NaHF2 crystallizes in the monoclinic C2 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. H(1) is bonded in a linear geometry to two equivalent F(1) atoms. F(1) is bonded in a distorted single-bond geometry to three equivalent Na(1) and one H(1) atom.
NaHF2 crystallizes in the monoclinic C2 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent F(1) atoms. There are a spread of Na(1)-F(1) bond distances ranging from 2.30-2.47 Å. H(1) is bonded in a linear geometry to two equivalent F(1) atoms. Both H(1)-F(1) bond lengths are 1.15 Å. F(1) is bonded in a distorted single-bond geometry to three equivalent Na(1) and one H(1) atom.