PbWO4 crystallizes in the triclinic P-1 space group. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms.
PbWO4 crystallizes in the triclinic P-1 space group. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The W(1)-O(1) bond length is 1.83 Å. The W(1)-O(2) bond length is 1.83 Å. The W(1)-O(3) bond length is 1.83 Å. The W(1)-O(4) bond length is 1.82 Å. Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There is one shorter (2.61 Å) and one longer (2.71 Å) Pb(1)-O(1) bond length. There is one shorter (2.67 Å) and one longer (2.68 Å) Pb(1)-O(2) bond length. There is one shorter (2.62 Å) and one longer (2.64 Å) Pb(1)-O(3) bond length. There is one shorter (2.64 Å) and one longer (2.77 Å) Pb(1)-O(4) bond length. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one W(1) and two equivalent Pb(1) atoms.