VC4P2N3(ClF6)2 is gamma plutonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four VC4P2N3(ClF6)2 clusters. V(1) is bonded to two equivalent N(1) and two equivalent Cl(1) atoms to form VN2Cl2 tetrahedra that share corners with two equivalent P(1)C2N2 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one P(1); one F(2,6); one F(4); and one F(5) atom to form distorted corner-sharing CPF3 tetrahedra. In the second C site, C(2) is bonded to one P(1); one F(1); one F(2,6); and one F(3) atom to form distorted corner-sharing CPF3 tetrahedra. P(1) is bonded to one C(1), one C(2), one N(1), and one N(2) atom to form PC2N2 tetrahedra that share  a cornercorner with one V(1)N2Cl2 tetrahedra and  a cornercorner with one P(1)C2N2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. Cl(1) is bonded in a single-bond geometry to one V(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(2) atom. In the second F site, F(2,6) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(1) atom.
VC4P2N3(ClF6)2 is gamma plutonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four VC4P2N3(ClF6)2 clusters. V(1) is bonded to two equivalent N(1) and two equivalent Cl(1) atoms to form VN2Cl2 tetrahedra that share corners with two equivalent P(1)C2N2 tetrahedra. Both V(1)-N(1) bond lengths are 1.76 Å. Both V(1)-Cl(1) bond lengths are 2.17 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded to one P(1); one F(2,6); one F(4); and one F(5) atom to form distorted corner-sharing CPF3 tetrahedra. The C(1)-P(1) bond length is 1.90 Å. The C(1)-F(2,6) bond length is 1.35 Å. The C(1)-F(4) bond length is 1.36 Å. The C(1)-F(5) bond length is 1.35 Å. In the second C site, C(2) is bonded to one P(1); one F(1); one F(2,6); and one F(3) atom to form distorted corner-sharing CPF3 tetrahedra. The C(2)-P(1) bond length is 1.90 Å. The C(2)-F(1) bond length is 1.35 Å. The C(2)-F(2,6) bond length is 1.36 Å. The C(2)-F(3) bond length is 1.36 Å. P(1) is bonded to one C(1), one C(2), one N(1), and one N(2) atom to form PC2N2 tetrahedra that share  a cornercorner with one V(1)N2Cl2 tetrahedra and  a cornercorner with one P(1)C2N2 tetrahedra. The P(1)-N(1) bond length is 1.61 Å. The P(1)-N(2) bond length is 1.59 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. Cl(1) is bonded in a single-bond geometry to one V(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(2) atom. In the second F site, F(2,6) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(1) atom.