TbVO2 crystallizes in the tetragonal I4_1/amd space group. Tb(1) is bonded to six equivalent O(1) atoms to form edge-sharing TbO6 octahedra. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Tb(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OTb3V2 trigonal bipyramids.
TbVO2 crystallizes in the tetragonal I4_1/amd space group. Tb(1) is bonded to six equivalent O(1) atoms to form edge-sharing TbO6 octahedra. There are four shorter (2.34 Å) and two longer (2.36 Å) Tb(1)-O(1) bond lengths. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All V(1)-O(1) bond lengths are 2.20 Å. O(1) is bonded to three equivalent Tb(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OTb3V2 trigonal bipyramids.