NdPdIn crystallizes in the triclinic P1 space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 10-coordinate geometry to one Pd(2), one Pd(3), two equivalent Pd(1), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to one Pd(2), one Pd(3), two equivalent Pd(1), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. In the third Nd site, Nd(3) is bonded in a 10-coordinate geometry to one Pd(2), one Pd(3), two equivalent Pd(1), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one In(1), one In(2), and one In(3) atom. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Nd(1), one Nd(2), one Nd(3), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to one Nd(1), one Nd(2), one Nd(3), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one Pd(1), two equivalent Pd(2), and two equivalent Pd(3) atoms. In the second In site, In(2) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one Pd(1), two equivalent Pd(2), and two equivalent Pd(3) atoms. In the third In site, In(3) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one Pd(1), two equivalent Pd(2), and two equivalent Pd(3) atoms.
NdPdIn crystallizes in the triclinic P1 space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 10-coordinate geometry to one Pd(2), one Pd(3), two equivalent Pd(1), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. The Nd(1)-Pd(2) bond length is 2.95 Å. The Nd(1)-Pd(3) bond length is 2.94 Å. There is one shorter (2.94 Å) and one longer (3.00 Å) Nd(1)-Pd(1) bond length. There is one shorter (3.37 Å) and one longer (3.40 Å) Nd(1)-In(1) bond length. There is one shorter (3.29 Å) and one longer (3.38 Å) Nd(1)-In(2) bond length. There is one shorter (3.37 Å) and one longer (3.40 Å) Nd(1)-In(3) bond length. In the second Nd site, Nd(2) is bonded in a 10-coordinate geometry to one Pd(2), one Pd(3), two equivalent Pd(1), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. The Nd(2)-Pd(2) bond length is 2.95 Å. The Nd(2)-Pd(3) bond length is 2.93 Å. Both Nd(2)-Pd(1) bond lengths are 2.99 Å. There is one shorter (3.35 Å) and one longer (3.36 Å) Nd(2)-In(1) bond length. There is one shorter (3.35 Å) and one longer (3.42 Å) Nd(2)-In(2) bond length. There is one shorter (3.34 Å) and one longer (3.41 Å) Nd(2)-In(3) bond length. In the third Nd site, Nd(3) is bonded in a 10-coordinate geometry to one Pd(2), one Pd(3), two equivalent Pd(1), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. The Nd(3)-Pd(2) bond length is 2.94 Å. The Nd(3)-Pd(3) bond length is 2.94 Å. There is one shorter (2.96 Å) and one longer (3.01 Å) Nd(3)-Pd(1) bond length. There is one shorter (3.35 Å) and one longer (3.40 Å) Nd(3)-In(1) bond length. There is one shorter (3.36 Å) and one longer (3.39 Å) Nd(3)-In(2) bond length. There is one shorter (3.31 Å) and one longer (3.39 Å) Nd(3)-In(3) bond length. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one In(1), one In(2), and one In(3) atom. The Pd(1)-In(1) bond length is 3.11 Å. The Pd(1)-In(2) bond length is 3.07 Å. The Pd(1)-In(3) bond length is 3.11 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to one Nd(1), one Nd(2), one Nd(3), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. There is one shorter (3.07 Å) and one longer (3.20 Å) Pd(2)-In(1) bond length. Both Pd(2)-In(2) bond lengths are 3.19 Å. There is one shorter (3.17 Å) and one longer (3.22 Å) Pd(2)-In(3) bond length. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to one Nd(1), one Nd(2), one Nd(3), two equivalent In(1), two equivalent In(2), and two equivalent In(3) atoms. There is one shorter (3.15 Å) and one longer (3.25 Å) Pd(3)-In(1) bond length. There is one shorter (3.19 Å) and one longer (3.22 Å) Pd(3)-In(2) bond length. There is one shorter (3.12 Å) and one longer (3.17 Å) Pd(3)-In(3) bond length. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one Pd(1), two equivalent Pd(2), and two equivalent Pd(3) atoms. In the second In site, In(2) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one Pd(1), two equivalent Pd(2), and two equivalent Pd(3) atoms. In the third In site, In(3) is bonded in a 11-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Nd(3), one Pd(1), two equivalent Pd(2), and two equivalent Pd(3) atoms.