Ba2LaIrO6 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form distorted BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent La(1)O6 octahedra, and faces with four equivalent Ir(1)O6 octahedra. La(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LaO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 7-8°. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent La(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 7-8°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to four equivalent Ba(1), one La(1), and one Ir(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to four equivalent Ba(1), one La(1), and one Ir(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to four equivalent Ba(1), one La(1), and one Ir(1) atom.
Ba2LaIrO6 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form distorted BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent La(1)O6 octahedra, and faces with four equivalent Ir(1)O6 octahedra. There are a spread of Ba(1)-O(1) bond distances ranging from 2.96-3.19 Å. There are a spread of Ba(1)-O(2) bond distances ranging from 2.92-3.21 Å. There are a spread of Ba(1)-O(3) bond distances ranging from 2.93-3.21 Å. La(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LaO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 7-8°. Both La(1)-O(1) bond lengths are 2.35 Å. Both La(1)-O(2) bond lengths are 2.35 Å. Both La(1)-O(3) bond lengths are 2.35 Å. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent La(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 7-8°. Both Ir(1)-O(1) bond lengths are 1.99 Å. Both Ir(1)-O(2) bond lengths are 1.99 Å. Both Ir(1)-O(3) bond lengths are 1.98 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to four equivalent Ba(1), one La(1), and one Ir(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to four equivalent Ba(1), one La(1), and one Ir(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to four equivalent Ba(1), one La(1), and one Ir(1) atom.