V3O5F is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(5), two equivalent O(3), and one F(1) atom to form a mixture of corner and edge-sharing VO5F octahedra. The corner-sharing octahedral tilt angles range from 46-49°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), two equivalent O(4), and one F(1) atom to form a mixture of corner and edge-sharing VO5F octahedra. The corner-sharing octahedral tilt angles range from 46-57°. In the third V site, V(3) is bonded to one O(2), two equivalent O(1), two equivalent O(5), and one F(1) atom to form a mixture of corner and edge-sharing VO5F octahedra. The corner-sharing octahedral tilt angles range from 45-57°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(3) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(3) atoms. F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom.
V3O5F is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(5), two equivalent O(3), and one F(1) atom to form a mixture of corner and edge-sharing VO5F octahedra. The corner-sharing octahedral tilt angles range from 46-49°. The V(1)-O(2) bond length is 2.00 Å. The V(1)-O(4) bond length is 1.92 Å. The V(1)-O(5) bond length is 1.93 Å. There is one shorter (1.84 Å) and one longer (1.99 Å) V(1)-O(3) bond length. The V(1)-F(1) bond length is 2.05 Å. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), two equivalent O(4), and one F(1) atom to form a mixture of corner and edge-sharing VO5F octahedra. The corner-sharing octahedral tilt angles range from 46-57°. The V(2)-O(1) bond length is 1.93 Å. The V(2)-O(2) bond length is 1.95 Å. The V(2)-O(3) bond length is 1.83 Å. There is one shorter (1.91 Å) and one longer (1.92 Å) V(2)-O(4) bond length. The V(2)-F(1) bond length is 2.08 Å. In the third V site, V(3) is bonded to one O(2), two equivalent O(1), two equivalent O(5), and one F(1) atom to form a mixture of corner and edge-sharing VO5F octahedra. The corner-sharing octahedral tilt angles range from 45-57°. The V(3)-O(2) bond length is 1.81 Å. There is one shorter (1.93 Å) and one longer (1.99 Å) V(3)-O(1) bond length. There is one shorter (1.92 Å) and one longer (1.96 Å) V(3)-O(5) bond length. The V(3)-F(1) bond length is 2.09 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(3) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(3) atoms. F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom.