CrN2 is Low Tridymite-like structured and crystallizes in the orthorhombic C222_1 space group. Cr(1) is bonded to one N(2), one N(3), and two equivalent N(1) atoms to form corner-sharing CrN4 tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to two equivalent Cr(1) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cr(1) atoms. In the third N site, N(3) is bonded in a bent 150 degrees geometry to two equivalent Cr(1) atoms.
CrN2 is Low Tridymite-like structured and crystallizes in the orthorhombic C222_1 space group. Cr(1) is bonded to one N(2), one N(3), and two equivalent N(1) atoms to form corner-sharing CrN4 tetrahedra. The Cr(1)-N(2) bond length is 1.73 Å. The Cr(1)-N(3) bond length is 1.73 Å. Both Cr(1)-N(1) bond lengths are 1.73 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to two equivalent Cr(1) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cr(1) atoms. In the third N site, N(3) is bonded in a bent 150 degrees geometry to two equivalent Cr(1) atoms.