LiCo(WO4)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-55°. In the second W site, W(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-56°. Co(1) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one W(2), and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Co(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Co(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one W(2), and one Co(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal pyramidal geometry to one Li(1), one W(1), one W(2), and one Co(1) atom.
LiCo(WO4)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. The Li(1)-O(1) bond length is 2.42 Å. The Li(1)-O(3) bond length is 2.04 Å. The Li(1)-O(4) bond length is 1.96 Å. The Li(1)-O(5) bond length is 2.11 Å. The Li(1)-O(7) bond length is 2.15 Å. The Li(1)-O(8) bond length is 2.19 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-55°. The W(1)-O(1) bond length is 1.88 Å. The W(1)-O(2) bond length is 2.05 Å. The W(1)-O(3) bond length is 1.82 Å. The W(1)-O(4) bond length is 1.87 Å. The W(1)-O(5) bond length is 2.18 Å. The W(1)-O(8) bond length is 2.04 Å. In the second W site, W(2) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-56°. The W(2)-O(2) bond length is 2.05 Å. The W(2)-O(4) bond length is 2.20 Å. The W(2)-O(5) bond length is 1.86 Å. The W(2)-O(6) bond length is 1.80 Å. The W(2)-O(7) bond length is 1.89 Å. The W(2)-O(8) bond length is 2.08 Å. Co(1) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. The Co(1)-O(1) bond length is 1.88 Å. The Co(1)-O(2) bond length is 2.10 Å. The Co(1)-O(3) bond length is 2.13 Å. The Co(1)-O(6) bond length is 2.02 Å. The Co(1)-O(7) bond length is 1.90 Å. The Co(1)-O(8) bond length is 2.26 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one W(2), and one Co(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Co(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one W(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Co(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one W(2), and one Co(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal pyramidal geometry to one Li(1), one W(1), one W(2), and one Co(1) atom.