YMo(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. In the second W site, W(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. Mo(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(5), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a trigonal pyramidal geometry to one Y(1), one W(1), one W(2), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(2) and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Y(1), one W(1), and one W(2) atom.
YMo(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. The Y(1)-O(1) bond length is 2.32 Å. The Y(1)-O(2) bond length is 2.25 Å. The Y(1)-O(3) bond length is 2.52 Å. The Y(1)-O(4) bond length is 2.32 Å. The Y(1)-O(6) bond length is 2.28 Å. The Y(1)-O(8) bond length is 2.26 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. The W(1)-O(1) bond length is 1.84 Å. The W(1)-O(2) bond length is 1.98 Å. The W(1)-O(3) bond length is 2.16 Å. The W(1)-O(4) bond length is 2.18 Å. The W(1)-O(7) bond length is 1.99 Å. The W(1)-O(8) bond length is 2.09 Å. In the second W site, W(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. The W(2)-O(3) bond length is 2.02 Å. The W(2)-O(4) bond length is 1.96 Å. The W(2)-O(5) bond length is 1.83 Å. The W(2)-O(6) bond length is 1.83 Å. The W(2)-O(7) bond length is 2.17 Å. The W(2)-O(8) bond length is 2.07 Å. Mo(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(5), and one O(7) atom. The Mo(1)-O(2) bond length is 2.21 Å. The Mo(1)-O(3) bond length is 2.21 Å. The Mo(1)-O(5) bond length is 2.23 Å. The Mo(1)-O(7) bond length is 2.15 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a trigonal pyramidal geometry to one Y(1), one W(1), one W(2), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(2) and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Y(1), one W(1), and one W(2) atom.