Pd3V crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent Pd(1) atoms to form distorted VPd6 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, and edges with six equivalent Pd(2)Pd12 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to three equivalent V(1) and three equivalent Pd(2) atoms to form distorted PdV3Pd3 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with six equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, and edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra. In the second Pd site, Pd(2) is bonded to six equivalent Pd(1) and six equivalent Pd(2) atoms to form PdPd12 cuboctahedra that share corners with six equivalent V(1)Pd6 cuboctahedra, corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with twelve equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra, and faces with six equivalent Pd(2)Pd12 cuboctahedra.
Pd3V crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent Pd(1) atoms to form distorted VPd6 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, and edges with six equivalent Pd(2)Pd12 cuboctahedra. All V(1)-Pd(1) bond lengths are 2.65 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to three equivalent V(1) and three equivalent Pd(2) atoms to form distorted PdV3Pd3 cuboctahedra that share corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with six equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, and edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra. All Pd(1)-Pd(2) bond lengths are 2.86 Å. In the second Pd site, Pd(2) is bonded to six equivalent Pd(1) and six equivalent Pd(2) atoms to form PdPd12 cuboctahedra that share corners with six equivalent V(1)Pd6 cuboctahedra, corners with six equivalent Pd(2)Pd12 cuboctahedra, corners with twelve equivalent Pd(1)V3Pd3 cuboctahedra, edges with six equivalent V(1)Pd6 cuboctahedra, edges with six equivalent Pd(2)Pd12 cuboctahedra, edges with twelve equivalent Pd(1)V3Pd3 cuboctahedra, and faces with six equivalent Pd(2)Pd12 cuboctahedra. All Pd(2)-Pd(2) bond lengths are 2.77 Å.