AgVO3 crystallizes in the monoclinic Cm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), one O(8), one O(9), and two equivalent O(7) atoms. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(6), one O(7), and two equivalent O(5) atoms. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(2), one O(7), and two equivalent O(9) atoms. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(11), one O(4), one O(8), one O(9), and two equivalent O(1) atoms. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(4), one O(8), and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded to one O(10), one O(11), two equivalent O(12), and two equivalent O(3) atoms to form AgO6 octahedra that share edges with two equivalent Ag(2)O6 octahedra, edges with two equivalent Ag(3)O5 square pyramids, and edges with two equivalent Ag(4)O5 square pyramids. In the third Ag site, Ag(3) is bonded to one O(3), two equivalent O(11), and two equivalent O(6) atoms to form AgO5 square pyramids that share edges with two equivalent Ag(2)O6 octahedra and edges with two equivalent Ag(3)O5 square pyramids. In the fourth Ag site, Ag(4) is bonded to one O(12), two equivalent O(10), and two equivalent O(4) atoms to form AgO5 square pyramids that share edges with two equivalent Ag(2)O6 octahedra and edges with two equivalent Ag(4)O5 square pyramids. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one V(3) and two equivalent V(4) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one V(2), one V(3), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(3), and two equivalent Ag(2) atoms. In the fourth O site, O(4) is bonded to one V(4), one Ag(1), and two equivalent Ag(4) atoms to form distorted corner-sharing OVAg3 tetrahedra. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1) and two equivalent V(2) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent Ag(3) atoms. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one V(2), one V(3), and two equivalent V(1) atoms. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one V(1), one V(4), and one Ag(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one V(1), one V(4), and two equivalent V(3) atoms. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one V(2), one Ag(2), and two equivalent Ag(4) atoms. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one V(4), one Ag(2), and two equivalent Ag(3) atoms. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one V(3), one Ag(4), and two equivalent Ag(2) atoms.
AgVO3 crystallizes in the monoclinic Cm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), one O(8), one O(9), and two equivalent O(7) atoms. The V(1)-O(3) bond length is 1.67 Å. The V(1)-O(5) bond length is 2.14 Å. The V(1)-O(8) bond length is 1.68 Å. The V(1)-O(9) bond length is 2.52 Å. Both V(1)-O(7) bond lengths are 1.89 Å. In the second V site, V(2) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(6), one O(7), and two equivalent O(5) atoms. The V(2)-O(10) bond length is 1.70 Å. The V(2)-O(2) bond length is 2.38 Å. The V(2)-O(6) bond length is 1.70 Å. The V(2)-O(7) bond length is 2.14 Å. Both V(2)-O(5) bond lengths are 1.87 Å. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(2), one O(7), and two equivalent O(9) atoms. The V(3)-O(1) bond length is 2.10 Å. The V(3)-O(12) bond length is 1.67 Å. The V(3)-O(2) bond length is 1.71 Å. The V(3)-O(7) bond length is 2.53 Å. Both V(3)-O(9) bond lengths are 1.88 Å. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(11), one O(4), one O(8), one O(9), and two equivalent O(1) atoms. The V(4)-O(11) bond length is 1.71 Å. The V(4)-O(4) bond length is 1.70 Å. The V(4)-O(8) bond length is 2.30 Å. The V(4)-O(9) bond length is 2.18 Å. Both V(4)-O(1) bond lengths are 1.87 Å. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(4), one O(8), and two equivalent O(2) atoms. The Ag(1)-O(4) bond length is 2.50 Å. The Ag(1)-O(8) bond length is 2.23 Å. Both Ag(1)-O(2) bond lengths are 2.33 Å. In the second Ag site, Ag(2) is bonded to one O(10), one O(11), two equivalent O(12), and two equivalent O(3) atoms to form AgO6 octahedra that share edges with two equivalent Ag(2)O6 octahedra, edges with two equivalent Ag(3)O5 square pyramids, and edges with two equivalent Ag(4)O5 square pyramids. The Ag(2)-O(10) bond length is 2.33 Å. The Ag(2)-O(11) bond length is 2.33 Å. Both Ag(2)-O(12) bond lengths are 2.43 Å. Both Ag(2)-O(3) bond lengths are 2.42 Å. In the third Ag site, Ag(3) is bonded to one O(3), two equivalent O(11), and two equivalent O(6) atoms to form AgO5 square pyramids that share edges with two equivalent Ag(2)O6 octahedra and edges with two equivalent Ag(3)O5 square pyramids. The Ag(3)-O(3) bond length is 2.45 Å. Both Ag(3)-O(11) bond lengths are 2.36 Å. Both Ag(3)-O(6) bond lengths are 2.34 Å. In the fourth Ag site, Ag(4) is bonded to one O(12), two equivalent O(10), and two equivalent O(4) atoms to form AgO5 square pyramids that share edges with two equivalent Ag(2)O6 octahedra and edges with two equivalent Ag(4)O5 square pyramids. The Ag(4)-O(12) bond length is 2.45 Å. Both Ag(4)-O(10) bond lengths are 2.35 Å. Both Ag(4)-O(4) bond lengths are 2.34 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one V(3) and two equivalent V(4) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to one V(2), one V(3), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(3), and two equivalent Ag(2) atoms. In the fourth O site, O(4) is bonded to one V(4), one Ag(1), and two equivalent Ag(4) atoms to form distorted corner-sharing OVAg3 tetrahedra. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1) and two equivalent V(2) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent Ag(3) atoms. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one V(2), one V(3), and two equivalent V(1) atoms. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one V(1), one V(4), and one Ag(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one V(1), one V(4), and two equivalent V(3) atoms. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one V(2), one Ag(2), and two equivalent Ag(4) atoms. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one V(4), one Ag(2), and two equivalent Ag(3) atoms. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one V(3), one Ag(4), and two equivalent Ag(2) atoms.