CaF3Tl is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a CaF3 framework. In the CaF3 framework, Ca(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing CaF6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Ca(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Ca(1) atoms.
CaF3Tl is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a CaF3 framework. In the CaF3 framework, Ca(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing CaF6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. There is one shorter (2.25 Å) and one longer (2.26 Å) Ca(1)-F(2) bond length. There are two shorter (2.25 Å) and two longer (2.26 Å) Ca(1)-F(1) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Ca(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Ca(1) atoms.