PbNiO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Pb(1) is bonded to twelve equivalent O(1) atoms to form PbO12 cuboctahedra that share corners with twelve equivalent Pb(1)O12 cuboctahedra, faces with six equivalent Pb(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. O(1) is bonded in a linear geometry to two equivalent Ni(1) and four equivalent Pb(1) atoms.
PbNiO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ni(1) is bonded to six equivalent O(1) atoms to form NiO6 octahedra that share corners with six equivalent Ni(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ni(1)-O(1) bond lengths are 1.91 Å. Pb(1) is bonded to twelve equivalent O(1) atoms to form PbO12 cuboctahedra that share corners with twelve equivalent Pb(1)O12 cuboctahedra, faces with six equivalent Pb(1)O12 cuboctahedra, and faces with eight equivalent Ni(1)O6 octahedra. All Pb(1)-O(1) bond lengths are 2.69 Å. O(1) is bonded in a linear geometry to two equivalent Ni(1) and four equivalent Pb(1) atoms.