VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F3 hexagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent V(1) atoms.
VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F3 hexagonal pyramids. There are a spread of V(1)-O(1) bond distances ranging from 2.04-2.10 Å. There is one shorter (2.12 Å) and two longer (2.13 Å) V(1)-F(1) bond lengths. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent V(1) atoms.