Ba2SbO6Bi crystallizes in the triclinic P-1 space group. The structure consists of one 7440-69-9 atom inside a Ba2SbO6 framework. In the Ba2SbO6 framework, Ba(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), and three equivalent O(2) atoms. Sb(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ba(1), one Sb(1), and one O(2) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Sb(1), and one O(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Sb(1), and one O(3) atom.
Ba2SbO6Bi crystallizes in the triclinic P-1 space group. The structure consists of one 7440-69-9 atom inside a Ba2SbO6 framework. In the Ba2SbO6 framework, Ba(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), and three equivalent O(2) atoms. The Ba(1)-O(1) bond length is 2.53 Å. The Ba(1)-O(3) bond length is 2.83 Å. There are a spread of Ba(1)-O(2) bond distances ranging from 2.39-3.14 Å. Sb(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Sb(1)-O(1) bond lengths are 2.43 Å. Both Sb(1)-O(2) bond lengths are 2.48 Å. Both Sb(1)-O(3) bond lengths are 2.46 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ba(1), one Sb(1), and one O(2) atom. The O(1)-O(2) bond length is 1.71 Å. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Ba(1), one Sb(1), and one O(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Sb(1), and one O(3) atom. The O(3)-O(3) bond length is 1.42 Å.