Li4CO4 crystallizes in the tetragonal I-42m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. C(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one C(1) atom.
Li4CO4 crystallizes in the tetragonal I-42m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are a spread of Li(1)-O(1) bond distances ranging from 1.90-2.09 Å. C(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. All C(1)-O(1) bond lengths are 1.42 Å. O(1) is bonded in a 5-coordinate geometry to four equivalent Li(1) and one C(1) atom.