BiNCa3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ca(1) is bonded in a linear geometry to four equivalent Bi(1) and two equivalent N(1) atoms. Bi(1) is bonded to twelve equivalent Ca(1) atoms to form BiCa12 cuboctahedra that share corners with twelve equivalent Bi(1)Ca12 cuboctahedra, faces with six equivalent Bi(1)Ca12 cuboctahedra, and faces with eight equivalent N(1)Ca6 octahedra. N(1) is bonded to six equivalent Ca(1) atoms to form NCa6 octahedra that share corners with six equivalent N(1)Ca6 octahedra and faces with eight equivalent Bi(1)Ca12 cuboctahedra. The corner-sharing octahedra are not tilted.
BiNCa3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ca(1) is bonded in a linear geometry to four equivalent Bi(1) and two equivalent N(1) atoms. All Ca(1)-Bi(1) bond lengths are 3.47 Å. Both Ca(1)-N(1) bond lengths are 2.45 Å. Bi(1) is bonded to twelve equivalent Ca(1) atoms to form BiCa12 cuboctahedra that share corners with twelve equivalent Bi(1)Ca12 cuboctahedra, faces with six equivalent Bi(1)Ca12 cuboctahedra, and faces with eight equivalent N(1)Ca6 octahedra. N(1) is bonded to six equivalent Ca(1) atoms to form NCa6 octahedra that share corners with six equivalent N(1)Ca6 octahedra and faces with eight equivalent Bi(1)Ca12 cuboctahedra. The corner-sharing octahedra are not tilted.