CrBN2 crystallizes in the hexagonal P6_3/mmc space group. Cr(1) is bonded to six equivalent N(1) atoms to form edge-sharing CrN6 octahedra. B(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a 4-coordinate geometry to three equivalent Cr(1) and one B(1) atom.
CrBN2 crystallizes in the hexagonal P6_3/mmc space group. Cr(1) is bonded to six equivalent N(1) atoms to form edge-sharing CrN6 octahedra. All Cr(1)-N(1) bond lengths are 2.09 Å. B(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both B(1)-N(1) bond lengths are 1.34 Å. N(1) is bonded in a 4-coordinate geometry to three equivalent Cr(1) and one B(1) atom.