NaAgO crystallizes in the tetragonal I-4m2 space group. Na(1) is bonded in a see-saw-like geometry to four equivalent O(1) atoms. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent Na(1) and two equivalent Ag(1) atoms to form a mixture of edge and corner-sharing ONa4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-15°.
NaAgO crystallizes in the tetragonal I-4m2 space group. Na(1) is bonded in a see-saw-like geometry to four equivalent O(1) atoms. There are a spread of Na(1)-O(1) bond distances ranging from 2.36-2.40 Å. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.10 Å. O(1) is bonded to four equivalent Na(1) and two equivalent Ag(1) atoms to form a mixture of edge and corner-sharing ONa4Ag2 octahedra. The corner-sharing octahedral tilt angles range from 1-15°.