AgSnF6 is Upper Bainite-derived structured and crystallizes in the triclinic P-1 space group. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form AgF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. Sn(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form SnF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Sn(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one Sn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ag(1) and one Sn(1) atom.
AgSnF6 is Upper Bainite-derived structured and crystallizes in the triclinic P-1 space group. Ag(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form AgF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. Both Ag(1)-F(1) bond lengths are 2.43 Å. Both Ag(1)-F(2) bond lengths are 2.12 Å. Both Ag(1)-F(3) bond lengths are 2.11 Å. Sn(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form SnF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 43-48°. Both Sn(1)-F(1) bond lengths are 1.94 Å. Both Sn(1)-F(2) bond lengths are 2.01 Å. Both Sn(1)-F(3) bond lengths are 2.01 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Sn(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one Sn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ag(1) and one Sn(1) atom.