LiV2P4(HO8)2 crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(21), one O(24), one O(5), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 79°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(23), one O(27), and one O(3) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles are 78°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(2)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(13), one O(16), one O(17), one O(21), one O(28), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. In the third V site, V(3) is bonded to one O(12), one O(15), one O(18), one O(20), one O(27), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(2)O5 trigonal bipyramid. In the fourth V site, V(4) is bonded to one O(22), one O(25), one O(26), one O(29), one O(30), and one O(31) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(16), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 14-47°. In the second P site, P(2) is bonded to one O(15), one O(29), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-47°. In the third P site, P(3) is bonded to one O(14), one O(20), one O(22), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 12-52°. In the fourth P site, P(4) is bonded to one O(1), one O(2), one O(21), and one O(30) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 14-45°. In the fifth P site, P(5) is bonded to one O(11), one O(12), one O(19), and one O(25) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 15-45°. In the sixth P site, P(6) is bonded to one O(13), one O(3), one O(31), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 15-50°. In the seventh P site, P(7) is bonded to one O(17), one O(23), one O(26), and one O(27) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-49°. In the eighth P site, P(8) is bonded to one O(18), one O(24), one O(28), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-44°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(23) and one O(9) atom. In the second H site, H(2) is bonded in a linear geometry to one O(10) and one O(24) atom. In the third H site, H(3) is bonded in a linear geometry to one O(14) and one O(19) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(4) and one H(4) atom. In the second O site, O(2) is bonded in a linear geometry to one V(1) and one P(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(2), one V(1), and one P(6) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(8) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Li(1), one V(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a linear geometry to one V(3) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one P(2), and one H(1) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Li(2), one P(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one V(1) and one P(5) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(2), one V(3), and one P(5) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one V(2) and one P(6) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one P(3) and one H(3) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one V(3) and one P(2) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(1) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(8) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one P(5) and one H(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(3) and one P(3) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a linear geometry to one V(4) and one P(3) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(2), one P(7), and one H(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Li(1), one P(8), and one H(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one V(4) and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one V(4) and one P(7) atom. In the twenty-seventh O site, O(27) is bonded in a T-shaped geometry to one Li(2), one V(3), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one V(2) and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one V(4) and one P(2) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 150 degrees geometry to one V(4) and one P(4) atom. In the thirty-first O site, O(31) is bonded in a linear geometry to one V(4) and one P(6) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one P(6) and one H(4) atom.
LiV2P4(HO8)2 crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(21), one O(24), one O(5), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 79°. The Li(1)-O(21) bond length is 2.12 Å. The Li(1)-O(24) bond length is 1.97 Å. The Li(1)-O(5) bond length is 2.01 Å. The Li(1)-O(8) bond length is 1.98 Å. The Li(1)-O(9) bond length is 2.21 Å. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(23), one O(27), and one O(3) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles are 78°. The Li(2)-O(10) bond length is 1.94 Å. The Li(2)-O(12) bond length is 2.11 Å. The Li(2)-O(23) bond length is 2.21 Å. The Li(2)-O(27) bond length is 2.01 Å. The Li(2)-O(3) bond length is 2.00 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The V(1)-O(11) bond length is 1.87 Å. The V(1)-O(2) bond length is 1.85 Å. The V(1)-O(3) bond length is 2.01 Å. The V(1)-O(4) bond length is 1.98 Å. The V(1)-O(7) bond length is 1.96 Å. The V(1)-O(8) bond length is 2.05 Å. In the second V site, V(2) is bonded to one O(13), one O(16), one O(17), one O(21), one O(28), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. The V(2)-O(13) bond length is 1.94 Å. The V(2)-O(16) bond length is 1.95 Å. The V(2)-O(17) bond length is 2.00 Å. The V(2)-O(21) bond length is 2.04 Å. The V(2)-O(28) bond length is 1.86 Å. The V(2)-O(5) bond length is 1.94 Å. In the third V site, V(3) is bonded to one O(12), one O(15), one O(18), one O(20), one O(27), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The V(3)-O(12) bond length is 2.05 Å. The V(3)-O(15) bond length is 1.91 Å. The V(3)-O(18) bond length is 1.92 Å. The V(3)-O(20) bond length is 1.83 Å. The V(3)-O(27) bond length is 1.97 Å. The V(3)-O(6) bond length is 1.80 Å. In the fourth V site, V(4) is bonded to one O(22), one O(25), one O(26), one O(29), one O(30), and one O(31) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The V(4)-O(22) bond length is 1.89 Å. The V(4)-O(25) bond length is 1.97 Å. The V(4)-O(26) bond length is 1.92 Å. The V(4)-O(29) bond length is 1.92 Å. The V(4)-O(30) bond length is 1.88 Å. The V(4)-O(31) bond length is 1.86 Å. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(16), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 14-47°. The P(1)-O(10) bond length is 1.52 Å. The P(1)-O(16) bond length is 1.53 Å. The P(1)-O(6) bond length is 1.60 Å. The P(1)-O(7) bond length is 1.53 Å. In the second P site, P(2) is bonded to one O(15), one O(29), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-47°. The P(2)-O(15) bond length is 1.57 Å. The P(2)-O(29) bond length is 1.55 Å. The P(2)-O(5) bond length is 1.56 Å. The P(2)-O(9) bond length is 1.51 Å. In the third P site, P(3) is bonded to one O(14), one O(20), one O(22), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 12-52°. The P(3)-O(14) bond length is 1.49 Å. The P(3)-O(20) bond length is 1.61 Å. The P(3)-O(22) bond length is 1.55 Å. The P(3)-O(8) bond length is 1.56 Å. In the fourth P site, P(4) is bonded to one O(1), one O(2), one O(21), and one O(30) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 14-45°. The P(4)-O(1) bond length is 1.49 Å. The P(4)-O(2) bond length is 1.57 Å. The P(4)-O(21) bond length is 1.55 Å. The P(4)-O(30) bond length is 1.59 Å. In the fifth P site, P(5) is bonded to one O(11), one O(12), one O(19), and one O(25) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 15-45°. The P(5)-O(11) bond length is 1.56 Å. The P(5)-O(12) bond length is 1.56 Å. The P(5)-O(19) bond length is 1.52 Å. The P(5)-O(25) bond length is 1.56 Å. In the sixth P site, P(6) is bonded to one O(13), one O(3), one O(31), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 15-50°. The P(6)-O(13) bond length is 1.53 Å. The P(6)-O(3) bond length is 1.56 Å. The P(6)-O(31) bond length is 1.56 Å. The P(6)-O(32) bond length is 1.53 Å. In the seventh P site, P(7) is bonded to one O(17), one O(23), one O(26), and one O(27) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 20-49°. The P(7)-O(17) bond length is 1.53 Å. The P(7)-O(23) bond length is 1.56 Å. The P(7)-O(26) bond length is 1.55 Å. The P(7)-O(27) bond length is 1.56 Å. In the eighth P site, P(8) is bonded to one O(18), one O(24), one O(28), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-44°. The P(8)-O(18) bond length is 1.55 Å. The P(8)-O(24) bond length is 1.55 Å. The P(8)-O(28) bond length is 1.54 Å. The P(8)-O(4) bond length is 1.52 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(23) and one O(9) atom. The H(1)-O(23) bond length is 1.07 Å. The H(1)-O(9) bond length is 1.40 Å. In the second H site, H(2) is bonded in a linear geometry to one O(10) and one O(24) atom. The H(2)-O(10) bond length is 1.37 Å. The H(2)-O(24) bond length is 1.08 Å. In the third H site, H(3) is bonded in a linear geometry to one O(14) and one O(19) atom. The H(3)-O(14) bond length is 1.38 Å. The H(3)-O(19) bond length is 1.07 Å. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. The H(4)-O(1) bond length is 1.36 Å. The H(4)-O(32) bond length is 1.08 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(4) and one H(4) atom. In the second O site, O(2) is bonded in a linear geometry to one V(1) and one P(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(2), one V(1), and one P(6) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(8) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Li(1), one V(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a linear geometry to one V(3) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one P(2), and one H(1) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Li(2), one P(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one V(1) and one P(5) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(2), one V(3), and one P(5) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one V(2) and one P(6) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one P(3) and one H(3) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one V(3) and one P(2) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(1) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(8) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one P(5) and one H(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(3) and one P(3) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a linear geometry to one V(4) and one P(3) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Li(2), one P(7), and one H(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Li(1), one P(8), and one H(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one V(4) and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one V(4) and one P(7) atom. In the twenty-seventh O site, O(27) is bonded in a T-shaped geometry to one Li(2), one V(3), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one V(2) and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one V(4) and one P(2) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 150 degrees geometry to one V(4) and one P(4) atom. In the thirty-first O site, O(31) is bonded in a linear geometry to one V(4) and one P(6) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one P(6) and one H(4) atom.