(PN2H)2(P(NH2)2)2(NH2)4H2(NH2Cl)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two azane;hydrochloride molecules, four azane;molecular hydrogen molecules, two P(NH2)2 clusters, and two PN2H clusters. In each P(NH2)2 cluster, P(2) is bonded in a 1-coordinate geometry to one N(3) and one N(4) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(3), and one H(8) atom. In the second N site, N(4) is bonded in a 3-coordinate geometry to one P(2), one H(11), and one H(6) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In each PN2H cluster, P(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one N(6) atom. There are two inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one P(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one P(1) and one H(4) atom. H(4) is bonded in a distorted single-bond geometry to one N(2) atom.
(PN2H)2(P(NH2)2)2(NH2)4H2(NH2Cl)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two azane;hydrochloride molecules, four azane;molecular hydrogen molecules, two P(NH2)2 clusters, and two PN2H clusters. In each P(NH2)2 cluster, P(2) is bonded in a 1-coordinate geometry to one N(3) and one N(4) atom. The P(2)-N(3) bond length is 1.17 Å. The P(2)-N(4) bond length is 1.78 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(3), and one H(8) atom. The N(3)-H(3) bond length is 1.11 Å. The N(3)-H(8) bond length is 0.97 Å. In the second N site, N(4) is bonded in a 3-coordinate geometry to one P(2), one H(11), and one H(6) atom. The N(4)-H(11) bond length is 1.29 Å. The N(4)-H(6) bond length is 0.61 Å. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In each PN2H cluster, P(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one N(6) atom. The P(1)-N(2) bond length is 1.64 Å. The P(1)-N(6) bond length is 1.02 Å. There are two inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one P(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one P(1) and one H(4) atom. The N(2)-H(4) bond length is 1.62 Å. H(4) is bonded in a distorted single-bond geometry to one N(2) atom.