PtAgF6 is Upper Bainite-derived structured and crystallizes in the triclinic P-1 space group. Pt(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form PtF6 octahedra that share corners with three equivalent Ag(1)F6 octahedra and corners with three equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(6) atoms to form AgF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the second Ag site, Ag(2) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms to form AgF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to one Pt(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Pt(1) and one Ag(2) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Pt(1) and one Ag(2) atom. In the sixth F site, F(6) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and one Ag(1) atom.
PtAgF6 is Upper Bainite-derived structured and crystallizes in the triclinic P-1 space group. Pt(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form PtF6 octahedra that share corners with three equivalent Ag(1)F6 octahedra and corners with three equivalent Ag(2)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. The Pt(1)-F(1) bond length is 1.94 Å. The Pt(1)-F(2) bond length is 1.96 Å. The Pt(1)-F(3) bond length is 1.92 Å. The Pt(1)-F(4) bond length is 1.95 Å. The Pt(1)-F(5) bond length is 1.96 Å. The Pt(1)-F(6) bond length is 1.93 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(6) atoms to form AgF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. Both Ag(1)-F(1) bond lengths are 2.22 Å. Both Ag(1)-F(2) bond lengths are 2.11 Å. Both Ag(1)-F(6) bond lengths are 2.39 Å. In the second Ag site, Ag(2) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms to form AgF6 octahedra that share corners with six equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. Both Ag(2)-F(3) bond lengths are 2.42 Å. Both Ag(2)-F(4) bond lengths are 2.17 Å. Both Ag(2)-F(5) bond lengths are 2.14 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one Ag(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to one Pt(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Pt(1) and one Ag(2) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Pt(1) and one Ag(2) atom. In the sixth F site, F(6) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and one Ag(1) atom.