CeCuCd crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 11-coordinate geometry to one Cu(2), four equivalent Cu(1), and six equivalent Cd(1) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(2) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Cd(1) atoms. In the second Cu site, Cu(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Cd(1) atoms. Cd(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Cu(1), and two equivalent Cu(2) atoms.
CeCuCd crystallizes in the hexagonal P-62m space group. Ce(1) is bonded in a 11-coordinate geometry to one Cu(2), four equivalent Cu(1), and six equivalent Cd(1) atoms. The Ce(1)-Cu(2) bond length is 3.09 Å. All Ce(1)-Cu(1) bond lengths are 3.05 Å. There are two shorter (3.26 Å) and four longer (3.38 Å) Ce(1)-Cd(1) bond lengths. There are two inequivalent Cu sites. In the first Cu site, Cu(2) is bonded in a 9-coordinate geometry to three equivalent Ce(1) and six equivalent Cd(1) atoms. All Cu(2)-Cd(1) bond lengths are 2.77 Å. In the second Cu site, Cu(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Cd(1) atoms. All Cu(1)-Cd(1) bond lengths are 2.87 Å. Cd(1) is bonded in a 10-coordinate geometry to six equivalent Ce(1), two equivalent Cu(1), and two equivalent Cu(2) atoms.