CsNO3 crystallizes in the orthorhombic Pmmn space group. Cs(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form a mixture of distorted edge, face, and corner-sharing CsO12 cuboctahedra. N(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to four equivalent Cs(1) and one N(1) atom.
CsNO3 crystallizes in the orthorhombic Pmmn space group. Cs(1) is bonded to four equivalent O(2) and eight equivalent O(1) atoms to form a mixture of distorted edge, face, and corner-sharing CsO12 cuboctahedra. There are two shorter (3.17 Å) and two longer (3.28 Å) Cs(1)-O(2) bond lengths. There are a spread of Cs(1)-O(1) bond distances ranging from 3.14-3.31 Å. N(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. The N(1)-O(2) bond length is 1.26 Å. Both N(1)-O(1) bond lengths are 1.26 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to four equivalent Cs(1) and one N(1) atom.