Ag4C(NO3)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one C(1), one O(7), one O(8), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one C(1), one O(1), and one O(4) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(1), one O(2), and one O(5) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one C(1), one O(3), and one O(6) atom. C(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(3) and one N(3) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(4) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(4) and one N(3) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Ag(1) and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Ag(1) and one N(2) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Ag(1) and one N(3) atom.
Ag4C(NO3)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one C(1), one O(7), one O(8), and one O(9) atom. The Ag(1)-C(1) bond length is 2.34 Å. The Ag(1)-O(7) bond length is 2.46 Å. The Ag(1)-O(8) bond length is 2.49 Å. The Ag(1)-O(9) bond length is 2.47 Å. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one C(1), one O(1), and one O(4) atom. The Ag(2)-C(1) bond length is 2.19 Å. The Ag(2)-O(1) bond length is 2.37 Å. The Ag(2)-O(4) bond length is 2.50 Å. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(1), one O(2), and one O(5) atom. The Ag(3)-C(1) bond length is 2.17 Å. The Ag(3)-O(2) bond length is 2.40 Å. The Ag(3)-O(5) bond length is 2.43 Å. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one C(1), one O(3), and one O(6) atom. The Ag(4)-C(1) bond length is 2.49 Å. The Ag(4)-O(3) bond length is 2.45 Å. The Ag(4)-O(6) bond length is 2.41 Å. C(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. The C(1)-C(1) bond length is 1.31 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(7) atom. The N(1)-O(3) bond length is 1.27 Å. The N(1)-O(4) bond length is 1.27 Å. The N(1)-O(7) bond length is 1.27 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(8) atom. The N(2)-O(1) bond length is 1.28 Å. The N(2)-O(5) bond length is 1.27 Å. The N(2)-O(8) bond length is 1.26 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(9) atom. The N(3)-O(2) bond length is 1.27 Å. The N(3)-O(6) bond length is 1.27 Å. The N(3)-O(9) bond length is 1.26 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one N(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Ag(3) and one N(3) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(4) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(4) and one N(3) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Ag(1) and one N(1) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Ag(1) and one N(2) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Ag(1) and one N(3) atom.