Cd(O2Br)2 crystallizes in the orthorhombic Pnnm space group. Cd(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Br(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent O(1) and one Br(1) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Cd(1), two equivalent O(2), and one Br(1) atom. Br(1) is bonded in a 4-coordinate geometry to two equivalent Cd(1), one O(1), and one O(2) atom.
Cd(O2Br)2 crystallizes in the orthorhombic Pnnm space group. Cd(1) is bonded in a distorted linear geometry to two equivalent O(1) and four equivalent Br(1) atoms. Both Cd(1)-O(1) bond lengths are 2.16 Å. All Cd(1)-Br(1) bond lengths are 2.97 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent O(1) and one Br(1) atom. Both O(2)-O(1) bond lengths are 1.94 Å. The O(2)-Br(1) bond length is 1.97 Å. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Cd(1), two equivalent O(2), and one Br(1) atom. The O(1)-Br(1) bond length is 2.13 Å. Br(1) is bonded in a 4-coordinate geometry to two equivalent Cd(1), one O(1), and one O(2) atom.