VO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pnnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 50°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms.
VO2 is Hydrophilite-like structured and crystallizes in the orthorhombic Pnnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two shorter (1.91 Å) and four longer (1.99 Å) V(1)-O(1) bond lengths. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms.