WZn2SbO6 crystallizes in the triclinic P1 space group. W(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(6) atom. Sb(1) is bonded in a 3-coordinate geometry to one O(2), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Zn(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one W(1) and one Zn(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one Sb(1) atom.
WZn2SbO6 crystallizes in the triclinic P1 space group. W(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The W(1)-O(1) bond length is 1.94 Å. The W(1)-O(2) bond length is 2.04 Å. The W(1)-O(3) bond length is 1.82 Å. The W(1)-O(4) bond length is 1.82 Å. The W(1)-O(5) bond length is 1.97 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-O(4) bond length is 1.90 Å. The Zn(1)-O(6) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(6) atom. The Zn(2)-O(1) bond length is 1.96 Å. The Zn(2)-O(2) bond length is 2.17 Å. The Zn(2)-O(6) bond length is 2.03 Å. Sb(1) is bonded in a 3-coordinate geometry to one O(2), one O(5), and one O(6) atom. The Sb(1)-O(2) bond length is 2.06 Å. The Sb(1)-O(5) bond length is 2.00 Å. The Sb(1)-O(6) bond length is 2.13 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Zn(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one W(1) and one Zn(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one Sb(1) atom.