PNH3F5 is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four azane;pentafluoro-lambda5-phosphane molecules. P(1) is bonded in an octahedral geometry to one N(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(1); one H(3); and two equivalent H(1,2) atoms. There are two inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one P(1) atom.
PNH3F5 is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four azane;pentafluoro-lambda5-phosphane molecules. P(1) is bonded in an octahedral geometry to one N(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The P(1)-N(1) bond length is 1.87 Å. The P(1)-F(1) bond length is 1.64 Å. The P(1)-F(2) bond length is 1.63 Å. The P(1)-F(3) bond length is 1.61 Å. The P(1)-F(4) bond length is 1.64 Å. The P(1)-F(5) bond length is 1.63 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(1); one H(3); and two equivalent H(1,2) atoms. The N(1)-H(3) bond length is 1.03 Å. Both N(1)-H(1,2) bond lengths are 1.03 Å. There are two inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one P(1) atom.