VBO3 is Calcite structured and crystallizes in the trigonal R-3c space group. V(1) is bonded to six equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 55°. B(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one B(1) atom.
VBO3 is Calcite structured and crystallizes in the trigonal R-3c space group. V(1) is bonded to six equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 55°. All V(1)-O(1) bond lengths are 2.03 Å. B(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All B(1)-O(1) bond lengths are 1.38 Å. O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one B(1) atom.