NiWO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted WO6 octahedra that share corners with eight equivalent Ni(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. Ni(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NiO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent W(1) and one Ni(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ni(1) atoms.
NiWO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted WO6 octahedra that share corners with eight equivalent Ni(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. Both W(1)-O(1) bond lengths are 1.81 Å. There are two shorter (1.91 Å) and two longer (2.12 Å) W(1)-O(2) bond lengths. Ni(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NiO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. Both Ni(1)-O(2) bond lengths are 2.04 Å. There are two shorter (2.03 Å) and two longer (2.06 Å) Ni(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent W(1) and one Ni(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ni(1) atoms.