LiZnPS4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent S(1) atoms to form LiS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. Zn(1) is bonded to four equivalent S(1) atoms to form ZnS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. P(1) is bonded to four equivalent S(1) atoms to form PS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and corners with four equivalent Zn(1)S4 tetrahedra. S(1) is bonded in a trigonal non-coplanar geometry to one Li(1), one Zn(1), and one P(1) atom.
LiZnPS4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent S(1) atoms to form LiS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. All Li(1)-S(1) bond lengths are 2.46 Å. Zn(1) is bonded to four equivalent S(1) atoms to form ZnS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and corners with four equivalent P(1)S4 tetrahedra. All Zn(1)-S(1) bond lengths are 2.36 Å. P(1) is bonded to four equivalent S(1) atoms to form PS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and corners with four equivalent Zn(1)S4 tetrahedra. All P(1)-S(1) bond lengths are 2.06 Å. S(1) is bonded in a trigonal non-coplanar geometry to one Li(1), one Zn(1), and one P(1) atom.