(Na)2TmAgCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a TmAgCl6 framework. In the TmAgCl6 framework, Tm(1) is bonded to six equivalent Cl(1) atoms to form TmCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded to six equivalent Cl(1) atoms to form AgCl6 octahedra that share corners with six equivalent Tm(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Tm(1) and one Ag(1) atom.
(Na)2TmAgCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a TmAgCl6 framework. In the TmAgCl6 framework, Tm(1) is bonded to six equivalent Cl(1) atoms to form TmCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Tm(1)-Cl(1) bond lengths are 2.58 Å. Ag(1) is bonded to six equivalent Cl(1) atoms to form AgCl6 octahedra that share corners with six equivalent Tm(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Ag(1)-Cl(1) bond lengths are 2.70 Å. Cl(1) is bonded in a linear geometry to one Tm(1) and one Ag(1) atom.