ZrO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Zr(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ZrO6 octahedra. The corner-sharing octahedral tilt angles are 51°. O(1) is bonded in a trigonal planar geometry to three equivalent Zr(1) atoms.
ZrO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Zr(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing ZrO6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are two shorter (2.10 Å) and four longer (2.11 Å) Zr(1)-O(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent Zr(1) atoms.