LiVGaO4 is Spinel-derived structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Ga(1)O6 octahedra. Ga(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form GaO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Ga(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one V(1), and two equivalent Ga(1) atoms to form distorted OLiVGa2 trigonal pyramids that share corners with six equivalent O(2)LiV2Ga trigonal pyramids, corners with six equivalent O(1)LiVGa2 trigonal pyramids,  an edgeedge with one O(1)LiVGa2 trigonal pyramid, and edges with two equivalent O(2)LiV2Ga trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), two equivalent V(1), and one Ga(1) atom to form distorted OLiV2Ga trigonal pyramids that share corners with six equivalent O(2)LiV2Ga trigonal pyramids, corners with six equivalent O(1)LiVGa2 trigonal pyramids,  an edgeedge with one O(2)LiV2Ga trigonal pyramid, and edges with two equivalent O(1)LiVGa2 trigonal pyramids.
LiVGaO4 is Spinel-derived structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. Both Li(1)-O(1) bond lengths are 1.98 Å. Both Li(1)-O(2) bond lengths are 2.04 Å. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Ga(1)O6 octahedra. Both V(1)-O(1) bond lengths are 2.00 Å. There are two shorter (1.92 Å) and two longer (2.02 Å) V(1)-O(2) bond lengths. Ga(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form GaO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Ga(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. Both Ga(1)-O(2) bond lengths are 2.10 Å. There are two shorter (1.97 Å) and two longer (2.01 Å) Ga(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one V(1), and two equivalent Ga(1) atoms to form distorted OLiVGa2 trigonal pyramids that share corners with six equivalent O(2)LiV2Ga trigonal pyramids, corners with six equivalent O(1)LiVGa2 trigonal pyramids,  an edgeedge with one O(1)LiVGa2 trigonal pyramid, and edges with two equivalent O(2)LiV2Ga trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), two equivalent V(1), and one Ga(1) atom to form distorted OLiV2Ga trigonal pyramids that share corners with six equivalent O(2)LiV2Ga trigonal pyramids, corners with six equivalent O(1)LiVGa2 trigonal pyramids,  an edgeedge with one O(2)LiV2Ga trigonal pyramid, and edges with two equivalent O(1)LiVGa2 trigonal pyramids.