Cs2AuInF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Au(1)F6 octahedra, and faces with four equivalent In(1)F6 octahedra. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent In(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Au(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Au(1), and one In(1) atom.
Cs2AuInF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Au(1)F6 octahedra, and faces with four equivalent In(1)F6 octahedra. All Cs(1)-F(1) bond lengths are 3.23 Å. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent In(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Au(1)-F(1) bond lengths are 2.47 Å. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Au(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-F(1) bond lengths are 2.09 Å. F(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Au(1), and one In(1) atom.