XeTe4(OF5)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one XeTe4(OF5)4 cluster. Xe(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(3), one F(5), one F(8), and one F(9) atom. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(2), one F(10), one F(2), one F(4), one F(6), and one F(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(2) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2) atom.
XeTe4(OF5)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one XeTe4(OF5)4 cluster. Xe(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Xe(1)-O(1) bond lengths are 2.16 Å. Both Xe(1)-O(2) bond lengths are 2.16 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(3), one F(5), one F(8), and one F(9) atom. The Te(1)-O(1) bond length is 1.93 Å. The Te(1)-F(1) bond length is 1.88 Å. The Te(1)-F(3) bond length is 1.86 Å. The Te(1)-F(5) bond length is 1.87 Å. The Te(1)-F(8) bond length is 1.87 Å. The Te(1)-F(9) bond length is 1.88 Å. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(2), one F(10), one F(2), one F(4), one F(6), and one F(7) atom. The Te(2)-O(2) bond length is 1.93 Å. The Te(2)-F(10) bond length is 1.86 Å. The Te(2)-F(2) bond length is 1.87 Å. The Te(2)-F(4) bond length is 1.88 Å. The Te(2)-F(6) bond length is 1.87 Å. The Te(2)-F(7) bond length is 1.87 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(2) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2) atom.