VOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Ama2 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second V site, V(2) is bonded to one O(2), two equivalent O(1), one F(3), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one F(1), one F(2), and one F(3) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(3) atoms.
VOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Ama2 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. The V(1)-O(3) bond length is 1.86 Å. Both V(1)-O(1) bond lengths are 1.97 Å. The V(1)-F(2) bond length is 2.09 Å. Both V(1)-F(1) bond lengths are 2.07 Å. In the second V site, V(2) is bonded to one O(2), two equivalent O(1), one F(3), and two equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. The V(2)-O(2) bond length is 1.85 Å. Both V(2)-O(1) bond lengths are 1.92 Å. The V(2)-F(3) bond length is 2.09 Å. Both V(2)-F(1) bond lengths are 2.11 Å. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one F(1), one F(2), and one F(3) atom to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-54°. The V(3)-O(1) bond length is 1.87 Å. The V(3)-O(2) bond length is 1.97 Å. The V(3)-O(3) bond length is 1.96 Å. The V(3)-F(1) bond length is 2.10 Å. The V(3)-F(2) bond length is 2.06 Å. The V(3)-F(3) bond length is 2.07 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(3) atoms.