C2SF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two trifluoro-[(e)-1,1,1,4,4,4-hexafluoro-3-(trifluoro-lambda4-sulfanyl)but-2-en-2-yl]-lambda4-sulfane molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one C(2), one F(1), one F(3), and one F(4) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one S(1) atom. S(1) is bonded in a distorted T-shaped geometry to one C(2), one F(2), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one C(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one S(1) atom.
C2SF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two trifluoro-[(e)-1,1,1,4,4,4-hexafluoro-3-(trifluoro-lambda4-sulfanyl)but-2-en-2-yl]-lambda4-sulfane molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one C(2), one F(1), one F(3), and one F(4) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-F(1) bond length is 1.37 Å. The C(1)-F(3) bond length is 1.35 Å. The C(1)-F(4) bond length is 1.35 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one S(1) atom. The C(2)-C(2) bond length is 1.34 Å. The C(2)-S(1) bond length is 1.85 Å. S(1) is bonded in a distorted T-shaped geometry to one C(2), one F(2), one F(5), and one F(6) atom. The S(1)-F(2) bond length is 1.60 Å. The S(1)-F(5) bond length is 1.72 Å. The S(1)-F(6) bond length is 1.73 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one C(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one S(1) atom.