NaCo(NO2)6N2 crystallizes in the cubic Fm-3 space group. The structure consists of eight ammonia atoms inside a NaCo(NO2)6 framework. In the NaCo(NO2)6 framework, Na(1) is bonded in a cuboctahedral geometry to twelve equivalent O(1) atoms. Co(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one Na(1) and one N(1) atom.
NaCo(NO2)6N2 crystallizes in the cubic Fm-3 space group. The structure consists of eight ammonia atoms inside a NaCo(NO2)6 framework. In the NaCo(NO2)6 framework, Na(1) is bonded in a cuboctahedral geometry to twelve equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.79 Å. Co(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Co(1)-N(1) bond lengths are 2.04 Å. N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.23 Å. O(1) is bonded in a distorted single-bond geometry to one Na(1) and one N(1) atom.