CuF4ClF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ClF6 clusters and two CuF4 clusters. In each ClF6 cluster, Cl(1) is bonded in an octahedral geometry to two equivalent F(3) and four equivalent F(1,2) atoms. There are two inequivalent F sites. In the first F site, F(1,2) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cl(1) atom. In each CuF4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent F(4) and two equivalent F(5) atoms. There are two inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Cu(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one Cu(1) atom.
CuF4ClF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ClF6 clusters and two CuF4 clusters. In each ClF6 cluster, Cl(1) is bonded in an octahedral geometry to two equivalent F(3) and four equivalent F(1,2) atoms. Both Cl(1)-F(3) bond lengths are 1.66 Å. All Cl(1)-F(1,2) bond lengths are 1.65 Å. There are two inequivalent F sites. In the first F site, F(1,2) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cl(1) atom. In each CuF4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent F(4) and two equivalent F(5) atoms. Both Cu(1)-F(4) bond lengths are 1.74 Å. Both Cu(1)-F(5) bond lengths are 1.73 Å. There are two inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one Cu(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one Cu(1) atom.