Tb2Pd2In crystallizes in the tetragonal P4/mbm space group. Tb(1) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Tb(1), one Pd(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Tb(1) and four equivalent Pd(1) atoms to form a mixture of face and corner-sharing InTb8Pd4 cuboctahedra.
Tb2Pd2In crystallizes in the tetragonal P4/mbm space group. Tb(1) is bonded in a 6-coordinate geometry to six equivalent Pd(1) and four equivalent In(1) atoms. There are two shorter (2.85 Å) and four longer (2.99 Å) Tb(1)-Pd(1) bond lengths. All Tb(1)-In(1) bond lengths are 3.40 Å. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Tb(1), one Pd(1), and two equivalent In(1) atoms. The Pd(1)-Pd(1) bond length is 2.80 Å. Both Pd(1)-In(1) bond lengths are 3.05 Å. In(1) is bonded to eight equivalent Tb(1) and four equivalent Pd(1) atoms to form a mixture of face and corner-sharing InTb8Pd4 cuboctahedra.