AuBr4Co(NBr)2(N2)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two AuBr4 clusters, and two Co(NBr)2 clusters. In each AuBr4 cluster, Au(1) is bonded in a square co-planar geometry to two equivalent Br(1) and two equivalent Br(2) atoms. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Au(1) atom. In each Co(NBr)2 cluster, Co(1) is bonded in a linear geometry to two equivalent N(2) atoms. N(2) is bonded in a distorted linear geometry to one Co(1) and one Br(3) atom. Br(3) is bonded in a single-bond geometry to one N(2) atom.
AuBr4Co(NBr)2(N2)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two AuBr4 clusters, and two Co(NBr)2 clusters. In each AuBr4 cluster, Au(1) is bonded in a square co-planar geometry to two equivalent Br(1) and two equivalent Br(2) atoms. Both Au(1)-Br(1) bond lengths are 2.52 Å. Both Au(1)-Br(2) bond lengths are 2.48 Å. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Au(1) atom. In each Co(NBr)2 cluster, Co(1) is bonded in a linear geometry to two equivalent N(2) atoms. Both Co(1)-N(2) bond lengths are 1.66 Å. N(2) is bonded in a distorted linear geometry to one Co(1) and one Br(3) atom. The N(2)-Br(3) bond length is 1.77 Å. Br(3) is bonded in a single-bond geometry to one N(2) atom.