V3Sb crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Sb(1) atoms. Sb(1) is bonded to twelve equivalent V(1) atoms to form a mixture of face and edge-sharing SbV12 cuboctahedra.
V3Sb crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Sb(1) atoms. Both V(1)-V(1) bond lengths are 2.45 Å. All V(1)-Sb(1) bond lengths are 2.74 Å. Sb(1) is bonded to twelve equivalent V(1) atoms to form a mixture of face and edge-sharing SbV12 cuboctahedra.