Cs2PdF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Pd(1)F6 octahedra. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Pd(1) atom.
Cs2PdF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Pd(1)F6 octahedra. All Cs(1)-F(1) bond lengths are 3.18 Å. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. All Pd(1)-F(1) bond lengths are 1.92 Å. F(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Pd(1) atom.