TiRhGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Rh(2), two equivalent Ge(1), and four equivalent Ge(2) atoms. In the second Ti site, Ti(2) is bonded in a 9-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. In the third Ti site, Ti(3) is bonded in a 11-coordinate geometry to two equivalent Rh(1), four equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to two equivalent Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to one Ti(1), one Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Rh(1), and four equivalent Rh(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Rh(1), and two equivalent Rh(2) atoms.
TiRhGe crystallizes in the orthorhombic Ima2 space group. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 7-coordinate geometry to two equivalent Rh(2), two equivalent Ge(1), and four equivalent Ge(2) atoms. Both Ti(1)-Rh(2) bond lengths are 2.82 Å. There is one shorter (2.68 Å) and one longer (3.20 Å) Ti(1)-Ge(1) bond length. There are two shorter (2.64 Å) and two longer (2.67 Å) Ti(1)-Ge(2) bond lengths. In the second Ti site, Ti(2) is bonded in a 9-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. Both Ti(2)-Rh(1) bond lengths are 2.78 Å. Both Ti(2)-Rh(2) bond lengths are 2.80 Å. The Ti(2)-Ge(1) bond length is 2.78 Å. There are two shorter (2.65 Å) and two longer (2.69 Å) Ti(2)-Ge(2) bond lengths. In the third Ti site, Ti(3) is bonded in a 11-coordinate geometry to two equivalent Rh(1), four equivalent Rh(2), one Ge(1), and four equivalent Ge(2) atoms. Both Ti(3)-Rh(1) bond lengths are 2.86 Å. There are two shorter (2.74 Å) and two longer (2.77 Å) Ti(3)-Rh(2) bond lengths. The Ti(3)-Ge(1) bond length is 2.94 Å. There are two shorter (2.67 Å) and two longer (2.69 Å) Ti(3)-Ge(2) bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to two equivalent Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. Both Rh(1)-Ge(1) bond lengths are 2.53 Å. Both Rh(1)-Ge(2) bond lengths are 2.49 Å. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to one Ti(1), one Ti(2), two equivalent Ti(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There is one shorter (2.48 Å) and one longer (2.51 Å) Rh(2)-Ge(1) bond length. There is one shorter (2.50 Å) and one longer (2.51 Å) Rh(2)-Ge(2) bond length. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Ti(2), one Ti(3), two equivalent Ti(1), two equivalent Rh(1), and four equivalent Rh(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Ti(1), two equivalent Ti(2), two equivalent Ti(3), one Rh(1), and two equivalent Rh(2) atoms.