S is alpha-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of six octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(13) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(14) and one S(20) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(7) and one S(8) atom. In the fourth S site, S(7) is bonded in a water-like geometry to one S(20) and one S(3) atom. In the fifth S site, S(8) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the sixth S site, S(13) is bonded in a water-like geometry to one S(1) and one S(14) atom. In the seventh S site, S(14) is bonded in a water-like geometry to one S(13) and one S(2) atom. In the eighth S site, S(20) is bonded in a water-like geometry to one S(2) and one S(7) atom.
S is alpha-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of six octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(13) and one S(8) atom. The S(1)-S(13) bond length is 2.05 Å. The S(1)-S(8) bond length is 2.05 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(14) and one S(20) atom. The S(2)-S(14) bond length is 2.05 Å. The S(2)-S(20) bond length is 2.05 Å. In the third S site, S(3) is bonded in a water-like geometry to one S(7) and one S(8) atom. The S(3)-S(7) bond length is 2.05 Å. The S(3)-S(8) bond length is 2.05 Å. In the fourth S site, S(7) is bonded in a water-like geometry to one S(20) and one S(3) atom. The S(7)-S(20) bond length is 2.05 Å. In the fifth S site, S(8) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the sixth S site, S(13) is bonded in a water-like geometry to one S(1) and one S(14) atom. The S(13)-S(14) bond length is 2.05 Å. In the seventh S site, S(14) is bonded in a water-like geometry to one S(13) and one S(2) atom. In the eighth S site, S(20) is bonded in a water-like geometry to one S(2) and one S(7) atom.