SrPr(CoO3)2 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Pr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. In the second Co site, Co(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom.
SrPr(CoO3)2 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There is one shorter (2.64 Å) and one longer (2.73 Å) Sr(1)-O(1) bond length. There is one shorter (2.54 Å) and one longer (2.99 Å) Sr(1)-O(2) bond length. There is one shorter (2.52 Å) and one longer (3.04 Å) Sr(1)-O(3) bond length. There is one shorter (2.70 Å) and one longer (2.84 Å) Sr(1)-O(4) bond length. There is one shorter (2.63 Å) and one longer (2.80 Å) Sr(1)-O(5) bond length. There is one shorter (2.54 Å) and one longer (2.93 Å) Sr(1)-O(6) bond length. Pr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There is one shorter (2.46 Å) and one longer (3.13 Å) Pr(1)-O(1) bond length. There is one shorter (2.53 Å) and one longer (2.78 Å) Pr(1)-O(2) bond length. There is one shorter (2.61 Å) and one longer (2.91 Å) Pr(1)-O(3) bond length. There is one shorter (2.46 Å) and one longer (3.10 Å) Pr(1)-O(4) bond length. There is one shorter (2.46 Å) and one longer (3.07 Å) Pr(1)-O(5) bond length. There is one shorter (2.52 Å) and one longer (2.84 Å) Pr(1)-O(6) bond length. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. The Co(1)-O(1) bond length is 1.90 Å. The Co(1)-O(2) bond length is 1.91 Å. The Co(1)-O(3) bond length is 1.94 Å. The Co(1)-O(4) bond length is 1.96 Å. The Co(1)-O(5) bond length is 1.91 Å. The Co(1)-O(6) bond length is 1.91 Å. In the second Co site, Co(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 14-22°. The Co(2)-O(1) bond length is 2.03 Å. The Co(2)-O(2) bond length is 2.05 Å. The Co(2)-O(3) bond length is 1.87 Å. The Co(2)-O(4) bond length is 1.89 Å. The Co(2)-O(5) bond length is 2.02 Å. The Co(2)-O(6) bond length is 2.05 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Pr(1), one Co(1), and one Co(2) atom.