PHOF2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight difluoro(oxo)phosphanium molecules. P(1) is bonded in a distorted tetrahedral geometry to one H(1), one O(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one P(1) atom.
PHOF2 is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight difluoro(oxo)phosphanium molecules. P(1) is bonded in a distorted tetrahedral geometry to one H(1), one O(1), one F(1), and one F(2) atom. The P(1)-H(1) bond length is 1.40 Å. The P(1)-O(1) bond length is 1.47 Å. The P(1)-F(1) bond length is 1.57 Å. The P(1)-F(2) bond length is 1.57 Å. H(1) is bonded in a single-bond geometry to one P(1) atom. O(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one P(1) atom.