CrSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. Cr(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CrO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent Cr(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Cr(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cr(1) and two equivalent Sb(1) atoms.
CrSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. Cr(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CrO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Both Cr(1)-O(2) bond lengths are 2.00 Å. All Cr(1)-O(1) bond lengths are 1.98 Å. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent Cr(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Both Sb(1)-O(1) bond lengths are 1.95 Å. All Sb(1)-O(2) bond lengths are 2.00 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Cr(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cr(1) and two equivalent Sb(1) atoms.