CrN5ClPtBr4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four platinum(iv) bromide molecules and four CrN5Cl clusters. In each CrN5Cl cluster, Cr(1) is bonded in a 4-coordinate geometry to one N(3), two equivalent N(1), two equivalent N(2), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(3) is bonded in a T-shaped geometry to one Cr(1) and two equivalent N(1) atoms. In the third N site, N(1) is bonded in a 2-coordinate geometry to one Cr(1) and one N(3) atom. Cl(1) is bonded in a single-bond geometry to one Cr(1) atom.
CrN5ClPtBr4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four platinum(iv) bromide molecules and four CrN5Cl clusters. In each CrN5Cl cluster, Cr(1) is bonded in a 4-coordinate geometry to one N(3), two equivalent N(1), two equivalent N(2), and one Cl(1) atom. The Cr(1)-N(3) bond length is 2.19 Å. Both Cr(1)-N(1) bond lengths are 2.48 Å. Both Cr(1)-N(2) bond lengths are 1.62 Å. The Cr(1)-Cl(1) bond length is 2.15 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(3) is bonded in a T-shaped geometry to one Cr(1) and two equivalent N(1) atoms. Both N(3)-N(1) bond lengths are 1.21 Å. In the third N site, N(1) is bonded in a 2-coordinate geometry to one Cr(1) and one N(3) atom. Cl(1) is bonded in a single-bond geometry to one Cr(1) atom.