Li3CrS4 is Sulvanite structured and crystallizes in the cubic P-43m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. Cr(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded to three equivalent Li(1) and one Cr(1) atom to form a mixture of edge and corner-sharing SLi3Cr trigonal pyramids.
Li3CrS4 is Sulvanite structured and crystallizes in the cubic P-43m space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All Li(1)-S(1) bond lengths are 2.46 Å. Cr(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All Cr(1)-S(1) bond lengths are 2.13 Å. S(1) is bonded to three equivalent Li(1) and one Cr(1) atom to form a mixture of edge and corner-sharing SLi3Cr trigonal pyramids.