NaPd3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Na(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form a mixture of edge, face, and corner-sharing NaPd12 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent Na(1) atoms to form a mixture of distorted edge and corner-sharing PdNa4 cuboctahedra. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Na(1) atoms.
NaPd3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Na(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form a mixture of edge, face, and corner-sharing NaPd12 cuboctahedra. All Na(1)-Pd(2) bond lengths are 2.80 Å. All Na(1)-Pd(1) bond lengths are 2.82 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent Na(1) atoms to form a mixture of distorted edge and corner-sharing PdNa4 cuboctahedra. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent Na(1) atoms.