VMo5AgCu6O24 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(1), one O(18), one O(3), one O(4), and one O(5) atom to form distorted VO5 tetrahedra that share  an edgeedge with one Mo(1)O7 pentagonal bipyramid. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(18), one O(2), one O(4), and one O(8) atom to form distorted MoO7 pentagonal bipyramids that share  a cornercorner with one O(7)Cu2MoO tetrahedra and  an edgeedge with one V(1)O5 tetrahedra. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(19), one O(4), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(13), one O(16), one O(21), one O(5), and one O(6) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(14), one O(21), one O(22), one O(23), one O(24), and one O(7) atom. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(16), one O(19), one O(20), and one O(23) atom. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(20), one O(24), and one O(6) atom. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 3-coordinate geometry to one O(23), one O(8), and one O(9) atom. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(24), one O(3), and one O(7) atom. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one O(14), one O(17), one O(3), and one O(5) atom. In the fourth Cu site, Cu(4) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(20) atom. In the fifth Cu site, Cu(5) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), and one O(22) atom. In the sixth Cu site, Cu(6) is bonded in a see-saw-like geometry to one O(15), one O(16), one O(2), and one O(7) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mo(5), and one Ag(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Cu(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(2), and one Cu(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), one Mo(3), one Cu(3), and one O(6) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one O(5) atom. In the seventh O site, O(7) is bonded to one Mo(4), one Cu(2), one Cu(6), and one O(8) atom to form distorted OCu2MoO tetrahedra that share  a cornercorner with one Mo(1)O7 pentagonal bipyramid and  a cornercorner with one O(16)CuMo2O tetrahedra. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cu(1), and one O(7) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Mo(1) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Cu(2), and one Cu(4) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(4) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one Mo(4) and one Cu(3) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(6) atom. In the sixteenth O site, O(16) is bonded to one Mo(3), one Mo(5), one Cu(6), and one O(17) atom to form distorted corner-sharing OCuMo2O tetrahedra. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Cu(3), one Cu(5), and one O(16) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Cu(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(5), and one Cu(5) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Mo(5), one Ag(1), and one Cu(4) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(4) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one Cu(5) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Mo(4), one Mo(5), and one Cu(1) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Mo(4), one Ag(1), and one Cu(2) atom.
VMo5AgCu6O24 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(1), one O(18), one O(3), one O(4), and one O(5) atom to form distorted VO5 tetrahedra that share  an edgeedge with one Mo(1)O7 pentagonal bipyramid. The V(1)-O(1) bond length is 1.77 Å. The V(1)-O(18) bond length is 1.77 Å. The V(1)-O(3) bond length is 1.73 Å. The V(1)-O(4) bond length is 1.81 Å. The V(1)-O(5) bond length is 2.61 Å. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(18), one O(2), one O(4), and one O(8) atom to form distorted MoO7 pentagonal bipyramids that share  a cornercorner with one O(7)Cu2MoO tetrahedra and  an edgeedge with one V(1)O5 tetrahedra. The Mo(1)-O(10) bond length is 2.42 Å. The Mo(1)-O(11) bond length is 1.90 Å. The Mo(1)-O(12) bond length is 2.15 Å. The Mo(1)-O(18) bond length is 2.23 Å. The Mo(1)-O(2) bond length is 1.82 Å. The Mo(1)-O(4) bond length is 2.12 Å. The Mo(1)-O(8) bond length is 2.10 Å. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(19), one O(4), and one O(9) atom. The Mo(2)-O(12) bond length is 1.93 Å. The Mo(2)-O(15) bond length is 1.80 Å. The Mo(2)-O(19) bond length is 1.85 Å. The Mo(2)-O(4) bond length is 2.22 Å. The Mo(2)-O(9) bond length is 1.76 Å. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(13), one O(16), one O(21), one O(5), and one O(6) atom. The Mo(3)-O(10) bond length is 1.78 Å. The Mo(3)-O(13) bond length is 1.96 Å. The Mo(3)-O(16) bond length is 2.30 Å. The Mo(3)-O(21) bond length is 2.11 Å. The Mo(3)-O(5) bond length is 2.06 Å. The Mo(3)-O(6) bond length is 1.98 Å. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(14), one O(21), one O(22), one O(23), one O(24), and one O(7) atom. The Mo(4)-O(14) bond length is 1.79 Å. The Mo(4)-O(21) bond length is 1.86 Å. The Mo(4)-O(22) bond length is 1.85 Å. The Mo(4)-O(23) bond length is 2.29 Å. The Mo(4)-O(24) bond length is 1.91 Å. The Mo(4)-O(7) bond length is 2.36 Å. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(16), one O(19), one O(20), and one O(23) atom. The Mo(5)-O(1) bond length is 2.25 Å. The Mo(5)-O(13) bond length is 1.94 Å. The Mo(5)-O(16) bond length is 2.55 Å. The Mo(5)-O(19) bond length is 1.99 Å. The Mo(5)-O(20) bond length is 1.86 Å. The Mo(5)-O(23) bond length is 1.84 Å. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(20), one O(24), and one O(6) atom. The Ag(1)-O(1) bond length is 2.27 Å. The Ag(1)-O(20) bond length is 2.73 Å. The Ag(1)-O(24) bond length is 2.25 Å. The Ag(1)-O(6) bond length is 2.43 Å. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 3-coordinate geometry to one O(23), one O(8), and one O(9) atom. The Cu(1)-O(23) bond length is 1.97 Å. The Cu(1)-O(8) bond length is 2.01 Å. The Cu(1)-O(9) bond length is 1.85 Å. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(24), one O(3), and one O(7) atom. The Cu(2)-O(11) bond length is 1.98 Å. The Cu(2)-O(24) bond length is 1.93 Å. The Cu(2)-O(3) bond length is 1.99 Å. The Cu(2)-O(7) bond length is 2.24 Å. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to one O(14), one O(17), one O(3), and one O(5) atom. The Cu(3)-O(14) bond length is 1.89 Å. The Cu(3)-O(17) bond length is 1.95 Å. The Cu(3)-O(3) bond length is 2.15 Å. The Cu(3)-O(5) bond length is 2.10 Å. In the fourth Cu site, Cu(4) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(20) atom. The Cu(4)-O(11) bond length is 1.97 Å. The Cu(4)-O(12) bond length is 1.93 Å. The Cu(4)-O(20) bond length is 1.86 Å. In the fifth Cu site, Cu(5) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(19), and one O(22) atom. The Cu(5)-O(17) bond length is 1.95 Å. The Cu(5)-O(18) bond length is 1.97 Å. The Cu(5)-O(19) bond length is 2.48 Å. The Cu(5)-O(22) bond length is 1.95 Å. In the sixth Cu site, Cu(6) is bonded in a see-saw-like geometry to one O(15), one O(16), one O(2), and one O(7) atom. The Cu(6)-O(15) bond length is 1.91 Å. The Cu(6)-O(16) bond length is 2.14 Å. The Cu(6)-O(2) bond length is 1.88 Å. The Cu(6)-O(7) bond length is 2.04 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Mo(5), and one Ag(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(1) and one Cu(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(2), and one Cu(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), one Mo(3), one Cu(3), and one O(6) atom. The O(5)-O(6) bond length is 1.48 Å. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one O(5) atom. In the seventh O site, O(7) is bonded to one Mo(4), one Cu(2), one Cu(6), and one O(8) atom to form distorted OCu2MoO tetrahedra that share  a cornercorner with one Mo(1)O7 pentagonal bipyramid and  a cornercorner with one O(16)CuMo2O tetrahedra. The O(7)-O(8) bond length is 1.46 Å. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cu(1), and one O(7) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Mo(1) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Mo(1), one Cu(2), and one Cu(4) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Cu(4) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one Mo(4) and one Cu(3) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mo(2) and one Cu(6) atom. In the sixteenth O site, O(16) is bonded to one Mo(3), one Mo(5), one Cu(6), and one O(17) atom to form distorted corner-sharing OCuMo2O tetrahedra. The O(16)-O(17) bond length is 1.47 Å. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Cu(3), one Cu(5), and one O(16) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one V(1), one Mo(1), and one Cu(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(5), and one Cu(5) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Mo(5), one Ag(1), and one Cu(4) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(4) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one Cu(5) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Mo(4), one Mo(5), and one Cu(1) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Mo(4), one Ag(1), and one Cu(2) atom.