Ag2PO3F crystallizes in the monoclinic C2/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form AgO4 tetrahedra that share corners with two equivalent Ag(1)O4 tetrahedra and corners with four equivalent P(1)O3F tetrahedra. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the third Ag site, Ag(3) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. P(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form PO3F tetrahedra that share corners with four equivalent Ag(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), one Ag(3), and one P(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), and one P(1) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.
Ag2PO3F crystallizes in the monoclinic C2/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form AgO4 tetrahedra that share corners with two equivalent Ag(1)O4 tetrahedra and corners with four equivalent P(1)O3F tetrahedra. The Ag(1)-O(2) bond length is 2.42 Å. The Ag(1)-O(3) bond length is 2.41 Å. There is one shorter (2.37 Å) and one longer (2.53 Å) Ag(1)-O(1) bond length. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Ag(2)-O(1) bond lengths are 2.57 Å. Both Ag(2)-O(2) bond lengths are 2.50 Å. Both Ag(2)-O(3) bond lengths are 2.76 Å. In the third Ag site, Ag(3) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(3) atoms. Both Ag(3)-O(2) bond lengths are 2.65 Å. Both Ag(3)-O(3) bond lengths are 2.34 Å. P(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form PO3F tetrahedra that share corners with four equivalent Ag(1)O4 tetrahedra. The P(1)-O(1) bond length is 1.54 Å. The P(1)-O(2) bond length is 1.53 Å. The P(1)-O(3) bond length is 1.54 Å. The P(1)-F(1) bond length is 1.61 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), one Ag(3), and one P(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), and one P(1) atom. F(1) is bonded in a single-bond geometry to one P(1) atom.