Mn4O7F is Hydrophilite-derived structured and crystallizes in the monoclinic Cc space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(5), one O(6), two equivalent O(2), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O5F octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. In the second Mn site, Mn(2) is bonded to one O(2), one O(3), one O(5), one O(7), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the third Mn site, Mn(3) is bonded to one O(4), one O(5), one O(7), two equivalent O(1), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O5F octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(3), one O(7), two equivalent O(6), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 48-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(4) and two equivalent Mn(3) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(2) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(4) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(4) atom.
Mn4O7F is Hydrophilite-derived structured and crystallizes in the monoclinic Cc space group. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(5), one O(6), two equivalent O(2), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O5F octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. The Mn(1)-O(3) bond length is 1.96 Å. The Mn(1)-O(5) bond length is 1.95 Å. The Mn(1)-O(6) bond length is 1.95 Å. There is one shorter (1.93 Å) and one longer (1.95 Å) Mn(1)-O(2) bond length. The Mn(1)-F(1) bond length is 2.15 Å. In the second Mn site, Mn(2) is bonded to one O(2), one O(3), one O(5), one O(7), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-53°. The Mn(2)-O(2) bond length is 1.92 Å. The Mn(2)-O(3) bond length is 1.93 Å. The Mn(2)-O(5) bond length is 1.92 Å. The Mn(2)-O(7) bond length is 1.99 Å. There is one shorter (1.95 Å) and one longer (2.02 Å) Mn(2)-O(4) bond length. In the third Mn site, Mn(3) is bonded to one O(4), one O(5), one O(7), two equivalent O(1), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O5F octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. The Mn(3)-O(4) bond length is 1.94 Å. The Mn(3)-O(5) bond length is 1.89 Å. The Mn(3)-O(7) bond length is 1.94 Å. There is one shorter (1.93 Å) and one longer (1.95 Å) Mn(3)-O(1) bond length. The Mn(3)-F(1) bond length is 2.03 Å. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(3), one O(7), two equivalent O(6), and one F(1) atom to form MnO5F octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with two equivalent Mn(4)O5F octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 48-56°. The Mn(4)-O(1) bond length is 1.89 Å. The Mn(4)-O(3) bond length is 1.95 Å. The Mn(4)-O(7) bond length is 1.93 Å. There is one shorter (1.97 Å) and one longer (2.00 Å) Mn(4)-O(6) bond length. The Mn(4)-F(1) bond length is 2.01 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(4) and two equivalent Mn(3) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(3) and two equivalent Mn(2) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Mn(4) atoms. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(4) atom.