FeNBr4(NS)4 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 293-40-3 molecules and four FeNBr4 clusters. In each FeNBr4 cluster, Fe(1) is bonded in a tetrahedral geometry to one Br(1), one Br(2), one Br(3), and one Br(4) atom. N(1) is bonded in a single-bond geometry to one Br(2) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Fe(1) atom. In the second Br site, Br(2) is bonded in a bent 120 degrees geometry to one Fe(1) and one N(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Fe(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Fe(1) atom.
FeNBr4(NS)4 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 293-40-3 molecules and four FeNBr4 clusters. In each FeNBr4 cluster, Fe(1) is bonded in a tetrahedral geometry to one Br(1), one Br(2), one Br(3), and one Br(4) atom. The Fe(1)-Br(1) bond length is 2.30 Å. The Fe(1)-Br(2) bond length is 2.71 Å. The Fe(1)-Br(3) bond length is 2.30 Å. The Fe(1)-Br(4) bond length is 2.29 Å. N(1) is bonded in a single-bond geometry to one Br(2) atom. The N(1)-Br(2) bond length is 1.79 Å. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Fe(1) atom. In the second Br site, Br(2) is bonded in a bent 120 degrees geometry to one Fe(1) and one N(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Fe(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Fe(1) atom.