Rh6BSn4 crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded in a 1-coordinate geometry to one B(1), one Sn(1), one Sn(2), and three equivalent Sn(3) atoms. B(1) is bonded in an octahedral geometry to six equivalent Rh(1) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. In the second Sn site, Sn(2) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. In the third Sn site, Sn(3) is bonded in a distorted q6 geometry to nine equivalent Rh(1) atoms.
Rh6BSn4 crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded in a 1-coordinate geometry to one B(1), one Sn(1), one Sn(2), and three equivalent Sn(3) atoms. The Rh(1)-B(1) bond length is 2.08 Å. The Rh(1)-Sn(1) bond length is 2.70 Å. The Rh(1)-Sn(2) bond length is 2.69 Å. There are two shorter (2.82 Å) and one longer (2.84 Å) Rh(1)-Sn(3) bond length. B(1) is bonded in an octahedral geometry to six equivalent Rh(1) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. In the second Sn site, Sn(2) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. In the third Sn site, Sn(3) is bonded in a distorted q6 geometry to nine equivalent Rh(1) atoms.