ZrWMo is Hexagonal Laves-derived structured and crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent W(1) and six equivalent Mo(1) atoms. W(1) is bonded to six equivalent Zr(1), two equivalent W(1), and four equivalent Mo(1) atoms to form WZr6Mo4W2 cuboctahedra that share corners with eight equivalent Mo(1)Zr6Mo2W4 cuboctahedra, corners with ten equivalent W(1)Zr6Mo4W2 cuboctahedra, edges with six equivalent W(1)Zr6Mo4W2 cuboctahedra, faces with six equivalent W(1)Zr6Mo4W2 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6Mo2W4 cuboctahedra. Mo(1) is bonded to six equivalent Zr(1), four equivalent W(1), and two equivalent Mo(1) atoms to form MoZr6Mo2W4 cuboctahedra that share corners with eight equivalent W(1)Zr6Mo4W2 cuboctahedra, corners with ten equivalent Mo(1)Zr6Mo2W4 cuboctahedra, edges with six equivalent Mo(1)Zr6Mo2W4 cuboctahedra, faces with six equivalent Mo(1)Zr6Mo2W4 cuboctahedra, and faces with twelve equivalent W(1)Zr6Mo4W2 cuboctahedra.
ZrWMo is Hexagonal Laves-derived structured and crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent W(1) and six equivalent Mo(1) atoms. There are four shorter (3.15 Å) and two longer (3.16 Å) Zr(1)-W(1) bond lengths. All Zr(1)-Mo(1) bond lengths are 3.16 Å. W(1) is bonded to six equivalent Zr(1), two equivalent W(1), and four equivalent Mo(1) atoms to form WZr6Mo4W2 cuboctahedra that share corners with eight equivalent Mo(1)Zr6Mo2W4 cuboctahedra, corners with ten equivalent W(1)Zr6Mo4W2 cuboctahedra, edges with six equivalent W(1)Zr6Mo4W2 cuboctahedra, faces with six equivalent W(1)Zr6Mo4W2 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6Mo2W4 cuboctahedra. Both W(1)-W(1) bond lengths are 2.70 Å. All W(1)-Mo(1) bond lengths are 2.69 Å. Mo(1) is bonded to six equivalent Zr(1), four equivalent W(1), and two equivalent Mo(1) atoms to form MoZr6Mo2W4 cuboctahedra that share corners with eight equivalent W(1)Zr6Mo4W2 cuboctahedra, corners with ten equivalent Mo(1)Zr6Mo2W4 cuboctahedra, edges with six equivalent Mo(1)Zr6Mo2W4 cuboctahedra, faces with six equivalent Mo(1)Zr6Mo2W4 cuboctahedra, and faces with twelve equivalent W(1)Zr6Mo4W2 cuboctahedra. Both Mo(1)-Mo(1) bond lengths are 2.68 Å.