SrMg6Bi crystallizes in the orthorhombic Amm2 space group. Sr(1) is bonded to two equivalent Mg(3), four equivalent Mg(1), four equivalent Mg(2), and two equivalent Bi(1) atoms to form SrMg10Bi2 cuboctahedra that share corners with four equivalent Bi(1)Sr2Mg10 cuboctahedra, corners with six equivalent Sr(1)Mg10Bi2 cuboctahedra, corners with eight equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Bi(1)Sr2Mg10 cuboctahedra, edges with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, faces with two equivalent Sr(1)Mg10Bi2 cuboctahedra, faces with two equivalent Bi(1)Sr2Mg10 cuboctahedra, and faces with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Sr(1), two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(3), two equivalent Mg(4), and two equivalent Bi(1) atoms to form distorted MgSr2Mg8Bi2 cuboctahedra that share corners with four equivalent Sr(1)Mg10Bi2 cuboctahedra, corners with four equivalent Bi(1)Sr2Mg10 cuboctahedra, corners with ten equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Sr(1)Mg10Bi2 cuboctahedra, edges with two equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Bi(1)Sr2Mg10 cuboctahedra, faces with two equivalent Sr(1)Mg10Bi2 cuboctahedra, faces with two equivalent Bi(1)Sr2Mg10 cuboctahedra, and faces with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra. In the second Mg site, Mg(2) is bonded in a 10-coordinate geometry to two equivalent Sr(1), one Mg(3), one Mg(4), two equivalent Mg(1), two equivalent Mg(2), and two equivalent Bi(1) atoms. In the third Mg site, Mg(3) is bonded in a 10-coordinate geometry to two equivalent Sr(1), two equivalent Mg(2), two equivalent Mg(4), and four equivalent Mg(1) atoms. In the fourth Mg site, Mg(4) is bonded in a 10-coordinate geometry to two equivalent Mg(2), two equivalent Mg(3), four equivalent Mg(1), and two equivalent Bi(1) atoms. Bi(1) is bonded to two equivalent Sr(1), two equivalent Mg(4), four equivalent Mg(1), and four equivalent Mg(2) atoms to form BiSr2Mg10 cuboctahedra that share corners with four equivalent Sr(1)Mg10Bi2 cuboctahedra, corners with six equivalent Bi(1)Sr2Mg10 cuboctahedra, corners with eight equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Sr(1)Mg10Bi2 cuboctahedra, edges with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, faces with two equivalent Sr(1)Mg10Bi2 cuboctahedra, faces with two equivalent Bi(1)Sr2Mg10 cuboctahedra, and faces with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra.
SrMg6Bi crystallizes in the orthorhombic Amm2 space group. Sr(1) is bonded to two equivalent Mg(3), four equivalent Mg(1), four equivalent Mg(2), and two equivalent Bi(1) atoms to form SrMg10Bi2 cuboctahedra that share corners with four equivalent Bi(1)Sr2Mg10 cuboctahedra, corners with six equivalent Sr(1)Mg10Bi2 cuboctahedra, corners with eight equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Bi(1)Sr2Mg10 cuboctahedra, edges with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, faces with two equivalent Sr(1)Mg10Bi2 cuboctahedra, faces with two equivalent Bi(1)Sr2Mg10 cuboctahedra, and faces with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra. Both Sr(1)-Mg(3) bond lengths are 3.44 Å. There are two shorter (3.41 Å) and two longer (3.47 Å) Sr(1)-Mg(1) bond lengths. All Sr(1)-Mg(2) bond lengths are 3.41 Å. Both Sr(1)-Bi(1) bond lengths are 3.26 Å. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Sr(1), two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(3), two equivalent Mg(4), and two equivalent Bi(1) atoms to form distorted MgSr2Mg8Bi2 cuboctahedra that share corners with four equivalent Sr(1)Mg10Bi2 cuboctahedra, corners with four equivalent Bi(1)Sr2Mg10 cuboctahedra, corners with ten equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Sr(1)Mg10Bi2 cuboctahedra, edges with two equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Bi(1)Sr2Mg10 cuboctahedra, faces with two equivalent Sr(1)Mg10Bi2 cuboctahedra, faces with two equivalent Bi(1)Sr2Mg10 cuboctahedra, and faces with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra. There is one shorter (3.24 Å) and one longer (3.29 Å) Mg(1)-Mg(1) bond length. Both Mg(1)-Mg(2) bond lengths are 3.31 Å. Both Mg(1)-Mg(3) bond lengths are 3.30 Å. Both Mg(1)-Mg(4) bond lengths are 3.33 Å. There is one shorter (3.38 Å) and one longer (3.50 Å) Mg(1)-Bi(1) bond length. In the second Mg site, Mg(2) is bonded in a 10-coordinate geometry to two equivalent Sr(1), one Mg(3), one Mg(4), two equivalent Mg(1), two equivalent Mg(2), and two equivalent Bi(1) atoms. The Mg(2)-Mg(3) bond length is 3.21 Å. The Mg(2)-Mg(4) bond length is 3.29 Å. There is one shorter (3.18 Å) and one longer (3.34 Å) Mg(2)-Mg(2) bond length. Both Mg(2)-Bi(1) bond lengths are 3.34 Å. In the third Mg site, Mg(3) is bonded in a 10-coordinate geometry to two equivalent Sr(1), two equivalent Mg(2), two equivalent Mg(4), and four equivalent Mg(1) atoms. Both Mg(3)-Mg(4) bond lengths are 3.26 Å. In the fourth Mg site, Mg(4) is bonded in a 10-coordinate geometry to two equivalent Mg(2), two equivalent Mg(3), four equivalent Mg(1), and two equivalent Bi(1) atoms. Both Mg(4)-Bi(1) bond lengths are 3.46 Å. Bi(1) is bonded to two equivalent Sr(1), two equivalent Mg(4), four equivalent Mg(1), and four equivalent Mg(2) atoms to form BiSr2Mg10 cuboctahedra that share corners with four equivalent Sr(1)Mg10Bi2 cuboctahedra, corners with six equivalent Bi(1)Sr2Mg10 cuboctahedra, corners with eight equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, edges with two equivalent Sr(1)Mg10Bi2 cuboctahedra, edges with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra, faces with two equivalent Sr(1)Mg10Bi2 cuboctahedra, faces with two equivalent Bi(1)Sr2Mg10 cuboctahedra, and faces with four equivalent Mg(1)Sr2Mg8Bi2 cuboctahedra.