CH3S is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dimethyl disulfide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one S(1) atom.
CH3S is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four dimethyl disulfide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), one H(3), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.82 Å. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(4), one H(5), one H(6), and one S(2) atom. The C(2)-H(4) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-S(2) bond length is 1.82 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one S(2) atom. The S(1)-S(2) bond length is 2.04 Å. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one S(1) atom.