Ga3NO3 crystallizes in the triclinic P1 space group. There are twelve inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one N(2), one O(1), one O(3), and one O(6) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(10)N2O2 tetrahedra. In the second Ga site, Ga(2) is bonded to one N(2), one N(4), one O(2), and one O(4) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and corners with two equivalent Ga(11)NO3 tetrahedra. In the third Ga site, Ga(3) is bonded to one N(3), one O(11), one O(3), and one O(4) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(9)O4 tetrahedra. In the fourth Ga site, Ga(4) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form GaO4 tetrahedra that share  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra, and corners with two equivalent Ga(5)O4 tetrahedra. In the fifth Ga site, Ga(5) is bonded to one O(11), one O(5), one O(7), and one O(8) atom to form GaO4 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(4)O4 tetrahedra. In the sixth Ga site, Ga(6) is bonded to one N(1), one O(10), one O(4), and one O(8) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(8)NO3 tetrahedra. In the seventh Ga site, Ga(7) is bonded to one N(3), one O(10), one O(6), and one O(9) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(12)N2O2 tetrahedra. In the eighth Ga site, Ga(8) is bonded to one N(1), one O(10), one O(12), and one O(7) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(6)NO3 tetrahedra. In the ninth Ga site, Ga(9) is bonded to one O(11), one O(12), one O(3), and one O(9) atom to form GaO4 tetrahedra that share  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(3)NO3 tetrahedra. In the tenth Ga site, Ga(10) is bonded to one N(1), one N(2), one O(1), and one O(5) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(1)NO3 tetrahedra. In the eleventh Ga site, Ga(11) is bonded to one N(4), one O(1), one O(12), and one O(2) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(2)N2O2 tetrahedra. In the twelfth Ga site, Ga(12) is bonded to one N(3), one N(4), one O(5), and one O(9) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(7)NO3 tetrahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ga(10), one Ga(6), and one Ga(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ga(1), one Ga(10), and one Ga(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ga(12), one Ga(3), and one Ga(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ga(11), one Ga(12), and one Ga(2) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ga(1), one Ga(10), and one Ga(11) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ga(11), one Ga(2), and one Ga(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ga(1), one Ga(3), and one Ga(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Ga(2), one Ga(3), and one Ga(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Ga(10), one Ga(12), and one Ga(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Ga(1), one Ga(4), and one Ga(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Ga(4), one Ga(5), and one Ga(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Ga(4), one Ga(5), and one Ga(6) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Ga(12), one Ga(7), and one Ga(9) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Ga(6), one Ga(7), and one Ga(8) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Ga(3), one Ga(5), and one Ga(9) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to one Ga(11), one Ga(8), and one Ga(9) atom.
Ga3NO3 crystallizes in the triclinic P1 space group. There are twelve inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one N(2), one O(1), one O(3), and one O(6) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(10)N2O2 tetrahedra. The Ga(1)-N(2) bond length is 1.83 Å. The Ga(1)-O(1) bond length is 1.86 Å. The Ga(1)-O(3) bond length is 1.92 Å. The Ga(1)-O(6) bond length is 1.91 Å. In the second Ga site, Ga(2) is bonded to one N(2), one N(4), one O(2), and one O(4) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and corners with two equivalent Ga(11)NO3 tetrahedra. The Ga(2)-N(2) bond length is 1.87 Å. The Ga(2)-N(4) bond length is 1.87 Å. The Ga(2)-O(2) bond length is 1.95 Å. The Ga(2)-O(4) bond length is 1.92 Å. In the third Ga site, Ga(3) is bonded to one N(3), one O(11), one O(3), and one O(4) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(9)O4 tetrahedra. The Ga(3)-N(3) bond length is 1.87 Å. The Ga(3)-O(11) bond length is 1.94 Å. The Ga(3)-O(3) bond length is 1.94 Å. The Ga(3)-O(4) bond length is 1.89 Å. In the fourth Ga site, Ga(4) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form GaO4 tetrahedra that share  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra, and corners with two equivalent Ga(5)O4 tetrahedra. The Ga(4)-O(2) bond length is 1.85 Å. The Ga(4)-O(6) bond length is 1.88 Å. The Ga(4)-O(7) bond length is 1.87 Å. The Ga(4)-O(8) bond length is 1.90 Å. In the fifth Ga site, Ga(5) is bonded to one O(11), one O(5), one O(7), and one O(8) atom to form GaO4 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(4)O4 tetrahedra. The Ga(5)-O(11) bond length is 1.91 Å. The Ga(5)-O(5) bond length is 1.84 Å. The Ga(5)-O(7) bond length is 1.90 Å. The Ga(5)-O(8) bond length is 1.87 Å. In the sixth Ga site, Ga(6) is bonded to one N(1), one O(10), one O(4), and one O(8) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(8)NO3 tetrahedra. The Ga(6)-N(1) bond length is 1.83 Å. The Ga(6)-O(10) bond length is 1.92 Å. The Ga(6)-O(4) bond length is 1.86 Å. The Ga(6)-O(8) bond length is 1.97 Å. In the seventh Ga site, Ga(7) is bonded to one N(3), one O(10), one O(6), and one O(9) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(12)N2O2 tetrahedra. The Ga(7)-N(3) bond length is 1.84 Å. The Ga(7)-O(10) bond length is 1.92 Å. The Ga(7)-O(6) bond length is 1.92 Å. The Ga(7)-O(9) bond length is 1.89 Å. In the eighth Ga site, Ga(8) is bonded to one N(1), one O(10), one O(12), and one O(7) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(6)NO3 tetrahedra. The Ga(8)-N(1) bond length is 1.83 Å. The Ga(8)-O(10) bond length is 1.88 Å. The Ga(8)-O(12) bond length is 1.91 Å. The Ga(8)-O(7) bond length is 1.93 Å. In the ninth Ga site, Ga(9) is bonded to one O(11), one O(12), one O(3), and one O(9) atom to form GaO4 tetrahedra that share  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(7)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(3)NO3 tetrahedra. The Ga(9)-O(11) bond length is 1.91 Å. The Ga(9)-O(12) bond length is 1.88 Å. The Ga(9)-O(3) bond length is 1.87 Å. The Ga(9)-O(9) bond length is 1.88 Å. In the tenth Ga site, Ga(10) is bonded to one N(1), one N(2), one O(1), and one O(5) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(6)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and corners with two equivalent Ga(1)NO3 tetrahedra. The Ga(10)-N(1) bond length is 1.86 Å. The Ga(10)-N(2) bond length is 1.84 Å. The Ga(10)-O(1) bond length is 1.96 Å. The Ga(10)-O(5) bond length is 1.92 Å. In the eleventh Ga site, Ga(11) is bonded to one N(4), one O(1), one O(12), and one O(2) atom to form GaNO3 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(12)N2O2 tetrahedra,  a cornercorner with one Ga(1)NO3 tetrahedra,  a cornercorner with one Ga(8)NO3 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(2)N2O2 tetrahedra. The Ga(11)-N(4) bond length is 1.85 Å. The Ga(11)-O(1) bond length is 1.90 Å. The Ga(11)-O(12) bond length is 1.93 Å. The Ga(11)-O(2) bond length is 1.90 Å. In the twelfth Ga site, Ga(12) is bonded to one N(3), one N(4), one O(5), and one O(9) atom to form GaN2O2 tetrahedra that share  a cornercorner with one Ga(10)N2O2 tetrahedra,  a cornercorner with one Ga(2)N2O2 tetrahedra,  a cornercorner with one Ga(11)NO3 tetrahedra,  a cornercorner with one Ga(3)NO3 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(9)O4 tetrahedra, and corners with two equivalent Ga(7)NO3 tetrahedra. The Ga(12)-N(3) bond length is 1.85 Å. The Ga(12)-N(4) bond length is 1.87 Å. The Ga(12)-O(5) bond length is 1.94 Å. The Ga(12)-O(9) bond length is 1.98 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ga(10), one Ga(6), and one Ga(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ga(1), one Ga(10), and one Ga(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ga(12), one Ga(3), and one Ga(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ga(11), one Ga(12), and one Ga(2) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ga(1), one Ga(10), and one Ga(11) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ga(11), one Ga(2), and one Ga(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ga(1), one Ga(3), and one Ga(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Ga(2), one Ga(3), and one Ga(6) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Ga(10), one Ga(12), and one Ga(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Ga(1), one Ga(4), and one Ga(7) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Ga(4), one Ga(5), and one Ga(8) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Ga(4), one Ga(5), and one Ga(6) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Ga(12), one Ga(7), and one Ga(9) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Ga(6), one Ga(7), and one Ga(8) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Ga(3), one Ga(5), and one Ga(9) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to one Ga(11), one Ga(8), and one Ga(9) atom.