Ce2Pd2In crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Pd(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Ce(1) and four equivalent Pd(1) atoms to form a mixture of corner and face-sharing InCe8Pd4 cuboctahedra.
Ce2Pd2In crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. There are two shorter (2.90 Å) and four longer (3.08 Å) Ce(1)-Pd(1) bond lengths. All Ce(1)-In(1) bond lengths are 3.47 Å. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Pd(1), and two equivalent In(1) atoms. The Pd(1)-Pd(1) bond length is 2.86 Å. Both Pd(1)-In(1) bond lengths are 3.07 Å. In(1) is bonded to eight equivalent Ce(1) and four equivalent Pd(1) atoms to form a mixture of corner and face-sharing InCe8Pd4 cuboctahedra.