ReO2Cl3 is Tungsten structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two ReO2Cl3 clusters. Re(1) is bonded in a 6-coordinate geometry to two equivalent O(1), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Re(1) atoms.
ReO2Cl3 is Tungsten structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two ReO2Cl3 clusters. Re(1) is bonded in a 6-coordinate geometry to two equivalent O(1), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. Both Re(1)-O(1) bond lengths are 1.70 Å. The Re(1)-Cl(1) bond length is 2.27 Å. The Re(1)-Cl(2) bond length is 2.28 Å. Both Re(1)-Cl(3) bond lengths are 2.62 Å. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Re(1) atoms.