NaH6TeO6F crystallizes in the trigonal R3 space group. Na(1) is bonded in a 7-coordinate geometry to three equivalent O(1), three equivalent O(2), and one F(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a linear geometry to one O(2) and one F(1) atom. Te(1) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Na(1), one H(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Na(1), one H(2), and one Te(1) atom. F(1) is bonded in a distorted tetrahedral geometry to one Na(1) and three equivalent H(2) atoms.
NaH6TeO6F crystallizes in the trigonal R3 space group. Na(1) is bonded in a 7-coordinate geometry to three equivalent O(1), three equivalent O(2), and one F(1) atom. All Na(1)-O(1) bond lengths are 2.39 Å. All Na(1)-O(2) bond lengths are 2.66 Å. The Na(1)-F(1) bond length is 2.42 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. In the second H site, H(2) is bonded in a linear geometry to one O(2) and one F(1) atom. The H(2)-O(2) bond length is 1.03 Å. The H(2)-F(1) bond length is 1.51 Å. Te(1) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(2) atoms. All Te(1)-O(1) bond lengths are 1.95 Å. All Te(1)-O(2) bond lengths are 1.96 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Na(1), one H(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Na(1), one H(2), and one Te(1) atom. F(1) is bonded in a distorted tetrahedral geometry to one Na(1) and three equivalent H(2) atoms.