B2N2Cl3BNCl3(Cl2)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three 7782-50-5 molecules, one B2N2Cl3 cluster, and one BNCl3 cluster. In the B2N2Cl3 cluster, there are two inequivalent B sites. In the first B site, B(1) is bonded in a linear geometry to one N(2) and one Cl(2) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(4) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to one B(1) and one B(2) atom. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one B(2) and one Cl(11) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one B(2) atom. In the third Cl site, Cl(11) is bonded in a single-bond geometry to one N(3) atom. In the BNCl3 cluster, B(3) is bonded in a trigonal planar geometry to one N(1), one Cl(6), and one Cl(7) atom. N(1) is bonded in a distorted single-bond geometry to one B(3) and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one B(3) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one B(3) atom.
B2N2Cl3BNCl3(Cl2)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three 7782-50-5 molecules, one B2N2Cl3 cluster, and one BNCl3 cluster. In the B2N2Cl3 cluster, there are two inequivalent B sites. In the first B site, B(1) is bonded in a linear geometry to one N(2) and one Cl(2) atom. The B(1)-N(2) bond length is 1.27 Å. The B(1)-Cl(2) bond length is 1.67 Å. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one Cl(4) atom. The B(2)-N(2) bond length is 1.41 Å. The B(2)-N(3) bond length is 1.46 Å. The B(2)-Cl(4) bond length is 1.77 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to one B(1) and one B(2) atom. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one B(2) and one Cl(11) atom. The N(3)-Cl(11) bond length is 1.65 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one B(2) atom. In the third Cl site, Cl(11) is bonded in a single-bond geometry to one N(3) atom. In the BNCl3 cluster, B(3) is bonded in a trigonal planar geometry to one N(1), one Cl(6), and one Cl(7) atom. The B(3)-N(1) bond length is 1.43 Å. The B(3)-Cl(6) bond length is 1.77 Å. The B(3)-Cl(7) bond length is 1.74 Å. N(1) is bonded in a distorted single-bond geometry to one B(3) and one Cl(3) atom. The N(1)-Cl(3) bond length is 1.64 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one B(3) atom. In the third Cl site, Cl(7) is bonded in a single-bond geometry to one B(3) atom.