GdFeO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Gd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Gd(1) and two equivalent Fe(1) atoms. In the second O site, O(2) is bonded to two equivalent Gd(1) and two equivalent Fe(1) atoms to form distorted corner-sharing OGd2Fe2 trigonal pyramids.
GdFeO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Gd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.27 Å) and one longer (2.34 Å) Gd(1)-O(2) bond length. There are a spread of Gd(1)-O(1) bond distances ranging from 2.31-2.70 Å. Fe(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing FeO6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. Both Fe(1)-O(2) bond lengths are 2.01 Å. There are two shorter (2.02 Å) and two longer (2.05 Å) Fe(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Gd(1) and two equivalent Fe(1) atoms. In the second O site, O(2) is bonded to two equivalent Gd(1) and two equivalent Fe(1) atoms to form distorted corner-sharing OGd2Fe2 trigonal pyramids.