Pb3WZn3P2O14 crystallizes in the trigonal P321 space group. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra. Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent W(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 60°. Pb(1) is bonded in a 2-coordinate geometry to two equivalent O(1) atoms. P(1) is bonded to one O(2) and three equivalent O(3) atoms to form PO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Zn(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(1) atom.
Pb3WZn3P2O14 crystallizes in the trigonal P321 space group. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra. All W(1)-O(1) bond lengths are 1.96 Å. Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent W(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 60°. Both Zn(1)-O(1) bond lengths are 1.95 Å. Both Zn(1)-O(3) bond lengths are 2.01 Å. Pb(1) is bonded in a 2-coordinate geometry to two equivalent O(1) atoms. Both Pb(1)-O(1) bond lengths are 2.39 Å. P(1) is bonded to one O(2) and three equivalent O(3) atoms to form PO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra. The P(1)-O(2) bond length is 1.54 Å. All P(1)-O(3) bond lengths are 1.57 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Zn(1), and one Pb(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(1) atom.