AgCoO2 crystallizes in the trigonal R-3m space group. Co(1) is bonded to six equivalent O(1) atoms to form edge-sharing CoO6 octahedra. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent Co(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing OCo3Ag tetrahedra.
AgCoO2 crystallizes in the trigonal R-3m space group. Co(1) is bonded to six equivalent O(1) atoms to form edge-sharing CoO6 octahedra. All Co(1)-O(1) bond lengths are 2.03 Å. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.10 Å. O(1) is bonded to three equivalent Co(1) and one Ag(1) atom to form a mixture of distorted edge and corner-sharing OCo3Ag tetrahedra.