Na2Ti2Sb2O crystallizes in the tetragonal I4/mmm space group. Na(1) is bonded in a 6-coordinate geometry to five equivalent Sb(1) and one O(1) atom. Ti(1) is bonded in a linear geometry to four equivalent Sb(1) and two equivalent O(1) atoms. Sb(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Ti(1) atoms. O(1) is bonded in a square co-planar geometry to two equivalent Na(1) and four equivalent Ti(1) atoms.
Na2Ti2Sb2O crystallizes in the tetragonal I4/mmm space group. Na(1) is bonded in a 6-coordinate geometry to five equivalent Sb(1) and one O(1) atom. There are four shorter (3.12 Å) and one longer (3.30 Å) Na(1)-Sb(1) bond length. The Na(1)-O(1) bond length is 3.07 Å. Ti(1) is bonded in a linear geometry to four equivalent Sb(1) and two equivalent O(1) atoms. All Ti(1)-Sb(1) bond lengths are 2.90 Å. Both Ti(1)-O(1) bond lengths are 2.08 Å. Sb(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Ti(1) atoms. O(1) is bonded in a square co-planar geometry to two equivalent Na(1) and four equivalent Ti(1) atoms.