(IrN2S2(OCl)4)2N2(NO)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ammonia atoms, four nitroxyl molecules, and two IrN2S2(OCl)4 clusters. In each IrN2S2(OCl)4 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. N(1) is bonded in a single-bond geometry to one Cl(2) atom. S(1) is bonded in a distorted trigonal planar geometry to one Ir(1), one O(2), and one O(3) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Ir(1) and one N(1) atom.
(IrN2S2(OCl)4)2N2(NO)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ammonia atoms, four nitroxyl molecules, and two IrN2S2(OCl)4 clusters. In each IrN2S2(OCl)4 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. Both Ir(1)-S(1) bond lengths are 2.25 Å. Both Ir(1)-Cl(1) bond lengths are 2.37 Å. Both Ir(1)-Cl(2) bond lengths are 2.59 Å. N(1) is bonded in a single-bond geometry to one Cl(2) atom. The N(1)-Cl(2) bond length is 1.58 Å. S(1) is bonded in a distorted trigonal planar geometry to one Ir(1), one O(2), and one O(3) atom. The S(1)-O(2) bond length is 1.45 Å. The S(1)-O(3) bond length is 1.45 Å. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Ir(1) and one N(1) atom.