Li(NH3)4Te is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ditelluride molecule and two Li(NH3)4 clusters. In each Li(NH3)4 cluster, Li(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Li(1), one H(1), one H(10), and one H(2) atom to form distorted corner-sharing NLiH3 tetrahedra. In the second N site, N(2) is bonded to one Li(1), one H(3), one H(4), and one H(6) atom to form distorted corner-sharing NLiH3 tetrahedra. In the third N site, N(3) is bonded to one Li(1), one H(12), one H(5), and one H(9) atom to form distorted corner-sharing NLiH3 tetrahedra. In the fourth N site, N(4) is bonded to one Li(1), one H(11), one H(7), and one H(8) atom to form distorted corner-sharing NLiH3 tetrahedra. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom.
Li(NH3)4Te is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ditelluride molecule and two Li(NH3)4 clusters. In each Li(NH3)4 cluster, Li(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Li(1)-N(1) bond length is 2.05 Å. The Li(1)-N(2) bond length is 2.12 Å. The Li(1)-N(3) bond length is 2.09 Å. The Li(1)-N(4) bond length is 2.08 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Li(1), one H(1), one H(10), and one H(2) atom to form distorted corner-sharing NLiH3 tetrahedra. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(10) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded to one Li(1), one H(3), one H(4), and one H(6) atom to form distorted corner-sharing NLiH3 tetrahedra. The N(2)-H(3) bond length is 1.02 Å. The N(2)-H(4) bond length is 1.03 Å. The N(2)-H(6) bond length is 1.03 Å. In the third N site, N(3) is bonded to one Li(1), one H(12), one H(5), and one H(9) atom to form distorted corner-sharing NLiH3 tetrahedra. The N(3)-H(12) bond length is 1.03 Å. The N(3)-H(5) bond length is 1.03 Å. The N(3)-H(9) bond length is 1.03 Å. In the fourth N site, N(4) is bonded to one Li(1), one H(11), one H(7), and one H(8) atom to form distorted corner-sharing NLiH3 tetrahedra. The N(4)-H(11) bond length is 1.03 Å. The N(4)-H(7) bond length is 1.02 Å. The N(4)-H(8) bond length is 1.03 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom.