CeVO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 29-32°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ce(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded to two equivalent Ce(1) and two equivalent V(1) atoms to form distorted corner-sharing OCe2V2 tetrahedra.
CeVO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.35 Å) and one longer (2.44 Å) Ce(1)-O(2) bond length. There are two shorter (2.34 Å) and four longer (2.67 Å) Ce(1)-O(1) bond lengths. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 29-32°. Both V(1)-O(2) bond lengths are 1.99 Å. There are two shorter (2.04 Å) and two longer (2.05 Å) V(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ce(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded to two equivalent Ce(1) and two equivalent V(1) atoms to form distorted corner-sharing OCe2V2 tetrahedra.