Mn2Sb is half-Heusler-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to four equivalent Mn(2) and four equivalent Sb(1) atoms. In the second Mn site, Mn(2) is bonded in a distorted q6 geometry to four equivalent Mn(1) and six equivalent Sb(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to four equivalent Mn(1) and six equivalent Mn(2) atoms.
Mn2Sb is half-Heusler-derived structured and crystallizes in the cubic F-43m space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to four equivalent Mn(2) and four equivalent Sb(1) atoms. All Mn(1)-Mn(2) bond lengths are 2.60 Å. All Mn(1)-Sb(1) bond lengths are 2.60 Å. In the second Mn site, Mn(2) is bonded in a distorted q6 geometry to four equivalent Mn(1) and six equivalent Sb(1) atoms. All Mn(2)-Sb(1) bond lengths are 3.00 Å. Sb(1) is bonded in a 10-coordinate geometry to four equivalent Mn(1) and six equivalent Mn(2) atoms.