VO is Halite, Rock Salt structured and crystallizes in the monoclinic C2/m space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent O sites. In the first O site, O(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°. In the second O site, O(2) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°.
VO is Halite, Rock Salt structured and crystallizes in the monoclinic C2/m space group. V(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedra are not tilted. There are two shorter (2.13 Å) and one longer (2.18 Å) V(1)-O(1) bond length. There is one shorter (2.12 Å) and two longer (2.18 Å) V(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°. In the second O site, O(2) is bonded to six equivalent V(1) atoms to form a mixture of corner and edge-sharing OV6 octahedra. The corner-sharing octahedral tilt angles are 2°.