Te7(OF5)6 is Protactinium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Te7(OF5)6 cluster. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 42°. In the second Te site, Te(2,3) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. In the third Te site, Te(4) is bonded to one O(3), one F(11), one F(12), one F(13), one F(14), and one F(15) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(2,3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2,3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(2,3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2,3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(2,3) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2,3) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2,3) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(2,3) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(2,3) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2,3) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Te(4) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Te(4) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Te(4) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one Te(4) atom. In the fifteenth F site, F(15) is bonded in a single-bond geometry to one Te(4) atom.
Te7(OF5)6 is Protactinium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Te7(OF5)6 cluster. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 42°. Both Te(1)-O(1) bond lengths are 1.96 Å. Both Te(1)-O(2) bond lengths are 1.96 Å. Both Te(1)-O(3) bond lengths are 1.96 Å. In the second Te site, Te(2,3) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. The Te(2,3)-O(1) bond length is 1.94 Å. The Te(2,3)-F(1) bond length is 1.87 Å. The Te(2,3)-F(2) bond length is 1.87 Å. The Te(2,3)-F(3) bond length is 1.87 Å. The Te(2,3)-F(4) bond length is 1.87 Å. The Te(2,3)-F(5) bond length is 1.87 Å. In the third Te site, Te(4) is bonded to one O(3), one F(11), one F(12), one F(13), one F(14), and one F(15) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 42°. The Te(4)-O(3) bond length is 1.94 Å. The Te(4)-F(11) bond length is 1.87 Å. The Te(4)-F(12) bond length is 1.87 Å. The Te(4)-F(13) bond length is 1.87 Å. The Te(4)-F(14) bond length is 1.87 Å. The Te(4)-F(15) bond length is 1.86 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2,3) atom. The O(2)-Te(2,3) bond length is 1.94 Å. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(2,3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2,3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(2,3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2,3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(2,3) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2,3) atom. The F(6)-Te(2,3) bond length is 1.87 Å. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2,3) atom. The F(7)-Te(2,3) bond length is 1.87 Å. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(2,3) atom. The F(8)-Te(2,3) bond length is 1.87 Å. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(2,3) atom. The F(9)-Te(2,3) bond length is 1.87 Å. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2,3) atom. The F(10)-Te(2,3) bond length is 1.86 Å. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Te(4) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Te(4) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Te(4) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one Te(4) atom. In the fifteenth F site, F(15) is bonded in a single-bond geometry to one Te(4) atom.