Rb(CrS2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rb(1) is bonded to four equivalent S(1) atoms to form RbS4 tetrahedra that share corners with twelve equivalent Cr(1)S6 octahedra. The corner-sharing octahedral tilt angles are 65°. Cr(1) is bonded to six equivalent S(1) atoms to form distorted CrS6 octahedra that share corners with six equivalent Rb(1)S4 tetrahedra and edges with six equivalent Cr(1)S6 octahedra. S(1) is bonded to one Rb(1) and three equivalent Cr(1) atoms to form a mixture of corner and edge-sharing SRbCr3 tetrahedra.
Rb(CrS2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rb(1) is bonded to four equivalent S(1) atoms to form RbS4 tetrahedra that share corners with twelve equivalent Cr(1)S6 octahedra. The corner-sharing octahedral tilt angles are 65°. All Rb(1)-S(1) bond lengths are 2.90 Å. Cr(1) is bonded to six equivalent S(1) atoms to form distorted CrS6 octahedra that share corners with six equivalent Rb(1)S4 tetrahedra and edges with six equivalent Cr(1)S6 octahedra. All Cr(1)-S(1) bond lengths are 2.46 Å. S(1) is bonded to one Rb(1) and three equivalent Cr(1) atoms to form a mixture of corner and edge-sharing SRbCr3 tetrahedra.