(Na)2HgAlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a HgAlF6 framework. In the HgAlF6 framework, Hg(1) is bonded to six equivalent F(1) atoms to form HgF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent Hg(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted linear geometry to one Hg(1) and one Al(1) atom.
(Na)2HgAlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a HgAlF6 framework. In the HgAlF6 framework, Hg(1) is bonded to six equivalent F(1) atoms to form HgF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Hg(1)-F(1) bond lengths are 2.49 Å. Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent Hg(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-F(1) bond lengths are 1.83 Å. F(1) is bonded in a distorted linear geometry to one Hg(1) and one Al(1) atom.