AgCNH2S2 crystallizes in the tetragonal I-42d space group. Ag(1) is bonded to four equivalent S(1) atoms to form corner-sharing AgS4 tetrahedra. C(1) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent S(1) atoms. N(1) is bonded in a trigonal planar geometry to one C(1) and two equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom.
AgCNH2S2 crystallizes in the tetragonal I-42d space group. Ag(1) is bonded to four equivalent S(1) atoms to form corner-sharing AgS4 tetrahedra. There are two shorter (2.62 Å) and two longer (2.78 Å) Ag(1)-S(1) bond lengths. C(1) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent S(1) atoms. The C(1)-N(1) bond length is 1.33 Å. Both C(1)-S(1) bond lengths are 1.73 Å. N(1) is bonded in a trigonal planar geometry to one C(1) and two equivalent H(1) atoms. Both N(1)-H(1) bond lengths are 1.02 Å. H(1) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom.