Hg2Cl5C3H7NH3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trimethylammonium molecules and two Hg2Cl5 clusters. In each Hg2Cl5 cluster, there are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 3-coordinate geometry to one Cl(2), one Cl(3), and one Cl(5) atom. In the second Hg site, Hg(2) is bonded in a distorted trigonal planar geometry to one Cl(1), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Hg(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Hg(2) atom. In the fifth Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one Hg(2) atom.
Hg2Cl5C3H7NH3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trimethylammonium molecules and two Hg2Cl5 clusters. In each Hg2Cl5 cluster, there are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 3-coordinate geometry to one Cl(2), one Cl(3), and one Cl(5) atom. The Hg(1)-Cl(2) bond length is 2.36 Å. The Hg(1)-Cl(3) bond length is 2.37 Å. The Hg(1)-Cl(5) bond length is 2.96 Å. In the second Hg site, Hg(2) is bonded in a distorted trigonal planar geometry to one Cl(1), one Cl(4), and one Cl(5) atom. The Hg(2)-Cl(1) bond length is 2.41 Å. The Hg(2)-Cl(4) bond length is 2.47 Å. The Hg(2)-Cl(5) bond length is 2.58 Å. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Hg(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Hg(2) atom. In the fifth Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one Hg(2) atom.