LiMnF3 crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. Mn(1) is bonded to six equivalent F(1) atoms to form distorted face-sharing MnF6 octahedra. F(1) is bonded in a distorted T-shaped geometry to one Li(1) and two equivalent Mn(1) atoms.
LiMnF3 crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. All Li(1)-F(1) bond lengths are 1.83 Å. Mn(1) is bonded to six equivalent F(1) atoms to form distorted face-sharing MnF6 octahedra. All Mn(1)-F(1) bond lengths are 2.16 Å. F(1) is bonded in a distorted T-shaped geometry to one Li(1) and two equivalent Mn(1) atoms.