GaBiS crystallizes in the tetragonal I4/mcm space group. Ga(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Bi(1) and two equivalent S(1) atoms. Bi(1) is bonded in a 5-coordinate geometry to two equivalent Ga(1) and three equivalent S(1) atoms. S(1) is bonded in a 5-coordinate geometry to two equivalent Ga(1) and three equivalent Bi(1) atoms.
GaBiS crystallizes in the tetragonal I4/mcm space group. Ga(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Bi(1) and two equivalent S(1) atoms. Both Ga(1)-Bi(1) bond lengths are 2.94 Å. Both Ga(1)-S(1) bond lengths are 2.89 Å. Bi(1) is bonded in a 5-coordinate geometry to two equivalent Ga(1) and three equivalent S(1) atoms. There are two shorter (2.77 Å) and one longer (3.18 Å) Bi(1)-S(1) bond length. S(1) is bonded in a 5-coordinate geometry to two equivalent Ga(1) and three equivalent Bi(1) atoms.