CdIn2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Cd(1) is bonded to four equivalent S(1) atoms to form CdS4 tetrahedra that share corners with twelve equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles are 58°. In(1) is bonded to six equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Cd(1)S4 tetrahedra and edges with six equivalent In(1)S6 octahedra. S(1) is bonded to one Cd(1) and three equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing SCdIn3 trigonal pyramids.
CdIn2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Cd(1) is bonded to four equivalent S(1) atoms to form CdS4 tetrahedra that share corners with twelve equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles are 58°. All Cd(1)-S(1) bond lengths are 2.55 Å. In(1) is bonded to six equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Cd(1)S4 tetrahedra and edges with six equivalent In(1)S6 octahedra. All In(1)-S(1) bond lengths are 2.63 Å. S(1) is bonded to one Cd(1) and three equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing SCdIn3 trigonal pyramids.