Li2CuF4 crystallizes in the tetragonal P4/ncc space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. Cu(1) is bonded in a rectangular see-saw-like geometry to four equivalent F(1) atoms. F(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(1) and one Cu(1) atom.
Li2CuF4 crystallizes in the tetragonal P4/ncc space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent F(1) atoms. There are two shorter (1.97 Å) and two longer (1.99 Å) Li(1)-F(1) bond lengths. Cu(1) is bonded in a rectangular see-saw-like geometry to four equivalent F(1) atoms. All Cu(1)-F(1) bond lengths are 1.89 Å. F(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(1) and one Cu(1) atom.