Nb2CrB2 crystallizes in the tetragonal P4/mbm space group. Nb(1) is bonded in a 6-coordinate geometry to six equivalent B(1) atoms. Cr(1) is bonded in a distorted square co-planar geometry to four equivalent B(1) atoms. B(1) is bonded in a 9-coordinate geometry to six equivalent Nb(1), two equivalent Cr(1), and one B(1) atom.
Nb2CrB2 crystallizes in the tetragonal P4/mbm space group. Nb(1) is bonded in a 6-coordinate geometry to six equivalent B(1) atoms. There are two shorter (2.40 Å) and four longer (2.41 Å) Nb(1)-B(1) bond lengths. Cr(1) is bonded in a distorted square co-planar geometry to four equivalent B(1) atoms. All Cr(1)-B(1) bond lengths are 2.41 Å. B(1) is bonded in a 9-coordinate geometry to six equivalent Nb(1), two equivalent Cr(1), and one B(1) atom. The B(1)-B(1) bond length is 1.85 Å.