Li5Cr6P5O24 crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(15), one O(21), one O(4), one O(5), one O(8), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one Cr(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-58°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(2), one O(22), one O(5), and one O(8) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(23), one O(3), one O(6), and one O(7) atom. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(13), one O(16), one O(23), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Cr(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-61°. In the fifth Li site, Li(5) is bonded to one O(10), one O(18), one O(19), one O(24), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one Cr(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. There are six inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(2), one O(20), one O(3), one O(5), and one O(6) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Cr(5)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 58°. In the second Cr site, Cr(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(7), and one O(8) atom. In the third Cr site, Cr(3) is bonded to one O(10), one O(11), one O(14), one O(15), one O(19), and one O(4) atom to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 58°. In the fourth Cr site, Cr(4) is bonded to one O(12), one O(13), one O(16), one O(17), one O(7), and one O(8) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Cr(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the fifth Cr site, Cr(5) is bonded to one O(12), one O(14), one O(17), one O(2), one O(20), and one O(22) atom to form CrO6 octahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Cr(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-60°. In the sixth Cr site, Cr(6) is bonded to one O(18), one O(21), one O(22), one O(23), one O(24), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 60-61°. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(16), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, and corners with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the second P site, P(2) is bonded to one O(12), one O(13), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra, corners with two equivalent Cr(4)O6 octahedra, and  an edgeedge with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-52°. In the third P site, P(3) is bonded to one O(11), one O(14), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra, corners with two equivalent Cr(6)O6 octahedra, and  an edgeedge with one Cr(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-55°. In the fourth P site, P(4) is bonded to one O(15), one O(17), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, and corners with two equivalent Cr(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. In the fifth P site, P(5) is bonded to one O(19), one O(22), one O(23), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Cr(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(4), one Cr(1), and one P(1) atom. In the second O site, O(2) is bonded to one Li(2), one Cr(1), one Cr(2), and one Cr(5) atom to form OLiCr3 trigonal pyramids that share  a cornercorner with one O(7)Li2Cr2 tetrahedra, corners with two equivalent O(14)LiCr2P tetrahedra, corners with two equivalent O(3)Li2Cr2 trigonal pyramids,  an edgeedge with one O(8)Li2Cr2 tetrahedra, and  an edgeedge with one O(22)LiCr2P tetrahedra. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Cr(1), and one Cr(2) atom to form OLi2Cr2 trigonal pyramids that share  a cornercorner with one O(8)Li2Cr2 tetrahedra, corners with two equivalent O(23)Li2CrP tetrahedra, corners with two equivalent O(2)LiCr3 trigonal pyramids,  an edgeedge with one O(7)Li2Cr2 tetrahedra, and  an edgeedge with one O(11)Li2CrP tetrahedra. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Cr(3), and one P(5) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Cr(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one Cr(1), and one P(2) atom. In the seventh O site, O(7) is bonded to one Li(3), one Li(5), one Cr(2), and one Cr(4) atom to form OLi2Cr2 tetrahedra that share  a cornercorner with one O(11)Li2CrP tetrahedra,  a cornercorner with one O(23)Li2CrP tetrahedra,  a cornercorner with one O(2)LiCr3 trigonal pyramid,  an edgeedge with one O(8)Li2Cr2 tetrahedra, and  an edgeedge with one O(3)Li2Cr2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Cr(2), and one Cr(4) atom to form OLi2Cr2 tetrahedra that share  a cornercorner with one O(14)LiCr2P tetrahedra,  a cornercorner with one O(22)LiCr2P tetrahedra,  a cornercorner with one O(3)Li2Cr2 trigonal pyramid,  an edgeedge with one O(7)Li2Cr2 tetrahedra, and  an edgeedge with one O(2)LiCr3 trigonal pyramid. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one Cr(6), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(5), one Cr(3), and one P(1) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(4), one Cr(3), and one P(3) atom to form distorted OLi2CrP tetrahedra that share  a cornercorner with one O(7)Li2Cr2 tetrahedra, corners with two equivalent O(23)Li2CrP tetrahedra,  an edgeedge with one O(14)LiCr2P tetrahedra, and  an edgeedge with one O(3)Li2Cr2 trigonal pyramid. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Cr(4), one Cr(5), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(4), one Cr(4), and one P(2) atom. In the fourteenth O site, O(14) is bonded to one Li(2), one Cr(3), one Cr(5), and one P(3) atom to form distorted OLiCr2P tetrahedra that share  a cornercorner with one O(8)Li2Cr2 tetrahedra, corners with two equivalent O(22)LiCr2P tetrahedra, corners with two equivalent O(2)LiCr3 trigonal pyramids, and  an edgeedge with one O(11)Li2CrP tetrahedra. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(3), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Li(4), one Cr(4), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Cr(4), one Cr(5), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Li(5), one Cr(6), and one P(3) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(5), one Cr(3), and one P(5) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Cr(1), one Cr(5), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(6), and one P(4) atom. In the twenty-second O site, O(22) is bonded to one Li(2), one Cr(5), one Cr(6), and one P(5) atom to form distorted OLiCr2P tetrahedra that share  a cornercorner with one O(8)Li2Cr2 tetrahedra, corners with two equivalent O(14)LiCr2P tetrahedra,  an edgeedge with one O(23)Li2CrP tetrahedra, and  an edgeedge with one O(2)LiCr3 trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(3), one Li(4), one Cr(6), and one P(5) atom to form OLi2CrP tetrahedra that share  a cornercorner with one O(7)Li2Cr2 tetrahedra, corners with two equivalent O(11)Li2CrP tetrahedra, corners with two equivalent O(3)Li2Cr2 trigonal pyramids, and  an edgeedge with one O(22)LiCr2P tetrahedra. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Li(5), one Cr(6), and one P(1) atom.
Li5Cr6P5O24 crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(15), one O(21), one O(4), one O(5), one O(8), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one Cr(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-58°. The Li(1)-O(15) bond length is 2.10 Å. The Li(1)-O(21) bond length is 2.12 Å. The Li(1)-O(4) bond length is 2.51 Å. The Li(1)-O(5) bond length is 2.06 Å. The Li(1)-O(8) bond length is 2.00 Å. The Li(1)-O(9) bond length is 2.52 Å. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(12), one O(14), one O(2), one O(22), one O(5), and one O(8) atom. The Li(2)-O(12) bond length is 2.61 Å. The Li(2)-O(14) bond length is 2.37 Å. The Li(2)-O(2) bond length is 2.25 Å. The Li(2)-O(22) bond length is 2.18 Å. The Li(2)-O(5) bond length is 2.21 Å. The Li(2)-O(8) bond length is 2.08 Å. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(23), one O(3), one O(6), and one O(7) atom. The Li(3)-O(11) bond length is 2.18 Å. The Li(3)-O(23) bond length is 2.29 Å. The Li(3)-O(3) bond length is 2.32 Å. The Li(3)-O(6) bond length is 2.21 Å. The Li(3)-O(7) bond length is 2.10 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(13), one O(16), one O(23), and one O(3) atom to form LiO6 octahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Cr(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-61°. The Li(4)-O(1) bond length is 2.13 Å. The Li(4)-O(11) bond length is 2.14 Å. The Li(4)-O(13) bond length is 2.27 Å. The Li(4)-O(16) bond length is 2.26 Å. The Li(4)-O(23) bond length is 2.08 Å. The Li(4)-O(3) bond length is 2.02 Å. In the fifth Li site, Li(5) is bonded to one O(10), one O(18), one O(19), one O(24), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one Cr(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. The Li(5)-O(10) bond length is 2.11 Å. The Li(5)-O(18) bond length is 2.45 Å. The Li(5)-O(19) bond length is 2.48 Å. The Li(5)-O(24) bond length is 2.07 Å. The Li(5)-O(6) bond length is 2.07 Å. The Li(5)-O(7) bond length is 1.99 Å. There are six inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(2), one O(20), one O(3), one O(5), and one O(6) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Cr(5)O6 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 58°. The Cr(1)-O(1) bond length is 2.02 Å. The Cr(1)-O(2) bond length is 1.95 Å. The Cr(1)-O(20) bond length is 2.05 Å. The Cr(1)-O(3) bond length is 1.92 Å. The Cr(1)-O(5) bond length is 2.07 Å. The Cr(1)-O(6) bond length is 2.06 Å. In the second Cr site, Cr(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(7), and one O(8) atom. The Cr(2)-O(2) bond length is 1.86 Å. The Cr(2)-O(3) bond length is 1.77 Å. The Cr(2)-O(7) bond length is 1.82 Å. The Cr(2)-O(8) bond length is 1.85 Å. In the third Cr site, Cr(3) is bonded to one O(10), one O(11), one O(14), one O(15), one O(19), and one O(4) atom to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 58°. The Cr(3)-O(10) bond length is 1.99 Å. The Cr(3)-O(11) bond length is 2.03 Å. The Cr(3)-O(14) bond length is 2.10 Å. The Cr(3)-O(15) bond length is 2.03 Å. The Cr(3)-O(19) bond length is 2.03 Å. The Cr(3)-O(4) bond length is 2.02 Å. In the fourth Cr site, Cr(4) is bonded to one O(12), one O(13), one O(16), one O(17), one O(7), and one O(8) atom to form CrO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Li(4)O6 octahedra, and  an edgeedge with one Cr(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. The Cr(4)-O(12) bond length is 2.18 Å. The Cr(4)-O(13) bond length is 2.11 Å. The Cr(4)-O(16) bond length is 2.06 Å. The Cr(4)-O(17) bond length is 2.08 Å. The Cr(4)-O(7) bond length is 1.95 Å. The Cr(4)-O(8) bond length is 1.95 Å. In the fifth Cr site, Cr(5) is bonded to one O(12), one O(14), one O(17), one O(2), one O(20), and one O(22) atom to form CrO6 octahedra that share  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Cr(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-60°. The Cr(5)-O(12) bond length is 2.30 Å. The Cr(5)-O(14) bond length is 2.07 Å. The Cr(5)-O(17) bond length is 2.21 Å. The Cr(5)-O(2) bond length is 2.00 Å. The Cr(5)-O(20) bond length is 2.23 Å. The Cr(5)-O(22) bond length is 2.17 Å. In the sixth Cr site, Cr(6) is bonded to one O(18), one O(21), one O(22), one O(23), one O(24), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 60-61°. The Cr(6)-O(18) bond length is 2.03 Å. The Cr(6)-O(21) bond length is 2.03 Å. The Cr(6)-O(22) bond length is 2.05 Å. The Cr(6)-O(23) bond length is 2.07 Å. The Cr(6)-O(24) bond length is 2.01 Å. The Cr(6)-O(9) bond length is 2.02 Å. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(16), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, and corners with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. The P(1)-O(1) bond length is 1.55 Å. The P(1)-O(10) bond length is 1.57 Å. The P(1)-O(16) bond length is 1.56 Å. The P(1)-O(24) bond length is 1.56 Å. In the second P site, P(2) is bonded to one O(12), one O(13), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra, corners with two equivalent Cr(4)O6 octahedra, and  an edgeedge with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-52°. The P(2)-O(12) bond length is 1.56 Å. The P(2)-O(13) bond length is 1.55 Å. The P(2)-O(5) bond length is 1.57 Å. The P(2)-O(6) bond length is 1.57 Å. In the third P site, P(3) is bonded to one O(11), one O(14), one O(18), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra, corners with two equivalent Cr(6)O6 octahedra, and  an edgeedge with one Cr(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-55°. The P(3)-O(11) bond length is 1.57 Å. The P(3)-O(14) bond length is 1.61 Å. The P(3)-O(18) bond length is 1.53 Å. The P(3)-O(9) bond length is 1.53 Å. In the fourth P site, P(4) is bonded to one O(15), one O(17), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Cr(4)O6 octahedra,  a cornercorner with one Cr(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, and corners with two equivalent Cr(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. The P(4)-O(15) bond length is 1.55 Å. The P(4)-O(17) bond length is 1.57 Å. The P(4)-O(20) bond length is 1.55 Å. The P(4)-O(21) bond length is 1.55 Å. In the fifth P site, P(5) is bonded to one O(19), one O(22), one O(23), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Cr(5)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Cr(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. The P(5)-O(19) bond length is 1.53 Å. The P(5)-O(22) bond length is 1.60 Å. The P(5)-O(23) bond length is 1.58 Å. The P(5)-O(4) bond length is 1.53 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(4), one Cr(1), and one P(1) atom. In the second O site, O(2) is bonded to one Li(2), one Cr(1), one Cr(2), and one Cr(5) atom to form OLiCr3 trigonal pyramids that share  a cornercorner with one O(7)Li2Cr2 tetrahedra, corners with two equivalent O(14)LiCr2P tetrahedra, corners with two equivalent O(3)Li2Cr2 trigonal pyramids,  an edgeedge with one O(8)Li2Cr2 tetrahedra, and  an edgeedge with one O(22)LiCr2P tetrahedra. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Cr(1), and one Cr(2) atom to form OLi2Cr2 trigonal pyramids that share  a cornercorner with one O(8)Li2Cr2 tetrahedra, corners with two equivalent O(23)Li2CrP tetrahedra, corners with two equivalent O(2)LiCr3 trigonal pyramids,  an edgeedge with one O(7)Li2Cr2 tetrahedra, and  an edgeedge with one O(11)Li2CrP tetrahedra. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Cr(3), and one P(5) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Cr(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one Cr(1), and one P(2) atom. In the seventh O site, O(7) is bonded to one Li(3), one Li(5), one Cr(2), and one Cr(4) atom to form OLi2Cr2 tetrahedra that share  a cornercorner with one O(11)Li2CrP tetrahedra,  a cornercorner with one O(23)Li2CrP tetrahedra,  a cornercorner with one O(2)LiCr3 trigonal pyramid,  an edgeedge with one O(8)Li2Cr2 tetrahedra, and  an edgeedge with one O(3)Li2Cr2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Cr(2), and one Cr(4) atom to form OLi2Cr2 tetrahedra that share  a cornercorner with one O(14)LiCr2P tetrahedra,  a cornercorner with one O(22)LiCr2P tetrahedra,  a cornercorner with one O(3)Li2Cr2 trigonal pyramid,  an edgeedge with one O(7)Li2Cr2 tetrahedra, and  an edgeedge with one O(2)LiCr3 trigonal pyramid. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one Cr(6), and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(5), one Cr(3), and one P(1) atom. In the eleventh O site, O(11) is bonded to one Li(3), one Li(4), one Cr(3), and one P(3) atom to form distorted OLi2CrP tetrahedra that share  a cornercorner with one O(7)Li2Cr2 tetrahedra, corners with two equivalent O(23)Li2CrP tetrahedra,  an edgeedge with one O(14)LiCr2P tetrahedra, and  an edgeedge with one O(3)Li2Cr2 trigonal pyramid. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Cr(4), one Cr(5), and one P(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(4), one Cr(4), and one P(2) atom. In the fourteenth O site, O(14) is bonded to one Li(2), one Cr(3), one Cr(5), and one P(3) atom to form distorted OLiCr2P tetrahedra that share  a cornercorner with one O(8)Li2Cr2 tetrahedra, corners with two equivalent O(22)LiCr2P tetrahedra, corners with two equivalent O(2)LiCr3 trigonal pyramids, and  an edgeedge with one O(11)Li2CrP tetrahedra. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(3), and one P(4) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Li(4), one Cr(4), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Cr(4), one Cr(5), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Li(5), one Cr(6), and one P(3) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(5), one Cr(3), and one P(5) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Cr(1), one Cr(5), and one P(4) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(6), and one P(4) atom. In the twenty-second O site, O(22) is bonded to one Li(2), one Cr(5), one Cr(6), and one P(5) atom to form distorted OLiCr2P tetrahedra that share  a cornercorner with one O(8)Li2Cr2 tetrahedra, corners with two equivalent O(14)LiCr2P tetrahedra,  an edgeedge with one O(23)Li2CrP tetrahedra, and  an edgeedge with one O(2)LiCr3 trigonal pyramid. In the twenty-third O site, O(23) is bonded to one Li(3), one Li(4), one Cr(6), and one P(5) atom to form OLi2CrP tetrahedra that share  a cornercorner with one O(7)Li2Cr2 tetrahedra, corners with two equivalent O(11)Li2CrP tetrahedra, corners with two equivalent O(3)Li2Cr2 trigonal pyramids, and  an edgeedge with one O(22)LiCr2P tetrahedra. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Li(5), one Cr(6), and one P(1) atom.