CdS18(N2O)6(AsF6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and one CdS18(N2O)6 cluster. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the CdS18(N2O)6 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(5) and one S(8) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(4) and one S(6) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(5) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one S(2) and one S(9) atom. There are nine inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(5) and one O(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(2) and one N(6) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one N(1) and one N(5) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one N(3) and one N(4) atom. In the seventh S site, S(7) is bonded in a distorted water-like geometry to one N(3) and one O(3) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one N(1) atom. In the ninth S site, S(9) is bonded in a distorted water-like geometry to one N(6) and one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(1) and one S(9) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Cd(1) and one S(7) atom.
CdS18(N2O)6(AsF6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and one CdS18(N2O)6 cluster. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.78 Å. The As(1)-F(2) bond length is 1.79 Å. The As(1)-F(3) bond length is 1.78 Å. The As(1)-F(4) bond length is 1.78 Å. The As(1)-F(5) bond length is 1.78 Å. The As(1)-F(6) bond length is 1.78 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the CdS18(N2O)6 cluster, Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Cd(1)-O(1) bond lengths are 2.34 Å. Both Cd(1)-O(2) bond lengths are 2.33 Å. Both Cd(1)-O(3) bond lengths are 2.33 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(5) and one S(8) atom. The N(1)-S(5) bond length is 1.57 Å. The N(1)-S(8) bond length is 1.61 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(2)-S(2) bond length is 1.57 Å. The N(2)-S(3) bond length is 1.61 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. The N(3)-S(6) bond length is 1.60 Å. The N(3)-S(7) bond length is 1.63 Å. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(4) and one S(6) atom. The N(4)-S(4) bond length is 1.61 Å. The N(4)-S(6) bond length is 1.57 Å. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one S(1) and one S(5) atom. The N(5)-S(1) bond length is 1.62 Å. The N(5)-S(5) bond length is 1.60 Å. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one S(2) and one S(9) atom. The N(6)-S(2) bond length is 1.60 Å. The N(6)-S(9) bond length is 1.62 Å. There are nine inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(5) and one O(1) atom. The S(1)-O(1) bond length is 1.51 Å. In the second S site, S(2) is bonded in a water-like geometry to one N(2) and one N(6) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one N(1) and one N(5) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one N(3) and one N(4) atom. In the seventh S site, S(7) is bonded in a distorted water-like geometry to one N(3) and one O(3) atom. The S(7)-O(3) bond length is 1.50 Å. In the eighth S site, S(8) is bonded in a single-bond geometry to one N(1) atom. In the ninth S site, S(9) is bonded in a distorted water-like geometry to one N(6) and one O(2) atom. The S(9)-O(2) bond length is 1.51 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(1) and one S(9) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Cd(1) and one S(7) atom.