K3P is Sodium arsenide structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 1-coordinate geometry to four equivalent P(1) atoms. In the second K site, K(2) is bonded in a trigonal planar geometry to three equivalent P(1) atoms. P(1) is bonded in a 11-coordinate geometry to three equivalent K(2) and eight equivalent K(1) atoms.
K3P is Sodium arsenide structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 1-coordinate geometry to four equivalent P(1) atoms. There is one shorter (3.32 Å) and three longer (3.69 Å) K(1)-P(1) bond lengths. In the second K site, K(2) is bonded in a trigonal planar geometry to three equivalent P(1) atoms. All K(2)-P(1) bond lengths are 3.28 Å. P(1) is bonded in a 11-coordinate geometry to three equivalent K(2) and eight equivalent K(1) atoms.