(K)2TlInI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlInI6 framework. In the TlInI6 framework, Tl(1) is bonded to six equivalent I(1) atoms to form TlI6 octahedra that share corners with six equivalent In(1)I6 octahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to six equivalent I(1) atoms to form InI6 octahedra that share corners with six equivalent Tl(1)I6 octahedra. The corner-sharing octahedra are not tilted. I(1) is bonded in a linear geometry to one Tl(1) and one In(1) atom.
(K)2TlInI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlInI6 framework. In the TlInI6 framework, Tl(1) is bonded to six equivalent I(1) atoms to form TlI6 octahedra that share corners with six equivalent In(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-I(1) bond lengths are 3.31 Å. In(1) is bonded to six equivalent I(1) atoms to form InI6 octahedra that share corners with six equivalent Tl(1)I6 octahedra. The corner-sharing octahedra are not tilted. All In(1)-I(1) bond lengths are 2.95 Å. I(1) is bonded in a linear geometry to one Tl(1) and one In(1) atom.