XeF4Sb2F11 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Sb2F11 clusters and four XeF4 clusters. In each Sb2F11 cluster, Sb(1) is bonded to one F(2), one F(3), one F(4), one F(5), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedra are not tilted. There are six inequivalent F sites. In the first F site, F(7) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF4 cluster, Xe(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(6) atoms. There are two inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom.
XeF4Sb2F11 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Sb2F11 clusters and four XeF4 clusters. In each Sb2F11 cluster, Sb(1) is bonded to one F(2), one F(3), one F(4), one F(5), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedra are not tilted. The Sb(1)-F(2) bond length is 1.92 Å. The Sb(1)-F(3) bond length is 1.91 Å. The Sb(1)-F(4) bond length is 1.89 Å. The Sb(1)-F(5) bond length is 1.90 Å. The Sb(1)-F(7) bond length is 2.08 Å. The Sb(1)-F(8) bond length is 1.90 Å. There are six inequivalent F sites. In the first F site, F(7) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF4 cluster, Xe(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(6) atoms. Both Xe(1)-F(1) bond lengths are 2.00 Å. Both Xe(1)-F(6) bond lengths are 2.02 Å. There are two inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom.