(K)2ScTlCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a ScTlCl6 framework. In the ScTlCl6 framework, Sc(1) is bonded to six equivalent Cl(1) atoms to form ScCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent Sc(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Sc(1) and one Tl(1) atom.
(K)2ScTlCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a ScTlCl6 framework. In the ScTlCl6 framework, Sc(1) is bonded to six equivalent Cl(1) atoms to form ScCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-Cl(1) bond lengths are 2.49 Å. Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent Sc(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Cl(1) bond lengths are 3.04 Å. Cl(1) is bonded in a linear geometry to one Sc(1) and one Tl(1) atom.