WCoZn2O6 is pyrite-derived structured and crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-51°. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-51°. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one W(1), one Co(1), and two equivalent Zn(1) atoms.
WCoZn2O6 is pyrite-derived structured and crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-51°. Both W(1)-O(1) bond lengths are 1.94 Å. Both W(1)-O(2) bond lengths are 1.94 Å. Both W(1)-O(3) bond lengths are 2.01 Å. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-51°. Both Co(1)-O(1) bond lengths are 2.19 Å. Both Co(1)-O(2) bond lengths are 2.02 Å. Both Co(1)-O(3) bond lengths are 2.23 Å. Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 2.06 Å. There is one shorter (2.07 Å) and one longer (2.08 Å) Zn(1)-O(3) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one W(1), one Co(1), and two equivalent Zn(1) atoms.