FeVSb crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded in a 14-coordinate geometry to two equivalent V(1), six equivalent Fe(1), and six equivalent Sb(1) atoms. Fe(1) is bonded in a 11-coordinate geometry to six equivalent V(1) and five equivalent Sb(1) atoms. Sb(1) is bonded in a 11-coordinate geometry to six equivalent V(1) and five equivalent Fe(1) atoms.
FeVSb crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded in a 14-coordinate geometry to two equivalent V(1), six equivalent Fe(1), and six equivalent Sb(1) atoms. Both V(1)-V(1) bond lengths are 2.65 Å. All V(1)-Fe(1) bond lengths are 2.86 Å. All V(1)-Sb(1) bond lengths are 2.86 Å. Fe(1) is bonded in a 11-coordinate geometry to six equivalent V(1) and five equivalent Sb(1) atoms. There are three shorter (2.53 Å) and two longer (2.65 Å) Fe(1)-Sb(1) bond lengths. Sb(1) is bonded in a 11-coordinate geometry to six equivalent V(1) and five equivalent Fe(1) atoms.