PtNiF6 is Upper Bainite-derived structured and crystallizes in the trigonal R-3 space group. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 46°. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 46°. F(1) is bonded in a distorted bent 120 degrees geometry to one Pt(1) and one Ni(1) atom.
PtNiF6 is Upper Bainite-derived structured and crystallizes in the trigonal R-3 space group. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedral tilt angles are 46°. All Pt(1)-F(1) bond lengths are 1.96 Å. Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 46°. All Ni(1)-F(1) bond lengths are 1.98 Å. F(1) is bonded in a distorted bent 120 degrees geometry to one Pt(1) and one Ni(1) atom.