Mn2Ru(CN)6 crystallizes in the trigonal P-31m space group. Mn(1) is bonded to six equivalent N(1) atoms to form edge-sharing MnN6 octahedra. Ru(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Ru(1) and one N(1) atom. N(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one C(1) atom.
Mn2Ru(CN)6 crystallizes in the trigonal P-31m space group. Mn(1) is bonded to six equivalent N(1) atoms to form edge-sharing MnN6 octahedra. All Mn(1)-N(1) bond lengths are 2.25 Å. Ru(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. All Ru(1)-C(1) bond lengths are 2.01 Å. C(1) is bonded in a linear geometry to one Ru(1) and one N(1) atom. The C(1)-N(1) bond length is 1.19 Å. N(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one C(1) atom.