Ca2InSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with six equivalent Ca(1)O12 cuboctahedra, faces with four equivalent In(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra and faces with eight equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent In(1)O6 octahedra and faces with eight equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Ca(1), one In(1), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing OCa4InSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
Ca2InSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with six equivalent Ca(1)O12 cuboctahedra, faces with four equivalent In(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. All Ca(1)-O(1) bond lengths are 2.88 Å. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra and faces with eight equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-O(1) bond lengths are 2.11 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent In(1)O6 octahedra and faces with eight equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Sb(1)-O(1) bond lengths are 1.97 Å. O(1) is bonded to four equivalent Ca(1), one In(1), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing OCa4InSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°.