CoH15(N3O)2Cl2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight hydrochloric acid atoms and four CoH15(N3O)2 clusters. In each CoH15(N3O)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(3), one H(5), and one H(7) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(4), one H(6), and one H(8) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(13), one H(14), and one H(15) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(1), one H(11), and one H(9) atom. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(10), one H(12), and one H(2) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1,2) atoms. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(5) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(3) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(3) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one N(3) atom. O(1,2) is bonded in a single-bond geometry to one N(6) atom.
CoH15(N3O)2Cl2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight hydrochloric acid atoms and four CoH15(N3O)2 clusters. In each CoH15(N3O)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. The Co(1)-N(1) bond length is 2.11 Å. The Co(1)-N(2) bond length is 2.11 Å. The Co(1)-N(3) bond length is 2.01 Å. The Co(1)-N(4) bond length is 2.08 Å. The Co(1)-N(5) bond length is 2.08 Å. The Co(1)-N(6) bond length is 1.96 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(3), one H(5), and one H(7) atom. The N(1)-H(3) bond length is 1.02 Å. The N(1)-H(5) bond length is 1.03 Å. The N(1)-H(7) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(4), one H(6), and one H(8) atom. The N(2)-H(4) bond length is 1.02 Å. The N(2)-H(6) bond length is 1.03 Å. The N(2)-H(8) bond length is 1.03 Å. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(13), one H(14), and one H(15) atom. The N(3)-H(13) bond length is 1.03 Å. The N(3)-H(14) bond length is 1.03 Å. The N(3)-H(15) bond length is 1.04 Å. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(1), one H(11), and one H(9) atom. The N(4)-H(1) bond length is 1.03 Å. The N(4)-H(11) bond length is 1.02 Å. The N(4)-H(9) bond length is 1.03 Å. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(10), one H(12), and one H(2) atom. The N(5)-H(10) bond length is 1.03 Å. The N(5)-H(12) bond length is 1.02 Å. The N(5)-H(2) bond length is 1.03 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1,2) atoms. Both N(6)-O(1,2) bond lengths are 1.24 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(4) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(5) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(3) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(3) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one N(3) atom. O(1,2) is bonded in a single-bond geometry to one N(6) atom.