TiS2 crystallizes in the tetragonal I-42d space group. Ti(1) is bonded to four equivalent S(1) atoms to form corner-sharing TiS4 tetrahedra. S(1) is bonded in a bent 120 degrees geometry to two equivalent Ti(1) atoms.
TiS2 crystallizes in the tetragonal I-42d space group. Ti(1) is bonded to four equivalent S(1) atoms to form corner-sharing TiS4 tetrahedra. All Ti(1)-S(1) bond lengths are 2.28 Å. S(1) is bonded in a bent 120 degrees geometry to two equivalent Ti(1) atoms.