V6AlGe crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 14-coordinate geometry to ten equivalent V(1), two equivalent Al(1), and two equivalent Ge(1) atoms. Al(1) is bonded to twelve equivalent V(1) atoms to form AlV12 cuboctahedra that share edges with six equivalent Al(1)V12 cuboctahedra and faces with eight equivalent Ge(1)V12 cuboctahedra. Ge(1) is bonded to twelve equivalent V(1) atoms to form GeV12 cuboctahedra that share edges with six equivalent Ge(1)V12 cuboctahedra and faces with eight equivalent Al(1)V12 cuboctahedra.
V6AlGe crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 14-coordinate geometry to ten equivalent V(1), two equivalent Al(1), and two equivalent Ge(1) atoms. There are two shorter (2.38 Å) and eight longer (2.92 Å) V(1)-V(1) bond lengths. Both V(1)-Al(1) bond lengths are 2.66 Å. Both V(1)-Ge(1) bond lengths are 2.66 Å. Al(1) is bonded to twelve equivalent V(1) atoms to form AlV12 cuboctahedra that share edges with six equivalent Al(1)V12 cuboctahedra and faces with eight equivalent Ge(1)V12 cuboctahedra. Ge(1) is bonded to twelve equivalent V(1) atoms to form GeV12 cuboctahedra that share edges with six equivalent Ge(1)V12 cuboctahedra and faces with eight equivalent Al(1)V12 cuboctahedra.