(CN2S)2C2Te(N2Cl)2(SO)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules, four sulfur monoxide molecules, and two C2Te(N2Cl)2 clusters. In each C2Te(N2Cl)2 cluster, C(1) is bonded in a distorted bent 150 degrees geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one Cl(1) atom. Te(1) is bonded in a 2-coordinate geometry to two equivalent N(1) atoms. Cl(1) is bonded in a single-bond geometry to one N(2) atom.
(CN2S)2C2Te(N2Cl)2(SO)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules, four sulfur monoxide molecules, and two C2Te(N2Cl)2 clusters. In each C2Te(N2Cl)2 cluster, C(1) is bonded in a distorted bent 150 degrees geometry to one N(1) and one N(2) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(2) bond length is 1.31 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. The N(1)-Te(1) bond length is 2.07 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one Cl(1) atom. The N(2)-Cl(1) bond length is 1.69 Å. Te(1) is bonded in a 2-coordinate geometry to two equivalent N(1) atoms. Cl(1) is bonded in a single-bond geometry to one N(2) atom.