NaPt3O4 crystallizes in the cubic Pm-3n space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Pt(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Na(1) and three equivalent Pt(1) atoms to form a mixture of edge and corner-sharing ONa2Pt3 trigonal bipyramids.
NaPt3O4 crystallizes in the cubic Pm-3n space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.47 Å. Pt(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Pt(1)-O(1) bond lengths are 2.02 Å. O(1) is bonded to two equivalent Na(1) and three equivalent Pt(1) atoms to form a mixture of edge and corner-sharing ONa2Pt3 trigonal bipyramids.