Ce2Ni2In crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. Ni(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Ni(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Ce(1) and four equivalent Ni(1) atoms to form a mixture of face and corner-sharing InCe8Ni4 cuboctahedra.
Ce2Ni2In crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. There are two shorter (2.80 Å) and four longer (2.90 Å) Ce(1)-Ni(1) bond lengths. All Ce(1)-In(1) bond lengths are 3.31 Å. Ni(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Ni(1), and two equivalent In(1) atoms. The Ni(1)-Ni(1) bond length is 2.67 Å. Both Ni(1)-In(1) bond lengths are 2.96 Å. In(1) is bonded to eight equivalent Ce(1) and four equivalent Ni(1) atoms to form a mixture of face and corner-sharing InCe8Ni4 cuboctahedra.