Rb2InAsF6 crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with twelve equivalent Rb(1)F12 cuboctahedra, faces with six equivalent Rb(1)F12 cuboctahedra, faces with four equivalent In(1)F6 octahedra, and faces with four equivalent As(1)F6 octahedra. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent As(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. As(1) is bonded to six equivalent F(1) atoms to form AsF6 octahedra that share corners with six equivalent In(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one In(1), and one As(1) atom.
Rb2InAsF6 crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with twelve equivalent Rb(1)F12 cuboctahedra, faces with six equivalent Rb(1)F12 cuboctahedra, faces with four equivalent In(1)F6 octahedra, and faces with four equivalent As(1)F6 octahedra. All Rb(1)-F(1) bond lengths are 3.32 Å. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent As(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-F(1) bond lengths are 2.60 Å. As(1) is bonded to six equivalent F(1) atoms to form AsF6 octahedra that share corners with six equivalent In(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All As(1)-F(1) bond lengths are 2.08 Å. F(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one In(1), and one As(1) atom.