VFeSbO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with four equivalent Fe(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. Fe(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form FeO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one Fe(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Fe(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one Fe(1), and one Sb(1) atom.
VFeSbO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with four equivalent Fe(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. Both V(1)-O(1) bond lengths are 1.96 Å. Both V(1)-O(2) bond lengths are 1.95 Å. Both V(1)-O(3) bond lengths are 1.98 Å. Fe(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form FeO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. Both Fe(1)-O(1) bond lengths are 2.02 Å. Both Fe(1)-O(2) bond lengths are 2.06 Å. Both Fe(1)-O(3) bond lengths are 2.01 Å. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent V(1)O6 octahedra, corners with four equivalent Fe(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. Both Sb(1)-O(1) bond lengths are 2.02 Å. Both Sb(1)-O(2) bond lengths are 2.02 Å. Both Sb(1)-O(3) bond lengths are 2.01 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one Fe(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Fe(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one Fe(1), and one Sb(1) atom.