MnH8(SO6)2(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two guanidinium molecules and one MnH8(SO6)2 cluster. In the MnH8(SO6)2 cluster, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(3), and one H(4) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom.
MnH8(SO6)2(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two guanidinium molecules and one MnH8(SO6)2 cluster. In the MnH8(SO6)2 cluster, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. Both Mn(1)-O(1) bond lengths are 2.18 Å. Both Mn(1)-O(2) bond lengths are 2.25 Å. Both Mn(1)-O(5) bond lengths are 2.18 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. S(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. The S(1)-O(3) bond length is 1.49 Å. The S(1)-O(4) bond length is 1.50 Å. The S(1)-O(5) bond length is 1.49 Å. The S(1)-O(6) bond length is 1.50 Å. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(3), and one H(4) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom.