RbMg14BO15 crystallizes in the orthorhombic Pmm2 space group. Rb(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(10), and two equivalent O(6) atoms. There are ten inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to one O(1), one O(2), two equivalent O(11), and two equivalent O(8) atoms to form MgO6 octahedra that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Mg(2)O5 square pyramids, edges with two equivalent Mg(5)O6 octahedra, edges with four equivalent Mg(4)O5 square pyramids, edges with two equivalent Mg(10)O5 trigonal bipyramids, edges with two equivalent Mg(7)O5 trigonal bipyramids, and edges with two equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the second Mg site, Mg(2) is bonded to one O(3), two equivalent O(11), and two equivalent O(9) atoms to form MgO5 square pyramids that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Mg(2)O5 square pyramids, corners with two equivalent Mg(8)O5 trigonal bipyramids, corners with two equivalent Mg(9)O5 trigonal bipyramids, edges with four equivalent Mg(4)O5 square pyramids, and edges with two equivalent Mg(10)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 4°. In the third Mg site, Mg(3) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(10) atoms to form distorted MgO6 octahedra that share corners with four equivalent Mg(3)O6 octahedra,  a cornercorner with one Mg(4)O5 square pyramid,  a cornercorner with one Mg(7)O5 trigonal bipyramid, corners with two equivalent Mg(10)O5 trigonal bipyramids,  an edgeedge with one Mg(5)O6 octahedra,  an edgeedge with one Mg(8)O5 trigonal bipyramid, and edges with two equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 4-32°. In the fourth Mg site, Mg(4) is bonded to one O(4), one O(8), one O(9), and two equivalent O(11) atoms to form MgO5 square pyramids that share  a cornercorner with one Mg(3)O6 octahedra, corners with four equivalent Mg(4)O5 square pyramids,  a cornercorner with one Mg(7)O5 trigonal bipyramid, corners with two equivalent Mg(10)O5 trigonal bipyramids,  an edgeedge with one Mg(5)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(2)O5 square pyramids, and edges with two equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 1°. In the fifth Mg site, Mg(5) is bonded to one O(6), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form MgO6 octahedra that share corners with two equivalent Mg(5)O6 octahedra,  a cornercorner with one Mg(7)O5 trigonal bipyramid, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, edges with two equivalent Mg(4)O5 square pyramids, and edges with four equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 10°. In the sixth Mg site, Mg(6) is bonded in a distorted square co-planar geometry to one O(7), one O(9), and two equivalent O(4) atoms. In the seventh Mg site, Mg(7) is bonded to one O(8), two equivalent O(2), and two equivalent O(5) atoms to form MgO5 trigonal bipyramids that share  a cornercorner with one Mg(5)O6 octahedra, corners with two equivalent Mg(3)O6 octahedra, corners with two equivalent Mg(4)O5 square pyramids, corners with two equivalent Mg(7)O5 trigonal bipyramids, corners with two equivalent Mg(8)O5 trigonal bipyramids, edges with two equivalent Mg(1)O6 octahedra, and edges with four equivalent Mg(10)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 0-70°. In the eighth Mg site, Mg(8) is bonded to one O(7), two equivalent O(3), and two equivalent O(5) atoms to form MgO5 trigonal bipyramids that share corners with two equivalent Mg(2)O5 square pyramids, corners with two equivalent Mg(7)O5 trigonal bipyramids, corners with two equivalent Mg(8)O5 trigonal bipyramids, edges with two equivalent Mg(3)O6 octahedra, and edges with four equivalent Mg(10)O5 trigonal bipyramids. In the ninth Mg site, Mg(9) is bonded to one O(1), one O(10), one O(11), and two equivalent O(4) atoms to form distorted MgO5 trigonal bipyramids that share  a cornercorner with one Mg(2)O5 square pyramid,  a cornercorner with one Mg(10)O5 trigonal bipyramid, corners with three equivalent Mg(9)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, edges with two equivalent Mg(5)O6 octahedra, and edges with two equivalent Mg(4)O5 square pyramids. In the tenth Mg site, Mg(10) is bonded to one O(11), one O(2), one O(3), and two equivalent O(5) atoms to form MgO5 trigonal bipyramids that share corners with two equivalent Mg(3)O6 octahedra, corners with two equivalent Mg(4)O5 square pyramids,  a cornercorner with one Mg(9)O5 trigonal bipyramid, corners with four equivalent Mg(10)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one Mg(2)O5 square pyramid, edges with two equivalent Mg(7)O5 trigonal bipyramids, and edges with two equivalent Mg(8)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 77°. B(1) is bonded in a bent 150 degrees geometry to two equivalent O(10) atoms. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), two equivalent Mg(5), and two equivalent Mg(9) atoms to form distorted OMg5 square pyramids that share  a cornercorner with one O(2)RbMg5 octahedra, corners with two equivalent O(1)Mg5 square pyramids, corners with two equivalent O(6)Rb2Mg3 trigonal bipyramids, edges with two equivalent O(11)Mg6 octahedra, edges with two equivalent O(8)Mg6 octahedra, and edges with four equivalent O(4)Mg6 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to one Rb(1), one Mg(1), two equivalent Mg(10), and two equivalent Mg(7) atoms to form ORbMg5 octahedra that share corners with two equivalent O(2)RbMg5 octahedra,  a cornercorner with one O(1)Mg5 square pyramid, corners with two equivalent O(3)Mg5 trigonal bipyramids, corners with two equivalent O(6)Rb2Mg3 trigonal bipyramids, edges with two equivalent O(11)Mg6 octahedra, edges with two equivalent O(8)Mg6 octahedra, and edges with four equivalent O(5)Mg5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 6°. In the third O site, O(3) is bonded to one Mg(2), two equivalent Mg(10), and two equivalent Mg(8) atoms to form OMg5 trigonal bipyramids that share corners with two equivalent O(2)RbMg5 octahedra, corners with two equivalent O(9)Mg5 square pyramids, corners with two equivalent O(3)Mg5 trigonal bipyramids, edges with two equivalent O(11)Mg6 octahedra, and edges with four equivalent O(5)Mg5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 4°. In the fourth O site, O(4) is bonded to one Mg(3), one Mg(4), one Mg(5), one Mg(6), and two equivalent Mg(9) atoms to form OMg6 octahedra that share corners with four equivalent O(4)Mg6 octahedra,  a cornercorner with one O(5)Mg5 trigonal bipyramid,  an edgeedge with one O(8)Mg6 octahedra, edges with two equivalent O(11)Mg6 octahedra,  an edgeedge with one O(9)Mg5 square pyramid, edges with two equivalent O(1)Mg5 square pyramids, and  an edgeedge with one O(6)Rb2Mg3 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(5) is bonded to one Mg(3), one Mg(7), one Mg(8), and two equivalent Mg(10) atoms to form distorted OMg5 trigonal bipyramids that share  a cornercorner with one O(4)Mg6 octahedra,  a cornercorner with one O(8)Mg6 octahedra, corners with two equivalent O(11)Mg6 octahedra,  a cornercorner with one O(6)Rb2Mg3 trigonal bipyramid, corners with four equivalent O(5)Mg5 trigonal bipyramids, edges with two equivalent O(2)RbMg5 octahedra, and edges with two equivalent O(3)Mg5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 3-76°. In the sixth O site, O(6) is bonded to two equivalent Rb(1), one Mg(5), and two equivalent Mg(3) atoms to form ORb2Mg3 trigonal bipyramids that share  a cornercorner with one O(8)Mg6 octahedra, corners with two equivalent O(2)RbMg5 octahedra, corners with two equivalent O(1)Mg5 square pyramids, corners with two equivalent O(5)Mg5 trigonal bipyramids, corners with two equivalent O(6)Rb2Mg3 trigonal bipyramids, and edges with two equivalent O(4)Mg6 octahedra. The corner-sharing octahedral tilt angles range from 0-65°. In the seventh O site, O(7) is bonded in a distorted square co-planar geometry to one Mg(6), one Mg(8), and two equivalent Mg(3) atoms. In the eighth O site, O(8) is bonded to one Mg(5), one Mg(7), two equivalent Mg(1), and two equivalent Mg(4) atoms to form OMg6 octahedra that share corners with two equivalent O(8)Mg6 octahedra, corners with two equivalent O(9)Mg5 square pyramids,  a cornercorner with one O(6)Rb2Mg3 trigonal bipyramid, corners with two equivalent O(5)Mg5 trigonal bipyramids, edges with two equivalent O(4)Mg6 octahedra, edges with two equivalent O(2)RbMg5 octahedra, edges with four equivalent O(11)Mg6 octahedra, and edges with two equivalent O(1)Mg5 square pyramids. The corner-sharing octahedral tilt angles are 3°. In the ninth O site, O(9) is bonded to one Mg(6), two equivalent Mg(2), and two equivalent Mg(4) atoms to form OMg5 square pyramids that share corners with two equivalent O(8)Mg6 octahedra, corners with two equivalent O(9)Mg5 square pyramids, corners with two equivalent O(3)Mg5 trigonal bipyramids, edges with two equivalent O(4)Mg6 octahedra, and edges with four equivalent O(11)Mg6 octahedra. The corner-sharing octahedral tilt angles are 5°. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Rb(1), one Mg(9), two equivalent Mg(3), and one B(1) atom. In the eleventh O site, O(11) is bonded to one Mg(1), one Mg(10), one Mg(2), one Mg(9), and two equivalent Mg(4) atoms to form OMg6 octahedra that share corners with four equivalent O(11)Mg6 octahedra, corners with two equivalent O(5)Mg5 trigonal bipyramids,  an edgeedge with one O(2)RbMg5 octahedra, edges with two equivalent O(4)Mg6 octahedra, edges with two equivalent O(8)Mg6 octahedra,  an edgeedge with one O(1)Mg5 square pyramid, edges with two equivalent O(9)Mg5 square pyramids, and  an edgeedge with one O(3)Mg5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-11°.
RbMg14BO15 crystallizes in the orthorhombic Pmm2 space group. Rb(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(10), and two equivalent O(6) atoms. The Rb(1)-O(2) bond length is 2.53 Å. Both Rb(1)-O(10) bond lengths are 2.82 Å. Both Rb(1)-O(6) bond lengths are 2.38 Å. There are ten inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to one O(1), one O(2), two equivalent O(11), and two equivalent O(8) atoms to form MgO6 octahedra that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Mg(2)O5 square pyramids, edges with two equivalent Mg(5)O6 octahedra, edges with four equivalent Mg(4)O5 square pyramids, edges with two equivalent Mg(10)O5 trigonal bipyramids, edges with two equivalent Mg(7)O5 trigonal bipyramids, and edges with two equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. The Mg(1)-O(1) bond length is 2.02 Å. The Mg(1)-O(2) bond length is 2.02 Å. Both Mg(1)-O(11) bond lengths are 2.08 Å. Both Mg(1)-O(8) bond lengths are 2.16 Å. In the second Mg site, Mg(2) is bonded to one O(3), two equivalent O(11), and two equivalent O(9) atoms to form MgO5 square pyramids that share corners with two equivalent Mg(1)O6 octahedra, corners with two equivalent Mg(2)O5 square pyramids, corners with two equivalent Mg(8)O5 trigonal bipyramids, corners with two equivalent Mg(9)O5 trigonal bipyramids, edges with four equivalent Mg(4)O5 square pyramids, and edges with two equivalent Mg(10)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 4°. The Mg(2)-O(3) bond length is 2.07 Å. Both Mg(2)-O(11) bond lengths are 2.00 Å. Both Mg(2)-O(9) bond lengths are 2.18 Å. In the third Mg site, Mg(3) is bonded to one O(4), one O(5), one O(6), one O(7), and two equivalent O(10) atoms to form distorted MgO6 octahedra that share corners with four equivalent Mg(3)O6 octahedra,  a cornercorner with one Mg(4)O5 square pyramid,  a cornercorner with one Mg(7)O5 trigonal bipyramid, corners with two equivalent Mg(10)O5 trigonal bipyramids,  an edgeedge with one Mg(5)O6 octahedra,  an edgeedge with one Mg(8)O5 trigonal bipyramid, and edges with two equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 4-32°. The Mg(3)-O(4) bond length is 2.24 Å. The Mg(3)-O(5) bond length is 2.53 Å. The Mg(3)-O(6) bond length is 2.10 Å. The Mg(3)-O(7) bond length is 1.99 Å. Both Mg(3)-O(10) bond lengths are 2.24 Å. In the fourth Mg site, Mg(4) is bonded to one O(4), one O(8), one O(9), and two equivalent O(11) atoms to form MgO5 square pyramids that share  a cornercorner with one Mg(3)O6 octahedra, corners with four equivalent Mg(4)O5 square pyramids,  a cornercorner with one Mg(7)O5 trigonal bipyramid, corners with two equivalent Mg(10)O5 trigonal bipyramids,  an edgeedge with one Mg(5)O6 octahedra, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(2)O5 square pyramids, and edges with two equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 1°. The Mg(4)-O(4) bond length is 2.08 Å. The Mg(4)-O(8) bond length is 2.09 Å. The Mg(4)-O(9) bond length is 1.99 Å. Both Mg(4)-O(11) bond lengths are 2.16 Å. In the fifth Mg site, Mg(5) is bonded to one O(6), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form MgO6 octahedra that share corners with two equivalent Mg(5)O6 octahedra,  a cornercorner with one Mg(7)O5 trigonal bipyramid, edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, edges with two equivalent Mg(4)O5 square pyramids, and edges with four equivalent Mg(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 10°. The Mg(5)-O(6) bond length is 1.94 Å. The Mg(5)-O(8) bond length is 2.27 Å. Both Mg(5)-O(1) bond lengths are 2.16 Å. Both Mg(5)-O(4) bond lengths are 2.07 Å. In the sixth Mg site, Mg(6) is bonded in a distorted square co-planar geometry to one O(7), one O(9), and two equivalent O(4) atoms. The Mg(6)-O(7) bond length is 2.21 Å. The Mg(6)-O(9) bond length is 2.19 Å. Both Mg(6)-O(4) bond lengths are 2.01 Å. In the seventh Mg site, Mg(7) is bonded to one O(8), two equivalent O(2), and two equivalent O(5) atoms to form MgO5 trigonal bipyramids that share  a cornercorner with one Mg(5)O6 octahedra, corners with two equivalent Mg(3)O6 octahedra, corners with two equivalent Mg(4)O5 square pyramids, corners with two equivalent Mg(7)O5 trigonal bipyramids, corners with two equivalent Mg(8)O5 trigonal bipyramids, edges with two equivalent Mg(1)O6 octahedra, and edges with four equivalent Mg(10)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 0-70°. The Mg(7)-O(8) bond length is 2.08 Å. Both Mg(7)-O(2) bond lengths are 2.16 Å. Both Mg(7)-O(5) bond lengths are 2.07 Å. In the eighth Mg site, Mg(8) is bonded to one O(7), two equivalent O(3), and two equivalent O(5) atoms to form MgO5 trigonal bipyramids that share corners with two equivalent Mg(2)O5 square pyramids, corners with two equivalent Mg(7)O5 trigonal bipyramids, corners with two equivalent Mg(8)O5 trigonal bipyramids, edges with two equivalent Mg(3)O6 octahedra, and edges with four equivalent Mg(10)O5 trigonal bipyramids. The Mg(8)-O(7) bond length is 2.18 Å. Both Mg(8)-O(3) bond lengths are 2.28 Å. Both Mg(8)-O(5) bond lengths are 2.12 Å. In the ninth Mg site, Mg(9) is bonded to one O(1), one O(10), one O(11), and two equivalent O(4) atoms to form distorted MgO5 trigonal bipyramids that share  a cornercorner with one Mg(2)O5 square pyramid,  a cornercorner with one Mg(10)O5 trigonal bipyramid, corners with three equivalent Mg(9)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O6 octahedra, edges with two equivalent Mg(3)O6 octahedra, edges with two equivalent Mg(5)O6 octahedra, and edges with two equivalent Mg(4)O5 square pyramids. The Mg(9)-O(1) bond length is 2.03 Å. The Mg(9)-O(10) bond length is 2.17 Å. The Mg(9)-O(11) bond length is 2.28 Å. Both Mg(9)-O(4) bond lengths are 2.16 Å. In the tenth Mg site, Mg(10) is bonded to one O(11), one O(2), one O(3), and two equivalent O(5) atoms to form MgO5 trigonal bipyramids that share corners with two equivalent Mg(3)O6 octahedra, corners with two equivalent Mg(4)O5 square pyramids,  a cornercorner with one Mg(9)O5 trigonal bipyramid, corners with four equivalent Mg(10)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O6 octahedra,  an edgeedge with one Mg(2)O5 square pyramid, edges with two equivalent Mg(7)O5 trigonal bipyramids, and edges with two equivalent Mg(8)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 77°. The Mg(10)-O(11) bond length is 2.18 Å. The Mg(10)-O(2) bond length is 2.08 Å. The Mg(10)-O(3) bond length is 2.00 Å. Both Mg(10)-O(5) bond lengths are 2.22 Å. B(1) is bonded in a bent 150 degrees geometry to two equivalent O(10) atoms. Both B(1)-O(10) bond lengths are 1.45 Å. There are eleven inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), two equivalent Mg(5), and two equivalent Mg(9) atoms to form distorted OMg5 square pyramids that share  a cornercorner with one O(2)RbMg5 octahedra, corners with two equivalent O(1)Mg5 square pyramids, corners with two equivalent O(6)Rb2Mg3 trigonal bipyramids, edges with two equivalent O(11)Mg6 octahedra, edges with two equivalent O(8)Mg6 octahedra, and edges with four equivalent O(4)Mg6 octahedra. The corner-sharing octahedra are not tilted. In the second O site, O(2) is bonded to one Rb(1), one Mg(1), two equivalent Mg(10), and two equivalent Mg(7) atoms to form ORbMg5 octahedra that share corners with two equivalent O(2)RbMg5 octahedra,  a cornercorner with one O(1)Mg5 square pyramid, corners with two equivalent O(3)Mg5 trigonal bipyramids, corners with two equivalent O(6)Rb2Mg3 trigonal bipyramids, edges with two equivalent O(11)Mg6 octahedra, edges with two equivalent O(8)Mg6 octahedra, and edges with four equivalent O(5)Mg5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 6°. In the third O site, O(3) is bonded to one Mg(2), two equivalent Mg(10), and two equivalent Mg(8) atoms to form OMg5 trigonal bipyramids that share corners with two equivalent O(2)RbMg5 octahedra, corners with two equivalent O(9)Mg5 square pyramids, corners with two equivalent O(3)Mg5 trigonal bipyramids, edges with two equivalent O(11)Mg6 octahedra, and edges with four equivalent O(5)Mg5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 4°. In the fourth O site, O(4) is bonded to one Mg(3), one Mg(4), one Mg(5), one Mg(6), and two equivalent Mg(9) atoms to form OMg6 octahedra that share corners with four equivalent O(4)Mg6 octahedra,  a cornercorner with one O(5)Mg5 trigonal bipyramid,  an edgeedge with one O(8)Mg6 octahedra, edges with two equivalent O(11)Mg6 octahedra,  an edgeedge with one O(9)Mg5 square pyramid, edges with two equivalent O(1)Mg5 square pyramids, and  an edgeedge with one O(6)Rb2Mg3 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(5) is bonded to one Mg(3), one Mg(7), one Mg(8), and two equivalent Mg(10) atoms to form distorted OMg5 trigonal bipyramids that share  a cornercorner with one O(4)Mg6 octahedra,  a cornercorner with one O(8)Mg6 octahedra, corners with two equivalent O(11)Mg6 octahedra,  a cornercorner with one O(6)Rb2Mg3 trigonal bipyramid, corners with four equivalent O(5)Mg5 trigonal bipyramids, edges with two equivalent O(2)RbMg5 octahedra, and edges with two equivalent O(3)Mg5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 3-76°. In the sixth O site, O(6) is bonded to two equivalent Rb(1), one Mg(5), and two equivalent Mg(3) atoms to form ORb2Mg3 trigonal bipyramids that share  a cornercorner with one O(8)Mg6 octahedra, corners with two equivalent O(2)RbMg5 octahedra, corners with two equivalent O(1)Mg5 square pyramids, corners with two equivalent O(5)Mg5 trigonal bipyramids, corners with two equivalent O(6)Rb2Mg3 trigonal bipyramids, and edges with two equivalent O(4)Mg6 octahedra. The corner-sharing octahedral tilt angles range from 0-65°. In the seventh O site, O(7) is bonded in a distorted square co-planar geometry to one Mg(6), one Mg(8), and two equivalent Mg(3) atoms. In the eighth O site, O(8) is bonded to one Mg(5), one Mg(7), two equivalent Mg(1), and two equivalent Mg(4) atoms to form OMg6 octahedra that share corners with two equivalent O(8)Mg6 octahedra, corners with two equivalent O(9)Mg5 square pyramids,  a cornercorner with one O(6)Rb2Mg3 trigonal bipyramid, corners with two equivalent O(5)Mg5 trigonal bipyramids, edges with two equivalent O(4)Mg6 octahedra, edges with two equivalent O(2)RbMg5 octahedra, edges with four equivalent O(11)Mg6 octahedra, and edges with two equivalent O(1)Mg5 square pyramids. The corner-sharing octahedral tilt angles are 3°. In the ninth O site, O(9) is bonded to one Mg(6), two equivalent Mg(2), and two equivalent Mg(4) atoms to form OMg5 square pyramids that share corners with two equivalent O(8)Mg6 octahedra, corners with two equivalent O(9)Mg5 square pyramids, corners with two equivalent O(3)Mg5 trigonal bipyramids, edges with two equivalent O(4)Mg6 octahedra, and edges with four equivalent O(11)Mg6 octahedra. The corner-sharing octahedral tilt angles are 5°. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Rb(1), one Mg(9), two equivalent Mg(3), and one B(1) atom. In the eleventh O site, O(11) is bonded to one Mg(1), one Mg(10), one Mg(2), one Mg(9), and two equivalent Mg(4) atoms to form OMg6 octahedra that share corners with four equivalent O(11)Mg6 octahedra, corners with two equivalent O(5)Mg5 trigonal bipyramids,  an edgeedge with one O(2)RbMg5 octahedra, edges with two equivalent O(4)Mg6 octahedra, edges with two equivalent O(8)Mg6 octahedra,  an edgeedge with one O(1)Mg5 square pyramid, edges with two equivalent O(9)Mg5 square pyramids, and  an edgeedge with one O(3)Mg5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-11°.