LiCa4(BN2)3 crystallizes in the cubic Im-3m space group. Li(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. Ca(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. B(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to one Li(1), four equivalent Ca(1), and one B(1) atom.
LiCa4(BN2)3 crystallizes in the cubic Im-3m space group. Li(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Li(1)-N(1) bond lengths are 2.23 Å. Ca(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. All Ca(1)-N(1) bond lengths are 2.56 Å. B(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both B(1)-N(1) bond lengths are 1.34 Å. N(1) is bonded in a 6-coordinate geometry to one Li(1), four equivalent Ca(1), and one B(1) atom.