Zr2PdAgF11 crystallizes in the monoclinic C2/m space group. Zr(1) is bonded to one F(2), one F(4), one F(5), two equivalent F(1), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Pd(1)F6 octahedra,  a cornercorner with one Zr(1)F7 pentagonal bipyramid, and  an edgeedge with one Zr(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 7-32°. Pd(1) is bonded to two equivalent F(4) and four equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Zr(1)F7 pentagonal bipyramids. Ag(1) is bonded in a square co-planar geometry to two equivalent F(3) and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Zr(1) atoms. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Zr(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Pd(1) atom. In the fifth F site, F(5) is bonded in a linear geometry to one Zr(1) and one Ag(1) atom.
Zr2PdAgF11 crystallizes in the monoclinic C2/m space group. Zr(1) is bonded to one F(2), one F(4), one F(5), two equivalent F(1), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Pd(1)F6 octahedra,  a cornercorner with one Zr(1)F7 pentagonal bipyramid, and  an edgeedge with one Zr(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 7-32°. The Zr(1)-F(2) bond length is 2.12 Å. The Zr(1)-F(4) bond length is 2.05 Å. The Zr(1)-F(5) bond length is 1.98 Å. Both Zr(1)-F(1) bond lengths are 2.09 Å. Both Zr(1)-F(3) bond lengths are 2.19 Å. Pd(1) is bonded to two equivalent F(4) and four equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Zr(1)F7 pentagonal bipyramids. Both Pd(1)-F(4) bond lengths are 2.20 Å. All Pd(1)-F(1) bond lengths are 2.22 Å. Ag(1) is bonded in a square co-planar geometry to two equivalent F(3) and two equivalent F(5) atoms. Both Ag(1)-F(3) bond lengths are 2.39 Å. Both Ag(1)-F(5) bond lengths are 2.40 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Zr(1) atoms. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Zr(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Pd(1) atom. In the fifth F site, F(5) is bonded in a linear geometry to one Zr(1) and one Ag(1) atom.