Sr3BiN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded in a see-saw-like geometry to four equivalent N(1) atoms. Bi(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded to four equivalent Sr(1) and one Bi(1) atom to form a mixture of corner and edge-sharing NSr4Bi trigonal bipyramids.
Sr3BiN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded in a see-saw-like geometry to four equivalent N(1) atoms. There are a spread of Sr(1)-N(1) bond distances ranging from 2.61-2.67 Å. Bi(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All Bi(1)-N(1) bond lengths are 2.27 Å. N(1) is bonded to four equivalent Sr(1) and one Bi(1) atom to form a mixture of corner and edge-sharing NSr4Bi trigonal bipyramids.