TeO3BrF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four TeO3BrF5 clusters. Te(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Br(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Te(1) and one Br(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom.
TeO3BrF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four TeO3BrF5 clusters. Te(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The Te(1)-O(2) bond length is 1.92 Å. The Te(1)-F(1) bond length is 1.87 Å. The Te(1)-F(2) bond length is 1.88 Å. The Te(1)-F(3) bond length is 1.89 Å. The Te(1)-F(4) bond length is 1.87 Å. The Te(1)-F(5) bond length is 1.87 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Br(1) atom. The O(1)-Br(1) bond length is 1.63 Å. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Te(1) and one Br(1) atom. The O(2)-Br(1) bond length is 2.01 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Br(1) atom. The O(3)-Br(1) bond length is 1.63 Å. Br(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom.