Mn(H2O)6(MnH4(OF2)2)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one manganese;hexahydrate molecule, two water molecules, and two MnH4(OF2)2 clusters. In each MnH4(OF2)2 cluster, Mn(2) is bonded in an octahedral geometry to one O(3), one O(5), one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Mn(2), one H(10), and one H(9) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(2), one H(5), and one H(6) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Mn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Mn(2) atom.
Mn(H2O)6(MnH4(OF2)2)2(H2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one manganese;hexahydrate molecule, two water molecules, and two MnH4(OF2)2 clusters. In each MnH4(OF2)2 cluster, Mn(2) is bonded in an octahedral geometry to one O(3), one O(5), one F(1), one F(2), one F(3), and one F(4) atom. The Mn(2)-O(3) bond length is 2.21 Å. The Mn(2)-O(5) bond length is 2.33 Å. The Mn(2)-F(1) bond length is 1.90 Å. The Mn(2)-F(2) bond length is 1.89 Å. The Mn(2)-F(3) bond length is 1.91 Å. The Mn(2)-F(4) bond length is 1.88 Å. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.99 Å. In the second H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.99 Å. In the third H site, H(9) is bonded in a single-bond geometry to one O(5) atom. The H(9)-O(5) bond length is 0.99 Å. In the fourth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. The H(10)-O(5) bond length is 1.00 Å. There are two inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Mn(2), one H(10), and one H(9) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(2), one H(5), and one H(6) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Mn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Mn(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Mn(2) atom.