(H2)2(CF3)2(H9SO7)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one hydrogen peroxide molecule, two trifluoromethane molecules, and two H9SO7 clusters. In each H9SO7 cluster, there are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(7) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(4) and one O(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one O(7) atom. In the seventh H site, H(8) is bonded in a distorted linear geometry to one O(7) and one O(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one O(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one O(2) and one O(8) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. In the second O site, O(5) is bonded in a distorted trigonal planar geometry to one H(2), one H(4), and one H(5) atom. In the third O site, O(7) is bonded in a trigonal non-coplanar geometry to one H(1), one H(7), and one H(8) atom. In the fourth O site, O(8) is bonded in a trigonal non-coplanar geometry to one H(10), one H(11), and one H(8) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(11) and one S(1) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one S(1) atom.
(H2)2(CF3)2(H9SO7)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one hydrogen peroxide molecule, two trifluoromethane molecules, and two H9SO7 clusters. In each H9SO7 cluster, there are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(7) atom. The H(1)-O(4) bond length is 1.29 Å. The H(1)-O(7) bond length is 1.14 Å. In the second H site, H(2) is bonded in a distorted linear geometry to one O(4) and one O(5) atom. The H(2)-O(4) bond length is 1.01 Å. The H(2)-O(5) bond length is 1.59 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. The H(3)-O(4) bond length is 0.97 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. The H(4)-O(5) bond length is 0.97 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. The H(5)-O(5) bond length is 0.99 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one O(7) atom. The H(7)-O(7) bond length is 0.98 Å. In the seventh H site, H(8) is bonded in a distorted linear geometry to one O(7) and one O(8) atom. The H(8)-O(7) bond length is 1.05 Å. The H(8)-O(8) bond length is 1.49 Å. In the eighth H site, H(10) is bonded in a single-bond geometry to one O(8) atom. The H(10)-O(8) bond length is 0.98 Å. In the ninth H site, H(11) is bonded in a single-bond geometry to one O(2) and one O(8) atom. The H(11)-O(2) bond length is 1.71 Å. The H(11)-O(8) bond length is 1.00 Å. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.47 Å. The S(1)-O(3) bond length is 1.45 Å. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. In the second O site, O(5) is bonded in a distorted trigonal planar geometry to one H(2), one H(4), and one H(5) atom. In the third O site, O(7) is bonded in a trigonal non-coplanar geometry to one H(1), one H(7), and one H(8) atom. In the fourth O site, O(8) is bonded in a trigonal non-coplanar geometry to one H(10), one H(11), and one H(8) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(11) and one S(1) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one S(1) atom.