CrOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one F(2), one F(3), one F(4), and one F(8) atom. O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Cr(1) atom.
CrOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one F(2), one F(3), one F(4), and one F(8) atom. The Cr(1)-O(2) bond length is 1.56 Å. The Cr(1)-F(2) bond length is 1.75 Å. The Cr(1)-F(3) bond length is 1.75 Å. The Cr(1)-F(4) bond length is 1.75 Å. The Cr(1)-F(8) bond length is 1.79 Å. O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Cr(1) atom.