(Na)2NaTmCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaTmCl6 framework. In the NaTmCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Tm(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Tm(1) is bonded to six equivalent Cl(1) atoms to form TmCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Na(2) and one Tm(1) atom.
(Na)2NaTmCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaTmCl6 framework. In the NaTmCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Tm(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-Cl(1) bond lengths are 2.70 Å. Tm(1) is bonded to six equivalent Cl(1) atoms to form TmCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Tm(1)-Cl(1) bond lengths are 2.58 Å. Cl(1) is bonded in a linear geometry to one Na(2) and one Tm(1) atom.