HCOONa is Ullmanite-derived structured and crystallizes in the monoclinic C2/c space group. Na(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing NaO6 pentagonal pyramids. C(1) is bonded in a trigonal planar geometry to one H(1) and two equivalent O(1) atoms. H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a 4-coordinate geometry to three equivalent Na(1) and one C(1) atom.
HCOONa is Ullmanite-derived structured and crystallizes in the monoclinic C2/c space group. Na(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted corner and edge-sharing NaO6 pentagonal pyramids. There are a spread of Na(1)-O(1) bond distances ranging from 2.43-2.54 Å. C(1) is bonded in a trigonal planar geometry to one H(1) and two equivalent O(1) atoms. The C(1)-H(1) bond length is 1.11 Å. Both C(1)-O(1) bond lengths are 1.27 Å. H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a 4-coordinate geometry to three equivalent Na(1) and one C(1) atom.