TiW3P4 is Modderite-derived structured and crystallizes in the monoclinic Pm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent W(2), one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms. In the second W site, W(2) is bonded in a 8-coordinate geometry to two equivalent Ti(1), one P(3), one P(4), two equivalent P(1), and two equivalent P(2) atoms. In the third W site, W(3) is bonded in a 6-coordinate geometry to one P(3), one P(4), two equivalent P(1), and two equivalent P(2) atoms. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Ti(1), one W(1), two equivalent W(2), and two equivalent W(3) atoms. In the second P site, P(2) is bonded in a 6-coordinate geometry to one Ti(1), one W(1), two equivalent W(2), and two equivalent W(3) atoms. In the third P site, P(3) is bonded in a 6-coordinate geometry to two equivalent Ti(1), one W(2), one W(3), and two equivalent W(1) atoms. In the fourth P site, P(4) is bonded in a 6-coordinate geometry to two equivalent Ti(1), one W(2), one W(3), and two equivalent W(1) atoms.
TiW3P4 is Modderite-derived structured and crystallizes in the monoclinic Pm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent W(2), one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms. Both Ti(1)-W(2) bond lengths are 2.90 Å. The Ti(1)-P(1) bond length is 2.60 Å. The Ti(1)-P(2) bond length is 2.44 Å. Both Ti(1)-P(3) bond lengths are 2.52 Å. Both Ti(1)-P(4) bond lengths are 2.54 Å. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms. The W(1)-P(1) bond length is 2.46 Å. The W(1)-P(2) bond length is 2.60 Å. Both W(1)-P(3) bond lengths are 2.51 Å. Both W(1)-P(4) bond lengths are 2.52 Å. In the second W site, W(2) is bonded in a 8-coordinate geometry to two equivalent Ti(1), one P(3), one P(4), two equivalent P(1), and two equivalent P(2) atoms. The W(2)-P(3) bond length is 2.59 Å. The W(2)-P(4) bond length is 2.44 Å. Both W(2)-P(1) bond lengths are 2.52 Å. Both W(2)-P(2) bond lengths are 2.50 Å. In the third W site, W(3) is bonded in a 6-coordinate geometry to one P(3), one P(4), two equivalent P(1), and two equivalent P(2) atoms. The W(3)-P(3) bond length is 2.45 Å. The W(3)-P(4) bond length is 2.57 Å. Both W(3)-P(1) bond lengths are 2.50 Å. Both W(3)-P(2) bond lengths are 2.53 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Ti(1), one W(1), two equivalent W(2), and two equivalent W(3) atoms. In the second P site, P(2) is bonded in a 6-coordinate geometry to one Ti(1), one W(1), two equivalent W(2), and two equivalent W(3) atoms. In the third P site, P(3) is bonded in a 6-coordinate geometry to two equivalent Ti(1), one W(2), one W(3), and two equivalent W(1) atoms. In the fourth P site, P(4) is bonded in a 6-coordinate geometry to two equivalent Ti(1), one W(2), one W(3), and two equivalent W(1) atoms.