ZnO8(N3O4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dinitramide molecules and two ZnO8 clusters. In each ZnO8 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Zn(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Zn(1) and one O(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one O(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(3) atom.
ZnO8(N3O4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dinitramide molecules and two ZnO8 clusters. In each ZnO8 cluster, Zn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Zn(1)-O(1) bond lengths are 2.02 Å. Both Zn(1)-O(2) bond lengths are 2.01 Å. Both Zn(1)-O(3) bond lengths are 2.28 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Zn(1) and one O(2) atom. The O(1)-O(2) bond length is 1.33 Å. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Zn(1) and one O(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one O(4) atom. The O(3)-O(4) bond length is 1.23 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(3) atom.