KLiWO4 is Cuprite-derived structured and crystallizes in the hexagonal P6_3mc space group. The structure consists of two 7440-09-7 atoms inside a LiWO4 framework. In the LiWO4 framework, Li(1) is bonded to one O(1) and three equivalent O(2) atoms to form LiO4 tetrahedra that share corners with four equivalent W(1)O4 tetrahedra. W(1) is bonded to one O(1) and three equivalent O(2) atoms to form WO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra. There are two inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to one Li(1) and one W(1) atom. In the second O site, O(1) is bonded in a linear geometry to one Li(1) and one W(1) atom.
KLiWO4 is Cuprite-derived structured and crystallizes in the hexagonal P6_3mc space group. The structure consists of two 7440-09-7 atoms inside a LiWO4 framework. In the LiWO4 framework, Li(1) is bonded to one O(1) and three equivalent O(2) atoms to form LiO4 tetrahedra that share corners with four equivalent W(1)O4 tetrahedra. The Li(1)-O(1) bond length is 1.94 Å. All Li(1)-O(2) bond lengths are 1.90 Å. W(1) is bonded to one O(1) and three equivalent O(2) atoms to form WO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra. The W(1)-O(1) bond length is 1.82 Å. All W(1)-O(2) bond lengths are 1.81 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to one Li(1) and one W(1) atom. In the second O site, O(1) is bonded in a linear geometry to one Li(1) and one W(1) atom.