PbO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbcn space group. Pb(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. O(1) is bonded in a trigonal planar geometry to three equivalent Pb(1) atoms.
PbO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pbcn space group. Pb(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing PbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. There are a spread of Pb(1)-O(1) bond distances ranging from 2.14-2.24 Å. O(1) is bonded in a trigonal planar geometry to three equivalent Pb(1) atoms.