Li5Ti2Mn5O12 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second Ti site, Ti(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Mn(2), and one Mn(4) atom to form OLi3TiMn2 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(1)Li3TiMn2 octahedra, and edges with four equivalent O(3)Li3TiMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ti(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2TiMn3 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(2)Li2TiMn3 octahedra, and edges with four equivalent O(4)Li2TiMn3 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Mn(2), and one Mn(4) atom to form OLi3TiMn2 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra, edges with four equivalent O(3)Li3TiMn2 octahedra, and edges with four equivalent O(5)Li3TiMn2 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2TiMn3 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(4)Li2TiMn3 octahedra, and edges with four equivalent O(6)Li2TiMn3 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Mn(2), and one Mn(4) atom to form OLi3TiMn2 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra, edges with four equivalent O(1)Li3TiMn2 octahedra, and edges with four equivalent O(5)Li3TiMn2 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ti(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2TiMn3 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(2)Li2TiMn3 octahedra, and edges with four equivalent O(6)Li2TiMn3 octahedra. The corner-sharing octahedral tilt angles range from 1-9°.
Li5Ti2Mn5O12 is Caswellsilverite-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. The Li(1)-O(1) bond length is 2.32 Å. The Li(1)-O(2) bond length is 2.17 Å. The Li(1)-O(3) bond length is 2.12 Å. The Li(1)-O(4) bond length is 2.40 Å. The Li(1)-O(5) bond length is 2.15 Å. The Li(1)-O(6) bond length is 2.15 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. The Li(2)-O(1) bond length is 2.08 Å. The Li(2)-O(2) bond length is 2.17 Å. The Li(2)-O(3) bond length is 2.30 Å. The Li(2)-O(4) bond length is 2.19 Å. The Li(2)-O(5) bond length is 2.08 Å. The Li(2)-O(6) bond length is 2.37 Å. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. Both Li(3)-O(1) bond lengths are 2.23 Å. Both Li(3)-O(3) bond lengths are 2.20 Å. Both Li(3)-O(5) bond lengths are 2.15 Å. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. Both Ti(1)-O(1) bond lengths are 1.95 Å. Both Ti(1)-O(3) bond lengths are 2.06 Å. Both Ti(1)-O(5) bond lengths are 2.02 Å. In the second Ti site, Ti(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. Both Ti(2)-O(2) bond lengths are 2.00 Å. Both Ti(2)-O(4) bond lengths are 1.98 Å. Both Ti(2)-O(6) bond lengths are 2.04 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. Both Mn(1)-O(2) bond lengths are 2.18 Å. Both Mn(1)-O(4) bond lengths are 2.20 Å. Both Mn(1)-O(6) bond lengths are 2.17 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. The Mn(2)-O(1) bond length is 2.11 Å. The Mn(2)-O(2) bond length is 2.40 Å. The Mn(2)-O(3) bond length is 2.13 Å. The Mn(2)-O(4) bond length is 2.19 Å. The Mn(2)-O(5) bond length is 2.24 Å. The Mn(2)-O(6) bond length is 2.13 Å. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. Both Mn(3)-O(2) bond lengths are 2.17 Å. Both Mn(3)-O(4) bond lengths are 2.19 Å. Both Mn(3)-O(6) bond lengths are 2.20 Å. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. Both Mn(4)-O(1) bond lengths are 2.21 Å. Both Mn(4)-O(3) bond lengths are 2.07 Å. Both Mn(4)-O(5) bond lengths are 2.13 Å. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Mn(2), and one Mn(4) atom to form OLi3TiMn2 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(1)Li3TiMn2 octahedra, and edges with four equivalent O(3)Li3TiMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ti(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2TiMn3 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(2)Li2TiMn3 octahedra, and edges with four equivalent O(4)Li2TiMn3 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Mn(2), and one Mn(4) atom to form OLi3TiMn2 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra, edges with four equivalent O(3)Li3TiMn2 octahedra, and edges with four equivalent O(5)Li3TiMn2 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2TiMn3 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(4)Li2TiMn3 octahedra, and edges with four equivalent O(6)Li2TiMn3 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one Mn(2), and one Mn(4) atom to form OLi3TiMn2 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(2)Li2TiMn3 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(6)Li2TiMn3 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra, edges with four equivalent O(1)Li3TiMn2 octahedra, and edges with four equivalent O(5)Li3TiMn2 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ti(2), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi2TiMn3 octahedra that share  a cornercorner with one O(2)Li2TiMn3 octahedra,  a cornercorner with one O(4)Li2TiMn3 octahedra,  a cornercorner with one O(6)Li2TiMn3 octahedra,  a cornercorner with one O(1)Li3TiMn2 octahedra,  a cornercorner with one O(3)Li3TiMn2 octahedra,  a cornercorner with one O(5)Li3TiMn2 octahedra,  an edgeedge with one O(4)Li2TiMn3 octahedra,  an edgeedge with one O(1)Li3TiMn2 octahedra,  an edgeedge with one O(3)Li3TiMn2 octahedra,  an edgeedge with one O(5)Li3TiMn2 octahedra, edges with four equivalent O(2)Li2TiMn3 octahedra, and edges with four equivalent O(6)Li2TiMn3 octahedra. The corner-sharing octahedral tilt angles range from 1-9°.