Li2CoCu(PO4)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(9) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra,  an edgeedge with one Cu(1)O6 pentagonal pyramid,  an edgeedge with one Cu(2)O6 pentagonal pyramid,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-70°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(11), one O(2), one O(3), and one O(4) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Li(1)O6 octahedra,  an edgeedge with one Cu(1)O6 pentagonal pyramid,  an edgeedge with one Cu(2)O6 pentagonal pyramid,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-70°. In the third Li site, Li(3) is bonded to one O(14), one O(15), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with two equivalent Cu(1)O6 pentagonal pyramids, corners with two equivalent Cu(2)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. In the fourth Li site, Li(4) is bonded to one O(13), one O(16), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with two equivalent Cu(1)O6 pentagonal pyramids, corners with two equivalent Cu(2)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(12), one O(15), one O(16), one O(2), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Cu(2)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-70°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(5), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Cu(1)O6 pentagonal pyramids,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-69°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(10), one O(13), one O(14), one O(3), one O(7), and one O(9) atom to form distorted CuO6 pentagonal pyramids that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-72°. In the second Cu site, Cu(2) is bonded to one O(11), one O(12), one O(15), one O(16), one O(4), and one O(8) atom to form distorted CuO6 pentagonal pyramids that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-72°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(2), one O(3), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Cu(1)O6 pentagonal pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one Cu(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 50-59°. In the second P site, P(2) is bonded to one O(1), one O(11), one O(12), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Cu(2)O6 pentagonal pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one Cu(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 49-58°. In the third P site, P(3) is bonded to one O(13), one O(14), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Cu(2)O6 pentagonal pyramid, corners with two equivalent Cu(1)O6 pentagonal pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-59°. In the fourth P site, P(4) is bonded to one O(15), one O(16), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Cu(1)O6 pentagonal pyramid, corners with two equivalent Cu(2)O6 pentagonal pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-59°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Co(2), and one P(2) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Co(1), and one P(1) atom. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Cu(1), and one P(1) atom to form distorted corner-sharing OLi2CuP tetrahedra. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Cu(2), and one P(2) atom to form distorted corner-sharing OLi2CuP tetrahedra. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(4), one Co(2), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(4), one Co(1), and one P(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Cu(1), and one P(4) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Cu(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(2), one Cu(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(1), and one P(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(1), one Cu(2), and one P(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(1), one Cu(2), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(2), one Cu(1), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(2), one Cu(1), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Cu(2), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(1), one Cu(2), and one P(4) atom.
Li2CoCu(PO4)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(9) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Li(2)O6 octahedra,  an edgeedge with one Cu(1)O6 pentagonal pyramid,  an edgeedge with one Cu(2)O6 pentagonal pyramid,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-70°. The Li(1)-O(1) bond length is 2.14 Å. The Li(1)-O(12) bond length is 2.15 Å. The Li(1)-O(2) bond length is 2.17 Å. The Li(1)-O(3) bond length is 2.24 Å. The Li(1)-O(4) bond length is 2.22 Å. The Li(1)-O(9) bond length is 2.14 Å. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(11), one O(2), one O(3), and one O(4) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent Li(1)O6 octahedra,  an edgeedge with one Cu(1)O6 pentagonal pyramid,  an edgeedge with one Cu(2)O6 pentagonal pyramid,  an edgeedge with one P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-70°. The Li(2)-O(1) bond length is 2.14 Å. The Li(2)-O(10) bond length is 2.13 Å. The Li(2)-O(11) bond length is 2.15 Å. The Li(2)-O(2) bond length is 2.18 Å. The Li(2)-O(3) bond length is 2.23 Å. The Li(2)-O(4) bond length is 2.21 Å. In the third Li site, Li(3) is bonded to one O(14), one O(15), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with two equivalent Cu(1)O6 pentagonal pyramids, corners with two equivalent Cu(2)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. The Li(3)-O(14) bond length is 2.22 Å. The Li(3)-O(15) bond length is 2.18 Å. The Li(3)-O(5) bond length is 2.15 Å. The Li(3)-O(6) bond length is 2.15 Å. The Li(3)-O(7) bond length is 2.20 Å. The Li(3)-O(8) bond length is 2.17 Å. In the fourth Li site, Li(4) is bonded to one O(13), one O(16), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with two equivalent Cu(1)O6 pentagonal pyramids, corners with two equivalent Cu(2)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra,  an edgeedge with one P(3)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. The Li(4)-O(13) bond length is 2.17 Å. The Li(4)-O(16) bond length is 2.18 Å. The Li(4)-O(5) bond length is 2.13 Å. The Li(4)-O(6) bond length is 2.15 Å. The Li(4)-O(7) bond length is 2.20 Å. The Li(4)-O(8) bond length is 2.20 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(12), one O(15), one O(16), one O(2), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Cu(2)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-70°. The Co(1)-O(11) bond length is 2.05 Å. The Co(1)-O(12) bond length is 2.04 Å. The Co(1)-O(15) bond length is 2.23 Å. The Co(1)-O(16) bond length is 2.22 Å. The Co(1)-O(2) bond length is 2.02 Å. The Co(1)-O(6) bond length is 2.12 Å. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(13), one O(14), one O(5), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Cu(1)O6 pentagonal pyramids,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-69°. The Co(2)-O(1) bond length is 2.05 Å. The Co(2)-O(10) bond length is 2.09 Å. The Co(2)-O(13) bond length is 2.20 Å. The Co(2)-O(14) bond length is 2.21 Å. The Co(2)-O(5) bond length is 2.19 Å. The Co(2)-O(9) bond length is 2.07 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(10), one O(13), one O(14), one O(3), one O(7), and one O(9) atom to form distorted CuO6 pentagonal pyramids that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Co(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-72°. The Cu(1)-O(10) bond length is 2.40 Å. The Cu(1)-O(13) bond length is 2.07 Å. The Cu(1)-O(14) bond length is 2.04 Å. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(7) bond length is 1.97 Å. The Cu(1)-O(9) bond length is 2.42 Å. In the second Cu site, Cu(2) is bonded to one O(11), one O(12), one O(15), one O(16), one O(4), and one O(8) atom to form distorted CuO6 pentagonal pyramids that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-72°. The Cu(2)-O(11) bond length is 2.39 Å. The Cu(2)-O(12) bond length is 2.40 Å. The Cu(2)-O(15) bond length is 2.04 Å. The Cu(2)-O(16) bond length is 2.06 Å. The Cu(2)-O(4) bond length is 2.01 Å. The Cu(2)-O(8) bond length is 1.96 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(2), one O(3), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Cu(1)O6 pentagonal pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one Cu(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 50-59°. The P(1)-O(10) bond length is 1.56 Å. The P(1)-O(2) bond length is 1.56 Å. The P(1)-O(3) bond length is 1.56 Å. The P(1)-O(9) bond length is 1.56 Å. In the second P site, P(2) is bonded to one O(1), one O(11), one O(12), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Cu(2)O6 pentagonal pyramid,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra, and  an edgeedge with one Cu(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 49-58°. The P(2)-O(1) bond length is 1.56 Å. The P(2)-O(11) bond length is 1.56 Å. The P(2)-O(12) bond length is 1.56 Å. The P(2)-O(4) bond length is 1.56 Å. In the third P site, P(3) is bonded to one O(13), one O(14), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Cu(2)O6 pentagonal pyramid, corners with two equivalent Cu(1)O6 pentagonal pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-59°. The P(3)-O(13) bond length is 1.57 Å. The P(3)-O(14) bond length is 1.57 Å. The P(3)-O(5) bond length is 1.53 Å. The P(3)-O(8) bond length is 1.57 Å. In the fourth P site, P(4) is bonded to one O(15), one O(16), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Cu(1)O6 pentagonal pyramid, corners with two equivalent Cu(2)O6 pentagonal pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-59°. The P(4)-O(15) bond length is 1.57 Å. The P(4)-O(16) bond length is 1.57 Å. The P(4)-O(6) bond length is 1.54 Å. The P(4)-O(7) bond length is 1.57 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Co(2), and one P(2) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Co(1), and one P(1) atom. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Cu(1), and one P(1) atom to form distorted corner-sharing OLi2CuP tetrahedra. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Cu(2), and one P(2) atom to form distorted corner-sharing OLi2CuP tetrahedra. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(4), one Co(2), and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(4), one Co(1), and one P(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Cu(1), and one P(4) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), one Li(4), one Cu(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(2), one Cu(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(2), one Cu(1), and one P(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Co(1), one Cu(2), and one P(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(1), one Cu(2), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(2), one Cu(1), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(2), one Cu(1), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Co(1), one Cu(2), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(1), one Cu(2), and one P(4) atom.