(Cs)2CsSbI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsSbI6 framework. In the CsSbI6 framework, Cs(2) is bonded to six equivalent I(1) atoms to form CsI6 octahedra that share corners with six equivalent Sb(1)I6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent I(1) atoms to form SbI6 octahedra that share corners with six equivalent Cs(2)I6 octahedra. The corner-sharing octahedra are not tilted. I(1) is bonded in a linear geometry to one Cs(2) and one Sb(1) atom.
(Cs)2CsSbI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-46-2 atoms inside a CsSbI6 framework. In the CsSbI6 framework, Cs(2) is bonded to six equivalent I(1) atoms to form CsI6 octahedra that share corners with six equivalent Sb(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Cs(2)-I(1) bond lengths are 3.63 Å. Sb(1) is bonded to six equivalent I(1) atoms to form SbI6 octahedra that share corners with six equivalent Cs(2)I6 octahedra. The corner-sharing octahedra are not tilted. All Sb(1)-I(1) bond lengths are 3.03 Å. I(1) is bonded in a linear geometry to one Cs(2) and one Sb(1) atom.