V2O3 is Corundum-like structured and crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of distorted corner, face, and edge-sharing VO6 pentagonal pyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to four equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to four equivalent V(1) atoms.
V2O3 is Corundum-like structured and crystallizes in the monoclinic C2/c space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of distorted corner, face, and edge-sharing VO6 pentagonal pyramids. There is one shorter (2.03 Å) and one longer (2.12 Å) V(1)-O(2) bond length. There are a spread of V(1)-O(1) bond distances ranging from 1.97-2.13 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to four equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to four equivalent V(1) atoms.