KHf2O6Bi crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-69-9 atoms inside a KHf2O6 framework. In the KHf2O6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra and faces with eight equivalent Hf(1)O6 octahedra. Hf(1) is bonded to six equivalent O(1) atoms to form HfO6 octahedra that share corners with six equivalent Hf(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent K(1) and two equivalent Hf(1) atoms.
KHf2O6Bi crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-69-9 atoms inside a KHf2O6 framework. In the KHf2O6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra and faces with eight equivalent Hf(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.92 Å. Hf(1) is bonded to six equivalent O(1) atoms to form HfO6 octahedra that share corners with six equivalent Hf(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Hf(1)-O(1) bond lengths are 2.07 Å. O(1) is bonded in a distorted linear geometry to two equivalent K(1) and two equivalent Hf(1) atoms.