LiIrSn4 crystallizes in the tetragonal I4/mcm space group. Li(1) is bonded in a q6 geometry to two equivalent Ir(1) and eight equivalent Sn(1) atoms. Ir(1) is bonded in a distorted q6 geometry to two equivalent Li(1) and eight equivalent Sn(1) atoms. Sn(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ir(1) atoms.
LiIrSn4 crystallizes in the tetragonal I4/mcm space group. Li(1) is bonded in a q6 geometry to two equivalent Ir(1) and eight equivalent Sn(1) atoms. Both Li(1)-Ir(1) bond lengths are 2.85 Å. All Li(1)-Sn(1) bond lengths are 2.93 Å. Ir(1) is bonded in a distorted q6 geometry to two equivalent Li(1) and eight equivalent Sn(1) atoms. All Ir(1)-Sn(1) bond lengths are 2.82 Å. Sn(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ir(1) atoms.