CeMoO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. Mo(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Ce(1) and two equivalent Mo(1) atoms to form a mixture of distorted corner and edge-sharing OCe3Mo2 trigonal bipyramids.
CeMoO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. All Ce(1)-O(1) bond lengths are 2.47 Å. Mo(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Mo(1)-O(1) bond lengths are 2.24 Å. O(1) is bonded to three equivalent Ce(1) and two equivalent Mo(1) atoms to form a mixture of distorted corner and edge-sharing OCe3Mo2 trigonal bipyramids.