NbMn3F6 crystallizes in the triclinic P-1 space group. Nb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Mn site, Mn(2) is bonded in a linear geometry to two equivalent F(3) atoms. In the third Mn site, Mn(3) is bonded in a linear geometry to two equivalent F(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Nb(1) and one Mn(3) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Nb(1) and one Mn(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Nb(1) and one Mn(2) atom.
NbMn3F6 crystallizes in the triclinic P-1 space group. Nb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Both Nb(1)-F(1) bond lengths are 2.01 Å. Both Nb(1)-F(2) bond lengths are 2.11 Å. Both Nb(1)-F(3) bond lengths are 2.05 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a linear geometry to two equivalent F(2) atoms. Both Mn(1)-F(2) bond lengths are 1.95 Å. In the second Mn site, Mn(2) is bonded in a linear geometry to two equivalent F(3) atoms. Both Mn(2)-F(3) bond lengths are 2.20 Å. In the third Mn site, Mn(3) is bonded in a linear geometry to two equivalent F(1) atoms. Both Mn(3)-F(1) bond lengths are 2.21 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Nb(1) and one Mn(3) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Nb(1) and one Mn(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Nb(1) and one Mn(2) atom.