Sr3LaMn2(WO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(7), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(10), one O(8), two equivalent O(4), two equivalent O(6), and three equivalent O(1) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(3), one O(6), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. La(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(12), one O(5), one O(7), one O(8), and one O(9) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with five equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the second W site, W(2) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with five equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-30°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra and corners with five equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra and corners with five equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-26°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent Sr(2), one W(2), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one W(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(1), one W(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one W(2), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one W(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(2), one W(2), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one La(1), one W(2), and one Mn(1) atom.
Sr3LaMn2(WO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(7), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. The Sr(1)-O(7) bond length is 3.03 Å. There is one shorter (2.53 Å) and one longer (2.76 Å) Sr(1)-O(2) bond length. There is one shorter (2.56 Å) and one longer (2.71 Å) Sr(1)-O(3) bond length. There is one shorter (2.54 Å) and one longer (2.74 Å) Sr(1)-O(5) bond length. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(10), one O(8), two equivalent O(4), two equivalent O(6), and three equivalent O(1) atoms. The Sr(2)-O(10) bond length is 2.99 Å. The Sr(2)-O(8) bond length is 3.06 Å. There is one shorter (2.57 Å) and one longer (2.67 Å) Sr(2)-O(4) bond length. There is one shorter (2.55 Å) and one longer (2.68 Å) Sr(2)-O(6) bond length. There are a spread of Sr(2)-O(1) bond distances ranging from 2.50-3.16 Å. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(3), one O(6), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. The Sr(3)-O(10) bond length is 2.75 Å. The Sr(3)-O(11) bond length is 2.51 Å. The Sr(3)-O(3) bond length is 2.88 Å. The Sr(3)-O(6) bond length is 3.06 Å. The Sr(3)-O(7) bond length is 2.64 Å. The Sr(3)-O(8) bond length is 2.65 Å. The Sr(3)-O(9) bond length is 2.51 Å. There is one shorter (2.78 Å) and one longer (3.17 Å) Sr(3)-O(12) bond length. La(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(12), one O(5), one O(7), one O(8), and one O(9) atom. The La(1)-O(10) bond length is 2.63 Å. The La(1)-O(11) bond length is 2.68 Å. The La(1)-O(12) bond length is 2.46 Å. The La(1)-O(5) bond length is 2.79 Å. The La(1)-O(7) bond length is 2.36 Å. The La(1)-O(8) bond length is 2.68 Å. The La(1)-O(9) bond length is 2.45 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with five equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. The W(1)-O(11) bond length is 2.00 Å. The W(1)-O(2) bond length is 1.93 Å. The W(1)-O(3) bond length is 2.02 Å. The W(1)-O(5) bond length is 2.03 Å. The W(1)-O(7) bond length is 2.06 Å. The W(1)-O(9) bond length is 2.06 Å. In the second W site, W(2) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with five equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-30°. The W(2)-O(1) bond length is 1.96 Å. The W(2)-O(10) bond length is 1.98 Å. The W(2)-O(12) bond length is 1.96 Å. The W(2)-O(4) bond length is 1.95 Å. The W(2)-O(6) bond length is 1.96 Å. The W(2)-O(8) bond length is 1.97 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra and corners with five equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. The Mn(1)-O(12) bond length is 2.28 Å. The Mn(1)-O(2) bond length is 2.20 Å. The Mn(1)-O(3) bond length is 2.13 Å. The Mn(1)-O(5) bond length is 2.14 Å. The Mn(1)-O(7) bond length is 2.18 Å. The Mn(1)-O(9) bond length is 2.16 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra and corners with five equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-26°. The Mn(2)-O(1) bond length is 2.19 Å. The Mn(2)-O(10) bond length is 2.21 Å. The Mn(2)-O(11) bond length is 2.14 Å. The Mn(2)-O(4) bond length is 2.22 Å. The Mn(2)-O(6) bond length is 2.22 Å. The Mn(2)-O(8) bond length is 2.22 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent Sr(2), one W(2), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one W(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(1), one W(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one W(2), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one W(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(2), one W(2), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one La(1), one W(2), and one Mn(1) atom.