SrAgGe crystallizes in the monoclinic Cm space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one Ag(2), two equivalent Ag(5), three equivalent Ag(3), one Ge(1), two equivalent Ge(4), and three equivalent Ge(2) atoms. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one Ag(1), one Ag(5), three equivalent Ag(4), two equivalent Ge(1), two equivalent Ge(5), and three equivalent Ge(3) atoms. In the third Sr site, Sr(3) is bonded in a 12-coordinate geometry to one Ag(4), two equivalent Ag(2), three equivalent Ag(1), one Ge(4), two equivalent Ge(3), and three equivalent Ge(5) atoms. In the fourth Sr site, Sr(4) is bonded in a 12-coordinate geometry to one Ag(3), two equivalent Ag(1), three equivalent Ag(2), one Ge(5), two equivalent Ge(2), and three equivalent Ge(4) atoms. In the fifth Sr site, Sr(5) is bonded in a 12-coordinate geometry to two equivalent Ag(3), two equivalent Ag(4), three equivalent Ag(5), one Ge(2), one Ge(3), and three equivalent Ge(1) atoms. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 10-coordinate geometry to one Sr(2), two equivalent Sr(4), three equivalent Sr(3), one Ag(2), one Ge(3), and two equivalent Ge(5) atoms. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to one Sr(1), two equivalent Sr(3), three equivalent Sr(4), one Ag(1), one Ge(2), and two equivalent Ge(4) atoms. In the third Ag site, Ag(3) is bonded in a 10-coordinate geometry to one Sr(4), two equivalent Sr(5), three equivalent Sr(1), one Ag(5), one Ge(4), and two equivalent Ge(2) atoms. In the fourth Ag site, Ag(4) is bonded in a 10-coordinate geometry to one Sr(3), two equivalent Sr(5), three equivalent Sr(2), one Ge(1), one Ge(5), and two equivalent Ge(3) atoms. In the fifth Ag site, Ag(5) is bonded in a 9-coordinate geometry to one Sr(2), two equivalent Sr(1), three equivalent Sr(5), one Ag(3), and two equivalent Ge(1) atoms. There are five inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to one Sr(1), two equivalent Sr(2), three equivalent Sr(5), one Ag(4), and two equivalent Ag(5) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one Sr(5), two equivalent Sr(4), three equivalent Sr(1), one Ag(2), two equivalent Ag(3), and one Ge(4) atom. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Sr(5), two equivalent Sr(3), three equivalent Sr(2), one Ag(1), two equivalent Ag(4), and one Ge(5) atom. In the fourth Ge site, Ge(4) is bonded in a 10-coordinate geometry to one Sr(3), two equivalent Sr(1), three equivalent Sr(4), one Ag(3), two equivalent Ag(2), and one Ge(2) atom. In the fifth Ge site, Ge(5) is bonded in a 10-coordinate geometry to one Sr(4), two equivalent Sr(2), three equivalent Sr(3), one Ag(4), two equivalent Ag(1), and one Ge(3) atom.
SrAgGe crystallizes in the monoclinic Cm space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 12-coordinate geometry to one Ag(2), two equivalent Ag(5), three equivalent Ag(3), one Ge(1), two equivalent Ge(4), and three equivalent Ge(2) atoms. The Sr(1)-Ag(2) bond length is 3.35 Å. Both Sr(1)-Ag(5) bond lengths are 3.38 Å. There are two shorter (3.30 Å) and one longer (3.31 Å) Sr(1)-Ag(3) bond length. The Sr(1)-Ge(1) bond length is 3.21 Å. Both Sr(1)-Ge(4) bond lengths are 3.29 Å. There is one shorter (3.42 Å) and two longer (3.49 Å) Sr(1)-Ge(2) bond lengths. In the second Sr site, Sr(2) is bonded in a 12-coordinate geometry to one Ag(1), one Ag(5), three equivalent Ag(4), two equivalent Ge(1), two equivalent Ge(5), and three equivalent Ge(3) atoms. The Sr(2)-Ag(1) bond length is 3.32 Å. The Sr(2)-Ag(5) bond length is 3.21 Å. There are two shorter (3.29 Å) and one longer (3.31 Å) Sr(2)-Ag(4) bond length. Both Sr(2)-Ge(1) bond lengths are 3.41 Å. Both Sr(2)-Ge(5) bond lengths are 3.30 Å. There is one shorter (3.42 Å) and two longer (3.48 Å) Sr(2)-Ge(3) bond lengths. In the third Sr site, Sr(3) is bonded in a 12-coordinate geometry to one Ag(4), two equivalent Ag(2), three equivalent Ag(1), one Ge(4), two equivalent Ge(3), and three equivalent Ge(5) atoms. The Sr(3)-Ag(4) bond length is 3.37 Å. Both Sr(3)-Ag(2) bond lengths are 3.56 Å. There are two shorter (3.27 Å) and one longer (3.34 Å) Sr(3)-Ag(1) bond length. The Sr(3)-Ge(4) bond length is 3.46 Å. Both Sr(3)-Ge(3) bond lengths are 3.31 Å. There is one shorter (3.42 Å) and two longer (3.48 Å) Sr(3)-Ge(5) bond lengths. In the fourth Sr site, Sr(4) is bonded in a 12-coordinate geometry to one Ag(3), two equivalent Ag(1), three equivalent Ag(2), one Ge(5), two equivalent Ge(2), and three equivalent Ge(4) atoms. The Sr(4)-Ag(3) bond length is 3.28 Å. Both Sr(4)-Ag(1) bond lengths are 3.54 Å. There are two shorter (3.28 Å) and one longer (3.32 Å) Sr(4)-Ag(2) bond length. The Sr(4)-Ge(5) bond length is 3.37 Å. Both Sr(4)-Ge(2) bond lengths are 3.34 Å. There is one shorter (3.45 Å) and two longer (3.51 Å) Sr(4)-Ge(4) bond lengths. In the fifth Sr site, Sr(5) is bonded in a 12-coordinate geometry to two equivalent Ag(3), two equivalent Ag(4), three equivalent Ag(5), one Ge(2), one Ge(3), and three equivalent Ge(1) atoms. Both Sr(5)-Ag(3) bond lengths are 3.95 Å. Both Sr(5)-Ag(4) bond lengths are 3.82 Å. There is one shorter (3.20 Å) and two longer (3.42 Å) Sr(5)-Ag(5) bond lengths. The Sr(5)-Ge(2) bond length is 3.80 Å. The Sr(5)-Ge(3) bond length is 3.76 Å. There is one shorter (3.26 Å) and two longer (3.37 Å) Sr(5)-Ge(1) bond lengths. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 10-coordinate geometry to one Sr(2), two equivalent Sr(4), three equivalent Sr(3), one Ag(2), one Ge(3), and two equivalent Ge(5) atoms. The Ag(1)-Ag(2) bond length is 2.96 Å. The Ag(1)-Ge(3) bond length is 3.19 Å. Both Ag(1)-Ge(5) bond lengths are 2.72 Å. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to one Sr(1), two equivalent Sr(3), three equivalent Sr(4), one Ag(1), one Ge(2), and two equivalent Ge(4) atoms. The Ag(2)-Ge(2) bond length is 3.24 Å. Both Ag(2)-Ge(4) bond lengths are 2.74 Å. In the third Ag site, Ag(3) is bonded in a 10-coordinate geometry to one Sr(4), two equivalent Sr(5), three equivalent Sr(1), one Ag(5), one Ge(4), and two equivalent Ge(2) atoms. The Ag(3)-Ag(5) bond length is 2.86 Å. The Ag(3)-Ge(4) bond length is 3.15 Å. Both Ag(3)-Ge(2) bond lengths are 2.68 Å. In the fourth Ag site, Ag(4) is bonded in a 10-coordinate geometry to one Sr(3), two equivalent Sr(5), three equivalent Sr(2), one Ge(1), one Ge(5), and two equivalent Ge(3) atoms. The Ag(4)-Ge(1) bond length is 2.69 Å. The Ag(4)-Ge(5) bond length is 3.25 Å. Both Ag(4)-Ge(3) bond lengths are 2.73 Å. In the fifth Ag site, Ag(5) is bonded in a 9-coordinate geometry to one Sr(2), two equivalent Sr(1), three equivalent Sr(5), one Ag(3), and two equivalent Ge(1) atoms. Both Ag(5)-Ge(1) bond lengths are 2.68 Å. There are five inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to one Sr(1), two equivalent Sr(2), three equivalent Sr(5), one Ag(4), and two equivalent Ag(5) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one Sr(5), two equivalent Sr(4), three equivalent Sr(1), one Ag(2), two equivalent Ag(3), and one Ge(4) atom. The Ge(2)-Ge(4) bond length is 2.52 Å. In the third Ge site, Ge(3) is bonded in a 10-coordinate geometry to one Sr(5), two equivalent Sr(3), three equivalent Sr(2), one Ag(1), two equivalent Ag(4), and one Ge(5) atom. The Ge(3)-Ge(5) bond length is 2.56 Å. In the fourth Ge site, Ge(4) is bonded in a 10-coordinate geometry to one Sr(3), two equivalent Sr(1), three equivalent Sr(4), one Ag(3), two equivalent Ag(2), and one Ge(2) atom. In the fifth Ge site, Ge(5) is bonded in a 10-coordinate geometry to one Sr(4), two equivalent Sr(2), three equivalent Sr(3), one Ag(4), two equivalent Ag(1), and one Ge(3) atom.