CsSrCl3 is Orthorhombic Perovskite-like structured and crystallizes in the trigonal R3c space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent Cl(1) atoms. Sr(1) is bonded to six equivalent Cl(1) atoms to form corner-sharing SrCl6 octahedra. The corner-sharing octahedral tilt angles are 19°. Cl(1) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Sr(1) atoms.
CsSrCl3 is Orthorhombic Perovskite-like structured and crystallizes in the trigonal R3c space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent Cl(1) atoms. There are a spread of Cs(1)-Cl(1) bond distances ranging from 3.56-4.10 Å. Sr(1) is bonded to six equivalent Cl(1) atoms to form corner-sharing SrCl6 octahedra. The corner-sharing octahedral tilt angles are 19°. All Sr(1)-Cl(1) bond lengths are 2.86 Å. Cl(1) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Sr(1) atoms.