Li6Mn5SbO12 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(17), one O(21), one O(3), and one O(5) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. In the second Li site, Li(2) is bonded to one O(18), one O(22), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. In the third Li site, Li(3) is bonded to one O(1), one O(19), one O(23), and one O(7) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. In the fourth Li site, Li(4) is bonded to one O(2), one O(20), one O(24), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. In the fifth Li site, Li(5) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(15), one O(19), and one O(24) atom. In the sixth Li site, Li(6) is bonded in a distorted rectangular see-saw-like geometry to one O(16), one O(2), one O(20), and one O(23) atom. In the seventh Li site, Li(7) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(17), one O(22), and one O(3) atom. In the eighth Li site, Li(8) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(18), one O(21), and one O(4) atom. In the ninth Li site, Li(9) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(11), one O(20), and one O(23) atom. In the tenth Li site, Li(10) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(19), one O(2), and one O(24) atom. In the eleventh Li site, Li(11) is bonded in a distorted rectangular see-saw-like geometry to one O(18), one O(21), one O(3), and one O(9) atom. In the twelfth Li site, Li(12) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(17), one O(22), and one O(4) atom. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(18), one O(2), one O(20), one O(21), one O(23), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(2)O4 tetrahedra, and  an edgeedge with one Li(4)O4 tetrahedra. In the third Mn site, Mn(3) is bonded to one O(1), one O(17), one O(19), one O(22), one O(24), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(11), one O(13), one O(16), one O(5), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(9)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(14), one O(15), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(9)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the sixth Mn site, Mn(6) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(2)O4 tetrahedra, and  an edgeedge with one Li(4)O4 tetrahedra. In the seventh Mn site, Mn(7) is bonded to one O(17), one O(19), one O(2), one O(22), one O(24), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(2)O4 tetrahedra, and  an edgeedge with one Li(4)O4 tetrahedra. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(18), one O(20), one O(21), one O(23), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(11), one O(13), one O(16), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. In the tenth Mn site, Mn(10) is bonded to one O(12), one O(14), one O(15), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(9)O6 octahedra. In the second Sb site, Sb(2) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, and edges with two equivalent O(23)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second O site, O(2) is bonded to one Li(10), one Li(4), one Li(6), one Mn(2), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, and edges with two equivalent O(24)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the third O site, O(3) is bonded to one Li(1), one Li(11), one Li(7), one Mn(1), one Mn(3), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra, edges with two equivalent O(17)Li3Mn3 octahedra, and edges with two equivalent O(21)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fourth O site, O(4) is bonded to one Li(12), one Li(2), one Li(8), one Mn(2), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra, edges with two equivalent O(18)Li3Mn3 octahedra, and edges with two equivalent O(22)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(5) is bonded to one Li(1), one Mn(10), one Mn(4), and one Sb(2) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(8)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 56-62°. In the sixth O site, O(6) is bonded to one Li(2), one Mn(5), one Mn(9), and one Sb(1) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(7)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 56-63°. In the seventh O site, O(7) is bonded to one Li(3), one Mn(5), one Mn(9), and one Sb(1) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(6)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 57-62°. In the eighth O site, O(8) is bonded to one Li(4), one Mn(10), one Mn(4), and one Sb(2) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(5)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 56-62°. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(11), one Mn(10), one Mn(5), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(12), one Mn(4), one Mn(9), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(9), one Mn(4), one Mn(9), and one Sb(1) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(10), one Mn(5), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(7), one Mn(4), one Mn(9), and one Sb(2) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Mn(10), one Mn(5), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(10), one Mn(5), and one Sb(1) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(4), one Mn(9), and one Sb(2) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(12), one Li(7), one Mn(1), one Mn(3), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(22)Li3Mn3 octahedra, and edges with two equivalent O(3)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the eighteenth O site, O(18) is bonded to one Li(11), one Li(2), one Li(8), one Mn(2), one Mn(6), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(21)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(3), one Li(5), one Mn(1), one Mn(3), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, and edges with two equivalent O(24)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the twentieth O site, O(20) is bonded to one Li(4), one Li(6), one Li(9), one Mn(2), one Mn(6), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra, and edges with two equivalent O(23)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(11), one Li(8), one Mn(1), one Mn(2), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(18)Li3Mn3 octahedra, and edges with two equivalent O(3)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-second O site, O(22) is bonded to one Li(12), one Li(2), one Li(7), one Mn(3), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(17)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the twenty-third O site, O(23) is bonded to one Li(3), one Li(6), one Li(9), one Mn(1), one Mn(2), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, and edges with two equivalent O(20)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-fourth O site, O(24) is bonded to one Li(10), one Li(4), one Li(5), one Mn(3), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°.
Li6Mn5SbO12 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(17), one O(21), one O(3), and one O(5) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. The Li(1)-O(17) bond length is 2.17 Å. The Li(1)-O(21) bond length is 2.15 Å. The Li(1)-O(3) bond length is 2.08 Å. The Li(1)-O(5) bond length is 1.93 Å. In the second Li site, Li(2) is bonded to one O(18), one O(22), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. The Li(2)-O(18) bond length is 2.16 Å. The Li(2)-O(22) bond length is 2.17 Å. The Li(2)-O(4) bond length is 2.08 Å. The Li(2)-O(6) bond length is 1.93 Å. In the third Li site, Li(3) is bonded to one O(1), one O(19), one O(23), and one O(7) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. The Li(3)-O(1) bond length is 2.08 Å. The Li(3)-O(19) bond length is 2.14 Å. The Li(3)-O(23) bond length is 2.19 Å. The Li(3)-O(7) bond length is 1.93 Å. In the fourth Li site, Li(4) is bonded to one O(2), one O(20), one O(24), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(10)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Sb(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-67°. The Li(4)-O(2) bond length is 2.08 Å. The Li(4)-O(20) bond length is 2.18 Å. The Li(4)-O(24) bond length is 2.14 Å. The Li(4)-O(8) bond length is 1.93 Å. In the fifth Li site, Li(5) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(15), one O(19), and one O(24) atom. The Li(5)-O(1) bond length is 2.16 Å. The Li(5)-O(15) bond length is 1.90 Å. The Li(5)-O(19) bond length is 2.06 Å. The Li(5)-O(24) bond length is 1.97 Å. In the sixth Li site, Li(6) is bonded in a distorted rectangular see-saw-like geometry to one O(16), one O(2), one O(20), and one O(23) atom. The Li(6)-O(16) bond length is 1.87 Å. The Li(6)-O(2) bond length is 2.16 Å. The Li(6)-O(20) bond length is 2.05 Å. The Li(6)-O(23) bond length is 1.98 Å. In the seventh Li site, Li(7) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(17), one O(22), and one O(3) atom. The Li(7)-O(13) bond length is 1.87 Å. The Li(7)-O(17) bond length is 2.06 Å. The Li(7)-O(22) bond length is 1.98 Å. The Li(7)-O(3) bond length is 2.13 Å. In the eighth Li site, Li(8) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(18), one O(21), and one O(4) atom. The Li(8)-O(14) bond length is 1.90 Å. The Li(8)-O(18) bond length is 2.05 Å. The Li(8)-O(21) bond length is 1.96 Å. The Li(8)-O(4) bond length is 2.18 Å. In the ninth Li site, Li(9) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(11), one O(20), and one O(23) atom. The Li(9)-O(1) bond length is 2.16 Å. The Li(9)-O(11) bond length is 1.87 Å. The Li(9)-O(20) bond length is 1.98 Å. The Li(9)-O(23) bond length is 2.05 Å. In the tenth Li site, Li(10) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(19), one O(2), and one O(24) atom. The Li(10)-O(12) bond length is 1.90 Å. The Li(10)-O(19) bond length is 1.97 Å. The Li(10)-O(2) bond length is 2.15 Å. The Li(10)-O(24) bond length is 2.06 Å. In the eleventh Li site, Li(11) is bonded in a distorted rectangular see-saw-like geometry to one O(18), one O(21), one O(3), and one O(9) atom. The Li(11)-O(18) bond length is 1.96 Å. The Li(11)-O(21) bond length is 2.05 Å. The Li(11)-O(3) bond length is 2.18 Å. The Li(11)-O(9) bond length is 1.90 Å. In the twelfth Li site, Li(12) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(17), one O(22), and one O(4) atom. The Li(12)-O(10) bond length is 1.87 Å. The Li(12)-O(17) bond length is 1.99 Å. The Li(12)-O(22) bond length is 2.06 Å. The Li(12)-O(4) bond length is 2.13 Å. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(17), one O(19), one O(21), one O(23), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The Mn(1)-O(1) bond length is 2.36 Å. The Mn(1)-O(17) bond length is 2.16 Å. The Mn(1)-O(19) bond length is 2.16 Å. The Mn(1)-O(21) bond length is 2.16 Å. The Mn(1)-O(23) bond length is 2.17 Å. The Mn(1)-O(3) bond length is 2.36 Å. In the second Mn site, Mn(2) is bonded to one O(18), one O(2), one O(20), one O(21), one O(23), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(2)O4 tetrahedra, and  an edgeedge with one Li(4)O4 tetrahedra. The Mn(2)-O(18) bond length is 2.37 Å. The Mn(2)-O(2) bond length is 2.02 Å. The Mn(2)-O(20) bond length is 2.35 Å. The Mn(2)-O(21) bond length is 1.99 Å. The Mn(2)-O(23) bond length is 1.99 Å. The Mn(2)-O(4) bond length is 2.01 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(17), one O(19), one O(22), one O(24), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The Mn(3)-O(1) bond length is 2.01 Å. The Mn(3)-O(17) bond length is 2.35 Å. The Mn(3)-O(19) bond length is 2.37 Å. The Mn(3)-O(22) bond length is 1.98 Å. The Mn(3)-O(24) bond length is 1.98 Å. The Mn(3)-O(3) bond length is 2.01 Å. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(11), one O(13), one O(16), one O(5), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(9)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The Mn(4)-O(10) bond length is 2.18 Å. The Mn(4)-O(11) bond length is 2.18 Å. The Mn(4)-O(13) bond length is 2.24 Å. The Mn(4)-O(16) bond length is 2.24 Å. The Mn(4)-O(5) bond length is 2.20 Å. The Mn(4)-O(8) bond length is 2.20 Å. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(14), one O(15), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(9)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The Mn(5)-O(12) bond length is 1.97 Å. The Mn(5)-O(14) bond length is 2.27 Å. The Mn(5)-O(15) bond length is 2.27 Å. The Mn(5)-O(6) bond length is 1.98 Å. The Mn(5)-O(7) bond length is 1.98 Å. The Mn(5)-O(9) bond length is 1.97 Å. In the sixth Mn site, Mn(6) is bonded to one O(18), one O(2), one O(20), one O(22), one O(24), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(2)O4 tetrahedra, and  an edgeedge with one Li(4)O4 tetrahedra. The Mn(6)-O(18) bond length is 2.16 Å. The Mn(6)-O(2) bond length is 2.36 Å. The Mn(6)-O(20) bond length is 2.17 Å. The Mn(6)-O(22) bond length is 2.16 Å. The Mn(6)-O(24) bond length is 2.16 Å. The Mn(6)-O(4) bond length is 2.36 Å. In the seventh Mn site, Mn(7) is bonded to one O(17), one O(19), one O(2), one O(22), one O(24), and one O(4) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(2)O4 tetrahedra, and  an edgeedge with one Li(4)O4 tetrahedra. The Mn(7)-O(17) bond length is 1.98 Å. The Mn(7)-O(19) bond length is 1.99 Å. The Mn(7)-O(2) bond length is 2.01 Å. The Mn(7)-O(22) bond length is 2.35 Å. The Mn(7)-O(24) bond length is 2.37 Å. The Mn(7)-O(4) bond length is 2.01 Å. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(18), one O(20), one O(21), one O(23), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The Mn(8)-O(1) bond length is 2.02 Å. The Mn(8)-O(18) bond length is 1.99 Å. The Mn(8)-O(20) bond length is 1.99 Å. The Mn(8)-O(21) bond length is 2.37 Å. The Mn(8)-O(23) bond length is 2.35 Å. The Mn(8)-O(3) bond length is 2.02 Å. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(11), one O(13), one O(16), one O(6), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The Mn(9)-O(10) bond length is 2.24 Å. The Mn(9)-O(11) bond length is 2.24 Å. The Mn(9)-O(13) bond length is 2.18 Å. The Mn(9)-O(16) bond length is 2.18 Å. The Mn(9)-O(6) bond length is 2.20 Å. The Mn(9)-O(7) bond length is 2.20 Å. In the tenth Mn site, Mn(10) is bonded to one O(12), one O(14), one O(15), one O(5), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The Mn(10)-O(12) bond length is 2.27 Å. The Mn(10)-O(14) bond length is 1.97 Å. The Mn(10)-O(15) bond length is 1.97 Å. The Mn(10)-O(5) bond length is 1.98 Å. The Mn(10)-O(8) bond length is 1.98 Å. The Mn(10)-O(9) bond length is 2.26 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(10), one O(11), one O(14), one O(15), one O(6), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(9)O6 octahedra. The Sb(1)-O(10) bond length is 1.97 Å. The Sb(1)-O(11) bond length is 1.97 Å. The Sb(1)-O(14) bond length is 2.02 Å. The Sb(1)-O(15) bond length is 2.02 Å. The Sb(1)-O(6) bond length is 2.06 Å. The Sb(1)-O(7) bond length is 2.06 Å. In the second Sb site, Sb(2) is bonded to one O(12), one O(13), one O(16), one O(5), one O(8), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(10)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The Sb(2)-O(12) bond length is 2.02 Å. The Sb(2)-O(13) bond length is 1.97 Å. The Sb(2)-O(16) bond length is 1.97 Å. The Sb(2)-O(5) bond length is 2.06 Å. The Sb(2)-O(8) bond length is 2.06 Å. The Sb(2)-O(9) bond length is 2.02 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, and edges with two equivalent O(23)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second O site, O(2) is bonded to one Li(10), one Li(4), one Li(6), one Mn(2), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(20)Li3Mn3 octahedra, and edges with two equivalent O(24)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the third O site, O(3) is bonded to one Li(1), one Li(11), one Li(7), one Mn(1), one Mn(3), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra, edges with two equivalent O(17)Li3Mn3 octahedra, and edges with two equivalent O(21)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fourth O site, O(4) is bonded to one Li(12), one Li(2), one Li(8), one Mn(2), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra, edges with two equivalent O(18)Li3Mn3 octahedra, and edges with two equivalent O(22)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(5) is bonded to one Li(1), one Mn(10), one Mn(4), and one Sb(2) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(8)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 56-62°. In the sixth O site, O(6) is bonded to one Li(2), one Mn(5), one Mn(9), and one Sb(1) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(7)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 56-63°. In the seventh O site, O(7) is bonded to one Li(3), one Mn(5), one Mn(9), and one Sb(1) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(6)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 57-62°. In the eighth O site, O(8) is bonded to one Li(4), one Mn(10), one Mn(4), and one Sb(2) atom to form distorted OLiMn2Sb trigonal pyramids that share  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid, and  an edgeedge with one O(5)LiMn2Sb trigonal pyramid. The corner-sharing octahedral tilt angles range from 56-62°. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(11), one Mn(10), one Mn(5), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(12), one Mn(4), one Mn(9), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(9), one Mn(4), one Mn(9), and one Sb(1) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(10), one Mn(10), one Mn(5), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(7), one Mn(4), one Mn(9), and one Sb(2) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(8), one Mn(10), one Mn(5), and one Sb(1) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(10), one Mn(5), and one Sb(1) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(6), one Mn(4), one Mn(9), and one Sb(2) atom. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(12), one Li(7), one Mn(1), one Mn(3), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(22)Li3Mn3 octahedra, and edges with two equivalent O(3)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the eighteenth O site, O(18) is bonded to one Li(11), one Li(2), one Li(8), one Mn(2), one Mn(6), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(21)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(3), one Li(5), one Mn(1), one Mn(3), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, and edges with two equivalent O(24)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the twentieth O site, O(20) is bonded to one Li(4), one Li(6), one Li(9), one Mn(2), one Mn(6), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(2)Li3Mn3 octahedra, and edges with two equivalent O(23)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(11), one Li(8), one Mn(1), one Mn(2), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(19)Li3Mn3 octahedra,  a cornercorner with one O(2)Li3Mn3 octahedra,  a cornercorner with one O(23)Li3Mn3 octahedra,  a cornercorner with one O(5)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(23)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(18)Li3Mn3 octahedra, and edges with two equivalent O(3)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-second O site, O(22) is bonded to one Li(12), one Li(2), one Li(7), one Mn(3), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(1)Li3Mn3 octahedra,  a cornercorner with one O(20)Li3Mn3 octahedra,  a cornercorner with one O(24)Li3Mn3 octahedra,  a cornercorner with one O(6)LiMn2Sb trigonal pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(24)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(17)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the twenty-third O site, O(23) is bonded to one Li(3), one Li(6), one Li(9), one Mn(1), one Mn(2), and one Mn(8) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(17)Li3Mn3 octahedra,  a cornercorner with one O(21)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)LiMn2Sb trigonal pyramid,  an edgeedge with one O(18)Li3Mn3 octahedra,  an edgeedge with one O(19)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(21)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, and edges with two equivalent O(20)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-fourth O site, O(24) is bonded to one Li(10), one Li(4), one Li(5), one Mn(3), one Mn(6), and one Mn(7) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(18)Li3Mn3 octahedra,  a cornercorner with one O(22)Li3Mn3 octahedra,  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(8)LiMn2Sb trigonal pyramid,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(17)Li3Mn3 octahedra,  an edgeedge with one O(20)Li3Mn3 octahedra,  an edgeedge with one O(22)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(19)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°.