(MgSO7)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four water atoms and two MgSO7 clusters. In each MgSO7 cluster, Mg(1) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(5), one O(7), and one O(8) atom. S(1) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a bent 150 degrees geometry to one Mg(1) and one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Mg(1) and one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Mg(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Mg(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Mg(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one S(1) atom.
(MgSO7)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four water atoms and two MgSO7 clusters. In each MgSO7 cluster, Mg(1) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(5), one O(7), and one O(8) atom. The Mg(1)-O(2) bond length is 2.28 Å. The Mg(1)-O(4) bond length is 2.05 Å. The Mg(1)-O(5) bond length is 2.06 Å. The Mg(1)-O(7) bond length is 1.98 Å. The Mg(1)-O(8) bond length is 1.95 Å. S(1) is bonded in a tetrahedral geometry to one O(3), one O(6), one O(7), and one O(8) atom. The S(1)-O(3) bond length is 1.47 Å. The S(1)-O(6) bond length is 1.52 Å. The S(1)-O(7) bond length is 1.49 Å. The S(1)-O(8) bond length is 1.48 Å. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a bent 150 degrees geometry to one Mg(1) and one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Mg(1) and one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Mg(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Mg(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Mg(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one S(1) atom.