IrCl6(CoN5Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, four CoN5Cl clusters, and two IrCl6 clusters. In each CoN5Cl cluster, Co(1) is bonded in a 5-coordinate geometry to one N(1), two equivalent N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Co(1) atom. In the second N site, N(2) is bonded in a distorted L-shaped geometry to one Co(1) and one N(2) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one Co(1) and one Cl(5) atom. Cl(5) is bonded in an L-shaped geometry to two equivalent N(3) atoms. In each IrCl6 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(3), and two equivalent Cl(4) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ir(1) atom.
IrCl6(CoN5Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, four CoN5Cl clusters, and two IrCl6 clusters. In each CoN5Cl cluster, Co(1) is bonded in a 5-coordinate geometry to one N(1), two equivalent N(2), and two equivalent N(3) atoms. The Co(1)-N(1) bond length is 1.60 Å. Both Co(1)-N(2) bond lengths are 2.37 Å. Both Co(1)-N(3) bond lengths are 1.78 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Co(1) atom. In the second N site, N(2) is bonded in a distorted L-shaped geometry to one Co(1) and one N(2) atom. The N(2)-N(2) bond length is 1.12 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one Co(1) and one Cl(5) atom. The N(3)-Cl(5) bond length is 1.74 Å. Cl(5) is bonded in an L-shaped geometry to two equivalent N(3) atoms. In each IrCl6 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(3), and two equivalent Cl(4) atoms. Both Ir(1)-Cl(1) bond lengths are 2.32 Å. Both Ir(1)-Cl(3) bond lengths are 2.30 Å. Both Ir(1)-Cl(4) bond lengths are 2.33 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ir(1) atom.