Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(7)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-58°. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(4), one O(5), one O(7), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(8)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the third Mn site, Mn(3) is bonded to one O(1), one O(12), one O(13), one O(2), one O(3), and one F(3) atom to form a mixture of corner and edge-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the fourth Mn site, Mn(4) is bonded to one O(6), one O(7), one O(8), one O(9), one F(1), and one F(2) atom to form a mixture of corner and edge-sharing MnO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(5), one O(7), one O(8), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(7)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra, and edges with two equivalent Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(10), one O(13), one O(2), one O(4), and one F(3) atom to form a mixture of corner and edge-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 49-58°. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(11), one O(3), one O(6), one O(8), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-60°. In the eighth Mn site, Mn(8) is bonded to one O(12), one O(13), one O(4), one O(5), one O(9), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(8) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(8) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom.
Mn8O13F3 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(7)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-58°. The Mn(1)-O(10) bond length is 1.91 Å. The Mn(1)-O(11) bond length is 1.86 Å. The Mn(1)-O(2) bond length is 1.99 Å. The Mn(1)-O(3) bond length is 1.96 Å. The Mn(1)-O(6) bond length is 1.93 Å. The Mn(1)-F(1) bond length is 2.02 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(4), one O(5), one O(7), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(8)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-55°. The Mn(2)-O(1) bond length is 1.95 Å. The Mn(2)-O(12) bond length is 1.96 Å. The Mn(2)-O(4) bond length is 1.97 Å. The Mn(2)-O(5) bond length is 1.95 Å. The Mn(2)-O(7) bond length is 1.97 Å. The Mn(2)-F(2) bond length is 2.16 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(12), one O(13), one O(2), one O(3), and one F(3) atom to form a mixture of corner and edge-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 47-54°. The Mn(3)-O(1) bond length is 1.88 Å. The Mn(3)-O(12) bond length is 1.96 Å. The Mn(3)-O(13) bond length is 1.95 Å. The Mn(3)-O(2) bond length is 1.97 Å. The Mn(3)-O(3) bond length is 2.00 Å. The Mn(3)-F(3) bond length is 2.03 Å. In the fourth Mn site, Mn(4) is bonded to one O(6), one O(7), one O(8), one O(9), one F(1), and one F(2) atom to form a mixture of corner and edge-sharing MnO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. The Mn(4)-O(6) bond length is 1.93 Å. The Mn(4)-O(7) bond length is 1.89 Å. The Mn(4)-O(8) bond length is 1.95 Å. The Mn(4)-O(9) bond length is 1.88 Å. The Mn(4)-F(1) bond length is 2.04 Å. The Mn(4)-F(2) bond length is 2.03 Å. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(5), one O(7), one O(8), one O(9), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(2)O5F octahedra, corners with two equivalent Mn(7)O5F octahedra, corners with two equivalent Mn(8)O5F octahedra, and edges with two equivalent Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. The Mn(5)-O(11) bond length is 1.99 Å. The Mn(5)-O(5) bond length is 1.99 Å. The Mn(5)-O(7) bond length is 1.93 Å. The Mn(5)-O(8) bond length is 1.94 Å. The Mn(5)-O(9) bond length is 2.02 Å. The Mn(5)-F(1) bond length is 2.13 Å. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(10), one O(13), one O(2), one O(4), and one F(3) atom to form a mixture of corner and edge-sharing MnO5F octahedra. The corner-sharing octahedral tilt angles range from 49-58°. The Mn(6)-O(1) bond length is 1.98 Å. The Mn(6)-O(10) bond length is 2.00 Å. The Mn(6)-O(13) bond length is 1.97 Å. The Mn(6)-O(2) bond length is 1.96 Å. The Mn(6)-O(4) bond length is 1.95 Å. The Mn(6)-F(3) bond length is 2.17 Å. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(11), one O(3), one O(6), one O(8), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-60°. The Mn(7)-O(10) bond length is 1.87 Å. The Mn(7)-O(11) bond length is 1.92 Å. The Mn(7)-O(3) bond length is 1.93 Å. The Mn(7)-O(6) bond length is 1.95 Å. The Mn(7)-O(8) bond length is 1.94 Å. The Mn(7)-F(3) bond length is 2.02 Å. In the eighth Mn site, Mn(8) is bonded to one O(12), one O(13), one O(4), one O(5), one O(9), and one F(2) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(5)O5F octahedra, corners with two equivalent Mn(6)O5F octahedra, and edges with two equivalent Mn(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-55°. The Mn(8)-O(12) bond length is 1.95 Å. The Mn(8)-O(13) bond length is 1.95 Å. The Mn(8)-O(4) bond length is 1.88 Å. The Mn(8)-O(5) bond length is 1.95 Å. The Mn(8)-O(9) bond length is 1.97 Å. The Mn(8)-F(2) bond length is 2.03 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(7) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(6), and one Mn(8) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(5), and one Mn(8) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(1), one Mn(6), and one Mn(7) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(8) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(8) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(7) atom.