B3H8NH4 is Indium-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four ammonium molecules and four B3H8 clusters. In each B3H8 cluster, there are two inequivalent B sites. In the first B site, B(1) is bonded in a 4-coordinate geometry to two equivalent H(4) and two equivalent H(5) atoms. In the second B site, B(2) is bonded in a distorted trigonal non-coplanar geometry to one H(4) and two equivalent H(3) atoms. There are three inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one B(2) atom. In the third H site, H(4) is bonded in an L-shaped geometry to one B(1) and one B(2) atom.
B3H8NH4 is Indium-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four ammonium molecules and four B3H8 clusters. In each B3H8 cluster, there are two inequivalent B sites. In the first B site, B(1) is bonded in a 4-coordinate geometry to two equivalent H(4) and two equivalent H(5) atoms. Both B(1)-H(4) bond lengths are 1.45 Å. Both B(1)-H(5) bond lengths are 1.21 Å. In the second B site, B(2) is bonded in a distorted trigonal non-coplanar geometry to one H(4) and two equivalent H(3) atoms. The B(2)-H(4) bond length is 1.27 Å. Both B(2)-H(3) bond lengths are 1.21 Å. There are three inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one B(2) atom. In the third H site, H(4) is bonded in an L-shaped geometry to one B(1) and one B(2) atom.