ReNClF5 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two ReNClF5 clusters. Re(1) is bonded in an octahedral geometry to one N(1), one F(2), two equivalent F(1), and two equivalent F(3) atoms. N(1) is bonded in a linear geometry to one Re(1) and one Cl(1) atom. Cl(1) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom.
ReNClF5 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two ReNClF5 clusters. Re(1) is bonded in an octahedral geometry to one N(1), one F(2), two equivalent F(1), and two equivalent F(3) atoms. The Re(1)-N(1) bond length is 1.75 Å. The Re(1)-F(2) bond length is 1.94 Å. Both Re(1)-F(1) bond lengths are 1.88 Å. Both Re(1)-F(3) bond lengths are 1.89 Å. N(1) is bonded in a linear geometry to one Re(1) and one Cl(1) atom. The N(1)-Cl(1) bond length is 1.57 Å. Cl(1) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom.