SmLa7TiV7O24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R3m space group. Sm(1) is bonded to three equivalent O(4), three equivalent O(6), and six equivalent O(5) atoms to form SmO12 cuboctahedra that share corners with twelve equivalent La(2)O12 cuboctahedra, faces with six equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. There are three inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(3)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. In the second La site, La(2) is bonded to one O(4), one O(6), two equivalent O(1), two equivalent O(3), two equivalent O(5), and four equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. In the third La site, La(3) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with six equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. Ti(1) is bonded to three equivalent O(1) and three equivalent O(4) atoms to form TiO6 octahedra that share corners with six equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are three inequivalent V sites. In the first V site, V(3) is bonded to three equivalent O(3) and three equivalent O(6) atoms to form VO6 octahedra that share corners with six equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the second V site, V(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third V site, V(2) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), one Ti(1), and one V(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), one V(1), and one V(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), one V(2), and one V(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(1), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(1), and one V(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(2), and one V(3) atom.
SmLa7TiV7O24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R3m space group. Sm(1) is bonded to three equivalent O(4), three equivalent O(6), and six equivalent O(5) atoms to form SmO12 cuboctahedra that share corners with twelve equivalent La(2)O12 cuboctahedra, faces with six equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. All Sm(1)-O(4) bond lengths are 2.83 Å. All Sm(1)-O(6) bond lengths are 2.73 Å. All Sm(1)-O(5) bond lengths are 2.78 Å. There are three inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(3), two equivalent O(2), two equivalent O(4), two equivalent O(6), and four equivalent O(5) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(3)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. The La(1)-O(1) bond length is 2.83 Å. The La(1)-O(3) bond length is 2.79 Å. Both La(1)-O(2) bond lengths are 2.80 Å. Both La(1)-O(4) bond lengths are 2.84 Å. Both La(1)-O(6) bond lengths are 2.77 Å. There are two shorter (2.80 Å) and two longer (2.81 Å) La(1)-O(5) bond lengths. In the second La site, La(2) is bonded to one O(4), one O(6), two equivalent O(1), two equivalent O(3), two equivalent O(5), and four equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. The La(2)-O(4) bond length is 2.85 Å. The La(2)-O(6) bond length is 2.81 Å. Both La(2)-O(1) bond lengths are 2.84 Å. Both La(2)-O(3) bond lengths are 2.77 Å. Both La(2)-O(5) bond lengths are 2.82 Å. There are two shorter (2.80 Å) and two longer (2.81 Å) La(2)-O(2) bond lengths. In the third La site, La(3) is bonded to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with twelve equivalent La(1)O12 cuboctahedra, faces with six equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(3)O6 octahedra, faces with three equivalent V(1)O6 octahedra, and faces with three equivalent V(2)O6 octahedra. All La(3)-O(1) bond lengths are 2.83 Å. All La(3)-O(3) bond lengths are 2.77 Å. All La(3)-O(2) bond lengths are 2.81 Å. Ti(1) is bonded to three equivalent O(1) and three equivalent O(4) atoms to form TiO6 octahedra that share corners with six equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. All Ti(1)-O(1) bond lengths are 1.95 Å. All Ti(1)-O(4) bond lengths are 1.94 Å. There are three inequivalent V sites. In the first V site, V(3) is bonded to three equivalent O(3) and three equivalent O(6) atoms to form VO6 octahedra that share corners with six equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. All V(3)-O(3) bond lengths are 1.97 Å. All V(3)-O(6) bond lengths are 1.97 Å. In the second V site, V(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. The V(1)-O(1) bond length is 2.03 Å. The V(1)-O(4) bond length is 2.02 Å. Both V(1)-O(2) bond lengths are 1.99 Å. Both V(1)-O(5) bond lengths are 1.99 Å. In the third V site, V(2) is bonded to one O(3), one O(6), two equivalent O(2), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. The V(2)-O(3) bond length is 2.00 Å. The V(2)-O(6) bond length is 1.99 Å. Both V(2)-O(2) bond lengths are 1.98 Å. Both V(2)-O(5) bond lengths are 1.97 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), one Ti(1), and one V(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), one V(1), and one V(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(3), two equivalent La(2), one V(2), and one V(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(1), and one V(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(1), and one V(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(2), and one V(3) atom.