NdRhSn crystallizes in the hexagonal P-62m space group. Nd(1) is bonded in a 11-coordinate geometry to one Rh(1), four equivalent Rh(2), and six equivalent Sn(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to three equivalent Nd(1) and six equivalent Sn(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent Sn(1) atoms. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.
NdRhSn crystallizes in the hexagonal P-62m space group. Nd(1) is bonded in a 11-coordinate geometry to one Rh(1), four equivalent Rh(2), and six equivalent Sn(1) atoms. The Nd(1)-Rh(1) bond length is 3.08 Å. All Nd(1)-Rh(2) bond lengths are 3.06 Å. There are two shorter (3.27 Å) and four longer (3.40 Å) Nd(1)-Sn(1) bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to three equivalent Nd(1) and six equivalent Sn(1) atoms. All Rh(1)-Sn(1) bond lengths are 2.79 Å. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent Sn(1) atoms. All Rh(2)-Sn(1) bond lengths are 2.85 Å. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.