YRe(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. Y(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted YO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-62°. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Re(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-62°. Re(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-51°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Re(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Re(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Re(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(1) atoms.
YRe(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. Y(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted YO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Re(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-62°. Both Y(1)-O(1) bond lengths are 2.34 Å. Both Y(1)-O(3) bond lengths are 2.30 Å. Both Y(1)-O(4) bond lengths are 2.14 Å. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra, corners with four equivalent Re(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-62°. The W(1)-O(1) bond length is 2.06 Å. The W(1)-O(3) bond length is 2.08 Å. There is one shorter (2.10 Å) and one longer (2.24 Å) W(1)-O(2) bond length. There is one shorter (2.04 Å) and one longer (2.08 Å) W(1)-O(4) bond length. Re(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ReO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-51°. Both Re(1)-O(1) bond lengths are 1.96 Å. Both Re(1)-O(2) bond lengths are 2.06 Å. Both Re(1)-O(3) bond lengths are 2.02 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Re(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Re(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Re(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Y(1) and two equivalent W(1) atoms.