ZrMnF7Tl crystallizes in the orthorhombic Cmcm space group. The structure consists of four 7440-28-0 atoms inside a ZrMnF7 framework. In the ZrMnF7 framework, Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Mn(1)F7 pentagonal bipyramids and edges with two equivalent Mn(1)F7 pentagonal bipyramids. Mn(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. There are four inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Zr(1) and one Mn(1) atom. In the second F site, F(2) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Zr(1) and one Mn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom.
ZrMnF7Tl crystallizes in the orthorhombic Cmcm space group. The structure consists of four 7440-28-0 atoms inside a ZrMnF7 framework. In the ZrMnF7 framework, Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Mn(1)F7 pentagonal bipyramids and edges with two equivalent Mn(1)F7 pentagonal bipyramids. The Zr(1)-F(4) bond length is 2.07 Å. Both Zr(1)-F(1) bond lengths are 2.12 Å. Both Zr(1)-F(2) bond lengths are 2.06 Å. Both Zr(1)-F(3) bond lengths are 2.10 Å. Mn(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form MnF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. The Mn(1)-F(4) bond length is 2.19 Å. Both Mn(1)-F(1) bond lengths are 2.30 Å. Both Mn(1)-F(2) bond lengths are 2.15 Å. Both Mn(1)-F(3) bond lengths are 2.21 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Zr(1) and one Mn(1) atom. In the second F site, F(2) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Zr(1) and one Mn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Mn(1) atom.