TbNiO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Tb(1) is bonded to twelve equivalent O(1) atoms to form TbO12 cuboctahedra that share corners with twelve equivalent Tb(1)O12 cuboctahedra, faces with six equivalent Tb(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Tb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Tb(1) and two equivalent Ni(1) atoms to form a mixture of distorted corner, face, and edge-sharing OTb4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
TbNiO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Tb(1) is bonded to twelve equivalent O(1) atoms to form TbO12 cuboctahedra that share corners with twelve equivalent Tb(1)O12 cuboctahedra, faces with six equivalent Tb(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. All Tb(1)-O(1) bond lengths are 2.64 Å. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Tb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ni(1)-O(1) bond lengths are 1.87 Å. O(1) is bonded to four equivalent Tb(1) and two equivalent Ni(1) atoms to form a mixture of distorted corner, face, and edge-sharing OTb4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.