Tb3Mn3GeGa2 crystallizes in the hexagonal P-6 space group. Tb(1) is bonded in a 11-coordinate geometry to six equivalent Mn(1), one Ga(2), two equivalent Ga(1), and two equivalent Ge(1) atoms. Mn(1) is bonded in a 12-coordinate geometry to six equivalent Tb(1), two equivalent Mn(1), one Ga(1), two equivalent Ga(2), and one Ge(1) atom. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 9-coordinate geometry to six equivalent Tb(1) and three equivalent Mn(1) atoms. In the second Ga site, Ga(2) is bonded in a distorted q6 geometry to three equivalent Tb(1) and six equivalent Mn(1) atoms. Ge(1) is bonded in a 9-coordinate geometry to six equivalent Tb(1) and three equivalent Mn(1) atoms.
Tb3Mn3GeGa2 crystallizes in the hexagonal P-6 space group. Tb(1) is bonded in a 11-coordinate geometry to six equivalent Mn(1), one Ga(2), two equivalent Ga(1), and two equivalent Ge(1) atoms. There are a spread of Tb(1)-Mn(1) bond distances ranging from 3.22-3.32 Å. The Tb(1)-Ga(2) bond length is 2.94 Å. Both Tb(1)-Ga(1) bond lengths are 2.98 Å. Both Tb(1)-Ge(1) bond lengths are 2.96 Å. Mn(1) is bonded in a 12-coordinate geometry to six equivalent Tb(1), two equivalent Mn(1), one Ga(1), two equivalent Ga(2), and one Ge(1) atom. Both Mn(1)-Mn(1) bond lengths are 2.86 Å. The Mn(1)-Ga(1) bond length is 2.78 Å. Both Mn(1)-Ga(2) bond lengths are 2.66 Å. The Mn(1)-Ge(1) bond length is 2.75 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 9-coordinate geometry to six equivalent Tb(1) and three equivalent Mn(1) atoms. In the second Ga site, Ga(2) is bonded in a distorted q6 geometry to three equivalent Tb(1) and six equivalent Mn(1) atoms. Ge(1) is bonded in a 9-coordinate geometry to six equivalent Tb(1) and three equivalent Mn(1) atoms.