Na3Pt crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a distorted see-saw-like geometry to four equivalent Pt(1) atoms. Pt(1) is bonded to twelve equivalent Na(1) atoms to form a mixture of face and corner-sharing PtNa12 cuboctahedra.
Na3Pt crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a distorted see-saw-like geometry to four equivalent Pt(1) atoms. There are two shorter (3.10 Å) and two longer (3.19 Å) Na(1)-Pt(1) bond lengths. Pt(1) is bonded to twelve equivalent Na(1) atoms to form a mixture of face and corner-sharing PtNa12 cuboctahedra.