MnOSO4 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 39°. S(1) is bonded to two equivalent O(2) and two equivalent O(3) atoms to form SO4 tetrahedra that share corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-49°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom.
MnOSO4 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 39°. Both Mn(1)-O(1) bond lengths are 1.84 Å. Both Mn(1)-O(2) bond lengths are 2.06 Å. Both Mn(1)-O(3) bond lengths are 2.09 Å. S(1) is bonded to two equivalent O(2) and two equivalent O(3) atoms to form SO4 tetrahedra that share corners with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-49°. Both S(1)-O(2) bond lengths are 1.49 Å. Both S(1)-O(3) bond lengths are 1.48 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom.