FeCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two FeCl4 clusters and four SCl3 clusters. In each FeCl4 cluster, Fe(1) is bonded to one Cl(1), one Cl(6), one Cl(7), and two equivalent Cl(5) atoms to form distorted edge-sharing FeCl5 trigonal bipyramids. There are four inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one Fe(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Fe(1) atom. In the third Cl site, Cl(5) is bonded in a water-like geometry to two equivalent Fe(1) atoms. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Fe(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(2), one Cl(3), and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom.
FeCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two FeCl4 clusters and four SCl3 clusters. In each FeCl4 cluster, Fe(1) is bonded to one Cl(1), one Cl(6), one Cl(7), and two equivalent Cl(5) atoms to form distorted edge-sharing FeCl5 trigonal bipyramids. The Fe(1)-Cl(1) bond length is 2.22 Å. The Fe(1)-Cl(6) bond length is 2.30 Å. The Fe(1)-Cl(7) bond length is 2.25 Å. There is one shorter (2.42 Å) and one longer (2.50 Å) Fe(1)-Cl(5) bond length. There are four inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one Fe(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Fe(1) atom. In the third Cl site, Cl(5) is bonded in a water-like geometry to two equivalent Fe(1) atoms. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Fe(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(2), one Cl(3), and one Cl(4) atom. The S(1)-Cl(2) bond length is 2.04 Å. The S(1)-Cl(3) bond length is 2.01 Å. The S(1)-Cl(4) bond length is 2.02 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom.