NaAuF4 crystallizes in the tetragonal I4/mcm space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. Au(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Au(1) atom.
NaAuF4 crystallizes in the tetragonal I4/mcm space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent F(1) atoms. All Na(1)-F(1) bond lengths are 2.40 Å. Au(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. All Au(1)-F(1) bond lengths are 1.95 Å. F(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Au(1) atom.