WMoO6 crystallizes in the monoclinic Cm space group. W(1) is bonded to one O(3), one O(4), and four equivalent O(1) atoms to form distorted WO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. Mo(1) is bonded to one O(3), one O(4), and four equivalent O(2) atoms to form distorted MoO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Mo(1) atom.
WMoO6 crystallizes in the monoclinic Cm space group. W(1) is bonded to one O(3), one O(4), and four equivalent O(1) atoms to form distorted WO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The W(1)-O(3) bond length is 1.88 Å. The W(1)-O(4) bond length is 1.90 Å. There are two shorter (1.78 Å) and two longer (2.14 Å) W(1)-O(1) bond lengths. Mo(1) is bonded to one O(3), one O(4), and four equivalent O(2) atoms to form distorted MoO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. The Mo(1)-O(3) bond length is 1.90 Å. The Mo(1)-O(4) bond length is 1.88 Å. There are two shorter (1.72 Å) and two longer (2.20 Å) Mo(1)-O(2) bond lengths. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Mo(1) atom.