PrPd3B is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Pr(1) is bonded to twelve equivalent Pd(1) atoms to form PrPd12 cuboctahedra that share corners with twelve equivalent Pr(1)Pd12 cuboctahedra, faces with six equivalent Pr(1)Pd12 cuboctahedra, and faces with eight equivalent B(1)Pd6 octahedra. Pd(1) is bonded to four equivalent Pr(1) and two equivalent B(1) atoms to form a mixture of distorted edge, corner, and face-sharing PdPr4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. B(1) is bonded to six equivalent Pd(1) atoms to form BPd6 octahedra that share corners with six equivalent B(1)Pd6 octahedra and faces with eight equivalent Pr(1)Pd12 cuboctahedra. The corner-sharing octahedra are not tilted.
PrPd3B is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Pr(1) is bonded to twelve equivalent Pd(1) atoms to form PrPd12 cuboctahedra that share corners with twelve equivalent Pr(1)Pd12 cuboctahedra, faces with six equivalent Pr(1)Pd12 cuboctahedra, and faces with eight equivalent B(1)Pd6 octahedra. All Pr(1)-Pd(1) bond lengths are 3.11 Å. Pd(1) is bonded to four equivalent Pr(1) and two equivalent B(1) atoms to form a mixture of distorted edge, corner, and face-sharing PdPr4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. Both Pd(1)-B(1) bond lengths are 2.20 Å. B(1) is bonded to six equivalent Pd(1) atoms to form BPd6 octahedra that share corners with six equivalent B(1)Pd6 octahedra and faces with eight equivalent Pr(1)Pd12 cuboctahedra. The corner-sharing octahedra are not tilted.