ZrGeSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent Ge(1) and five equivalent Sb(1) atoms. Ge(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1) and four equivalent Ge(1) atoms. Sb(1) is bonded in a 5-coordinate geometry to five equivalent Zr(1) atoms.
ZrGeSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent Ge(1) and five equivalent Sb(1) atoms. All Zr(1)-Ge(1) bond lengths are 2.89 Å. There are four shorter (2.96 Å) and one longer (3.16 Å) Zr(1)-Sb(1) bond length. Ge(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1) and four equivalent Ge(1) atoms. All Ge(1)-Ge(1) bond lengths are 2.70 Å. Sb(1) is bonded in a 5-coordinate geometry to five equivalent Zr(1) atoms.