Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(6), one O(7), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(6)O2F4 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the second Mn site, Mn(2) is bonded to one O(3), one O(4), one O(5), one F(1), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. In the third Mn site, Mn(3) is bonded to one O(1), one O(4), one O(5), one O(6), one F(2), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(4)O4F2 octahedra, corners with four equivalent Mn(5)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-55°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(3), one O(5), one O(7), one F(1), and one F(4) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(3)O4F2 octahedra, corners with four equivalent Mn(2)O3F3 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(4), one O(6), one F(4), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, corners with four equivalent Mn(3)O4F2 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(7), one F(1), one F(2), one F(3), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(3)O4F2 octahedra, corners with four equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(4)O4F2 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-59°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one Mn(3), one Mn(5), and one Mn(6) atom.
Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(6), one O(7), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(4)O4F2 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(6)O2F4 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. The Mn(1)-O(2) bond length is 2.11 Å. The Mn(1)-O(3) bond length is 2.00 Å. The Mn(1)-O(6) bond length is 2.01 Å. The Mn(1)-O(7) bond length is 2.03 Å. The Mn(1)-F(2) bond length is 2.13 Å. The Mn(1)-F(3) bond length is 2.12 Å. In the second Mn site, Mn(2) is bonded to one O(3), one O(4), one O(5), one F(1), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. The Mn(2)-O(3) bond length is 1.95 Å. The Mn(2)-O(4) bond length is 1.93 Å. The Mn(2)-O(5) bond length is 1.97 Å. The Mn(2)-F(1) bond length is 2.07 Å. The Mn(2)-F(3) bond length is 2.01 Å. The Mn(2)-F(4) bond length is 2.06 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(4), one O(5), one O(6), one F(2), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(4)O4F2 octahedra, corners with four equivalent Mn(5)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-55°. The Mn(3)-O(1) bond length is 1.88 Å. The Mn(3)-O(4) bond length is 1.96 Å. The Mn(3)-O(5) bond length is 1.87 Å. The Mn(3)-O(6) bond length is 1.99 Å. The Mn(3)-F(2) bond length is 2.00 Å. The Mn(3)-F(5) bond length is 2.06 Å. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(3), one O(5), one O(7), one F(1), and one F(4) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(3)O4F2 octahedra, corners with four equivalent Mn(2)O3F3 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. The Mn(4)-O(1) bond length is 1.98 Å. The Mn(4)-O(3) bond length is 1.99 Å. The Mn(4)-O(5) bond length is 2.05 Å. The Mn(4)-O(7) bond length is 2.00 Å. The Mn(4)-F(1) bond length is 2.09 Å. The Mn(4)-F(4) bond length is 2.10 Å. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(4), one O(6), one F(4), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, corners with four equivalent Mn(3)O4F2 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. The Mn(5)-O(1) bond length is 2.02 Å. The Mn(5)-O(2) bond length is 1.91 Å. The Mn(5)-O(4) bond length is 1.99 Å. The Mn(5)-O(6) bond length is 1.99 Å. The Mn(5)-F(4) bond length is 2.03 Å. The Mn(5)-F(5) bond length is 2.21 Å. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(7), one F(1), one F(2), one F(3), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(3)O4F2 octahedra, corners with four equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(4)O4F2 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 41-59°. The Mn(6)-O(2) bond length is 1.97 Å. The Mn(6)-O(7) bond length is 1.95 Å. The Mn(6)-F(1) bond length is 2.01 Å. The Mn(6)-F(2) bond length is 2.01 Å. The Mn(6)-F(3) bond length is 2.00 Å. The Mn(6)-F(5) bond length is 2.04 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one Mn(3), one Mn(5), and one Mn(6) atom.