H4S(NO)2 is gamma plutonium structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfamide molecules. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom.
H4S(NO)2 is gamma plutonium structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfamide molecules. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-S(1) bond length is 1.65 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both S(1)-O(1) bond lengths are 1.44 Å. O(1) is bonded in a single-bond geometry to one S(1) atom.