Sr2MgMoZnO6 crystallizes in the triclinic P-1 space group. Sr(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mg(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share faces with two equivalent Mo(1)O6 octahedra. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share faces with two equivalent Mg(1)O6 octahedra. Zn(1) is bonded in a linear geometry to two equivalent O(2) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a see-saw-like geometry to two equivalent Sr(1), one Mg(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one Mo(1), and one Zn(1) atom.
Sr2MgMoZnO6 crystallizes in the triclinic P-1 space group. Sr(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There is one shorter (2.47 Å) and one longer (2.61 Å) Sr(1)-O(1) bond length. There is one shorter (2.46 Å) and one longer (2.66 Å) Sr(1)-O(2) bond length. There is one shorter (2.59 Å) and one longer (2.71 Å) Sr(1)-O(3) bond length. Mg(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MgO6 octahedra that share faces with two equivalent Mo(1)O6 octahedra. Both Mg(1)-O(1) bond lengths are 2.14 Å. Both Mg(1)-O(2) bond lengths are 2.08 Å. Both Mg(1)-O(3) bond lengths are 2.12 Å. Mo(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share faces with two equivalent Mg(1)O6 octahedra. Both Mo(1)-O(1) bond lengths are 2.02 Å. Both Mo(1)-O(2) bond lengths are 2.10 Å. Both Mo(1)-O(3) bond lengths are 2.19 Å. Zn(1) is bonded in a linear geometry to two equivalent O(2) and two equivalent O(3) atoms. Both Zn(1)-O(2) bond lengths are 2.60 Å. Both Zn(1)-O(3) bond lengths are 1.84 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a see-saw-like geometry to two equivalent Sr(1), one Mg(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one Mo(1), and one Zn(1) atom.