Zr3Rh crystallizes in the monoclinic C2 space group. There are seven inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a distorted water-like geometry to one Rh(1) and one Rh(3) atom. In the second Zr site, Zr(2) is bonded in a distorted water-like geometry to one Rh(2) and one Rh(3) atom. In the third Zr site, Zr(3) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Rh(3) atoms. In the fourth Zr site, Zr(4) is bonded in a 4-coordinate geometry to two equivalent Rh(2) and two equivalent Rh(3) atoms. In the fifth Zr site, Zr(5) is bonded in a 4-coordinate geometry to one Rh(1), one Rh(2), and two equivalent Rh(3) atoms. In the sixth Zr site, Zr(6) is bonded in a water-like geometry to one Rh(1) and one Rh(3) atom. In the seventh Zr site, Zr(7) is bonded in a water-like geometry to one Rh(2) and one Rh(3) atom. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to two equivalent Zr(1), two equivalent Zr(3), two equivalent Zr(5), and two equivalent Zr(6) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to two equivalent Zr(2), two equivalent Zr(4), two equivalent Zr(5), and two equivalent Zr(7) atoms. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Zr(1), one Zr(2), one Zr(3), one Zr(4), one Zr(6), one Zr(7), and two equivalent Zr(5) atoms.
Zr3Rh crystallizes in the monoclinic C2 space group. There are seven inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a distorted water-like geometry to one Rh(1) and one Rh(3) atom. The Zr(1)-Rh(1) bond length is 2.80 Å. The Zr(1)-Rh(3) bond length is 2.79 Å. In the second Zr site, Zr(2) is bonded in a distorted water-like geometry to one Rh(2) and one Rh(3) atom. The Zr(2)-Rh(2) bond length is 2.80 Å. The Zr(2)-Rh(3) bond length is 2.81 Å. In the third Zr site, Zr(3) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Rh(3) atoms. Both Zr(3)-Rh(1) bond lengths are 2.95 Å. Both Zr(3)-Rh(3) bond lengths are 2.71 Å. In the fourth Zr site, Zr(4) is bonded in a 4-coordinate geometry to two equivalent Rh(2) and two equivalent Rh(3) atoms. Both Zr(4)-Rh(2) bond lengths are 2.95 Å. Both Zr(4)-Rh(3) bond lengths are 2.71 Å. In the fifth Zr site, Zr(5) is bonded in a 4-coordinate geometry to one Rh(1), one Rh(2), and two equivalent Rh(3) atoms. The Zr(5)-Rh(1) bond length is 2.71 Å. The Zr(5)-Rh(2) bond length is 2.71 Å. Both Zr(5)-Rh(3) bond lengths are 2.95 Å. In the sixth Zr site, Zr(6) is bonded in a water-like geometry to one Rh(1) and one Rh(3) atom. The Zr(6)-Rh(1) bond length is 2.78 Å. The Zr(6)-Rh(3) bond length is 2.79 Å. In the seventh Zr site, Zr(7) is bonded in a water-like geometry to one Rh(2) and one Rh(3) atom. The Zr(7)-Rh(2) bond length is 2.79 Å. The Zr(7)-Rh(3) bond length is 2.79 Å. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to two equivalent Zr(1), two equivalent Zr(3), two equivalent Zr(5), and two equivalent Zr(6) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to two equivalent Zr(2), two equivalent Zr(4), two equivalent Zr(5), and two equivalent Zr(7) atoms. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Zr(1), one Zr(2), one Zr(3), one Zr(4), one Zr(6), one Zr(7), and two equivalent Zr(5) atoms.