OsO2F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two OsO2F3 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one O(3), one F(1), one F(3), one F(4), one F(5), and one F(6) atom. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one F(2), one F(5), and one F(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Os(2) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the second F site, F(6) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Os(2) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Os(1) atom.
OsO2F3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two OsO2F3 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one O(3), one F(1), one F(3), one F(4), one F(5), and one F(6) atom. The Os(1)-O(3) bond length is 1.68 Å. The Os(1)-F(1) bond length is 1.89 Å. The Os(1)-F(3) bond length is 1.89 Å. The Os(1)-F(4) bond length is 1.89 Å. The Os(1)-F(5) bond length is 2.05 Å. The Os(1)-F(6) bond length is 2.04 Å. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one F(2), one F(5), and one F(6) atom. The Os(2)-O(1) bond length is 1.71 Å. The Os(2)-O(2) bond length is 1.71 Å. The Os(2)-O(4) bond length is 1.71 Å. The Os(2)-F(2) bond length is 1.90 Å. The Os(2)-F(5) bond length is 2.23 Å. The Os(2)-F(6) bond length is 2.24 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Os(2) atom. There are six inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the second F site, F(6) is bonded in a distorted bent 150 degrees geometry to one Os(1) and one Os(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Os(2) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(4) is bonded in a single-bond geometry to one Os(1) atom.