CdTiO3 crystallizes in the triclinic P-1 space group. Ti(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form edge-sharing TiO4 tetrahedra. Cd(1) is bonded in a distorted see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent Cd(1) atoms. In the second O site, O(2) is bonded in a distorted linear geometry to one Ti(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one Cd(1) atom.
CdTiO3 crystallizes in the triclinic P-1 space group. Ti(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form edge-sharing TiO4 tetrahedra. The Ti(1)-O(1) bond length is 1.82 Å. The Ti(1)-O(2) bond length is 1.74 Å. There is one shorter (1.90 Å) and one longer (1.91 Å) Ti(1)-O(3) bond length. Cd(1) is bonded in a distorted see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. The Cd(1)-O(2) bond length is 2.10 Å. The Cd(1)-O(3) bond length is 2.28 Å. There is one shorter (2.20 Å) and one longer (2.25 Å) Cd(1)-O(1) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1) and two equivalent Cd(1) atoms. In the second O site, O(2) is bonded in a distorted linear geometry to one Ti(1) and one Cd(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one Cd(1) atom.