ZrOS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 9-coordinate geometry to five equivalent S(1) and four equivalent O(1) atoms. S(1) is bonded in a 5-coordinate geometry to five equivalent Zr(1) atoms. O(1) is bonded to four equivalent Zr(1) atoms to form a mixture of corner and edge-sharing OZr4 tetrahedra.
ZrOS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 9-coordinate geometry to five equivalent S(1) and four equivalent O(1) atoms. There is one shorter (2.75 Å) and four longer (2.78 Å) Zr(1)-S(1) bond lengths. All Zr(1)-O(1) bond lengths are 2.19 Å. S(1) is bonded in a 5-coordinate geometry to five equivalent Zr(1) atoms. O(1) is bonded to four equivalent Zr(1) atoms to form a mixture of corner and edge-sharing OZr4 tetrahedra.