KLiWO3 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 10-coordinate geometry to one Li(1), three equivalent O(2), and six equivalent O(1) atoms. Li(1) is bonded in a 3-coordinate geometry to one K(1), one O(2), and two equivalent O(1) atoms. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 7°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to three equivalent K(1), one Li(1), and two equivalent W(1) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent K(1), one Li(1), and two equivalent W(1) atoms.
KLiWO3 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 10-coordinate geometry to one Li(1), three equivalent O(2), and six equivalent O(1) atoms. The K(1)-Li(1) bond length is 2.35 Å. There is one shorter (2.62 Å) and two longer (2.93 Å) K(1)-O(2) bond lengths. There are two shorter (2.63 Å) and four longer (2.93 Å) K(1)-O(1) bond lengths. Li(1) is bonded in a 3-coordinate geometry to one K(1), one O(2), and two equivalent O(1) atoms. The Li(1)-O(2) bond length is 1.87 Å. Both Li(1)-O(1) bond lengths are 1.89 Å. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form distorted corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 7°. There is one shorter (2.08 Å) and one longer (2.18 Å) W(1)-O(2) bond length. There are two shorter (2.07 Å) and two longer (2.17 Å) W(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to three equivalent K(1), one Li(1), and two equivalent W(1) atoms. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent K(1), one Li(1), and two equivalent W(1) atoms.