(CH2)3PbC3NH4S2I is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two PbC3NH4S2I clusters. In each PbC3NH4S2I cluster, Pb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one I(1) atom. There are three inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. In the second C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(2) atom. In the third C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Pb(1) and one C(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Pb(1) and one C(1) atom. I(1) is bonded in a single-bond geometry to one Pb(1) atom.
(CH2)3PbC3NH4S2I is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two PbC3NH4S2I clusters. In each PbC3NH4S2I cluster, Pb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one I(1) atom. The Pb(1)-S(1) bond length is 2.75 Å. The Pb(1)-S(2) bond length is 2.75 Å. The Pb(1)-I(1) bond length is 3.06 Å. There are three inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(9) atom. The C(6)-N(1) bond length is 1.47 Å. The C(6)-H(10) bond length is 1.10 Å. The C(6)-H(9) bond length is 1.10 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(1), and one S(2) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-S(1) bond length is 1.74 Å. The C(1)-S(2) bond length is 1.73 Å. In the third C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(1), and one H(2) atom. The C(2)-N(1) bond length is 1.47 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(2) bond length is 1.10 Å. N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Pb(1) and one C(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Pb(1) and one C(1) atom. I(1) is bonded in a single-bond geometry to one Pb(1) atom.