AgCrS2 is Ilmenite-like structured and crystallizes in the monoclinic Pc space group. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing CrS6 octahedra. Ag(1) is bonded in a 4-coordinate geometry to one S(1) and three equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Cr(1) and one Ag(1) atom to form distorted corner-sharing SCr3Ag trigonal pyramids. In the second S site, S(2) is bonded in a 6-coordinate geometry to three equivalent Cr(1) and three equivalent Ag(1) atoms.
AgCrS2 is Ilmenite-like structured and crystallizes in the monoclinic Pc space group. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing CrS6 octahedra. All Cr(1)-S(1) bond lengths are 2.39 Å. There are a spread of Cr(1)-S(2) bond distances ranging from 2.42-2.44 Å. Ag(1) is bonded in a 4-coordinate geometry to one S(1) and three equivalent S(2) atoms. The Ag(1)-S(1) bond length is 2.44 Å. There are a spread of Ag(1)-S(2) bond distances ranging from 2.71-2.74 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Cr(1) and one Ag(1) atom to form distorted corner-sharing SCr3Ag trigonal pyramids. In the second S site, S(2) is bonded in a 6-coordinate geometry to three equivalent Cr(1) and three equivalent Ag(1) atoms.