N2(PNO4F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and four PNO4F clusters. In each PNO4F cluster, P(1) is bonded in a distorted trigonal pyramidal geometry to one O(1), one O(2), one O(3), and one F(1) atom. N(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.
N2(PNO4F)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and four PNO4F clusters. In each PNO4F cluster, P(1) is bonded in a distorted trigonal pyramidal geometry to one O(1), one O(2), one O(3), and one F(1) atom. The P(1)-O(1) bond length is 1.47 Å. The P(1)-O(2) bond length is 1.47 Å. The P(1)-O(3) bond length is 2.25 Å. The P(1)-F(1) bond length is 1.57 Å. N(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. The N(2)-O(3) bond length is 1.23 Å. The N(2)-O(4) bond length is 1.19 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.