KAgF3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent F(1) and six equivalent F(2) atoms. Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded to three equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FK3Ag2 square pyramids.
KAgF3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent F(1) and six equivalent F(2) atoms. There is one shorter (2.74 Å) and one longer (2.79 Å) K(1)-F(1) bond length. There are a spread of K(1)-F(2) bond distances ranging from 2.72-2.94 Å. Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. Both Ag(1)-F(1) bond lengths are 2.15 Å. There are two shorter (2.11 Å) and two longer (2.28 Å) Ag(1)-F(2) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded to three equivalent K(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FK3Ag2 square pyramids.