W3Re crystallizes in the orthorhombic Cmmm space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent W(2) and two equivalent Re(1) atoms. In the second W site, W(2) is bonded in a distorted body-centered cubic geometry to four equivalent W(1) and four equivalent W(2) atoms. Re(1) is bonded in a 4-coordinate geometry to four equivalent W(1) atoms.
W3Re crystallizes in the orthorhombic Cmmm space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent W(2) and two equivalent Re(1) atoms. Both W(1)-W(2) bond lengths are 2.75 Å. Both W(1)-Re(1) bond lengths are 2.74 Å. In the second W site, W(2) is bonded in a distorted body-centered cubic geometry to four equivalent W(1) and four equivalent W(2) atoms. All W(2)-W(2) bond lengths are 2.74 Å. Re(1) is bonded in a 4-coordinate geometry to four equivalent W(1) atoms.