NaAuSn crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 11-coordinate geometry to five equivalent Au(1) and six equivalent Sn(1) atoms. Au(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Sn(1) atoms. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Na(1) and four equivalent Au(1) atoms.
NaAuSn crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 11-coordinate geometry to five equivalent Au(1) and six equivalent Sn(1) atoms. There are a spread of Na(1)-Au(1) bond distances ranging from 3.17-3.29 Å. There are a spread of Na(1)-Sn(1) bond distances ranging from 3.28-3.45 Å. Au(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Sn(1) atoms. There are a spread of Au(1)-Sn(1) bond distances ranging from 2.72-2.81 Å. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Na(1) and four equivalent Au(1) atoms.