C2SOC2BiSOCl3 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two C2BiSOCl3 clusters and two C2SO clusters. In each C2BiSOCl3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one C(2) and one S(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one Bi(1) atom. Bi(1) is bonded in a 4-coordinate geometry to one C(2), one O(1), one Cl(2), and one Cl(3) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), and one Cl(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Bi(1) and one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Bi(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Bi(1) atom. In each C2SO cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one C(3) and one C(4) atom. In the second C site, C(4) is bonded in a bent 150 degrees geometry to one C(3) and one S(2) atom. S(2) is bonded in a distorted single-bond geometry to one C(4) and one O(2) atom. O(2) is bonded in a single-bond geometry to one S(2) atom.
C2SOC2BiSOCl3 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two C2BiSOCl3 clusters and two C2SO clusters. In each C2BiSOCl3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one C(2) and one S(1) atom. The C(1)-C(2) bond length is 1.24 Å. The C(1)-S(1) bond length is 1.67 Å. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one Bi(1) atom. The C(2)-Bi(1) bond length is 2.50 Å. Bi(1) is bonded in a 4-coordinate geometry to one C(2), one O(1), one Cl(2), and one Cl(3) atom. The Bi(1)-O(1) bond length is 2.39 Å. The Bi(1)-Cl(2) bond length is 2.53 Å. The Bi(1)-Cl(3) bond length is 2.63 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), and one Cl(1) atom. The S(1)-O(1) bond length is 1.52 Å. The S(1)-Cl(1) bond length is 2.19 Å. O(1) is bonded in a bent 120 degrees geometry to one Bi(1) and one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Bi(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Bi(1) atom. In each C2SO cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one C(3) and one C(4) atom. The C(3)-C(3) bond length is 1.30 Å. The C(3)-C(4) bond length is 1.27 Å. In the second C site, C(4) is bonded in a bent 150 degrees geometry to one C(3) and one S(2) atom. The C(4)-S(2) bond length is 1.61 Å. S(2) is bonded in a distorted single-bond geometry to one C(4) and one O(2) atom. The S(2)-O(2) bond length is 1.51 Å. O(2) is bonded in a single-bond geometry to one S(2) atom.