Cu(OH)2Cu(H3O2)2(H2)3(HO2)2(H2SO2)2(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, one 20427-59-2 molecule, one copper;tetrahydrate molecule, two hydrogen peroxide molecules, two hydrogen peroxide molecules, and two H2SO2 clusters. In each H2SO2 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. S(1) is bonded in a trigonal non-coplanar geometry to one H(1), one O(5), and one O(6) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(6) is bonded in a 2-coordinate geometry to one H(2) and one S(1) atom.
Cu(OH)2Cu(H3O2)2(H2)3(HO2)2(H2SO2)2(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, one 20427-59-2 molecule, one copper;tetrahydrate molecule, two hydrogen peroxide molecules, two hydrogen peroxide molecules, and two H2SO2 clusters. In each H2SO2 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(1) atom. The H(1)-S(1) bond length is 1.39 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. The H(2)-O(6) bond length is 0.99 Å. S(1) is bonded in a trigonal non-coplanar geometry to one H(1), one O(5), and one O(6) atom. The S(1)-O(5) bond length is 1.48 Å. The S(1)-O(6) bond length is 1.69 Å. There are two inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(6) is bonded in a 2-coordinate geometry to one H(2) and one S(1) atom.