Ca2Pd2Ag crystallizes in the orthorhombic Immm space group. Ca(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Ag(1) atoms. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ca(1), one Pd(1), and two equivalent Ag(1) atoms. Ag(1) is bonded to eight equivalent Ca(1) and four equivalent Pd(1) atoms to form a mixture of face and edge-sharing AgCa8Pd4 cuboctahedra.
Ca2Pd2Ag crystallizes in the orthorhombic Immm space group. Ca(1) is bonded in a 10-coordinate geometry to six equivalent Pd(1) and four equivalent Ag(1) atoms. There are two shorter (2.95 Å) and four longer (3.12 Å) Ca(1)-Pd(1) bond lengths. There are two shorter (3.36 Å) and two longer (3.37 Å) Ca(1)-Ag(1) bond lengths. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Ca(1), one Pd(1), and two equivalent Ag(1) atoms. The Pd(1)-Pd(1) bond length is 2.68 Å. Both Pd(1)-Ag(1) bond lengths are 2.73 Å. Ag(1) is bonded to eight equivalent Ca(1) and four equivalent Pd(1) atoms to form a mixture of face and edge-sharing AgCa8Pd4 cuboctahedra.