FeOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. O(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Fe(1) atoms.
FeOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. Fe(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing FeO3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. There is one shorter (1.89 Å) and two longer (1.96 Å) Fe(1)-O(1) bond lengths. There are two shorter (2.06 Å) and one longer (2.28 Å) Fe(1)-F(1) bond length. O(1) is bonded in a trigonal planar geometry to three equivalent Fe(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Fe(1) atoms.