CoPtN2 crystallizes in the orthorhombic Cmcm space group. Co(1) is bonded to six equivalent N(1) atoms to form edge-sharing CoN6 octahedra. Pt(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Co(1) and one Pt(1) atom.
CoPtN2 crystallizes in the orthorhombic Cmcm space group. Co(1) is bonded to six equivalent N(1) atoms to form edge-sharing CoN6 octahedra. There are four shorter (1.92 Å) and two longer (1.93 Å) Co(1)-N(1) bond lengths. Pt(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Pt(1)-N(1) bond lengths are 1.99 Å. N(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Co(1) and one Pt(1) atom.