Cs2CoAgF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Co(1)F6 octahedra, and faces with four equivalent Ag(1)F6 octahedra. Co(1) is bonded to six equivalent F(1) atoms to form CoF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Co(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Co(1), and one Ag(1) atom.
Cs2CoAgF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Co(1)F6 octahedra, and faces with four equivalent Ag(1)F6 octahedra. All Cs(1)-F(1) bond lengths are 3.17 Å. Co(1) is bonded to six equivalent F(1) atoms to form CoF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Co(1)-F(1) bond lengths are 1.97 Å. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Co(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ag(1)-F(1) bond lengths are 2.50 Å. F(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Co(1), and one Ag(1) atom.