Ag2F5 crystallizes in the triclinic P-1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(2), two equivalent F(7), and two equivalent F(8) atoms. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(10), and two equivalent F(5) atoms. In the third Ag site, Ag(3) is bonded to one F(2), one F(4), one F(5), one F(6), one F(8), and one F(9) atom to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(3) atoms. In the fifth Ag site, Ag(5) is bonded to two equivalent F(1), two equivalent F(6), and two equivalent F(9) atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. In the sixth Ag site, Ag(6) is bonded in a rectangular see-saw-like geometry to one F(10), one F(4), one F(7), and one F(9) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(2) and one Ag(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(3), and one Ag(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ag(4) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one Ag(6) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Ag(2) and one Ag(3) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one Ag(3) and one Ag(5) atom. In the seventh F site, F(7) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(6) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ag(1) and one Ag(3) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Ag(3), one Ag(5), and one Ag(6) atom. In the tenth F site, F(10) is bonded in a distorted single-bond geometry to one Ag(2) and one Ag(6) atom.
Ag2F5 crystallizes in the triclinic P-1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(2), two equivalent F(7), and two equivalent F(8) atoms. Both Ag(1)-F(2) bond lengths are 2.56 Å. Both Ag(1)-F(7) bond lengths are 2.12 Å. Both Ag(1)-F(8) bond lengths are 2.04 Å. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(10), and two equivalent F(5) atoms. Both Ag(2)-F(1) bond lengths are 2.13 Å. Both Ag(2)-F(10) bond lengths are 2.61 Å. Both Ag(2)-F(5) bond lengths are 2.03 Å. In the third Ag site, Ag(3) is bonded to one F(2), one F(4), one F(5), one F(6), one F(8), and one F(9) atom to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. The Ag(3)-F(2) bond length is 2.22 Å. The Ag(3)-F(4) bond length is 2.33 Å. The Ag(3)-F(5) bond length is 2.03 Å. The Ag(3)-F(6) bond length is 2.15 Å. The Ag(3)-F(8) bond length is 2.03 Å. The Ag(3)-F(9) bond length is 2.32 Å. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(3) atoms. Both Ag(4)-F(2) bond lengths are 1.95 Å. Both Ag(4)-F(3) bond lengths are 1.93 Å. In the fifth Ag site, Ag(5) is bonded to two equivalent F(1), two equivalent F(6), and two equivalent F(9) atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. Both Ag(5)-F(1) bond lengths are 1.99 Å. Both Ag(5)-F(6) bond lengths are 1.94 Å. Both Ag(5)-F(9) bond lengths are 2.59 Å. In the sixth Ag site, Ag(6) is bonded in a rectangular see-saw-like geometry to one F(10), one F(4), one F(7), and one F(9) atom. The Ag(6)-F(10) bond length is 1.92 Å. The Ag(6)-F(4) bond length is 1.95 Å. The Ag(6)-F(7) bond length is 1.96 Å. The Ag(6)-F(9) bond length is 1.95 Å. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(2) and one Ag(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(3), and one Ag(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ag(4) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one Ag(6) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Ag(2) and one Ag(3) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one Ag(3) and one Ag(5) atom. In the seventh F site, F(7) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(6) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ag(1) and one Ag(3) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Ag(3), one Ag(5), and one Ag(6) atom. In the tenth F site, F(10) is bonded in a distorted single-bond geometry to one Ag(2) and one Ag(6) atom.