Mn4N crystallizes in the cubic Pm-3m space group. The structure consists of one ammonia atom inside a Mn framework. In the Mn framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to six equivalent Mn(2) atoms to form corner-sharing MnMn6 octahedra. The corner-sharing octahedra are not tilted. In the second Mn site, Mn(2) is bonded in a linear geometry to two equivalent Mn(1) atoms.
Mn4N crystallizes in the cubic Pm-3m space group. The structure consists of one ammonia atom inside a Mn framework. In the Mn framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to six equivalent Mn(2) atoms to form corner-sharing MnMn6 octahedra. The corner-sharing octahedra are not tilted. All Mn(1)-Mn(2) bond lengths are 2.16 Å. In the second Mn site, Mn(2) is bonded in a linear geometry to two equivalent Mn(1) atoms.