Li5Ti2V5O12 is beta Polonium-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the second Ti site, Ti(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent V(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(3)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(4)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra, edges with four equivalent O(3)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(4)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°.
Li5Ti2V5O12 is beta Polonium-derived structured and crystallizes in the monoclinic C2 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. The Li(1)-O(1) bond length is 2.23 Å. The Li(1)-O(2) bond length is 2.19 Å. The Li(1)-O(3) bond length is 2.07 Å. The Li(1)-O(4) bond length is 2.33 Å. The Li(1)-O(5) bond length is 2.18 Å. The Li(1)-O(6) bond length is 2.06 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. The Li(2)-O(1) bond length is 2.10 Å. The Li(2)-O(2) bond length is 2.23 Å. The Li(2)-O(3) bond length is 2.25 Å. The Li(2)-O(4) bond length is 2.10 Å. The Li(2)-O(5) bond length is 2.14 Å. The Li(2)-O(6) bond length is 2.24 Å. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. Both Li(3)-O(1) bond lengths are 2.13 Å. Both Li(3)-O(3) bond lengths are 2.13 Å. Both Li(3)-O(5) bond lengths are 2.17 Å. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. Both Ti(1)-O(1) bond lengths are 2.04 Å. Both Ti(1)-O(3) bond lengths are 1.98 Å. Both Ti(1)-O(5) bond lengths are 1.99 Å. In the second Ti site, Ti(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent V(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. Both Ti(2)-O(2) bond lengths are 2.02 Å. Both Ti(2)-O(4) bond lengths are 2.01 Å. Both Ti(2)-O(6) bond lengths are 2.04 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. The V(1)-O(1) bond length is 2.13 Å. The V(1)-O(2) bond length is 2.20 Å. The V(1)-O(3) bond length is 2.16 Å. The V(1)-O(4) bond length is 2.16 Å. The V(1)-O(5) bond length is 2.16 Å. The V(1)-O(6) bond length is 2.15 Å. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. Both V(2)-O(2) bond lengths are 2.14 Å. Both V(2)-O(4) bond lengths are 2.13 Å. Both V(2)-O(6) bond lengths are 2.14 Å. In the third V site, V(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. Both V(3)-O(1) bond lengths are 2.05 Å. Both V(3)-O(3) bond lengths are 2.08 Å. Both V(3)-O(5) bond lengths are 2.08 Å. In the fourth V site, V(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with three equivalent Ti(2)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. Both V(4)-O(2) bond lengths are 2.14 Å. Both V(4)-O(4) bond lengths are 2.14 Å. Both V(4)-O(6) bond lengths are 2.15 Å. There are six inequivalent O sites. In the first O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(3)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the second O site, O(6) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(4)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra, edges with four equivalent O(3)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(4)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Ti(1), one V(1), and one V(3) atom to form OLi3TiV2 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(2)Li2TiV3 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(6)Li2TiV3 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra, edges with four equivalent O(1)Li3TiV2 octahedra, and edges with four equivalent O(5)Li3TiV2 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the sixth O site, O(4) is bonded to one Li(1), one Li(2), one Ti(2), one V(1), one V(2), and one V(4) atom to form OLi2TiV3 octahedra that share  a cornercorner with one O(2)Li2TiV3 octahedra,  a cornercorner with one O(4)Li2TiV3 octahedra,  a cornercorner with one O(6)Li2TiV3 octahedra,  a cornercorner with one O(1)Li3TiV2 octahedra,  a cornercorner with one O(3)Li3TiV2 octahedra,  a cornercorner with one O(5)Li3TiV2 octahedra,  an edgeedge with one O(4)Li2TiV3 octahedra,  an edgeedge with one O(1)Li3TiV2 octahedra,  an edgeedge with one O(3)Li3TiV2 octahedra,  an edgeedge with one O(5)Li3TiV2 octahedra, edges with four equivalent O(2)Li2TiV3 octahedra, and edges with four equivalent O(6)Li2TiV3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°.