Cs2NaInH6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent H(1) atoms to form CsH12 cuboctahedra that share corners with twelve equivalent Cs(1)H12 cuboctahedra, faces with six equivalent Cs(1)H12 cuboctahedra, faces with four equivalent Na(1)H6 octahedra, and faces with four equivalent In(1)H6 octahedra. Na(1) is bonded to six equivalent H(1) atoms to form NaH6 octahedra that share corners with six equivalent In(1)H6 octahedra and faces with eight equivalent Cs(1)H12 cuboctahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to six equivalent H(1) atoms to form InH6 octahedra that share corners with six equivalent Na(1)H6 octahedra and faces with eight equivalent Cs(1)H12 cuboctahedra. The corner-sharing octahedra are not tilted. H(1) is bonded in a distorted linear geometry to four equivalent Cs(1), one Na(1), and one In(1) atom.
Cs2NaInH6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent H(1) atoms to form CsH12 cuboctahedra that share corners with twelve equivalent Cs(1)H12 cuboctahedra, faces with six equivalent Cs(1)H12 cuboctahedra, faces with four equivalent Na(1)H6 octahedra, and faces with four equivalent In(1)H6 octahedra. All Cs(1)-H(1) bond lengths are 3.14 Å. Na(1) is bonded to six equivalent H(1) atoms to form NaH6 octahedra that share corners with six equivalent In(1)H6 octahedra and faces with eight equivalent Cs(1)H12 cuboctahedra. The corner-sharing octahedra are not tilted. All Na(1)-H(1) bond lengths are 2.45 Å. In(1) is bonded to six equivalent H(1) atoms to form InH6 octahedra that share corners with six equivalent Na(1)H6 octahedra and faces with eight equivalent Cs(1)H12 cuboctahedra. The corner-sharing octahedra are not tilted. All In(1)-H(1) bond lengths are 1.97 Å. H(1) is bonded in a distorted linear geometry to four equivalent Cs(1), one Na(1), and one In(1) atom.