AlCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two AlCl4 clusters and two SCl3 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(5), one Cl(6), and one Cl(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Al(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom.
AlCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two AlCl4 clusters and two SCl3 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(5), one Cl(6), and one Cl(7) atom. The Al(1)-Cl(3) bond length is 2.14 Å. The Al(1)-Cl(5) bond length is 2.15 Å. The Al(1)-Cl(6) bond length is 2.15 Å. The Al(1)-Cl(7) bond length is 2.15 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Al(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(4) atom. The S(1)-Cl(1) bond length is 2.00 Å. The S(1)-Cl(2) bond length is 2.00 Å. The S(1)-Cl(4) bond length is 2.00 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom.