SrAgO2 crystallizes in the monoclinic C2/m space group. Sr(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of corner and edge-sharing SrO6 octahedra. The corner-sharing octahedral tilt angles range from 14-36°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1), one Ag(1), and one Ag(2) atom to form a mixture of distorted corner and edge-sharing OSr4Ag2 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Sr(1), one Ag(1), and one Ag(2) atom.
SrAgO2 crystallizes in the monoclinic C2/m space group. Sr(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of corner and edge-sharing SrO6 octahedra. The corner-sharing octahedral tilt angles range from 14-36°. Both Sr(1)-O(2) bond lengths are 2.51 Å. There are two shorter (2.55 Å) and two longer (2.58 Å) Sr(1)-O(1) bond lengths. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ag(1)-O(1) bond lengths are 2.70 Å. Both Ag(1)-O(2) bond lengths are 2.09 Å. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ag(2)-O(1) bond lengths are 2.06 Å. Both Ag(2)-O(2) bond lengths are 2.05 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Sr(1), one Ag(1), and one Ag(2) atom to form a mixture of distorted corner and edge-sharing OSr4Ag2 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Sr(1), one Ag(1), and one Ag(2) atom.