(MoS)4GaSiS4 is Cuprite-derived structured and crystallizes in the cubic F-43m space group. The structure consists of four MoS clusters inside a GaSiS4 framework. In each MoS cluster, Mo(1) is bonded in a 3-coordinate geometry to three equivalent S(2) atoms. S(2) is bonded in a 3-coordinate geometry to three equivalent Mo(1) atoms. In the GaSiS4 framework, Ga(1) is bonded to four equivalent S(1) atoms to form GaS4 tetrahedra that share corners with four equivalent Si(1)S4 tetrahedra. Si(1) is bonded to four equivalent S(1) atoms to form SiS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra. S(1) is bonded in a distorted linear geometry to one Ga(1) and one Si(1) atom.
(MoS)4GaSiS4 is Cuprite-derived structured and crystallizes in the cubic F-43m space group. The structure consists of four MoS clusters inside a GaSiS4 framework. In each MoS cluster, Mo(1) is bonded in a 3-coordinate geometry to three equivalent S(2) atoms. All Mo(1)-S(2) bond lengths are 2.36 Å. S(2) is bonded in a 3-coordinate geometry to three equivalent Mo(1) atoms. In the GaSiS4 framework, Ga(1) is bonded to four equivalent S(1) atoms to form GaS4 tetrahedra that share corners with four equivalent Si(1)S4 tetrahedra. All Ga(1)-S(1) bond lengths are 2.50 Å. Si(1) is bonded to four equivalent S(1) atoms to form SiS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra. All Si(1)-S(1) bond lengths are 2.09 Å. S(1) is bonded in a distorted linear geometry to one Ga(1) and one Si(1) atom.