CrPO4 crystallizes in the orthorhombic Fdd2 space group. Cr(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cr(1) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cr(1) and one P(1) atom.
CrPO4 crystallizes in the orthorhombic Fdd2 space group. Cr(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Both Cr(1)-O(1) bond lengths are 1.91 Å. There are two shorter (2.05 Å) and two longer (2.23 Å) Cr(1)-O(2) bond lengths. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both P(1)-O(1) bond lengths are 1.54 Å. Both P(1)-O(2) bond lengths are 1.57 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cr(1) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cr(1) and one P(1) atom.