V2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form edge-sharing VO4F2 octahedra. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(1), four equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a 3-coordinate geometry to one V(2) and two equivalent V(1) atoms.
V2O3F is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form edge-sharing VO4F2 octahedra. Both V(1)-O(1) bond lengths are 1.98 Å. Both V(1)-O(2) bond lengths are 1.91 Å. Both V(1)-F(1) bond lengths are 2.00 Å. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(1), four equivalent O(2), and one F(1) atom. The V(2)-O(1) bond length is 1.75 Å. All V(2)-O(2) bond lengths are 1.95 Å. The V(2)-F(1) bond length is 2.40 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(2) atoms. F(1) is bonded in a 3-coordinate geometry to one V(2) and two equivalent V(1) atoms.