Ag2TeS3 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), and two equivalent S(1) atoms. In the second Ag site, Ag(2) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. Te(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form corner-sharing SAg3Te tetrahedra. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ag(1), two equivalent Ag(2), and one Te(1) atom.
Ag2TeS3 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one S(2), one S(3), and two equivalent S(1) atoms. The Ag(1)-S(2) bond length is 2.59 Å. The Ag(1)-S(3) bond length is 2.80 Å. There is one shorter (2.53 Å) and one longer (2.55 Å) Ag(1)-S(1) bond length. In the second Ag site, Ag(2) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form corner-sharing AgS4 tetrahedra. The Ag(2)-S(1) bond length is 2.69 Å. The Ag(2)-S(2) bond length is 2.51 Å. There is one shorter (2.58 Å) and one longer (2.61 Å) Ag(2)-S(3) bond length. Te(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. The Te(1)-S(1) bond length is 2.41 Å. The Te(1)-S(2) bond length is 2.36 Å. The Te(1)-S(3) bond length is 2.39 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(2), two equivalent Ag(1), and one Te(1) atom to form corner-sharing SAg3Te tetrahedra. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ag(1), two equivalent Ag(2), and one Te(1) atom.