CaCeV2O8 is Zircon-derived structured and crystallizes in the tetragonal I-4m2 space group. Ca(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Ce(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ca(1), one Ce(1), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ca(1), one Ce(1), and one V(2) atom.
CaCeV2O8 is Zircon-derived structured and crystallizes in the tetragonal I-4m2 space group. Ca(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Ca(1)-O(1) bond lengths are 2.39 Å. All Ca(1)-O(2) bond lengths are 2.54 Å. Ce(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Ce(1)-O(1) bond lengths are 2.44 Å. All Ce(1)-O(2) bond lengths are 2.34 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 1.74 Å. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(2) atoms. All V(2)-O(2) bond lengths are 1.74 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ca(1), one Ce(1), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ca(1), one Ce(1), and one V(2) atom.