TiSe is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent Se(1) atoms to form a mixture of edge, face, and corner-sharing TiSe6 octahedra. The corner-sharing octahedral tilt angles are 45°. Se(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted edge and corner-sharing SeTi6 pentagonal pyramids.
TiSe is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent Se(1) atoms to form a mixture of edge, face, and corner-sharing TiSe6 octahedra. The corner-sharing octahedral tilt angles are 45°. All Ti(1)-Se(1) bond lengths are 2.60 Å. Se(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted edge and corner-sharing SeTi6 pentagonal pyramids.