V5Te4 is Titanium telluride structured and crystallizes in the tetragonal I4/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to eight equivalent V(2) and four equivalent Te(1) atoms to form face-sharing VV8Te4 cuboctahedra. In the second V site, V(2) is bonded in a 9-coordinate geometry to two equivalent V(1), two equivalent V(2), and five equivalent Te(1) atoms. Te(1) is bonded in a 6-coordinate geometry to one V(1) and five equivalent V(2) atoms.
V5Te4 is Titanium telluride structured and crystallizes in the tetragonal I4/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to eight equivalent V(2) and four equivalent Te(1) atoms to form face-sharing VV8Te4 cuboctahedra. All V(1)-V(2) bond lengths are 2.67 Å. All V(1)-Te(1) bond lengths are 2.77 Å. In the second V site, V(2) is bonded in a 9-coordinate geometry to two equivalent V(1), two equivalent V(2), and five equivalent Te(1) atoms. Both V(2)-V(2) bond lengths are 2.52 Å. There are a spread of V(2)-Te(1) bond distances ranging from 2.78-2.89 Å. Te(1) is bonded in a 6-coordinate geometry to one V(1) and five equivalent V(2) atoms.