ClF3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ClF3 clusters. Cl(1) is bonded in a T-shaped geometry to one F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Cl(1) atom.
ClF3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ClF3 clusters. Cl(1) is bonded in a T-shaped geometry to one F(1) and two equivalent F(2) atoms. The Cl(1)-F(1) bond length is 1.61 Å. Both Cl(1)-F(2) bond lengths are 1.73 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Cl(1) atom.