AgBiTe2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form AgTe6 octahedra that share corners with six equivalent Ag(1)Te6 octahedra, edges with four equivalent Ag(1)Te6 octahedra, and edges with eight equivalent Bi(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to two equivalent Te(2) and four equivalent Te(1) atoms to form BiTe6 octahedra that share corners with six equivalent Bi(1)Te6 octahedra, edges with four equivalent Bi(1)Te6 octahedra, and edges with eight equivalent Ag(1)Te6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent Ag(1) and four equivalent Bi(1) atoms to form TeAg2Bi4 octahedra that share corners with six equivalent Te(1)Ag2Bi4 octahedra, edges with four equivalent Te(1)Ag2Bi4 octahedra, and edges with eight equivalent Te(2)Ag4Bi2 octahedra. The corner-sharing octahedra are not tilted. In the second Te site, Te(2) is bonded to four equivalent Ag(1) and two equivalent Bi(1) atoms to form TeAg4Bi2 octahedra that share corners with six equivalent Te(2)Ag4Bi2 octahedra, edges with four equivalent Te(2)Ag4Bi2 octahedra, and edges with eight equivalent Te(1)Ag2Bi4 octahedra. The corner-sharing octahedra are not tilted.
AgBiTe2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form AgTe6 octahedra that share corners with six equivalent Ag(1)Te6 octahedra, edges with four equivalent Ag(1)Te6 octahedra, and edges with eight equivalent Bi(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Both Ag(1)-Te(1) bond lengths are 3.15 Å. All Ag(1)-Te(2) bond lengths are 3.10 Å. Bi(1) is bonded to two equivalent Te(2) and four equivalent Te(1) atoms to form BiTe6 octahedra that share corners with six equivalent Bi(1)Te6 octahedra, edges with four equivalent Bi(1)Te6 octahedra, and edges with eight equivalent Ag(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Both Bi(1)-Te(2) bond lengths are 3.15 Å. All Bi(1)-Te(1) bond lengths are 3.10 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent Ag(1) and four equivalent Bi(1) atoms to form TeAg2Bi4 octahedra that share corners with six equivalent Te(1)Ag2Bi4 octahedra, edges with four equivalent Te(1)Ag2Bi4 octahedra, and edges with eight equivalent Te(2)Ag4Bi2 octahedra. The corner-sharing octahedra are not tilted. In the second Te site, Te(2) is bonded to four equivalent Ag(1) and two equivalent Bi(1) atoms to form TeAg4Bi2 octahedra that share corners with six equivalent Te(2)Ag4Bi2 octahedra, edges with four equivalent Te(2)Ag4Bi2 octahedra, and edges with eight equivalent Te(1)Ag2Bi4 octahedra. The corner-sharing octahedra are not tilted.