WMnZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with three equivalent Zn(1)O6 pentagonal pyramids, and  a faceface with one Zn(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 43-44°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra and edges with three equivalent Zn(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 43-44°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted ZnO6 pentagonal pyramids that share corners with three equivalent W(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OMnZn2W tetrahedra. In the second O site, O(2) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OMnZn2W tetrahedra. In the third O site, O(3) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OMnZn2W tetrahedra. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom.
WMnZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with three equivalent Zn(1)O6 pentagonal pyramids, and  a faceface with one Zn(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 43-44°. The W(1)-O(1) bond length is 2.03 Å. The W(1)-O(2) bond length is 2.03 Å. The W(1)-O(3) bond length is 2.03 Å. The W(1)-O(4) bond length is 1.91 Å. The W(1)-O(5) bond length is 1.91 Å. The W(1)-O(6) bond length is 1.91 Å. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra and edges with three equivalent Zn(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 43-44°. The Mn(1)-O(1) bond length is 2.16 Å. The Mn(1)-O(2) bond length is 2.16 Å. The Mn(1)-O(3) bond length is 2.16 Å. The Mn(1)-O(4) bond length is 2.26 Å. The Mn(1)-O(5) bond length is 2.26 Å. The Mn(1)-O(6) bond length is 2.26 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted ZnO6 pentagonal pyramids that share corners with three equivalent W(1)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. The Zn(1)-O(1) bond length is 2.29 Å. The Zn(1)-O(2) bond length is 2.30 Å. The Zn(1)-O(3) bond length is 2.30 Å. The Zn(1)-O(4) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 2.04 Å. The Zn(1)-O(6) bond length is 2.04 Å. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The Zn(2)-O(1) bond length is 1.94 Å. The Zn(2)-O(2) bond length is 1.94 Å. The Zn(2)-O(3) bond length is 1.94 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OMnZn2W tetrahedra. In the second O site, O(2) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OMnZn2W tetrahedra. In the third O site, O(3) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OMnZn2W tetrahedra. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom.