Li2SbSO4F3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one F(1) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to two equivalent F(2) and two equivalent F(3) atoms. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one F(1), one F(2), and one F(3) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom.
Li2SbSO4F3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one F(1) atom. The Li(1)-O(2) bond length is 2.28 Å. The Li(1)-O(3) bond length is 2.01 Å. The Li(1)-O(4) bond length is 2.38 Å. The Li(1)-F(1) bond length is 1.94 Å. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to two equivalent F(2) and two equivalent F(3) atoms. There is one shorter (1.95 Å) and one longer (1.96 Å) Li(2)-F(2) bond length. There is one shorter (1.98 Å) and one longer (2.15 Å) Li(2)-F(3) bond length. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one F(1), one F(2), and one F(3) atom. The Sb(1)-O(1) bond length is 2.31 Å. The Sb(1)-O(2) bond length is 2.43 Å. The Sb(1)-F(1) bond length is 2.03 Å. The Sb(1)-F(2) bond length is 2.09 Å. The Sb(1)-F(3) bond length is 2.01 Å. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The S(1)-O(1) bond length is 1.54 Å. The S(1)-O(2) bond length is 1.52 Å. The S(1)-O(3) bond length is 1.46 Å. The S(1)-O(4) bond length is 1.48 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Li(1) and one S(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(2) and one Sb(1) atom.