NaSrVF6 crystallizes in the orthorhombic P2_12_12_1 space group. Na(1) is bonded to one F(2), one F(4), one F(5), one F(6), and two equivalent F(1) atoms to form distorted NaF6 octahedra that share corners with two equivalent Na(1)F6 octahedra, corners with two equivalent V(1)F6 octahedra, and edges with two equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-71°. Sr(1) is bonded in a 7-coordinate geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and two equivalent F(3) atoms. V(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form VF6 octahedra that share corners with two equivalent Na(1)F6 octahedra and edges with two equivalent Na(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one V(1) atom. In the second F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Sr(1), and one V(1) atom. In the third F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one V(1) atom. In the fourth F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Sr(1) and one V(1) atom. In the fifth F site, F(4) is bonded in a distorted trigonal planar geometry to one Na(1), one Sr(1), and one V(1) atom. In the sixth F site, F(5) is bonded in a trigonal planar geometry to one Na(1), one Sr(1), and one V(1) atom.
NaSrVF6 crystallizes in the orthorhombic P2_12_12_1 space group. Na(1) is bonded to one F(2), one F(4), one F(5), one F(6), and two equivalent F(1) atoms to form distorted NaF6 octahedra that share corners with two equivalent Na(1)F6 octahedra, corners with two equivalent V(1)F6 octahedra, and edges with two equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-71°. The Na(1)-F(2) bond length is 2.44 Å. The Na(1)-F(4) bond length is 2.38 Å. The Na(1)-F(5) bond length is 2.25 Å. The Na(1)-F(6) bond length is 2.34 Å. There is one shorter (2.26 Å) and one longer (2.42 Å) Na(1)-F(1) bond length. Sr(1) is bonded in a 7-coordinate geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and two equivalent F(3) atoms. The Sr(1)-F(1) bond length is 2.77 Å. The Sr(1)-F(2) bond length is 2.40 Å. The Sr(1)-F(4) bond length is 2.42 Å. The Sr(1)-F(5) bond length is 2.48 Å. The Sr(1)-F(6) bond length is 2.51 Å. There is one shorter (2.54 Å) and one longer (2.66 Å) Sr(1)-F(3) bond length. V(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form VF6 octahedra that share corners with two equivalent Na(1)F6 octahedra and edges with two equivalent Na(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. The V(1)-F(1) bond length is 2.00 Å. The V(1)-F(2) bond length is 1.98 Å. The V(1)-F(3) bond length is 2.00 Å. The V(1)-F(4) bond length is 1.97 Å. The V(1)-F(5) bond length is 1.96 Å. The V(1)-F(6) bond length is 1.96 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one V(1) atom. In the second F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Sr(1), and one V(1) atom. In the third F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Sr(1), and one V(1) atom. In the fourth F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Sr(1) and one V(1) atom. In the fifth F site, F(4) is bonded in a distorted trigonal planar geometry to one Na(1), one Sr(1), and one V(1) atom. In the sixth F site, F(5) is bonded in a trigonal planar geometry to one Na(1), one Sr(1), and one V(1) atom.