CeRh2B2C crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a distorted square co-planar geometry to four equivalent C(1) atoms. Rh(1) is bonded in a 4-coordinate geometry to four equivalent B(1) atoms. B(1) is bonded in a distorted single-bond geometry to four equivalent Rh(1) and one C(1) atom. C(1) is bonded in a distorted linear geometry to four equivalent Ce(1) and two equivalent B(1) atoms.
CeRh2B2C crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a distorted square co-planar geometry to four equivalent C(1) atoms. All Ce(1)-C(1) bond lengths are 2.73 Å. Rh(1) is bonded in a 4-coordinate geometry to four equivalent B(1) atoms. All Rh(1)-B(1) bond lengths are 2.20 Å. B(1) is bonded in a distorted single-bond geometry to four equivalent Rh(1) and one C(1) atom. The B(1)-C(1) bond length is 1.50 Å. C(1) is bonded in a distorted linear geometry to four equivalent Ce(1) and two equivalent B(1) atoms.