CH3BrClF is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CH3BrClF clusters. C(1) is bonded in a tetrahedral geometry to one H(1), two equivalent H(2), and one Cl(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. Br(1) is bonded in a distorted linear geometry to one Cl(1) and one F(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one C(1) and one Br(1) atom. F(1) is bonded in a single-bond geometry to one Br(1) atom.
CH3BrClF is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CH3BrClF clusters. C(1) is bonded in a tetrahedral geometry to one H(1), two equivalent H(2), and one Cl(1) atom. The C(1)-H(1) bond length is 1.09 Å. Both C(1)-H(2) bond lengths are 1.09 Å. The C(1)-Cl(1) bond length is 1.80 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. Br(1) is bonded in a distorted linear geometry to one Cl(1) and one F(1) atom. The Br(1)-Cl(1) bond length is 2.54 Å. The Br(1)-F(1) bond length is 1.90 Å. Cl(1) is bonded in a distorted single-bond geometry to one C(1) and one Br(1) atom. F(1) is bonded in a single-bond geometry to one Br(1) atom.