SrDyV4O12 crystallizes in the orthorhombic Amm2 space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(2), two equivalent O(3), four equivalent O(1), and four equivalent O(5) atoms. Dy(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(1) atoms. V(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form distorted corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 11-30°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1), one Dy(1), and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(1), one Dy(1), and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Sr(1), one Dy(1), and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Dy(1) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Sr(1) and two equivalent V(1) atoms.
SrDyV4O12 crystallizes in the orthorhombic Amm2 space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(2), two equivalent O(3), four equivalent O(1), and four equivalent O(5) atoms. Both Sr(1)-O(2) bond lengths are 2.88 Å. Both Sr(1)-O(3) bond lengths are 3.07 Å. All Sr(1)-O(1) bond lengths are 2.57 Å. There are two shorter (2.55 Å) and two longer (2.94 Å) Sr(1)-O(5) bond lengths. Dy(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and four equivalent O(1) atoms. Both Dy(1)-O(2) bond lengths are 2.47 Å. Both Dy(1)-O(3) bond lengths are 2.58 Å. Both Dy(1)-O(4) bond lengths are 2.22 Å. All Dy(1)-O(1) bond lengths are 2.73 Å. V(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form distorted corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 11-30°. The V(1)-O(2) bond length is 1.94 Å. The V(1)-O(3) bond length is 1.89 Å. The V(1)-O(4) bond length is 1.90 Å. The V(1)-O(5) bond length is 1.88 Å. There is one shorter (1.71 Å) and one longer (2.34 Å) V(1)-O(1) bond length. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1), one Dy(1), and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(1), one Dy(1), and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Sr(1), one Dy(1), and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Dy(1) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to two equivalent Sr(1) and two equivalent V(1) atoms.