Ce2PdGa10 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Ga(1), four equivalent Ga(2), four equivalent Ga(3), and four equivalent Ga(4) atoms. Pd(1) is bonded in a body-centered cubic geometry to eight equivalent Ga(4) atoms. There are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Ga(2), and four equivalent Ga(3) atoms. In the second Ga site, Ga(2) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Ga(1), and four equivalent Ga(4) atoms. In the third Ga site, Ga(3) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Ga(1) atoms. In the fourth Ga site, Ga(4) is bonded in a 2-coordinate geometry to two equivalent Ce(1), two equivalent Pd(1), and two equivalent Ga(2) atoms.
Ce2PdGa10 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Ga(1), four equivalent Ga(2), four equivalent Ga(3), and four equivalent Ga(4) atoms. All Ce(1)-Ga(1) bond lengths are 3.42 Å. All Ce(1)-Ga(2) bond lengths are 3.29 Å. All Ce(1)-Ga(3) bond lengths are 3.54 Å. All Ce(1)-Ga(4) bond lengths are 3.27 Å. Pd(1) is bonded in a body-centered cubic geometry to eight equivalent Ga(4) atoms. All Pd(1)-Ga(4) bond lengths are 2.60 Å. There are four inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Ga(2), and four equivalent Ga(3) atoms. The Ga(1)-Ga(2) bond length is 2.41 Å. All Ga(1)-Ga(3) bond lengths are 2.60 Å. In the second Ga site, Ga(2) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Ga(1), and four equivalent Ga(4) atoms. All Ga(2)-Ga(4) bond lengths are 2.62 Å. In the third Ga site, Ga(3) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Ga(1) atoms. In the fourth Ga site, Ga(4) is bonded in a 2-coordinate geometry to two equivalent Ce(1), two equivalent Pd(1), and two equivalent Ga(2) atoms.