PtN4HCl3NCl is Indium-derived structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of nine chloramine molecules and nine PtN4HCl3 clusters. In each PtN4HCl3 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(2), one N(4), two equivalent N(1), and one Cl(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Pt(1) and two equivalent Cl(3) atoms. In the third N site, N(4) is bonded in a single-bond geometry to one Pt(1) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent Cl(3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(3) is bonded in a distorted single-bond geometry to one N(2) and one H(1) atom.
PtN4HCl3NCl is Indium-derived structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of nine chloramine molecules and nine PtN4HCl3 clusters. In each PtN4HCl3 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(2), one N(4), two equivalent N(1), and one Cl(2) atom. The Pt(1)-N(2) bond length is 2.16 Å. The Pt(1)-N(4) bond length is 1.82 Å. Both Pt(1)-N(1) bond lengths are 1.81 Å. The Pt(1)-Cl(2) bond length is 2.37 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Pt(1) and two equivalent Cl(3) atoms. Both N(2)-Cl(3) bond lengths are 1.87 Å. In the third N site, N(4) is bonded in a single-bond geometry to one Pt(1) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent Cl(3) atoms. Both H(1)-Cl(3) bond lengths are 1.58 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(3) is bonded in a distorted single-bond geometry to one N(2) and one H(1) atom.