(GaCl4)2N2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom.
(GaCl4)2N2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. The Ga(1)-Cl(2) bond length is 2.20 Å. The Ga(1)-Cl(3) bond length is 2.19 Å. Both Ga(1)-Cl(1) bond lengths are 2.21 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom.