Sb4Cl13F7 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Sb4Cl13F7 cluster. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one Cl(1), one Cl(3), one Cl(9), one F(1), one F(3), and one F(5) atom to form distorted SbCl3F3 octahedra that share  a cornercorner with one Sb(4)Cl3F3 octahedra and  a cornercorner with one Sb(3)Cl4F2 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. In the second Sb site, Sb(2) is bonded to one Cl(10), one Cl(2), one Cl(4), one F(2), one F(4), and one F(6) atom to form distorted SbCl3F3 octahedra that share  a cornercorner with one Sb(4)Cl3F3 octahedra and  a cornercorner with one Sb(3)Cl4F2 octahedra. The corner-sharing octahedral tilt angles range from 12-14°. In the third Sb site, Sb(3) is bonded to one Cl(11), one Cl(12), one Cl(5), one Cl(7), one F(1), and one F(4) atom to form corner-sharing SbCl4F2 octahedra. The corner-sharing octahedral tilt angles are 14°. In the fourth Sb site, Sb(4) is bonded to one Cl(13), one Cl(6), one Cl(8), one F(2), one F(3), and one F(7) atom to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles range from 11-12°. There are thirteen inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(3) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(4) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(3) atom. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(4) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the tenth Cl site, Cl(10) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh Cl site, Cl(11) is bonded in a single-bond geometry to one Sb(3) atom. In the twelfth Cl site, Cl(12) is bonded in a single-bond geometry to one Sb(3) atom. In the thirteenth Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(4) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Sb(1) and one Sb(3) atom. In the second F site, F(2) is bonded in a linear geometry to one Sb(2) and one Sb(4) atom. In the third F site, F(3) is bonded in a linear geometry to one Sb(1) and one Sb(4) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Sb(2) and one Sb(3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(4) atom.
Sb4Cl13F7 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Sb4Cl13F7 cluster. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one Cl(1), one Cl(3), one Cl(9), one F(1), one F(3), and one F(5) atom to form distorted SbCl3F3 octahedra that share  a cornercorner with one Sb(4)Cl3F3 octahedra and  a cornercorner with one Sb(3)Cl4F2 octahedra. The corner-sharing octahedral tilt angles range from 11-14°. The Sb(1)-Cl(1) bond length is 2.30 Å. The Sb(1)-Cl(3) bond length is 2.31 Å. The Sb(1)-Cl(9) bond length is 2.29 Å. The Sb(1)-F(1) bond length is 2.06 Å. The Sb(1)-F(3) bond length is 2.08 Å. The Sb(1)-F(5) bond length is 1.88 Å. In the second Sb site, Sb(2) is bonded to one Cl(10), one Cl(2), one Cl(4), one F(2), one F(4), and one F(6) atom to form distorted SbCl3F3 octahedra that share  a cornercorner with one Sb(4)Cl3F3 octahedra and  a cornercorner with one Sb(3)Cl4F2 octahedra. The corner-sharing octahedral tilt angles range from 12-14°. The Sb(2)-Cl(10) bond length is 2.30 Å. The Sb(2)-Cl(2) bond length is 2.30 Å. The Sb(2)-Cl(4) bond length is 2.31 Å. The Sb(2)-F(2) bond length is 2.08 Å. The Sb(2)-F(4) bond length is 2.06 Å. The Sb(2)-F(6) bond length is 1.88 Å. In the third Sb site, Sb(3) is bonded to one Cl(11), one Cl(12), one Cl(5), one Cl(7), one F(1), and one F(4) atom to form corner-sharing SbCl4F2 octahedra. The corner-sharing octahedral tilt angles are 14°. The Sb(3)-Cl(11) bond length is 2.30 Å. The Sb(3)-Cl(12) bond length is 2.30 Å. The Sb(3)-Cl(5) bond length is 2.30 Å. The Sb(3)-Cl(7) bond length is 2.31 Å. The Sb(3)-F(1) bond length is 2.13 Å. The Sb(3)-F(4) bond length is 2.13 Å. In the fourth Sb site, Sb(4) is bonded to one Cl(13), one Cl(6), one Cl(8), one F(2), one F(3), and one F(7) atom to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles range from 11-12°. The Sb(4)-Cl(13) bond length is 2.31 Å. The Sb(4)-Cl(6) bond length is 2.30 Å. The Sb(4)-Cl(8) bond length is 2.30 Å. The Sb(4)-F(2) bond length is 2.08 Å. The Sb(4)-F(3) bond length is 2.08 Å. The Sb(4)-F(7) bond length is 1.88 Å. There are thirteen inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(3) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Sb(4) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Sb(3) atom. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one Sb(4) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. In the tenth Cl site, Cl(10) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh Cl site, Cl(11) is bonded in a single-bond geometry to one Sb(3) atom. In the twelfth Cl site, Cl(12) is bonded in a single-bond geometry to one Sb(3) atom. In the thirteenth Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(4) atom. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Sb(1) and one Sb(3) atom. In the second F site, F(2) is bonded in a linear geometry to one Sb(2) and one Sb(4) atom. In the third F site, F(3) is bonded in a linear geometry to one Sb(1) and one Sb(4) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Sb(2) and one Sb(3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(4) atom.