CeSCl is Baddeleyite-derived structured and crystallizes in the orthorhombic Pbca space group. Ce(1) is bonded to four equivalent S(1) and three equivalent Cl(1) atoms to form a mixture of distorted corner and edge-sharing CeS4Cl3 pentagonal bipyramids. S(1) is bonded to four equivalent Ce(1) atoms to form a mixture of corner and edge-sharing SCe4 tetrahedra. Cl(1) is bonded in a distorted trigonal planar geometry to three equivalent Ce(1) atoms.
CeSCl is Baddeleyite-derived structured and crystallizes in the orthorhombic Pbca space group. Ce(1) is bonded to four equivalent S(1) and three equivalent Cl(1) atoms to form a mixture of distorted corner and edge-sharing CeS4Cl3 pentagonal bipyramids. There are a spread of Ce(1)-S(1) bond distances ranging from 2.82-2.84 Å. There are a spread of Ce(1)-Cl(1) bond distances ranging from 2.91-3.06 Å. S(1) is bonded to four equivalent Ce(1) atoms to form a mixture of corner and edge-sharing SCe4 tetrahedra. Cl(1) is bonded in a distorted trigonal planar geometry to three equivalent Ce(1) atoms.