Ti2Ru2FeRh3B2 crystallizes in the orthorhombic Pbam space group. Ti(1) is bonded in a 13-coordinate geometry to four equivalent Ru(1), two equivalent Rh(2), four equivalent Rh(1), and three equivalent B(1) atoms. Ru(1) is bonded in a 8-coordinate geometry to four equivalent Ti(1), two equivalent Fe(1), and two equivalent B(1) atoms. Fe(1) is bonded in a body-centered cubic geometry to four equivalent Ru(1) and four equivalent Rh(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to four equivalent Ti(1), two equivalent Fe(1), and two equivalent B(1) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent B(1) atoms. B(1) is bonded in a 9-coordinate geometry to three equivalent Ti(1), two equivalent Ru(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.
Ti2Ru2FeRh3B2 crystallizes in the orthorhombic Pbam space group. Ti(1) is bonded in a 13-coordinate geometry to four equivalent Ru(1), two equivalent Rh(2), four equivalent Rh(1), and three equivalent B(1) atoms. There are two shorter (2.74 Å) and two longer (2.91 Å) Ti(1)-Ru(1) bond lengths. Both Ti(1)-Rh(2) bond lengths are 2.75 Å. There are two shorter (2.75 Å) and two longer (2.93 Å) Ti(1)-Rh(1) bond lengths. There are a spread of Ti(1)-B(1) bond distances ranging from 2.54-2.87 Å. Ru(1) is bonded in a 8-coordinate geometry to four equivalent Ti(1), two equivalent Fe(1), and two equivalent B(1) atoms. Both Ru(1)-Fe(1) bond lengths are 2.55 Å. Both Ru(1)-B(1) bond lengths are 2.15 Å. Fe(1) is bonded in a body-centered cubic geometry to four equivalent Ru(1) and four equivalent Rh(1) atoms. All Fe(1)-Rh(1) bond lengths are 2.56 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to four equivalent Ti(1), two equivalent Fe(1), and two equivalent B(1) atoms. Both Rh(1)-B(1) bond lengths are 2.16 Å. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent B(1) atoms. All Rh(2)-B(1) bond lengths are 2.21 Å. B(1) is bonded in a 9-coordinate geometry to three equivalent Ti(1), two equivalent Ru(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.