ZrFeSi crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent Fe(1) and five equivalent Si(1) atoms. Fe(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1) and four equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to five equivalent Zr(1) and four equivalent Fe(1) atoms.
ZrFeSi crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent Fe(1) and five equivalent Si(1) atoms. There are a spread of Zr(1)-Fe(1) bond distances ranging from 2.75-2.83 Å. There are a spread of Zr(1)-Si(1) bond distances ranging from 2.78-2.88 Å. Fe(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1) and four equivalent Si(1) atoms. There are a spread of Fe(1)-Si(1) bond distances ranging from 2.35-2.47 Å. Si(1) is bonded in a 9-coordinate geometry to five equivalent Zr(1) and four equivalent Fe(1) atoms.