Rb2Pd(NO3)4 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), two equivalent O(3), and three equivalent O(5) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(6) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one N(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(2) atom.
Rb2Pd(NO3)4 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), two equivalent O(3), and three equivalent O(5) atoms. The Rb(1)-O(2) bond length is 3.01 Å. The Rb(1)-O(4) bond length is 3.28 Å. The Rb(1)-O(6) bond length is 2.97 Å. There is one shorter (2.96 Å) and one longer (3.18 Å) Rb(1)-O(1) bond length. There is one shorter (3.02 Å) and one longer (3.50 Å) Rb(1)-O(3) bond length. There are a spread of Rb(1)-O(5) bond distances ranging from 3.03-3.47 Å. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(6) atoms. Both Pd(1)-O(2) bond lengths are 2.04 Å. Both Pd(1)-O(6) bond lengths are 2.03 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. The N(1)-O(2) bond length is 1.33 Å. The N(1)-O(4) bond length is 1.24 Å. The N(1)-O(5) bond length is 1.25 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. The N(2)-O(1) bond length is 1.25 Å. The N(2)-O(3) bond length is 1.24 Å. The N(2)-O(6) bond length is 1.32 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one N(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(2) atom.