(H2O)2C2H9O6Cl2F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules and two C2H9O6Cl2F clusters. In each C2H9O6Cl2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one Cl(1), one Cl(2), and one F(1) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(3) and one O(6) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(4) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(4) and one O(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(8) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(8) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one C(2) and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(5) atom. In the fifth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(8), and one H(9) atom. In the sixth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one H(12), one H(13), and one H(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(1) atom.
(H2O)2C2H9O6Cl2F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules and two C2H9O6Cl2F clusters. In each C2H9O6Cl2F cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one Cl(1), one Cl(2), and one F(1) atom. The C(1)-C(2) bond length is 1.57 Å. The C(1)-Cl(1) bond length is 1.78 Å. The C(1)-Cl(2) bond length is 1.77 Å. The C(1)-F(1) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.26 Å. The C(2)-O(2) bond length is 1.26 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(3) and one O(4) atom. The H(1)-O(3) bond length is 1.27 Å. The H(1)-O(4) bond length is 1.16 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. The H(2)-O(3) bond length is 1.00 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(3) and one O(6) atom. The H(3)-O(3) bond length is 1.01 Å. The H(3)-O(6) bond length is 1.64 Å. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(1) and one O(4) atom. The H(4)-O(1) bond length is 1.67 Å. The H(4)-O(4) bond length is 1.01 Å. In the fifth H site, H(5) is bonded in a linear geometry to one O(4) and one O(8) atom. The H(5)-O(4) bond length is 1.02 Å. The H(5)-O(8) bond length is 1.59 Å. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(6) atom. The H(8)-O(6) bond length is 0.99 Å. In the seventh H site, H(9) is bonded in a single-bond geometry to one O(6) atom. The H(9)-O(6) bond length is 1.00 Å. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(8) atom. The H(12)-O(8) bond length is 1.00 Å. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(8) atom. The H(13)-O(8) bond length is 1.00 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one C(2) and one H(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one H(1), one H(4), and one H(5) atom. In the fifth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(8), and one H(9) atom. In the sixth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one H(12), one H(13), and one H(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one C(1) atom.