KAg2 is Hexagonal Laves structured and crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded in a 12-coordinate geometry to three equivalent Ag(1) and nine equivalent Ag(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to six equivalent K(1) and six equivalent Ag(2) atoms to form a mixture of face, corner, and edge-sharing AgK6Ag6 cuboctahedra. In the second Ag site, Ag(2) is bonded to six equivalent K(1), two equivalent Ag(1), and four equivalent Ag(2) atoms to form a mixture of face, corner, and edge-sharing AgK6Ag6 cuboctahedra.
KAg2 is Hexagonal Laves structured and crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded in a 12-coordinate geometry to three equivalent Ag(1) and nine equivalent Ag(2) atoms. All K(1)-Ag(1) bond lengths are 3.42 Å. There are six shorter (3.45 Å) and three longer (3.49 Å) K(1)-Ag(2) bond lengths. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to six equivalent K(1) and six equivalent Ag(2) atoms to form a mixture of face, corner, and edge-sharing AgK6Ag6 cuboctahedra. All Ag(1)-Ag(2) bond lengths are 2.97 Å. In the second Ag site, Ag(2) is bonded to six equivalent K(1), two equivalent Ag(1), and four equivalent Ag(2) atoms to form a mixture of face, corner, and edge-sharing AgK6Ag6 cuboctahedra. There are two shorter (2.90 Å) and two longer (2.94 Å) Ag(2)-Ag(2) bond lengths.