Ce(PdSb)2 crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Pd(1), four equivalent Pd(2), four equivalent Sb(1), and four equivalent Sb(2) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. In the second Pd site, Pd(2) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one Sb(2), and four equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Pd(2) atoms. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Pd(2), and four equivalent Pd(1) atoms.
Ce(PdSb)2 crystallizes in the tetragonal P4/nmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Pd(1), four equivalent Pd(2), four equivalent Sb(1), and four equivalent Sb(2) atoms. All Ce(1)-Pd(1) bond lengths are 3.44 Å. All Ce(1)-Pd(2) bond lengths are 3.59 Å. All Ce(1)-Sb(1) bond lengths are 3.58 Å. All Ce(1)-Sb(2) bond lengths are 3.51 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. All Pd(1)-Sb(2) bond lengths are 2.70 Å. In the second Pd site, Pd(2) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one Sb(2), and four equivalent Sb(1) atoms. The Pd(2)-Sb(2) bond length is 2.58 Å. All Pd(2)-Sb(1) bond lengths are 2.68 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Pd(2) atoms. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Pd(2), and four equivalent Pd(1) atoms.