N2Sb2OCl6NCl is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of eight ammonia atoms, four chloramine molecules, and two Sb2OCl6 clusters. In each Sb2OCl6 cluster, Sb(1) is bonded to one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom to form a mixture of distorted corner and edge-sharing SbCl4O trigonal bipyramids. O(1) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Sb(1) atoms. In the second Cl site, Cl(5) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom.
N2Sb2OCl6NCl is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of eight ammonia atoms, four chloramine molecules, and two Sb2OCl6 clusters. In each Sb2OCl6 cluster, Sb(1) is bonded to one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom to form a mixture of distorted corner and edge-sharing SbCl4O trigonal bipyramids. The Sb(1)-O(1) bond length is 1.97 Å. The Sb(1)-Cl(1) bond length is 2.37 Å. The Sb(1)-Cl(2) bond length is 2.38 Å. The Sb(1)-Cl(3) bond length is 2.70 Å. The Sb(1)-Cl(5) bond length is 2.65 Å. O(1) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Sb(1) atoms. In the second Cl site, Cl(5) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom.