CeCH3SO7 crystallizes in the tetragonal P4_1 space group. Ce(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), two equivalent O(5), and two equivalent O(6) atoms. C(1) is bonded in a trigonal planar geometry to one H(1), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Ce(1) and one S(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ce(1) and one C(1) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ce(1) and one C(1) atom. In the fifth O site, O(7) is bonded in a water-like geometry to one Ce(1), one H(2), and one H(3) atom. In the sixth O site, O(1) is bonded in a 1-coordinate geometry to one Ce(1) and one S(1) atom. In the seventh O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom.
CeCH3SO7 crystallizes in the tetragonal P4_1 space group. Ce(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), two equivalent O(5), and two equivalent O(6) atoms. The Ce(1)-O(1) bond length is 2.53 Å. The Ce(1)-O(2) bond length is 2.40 Å. The Ce(1)-O(3) bond length is 2.47 Å. The Ce(1)-O(4) bond length is 2.51 Å. The Ce(1)-O(7) bond length is 2.53 Å. There is one shorter (2.60 Å) and one longer (2.86 Å) Ce(1)-O(5) bond length. There is one shorter (2.64 Å) and one longer (2.73 Å) Ce(1)-O(6) bond length. C(1) is bonded in a trigonal planar geometry to one H(1), one O(5), and one O(6) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-O(5) bond length is 1.27 Å. The C(1)-O(6) bond length is 1.28 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. The H(2)-O(7) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. The H(3)-O(7) bond length is 0.98 Å. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.50 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. The S(1)-O(4) bond length is 1.49 Å. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Ce(1) and one S(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ce(1) and one C(1) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ce(1) and one C(1) atom. In the fifth O site, O(7) is bonded in a water-like geometry to one Ce(1), one H(2), and one H(3) atom. In the sixth O site, O(1) is bonded in a 1-coordinate geometry to one Ce(1) and one S(1) atom. In the seventh O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom.