MnRhP crystallizes in the hexagonal P-62m space group. Mn(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1), one P(2), and four equivalent P(1) atoms. Rh(1) is bonded in a 10-coordinate geometry to six equivalent Mn(1), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Mn(1) and three equivalent Rh(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Mn(1) and six equivalent Rh(1) atoms.
MnRhP crystallizes in the hexagonal P-62m space group. Mn(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1), one P(2), and four equivalent P(1) atoms. There are two shorter (2.75 Å) and four longer (2.79 Å) Mn(1)-Rh(1) bond lengths. The Mn(1)-P(2) bond length is 2.37 Å. All Mn(1)-P(1) bond lengths are 2.60 Å. Rh(1) is bonded in a 10-coordinate geometry to six equivalent Mn(1), two equivalent P(1), and two equivalent P(2) atoms. Both Rh(1)-P(1) bond lengths are 2.23 Å. Both Rh(1)-P(2) bond lengths are 2.43 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Mn(1) and three equivalent Rh(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Mn(1) and six equivalent Rh(1) atoms.