(K)2RbTlBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a RbTlBr6 framework. In the RbTlBr6 framework, Rb(1) is bonded to six equivalent Br(1) atoms to form RbBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Rb(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Rb(1) and one Tl(1) atom.
(K)2RbTlBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a RbTlBr6 framework. In the RbTlBr6 framework, Rb(1) is bonded to six equivalent Br(1) atoms to form RbBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Rb(1)-Br(1) bond lengths are 3.23 Å. Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Rb(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 2.77 Å. Br(1) is bonded in a linear geometry to one Rb(1) and one Tl(1) atom.