CdV2O6 is Brookite-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(3), and three equivalent O(1) atoms. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent V(1) and one Cd(1) atom.
CdV2O6 is Brookite-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(3), and three equivalent O(1) atoms. The V(1)-O(2) bond length is 1.69 Å. There is one shorter (1.83 Å) and one longer (2.03 Å) V(1)-O(3) bond length. There are a spread of V(1)-O(1) bond distances ranging from 1.80-2.42 Å. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(2) atoms. Both Cd(1)-O(3) bond lengths are 2.26 Å. There are two shorter (2.30 Å) and two longer (2.46 Å) Cd(1)-O(2) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent V(1) and one Cd(1) atom.