PbSnO3 crystallizes in the cubic Fd-3m space group. Pb(1) is bonded in a hexagonal planar geometry to six equivalent O(1) atoms. Sn(1) is bonded to six equivalent O(1) atoms to form corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 49°. O(1) is bonded in a 4-coordinate geometry to two equivalent Pb(1) and two equivalent Sn(1) atoms.
PbSnO3 crystallizes in the cubic Fd-3m space group. Pb(1) is bonded in a hexagonal planar geometry to six equivalent O(1) atoms. All Pb(1)-O(1) bond lengths are 2.63 Å. Sn(1) is bonded to six equivalent O(1) atoms to form corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 49°. All Sn(1)-O(1) bond lengths are 2.09 Å. O(1) is bonded in a 4-coordinate geometry to two equivalent Pb(1) and two equivalent Sn(1) atoms.