NS is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of twelve NS clusters. In two of the NS clusters, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(6) atom. In the second N site, N(6) is bonded in a single-bond geometry to one S(7) atom. In the third N site, N(7) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) atom. In the second S site, S(6) is bonded in a water-like geometry to one N(1) and one N(7) atom. In the third S site, S(7) is bonded in a bent 120 degrees geometry to one N(6) and one N(7) atom. In two of the NS clusters, there are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one S(3) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(3) atom. In the second S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In eight of the NS clusters, N(5) is bonded in a single-bond geometry to one S(4) atom. S(4) is bonded in a single-bond geometry to one N(5) atom.
NS is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of twelve NS clusters. In two of the NS clusters, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(6) atom. The N(1)-S(1) bond length is 1.61 Å. The N(1)-S(6) bond length is 1.60 Å. In the second N site, N(6) is bonded in a single-bond geometry to one S(7) atom. The N(6)-S(7) bond length is 1.47 Å. In the third N site, N(7) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. The N(7)-S(6) bond length is 1.57 Å. The N(7)-S(7) bond length is 1.73 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) atom. In the second S site, S(6) is bonded in a water-like geometry to one N(1) and one N(7) atom. In the third S site, S(7) is bonded in a bent 120 degrees geometry to one N(6) and one N(7) atom. In two of the NS clusters, there are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one S(3) atom. The N(2)-S(3) bond length is 1.47 Å. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(3)-S(2) bond length is 1.57 Å. The N(3)-S(3) bond length is 1.80 Å. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(3) atom. In the second S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In eight of the NS clusters, N(5) is bonded in a single-bond geometry to one S(4) atom. The N(5)-S(4) bond length is 1.48 Å. S(4) is bonded in a single-bond geometry to one N(5) atom.