Rb3Sc(HO)6 crystallizes in the trigonal R-3c space group. Rb(1) is bonded in a 12-coordinate geometry to four equivalent H(1) and eight equivalent O(1) atoms. Sc(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. H(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1), one Sc(1), and one H(1) atom.
Rb3Sc(HO)6 crystallizes in the trigonal R-3c space group. Rb(1) is bonded in a 12-coordinate geometry to four equivalent H(1) and eight equivalent O(1) atoms. There are two shorter (3.00 Å) and two longer (3.08 Å) Rb(1)-H(1) bond lengths. There are a spread of Rb(1)-O(1) bond distances ranging from 2.88-3.22 Å. Sc(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Sc(1)-O(1) bond lengths are 2.16 Å. H(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one O(1) atom. The H(1)-O(1) bond length is 0.97 Å. O(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1), one Sc(1), and one H(1) atom.