Cs2PdCl4 crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Cl(1) is bonded to four equivalent Cs(1) and one Pd(1) atom to form a mixture of distorted corner, face, and edge-sharing ClCs4Pd square pyramids.
Cs2PdCl4 crystallizes in the tetragonal P4/mmm space group. Cs(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. All Cs(1)-Cl(1) bond lengths are 3.55 Å. Pd(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. All Pd(1)-Cl(1) bond lengths are 2.32 Å. Cl(1) is bonded to four equivalent Cs(1) and one Pd(1) atom to form a mixture of distorted corner, face, and edge-sharing ClCs4Pd square pyramids.