BaHOBr crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and five equivalent Br(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Ba(1) and one H(1) atom. Br(1) is bonded in a 5-coordinate geometry to five equivalent Ba(1) atoms.
BaHOBr crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and five equivalent Br(1) atoms. There is one shorter (2.63 Å) and two longer (2.64 Å) Ba(1)-O(1) bond lengths. There are a spread of Ba(1)-Br(1) bond distances ranging from 3.48-3.51 Å. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.97 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent Ba(1) and one H(1) atom. Br(1) is bonded in a 5-coordinate geometry to five equivalent Ba(1) atoms.