CNS2F5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two isothiocyanatosulfur pentafluoride molecules. C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an octahedral geometry to one N(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one S(1) atom.
CNS2F5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two isothiocyanatosulfur pentafluoride molecules. C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. The C(1)-N(1) bond length is 1.23 Å. The C(1)-S(2) bond length is 1.55 Å. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. The N(1)-S(1) bond length is 1.69 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in an octahedral geometry to one N(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The S(1)-F(1) bond length is 1.60 Å. The S(1)-F(2) bond length is 1.61 Å. The S(1)-F(3) bond length is 1.62 Å. The S(1)-F(4) bond length is 1.62 Å. The S(1)-F(5) bond length is 1.62 Å. In the second S site, S(2) is bonded in a single-bond geometry to one C(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one S(1) atom.