AgTaF6 crystallizes in the tetragonal P4_2/mcm space group. Ta(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Ta(1) atom. In the second F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ta(1) and one Ag(1) atom.
AgTaF6 crystallizes in the tetragonal P4_2/mcm space group. Ta(1) is bonded in an octahedral geometry to two equivalent F(2) and four equivalent F(1) atoms. Both Ta(1)-F(2) bond lengths are 1.92 Å. All Ta(1)-F(1) bond lengths are 1.91 Å. Ag(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. All Ag(1)-F(1) bond lengths are 2.39 Å. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Ta(1) atom. In the second F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ta(1) and one Ag(1) atom.