VPb2N3 crystallizes in the orthorhombic Cmce space group. The structure consists of a VPb2N3 framework. V(1) is bonded to one N(1), one N(2), and two equivalent N(3) atoms to form corner-sharing VN4 tetrahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted L-shaped geometry to two equivalent N(1) atoms. In the second Pb site, Pb(2) is bonded in a distorted L-shaped geometry to two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(3) is bonded in a linear geometry to two equivalent V(1) atoms. In the second N site, N(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the third N site, N(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(2) atoms.
VPb2N3 crystallizes in the orthorhombic Cmce space group. The structure consists of a VPb2N3 framework. V(1) is bonded to one N(1), one N(2), and two equivalent N(3) atoms to form corner-sharing VN4 tetrahedra. The V(1)-N(1) bond length is 1.84 Å. The V(1)-N(2) bond length is 1.81 Å. Both V(1)-N(3) bond lengths are 1.83 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted L-shaped geometry to two equivalent N(1) atoms. There is one shorter (2.47 Å) and one longer (2.56 Å) Pb(1)-N(1) bond length. In the second Pb site, Pb(2) is bonded in a distorted L-shaped geometry to two equivalent N(2) atoms. There is one shorter (2.43 Å) and one longer (2.55 Å) Pb(2)-N(2) bond length. There are three inequivalent N sites. In the first N site, N(3) is bonded in a linear geometry to two equivalent V(1) atoms. In the second N site, N(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the third N site, N(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(2) atoms.