LiVO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent V(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. O(1) is bonded to three equivalent Li(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing OLi3V3 octahedra. The corner-sharing octahedra are not tilted.
LiVO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent V(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. All Li(1)-O(1) bond lengths are 2.11 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 3°. All V(1)-O(1) bond lengths are 2.02 Å. O(1) is bonded to three equivalent Li(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing OLi3V3 octahedra. The corner-sharing octahedra are not tilted.