(Na)2AgAlCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a AgAlCl6 framework. In the AgAlCl6 framework, Ag(1) is bonded to six equivalent Cl(1) atoms to form AgCl6 octahedra that share corners with six equivalent Al(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Al(1) is bonded to six equivalent Cl(1) atoms to form AlCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Ag(1) and one Al(1) atom.
(Na)2AgAlCl6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a AgAlCl6 framework. In the AgAlCl6 framework, Ag(1) is bonded to six equivalent Cl(1) atoms to form AgCl6 octahedra that share corners with six equivalent Al(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Ag(1)-Cl(1) bond lengths are 2.69 Å. Al(1) is bonded to six equivalent Cl(1) atoms to form AlCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-Cl(1) bond lengths are 2.34 Å. Cl(1) is bonded in a linear geometry to one Ag(1) and one Al(1) atom.