LiCa2InGe2 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 5-coordinate geometry to one In(1), one Ge(1), and three equivalent Ge(2) atoms. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 5-coordinate geometry to three equivalent In(1), two equivalent Ge(1), and three equivalent Ge(2) atoms. In the second Ca site, Ca(2) is bonded in a 9-coordinate geometry to four equivalent In(1), one Ge(2), and four equivalent Ge(1) atoms. In(1) is bonded in a 12-coordinate geometry to one Li(1), three equivalent Ca(1), four equivalent Ca(2), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to one Li(1), two equivalent Ca(1), four equivalent Ca(2), and two equivalent In(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Li(1), one Ca(2), three equivalent Ca(1), and two equivalent In(1) atoms.
LiCa2InGe2 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 5-coordinate geometry to one In(1), one Ge(1), and three equivalent Ge(2) atoms. The Li(1)-In(1) bond length is 2.95 Å. The Li(1)-Ge(1) bond length is 2.76 Å. There is one shorter (2.70 Å) and two longer (2.83 Å) Li(1)-Ge(2) bond lengths. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 5-coordinate geometry to three equivalent In(1), two equivalent Ge(1), and three equivalent Ge(2) atoms. There are two shorter (3.56 Å) and one longer (3.65 Å) Ca(1)-In(1) bond length. Both Ca(1)-Ge(1) bond lengths are 3.09 Å. There is one shorter (3.14 Å) and two longer (3.19 Å) Ca(1)-Ge(2) bond lengths. In the second Ca site, Ca(2) is bonded in a 9-coordinate geometry to four equivalent In(1), one Ge(2), and four equivalent Ge(1) atoms. There are two shorter (3.32 Å) and two longer (3.48 Å) Ca(2)-In(1) bond lengths. The Ca(2)-Ge(2) bond length is 3.11 Å. There are two shorter (3.10 Å) and two longer (3.16 Å) Ca(2)-Ge(1) bond lengths. In(1) is bonded in a 12-coordinate geometry to one Li(1), three equivalent Ca(1), four equivalent Ca(2), two equivalent Ge(1), and two equivalent Ge(2) atoms. There is one shorter (2.85 Å) and one longer (2.87 Å) In(1)-Ge(1) bond length. Both In(1)-Ge(2) bond lengths are 2.83 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to one Li(1), two equivalent Ca(1), four equivalent Ca(2), and two equivalent In(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Li(1), one Ca(2), three equivalent Ca(1), and two equivalent In(1) atoms.