CoH15(N3O)2(Br)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrogen bromide atoms and two CoH15(N3O)2 clusters. In each CoH15(N3O)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1,2) atoms. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(1), one H(5), and one H(9) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(10), one H(2), and one H(6) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(11), one H(3), and one H(7) atom. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(12), one H(4), and one H(8) atom. In the sixth N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(13), one H(14), and one H(15) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(5) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(6) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(6) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one N(6) atom. O(1,2) is bonded in a single-bond geometry to one N(1) atom.
CoH15(N3O)2(Br)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrogen bromide atoms and two CoH15(N3O)2 clusters. In each CoH15(N3O)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. The Co(1)-N(1) bond length is 1.90 Å. The Co(1)-N(2) bond length is 1.96 Å. The Co(1)-N(3) bond length is 1.96 Å. The Co(1)-N(4) bond length is 1.96 Å. The Co(1)-N(5) bond length is 1.96 Å. The Co(1)-N(6) bond length is 1.99 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1,2) atoms. Both N(1)-O(1,2) bond lengths are 1.24 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(1), one H(5), and one H(9) atom. The N(2)-H(1) bond length is 1.02 Å. The N(2)-H(5) bond length is 1.02 Å. The N(2)-H(9) bond length is 1.02 Å. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(10), one H(2), and one H(6) atom. The N(3)-H(10) bond length is 1.02 Å. The N(3)-H(2) bond length is 1.03 Å. The N(3)-H(6) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(11), one H(3), and one H(7) atom. The N(4)-H(11) bond length is 1.02 Å. The N(4)-H(3) bond length is 1.03 Å. The N(4)-H(7) bond length is 1.02 Å. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(12), one H(4), and one H(8) atom. The N(5)-H(12) bond length is 1.02 Å. The N(5)-H(4) bond length is 1.03 Å. The N(5)-H(8) bond length is 1.02 Å. In the sixth N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one H(13), one H(14), and one H(15) atom. The N(6)-H(13) bond length is 1.02 Å. The N(6)-H(14) bond length is 1.03 Å. The N(6)-H(15) bond length is 1.02 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(5) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(6) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(6) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one N(6) atom. O(1,2) is bonded in a single-bond geometry to one N(1) atom.