PrWO5 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Pr(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Pr(1) and one W(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Pr(1) and one W(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Pr(1) and one W(1) atom.
PrWO5 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. The Pr(1)-O(4) bond length is 2.41 Å. The Pr(1)-O(5) bond length is 2.38 Å. There is one shorter (2.46 Å) and one longer (2.60 Å) Pr(1)-O(1) bond length. There is one shorter (2.52 Å) and one longer (2.62 Å) Pr(1)-O(2) bond length. There is one shorter (2.46 Å) and one longer (2.57 Å) Pr(1)-O(3) bond length. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The W(1)-O(1) bond length is 2.08 Å. The W(1)-O(2) bond length is 1.95 Å. The W(1)-O(3) bond length is 1.86 Å. The W(1)-O(4) bond length is 1.80 Å. The W(1)-O(5) bond length is 1.82 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Pr(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Pr(1) and one W(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Pr(1) and one W(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Pr(1) and one W(1) atom.