La2ZnMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R-3 space group. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 23°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 23°. O(1) is bonded in a 3-coordinate geometry to three equivalent La(1), one Mn(1), and one Zn(1) atom.
La2ZnMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R-3 space group. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. There are a spread of La(1)-O(1) bond distances ranging from 2.41-2.83 Å. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 23°. All Mn(1)-O(1) bond lengths are 1.93 Å. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 23°. All Zn(1)-O(1) bond lengths are 2.09 Å. O(1) is bonded in a 3-coordinate geometry to three equivalent La(1), one Mn(1), and one Zn(1) atom.