BPBr6 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BPBr6 clusters. B(1) is bonded in a tetrahedral geometry to one P(1), one Br(2), and two equivalent Br(3) atoms. P(1) is bonded in a tetrahedral geometry to one B(1), one Br(1), and two equivalent Br(4) atoms. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one B(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one P(1) atom.
BPBr6 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BPBr6 clusters. B(1) is bonded in a tetrahedral geometry to one P(1), one Br(2), and two equivalent Br(3) atoms. The B(1)-P(1) bond length is 2.00 Å. The B(1)-Br(2) bond length is 2.00 Å. Both B(1)-Br(3) bond lengths are 1.99 Å. P(1) is bonded in a tetrahedral geometry to one B(1), one Br(1), and two equivalent Br(4) atoms. The P(1)-Br(1) bond length is 2.17 Å. Both P(1)-Br(4) bond lengths are 2.17 Å. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one P(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one B(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one P(1) atom.