CuCNH2S2 crystallizes in the orthorhombic P2_12_12_1 space group. Cu(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing CuS4 tetrahedra. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom.
CuCNH2S2 crystallizes in the orthorhombic P2_12_12_1 space group. Cu(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing CuS4 tetrahedra. Both Cu(1)-S(1) bond lengths are 2.28 Å. There is one shorter (2.38 Å) and one longer (2.42 Å) Cu(1)-S(2) bond length. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.72 Å. The C(1)-S(2) bond length is 1.74 Å. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.02 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom.