K4PtC6H4S2(NO6)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to two equivalent N(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to one N(1), one S(1), one O(1), one O(2), one O(3), one O(5), and two equivalent O(6) atoms. Pt(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. N(1) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. S(1) is bonded in a distorted water-like geometry to one K(2), one Pt(1), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one K(2), one Pt(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one K(1), one K(2), one H(1), and one H(2) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to two equivalent K(2) atoms.
K4PtC6H4S2(NO6)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to two equivalent N(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms. There is one shorter (2.89 Å) and one longer (3.11 Å) K(1)-N(1) bond length. The K(1)-O(2) bond length is 2.86 Å. The K(1)-O(4) bond length is 2.74 Å. The K(1)-O(5) bond length is 2.86 Å. There is one shorter (2.79 Å) and one longer (2.83 Å) K(1)-O(3) bond length. In the second K site, K(2) is bonded in a 8-coordinate geometry to one N(1), one S(1), one O(1), one O(2), one O(3), one O(5), and two equivalent O(6) atoms. The K(2)-N(1) bond length is 3.14 Å. The K(2)-S(1) bond length is 3.53 Å. The K(2)-O(1) bond length is 2.80 Å. The K(2)-O(2) bond length is 2.92 Å. The K(2)-O(3) bond length is 2.71 Å. The K(2)-O(5) bond length is 2.73 Å. Both K(2)-O(6) bond lengths are 2.86 Å. Pt(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(1) atoms. Both Pt(1)-S(1) bond lengths are 2.31 Å. Both Pt(1)-O(1) bond lengths are 2.05 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.66 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(2)-O(1) bond length is 1.31 Å. The C(2)-O(2) bond length is 1.24 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.26 Å. The C(3)-O(4) bond length is 1.27 Å. N(1) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 0.99 Å. S(1) is bonded in a distorted water-like geometry to one K(2), one Pt(1), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one K(2), one Pt(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one K(1), one K(2), one H(1), and one H(2) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to two equivalent K(2) atoms.