(Ag3MoO3F3)(Ag3MoO4)Cl crystallizes in the trigonal P3m1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(3) and three equivalent O(2) atoms to form MoO4 tetrahedra that share corners with six equivalent Ag(1)ClO3F2 pentagonal pyramids. In the second Mo site, Mo(2) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form distorted MoO3F3 octahedra that share corners with three equivalent Ag(1)ClO3F2 pentagonal pyramids and edges with three equivalent Ag(1)ClO3F2 pentagonal pyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), two equivalent O(2), one Cl(1), and two equivalent F(1) atoms to form distorted AgClO3F2 pentagonal pyramids that share  a cornercorner with one Mo(2)O3F3 octahedra, corners with two equivalent Ag(1)ClO3F2 pentagonal pyramids, corners with two equivalent Mo(1)O4 tetrahedra,  an edgeedge with one Mo(2)O3F3 octahedra, and edges with two equivalent Ag(1)ClO3F2 pentagonal pyramids. The corner-sharing octahedral tilt angles are 46°. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(2), one O(3), two equivalent O(1), and one Cl(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(2), one Ag(1), and two equivalent Ag(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Ag(2), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded to one Mo(1) and three equivalent Ag(2) atoms to form distorted OAg3Mo tetrahedra that share corners with three equivalent Cl(1)Ag6 octahedra. The corner-sharing octahedral tilt angles are 60°. Cl(1) is bonded to three equivalent Ag(1) and three equivalent Ag(2) atoms to form ClAg6 octahedra that share corners with three equivalent O(3)Ag3Mo tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Ag(1) atoms.
(Ag3MoO3F3)(Ag3MoO4)Cl crystallizes in the trigonal P3m1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(3) and three equivalent O(2) atoms to form MoO4 tetrahedra that share corners with six equivalent Ag(1)ClO3F2 pentagonal pyramids. The Mo(1)-O(3) bond length is 1.84 Å. All Mo(1)-O(2) bond lengths are 1.81 Å. In the second Mo site, Mo(2) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form distorted MoO3F3 octahedra that share corners with three equivalent Ag(1)ClO3F2 pentagonal pyramids and edges with three equivalent Ag(1)ClO3F2 pentagonal pyramids. All Mo(2)-O(1) bond lengths are 1.81 Å. All Mo(2)-F(1) bond lengths are 2.12 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), two equivalent O(2), one Cl(1), and two equivalent F(1) atoms to form distorted AgClO3F2 pentagonal pyramids that share  a cornercorner with one Mo(2)O3F3 octahedra, corners with two equivalent Ag(1)ClO3F2 pentagonal pyramids, corners with two equivalent Mo(1)O4 tetrahedra,  an edgeedge with one Mo(2)O3F3 octahedra, and edges with two equivalent Ag(1)ClO3F2 pentagonal pyramids. The corner-sharing octahedral tilt angles are 46°. The Ag(1)-O(1) bond length is 2.34 Å. Both Ag(1)-O(2) bond lengths are 2.49 Å. The Ag(1)-Cl(1) bond length is 2.76 Å. Both Ag(1)-F(1) bond lengths are 2.54 Å. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(2), one O(3), two equivalent O(1), and one Cl(1) atom. The Ag(2)-O(2) bond length is 2.42 Å. The Ag(2)-O(3) bond length is 2.41 Å. Both Ag(2)-O(1) bond lengths are 2.60 Å. The Ag(2)-Cl(1) bond length is 2.67 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(2), one Ag(1), and two equivalent Ag(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Ag(2), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded to one Mo(1) and three equivalent Ag(2) atoms to form distorted OAg3Mo tetrahedra that share corners with three equivalent Cl(1)Ag6 octahedra. The corner-sharing octahedral tilt angles are 60°. Cl(1) is bonded to three equivalent Ag(1) and three equivalent Ag(2) atoms to form ClAg6 octahedra that share corners with three equivalent O(3)Ag3Mo tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Ag(1) atoms.