CsCHO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one H(1), two equivalent O(3), three equivalent O(2), and four equivalent O(1) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. H(1) is bonded in a distorted linear geometry to one Cs(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to three equivalent Cs(1), one C(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Cs(1), one C(1), and one H(1) atom.
CsCHO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one H(1), two equivalent O(3), three equivalent O(2), and four equivalent O(1) atoms. The Cs(1)-H(1) bond length is 3.27 Å. There is one shorter (3.14 Å) and one longer (3.28 Å) Cs(1)-O(3) bond length. There are a spread of Cs(1)-O(2) bond distances ranging from 3.08-3.74 Å. There are a spread of Cs(1)-O(1) bond distances ranging from 3.04-3.81 Å. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.37 Å. H(1) is bonded in a distorted linear geometry to one Cs(1), one O(2), and one O(3) atom. The H(1)-O(2) bond length is 1.56 Å. The H(1)-O(3) bond length is 1.03 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to three equivalent Cs(1), one C(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Cs(1), one C(1), and one H(1) atom.