PdTe2Cl10 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PdTe2Cl10 clusters. Pd(1) is bonded in a rectangular see-saw-like geometry to one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a square pyramidal geometry to one Cl(10), one Cl(6), one Cl(7), one Cl(8), and one Cl(9) atom. In the second Te site, Te(2) is bonded in a square pyramidal geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are ten inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a water-like geometry to one Pd(1) and one Te(1) atom. In the second Cl site, Cl(7) is bonded in a water-like geometry to one Pd(1) and one Te(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(1) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the seventh Cl site, Cl(10) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(3) is bonded in a single-bond geometry to one Te(2) atom. In the ninth Cl site, Cl(4) is bonded in a water-like geometry to one Pd(1) and one Te(2) atom. In the tenth Cl site, Cl(5) is bonded in a water-like geometry to one Pd(1) and one Te(2) atom.
PdTe2Cl10 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PdTe2Cl10 clusters. Pd(1) is bonded in a rectangular see-saw-like geometry to one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom. The Pd(1)-Cl(4) bond length is 2.32 Å. The Pd(1)-Cl(5) bond length is 2.32 Å. The Pd(1)-Cl(6) bond length is 2.32 Å. The Pd(1)-Cl(7) bond length is 2.33 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a square pyramidal geometry to one Cl(10), one Cl(6), one Cl(7), one Cl(8), and one Cl(9) atom. The Te(1)-Cl(10) bond length is 2.34 Å. The Te(1)-Cl(6) bond length is 2.85 Å. The Te(1)-Cl(7) bond length is 2.86 Å. The Te(1)-Cl(8) bond length is 2.37 Å. The Te(1)-Cl(9) bond length is 2.37 Å. In the second Te site, Te(2) is bonded in a square pyramidal geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. The Te(2)-Cl(1) bond length is 2.39 Å. The Te(2)-Cl(2) bond length is 2.37 Å. The Te(2)-Cl(3) bond length is 2.34 Å. The Te(2)-Cl(4) bond length is 2.90 Å. The Te(2)-Cl(5) bond length is 2.80 Å. There are ten inequivalent Cl sites. In the first Cl site, Cl(6) is bonded in a water-like geometry to one Pd(1) and one Te(1) atom. In the second Cl site, Cl(7) is bonded in a water-like geometry to one Pd(1) and one Te(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(1) is bonded in a single-bond geometry to one Te(2) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the seventh Cl site, Cl(10) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(3) is bonded in a single-bond geometry to one Te(2) atom. In the ninth Cl site, Cl(4) is bonded in a water-like geometry to one Pd(1) and one Te(2) atom. In the tenth Cl site, Cl(5) is bonded in a water-like geometry to one Pd(1) and one Te(2) atom.