LiMnP3HO10 crystallizes in the monoclinic C2/c space group. The structure consists of four 7439-93-2 atoms inside a MnP3HO10 framework. In the MnP3HO10 framework, Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 35-49°. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 52°. H(1) is bonded in a linear geometry to two equivalent O(4) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(2) atom.
LiMnP3HO10 crystallizes in the monoclinic C2/c space group. The structure consists of four 7439-93-2 atoms inside a MnP3HO10 framework. In the MnP3HO10 framework, Mn(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. Both Mn(1)-O(2) bond lengths are 1.94 Å. Both Mn(1)-O(3) bond lengths are 1.98 Å. Both Mn(1)-O(5) bond lengths are 2.14 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 35-49°. The P(1)-O(1) bond length is 1.61 Å. The P(1)-O(2) bond length is 1.54 Å. The P(1)-O(3) bond length is 1.52 Å. The P(1)-O(4) bond length is 1.54 Å. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 52°. Both P(2)-O(1) bond lengths are 1.61 Å. Both P(2)-O(5) bond lengths are 1.50 Å. H(1) is bonded in a linear geometry to two equivalent O(4) atoms. Both H(1)-O(4) bond lengths are 1.22 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(2) atom.