SrN6 crystallizes in the orthorhombic Fddd space group. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to two equivalent Sr(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to two equivalent N(1) atoms.
SrN6 crystallizes in the orthorhombic Fddd space group. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent N(1) atoms. There are four shorter (2.68 Å) and four longer (2.72 Å) Sr(1)-N(1) bond lengths. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to two equivalent Sr(1) and one N(2) atom. The N(1)-N(2) bond length is 1.18 Å. In the second N site, N(2) is bonded in a linear geometry to two equivalent N(1) atoms.