FeC3SO3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two FeC3SO3 clusters. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 5-coordinate geometry to one C(1), one C(2), one C(3), one S(1), and one S(2) atom. In the second Fe site, Fe(2) is bonded in a 5-coordinate geometry to one C(4), one C(5), one C(6), one S(1), and one S(2) atom. There are six inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one O(1,6) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one O(3) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(1) and one O(2) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(5) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Fe(2) and one O(1,6) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(2) and one O(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one S(1) atom. There are five inequivalent O sites. In the first O site, O(1,6) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom.
FeC3SO3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two FeC3SO3 clusters. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 5-coordinate geometry to one C(1), one C(2), one C(3), one S(1), and one S(2) atom. The Fe(1)-C(1) bond length is 1.80 Å. The Fe(1)-C(2) bond length is 1.79 Å. The Fe(1)-C(3) bond length is 1.80 Å. The Fe(1)-S(1) bond length is 2.26 Å. The Fe(1)-S(2) bond length is 2.27 Å. In the second Fe site, Fe(2) is bonded in a 5-coordinate geometry to one C(4), one C(5), one C(6), one S(1), and one S(2) atom. The Fe(2)-C(4) bond length is 1.80 Å. The Fe(2)-C(5) bond length is 1.80 Å. The Fe(2)-C(6) bond length is 1.79 Å. The Fe(2)-S(1) bond length is 2.25 Å. The Fe(2)-S(2) bond length is 2.27 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one O(1,6) atom. The C(1)-O(1,6) bond length is 1.16 Å. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one O(3) atom. The C(2)-O(3) bond length is 1.16 Å. In the third C site, C(3) is bonded in a linear geometry to one Fe(1) and one O(2) atom. The C(3)-O(2) bond length is 1.16 Å. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(5) atom. The C(4)-O(5) bond length is 1.16 Å. In the fifth C site, C(5) is bonded in a linear geometry to one Fe(2) and one O(1,6) atom. The C(5)-O(1,6) bond length is 1.16 Å. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(2) and one O(4) atom. The C(6)-O(4) bond length is 1.16 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one S(2) atom. The S(1)-S(2) bond length is 2.04 Å. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one S(1) atom. There are five inequivalent O sites. In the first O site, O(1,6) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom.