PO3NNO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four PO3N clusters. In each PO3N cluster, P(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. N(2) is bonded in a single-bond geometry to one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom.
PO3NNO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four PO3N clusters. In each PO3N cluster, P(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The P(1)-O(1) bond length is 1.65 Å. The P(1)-O(2) bond length is 1.46 Å. The P(1)-O(3) bond length is 1.47 Å. N(2) is bonded in a single-bond geometry to one O(1) atom. The N(2)-O(1) bond length is 1.33 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom.