S3(NO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four S3(NO)2 clusters. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent N(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom.
S3(NO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four S3(NO)2 clusters. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(1)-S(1) bond length is 1.55 Å. The N(1)-S(2) bond length is 1.64 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. The S(1)-O(1) bond length is 1.48 Å. In the second S site, S(2) is bonded in a water-like geometry to two equivalent N(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom.