AgBiO2 crystallizes in the hexagonal P6_3/mmc space group. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. O(1) is bonded to one Ag(1) and three equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OAgBi3 tetrahedra.
AgBiO2 crystallizes in the hexagonal P6_3/mmc space group. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.09 Å. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. All Bi(1)-O(1) bond lengths are 2.41 Å. O(1) is bonded to one Ag(1) and three equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OAgBi3 tetrahedra.