K2TiF6 crystallizes in the trigonal P-3m1 space group. K(1) is bonded to twelve equivalent F(1) atoms to form distorted KF12 cuboctahedra that share corners with six equivalent K(1)F12 cuboctahedra, corners with three equivalent Ti(1)F6 octahedra, faces with eight equivalent K(1)F12 cuboctahedra, and faces with three equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles are 18°. Ti(1) is bonded to six equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent K(1)F12 cuboctahedra and faces with six equivalent K(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Ti(1) atom.
K2TiF6 crystallizes in the trigonal P-3m1 space group. K(1) is bonded to twelve equivalent F(1) atoms to form distorted KF12 cuboctahedra that share corners with six equivalent K(1)F12 cuboctahedra, corners with three equivalent Ti(1)F6 octahedra, faces with eight equivalent K(1)F12 cuboctahedra, and faces with three equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles are 18°. There are a spread of K(1)-F(1) bond distances ranging from 2.76-2.98 Å. Ti(1) is bonded to six equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent K(1)F12 cuboctahedra and faces with six equivalent K(1)F12 cuboctahedra. All Ti(1)-F(1) bond lengths are 1.88 Å. F(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one Ti(1) atom.