NaSr3BiO6 crystallizes in the trigonal R-3c space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Bi(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to one Na(1), four equivalent Sr(1), and one Bi(1) atom.
NaSr3BiO6 crystallizes in the trigonal R-3c space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.49 Å. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are a spread of Sr(1)-O(1) bond distances ranging from 2.50-3.08 Å. Bi(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Bi(1)-O(1) bond lengths are 2.15 Å. O(1) is bonded in a 6-coordinate geometry to one Na(1), four equivalent Sr(1), and one Bi(1) atom.