Li(MoO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with twelve equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. Mo(1) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra and edges with six equivalent Mo(1)O6 octahedra. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1) and three equivalent Mo(1) atoms.
Li(MoO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with twelve equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. All Li(1)-O(1) bond lengths are 1.84 Å. Mo(1) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra and edges with six equivalent Mo(1)O6 octahedra. All Mo(1)-O(1) bond lengths are 2.10 Å. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1) and three equivalent Mo(1) atoms.