InBi2S4Cl crystallizes in the monoclinic C2/m space group. In(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form edge-sharing InS6 octahedra. Bi(1) is bonded in a 7-coordinate geometry to two equivalent S(1), three equivalent S(2), and two equivalent Cl(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one In(1) and two equivalent Bi(1) atoms. In the second S site, S(2) is bonded in a 5-coordinate geometry to two equivalent In(1) and three equivalent Bi(1) atoms. Cl(1) is bonded in a distorted square co-planar geometry to four equivalent Bi(1) atoms.
InBi2S4Cl crystallizes in the monoclinic C2/m space group. In(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form edge-sharing InS6 octahedra. Both In(1)-S(1) bond lengths are 2.62 Å. All In(1)-S(2) bond lengths are 2.69 Å. Bi(1) is bonded in a 7-coordinate geometry to two equivalent S(1), three equivalent S(2), and two equivalent Cl(1) atoms. Both Bi(1)-S(1) bond lengths are 2.70 Å. There is one shorter (2.72 Å) and two longer (3.18 Å) Bi(1)-S(2) bond lengths. Both Bi(1)-Cl(1) bond lengths are 3.16 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one In(1) and two equivalent Bi(1) atoms. In the second S site, S(2) is bonded in a 5-coordinate geometry to two equivalent In(1) and three equivalent Bi(1) atoms. Cl(1) is bonded in a distorted square co-planar geometry to four equivalent Bi(1) atoms.