RbP(HO)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. P(1) is bonded in a distorted tetrahedral geometry to one H(1), one H(2), and two equivalent O(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom.
RbP(HO)2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are a spread of Rb(1)-O(1) bond distances ranging from 2.91-3.11 Å. P(1) is bonded in a distorted tetrahedral geometry to one H(1), one H(2), and two equivalent O(1) atoms. The P(1)-H(1) bond length is 1.43 Å. The P(1)-H(2) bond length is 1.43 Å. Both P(1)-O(1) bond lengths are 1.52 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom.