(Mo(OF)2)2N2(NO)2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitroxyl molecules, and four Mo(OF)2 clusters. In each Mo(OF)2 cluster, Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(3), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Mo(1) atom.
(Mo(OF)2)2N2(NO)2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitroxyl molecules, and four Mo(OF)2 clusters. In each Mo(OF)2 cluster, Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(3), one F(1), and one F(2) atom. The Mo(1)-O(1) bond length is 1.74 Å. The Mo(1)-O(3) bond length is 1.71 Å. The Mo(1)-F(1) bond length is 1.92 Å. The Mo(1)-F(2) bond length is 1.89 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Mo(1) atom.