CaMoO2 crystallizes in the tetragonal I4_1/amd space group. Ca(1) is bonded to six equivalent O(1) atoms to form edge-sharing CaO6 octahedra. Mo(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Ca(1) and two equivalent Mo(1) atoms to form a mixture of distorted corner and edge-sharing OCa3Mo2 trigonal bipyramids.
CaMoO2 crystallizes in the tetragonal I4_1/amd space group. Ca(1) is bonded to six equivalent O(1) atoms to form edge-sharing CaO6 octahedra. All Ca(1)-O(1) bond lengths are 2.36 Å. Mo(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Mo(1)-O(1) bond lengths are 2.13 Å. O(1) is bonded to three equivalent Ca(1) and two equivalent Mo(1) atoms to form a mixture of distorted corner and edge-sharing OCa3Mo2 trigonal bipyramids.