Pd6B(Pd5B)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pd5B clusters and four Pd6B clusters. In each Pd5B cluster, there are five inequivalent Pd sites. In the first Pd site, Pd(7) is bonded in an L-shaped geometry to two equivalent B(2) atoms. In the second Pd site, Pd(8) is bonded in a single-bond geometry to one B(2) atom. In the third Pd site, Pd(9) is bonded in a single-bond geometry to one B(2) atom. In the fourth Pd site, Pd(3) is bonded in a single-bond geometry to one B(2) atom. In the fifth Pd site, Pd(5) is bonded in a single-bond geometry to one B(2) atom. B(2) is bonded to one Pd(3), one Pd(5), one Pd(8), one Pd(9), and two equivalent Pd(7) atoms to form edge-sharing BPd6 octahedra. In each Pd6B cluster, there are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one B(1) atom. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one B(1) atom. In the third Pd site, Pd(4) is bonded in a single-bond geometry to one B(1) atom. In the fourth Pd site, Pd(6) is bonded in a single-bond geometry to one B(1) atom. B(1) is bonded in an octahedral geometry to one Pd(1), one Pd(2), two equivalent Pd(4), and two equivalent Pd(6) atoms.
Pd6B(Pd5B)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pd5B clusters and four Pd6B clusters. In each Pd5B cluster, there are five inequivalent Pd sites. In the first Pd site, Pd(7) is bonded in an L-shaped geometry to two equivalent B(2) atoms. There is one shorter (2.11 Å) and one longer (2.12 Å) Pd(7)-B(2) bond length. In the second Pd site, Pd(8) is bonded in a single-bond geometry to one B(2) atom. The Pd(8)-B(2) bond length is 2.04 Å. In the third Pd site, Pd(9) is bonded in a single-bond geometry to one B(2) atom. The Pd(9)-B(2) bond length is 2.06 Å. In the fourth Pd site, Pd(3) is bonded in a single-bond geometry to one B(2) atom. The Pd(3)-B(2) bond length is 2.04 Å. In the fifth Pd site, Pd(5) is bonded in a single-bond geometry to one B(2) atom. The Pd(5)-B(2) bond length is 2.06 Å. B(2) is bonded to one Pd(3), one Pd(5), one Pd(8), one Pd(9), and two equivalent Pd(7) atoms to form edge-sharing BPd6 octahedra. In each Pd6B cluster, there are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one B(1) atom. The Pd(1)-B(1) bond length is 2.07 Å. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one B(1) atom. The Pd(2)-B(1) bond length is 2.06 Å. In the third Pd site, Pd(4) is bonded in a single-bond geometry to one B(1) atom. The Pd(4)-B(1) bond length is 2.07 Å. In the fourth Pd site, Pd(6) is bonded in a single-bond geometry to one B(1) atom. The Pd(6)-B(1) bond length is 2.06 Å. B(1) is bonded in an octahedral geometry to one Pd(1), one Pd(2), two equivalent Pd(4), and two equivalent Pd(6) atoms.