Na2AuSb crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Au(1) and four equivalent Sb(1) atoms. Au(1) is bonded in a 12-coordinate geometry to eight equivalent Na(1), two equivalent Au(1), and two equivalent Sb(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to eight equivalent Na(1) and two equivalent Au(1) atoms.
Na2AuSb crystallizes in the orthorhombic Cmcm space group. Na(1) is bonded in a 8-coordinate geometry to four equivalent Au(1) and four equivalent Sb(1) atoms. There are two shorter (3.35 Å) and two longer (3.55 Å) Na(1)-Au(1) bond lengths. There are a spread of Na(1)-Sb(1) bond distances ranging from 3.14-3.39 Å. Au(1) is bonded in a 12-coordinate geometry to eight equivalent Na(1), two equivalent Au(1), and two equivalent Sb(1) atoms. Both Au(1)-Au(1) bond lengths are 2.95 Å. Both Au(1)-Sb(1) bond lengths are 2.67 Å. Sb(1) is bonded in a 10-coordinate geometry to eight equivalent Na(1) and two equivalent Au(1) atoms.