LiTiV2CrO10 crystallizes in the monoclinic Pm space group. Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(8), and two equivalent O(6) atoms. Ti(1) is bonded to one O(5), one O(8), and two equivalent O(6) atoms to form TiO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids and corners with two equivalent V(2)O5 trigonal bipyramids. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(5), one O(8), and two equivalent O(3) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent Ti(1)O4 tetrahedra and corners with two equivalent Cr(1)O4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(4), one O(7), and two equivalent O(6) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent Ti(1)O4 tetrahedra and corners with two equivalent Cr(1)O4 tetrahedra. Cr(1) is bonded to one O(1), one O(4), and two equivalent O(3) atoms to form CrO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids and corners with two equivalent V(2)O5 trigonal bipyramids. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(2) and one Cr(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(2) and one Cr(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Ti(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ti(1), and one V(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one V(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Li(1), one Ti(1), and one V(1) atom.
LiTiV2CrO10 crystallizes in the monoclinic Pm space group. Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(8), and two equivalent O(6) atoms. The Li(1)-O(2) bond length is 1.98 Å. The Li(1)-O(8) bond length is 1.88 Å. Both Li(1)-O(6) bond lengths are 2.24 Å. Ti(1) is bonded to one O(5), one O(8), and two equivalent O(6) atoms to form TiO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids and corners with two equivalent V(2)O5 trigonal bipyramids. The Ti(1)-O(5) bond length is 1.77 Å. The Ti(1)-O(8) bond length is 1.82 Å. Both Ti(1)-O(6) bond lengths are 1.89 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(5), one O(8), and two equivalent O(3) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent Ti(1)O4 tetrahedra and corners with two equivalent Cr(1)O4 tetrahedra. The V(1)-O(2) bond length is 1.66 Å. The V(1)-O(5) bond length is 1.92 Å. The V(1)-O(8) bond length is 1.96 Å. Both V(1)-O(3) bond lengths are 1.99 Å. In the second V site, V(2) is bonded to one O(1), one O(4), one O(7), and two equivalent O(6) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent Ti(1)O4 tetrahedra and corners with two equivalent Cr(1)O4 tetrahedra. The V(2)-O(1) bond length is 2.04 Å. The V(2)-O(4) bond length is 1.96 Å. The V(2)-O(7) bond length is 1.62 Å. Both V(2)-O(6) bond lengths are 1.86 Å. Cr(1) is bonded to one O(1), one O(4), and two equivalent O(3) atoms to form CrO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids and corners with two equivalent V(2)O5 trigonal bipyramids. The Cr(1)-O(1) bond length is 1.67 Å. The Cr(1)-O(4) bond length is 1.69 Å. Both Cr(1)-O(3) bond lengths are 1.65 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(2) and one Cr(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(2) and one Cr(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Ti(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Ti(1), and one V(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one V(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Li(1), one Ti(1), and one V(1) atom.