Li2AgGa is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to six equivalent Ag(1) and four equivalent Ga(1) atoms to form distorted LiGa4Ag6 tetrahedra that share corners with six equivalent Li(1)Ga4Ag6 tetrahedra, edges with twelve equivalent Li(2)Ga6Ag4 tetrahedra, faces with four equivalent Li(2)Ga6Ag4 tetrahedra, and faces with twelve equivalent Li(1)Ga4Ag6 tetrahedra. In the second Li site, Li(2) is bonded to four equivalent Ag(1) and six equivalent Ga(1) atoms to form distorted LiGa6Ag4 tetrahedra that share corners with six equivalent Li(2)Ga6Ag4 tetrahedra, edges with twelve equivalent Li(1)Ga4Ag6 tetrahedra, faces with four equivalent Li(1)Ga4Ag6 tetrahedra, and faces with twelve equivalent Li(2)Ga6Ag4 tetrahedra. Ag(1) is bonded in a 14-coordinate geometry to four equivalent Li(2), six equivalent Li(1), and four equivalent Ga(1) atoms. Ga(1) is bonded in a 14-coordinate geometry to four equivalent Li(1), six equivalent Li(2), and four equivalent Ag(1) atoms.
Li2AgGa is Zintl Phase-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to six equivalent Ag(1) and four equivalent Ga(1) atoms to form distorted LiGa4Ag6 tetrahedra that share corners with six equivalent Li(1)Ga4Ag6 tetrahedra, edges with twelve equivalent Li(2)Ga6Ag4 tetrahedra, faces with four equivalent Li(2)Ga6Ag4 tetrahedra, and faces with twelve equivalent Li(1)Ga4Ag6 tetrahedra. All Li(1)-Ag(1) bond lengths are 3.11 Å. All Li(1)-Ga(1) bond lengths are 2.69 Å. In the second Li site, Li(2) is bonded to four equivalent Ag(1) and six equivalent Ga(1) atoms to form distorted LiGa6Ag4 tetrahedra that share corners with six equivalent Li(2)Ga6Ag4 tetrahedra, edges with twelve equivalent Li(1)Ga4Ag6 tetrahedra, faces with four equivalent Li(1)Ga4Ag6 tetrahedra, and faces with twelve equivalent Li(2)Ga6Ag4 tetrahedra. All Li(2)-Ag(1) bond lengths are 2.69 Å. All Li(2)-Ga(1) bond lengths are 3.11 Å. Ag(1) is bonded in a 14-coordinate geometry to four equivalent Li(2), six equivalent Li(1), and four equivalent Ga(1) atoms. All Ag(1)-Ga(1) bond lengths are 2.69 Å. Ga(1) is bonded in a 14-coordinate geometry to four equivalent Li(1), six equivalent Li(2), and four equivalent Ag(1) atoms.