WO2F is alpha Rhenium trioxide-derived structured and crystallizes in the monoclinic Cc space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form corner-sharing WO4F2 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent W(1) atoms. F(1) is bonded in a linear geometry to two equivalent W(1) atoms.
WO2F is alpha Rhenium trioxide-derived structured and crystallizes in the monoclinic Cc space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form corner-sharing WO4F2 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. There is one shorter (1.90 Å) and one longer (1.98 Å) W(1)-O(1) bond length. There is one shorter (1.91 Å) and one longer (1.92 Å) W(1)-O(2) bond length. There is one shorter (2.12 Å) and one longer (2.13 Å) W(1)-F(1) bond length. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent W(1) atoms. F(1) is bonded in a linear geometry to two equivalent W(1) atoms.