UCl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two UCl5 clusters. U(1) is bonded in a 2-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one U(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one U(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one U(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one U(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one U(1) atom.
UCl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two UCl5 clusters. U(1) is bonded in a 2-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. The U(1)-Cl(1) bond length is 3.59 Å. The U(1)-Cl(2) bond length is 1.85 Å. The U(1)-Cl(3) bond length is 2.57 Å. The U(1)-Cl(4) bond length is 2.54 Å. The U(1)-Cl(5) bond length is 1.73 Å. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one U(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one U(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one U(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one U(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one U(1) atom.