Mg2Cu3Ge is Hexagonal Laves-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Mg(1) is bonded in a 12-coordinate geometry to nine equivalent Cu(1) and three equivalent Ge(1) atoms. Cu(1) is bonded to six equivalent Mg(1), four equivalent Cu(1), and two equivalent Ge(1) atoms to form CuMg6Cu4Ge2 cuboctahedra that share corners with four equivalent Ge(1)Mg6Cu6 cuboctahedra, corners with fourteen equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra, edges with six equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra, faces with six equivalent Ge(1)Mg6Cu6 cuboctahedra, and faces with twelve equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra. Ge(1) is bonded to six equivalent Mg(1) and six equivalent Cu(1) atoms to form GeMg6Cu6 cuboctahedra that share corners with twelve equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra, edges with six equivalent Ge(1)Mg6Cu6 cuboctahedra, faces with two equivalent Ge(1)Mg6Cu6 cuboctahedra, and faces with eighteen equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra.
Mg2Cu3Ge is Hexagonal Laves-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Mg(1) is bonded in a 12-coordinate geometry to nine equivalent Cu(1) and three equivalent Ge(1) atoms. There are three shorter (2.86 Å) and six longer (2.92 Å) Mg(1)-Cu(1) bond lengths. All Mg(1)-Ge(1) bond lengths are 2.94 Å. Cu(1) is bonded to six equivalent Mg(1), four equivalent Cu(1), and two equivalent Ge(1) atoms to form CuMg6Cu4Ge2 cuboctahedra that share corners with four equivalent Ge(1)Mg6Cu6 cuboctahedra, corners with fourteen equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra, edges with six equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra, faces with six equivalent Ge(1)Mg6Cu6 cuboctahedra, and faces with twelve equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra. There are two shorter (2.45 Å) and two longer (2.57 Å) Cu(1)-Cu(1) bond lengths. Both Cu(1)-Ge(1) bond lengths are 2.48 Å. Ge(1) is bonded to six equivalent Mg(1) and six equivalent Cu(1) atoms to form GeMg6Cu6 cuboctahedra that share corners with twelve equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra, edges with six equivalent Ge(1)Mg6Cu6 cuboctahedra, faces with two equivalent Ge(1)Mg6Cu6 cuboctahedra, and faces with eighteen equivalent Cu(1)Mg6Cu4Ge2 cuboctahedra.