Ba2TmRuO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Tm(1)O6 octahedra, and faces with four equivalent Ru(1)O6 octahedra. Tm(1) is bonded to six equivalent O(1) atoms to form TmO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Tm(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to four equivalent Ba(1), one Tm(1), and one Ru(1) atom.
Ba2TmRuO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Tm(1)O6 octahedra, and faces with four equivalent Ru(1)O6 octahedra. All Ba(1)-O(1) bond lengths are 2.97 Å. Tm(1) is bonded to six equivalent O(1) atoms to form TmO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Tm(1)-O(1) bond lengths are 2.21 Å. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Tm(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ru(1)-O(1) bond lengths are 1.99 Å. O(1) is bonded in a distorted linear geometry to four equivalent Ba(1), one Tm(1), and one Ru(1) atom.