CuO8(NO)2(SO2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four sulfur dioxide molecules, and two CuO8 clusters. In each CuO8 cluster, Cu(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. There are four inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one O(3) atom. In the second O site, O(3) is bonded in a single-bond geometry to one O(7) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one Cu(1) and one O(6) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Cu(1) and one O(5) atom.
CuO8(NO)2(SO2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four sulfur dioxide molecules, and two CuO8 clusters. In each CuO8 cluster, Cu(1) is bonded in an octahedral geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. Both Cu(1)-O(5) bond lengths are 1.89 Å. Both Cu(1)-O(6) bond lengths are 1.86 Å. Both Cu(1)-O(7) bond lengths are 2.56 Å. There are four inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one O(3) atom. The O(7)-O(3) bond length is 1.25 Å. In the second O site, O(3) is bonded in a single-bond geometry to one O(7) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one Cu(1) and one O(6) atom. The O(5)-O(6) bond length is 1.37 Å. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Cu(1) and one O(5) atom.