Ca12ScCo7O24 crystallizes in the monoclinic C2 space group. There are seven inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(12), two equivalent O(5), and two equivalent O(9) atoms. In the second Ca site, Ca(2) is bonded in a 8-coordinate geometry to two equivalent O(10), two equivalent O(11), two equivalent O(2), and two equivalent O(6) atoms. In the third Ca site, Ca(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. In the fourth Ca site, Ca(4) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. In the fifth Ca site, Ca(5) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(3), one O(7), two equivalent O(5), and two equivalent O(9) atoms. In the sixth Ca site, Ca(6) is bonded in a 8-coordinate geometry to one O(11), one O(2), one O(4), one O(8), two equivalent O(10), and two equivalent O(6) atoms. In the seventh Ca site, Ca(7) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(3), one O(4), one O(7), and one O(8) atom. Sc(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form distorted ScO6 pentagonal pyramids that share faces with two equivalent Co(1)O6 octahedra. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form face-sharing CoO6 octahedra. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form distorted face-sharing CoO6 pentagonal pyramids. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(1), one Ca(3), one Ca(5), one Ca(7), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(2)Ca4Co2 octahedra, corners with two equivalent O(4)Ca4Co2 octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with three equivalent O(7)Ca4Co2 octahedra, corners with three equivalent O(9)Ca4Co2 octahedra, corners with three equivalent O(3)Ca4ScCo octahedra,  an edgeedge with one O(11)Ca4Co2 octahedra,  an edgeedge with one O(1)Ca4ScCo octahedra, edges with two equivalent O(12)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(3)Ca4ScCo octahedra, and faces with two equivalent O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-68°. In the second O site, O(2) is bonded to one Ca(2), one Ca(4), one Ca(6), one Ca(7), one Co(2), and one Co(3) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(1)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4Co2 octahedra, corners with two equivalent O(3)Ca4ScCo octahedra, corners with three equivalent O(10)Ca4Co2 octahedra, corners with three equivalent O(4)Ca4Co2 octahedra, corners with three equivalent O(8)Ca4Co2 octahedra,  an edgeedge with one O(12)Ca4Co2 octahedra,  an edgeedge with one O(2)Ca4Co2 octahedra, edges with two equivalent O(11)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra,  a faceface with one O(7)Ca4Co2 octahedra, and faces with two equivalent O(6)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-65°. In the third O site, O(3) is bonded to one Ca(3), one Ca(4), one Ca(5), one Ca(7), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(10)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(11)Ca4Co2 octahedra, corners with two equivalent O(2)Ca4Co2 octahedra, corners with two equivalent O(9)Ca4Co2 octahedra, corners with three equivalent O(1)Ca4ScCo octahedra,  an edgeedge with one O(9)Ca4Co2 octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra, edges with two equivalent O(7)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(1)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 1-65°. In the fourth O site, O(4) is bonded to one Ca(3), one Ca(4), one Ca(6), one Ca(7), one Co(2), and one Co(3) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(9)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(10)Ca4Co2 octahedra, corners with two equivalent O(12)Ca4Co2 octahedra, corners with two equivalent O(1)Ca4ScCo octahedra, corners with three equivalent O(2)Ca4Co2 octahedra,  an edgeedge with one O(10)Ca4Co2 octahedra,  an edgeedge with one O(6)Ca4Co2 octahedra, edges with two equivalent O(8)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(2)Ca4Co2 octahedra,  a faceface with one O(6)Ca4Co2 octahedra,  a faceface with one O(7)Ca4Co2 octahedra, and  a faceface with one O(3)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 1-67°. In the fifth O site, O(5) is bonded to one Ca(1), one Ca(3), two equivalent Ca(5), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(9)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(12)Ca4Co2 octahedra, corners with two equivalent O(8)Ca4Co2 octahedra, corners with two equivalent O(1)Ca4ScCo octahedra, corners with four equivalent O(5)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4Co2 octahedra,  an edgeedge with one O(3)Ca4ScCo octahedra, edges with two equivalent O(9)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(3)Ca4ScCo octahedra, and faces with two equivalent O(1)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-64°. In the sixth O site, O(6) is bonded to one Ca(2), one Ca(4), two equivalent Ca(6), one Co(2), and one Co(3) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(10)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(11)Ca4Co2 octahedra, corners with two equivalent O(2)Ca4Co2 octahedra, corners with two equivalent O(7)Ca4Co2 octahedra, corners with four equivalent O(6)Ca4Co2 octahedra,  an edgeedge with one O(4)Ca4Co2 octahedra,  an edgeedge with one O(8)Ca4Co2 octahedra, edges with two equivalent O(10)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra, and faces with two equivalent O(2)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-66°. In the seventh O site, O(7) is bonded to one Ca(3), one Ca(4), one Ca(5), one Ca(7), one Co(2), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4Co2 octahedra, corners with two equivalent O(9)Ca4Co2 octahedra, corners with three equivalent O(1)Ca4ScCo octahedra, corners with four equivalent O(8)Ca4Co2 octahedra,  an edgeedge with one O(9)Ca4Co2 octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra, edges with two equivalent O(3)Ca4ScCo octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(2)Ca4Co2 octahedra, and  a faceface with one O(4)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-68°. In the eighth O site, O(8) is bonded to one Ca(3), one Ca(4), one Ca(6), one Ca(7), one Co(1), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(10)Ca4Co2 octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with three equivalent O(2)Ca4Co2 octahedra, corners with four equivalent O(7)Ca4Co2 octahedra,  an edgeedge with one O(10)Ca4Co2 octahedra,  an edgeedge with one O(6)Ca4Co2 octahedra, edges with two equivalent O(4)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(1)Ca4ScCo octahedra, and  a faceface with one O(3)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-65°. In the ninth O site, O(9) is bonded to one Ca(1), one Ca(3), two equivalent Ca(5), one Co(1), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(10)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(11)Ca4Co2 octahedra, corners with two equivalent O(7)Ca4Co2 octahedra, corners with two equivalent O(3)Ca4ScCo octahedra, corners with three equivalent O(12)Ca4Co2 octahedra, corners with three equivalent O(1)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4Co2 octahedra,  an edgeedge with one O(3)Ca4ScCo octahedra, edges with two equivalent O(5)Ca4ScCo octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(1)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 1-65°. In the tenth O site, O(10) is bonded to one Ca(2), one Ca(4), two equivalent Ca(6), one Co(2), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(9)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(12)Ca4Co2 octahedra, corners with two equivalent O(4)Ca4Co2 octahedra, corners with two equivalent O(8)Ca4Co2 octahedra, corners with three equivalent O(11)Ca4Co2 octahedra, corners with three equivalent O(2)Ca4Co2 octahedra,  an edgeedge with one O(4)Ca4Co2 octahedra,  an edgeedge with one O(8)Ca4Co2 octahedra, edges with two equivalent O(6)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(2)Ca4Co2 octahedra,  a faceface with one O(6)Ca4Co2 octahedra, and  a faceface with one O(7)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-67°. In the eleventh O site, O(11) is bonded to one Ca(2), one Ca(3), one Ca(6), one Ca(7), one Co(2), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(2)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4Co2 octahedra, corners with two equivalent O(9)Ca4Co2 octahedra, corners with two equivalent O(3)Ca4ScCo octahedra, corners with three equivalent O(10)Ca4Co2 octahedra,  an edgeedge with one O(12)Ca4Co2 octahedra,  an edgeedge with one O(1)Ca4ScCo octahedra, edges with two equivalent O(2)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra,  a faceface with one O(6)Ca4Co2 octahedra,  a faceface with one O(7)Ca4Co2 octahedra, and  a faceface with one O(8)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-66°. In the twelfth O site, O(12) is bonded to one Ca(1), one Ca(4), one Ca(5), one Ca(7), one Co(1), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(1)Ca4ScCo octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(10)Ca4Co2 octahedra, corners with two equivalent O(4)Ca4Co2 octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with three equivalent O(9)Ca4Co2 octahedra,  an edgeedge with one O(11)Ca4Co2 octahedra,  an edgeedge with one O(2)Ca4Co2 octahedra, edges with two equivalent O(1)Ca4ScCo octahedra,  a faceface with one O(7)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(3)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-64°.
Ca12ScCo7O24 crystallizes in the monoclinic C2 space group. There are seven inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(12), two equivalent O(5), and two equivalent O(9) atoms. Both Ca(1)-O(1) bond lengths are 2.41 Å. Both Ca(1)-O(12) bond lengths are 2.45 Å. Both Ca(1)-O(5) bond lengths are 2.48 Å. Both Ca(1)-O(9) bond lengths are 2.53 Å. In the second Ca site, Ca(2) is bonded in a 8-coordinate geometry to two equivalent O(10), two equivalent O(11), two equivalent O(2), and two equivalent O(6) atoms. Both Ca(2)-O(10) bond lengths are 2.60 Å. Both Ca(2)-O(11) bond lengths are 2.51 Å. Both Ca(2)-O(2) bond lengths are 2.35 Å. Both Ca(2)-O(6) bond lengths are 2.51 Å. In the third Ca site, Ca(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. The Ca(3)-O(1) bond length is 2.50 Å. The Ca(3)-O(11) bond length is 2.48 Å. The Ca(3)-O(3) bond length is 2.41 Å. The Ca(3)-O(4) bond length is 2.52 Å. The Ca(3)-O(5) bond length is 2.41 Å. The Ca(3)-O(7) bond length is 2.44 Å. The Ca(3)-O(8) bond length is 2.55 Å. The Ca(3)-O(9) bond length is 2.54 Å. In the fourth Ca site, Ca(4) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom. The Ca(4)-O(10) bond length is 2.43 Å. The Ca(4)-O(12) bond length is 2.64 Å. The Ca(4)-O(2) bond length is 2.49 Å. The Ca(4)-O(3) bond length is 2.51 Å. The Ca(4)-O(4) bond length is 2.36 Å. The Ca(4)-O(6) bond length is 2.34 Å. The Ca(4)-O(7) bond length is 2.57 Å. The Ca(4)-O(8) bond length is 2.52 Å. In the fifth Ca site, Ca(5) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(3), one O(7), two equivalent O(5), and two equivalent O(9) atoms. The Ca(5)-O(1) bond length is 2.64 Å. The Ca(5)-O(12) bond length is 2.44 Å. The Ca(5)-O(3) bond length is 2.48 Å. The Ca(5)-O(7) bond length is 2.31 Å. There is one shorter (2.49 Å) and one longer (2.63 Å) Ca(5)-O(5) bond length. There is one shorter (2.36 Å) and one longer (2.48 Å) Ca(5)-O(9) bond length. In the sixth Ca site, Ca(6) is bonded in a 8-coordinate geometry to one O(11), one O(2), one O(4), one O(8), two equivalent O(10), and two equivalent O(6) atoms. The Ca(6)-O(11) bond length is 2.48 Å. The Ca(6)-O(2) bond length is 2.57 Å. The Ca(6)-O(4) bond length is 2.52 Å. The Ca(6)-O(8) bond length is 2.44 Å. There is one shorter (2.39 Å) and one longer (2.44 Å) Ca(6)-O(10) bond length. There is one shorter (2.46 Å) and one longer (2.60 Å) Ca(6)-O(6) bond length. In the seventh Ca site, Ca(7) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(3), one O(4), one O(7), and one O(8) atom. The Ca(7)-O(1) bond length is 2.58 Å. The Ca(7)-O(11) bond length is 2.32 Å. The Ca(7)-O(12) bond length is 2.46 Å. The Ca(7)-O(2) bond length is 2.41 Å. The Ca(7)-O(3) bond length is 2.66 Å. The Ca(7)-O(4) bond length is 2.56 Å. The Ca(7)-O(7) bond length is 2.42 Å. The Ca(7)-O(8) bond length is 2.47 Å. Sc(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form distorted ScO6 pentagonal pyramids that share faces with two equivalent Co(1)O6 octahedra. Both Sc(1)-O(1) bond lengths are 2.12 Å. Both Sc(1)-O(3) bond lengths are 2.11 Å. Both Sc(1)-O(5) bond lengths are 2.12 Å. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form CoO6 octahedra that share  a faceface with one Sc(1)O6 pentagonal pyramid. The Co(1)-O(1) bond length is 1.93 Å. The Co(1)-O(12) bond length is 1.86 Å. The Co(1)-O(3) bond length is 1.95 Å. The Co(1)-O(5) bond length is 1.93 Å. The Co(1)-O(8) bond length is 1.86 Å. The Co(1)-O(9) bond length is 1.90 Å. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form face-sharing CoO6 octahedra. The Co(2)-O(10) bond length is 1.94 Å. The Co(2)-O(11) bond length is 1.94 Å. The Co(2)-O(2) bond length is 1.93 Å. The Co(2)-O(4) bond length is 1.93 Å. The Co(2)-O(6) bond length is 1.93 Å. The Co(2)-O(7) bond length is 1.94 Å. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form distorted face-sharing CoO6 pentagonal pyramids. Both Co(3)-O(2) bond lengths are 2.12 Å. Both Co(3)-O(4) bond lengths are 2.01 Å. Both Co(3)-O(6) bond lengths are 2.10 Å. In the fourth Co site, Co(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom. The Co(4)-O(10) bond length is 2.07 Å. The Co(4)-O(11) bond length is 2.13 Å. The Co(4)-O(12) bond length is 2.21 Å. The Co(4)-O(7) bond length is 2.18 Å. The Co(4)-O(8) bond length is 2.16 Å. The Co(4)-O(9) bond length is 2.17 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(1), one Ca(3), one Ca(5), one Ca(7), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(2)Ca4Co2 octahedra, corners with two equivalent O(4)Ca4Co2 octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with three equivalent O(7)Ca4Co2 octahedra, corners with three equivalent O(9)Ca4Co2 octahedra, corners with three equivalent O(3)Ca4ScCo octahedra,  an edgeedge with one O(11)Ca4Co2 octahedra,  an edgeedge with one O(1)Ca4ScCo octahedra, edges with two equivalent O(12)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(3)Ca4ScCo octahedra, and faces with two equivalent O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-68°. In the second O site, O(2) is bonded to one Ca(2), one Ca(4), one Ca(6), one Ca(7), one Co(2), and one Co(3) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(1)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4Co2 octahedra, corners with two equivalent O(3)Ca4ScCo octahedra, corners with three equivalent O(10)Ca4Co2 octahedra, corners with three equivalent O(4)Ca4Co2 octahedra, corners with three equivalent O(8)Ca4Co2 octahedra,  an edgeedge with one O(12)Ca4Co2 octahedra,  an edgeedge with one O(2)Ca4Co2 octahedra, edges with two equivalent O(11)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra,  a faceface with one O(7)Ca4Co2 octahedra, and faces with two equivalent O(6)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-65°. In the third O site, O(3) is bonded to one Ca(3), one Ca(4), one Ca(5), one Ca(7), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(10)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(11)Ca4Co2 octahedra, corners with two equivalent O(2)Ca4Co2 octahedra, corners with two equivalent O(9)Ca4Co2 octahedra, corners with three equivalent O(1)Ca4ScCo octahedra,  an edgeedge with one O(9)Ca4Co2 octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra, edges with two equivalent O(7)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(1)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 1-65°. In the fourth O site, O(4) is bonded to one Ca(3), one Ca(4), one Ca(6), one Ca(7), one Co(2), and one Co(3) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(9)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(10)Ca4Co2 octahedra, corners with two equivalent O(12)Ca4Co2 octahedra, corners with two equivalent O(1)Ca4ScCo octahedra, corners with three equivalent O(2)Ca4Co2 octahedra,  an edgeedge with one O(10)Ca4Co2 octahedra,  an edgeedge with one O(6)Ca4Co2 octahedra, edges with two equivalent O(8)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(2)Ca4Co2 octahedra,  a faceface with one O(6)Ca4Co2 octahedra,  a faceface with one O(7)Ca4Co2 octahedra, and  a faceface with one O(3)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 1-67°. In the fifth O site, O(5) is bonded to one Ca(1), one Ca(3), two equivalent Ca(5), one Sc(1), and one Co(1) atom to form distorted OCa4ScCo octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(9)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(12)Ca4Co2 octahedra, corners with two equivalent O(8)Ca4Co2 octahedra, corners with two equivalent O(1)Ca4ScCo octahedra, corners with four equivalent O(5)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4Co2 octahedra,  an edgeedge with one O(3)Ca4ScCo octahedra, edges with two equivalent O(9)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(3)Ca4ScCo octahedra, and faces with two equivalent O(1)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-64°. In the sixth O site, O(6) is bonded to one Ca(2), one Ca(4), two equivalent Ca(6), one Co(2), and one Co(3) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(10)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(11)Ca4Co2 octahedra, corners with two equivalent O(2)Ca4Co2 octahedra, corners with two equivalent O(7)Ca4Co2 octahedra, corners with four equivalent O(6)Ca4Co2 octahedra,  an edgeedge with one O(4)Ca4Co2 octahedra,  an edgeedge with one O(8)Ca4Co2 octahedra, edges with two equivalent O(10)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra, and faces with two equivalent O(2)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-66°. In the seventh O site, O(7) is bonded to one Ca(3), one Ca(4), one Ca(5), one Ca(7), one Co(2), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4Co2 octahedra, corners with two equivalent O(9)Ca4Co2 octahedra, corners with three equivalent O(1)Ca4ScCo octahedra, corners with four equivalent O(8)Ca4Co2 octahedra,  an edgeedge with one O(9)Ca4Co2 octahedra,  an edgeedge with one O(5)Ca4ScCo octahedra, edges with two equivalent O(3)Ca4ScCo octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(2)Ca4Co2 octahedra, and  a faceface with one O(4)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-68°. In the eighth O site, O(8) is bonded to one Ca(3), one Ca(4), one Ca(6), one Ca(7), one Co(1), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(10)Ca4Co2 octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with three equivalent O(2)Ca4Co2 octahedra, corners with four equivalent O(7)Ca4Co2 octahedra,  an edgeedge with one O(10)Ca4Co2 octahedra,  an edgeedge with one O(6)Ca4Co2 octahedra, edges with two equivalent O(4)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(1)Ca4ScCo octahedra, and  a faceface with one O(3)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-65°. In the ninth O site, O(9) is bonded to one Ca(1), one Ca(3), two equivalent Ca(5), one Co(1), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(10)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(11)Ca4Co2 octahedra, corners with two equivalent O(7)Ca4Co2 octahedra, corners with two equivalent O(3)Ca4ScCo octahedra, corners with three equivalent O(12)Ca4Co2 octahedra, corners with three equivalent O(1)Ca4ScCo octahedra,  an edgeedge with one O(7)Ca4Co2 octahedra,  an edgeedge with one O(3)Ca4ScCo octahedra, edges with two equivalent O(5)Ca4ScCo octahedra,  a faceface with one O(12)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(1)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 1-65°. In the tenth O site, O(10) is bonded to one Ca(2), one Ca(4), two equivalent Ca(6), one Co(2), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(9)Ca4Co2 octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(12)Ca4Co2 octahedra, corners with two equivalent O(4)Ca4Co2 octahedra, corners with two equivalent O(8)Ca4Co2 octahedra, corners with three equivalent O(11)Ca4Co2 octahedra, corners with three equivalent O(2)Ca4Co2 octahedra,  an edgeedge with one O(4)Ca4Co2 octahedra,  an edgeedge with one O(8)Ca4Co2 octahedra, edges with two equivalent O(6)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(11)Ca4Co2 octahedra,  a faceface with one O(2)Ca4Co2 octahedra,  a faceface with one O(6)Ca4Co2 octahedra, and  a faceface with one O(7)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-67°. In the eleventh O site, O(11) is bonded to one Ca(2), one Ca(3), one Ca(6), one Ca(7), one Co(2), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(11)Ca4Co2 octahedra,  a cornercorner with one O(2)Ca4Co2 octahedra,  a cornercorner with one O(4)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(5)Ca4ScCo octahedra, corners with two equivalent O(6)Ca4Co2 octahedra, corners with two equivalent O(9)Ca4Co2 octahedra, corners with two equivalent O(3)Ca4ScCo octahedra, corners with three equivalent O(10)Ca4Co2 octahedra,  an edgeedge with one O(12)Ca4Co2 octahedra,  an edgeedge with one O(1)Ca4ScCo octahedra, edges with two equivalent O(2)Ca4Co2 octahedra,  a faceface with one O(10)Ca4Co2 octahedra,  a faceface with one O(4)Ca4Co2 octahedra,  a faceface with one O(6)Ca4Co2 octahedra,  a faceface with one O(7)Ca4Co2 octahedra, and  a faceface with one O(8)Ca4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-66°. In the twelfth O site, O(12) is bonded to one Ca(1), one Ca(4), one Ca(5), one Ca(7), one Co(1), and one Co(4) atom to form distorted OCa4Co2 octahedra that share  a cornercorner with one O(12)Ca4Co2 octahedra,  a cornercorner with one O(6)Ca4Co2 octahedra,  a cornercorner with one O(7)Ca4Co2 octahedra,  a cornercorner with one O(8)Ca4Co2 octahedra,  a cornercorner with one O(1)Ca4ScCo octahedra,  a cornercorner with one O(3)Ca4ScCo octahedra, corners with two equivalent O(10)Ca4Co2 octahedra, corners with two equivalent O(4)Ca4Co2 octahedra, corners with two equivalent O(5)Ca4ScCo octahedra, corners with three equivalent O(9)Ca4Co2 octahedra,  an edgeedge with one O(11)Ca4Co2 octahedra,  an edgeedge with one O(2)Ca4Co2 octahedra, edges with two equivalent O(1)Ca4ScCo octahedra,  a faceface with one O(7)Ca4Co2 octahedra,  a faceface with one O(8)Ca4Co2 octahedra,  a faceface with one O(9)Ca4Co2 octahedra,  a faceface with one O(3)Ca4ScCo octahedra, and  a faceface with one O(5)Ca4ScCo octahedra. The corner-sharing octahedral tilt angles range from 2-64°.