(WO3)3Tl crystallizes in the hexagonal P6mm space group. The structure consists of one 7440-28-0 atom inside a WO3 framework. In the WO3 framework, W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-30°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.
(WO3)3Tl crystallizes in the hexagonal P6mm space group. The structure consists of one 7440-28-0 atom inside a WO3 framework. In the WO3 framework, W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-30°. Both W(1)-O(1) bond lengths are 1.91 Å. All W(1)-O(2) bond lengths are 1.92 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms.