LiLa2TiCrO6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LaO6 octahedra that share corners with three equivalent Cr(1)O5 square pyramids and  an edgeedge with one Cr(1)O5 square pyramid. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Ti(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted CrO5 square pyramids that share corners with three equivalent La(1)O6 octahedra and  an edgeedge with one La(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one La(1), one La(2), and one Ti(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom.
LiLa2TiCrO6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), one O(5), and one O(6) atom. The Li(1)-O(3) bond length is 2.07 Å. The Li(1)-O(4) bond length is 2.23 Å. The Li(1)-O(5) bond length is 1.87 Å. The Li(1)-O(6) bond length is 1.89 Å. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted LaO6 octahedra that share corners with three equivalent Cr(1)O5 square pyramids and  an edgeedge with one Cr(1)O5 square pyramid. The La(1)-O(1) bond length is 2.39 Å. The La(1)-O(2) bond length is 2.41 Å. The La(1)-O(3) bond length is 2.47 Å. The La(1)-O(4) bond length is 2.49 Å. The La(1)-O(5) bond length is 2.39 Å. The La(1)-O(6) bond length is 2.41 Å. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The La(2)-O(1) bond length is 2.50 Å. The La(2)-O(2) bond length is 2.46 Å. The La(2)-O(3) bond length is 2.79 Å. The La(2)-O(4) bond length is 2.38 Å. The La(2)-O(5) bond length is 2.38 Å. The La(2)-O(6) bond length is 2.42 Å. Ti(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Ti(1)-O(1) bond length is 2.06 Å. The Ti(1)-O(2) bond length is 1.96 Å. The Ti(1)-O(3) bond length is 2.09 Å. The Ti(1)-O(4) bond length is 1.96 Å. The Ti(1)-O(5) bond length is 2.32 Å. The Ti(1)-O(6) bond length is 2.42 Å. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted CrO5 square pyramids that share corners with three equivalent La(1)O6 octahedra and  an edgeedge with one La(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. The Cr(1)-O(1) bond length is 2.05 Å. The Cr(1)-O(2) bond length is 2.64 Å. The Cr(1)-O(3) bond length is 2.09 Å. The Cr(1)-O(5) bond length is 2.19 Å. The Cr(1)-O(6) bond length is 2.14 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one La(1), one La(2), and one Ti(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal bipyramidal geometry to one Li(1), one La(1), one La(2), one Ti(1), and one Cr(1) atom.