LiVCrP2(HO5)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one Cr(1), one O(10), one O(4), one O(5), one O(6), and one O(7) atom. V(1) is bonded in a 6-coordinate geometry to one H(1), one H(2), one O(1), one O(10), one O(2), and one O(9) atom. Cr(1) is bonded in a 9-coordinate geometry to one Li(1), one O(1), one O(10), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(4), one O(5), and one O(8) atom. In the second P site, P(2) is bonded in a distorted L-shaped geometry to one O(3), one O(6), one O(7), and one O(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one V(1) and one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one V(1) and one O(1) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1), one Cr(1), one H(2), and one O(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and one P(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Cr(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Cr(1), one P(1), and one O(10) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one Cr(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Li(1), one Cr(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Cr(1), one P(2), and one O(1) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Cr(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one V(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one V(1), one Cr(1), one H(1), and one O(4) atom.
LiVCrP2(HO5)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 5-coordinate geometry to one Cr(1), one O(10), one O(4), one O(5), one O(6), and one O(7) atom. The Li(1)-Cr(1) bond length is 2.65 Å. The Li(1)-O(10) bond length is 2.46 Å. The Li(1)-O(4) bond length is 2.25 Å. The Li(1)-O(5) bond length is 2.12 Å. The Li(1)-O(6) bond length is 2.04 Å. The Li(1)-O(7) bond length is 2.14 Å. V(1) is bonded in a 6-coordinate geometry to one H(1), one H(2), one O(1), one O(10), one O(2), and one O(9) atom. The V(1)-H(1) bond length is 1.82 Å. The V(1)-H(2) bond length is 1.84 Å. The V(1)-O(1) bond length is 1.59 Å. The V(1)-O(10) bond length is 1.77 Å. The V(1)-O(2) bond length is 2.12 Å. The V(1)-O(9) bond length is 2.05 Å. Cr(1) is bonded in a 9-coordinate geometry to one Li(1), one O(1), one O(10), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Cr(1)-O(1) bond length is 2.34 Å. The Cr(1)-O(10) bond length is 2.37 Å. The Cr(1)-O(3) bond length is 2.46 Å. The Cr(1)-O(4) bond length is 2.48 Å. The Cr(1)-O(5) bond length is 2.35 Å. The Cr(1)-O(6) bond length is 2.25 Å. The Cr(1)-O(7) bond length is 2.41 Å. The Cr(1)-O(8) bond length is 2.44 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(4), one O(5), and one O(8) atom. The P(1)-O(2) bond length is 1.24 Å. The P(1)-O(4) bond length is 2.32 Å. The P(1)-O(5) bond length is 1.21 Å. The P(1)-O(8) bond length is 2.07 Å. In the second P site, P(2) is bonded in a distorted L-shaped geometry to one O(3), one O(6), one O(7), and one O(9) atom. The P(2)-O(3) bond length is 2.15 Å. The P(2)-O(6) bond length is 1.20 Å. The P(2)-O(7) bond length is 2.31 Å. The P(2)-O(9) bond length is 1.30 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one V(1) and one O(10) atom. The H(1)-O(10) bond length is 1.39 Å. In the second H site, H(2) is bonded in a single-bond geometry to one V(1) and one O(1) atom. The H(2)-O(1) bond length is 1.29 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one V(1), one Cr(1), one H(2), and one O(7) atom. The O(1)-O(7) bond length is 1.69 Å. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and one P(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Cr(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Cr(1), one P(1), and one O(10) atom. The O(4)-O(10) bond length is 1.74 Å. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one Cr(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Li(1), one Cr(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Cr(1), one P(2), and one O(1) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Cr(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one V(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Li(1), one V(1), one Cr(1), one H(1), and one O(4) atom.