CsUPNO9 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(4), one O(5), one O(6), one O(7), one O(8), two equivalent O(2), and two equivalent O(9) atoms. U(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(8) atom. N(1) is bonded in a trigonal planar geometry to one O(5), one O(7), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one U(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one U(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1), one U(1), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one U(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one U(1), and one N(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one N(1) atom.
CsUPNO9 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(4), one O(5), one O(6), one O(7), one O(8), two equivalent O(2), and two equivalent O(9) atoms. The Cs(1)-O(1) bond length is 3.48 Å. The Cs(1)-O(4) bond length is 3.46 Å. The Cs(1)-O(5) bond length is 3.33 Å. The Cs(1)-O(6) bond length is 3.39 Å. The Cs(1)-O(7) bond length is 3.22 Å. The Cs(1)-O(8) bond length is 3.28 Å. There is one shorter (3.29 Å) and one longer (3.41 Å) Cs(1)-O(2) bond length. There is one shorter (3.28 Å) and one longer (3.52 Å) Cs(1)-O(9) bond length. U(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. The U(1)-O(1) bond length is 2.27 Å. The U(1)-O(2) bond length is 1.82 Å. The U(1)-O(3) bond length is 2.32 Å. The U(1)-O(4) bond length is 2.34 Å. The U(1)-O(5) bond length is 2.56 Å. The U(1)-O(6) bond length is 1.81 Å. The U(1)-O(7) bond length is 2.53 Å. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(8) atom. The P(1)-O(1) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.55 Å. The P(1)-O(4) bond length is 1.55 Å. The P(1)-O(8) bond length is 1.55 Å. N(1) is bonded in a trigonal planar geometry to one O(5), one O(7), and one O(9) atom. The N(1)-O(5) bond length is 1.28 Å. The N(1)-O(7) bond length is 1.29 Å. The N(1)-O(9) bond length is 1.23 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one U(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one U(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1), one U(1), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one U(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one U(1), and one N(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one N(1) atom.