SrVCuHO5 crystallizes in the orthorhombic P2_12_12_1 space group. Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(5), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. Cu(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(5) atoms to form distorted CuO6 octahedra that share corners with four equivalent V(1)O4 tetrahedra and edges with two equivalent Cu(1)O6 octahedra. H(1) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Sr(1), two equivalent Cu(1), and one H(1) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Sr(1), one V(1), and two equivalent Cu(1) atoms. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Sr(1), one V(1), and one Cu(1) atom. In the fifth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one V(1), and one Cu(1) atom.
SrVCuHO5 crystallizes in the orthorhombic P2_12_12_1 space group. Sr(1) is bonded in a 8-coordinate geometry to one O(1), one O(5), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. The Sr(1)-O(1) bond length is 2.72 Å. The Sr(1)-O(5) bond length is 2.60 Å. There is one shorter (2.64 Å) and one longer (2.82 Å) Sr(1)-O(2) bond length. There is one shorter (2.57 Å) and one longer (2.60 Å) Sr(1)-O(3) bond length. There is one shorter (2.53 Å) and one longer (2.62 Å) Sr(1)-O(4) bond length. V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. The V(1)-O(1) bond length is 1.82 Å. The V(1)-O(2) bond length is 1.73 Å. The V(1)-O(3) bond length is 1.73 Å. The V(1)-O(4) bond length is 1.73 Å. Cu(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(5) atoms to form distorted CuO6 octahedra that share corners with four equivalent V(1)O4 tetrahedra and edges with two equivalent Cu(1)O6 octahedra. The Cu(1)-O(3) bond length is 2.58 Å. The Cu(1)-O(4) bond length is 2.49 Å. There is one shorter (2.05 Å) and one longer (2.06 Å) Cu(1)-O(1) bond length. Both Cu(1)-O(5) bond lengths are 1.93 Å. H(1) is bonded in a single-bond geometry to one O(5) atom. The H(1)-O(5) bond length is 0.99 Å. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Sr(1), two equivalent Cu(1), and one H(1) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Sr(1), one V(1), and two equivalent Cu(1) atoms. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one V(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Sr(1), one V(1), and one Cu(1) atom. In the fifth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one V(1), and one Cu(1) atom.