CoZrF6 crystallizes in the trigonal R-3 space group. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Co(1)F6 octahedra. The corner-sharing octahedral tilt angles are 19°. Co(1) is bonded to six equivalent F(1) atoms to form CoF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedral tilt angles are 19°. F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Co(1) atom.
CoZrF6 crystallizes in the trigonal R-3 space group. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Co(1)F6 octahedra. The corner-sharing octahedral tilt angles are 19°. All Zr(1)-F(1) bond lengths are 2.02 Å. Co(1) is bonded to six equivalent F(1) atoms to form CoF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedral tilt angles are 19°. All Co(1)-F(1) bond lengths are 2.02 Å. F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Co(1) atom.