CsReO4 crystallizes in the tetragonal I4_1/amd space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. Re(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Re(1) atom.
CsReO4 crystallizes in the tetragonal I4_1/amd space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. There are four shorter (3.09 Å) and eight longer (3.47 Å) Cs(1)-O(1) bond lengths. Re(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All Re(1)-O(1) bond lengths are 1.74 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Re(1) atom.