RhN5Cl(NO3)2 is Fluorite structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of four nitric acid molecules and two RhN5Cl clusters. In each RhN5Cl cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), four equivalent N(2), and one Cl(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. Cl(1) is bonded in a single-bond geometry to one Rh(1) atom.
RhN5Cl(NO3)2 is Fluorite structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of four nitric acid molecules and two RhN5Cl clusters. In each RhN5Cl cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), four equivalent N(2), and one Cl(1) atom. The Rh(1)-N(1) bond length is 1.70 Å. All Rh(1)-N(2) bond lengths are 1.99 Å. The Rh(1)-Cl(1) bond length is 2.57 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. Cl(1) is bonded in a single-bond geometry to one Rh(1) atom.