PbCl4 is Silicon tetrafluoride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two lead tetrachloride molecules. Pb(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pb(1) atom.
PbCl4 is Silicon tetrafluoride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two lead tetrachloride molecules. Pb(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Pb(1)-Cl(1) bond length is 2.40 Å. The Pb(1)-Cl(2) bond length is 2.40 Å. The Pb(1)-Cl(3) bond length is 2.40 Å. The Pb(1)-Cl(4) bond length is 2.40 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pb(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pb(1) atom.