TcCdO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Tc(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TcO6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. Cd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Tc(1) and three equivalent Cd(1) atoms. In the second O site, O(2) is bonded to two equivalent Tc(1) and two equivalent Cd(1) atoms to form distorted corner-sharing OCd2Tc2 tetrahedra.
TcCdO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Tc(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TcO6 octahedra. The corner-sharing octahedral tilt angles range from 34-35°. Both Tc(1)-O(2) bond lengths are 2.06 Å. All Tc(1)-O(1) bond lengths are 2.04 Å. Cd(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. There is one shorter (2.27 Å) and one longer (2.36 Å) Cd(1)-O(2) bond length. There are a spread of Cd(1)-O(1) bond distances ranging from 2.28-2.77 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Tc(1) and three equivalent Cd(1) atoms. In the second O site, O(2) is bonded to two equivalent Tc(1) and two equivalent Cd(1) atoms to form distorted corner-sharing OCd2Tc2 tetrahedra.