RbIn(MoO4)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-33°. In the second Mo site, Mo(2) is bonded to one O(4), one O(5), and two equivalent O(6) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-42°. In(1) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent O(6) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra and corners with three equivalent Mo(2)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the second O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mo(2), and one In(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mo(1), and one In(1) atom. In the sixth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one Mo(1), and one In(1) atom.
RbIn(MoO4)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(6) atoms. The Rb(1)-O(1) bond length is 2.83 Å. Both Rb(1)-O(2) bond lengths are 3.12 Å. Both Rb(1)-O(3) bond lengths are 3.42 Å. Both Rb(1)-O(4) bond lengths are 3.28 Å. All Rb(1)-O(6) bond lengths are 3.25 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 32-33°. The Mo(1)-O(1) bond length is 1.74 Å. The Mo(1)-O(3) bond length is 1.82 Å. Both Mo(1)-O(2) bond lengths are 1.82 Å. In the second Mo site, Mo(2) is bonded to one O(4), one O(5), and two equivalent O(6) atoms to form MoO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-42°. The Mo(2)-O(4) bond length is 1.75 Å. The Mo(2)-O(5) bond length is 1.79 Å. Both Mo(2)-O(6) bond lengths are 1.83 Å. In(1) is bonded to one O(3), one O(5), two equivalent O(2), and two equivalent O(6) atoms to form InO6 octahedra that share corners with three equivalent Mo(1)O4 tetrahedra and corners with three equivalent Mo(2)O4 tetrahedra. The In(1)-O(3) bond length is 2.17 Å. The In(1)-O(5) bond length is 2.17 Å. Both In(1)-O(2) bond lengths are 2.18 Å. Both In(1)-O(6) bond lengths are 2.18 Å. There are six inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the second O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mo(2), and one In(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Mo(1), and one In(1) atom. In the sixth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one Mo(1), and one In(1) atom.