Cs2VAgS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one V(1), and one Ag(1) atom.
Cs2VAgS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. There are a spread of Cs(1)-S(1) bond distances ranging from 3.55-3.98 Å. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All V(1)-S(1) bond lengths are 2.19 Å. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All Ag(1)-S(1) bond lengths are 2.53 Å. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one V(1), and one Ag(1) atom.