LaMn2CdO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. La(1) is bonded in a 3-coordinate geometry to one O(4), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. Cd(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent La(1), one Mn(1), one Mn(2), and one Cd(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent La(1), one Mn(1), one Mn(2), and one Cd(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent La(1), one Mn(1), one Mn(2), and one Cd(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), and one Mn(2) atom.
LaMn2CdO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. La(1) is bonded in a 3-coordinate geometry to one O(4), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. The La(1)-O(4) bond length is 2.39 Å. The La(1)-O(5) bond length is 2.38 Å. The La(1)-O(6) bond length is 2.34 Å. There is one shorter (2.69 Å) and one longer (2.77 Å) La(1)-O(1) bond length. There is one shorter (2.78 Å) and one longer (2.85 Å) La(1)-O(2) bond length. There is one shorter (2.74 Å) and one longer (2.85 Å) La(1)-O(3) bond length. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. The Mn(1)-O(1) bond length is 1.93 Å. The Mn(1)-O(2) bond length is 1.95 Å. The Mn(1)-O(3) bond length is 1.96 Å. The Mn(1)-O(4) bond length is 1.93 Å. The Mn(1)-O(5) bond length is 1.92 Å. The Mn(1)-O(6) bond length is 1.91 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 21-29°. The Mn(2)-O(1) bond length is 2.25 Å. The Mn(2)-O(2) bond length is 1.97 Å. The Mn(2)-O(3) bond length is 1.97 Å. The Mn(2)-O(4) bond length is 1.95 Å. The Mn(2)-O(5) bond length is 1.95 Å. The Mn(2)-O(6) bond length is 2.19 Å. Cd(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. The Cd(1)-O(1) bond length is 2.24 Å. The Cd(1)-O(2) bond length is 2.29 Å. The Cd(1)-O(3) bond length is 2.30 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent La(1), one Mn(1), one Mn(2), and one Cd(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent La(1), one Mn(1), one Mn(2), and one Cd(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent La(1), one Mn(1), one Mn(2), and one Cd(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Mn(1), and one Mn(2) atom.