Li4RhH4 crystallizes in the tetragonal I4/m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent H(1) atoms. Rh(1) is bonded in a square co-planar geometry to four equivalent H(1) atoms. H(1) is bonded to four equivalent Li(1) and one Rh(1) atom to form a mixture of distorted edge and corner-sharing HLi4Rh square pyramids.
Li4RhH4 crystallizes in the tetragonal I4/m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent H(1) atoms. There are a spread of Li(1)-H(1) bond distances ranging from 1.93-2.07 Å. Rh(1) is bonded in a square co-planar geometry to four equivalent H(1) atoms. All Rh(1)-H(1) bond lengths are 1.70 Å. H(1) is bonded to four equivalent Li(1) and one Rh(1) atom to form a mixture of distorted edge and corner-sharing HLi4Rh square pyramids.