PHF2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four difluorophosphine molecules. P(1) is bonded in a 3-coordinate geometry to one H(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.
PHF2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four difluorophosphine molecules. P(1) is bonded in a 3-coordinate geometry to one H(1), one F(1), and one F(2) atom. The P(1)-H(1) bond length is 1.43 Å. The P(1)-F(1) bond length is 1.62 Å. The P(1)-F(2) bond length is 1.62 Å. H(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom.