UV3O10 crystallizes in the orthorhombic Fddd space group. U(1) is bonded in a distorted linear geometry to two equivalent O(3), two equivalent O(4), and four equivalent O(1) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in an octahedral geometry to two equivalent O(2) and four equivalent O(1) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one U(1), one V(1), and one V(2) atom. In the second O site, O(2) is bonded in a linear geometry to one V(1) and one V(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one U(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one U(1) and two equivalent V(2) atoms.
UV3O10 crystallizes in the orthorhombic Fddd space group. U(1) is bonded in a distorted linear geometry to two equivalent O(3), two equivalent O(4), and four equivalent O(1) atoms. Both U(1)-O(3) bond lengths are 1.81 Å. Both U(1)-O(4) bond lengths are 2.55 Å. All U(1)-O(1) bond lengths are 2.47 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in an octahedral geometry to two equivalent O(2) and four equivalent O(1) atoms. Both V(1)-O(2) bond lengths are 1.97 Å. All V(1)-O(1) bond lengths are 1.89 Å. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), and two equivalent O(4) atoms. The V(2)-O(2) bond length is 1.69 Å. Both V(2)-O(1) bond lengths are 1.86 Å. Both V(2)-O(4) bond lengths are 1.88 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one U(1), one V(1), and one V(2) atom. In the second O site, O(2) is bonded in a linear geometry to one V(1) and one V(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one U(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one U(1) and two equivalent V(2) atoms.