Li5Mn2(PO4)3 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(11), one O(16), and one O(21) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 69°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(17), one O(2), one O(6), and one O(8) atom. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(13), one O(5), one O(8), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(10), one O(19), one O(4), and one O(7) atom. In the fifth Li site, Li(5) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(16), one O(23), and one O(3) atom. In the sixth Li site, Li(6) is bonded in a rectangular see-saw-like geometry to one O(14), one O(2), one O(22), and one O(9) atom. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(12), one O(16), one O(17), and one O(20) atom. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(13), one O(17), one O(19), one O(23), and one O(8) atom. In the ninth Li site, Li(9) is bonded in a 4-coordinate geometry to one O(15), one O(18), one O(21), and one O(6) atom. In the tenth Li site, Li(10) is bonded to one O(14), one O(24), one O(4), and one O(9) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 69°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(18), one O(2), one O(3), and one O(5) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(10)O4 trigonal pyramid. In the second Mn site, Mn(2) is bonded to one O(1), one O(13), one O(15), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, and  an edgeedge with one Li(10)O4 trigonal pyramid. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(16), one O(19), one O(21), and one O(24) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(10)O4 trigonal pyramid, and  an edgeedge with one Li(1)O4 trigonal pyramid. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(20), one O(22), one O(23), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(1)O4 trigonal pyramid. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(21), one O(22), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid,  a cornercorner with one Li(1)O4 trigonal pyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 44-54°. In the second P site, P(2) is bonded to one O(10), one O(11), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  a cornercorner with one Li(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 41-44°. In the third P site, P(3) is bonded to one O(1), one O(12), one O(2), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  a cornercorner with one Li(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. In the fourth P site, P(4) is bonded to one O(13), one O(18), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. In the fifth P site, P(5) is bonded to one O(14), one O(15), one O(17), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 41-44°. In the sixth P site, P(6) is bonded to one O(16), one O(20), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid,  a cornercorner with one Li(1)O4 trigonal pyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 43-54°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Mn(2), and one P(3) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(6), one Mn(1), and one P(3) atom. In the third O site, O(3) is bonded in a T-shaped geometry to one Li(5), one Mn(1), and one P(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal pyramidal geometry to one Li(10), one Li(4), one Mn(2), and one P(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(9), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(4), one Mn(4), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Li(8), and one P(2) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(10), one Li(3), one Li(6), one Mn(2), and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(3), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Mn(4), and one P(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(7), one Mn(3), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(8), one Mn(2), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(10), one Li(6), one Mn(1), and one P(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(9), one Mn(2), and one P(5) atom. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Li(1), one Li(5), one Li(7), one Mn(3), and one P(6) atom. In the seventeenth O site, O(17) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(7), one Li(8), and one P(5) atom. In the eighteenth O site, O(18) is bonded in a trigonal planar geometry to one Li(9), one Mn(1), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Li(4), one Li(8), one Mn(3), and one P(5) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Li(7), one Mn(4), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a distorted tetrahedral geometry to one Li(1), one Li(9), one Mn(3), and one P(1) atom. In the twenty-second O site, O(22) is bonded in a T-shaped geometry to one Li(6), one Mn(4), and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(5), one Li(8), one Mn(4), and one P(4) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal planar geometry to one Li(10), one Mn(3), and one P(4) atom.
Li5Mn2(PO4)3 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(11), one O(16), and one O(21) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 69°. The Li(1)-O(1) bond length is 1.96 Å. The Li(1)-O(11) bond length is 1.98 Å. The Li(1)-O(16) bond length is 2.09 Å. The Li(1)-O(21) bond length is 1.96 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(17), one O(2), one O(6), and one O(8) atom. The Li(2)-O(12) bond length is 2.33 Å. The Li(2)-O(17) bond length is 2.02 Å. The Li(2)-O(2) bond length is 2.14 Å. The Li(2)-O(6) bond length is 2.04 Å. The Li(2)-O(8) bond length is 2.15 Å. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to one O(13), one O(5), one O(8), and one O(9) atom. The Li(3)-O(13) bond length is 1.96 Å. The Li(3)-O(5) bond length is 1.94 Å. The Li(3)-O(8) bond length is 1.99 Å. The Li(3)-O(9) bond length is 2.43 Å. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(10), one O(19), one O(4), and one O(7) atom. The Li(4)-O(10) bond length is 1.96 Å. The Li(4)-O(19) bond length is 2.56 Å. The Li(4)-O(4) bond length is 1.99 Å. The Li(4)-O(7) bond length is 1.93 Å. In the fifth Li site, Li(5) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(16), one O(23), and one O(3) atom. The Li(5)-O(11) bond length is 2.14 Å. The Li(5)-O(16) bond length is 2.14 Å. The Li(5)-O(23) bond length is 2.00 Å. The Li(5)-O(3) bond length is 2.08 Å. In the sixth Li site, Li(6) is bonded in a rectangular see-saw-like geometry to one O(14), one O(2), one O(22), and one O(9) atom. The Li(6)-O(14) bond length is 2.13 Å. The Li(6)-O(2) bond length is 2.00 Å. The Li(6)-O(22) bond length is 2.09 Å. The Li(6)-O(9) bond length is 2.12 Å. In the seventh Li site, Li(7) is bonded in a 4-coordinate geometry to one O(12), one O(16), one O(17), and one O(20) atom. The Li(7)-O(12) bond length is 1.96 Å. The Li(7)-O(16) bond length is 2.44 Å. The Li(7)-O(17) bond length is 1.98 Å. The Li(7)-O(20) bond length is 1.94 Å. In the eighth Li site, Li(8) is bonded in a 5-coordinate geometry to one O(13), one O(17), one O(19), one O(23), and one O(8) atom. The Li(8)-O(13) bond length is 2.35 Å. The Li(8)-O(17) bond length is 2.15 Å. The Li(8)-O(19) bond length is 2.04 Å. The Li(8)-O(23) bond length is 2.13 Å. The Li(8)-O(8) bond length is 2.02 Å. In the ninth Li site, Li(9) is bonded in a 4-coordinate geometry to one O(15), one O(18), one O(21), and one O(6) atom. The Li(9)-O(15) bond length is 1.96 Å. The Li(9)-O(18) bond length is 1.93 Å. The Li(9)-O(21) bond length is 1.99 Å. The Li(9)-O(6) bond length is 2.56 Å. In the tenth Li site, Li(10) is bonded to one O(14), one O(24), one O(4), and one O(9) atom to form LiO4 trigonal pyramids that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 69°. The Li(10)-O(14) bond length is 1.97 Å. The Li(10)-O(24) bond length is 1.96 Å. The Li(10)-O(4) bond length is 1.96 Å. The Li(10)-O(9) bond length is 2.13 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(18), one O(2), one O(3), and one O(5) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(10)O4 trigonal pyramid. The Mn(1)-O(14) bond length is 2.21 Å. The Mn(1)-O(18) bond length is 2.12 Å. The Mn(1)-O(2) bond length is 2.31 Å. The Mn(1)-O(3) bond length is 2.07 Å. The Mn(1)-O(5) bond length is 2.07 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(13), one O(15), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(1)O4 trigonal pyramid, and  an edgeedge with one Li(10)O4 trigonal pyramid. The Mn(2)-O(1) bond length is 2.13 Å. The Mn(2)-O(13) bond length is 2.29 Å. The Mn(2)-O(15) bond length is 2.18 Å. The Mn(2)-O(4) bond length is 2.33 Å. The Mn(2)-O(6) bond length is 2.22 Å. The Mn(2)-O(9) bond length is 2.25 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(16), one O(19), one O(21), and one O(24) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(10)O4 trigonal pyramid, and  an edgeedge with one Li(1)O4 trigonal pyramid. The Mn(3)-O(10) bond length is 2.18 Å. The Mn(3)-O(12) bond length is 2.30 Å. The Mn(3)-O(16) bond length is 2.25 Å. The Mn(3)-O(19) bond length is 2.21 Å. The Mn(3)-O(21) bond length is 2.33 Å. The Mn(3)-O(24) bond length is 2.13 Å. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(20), one O(22), one O(23), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(1)O4 trigonal pyramid. The Mn(4)-O(11) bond length is 2.21 Å. The Mn(4)-O(20) bond length is 2.07 Å. The Mn(4)-O(22) bond length is 2.07 Å. The Mn(4)-O(23) bond length is 2.31 Å. The Mn(4)-O(7) bond length is 2.12 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(21), one O(22), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid,  a cornercorner with one Li(1)O4 trigonal pyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 44-54°. The P(1)-O(21) bond length is 1.56 Å. The P(1)-O(22) bond length is 1.53 Å. The P(1)-O(5) bond length is 1.55 Å. The P(1)-O(9) bond length is 1.57 Å. In the second P site, P(2) is bonded to one O(10), one O(11), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  a cornercorner with one Li(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 41-44°. The P(2)-O(10) bond length is 1.54 Å. The P(2)-O(11) bond length is 1.58 Å. The P(2)-O(6) bond length is 1.56 Å. The P(2)-O(8) bond length is 1.56 Å. In the third P site, P(3) is bonded to one O(1), one O(12), one O(2), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  a cornercorner with one Li(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. The P(3)-O(1) bond length is 1.55 Å. The P(3)-O(12) bond length is 1.56 Å. The P(3)-O(2) bond length is 1.57 Å. The P(3)-O(7) bond length is 1.55 Å. In the fourth P site, P(4) is bonded to one O(13), one O(18), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. The P(4)-O(13) bond length is 1.56 Å. The P(4)-O(18) bond length is 1.55 Å. The P(4)-O(23) bond length is 1.57 Å. The P(4)-O(24) bond length is 1.55 Å. In the fifth P site, P(5) is bonded to one O(14), one O(15), one O(17), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 41-44°. The P(5)-O(14) bond length is 1.58 Å. The P(5)-O(15) bond length is 1.54 Å. The P(5)-O(17) bond length is 1.56 Å. The P(5)-O(19) bond length is 1.56 Å. In the sixth P site, P(6) is bonded to one O(16), one O(20), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid,  a cornercorner with one Li(1)O4 trigonal pyramid, and  a cornercorner with one Li(10)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 43-54°. The P(6)-O(16) bond length is 1.58 Å. The P(6)-O(20) bond length is 1.55 Å. The P(6)-O(3) bond length is 1.53 Å. The P(6)-O(4) bond length is 1.56 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Mn(2), and one P(3) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(6), one Mn(1), and one P(3) atom. In the third O site, O(3) is bonded in a T-shaped geometry to one Li(5), one Mn(1), and one P(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal pyramidal geometry to one Li(10), one Li(4), one Mn(2), and one P(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(2), one Li(9), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(4), one Mn(4), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Li(8), and one P(2) atom. In the ninth O site, O(9) is bonded in a 5-coordinate geometry to one Li(10), one Li(3), one Li(6), one Mn(2), and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(3), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one Li(5), one Mn(4), and one P(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(7), one Mn(3), and one P(3) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(8), one Mn(2), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Li(10), one Li(6), one Mn(1), and one P(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(9), one Mn(2), and one P(5) atom. In the sixteenth O site, O(16) is bonded in a 5-coordinate geometry to one Li(1), one Li(5), one Li(7), one Mn(3), and one P(6) atom. In the seventeenth O site, O(17) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(7), one Li(8), and one P(5) atom. In the eighteenth O site, O(18) is bonded in a trigonal planar geometry to one Li(9), one Mn(1), and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one Li(4), one Li(8), one Mn(3), and one P(5) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Li(7), one Mn(4), and one P(6) atom. In the twenty-first O site, O(21) is bonded in a distorted tetrahedral geometry to one Li(1), one Li(9), one Mn(3), and one P(1) atom. In the twenty-second O site, O(22) is bonded in a T-shaped geometry to one Li(6), one Mn(4), and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(5), one Li(8), one Mn(4), and one P(4) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal planar geometry to one Li(10), one Mn(3), and one P(4) atom.