Cs2WO2F4 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 12-coordinate geometry to four equivalent O(1) and eight equivalent F(1) atoms. W(1) is bonded in an octahedral geometry to two equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one W(1) atom. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one W(1) atom.
Cs2WO2F4 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 12-coordinate geometry to four equivalent O(1) and eight equivalent F(1) atoms. There are a spread of Cs(1)-O(1) bond distances ranging from 3.17-3.24 Å. There are a spread of Cs(1)-F(1) bond distances ranging from 3.16-3.35 Å. W(1) is bonded in an octahedral geometry to two equivalent O(1) and four equivalent F(1) atoms. Both W(1)-O(1) bond lengths are 1.82 Å. All W(1)-F(1) bond lengths are 1.94 Å. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one W(1) atom. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one W(1) atom.