NiAs crystallizes in the hexagonal P6_3/mmc space group. Ni(1) is bonded to six equivalent As(1) atoms to form a mixture of distorted edge, corner, and face-sharing NiAs6 octahedra. The corner-sharing octahedral tilt angles are 51°. As(1) is bonded in a 6-coordinate geometry to six equivalent Ni(1) atoms.
NiAs crystallizes in the hexagonal P6_3/mmc space group. Ni(1) is bonded to six equivalent As(1) atoms to form a mixture of distorted edge, corner, and face-sharing NiAs6 octahedra. The corner-sharing octahedral tilt angles are 51°. All Ni(1)-As(1) bond lengths are 2.43 Å. As(1) is bonded in a 6-coordinate geometry to six equivalent Ni(1) atoms.