Re3Fe2 is beta-derived structured and crystallizes in the cubic P4_132 space group. Re(1) is bonded in a 12-coordinate geometry to six equivalent Re(1) and six equivalent Fe(1) atoms. Fe(1) is bonded to nine equivalent Re(1) and three equivalent Fe(1) atoms to form a mixture of corner and face-sharing FeFe3Re9 cuboctahedra.
Re3Fe2 is beta-derived structured and crystallizes in the cubic P4_132 space group. Re(1) is bonded in a 12-coordinate geometry to six equivalent Re(1) and six equivalent Fe(1) atoms. There are four shorter (2.67 Å) and two longer (2.77 Å) Re(1)-Re(1) bond lengths. There are a spread of Re(1)-Fe(1) bond distances ranging from 2.61-2.72 Å. Fe(1) is bonded to nine equivalent Re(1) and three equivalent Fe(1) atoms to form a mixture of corner and face-sharing FeFe3Re9 cuboctahedra. All Fe(1)-Fe(1) bond lengths are 2.42 Å.