(Na)2AuAlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a AuAlF6 framework. In the AuAlF6 framework, Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted linear geometry to one Au(1) and one Al(1) atom.
(Na)2AuAlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a AuAlF6 framework. In the AuAlF6 framework, Au(1) is bonded to six equivalent F(1) atoms to form AuF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Au(1)-F(1) bond lengths are 2.43 Å. Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-F(1) bond lengths are 1.82 Å. F(1) is bonded in a distorted linear geometry to one Au(1) and one Al(1) atom.