Ir(NCl)4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ir(NCl)4 cluster. Ir(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(3), one N(4), one Cl(1), and one Cl(2) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(4) atom. In the second N site, N(2) is bonded in a water-like geometry to one Cl(3) and one Cl(4) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Ir(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one N(1) and one N(2) atom.
Ir(NCl)4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Ir(NCl)4 cluster. Ir(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(3), one N(4), one Cl(1), and one Cl(2) atom. The Ir(1)-N(1) bond length is 2.01 Å. The Ir(1)-N(3) bond length is 1.73 Å. The Ir(1)-N(4) bond length is 1.74 Å. The Ir(1)-Cl(1) bond length is 2.33 Å. The Ir(1)-Cl(2) bond length is 2.47 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(4) atom. The N(1)-Cl(4) bond length is 1.57 Å. In the second N site, N(2) is bonded in a water-like geometry to one Cl(3) and one Cl(4) atom. The N(2)-Cl(3) bond length is 1.60 Å. The N(2)-Cl(4) bond length is 2.05 Å. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Ir(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one N(1) and one N(2) atom.