Li3VS4 is Sulvanite structured and crystallizes in the cubic P-43m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded to three equivalent Li(1) and one V(1) atom to form a mixture of corner and edge-sharing SLi3V trigonal pyramids.
Li3VS4 is Sulvanite structured and crystallizes in the cubic P-43m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All Li(1)-S(1) bond lengths are 2.46 Å. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All V(1)-S(1) bond lengths are 2.15 Å. S(1) is bonded to three equivalent Li(1) and one V(1) atom to form a mixture of corner and edge-sharing SLi3V trigonal pyramids.