CaRhSn2 crystallizes in the orthorhombic Cmcm space group. Ca(1) is bonded in a 13-coordinate geometry to three equivalent Rh(1) and ten equivalent Sn(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to three equivalent Ca(1) and six equivalent Sn(1) atoms. Sn(1) is bonded in a 5-coordinate geometry to five equivalent Ca(1) and three equivalent Rh(1) atoms.
CaRhSn2 crystallizes in the orthorhombic Cmcm space group. Ca(1) is bonded in a 13-coordinate geometry to three equivalent Rh(1) and ten equivalent Sn(1) atoms. There is one shorter (3.00 Å) and two longer (3.27 Å) Ca(1)-Rh(1) bond lengths. There are a spread of Ca(1)-Sn(1) bond distances ranging from 3.25-3.53 Å. Rh(1) is bonded in a 9-coordinate geometry to three equivalent Ca(1) and six equivalent Sn(1) atoms. There are two shorter (2.73 Å) and four longer (2.75 Å) Rh(1)-Sn(1) bond lengths. Sn(1) is bonded in a 5-coordinate geometry to five equivalent Ca(1) and three equivalent Rh(1) atoms.