Rh3V is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Rh(1) atoms to form VRh12 cuboctahedra that share corners with twelve equivalent V(1)Rh12 cuboctahedra, edges with twenty-four equivalent Rh(1)V4Rh8 cuboctahedra, faces with six equivalent V(1)Rh12 cuboctahedra, and faces with twelve equivalent Rh(1)V4Rh8 cuboctahedra. Rh(1) is bonded to four equivalent V(1) and eight equivalent Rh(1) atoms to form distorted RhV4Rh8 cuboctahedra that share corners with twelve equivalent Rh(1)V4Rh8 cuboctahedra, edges with eight equivalent V(1)Rh12 cuboctahedra, edges with sixteen equivalent Rh(1)V4Rh8 cuboctahedra, faces with four equivalent V(1)Rh12 cuboctahedra, and faces with fourteen equivalent Rh(1)V4Rh8 cuboctahedra.
Rh3V is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. V(1) is bonded to twelve equivalent Rh(1) atoms to form VRh12 cuboctahedra that share corners with twelve equivalent V(1)Rh12 cuboctahedra, edges with twenty-four equivalent Rh(1)V4Rh8 cuboctahedra, faces with six equivalent V(1)Rh12 cuboctahedra, and faces with twelve equivalent Rh(1)V4Rh8 cuboctahedra. All V(1)-Rh(1) bond lengths are 2.67 Å. Rh(1) is bonded to four equivalent V(1) and eight equivalent Rh(1) atoms to form distorted RhV4Rh8 cuboctahedra that share corners with twelve equivalent Rh(1)V4Rh8 cuboctahedra, edges with eight equivalent V(1)Rh12 cuboctahedra, edges with sixteen equivalent Rh(1)V4Rh8 cuboctahedra, faces with four equivalent V(1)Rh12 cuboctahedra, and faces with fourteen equivalent Rh(1)V4Rh8 cuboctahedra. All Rh(1)-Rh(1) bond lengths are 2.67 Å.