PtS2(NO2)4 is alpha structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two PtS2(NO2)4 clusters. Pt(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent O(2) atoms to form PtN4O2 octahedra that share corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pt(1) atom. S(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form SO4 tetrahedra that share  a cornercorner with one Pt(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 57°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom.
PtS2(NO2)4 is alpha structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two PtS2(NO2)4 clusters. Pt(1) is bonded to two equivalent N(1), two equivalent N(2), and two equivalent O(2) atoms to form PtN4O2 octahedra that share corners with two equivalent S(1)O4 tetrahedra. Both Pt(1)-N(1) bond lengths are 2.03 Å. Both Pt(1)-N(2) bond lengths are 2.06 Å. Both Pt(1)-O(2) bond lengths are 2.02 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pt(1) atom. S(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form SO4 tetrahedra that share  a cornercorner with one Pt(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 57°. The S(1)-O(2) bond length is 1.59 Å. The S(1)-O(3) bond length is 1.46 Å. Both S(1)-O(1) bond lengths are 1.47 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom.