B(Sn)3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-42-8 atoms inside a Sn framework. In the Sn framework, there are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to four equivalent Sn(2) atoms to form a mixture of corner and edge-sharing SnSn4 tetrahedra. In the second Sn site, Sn(2) is bonded in a body-centered cubic geometry to eight equivalent Sn(1) atoms.
B(Sn)3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure consists of four 7440-42-8 atoms inside a Sn framework. In the Sn framework, there are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to four equivalent Sn(2) atoms to form a mixture of corner and edge-sharing SnSn4 tetrahedra. All Sn(1)-Sn(2) bond lengths are 3.11 Å. In the second Sn site, Sn(2) is bonded in a body-centered cubic geometry to eight equivalent Sn(1) atoms.