CoPbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Co(1) is bonded to six equivalent O(1) atoms to form distorted CoO6 octahedra that share corners with nine equivalent Pb(1)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with nine equivalent Co(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. O(1) is bonded to two equivalent Co(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OCo2Pb2 trigonal pyramids.
CoPbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Co(1) is bonded to six equivalent O(1) atoms to form distorted CoO6 octahedra that share corners with nine equivalent Pb(1)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. There are three shorter (2.08 Å) and three longer (2.20 Å) Co(1)-O(1) bond lengths. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with nine equivalent Co(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. There are three shorter (2.17 Å) and three longer (2.33 Å) Pb(1)-O(1) bond lengths. O(1) is bonded to two equivalent Co(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OCo2Pb2 trigonal pyramids.