Cu(NH3)4(N3O4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dinitramide molecules and one Cu(NH3)4 cluster. In the Cu(NH3)4 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent N(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(1), one H(5), and one H(6) atom. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(2), one H(3), and one H(4) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom.
Cu(NH3)4(N3O4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dinitramide molecules and one Cu(NH3)4 cluster. In the Cu(NH3)4 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Cu(1)-N(1) bond lengths are 2.05 Å. Both Cu(1)-N(3) bond lengths are 2.03 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(1), one H(5), and one H(6) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(5) bond length is 1.03 Å. The N(1)-H(6) bond length is 1.03 Å. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(2), one H(3), and one H(4) atom. The N(3)-H(2) bond length is 1.03 Å. The N(3)-H(3) bond length is 1.02 Å. The N(3)-H(4) bond length is 1.03 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom.