Sr4LaMn5O13 crystallizes in the monoclinic Cm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(15), one O(16), one O(2), one O(21), one O(22), one O(3), one O(4), one O(7), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 11-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(14), one O(2), one O(21), one O(22), one O(5), one O(6), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a distorted q6 geometry to one O(10), one O(13), one O(14), one O(17), one O(18), one O(21), one O(7), one O(8), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a distorted q6 geometry to one O(11), one O(12), one O(15), one O(16), one O(19), one O(20), one O(22), one O(7), and one O(8) atom. La(1) is bonded to one O(17), one O(18), one O(19), one O(20), one O(21), one O(22), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LaO12 cuboctahedra that share faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(8)O6 octahedra,  a faceface with one Mn(9)O6 octahedra,  a faceface with one Mn(10)O5 trigonal bipyramid,  a faceface with one Mn(3)O5 trigonal bipyramid,  a faceface with one Mn(4)O5 trigonal bipyramid, and  a faceface with one Mn(5)O5 trigonal bipyramid. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(13), one O(17), one O(2), one O(3), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra,  a cornercorner with one Mn(10)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Mn site, Mn(2) is bonded to one O(16), one O(2), one O(20), one O(6), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Mn(9)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid,  a cornercorner with one Mn(5)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third Mn site, Mn(3) is bonded to one O(10), one O(20), one O(4), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(10)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 9-15°. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(17), one O(5), and two equivalent O(8) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(5)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(18), one O(6), and two equivalent O(8) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(4)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the sixth Mn site, Mn(6) is bonded in a rectangular see-saw-like geometry to one O(10), one O(11), one O(14), and one O(15) atom. In the seventh Mn site, Mn(7) is bonded in a rectangular see-saw-like geometry to one O(12), one O(13), one O(16), and one O(9) atom. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(14), one O(18), one O(4), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid,  a cornercorner with one Mn(5)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(15), one O(19), one O(5), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Mn(10)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the tenth Mn site, Mn(10) is bonded to one O(19), one O(3), one O(9), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(3)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-12°. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(8), and one Mn(9) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra,  an edgeedge with one O(10)Sr4Mn2 octahedra,  an edgeedge with one O(11)Sr4Mn2 octahedra, edges with two equivalent O(2)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(12)Sr4Mn2 octahedra, edges with two equivalent O(1)Sr4Mn2 octahedra,  a faceface with one O(3)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-58°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(10) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(13)Sr4Mn2 octahedra, corners with two equivalent O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(16)Sr4Mn2 octahedra, edges with two equivalent O(4)Sr2La2Mn2 octahedra,  a faceface with one O(17)Sr2La2Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(3), and one Mn(8) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(15)Sr4Mn2 octahedra, edges with two equivalent O(3)Sr2La2Mn2 octahedra,  a faceface with one O(18)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra, and  a faceface with one O(10)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 3-58°. In the fifth O site, O(5) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(4), and one Mn(9) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr2La2Mn2 octahedra,  an edgeedge with one O(14)Sr4Mn2 octahedra, edges with two equivalent O(6)Sr2La2Mn2 octahedra,  a faceface with one O(17)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the sixth O site, O(6) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(2), and one Mn(5) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra,  an edgeedge with one O(13)Sr4Mn2 octahedra, edges with two equivalent O(5)Sr2La2Mn2 octahedra,  a faceface with one O(18)Sr2La2Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one La(1), one Mn(10), and one Mn(3) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one La(1), one Mn(4), and one Mn(5) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(3), one Mn(10), and one Mn(7) atom. In the tenth O site, O(10) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mn(3), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(11)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(18)Sr2La2Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-69°. In the eleventh O site, O(11) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(4), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(17)Sr2La2Mn2 octahedra,  a cornercorner with one O(10)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra, edges with two equivalent O(12)Sr4Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-69°. In the twelfth O site, O(12) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(5), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(2)Sr4Mn2 octahedra, edges with two equivalent O(11)Sr4Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 6-70°. In the thirteenth O site, O(13) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(1), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(3)Sr2La2Mn2 octahedra,  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra, edges with two equivalent O(14)Sr4Mn2 octahedra,  a faceface with one O(17)Sr2La2Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-69°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(6), and one Mn(8) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(4)Sr2La2Mn2 octahedra,  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra, edges with two equivalent O(13)Sr4Mn2 octahedra,  a faceface with one O(18)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-70°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(6), and one Mn(9) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra, edges with two equivalent O(16)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the sixteenth O site, O(16) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(2), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(13)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr2La2Mn2 octahedra, edges with two equivalent O(15)Sr4Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-69°. In the seventeenth O site, O(17) is bonded to two equivalent Sr(3), two equivalent La(1), one Mn(1), and one Mn(4) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(11)Sr4Mn2 octahedra,  a cornercorner with one O(2)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, edges with two equivalent O(18)Sr2La2Mn2 octahedra,  a faceface with one O(3)Sr2La2Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra, and  a faceface with one O(13)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the eighteenth O site, O(18) is bonded to two equivalent Sr(3), two equivalent La(1), one Mn(5), and one Mn(8) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(1)Sr4Mn2 octahedra,  a cornercorner with one O(12)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra,  an edgeedge with one O(10)Sr4Mn2 octahedra, edges with two equivalent O(17)Sr2La2Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra, and  a faceface with one O(14)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the nineteenth O site, O(19) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(1), one Mn(10), and one Mn(9) atom. In the twentieth O site, O(20) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(1), one Mn(2), and one Mn(3) atom. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one La(1), one Mn(1), and one Mn(8) atom. In the twenty-second O site, O(22) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(4), one La(1), one Mn(2), and one Mn(9) atom.
Sr4LaMn5O13 crystallizes in the monoclinic Cm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(15), one O(16), one O(2), one O(21), one O(22), one O(3), one O(4), one O(7), and one O(9) atom. The Sr(1)-O(1) bond length is 2.66 Å. The Sr(1)-O(10) bond length is 2.88 Å. The Sr(1)-O(15) bond length is 2.73 Å. The Sr(1)-O(16) bond length is 2.77 Å. The Sr(1)-O(2) bond length is 2.68 Å. The Sr(1)-O(21) bond length is 2.71 Å. The Sr(1)-O(22) bond length is 2.83 Å. The Sr(1)-O(3) bond length is 2.84 Å. The Sr(1)-O(4) bond length is 2.86 Å. The Sr(1)-O(7) bond length is 3.05 Å. The Sr(1)-O(9) bond length is 2.98 Å. In the second Sr site, Sr(2) is bonded in a 11-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(14), one O(2), one O(21), one O(22), one O(5), one O(6), and one O(8) atom. The Sr(2)-O(1) bond length is 2.65 Å. The Sr(2)-O(11) bond length is 2.97 Å. The Sr(2)-O(12) bond length is 2.93 Å. The Sr(2)-O(13) bond length is 2.74 Å. The Sr(2)-O(14) bond length is 2.76 Å. The Sr(2)-O(2) bond length is 2.68 Å. The Sr(2)-O(21) bond length is 2.83 Å. The Sr(2)-O(22) bond length is 2.72 Å. The Sr(2)-O(5) bond length is 2.84 Å. The Sr(2)-O(6) bond length is 2.86 Å. The Sr(2)-O(8) bond length is 3.08 Å. In the third Sr site, Sr(3) is bonded in a distorted q6 geometry to one O(10), one O(13), one O(14), one O(17), one O(18), one O(21), one O(7), one O(8), and one O(9) atom. The Sr(3)-O(10) bond length is 2.76 Å. The Sr(3)-O(13) bond length is 2.77 Å. The Sr(3)-O(14) bond length is 2.75 Å. The Sr(3)-O(17) bond length is 2.63 Å. The Sr(3)-O(18) bond length is 2.64 Å. The Sr(3)-O(21) bond length is 2.64 Å. The Sr(3)-O(7) bond length is 2.64 Å. The Sr(3)-O(8) bond length is 2.63 Å. The Sr(3)-O(9) bond length is 2.71 Å. In the fourth Sr site, Sr(4) is bonded in a distorted q6 geometry to one O(11), one O(12), one O(15), one O(16), one O(19), one O(20), one O(22), one O(7), and one O(8) atom. The Sr(4)-O(11) bond length is 2.69 Å. The Sr(4)-O(12) bond length is 2.75 Å. The Sr(4)-O(15) bond length is 2.78 Å. The Sr(4)-O(16) bond length is 2.79 Å. The Sr(4)-O(19) bond length is 2.63 Å. The Sr(4)-O(20) bond length is 2.56 Å. The Sr(4)-O(22) bond length is 2.67 Å. The Sr(4)-O(7) bond length is 2.62 Å. The Sr(4)-O(8) bond length is 2.67 Å. La(1) is bonded to one O(17), one O(18), one O(19), one O(20), one O(21), one O(22), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LaO12 cuboctahedra that share faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(8)O6 octahedra,  a faceface with one Mn(9)O6 octahedra,  a faceface with one Mn(10)O5 trigonal bipyramid,  a faceface with one Mn(3)O5 trigonal bipyramid,  a faceface with one Mn(4)O5 trigonal bipyramid, and  a faceface with one Mn(5)O5 trigonal bipyramid. The La(1)-O(17) bond length is 2.84 Å. The La(1)-O(18) bond length is 2.83 Å. The La(1)-O(19) bond length is 2.84 Å. The La(1)-O(20) bond length is 2.91 Å. The La(1)-O(21) bond length is 2.70 Å. The La(1)-O(22) bond length is 2.76 Å. The La(1)-O(3) bond length is 2.62 Å. The La(1)-O(4) bond length is 2.56 Å. The La(1)-O(5) bond length is 2.66 Å. The La(1)-O(6) bond length is 2.64 Å. The La(1)-O(7) bond length is 3.11 Å. The La(1)-O(8) bond length is 3.10 Å. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(13), one O(17), one O(2), one O(3), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra,  a cornercorner with one Mn(10)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(1)-O(13) bond length is 2.00 Å. The Mn(1)-O(17) bond length is 2.05 Å. The Mn(1)-O(2) bond length is 1.94 Å. The Mn(1)-O(3) bond length is 1.94 Å. Both Mn(1)-O(21) bond lengths are 1.88 Å. In the second Mn site, Mn(2) is bonded to one O(16), one O(2), one O(20), one O(6), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Mn(9)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid,  a cornercorner with one Mn(5)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(2)-O(16) bond length is 2.02 Å. The Mn(2)-O(2) bond length is 2.06 Å. The Mn(2)-O(20) bond length is 2.13 Å. The Mn(2)-O(6) bond length is 1.96 Å. Both Mn(2)-O(22) bond lengths are 1.91 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(20), one O(4), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(10)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 9-15°. The Mn(3)-O(10) bond length is 1.98 Å. The Mn(3)-O(20) bond length is 1.91 Å. The Mn(3)-O(4) bond length is 2.02 Å. Both Mn(3)-O(7) bond lengths are 1.95 Å. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(17), one O(5), and two equivalent O(8) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(5)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 5-12°. The Mn(4)-O(11) bond length is 2.00 Å. The Mn(4)-O(17) bond length is 1.97 Å. The Mn(4)-O(5) bond length is 2.08 Å. Both Mn(4)-O(8) bond lengths are 1.96 Å. In the fifth Mn site, Mn(5) is bonded to one O(12), one O(18), one O(6), and two equivalent O(8) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(4)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-12°. The Mn(5)-O(12) bond length is 1.99 Å. The Mn(5)-O(18) bond length is 1.96 Å. The Mn(5)-O(6) bond length is 2.08 Å. Both Mn(5)-O(8) bond lengths are 1.93 Å. In the sixth Mn site, Mn(6) is bonded in a rectangular see-saw-like geometry to one O(10), one O(11), one O(14), and one O(15) atom. The Mn(6)-O(10) bond length is 1.93 Å. The Mn(6)-O(11) bond length is 1.93 Å. The Mn(6)-O(14) bond length is 1.86 Å. The Mn(6)-O(15) bond length is 1.92 Å. In the seventh Mn site, Mn(7) is bonded in a rectangular see-saw-like geometry to one O(12), one O(13), one O(16), and one O(9) atom. The Mn(7)-O(12) bond length is 1.93 Å. The Mn(7)-O(13) bond length is 1.92 Å. The Mn(7)-O(16) bond length is 1.90 Å. The Mn(7)-O(9) bond length is 1.92 Å. In the eighth Mn site, Mn(8) is bonded to one O(1), one O(14), one O(18), one O(4), and two equivalent O(21) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid,  a cornercorner with one Mn(5)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(8)-O(1) bond length is 1.91 Å. The Mn(8)-O(14) bond length is 2.10 Å. The Mn(8)-O(18) bond length is 2.04 Å. The Mn(8)-O(4) bond length is 2.08 Å. Both Mn(8)-O(21) bond lengths are 1.95 Å. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(15), one O(19), one O(5), and two equivalent O(22) atoms to form MnO6 octahedra that share  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Mn(10)O5 trigonal bipyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(9)-O(1) bond length is 2.11 Å. The Mn(9)-O(15) bond length is 1.97 Å. The Mn(9)-O(19) bond length is 2.14 Å. The Mn(9)-O(5) bond length is 1.94 Å. Both Mn(9)-O(22) bond lengths are 1.92 Å. In the tenth Mn site, Mn(10) is bonded to one O(19), one O(3), one O(9), and two equivalent O(7) atoms to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(3)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-12°. The Mn(10)-O(19) bond length is 1.91 Å. The Mn(10)-O(3) bond length is 2.12 Å. The Mn(10)-O(9) bond length is 1.99 Å. Both Mn(10)-O(7) bond lengths are 1.93 Å. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(8), and one Mn(9) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra,  an edgeedge with one O(10)Sr4Mn2 octahedra,  an edgeedge with one O(11)Sr4Mn2 octahedra, edges with two equivalent O(2)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(12)Sr4Mn2 octahedra, edges with two equivalent O(1)Sr4Mn2 octahedra,  a faceface with one O(3)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-58°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(10) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(13)Sr4Mn2 octahedra, corners with two equivalent O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(16)Sr4Mn2 octahedra, edges with two equivalent O(4)Sr2La2Mn2 octahedra,  a faceface with one O(17)Sr2La2Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-61°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(3), and one Mn(8) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(15)Sr4Mn2 octahedra, edges with two equivalent O(3)Sr2La2Mn2 octahedra,  a faceface with one O(18)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra, and  a faceface with one O(10)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 3-58°. In the fifth O site, O(5) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(4), and one Mn(9) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr2La2Mn2 octahedra,  an edgeedge with one O(14)Sr4Mn2 octahedra, edges with two equivalent O(6)Sr2La2Mn2 octahedra,  a faceface with one O(17)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the sixth O site, O(6) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(2), and one Mn(5) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra,  an edgeedge with one O(13)Sr4Mn2 octahedra, edges with two equivalent O(5)Sr2La2Mn2 octahedra,  a faceface with one O(18)Sr2La2Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-63°. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(3), one Sr(4), one La(1), one Mn(10), and one Mn(3) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), one La(1), one Mn(4), and one Mn(5) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(3), one Mn(10), and one Mn(7) atom. In the tenth O site, O(10) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mn(3), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(11)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(18)Sr2La2Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-69°. In the eleventh O site, O(11) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(4), and one Mn(6) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(17)Sr2La2Mn2 octahedra,  a cornercorner with one O(10)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra, corners with two equivalent O(16)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4Mn2 octahedra, edges with two equivalent O(12)Sr4Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra,  a faceface with one O(14)Sr4Mn2 octahedra, and  a faceface with one O(15)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-69°. In the twelfth O site, O(12) is bonded to two equivalent Sr(2), two equivalent Sr(4), one Mn(5), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, corners with two equivalent O(15)Sr4Mn2 octahedra,  an edgeedge with one O(2)Sr4Mn2 octahedra, edges with two equivalent O(11)Sr4Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra,  a faceface with one O(13)Sr4Mn2 octahedra, and  a faceface with one O(16)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 6-70°. In the thirteenth O site, O(13) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(1), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(3)Sr2La2Mn2 octahedra,  a cornercorner with one O(16)Sr4Mn2 octahedra, corners with two equivalent O(18)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra, edges with two equivalent O(14)Sr4Mn2 octahedra,  a faceface with one O(17)Sr2La2Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-69°. In the fourteenth O site, O(14) is bonded to two equivalent Sr(2), two equivalent Sr(3), one Mn(6), and one Mn(8) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(4)Sr2La2Mn2 octahedra,  a cornercorner with one O(15)Sr4Mn2 octahedra, corners with two equivalent O(17)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra, edges with two equivalent O(13)Sr4Mn2 octahedra,  a faceface with one O(18)Sr2La2Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-70°. In the fifteenth O site, O(15) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(6), and one Mn(9) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(14)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra,  an edgeedge with one O(4)Sr2La2Mn2 octahedra, edges with two equivalent O(16)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4Mn2 octahedra,  a faceface with one O(10)Sr4Mn2 octahedra, and  a faceface with one O(11)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-62°. In the sixteenth O site, O(16) is bonded to two equivalent Sr(1), two equivalent Sr(4), one Mn(2), and one Mn(7) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(13)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(11)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr2La2Mn2 octahedra, edges with two equivalent O(15)Sr4Mn2 octahedra,  a faceface with one O(12)Sr4Mn2 octahedra, and  a faceface with one O(2)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-69°. In the seventeenth O site, O(17) is bonded to two equivalent Sr(3), two equivalent La(1), one Mn(1), and one Mn(4) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(11)Sr4Mn2 octahedra,  a cornercorner with one O(2)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr2La2Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(14)Sr4Mn2 octahedra, edges with two equivalent O(18)Sr2La2Mn2 octahedra,  a faceface with one O(3)Sr2La2Mn2 octahedra,  a faceface with one O(5)Sr2La2Mn2 octahedra, and  a faceface with one O(13)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the eighteenth O site, O(18) is bonded to two equivalent Sr(3), two equivalent La(1), one Mn(5), and one Mn(8) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(1)Sr4Mn2 octahedra,  a cornercorner with one O(12)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(13)Sr4Mn2 octahedra,  an edgeedge with one O(10)Sr4Mn2 octahedra, edges with two equivalent O(17)Sr2La2Mn2 octahedra,  a faceface with one O(4)Sr2La2Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra, and  a faceface with one O(14)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the nineteenth O site, O(19) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(1), one Mn(10), and one Mn(9) atom. In the twentieth O site, O(20) is bonded in a 6-coordinate geometry to two equivalent Sr(4), two equivalent La(1), one Mn(2), and one Mn(3) atom. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one La(1), one Mn(1), and one Mn(8) atom. In the twenty-second O site, O(22) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(4), one La(1), one Mn(2), and one Mn(9) atom.