SrWO2 crystallizes in the tetragonal I4_1/amd space group. Sr(1) is bonded to six equivalent O(1) atoms to form edge-sharing SrO6 octahedra. W(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Sr(1) and two equivalent W(1) atoms to form a mixture of distorted corner and edge-sharing OSr3W2 trigonal bipyramids.
SrWO2 crystallizes in the tetragonal I4_1/amd space group. Sr(1) is bonded to six equivalent O(1) atoms to form edge-sharing SrO6 octahedra. There are four shorter (2.56 Å) and two longer (2.57 Å) Sr(1)-O(1) bond lengths. W(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All W(1)-O(1) bond lengths are 2.21 Å. O(1) is bonded to three equivalent Sr(1) and two equivalent W(1) atoms to form a mixture of distorted corner and edge-sharing OSr3W2 trigonal bipyramids.