NaCuN crystallizes in the orthorhombic Amm2 space group. Na(1) is bonded to six equivalent Cu(1) and six equivalent N(1) atoms to form a mixture of distorted face and edge-sharing NaCu6N6 cuboctahedra. Cu(1) is bonded in a trigonal planar geometry to six equivalent Na(1) and three equivalent N(1) atoms. N(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Cu(1) atoms.
NaCuN crystallizes in the orthorhombic Amm2 space group. Na(1) is bonded to six equivalent Cu(1) and six equivalent N(1) atoms to form a mixture of distorted face and edge-sharing NaCu6N6 cuboctahedra. There are four shorter (2.83 Å) and two longer (2.88 Å) Na(1)-Cu(1) bond lengths. There are two shorter (2.76 Å) and four longer (2.89 Å) Na(1)-N(1) bond lengths. Cu(1) is bonded in a trigonal planar geometry to six equivalent Na(1) and three equivalent N(1) atoms. There is one shorter (1.90 Å) and two longer (1.91 Å) Cu(1)-N(1) bond lengths. N(1) is bonded in a distorted trigonal planar geometry to six equivalent Na(1) and three equivalent Cu(1) atoms.