ScAgS2 is Ilmenite-like structured and crystallizes in the trigonal R3m space group. Sc(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing ScS6 octahedra. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1) and three equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Sc(1) and one Ag(1) atom to form distorted corner-sharing SSc3Ag trigonal pyramids. In the second S site, S(2) is bonded in a 6-coordinate geometry to three equivalent Sc(1) and three equivalent Ag(1) atoms.
ScAgS2 is Ilmenite-like structured and crystallizes in the trigonal R3m space group. Sc(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing ScS6 octahedra. All Sc(1)-S(1) bond lengths are 2.55 Å. All Sc(1)-S(2) bond lengths are 2.64 Å. Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1) and three equivalent S(2) atoms. The Ag(1)-S(1) bond length is 2.42 Å. All Ag(1)-S(2) bond lengths are 2.68 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Sc(1) and one Ag(1) atom to form distorted corner-sharing SSc3Ag trigonal pyramids. In the second S site, S(2) is bonded in a 6-coordinate geometry to three equivalent Sc(1) and three equivalent Ag(1) atoms.