TlMnCl3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a MnCl3 framework. In the MnCl3 framework, Mn(1) is bonded to two equivalent Cl(2) and four equivalent Cl(1) atoms to form corner-sharing MnCl6 octahedra. The corner-sharing octahedral tilt angles range from 12-16°. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Mn(1) atoms.
TlMnCl3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a MnCl3 framework. In the MnCl3 framework, Mn(1) is bonded to two equivalent Cl(2) and four equivalent Cl(1) atoms to form corner-sharing MnCl6 octahedra. The corner-sharing octahedral tilt angles range from 12-16°. Both Mn(1)-Cl(2) bond lengths are 2.53 Å. All Mn(1)-Cl(1) bond lengths are 2.52 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Mn(1) atoms.