WOF4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight WOF4 clusters. W(1) is bonded in a 5-coordinate geometry to one O(2), one F(1), one F(2), one F(3), and one F(5) atom. O(2) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one W(1) atom.
WOF4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight WOF4 clusters. W(1) is bonded in a 5-coordinate geometry to one O(2), one F(1), one F(2), one F(3), and one F(5) atom. The W(1)-O(2) bond length is 1.71 Å. The W(1)-F(1) bond length is 1.89 Å. The W(1)-F(2) bond length is 1.95 Å. The W(1)-F(3) bond length is 1.88 Å. The W(1)-F(5) bond length is 1.88 Å. O(2) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one W(1) atom.