Sr5La3Mn4(WO6)4 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(13), one O(16), one O(18), one O(21), one O(22), one O(3), and one O(8) atom. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(12), one O(19), one O(2), one O(22), one O(23), one O(24), one O(5), one O(7), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(2), one O(20), one O(21), one O(24), one O(6), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(1), one O(13), one O(17), one O(18), one O(2), one O(20), one O(23), one O(3), and one O(6) atom. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(10), one O(14), one O(15), one O(16), one O(17), one O(19), one O(20), one O(4), and one O(7) atom. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(18), one O(21), one O(8), and one O(9) atom. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(16), one O(19), one O(23), one O(4), and one O(5) atom. In the third La site, La(3) is bonded in a 6-coordinate geometry to one O(12), one O(15), one O(17), one O(22), one O(24), and one O(7) atom. There are four inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(17), one O(19), one O(24), one O(6), and one O(8) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-33°. In the second W site, W(2) is bonded to one O(12), one O(14), one O(15), one O(2), one O(21), and one O(3) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-34°. In the third W site, W(3) is bonded to one O(16), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-32°. In the fourth W site, W(4) is bonded to one O(10), one O(11), one O(13), one O(22), one O(23), and one O(4) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(14), one O(23), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and corners with two equivalent W(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-32°. In the second Mn site, Mn(2) is bonded to one O(1), one O(20), one O(21), one O(24), one O(4), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, corners with two equivalent W(1)O6 octahedra, and corners with two equivalent W(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-34°. In the third Mn site, Mn(3) is bonded to one O(11), one O(15), one O(18), one O(19), one O(2), and one O(22) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and corners with two equivalent W(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-33°. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(13), one O(16), one O(17), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, corners with two equivalent W(1)O6 octahedra, and corners with two equivalent W(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-29°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(4), one La(2), one W(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one W(2), and one Mn(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(4), one W(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(5), one La(2), one W(4), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), one W(3), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(4), one W(1), and one Mn(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Sr(2), one Sr(5), one La(3), one W(3), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), one La(1), one W(1), and one Mn(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(3), and one Mn(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(5), one La(1), one W(4), and one Mn(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(4), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Sr(2), one La(3), one W(2), and one Mn(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one W(4), and one Mn(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(5), one La(2), one W(2), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Sr(5), one La(3), one W(2), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(5), one La(2), one W(3), and one Mn(4) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Sr(4), one Sr(5), one La(3), one W(1), and one Mn(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(4), one La(1), one W(3), and one Mn(3) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Sr(2), one Sr(5), one La(2), one W(1), and one Mn(3) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(4), one Sr(5), one W(3), and one Mn(2) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the twenty-second O site, O(22) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), one La(3), one W(4), and one Mn(3) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one La(2), one W(4), and one Mn(1) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one La(3), one W(1), and one Mn(2) atom.
Sr5La3Mn4(WO6)4 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(13), one O(16), one O(18), one O(21), one O(22), one O(3), and one O(8) atom. The Sr(1)-O(1) bond length is 2.55 Å. The Sr(1)-O(10) bond length is 2.67 Å. The Sr(1)-O(13) bond length is 2.77 Å. The Sr(1)-O(16) bond length is 3.05 Å. The Sr(1)-O(18) bond length is 2.48 Å. The Sr(1)-O(21) bond length is 3.14 Å. The Sr(1)-O(22) bond length is 3.09 Å. The Sr(1)-O(3) bond length is 2.56 Å. The Sr(1)-O(8) bond length is 2.65 Å. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(12), one O(19), one O(2), one O(22), one O(23), one O(24), one O(5), one O(7), and one O(8) atom. The Sr(2)-O(12) bond length is 2.50 Å. The Sr(2)-O(19) bond length is 2.79 Å. The Sr(2)-O(2) bond length is 3.11 Å. The Sr(2)-O(22) bond length is 2.65 Å. The Sr(2)-O(23) bond length is 2.58 Å. The Sr(2)-O(24) bond length is 2.64 Å. The Sr(2)-O(5) bond length is 2.51 Å. The Sr(2)-O(7) bond length is 3.08 Å. The Sr(2)-O(8) bond length is 3.06 Å. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(2), one O(20), one O(21), one O(24), one O(6), and one O(9) atom. The Sr(3)-O(11) bond length is 2.54 Å. The Sr(3)-O(13) bond length is 3.08 Å. The Sr(3)-O(14) bond length is 3.09 Å. The Sr(3)-O(2) bond length is 2.65 Å. The Sr(3)-O(20) bond length is 2.64 Å. The Sr(3)-O(21) bond length is 2.87 Å. The Sr(3)-O(24) bond length is 3.08 Å. The Sr(3)-O(6) bond length is 2.48 Å. The Sr(3)-O(9) bond length is 2.55 Å. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(1), one O(13), one O(17), one O(18), one O(2), one O(20), one O(23), one O(3), and one O(6) atom. The Sr(4)-O(1) bond length is 2.68 Å. The Sr(4)-O(13) bond length is 2.49 Å. The Sr(4)-O(17) bond length is 3.13 Å. The Sr(4)-O(18) bond length is 3.14 Å. The Sr(4)-O(2) bond length is 2.59 Å. The Sr(4)-O(20) bond length is 2.52 Å. The Sr(4)-O(23) bond length is 3.21 Å. The Sr(4)-O(3) bond length is 2.64 Å. The Sr(4)-O(6) bond length is 2.80 Å. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(10), one O(14), one O(15), one O(16), one O(17), one O(19), one O(20), one O(4), and one O(7) atom. The Sr(5)-O(10) bond length is 3.08 Å. The Sr(5)-O(14) bond length is 2.66 Å. The Sr(5)-O(15) bond length is 2.59 Å. The Sr(5)-O(16) bond length is 2.62 Å. The Sr(5)-O(17) bond length is 2.53 Å. The Sr(5)-O(19) bond length is 3.17 Å. The Sr(5)-O(20) bond length is 3.05 Å. The Sr(5)-O(4) bond length is 2.48 Å. The Sr(5)-O(7) bond length is 2.84 Å. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(18), one O(21), one O(8), and one O(9) atom. The La(1)-O(10) bond length is 2.44 Å. The La(1)-O(11) bond length is 2.49 Å. The La(1)-O(18) bond length is 2.78 Å. The La(1)-O(21) bond length is 2.46 Å. The La(1)-O(8) bond length is 2.41 Å. The La(1)-O(9) bond length is 2.51 Å. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(16), one O(19), one O(23), one O(4), and one O(5) atom. The La(2)-O(1) bond length is 2.93 Å. The La(2)-O(14) bond length is 2.54 Å. The La(2)-O(16) bond length is 2.43 Å. The La(2)-O(19) bond length is 2.42 Å. The La(2)-O(23) bond length is 2.49 Å. The La(2)-O(4) bond length is 2.70 Å. The La(2)-O(5) bond length is 2.50 Å. In the third La site, La(3) is bonded in a 6-coordinate geometry to one O(12), one O(15), one O(17), one O(22), one O(24), and one O(7) atom. The La(3)-O(12) bond length is 2.78 Å. The La(3)-O(15) bond length is 2.60 Å. The La(3)-O(17) bond length is 2.51 Å. The La(3)-O(22) bond length is 2.43 Å. The La(3)-O(24) bond length is 2.43 Å. The La(3)-O(7) bond length is 2.40 Å. There are four inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(17), one O(19), one O(24), one O(6), and one O(8) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-33°. The W(1)-O(1) bond length is 2.03 Å. The W(1)-O(17) bond length is 2.04 Å. The W(1)-O(19) bond length is 2.00 Å. The W(1)-O(24) bond length is 2.05 Å. The W(1)-O(6) bond length is 1.94 Å. The W(1)-O(8) bond length is 2.04 Å. In the second W site, W(2) is bonded to one O(12), one O(14), one O(15), one O(2), one O(21), and one O(3) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-34°. The W(2)-O(12) bond length is 1.94 Å. The W(2)-O(14) bond length is 1.97 Å. The W(2)-O(15) bond length is 1.97 Å. The W(2)-O(2) bond length is 1.94 Å. The W(2)-O(21) bond length is 1.97 Å. The W(2)-O(3) bond length is 1.95 Å. In the third W site, W(3) is bonded to one O(16), one O(18), one O(20), one O(5), one O(7), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-32°. The W(3)-O(16) bond length is 2.05 Å. The W(3)-O(18) bond length is 1.98 Å. The W(3)-O(20) bond length is 1.99 Å. The W(3)-O(5) bond length is 2.01 Å. The W(3)-O(7) bond length is 2.04 Å. The W(3)-O(9) bond length is 2.03 Å. In the fourth W site, W(4) is bonded to one O(10), one O(11), one O(13), one O(22), one O(23), and one O(4) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-29°. The W(4)-O(10) bond length is 2.04 Å. The W(4)-O(11) bond length is 2.05 Å. The W(4)-O(13) bond length is 1.95 Å. The W(4)-O(22) bond length is 2.05 Å. The W(4)-O(23) bond length is 2.05 Å. The W(4)-O(4) bond length is 1.96 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(14), one O(23), one O(3), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and corners with two equivalent W(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-32°. The Mn(1)-O(10) bond length is 2.13 Å. The Mn(1)-O(14) bond length is 2.25 Å. The Mn(1)-O(23) bond length is 2.14 Å. The Mn(1)-O(3) bond length is 2.23 Å. The Mn(1)-O(6) bond length is 2.23 Å. The Mn(1)-O(7) bond length is 2.21 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(20), one O(21), one O(24), one O(4), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, corners with two equivalent W(1)O6 octahedra, and corners with two equivalent W(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-34°. The Mn(2)-O(1) bond length is 2.15 Å. The Mn(2)-O(20) bond length is 2.18 Å. The Mn(2)-O(21) bond length is 2.25 Å. The Mn(2)-O(24) bond length is 2.16 Å. The Mn(2)-O(4) bond length is 2.25 Å. The Mn(2)-O(5) bond length is 2.20 Å. In the third Mn site, Mn(3) is bonded to one O(11), one O(15), one O(18), one O(19), one O(2), and one O(22) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, corners with two equivalent W(2)O6 octahedra, and corners with two equivalent W(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-33°. The Mn(3)-O(11) bond length is 2.16 Å. The Mn(3)-O(15) bond length is 2.22 Å. The Mn(3)-O(18) bond length is 2.18 Å. The Mn(3)-O(19) bond length is 2.23 Å. The Mn(3)-O(2) bond length is 2.21 Å. The Mn(3)-O(22) bond length is 2.17 Å. In the fourth Mn site, Mn(4) is bonded to one O(12), one O(13), one O(16), one O(17), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, corners with two equivalent W(1)O6 octahedra, and corners with two equivalent W(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-29°. The Mn(4)-O(12) bond length is 2.23 Å. The Mn(4)-O(13) bond length is 2.24 Å. The Mn(4)-O(16) bond length is 2.16 Å. The Mn(4)-O(17) bond length is 2.16 Å. The Mn(4)-O(8) bond length is 2.16 Å. The Mn(4)-O(9) bond length is 2.17 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(4), one La(2), one W(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one W(2), and one Mn(3) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(4), one W(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(5), one La(2), one W(4), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(2), one La(2), one W(3), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(4), one W(1), and one Mn(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Sr(2), one Sr(5), one La(3), one W(3), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), one La(1), one W(1), and one Mn(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(3), and one Mn(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(5), one La(1), one W(4), and one Mn(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(4), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Sr(2), one La(3), one W(2), and one Mn(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one W(4), and one Mn(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(5), one La(2), one W(2), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Sr(5), one La(3), one W(2), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(5), one La(2), one W(3), and one Mn(4) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Sr(4), one Sr(5), one La(3), one W(1), and one Mn(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(4), one La(1), one W(3), and one Mn(3) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Sr(2), one Sr(5), one La(2), one W(1), and one Mn(3) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(4), one Sr(5), one W(3), and one Mn(2) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Sr(1), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the twenty-second O site, O(22) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(2), one La(3), one W(4), and one Mn(3) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one La(2), one W(4), and one Mn(1) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one La(3), one W(1), and one Mn(2) atom.