ZnCl4(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four guanidinium molecules and two ZnCl4 clusters. In each ZnCl4 cluster, Zn(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(1) atom.
ZnCl4(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four guanidinium molecules and two ZnCl4 clusters. In each ZnCl4 cluster, Zn(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Zn(1)-Cl(1) bond length is 2.32 Å. The Zn(1)-Cl(2) bond length is 2.29 Å. The Zn(1)-Cl(3) bond length is 2.30 Å. The Zn(1)-Cl(4) bond length is 2.28 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(1) atom.