KNiN crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. Ni(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. N(1) is bonded in a 7-coordinate geometry to four equivalent K(1) and three equivalent Ni(1) atoms.
KNiN crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. There are a spread of K(1)-N(1) bond distances ranging from 2.86-3.09 Å. Ni(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. There are two shorter (1.80 Å) and one longer (2.05 Å) Ni(1)-N(1) bond length. N(1) is bonded in a 7-coordinate geometry to four equivalent K(1) and three equivalent Ni(1) atoms.