GdSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing GdS4Br3 pentagonal bipyramids. S(1) is bonded to four equivalent Gd(1) atoms to form a mixture of corner and edge-sharing SGd4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Gd(1) atoms.
GdSBr is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded to four equivalent S(1) and three equivalent Br(1) atoms to form a mixture of distorted corner and edge-sharing GdS4Br3 pentagonal bipyramids. There are three shorter (2.76 Å) and one longer (2.77 Å) Gd(1)-S(1) bond length. There are a spread of Gd(1)-Br(1) bond distances ranging from 2.96-3.11 Å. S(1) is bonded to four equivalent Gd(1) atoms to form a mixture of corner and edge-sharing SGd4 tetrahedra. Br(1) is bonded in a distorted T-shaped geometry to three equivalent Gd(1) atoms.