MgCo2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a tetrahedral geometry to one O(11), one O(5), one O(7), and one O(8) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(4), one O(7), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(3), one O(5), and one O(9) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(9) atom. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(9) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(6), and one O(9) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one O(10), one O(12), one O(2), and one O(4) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Co(1), and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Te(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(2), one Co(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted tetrahedral geometry to one Mo(1), one Co(1), one Co(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Mo(2), one Co(1), one Co(2), and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Co(2), and one Te(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Mo(1), one Co(2), and one Te(2) atom.
MgCo2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a tetrahedral geometry to one O(11), one O(5), one O(7), and one O(8) atom. The Mg(1)-O(11) bond length is 1.97 Å. The Mg(1)-O(5) bond length is 1.96 Å. The Mg(1)-O(7) bond length is 1.97 Å. The Mg(1)-O(8) bond length is 1.99 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(4), one O(7), and one O(8) atom. The Mo(1)-O(10) bond length is 1.91 Å. The Mo(1)-O(12) bond length is 1.93 Å. The Mo(1)-O(4) bond length is 2.50 Å. The Mo(1)-O(7) bond length is 1.85 Å. The Mo(1)-O(8) bond length is 1.84 Å. In the second Mo site, Mo(2) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(3), one O(5), and one O(9) atom. The Mo(2)-O(1) bond length is 1.92 Å. The Mo(2)-O(11) bond length is 1.84 Å. The Mo(2)-O(3) bond length is 1.93 Å. The Mo(2)-O(5) bond length is 1.86 Å. The Mo(2)-O(9) bond length is 2.51 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(9) atom. The Co(1)-O(1) bond length is 2.23 Å. The Co(1)-O(2) bond length is 2.07 Å. The Co(1)-O(3) bond length is 2.17 Å. The Co(1)-O(4) bond length is 2.17 Å. The Co(1)-O(6) bond length is 2.15 Å. The Co(1)-O(9) bond length is 2.24 Å. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(9) atom. The Co(2)-O(10) bond length is 2.24 Å. The Co(2)-O(12) bond length is 2.34 Å. The Co(2)-O(2) bond length is 2.11 Å. The Co(2)-O(4) bond length is 2.18 Å. The Co(2)-O(6) bond length is 2.09 Å. The Co(2)-O(9) bond length is 2.12 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(6), and one O(9) atom. The Te(1)-O(1) bond length is 2.07 Å. The Te(1)-O(3) bond length is 2.11 Å. The Te(1)-O(6) bond length is 1.92 Å. The Te(1)-O(9) bond length is 1.96 Å. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one O(10), one O(12), one O(2), and one O(4) atom. The Te(2)-O(10) bond length is 2.09 Å. The Te(2)-O(12) bond length is 2.07 Å. The Te(2)-O(2) bond length is 1.91 Å. The Te(2)-O(4) bond length is 1.95 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Co(1), and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Te(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(2), one Co(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted tetrahedral geometry to one Mo(1), one Co(1), one Co(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Mo(2), one Co(1), one Co(2), and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Co(2), and one Te(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Mo(1), one Co(2), and one Te(2) atom.