Li4V2Mn3Fe3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-65°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-64°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the second V site, V(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-50°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Fe(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Fe site, Fe(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Fe(3) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one Fe(1), and one Fe(2) atom to form a mixture of distorted edge and corner-sharing OLiVFe2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Mn(1), one Fe(1), and one Fe(2) atom to form distorted OLiMnFe2 trigonal pyramids that share  a cornercorner with one O(11)LiMnVFe tetrahedra,  a cornercorner with one O(12)LiMnVFe tetrahedra, corners with three equivalent O(4)LiMnFe2 tetrahedra,  a cornercorner with one O(15)LiMn2V trigonal pyramid, and  an edgeedge with one O(2)LiVFe2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), one Fe(1), and one Fe(2) atom to form OLiMnFe2 tetrahedra that share corners with two equivalent O(2)LiVFe2 tetrahedra and corners with three equivalent O(3)LiMnFe2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Mn(2), one Mn(3), and one Fe(3) atom to form OLiMn2Fe tetrahedra that share corners with two equivalent O(11)LiMnVFe tetrahedra, corners with two equivalent O(12)LiMnVFe tetrahedra, and corners with two equivalent O(15)LiMn2V trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(3), and one Fe(3) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Mn(1), and one Fe(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Mn(1), and one Fe(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Fe(1), and one Fe(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Mn(2), and one Fe(3) atom to form distorted OLiMnVFe tetrahedra that share  a cornercorner with one O(12)LiMnVFe tetrahedra, corners with two equivalent O(5)LiMn2Fe tetrahedra,  a cornercorner with one O(15)LiMn2V trigonal pyramid,  a cornercorner with one O(3)LiMnFe2 trigonal pyramid,  an edgeedge with one O(12)LiMnVFe tetrahedra, and  an edgeedge with one O(15)LiMn2V trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Mn(3), and one Fe(3) atom to form distorted OLiMnVFe tetrahedra that share  a cornercorner with one O(11)LiMnVFe tetrahedra, corners with two equivalent O(5)LiMn2Fe tetrahedra,  a cornercorner with one O(15)LiMn2V trigonal pyramid,  a cornercorner with one O(3)LiMnFe2 trigonal pyramid,  an edgeedge with one O(11)LiMnVFe tetrahedra, and  an edgeedge with one O(15)LiMn2V trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(2), one Mn(3), and one Fe(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Fe(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one Mn(2), and one Mn(3) atom to form distorted OLiMn2V trigonal pyramids that share  a cornercorner with one O(11)LiMnVFe tetrahedra,  a cornercorner with one O(12)LiMnVFe tetrahedra, corners with two equivalent O(5)LiMn2Fe tetrahedra,  a cornercorner with one O(3)LiMnFe2 trigonal pyramid,  an edgeedge with one O(11)LiMnVFe tetrahedra, and  an edgeedge with one O(12)LiMnVFe tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Fe(2) atom.
Li4V2Mn3Fe3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. The Li(1)-O(11) bond length is 2.00 Å. The Li(1)-O(12) bond length is 1.98 Å. The Li(1)-O(15) bond length is 1.99 Å. The Li(1)-O(3) bond length is 1.97 Å. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-65°. The Li(2)-O(14) bond length is 1.97 Å. The Li(2)-O(16) bond length is 1.98 Å. The Li(2)-O(5) bond length is 1.80 Å. The Li(2)-O(9) bond length is 2.00 Å. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 59-64°. The Li(3)-O(1) bond length is 1.98 Å. The Li(3)-O(10) bond length is 1.98 Å. The Li(3)-O(4) bond length is 1.79 Å. The Li(3)-O(6) bond length is 1.97 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, and corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. The Li(4)-O(13) bond length is 2.00 Å. The Li(4)-O(2) bond length is 1.96 Å. The Li(4)-O(7) bond length is 2.03 Å. The Li(4)-O(8) bond length is 2.00 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-54°. The V(1)-O(1) bond length is 2.03 Å. The V(1)-O(10) bond length is 1.88 Å. The V(1)-O(2) bond length is 1.96 Å. The V(1)-O(6) bond length is 2.00 Å. The V(1)-O(7) bond length is 2.06 Å. The V(1)-O(8) bond length is 2.08 Å. In the second V site, V(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. The V(2)-O(11) bond length is 2.04 Å. The V(2)-O(12) bond length is 2.01 Å. The V(2)-O(14) bond length is 2.01 Å. The V(2)-O(15) bond length is 2.02 Å. The V(2)-O(16) bond length is 2.00 Å. The V(2)-O(9) bond length is 1.92 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-50°. The Mn(1)-O(14) bond length is 2.02 Å. The Mn(1)-O(16) bond length is 2.04 Å. The Mn(1)-O(3) bond length is 1.92 Å. The Mn(1)-O(4) bond length is 1.91 Å. The Mn(1)-O(7) bond length is 1.95 Å. The Mn(1)-O(8) bond length is 1.94 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Fe(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-50°. The Mn(2)-O(1) bond length is 2.01 Å. The Mn(2)-O(10) bond length is 2.04 Å. The Mn(2)-O(11) bond length is 1.94 Å. The Mn(2)-O(13) bond length is 1.92 Å. The Mn(2)-O(15) bond length is 1.92 Å. The Mn(2)-O(5) bond length is 1.92 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-54°. The Mn(3)-O(10) bond length is 2.27 Å. The Mn(3)-O(12) bond length is 1.98 Å. The Mn(3)-O(13) bond length is 1.95 Å. The Mn(3)-O(15) bond length is 2.21 Å. The Mn(3)-O(5) bond length is 1.94 Å. The Mn(3)-O(6) bond length is 1.98 Å. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-52°. The Fe(1)-O(14) bond length is 2.08 Å. The Fe(1)-O(2) bond length is 2.04 Å. The Fe(1)-O(3) bond length is 1.99 Å. The Fe(1)-O(4) bond length is 1.97 Å. The Fe(1)-O(7) bond length is 2.07 Å. The Fe(1)-O(9) bond length is 2.10 Å. In the second Fe site, Fe(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-52°. The Fe(2)-O(16) bond length is 2.07 Å. The Fe(2)-O(2) bond length is 2.05 Å. The Fe(2)-O(3) bond length is 2.00 Å. The Fe(2)-O(4) bond length is 1.98 Å. The Fe(2)-O(8) bond length is 2.05 Å. The Fe(2)-O(9) bond length is 2.09 Å. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. The Fe(3)-O(1) bond length is 2.08 Å. The Fe(3)-O(11) bond length is 2.06 Å. The Fe(3)-O(12) bond length is 2.05 Å. The Fe(3)-O(13) bond length is 2.00 Å. The Fe(3)-O(5) bond length is 1.99 Å. The Fe(3)-O(6) bond length is 2.06 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Fe(3) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one Fe(1), and one Fe(2) atom to form a mixture of distorted edge and corner-sharing OLiVFe2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Mn(1), one Fe(1), and one Fe(2) atom to form distorted OLiMnFe2 trigonal pyramids that share  a cornercorner with one O(11)LiMnVFe tetrahedra,  a cornercorner with one O(12)LiMnVFe tetrahedra, corners with three equivalent O(4)LiMnFe2 tetrahedra,  a cornercorner with one O(15)LiMn2V trigonal pyramid, and  an edgeedge with one O(2)LiVFe2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), one Fe(1), and one Fe(2) atom to form OLiMnFe2 tetrahedra that share corners with two equivalent O(2)LiVFe2 tetrahedra and corners with three equivalent O(3)LiMnFe2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Mn(2), one Mn(3), and one Fe(3) atom to form OLiMn2Fe tetrahedra that share corners with two equivalent O(11)LiMnVFe tetrahedra, corners with two equivalent O(12)LiMnVFe tetrahedra, and corners with two equivalent O(15)LiMn2V trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(3), and one Fe(3) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Mn(1), and one Fe(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Mn(1), and one Fe(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Fe(1), and one Fe(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(2), one Mn(2), and one Fe(3) atom to form distorted OLiMnVFe tetrahedra that share  a cornercorner with one O(12)LiMnVFe tetrahedra, corners with two equivalent O(5)LiMn2Fe tetrahedra,  a cornercorner with one O(15)LiMn2V trigonal pyramid,  a cornercorner with one O(3)LiMnFe2 trigonal pyramid,  an edgeedge with one O(12)LiMnVFe tetrahedra, and  an edgeedge with one O(15)LiMn2V trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), one Mn(3), and one Fe(3) atom to form distorted OLiMnVFe tetrahedra that share  a cornercorner with one O(11)LiMnVFe tetrahedra, corners with two equivalent O(5)LiMn2Fe tetrahedra,  a cornercorner with one O(15)LiMn2V trigonal pyramid,  a cornercorner with one O(3)LiMnFe2 trigonal pyramid,  an edgeedge with one O(11)LiMnVFe tetrahedra, and  an edgeedge with one O(15)LiMn2V trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(2), one Mn(3), and one Fe(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Fe(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one V(2), one Mn(2), and one Mn(3) atom to form distorted OLiMn2V trigonal pyramids that share  a cornercorner with one O(11)LiMnVFe tetrahedra,  a cornercorner with one O(12)LiMnVFe tetrahedra, corners with two equivalent O(5)LiMn2Fe tetrahedra,  a cornercorner with one O(3)LiMnFe2 trigonal pyramid,  an edgeedge with one O(11)LiMnVFe tetrahedra, and  an edgeedge with one O(12)LiMnVFe tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Fe(2) atom.