ZnN4(I)6 is Indium-derived structured and crystallizes in the trigonal P3_121 space group. The structure is zero-dimensional and consists of three azanide;zinc molecules and six I clusters. In each I cluster, there are three inequivalent I sites. In the first I site, I(2) is bonded in a linear geometry to one I(1) and one I(3) atom. In the second I site, I(1) is bonded in a single-bond geometry to one I(2) atom. In the third I site, I(3) is bonded in a single-bond geometry to one I(2) atom.
ZnN4(I)6 is Indium-derived structured and crystallizes in the trigonal P3_121 space group. The structure is zero-dimensional and consists of three azanide;zinc molecules and six I clusters. In each I cluster, there are three inequivalent I sites. In the first I site, I(2) is bonded in a linear geometry to one I(1) and one I(3) atom. The I(2)-I(1) bond length is 2.87 Å. The I(2)-I(3) bond length is 2.93 Å. In the second I site, I(1) is bonded in a single-bond geometry to one I(2) atom. In the third I site, I(3) is bonded in a single-bond geometry to one I(2) atom.