Zr2Ag2ZnF14 crystallizes in the monoclinic C2/m space group. Zr(1) is bonded to one F(1), one F(3), one F(4), two equivalent F(2), and two equivalent F(5) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Zn(1)F6 octahedra and  a cornercorner with one Zr(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 28-35°. Ag(1) is bonded in a square co-planar geometry to one F(4), one F(6), and two equivalent F(5) atoms. Zn(1) is bonded to two equivalent F(3) and four equivalent F(2) atoms to form ZnF6 octahedra that share corners with six equivalent Zr(1)F7 pentagonal bipyramids. There are six inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Zr(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Zr(1) and one Ag(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Ag(1) atoms.
Zr2Ag2ZnF14 crystallizes in the monoclinic C2/m space group. Zr(1) is bonded to one F(1), one F(3), one F(4), two equivalent F(2), and two equivalent F(5) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Zn(1)F6 octahedra and  a cornercorner with one Zr(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 28-35°. The Zr(1)-F(1) bond length is 2.12 Å. The Zr(1)-F(3) bond length is 2.04 Å. The Zr(1)-F(4) bond length is 2.04 Å. Both Zr(1)-F(2) bond lengths are 2.09 Å. Both Zr(1)-F(5) bond lengths are 2.13 Å. Ag(1) is bonded in a square co-planar geometry to one F(4), one F(6), and two equivalent F(5) atoms. The Ag(1)-F(4) bond length is 2.18 Å. The Ag(1)-F(6) bond length is 2.06 Å. Both Ag(1)-F(5) bond lengths are 2.14 Å. Zn(1) is bonded to two equivalent F(3) and four equivalent F(2) atoms to form ZnF6 octahedra that share corners with six equivalent Zr(1)F7 pentagonal bipyramids. Both Zn(1)-F(3) bond lengths are 2.03 Å. All Zn(1)-F(2) bond lengths are 2.07 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Zr(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zr(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Zr(1) and one Ag(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Ag(1) atoms.