Zn(RhZn(CN)6)2 is alpha Rhenium trioxide-derived structured and crystallizes in the tetragonal P-4m2 space group. The structure consists of one 7440-66-6 atom inside a RhZn(CN)6 framework. In the RhZn(CN)6 framework, Rh(1) is bonded in an octahedral geometry to one C(1), one C(2), and four equivalent C(3) atoms. Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), and four equivalent N(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Rh(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Rh(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Rh(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(3) atom.
Zn(RhZn(CN)6)2 is alpha Rhenium trioxide-derived structured and crystallizes in the tetragonal P-4m2 space group. The structure consists of one 7440-66-6 atom inside a RhZn(CN)6 framework. In the RhZn(CN)6 framework, Rh(1) is bonded in an octahedral geometry to one C(1), one C(2), and four equivalent C(3) atoms. The Rh(1)-C(1) bond length is 2.01 Å. The Rh(1)-C(2) bond length is 2.01 Å. All Rh(1)-C(3) bond lengths are 2.01 Å. Zn(1) is bonded in an octahedral geometry to one N(1), one N(2), and four equivalent N(3) atoms. The Zn(1)-N(1) bond length is 2.17 Å. The Zn(1)-N(2) bond length is 2.11 Å. All Zn(1)-N(3) bond lengths are 2.14 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Rh(1) and one N(1) atom. The C(1)-N(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a linear geometry to one Rh(1) and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. In the third C site, C(3) is bonded in a linear geometry to one Rh(1) and one N(3) atom. The C(3)-N(3) bond length is 1.17 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Zn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Zn(1) and one C(3) atom.