CsPb3 crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded to twelve equivalent Pb(1) atoms to form a mixture of distorted face and corner-sharing CsPb12 cuboctahedra. Pb(1) is bonded in a 10-coordinate geometry to four equivalent Cs(1) and six equivalent Pb(1) atoms.
CsPb3 crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded to twelve equivalent Pb(1) atoms to form a mixture of distorted face and corner-sharing CsPb12 cuboctahedra. There are six shorter (4.11 Å) and six longer (4.16 Å) Cs(1)-Pb(1) bond lengths. Pb(1) is bonded in a 10-coordinate geometry to four equivalent Cs(1) and six equivalent Pb(1) atoms. There are two shorter (3.17 Å) and four longer (3.40 Å) Pb(1)-Pb(1) bond lengths.