Na4Mn2C4SO16 crystallizes in the triclinic P1 space group. There are eight inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(12), one O(13), one O(2), one O(22), one O(23), and one O(3) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 62-87°. In the second Na site, Na(2) is bonded to one O(1), one O(19), one O(21), one O(27), one O(3), and one O(4) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(6)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. In the third Na site, Na(3) is bonded in a distorted hexagonal planar geometry to one O(1), one O(11), one O(12), one O(28), one O(7), and one O(9) atom. In the fourth Na site, Na(4) is bonded in a distorted hexagonal planar geometry to one O(13), one O(14), one O(16), one O(31), one O(5), and one O(7) atom. In the fifth Na site, Na(5) is bonded to one O(17), one O(18), one O(2), one O(20), one O(26), and one O(28) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(6)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 62-87°. In the sixth Na site, Na(6) is bonded to one O(18), one O(19), one O(24), one O(25), one O(6), and one O(7) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-87°. In the seventh Na site, Na(7) is bonded to one O(12), one O(15), one O(29), one O(30), one O(32), and one O(6) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(6)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-82°. In the eighth Na site, Na(8) is bonded to one O(10), one O(11), one O(20), one O(21), one O(30), and one O(31) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-82°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(15), one O(19), one O(24), one O(32), and one O(9) atom to form MnO6 octahedra that share  an edgeedge with one Na(2)O6 octahedra,  an edgeedge with one Na(6)O6 octahedra, and  an edgeedge with one Na(7)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(23), one O(29), one O(3), one O(30), and one O(4) atom to form MnO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(2)O6 octahedra,  an edgeedge with one Na(7)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(17), one O(18), one O(25), and one O(8) atom to form MnO6 octahedra that share  an edgeedge with one Na(5)O6 octahedra and  an edgeedge with one Na(6)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(2), one O(22), one O(28), one O(31), and one O(5) atom to form MnO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(2), one O(29), and one O(9) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(8) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(10), one O(18), and one O(32) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(11), one O(16), and one O(19) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(1), one O(14), and one O(23) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(15), one O(17), and one O(22) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one O(24), one O(31), and one O(4) atom. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one O(25), one O(28), and one O(30) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(12), one O(13), one O(6), and one O(7) atom to form SO4 tetrahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(6)O6 octahedra, and  an edgeedge with one Na(7)O6 octahedra. In the second S site, S(2) is bonded to one O(20), one O(21), one O(26), and one O(27) atom to form SO4 tetrahedra that share  an edgeedge with one Na(2)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(1), and one C(5) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(5), one Mn(4), and one C(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Mn(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(2), one Mn(2), and one C(7) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(4), one Mn(4), and one C(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(6), one Na(7), and one S(1) atom. In the seventh O site, O(7) is bonded to one Na(3), one Na(4), one Na(6), and one S(1) atom to form edge-sharing ONa3S trigonal pyramids. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one C(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(8), one Mn(2), and one C(3) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(3), one Na(8), one Mn(4), and one C(4) atom. In the twelfth O site, O(12) is bonded to one Na(1), one Na(3), one Na(7), and one S(1) atom to form distorted edge-sharing ONa3S trigonal pyramids. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(1), one Na(4), and one S(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(4), one Mn(3), and one C(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Na(7), one Mn(1), and one C(6) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(4), one Mn(3), and one C(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Na(5), one Mn(3), and one C(6) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(6), one Mn(3), and one C(3) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one Mn(1), and one C(4) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Na(5), one Na(8), and one S(2) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Na(2), one Na(8), and one S(2) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(1), one Mn(4), and one C(6) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Na(1), one Mn(2), and one C(5) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Na(6), one Mn(1), and one C(7) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(6), one Mn(3), and one C(8) atom. In the twenty-sixth O site, O(26) is bonded in an L-shaped geometry to one Na(5) and one S(2) atom. In the twenty-seventh O site, O(27) is bonded in a water-like geometry to one Na(2) and one S(2) atom. In the twenty-eighth O site, O(28) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(5), one Mn(4), and one C(8) atom. In the twenty-ninth O site, O(29) is bonded in a 3-coordinate geometry to one Na(7), one Mn(2), and one C(1) atom. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Na(7), one Na(8), one Mn(2), and one C(8) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(8), one Mn(4), and one C(7) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one Na(7), one Mn(1), and one C(3) atom.
Na4Mn2C4SO16 crystallizes in the triclinic P1 space group. There are eight inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(12), one O(13), one O(2), one O(22), one O(23), and one O(3) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 62-87°. The Na(1)-O(12) bond length is 2.41 Å. The Na(1)-O(13) bond length is 2.37 Å. The Na(1)-O(2) bond length is 2.41 Å. The Na(1)-O(22) bond length is 2.48 Å. The Na(1)-O(23) bond length is 2.53 Å. The Na(1)-O(3) bond length is 2.41 Å. In the second Na site, Na(2) is bonded to one O(1), one O(19), one O(21), one O(27), one O(3), and one O(4) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(6)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. The Na(2)-O(1) bond length is 2.54 Å. The Na(2)-O(19) bond length is 2.51 Å. The Na(2)-O(21) bond length is 2.48 Å. The Na(2)-O(27) bond length is 2.40 Å. The Na(2)-O(3) bond length is 2.42 Å. The Na(2)-O(4) bond length is 2.47 Å. In the third Na site, Na(3) is bonded in a distorted hexagonal planar geometry to one O(1), one O(11), one O(12), one O(28), one O(7), and one O(9) atom. The Na(3)-O(1) bond length is 2.49 Å. The Na(3)-O(11) bond length is 2.54 Å. The Na(3)-O(12) bond length is 2.46 Å. The Na(3)-O(28) bond length is 2.52 Å. The Na(3)-O(7) bond length is 2.38 Å. The Na(3)-O(9) bond length is 2.43 Å. In the fourth Na site, Na(4) is bonded in a distorted hexagonal planar geometry to one O(13), one O(14), one O(16), one O(31), one O(5), and one O(7) atom. The Na(4)-O(13) bond length is 2.47 Å. The Na(4)-O(14) bond length is 2.44 Å. The Na(4)-O(16) bond length is 2.54 Å. The Na(4)-O(31) bond length is 2.54 Å. The Na(4)-O(5) bond length is 2.44 Å. The Na(4)-O(7) bond length is 2.43 Å. In the fifth Na site, Na(5) is bonded to one O(17), one O(18), one O(2), one O(20), one O(26), and one O(28) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(6)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 62-87°. The Na(5)-O(17) bond length is 2.45 Å. The Na(5)-O(18) bond length is 2.45 Å. The Na(5)-O(2) bond length is 2.48 Å. The Na(5)-O(20) bond length is 2.38 Å. The Na(5)-O(26) bond length is 2.49 Å. The Na(5)-O(28) bond length is 2.55 Å. In the sixth Na site, Na(6) is bonded to one O(18), one O(19), one O(24), one O(25), one O(6), and one O(7) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-87°. The Na(6)-O(18) bond length is 2.42 Å. The Na(6)-O(19) bond length is 2.42 Å. The Na(6)-O(24) bond length is 2.49 Å. The Na(6)-O(25) bond length is 2.53 Å. The Na(6)-O(6) bond length is 2.36 Å. The Na(6)-O(7) bond length is 2.41 Å. In the seventh Na site, Na(7) is bonded to one O(12), one O(15), one O(29), one O(30), one O(32), and one O(6) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(6)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 58-82°. The Na(7)-O(12) bond length is 2.55 Å. The Na(7)-O(15) bond length is 2.44 Å. The Na(7)-O(29) bond length is 2.49 Å. The Na(7)-O(30) bond length is 2.54 Å. The Na(7)-O(32) bond length is 2.51 Å. The Na(7)-O(6) bond length is 2.38 Å. In the eighth Na site, Na(8) is bonded to one O(10), one O(11), one O(20), one O(21), one O(30), and one O(31) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(2)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-82°. The Na(8)-O(10) bond length is 2.48 Å. The Na(8)-O(11) bond length is 2.55 Å. The Na(8)-O(20) bond length is 2.33 Å. The Na(8)-O(21) bond length is 2.40 Å. The Na(8)-O(30) bond length is 2.45 Å. The Na(8)-O(31) bond length is 2.38 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(15), one O(19), one O(24), one O(32), and one O(9) atom to form MnO6 octahedra that share  an edgeedge with one Na(2)O6 octahedra,  an edgeedge with one Na(6)O6 octahedra, and  an edgeedge with one Na(7)O6 octahedra. The Mn(1)-O(1) bond length is 2.08 Å. The Mn(1)-O(15) bond length is 2.16 Å. The Mn(1)-O(19) bond length is 2.28 Å. The Mn(1)-O(24) bond length is 2.06 Å. The Mn(1)-O(32) bond length is 2.04 Å. The Mn(1)-O(9) bond length is 2.05 Å. In the second Mn site, Mn(2) is bonded to one O(10), one O(23), one O(29), one O(3), one O(30), and one O(4) atom to form MnO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(2)O6 octahedra,  an edgeedge with one Na(7)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. The Mn(2)-O(10) bond length is 2.01 Å. The Mn(2)-O(23) bond length is 2.00 Å. The Mn(2)-O(29) bond length is 2.00 Å. The Mn(2)-O(3) bond length is 2.25 Å. The Mn(2)-O(30) bond length is 2.27 Å. The Mn(2)-O(4) bond length is 2.00 Å. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(17), one O(18), one O(25), and one O(8) atom to form MnO6 octahedra that share  an edgeedge with one Na(5)O6 octahedra and  an edgeedge with one Na(6)O6 octahedra. The Mn(3)-O(14) bond length is 2.20 Å. The Mn(3)-O(16) bond length is 2.03 Å. The Mn(3)-O(17) bond length is 2.00 Å. The Mn(3)-O(18) bond length is 2.28 Å. The Mn(3)-O(25) bond length is 2.03 Å. The Mn(3)-O(8) bond length is 1.97 Å. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(2), one O(22), one O(28), one O(31), and one O(5) atom to form MnO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. The Mn(4)-O(11) bond length is 2.09 Å. The Mn(4)-O(2) bond length is 2.25 Å. The Mn(4)-O(22) bond length is 2.04 Å. The Mn(4)-O(28) bond length is 2.10 Å. The Mn(4)-O(31) bond length is 2.24 Å. The Mn(4)-O(5) bond length is 2.04 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(2), one O(29), and one O(9) atom. The C(1)-O(2) bond length is 1.29 Å. The C(1)-O(29) bond length is 1.30 Å. The C(1)-O(9) bond length is 1.30 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(8) atom. The C(2)-O(3) bond length is 1.29 Å. The C(2)-O(5) bond length is 1.30 Å. The C(2)-O(8) bond length is 1.30 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(10), one O(18), and one O(32) atom. The C(3)-O(10) bond length is 1.32 Å. The C(3)-O(18) bond length is 1.28 Å. The C(3)-O(32) bond length is 1.29 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(11), one O(16), and one O(19) atom. The C(4)-O(11) bond length is 1.32 Å. The C(4)-O(16) bond length is 1.30 Å. The C(4)-O(19) bond length is 1.29 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(1), one O(14), and one O(23) atom. The C(5)-O(1) bond length is 1.31 Å. The C(5)-O(14) bond length is 1.27 Å. The C(5)-O(23) bond length is 1.31 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(15), one O(17), and one O(22) atom. The C(6)-O(15) bond length is 1.27 Å. The C(6)-O(17) bond length is 1.30 Å. The C(6)-O(22) bond length is 1.31 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one O(24), one O(31), and one O(4) atom. The C(7)-O(24) bond length is 1.30 Å. The C(7)-O(31) bond length is 1.28 Å. The C(7)-O(4) bond length is 1.30 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one O(25), one O(28), and one O(30) atom. The C(8)-O(25) bond length is 1.31 Å. The C(8)-O(28) bond length is 1.31 Å. The C(8)-O(30) bond length is 1.28 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(12), one O(13), one O(6), and one O(7) atom to form SO4 tetrahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(6)O6 octahedra, and  an edgeedge with one Na(7)O6 octahedra. The S(1)-O(12) bond length is 1.51 Å. The S(1)-O(13) bond length is 1.49 Å. The S(1)-O(6) bond length is 1.49 Å. The S(1)-O(7) bond length is 1.51 Å. In the second S site, S(2) is bonded to one O(20), one O(21), one O(26), and one O(27) atom to form SO4 tetrahedra that share  an edgeedge with one Na(2)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. The S(2)-O(20) bond length is 1.50 Å. The S(2)-O(21) bond length is 1.51 Å. The S(2)-O(26) bond length is 1.50 Å. The S(2)-O(27) bond length is 1.49 Å. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(1), and one C(5) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(5), one Mn(4), and one C(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Mn(2), and one C(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(2), one Mn(2), and one C(7) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(4), one Mn(4), and one C(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(6), one Na(7), and one S(1) atom. In the seventh O site, O(7) is bonded to one Na(3), one Na(4), one Na(6), and one S(1) atom to form edge-sharing ONa3S trigonal pyramids. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one C(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(8), one Mn(2), and one C(3) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(3), one Na(8), one Mn(4), and one C(4) atom. In the twelfth O site, O(12) is bonded to one Na(1), one Na(3), one Na(7), and one S(1) atom to form distorted edge-sharing ONa3S trigonal pyramids. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(1), one Na(4), and one S(1) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(4), one Mn(3), and one C(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Na(7), one Mn(1), and one C(6) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(4), one Mn(3), and one C(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Na(5), one Mn(3), and one C(6) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(6), one Mn(3), and one C(3) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one Mn(1), and one C(4) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Na(5), one Na(8), and one S(2) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Na(2), one Na(8), and one S(2) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(1), one Mn(4), and one C(6) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Na(1), one Mn(2), and one C(5) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Na(6), one Mn(1), and one C(7) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(6), one Mn(3), and one C(8) atom. In the twenty-sixth O site, O(26) is bonded in an L-shaped geometry to one Na(5) and one S(2) atom. In the twenty-seventh O site, O(27) is bonded in a water-like geometry to one Na(2) and one S(2) atom. In the twenty-eighth O site, O(28) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(5), one Mn(4), and one C(8) atom. In the twenty-ninth O site, O(29) is bonded in a 3-coordinate geometry to one Na(7), one Mn(2), and one C(1) atom. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Na(7), one Na(8), one Mn(2), and one C(8) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(8), one Mn(4), and one C(7) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one Na(7), one Mn(1), and one C(3) atom.