(DyN2O9)2(NO3)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, two trioxidane molecules, and two DyN2O9 clusters. In each DyN2O9 cluster, Dy(1) is bonded in a 1-coordinate geometry to one N(2), one O(10), one O(3), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(5) atom. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one O(2), one O(7), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one O(12) and one O(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Dy(1) and one O(1) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(9) is bonded in a distorted single-bond geometry to one Dy(1) and one N(2) atom. In the seventh O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one N(1) atom. In the eighth O site, O(11) is bonded in a single-bond geometry to one N(1) atom. In the ninth O site, O(12) is bonded in a single-bond geometry to one O(1) atom.
(DyN2O9)2(NO3)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, two trioxidane molecules, and two DyN2O9 clusters. In each DyN2O9 cluster, Dy(1) is bonded in a 1-coordinate geometry to one N(2), one O(10), one O(3), and one O(9) atom. The Dy(1)-N(2) bond length is 2.17 Å. The Dy(1)-O(10) bond length is 2.51 Å. The Dy(1)-O(3) bond length is 2.33 Å. The Dy(1)-O(9) bond length is 1.60 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(5) atom. The N(1)-O(10) bond length is 1.41 Å. The N(1)-O(11) bond length is 1.44 Å. The N(1)-O(5) bond length is 0.99 Å. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Dy(1), one O(2), one O(7), and one O(9) atom. The N(2)-O(2) bond length is 1.35 Å. The N(2)-O(7) bond length is 0.92 Å. The N(2)-O(9) bond length is 1.83 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one O(12) and one O(3) atom. The O(1)-O(12) bond length is 1.17 Å. The O(1)-O(3) bond length is 1.99 Å. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Dy(1) and one O(1) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(9) is bonded in a distorted single-bond geometry to one Dy(1) and one N(2) atom. In the seventh O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one N(1) atom. In the eighth O site, O(11) is bonded in a single-bond geometry to one N(1) atom. In the ninth O site, O(12) is bonded in a single-bond geometry to one O(1) atom.