CdC2H8S2(N2Cl)2 is Indium-like structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of two CdC2H8S2(N2Cl)2 clusters. Cd(1) is bonded in a tetrahedral geometry to two equivalent S(1), one Cl(1), and one Cl(2) atom. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1) and two equivalent H(1,2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. There are three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cd(1) atom.
CdC2H8S2(N2Cl)2 is Indium-like structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of two CdC2H8S2(N2Cl)2 clusters. Cd(1) is bonded in a tetrahedral geometry to two equivalent S(1), one Cl(1), and one Cl(2) atom. Both Cd(1)-S(1) bond lengths are 2.54 Å. The Cd(1)-Cl(1) bond length is 2.59 Å. The Cd(1)-Cl(2) bond length is 2.55 Å. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-S(1) bond length is 1.72 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1) and two equivalent H(1,2) atoms. There is one shorter (1.01 Å) and one longer (1.02 Å) N(1)-H(1,2) bond length. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 1.02 Å. The N(2)-H(4) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cd(1) atom.