V3Si crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Si(1) atoms. Si(1) is bonded to twelve equivalent V(1) atoms to form a mixture of edge and face-sharing SiV12 cuboctahedra.
V3Si crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Si(1) atoms. Both V(1)-V(1) bond lengths are 2.34 Å. All V(1)-Si(1) bond lengths are 2.62 Å. Si(1) is bonded to twelve equivalent V(1) atoms to form a mixture of edge and face-sharing SiV12 cuboctahedra.