KCH(NO)2 crystallizes in the tetragonal I-42d space group. K(1) is bonded in a 10-coordinate geometry to four equivalent N(1) and six equivalent O(1) atoms. C(1) is bonded in a trigonal planar geometry to two equivalent N(1) and one H(1) atom. N(1) is bonded in a bent 120 degrees geometry to two equivalent K(1), one C(1), and one O(1) atom. H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one N(1) atom.
KCH(NO)2 crystallizes in the tetragonal I-42d space group. K(1) is bonded in a 10-coordinate geometry to four equivalent N(1) and six equivalent O(1) atoms. There are two shorter (3.11 Å) and two longer (3.21 Å) K(1)-N(1) bond lengths. There are a spread of K(1)-O(1) bond distances ranging from 2.86-2.94 Å. C(1) is bonded in a trigonal planar geometry to two equivalent N(1) and one H(1) atom. Both C(1)-N(1) bond lengths are 1.35 Å. The C(1)-H(1) bond length is 1.10 Å. N(1) is bonded in a bent 120 degrees geometry to two equivalent K(1), one C(1), and one O(1) atom. The N(1)-O(1) bond length is 1.29 Å. H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one N(1) atom.