(CN3)2SiF6 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four guanidine molecules and two SiF6 clusters. In each SiF6 cluster, Si(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Si(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Si(1) atom.
(CN3)2SiF6 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four guanidine molecules and two SiF6 clusters. In each SiF6 cluster, Si(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. The Si(1)-F(1) bond length is 1.71 Å. The Si(1)-F(2) bond length is 1.71 Å. Both Si(1)-F(3) bond lengths are 1.72 Å. Both Si(1)-F(4) bond lengths are 1.72 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Si(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Si(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Si(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Si(1) atom.