PrSO crystallizes in the monoclinic C2/m space group. Pr(1) is bonded in a 4-coordinate geometry to five equivalent S(1) and four equivalent O(1) atoms. S(1) is bonded in a 6-coordinate geometry to five equivalent Pr(1) and one S(1) atom. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of corner and edge-sharing OPr4 tetrahedra.
PrSO crystallizes in the monoclinic C2/m space group. Pr(1) is bonded in a 4-coordinate geometry to five equivalent S(1) and four equivalent O(1) atoms. There are a spread of Pr(1)-S(1) bond distances ranging from 3.09-3.34 Å. There are two shorter (2.36 Å) and two longer (2.39 Å) Pr(1)-O(1) bond lengths. S(1) is bonded in a 6-coordinate geometry to five equivalent Pr(1) and one S(1) atom. The S(1)-S(1) bond length is 2.10 Å. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of corner and edge-sharing OPr4 tetrahedra.