Te(OH)6 crystallizes in the monoclinic P2_1/c space group. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(2) and one O(5) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(2) and one O(4) atom. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(3) and one O(5) atom. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Te site, Te(2) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one H(2), one H(4), and one Te(1) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one H(3), one H(5), and one Te(1) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to one H(3), one H(4), and one Te(2) atom. In the fourth O site, O(5) is bonded in a distorted trigonal planar geometry to one H(2), one H(5), and one Te(2) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one H(1), one H(6), and one Te(2) atom. In the sixth O site, O(1) is bonded in a distorted single-bond geometry to one H(1), one H(6), and one Te(1) atom.
Te(OH)6 crystallizes in the monoclinic P2_1/c space group. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. The H(1)-O(1) bond length is 1.00 Å. The H(1)-O(6) bond length is 1.67 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(2) and one O(5) atom. The H(2)-O(2) bond length is 1.00 Å. The H(2)-O(5) bond length is 1.63 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. The H(3)-O(3) bond length is 1.00 Å. The H(3)-O(4) bond length is 1.63 Å. In the fourth H site, H(4) is bonded in a distorted linear geometry to one O(2) and one O(4) atom. The H(4)-O(2) bond length is 1.63 Å. The H(4)-O(4) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(3) and one O(5) atom. The H(5)-O(3) bond length is 1.65 Å. The H(5)-O(5) bond length is 1.00 Å. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(1) and one O(6) atom. The H(6)-O(1) bond length is 1.64 Å. The H(6)-O(6) bond length is 1.00 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Te(1)-O(1) bond lengths are 1.92 Å. Both Te(1)-O(2) bond lengths are 1.91 Å. Both Te(1)-O(3) bond lengths are 1.92 Å. In the second Te site, Te(2) is bonded in an octahedral geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Both Te(2)-O(4) bond lengths are 1.92 Å. Both Te(2)-O(5) bond lengths are 1.92 Å. Both Te(2)-O(6) bond lengths are 1.92 Å. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one H(2), one H(4), and one Te(1) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one H(3), one H(5), and one Te(1) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to one H(3), one H(4), and one Te(2) atom. In the fourth O site, O(5) is bonded in a distorted trigonal planar geometry to one H(2), one H(5), and one Te(2) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one H(1), one H(6), and one Te(2) atom. In the sixth O site, O(1) is bonded in a distorted single-bond geometry to one H(1), one H(6), and one Te(1) atom.