MgTmPd crystallizes in the hexagonal P-62m space group. Mg(1) is bonded to two equivalent Pd(1) and two equivalent Pd(2) atoms to form a mixture of distorted corner and edge-sharing MgPd4 tetrahedra. Tm(1) is bonded in a 5-coordinate geometry to one Pd(2) and four equivalent Pd(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Mg(1) and three equivalent Tm(1) atoms. In the second Pd site, Pd(1) is bonded in a 9-coordinate geometry to three equivalent Mg(1) and six equivalent Tm(1) atoms.
MgTmPd crystallizes in the hexagonal P-62m space group. Mg(1) is bonded to two equivalent Pd(1) and two equivalent Pd(2) atoms to form a mixture of distorted corner and edge-sharing MgPd4 tetrahedra. Both Mg(1)-Pd(1) bond lengths are 2.81 Å. Both Mg(1)-Pd(2) bond lengths are 2.71 Å. Tm(1) is bonded in a 5-coordinate geometry to one Pd(2) and four equivalent Pd(1) atoms. The Tm(1)-Pd(2) bond length is 3.00 Å. All Tm(1)-Pd(1) bond lengths are 3.00 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(2) is bonded in a 9-coordinate geometry to six equivalent Mg(1) and three equivalent Tm(1) atoms. In the second Pd site, Pd(1) is bonded in a 9-coordinate geometry to three equivalent Mg(1) and six equivalent Tm(1) atoms.