Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. In the second Ag site, Ag(2) is bonded in a distorted octahedral geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ag(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Ag(1) and one Ag(2) atom.
Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. The Ag(1)-F(1) bond length is 1.96 Å. The Ag(1)-F(2) bond length is 1.93 Å. The Ag(1)-F(3) bond length is 1.96 Å. The Ag(1)-F(4) bond length is 1.92 Å. In the second Ag site, Ag(2) is bonded in a distorted octahedral geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. Both Ag(2)-F(1) bond lengths are 2.07 Å. Both Ag(2)-F(3) bond lengths are 2.13 Å. Both Ag(2)-F(4) bond lengths are 2.46 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ag(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Ag(1) and one Ag(2) atom.