EuRhO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Eu(1) and two equivalent Rh(1) atoms. In the second O site, O(2) is bonded to two equivalent Eu(1) and two equivalent Rh(1) atoms to form distorted corner-sharing OEu2Rh2 trigonal pyramids.
EuRhO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.32 Å) and one longer (2.36 Å) Eu(1)-O(2) bond length. There are a spread of Eu(1)-O(1) bond distances ranging from 2.35-2.69 Å. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. Both Rh(1)-O(2) bond lengths are 2.02 Å. All Rh(1)-O(1) bond lengths are 2.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Eu(1) and two equivalent Rh(1) atoms. In the second O site, O(2) is bonded to two equivalent Eu(1) and two equivalent Rh(1) atoms to form distorted corner-sharing OEu2Rh2 trigonal pyramids.