Ag2TeO6 crystallizes in the triclinic P1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(7), and one O(9) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Ag(3)O5 trigonal bipyramids, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(8) atom. In the third Ag site, Ag(3) is bonded to one O(11), one O(3), one O(4), one O(5), and one O(7) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(1)O6 octahedra, corners with two equivalent Ag(1)O5 trigonal bipyramids, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the fourth Ag site, Ag(4) is bonded in a rectangular see-saw-like geometry to one O(12), one O(3), one O(4), and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Ag(3)O5 trigonal bipyramid and edges with two equivalent Ag(1)O5 trigonal bipyramids. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form TeO6 octahedra that share  a cornercorner with one Ag(1)O5 trigonal bipyramid and edges with two equivalent Ag(3)O5 trigonal bipyramids. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(4) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ag(2) and one Te(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Ag(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Ag(2) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Ag(3) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Ag(4) and one Te(2) atom.
Ag2TeO6 crystallizes in the triclinic P1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(2), one O(5), one O(7), and one O(9) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Ag(3)O5 trigonal bipyramids, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. The Ag(1)-O(1) bond length is 2.05 Å. The Ag(1)-O(2) bond length is 2.20 Å. The Ag(1)-O(5) bond length is 2.30 Å. The Ag(1)-O(7) bond length is 2.34 Å. The Ag(1)-O(9) bond length is 2.01 Å. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(8) atom. The Ag(2)-O(1) bond length is 2.07 Å. The Ag(2)-O(10) bond length is 2.07 Å. The Ag(2)-O(2) bond length is 2.20 Å. The Ag(2)-O(8) bond length is 2.04 Å. In the third Ag site, Ag(3) is bonded to one O(11), one O(3), one O(4), one O(5), and one O(7) atom to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one Te(1)O6 octahedra, corners with two equivalent Ag(1)O5 trigonal bipyramids, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. The Ag(3)-O(11) bond length is 2.01 Å. The Ag(3)-O(3) bond length is 2.05 Å. The Ag(3)-O(4) bond length is 2.21 Å. The Ag(3)-O(5) bond length is 2.34 Å. The Ag(3)-O(7) bond length is 2.30 Å. In the fourth Ag site, Ag(4) is bonded in a rectangular see-saw-like geometry to one O(12), one O(3), one O(4), and one O(6) atom. The Ag(4)-O(12) bond length is 2.07 Å. The Ag(4)-O(3) bond length is 2.07 Å. The Ag(4)-O(4) bond length is 2.19 Å. The Ag(4)-O(6) bond length is 2.04 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Ag(3)O5 trigonal bipyramid and edges with two equivalent Ag(1)O5 trigonal bipyramids. The Te(1)-O(1) bond length is 2.09 Å. The Te(1)-O(10) bond length is 1.95 Å. The Te(1)-O(2) bond length is 2.01 Å. The Te(1)-O(5) bond length is 1.95 Å. The Te(1)-O(6) bond length is 1.93 Å. The Te(1)-O(9) bond length is 1.96 Å. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form TeO6 octahedra that share  a cornercorner with one Ag(1)O5 trigonal bipyramid and edges with two equivalent Ag(3)O5 trigonal bipyramids. The Te(2)-O(11) bond length is 1.96 Å. The Te(2)-O(12) bond length is 1.95 Å. The Te(2)-O(3) bond length is 2.09 Å. The Te(2)-O(4) bond length is 2.01 Å. The Te(2)-O(7) bond length is 1.95 Å. The Te(2)-O(8) bond length is 1.93 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Ag(3), one Ag(4), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(4) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Te(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ag(2) and one Te(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Ag(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Ag(2) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Ag(3) and one Te(2) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Ag(4) and one Te(2) atom.