ZnCFe3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Fe(1) is bonded in a linear geometry to four equivalent Zn(1) and two equivalent C(1) atoms. Zn(1) is bonded to twelve equivalent Fe(1) atoms to form ZnFe12 cuboctahedra that share corners with twelve equivalent Zn(1)Fe12 cuboctahedra, faces with six equivalent Zn(1)Fe12 cuboctahedra, and faces with eight equivalent C(1)Fe6 octahedra. C(1) is bonded to six equivalent Fe(1) atoms to form CFe6 octahedra that share corners with six equivalent C(1)Fe6 octahedra and faces with eight equivalent Zn(1)Fe12 cuboctahedra. The corner-sharing octahedra are not tilted.
ZnCFe3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Fe(1) is bonded in a linear geometry to four equivalent Zn(1) and two equivalent C(1) atoms. All Fe(1)-Zn(1) bond lengths are 2.67 Å. Both Fe(1)-C(1) bond lengths are 1.89 Å. Zn(1) is bonded to twelve equivalent Fe(1) atoms to form ZnFe12 cuboctahedra that share corners with twelve equivalent Zn(1)Fe12 cuboctahedra, faces with six equivalent Zn(1)Fe12 cuboctahedra, and faces with eight equivalent C(1)Fe6 octahedra. C(1) is bonded to six equivalent Fe(1) atoms to form CFe6 octahedra that share corners with six equivalent C(1)Fe6 octahedra and faces with eight equivalent Zn(1)Fe12 cuboctahedra. The corner-sharing octahedra are not tilted.