HgC6(NS2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four HgC6(NS2)2 clusters. Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(1) atom. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(3) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(1) is bonded in an L-shaped geometry to one Hg(1) and one C(1) atom.
HgC6(NS2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four HgC6(NS2)2 clusters. Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. Both Hg(1)-S(1) bond lengths are 2.45 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. The C(1)-N(1) bond length is 1.44 Å. The C(1)-S(1) bond length is 1.71 Å. The C(1)-S(2) bond length is 1.65 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(1) atom. The C(2)-N(1) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(1) atom. The C(3)-N(1) bond length is 1.35 Å. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(3) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(1) is bonded in an L-shaped geometry to one Hg(1) and one C(1) atom.