LiNH2 crystallizes in the orthorhombic Pbcm space group. Li(1) is bonded in a 8-coordinate geometry to four equivalent N(1), two equivalent H(1), and two equivalent H(2) atoms. N(1) is bonded in a 3-coordinate geometry to four equivalent Li(1), one H(2), and two equivalent H(1) atoms. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to two equivalent Li(1) and one N(1) atom. In the second H site, H(1) is bonded in a distorted linear geometry to two equivalent Li(1) and two equivalent N(1) atoms.
LiNH2 crystallizes in the orthorhombic Pbcm space group. Li(1) is bonded in a 8-coordinate geometry to four equivalent N(1), two equivalent H(1), and two equivalent H(2) atoms. There are two shorter (2.10 Å) and two longer (2.23 Å) Li(1)-N(1) bond lengths. Both Li(1)-H(1) bond lengths are 2.11 Å. Both Li(1)-H(2) bond lengths are 2.05 Å. N(1) is bonded in a 3-coordinate geometry to four equivalent Li(1), one H(2), and two equivalent H(1) atoms. The N(1)-H(2) bond length is 1.03 Å. Both N(1)-H(1) bond lengths are 1.38 Å. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to two equivalent Li(1) and one N(1) atom. In the second H site, H(1) is bonded in a distorted linear geometry to two equivalent Li(1) and two equivalent N(1) atoms.