RbNO2 crystallizes in the trigonal P3_121 space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent N(1) and eight equivalent O(1) atoms. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one N(1) atom.
RbNO2 crystallizes in the trigonal P3_121 space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent N(1) and eight equivalent O(1) atoms. Both Rb(1)-N(1) bond lengths are 3.22 Å. There are a spread of Rb(1)-O(1) bond distances ranging from 2.91-3.36 Å. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.26 Å. O(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one N(1) atom.