(Na)2NaTlBr6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaTlBr6 framework. In the NaTlBr6 framework, Na(2) is bonded to six equivalent Br(1) atoms to form NaBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Na(2)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Na(2) and one Tl(1) atom.
(Na)2NaTlBr6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaTlBr6 framework. In the NaTlBr6 framework, Na(2) is bonded to six equivalent Br(1) atoms to form NaBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-Br(1) bond lengths are 2.87 Å. Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Na(2)Br6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 2.76 Å. Br(1) is bonded in a linear geometry to one Na(2) and one Tl(1) atom.