LiAgF3 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to one F(2), one F(3), and two equivalent F(1) atoms to form corner-sharing LiF4 tetrahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent F(2) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom.
LiAgF3 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to one F(2), one F(3), and two equivalent F(1) atoms to form corner-sharing LiF4 tetrahedra. The Li(1)-F(2) bond length is 1.91 Å. The Li(1)-F(3) bond length is 1.98 Å. There is one shorter (1.89 Å) and one longer (1.91 Å) Li(1)-F(1) bond length. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Ag(1)-F(1) bond lengths are 2.16 Å. Both Ag(1)-F(2) bond lengths are 2.65 Å. Both Ag(1)-F(3) bond lengths are 2.25 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent F(2) and two equivalent F(3) atoms. Both Ag(2)-F(2) bond lengths are 2.04 Å. Both Ag(2)-F(3) bond lengths are 2.12 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom.