CCl3SiF3 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four (trifluoromethyl)trichlorosilane molecules. Si(1) is bonded in a tetrahedral geometry to one C(1), one Cl(1), and two equivalent Cl(2) atoms. C(1) is bonded in a distorted tetrahedral geometry to one Si(1), one F(2), and two equivalent F(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Si(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Si(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.
CCl3SiF3 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four (trifluoromethyl)trichlorosilane molecules. Si(1) is bonded in a tetrahedral geometry to one C(1), one Cl(1), and two equivalent Cl(2) atoms. The Si(1)-C(1) bond length is 1.94 Å. The Si(1)-Cl(1) bond length is 2.03 Å. Both Si(1)-Cl(2) bond lengths are 2.03 Å. C(1) is bonded in a distorted tetrahedral geometry to one Si(1), one F(2), and two equivalent F(1) atoms. The C(1)-F(2) bond length is 1.37 Å. Both C(1)-F(1) bond lengths are 1.37 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Si(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Si(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom.