As2Te crystallizes in the tetragonal I4_1/amd space group. As(1) is bonded to four equivalent As(1) and two equivalent Te(1) atoms to form a mixture of face and corner-sharing AsTe2As4 octahedra. The corner-sharing octahedral tilt angles range from 0-75°. Te(1) is bonded in a 4-coordinate geometry to four equivalent As(1) atoms.
As2Te crystallizes in the tetragonal I4_1/amd space group. As(1) is bonded to four equivalent As(1) and two equivalent Te(1) atoms to form a mixture of face and corner-sharing AsTe2As4 octahedra. The corner-sharing octahedral tilt angles range from 0-75°. All As(1)-As(1) bond lengths are 2.91 Å. Both As(1)-Te(1) bond lengths are 2.83 Å. Te(1) is bonded in a 4-coordinate geometry to four equivalent As(1) atoms.