CaLa2WO6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 35°. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 35°. O(1) is bonded in a 4-coordinate geometry to one Ca(1), two equivalent La(1), and one W(1) atom.
CaLa2WO6 crystallizes in the trigonal R-3 space group. Ca(1) is bonded to six equivalent O(1) atoms to form CaO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 35°. All Ca(1)-O(1) bond lengths are 2.32 Å. La(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.35 Å) and three longer (2.72 Å) La(1)-O(1) bond lengths. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Ca(1)O6 octahedra. The corner-sharing octahedral tilt angles are 35°. All W(1)-O(1) bond lengths are 2.08 Å. O(1) is bonded in a 4-coordinate geometry to one Ca(1), two equivalent La(1), and one W(1) atom.