PN3H6O is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four phosphoramide molecules. P(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one O(1) atom. There are three inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(3), and one H(4) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one P(1), one H(5), and one H(6) atom. In the third N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(1), and one H(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. O(1) is bonded in a single-bond geometry to one P(1) atom.
PN3H6O is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four phosphoramide molecules. P(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one O(1) atom. The P(1)-N(1) bond length is 1.66 Å. The P(1)-N(2) bond length is 1.67 Å. The P(1)-N(3) bond length is 1.64 Å. The P(1)-O(1) bond length is 1.51 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.03 Å. The N(2)-H(4) bond length is 1.03 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one P(1), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 1.02 Å. The N(3)-H(6) bond length is 1.02 Å. In the third N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.02 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. O(1) is bonded in a single-bond geometry to one P(1) atom.