LiMnF3 is Calcite structured and crystallizes in the trigonal R-3c space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. Mn(1) is bonded to six equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles are 45°. F(1) is bonded in a trigonal planar geometry to one Li(1) and two equivalent Mn(1) atoms.
LiMnF3 is Calcite structured and crystallizes in the trigonal R-3c space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. All Li(1)-F(1) bond lengths are 1.88 Å. Mn(1) is bonded to six equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles are 45°. All Mn(1)-F(1) bond lengths are 2.15 Å. F(1) is bonded in a trigonal planar geometry to one Li(1) and two equivalent Mn(1) atoms.