VRhSi is half-Heusler structured and crystallizes in the cubic F-43m space group. V(1) is bonded to four equivalent Rh(1) and six equivalent Si(1) atoms to form distorted VSi6Rh4 tetrahedra that share corners with four equivalent Si(1)V6Rh4 tetrahedra, corners with six equivalent V(1)Si6Rh4 tetrahedra, edges with six equivalent Si(1)V6Rh4 tetrahedra, and faces with twelve equivalent V(1)Si6Rh4 tetrahedra. Rh(1) is bonded in a body-centered cubic geometry to four equivalent V(1) and four equivalent Si(1) atoms. Si(1) is bonded to six equivalent V(1) and four equivalent Rh(1) atoms to form distorted SiV6Rh4 tetrahedra that share corners with four equivalent V(1)Si6Rh4 tetrahedra, corners with six equivalent Si(1)V6Rh4 tetrahedra, edges with six equivalent V(1)Si6Rh4 tetrahedra, and faces with twelve equivalent Si(1)V6Rh4 tetrahedra.
VRhSi is half-Heusler structured and crystallizes in the cubic F-43m space group. V(1) is bonded to four equivalent Rh(1) and six equivalent Si(1) atoms to form distorted VSi6Rh4 tetrahedra that share corners with four equivalent Si(1)V6Rh4 tetrahedra, corners with six equivalent V(1)Si6Rh4 tetrahedra, edges with six equivalent Si(1)V6Rh4 tetrahedra, and faces with twelve equivalent V(1)Si6Rh4 tetrahedra. All V(1)-Rh(1) bond lengths are 2.48 Å. All V(1)-Si(1) bond lengths are 2.86 Å. Rh(1) is bonded in a body-centered cubic geometry to four equivalent V(1) and four equivalent Si(1) atoms. All Rh(1)-Si(1) bond lengths are 2.48 Å. Si(1) is bonded to six equivalent V(1) and four equivalent Rh(1) atoms to form distorted SiV6Rh4 tetrahedra that share corners with four equivalent V(1)Si6Rh4 tetrahedra, corners with six equivalent Si(1)V6Rh4 tetrahedra, edges with six equivalent V(1)Si6Rh4 tetrahedra, and faces with twelve equivalent Si(1)V6Rh4 tetrahedra.