Pb3SbN is Pb (Zr_0.50 Ti_0.48) O_3-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and two equivalent N(1) atoms. In the second Pb site, Pb(1) is bonded in a 2-coordinate geometry to two equivalent Sb(1) and two equivalent N(1) atoms. Sb(1) is bonded in a 5-coordinate geometry to one Pb(2) and four equivalent Pb(1) atoms. N(1) is bonded to two equivalent Pb(2) and four equivalent Pb(1) atoms to form corner-sharing NPb6 octahedra. The corner-sharing octahedral tilt angles range from 17-23°.
Pb3SbN is Pb (Zr_0.50 Ti_0.48) O_3-like structured and crystallizes in the orthorhombic Imma space group. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and two equivalent N(1) atoms. The Pb(2)-Sb(1) bond length is 3.25 Å. Both Pb(2)-N(1) bond lengths are 2.53 Å. In the second Pb site, Pb(1) is bonded in a 2-coordinate geometry to two equivalent Sb(1) and two equivalent N(1) atoms. Both Pb(1)-Sb(1) bond lengths are 3.37 Å. Both Pb(1)-N(1) bond lengths are 2.65 Å. Sb(1) is bonded in a 5-coordinate geometry to one Pb(2) and four equivalent Pb(1) atoms. N(1) is bonded to two equivalent Pb(2) and four equivalent Pb(1) atoms to form corner-sharing NPb6 octahedra. The corner-sharing octahedral tilt angles range from 17-23°.