PtO3Cl4O2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four PtO3Cl4 clusters. In each PtO3Cl4 cluster, Pt(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one O(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom.
PtO3Cl4O2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and four PtO3Cl4 clusters. In each PtO3Cl4 cluster, Pt(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Pt(1)-O(1) bond length is 2.69 Å. The Pt(1)-O(2) bond length is 1.83 Å. The Pt(1)-Cl(1) bond length is 2.33 Å. The Pt(1)-Cl(2) bond length is 2.34 Å. The Pt(1)-Cl(3) bond length is 2.32 Å. The Pt(1)-Cl(4) bond length is 2.27 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(5) atom. The O(1)-O(5) bond length is 1.22 Å. In the second O site, O(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one O(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom.