(Mg(HCl)2)2Ca(ClO)2(H2)8(H2O2)2(O2)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 molecules, one chlorkalk molecule, two trioxidane molecules, four water molecules, and one Mg(HCl)2 cluster. In the Mg(HCl)2 cluster, Mg(1) is bonded in a 5-coordinate geometry to one H(3), one H(9), one Cl(2), and two equivalent Cl(3) atoms. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one Mg(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one Mg(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mg(1) atom. In the second Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Mg(1) atoms.
(Mg(HCl)2)2Ca(ClO)2(H2)8(H2O2)2(O2)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 molecules, one chlorkalk molecule, two trioxidane molecules, four water molecules, and one Mg(HCl)2 cluster. In the Mg(HCl)2 cluster, Mg(1) is bonded in a 5-coordinate geometry to one H(3), one H(9), one Cl(2), and two equivalent Cl(3) atoms. The Mg(1)-H(3) bond length is 2.01 Å. The Mg(1)-H(9) bond length is 2.28 Å. The Mg(1)-Cl(2) bond length is 2.27 Å. There is one shorter (2.35 Å) and one longer (2.41 Å) Mg(1)-Cl(3) bond length. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one Mg(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one Mg(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mg(1) atom. In the second Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Mg(1) atoms.