TlCuF3 is (Cubic) Perovskite structured and crystallizes in the tetragonal P4/mmm space group. The structure consists of one 7440-28-0 atom inside a CuF3 framework. In the CuF3 framework, Cu(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing CuF6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Cu(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Cu(1) atoms.
TlCuF3 is (Cubic) Perovskite structured and crystallizes in the tetragonal P4/mmm space group. The structure consists of one 7440-28-0 atom inside a CuF3 framework. In the CuF3 framework, Cu(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing CuF6 octahedra. The corner-sharing octahedra are not tilted. Both Cu(1)-F(1) bond lengths are 2.04 Å. All Cu(1)-F(2) bond lengths are 2.05 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Cu(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Cu(1) atoms.