YbAg(WO4)2 crystallizes in the monoclinic C2/m space group. Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. In the second W site, W(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Ag(1) is bonded in a distorted bent 150 degrees geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Yb(1), one W(1), one W(2), and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Yb(1), one W(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded to one W(1), two equivalent W(2), and one Ag(1) atom to form distorted edge-sharing OAgW3 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Yb(1), one W(1), and one Ag(1) atom.
YbAg(WO4)2 crystallizes in the monoclinic C2/m space group. Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. Both Yb(1)-O(1) bond lengths are 2.36 Å. Both Yb(1)-O(2) bond lengths are 2.34 Å. Both Yb(1)-O(3) bond lengths are 2.37 Å. Both Yb(1)-O(5) bond lengths are 2.74 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. The W(1)-O(4) bond length is 2.14 Å. The W(1)-O(5) bond length is 1.86 Å. Both W(1)-O(1) bond lengths are 2.14 Å. Both W(1)-O(3) bond lengths are 1.81 Å. In the second W site, W(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Both W(2)-O(1) bond lengths are 1.94 Å. Both W(2)-O(2) bond lengths are 1.79 Å. Both W(2)-O(4) bond lengths are 2.29 Å. Ag(1) is bonded in a distorted bent 150 degrees geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. The Ag(1)-O(4) bond length is 2.16 Å. The Ag(1)-O(5) bond length is 2.16 Å. Both Ag(1)-O(1) bond lengths are 2.69 Å. Both Ag(1)-O(3) bond lengths are 2.75 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Yb(1), one W(1), one W(2), and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Yb(1), one W(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded to one W(1), two equivalent W(2), and one Ag(1) atom to form distorted edge-sharing OAgW3 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Yb(1), one W(1), and one Ag(1) atom.