-O(5) bond lengths are 1.91 Å. Both Ni(1)-O(6) bond lengths are 1.95 Å. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. The P(1)-O(1) bond length is 1.61 Å. The P(1)-O(2) bond length is 1.46 Å. The P(1)-O(3) bond length is 1.69 Å. The P(1)-F(1) bond length is 1.57 Å. N(1) is bonded in a single-bond geometry to one O(3) atom. The N(1)-O(3) bond length is 1.30 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one P(1) and one O(4) atom. The O(1)-O(4) bond length is 1.45 Å. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one O(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ni(1) and one O(6) atom. The O(5)-O(6) bond length is 1.30 Å. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Ni(1) and one O(5) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.