MoPN(OCl3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MoPN(OCl3)2 clusters. Mo(1) is bonded to one N(1), one O(1), one Cl(1), one Cl(2), and two equivalent Cl(4) atoms to form distorted MoNCl4O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra and  an edgeedge with one Mo(1)NCl4O octahedra. P(1) is bonded to one O(1), one Cl(3), one Cl(5), and one Cl(6) atom to form PCl3O tetrahedra that share  a cornercorner with one Mo(1)NCl4O octahedra. The corner-sharing octahedral tilt angles are 31°. N(1) is bonded in a linear geometry to one Mo(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Mo(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom.
MoPN(OCl3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MoPN(OCl3)2 clusters. Mo(1) is bonded to one N(1), one O(1), one Cl(1), one Cl(2), and two equivalent Cl(4) atoms to form distorted MoNCl4O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra and  an edgeedge with one Mo(1)NCl4O octahedra. The Mo(1)-N(1) bond length is 1.78 Å. The Mo(1)-O(1) bond length is 2.26 Å. The Mo(1)-Cl(1) bond length is 2.34 Å. The Mo(1)-Cl(2) bond length is 2.35 Å. There is one shorter (2.54 Å) and one longer (2.57 Å) Mo(1)-Cl(4) bond length. P(1) is bonded to one O(1), one Cl(3), one Cl(5), and one Cl(6) atom to form PCl3O tetrahedra that share  a cornercorner with one Mo(1)NCl4O octahedra. The corner-sharing octahedral tilt angles are 31°. The P(1)-O(1) bond length is 1.51 Å. The P(1)-Cl(3) bond length is 1.99 Å. The P(1)-Cl(5) bond length is 1.98 Å. The P(1)-Cl(6) bond length is 1.98 Å. N(1) is bonded in a linear geometry to one Mo(1) and one O(2) atom. The N(1)-O(2) bond length is 1.19 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Mo(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom.