Ag2F3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ag(1) is bonded to six equivalent F(1) atoms to form a mixture of face, corner, and edge-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. F(1) is bonded to four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FAg4 trigonal pyramids.
Ag2F3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ag(1) is bonded to six equivalent F(1) atoms to form a mixture of face, corner, and edge-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. There are three shorter (2.28 Å) and three longer (2.36 Å) Ag(1)-F(1) bond lengths. F(1) is bonded to four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing FAg4 trigonal pyramids.