P4(S2O)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two P4(S2O)3 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(3), one O(1), and one O(2) atom to form distorted corner-sharing PS2O2 tetrahedra. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one S(4) and two equivalent S(3) atoms. In the third P site, P(3) is bonded to one S(2), one S(4), and two equivalent O(1) atoms to form distorted corner-sharing PS2O2 tetrahedra. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one P(2) and one P(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms.
P4(S2O)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two P4(S2O)3 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one S(3), one O(1), and one O(2) atom to form distorted corner-sharing PS2O2 tetrahedra. The P(1)-S(1) bond length is 1.88 Å. The P(1)-S(3) bond length is 2.07 Å. The P(1)-O(1) bond length is 1.62 Å. The P(1)-O(2) bond length is 1.62 Å. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one S(4) and two equivalent S(3) atoms. The P(2)-S(4) bond length is 2.13 Å. Both P(2)-S(3) bond lengths are 2.13 Å. In the third P site, P(3) is bonded to one S(2), one S(4), and two equivalent O(1) atoms to form distorted corner-sharing PS2O2 tetrahedra. The P(3)-S(2) bond length is 1.88 Å. The P(3)-S(4) bond length is 2.07 Å. Both P(3)-O(1) bond lengths are 1.61 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one P(2) and one P(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms.