VO2 is beta Vanadium nitride-like structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms.
VO2 is beta Vanadium nitride-like structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. There are a spread of V(1)-O(1) bond distances ranging from 1.91-2.03 Å. There are a spread of V(1)-O(2) bond distances ranging from 1.85-2.09 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent V(1) atoms.