(WPO3F)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a WPO3F framework. In the WPO3F framework, there are two inequivalent W sites. In the first W site, W(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent F(1) atoms. In the second W site, W(2) is bonded in a linear geometry to two equivalent O(3) atoms. P(1) is bonded in a distorted single-bond geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one P(1), one O(2), and one F(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one P(1), and one O(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one W(2) and one P(1) atom. F(1) is bonded in a distorted L-shaped geometry to one W(1) and one O(1) atom.
(WPO3F)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a WPO3F framework. In the WPO3F framework, there are two inequivalent W sites. In the first W site, W(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent F(1) atoms. Both W(1)-O(2) bond lengths are 2.72 Å. Both W(1)-F(1) bond lengths are 2.58 Å. In the second W site, W(2) is bonded in a linear geometry to two equivalent O(3) atoms. Both W(2)-O(3) bond lengths are 1.38 Å. P(1) is bonded in a distorted single-bond geometry to one O(1), one O(2), and one O(3) atom. The P(1)-O(1) bond length is 2.07 Å. The P(1)-O(2) bond length is 2.17 Å. The P(1)-O(3) bond length is 1.09 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one P(1), one O(2), and one F(1) atom. The O(1)-O(2) bond length is 1.69 Å. The O(1)-F(1) bond length is 1.71 Å. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1), one P(1), and one O(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one W(2) and one P(1) atom. F(1) is bonded in a distorted L-shaped geometry to one W(1) and one O(1) atom.