K2NaAs is Sodium arsenide-derived structured and crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded in a 11-coordinate geometry to four equivalent K(1), three equivalent Na(1), and four equivalent As(1) atoms. Na(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent As(1) atoms. As(1) is bonded in a 11-coordinate geometry to eight equivalent K(1) and three equivalent Na(1) atoms.
K2NaAs is Sodium arsenide-derived structured and crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded in a 11-coordinate geometry to four equivalent K(1), three equivalent Na(1), and four equivalent As(1) atoms. There is one shorter (3.45 Å) and three longer (3.57 Å) K(1)-K(1) bond lengths. All K(1)-Na(1) bond lengths are 3.53 Å. All K(1)-As(1) bond lengths are 3.53 Å. Na(1) is bonded in a trigonal planar geometry to six equivalent K(1) and three equivalent As(1) atoms. All Na(1)-As(1) bond lengths are 3.08 Å. As(1) is bonded in a 11-coordinate geometry to eight equivalent K(1) and three equivalent Na(1) atoms.