Ag3AuS2 crystallizes in the triclinic P1 space group. Au(1) is bonded in a 7-coordinate geometry to one Ag(2), two equivalent Ag(1), two equivalent Ag(3), one S(1), and one S(2) atom. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to two equivalent Au(1), one Ag(2), one Ag(3), one S(2), and two equivalent S(1) atoms. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one Au(1), one Ag(1), two equivalent S(1), and two equivalent S(2) atoms. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to two equivalent Au(1), one Ag(1), one S(1), and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to one Au(1), one Ag(3), two equivalent Ag(1), and two equivalent Ag(2) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to one Au(1), one Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms.
Ag3AuS2 crystallizes in the triclinic P1 space group. Au(1) is bonded in a 7-coordinate geometry to one Ag(2), two equivalent Ag(1), two equivalent Ag(3), one S(1), and one S(2) atom. The Au(1)-Ag(2) bond length is 3.05 Å. There is one shorter (3.03 Å) and one longer (3.14 Å) Au(1)-Ag(1) bond length. There is one shorter (2.93 Å) and one longer (2.94 Å) Au(1)-Ag(3) bond length. The Au(1)-S(1) bond length is 2.36 Å. The Au(1)-S(2) bond length is 2.36 Å. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to two equivalent Au(1), one Ag(2), one Ag(3), one S(2), and two equivalent S(1) atoms. The Ag(1)-Ag(2) bond length is 2.84 Å. The Ag(1)-Ag(3) bond length is 2.91 Å. The Ag(1)-S(2) bond length is 2.66 Å. There is one shorter (2.59 Å) and one longer (2.62 Å) Ag(1)-S(1) bond length. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one Au(1), one Ag(1), two equivalent S(1), and two equivalent S(2) atoms. There is one shorter (2.55 Å) and one longer (2.99 Å) Ag(2)-S(1) bond length. There is one shorter (2.61 Å) and one longer (2.81 Å) Ag(2)-S(2) bond length. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to two equivalent Au(1), one Ag(1), one S(1), and two equivalent S(2) atoms. The Ag(3)-S(1) bond length is 2.77 Å. There is one shorter (2.48 Å) and one longer (2.81 Å) Ag(3)-S(2) bond length. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to one Au(1), one Ag(3), two equivalent Ag(1), and two equivalent Ag(2) atoms. In the second S site, S(2) is bonded in a 6-coordinate geometry to one Au(1), one Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms.