NdWO3N is Zircon-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one O(1), one O(5), and one O(6) atom to form distorted corner-sharing WNO3 tetrahedra. In the second W site, W(2) is bonded to one N(1), one N(2), one O(2), one O(3), and one O(4) atom to form distorted corner-sharing WN2O3 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Nd(1), one Nd(2), one W(1), and one W(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom.
NdWO3N is Zircon-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Nd(1)-N(1) bond length is 2.63 Å. The Nd(1)-N(2) bond length is 2.57 Å. The Nd(1)-O(1) bond length is 2.51 Å. The Nd(1)-O(2) bond length is 2.49 Å. The Nd(1)-O(3) bond length is 2.55 Å. The Nd(1)-O(4) bond length is 2.45 Å. The Nd(1)-O(5) bond length is 2.42 Å. The Nd(1)-O(6) bond length is 2.44 Å. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Nd(2)-N(1) bond length is 2.66 Å. The Nd(2)-N(2) bond length is 2.50 Å. The Nd(2)-O(1) bond length is 2.46 Å. The Nd(2)-O(2) bond length is 2.54 Å. The Nd(2)-O(3) bond length is 2.46 Å. The Nd(2)-O(4) bond length is 2.37 Å. The Nd(2)-O(5) bond length is 2.50 Å. The Nd(2)-O(6) bond length is 2.51 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one O(1), one O(5), and one O(6) atom to form distorted corner-sharing WNO3 tetrahedra. The W(1)-N(1) bond length is 1.84 Å. The W(1)-O(1) bond length is 1.87 Å. The W(1)-O(5) bond length is 1.86 Å. The W(1)-O(6) bond length is 1.84 Å. In the second W site, W(2) is bonded to one N(1), one N(2), one O(2), one O(3), and one O(4) atom to form distorted corner-sharing WN2O3 trigonal bipyramids. The W(2)-N(1) bond length is 2.28 Å. The W(2)-N(2) bond length is 1.79 Å. The W(2)-O(2) bond length is 1.92 Å. The W(2)-O(3) bond length is 1.93 Å. The W(2)-O(4) bond length is 1.92 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Nd(1), one Nd(2), one W(1), and one W(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Nd(1), one Nd(2), and one W(1) atom.