ZrTiF6 is alpha Rhenium trioxide-derived structured and crystallizes in the orthorhombic Immm space group. Zr(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. Ti(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Zr(1) and one Ti(1) atom. In the second F site, F(2) is bonded in a linear geometry to one Zr(1) and one Ti(1) atom.
ZrTiF6 is alpha Rhenium trioxide-derived structured and crystallizes in the orthorhombic Immm space group. Zr(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Ti(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. Both Zr(1)-F(2) bond lengths are 2.03 Å. All Zr(1)-F(1) bond lengths are 2.03 Å. Ti(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form TiF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. Both Ti(1)-F(2) bond lengths are 2.08 Å. All Ti(1)-F(1) bond lengths are 2.08 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Zr(1) and one Ti(1) atom. In the second F site, F(2) is bonded in a linear geometry to one Zr(1) and one Ti(1) atom.