(Fe(SO3)6)2(N2)9 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of nine ammonia atoms and one Fe(SO3)6 cluster. In the Fe(SO3)6 cluster, Fe(1) is bonded in an octahedral geometry to two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(7) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(2), one O(5), and one O(8) atom. In the third S site, S(3) is bonded in a trigonal planar geometry to one O(9) and two equivalent O(3,6) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3,6) is bonded in a single-bond geometry to one S(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(7) is bonded in a bent 150 degrees geometry to one Fe(1) and one S(1) atom. In the seventh O site, O(8) is bonded in a bent 150 degrees geometry to one Fe(1) and one S(2) atom. In the eighth O site, O(9) is bonded in a bent 150 degrees geometry to one Fe(1) and one S(3) atom.
(Fe(SO3)6)2(N2)9 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of nine ammonia atoms and one Fe(SO3)6 cluster. In the Fe(SO3)6 cluster, Fe(1) is bonded in an octahedral geometry to two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. Both Fe(1)-O(7) bond lengths are 2.29 Å. Both Fe(1)-O(8) bond lengths are 1.96 Å. Both Fe(1)-O(9) bond lengths are 2.32 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(7) atom. The S(1)-O(1) bond length is 1.43 Å. The S(1)-O(4) bond length is 1.43 Å. The S(1)-O(7) bond length is 1.45 Å. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one O(2), one O(5), and one O(8) atom. The S(2)-O(2) bond length is 1.46 Å. The S(2)-O(5) bond length is 1.47 Å. The S(2)-O(8) bond length is 1.56 Å. In the third S site, S(3) is bonded in a trigonal planar geometry to one O(9) and two equivalent O(3,6) atoms. The S(3)-O(9) bond length is 1.44 Å. Both S(3)-O(3,6) bond lengths are 1.43 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3,6) is bonded in a single-bond geometry to one S(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(7) is bonded in a bent 150 degrees geometry to one Fe(1) and one S(1) atom. In the seventh O site, O(8) is bonded in a bent 150 degrees geometry to one Fe(1) and one S(2) atom. In the eighth O site, O(9) is bonded in a bent 150 degrees geometry to one Fe(1) and one S(3) atom.