K2Ag2GeS4 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. Ag(1) is bonded in a distorted linear geometry to four equivalent S(1) atoms. Ge(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Ag(1), and one Ge(1) atom.
K2Ag2GeS4 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. There are a spread of K(1)-S(1) bond distances ranging from 3.27-3.49 Å. Ag(1) is bonded in a distorted linear geometry to four equivalent S(1) atoms. There are two shorter (2.43 Å) and two longer (3.20 Å) Ag(1)-S(1) bond lengths. Ge(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All Ge(1)-S(1) bond lengths are 2.26 Å. S(1) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Ag(1), and one Ge(1) atom.