VNiGe crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 11-coordinate geometry to six equivalent Ni(1) and five equivalent Ge(1) atoms. Ni(1) is bonded in a 12-coordinate geometry to six equivalent V(1), two equivalent Ni(1), and four equivalent Ge(1) atoms. Ge(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Ni(1) atoms.
VNiGe crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 11-coordinate geometry to six equivalent Ni(1) and five equivalent Ge(1) atoms. There are a spread of V(1)-Ni(1) bond distances ranging from 2.74-2.84 Å. There are three shorter (2.55 Å) and two longer (2.64 Å) V(1)-Ge(1) bond lengths. Ni(1) is bonded in a 12-coordinate geometry to six equivalent V(1), two equivalent Ni(1), and four equivalent Ge(1) atoms. Both Ni(1)-Ni(1) bond lengths are 2.67 Å. There are three shorter (2.33 Å) and one longer (2.37 Å) Ni(1)-Ge(1) bond length. Ge(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Ni(1) atoms.