KGaCl4 is Zircon-like structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom.
KGaCl4 is Zircon-like structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. There is one shorter (3.28 Å) and one longer (3.61 Å) K(1)-Cl(1) bond length. There is one shorter (3.20 Å) and one longer (3.23 Å) K(1)-Cl(2) bond length. There is one shorter (3.29 Å) and one longer (3.57 Å) K(1)-Cl(3) bond length. There is one shorter (3.26 Å) and one longer (3.27 Å) K(1)-Cl(4) bond length. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Ga(1)-Cl(1) bond length is 2.18 Å. The Ga(1)-Cl(2) bond length is 2.19 Å. The Ga(1)-Cl(3) bond length is 2.19 Å. The Ga(1)-Cl(4) bond length is 2.19 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Ga(1) atom.