Zr2Co2In crystallizes in the tetragonal P4/mbm space group. Zr(1) is bonded in a 10-coordinate geometry to six equivalent Co(1) and four equivalent In(1) atoms. Co(1) is bonded in a 9-coordinate geometry to six equivalent Zr(1), one Co(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Zr(1) and four equivalent Co(1) atoms to form a mixture of distorted face and corner-sharing InZr8Co4 cuboctahedra.
Zr2Co2In crystallizes in the tetragonal P4/mbm space group. Zr(1) is bonded in a 10-coordinate geometry to six equivalent Co(1) and four equivalent In(1) atoms. There are four shorter (2.71 Å) and two longer (2.72 Å) Zr(1)-Co(1) bond lengths. All Zr(1)-In(1) bond lengths are 3.15 Å. Co(1) is bonded in a 9-coordinate geometry to six equivalent Zr(1), one Co(1), and two equivalent In(1) atoms. The Co(1)-Co(1) bond length is 2.39 Å. Both Co(1)-In(1) bond lengths are 2.88 Å. In(1) is bonded to eight equivalent Zr(1) and four equivalent Co(1) atoms to form a mixture of distorted face and corner-sharing InZr8Co4 cuboctahedra.