PuO3Tl is High-temperature superconductor-derived structured and crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a PuO3 framework. In the PuO3 framework, Pu(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing PuO6 octahedra. The corner-sharing octahedral tilt angles are 1°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent Pu(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent Pu(1) atoms.
PuO3Tl is High-temperature superconductor-derived structured and crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a PuO3 framework. In the PuO3 framework, Pu(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing PuO6 octahedra. The corner-sharing octahedral tilt angles are 1°. Both Pu(1)-O(1) bond lengths are 2.16 Å. There are two shorter (2.05 Å) and two longer (2.29 Å) Pu(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent Pu(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent Pu(1) atoms.