AsO2(CF3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and one AsO2 cluster. In the AsO2 cluster, As(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(1) is bonded in an L-shaped geometry to two equivalent As(1) atoms.
AsO2(CF3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and one AsO2 cluster. In the AsO2 cluster, As(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. The As(1)-O(2) bond length is 1.66 Å. There is one shorter (1.81 Å) and one longer (1.87 Å) As(1)-O(1) bond length. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(1) is bonded in an L-shaped geometry to two equivalent As(1) atoms.