Ba2V2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. V(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form VF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra and corners with two equivalent Zn(1)F6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 50-65°. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form distorted CuF6 octahedra that share corners with four equivalent V(1)F6 octahedra and corners with two equivalent Zn(1)F6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 50-65°. Zn(1) is bonded to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms to form distorted ZnF6 pentagonal pyramids that share corners with two equivalent Cu(1)F6 octahedra and corners with four equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-66°. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one V(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one V(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one V(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one V(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one V(1), and one Cu(1) atom. In the sixth F site, F(3) is bonded in a 1-coordinate geometry to two equivalent Ba(1) and one V(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom.
Ba2V2CuZnF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. The Ba(1)-F(1) bond length is 2.85 Å. The Ba(1)-F(4) bond length is 2.71 Å. The Ba(1)-F(6) bond length is 2.93 Å. The Ba(1)-F(7) bond length is 2.91 Å. There is one shorter (2.74 Å) and one longer (2.87 Å) Ba(1)-F(2) bond length. There is one shorter (2.69 Å) and one longer (3.01 Å) Ba(1)-F(3) bond length. There is one shorter (2.69 Å) and one longer (2.79 Å) Ba(1)-F(5) bond length. V(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form VF6 octahedra that share corners with two equivalent Cu(1)F6 octahedra and corners with two equivalent Zn(1)F6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 50-65°. The V(1)-F(1) bond length is 1.95 Å. The V(1)-F(2) bond length is 1.97 Å. The V(1)-F(3) bond length is 1.92 Å. The V(1)-F(5) bond length is 1.97 Å. The V(1)-F(6) bond length is 2.00 Å. The V(1)-F(7) bond length is 2.03 Å. Cu(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(7) atoms to form distorted CuF6 octahedra that share corners with four equivalent V(1)F6 octahedra and corners with two equivalent Zn(1)F6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 50-65°. Both Cu(1)-F(2) bond lengths are 2.47 Å. Both Cu(1)-F(4) bond lengths are 1.95 Å. Both Cu(1)-F(7) bond lengths are 1.95 Å. Zn(1) is bonded to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms to form distorted ZnF6 pentagonal pyramids that share corners with two equivalent Cu(1)F6 octahedra and corners with four equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-66°. Both Zn(1)-F(1) bond lengths are 2.17 Å. Both Zn(1)-F(4) bond lengths are 2.12 Å. Both Zn(1)-F(6) bond lengths are 2.12 Å. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one V(1) atom. In the second F site, F(6) is bonded in a 2-coordinate geometry to one Ba(1), one V(1), and one Zn(1) atom. In the third F site, F(7) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one V(1), and one Cu(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one V(1), and one Zn(1) atom. In the fifth F site, F(2) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one V(1), and one Cu(1) atom. In the sixth F site, F(3) is bonded in a 1-coordinate geometry to two equivalent Ba(1) and one V(1) atom. In the seventh F site, F(4) is bonded in a distorted trigonal planar geometry to one Ba(1), one Cu(1), and one Zn(1) atom.