AsF6OClF2 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four OClF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each OClF2 cluster, O(1) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one F(7), and one F(8) atom. There are two inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Cl(1) atom.
AsF6OClF2 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four OClF2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The As(1)-F(1) bond length is 1.76 Å. The As(1)-F(2) bond length is 1.76 Å. The As(1)-F(3) bond length is 1.75 Å. The As(1)-F(4) bond length is 1.81 Å. The As(1)-F(5) bond length is 1.78 Å. The As(1)-F(6) bond length is 1.80 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each OClF2 cluster, O(1) is bonded in a single-bond geometry to one Cl(1) atom. The O(1)-Cl(1) bond length is 1.39 Å. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1), one F(7), and one F(8) atom. The Cl(1)-F(7) bond length is 1.63 Å. The Cl(1)-F(8) bond length is 1.63 Å. There are two inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Cl(1) atom.