(PtF6)2PtOF6PtO3F5(O2)2OF is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one hypofluorous acid molecule, two PtF6 clusters, one PtO3F5 cluster, and one PtOF6 cluster. In each PtF6 cluster, Pt(2) is bonded in an octahedral geometry to one F(12), one F(13), one F(17), one F(18), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Pt(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Pt(2) atom. In the third F site, F(12) is bonded in a single-bond geometry to one Pt(2) atom. In the fourth F site, F(13) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth F site, F(17) is bonded in a single-bond geometry to one Pt(2) atom. In the sixth F site, F(18) is bonded in a single-bond geometry to one Pt(2) atom. In the PtO3F5 cluster, Pt(4) is bonded in an octahedral geometry to one O(5), one F(1), one F(2), one F(23), one F(24), and one F(3) atom. There are three inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(7) atom. In the second O site, O(6) is bonded in a single-bond geometry to one F(23) atom. In the third O site, O(7) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent F sites. In the first F site, F(23) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(6) atom. In the second F site, F(24) is bonded in a single-bond geometry to one Pt(4) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Pt(4) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Pt(4) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Pt(4) atom. In the PtOF6 cluster, Pt(1) is bonded in an octahedral geometry to one F(11), one F(14), one F(16), one F(19), one F(6), and one F(9) atom. O(9) is bonded in a single-bond geometry to one F(11) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(9) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(11) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(9) atom. In the fourth F site, F(14) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth F site, F(16) is bonded in a single-bond geometry to one Pt(1) atom. In the sixth F site, F(19) is bonded in a single-bond geometry to one Pt(1) atom.
(PtF6)2PtOF6PtO3F5(O2)2OF is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one hypofluorous acid molecule, two PtF6 clusters, one PtO3F5 cluster, and one PtOF6 cluster. In each PtF6 cluster, Pt(2) is bonded in an octahedral geometry to one F(12), one F(13), one F(17), one F(18), one F(7), and one F(8) atom. The Pt(2)-F(12) bond length is 1.90 Å. The Pt(2)-F(13) bond length is 1.90 Å. The Pt(2)-F(17) bond length is 1.91 Å. The Pt(2)-F(18) bond length is 1.93 Å. The Pt(2)-F(7) bond length is 1.91 Å. The Pt(2)-F(8) bond length is 1.92 Å. There are six inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Pt(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Pt(2) atom. In the third F site, F(12) is bonded in a single-bond geometry to one Pt(2) atom. In the fourth F site, F(13) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth F site, F(17) is bonded in a single-bond geometry to one Pt(2) atom. In the sixth F site, F(18) is bonded in a single-bond geometry to one Pt(2) atom. In the PtO3F5 cluster, Pt(4) is bonded in an octahedral geometry to one O(5), one F(1), one F(2), one F(23), one F(24), and one F(3) atom. The Pt(4)-O(5) bond length is 2.16 Å. The Pt(4)-F(1) bond length is 1.96 Å. The Pt(4)-F(2) bond length is 1.91 Å. The Pt(4)-F(23) bond length is 2.17 Å. The Pt(4)-F(24) bond length is 1.93 Å. The Pt(4)-F(3) bond length is 1.91 Å. There are three inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(7) atom. The O(5)-O(7) bond length is 1.24 Å. In the second O site, O(6) is bonded in a single-bond geometry to one F(23) atom. The O(6)-F(23) bond length is 1.42 Å. In the third O site, O(7) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent F sites. In the first F site, F(23) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(6) atom. In the second F site, F(24) is bonded in a single-bond geometry to one Pt(4) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Pt(4) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Pt(4) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Pt(4) atom. In the PtOF6 cluster, Pt(1) is bonded in an octahedral geometry to one F(11), one F(14), one F(16), one F(19), one F(6), and one F(9) atom. The Pt(1)-F(11) bond length is 2.25 Å. The Pt(1)-F(14) bond length is 1.91 Å. The Pt(1)-F(16) bond length is 1.92 Å. The Pt(1)-F(19) bond length is 1.91 Å. The Pt(1)-F(6) bond length is 1.91 Å. The Pt(1)-F(9) bond length is 1.91 Å. O(9) is bonded in a single-bond geometry to one F(11) atom. The O(9)-F(11) bond length is 1.40 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(9) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(11) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(9) atom. In the fourth F site, F(14) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth F site, F(16) is bonded in a single-bond geometry to one Pt(1) atom. In the sixth F site, F(19) is bonded in a single-bond geometry to one Pt(1) atom.