VF5 is alpha U structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom.
VF5 is alpha U structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The V(1)-F(1) bond length is 1.77 Å. The V(1)-F(2) bond length is 1.77 Å. The V(1)-F(3) bond length is 1.76 Å. The V(1)-F(4) bond length is 1.77 Å. The V(1)-F(5) bond length is 1.75 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom.