Mo8NiP3 crystallizes in the triclinic P1 space group. There are thirty-two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 14-coordinate geometry to one Mo(13), one Mo(19), one Mo(27), one Mo(30), one Mo(4), two equivalent Mo(10), two equivalent Mo(7), one Ni(4), two equivalent Ni(1), one P(1), and one P(7) atom. In the second Mo site, Mo(2) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(20), one Mo(25), one Mo(28), one Mo(31), one Mo(5), two equivalent Mo(11), two equivalent Mo(8), two equivalent Ni(2), one P(2), and one P(8) atom. In the third Mo site, Mo(3) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(21), one Mo(26), one Mo(29), one Mo(32), one Mo(6), two equivalent Mo(12), two equivalent Mo(9), two equivalent Ni(3), one P(3), and one P(9) atom. In the fourth Mo site, Mo(4) is bonded in a 14-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), one Mo(27), one Mo(30), two equivalent Mo(10), two equivalent Mo(7), one Ni(1), two equivalent Ni(4), one P(10), and one P(4) atom. In the fifth Mo site, Mo(5) is bonded in a 14-coordinate geometry to one Mo(17), one Mo(2), one Mo(23), one Mo(28), one Mo(31), two equivalent Mo(11), two equivalent Mo(25), two equivalent Mo(8), one Ni(2), one P(11), and one P(5) atom. In the sixth Mo site, Mo(6) is bonded in a 14-coordinate geometry to one Mo(18), one Mo(24), one Mo(29), one Mo(3), one Mo(32), two equivalent Mo(12), two equivalent Mo(26), two equivalent Mo(9), one Ni(3), one P(12), and one P(6) atom. In the seventh Mo site, Mo(7) is bonded in a 3-coordinate geometry to one Mo(10), two equivalent Mo(1), two equivalent Mo(4), one P(4), and one P(7) atom. In the eighth Mo site, Mo(8) is bonded in a 14-coordinate geometry to one Mo(11), one Mo(17), one Mo(20), one Mo(25), one Mo(30), two equivalent Mo(2), two equivalent Mo(28), two equivalent Mo(5), one Ni(2), one P(5), and one P(8) atom. In the ninth Mo site, Mo(9) is bonded in a 3-coordinate geometry to one Mo(12), two equivalent Mo(3), two equivalent Mo(6), one P(6), and one P(9) atom. In the tenth Mo site, Mo(10) is bonded in a 3-coordinate geometry to one Mo(7), two equivalent Mo(1), two equivalent Mo(4), one P(1), and one P(10) atom. In the eleventh Mo site, Mo(11) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(23), one Mo(25), one Mo(29), one Mo(8), two equivalent Mo(2), two equivalent Mo(31), two equivalent Mo(5), one Ni(2), one P(11), and one P(2) atom. In the twelfth Mo site, Mo(12) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(24), one Mo(26), one Mo(27), one Mo(9), two equivalent Mo(3), two equivalent Mo(32), two equivalent Mo(6), one Ni(3), one P(12), and one P(3) atom. In the thirteenth Mo site, Mo(13) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(10), one P(8), and two equivalent P(1) atoms. In the fourteenth Mo site, Mo(14) is bonded in a 5-coordinate geometry to one Mo(11), one Mo(2), one Ni(2), one P(11), one P(9), and two equivalent P(2) atoms. In the fifteenth Mo site, Mo(15) is bonded in a 5-coordinate geometry to one Mo(12), one Mo(3), one Ni(3), one P(12), one P(7), and two equivalent P(3) atoms. In the sixteenth Mo site, Mo(16) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(12), one P(7), and two equivalent P(4) atoms. In the seventeenth Mo site, Mo(17) is bonded in a 4-coordinate geometry to one Mo(5), one Mo(8), one P(10), one P(8), and two equivalent P(5) atoms. In the eighteenth Mo site, Mo(18) is bonded in a 4-coordinate geometry to one Mo(6), one P(11), one P(9), and two equivalent P(6) atoms. In the nineteenth Mo site, Mo(19) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(3), one P(4), and two equivalent P(7) atoms. In the twentieth Mo site, Mo(20) is bonded in a 5-coordinate geometry to one Mo(2), one Mo(8), one Ni(2), one P(1), one P(5), and two equivalent P(8) atoms. In the twenty-first Mo site, Mo(21) is bonded in a 5-coordinate geometry to one Mo(3), one Ni(3), one P(2), one P(6), and two equivalent P(9) atoms. In the twenty-second Mo site, Mo(22) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(1), one P(5), and two equivalent P(10) atoms. In the twenty-third Mo site, Mo(23) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(5), one P(2), one P(6), and two equivalent P(11) atoms. In the twenty-fourth Mo site, Mo(24) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(6), one P(3), one P(4), and two equivalent P(12) atoms. In the twenty-fifth Mo site, Mo(25) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(2), one Mo(8), two equivalent Mo(5), two equivalent Ni(2), one P(11), and one P(5) atom. In the twenty-sixth Mo site, Mo(26) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(3), two equivalent Mo(6), two equivalent Ni(3), one P(12), one P(3), and one P(6) atom. In the twenty-seventh Mo site, Mo(27) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(12), one Mo(4), one P(4), and one P(7) atom. In the twenty-eighth Mo site, Mo(28) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(8), one P(5), and one P(8) atom. In the twenty-ninth Mo site, Mo(29) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(3), one Mo(6), one P(6), and one P(9) atom. In the thirtieth Mo site, Mo(30) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(4), one Mo(8), one P(1), and one P(10) atom. In the thirty-first Mo site, Mo(31) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(11), one P(11), and one P(2) atom. In the thirty-second Mo site, Mo(32) is bonded in a 2-coordinate geometry to one Mo(3), one Mo(6), two equivalent Mo(12), one P(12), and one P(3) atom. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 2-coordinate geometry to one Mo(13), one Mo(19), one Mo(4), two equivalent Mo(1), one P(1), and one P(7) atom. In the second Ni site, Ni(2) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(14), one Mo(20), one Mo(5), one Mo(8), two equivalent Mo(2), two equivalent Mo(25), one P(2), and one P(8) atom. In the third Ni site, Ni(3) is bonded in a 2-coordinate geometry to one Mo(12), one Mo(15), one Mo(21), one Mo(6), two equivalent Mo(26), two equivalent Mo(3), one P(3), and one P(9) atom. In the fourth Ni site, Ni(4) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), two equivalent Mo(4), one P(10), and one P(4) atom. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(10), one Mo(20), one Mo(22), one Mo(30), two equivalent Mo(13), and one Ni(1) atom. In the second P site, P(2) is bonded in a 1-coordinate geometry to one Mo(11), one Mo(2), one Mo(21), one Mo(23), one Mo(31), two equivalent Mo(14), and one Ni(2) atom. In the third P site, P(3) is bonded in a 9-coordinate geometry to one Mo(12), one Mo(19), one Mo(24), one Mo(26), one Mo(3), one Mo(32), two equivalent Mo(15), and one Ni(3) atom. In the fourth P site, P(4) is bonded in a 8-coordinate geometry to one Mo(19), one Mo(24), one Mo(27), one Mo(4), one Mo(7), two equivalent Mo(16), and one Ni(4) atom. In the fifth P site, P(5) is bonded in a 8-coordinate geometry to one Mo(20), one Mo(22), one Mo(25), one Mo(28), one Mo(5), one Mo(8), and two equivalent Mo(17) atoms. In the sixth P site, P(6) is bonded in a 8-coordinate geometry to one Mo(21), one Mo(23), one Mo(26), one Mo(29), one Mo(6), one Mo(9), and two equivalent Mo(18) atoms. In the seventh P site, P(7) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(15), one Mo(16), one Mo(27), one Mo(7), two equivalent Mo(19), and one Ni(1) atom. In the eighth P site, P(8) is bonded in a 8-coordinate geometry to one Mo(13), one Mo(17), one Mo(2), one Mo(28), one Mo(8), two equivalent Mo(20), and one Ni(2) atom. In the ninth P site, P(9) is bonded in a 8-coordinate geometry to one Mo(14), one Mo(18), one Mo(29), one Mo(3), one Mo(9), two equivalent Mo(21), and one Ni(3) atom. In the tenth P site, P(10) is bonded in a 8-coordinate geometry to one Mo(10), one Mo(13), one Mo(17), one Mo(30), one Mo(4), two equivalent Mo(22), and one Ni(4) atom. In the eleventh P site, P(11) is bonded in a 8-coordinate geometry to one Mo(11), one Mo(14), one Mo(18), one Mo(25), one Mo(31), one Mo(5), and two equivalent Mo(23) atoms. In the twelfth P site, P(12) is bonded in a 8-coordinate geometry to one Mo(12), one Mo(15), one Mo(16), one Mo(26), one Mo(32), one Mo(6), and two equivalent Mo(24) atoms.
Mo8NiP3 crystallizes in the triclinic P1 space group. There are thirty-two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 14-coordinate geometry to one Mo(13), one Mo(19), one Mo(27), one Mo(30), one Mo(4), two equivalent Mo(10), two equivalent Mo(7), one Ni(4), two equivalent Ni(1), one P(1), and one P(7) atom. The Mo(1)-Mo(13) bond length is 2.92 Å. The Mo(1)-Mo(19) bond length is 2.84 Å. The Mo(1)-Mo(27) bond length is 3.12 Å. The Mo(1)-Mo(30) bond length is 3.08 Å. The Mo(1)-Mo(4) bond length is 2.62 Å. There is one shorter (2.85 Å) and one longer (3.18 Å) Mo(1)-Mo(10) bond length. There is one shorter (2.84 Å) and one longer (3.20 Å) Mo(1)-Mo(7) bond length. The Mo(1)-Ni(4) bond length is 2.82 Å. There is one shorter (2.82 Å) and one longer (2.84 Å) Mo(1)-Ni(1) bond length. The Mo(1)-P(1) bond length is 2.49 Å. The Mo(1)-P(7) bond length is 2.50 Å. In the second Mo site, Mo(2) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(20), one Mo(25), one Mo(28), one Mo(31), one Mo(5), two equivalent Mo(11), two equivalent Mo(8), two equivalent Ni(2), one P(2), and one P(8) atom. The Mo(2)-Mo(14) bond length is 2.98 Å. The Mo(2)-Mo(20) bond length is 2.89 Å. The Mo(2)-Mo(25) bond length is 2.81 Å. The Mo(2)-Mo(28) bond length is 3.05 Å. The Mo(2)-Mo(31) bond length is 3.04 Å. The Mo(2)-Mo(5) bond length is 2.61 Å. There is one shorter (2.86 Å) and one longer (3.15 Å) Mo(2)-Mo(11) bond length. There is one shorter (2.85 Å) and one longer (3.17 Å) Mo(2)-Mo(8) bond length. There is one shorter (2.80 Å) and one longer (2.83 Å) Mo(2)-Ni(2) bond length. The Mo(2)-P(2) bond length is 2.48 Å. The Mo(2)-P(8) bond length is 2.52 Å. In the third Mo site, Mo(3) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(21), one Mo(26), one Mo(29), one Mo(32), one Mo(6), two equivalent Mo(12), two equivalent Mo(9), two equivalent Ni(3), one P(3), and one P(9) atom. The Mo(3)-Mo(15) bond length is 2.99 Å. The Mo(3)-Mo(21) bond length is 2.88 Å. The Mo(3)-Mo(26) bond length is 2.80 Å. The Mo(3)-Mo(29) bond length is 3.07 Å. The Mo(3)-Mo(32) bond length is 3.04 Å. The Mo(3)-Mo(6) bond length is 2.60 Å. There is one shorter (2.86 Å) and one longer (3.14 Å) Mo(3)-Mo(12) bond length. There is one shorter (2.84 Å) and one longer (3.18 Å) Mo(3)-Mo(9) bond length. There is one shorter (2.79 Å) and one longer (2.83 Å) Mo(3)-Ni(3) bond length. The Mo(3)-P(3) bond length is 2.48 Å. The Mo(3)-P(9) bond length is 2.51 Å. In the fourth Mo site, Mo(4) is bonded in a 14-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), one Mo(27), one Mo(30), two equivalent Mo(10), two equivalent Mo(7), one Ni(1), two equivalent Ni(4), one P(10), and one P(4) atom. The Mo(4)-Mo(16) bond length is 2.90 Å. The Mo(4)-Mo(22) bond length is 2.85 Å. The Mo(4)-Mo(27) bond length is 3.10 Å. The Mo(4)-Mo(30) bond length is 3.09 Å. There is one shorter (2.87 Å) and one longer (3.18 Å) Mo(4)-Mo(10) bond length. There is one shorter (2.84 Å) and one longer (3.19 Å) Mo(4)-Mo(7) bond length. The Mo(4)-Ni(1) bond length is 2.84 Å. Both Mo(4)-Ni(4) bond lengths are 2.84 Å. The Mo(4)-P(10) bond length is 2.48 Å. The Mo(4)-P(4) bond length is 2.48 Å. In the fifth Mo site, Mo(5) is bonded in a 14-coordinate geometry to one Mo(17), one Mo(2), one Mo(23), one Mo(28), one Mo(31), two equivalent Mo(11), two equivalent Mo(25), two equivalent Mo(8), one Ni(2), one P(11), and one P(5) atom. The Mo(5)-Mo(17) bond length is 2.97 Å. The Mo(5)-Mo(23) bond length is 2.95 Å. The Mo(5)-Mo(28) bond length is 3.09 Å. The Mo(5)-Mo(31) bond length is 3.09 Å. There is one shorter (2.94 Å) and one longer (3.14 Å) Mo(5)-Mo(11) bond length. There is one shorter (2.84 Å) and one longer (2.87 Å) Mo(5)-Mo(25) bond length. There is one shorter (2.92 Å) and one longer (3.15 Å) Mo(5)-Mo(8) bond length. The Mo(5)-Ni(2) bond length is 2.89 Å. The Mo(5)-P(11) bond length is 2.47 Å. The Mo(5)-P(5) bond length is 2.50 Å. In the sixth Mo site, Mo(6) is bonded in a 14-coordinate geometry to one Mo(18), one Mo(24), one Mo(29), one Mo(3), one Mo(32), two equivalent Mo(12), two equivalent Mo(26), two equivalent Mo(9), one Ni(3), one P(12), and one P(6) atom. The Mo(6)-Mo(18) bond length is 2.96 Å. The Mo(6)-Mo(24) bond length is 2.96 Å. The Mo(6)-Mo(29) bond length is 3.11 Å. The Mo(6)-Mo(32) bond length is 3.09 Å. There is one shorter (2.93 Å) and one longer (3.13 Å) Mo(6)-Mo(12) bond length. There is one shorter (2.86 Å) and one longer (2.87 Å) Mo(6)-Mo(26) bond length. There is one shorter (2.90 Å) and one longer (3.16 Å) Mo(6)-Mo(9) bond length. The Mo(6)-Ni(3) bond length is 2.90 Å. The Mo(6)-P(12) bond length is 2.48 Å. The Mo(6)-P(6) bond length is 2.48 Å. In the seventh Mo site, Mo(7) is bonded in a 3-coordinate geometry to one Mo(10), two equivalent Mo(1), two equivalent Mo(4), one P(4), and one P(7) atom. The Mo(7)-Mo(10) bond length is 2.53 Å. The Mo(7)-P(4) bond length is 2.50 Å. The Mo(7)-P(7) bond length is 2.47 Å. In the eighth Mo site, Mo(8) is bonded in a 14-coordinate geometry to one Mo(11), one Mo(17), one Mo(20), one Mo(25), one Mo(30), two equivalent Mo(2), two equivalent Mo(28), two equivalent Mo(5), one Ni(2), one P(5), and one P(8) atom. The Mo(8)-Mo(11) bond length is 2.57 Å. The Mo(8)-Mo(17) bond length is 2.95 Å. The Mo(8)-Mo(20) bond length is 2.97 Å. The Mo(8)-Mo(25) bond length is 3.15 Å. The Mo(8)-Mo(30) bond length is 2.84 Å. There is one shorter (2.82 Å) and one longer (2.84 Å) Mo(8)-Mo(28) bond length. The Mo(8)-Ni(2) bond length is 3.02 Å. The Mo(8)-P(5) bond length is 2.52 Å. The Mo(8)-P(8) bond length is 2.48 Å. In the ninth Mo site, Mo(9) is bonded in a 3-coordinate geometry to one Mo(12), two equivalent Mo(3), two equivalent Mo(6), one P(6), and one P(9) atom. The Mo(9)-Mo(12) bond length is 2.56 Å. The Mo(9)-P(6) bond length is 2.51 Å. The Mo(9)-P(9) bond length is 2.47 Å. In the tenth Mo site, Mo(10) is bonded in a 3-coordinate geometry to one Mo(7), two equivalent Mo(1), two equivalent Mo(4), one P(1), and one P(10) atom. The Mo(10)-P(1) bond length is 2.51 Å. The Mo(10)-P(10) bond length is 2.48 Å. In the eleventh Mo site, Mo(11) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(23), one Mo(25), one Mo(29), one Mo(8), two equivalent Mo(2), two equivalent Mo(31), two equivalent Mo(5), one Ni(2), one P(11), and one P(2) atom. The Mo(11)-Mo(14) bond length is 2.93 Å. The Mo(11)-Mo(23) bond length is 2.94 Å. The Mo(11)-Mo(25) bond length is 3.16 Å. The Mo(11)-Mo(29) bond length is 2.84 Å. There is one shorter (2.80 Å) and one longer (2.85 Å) Mo(11)-Mo(31) bond length. The Mo(11)-Ni(2) bond length is 3.03 Å. The Mo(11)-P(11) bond length is 2.51 Å. The Mo(11)-P(2) bond length is 2.54 Å. In the twelfth Mo site, Mo(12) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(24), one Mo(26), one Mo(27), one Mo(9), two equivalent Mo(3), two equivalent Mo(32), two equivalent Mo(6), one Ni(3), one P(12), and one P(3) atom. The Mo(12)-Mo(15) bond length is 2.93 Å. The Mo(12)-Mo(24) bond length is 2.96 Å. The Mo(12)-Mo(26) bond length is 3.16 Å. The Mo(12)-Mo(27) bond length is 2.83 Å. There is one shorter (2.80 Å) and one longer (2.85 Å) Mo(12)-Mo(32) bond length. The Mo(12)-Ni(3) bond length is 3.02 Å. The Mo(12)-P(12) bond length is 2.52 Å. The Mo(12)-P(3) bond length is 2.55 Å. In the thirteenth Mo site, Mo(13) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(10), one P(8), and two equivalent P(1) atoms. The Mo(13)-Ni(1) bond length is 2.80 Å. The Mo(13)-P(10) bond length is 2.49 Å. The Mo(13)-P(8) bond length is 2.55 Å. There is one shorter (2.45 Å) and one longer (2.52 Å) Mo(13)-P(1) bond length. In the fourteenth Mo site, Mo(14) is bonded in a 5-coordinate geometry to one Mo(11), one Mo(2), one Ni(2), one P(11), one P(9), and two equivalent P(2) atoms. The Mo(14)-Ni(2) bond length is 2.82 Å. The Mo(14)-P(11) bond length is 2.50 Å. The Mo(14)-P(9) bond length is 2.52 Å. There is one shorter (2.45 Å) and one longer (2.54 Å) Mo(14)-P(2) bond length. In the fifteenth Mo site, Mo(15) is bonded in a 5-coordinate geometry to one Mo(12), one Mo(3), one Ni(3), one P(12), one P(7), and two equivalent P(3) atoms. The Mo(15)-Ni(3) bond length is 2.83 Å. The Mo(15)-P(12) bond length is 2.50 Å. The Mo(15)-P(7) bond length is 2.51 Å. There is one shorter (2.44 Å) and one longer (2.54 Å) Mo(15)-P(3) bond length. In the sixteenth Mo site, Mo(16) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(12), one P(7), and two equivalent P(4) atoms. The Mo(16)-Ni(4) bond length is 2.78 Å. The Mo(16)-P(12) bond length is 2.51 Å. The Mo(16)-P(7) bond length is 2.49 Å. There is one shorter (2.45 Å) and one longer (2.52 Å) Mo(16)-P(4) bond length. In the seventeenth Mo site, Mo(17) is bonded in a 4-coordinate geometry to one Mo(5), one Mo(8), one P(10), one P(8), and two equivalent P(5) atoms. The Mo(17)-P(10) bond length is 2.50 Å. The Mo(17)-P(8) bond length is 2.50 Å. There is one shorter (2.47 Å) and one longer (2.50 Å) Mo(17)-P(5) bond length. In the eighteenth Mo site, Mo(18) is bonded in a 4-coordinate geometry to one Mo(6), one P(11), one P(9), and two equivalent P(6) atoms. The Mo(18)-P(11) bond length is 2.48 Å. The Mo(18)-P(9) bond length is 2.49 Å. There is one shorter (2.47 Å) and one longer (2.50 Å) Mo(18)-P(6) bond length. In the nineteenth Mo site, Mo(19) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(3), one P(4), and two equivalent P(7) atoms. The Mo(19)-Ni(1) bond length is 2.75 Å. The Mo(19)-P(3) bond length is 2.63 Å. The Mo(19)-P(4) bond length is 2.50 Å. There is one shorter (2.45 Å) and one longer (2.51 Å) Mo(19)-P(7) bond length. In the twentieth Mo site, Mo(20) is bonded in a 5-coordinate geometry to one Mo(2), one Mo(8), one Ni(2), one P(1), one P(5), and two equivalent P(8) atoms. The Mo(20)-Ni(2) bond length is 2.74 Å. The Mo(20)-P(1) bond length is 2.56 Å. The Mo(20)-P(5) bond length is 2.49 Å. There is one shorter (2.45 Å) and one longer (2.51 Å) Mo(20)-P(8) bond length. In the twenty-first Mo site, Mo(21) is bonded in a 5-coordinate geometry to one Mo(3), one Ni(3), one P(2), one P(6), and two equivalent P(9) atoms. The Mo(21)-Ni(3) bond length is 2.72 Å. The Mo(21)-P(2) bond length is 2.61 Å. The Mo(21)-P(6) bond length is 2.50 Å. There is one shorter (2.46 Å) and one longer (2.51 Å) Mo(21)-P(9) bond length. In the twenty-second Mo site, Mo(22) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(1), one P(5), and two equivalent P(10) atoms. The Mo(22)-Ni(4) bond length is 2.74 Å. The Mo(22)-P(1) bond length is 2.50 Å. The Mo(22)-P(5) bond length is 2.53 Å. There is one shorter (2.44 Å) and one longer (2.51 Å) Mo(22)-P(10) bond length. In the twenty-third Mo site, Mo(23) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(5), one P(2), one P(6), and two equivalent P(11) atoms. The Mo(23)-P(2) bond length is 2.50 Å. The Mo(23)-P(6) bond length is 2.48 Å. There is one shorter (2.46 Å) and one longer (2.50 Å) Mo(23)-P(11) bond length. In the twenty-fourth Mo site, Mo(24) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(6), one P(3), one P(4), and two equivalent P(12) atoms. The Mo(24)-P(3) bond length is 2.50 Å. The Mo(24)-P(4) bond length is 2.50 Å. There is one shorter (2.47 Å) and one longer (2.49 Å) Mo(24)-P(12) bond length. In the twenty-fifth Mo site, Mo(25) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(2), one Mo(8), two equivalent Mo(5), two equivalent Ni(2), one P(11), and one P(5) atom. There is one shorter (2.75 Å) and one longer (2.76 Å) Mo(25)-Ni(2) bond length. The Mo(25)-P(11) bond length is 2.48 Å. The Mo(25)-P(5) bond length is 2.47 Å. In the twenty-sixth Mo site, Mo(26) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(3), two equivalent Mo(6), two equivalent Ni(3), one P(12), one P(3), and one P(6) atom. Both Mo(26)-Ni(3) bond lengths are 2.76 Å. The Mo(26)-P(12) bond length is 2.49 Å. The Mo(26)-P(3) bond length is 2.87 Å. The Mo(26)-P(6) bond length is 2.46 Å. In the twenty-seventh Mo site, Mo(27) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(12), one Mo(4), one P(4), and one P(7) atom. The Mo(27)-P(4) bond length is 2.52 Å. The Mo(27)-P(7) bond length is 2.48 Å. In the twenty-eighth Mo site, Mo(28) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(8), one P(5), and one P(8) atom. The Mo(28)-P(5) bond length is 2.46 Å. The Mo(28)-P(8) bond length is 2.48 Å. In the twenty-ninth Mo site, Mo(29) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(3), one Mo(6), one P(6), and one P(9) atom. The Mo(29)-P(6) bond length is 2.47 Å. The Mo(29)-P(9) bond length is 2.47 Å. In the thirtieth Mo site, Mo(30) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(4), one Mo(8), one P(1), and one P(10) atom. The Mo(30)-P(1) bond length is 2.50 Å. The Mo(30)-P(10) bond length is 2.49 Å. In the thirty-first Mo site, Mo(31) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(11), one P(11), and one P(2) atom. The Mo(31)-P(11) bond length is 2.46 Å. The Mo(31)-P(2) bond length is 2.53 Å. In the thirty-second Mo site, Mo(32) is bonded in a 2-coordinate geometry to one Mo(3), one Mo(6), two equivalent Mo(12), one P(12), and one P(3) atom. The Mo(32)-P(12) bond length is 2.47 Å. The Mo(32)-P(3) bond length is 2.53 Å. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 2-coordinate geometry to one Mo(13), one Mo(19), one Mo(4), two equivalent Mo(1), one P(1), and one P(7) atom. The Ni(1)-P(1) bond length is 2.35 Å. The Ni(1)-P(7) bond length is 2.36 Å. In the second Ni site, Ni(2) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(14), one Mo(20), one Mo(5), one Mo(8), two equivalent Mo(2), two equivalent Mo(25), one P(2), and one P(8) atom. The Ni(2)-P(2) bond length is 2.32 Å. The Ni(2)-P(8) bond length is 2.32 Å. In the third Ni site, Ni(3) is bonded in a 2-coordinate geometry to one Mo(12), one Mo(15), one Mo(21), one Mo(6), two equivalent Mo(26), two equivalent Mo(3), one P(3), and one P(9) atom. The Ni(3)-P(3) bond length is 2.33 Å. The Ni(3)-P(9) bond length is 2.31 Å. In the fourth Ni site, Ni(4) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), two equivalent Mo(4), one P(10), and one P(4) atom. The Ni(4)-P(10) bond length is 2.38 Å. The Ni(4)-P(4) bond length is 2.31 Å. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(10), one Mo(20), one Mo(22), one Mo(30), two equivalent Mo(13), and one Ni(1) atom. In the second P site, P(2) is bonded in a 1-coordinate geometry to one Mo(11), one Mo(2), one Mo(21), one Mo(23), one Mo(31), two equivalent Mo(14), and one Ni(2) atom. In the third P site, P(3) is bonded in a 9-coordinate geometry to one Mo(12), one Mo(19), one Mo(24), one Mo(26), one Mo(3), one Mo(32), two equivalent Mo(15), and one Ni(3) atom. In the fourth P site, P(4) is bonded in a 8-coordinate geometry to one Mo(19), one Mo(24), one Mo(27), one Mo(4), one Mo(7), two equivalent Mo(16), and one Ni(4) atom. In the fifth P site, P(5) is bonded in a 8-coordinate geometry to one Mo(20), one Mo(22), one Mo(25), one Mo(28), one Mo(5), one Mo(8), and two equivalent Mo(17) atoms. In the sixth P site, P(6) is bonded in a 8-coordinate geometry to one Mo(21), one Mo(23), one Mo(26), one Mo(29), one Mo(6), one Mo(9), and two equivalent Mo(18) atoms. In the seventh P site, P(7) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(15), one Mo(16), one Mo(27), one Mo(7), two equivalent Mo(19), and one Ni(1) atom. In the eighth P site, P(8) is bonded in a 8-coordinate geometry to one Mo(13), one Mo(17), one Mo(2), one Mo(28), one Mo(8), two equivalent Mo(20), and one Ni(2) atom. In the ninth P site, P(9) is bonded in a 8-coordinate geometry to one Mo(14), one Mo(18), one Mo(29), one Mo(3), one Mo(9), two equivalent Mo(21), and one Ni(3) atom. In the tenth P site, P(10) is bonded in a 8-coordinate geometry to one Mo(10), one Mo(13), one Mo(17), one Mo(30), one Mo(4), two equivalent Mo(22), and one Ni(4) atom. In the eleventh P site, P(11) is bonded in a 8-coordinate geometry to one Mo(11), one Mo(14), one Mo(18), one Mo(25), one Mo(31), one Mo(5), and two equivalent Mo(23) atoms. In the twelfth P site, P(12) is bonded in a 8-coordinate geometry to one Mo(12), one Mo(15), one Mo(16), one Mo(26), one Mo(32), one Mo(6), and two equivalent Mo(24) atoms.