NaInF6(NH4)2 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonium molecules inside a NaInF6 framework. In the NaInF6 framework, Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent In(1)F6 octahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Na(1) and one In(1) atom.
NaInF6(NH4)2 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonium molecules inside a NaInF6 framework. In the NaInF6 framework, Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent In(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-F(1) bond lengths are 2.26 Å. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. All In(1)-F(1) bond lengths are 2.12 Å. F(1) is bonded in a linear geometry to one Na(1) and one In(1) atom.