Te7(OF5)6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Te7(OF5)6 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 43°. In the second Te site, Te(2) is bonded to six equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 43°. O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom.
Te7(OF5)6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Te7(OF5)6 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 43°. The Te(1)-O(1) bond length is 1.94 Å. The Te(1)-F(1) bond length is 1.87 Å. The Te(1)-F(2) bond length is 1.87 Å. The Te(1)-F(3) bond length is 1.86 Å. The Te(1)-F(4) bond length is 1.87 Å. The Te(1)-F(5) bond length is 1.87 Å. In the second Te site, Te(2) is bonded to six equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Te(2)-O(1) bond lengths are 1.96 Å. O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom.