(Mn3Ga)4(C)2N2 is High-temperature superconductor-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure consists of one 02329_fluka atom and one ammonia atom inside a Mn3Ga framework. In the Mn3Ga framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a linear geometry to two equivalent Ga(1) atoms. In the second Mn site, Mn(2) is bonded in a linear geometry to two equivalent Ga(1) atoms. In the third Mn site, Mn(3) is bonded in a linear geometry to two equivalent Ga(1) atoms. Ga(1) is bonded to one Mn(1), one Mn(2), and four equivalent Mn(3) atoms to form corner-sharing GaMn6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°.
(Mn3Ga)4(C)2N2 is High-temperature superconductor-derived structured and crystallizes in the tetragonal P4/mmm space group. The structure consists of one 02329_fluka atom and one ammonia atom inside a Mn3Ga framework. In the Mn3Ga framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a linear geometry to two equivalent Ga(1) atoms. Both Mn(1)-Ga(1) bond lengths are 2.36 Å. In the second Mn site, Mn(2) is bonded in a linear geometry to two equivalent Ga(1) atoms. Both Mn(2)-Ga(1) bond lengths are 2.34 Å. In the third Mn site, Mn(3) is bonded in a linear geometry to two equivalent Ga(1) atoms. Both Mn(3)-Ga(1) bond lengths are 2.35 Å. Ga(1) is bonded to one Mn(1), one Mn(2), and four equivalent Mn(3) atoms to form corner-sharing GaMn6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°.