ZrBiO4 crystallizes in the tetragonal I4_1/a space group. Zr(1) is bonded in a distorted body-centered cubic geometry to eight equivalent O(1) atoms. Bi(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. O(1) is bonded to two equivalent Zr(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OZr2Bi2 tetrahedra.
ZrBiO4 crystallizes in the tetragonal I4_1/a space group. Zr(1) is bonded in a distorted body-centered cubic geometry to eight equivalent O(1) atoms. There are four shorter (2.10 Å) and four longer (2.48 Å) Zr(1)-O(1) bond lengths. Bi(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. There are four shorter (2.29 Å) and four longer (2.44 Å) Bi(1)-O(1) bond lengths. O(1) is bonded to two equivalent Zr(1) and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OZr2Bi2 tetrahedra.