AgInTeSe is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Ag(1) is bonded to two equivalent Te(1) and two equivalent Se(1) atoms to form AgTe2Se2 tetrahedra that share corners with four equivalent Ag(1)Te2Se2 tetrahedra and corners with eight equivalent In(1)Te2Se2 tetrahedra. In(1) is bonded to two equivalent Te(1) and two equivalent Se(1) atoms to form InTe2Se2 tetrahedra that share corners with four equivalent In(1)Te2Se2 tetrahedra and corners with eight equivalent Ag(1)Te2Se2 tetrahedra. Te(1) is bonded to two equivalent Ag(1) and two equivalent In(1) atoms to form TeIn2Ag2 tetrahedra that share corners with four equivalent Te(1)In2Ag2 tetrahedra and corners with eight equivalent Se(1)In2Ag2 tetrahedra. Se(1) is bonded to two equivalent Ag(1) and two equivalent In(1) atoms to form SeIn2Ag2 tetrahedra that share corners with four equivalent Se(1)In2Ag2 tetrahedra and corners with eight equivalent Te(1)In2Ag2 tetrahedra.
AgInTeSe is Stannite-like structured and crystallizes in the orthorhombic I2_12_12_1 space group. Ag(1) is bonded to two equivalent Te(1) and two equivalent Se(1) atoms to form AgTe2Se2 tetrahedra that share corners with four equivalent Ag(1)Te2Se2 tetrahedra and corners with eight equivalent In(1)Te2Se2 tetrahedra. Both Ag(1)-Te(1) bond lengths are 2.79 Å. Both Ag(1)-Se(1) bond lengths are 2.74 Å. In(1) is bonded to two equivalent Te(1) and two equivalent Se(1) atoms to form InTe2Se2 tetrahedra that share corners with four equivalent In(1)Te2Se2 tetrahedra and corners with eight equivalent Ag(1)Te2Se2 tetrahedra. Both In(1)-Te(1) bond lengths are 2.84 Å. Both In(1)-Se(1) bond lengths are 2.67 Å. Te(1) is bonded to two equivalent Ag(1) and two equivalent In(1) atoms to form TeIn2Ag2 tetrahedra that share corners with four equivalent Te(1)In2Ag2 tetrahedra and corners with eight equivalent Se(1)In2Ag2 tetrahedra. Se(1) is bonded to two equivalent Ag(1) and two equivalent In(1) atoms to form SeIn2Ag2 tetrahedra that share corners with four equivalent Se(1)In2Ag2 tetrahedra and corners with eight equivalent Te(1)In2Ag2 tetrahedra.