CNH is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CNH clusters. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(2) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one C(2) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. In the third N site, N(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom.
CNH is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CNH clusters. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(2) atom. The C(1)-C(2) bond length is 1.44 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.34 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one C(2) and one N(3) atom. The C(3)-N(3) bond length is 1.17 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one N(4) atom. The C(4)-N(4) bond length is 1.18 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.01 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.02 Å. The N(2)-H(4) bond length is 1.03 Å. In the third N site, N(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom.