LiAlO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Li(1) is bonded to twelve equivalent O(1) atoms to form LiO12 cuboctahedra that share corners with twelve equivalent Li(1)O12 cuboctahedra, faces with six equivalent Li(1)O12 cuboctahedra, and faces with eight equivalent Al(1)O6 octahedra. Al(1) is bonded to six equivalent O(1) atoms to form AlO6 octahedra that share corners with six equivalent Al(1)O6 octahedra and faces with eight equivalent Li(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to four equivalent Li(1) and two equivalent Al(1) atoms.
LiAlO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Li(1) is bonded to twelve equivalent O(1) atoms to form LiO12 cuboctahedra that share corners with twelve equivalent Li(1)O12 cuboctahedra, faces with six equivalent Li(1)O12 cuboctahedra, and faces with eight equivalent Al(1)O6 octahedra. All Li(1)-O(1) bond lengths are 2.62 Å. Al(1) is bonded to six equivalent O(1) atoms to form AlO6 octahedra that share corners with six equivalent Al(1)O6 octahedra and faces with eight equivalent Li(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Al(1)-O(1) bond lengths are 1.85 Å. O(1) is bonded in a linear geometry to four equivalent Li(1) and two equivalent Al(1) atoms.