La2NiZnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R-3 space group. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. O(1) is bonded in a 5-coordinate geometry to three equivalent La(1), one Ni(1), and one Zn(1) atom.
La2NiZnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the trigonal R-3 space group. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. There are a spread of La(1)-O(1) bond distances ranging from 2.40-2.78 Å. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. All Ni(1)-O(1) bond lengths are 1.89 Å. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. All Zn(1)-O(1) bond lengths are 2.06 Å. O(1) is bonded in a 5-coordinate geometry to three equivalent La(1), one Ni(1), and one Zn(1) atom.