Rb2Pd(IBr2)2 crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded in a distorted body-centered cubic geometry to eight equivalent Br(1) atoms. Pd(1) is bonded in an octahedral geometry to two equivalent I(1) and four equivalent Br(1) atoms. I(1) is bonded in a distorted linear geometry to one Pd(1) and one I(1) atom. Br(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Pd(1) atom.
Rb2Pd(IBr2)2 crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded in a distorted body-centered cubic geometry to eight equivalent Br(1) atoms. All Rb(1)-Br(1) bond lengths are 3.80 Å. Pd(1) is bonded in an octahedral geometry to two equivalent I(1) and four equivalent Br(1) atoms. Both Pd(1)-I(1) bond lengths are 3.06 Å. All Pd(1)-Br(1) bond lengths are 2.48 Å. I(1) is bonded in a distorted linear geometry to one Pd(1) and one I(1) atom. The I(1)-I(1) bond length is 2.89 Å. Br(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Pd(1) atom.