CsAlO2 crystallizes in the cubic Fd-3m space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. Al(1) is bonded to four equivalent O(1) atoms to form corner-sharing AlO4 tetrahedra. O(1) is bonded in a linear geometry to six equivalent Cs(1) and two equivalent Al(1) atoms.
CsAlO2 crystallizes in the cubic Fd-3m space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. All Cs(1)-O(1) bond lengths are 3.37 Å. Al(1) is bonded to four equivalent O(1) atoms to form corner-sharing AlO4 tetrahedra. All Al(1)-O(1) bond lengths are 1.76 Å. O(1) is bonded in a linear geometry to six equivalent Cs(1) and two equivalent Al(1) atoms.