Cr2OF2 crystallizes in the tetragonal I4_1/amd space group. Cr(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent F(1) atoms. O(1) is bonded to four equivalent Cr(1) atoms to form corner-sharing OCr4 tetrahedra. F(1) is bonded in a water-like geometry to two equivalent Cr(1) atoms.
Cr2OF2 crystallizes in the tetragonal I4_1/amd space group. Cr(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent F(1) atoms. Both Cr(1)-O(1) bond lengths are 2.03 Å. Both Cr(1)-F(1) bond lengths are 2.01 Å. O(1) is bonded to four equivalent Cr(1) atoms to form corner-sharing OCr4 tetrahedra. F(1) is bonded in a water-like geometry to two equivalent Cr(1) atoms.