TiSi2 crystallizes in the orthorhombic Immm space group. Ti(1) is bonded in a 10-coordinate geometry to ten equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Si(1) atoms.
TiSi2 crystallizes in the orthorhombic Immm space group. Ti(1) is bonded in a 10-coordinate geometry to ten equivalent Si(1) atoms. There are eight shorter (2.67 Å) and two longer (2.78 Å) Ti(1)-Si(1) bond lengths. Si(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Si(1) atoms. All Si(1)-Si(1) bond lengths are 2.63 Å.