RbLiBi2(MoO4)4 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(8) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(7), and one O(8) atom. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mo(2) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Li(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(2) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Bi(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one Mo(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Rb(1), one Mo(2), and one Bi(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Rb(1), one Li(1), and one Mo(2) atom.
RbLiBi2(MoO4)4 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Both Rb(1)-O(2) bond lengths are 2.81 Å. Both Rb(1)-O(3) bond lengths are 3.15 Å. Both Rb(1)-O(6) bond lengths are 2.81 Å. Both Rb(1)-O(7) bond lengths are 3.19 Å. Both Rb(1)-O(8) bond lengths are 3.15 Å. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(8) atoms. Both Li(1)-O(2) bond lengths are 2.13 Å. Both Li(1)-O(8) bond lengths are 2.06 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(6) atom. The Mo(1)-O(2) bond length is 1.77 Å. The Mo(1)-O(3) bond length is 1.84 Å. The Mo(1)-O(5) bond length is 1.87 Å. The Mo(1)-O(6) bond length is 1.76 Å. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(7), and one O(8) atom. The Mo(2)-O(1) bond length is 1.88 Å. The Mo(2)-O(4) bond length is 1.84 Å. The Mo(2)-O(7) bond length is 1.79 Å. The Mo(2)-O(8) bond length is 1.76 Å. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms. The Bi(1)-O(3) bond length is 2.32 Å. The Bi(1)-O(7) bond length is 2.47 Å. There is one shorter (2.50 Å) and one longer (2.53 Å) Bi(1)-O(1) bond length. There is one shorter (2.57 Å) and one longer (2.62 Å) Bi(1)-O(4) bond length. There is one shorter (2.41 Å) and one longer (2.57 Å) Bi(1)-O(5) bond length. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mo(2) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Li(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(2) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(1) and two equivalent Bi(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one Mo(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Rb(1), one Mo(2), and one Bi(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Rb(1), one Li(1), and one Mo(2) atom.