NdPdIn crystallizes in the hexagonal P-62m space group. Nd(1) is bonded in a 11-coordinate geometry to one Pd(2), four equivalent Pd(1), and six equivalent In(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent In(1) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to three equivalent Nd(1) and six equivalent In(1) atoms. In(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.
NdPdIn crystallizes in the hexagonal P-62m space group. Nd(1) is bonded in a 11-coordinate geometry to one Pd(2), four equivalent Pd(1), and six equivalent In(1) atoms. The Nd(1)-Pd(2) bond length is 3.22 Å. All Nd(1)-Pd(1) bond lengths are 3.08 Å. There are two shorter (3.28 Å) and four longer (3.44 Å) Nd(1)-In(1) bond lengths. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to six equivalent Nd(1) and three equivalent In(1) atoms. All Pd(1)-In(1) bond lengths are 2.97 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to three equivalent Nd(1) and six equivalent In(1) atoms. All Pd(2)-In(1) bond lengths are 2.80 Å. In(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.