LiGa3P2O11F3 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(4), one O(6), and one O(8) atom. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(2), one O(7), one O(8), one F(1), and one F(2) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(2)O4F2 octahedra,  a cornercorner with one Ga(3)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. In the second Ga site, Ga(2) is bonded to one O(11), one O(3), one O(5), one O(9), one F(1), and one F(3) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra, corners with two equivalent Ga(3)O4F2 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-50°. In the third Ga site, Ga(3) is bonded to one O(10), one O(11), one O(4), one O(6), one F(2), and one F(3) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra, corners with two equivalent Ga(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-46°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(3)O4F2 octahedra, and corners with two equivalent Ga(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the second P site, P(2) is bonded to one O(10), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O4F2 octahedra, and corners with two equivalent Ga(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(3), and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Ga(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(3), and one P(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Ga(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Li(1) and one Ga(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ga(2) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(3), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Li(1), one Ga(2), and one Ga(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one Ga(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(3) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(3) atom.
LiGa3P2O11F3 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(4), one O(6), and one O(8) atom. The Li(1)-O(10) bond length is 2.02 Å. The Li(1)-O(11) bond length is 2.15 Å. The Li(1)-O(4) bond length is 2.04 Å. The Li(1)-O(6) bond length is 2.06 Å. The Li(1)-O(8) bond length is 1.95 Å. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(2), one O(7), one O(8), one F(1), and one F(2) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(2)O4F2 octahedra,  a cornercorner with one Ga(3)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. The Ga(1)-O(1) bond length is 2.02 Å. The Ga(1)-O(2) bond length is 1.90 Å. The Ga(1)-O(7) bond length is 2.01 Å. The Ga(1)-O(8) bond length is 1.95 Å. The Ga(1)-F(1) bond length is 1.95 Å. The Ga(1)-F(2) bond length is 1.97 Å. In the second Ga site, Ga(2) is bonded to one O(11), one O(3), one O(5), one O(9), one F(1), and one F(3) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra, corners with two equivalent Ga(3)O4F2 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-50°. The Ga(2)-O(11) bond length is 2.01 Å. The Ga(2)-O(3) bond length is 1.96 Å. The Ga(2)-O(5) bond length is 1.95 Å. The Ga(2)-O(9) bond length is 1.92 Å. The Ga(2)-F(1) bond length is 2.00 Å. The Ga(2)-F(3) bond length is 1.97 Å. In the third Ga site, Ga(3) is bonded to one O(10), one O(11), one O(4), one O(6), one F(2), and one F(3) atom to form GaO4F2 octahedra that share  a cornercorner with one Ga(1)O4F2 octahedra, corners with two equivalent Ga(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-46°. The Ga(3)-O(10) bond length is 1.99 Å. The Ga(3)-O(11) bond length is 2.06 Å. The Ga(3)-O(4) bond length is 1.98 Å. The Ga(3)-O(6) bond length is 1.95 Å. The Ga(3)-F(2) bond length is 1.95 Å. The Ga(3)-F(3) bond length is 1.92 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(3)O4F2 octahedra, and corners with two equivalent Ga(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. The P(1)-O(1) bond length is 1.58 Å. The P(1)-O(3) bond length is 1.53 Å. The P(1)-O(6) bond length is 1.56 Å. The P(1)-O(9) bond length is 1.53 Å. In the second P site, P(2) is bonded to one O(10), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O4F2 octahedra, and corners with two equivalent Ga(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-55°. The P(2)-O(10) bond length is 1.57 Å. The P(2)-O(2) bond length is 1.54 Å. The P(2)-O(4) bond length is 1.55 Å. The P(2)-O(5) bond length is 1.54 Å. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(3), and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Ga(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(3), and one P(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Ga(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Li(1) and one Ga(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ga(2) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Ga(3), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Li(1), one Ga(2), and one Ga(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one Ga(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Ga(1) and one Ga(3) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ga(2) and one Ga(3) atom.