Ce2CdS4 crystallizes in the tetragonal I-42d space group. Ce(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Cd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1) and one Cd(1) atom.
Ce2CdS4 crystallizes in the tetragonal I-42d space group. Ce(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. There are a spread of Ce(1)-S(1) bond distances ranging from 2.80-3.23 Å. Cd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. All Cd(1)-S(1) bond lengths are 2.72 Å. S(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1) and one Cd(1) atom.