LiAg3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to four equivalent Ag(2) and eight equivalent Ag(1) atoms to form a mixture of face, corner, and edge-sharing LiAg12 cuboctahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Li(1) atoms to form a mixture of distorted corner and edge-sharing AgLi4 cuboctahedra. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to four equivalent Li(1) atoms.
LiAg3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to four equivalent Ag(2) and eight equivalent Ag(1) atoms to form a mixture of face, corner, and edge-sharing LiAg12 cuboctahedra. All Li(1)-Ag(2) bond lengths are 2.86 Å. All Li(1)-Ag(1) bond lengths are 2.86 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Li(1) atoms to form a mixture of distorted corner and edge-sharing AgLi4 cuboctahedra. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to four equivalent Li(1) atoms.