Bi2O3 crystallizes in the cubic Pn-3m space group. Bi(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of edge and corner-sharing OBi4 tetrahedra.
Bi2O3 crystallizes in the cubic Pn-3m space group. Bi(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Bi(1)-O(1) bond lengths are 2.42 Å. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of edge and corner-sharing OBi4 tetrahedra.