(Na2Cd3P4O14Cl)2N2 crystallizes in the monoclinic C2/c space group. The structure consists of four ammonia atoms inside a Na2Cd3P4O14Cl framework. In the Na2Cd3P4O14Cl framework, Na(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), two equivalent O(6), and two equivalent O(7) atoms. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom to form distorted CdClO5 octahedra that share  a cornercorner with one Cd(2)Cl2O4 octahedra,  a cornercorner with one Cd(1)ClO5 octahedra, corners with two equivalent P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Cd(2)Cl2O4 octahedra. The corner-sharing octahedral tilt angles range from 10-85°. In the second Cd site, Cd(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent Cl(1) atoms to form distorted CdCl2O4 octahedra that share corners with two equivalent Cd(2)Cl2O4 octahedra, corners with two equivalent Cd(1)ClO5 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and edges with two equivalent Cd(1)ClO5 octahedra. The corner-sharing octahedral tilt angles range from 0-85°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Cd(2)Cl2O4 octahedra, corners with three equivalent Cd(1)ClO5 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Cd(2)Cl2O4 octahedra, corners with two equivalent Cd(1)ClO5 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Cd(1), and one P(2) atom. In the second O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Cd(1), and one P(2) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one P(2) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(3) is bonded in a trigonal planar geometry to one Na(1), one Cd(1), and one P(1) atom. In the sixth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one P(1) atom. In the seventh O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Cd(1), and one P(1) atom. Cl(1) is bonded in a square co-planar geometry to two equivalent Cd(1) and two equivalent Cd(2) atoms.
(Na2Cd3P4O14Cl)2N2 crystallizes in the monoclinic C2/c space group. The structure consists of four ammonia atoms inside a Na2Cd3P4O14Cl framework. In the Na2Cd3P4O14Cl framework, Na(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), two equivalent O(6), and two equivalent O(7) atoms. The Na(1)-O(3) bond length is 2.40 Å. The Na(1)-O(5) bond length is 2.37 Å. There is one shorter (2.49 Å) and one longer (2.52 Å) Na(1)-O(6) bond length. There is one shorter (2.38 Å) and one longer (2.75 Å) Na(1)-O(7) bond length. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom to form distorted CdClO5 octahedra that share  a cornercorner with one Cd(2)Cl2O4 octahedra,  a cornercorner with one Cd(1)ClO5 octahedra, corners with two equivalent P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one Cd(2)Cl2O4 octahedra. The corner-sharing octahedral tilt angles range from 10-85°. The Cd(1)-O(3) bond length is 2.27 Å. The Cd(1)-O(4) bond length is 2.34 Å. The Cd(1)-O(5) bond length is 2.30 Å. The Cd(1)-O(6) bond length is 2.37 Å. The Cd(1)-O(7) bond length is 2.36 Å. The Cd(1)-Cl(1) bond length is 2.88 Å. In the second Cd site, Cd(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent Cl(1) atoms to form distorted CdCl2O4 octahedra that share corners with two equivalent Cd(2)Cl2O4 octahedra, corners with two equivalent Cd(1)ClO5 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and edges with two equivalent Cd(1)ClO5 octahedra. The corner-sharing octahedral tilt angles range from 0-85°. Both Cd(2)-O(1) bond lengths are 2.19 Å. Both Cd(2)-O(4) bond lengths are 2.37 Å. There is one shorter (2.68 Å) and one longer (2.74 Å) Cd(2)-Cl(1) bond length. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Cd(2)Cl2O4 octahedra, corners with three equivalent Cd(1)ClO5 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-55°. The P(1)-O(2) bond length is 1.63 Å. The P(1)-O(3) bond length is 1.53 Å. The P(1)-O(4) bond length is 1.54 Å. The P(1)-O(5) bond length is 1.53 Å. In the second P site, P(2) is bonded to one O(1), one O(2), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Cd(2)Cl2O4 octahedra, corners with two equivalent Cd(1)ClO5 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-55°. The P(2)-O(1) bond length is 1.52 Å. The P(2)-O(2) bond length is 1.62 Å. The P(2)-O(6) bond length is 1.55 Å. The P(2)-O(7) bond length is 1.54 Å. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Cd(1), and one P(2) atom. In the second O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Cd(1), and one P(2) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one P(2) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(3) is bonded in a trigonal planar geometry to one Na(1), one Cd(1), and one P(1) atom. In the sixth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one P(1) atom. In the seventh O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Cd(1), and one P(1) atom. Cl(1) is bonded in a square co-planar geometry to two equivalent Cd(1) and two equivalent Cd(2) atoms.