ReHOCl3CN2S is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four CN2S clusters and four ReHOCl3 clusters. In each CN2S cluster, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. S(1) is bonded in a distorted single-bond geometry to one C(1) atom. In each ReHOCl3 cluster, Re(1) is bonded in a 5-coordinate geometry to one H(1), one O(1), one Cl(1), one Cl(2), and one Cl(3) atom. H(1) is bonded in a single-bond geometry to one Re(1) atom. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom.
ReHOCl3CN2S is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four CN2S clusters and four ReHOCl3 clusters. In each CN2S cluster, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.40 Å. The C(1)-N(2) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.60 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. The N(1)-N(2) bond length is 1.29 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. S(1) is bonded in a distorted single-bond geometry to one C(1) atom. In each ReHOCl3 cluster, Re(1) is bonded in a 5-coordinate geometry to one H(1), one O(1), one Cl(1), one Cl(2), and one Cl(3) atom. The Re(1)-H(1) bond length is 1.71 Å. The Re(1)-O(1) bond length is 1.73 Å. The Re(1)-Cl(1) bond length is 2.31 Å. The Re(1)-Cl(2) bond length is 2.26 Å. The Re(1)-Cl(3) bond length is 2.31 Å. H(1) is bonded in a single-bond geometry to one Re(1) atom. O(1) is bonded in a single-bond geometry to one Re(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom.