TbTiGe is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Tb(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. Ti(1) is bonded to four equivalent Ge(1) atoms to form a mixture of distorted corner and edge-sharing TiGe4 cuboctahedra. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Tb(1) and four equivalent Ti(1) atoms.
TbTiGe is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Tb(1) is bonded in a 5-coordinate geometry to five equivalent Ge(1) atoms. There are four shorter (2.98 Å) and one longer (3.20 Å) Tb(1)-Ge(1) bond length. Ti(1) is bonded to four equivalent Ge(1) atoms to form a mixture of distorted corner and edge-sharing TiGe4 cuboctahedra. All Ti(1)-Ge(1) bond lengths are 2.75 Å. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Tb(1) and four equivalent Ti(1) atoms.