(K)2TlBiF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlBiF6 framework. In the TlBiF6 framework, Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Tl(1) and one Bi(1) atom.
(K)2TlBiF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a TlBiF6 framework. In the TlBiF6 framework, Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Bi(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-F(1) bond lengths are 2.64 Å. Bi(1) is bonded to six equivalent F(1) atoms to form BiF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Bi(1)-F(1) bond lengths are 2.27 Å. F(1) is bonded in a linear geometry to one Tl(1) and one Bi(1) atom.