CSbNCl6 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CSbNCl6 clusters. C(1) is bonded in a linear geometry to one N(1) and one Cl(4) atom. Sb(1) is bonded in an octahedral geometry to one N(1), one Cl(2), two equivalent Cl(1), and two equivalent Cl(3) atoms. N(1) is bonded in a linear geometry to one C(1) and one Sb(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one C(1) atom.
CSbNCl6 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CSbNCl6 clusters. C(1) is bonded in a linear geometry to one N(1) and one Cl(4) atom. The C(1)-N(1) bond length is 1.17 Å. The C(1)-Cl(4) bond length is 1.59 Å. Sb(1) is bonded in an octahedral geometry to one N(1), one Cl(2), two equivalent Cl(1), and two equivalent Cl(3) atoms. The Sb(1)-N(1) bond length is 2.32 Å. The Sb(1)-Cl(2) bond length is 2.37 Å. Both Sb(1)-Cl(1) bond lengths are 2.38 Å. Both Sb(1)-Cl(3) bond lengths are 2.38 Å. N(1) is bonded in a linear geometry to one C(1) and one Sb(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one C(1) atom.