BaSrDySbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Sr(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form DyO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-20°. In the second Dy site, Dy(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form DyO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-20°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Dy(2)O6 octahedra and corners with four equivalent Dy(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-20°. In the second Sb site, Sb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Dy(1)O6 octahedra and corners with four equivalent Dy(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-20°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent Sr(1), one Dy(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(2), and one Sb(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent Sr(1), one Dy(2), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(2), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(1), and one Sb(2) atom.
BaSrDySbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There is one shorter (2.92 Å) and one longer (3.40 Å) Ba(1)-O(1) bond length. There is one shorter (2.73 Å) and one longer (3.00 Å) Ba(1)-O(2) bond length. There is one shorter (2.72 Å) and one longer (2.99 Å) Ba(1)-O(3) bond length. There is one shorter (2.94 Å) and one longer (3.42 Å) Ba(1)-O(4) bond length. There is one shorter (2.89 Å) and one longer (3.13 Å) Ba(1)-O(5) bond length. There is one shorter (2.73 Å) and one longer (3.25 Å) Ba(1)-O(6) bond length. Sr(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. The Sr(1)-O(2) bond length is 2.87 Å. The Sr(1)-O(3) bond length is 2.89 Å. The Sr(1)-O(5) bond length is 2.63 Å. The Sr(1)-O(6) bond length is 2.77 Å. There is one shorter (2.67 Å) and one longer (2.98 Å) Sr(1)-O(1) bond length. There is one shorter (2.68 Å) and one longer (2.92 Å) Sr(1)-O(4) bond length. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form DyO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-20°. Both Dy(1)-O(1) bond lengths are 2.26 Å. Both Dy(1)-O(3) bond lengths are 2.24 Å. Both Dy(1)-O(6) bond lengths are 2.24 Å. In the second Dy site, Dy(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form DyO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-20°. Both Dy(2)-O(2) bond lengths are 2.24 Å. Both Dy(2)-O(4) bond lengths are 2.26 Å. Both Dy(2)-O(5) bond lengths are 2.26 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Dy(2)O6 octahedra and corners with four equivalent Dy(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-20°. Both Sb(1)-O(1) bond lengths are 2.03 Å. Both Sb(1)-O(3) bond lengths are 2.01 Å. Both Sb(1)-O(5) bond lengths are 2.02 Å. In the second Sb site, Sb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Dy(1)O6 octahedra and corners with four equivalent Dy(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-20°. Both Sb(2)-O(2) bond lengths are 2.01 Å. Both Sb(2)-O(4) bond lengths are 2.03 Å. Both Sb(2)-O(6) bond lengths are 2.02 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent Sr(1), one Dy(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(2), and one Sb(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent Sr(1), one Dy(2), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(2), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Sr(1), one Dy(1), and one Sb(2) atom.