CaMgBiSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with six equivalent Bi(1)O12 cuboctahedra, faces with four equivalent Mg(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to twelve equivalent O(1) atoms to form BiO12 cuboctahedra that share corners with twelve equivalent Bi(1)O12 cuboctahedra, faces with six equivalent Ca(1)O12 cuboctahedra, faces with four equivalent Mg(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent Ca(1), one Mg(1), two equivalent Bi(1), and one Sb(1) atom.
CaMgBiSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Ca(1) is bonded to twelve equivalent O(1) atoms to form CaO12 cuboctahedra that share corners with twelve equivalent Ca(1)O12 cuboctahedra, faces with six equivalent Bi(1)O12 cuboctahedra, faces with four equivalent Mg(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. All Ca(1)-O(1) bond lengths are 2.81 Å. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Mg(1)-O(1) bond lengths are 2.01 Å. Bi(1) is bonded to twelve equivalent O(1) atoms to form BiO12 cuboctahedra that share corners with twelve equivalent Bi(1)O12 cuboctahedra, faces with six equivalent Ca(1)O12 cuboctahedra, faces with four equivalent Mg(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. All Bi(1)-O(1) bond lengths are 2.81 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra, faces with four equivalent Ca(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Sb(1)-O(1) bond lengths are 1.97 Å. O(1) is bonded in a distorted linear geometry to two equivalent Ca(1), one Mg(1), two equivalent Bi(1), and one Sb(1) atom.