TlCrTe2 crystallizes in the trigonal P-3m1 space group. Cr(1) is bonded to six equivalent Te(1) atoms to form edge-sharing CrTe6 octahedra. Tl(1) is bonded in a 6-coordinate geometry to six equivalent Te(1) atoms. Te(1) is bonded in a 6-coordinate geometry to three equivalent Cr(1) and three equivalent Tl(1) atoms.
TlCrTe2 crystallizes in the trigonal P-3m1 space group. Cr(1) is bonded to six equivalent Te(1) atoms to form edge-sharing CrTe6 octahedra. All Cr(1)-Te(1) bond lengths are 2.78 Å. Tl(1) is bonded in a 6-coordinate geometry to six equivalent Te(1) atoms. All Tl(1)-Te(1) bond lengths are 3.46 Å. Te(1) is bonded in a 6-coordinate geometry to three equivalent Cr(1) and three equivalent Tl(1) atoms.