AgFeO2 crystallizes in the hexagonal P6_3/mmc space group. Fe(1) is bonded to six equivalent O(1) atoms to form edge-sharing FeO6 octahedra. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent Fe(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OFe3Ag trigonal pyramids.
AgFeO2 crystallizes in the hexagonal P6_3/mmc space group. Fe(1) is bonded to six equivalent O(1) atoms to form edge-sharing FeO6 octahedra. All Fe(1)-O(1) bond lengths are 2.03 Å. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.08 Å. O(1) is bonded to three equivalent Fe(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OFe3Ag trigonal pyramids.