Li5Ni5(SbO6)2 is alpha Po-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(4)O6 octahedra, and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(3)O6 octahedra, and edges with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. In the second Ni site, Ni(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form NiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the third Ni site, Ni(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the fourth Ni site, Ni(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second Sb site, Sb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with three equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ni(2), one Ni(4), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(1)Li3Ni2Sb octahedra, and edges with four equivalent O(3)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), one Ni(3), and one Sb(2) atom to form OLi2Ni3Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(2)Li2Ni3Sb octahedra, and edges with four equivalent O(4)Li2Ni3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ni(2), one Ni(4), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra, edges with four equivalent O(3)Li3Ni2Sb octahedra, and edges with four equivalent O(5)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), one Ni(3), and one Sb(2) atom to form OLi2Ni3Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(4)Li2Ni3Sb octahedra, and edges with four equivalent O(6)Li2Ni3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ni(2), one Ni(4), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra, edges with four equivalent O(1)Li3Ni2Sb octahedra, and edges with four equivalent O(5)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), one Ni(3), and one Sb(2) atom to form OLi2Ni3Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(2)Li2Ni3Sb octahedra, and edges with four equivalent O(6)Li2Ni3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-7°.
Li5Ni5(SbO6)2 is alpha Po-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. The Li(1)-O(1) bond length is 2.21 Å. The Li(1)-O(2) bond length is 2.30 Å. The Li(1)-O(3) bond length is 2.09 Å. The Li(1)-O(4) bond length is 2.15 Å. The Li(1)-O(5) bond length is 2.21 Å. The Li(1)-O(6) bond length is 2.15 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. The Li(2)-O(1) bond length is 2.13 Å. The Li(2)-O(2) bond length is 2.27 Å. The Li(2)-O(3) bond length is 2.20 Å. The Li(2)-O(4) bond length is 2.18 Å. The Li(2)-O(5) bond length is 2.14 Å. The Li(2)-O(6) bond length is 2.19 Å. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(4)O6 octahedra, and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. Both Li(3)-O(1) bond lengths are 2.23 Å. Both Li(3)-O(3) bond lengths are 2.13 Å. Both Li(3)-O(5) bond lengths are 2.16 Å. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(3)O6 octahedra, and edges with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. Both Ni(1)-O(2) bond lengths are 2.10 Å. Both Ni(1)-O(4) bond lengths are 2.09 Å. Both Ni(1)-O(6) bond lengths are 2.17 Å. In the second Ni site, Ni(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form NiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. The Ni(2)-O(1) bond length is 2.08 Å. The Ni(2)-O(2) bond length is 2.12 Å. The Ni(2)-O(3) bond length is 2.13 Å. The Ni(2)-O(4) bond length is 2.17 Å. The Ni(2)-O(5) bond length is 2.19 Å. The Ni(2)-O(6) bond length is 2.12 Å. In the third Ni site, Ni(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. Both Ni(3)-O(2) bond lengths are 2.10 Å. Both Ni(3)-O(4) bond lengths are 2.18 Å. Both Ni(3)-O(6) bond lengths are 2.09 Å. In the fourth Ni site, Ni(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. Both Ni(4)-O(1) bond lengths are 2.08 Å. Both Ni(4)-O(3) bond lengths are 2.16 Å. Both Ni(4)-O(5) bond lengths are 2.10 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. Both Sb(1)-O(1) bond lengths are 2.02 Å. Both Sb(1)-O(3) bond lengths are 2.01 Å. Both Sb(1)-O(5) bond lengths are 2.02 Å. In the second Sb site, Sb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with three equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. Both Sb(2)-O(2) bond lengths are 2.12 Å. Both Sb(2)-O(4) bond lengths are 2.12 Å. Both Sb(2)-O(6) bond lengths are 2.13 Å. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ni(2), one Ni(4), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(1)Li3Ni2Sb octahedra, and edges with four equivalent O(3)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), one Ni(3), and one Sb(2) atom to form OLi2Ni3Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(2)Li2Ni3Sb octahedra, and edges with four equivalent O(4)Li2Ni3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ni(2), one Ni(4), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra, edges with four equivalent O(3)Li3Ni2Sb octahedra, and edges with four equivalent O(5)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), one Ni(3), and one Sb(2) atom to form OLi2Ni3Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(4)Li2Ni3Sb octahedra, and edges with four equivalent O(6)Li2Ni3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ni(2), one Ni(4), and one Sb(1) atom to form OLi3Ni2Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(2)Li2Ni3Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(6)Li2Ni3Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra, edges with four equivalent O(1)Li3Ni2Sb octahedra, and edges with four equivalent O(5)Li3Ni2Sb octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), one Ni(3), and one Sb(2) atom to form OLi2Ni3Sb octahedra that share  a cornercorner with one O(2)Li2Ni3Sb octahedra,  a cornercorner with one O(4)Li2Ni3Sb octahedra,  a cornercorner with one O(6)Li2Ni3Sb octahedra,  a cornercorner with one O(1)Li3Ni2Sb octahedra,  a cornercorner with one O(3)Li3Ni2Sb octahedra,  a cornercorner with one O(5)Li3Ni2Sb octahedra,  an edgeedge with one O(4)Li2Ni3Sb octahedra,  an edgeedge with one O(1)Li3Ni2Sb octahedra,  an edgeedge with one O(3)Li3Ni2Sb octahedra,  an edgeedge with one O(5)Li3Ni2Sb octahedra, edges with four equivalent O(2)Li2Ni3Sb octahedra, and edges with four equivalent O(6)Li2Ni3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-7°.