RhSn4 crystallizes in the trigonal P3_121 space group. Rh(1) is bonded in a 8-coordinate geometry to two equivalent Sn(2), two equivalent Sn(3), and four equivalent Sn(1) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 2-coordinate geometry to two equivalent Rh(1) atoms. In the second Sn site, Sn(3) is bonded in a distorted water-like geometry to two equivalent Rh(1) atoms. In the third Sn site, Sn(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rh(1) atoms.
RhSn4 crystallizes in the trigonal P3_121 space group. Rh(1) is bonded in a 8-coordinate geometry to two equivalent Sn(2), two equivalent Sn(3), and four equivalent Sn(1) atoms. Both Rh(1)-Sn(2) bond lengths are 2.77 Å. Both Rh(1)-Sn(3) bond lengths are 2.86 Å. There are two shorter (2.73 Å) and two longer (2.75 Å) Rh(1)-Sn(1) bond lengths. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 2-coordinate geometry to two equivalent Rh(1) atoms. In the second Sn site, Sn(3) is bonded in a distorted water-like geometry to two equivalent Rh(1) atoms. In the third Sn site, Sn(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Rh(1) atoms.