Cr2Pb4H2O10ClF crystallizes in the orthorhombic Pmn2_1 space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a tetrahedral geometry to one O(3), one O(6), and two equivalent O(1) atoms. In the second Cr site, Cr(2) is bonded in a tetrahedral geometry to one O(4), one O(7), and two equivalent O(2) atoms. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), one Cl(1), and one F(1) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(3), two equivalent O(5), and one F(1) atom. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to one O(4), two equivalent O(5), and one F(1) atom. H(1) is bonded in a single-bond geometry to one O(5) atom. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Pb(1) atoms. In the second O site, O(7) is bonded in a distorted single-bond geometry to one Cr(2) and two equivalent Pb(1) atoms. In the third O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Cr(2) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Cr(1), one Pb(2), and two equivalent Pb(1) atoms. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Cr(2), one Pb(3), and two equivalent Pb(1) atoms. In the seventh O site, O(5) is bonded in a single-bond geometry to one Pb(1), one Pb(2), one Pb(3), and one H(1) atom. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Pb(1) atoms. F(1) is bonded in a distorted L-shaped geometry to one Pb(2), one Pb(3), and two equivalent Pb(1) atoms.
Cr2Pb4H2O10ClF crystallizes in the orthorhombic Pmn2_1 space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a tetrahedral geometry to one O(3), one O(6), and two equivalent O(1) atoms. The Cr(1)-O(3) bond length is 1.71 Å. The Cr(1)-O(6) bond length is 1.68 Å. Both Cr(1)-O(1) bond lengths are 1.65 Å. In the second Cr site, Cr(2) is bonded in a tetrahedral geometry to one O(4), one O(7), and two equivalent O(2) atoms. The Cr(2)-O(4) bond length is 1.71 Å. The Cr(2)-O(7) bond length is 1.68 Å. Both Cr(2)-O(2) bond lengths are 1.65 Å. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), one Cl(1), and one F(1) atom. The Pb(1)-O(3) bond length is 2.64 Å. The Pb(1)-O(4) bond length is 2.65 Å. The Pb(1)-O(5) bond length is 2.48 Å. The Pb(1)-O(6) bond length is 2.56 Å. The Pb(1)-O(7) bond length is 2.56 Å. The Pb(1)-Cl(1) bond length is 3.09 Å. The Pb(1)-F(1) bond length is 2.80 Å. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(3), two equivalent O(5), and one F(1) atom. The Pb(2)-O(3) bond length is 2.58 Å. Both Pb(2)-O(5) bond lengths are 2.42 Å. The Pb(2)-F(1) bond length is 2.51 Å. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to one O(4), two equivalent O(5), and one F(1) atom. The Pb(3)-O(4) bond length is 2.57 Å. Both Pb(3)-O(5) bond lengths are 2.44 Å. The Pb(3)-F(1) bond length is 2.53 Å. H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 0.99 Å. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Pb(1) atoms. In the second O site, O(7) is bonded in a distorted single-bond geometry to one Cr(2) and two equivalent Pb(1) atoms. In the third O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Cr(2) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Cr(1), one Pb(2), and two equivalent Pb(1) atoms. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Cr(2), one Pb(3), and two equivalent Pb(1) atoms. In the seventh O site, O(5) is bonded in a single-bond geometry to one Pb(1), one Pb(2), one Pb(3), and one H(1) atom. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Pb(1) atoms. F(1) is bonded in a distorted L-shaped geometry to one Pb(2), one Pb(3), and two equivalent Pb(1) atoms.