Sn3As2F15AsF6 is Indium-derived structured and crystallizes in the trigonal R32 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three Sn3As2F15 clusters. In each AsF6 cluster, As(2) is bonded in an octahedral geometry to six equivalent F(3) atoms. F(3) is bonded in a single-bond geometry to one As(2) atom. In each Sn3As2F15 cluster, Sn(1) is bonded in a distorted L-shaped geometry to two equivalent F(1) and two equivalent F(2) atoms. As(1) is bonded in an octahedral geometry to three equivalent F(2) and three equivalent F(4) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Sn(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Sn(1) and one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom.
Sn3As2F15AsF6 is Indium-derived structured and crystallizes in the trigonal R32 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three Sn3As2F15 clusters. In each AsF6 cluster, As(2) is bonded in an octahedral geometry to six equivalent F(3) atoms. All As(2)-F(3) bond lengths are 1.78 Å. F(3) is bonded in a single-bond geometry to one As(2) atom. In each Sn3As2F15 cluster, Sn(1) is bonded in a distorted L-shaped geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Sn(1)-F(1) bond lengths are 2.14 Å. Both Sn(1)-F(2) bond lengths are 2.59 Å. As(1) is bonded in an octahedral geometry to three equivalent F(2) and three equivalent F(4) atoms. All As(1)-F(2) bond lengths are 1.79 Å. All As(1)-F(4) bond lengths are 1.76 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Sn(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Sn(1) and one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom.