LiSnVO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-61°. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Sn(1)O6 octahedra. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one V(1), and two equivalent Sn(1) atoms to form distorted OLiVSn2 trigonal pyramids that share corners with six equivalent O(2)LiV2Sn trigonal pyramids, corners with six equivalent O(1)LiVSn2 trigonal pyramids,  an edgeedge with one O(1)LiVSn2 trigonal pyramid, and edges with two equivalent O(2)LiV2Sn trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), two equivalent V(1), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share corners with six equivalent O(2)LiV2Sn trigonal pyramids, corners with six equivalent O(1)LiVSn2 trigonal pyramids,  an edgeedge with one O(2)LiV2Sn trigonal pyramid, and edges with two equivalent O(1)LiVSn2 trigonal pyramids.
LiSnVO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent V(1)O6 octahedra and corners with six equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-61°. Both Li(1)-O(1) bond lengths are 2.03 Å. Both Li(1)-O(2) bond lengths are 2.14 Å. V(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, and edges with four equivalent Sn(1)O6 octahedra. Both V(1)-O(1) bond lengths are 2.14 Å. All V(1)-O(2) bond lengths are 2.05 Å. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. Both Sn(1)-O(2) bond lengths are 2.11 Å. All Sn(1)-O(1) bond lengths are 2.11 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one V(1), and two equivalent Sn(1) atoms to form distorted OLiVSn2 trigonal pyramids that share corners with six equivalent O(2)LiV2Sn trigonal pyramids, corners with six equivalent O(1)LiVSn2 trigonal pyramids,  an edgeedge with one O(1)LiVSn2 trigonal pyramid, and edges with two equivalent O(2)LiV2Sn trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), two equivalent V(1), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share corners with six equivalent O(2)LiV2Sn trigonal pyramids, corners with six equivalent O(1)LiVSn2 trigonal pyramids,  an edgeedge with one O(2)LiV2Sn trigonal pyramid, and edges with two equivalent O(1)LiVSn2 trigonal pyramids.