NaBrO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded to six equivalent O(1) atoms to form corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles are 62°. O(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.
NaBrO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded to six equivalent O(1) atoms to form corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles are 62°. There are three shorter (2.38 Å) and three longer (2.47 Å) Na(1)-O(1) bond lengths. O(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Br(1) atom. The O(1)-Br(1) bond length is 1.67 Å. Br(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.