Rb2PdCl4 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Cl(1) is bonded to four equivalent Rb(1) and one Pd(1) atom to form a mixture of edge, face, and corner-sharing ClRb4Pd square pyramids.
Rb2PdCl4 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. All Rb(1)-Cl(1) bond lengths are 3.37 Å. Pd(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. All Pd(1)-Cl(1) bond lengths are 2.32 Å. Cl(1) is bonded to four equivalent Rb(1) and one Pd(1) atom to form a mixture of edge, face, and corner-sharing ClRb4Pd square pyramids.