CaSbF6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 31°. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedral tilt angles are 31°. F(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one Sb(1) atom.
CaSbF6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent F(1) atoms to form CaF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 31°. All Ca(1)-F(1) bond lengths are 2.29 Å. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Ca(1)F6 octahedra. The corner-sharing octahedral tilt angles are 31°. All Sb(1)-F(1) bond lengths are 2.05 Å. F(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one Sb(1) atom.