(Rb)2TlBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a TlBiBr6 framework. In the TlBiBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Tl(1) and one Bi(1) atom.
(Rb)2TlBiBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-17-7 atoms inside a TlBiBr6 framework. In the TlBiBr6 framework, Tl(1) is bonded to six equivalent Br(1) atoms to form TlBr6 octahedra that share corners with six equivalent Bi(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-Br(1) bond lengths are 3.15 Å. Bi(1) is bonded to six equivalent Br(1) atoms to form BiBr6 octahedra that share corners with six equivalent Tl(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-Br(1) bond lengths are 2.87 Å. Br(1) is bonded in a linear geometry to one Tl(1) and one Bi(1) atom.