MgC6H8S2(NO4)2 crystallizes in the triclinic P-1 space group. Mg(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(1), one N(1), and one S(1) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one N(1), and one S(1) atom. N(1) is bonded in a water-like geometry to one C(1) and one C(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one O(4) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. S(1) is bonded in an L-shaped geometry to one C(1) and one C(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(3), and one H(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one C(2), one H(3), and one H(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mg(1), one C(2), and one H(2) atom.
MgC6H8S2(NO4)2 crystallizes in the triclinic P-1 space group. Mg(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Both Mg(1)-O(1) bond lengths are 2.04 Å. Both Mg(1)-O(2) bond lengths are 2.10 Å. Both Mg(1)-O(4) bond lengths are 2.23 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(1), one N(1), and one S(1) atom. The C(1)-C(1) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.36 Å. The C(1)-S(1) bond length is 1.72 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(2)-C(3) bond length is 1.50 Å. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.28 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one N(1), and one S(1) atom. The C(3)-N(1) bond length is 1.33 Å. The C(3)-S(1) bond length is 1.74 Å. N(1) is bonded in a water-like geometry to one C(1) and one C(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one O(4) atom. The H(2)-O(2) bond length is 1.00 Å. The H(2)-O(4) bond length is 1.75 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. The H(3)-O(1) bond length is 0.99 Å. The H(3)-O(3) bond length is 1.69 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(3) atom. The H(4)-O(1) bond length is 1.00 Å. The H(4)-O(3) bond length is 1.68 Å. S(1) is bonded in an L-shaped geometry to one C(1) and one C(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(3), and one H(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one C(2), one H(3), and one H(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mg(1), one C(2), and one H(2) atom.