RhNiF6 crystallizes in the trigonal R-3 space group. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. F(1) is bonded in a bent 150 degrees geometry to one Rh(1) and one Ni(1) atom.
RhNiF6 crystallizes in the trigonal R-3 space group. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Rh(1)-F(1) bond lengths are 1.93 Å. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Ni(1)-F(1) bond lengths are 1.96 Å. F(1) is bonded in a bent 150 degrees geometry to one Rh(1) and one Ni(1) atom.