MgPm2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mg(1) is bonded to four equivalent S(1) atoms to form MgS4 tetrahedra that share corners with twelve equivalent Pm(1)S6 octahedra. The corner-sharing octahedral tilt angles are 56°. Pm(1) is bonded to six equivalent S(1) atoms to form PmS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra and edges with six equivalent Pm(1)S6 octahedra. S(1) is bonded in a rectangular see-saw-like geometry to one Mg(1) and three equivalent Pm(1) atoms.
MgPm2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mg(1) is bonded to four equivalent S(1) atoms to form MgS4 tetrahedra that share corners with twelve equivalent Pm(1)S6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Mg(1)-S(1) bond lengths are 2.53 Å. Pm(1) is bonded to six equivalent S(1) atoms to form PmS6 octahedra that share corners with six equivalent Mg(1)S4 tetrahedra and edges with six equivalent Pm(1)S6 octahedra. All Pm(1)-S(1) bond lengths are 2.83 Å. S(1) is bonded in a rectangular see-saw-like geometry to one Mg(1) and three equivalent Pm(1) atoms.