WCl6Te3I is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tungsten(vi) chloride molecules and two Te3I clusters. In each Te3I cluster, there are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a water-like geometry to one Te(2) and one Te(3) atom. In the second Te site, Te(2) is bonded in a water-like geometry to one Te(1) and one Te(3) atom. In the third Te site, Te(3) is bonded in a distorted single-bond geometry to one Te(1), one Te(2), and one I(1) atom. I(1) is bonded in a single-bond geometry to one Te(3) atom.
WCl6Te3I is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tungsten(vi) chloride molecules and two Te3I clusters. In each Te3I cluster, there are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a water-like geometry to one Te(2) and one Te(3) atom. The Te(1)-Te(2) bond length is 2.67 Å. The Te(1)-Te(3) bond length is 2.96 Å. In the second Te site, Te(2) is bonded in a water-like geometry to one Te(1) and one Te(3) atom. The Te(2)-Te(3) bond length is 2.91 Å. In the third Te site, Te(3) is bonded in a distorted single-bond geometry to one Te(1), one Te(2), and one I(1) atom. The Te(3)-I(1) bond length is 2.71 Å. I(1) is bonded in a single-bond geometry to one Te(3) atom.