Sr2Ag2Cu(SO)2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. Cu(1) is bonded in a square co-planar geometry to two equivalent S(1) and four equivalent O(1) atoms. S(1) is bonded in a 9-coordinate geometry to four equivalent Sr(1), four equivalent Ag(1), and one Cu(1) atom. O(1) is bonded to four equivalent Sr(1) and two equivalent Cu(1) atoms to form a mixture of face, corner, and edge-sharing OSr4Cu2 octahedra. The corner-sharing octahedra are not tilted.
Sr2Ag2Cu(SO)2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. All Sr(1)-S(1) bond lengths are 3.16 Å. All Sr(1)-O(1) bond lengths are 2.62 Å. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All Ag(1)-S(1) bond lengths are 2.70 Å. Cu(1) is bonded in a square co-planar geometry to two equivalent S(1) and four equivalent O(1) atoms. Both Cu(1)-S(1) bond lengths are 3.07 Å. All Cu(1)-O(1) bond lengths are 2.01 Å. S(1) is bonded in a 9-coordinate geometry to four equivalent Sr(1), four equivalent Ag(1), and one Cu(1) atom. O(1) is bonded to four equivalent Sr(1) and two equivalent Cu(1) atoms to form a mixture of face, corner, and edge-sharing OSr4Cu2 octahedra. The corner-sharing octahedra are not tilted.