TlF is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. Tl(1) is bonded to six equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing TlF6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded to six equivalent Tl(1) atoms to form a mixture of distorted edge and corner-sharing FTl6 octahedra. The corner-sharing octahedra are not tilted.
TlF is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. Tl(1) is bonded to six equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing TlF6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-F(1) bond lengths are 2.77 Å. F(1) is bonded to six equivalent Tl(1) atoms to form a mixture of distorted edge and corner-sharing FTl6 octahedra. The corner-sharing octahedra are not tilted.