XeF2Sb2F11 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two xenon;dihydrofluoride molecules and two Sb2F11 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(3), one F(4), one F(5), one F(6), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 12°. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(12), one F(13), one F(8), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 12°. There are eleven inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. In the seventh F site, F(9) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(13) is bonded in a single-bond geometry to one Sb(2) atom.
XeF2Sb2F11 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two xenon;dihydrofluoride molecules and two Sb2F11 clusters. In each Sb2F11 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(3), one F(4), one F(5), one F(6), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 12°. The Sb(1)-F(3) bond length is 1.91 Å. The Sb(1)-F(4) bond length is 1.90 Å. The Sb(1)-F(5) bond length is 1.91 Å. The Sb(1)-F(6) bond length is 1.91 Å. The Sb(1)-F(7) bond length is 1.90 Å. The Sb(1)-F(8) bond length is 2.08 Å. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(12), one F(13), one F(8), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 12°. The Sb(2)-F(10) bond length is 1.91 Å. The Sb(2)-F(11) bond length is 1.91 Å. The Sb(2)-F(12) bond length is 1.91 Å. The Sb(2)-F(13) bond length is 1.90 Å. The Sb(2)-F(8) bond length is 2.06 Å. The Sb(2)-F(9) bond length is 1.91 Å. There are eleven inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. In the seventh F site, F(9) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(13) is bonded in a single-bond geometry to one Sb(2) atom.