TlCo(CO)4 is Indium-derived structured and crystallizes in the cubic P2_13 space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four Co(CO)4 clusters. In each Co(CO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one C(2) and three equivalent C(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom.
TlCo(CO)4 is Indium-derived structured and crystallizes in the cubic P2_13 space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four Co(CO)4 clusters. In each Co(CO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one C(2) and three equivalent C(1) atoms. The Co(1)-C(2) bond length is 1.75 Å. All Co(1)-C(1) bond lengths are 1.75 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. The C(1)-O(1) bond length is 1.17 Å. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. The C(2)-O(2) bond length is 1.17 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom.