Re3Pd is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Re(1) is bonded to eight equivalent Re(1) and four equivalent Pd(1) atoms to form distorted ReRe8Pd4 cuboctahedra that share corners with four equivalent Pd(1)Re12 cuboctahedra, corners with fourteen equivalent Re(1)Re8Pd4 cuboctahedra, edges with six equivalent Pd(1)Re12 cuboctahedra, edges with twelve equivalent Re(1)Re8Pd4 cuboctahedra, faces with four equivalent Pd(1)Re12 cuboctahedra, and faces with sixteen equivalent Re(1)Re8Pd4 cuboctahedra. Pd(1) is bonded to twelve equivalent Re(1) atoms to form PdRe12 cuboctahedra that share corners with six equivalent Pd(1)Re12 cuboctahedra, corners with twelve equivalent Re(1)Re8Pd4 cuboctahedra, edges with eighteen equivalent Re(1)Re8Pd4 cuboctahedra, faces with eight equivalent Pd(1)Re12 cuboctahedra, and faces with twelve equivalent Re(1)Re8Pd4 cuboctahedra.
Re3Pd is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. Re(1) is bonded to eight equivalent Re(1) and four equivalent Pd(1) atoms to form distorted ReRe8Pd4 cuboctahedra that share corners with four equivalent Pd(1)Re12 cuboctahedra, corners with fourteen equivalent Re(1)Re8Pd4 cuboctahedra, edges with six equivalent Pd(1)Re12 cuboctahedra, edges with twelve equivalent Re(1)Re8Pd4 cuboctahedra, faces with four equivalent Pd(1)Re12 cuboctahedra, and faces with sixteen equivalent Re(1)Re8Pd4 cuboctahedra. There are a spread of Re(1)-Re(1) bond distances ranging from 2.65-2.89 Å. All Re(1)-Pd(1) bond lengths are 2.77 Å. Pd(1) is bonded to twelve equivalent Re(1) atoms to form PdRe12 cuboctahedra that share corners with six equivalent Pd(1)Re12 cuboctahedra, corners with twelve equivalent Re(1)Re8Pd4 cuboctahedra, edges with eighteen equivalent Re(1)Re8Pd4 cuboctahedra, faces with eight equivalent Pd(1)Re12 cuboctahedra, and faces with twelve equivalent Re(1)Re8Pd4 cuboctahedra.