V4OF11 crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one F(1), one F(2), one F(4), one F(7), and one F(8) atom to form VOF5 octahedra that share corners with three equivalent V(7)F6 octahedra and corners with three equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. In the second V site, V(2) is bonded to one O(1), one F(12), one F(14), one F(18), one F(3), and one F(9) atom to form VOF5 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. In the third V site, V(3) is bonded to one O(2), one F(11), one F(13), one F(4), one F(5), and one F(8) atom to form VOF5 octahedra that share corners with three equivalent V(5)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. In the fourth V site, V(4) is bonded to one F(12), one F(15), one F(18), one F(19), one F(6), and one F(9) atom to form VF6 octahedra that share corners with three equivalent V(6)F6 octahedra and corners with three equivalent V(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 31-33°. In the fifth V site, V(5) is bonded to one F(10), one F(11), one F(13), one F(17), one F(21), and one F(5) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. In the sixth V site, V(6) is bonded to one F(15), one F(16), one F(19), one F(20), one F(22), and one F(6) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 32°. In the seventh V site, V(7) is bonded to one F(1), one F(16), one F(2), one F(20), one F(22), and one F(7) atom to form VF6 octahedra that share corners with three equivalent V(6)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-32°. In the eighth V site, V(8) is bonded to one O(1), one F(10), one F(14), one F(17), one F(21), and one F(3) atom to form VOF5 octahedra that share corners with three equivalent V(5)F6 octahedra and corners with three equivalent V(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the thirteenth F site, F(13) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the fourteenth F site, F(14) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the fifteenth F site, F(15) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the sixteenth F site, F(16) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the seventeenth F site, F(17) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the eighteenth F site, F(18) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the nineteenth F site, F(19) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the twentieth F site, F(20) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the twenty-first F site, F(21) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the twenty-second F site, F(22) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom.
V4OF11 crystallizes in the triclinic P1 space group. There are eight inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one F(1), one F(2), one F(4), one F(7), and one F(8) atom to form VOF5 octahedra that share corners with three equivalent V(7)F6 octahedra and corners with three equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. The V(1)-O(2) bond length is 1.70 Å. The V(1)-F(1) bond length is 1.96 Å. The V(1)-F(2) bond length is 1.98 Å. The V(1)-F(4) bond length is 1.96 Å. The V(1)-F(7) bond length is 2.02 Å. The V(1)-F(8) bond length is 1.96 Å. In the second V site, V(2) is bonded to one O(1), one F(12), one F(14), one F(18), one F(3), and one F(9) atom to form VOF5 octahedra that share corners with three equivalent V(4)F6 octahedra and corners with three equivalent V(8)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. The V(2)-O(1) bond length is 1.94 Å. The V(2)-F(12) bond length is 2.00 Å. The V(2)-F(14) bond length is 1.98 Å. The V(2)-F(18) bond length is 1.97 Å. The V(2)-F(3) bond length is 2.01 Å. The V(2)-F(9) bond length is 1.97 Å. In the third V site, V(3) is bonded to one O(2), one F(11), one F(13), one F(4), one F(5), and one F(8) atom to form VOF5 octahedra that share corners with three equivalent V(5)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. The V(3)-O(2) bond length is 1.96 Å. The V(3)-F(11) bond length is 1.99 Å. The V(3)-F(13) bond length is 1.96 Å. The V(3)-F(4) bond length is 2.00 Å. The V(3)-F(5) bond length is 1.97 Å. The V(3)-F(8) bond length is 1.99 Å. In the fourth V site, V(4) is bonded to one F(12), one F(15), one F(18), one F(19), one F(6), and one F(9) atom to form VF6 octahedra that share corners with three equivalent V(6)F6 octahedra and corners with three equivalent V(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 31-33°. The V(4)-F(12) bond length is 1.96 Å. The V(4)-F(15) bond length is 1.98 Å. The V(4)-F(18) bond length is 1.98 Å. The V(4)-F(19) bond length is 1.96 Å. The V(4)-F(6) bond length is 1.98 Å. The V(4)-F(9) bond length is 1.98 Å. In the fifth V site, V(5) is bonded to one F(10), one F(11), one F(13), one F(17), one F(21), and one F(5) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 27-31°. The V(5)-F(10) bond length is 1.98 Å. The V(5)-F(11) bond length is 1.97 Å. The V(5)-F(13) bond length is 1.99 Å. The V(5)-F(17) bond length is 1.98 Å. The V(5)-F(21) bond length is 1.96 Å. The V(5)-F(5) bond length is 1.98 Å. In the sixth V site, V(6) is bonded to one F(15), one F(16), one F(19), one F(20), one F(22), and one F(6) atom to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 32°. The V(6)-F(15) bond length is 1.96 Å. The V(6)-F(16) bond length is 1.97 Å. The V(6)-F(19) bond length is 1.99 Å. The V(6)-F(20) bond length is 1.99 Å. The V(6)-F(22) bond length is 1.97 Å. The V(6)-F(6) bond length is 1.97 Å. In the seventh V site, V(7) is bonded to one F(1), one F(16), one F(2), one F(20), one F(22), and one F(7) atom to form VF6 octahedra that share corners with three equivalent V(6)F6 octahedra and corners with three equivalent V(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 28-32°. The V(7)-F(1) bond length is 1.98 Å. The V(7)-F(16) bond length is 1.99 Å. The V(7)-F(2) bond length is 1.97 Å. The V(7)-F(20) bond length is 1.97 Å. The V(7)-F(22) bond length is 1.98 Å. The V(7)-F(7) bond length is 1.99 Å. In the eighth V site, V(8) is bonded to one O(1), one F(10), one F(14), one F(17), one F(21), and one F(3) atom to form VOF5 octahedra that share corners with three equivalent V(5)F6 octahedra and corners with three equivalent V(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 24-35°. The V(8)-O(1) bond length is 1.69 Å. The V(8)-F(10) bond length is 1.96 Å. The V(8)-F(14) bond length is 1.96 Å. The V(8)-F(17) bond length is 2.02 Å. The V(8)-F(21) bond length is 1.99 Å. The V(8)-F(3) bond length is 1.95 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(1) and one V(7) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the eleventh F site, F(11) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the twelfth F site, F(12) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the thirteenth F site, F(13) is bonded in a bent 150 degrees geometry to one V(3) and one V(5) atom. In the fourteenth F site, F(14) is bonded in a bent 150 degrees geometry to one V(2) and one V(8) atom. In the fifteenth F site, F(15) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the sixteenth F site, F(16) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the seventeenth F site, F(17) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the eighteenth F site, F(18) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the nineteenth F site, F(19) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the twentieth F site, F(20) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom. In the twenty-first F site, F(21) is bonded in a bent 150 degrees geometry to one V(5) and one V(8) atom. In the twenty-second F site, F(22) is bonded in a bent 150 degrees geometry to one V(6) and one V(7) atom.