ZnC2(N3Br2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC2(N3Br2)2 clusters. Zn(1) is bonded in a distorted trigonal pyramidal geometry to one Br(1), one Br(2), one Br(3), and one Br(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one N(3) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one N(4), one N(5), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one C(1) and one N(3) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(1) and one Br(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one C(2) and one N(6) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(2) and one Br(1) atom. In the sixth N site, N(6) is bonded in a 2-coordinate geometry to one C(2) and one N(4) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a water-like geometry to one Zn(1) and one N(5) atom. In the second Br site, Br(2) is bonded in a water-like geometry to one Zn(1) and one N(2) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Zn(1) atom.
ZnC2(N3Br2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC2(N3Br2)2 clusters. Zn(1) is bonded in a distorted trigonal pyramidal geometry to one Br(1), one Br(2), one Br(3), and one Br(4) atom. The Zn(1)-Br(1) bond length is 2.69 Å. The Zn(1)-Br(2) bond length is 2.88 Å. The Zn(1)-Br(3) bond length is 2.31 Å. The Zn(1)-Br(4) bond length is 2.29 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.41 Å. The C(1)-N(2) bond length is 1.26 Å. The C(1)-N(3) bond length is 1.40 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one N(4), one N(5), and one N(6) atom. The C(2)-N(4) bond length is 1.40 Å. The C(2)-N(5) bond length is 1.26 Å. The C(2)-N(6) bond length is 1.40 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one C(1) and one N(3) atom. The N(1)-N(3) bond length is 1.29 Å. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(1) and one Br(2) atom. The N(2)-Br(2) bond length is 1.97 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one C(2) and one N(6) atom. The N(4)-N(6) bond length is 1.30 Å. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(2) and one Br(1) atom. The N(5)-Br(1) bond length is 1.98 Å. In the sixth N site, N(6) is bonded in a 2-coordinate geometry to one C(2) and one N(4) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a water-like geometry to one Zn(1) and one N(5) atom. In the second Br site, Br(2) is bonded in a water-like geometry to one Zn(1) and one N(2) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Zn(1) atom.