CrSnSbO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Cr(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CrO6 octahedra that share corners with four equivalent Sn(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. Sn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SnO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cr(1), one Sn(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cr(1), one Sn(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cr(1), one Sn(1), and one Sb(1) atom.
CrSnSbO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Cr(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CrO6 octahedra that share corners with four equivalent Sn(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. Both Cr(1)-O(1) bond lengths are 2.03 Å. Both Cr(1)-O(2) bond lengths are 2.03 Å. Both Cr(1)-O(3) bond lengths are 2.03 Å. Sn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SnO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. Both Sn(1)-O(1) bond lengths are 2.09 Å. Both Sn(1)-O(2) bond lengths are 2.08 Å. Both Sn(1)-O(3) bond lengths are 2.08 Å. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. Both Sb(1)-O(1) bond lengths are 2.01 Å. Both Sb(1)-O(2) bond lengths are 2.01 Å. Both Sb(1)-O(3) bond lengths are 2.02 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Cr(1), one Sn(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cr(1), one Sn(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cr(1), one Sn(1), and one Sb(1) atom.