PuOF is half-Heusler structured and crystallizes in the cubic F-43m space group. Pu(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Pu(1) atoms to form OPu4 tetrahedra that share corners with four equivalent F(1)Pu4 tetrahedra, corners with twelve equivalent O(1)Pu4 tetrahedra, and edges with six equivalent F(1)Pu4 tetrahedra. F(1) is bonded to four equivalent Pu(1) atoms to form FPu4 tetrahedra that share corners with four equivalent O(1)Pu4 tetrahedra, corners with twelve equivalent F(1)Pu4 tetrahedra, and edges with six equivalent O(1)Pu4 tetrahedra.
PuOF is half-Heusler structured and crystallizes in the cubic F-43m space group. Pu(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. All Pu(1)-O(1) bond lengths are 2.43 Å. All Pu(1)-F(1) bond lengths are 2.43 Å. O(1) is bonded to four equivalent Pu(1) atoms to form OPu4 tetrahedra that share corners with four equivalent F(1)Pu4 tetrahedra, corners with twelve equivalent O(1)Pu4 tetrahedra, and edges with six equivalent F(1)Pu4 tetrahedra. F(1) is bonded to four equivalent Pu(1) atoms to form FPu4 tetrahedra that share corners with four equivalent O(1)Pu4 tetrahedra, corners with twelve equivalent F(1)Pu4 tetrahedra, and edges with six equivalent O(1)Pu4 tetrahedra.