BaFe2P2 crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. Fe(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing FeP4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Fe(1) atoms.
BaFe2P2 crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. All Ba(1)-P(1) bond lengths are 3.36 Å. Fe(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing FeP4 tetrahedra. All Fe(1)-P(1) bond lengths are 2.18 Å. P(1) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Fe(1) atoms.