CsWSbO6 crystallizes in the orthorhombic Ima2 space group. Cs(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CsO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-74°. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-74°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-70°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one W(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one W(1), and one Sb(1) atom.
CsWSbO6 crystallizes in the orthorhombic Ima2 space group. Cs(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CsO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-74°. The Cs(1)-O(1) bond length is 3.10 Å. The Cs(1)-O(2) bond length is 3.41 Å. Both Cs(1)-O(3) bond lengths are 3.31 Å. Both Cs(1)-O(4) bond lengths are 3.17 Å. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-74°. There is one shorter (1.95 Å) and one longer (1.97 Å) W(1)-O(2) bond length. Both W(1)-O(3) bond lengths are 1.94 Å. Both W(1)-O(4) bond lengths are 1.94 Å. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-70°. Both Sb(1)-O(1) bond lengths are 1.99 Å. Both Sb(1)-O(3) bond lengths are 2.01 Å. Both Sb(1)-O(4) bond lengths are 2.01 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one W(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one W(1), and one Sb(1) atom.