PbFCl is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Pb(1) is bonded in a 4-coordinate geometry to five equivalent Cl(1) and four equivalent F(1) atoms. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms. F(1) is bonded to four equivalent Pb(1) atoms to form a mixture of edge and corner-sharing FPb4 tetrahedra.
PbFCl is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Pb(1) is bonded in a 4-coordinate geometry to five equivalent Cl(1) and four equivalent F(1) atoms. There are four shorter (3.09 Å) and one longer (3.21 Å) Pb(1)-Cl(1) bond length. All Pb(1)-F(1) bond lengths are 2.53 Å. Cl(1) is bonded in a 5-coordinate geometry to five equivalent Pb(1) atoms. F(1) is bonded to four equivalent Pb(1) atoms to form a mixture of edge and corner-sharing FPb4 tetrahedra.