VNCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four VNCl5 clusters. In each VNCl5 cluster, V(1) is bonded in a trigonal bipyramidal geometry to one N(1), one Cl(1), one Cl(4), and two equivalent Cl(3) atoms. N(1) is bonded in a 2-coordinate geometry to one V(1) and one Cl(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one V(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one V(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one V(1) atom.
VNCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four VNCl5 clusters. In each VNCl5 cluster, V(1) is bonded in a trigonal bipyramidal geometry to one N(1), one Cl(1), one Cl(4), and two equivalent Cl(3) atoms. The V(1)-N(1) bond length is 1.80 Å. The V(1)-Cl(1) bond length is 2.16 Å. The V(1)-Cl(4) bond length is 2.19 Å. Both V(1)-Cl(3) bond lengths are 2.26 Å. N(1) is bonded in a 2-coordinate geometry to one V(1) and one Cl(2) atom. The N(1)-Cl(2) bond length is 1.59 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one V(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one V(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one V(1) atom.