K2LiGdCl6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. K(1) is bonded to twelve equivalent Cl(1) atoms to form KCl12 cuboctahedra that share corners with twelve equivalent K(1)Cl12 cuboctahedra, faces with six equivalent K(1)Cl12 cuboctahedra, faces with four equivalent Li(1)Cl6 octahedra, and faces with four equivalent Gd(1)Cl6 octahedra. Li(1) is bonded to six equivalent Cl(1) atoms to form LiCl6 octahedra that share corners with six equivalent Gd(1)Cl6 octahedra and faces with eight equivalent K(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Gd(1) is bonded to six equivalent Cl(1) atoms to form GdCl6 octahedra that share corners with six equivalent Li(1)Cl6 octahedra and faces with eight equivalent K(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to four equivalent K(1), one Li(1), and one Gd(1) atom.
K2LiGdCl6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. K(1) is bonded to twelve equivalent Cl(1) atoms to form KCl12 cuboctahedra that share corners with twelve equivalent K(1)Cl12 cuboctahedra, faces with six equivalent K(1)Cl12 cuboctahedra, faces with four equivalent Li(1)Cl6 octahedra, and faces with four equivalent Gd(1)Cl6 octahedra. All K(1)-Cl(1) bond lengths are 3.69 Å. Li(1) is bonded to six equivalent Cl(1) atoms to form LiCl6 octahedra that share corners with six equivalent Gd(1)Cl6 octahedra and faces with eight equivalent K(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. All Li(1)-Cl(1) bond lengths are 2.57 Å. Gd(1) is bonded to six equivalent Cl(1) atoms to form GdCl6 octahedra that share corners with six equivalent Li(1)Cl6 octahedra and faces with eight equivalent K(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. All Gd(1)-Cl(1) bond lengths are 2.66 Å. Cl(1) is bonded in a linear geometry to four equivalent K(1), one Li(1), and one Gd(1) atom.