Pt(NO)2NO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitrous acid molecules and one Pt(NO)2 cluster. In the Pt(NO)2 cluster, Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), and two equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Pt(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom.
Pt(NO)2NO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitrous acid molecules and one Pt(NO)2 cluster. In the Pt(NO)2 cluster, Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), and two equivalent O(1) atoms. The Pt(1)-N(1) bond length is 1.78 Å. The Pt(1)-N(2) bond length is 2.00 Å. There is one shorter (1.95 Å) and one longer (2.03 Å) Pt(1)-O(1) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(2) atom. The N(2)-O(2) bond length is 1.19 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Pt(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom.