AgPbC2N2HSO crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded to one C(1) and three equivalent S(1) atoms to form distorted corner-sharing AgCS3 tetrahedra. Pb(1) is bonded in a 4-coordinate geometry to one N(2) and three equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Ag(1) and one N(2) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pb(1) and one C(1) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. S(1) is bonded to three equivalent Ag(1) and one C(2) atom to form corner-sharing SAg3C tetrahedra. O(1) is bonded in a single-bond geometry to three equivalent Pb(1) and one H(1) atom.
AgPbC2N2HSO crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded to one C(1) and three equivalent S(1) atoms to form distorted corner-sharing AgCS3 tetrahedra. The Ag(1)-C(1) bond length is 2.11 Å. There are two shorter (2.62 Å) and one longer (2.86 Å) Ag(1)-S(1) bond length. Pb(1) is bonded in a 4-coordinate geometry to one N(2) and three equivalent O(1) atoms. The Pb(1)-N(2) bond length is 2.65 Å. There is one shorter (2.44 Å) and two longer (2.45 Å) Pb(1)-O(1) bond lengths. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Ag(1) and one N(2) atom. The C(1)-N(2) bond length is 1.18 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(2)-N(1) bond length is 1.18 Å. The C(2)-S(1) bond length is 1.65 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pb(1) and one C(1) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. S(1) is bonded to three equivalent Ag(1) and one C(2) atom to form corner-sharing SAg3C tetrahedra. O(1) is bonded in a single-bond geometry to three equivalent Pb(1) and one H(1) atom.