Li3Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(11), one O(13), one O(3), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-75°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(5), one O(6), and one O(7) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(3), one O(6), and one O(8) atom. In the fourth Li site, Li(4) is bonded to one O(15), one O(17), one O(20), one O(24), and one O(25) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 63-74°. In the fifth Li site, Li(5) is bonded to one O(16), one O(18), one O(22), one O(23), and one O(26) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-77°. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one O(19), one O(2), one O(22), and one O(24) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(13), one O(18), one O(2), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 trigonal bipyramid. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(15), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(21), one O(22), one O(25), and one O(27) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(5)O5 trigonal bipyramid. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(17), one O(19), one O(20), one O(23), and one O(28) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 trigonal bipyramid. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(24), and one O(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(26), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(23), one O(28), and one O(3) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(25), one O(27), and one O(5) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(16), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 41-53°. In the second P site, P(2) is bonded to one O(10), one O(14), one O(17), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 40-51°. In the third P site, P(3) is bonded to one O(13), one O(15), one O(19), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  a cornercorner with one Li(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-50°. In the fourth P site, P(4) is bonded to one O(12), one O(18), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  a cornercorner with one Li(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-50°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Mn(2) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(6), one Mn(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(3), and one C(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one C(4) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Mn(1), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Mn(4), and one P(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal pyramidal geometry to one Li(2), one Li(3), one Mn(2), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(3), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(2), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(5), one Mn(3), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Li(4), one Mn(4), and one P(2) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(5), one Mn(1), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(4), and one P(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Li(4), one Mn(4), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(4) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal pyramidal geometry to one Li(5), one Li(6), one Mn(3), and one P(3) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Li(5), one Mn(4), and one C(3) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal non-coplanar geometry to one Li(4), one Li(6), and one C(1) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Li(4), one Mn(3), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 150 degrees geometry to one Li(5) and one C(2) atom. In the twenty-seventh O site, O(27) is bonded in an L-shaped geometry to one Mn(3) and one C(4) atom. In the twenty-eighth O site, O(28) is bonded in an L-shaped geometry to one Mn(4) and one C(3) atom.
Li3Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(11), one O(13), one O(3), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-75°. The Li(1)-O(10) bond length is 2.19 Å. The Li(1)-O(11) bond length is 2.29 Å. The Li(1)-O(13) bond length is 2.19 Å. The Li(1)-O(3) bond length is 2.01 Å. The Li(1)-O(4) bond length is 2.19 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(5), one O(6), and one O(7) atom. The Li(2)-O(12) bond length is 2.24 Å. The Li(2)-O(14) bond length is 2.22 Å. The Li(2)-O(5) bond length is 1.92 Å. The Li(2)-O(6) bond length is 2.56 Å. The Li(2)-O(7) bond length is 2.04 Å. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(3), one O(6), and one O(8) atom. The Li(3)-O(11) bond length is 2.41 Å. The Li(3)-O(12) bond length is 2.21 Å. The Li(3)-O(3) bond length is 1.98 Å. The Li(3)-O(6) bond length is 2.35 Å. The Li(3)-O(8) bond length is 2.15 Å. In the fourth Li site, Li(4) is bonded to one O(15), one O(17), one O(20), one O(24), and one O(25) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 63-74°. The Li(4)-O(15) bond length is 2.28 Å. The Li(4)-O(17) bond length is 2.21 Å. The Li(4)-O(20) bond length is 2.05 Å. The Li(4)-O(24) bond length is 1.98 Å. The Li(4)-O(25) bond length is 2.39 Å. In the fifth Li site, Li(5) is bonded to one O(16), one O(18), one O(22), one O(23), and one O(26) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-77°. The Li(5)-O(16) bond length is 2.07 Å. The Li(5)-O(18) bond length is 2.27 Å. The Li(5)-O(22) bond length is 2.26 Å. The Li(5)-O(23) bond length is 2.22 Å. The Li(5)-O(26) bond length is 1.95 Å. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one O(19), one O(2), one O(22), and one O(24) atom. The Li(6)-O(19) bond length is 2.03 Å. The Li(6)-O(2) bond length is 2.04 Å. The Li(6)-O(22) bond length is 2.28 Å. The Li(6)-O(24) bond length is 2.04 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(13), one O(18), one O(2), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(1)O5 trigonal bipyramid. The Mn(1)-O(10) bond length is 1.97 Å. The Mn(1)-O(13) bond length is 1.96 Å. The Mn(1)-O(18) bond length is 1.96 Å. The Mn(1)-O(2) bond length is 2.07 Å. The Mn(1)-O(6) bond length is 1.99 Å. The Mn(1)-O(9) bond length is 1.93 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(12), one O(15), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The Mn(2)-O(1) bond length is 2.00 Å. The Mn(2)-O(12) bond length is 2.02 Å. The Mn(2)-O(15) bond length is 1.96 Å. The Mn(2)-O(4) bond length is 2.00 Å. The Mn(2)-O(7) bond length is 2.13 Å. The Mn(2)-O(8) bond length is 2.11 Å. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(21), one O(22), one O(25), and one O(27) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  an edgeedge with one Li(5)O5 trigonal bipyramid. The Mn(3)-O(14) bond length is 1.99 Å. The Mn(3)-O(16) bond length is 1.99 Å. The Mn(3)-O(21) bond length is 1.93 Å. The Mn(3)-O(22) bond length is 2.01 Å. The Mn(3)-O(25) bond length is 1.98 Å. The Mn(3)-O(27) bond length is 2.00 Å. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(17), one O(19), one O(20), one O(23), and one O(28) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(5)O5 trigonal bipyramid, and  an edgeedge with one Li(4)O5 trigonal bipyramid. The Mn(4)-O(11) bond length is 2.05 Å. The Mn(4)-O(17) bond length is 1.97 Å. The Mn(4)-O(19) bond length is 2.10 Å. The Mn(4)-O(20) bond length is 2.15 Å. The Mn(4)-O(23) bond length is 2.00 Å. The Mn(4)-O(28) bond length is 2.01 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(24), and one O(4) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(24) bond length is 1.25 Å. The C(1)-O(4) bond length is 1.32 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(26), and one O(6) atom. The C(2)-O(2) bond length is 1.32 Å. The C(2)-O(26) bond length is 1.24 Å. The C(2)-O(6) bond length is 1.33 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(23), one O(28), and one O(3) atom. The C(3)-O(23) bond length is 1.32 Å. The C(3)-O(28) bond length is 1.31 Å. The C(3)-O(3) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(25), one O(27), and one O(5) atom. The C(4)-O(25) bond length is 1.33 Å. The C(4)-O(27) bond length is 1.32 Å. The C(4)-O(5) bond length is 1.24 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(16), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 41-53°. The P(1)-O(11) bond length is 1.58 Å. The P(1)-O(16) bond length is 1.55 Å. The P(1)-O(7) bond length is 1.52 Å. The P(1)-O(9) bond length is 1.55 Å. In the second P site, P(2) is bonded to one O(10), one O(14), one O(17), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 40-51°. The P(2)-O(10) bond length is 1.57 Å. The P(2)-O(14) bond length is 1.57 Å. The P(2)-O(17) bond length is 1.54 Å. The P(2)-O(8) bond length is 1.53 Å. In the third P site, P(3) is bonded to one O(13), one O(15), one O(19), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  a cornercorner with one Li(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 38-50°. The P(3)-O(13) bond length is 1.55 Å. The P(3)-O(15) bond length is 1.55 Å. The P(3)-O(19) bond length is 1.53 Å. The P(3)-O(22) bond length is 1.57 Å. In the fourth P site, P(4) is bonded to one O(12), one O(18), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Li(4)O5 trigonal bipyramid, and  a cornercorner with one Li(5)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 37-50°. The P(4)-O(12) bond length is 1.56 Å. The P(4)-O(18) bond length is 1.58 Å. The P(4)-O(20) bond length is 1.52 Å. The P(4)-O(21) bond length is 1.54 Å. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Mn(2) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(6), one Mn(1), and one C(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(3), and one C(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Mn(2), and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Li(2) and one C(4) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Mn(1), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(2), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Mn(4), and one P(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal pyramidal geometry to one Li(2), one Li(3), one Mn(2), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(3), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(2), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Li(5), one Mn(3), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Li(4), one Mn(4), and one P(2) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(5), one Mn(1), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Li(6), one Mn(4), and one P(3) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Li(4), one Mn(4), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Mn(3) and one P(4) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal pyramidal geometry to one Li(5), one Li(6), one Mn(3), and one P(3) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Li(5), one Mn(4), and one C(3) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal non-coplanar geometry to one Li(4), one Li(6), and one C(1) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Li(4), one Mn(3), and one C(4) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 150 degrees geometry to one Li(5) and one C(2) atom. In the twenty-seventh O site, O(27) is bonded in an L-shaped geometry to one Mn(3) and one C(4) atom. In the twenty-eighth O site, O(28) is bonded in an L-shaped geometry to one Mn(4) and one C(3) atom.