Al(CuN)3 crystallizes in the cubic Pm-3m space group. Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. Al(1) is bonded to six equivalent N(1) atoms to form corner-sharing AlN6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to four equivalent Cu(1) and two equivalent Al(1) atoms to form a mixture of edge and corner-sharing NAl2Cu4 octahedra. The corner-sharing octahedra are not tilted.
Al(CuN)3 crystallizes in the cubic Pm-3m space group. Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.04 Å. Al(1) is bonded to six equivalent N(1) atoms to form corner-sharing AlN6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-N(1) bond lengths are 2.04 Å. N(1) is bonded to four equivalent Cu(1) and two equivalent Al(1) atoms to form a mixture of edge and corner-sharing NAl2Cu4 octahedra. The corner-sharing octahedra are not tilted.