AgNO3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 7-coordinate geometry to one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent Ag(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one N(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(2) atom.
AgNO3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms. The Ag(1)-O(2) bond length is 2.74 Å. The Ag(1)-O(4) bond length is 2.44 Å. The Ag(1)-O(5) bond length is 2.53 Å. The Ag(1)-O(6) bond length is 2.48 Å. There is one shorter (2.51 Å) and one longer (2.63 Å) Ag(1)-O(3) bond length. In the second Ag site, Ag(2) is bonded in a 7-coordinate geometry to one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(2) atoms. The Ag(2)-O(4) bond length is 2.54 Å. The Ag(2)-O(5) bond length is 2.75 Å. The Ag(2)-O(6) bond length is 2.63 Å. There is one shorter (2.54 Å) and one longer (2.58 Å) Ag(2)-O(1) bond length. There is one shorter (2.69 Å) and one longer (2.70 Å) Ag(2)-O(2) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The N(1)-O(3) bond length is 1.27 Å. The N(1)-O(4) bond length is 1.27 Å. The N(1)-O(5) bond length is 1.27 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(6) atom. The N(2)-O(1) bond length is 1.27 Å. The N(2)-O(2) bond length is 1.27 Å. The N(2)-O(6) bond length is 1.27 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent Ag(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one N(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one N(2) atom.