NaWSbO6 crystallizes in the orthorhombic Imma space group. Na(1) is bonded in a hexagonal planar geometry to two equivalent O(3) and four equivalent O(1) atoms. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-42°. Sb(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded to two equivalent Na(1) and two equivalent Sb(1) atoms to form distorted corner-sharing ONa2Sb2 tetrahedra.
NaWSbO6 crystallizes in the orthorhombic Imma space group. Na(1) is bonded in a hexagonal planar geometry to two equivalent O(3) and four equivalent O(1) atoms. Both Na(1)-O(3) bond lengths are 2.56 Å. All Na(1)-O(1) bond lengths are 2.61 Å. W(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-42°. Both W(1)-O(2) bond lengths are 1.94 Å. All W(1)-O(1) bond lengths are 1.94 Å. Sb(1) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. Both Sb(1)-O(3) bond lengths are 2.00 Å. All Sb(1)-O(1) bond lengths are 2.00 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded to two equivalent Na(1) and two equivalent Sb(1) atoms to form distorted corner-sharing ONa2Sb2 tetrahedra.