AgVO3 crystallizes in the monoclinic C2/c space group. V(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form VO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra, corners with four equivalent Ag(1)O6 octahedra, and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-67°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form AgO6 octahedra that share corners with eight equivalent V(1)O4 tetrahedra and edges with three equivalent Ag(2)O6 octahedra. In the second Ag site, Ag(2) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form AgO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra, edges with two equivalent Ag(2)O6 octahedra, and edges with three equivalent Ag(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(1), and two equivalent Ag(2) atoms.
AgVO3 crystallizes in the monoclinic C2/c space group. V(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form VO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra, corners with four equivalent Ag(1)O6 octahedra, and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-67°. The V(1)-O(1) bond length is 1.66 Å. The V(1)-O(3) bond length is 1.68 Å. There is one shorter (1.80 Å) and one longer (1.81 Å) V(1)-O(2) bond length. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form AgO6 octahedra that share corners with eight equivalent V(1)O4 tetrahedra and edges with three equivalent Ag(2)O6 octahedra. Both Ag(1)-O(1) bond lengths are 2.32 Å. Both Ag(1)-O(2) bond lengths are 2.63 Å. Both Ag(1)-O(3) bond lengths are 2.43 Å. In the second Ag site, Ag(2) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form AgO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra, edges with two equivalent Ag(2)O6 octahedra, and edges with three equivalent Ag(1)O6 octahedra. Both Ag(2)-O(1) bond lengths are 2.41 Å. There are two shorter (2.41 Å) and two longer (2.45 Å) Ag(2)-O(3) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one Ag(1), and two equivalent Ag(2) atoms.