(Rb)2KSmCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a KSmCl6 framework. In the KSmCl6 framework, K(1) is bonded to six equivalent Cl(1) atoms to form KCl6 octahedra that share corners with six equivalent Sm(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Sm(1) is bonded to six equivalent Cl(1) atoms to form SmCl6 octahedra that share corners with six equivalent K(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one K(1) and one Sm(1) atom.
(Rb)2KSmCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a KSmCl6 framework. In the KSmCl6 framework, K(1) is bonded to six equivalent Cl(1) atoms to form KCl6 octahedra that share corners with six equivalent Sm(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All K(1)-Cl(1) bond lengths are 3.00 Å. Sm(1) is bonded to six equivalent Cl(1) atoms to form SmCl6 octahedra that share corners with six equivalent K(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Sm(1)-Cl(1) bond lengths are 2.69 Å. Cl(1) is bonded in a linear geometry to one K(1) and one Sm(1) atom.