FeCl4N2S3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four N2S3Cl clusters. In each N2S3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(1) and one Cl(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one N(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom.
FeCl4N2S3Cl is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four N2S3Cl clusters. In each N2S3Cl cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. The N(1)-S(1) bond length is 1.58 Å. The N(1)-S(3) bond length is 1.63 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(2)-S(2) bond length is 1.59 Å. The N(2)-S(3) bond length is 1.57 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(1) and one Cl(1) atom. The S(1)-Cl(1) bond length is 2.12 Å. In the second S site, S(2) is bonded in a single-bond geometry to one N(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one S(1) atom.