NaIO4 is Zircon-like structured and crystallizes in the tetragonal I4_1/a space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one I(1) atom. I(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms.
NaIO4 is Zircon-like structured and crystallizes in the tetragonal I4_1/a space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are four shorter (2.50 Å) and four longer (2.55 Å) Na(1)-O(1) bond lengths. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one I(1) atom. The O(1)-I(1) bond length is 1.78 Å. I(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms.