MoO2 crystallizes in the orthorhombic Fddd space group. Mo(1) is bonded to six equivalent O(1) atoms to form edge-sharing MoO6 octahedra. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1) atoms.
MoO2 crystallizes in the orthorhombic Fddd space group. Mo(1) is bonded to six equivalent O(1) atoms to form edge-sharing MoO6 octahedra. There are a spread of Mo(1)-O(1) bond distances ranging from 2.06-2.14 Å. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Mo(1) atoms.