KRhF6 crystallizes in the trigonal R-3 space group. K(1) is bonded to twelve equivalent F(1) atoms to form KF12 cuboctahedra that share corners with six equivalent Rh(1)F6 octahedra, edges with six equivalent K(1)F12 cuboctahedra, and faces with two equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent K(1)F12 cuboctahedra and faces with two equivalent K(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Rh(1) atom.
KRhF6 crystallizes in the trigonal R-3 space group. K(1) is bonded to twelve equivalent F(1) atoms to form KF12 cuboctahedra that share corners with six equivalent Rh(1)F6 octahedra, edges with six equivalent K(1)F12 cuboctahedra, and faces with two equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. There are six shorter (2.81 Å) and six longer (2.92 Å) K(1)-F(1) bond lengths. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent K(1)F12 cuboctahedra and faces with two equivalent K(1)F12 cuboctahedra. All Rh(1)-F(1) bond lengths are 1.87 Å. F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Rh(1) atom.