V2OF5 crystallizes in the trigonal P3_221 space group. V(1) is bonded to one O(1), one F(3), two equivalent F(1), and two equivalent F(2) atoms to form corner-sharing VOF5 octahedra. The corner-sharing octahedral tilt angles range from 22-32°. O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.
V2OF5 crystallizes in the trigonal P3_221 space group. V(1) is bonded to one O(1), one F(3), two equivalent F(1), and two equivalent F(2) atoms to form corner-sharing VOF5 octahedra. The corner-sharing octahedral tilt angles range from 22-32°. The V(1)-O(1) bond length is 1.80 Å. The V(1)-F(3) bond length is 1.97 Å. There is one shorter (1.95 Å) and one longer (2.00 Å) V(1)-F(1) bond length. There is one shorter (1.99 Å) and one longer (2.00 Å) V(1)-F(2) bond length. O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms.