AgSbO3 crystallizes in the monoclinic C2 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(1), one O(8), and one O(9) atom. In the third Ag site, Ag(3) is bonded in a trigonal planar geometry to one O(4), one O(6), and one O(7) atom. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(2) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(4), one O(5), one O(6), and one O(9) atom to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sb site, Sb(3) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the fourth Sb site, Sb(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are ten inequivalent O sites. In the first O site, O(7) is bonded to one Ag(1), one Ag(3), one Sb(1), and one Sb(4) atom to form distorted corner-sharing OAg2Sb2 tetrahedra. In the second O site, O(8) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(1), and one Sb(3) atom. In the third O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Ag(2) and two equivalent Sb(2) atoms. In the fourth O site, O(10) is bonded in a water-like geometry to two equivalent Sb(2) atoms. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(2), and one Sb(4) atom. In the sixth O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the seventh O site, O(3) is bonded in a water-like geometry to one Sb(3) and one Sb(4) atom. In the eighth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(3), one Sb(1), and one Sb(2) atom. In the ninth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Sb(1), and one Sb(2) atom. In the tenth O site, O(6) is bonded to one Ag(1), one Ag(3), one Sb(2), and one Sb(3) atom to form distorted corner-sharing OAg2Sb2 tetrahedra.
AgSbO3 crystallizes in the monoclinic C2 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. The Ag(1)-O(5) bond length is 2.39 Å. The Ag(1)-O(6) bond length is 2.43 Å. The Ag(1)-O(7) bond length is 2.45 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(1), one O(8), and one O(9) atom. The Ag(2)-O(1) bond length is 2.57 Å. The Ag(2)-O(8) bond length is 2.57 Å. The Ag(2)-O(9) bond length is 2.66 Å. In the third Ag site, Ag(3) is bonded in a trigonal planar geometry to one O(4), one O(6), and one O(7) atom. The Ag(3)-O(4) bond length is 2.47 Å. The Ag(3)-O(6) bond length is 2.44 Å. The Ag(3)-O(7) bond length is 2.44 Å. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(2) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. The Sb(1)-O(4) bond length is 2.00 Å. The Sb(1)-O(5) bond length is 1.99 Å. The Sb(1)-O(7) bond length is 2.04 Å. The Sb(1)-O(8) bond length is 2.03 Å. Both Sb(1)-O(2) bond lengths are 2.03 Å. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(4), one O(5), one O(6), and one O(9) atom to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. The Sb(2)-O(1) bond length is 1.98 Å. The Sb(2)-O(10) bond length is 2.02 Å. The Sb(2)-O(4) bond length is 2.04 Å. The Sb(2)-O(5) bond length is 2.02 Å. The Sb(2)-O(6) bond length is 2.01 Å. The Sb(2)-O(9) bond length is 2.04 Å. In the third Sb site, Sb(3) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. Both Sb(3)-O(3) bond lengths are 2.02 Å. Both Sb(3)-O(6) bond lengths are 2.05 Å. Both Sb(3)-O(8) bond lengths are 1.99 Å. In the fourth Sb site, Sb(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. Both Sb(4)-O(1) bond lengths are 2.02 Å. Both Sb(4)-O(3) bond lengths are 2.02 Å. Both Sb(4)-O(7) bond lengths are 2.01 Å. There are ten inequivalent O sites. In the first O site, O(7) is bonded to one Ag(1), one Ag(3), one Sb(1), and one Sb(4) atom to form distorted corner-sharing OAg2Sb2 tetrahedra. In the second O site, O(8) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(1), and one Sb(3) atom. In the third O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Ag(2) and two equivalent Sb(2) atoms. In the fourth O site, O(10) is bonded in a water-like geometry to two equivalent Sb(2) atoms. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(2), and one Sb(4) atom. In the sixth O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the seventh O site, O(3) is bonded in a water-like geometry to one Sb(3) and one Sb(4) atom. In the eighth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(3), one Sb(1), and one Sb(2) atom. In the ninth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Sb(1), and one Sb(2) atom. In the tenth O site, O(6) is bonded to one Ag(1), one Ag(3), one Sb(2), and one Sb(3) atom to form distorted corner-sharing OAg2Sb2 tetrahedra.