KTlCl3 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlCl3 framework. In the TlCl3 framework, there are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to six equivalent Cl(1) atoms to form corner-sharing TlCl6 octahedra. The corner-sharing octahedra are not tilted. In the second Tl site, Tl(2) is bonded to six equivalent Cl(1) atoms to form corner-sharing TlCl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Tl(1) and one Tl(2) atom.
KTlCl3 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlCl3 framework. In the TlCl3 framework, there are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded to six equivalent Cl(1) atoms to form corner-sharing TlCl6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Cl(1) bond lengths are 2.98 Å. In the second Tl site, Tl(2) is bonded to six equivalent Cl(1) atoms to form corner-sharing TlCl6 octahedra. The corner-sharing octahedra are not tilted. All Tl(2)-Cl(1) bond lengths are 2.63 Å. Cl(1) is bonded in a linear geometry to one Tl(1) and one Tl(2) atom.