BiInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pna2_1 space group. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. Bi(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent In(1) and two equivalent Bi(1) atoms to form distorted edge-sharing OIn2Bi2 trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent In(1) and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent In(1) and two equivalent Bi(1) atoms.
BiInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pna2_1 space group. In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 38-41°. There is one shorter (2.20 Å) and one longer (2.24 Å) In(1)-O(1) bond length. There is one shorter (2.17 Å) and one longer (2.29 Å) In(1)-O(2) bond length. There is one shorter (2.18 Å) and one longer (2.25 Å) In(1)-O(3) bond length. Bi(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There is one shorter (2.32 Å) and one longer (2.53 Å) Bi(1)-O(1) bond length. There is one shorter (2.30 Å) and one longer (2.46 Å) Bi(1)-O(2) bond length. There is one shorter (2.26 Å) and one longer (2.76 Å) Bi(1)-O(3) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent In(1) and two equivalent Bi(1) atoms to form distorted edge-sharing OIn2Bi2 trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent In(1) and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent In(1) and two equivalent Bi(1) atoms.