AsTe(BrF2)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AsTe(BrF2)3 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. Te(1) is bonded in a 5-coordinate geometry to one Br(1), one Br(2), one Br(3), one F(3), and one F(4) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) and one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) and one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom.
AsTe(BrF2)3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two AsTe(BrF2)3 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.74 Å. The As(1)-F(2) bond length is 1.73 Å. The As(1)-F(3) bond length is 1.77 Å. The As(1)-F(4) bond length is 1.77 Å. The As(1)-F(5) bond length is 1.73 Å. The As(1)-F(6) bond length is 1.76 Å. Te(1) is bonded in a 5-coordinate geometry to one Br(1), one Br(2), one Br(3), one F(3), and one F(4) atom. The Te(1)-Br(1) bond length is 2.45 Å. The Te(1)-Br(2) bond length is 2.45 Å. The Te(1)-Br(3) bond length is 2.46 Å. The Te(1)-F(3) bond length is 2.70 Å. The Te(1)-F(4) bond length is 2.74 Å. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) and one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) and one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom.