Li7VO5F is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(8), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(4), and one F(2) atom to form distorted LiO3F tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(7)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the third Li site, Li(3) is bonded to one O(2), one O(3), one O(6), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the fifth Li site, Li(5) is bonded to one O(1), one O(4), one O(5), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the sixth Li site, Li(6) is bonded to one O(1), one O(4), one O(9), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the seventh Li site, Li(7) is bonded to one O(1), one O(4), one O(6), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with three equivalent Li(2)O3F tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the eighth Li site, Li(8) is bonded to one O(10), one O(2), one O(7), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. In the ninth Li site, Li(9) is bonded to one O(10), one O(6), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. In the tenth Li site, Li(10) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the eleventh Li site, Li(11) is bonded to one O(5), one O(8), one O(9), and one F(2) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the twelfth Li site, Li(12) is bonded to one O(10), one O(7), one O(9), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(13)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the thirteenth Li site, Li(13) is bonded to one O(10), one O(7), one O(8), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(12)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the fourteenth Li site, Li(14) is bonded to one O(10), one O(3), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(12)O3F trigonal pyramid, and  an edgeedge with one Li(13)O3F trigonal pyramid. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra, and  an edgeedge with one Li(7)O3F trigonal pyramid. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(5), one Li(6), one Li(7), and one V(2) atom. In the second O site, O(2) is bonded to one Li(10), one Li(2), one Li(3), one Li(8), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(6)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the third O site, O(3) is bonded to one Li(10), one Li(14), one Li(3), and one V(2) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(4), one Li(5), one Li(6), and one Li(7) atom. In the fifth O site, O(5) is bonded to one Li(11), one Li(4), one Li(5), and one V(1) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(10), one Li(3), one Li(7), one Li(9), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(2)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(13), one Li(14), one Li(8), and one Li(9) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(11), one Li(13), one Li(4), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(9)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(11), one Li(12), one Li(4), one Li(6), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(8)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(8), one Li(9), and one V(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(3), one Li(8), and one Li(9) atom. In the second F site, F(2) is bonded in a 6-coordinate geometry to one Li(1), one Li(11), one Li(2), one Li(5), one Li(6), and one Li(7) atom.
Li7VO5F is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(8), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. The Li(1)-O(1) bond length is 2.06 Å. The Li(1)-O(4) bond length is 1.92 Å. The Li(1)-O(8) bond length is 2.07 Å. The Li(1)-F(2) bond length is 2.03 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(4), and one F(2) atom to form distorted LiO3F tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(7)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. The Li(2)-O(1) bond length is 2.12 Å. The Li(2)-O(2) bond length is 1.97 Å. The Li(2)-O(4) bond length is 1.91 Å. The Li(2)-F(2) bond length is 2.01 Å. In the third Li site, Li(3) is bonded to one O(2), one O(3), one O(6), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. The Li(3)-O(2) bond length is 1.91 Å. The Li(3)-O(3) bond length is 1.90 Å. The Li(3)-O(6) bond length is 1.98 Å. The Li(3)-F(1) bond length is 2.27 Å. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. The Li(4)-O(4) bond length is 2.02 Å. The Li(4)-O(5) bond length is 1.96 Å. The Li(4)-O(8) bond length is 2.04 Å. The Li(4)-O(9) bond length is 1.96 Å. In the fifth Li site, Li(5) is bonded to one O(1), one O(4), one O(5), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. The Li(5)-O(1) bond length is 1.97 Å. The Li(5)-O(4) bond length is 1.92 Å. The Li(5)-O(5) bond length is 1.96 Å. The Li(5)-F(2) bond length is 2.12 Å. In the sixth Li site, Li(6) is bonded to one O(1), one O(4), one O(9), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. The Li(6)-O(1) bond length is 2.03 Å. The Li(6)-O(4) bond length is 1.92 Å. The Li(6)-O(9) bond length is 1.97 Å. The Li(6)-F(2) bond length is 2.11 Å. In the seventh Li site, Li(7) is bonded to one O(1), one O(4), one O(6), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with three equivalent Li(2)O3F tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. The Li(7)-O(1) bond length is 2.11 Å. The Li(7)-O(4) bond length is 1.90 Å. The Li(7)-O(6) bond length is 1.99 Å. The Li(7)-F(2) bond length is 2.01 Å. In the eighth Li site, Li(8) is bonded to one O(10), one O(2), one O(7), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. The Li(8)-O(10) bond length is 2.04 Å. The Li(8)-O(2) bond length is 2.02 Å. The Li(8)-O(7) bond length is 1.93 Å. The Li(8)-F(1) bond length is 2.09 Å. In the ninth Li site, Li(9) is bonded to one O(10), one O(6), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. The Li(9)-O(10) bond length is 2.06 Å. The Li(9)-O(6) bond length is 2.05 Å. The Li(9)-O(7) bond length is 1.91 Å. The Li(9)-F(1) bond length is 2.05 Å. In the tenth Li site, Li(10) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. The Li(10)-O(2) bond length is 2.02 Å. The Li(10)-O(3) bond length is 1.96 Å. The Li(10)-O(6) bond length is 2.00 Å. The Li(10)-O(7) bond length is 2.02 Å. In the eleventh Li site, Li(11) is bonded to one O(5), one O(8), one O(9), and one F(2) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. The Li(11)-O(5) bond length is 1.91 Å. The Li(11)-O(8) bond length is 1.94 Å. The Li(11)-O(9) bond length is 1.97 Å. The Li(11)-F(2) bond length is 2.27 Å. In the twelfth Li site, Li(12) is bonded to one O(10), one O(7), one O(9), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(13)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. The Li(12)-O(10) bond length is 2.15 Å. The Li(12)-O(7) bond length is 1.90 Å. The Li(12)-O(9) bond length is 1.95 Å. The Li(12)-F(1) bond length is 2.00 Å. In the thirteenth Li site, Li(13) is bonded to one O(10), one O(7), one O(8), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(12)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. The Li(13)-O(10) bond length is 2.09 Å. The Li(13)-O(7) bond length is 1.91 Å. The Li(13)-O(8) bond length is 1.99 Å. The Li(13)-F(1) bond length is 2.03 Å. In the fourteenth Li site, Li(14) is bonded to one O(10), one O(3), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. The Li(14)-O(10) bond length is 1.98 Å. The Li(14)-O(3) bond length is 1.94 Å. The Li(14)-O(7) bond length is 1.92 Å. The Li(14)-F(1) bond length is 2.08 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(12)O3F trigonal pyramid, and  an edgeedge with one Li(13)O3F trigonal pyramid. The V(1)-O(10) bond length is 1.89 Å. The V(1)-O(5) bond length is 1.78 Å. The V(1)-O(8) bond length is 1.81 Å. The V(1)-O(9) bond length is 1.87 Å. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra, and  an edgeedge with one Li(7)O3F trigonal pyramid. The V(2)-O(1) bond length is 1.89 Å. The V(2)-O(2) bond length is 1.87 Å. The V(2)-O(3) bond length is 1.78 Å. The V(2)-O(6) bond length is 1.81 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(5), one Li(6), one Li(7), and one V(2) atom. In the second O site, O(2) is bonded to one Li(10), one Li(2), one Li(3), one Li(8), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(6)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the third O site, O(3) is bonded to one Li(10), one Li(14), one Li(3), and one V(2) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(4), one Li(5), one Li(6), and one Li(7) atom. In the fifth O site, O(5) is bonded to one Li(11), one Li(4), one Li(5), and one V(1) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(10), one Li(3), one Li(7), one Li(9), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(2)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(13), one Li(14), one Li(8), and one Li(9) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(11), one Li(13), one Li(4), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(9)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(11), one Li(12), one Li(4), one Li(6), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(8)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(8), one Li(9), and one V(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(3), one Li(8), and one Li(9) atom. In the second F site, F(2) is bonded in a 6-coordinate geometry to one Li(1), one Li(11), one Li(2), one Li(5), one Li(6), and one Li(7) atom.