KMnH5(SO5)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one KMnH5(SO5)2 cluster. K(1) is bonded in a 1-coordinate geometry to one O(9) atom. Mn(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and one O(7) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. In the fifth H site, H(5) is bonded in a distorted bent 150 degrees geometry to one O(4) and one O(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to one O(4), one O(8), and one O(9) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(10), one O(2), and one O(7) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(3), and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mn(1) and one O(5) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mn(1), one H(5), and one S(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mn(1) and one O(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one H(5) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one S(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1), one H(2), and one S(1) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one H(1) and one S(2) atom.
KMnH5(SO5)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one KMnH5(SO5)2 cluster. K(1) is bonded in a 1-coordinate geometry to one O(9) atom. The K(1)-O(9) bond length is 2.62 Å. Mn(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and one O(7) atom. The Mn(1)-O(1) bond length is 2.20 Å. The Mn(1)-O(3) bond length is 1.98 Å. The Mn(1)-O(4) bond length is 2.04 Å. The Mn(1)-O(5) bond length is 1.93 Å. The Mn(1)-O(7) bond length is 2.02 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. The H(1)-O(10) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) atom. The H(3)-O(1) bond length is 1.01 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) atom. The H(4)-O(1) bond length is 0.98 Å. In the fifth H site, H(5) is bonded in a distorted bent 150 degrees geometry to one O(4) and one O(6) atom. The H(5)-O(4) bond length is 1.55 Å. The H(5)-O(6) bond length is 1.03 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to one O(4), one O(8), and one O(9) atom. The S(1)-O(4) bond length is 1.70 Å. The S(1)-O(8) bond length is 1.71 Å. The S(1)-O(9) bond length is 1.84 Å. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(10), one O(2), and one O(7) atom. The S(2)-O(10) bond length is 1.70 Å. The S(2)-O(2) bond length is 1.50 Å. The S(2)-O(7) bond length is 1.54 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(3), and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mn(1) and one O(5) atom. The O(3)-O(5) bond length is 1.42 Å. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mn(1), one H(5), and one S(1) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mn(1) and one O(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one H(5) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one S(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1), one H(2), and one S(1) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one H(1) and one S(2) atom.