SrF2 is Baddeleyite-like structured and crystallizes in the orthorhombic Pnma space group. Sr(1) is bonded to three equivalent F(1) and four equivalent F(2) atoms to form a mixture of distorted corner and edge-sharing SrF7 hexagonal pyramids. There are two inequivalent F sites. In the first F site, F(2) is bonded to four equivalent Sr(1) atoms to form a mixture of corner and edge-sharing FSr4 tetrahedra. In the second F site, F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Sr(1) atoms.
SrF2 is Baddeleyite-like structured and crystallizes in the orthorhombic Pnma space group. Sr(1) is bonded to three equivalent F(1) and four equivalent F(2) atoms to form a mixture of distorted corner and edge-sharing SrF7 hexagonal pyramids. There are two shorter (2.44 Å) and one longer (2.46 Å) Sr(1)-F(1) bond length. There are a spread of Sr(1)-F(2) bond distances ranging from 2.47-2.62 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded to four equivalent Sr(1) atoms to form a mixture of corner and edge-sharing FSr4 tetrahedra. In the second F site, F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Sr(1) atoms.