Pr2Pd2Pb crystallizes in the tetragonal P4/mbm space group. Pr(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Pb(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Pr(1), one Pd(1), and two equivalent Pb(1) atoms. Pb(1) is bonded to eight equivalent Pr(1) and four equivalent Pd(1) atoms to form a mixture of face and corner-sharing PbPr8Pd4 cuboctahedra.
Pr2Pd2Pb crystallizes in the tetragonal P4/mbm space group. Pr(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Pb(1) atoms. There are two shorter (2.98 Å) and four longer (3.10 Å) Pr(1)-Pd(1) bond lengths. All Pr(1)-Pb(1) bond lengths are 3.52 Å. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Pr(1), one Pd(1), and two equivalent Pb(1) atoms. The Pd(1)-Pd(1) bond length is 2.78 Å. Both Pd(1)-Pb(1) bond lengths are 3.19 Å. Pb(1) is bonded to eight equivalent Pr(1) and four equivalent Pd(1) atoms to form a mixture of face and corner-sharing PbPr8Pd4 cuboctahedra.