Zr10(GaSb)3 crystallizes in the hexagonal P-62m space group. There are three inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to three equivalent Ga(1) and three equivalent Sb(1) atoms. In the second Zr site, Zr(2) is bonded in a 5-coordinate geometry to three equivalent Ga(1) and two equivalent Sb(1) atoms. In the third Zr site, Zr(3) is bonded in a 5-coordinate geometry to two equivalent Ga(1) and three equivalent Sb(1) atoms. Ga(1) is bonded in a 9-coordinate geometry to two equivalent Zr(3), three equivalent Zr(2), and four equivalent Zr(1) atoms. Sb(1) is bonded in a 9-coordinate geometry to two equivalent Zr(2), three equivalent Zr(3), and four equivalent Zr(1) atoms.
Zr10(GaSb)3 crystallizes in the hexagonal P-62m space group. There are three inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 6-coordinate geometry to three equivalent Ga(1) and three equivalent Sb(1) atoms. All Zr(1)-Ga(1) bond lengths are 2.93 Å. All Zr(1)-Sb(1) bond lengths are 2.95 Å. In the second Zr site, Zr(2) is bonded in a 5-coordinate geometry to three equivalent Ga(1) and two equivalent Sb(1) atoms. There are two shorter (2.83 Å) and one longer (3.00 Å) Zr(2)-Ga(1) bond length. Both Zr(2)-Sb(1) bond lengths are 3.09 Å. In the third Zr site, Zr(3) is bonded in a 5-coordinate geometry to two equivalent Ga(1) and three equivalent Sb(1) atoms. Both Zr(3)-Ga(1) bond lengths are 3.09 Å. There are two shorter (2.87 Å) and one longer (2.98 Å) Zr(3)-Sb(1) bond length. Ga(1) is bonded in a 9-coordinate geometry to two equivalent Zr(3), three equivalent Zr(2), and four equivalent Zr(1) atoms. Sb(1) is bonded in a 9-coordinate geometry to two equivalent Zr(2), three equivalent Zr(3), and four equivalent Zr(1) atoms.