RuF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ruthenium hexafluoride molecules. Ru(1) is bonded in an octahedral geometry to two equivalent F(1,2); two equivalent F(3); and two equivalent F(4) atoms. There are three inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Ru(1) atom. In the second F site, F(1,2) is bonded in a single-bond geometry to one Ru(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ru(1) atom.
RuF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ruthenium hexafluoride molecules. Ru(1) is bonded in an octahedral geometry to two equivalent F(1,2); two equivalent F(3); and two equivalent F(4) atoms. There is one shorter (1.83 Å) and one longer (1.84 Å) Ru(1)-F(1,2) bond length. Both Ru(1)-F(3) bond lengths are 1.83 Å. Both Ru(1)-F(4) bond lengths are 1.83 Å. There are three inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Ru(1) atom. In the second F site, F(1,2) is bonded in a single-bond geometry to one Ru(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ru(1) atom.