SrCoO3 is (Cubic) Perovskite-like structured and crystallizes in the tetragonal P4/mbm space group. Sr(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, and faces with eight equivalent Co(1)O6 octahedra. Co(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are two inequivalent O sites. In the first O site, O(2) is bonded to four equivalent Sr(1) and two equivalent Co(1) atoms to form a mixture of distorted corner and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(1) is bonded in a distorted linear geometry to four equivalent Sr(1) and two equivalent Co(1) atoms.
SrCoO3 is (Cubic) Perovskite-like structured and crystallizes in the tetragonal P4/mbm space group. Sr(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, and faces with eight equivalent Co(1)O6 octahedra. All Sr(1)-O(2) bond lengths are 2.68 Å. All Sr(1)-O(1) bond lengths are 2.73 Å. Co(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and faces with eight equivalent Sr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Both Co(1)-O(2) bond lengths are 1.97 Å. There are two shorter (1.78 Å) and two longer (2.01 Å) Co(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(2) is bonded to four equivalent Sr(1) and two equivalent Co(1) atoms to form a mixture of distorted corner and edge-sharing OSr4Co2 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(1) is bonded in a distorted linear geometry to four equivalent Sr(1) and two equivalent Co(1) atoms.