VOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms.
VOF is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing VO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. There are a spread of V(1)-O(1) bond distances ranging from 1.90-2.01 Å. There are a spread of V(1)-F(1) bond distances ranging from 2.13-2.17 Å. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms.