TlTl2B3S10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two Tl2B3S10 clusters. In each Tl2B3S10 cluster, there are two inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a 2-coordinate geometry to one S(5) and one S(7) atom. In the second Tl site, Tl(3) is bonded in a single-bond geometry to one S(3) atom. There are three inequivalent B sites. In the first B site, B(1) is bonded to one S(2), one S(6), one S(7), and one S(8) atom to form corner-sharing BS4 tetrahedra. In the second B site, B(2) is bonded to one S(1), one S(2), one S(4), and one S(5) atom to form corner-sharing BS4 tetrahedra. In the third B site, B(3) is bonded to one S(1), one S(10), one S(3), and one S(9) atom to form corner-sharing BS4 tetrahedra. There are ten inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one B(1) and one B(2) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one Tl(3) and one B(3) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one B(2) atom. In the fifth S site, S(5) is bonded in a distorted single-bond geometry to one Tl(2) and one B(2) atom. In the sixth S site, S(6) is bonded in a distorted single-bond geometry to one B(1) atom. In the seventh S site, S(7) is bonded in a distorted single-bond geometry to one Tl(2) and one B(1) atom. In the eighth S site, S(8) is bonded in a distorted single-bond geometry to one B(1) atom. In the ninth S site, S(9) is bonded in a distorted single-bond geometry to one B(3) atom. In the tenth S site, S(10) is bonded in a distorted single-bond geometry to one B(3) atom.
TlTl2B3S10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two Tl2B3S10 clusters. In each Tl2B3S10 cluster, there are two inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a 2-coordinate geometry to one S(5) and one S(7) atom. The Tl(2)-S(5) bond length is 3.18 Å. The Tl(2)-S(7) bond length is 3.20 Å. In the second Tl site, Tl(3) is bonded in a single-bond geometry to one S(3) atom. The Tl(3)-S(3) bond length is 3.16 Å. There are three inequivalent B sites. In the first B site, B(1) is bonded to one S(2), one S(6), one S(7), and one S(8) atom to form corner-sharing BS4 tetrahedra. The B(1)-S(2) bond length is 1.92 Å. The B(1)-S(6) bond length is 1.92 Å. The B(1)-S(7) bond length is 1.91 Å. The B(1)-S(8) bond length is 1.91 Å. In the second B site, B(2) is bonded to one S(1), one S(2), one S(4), and one S(5) atom to form corner-sharing BS4 tetrahedra. The B(2)-S(1) bond length is 1.94 Å. The B(2)-S(2) bond length is 1.91 Å. The B(2)-S(4) bond length is 1.92 Å. The B(2)-S(5) bond length is 1.94 Å. In the third B site, B(3) is bonded to one S(1), one S(10), one S(3), and one S(9) atom to form corner-sharing BS4 tetrahedra. The B(3)-S(1) bond length is 1.91 Å. The B(3)-S(10) bond length is 1.92 Å. The B(3)-S(3) bond length is 1.92 Å. The B(3)-S(9) bond length is 1.91 Å. There are ten inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one B(1) and one B(2) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one Tl(3) and one B(3) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one B(2) atom. In the fifth S site, S(5) is bonded in a distorted single-bond geometry to one Tl(2) and one B(2) atom. In the sixth S site, S(6) is bonded in a distorted single-bond geometry to one B(1) atom. In the seventh S site, S(7) is bonded in a distorted single-bond geometry to one Tl(2) and one B(1) atom. In the eighth S site, S(8) is bonded in a distorted single-bond geometry to one B(1) atom. In the ninth S site, S(9) is bonded in a distorted single-bond geometry to one B(3) atom. In the tenth S site, S(10) is bonded in a distorted single-bond geometry to one B(3) atom.