SbOF crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one F(1), and one F(3) atom. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one F(2), and one F(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(3) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(3) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Sb(2) and one Sb(3) atom.
SbOF crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. The Sb(1)-O(2) bond length is 1.98 Å. The Sb(1)-O(3) bond length is 2.16 Å. There is one shorter (2.06 Å) and one longer (2.26 Å) Sb(1)-O(1) bond length. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one F(1), and one F(3) atom. The Sb(2)-O(2) bond length is 1.99 Å. The Sb(2)-O(3) bond length is 2.07 Å. The Sb(2)-F(1) bond length is 1.97 Å. The Sb(2)-F(3) bond length is 2.38 Å. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one F(2), and one F(3) atom. The Sb(3)-O(1) bond length is 2.04 Å. The Sb(3)-O(3) bond length is 2.11 Å. The Sb(3)-F(2) bond length is 1.97 Å. The Sb(3)-F(3) bond length is 2.30 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(3) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(3) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Sb(2) and one Sb(3) atom.