K2NaAg3(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the trigonal P-31m space group. K(1) is bonded to six equivalent N(1) atoms to form distorted KN6 octahedra that share edges with three equivalent K(1)N6 octahedra and edges with three equivalent Na(1)N6 octahedra. Na(1) is bonded to six equivalent N(1) atoms to form NaN6 octahedra that share edges with six equivalent K(1)N6 octahedra. Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. N(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent K(1), one Na(1), and one C(1) atom.
K2NaAg3(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the trigonal P-31m space group. K(1) is bonded to six equivalent N(1) atoms to form distorted KN6 octahedra that share edges with three equivalent K(1)N6 octahedra and edges with three equivalent Na(1)N6 octahedra. All K(1)-N(1) bond lengths are 2.92 Å. Na(1) is bonded to six equivalent N(1) atoms to form NaN6 octahedra that share edges with six equivalent K(1)N6 octahedra. All Na(1)-N(1) bond lengths are 2.58 Å. Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. Both Ag(1)-C(1) bond lengths are 2.05 Å. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. N(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent K(1), one Na(1), and one C(1) atom.