Rb2AuInF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with twelve equivalent Rb(1)F12 cuboctahedra, faces with six equivalent Rb(1)F12 cuboctahedra, faces with four equivalent Au(1)F6 octahedra, and faces with four equivalent In(1)F6 octahedra. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent In(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Au(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded to four equivalent Rb(1), one Au(1), and one In(1) atom to form a mixture of distorted edge, face, and corner-sharing FRb4InAu octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
Rb2AuInF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form RbF12 cuboctahedra that share corners with twelve equivalent Rb(1)F12 cuboctahedra, faces with six equivalent Rb(1)F12 cuboctahedra, faces with four equivalent Au(1)F6 octahedra, and faces with four equivalent In(1)F6 octahedra. All Rb(1)-F(1) bond lengths are 3.25 Å. Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent In(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Au(1)-F(1) bond lengths are 2.48 Å. In(1) is bonded to six equivalent F(1) atoms to form InF6 octahedra that share corners with six equivalent Au(1)F6 octahedra and faces with eight equivalent Rb(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-F(1) bond lengths are 2.11 Å. F(1) is bonded to four equivalent Rb(1), one Au(1), and one In(1) atom to form a mixture of distorted edge, face, and corner-sharing FRb4InAu octahedra. The corner-sharing octahedral tilt angles range from 0-60°.