MnAuO2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to six equivalent O(1) atoms to form edge-sharing MnO6 octahedra. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent Mn(1) and one Au(1) atom to form a mixture of distorted corner and edge-sharing OMn3Au tetrahedra.
MnAuO2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to six equivalent O(1) atoms to form edge-sharing MnO6 octahedra. There are four shorter (1.95 Å) and two longer (2.25 Å) Mn(1)-O(1) bond lengths. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Au(1)-O(1) bond lengths are 2.06 Å. O(1) is bonded to three equivalent Mn(1) and one Au(1) atom to form a mixture of distorted corner and edge-sharing OMn3Au tetrahedra.