TmPdZn crystallizes in the hexagonal P-62m space group. Tm(1) is bonded in a 11-coordinate geometry to one Pd(1), four equivalent Pd(2), and six equivalent Zn(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to three equivalent Tm(1) and six equivalent Zn(1) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Tm(1) and three equivalent Zn(1) atoms. Zn(1) is bonded in a 4-coordinate geometry to six equivalent Tm(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.
TmPdZn crystallizes in the hexagonal P-62m space group. Tm(1) is bonded in a 11-coordinate geometry to one Pd(1), four equivalent Pd(2), and six equivalent Zn(1) atoms. The Tm(1)-Pd(1) bond length is 2.89 Å. All Tm(1)-Pd(2) bond lengths are 2.90 Å. There are two shorter (3.12 Å) and four longer (3.17 Å) Tm(1)-Zn(1) bond lengths. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to three equivalent Tm(1) and six equivalent Zn(1) atoms. All Pd(1)-Zn(1) bond lengths are 2.63 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Tm(1) and three equivalent Zn(1) atoms. All Pd(2)-Zn(1) bond lengths are 2.72 Å. Zn(1) is bonded in a 4-coordinate geometry to six equivalent Tm(1), two equivalent Pd(1), and two equivalent Pd(2) atoms.