(K)2TlGaBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlGaBr6 framework. In the TlGaBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Ga(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Ga(1) is bonded to six equivalent Br(1) atoms to form GaBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Tl(1) and one Ga(1) atom.
(K)2TlGaBr6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlGaBr6 framework. In the TlGaBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Ga(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 3.12 Å. Ga(1) is bonded to six equivalent Br(1) atoms to form GaBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Ga(1)-Br(1) bond lengths are 2.57 Å. Br(1) is bonded in a linear geometry to one Tl(1) and one Ga(1) atom.