UO4U(NO6)2(NO3)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, one U(NO6)2 cluster, and one UO4 cluster. In the U(NO6)2 cluster, U(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(9) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(11) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one U(1) and one N(1) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(11) is bonded in a single-bond geometry to one O(2) atom. In the UO4 cluster, U(2) is bonded in a square co-planar geometry to four equivalent O(5,6) atoms. O(5,6) is bonded in a single-bond geometry to one U(2) atom.
UO4U(NO6)2(NO3)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules, one U(NO6)2 cluster, and one UO4 cluster. In the U(NO6)2 cluster, U(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both U(1)-O(1) bond lengths are 1.79 Å. Both U(1)-O(2) bond lengths are 2.67 Å. Both U(1)-O(3) bond lengths are 2.46 Å. Both U(1)-O(4) bond lengths are 2.49 Å. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(9) atom. The N(1)-O(3) bond length is 1.29 Å. The N(1)-O(4) bond length is 1.30 Å. The N(1)-O(9) bond length is 1.22 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one U(1) and one O(11) atom. The O(2)-O(11) bond length is 1.23 Å. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one U(1) and one N(1) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(11) is bonded in a single-bond geometry to one O(2) atom. In the UO4 cluster, U(2) is bonded in a square co-planar geometry to four equivalent O(5,6) atoms. All U(2)-O(5,6) bond lengths are 1.84 Å. O(5,6) is bonded in a single-bond geometry to one U(2) atom.