ReTeSCl4 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two ReTeSCl4 clusters. Re(1) is bonded in a 5-coordinate geometry to one Te(1), three equivalent S(1), one Cl(2), and one Cl(3) atom. Te(1) is bonded in a 5-coordinate geometry to one Re(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Te(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom.
ReTeSCl4 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two ReTeSCl4 clusters. Re(1) is bonded in a 5-coordinate geometry to one Te(1), three equivalent S(1), one Cl(2), and one Cl(3) atom. The Re(1)-Te(1) bond length is 2.78 Å. There are a spread of Re(1)-S(1) bond distances ranging from 2.33-2.35 Å. The Re(1)-Cl(2) bond length is 2.47 Å. The Re(1)-Cl(3) bond length is 2.46 Å. Te(1) is bonded in a 5-coordinate geometry to one Re(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Te(1)-Cl(1) bond length is 2.39 Å. The Te(1)-Cl(2) bond length is 2.82 Å. The Te(1)-Cl(3) bond length is 2.88 Å. The Te(1)-Cl(4) bond length is 2.38 Å. S(1) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Te(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom.