VOF3 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of four VOF3 clusters. In two of the VOF3 clusters, V(1) is bonded in a tetrahedral geometry to one O(2), one F(2), one F(3), and one F(6) atom. O(2) is bonded in a single-bond geometry to one V(1) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one V(1) atom. In two of the VOF3 clusters, V(2) is bonded in a tetrahedral geometry to one O(1), one F(1), one F(4), and one F(5) atom. O(1) is bonded in a single-bond geometry to one V(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(2) atom. In the second F site, F(4) is bonded in a single-bond geometry to one V(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one V(2) atom.
VOF3 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of four VOF3 clusters. In two of the VOF3 clusters, V(1) is bonded in a tetrahedral geometry to one O(2), one F(2), one F(3), and one F(6) atom. The V(1)-O(2) bond length is 1.60 Å. The V(1)-F(2) bond length is 1.76 Å. The V(1)-F(3) bond length is 1.76 Å. The V(1)-F(6) bond length is 1.76 Å. O(2) is bonded in a single-bond geometry to one V(1) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one V(1) atom. In two of the VOF3 clusters, V(2) is bonded in a tetrahedral geometry to one O(1), one F(1), one F(4), and one F(5) atom. The V(2)-O(1) bond length is 1.60 Å. The V(2)-F(1) bond length is 1.75 Å. The V(2)-F(4) bond length is 1.77 Å. The V(2)-F(5) bond length is 1.77 Å. O(1) is bonded in a single-bond geometry to one V(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(2) atom. In the second F site, F(4) is bonded in a single-bond geometry to one V(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one V(2) atom.