PNiNb crystallizes in the orthorhombic Pnma space group. Nb(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Ni(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to five equivalent Nb(1) and four equivalent Ni(1) atoms.
PNiNb crystallizes in the orthorhombic Pnma space group. Nb(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. There are a spread of Nb(1)-P(1) bond distances ranging from 2.60-2.63 Å. Ni(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. There are three shorter (2.27 Å) and one longer (2.35 Å) Ni(1)-P(1) bond length. P(1) is bonded in a 9-coordinate geometry to five equivalent Nb(1) and four equivalent Ni(1) atoms.