PbN3S2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PbN3S2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one N(2), one N(3), and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1) and one S(2) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Pb(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Pb(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom.
PbN3S2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PbN3S2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one N(2), one N(3), and one S(1) atom. The Pb(1)-N(2) bond length is 2.27 Å. The Pb(1)-N(3) bond length is 2.40 Å. The Pb(1)-S(1) bond length is 2.75 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.66 Å. The N(1)-S(2) bond length is 1.62 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1) and one S(2) atom. The N(2)-S(2) bond length is 1.53 Å. In the third N site, N(3) is bonded in a single-bond geometry to one Pb(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Pb(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom.