Cs2Mn(OCl2)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent Cl(1), and four equivalent Cl(2) atoms. Mn(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one Mn(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Mn(1) atom.
Cs2Mn(OCl2)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent Cl(1), and four equivalent Cl(2) atoms. There is one shorter (3.26 Å) and one longer (3.76 Å) Cs(1)-O(1) bond length. There are a spread of Cs(1)-Cl(1) bond distances ranging from 3.53-3.82 Å. There are a spread of Cs(1)-Cl(2) bond distances ranging from 3.63-3.76 Å. Mn(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. Both Mn(1)-O(1) bond lengths are 1.72 Å. Both Mn(1)-Cl(1) bond lengths are 2.36 Å. Both Mn(1)-Cl(2) bond lengths are 2.36 Å. O(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one Mn(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Mn(1) atom.