LiF2Li2MnOF(MnO2)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one lithium;fluoride;hydrofluoride molecule, two manganese;dihydrate molecules, and one Li2MnOF cluster. In the Li2MnOF cluster, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one F(3) atom. In the second Li site, Li(3) is bonded in a 1-coordinate geometry to one O(1) atom. Mn(1) is bonded in a distorted linear geometry to one O(1) and one F(3) atom. O(1) is bonded in a distorted L-shaped geometry to one Li(3) and one Mn(1) atom. F(3) is bonded in an L-shaped geometry to one Li(1) and one Mn(1) atom.
LiF2Li2MnOF(MnO2)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one lithium;fluoride;hydrofluoride molecule, two manganese;dihydrate molecules, and one Li2MnOF cluster. In the Li2MnOF cluster, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one F(3) atom. The Li(1)-F(3) bond length is 1.47 Å. In the second Li site, Li(3) is bonded in a 1-coordinate geometry to one O(1) atom. The Li(3)-O(1) bond length is 1.48 Å. Mn(1) is bonded in a distorted linear geometry to one O(1) and one F(3) atom. The Mn(1)-O(1) bond length is 1.43 Å. The Mn(1)-F(3) bond length is 1.49 Å. O(1) is bonded in a distorted L-shaped geometry to one Li(3) and one Mn(1) atom. F(3) is bonded in an L-shaped geometry to one Li(1) and one Mn(1) atom.