LiSbWO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. Li(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. W(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one W(1) atom.
LiSbWO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. Li(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. Both Li(1)-O(1) bond lengths are 2.31 Å. There are two shorter (2.12 Å) and two longer (2.16 Å) Li(1)-O(3) bond lengths. W(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both W(1)-O(1) bond lengths are 1.95 Å. Both W(1)-O(2) bond lengths are 2.33 Å. Both W(1)-O(3) bond lengths are 1.78 Å. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. Both Sb(1)-O(1) bond lengths are 2.01 Å. There are two shorter (2.01 Å) and two longer (2.04 Å) Sb(1)-O(2) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one W(1) atom.