TbO2ZrO12 crystallizes in the cubic Fd-3m space group. The structure consists of one TbO2 framework and one ZrO12 framework. In the TbO2 framework, Tb(1) is bonded to four equivalent O(1) atoms to form corner-sharing TbO4 tetrahedra. O(1) is bonded in a linear geometry to two equivalent Tb(1) atoms. In the ZrO12 framework, Zr(1) is bonded in a cuboctahedral geometry to twelve equivalent O(2) atoms. O(2) is bonded in a 3-coordinate geometry to one Zr(1) and two equivalent O(2) atoms.
TbO2ZrO12 crystallizes in the cubic Fd-3m space group. The structure consists of one TbO2 framework and one ZrO12 framework. In the TbO2 framework, Tb(1) is bonded to four equivalent O(1) atoms to form corner-sharing TbO4 tetrahedra. All Tb(1)-O(1) bond lengths are 2.34 Å. O(1) is bonded in a linear geometry to two equivalent Tb(1) atoms. In the ZrO12 framework, Zr(1) is bonded in a cuboctahedral geometry to twelve equivalent O(2) atoms. All Zr(1)-O(2) bond lengths are 2.39 Å. O(2) is bonded in a 3-coordinate geometry to one Zr(1) and two equivalent O(2) atoms. Both O(2)-O(2) bond lengths are 1.68 Å.