AlNF6N2 crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonia atoms inside a AlNF6 framework. In the AlNF6 framework, Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent N(1)F6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to six equivalent F(1) atoms to form NF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Al(1) and one N(1) atom.
AlNF6N2 crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonia atoms inside a AlNF6 framework. In the AlNF6 framework, Al(1) is bonded to six equivalent F(1) atoms to form AlF6 octahedra that share corners with six equivalent N(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Al(1)-F(1) bond lengths are 1.86 Å. N(1) is bonded to six equivalent F(1) atoms to form NF6 octahedra that share corners with six equivalent Al(1)F6 octahedra. The corner-sharing octahedra are not tilted. All N(1)-F(1) bond lengths are 1.92 Å. F(1) is bonded in a linear geometry to one Al(1) and one N(1) atom.