NdOZnP crystallizes in the trigonal R-3m space group. Nd(1) is bonded in a 4-coordinate geometry to three equivalent P(1) and four equivalent O(1) atoms. Zn(1) is bonded to four equivalent P(1) atoms to form a mixture of edge and corner-sharing ZnP4 tetrahedra. P(1) is bonded in a 7-coordinate geometry to three equivalent Nd(1) and four equivalent Zn(1) atoms. O(1) is bonded to four equivalent Nd(1) atoms to form a mixture of edge and corner-sharing ONd4 tetrahedra.
NdOZnP crystallizes in the trigonal R-3m space group. Nd(1) is bonded in a 4-coordinate geometry to three equivalent P(1) and four equivalent O(1) atoms. All Nd(1)-P(1) bond lengths are 3.10 Å. There is one shorter (2.38 Å) and three longer (2.39 Å) Nd(1)-O(1) bond lengths. Zn(1) is bonded to four equivalent P(1) atoms to form a mixture of edge and corner-sharing ZnP4 tetrahedra. There are three shorter (2.42 Å) and one longer (2.56 Å) Zn(1)-P(1) bond length. P(1) is bonded in a 7-coordinate geometry to three equivalent Nd(1) and four equivalent Zn(1) atoms. O(1) is bonded to four equivalent Nd(1) atoms to form a mixture of edge and corner-sharing ONd4 tetrahedra.