(Na)2NaScI6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaScI6 framework. In the NaScI6 framework, Na(2) is bonded to six equivalent I(1) atoms to form NaI6 octahedra that share corners with six equivalent Sc(1)I6 octahedra. The corner-sharing octahedra are not tilted. Sc(1) is bonded to six equivalent I(1) atoms to form ScI6 octahedra that share corners with six equivalent Na(2)I6 octahedra. The corner-sharing octahedra are not tilted. I(1) is bonded in a linear geometry to one Na(2) and one Sc(1) atom.
(Na)2NaScI6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaScI6 framework. In the NaScI6 framework, Na(2) is bonded to six equivalent I(1) atoms to form NaI6 octahedra that share corners with six equivalent Sc(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-I(1) bond lengths are 3.10 Å. Sc(1) is bonded to six equivalent I(1) atoms to form ScI6 octahedra that share corners with six equivalent Na(2)I6 octahedra. The corner-sharing octahedra are not tilted. All Sc(1)-I(1) bond lengths are 2.88 Å. I(1) is bonded in a linear geometry to one Na(2) and one Sc(1) atom.