NaInGeP2SO12 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a distorted hexagonal planar geometry to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom. In(1) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form InO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. Ge(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form GeO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent Ge(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-39°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent Ge(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-39°. S(1) is bonded to one O(11), one O(2), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent Ge(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-40°. There are twelve inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(1) atom. In the third O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(2) atom. In the fourth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one S(1) atom. In the fifth O site, O(10) is bonded in a 3-coordinate geometry to one Na(1), one In(1), and one P(1) atom. In the sixth O site, O(11) is bonded in a 3-coordinate geometry to one Na(1), one In(1), and one S(1) atom. In the seventh O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one In(1), and one P(2) atom. In the eighth O site, O(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the ninth O site, O(2) is bonded in a bent 150 degrees geometry to one Ge(1) and one S(1) atom. In the tenth O site, O(3) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the eleventh O site, O(4) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the twelfth O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one P(2) atom.
NaInGeP2SO12 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a distorted hexagonal planar geometry to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom. The Na(1)-O(10) bond length is 2.61 Å. The Na(1)-O(11) bond length is 2.68 Å. The Na(1)-O(12) bond length is 2.47 Å. The Na(1)-O(7) bond length is 2.53 Å. The Na(1)-O(8) bond length is 2.40 Å. The Na(1)-O(9) bond length is 2.52 Å. In(1) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form InO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. The In(1)-O(10) bond length is 2.07 Å. The In(1)-O(11) bond length is 2.17 Å. The In(1)-O(12) bond length is 2.12 Å. The In(1)-O(4) bond length is 2.02 Å. The In(1)-O(5) bond length is 2.06 Å. The In(1)-O(6) bond length is 2.14 Å. Ge(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form GeO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. The Ge(1)-O(1) bond length is 1.94 Å. The Ge(1)-O(2) bond length is 2.10 Å. The Ge(1)-O(3) bond length is 1.90 Å. The Ge(1)-O(7) bond length is 1.91 Å. The Ge(1)-O(8) bond length is 1.94 Å. The Ge(1)-O(9) bond length is 2.03 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent Ge(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-39°. The P(1)-O(1) bond length is 1.58 Å. The P(1)-O(10) bond length is 1.53 Å. The P(1)-O(4) bond length is 1.50 Å. The P(1)-O(7) bond length is 1.58 Å. In the second P site, P(2) is bonded to one O(12), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent Ge(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-39°. The P(2)-O(12) bond length is 1.53 Å. The P(2)-O(3) bond length is 1.59 Å. The P(2)-O(5) bond length is 1.50 Å. The P(2)-O(8) bond length is 1.58 Å. S(1) is bonded to one O(11), one O(2), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra and corners with two equivalent Ge(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-40°. The S(1)-O(11) bond length is 1.48 Å. The S(1)-O(2) bond length is 1.49 Å. The S(1)-O(6) bond length is 1.46 Å. The S(1)-O(9) bond length is 1.51 Å. There are twelve inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(1) atom. In the third O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(2) atom. In the fourth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one S(1) atom. In the fifth O site, O(10) is bonded in a 3-coordinate geometry to one Na(1), one In(1), and one P(1) atom. In the sixth O site, O(11) is bonded in a 3-coordinate geometry to one Na(1), one In(1), and one S(1) atom. In the seventh O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one In(1), and one P(2) atom. In the eighth O site, O(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the ninth O site, O(2) is bonded in a bent 150 degrees geometry to one Ge(1) and one S(1) atom. In the tenth O site, O(3) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the eleventh O site, O(4) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the twelfth O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one P(2) atom.