(Na)2LiTlCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a LiTlCl6 framework. In the LiTlCl6 framework, Li(1) is bonded to six equivalent Cl(1) atoms to form LiCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent Li(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Li(1) and one Tl(1) atom.
(Na)2LiTlCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a LiTlCl6 framework. In the LiTlCl6 framework, Li(1) is bonded to six equivalent Cl(1) atoms to form LiCl6 octahedra that share corners with six equivalent Tl(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Li(1)-Cl(1) bond lengths are 2.49 Å. Tl(1) is bonded to six equivalent Cl(1) atoms to form TlCl6 octahedra that share corners with six equivalent Li(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Cl(1) bond lengths are 2.57 Å. Cl(1) is bonded in a linear geometry to one Li(1) and one Tl(1) atom.