ZnOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Pnma space group. Zn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing ZnO3F3 octahedra. The corner-sharing octahedral tilt angles are 55°. O(1) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Zn(1) atoms.
ZnOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Pnma space group. Zn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing ZnO3F3 octahedra. The corner-sharing octahedral tilt angles are 55°. There is one shorter (2.01 Å) and two longer (2.02 Å) Zn(1)-O(1) bond lengths. There is one shorter (2.11 Å) and two longer (2.13 Å) Zn(1)-F(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Zn(1) atoms.