PdNiP crystallizes in the hexagonal P-62m space group. Pd(1) is bonded in a 11-coordinate geometry to six equivalent Ni(1), one P(2), and four equivalent P(1) atoms. Ni(1) is bonded in a 4-coordinate geometry to six equivalent Pd(1), two equivalent P(1), and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal planar geometry to six equivalent Pd(1) and three equivalent Ni(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Pd(1) and six equivalent Ni(1) atoms.
PdNiP crystallizes in the hexagonal P-62m space group. Pd(1) is bonded in a 11-coordinate geometry to six equivalent Ni(1), one P(2), and four equivalent P(1) atoms. There are two shorter (2.75 Å) and four longer (2.80 Å) Pd(1)-Ni(1) bond lengths. The Pd(1)-P(2) bond length is 2.44 Å. All Pd(1)-P(1) bond lengths are 2.58 Å. Ni(1) is bonded in a 4-coordinate geometry to six equivalent Pd(1), two equivalent P(1), and two equivalent P(2) atoms. Both Ni(1)-P(1) bond lengths are 2.29 Å. Both Ni(1)-P(2) bond lengths are 2.38 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal planar geometry to six equivalent Pd(1) and three equivalent Ni(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Pd(1) and six equivalent Ni(1) atoms.