CeCo4B4 crystallizes in the tetragonal P4_2/nmc space group. Ce(1) is bonded in a 24-coordinate geometry to twelve equivalent Co(1) and twelve equivalent B(1) atoms. Co(1) is bonded in a 5-coordinate geometry to three equivalent Ce(1) and five equivalent B(1) atoms. B(1) is bonded in a 6-coordinate geometry to three equivalent Ce(1), five equivalent Co(1), and one B(1) atom.
CeCo4B4 crystallizes in the tetragonal P4_2/nmc space group. Ce(1) is bonded in a 24-coordinate geometry to twelve equivalent Co(1) and twelve equivalent B(1) atoms. There are four shorter (2.84 Å) and eight longer (2.99 Å) Ce(1)-Co(1) bond lengths. There are eight shorter (2.89 Å) and four longer (2.91 Å) Ce(1)-B(1) bond lengths. Co(1) is bonded in a 5-coordinate geometry to three equivalent Ce(1) and five equivalent B(1) atoms. There are a spread of Co(1)-B(1) bond distances ranging from 2.07-2.12 Å. B(1) is bonded in a 6-coordinate geometry to three equivalent Ce(1), five equivalent Co(1), and one B(1) atom. The B(1)-B(1) bond length is 1.75 Å.