Mn2SbN3 crystallizes in the orthorhombic Cmc2_1 space group. Mn(1) is bonded to one N(2) and three equivalent N(1) atoms to form distorted corner-sharing MnN4 tetrahedra. Sb(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Sb(1) atoms to form corner-sharing NMn2Sb2 trigonal pyramids.
Mn2SbN3 crystallizes in the orthorhombic Cmc2_1 space group. Mn(1) is bonded to one N(2) and three equivalent N(1) atoms to form distorted corner-sharing MnN4 tetrahedra. The Mn(1)-N(2) bond length is 2.02 Å. There are a spread of Mn(1)-N(1) bond distances ranging from 1.76-1.87 Å. Sb(1) is bonded in a distorted bent 120 degrees geometry to two equivalent N(2) atoms. There is one shorter (2.20 Å) and one longer (2.24 Å) Sb(1)-N(2) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Sb(1) atoms to form corner-sharing NMn2Sb2 trigonal pyramids.