KSb3 is Sodium arsenide structured and crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded in a 11-coordinate geometry to three equivalent Sb(2) and eight equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Sb(1) atom. In the second Sb site, Sb(2) is bonded in a trigonal planar geometry to three equivalent K(1) atoms.
KSb3 is Sodium arsenide structured and crystallizes in the hexagonal P6_3/mmc space group. K(1) is bonded in a 11-coordinate geometry to three equivalent Sb(2) and eight equivalent Sb(1) atoms. All K(1)-Sb(2) bond lengths are 3.19 Å. There are two shorter (3.42 Å) and six longer (3.52 Å) K(1)-Sb(1) bond lengths. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Sb(1) atom. The Sb(1)-Sb(1) bond length is 2.97 Å. In the second Sb site, Sb(2) is bonded in a trigonal planar geometry to three equivalent K(1) atoms.