BaLaMn2O6 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent La(1)O12 cuboctahedra, and faces with eight equivalent Mn(1)O6 octahedra. La(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, and faces with eight equivalent Mn(1)O6 octahedra. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Ba(1), two equivalent La(1), and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded to two equivalent Ba(1), two equivalent La(1), and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing OBa2La2Mn2 octahedra. The corner-sharing octahedra are not tilted.
BaLaMn2O6 is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent La(1)O12 cuboctahedra, and faces with eight equivalent Mn(1)O6 octahedra. All Ba(1)-O(2) bond lengths are 2.75 Å. All Ba(1)-O(1) bond lengths are 2.82 Å. La(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, and faces with eight equivalent Mn(1)O6 octahedra. All La(1)-O(2) bond lengths are 2.75 Å. All La(1)-O(1) bond lengths are 2.82 Å. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, faces with four equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent La(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Both Mn(1)-O(2) bond lengths are 2.04 Å. All Mn(1)-O(1) bond lengths are 1.94 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Ba(1), two equivalent La(1), and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded to two equivalent Ba(1), two equivalent La(1), and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing OBa2La2Mn2 octahedra. The corner-sharing octahedra are not tilted.