Cs(CrS2)2 is Orthorhombic Perovskite-like structured and crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing CrS6 octahedra. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 5-coordinate geometry to two equivalent Cs(1) and three equivalent Cr(1) atoms. In the second S site, S(1) is bonded in a 3-coordinate geometry to one Cs(1) and three equivalent Cr(1) atoms.
Cs(CrS2)2 is Orthorhombic Perovskite-like structured and crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 6-coordinate geometry to two equivalent S(1) and four equivalent S(2) atoms. Both Cs(1)-S(1) bond lengths are 3.61 Å. All Cs(1)-S(2) bond lengths are 3.39 Å. Cr(1) is bonded to three equivalent S(1) and three equivalent S(2) atoms to form edge-sharing CrS6 octahedra. There is one shorter (2.37 Å) and two longer (2.40 Å) Cr(1)-S(1) bond lengths. There is one shorter (2.39 Å) and two longer (2.42 Å) Cr(1)-S(2) bond lengths. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 5-coordinate geometry to two equivalent Cs(1) and three equivalent Cr(1) atoms. In the second S site, S(1) is bonded in a 3-coordinate geometry to one Cs(1) and three equivalent Cr(1) atoms.