Co7(RuO6)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(20), one O(22), one O(23), one O(3), and one O(5) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. In the second Ru site, Ru(2) is bonded to one O(12), one O(2), one O(22), one O(24), one O(4), and one O(9) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. In the third Ru site, Ru(3) is bonded to one O(13), one O(14), one O(15), one O(16), one O(18), and one O(19) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. In the fourth Ru site, Ru(4) is bonded to one O(10), one O(15), one O(17), one O(19), one O(7), and one O(8) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. There are fourteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(16), one O(2), and one O(5) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-64°. In the second Co site, Co(2) is bonded to one O(1), one O(13), one O(14), one O(17), one O(18), and one O(19) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Ru(3)O6 octahedra. In the third Co site, Co(3) is bonded to one O(2), one O(20), one O(21), one O(23), one O(4), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Ru(1)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(11), one O(22), one O(4), and one O(7) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, and corners with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-65°. In the fifth Co site, Co(5) is bonded to one O(22), one O(24), one O(4), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(2)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(10), one O(11), one O(12), one O(24), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. In the seventh Co site, Co(7) is bonded to one O(10), one O(14), one O(18), and one O(8) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-64°. In the eighth Co site, Co(8) is bonded to one O(11), one O(12), one O(6), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. In the ninth Co site, Co(9) is bonded to one O(10), one O(11), one O(13), one O(15), one O(17), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(4)O6 octahedra. In the tenth Co site, Co(10) is bonded to one O(12), one O(15), one O(17), and one O(6) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, corners with two equivalent Co(8)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-67°. In the eleventh Co site, Co(11) is bonded to one O(1), one O(16), one O(18), one O(20), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(13)O6 octahedra. In the twelfth Co site, Co(12) is bonded to one O(13), one O(19), one O(21), and one O(3) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-65°. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(14), one O(16), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(11)O6 octahedra. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(23), one O(24), and one O(9) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(11), one Co(13), and one Co(2) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(13)Co3Ru trigonal pyramid,  a cornercorner with one O(5)Co3Ru trigonal pyramid, and corners with two equivalent O(21)Co4 trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(1), and one Co(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Co(11), one Co(12), and one Co(13) atom. In the fourth O site, O(4) is bonded to one Ru(2), one Co(3), one Co(4), and one Co(5) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(6)Co4 tetrahedra,  a cornercorner with one O(12)Co3Ru trigonal pyramid,  a cornercorner with one O(21)Co4 trigonal pyramid, corners with two equivalent O(9)Co3Ru trigonal pyramids, and  an edgeedge with one O(5)Co3Ru trigonal pyramid. In the fifth O site, O(5) is bonded to one Ru(1), one Co(1), one Co(3), and one Co(5) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(6)Co4 tetrahedra,  a cornercorner with one O(9)Co3Ru trigonal pyramid,  a cornercorner with one O(1)Co4 trigonal pyramid,  a cornercorner with one O(21)Co4 trigonal pyramid, and  an edgeedge with one O(4)Co3Ru trigonal pyramid. In the sixth O site, O(6) is bonded to one Co(10), one Co(5), one Co(6), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OCo4 tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Ru(4), one Co(4), one Co(6), and one Co(8) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Ru(4), one Co(7), one Co(8), and one Co(9) atom. In the ninth O site, O(9) is bonded to one Ru(2), one Co(14), one Co(5), and one Co(8) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(5)Co3Ru trigonal pyramid, corners with two equivalent O(4)Co3Ru trigonal pyramids,  an edgeedge with one O(6)Co4 tetrahedra, and  an edgeedge with one O(12)Co3Ru trigonal pyramid. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Ru(4), one Co(6), one Co(7), and one Co(9) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(4), one Co(6), one Co(8), and one Co(9) atom. In the twelfth O site, O(12) is bonded to one Ru(2), one Co(10), one Co(6), and one Co(8) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(6)Co4 tetrahedra,  a cornercorner with one O(4)Co3Ru trigonal pyramid,  an edgeedge with one O(6)Co4 tetrahedra, and  an edgeedge with one O(9)Co3Ru trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Ru(3), one Co(12), one Co(2), and one Co(9) atom to form distorted corner-sharing OCo3Ru trigonal pyramids. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Co(13), one Co(2), and one Co(7) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(10), and one Co(9) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Co(1), one Co(11), and one Co(13) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Ru(4), one Co(10), one Co(2), and one Co(9) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Ru(3), one Co(11), one Co(2), and one Co(7) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(12), and one Co(2) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Co(11), one Co(14), and one Co(3) atom. In the twenty-first O site, O(21) is bonded to one Co(11), one Co(12), one Co(13), and one Co(3) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(13)Co3Ru trigonal pyramid,  a cornercorner with one O(4)Co3Ru trigonal pyramid,  a cornercorner with one O(5)Co3Ru trigonal pyramid, and corners with two equivalent O(1)Co4 trigonal pyramids. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(4), and one Co(5) atom. In the twenty-third O site, O(23) is bonded in a distorted rectangular see-saw-like geometry to one Ru(1), one Co(13), one Co(14), and one Co(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Ru(2), one Co(14), one Co(5), and one Co(6) atom.
Co7(RuO6)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are four inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(20), one O(22), one O(23), one O(3), and one O(5) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The Ru(1)-O(2) bond length is 2.05 Å. The Ru(1)-O(20) bond length is 2.06 Å. The Ru(1)-O(22) bond length is 2.04 Å. The Ru(1)-O(23) bond length is 2.03 Å. The Ru(1)-O(3) bond length is 1.97 Å. The Ru(1)-O(5) bond length is 2.08 Å. In the second Ru site, Ru(2) is bonded to one O(12), one O(2), one O(22), one O(24), one O(4), and one O(9) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The Ru(2)-O(12) bond length is 2.00 Å. The Ru(2)-O(2) bond length is 2.02 Å. The Ru(2)-O(22) bond length is 2.04 Å. The Ru(2)-O(24) bond length is 2.04 Å. The Ru(2)-O(4) bond length is 2.06 Å. The Ru(2)-O(9) bond length is 2.07 Å. In the third Ru site, Ru(3) is bonded to one O(13), one O(14), one O(15), one O(16), one O(18), and one O(19) atom to form RuO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The Ru(3)-O(13) bond length is 2.06 Å. The Ru(3)-O(14) bond length is 2.05 Å. The Ru(3)-O(15) bond length is 2.03 Å. The Ru(3)-O(16) bond length is 1.98 Å. The Ru(3)-O(18) bond length is 2.03 Å. The Ru(3)-O(19) bond length is 2.05 Å. In the fourth Ru site, Ru(4) is bonded to one O(10), one O(15), one O(17), one O(19), one O(7), and one O(8) atom to form RuO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Co(9)O6 octahedra. The Ru(4)-O(10) bond length is 2.00 Å. The Ru(4)-O(15) bond length is 2.01 Å. The Ru(4)-O(17) bond length is 2.03 Å. The Ru(4)-O(19) bond length is 2.03 Å. The Ru(4)-O(7) bond length is 2.03 Å. The Ru(4)-O(8) bond length is 2.04 Å. There are fourteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(16), one O(2), and one O(5) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-64°. The Co(1)-O(1) bond length is 1.94 Å. The Co(1)-O(16) bond length is 1.96 Å. The Co(1)-O(2) bond length is 2.03 Å. The Co(1)-O(5) bond length is 2.00 Å. In the second Co site, Co(2) is bonded to one O(1), one O(13), one O(14), one O(17), one O(18), and one O(19) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Ru(3)O6 octahedra. The Co(2)-O(1) bond length is 1.93 Å. The Co(2)-O(13) bond length is 1.95 Å. The Co(2)-O(14) bond length is 1.93 Å. The Co(2)-O(17) bond length is 1.95 Å. The Co(2)-O(18) bond length is 1.93 Å. The Co(2)-O(19) bond length is 2.00 Å. In the third Co site, Co(3) is bonded to one O(2), one O(20), one O(21), one O(23), one O(4), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and edges with two equivalent Ru(1)O6 octahedra. The Co(3)-O(2) bond length is 1.99 Å. The Co(3)-O(20) bond length is 1.94 Å. The Co(3)-O(21) bond length is 1.93 Å. The Co(3)-O(23) bond length is 1.92 Å. The Co(3)-O(4) bond length is 1.96 Å. The Co(3)-O(5) bond length is 1.97 Å. In the fourth Co site, Co(4) is bonded to one O(11), one O(22), one O(4), and one O(7) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(5)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, and corners with two equivalent Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-65°. The Co(4)-O(11) bond length is 1.95 Å. The Co(4)-O(22) bond length is 2.04 Å. The Co(4)-O(4) bond length is 1.97 Å. The Co(4)-O(7) bond length is 1.97 Å. In the fifth Co site, Co(5) is bonded to one O(22), one O(24), one O(4), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(1)O4 tetrahedra,  a cornercorner with one Co(10)O4 tetrahedra, corners with two equivalent Co(14)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(2)O6 octahedra. The Co(5)-O(22) bond length is 1.99 Å. The Co(5)-O(24) bond length is 1.93 Å. The Co(5)-O(4) bond length is 1.95 Å. The Co(5)-O(5) bond length is 1.97 Å. The Co(5)-O(6) bond length is 1.93 Å. The Co(5)-O(9) bond length is 1.93 Å. In the sixth Co site, Co(6) is bonded to one O(10), one O(11), one O(12), one O(24), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The Co(6)-O(10) bond length is 2.08 Å. The Co(6)-O(11) bond length is 2.00 Å. The Co(6)-O(12) bond length is 2.14 Å. The Co(6)-O(24) bond length is 2.10 Å. The Co(6)-O(6) bond length is 2.02 Å. The Co(6)-O(7) bond length is 2.15 Å. In the seventh Co site, Co(7) is bonded to one O(10), one O(14), one O(18), and one O(8) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-64°. The Co(7)-O(10) bond length is 1.95 Å. The Co(7)-O(14) bond length is 1.98 Å. The Co(7)-O(18) bond length is 1.95 Å. The Co(7)-O(8) bond length is 1.98 Å. In the eighth Co site, Co(8) is bonded to one O(11), one O(12), one O(6), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(4)O4 tetrahedra,  an edgeedge with one Ru(2)O6 octahedra,  an edgeedge with one Ru(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(9)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The Co(8)-O(11) bond length is 1.94 Å. The Co(8)-O(12) bond length is 1.96 Å. The Co(8)-O(6) bond length is 1.94 Å. The Co(8)-O(7) bond length is 1.95 Å. The Co(8)-O(8) bond length is 1.96 Å. The Co(8)-O(9) bond length is 1.97 Å. In the ninth Co site, Co(9) is bonded to one O(10), one O(11), one O(13), one O(15), one O(17), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Co(12)O4 tetrahedra,  a cornercorner with one Co(4)O4 tetrahedra, corners with two equivalent Co(10)O4 tetrahedra, corners with two equivalent Co(7)O4 tetrahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and edges with two equivalent Ru(4)O6 octahedra. The Co(9)-O(10) bond length is 2.05 Å. The Co(9)-O(11) bond length is 2.06 Å. The Co(9)-O(13) bond length is 2.07 Å. The Co(9)-O(15) bond length is 2.16 Å. The Co(9)-O(17) bond length is 2.06 Å. The Co(9)-O(8) bond length is 2.06 Å. In the tenth Co site, Co(10) is bonded to one O(12), one O(15), one O(17), and one O(6) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(2)O6 octahedra,  a cornercorner with one Ru(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra, corners with two equivalent Ru(4)O6 octahedra, corners with two equivalent Co(6)O6 octahedra, corners with two equivalent Co(8)O6 octahedra, and corners with two equivalent Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-67°. The Co(10)-O(12) bond length is 1.99 Å. The Co(10)-O(15) bond length is 1.99 Å. The Co(10)-O(17) bond length is 1.95 Å. The Co(10)-O(6) bond length is 1.96 Å. In the eleventh Co site, Co(11) is bonded to one O(1), one O(16), one O(18), one O(20), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(13)O6 octahedra. The Co(11)-O(1) bond length is 2.01 Å. The Co(11)-O(16) bond length is 2.10 Å. The Co(11)-O(18) bond length is 2.11 Å. The Co(11)-O(20) bond length is 2.11 Å. The Co(11)-O(21) bond length is 2.01 Å. The Co(11)-O(3) bond length is 2.09 Å. In the twelfth Co site, Co(12) is bonded to one O(13), one O(19), one O(21), and one O(3) atom to form CoO4 tetrahedra that share  a cornercorner with one Ru(1)O6 octahedra,  a cornercorner with one Ru(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra, corners with two equivalent Ru(3)O6 octahedra, corners with two equivalent Co(11)O6 octahedra, corners with two equivalent Co(13)O6 octahedra, and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-65°. The Co(12)-O(13) bond length is 1.99 Å. The Co(12)-O(19) bond length is 2.03 Å. The Co(12)-O(21) bond length is 1.94 Å. The Co(12)-O(3) bond length is 1.97 Å. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(14), one O(16), one O(21), one O(23), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Co(14)O4 tetrahedra,  a cornercorner with one Co(7)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, corners with two equivalent Co(12)O4 tetrahedra,  an edgeedge with one Ru(1)O6 octahedra,  an edgeedge with one Ru(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with two equivalent Co(11)O6 octahedra. The Co(13)-O(1) bond length is 2.03 Å. The Co(13)-O(14) bond length is 2.13 Å. The Co(13)-O(16) bond length is 2.06 Å. The Co(13)-O(21) bond length is 2.03 Å. The Co(13)-O(23) bond length is 2.13 Å. The Co(13)-O(3) bond length is 2.07 Å. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(23), one O(24), and one O(9) atom to form CoO4 tetrahedra that share  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, corners with two equivalent Ru(1)O6 octahedra, corners with two equivalent Ru(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, and corners with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. The Co(14)-O(20) bond length is 1.96 Å. The Co(14)-O(23) bond length is 1.97 Å. The Co(14)-O(24) bond length is 1.96 Å. The Co(14)-O(9) bond length is 2.00 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(11), one Co(13), and one Co(2) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(13)Co3Ru trigonal pyramid,  a cornercorner with one O(5)Co3Ru trigonal pyramid, and corners with two equivalent O(21)Co4 trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(1), and one Co(3) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Co(11), one Co(12), and one Co(13) atom. In the fourth O site, O(4) is bonded to one Ru(2), one Co(3), one Co(4), and one Co(5) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(6)Co4 tetrahedra,  a cornercorner with one O(12)Co3Ru trigonal pyramid,  a cornercorner with one O(21)Co4 trigonal pyramid, corners with two equivalent O(9)Co3Ru trigonal pyramids, and  an edgeedge with one O(5)Co3Ru trigonal pyramid. In the fifth O site, O(5) is bonded to one Ru(1), one Co(1), one Co(3), and one Co(5) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(6)Co4 tetrahedra,  a cornercorner with one O(9)Co3Ru trigonal pyramid,  a cornercorner with one O(1)Co4 trigonal pyramid,  a cornercorner with one O(21)Co4 trigonal pyramid, and  an edgeedge with one O(4)Co3Ru trigonal pyramid. In the sixth O site, O(6) is bonded to one Co(10), one Co(5), one Co(6), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OCo4 tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Ru(4), one Co(4), one Co(6), and one Co(8) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Ru(4), one Co(7), one Co(8), and one Co(9) atom. In the ninth O site, O(9) is bonded to one Ru(2), one Co(14), one Co(5), and one Co(8) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(5)Co3Ru trigonal pyramid, corners with two equivalent O(4)Co3Ru trigonal pyramids,  an edgeedge with one O(6)Co4 tetrahedra, and  an edgeedge with one O(12)Co3Ru trigonal pyramid. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Ru(4), one Co(6), one Co(7), and one Co(9) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(4), one Co(6), one Co(8), and one Co(9) atom. In the twelfth O site, O(12) is bonded to one Ru(2), one Co(10), one Co(6), and one Co(8) atom to form distorted OCo3Ru trigonal pyramids that share  a cornercorner with one O(6)Co4 tetrahedra,  a cornercorner with one O(4)Co3Ru trigonal pyramid,  an edgeedge with one O(6)Co4 tetrahedra, and  an edgeedge with one O(9)Co3Ru trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Ru(3), one Co(12), one Co(2), and one Co(9) atom to form distorted corner-sharing OCo3Ru trigonal pyramids. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Co(13), one Co(2), and one Co(7) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(10), and one Co(9) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Co(1), one Co(11), and one Co(13) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Ru(4), one Co(10), one Co(2), and one Co(9) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Ru(3), one Co(11), one Co(2), and one Co(7) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Ru(3), one Ru(4), one Co(12), and one Co(2) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Co(11), one Co(14), and one Co(3) atom. In the twenty-first O site, O(21) is bonded to one Co(11), one Co(12), one Co(13), and one Co(3) atom to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(13)Co3Ru trigonal pyramid,  a cornercorner with one O(4)Co3Ru trigonal pyramid,  a cornercorner with one O(5)Co3Ru trigonal pyramid, and corners with two equivalent O(1)Co4 trigonal pyramids. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Ru(1), one Ru(2), one Co(4), and one Co(5) atom. In the twenty-third O site, O(23) is bonded in a distorted rectangular see-saw-like geometry to one Ru(1), one Co(13), one Co(14), and one Co(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Ru(2), one Co(14), one Co(5), and one Co(6) atom.