CP3N3Cl7SbCl6Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, two CP3N3Cl7 clusters, and two SbCl6 clusters. In each CP3N3Cl7 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a water-like geometry to one N(2) and one Cl(9) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one N(3), one Cl(3), one Cl(6), and one Cl(7) atom. In the third P site, P(3) is bonded in a tetrahedral geometry to one N(1), one Cl(2), one Cl(4), and one Cl(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one P(2) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one P(3) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one P(3) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(7) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Cl site, Cl(9) is bonded in a single-bond geometry to one P(1) atom. In each SbCl6 cluster, Sb(1) is bonded in a distorted see-saw-like geometry to one Cl(1), one Cl(10), one Cl(14), one Cl(15), and one Cl(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(15) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(5) is bonded in a distorted water-like geometry to one Sb(1) and one Cl(12) atom. In the fifth Cl site, Cl(10) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(12) is bonded in a single-bond geometry to one Cl(5) atom.
CP3N3Cl7SbCl6Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7782-50-5 molecules, two CP3N3Cl7 clusters, and two SbCl6 clusters. In each CP3N3Cl7 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.38 Å. The C(1)-N(3) bond length is 1.35 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded in a water-like geometry to one N(2) and one Cl(9) atom. The P(1)-N(2) bond length is 1.60 Å. The P(1)-Cl(9) bond length is 2.01 Å. In the second P site, P(2) is bonded in a tetrahedral geometry to one N(3), one Cl(3), one Cl(6), and one Cl(7) atom. The P(2)-N(3) bond length is 1.58 Å. The P(2)-Cl(3) bond length is 1.99 Å. The P(2)-Cl(6) bond length is 1.98 Å. The P(2)-Cl(7) bond length is 2.00 Å. In the third P site, P(3) is bonded in a tetrahedral geometry to one N(1), one Cl(2), one Cl(4), and one Cl(8) atom. The P(3)-N(1) bond length is 1.59 Å. The P(3)-Cl(2) bond length is 1.98 Å. The P(3)-Cl(4) bond length is 1.98 Å. The P(3)-Cl(8) bond length is 2.00 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one P(2) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one P(3) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one P(3) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(7) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(8) is bonded in a single-bond geometry to one P(3) atom. In the seventh Cl site, Cl(9) is bonded in a single-bond geometry to one P(1) atom. In each SbCl6 cluster, Sb(1) is bonded in a distorted see-saw-like geometry to one Cl(1), one Cl(10), one Cl(14), one Cl(15), and one Cl(5) atom. The Sb(1)-Cl(1) bond length is 2.42 Å. The Sb(1)-Cl(10) bond length is 2.47 Å. The Sb(1)-Cl(14) bond length is 2.61 Å. The Sb(1)-Cl(15) bond length is 2.63 Å. The Sb(1)-Cl(5) bond length is 3.20 Å. There are six inequivalent Cl sites. In the first Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(15) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(5) is bonded in a distorted water-like geometry to one Sb(1) and one Cl(12) atom. The Cl(5)-Cl(12) bond length is 2.01 Å. In the fifth Cl site, Cl(10) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(12) is bonded in a single-bond geometry to one Cl(5) atom.