C2NS3F2AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two C2NS3F2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In each C2NS3F2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one F(4), and one F(6) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one S(1) atom. N(1) is bonded in a bent 120 degrees geometry to one C(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) and one S(2) atom. There are two inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one C(1) atom.
C2NS3F2AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two C2NS3F2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(7), and one F(8) atom. The As(1)-F(1) bond length is 1.77 Å. The As(1)-F(2) bond length is 1.78 Å. The As(1)-F(3) bond length is 1.78 Å. The As(1)-F(5) bond length is 1.77 Å. The As(1)-F(7) bond length is 1.77 Å. The As(1)-F(8) bond length is 1.79 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In each C2NS3F2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one F(4), and one F(6) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-F(4) bond length is 1.36 Å. The C(1)-F(6) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one S(1) atom. The C(2)-N(1) bond length is 1.28 Å. The C(2)-S(1) bond length is 1.76 Å. N(1) is bonded in a bent 120 degrees geometry to one C(2) and one S(3) atom. The N(1)-S(3) bond length is 1.60 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. The S(1)-S(2) bond length is 2.03 Å. In the second S site, S(2) is bonded in an L-shaped geometry to one S(1) and one S(3) atom. The S(2)-S(3) bond length is 2.12 Å. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) and one S(2) atom. There are two inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one C(1) atom.