KC2PH5S2(NO)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one KC2PH5S2(NO)3 cluster. K(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one O(3) atom. P(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one S(1), and one S(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one P(1), and one H(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(3) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one K(1), one H(4), and one H(5) atom.
KC2PH5S2(NO)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one KC2PH5S2(NO)3 cluster. K(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. The K(1)-O(1) bond length is 2.80 Å. The K(1)-O(2) bond length is 2.78 Å. The K(1)-O(3) bond length is 2.73 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(3) bond length is 1.39 Å. The C(1)-O(1) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one O(3) atom. The C(2)-N(2) bond length is 1.36 Å. The C(2)-N(3) bond length is 1.39 Å. The C(2)-O(3) bond length is 1.25 Å. P(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one S(1), and one S(2) atom. The P(1)-N(1) bond length is 1.72 Å. The P(1)-N(2) bond length is 1.72 Å. The P(1)-S(1) bond length is 1.99 Å. The P(1)-S(2) bond length is 1.97 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(1) atom. The N(1)-H(1) bond length is 1.05 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one P(1), and one H(2) atom. The N(2)-H(2) bond length is 1.04 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(3) atom. The N(3)-H(3) bond length is 1.04 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. The H(5)-O(2) bond length is 0.99 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one K(1), one H(4), and one H(5) atom.