CrOF is Rutile-derived structured and crystallizes in the orthorhombic Pnma space group. Cr(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing CrO3F3 octahedra. The corner-sharing octahedral tilt angles are 49°. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Cr(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Cr(1) atoms.
CrOF is Rutile-derived structured and crystallizes in the orthorhombic Pnma space group. Cr(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing CrO3F3 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two shorter (1.94 Å) and one longer (1.95 Å) Cr(1)-O(1) bond length. There is one shorter (2.09 Å) and two longer (2.10 Å) Cr(1)-F(1) bond lengths. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Cr(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Cr(1) atoms.