TiZr is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. Zr(1) is bonded to four equivalent Zr(1) and eight equivalent Ti(1) atoms to form distorted ZrZr4Ti8 cuboctahedra that share corners with twelve equivalent Zr(1)Zr4Ti8 cuboctahedra, edges with eight equivalent Zr(1)Zr4Ti8 cuboctahedra, edges with sixteen equivalent Ti(1)Zr8Ti4 cuboctahedra, faces with eight equivalent Ti(1)Zr8Ti4 cuboctahedra, and faces with ten equivalent Zr(1)Zr4Ti8 cuboctahedra. Ti(1) is bonded to eight equivalent Zr(1) and four equivalent Ti(1) atoms to form distorted TiZr8Ti4 cuboctahedra that share corners with twelve equivalent Ti(1)Zr8Ti4 cuboctahedra, edges with eight equivalent Ti(1)Zr8Ti4 cuboctahedra, edges with sixteen equivalent Zr(1)Zr4Ti8 cuboctahedra, faces with eight equivalent Zr(1)Zr4Ti8 cuboctahedra, and faces with ten equivalent Ti(1)Zr8Ti4 cuboctahedra.
TiZr is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. Zr(1) is bonded to four equivalent Zr(1) and eight equivalent Ti(1) atoms to form distorted ZrZr4Ti8 cuboctahedra that share corners with twelve equivalent Zr(1)Zr4Ti8 cuboctahedra, edges with eight equivalent Zr(1)Zr4Ti8 cuboctahedra, edges with sixteen equivalent Ti(1)Zr8Ti4 cuboctahedra, faces with eight equivalent Ti(1)Zr8Ti4 cuboctahedra, and faces with ten equivalent Zr(1)Zr4Ti8 cuboctahedra. All Zr(1)-Zr(1) bond lengths are 3.11 Å. All Zr(1)-Ti(1) bond lengths are 3.04 Å. Ti(1) is bonded to eight equivalent Zr(1) and four equivalent Ti(1) atoms to form distorted TiZr8Ti4 cuboctahedra that share corners with twelve equivalent Ti(1)Zr8Ti4 cuboctahedra, edges with eight equivalent Ti(1)Zr8Ti4 cuboctahedra, edges with sixteen equivalent Zr(1)Zr4Ti8 cuboctahedra, faces with eight equivalent Zr(1)Zr4Ti8 cuboctahedra, and faces with ten equivalent Ti(1)Zr8Ti4 cuboctahedra. All Ti(1)-Ti(1) bond lengths are 3.11 Å.