(ReSeF)12(SeO)4(O2)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, eight oxyselenide molecules, four trioxidane molecules, and four ReSeF clusters. In each ReSeF cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(3) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(2) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(1) atom. There are three inequivalent Se sites. In the first Se site, Se(3) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second Se site, Se(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the third Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom.
(ReSeF)12(SeO)4(O2)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hydrogen peroxide molecules, eight oxyselenide molecules, four trioxidane molecules, and four ReSeF clusters. In each ReSeF cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(3) atom. The Re(1)-Se(2) bond length is 2.55 Å. The Re(1)-Se(3) bond length is 2.51 Å. The Re(1)-Se(4) bond length is 2.46 Å. The Re(1)-F(3) bond length is 1.94 Å. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(2) atom. The Re(2)-Se(2) bond length is 2.67 Å. The Re(2)-Se(3) bond length is 2.58 Å. The Re(2)-Se(4) bond length is 2.59 Å. The Re(2)-F(2) bond length is 1.94 Å. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one Se(2), one Se(3), one Se(4), and one F(1) atom. The Re(3)-Se(2) bond length is 2.48 Å. The Re(3)-Se(3) bond length is 2.54 Å. The Re(3)-Se(4) bond length is 2.60 Å. The Re(3)-F(1) bond length is 1.94 Å. There are three inequivalent Se sites. In the first Se site, Se(3) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second Se site, Se(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the third Se site, Se(2) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom.