SbCl3F2 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two SbCl3F2 clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one F(1), and two equivalent F(2) atoms to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles are 11°. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Sb(1) atoms.
SbCl3F2 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two SbCl3F2 clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one F(1), and two equivalent F(2) atoms to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles are 11°. The Sb(1)-Cl(1) bond length is 2.29 Å. The Sb(1)-Cl(2) bond length is 2.30 Å. The Sb(1)-Cl(3) bond length is 2.30 Å. The Sb(1)-F(1) bond length is 1.88 Å. There is one shorter (2.07 Å) and one longer (2.08 Å) Sb(1)-F(2) bond length. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Sb(1) atoms.