RhF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four rhodium hexafluoride molecules. Rh(1) is bonded in an octahedral geometry to three equivalent F(1,4) and three equivalent F(2,3) atoms. There are two inequivalent F sites. In the first F site, F(2,3) is bonded in a single-bond geometry to one Rh(1) atom. In the second F site, F(1,4) is bonded in a single-bond geometry to one Rh(1) atom.
RhF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four rhodium hexafluoride molecules. Rh(1) is bonded in an octahedral geometry to three equivalent F(1,4) and three equivalent F(2,3) atoms. There are two shorter (1.83 Å) and one longer (1.84 Å) Rh(1)-F(1,4) bond length. All Rh(1)-F(2,3) bond lengths are 1.84 Å. There are two inequivalent F sites. In the first F site, F(2,3) is bonded in a single-bond geometry to one Rh(1) atom. In the second F site, F(1,4) is bonded in a single-bond geometry to one Rh(1) atom.