Ce2SbO2 is alpha bismuth trifluoride-derived structured and crystallizes in the monoclinic C2/m space group. Ce(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent O(1) atoms. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Ce(1) atoms. O(1) is bonded to four equivalent Ce(1) atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra.
Ce2SbO2 is alpha bismuth trifluoride-derived structured and crystallizes in the monoclinic C2/m space group. Ce(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent O(1) atoms. There are a spread of Ce(1)-Sb(1) bond distances ranging from 3.46-3.52 Å. There are two shorter (2.33 Å) and two longer (2.35 Å) Ce(1)-O(1) bond lengths. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Ce(1) atoms. O(1) is bonded to four equivalent Ce(1) atoms to form a mixture of edge and corner-sharing OCe4 tetrahedra.