CeY4Rh5 is Heusler-like structured and crystallizes in the tetragonal P4/mmm space group. Ce(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. In the second Y site, Y(2) is bonded in a body-centered cubic geometry to four equivalent Rh(2) and four equivalent Rh(3) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a body-centered cubic geometry to four equivalent Ce(1) and four equivalent Y(1) atoms. In the second Rh site, Rh(2) is bonded in a body-centered cubic geometry to four equivalent Y(1) and four equivalent Y(2) atoms. In the third Rh site, Rh(3) is bonded in a body-centered cubic geometry to eight equivalent Y(2) atoms.
CeY4Rh5 is Heusler-like structured and crystallizes in the tetragonal P4/mmm space group. Ce(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms. All Ce(1)-Rh(1) bond lengths are 2.96 Å. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Rh(2) atoms. All Y(1)-Rh(1) bond lengths are 3.01 Å. All Y(1)-Rh(2) bond lengths are 2.95 Å. In the second Y site, Y(2) is bonded in a body-centered cubic geometry to four equivalent Rh(2) and four equivalent Rh(3) atoms. All Y(2)-Rh(2) bond lengths are 2.97 Å. All Y(2)-Rh(3) bond lengths are 2.96 Å. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a body-centered cubic geometry to four equivalent Ce(1) and four equivalent Y(1) atoms. In the second Rh site, Rh(2) is bonded in a body-centered cubic geometry to four equivalent Y(1) and four equivalent Y(2) atoms. In the third Rh site, Rh(3) is bonded in a body-centered cubic geometry to eight equivalent Y(2) atoms.