Sm2Cl2F crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Sm2Cl2F cluster. Sm(1) is bonded in a linear geometry to one Cl(1) and one F(1) atom. Cl(1) is bonded in a single-bond geometry to one Sm(1) atom. F(1) is bonded in a linear geometry to two equivalent Sm(1) atoms.
Sm2Cl2F crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Sm2Cl2F cluster. Sm(1) is bonded in a linear geometry to one Cl(1) and one F(1) atom. The Sm(1)-Cl(1) bond length is 2.44 Å. The Sm(1)-F(1) bond length is 2.29 Å. Cl(1) is bonded in a single-bond geometry to one Sm(1) atom. F(1) is bonded in a linear geometry to two equivalent Sm(1) atoms.