Ce2BiO2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 4-coordinate geometry to four equivalent Bi(1) and four equivalent O(1) atoms. Bi(1) is bonded in a body-centered cubic geometry to eight equivalent Ce(1) atoms. O(1) is bonded to four equivalent Ce(1) atoms to form a mixture of corner and edge-sharing OCe4 tetrahedra.
Ce2BiO2 is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 4-coordinate geometry to four equivalent Bi(1) and four equivalent O(1) atoms. All Ce(1)-Bi(1) bond lengths are 3.55 Å. All Ce(1)-O(1) bond lengths are 2.34 Å. Bi(1) is bonded in a body-centered cubic geometry to eight equivalent Ce(1) atoms. O(1) is bonded to four equivalent Ce(1) atoms to form a mixture of corner and edge-sharing OCe4 tetrahedra.