PdNiGe2 crystallizes in the orthorhombic Pmc2_1 space group. Pd(1) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent Ge(2), and four equivalent Ge(1) atoms. Ni(1) is bonded in a 8-coordinate geometry to two equivalent Pd(1), two equivalent Ge(1), and four equivalent Ge(2) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 6-coordinate geometry to four equivalent Pd(1) and two equivalent Ni(1) atoms. In the second Ge site, Ge(2) is bonded in a 6-coordinate geometry to two equivalent Pd(1) and four equivalent Ni(1) atoms.
PdNiGe2 crystallizes in the orthorhombic Pmc2_1 space group. Pd(1) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent Ge(2), and four equivalent Ge(1) atoms. Both Pd(1)-Ni(1) bond lengths are 2.91 Å. There is one shorter (2.48 Å) and one longer (2.77 Å) Pd(1)-Ge(2) bond length. There are two shorter (2.57 Å) and two longer (2.60 Å) Pd(1)-Ge(1) bond lengths. Ni(1) is bonded in a 8-coordinate geometry to two equivalent Pd(1), two equivalent Ge(1), and four equivalent Ge(2) atoms. There is one shorter (2.40 Å) and one longer (2.45 Å) Ni(1)-Ge(1) bond length. There are two shorter (2.41 Å) and two longer (2.52 Å) Ni(1)-Ge(2) bond lengths. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 6-coordinate geometry to four equivalent Pd(1) and two equivalent Ni(1) atoms. In the second Ge site, Ge(2) is bonded in a 6-coordinate geometry to two equivalent Pd(1) and four equivalent Ni(1) atoms.