Na2CdSn crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a 7-coordinate geometry to three equivalent Cd(1) and four equivalent Sn(1) atoms. Cd(1) is bonded in a 9-coordinate geometry to six equivalent Na(1) and three equivalent Sn(1) atoms. Sn(1) is bonded in a 11-coordinate geometry to eight equivalent Na(1) and three equivalent Cd(1) atoms.
Na2CdSn crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a 7-coordinate geometry to three equivalent Cd(1) and four equivalent Sn(1) atoms. All Na(1)-Cd(1) bond lengths are 3.33 Å. There are three shorter (3.33 Å) and one longer (3.34 Å) Na(1)-Sn(1) bond length. Cd(1) is bonded in a 9-coordinate geometry to six equivalent Na(1) and three equivalent Sn(1) atoms. All Cd(1)-Sn(1) bond lengths are 2.88 Å. Sn(1) is bonded in a 11-coordinate geometry to eight equivalent Na(1) and three equivalent Cd(1) atoms.