LiVBO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra and corners with four equivalent B(1)O4 tetrahedra. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent B(1)O4 tetrahedra. B(1) is bonded to four equivalent O(1) atoms to form BO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent V(1)O4 tetrahedra. O(1) is bonded in a trigonal non-coplanar geometry to one Li(1), one V(1), and one B(1) atom.
LiVBO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra and corners with four equivalent B(1)O4 tetrahedra. All Li(1)-O(1) bond lengths are 2.08 Å. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent B(1)O4 tetrahedra. All V(1)-O(1) bond lengths are 1.83 Å. B(1) is bonded to four equivalent O(1) atoms to form BO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent V(1)O4 tetrahedra. All B(1)-O(1) bond lengths are 1.48 Å. O(1) is bonded in a trigonal non-coplanar geometry to one Li(1), one V(1), and one B(1) atom.