AgAlO3 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Al(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing AlO4 tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ag(1) and one Al(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Al(1) atoms.
AgAlO3 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. There are two shorter (2.07 Å) and two longer (2.08 Å) Ag(1)-O(1) bond lengths. Al(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing AlO4 tetrahedra. Both Al(1)-O(1) bond lengths are 1.81 Å. Both Al(1)-O(2) bond lengths are 1.74 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ag(1) and one Al(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Al(1) atoms.