NdNi2In crystallizes in the orthorhombic Pmma space group. Nd(1) is bonded in a 13-coordinate geometry to three equivalent Ni(2), four equivalent Ni(1), and six equivalent In(1) atoms. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to four equivalent Nd(1), two equivalent Ni(1), four equivalent Ni(2), and two equivalent In(1) atoms to form a mixture of face, corner, and edge-sharing NiNd4In2Ni6 cuboctahedra. In the second Ni site, Ni(2) is bonded in a 9-coordinate geometry to three equivalent Nd(1), four equivalent Ni(1), and two equivalent In(1) atoms. In(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1), two equivalent Ni(1), and two equivalent Ni(2) atoms.
NdNi2In crystallizes in the orthorhombic Pmma space group. Nd(1) is bonded in a 13-coordinate geometry to three equivalent Ni(2), four equivalent Ni(1), and six equivalent In(1) atoms. There is one shorter (2.69 Å) and two longer (2.85 Å) Nd(1)-Ni(2) bond lengths. All Nd(1)-Ni(1) bond lengths are 3.09 Å. There are four shorter (3.32 Å) and two longer (3.41 Å) Nd(1)-In(1) bond lengths. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to four equivalent Nd(1), two equivalent Ni(1), four equivalent Ni(2), and two equivalent In(1) atoms to form a mixture of face, corner, and edge-sharing NiNd4In2Ni6 cuboctahedra. Both Ni(1)-Ni(1) bond lengths are 2.59 Å. All Ni(1)-Ni(2) bond lengths are 2.52 Å. Both Ni(1)-In(1) bond lengths are 2.74 Å. In the second Ni site, Ni(2) is bonded in a 9-coordinate geometry to three equivalent Nd(1), four equivalent Ni(1), and two equivalent In(1) atoms. Both Ni(2)-In(1) bond lengths are 2.62 Å. In(1) is bonded in a 10-coordinate geometry to six equivalent Nd(1), two equivalent Ni(1), and two equivalent Ni(2) atoms.