WO4 is Indium-like structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two WO4 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms. In the second W site, W(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one W(2) atom. In the second O site, O(1) is bonded in a distorted T-shaped geometry to one W(1) and two equivalent W(2) atoms. In the third O site, O(2) is bonded in a single-bond geometry to one W(1) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one W(1) atom.
WO4 is Indium-like structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two WO4 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms. The W(1)-O(1) bond length is 2.34 Å. The W(1)-O(2) bond length is 1.76 Å. Both W(1)-O(3) bond lengths are 1.91 Å. Both W(1)-O(4) bond lengths are 2.00 Å. In the second W site, W(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. Both W(2)-O(1) bond lengths are 2.20 Å. Both W(2)-O(3) bond lengths are 1.99 Å. Both W(2)-O(5) bond lengths are 1.79 Å. There are five inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one W(2) atom. In the second O site, O(1) is bonded in a distorted T-shaped geometry to one W(1) and two equivalent W(2) atoms. In the third O site, O(2) is bonded in a single-bond geometry to one W(1) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one W(1) atom.