Ca2Cd3(OCl)10(O2)4 crystallizes in the triclinic P-1 space group. The structure consists of four hydrogen peroxide molecules inside a Ca2Cd3(OCl)10 framework. In the Ca2Cd3(OCl)10 framework, Ca(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), and two equivalent O(4) atoms. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a square co-planar geometry to two equivalent Cl(3) and two equivalent Cl(4) atoms. In the second Cd site, Cd(2) is bonded to one Cl(1), one Cl(2), one Cl(4), one Cl(5), and two equivalent Cl(3) atoms to form edge-sharing CdCl6 octahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one O(7) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ca(1) and one Cl(5) atom. In the third O site, O(4) is bonded in a trigonal planar geometry to two equivalent Ca(1) and one Cl(2) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Ca(1) and one Cl(1) atom. In the fifth O site, O(7) is bonded in a distorted water-like geometry to one O(1) and one O(7) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Cd(2) and one O(5) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Cd(2) and one O(4) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to one Cd(1) and two equivalent Cd(2) atoms. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one Cd(1) and one Cd(2) atom. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to one Cd(2) and one O(2) atom.
Ca2Cd3(OCl)10(O2)4 crystallizes in the triclinic P-1 space group. The structure consists of four hydrogen peroxide molecules inside a Ca2Cd3(OCl)10 framework. In the Ca2Cd3(OCl)10 framework, Ca(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), and two equivalent O(4) atoms. The Ca(1)-O(1) bond length is 2.50 Å. The Ca(1)-O(2) bond length is 2.19 Å. The Ca(1)-O(5) bond length is 2.26 Å. There is one shorter (2.30 Å) and one longer (2.38 Å) Ca(1)-O(4) bond length. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a square co-planar geometry to two equivalent Cl(3) and two equivalent Cl(4) atoms. Both Cd(1)-Cl(3) bond lengths are 2.72 Å. Both Cd(1)-Cl(4) bond lengths are 2.46 Å. In the second Cd site, Cd(2) is bonded to one Cl(1), one Cl(2), one Cl(4), one Cl(5), and two equivalent Cl(3) atoms to form edge-sharing CdCl6 octahedra. The Cd(2)-Cl(1) bond length is 2.72 Å. The Cd(2)-Cl(2) bond length is 2.79 Å. The Cd(2)-Cl(4) bond length is 2.59 Å. The Cd(2)-Cl(5) bond length is 2.72 Å. There is one shorter (2.68 Å) and one longer (2.74 Å) Cd(2)-Cl(3) bond length. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ca(1) and one O(7) atom. The O(1)-O(7) bond length is 1.24 Å. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ca(1) and one Cl(5) atom. The O(2)-Cl(5) bond length is 1.62 Å. In the third O site, O(4) is bonded in a trigonal planar geometry to two equivalent Ca(1) and one Cl(2) atom. The O(4)-Cl(2) bond length is 1.66 Å. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Ca(1) and one Cl(1) atom. The O(5)-Cl(1) bond length is 1.64 Å. In the fifth O site, O(7) is bonded in a distorted water-like geometry to one O(1) and one O(7) atom. The O(7)-O(7) bond length is 1.97 Å. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Cd(2) and one O(5) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Cd(2) and one O(4) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to one Cd(1) and two equivalent Cd(2) atoms. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one Cd(1) and one Cd(2) atom. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to one Cd(2) and one O(2) atom.