ScAsO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Sc(1) is bonded to twelve equivalent O(1) atoms to form ScO12 cuboctahedra that share corners with twelve equivalent Sc(1)O12 cuboctahedra, faces with six equivalent Sc(1)O12 cuboctahedra, and faces with eight equivalent As(1)O6 octahedra. As(1) is bonded to six equivalent O(1) atoms to form AsO6 octahedra that share corners with six equivalent As(1)O6 octahedra and faces with eight equivalent Sc(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Sc(1) and two equivalent As(1) atoms to form a mixture of distorted edge, corner, and face-sharing OSc4As2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
ScAsO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Sc(1) is bonded to twelve equivalent O(1) atoms to form ScO12 cuboctahedra that share corners with twelve equivalent Sc(1)O12 cuboctahedra, faces with six equivalent Sc(1)O12 cuboctahedra, and faces with eight equivalent As(1)O6 octahedra. All Sc(1)-O(1) bond lengths are 2.79 Å. As(1) is bonded to six equivalent O(1) atoms to form AsO6 octahedra that share corners with six equivalent As(1)O6 octahedra and faces with eight equivalent Sc(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All As(1)-O(1) bond lengths are 1.97 Å. O(1) is bonded to four equivalent Sc(1) and two equivalent As(1) atoms to form a mixture of distorted edge, corner, and face-sharing OSc4As2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.