Li4Mn3(CoO4)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-16°. In the second Li site, Li(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(2), and one O(4) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(12), and one O(9) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(11), two equivalent O(6), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-16°. In the second Mn site, Mn(2) is bonded to two equivalent O(12), two equivalent O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(3), one O(5), and two equivalent O(1) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(4), one O(6), one O(9), and two equivalent O(2) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 6°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(6), two equivalent O(8), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. In the second Co site, Co(2) is bonded to one O(11), one O(2), one O(8), one O(9), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. In the third Co site, Co(3) is bonded to two equivalent O(10), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. In the fourth Co site, Co(4) is bonded to one O(1), one O(10), one O(12), one O(7), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 13°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), two equivalent Mn(3), and one Co(4) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(6)Li2Mn2Co square pyramid,  a cornercorner with one O(8)Li2MnCo2 square pyramid, corners with two equivalent O(12)Li2Mn2Co square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(5)Li2Mn2Co square pyramid, and  an edgeedge with one O(7)Li2MnCo2 square pyramid. In the second O site, O(2) is bonded to one Li(1), one Li(3), two equivalent Mn(4), and one Co(2) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(6)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid,  a cornercorner with one O(7)Li2MnCo2 square pyramid, corners with two equivalent O(11)Li2Mn2Co square pyramids,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, and edges with two equivalent O(4)Li2MnCo2 square pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Mn(3), and two equivalent Co(4) atoms. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Mn(4), and two equivalent Co(2) atoms to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(7)Li2MnCo2 square pyramid,  a cornercorner with one O(8)Li2MnCo2 square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid,  an edgeedge with one O(4)Li2MnCo2 square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, edges with two equivalent O(11)Li2Mn2Co square pyramids, and edges with two equivalent O(2)Li2Mn2Co square pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Mn(2), one Mn(3), and one Co(3) atom to form distorted OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid, corners with two equivalent O(5)Li2Mn2Co square pyramids, corners with two equivalent O(6)Li2Mn2Co square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, and edges with three equivalent O(7)Li2MnCo2 square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Mn(1), one Mn(4), and one Co(1) atom to form distorted OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid, corners with two equivalent O(5)Li2Mn2Co square pyramids, corners with two equivalent O(6)Li2Mn2Co square pyramids,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(4)Li2MnCo2 square pyramid,  an edgeedge with one O(7)Li2MnCo2 square pyramid, and edges with three equivalent O(8)Li2MnCo2 square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Mn(2), one Co(3), and one Co(4) atom to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid, corners with two equivalent O(7)Li2MnCo2 square pyramids, corners with two equivalent O(8)Li2MnCo2 square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid, and edges with three equivalent O(5)Li2Mn2Co square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Mn(1), one Co(1), and one Co(2) atom to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid, corners with two equivalent O(7)Li2MnCo2 square pyramids, corners with two equivalent O(8)Li2MnCo2 square pyramids,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(5)Li2Mn2Co square pyramid,  an edgeedge with one O(4)Li2MnCo2 square pyramid, and edges with three equivalent O(6)Li2Mn2Co square pyramids. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(4), one Co(1), and one Co(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(3), one Co(3), and one Co(4) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(4), one Mn(1), one Mn(4), and one Co(2) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(6)Li2Mn2Co square pyramid,  a cornercorner with one O(8)Li2MnCo2 square pyramid, corners with two equivalent O(2)Li2Mn2Co square pyramids,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, and edges with two equivalent O(4)Li2MnCo2 square pyramids. In the twelfth O site, O(12) is bonded to one Li(3), one Li(4), one Mn(2), one Mn(3), and one Co(4) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid,  a cornercorner with one O(7)Li2MnCo2 square pyramid, corners with two equivalent O(1)Li2Mn2Co square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(5)Li2Mn2Co square pyramid, and  an edgeedge with one O(7)Li2MnCo2 square pyramid.
Li4Mn3(CoO4)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-16°. The Li(1)-O(1) bond length is 2.31 Å. The Li(1)-O(2) bond length is 2.49 Å. The Li(1)-O(5) bond length is 2.08 Å. The Li(1)-O(6) bond length is 2.08 Å. The Li(1)-O(7) bond length is 2.29 Å. The Li(1)-O(8) bond length is 2.19 Å. In the second Li site, Li(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. The Li(2)-O(3) bond length is 2.23 Å. The Li(2)-O(4) bond length is 2.27 Å. The Li(2)-O(5) bond length is 2.15 Å. The Li(2)-O(6) bond length is 2.12 Å. The Li(2)-O(7) bond length is 2.15 Å. The Li(2)-O(8) bond length is 2.13 Å. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(2), and one O(4) atom. The Li(3)-O(10) bond length is 2.05 Å. The Li(3)-O(11) bond length is 2.01 Å. The Li(3)-O(12) bond length is 2.20 Å. The Li(3)-O(2) bond length is 2.08 Å. The Li(3)-O(4) bond length is 2.45 Å. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(12), and one O(9) atom. The Li(4)-O(1) bond length is 2.07 Å. The Li(4)-O(11) bond length is 2.26 Å. The Li(4)-O(12) bond length is 1.96 Å. The Li(4)-O(9) bond length is 1.95 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(11), two equivalent O(6), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-16°. Both Mn(1)-O(11) bond lengths are 2.20 Å. Both Mn(1)-O(6) bond lengths are 2.01 Å. Both Mn(1)-O(8) bond lengths are 1.95 Å. In the second Mn site, Mn(2) is bonded to two equivalent O(12), two equivalent O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. Both Mn(2)-O(12) bond lengths are 2.23 Å. Both Mn(2)-O(5) bond lengths are 2.01 Å. Both Mn(2)-O(7) bond lengths are 1.96 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(3), one O(5), and two equivalent O(1) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. The Mn(3)-O(10) bond length is 1.96 Å. The Mn(3)-O(12) bond length is 1.90 Å. The Mn(3)-O(3) bond length is 1.93 Å. The Mn(3)-O(5) bond length is 1.98 Å. Both Mn(3)-O(1) bond lengths are 1.96 Å. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(4), one O(6), one O(9), and two equivalent O(2) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 6°. The Mn(4)-O(11) bond length is 1.93 Å. The Mn(4)-O(4) bond length is 1.93 Å. The Mn(4)-O(6) bond length is 1.96 Å. The Mn(4)-O(9) bond length is 1.93 Å. There is one shorter (1.97 Å) and one longer (1.99 Å) Mn(4)-O(2) bond length. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(6), two equivalent O(8), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. Both Co(1)-O(6) bond lengths are 2.08 Å. Both Co(1)-O(8) bond lengths are 1.92 Å. Both Co(1)-O(9) bond lengths are 2.08 Å. In the second Co site, Co(2) is bonded to one O(11), one O(2), one O(8), one O(9), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. The Co(2)-O(11) bond length is 1.92 Å. The Co(2)-O(2) bond length is 1.95 Å. The Co(2)-O(8) bond length is 2.16 Å. The Co(2)-O(9) bond length is 1.90 Å. There is one shorter (1.88 Å) and one longer (2.13 Å) Co(2)-O(4) bond length. In the third Co site, Co(3) is bonded to two equivalent O(10), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 12-13°. Both Co(3)-O(10) bond lengths are 2.07 Å. Both Co(3)-O(5) bond lengths are 2.08 Å. Both Co(3)-O(7) bond lengths are 1.94 Å. In the fourth Co site, Co(4) is bonded to one O(1), one O(10), one O(12), one O(7), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 13°. The Co(4)-O(1) bond length is 2.06 Å. The Co(4)-O(10) bond length is 1.90 Å. The Co(4)-O(12) bond length is 2.00 Å. The Co(4)-O(7) bond length is 2.11 Å. There is one shorter (1.94 Å) and one longer (2.08 Å) Co(4)-O(3) bond length. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), two equivalent Mn(3), and one Co(4) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(6)Li2Mn2Co square pyramid,  a cornercorner with one O(8)Li2MnCo2 square pyramid, corners with two equivalent O(12)Li2Mn2Co square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(5)Li2Mn2Co square pyramid, and  an edgeedge with one O(7)Li2MnCo2 square pyramid. In the second O site, O(2) is bonded to one Li(1), one Li(3), two equivalent Mn(4), and one Co(2) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(6)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid,  a cornercorner with one O(7)Li2MnCo2 square pyramid, corners with two equivalent O(11)Li2Mn2Co square pyramids,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, and edges with two equivalent O(4)Li2MnCo2 square pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Mn(3), and two equivalent Co(4) atoms. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Mn(4), and two equivalent Co(2) atoms to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(7)Li2MnCo2 square pyramid,  a cornercorner with one O(8)Li2MnCo2 square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid,  an edgeedge with one O(4)Li2MnCo2 square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, edges with two equivalent O(11)Li2Mn2Co square pyramids, and edges with two equivalent O(2)Li2Mn2Co square pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Mn(2), one Mn(3), and one Co(3) atom to form distorted OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid, corners with two equivalent O(5)Li2Mn2Co square pyramids, corners with two equivalent O(6)Li2Mn2Co square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, and edges with three equivalent O(7)Li2MnCo2 square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Mn(1), one Mn(4), and one Co(1) atom to form distorted OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid, corners with two equivalent O(5)Li2Mn2Co square pyramids, corners with two equivalent O(6)Li2Mn2Co square pyramids,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(4)Li2MnCo2 square pyramid,  an edgeedge with one O(7)Li2MnCo2 square pyramid, and edges with three equivalent O(8)Li2MnCo2 square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Mn(2), one Co(3), and one Co(4) atom to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid, corners with two equivalent O(7)Li2MnCo2 square pyramids, corners with two equivalent O(8)Li2MnCo2 square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid, and edges with three equivalent O(5)Li2Mn2Co square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Mn(1), one Co(1), and one Co(2) atom to form OLi2MnCo2 square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid, corners with two equivalent O(7)Li2MnCo2 square pyramids, corners with two equivalent O(8)Li2MnCo2 square pyramids,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(5)Li2Mn2Co square pyramid,  an edgeedge with one O(4)Li2MnCo2 square pyramid, and edges with three equivalent O(6)Li2Mn2Co square pyramids. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(4), one Mn(4), one Co(1), and one Co(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(3), one Co(3), and one Co(4) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(4), one Mn(1), one Mn(4), and one Co(2) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(1)Li2Mn2Co square pyramid,  a cornercorner with one O(11)Li2Mn2Co square pyramid,  a cornercorner with one O(6)Li2Mn2Co square pyramid,  a cornercorner with one O(8)Li2MnCo2 square pyramid, corners with two equivalent O(2)Li2Mn2Co square pyramids,  an edgeedge with one O(12)Li2Mn2Co square pyramid,  an edgeedge with one O(2)Li2Mn2Co square pyramid,  an edgeedge with one O(6)Li2Mn2Co square pyramid,  an edgeedge with one O(8)Li2MnCo2 square pyramid, and edges with two equivalent O(4)Li2MnCo2 square pyramids. In the twelfth O site, O(12) is bonded to one Li(3), one Li(4), one Mn(2), one Mn(3), and one Co(4) atom to form OLi2Mn2Co square pyramids that share  a cornercorner with one O(12)Li2Mn2Co square pyramid,  a cornercorner with one O(2)Li2Mn2Co square pyramid,  a cornercorner with one O(5)Li2Mn2Co square pyramid,  a cornercorner with one O(4)Li2MnCo2 square pyramid,  a cornercorner with one O(7)Li2MnCo2 square pyramid, corners with two equivalent O(1)Li2Mn2Co square pyramids,  an edgeedge with one O(1)Li2Mn2Co square pyramid,  an edgeedge with one O(11)Li2Mn2Co square pyramid,  an edgeedge with one O(5)Li2Mn2Co square pyramid, and  an edgeedge with one O(7)Li2MnCo2 square pyramid.