SrLaVO4 is (La,Ba)CuO4-derived structured and crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 9-coordinate geometry to two equivalent O(1), three equivalent O(2), and four equivalent O(3) atoms. La(1) is bonded in a 9-coordinate geometry to two equivalent O(2), three equivalent O(1), and four equivalent O(3) atoms. V(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedra are not tilted. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), three equivalent La(1), and one V(1) atom to form distorted OSr2La3V octahedra that share  a cornercorner with one O(2)Sr3La2V octahedra, corners with four equivalent O(1)Sr2La3V octahedra, corners with twelve equivalent O(3)Sr2La2V2 octahedra, edges with two equivalent O(1)Sr2La3V octahedra, edges with six equivalent O(2)Sr3La2V octahedra, and faces with four equivalent O(3)Sr2La2V2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the second O site, O(2) is bonded to three equivalent Sr(1), two equivalent La(1), and one V(1) atom to form distorted OSr3La2V octahedra that share  a cornercorner with one O(1)Sr2La3V octahedra, corners with four equivalent O(2)Sr3La2V octahedra, corners with twelve equivalent O(3)Sr2La2V2 octahedra, edges with two equivalent O(2)Sr3La2V octahedra, edges with six equivalent O(1)Sr2La3V octahedra, and faces with four equivalent O(3)Sr2La2V2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent La(1), and two equivalent V(1) atoms to form distorted OSr2La2V2 octahedra that share corners with two equivalent O(3)Sr2La2V2 octahedra, corners with six equivalent O(1)Sr2La3V octahedra, corners with six equivalent O(2)Sr3La2V octahedra, edges with two equivalent O(3)Sr2La2V2 octahedra, faces with two equivalent O(1)Sr2La3V octahedra, faces with two equivalent O(2)Sr3La2V octahedra, and faces with four equivalent O(3)Sr2La2V2 octahedra. The corner-sharing octahedral tilt angles range from 1-55°.
SrLaVO4 is (La,Ba)CuO4-derived structured and crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 9-coordinate geometry to two equivalent O(1), three equivalent O(2), and four equivalent O(3) atoms. Both Sr(1)-O(1) bond lengths are 2.79 Å. There is one shorter (2.41 Å) and two longer (2.79 Å) Sr(1)-O(2) bond lengths. All Sr(1)-O(3) bond lengths are 2.71 Å. La(1) is bonded in a 9-coordinate geometry to two equivalent O(2), three equivalent O(1), and four equivalent O(3) atoms. Both La(1)-O(2) bond lengths are 2.78 Å. There is one shorter (2.32 Å) and two longer (2.81 Å) La(1)-O(1) bond lengths. All La(1)-O(3) bond lengths are 2.67 Å. V(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedra are not tilted. The V(1)-O(1) bond length is 2.27 Å. The V(1)-O(2) bond length is 2.10 Å. All V(1)-O(3) bond lengths are 1.96 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), three equivalent La(1), and one V(1) atom to form distorted OSr2La3V octahedra that share  a cornercorner with one O(2)Sr3La2V octahedra, corners with four equivalent O(1)Sr2La3V octahedra, corners with twelve equivalent O(3)Sr2La2V2 octahedra, edges with two equivalent O(1)Sr2La3V octahedra, edges with six equivalent O(2)Sr3La2V octahedra, and faces with four equivalent O(3)Sr2La2V2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the second O site, O(2) is bonded to three equivalent Sr(1), two equivalent La(1), and one V(1) atom to form distorted OSr3La2V octahedra that share  a cornercorner with one O(1)Sr2La3V octahedra, corners with four equivalent O(2)Sr3La2V octahedra, corners with twelve equivalent O(3)Sr2La2V2 octahedra, edges with two equivalent O(2)Sr3La2V octahedra, edges with six equivalent O(1)Sr2La3V octahedra, and faces with four equivalent O(3)Sr2La2V2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent La(1), and two equivalent V(1) atoms to form distorted OSr2La2V2 octahedra that share corners with two equivalent O(3)Sr2La2V2 octahedra, corners with six equivalent O(1)Sr2La3V octahedra, corners with six equivalent O(2)Sr3La2V octahedra, edges with two equivalent O(3)Sr2La2V2 octahedra, faces with two equivalent O(1)Sr2La3V octahedra, faces with two equivalent O(2)Sr3La2V octahedra, and faces with four equivalent O(3)Sr2La2V2 octahedra. The corner-sharing octahedral tilt angles range from 1-55°.