LiBiF2 crystallizes in the tetragonal I4_1/a space group. Li(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. Bi(1) is bonded in a linear geometry to two equivalent F(1) atoms. F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Bi(1) atom.
LiBiF2 crystallizes in the tetragonal I4_1/a space group. Li(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. There are two shorter (1.92 Å) and two longer (1.96 Å) Li(1)-F(1) bond lengths. Bi(1) is bonded in a linear geometry to two equivalent F(1) atoms. Both Bi(1)-F(1) bond lengths are 2.32 Å. F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Bi(1) atom.