PrS3(NO3)3 crystallizes in the hexagonal P6_3/m space group. Pr(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. N(1) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pr(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Pr(1) and one S(1) atom.
PrS3(NO3)3 crystallizes in the hexagonal P6_3/m space group. Pr(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. All Pr(1)-O(1) bond lengths are 2.62 Å. All Pr(1)-O(2) bond lengths are 2.48 Å. N(1) is bonded in a single-bond geometry to one S(1) atom. The N(1)-S(1) bond length is 1.66 Å. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. The S(1)-O(1) bond length is 1.46 Å. Both S(1)-O(2) bond lengths are 1.47 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pr(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Pr(1) and one S(1) atom.