InOF crystallizes in the orthorhombic Fddd space group. In(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing InO4F2 pentagonal pyramids. O(1) is bonded to four equivalent In(1) atoms to form a mixture of corner and edge-sharing OIn4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent In(1) atoms.
InOF crystallizes in the orthorhombic Fddd space group. In(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing InO4F2 pentagonal pyramids. There are two shorter (2.15 Å) and two longer (2.19 Å) In(1)-O(1) bond lengths. Both In(1)-F(1) bond lengths are 2.14 Å. O(1) is bonded to four equivalent In(1) atoms to form a mixture of corner and edge-sharing OIn4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent In(1) atoms.