(K)2NaEuCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaEuCl6 framework. In the NaEuCl6 framework, Na(1) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Eu(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Eu(1) is bonded to six equivalent Cl(1) atoms to form EuCl6 octahedra that share corners with six equivalent Na(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Na(1) and one Eu(1) atom.
(K)2NaEuCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaEuCl6 framework. In the NaEuCl6 framework, Na(1) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Eu(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-Cl(1) bond lengths are 2.72 Å. Eu(1) is bonded to six equivalent Cl(1) atoms to form EuCl6 octahedra that share corners with six equivalent Na(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Eu(1)-Cl(1) bond lengths are 2.70 Å. Cl(1) is bonded in a linear geometry to one Na(1) and one Eu(1) atom.