DyRhO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 39-43°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Dy(1) and two equivalent Rh(1) atoms. In the second O site, O(2) is bonded to two equivalent Dy(1) and two equivalent Rh(1) atoms to form distorted corner-sharing ODy2Rh2 trigonal pyramids.
DyRhO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.21 Å) and one longer (2.27 Å) Dy(1)-O(2) bond length. There are a spread of Dy(1)-O(1) bond distances ranging from 2.26-2.66 Å. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 39-43°. Both Rh(1)-O(2) bond lengths are 2.04 Å. There are two shorter (2.06 Å) and two longer (2.07 Å) Rh(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Dy(1) and two equivalent Rh(1) atoms. In the second O site, O(2) is bonded to two equivalent Dy(1) and two equivalent Rh(1) atoms to form distorted corner-sharing ODy2Rh2 trigonal pyramids.