Ga(MoSe2)4 crystallizes in the cubic F-43m space group. Mo(1) is bonded in a 6-coordinate geometry to three equivalent Se(1) and three equivalent Se(2) atoms. Ga(1) is bonded in a tetrahedral geometry to four equivalent Se(1) atoms. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded to three equivalent Mo(1) and one Ga(1) atom to form a mixture of corner and edge-sharing SeGaMo3 tetrahedra. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to three equivalent Mo(1) atoms.
Ga(MoSe2)4 crystallizes in the cubic F-43m space group. Mo(1) is bonded in a 6-coordinate geometry to three equivalent Se(1) and three equivalent Se(2) atoms. All Mo(1)-Se(1) bond lengths are 2.76 Å. All Mo(1)-Se(2) bond lengths are 2.48 Å. Ga(1) is bonded in a tetrahedral geometry to four equivalent Se(1) atoms. All Ga(1)-Se(1) bond lengths are 2.45 Å. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded to three equivalent Mo(1) and one Ga(1) atom to form a mixture of corner and edge-sharing SeGaMo3 tetrahedra. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to three equivalent Mo(1) atoms.