AgAlO2 crystallizes in the hexagonal P6_3/mmc space group. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Al(1) is bonded to six equivalent O(1) atoms to form edge-sharing AlO6 octahedra. O(1) is bonded to one Ag(1) and three equivalent Al(1) atoms to form a mixture of distorted corner and edge-sharing OAl3Ag tetrahedra.
AgAlO2 crystallizes in the hexagonal P6_3/mmc space group. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.11 Å. Al(1) is bonded to six equivalent O(1) atoms to form edge-sharing AlO6 octahedra. All Al(1)-O(1) bond lengths are 1.92 Å. O(1) is bonded to one Ag(1) and three equivalent Al(1) atoms to form a mixture of distorted corner and edge-sharing OAl3Ag tetrahedra.