KSbCl6 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 12-coordinate geometry to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom.
KSbCl6 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 12-coordinate geometry to four equivalent Cl(1), four equivalent Cl(2), and four equivalent Cl(3) atoms. There are two shorter (3.46 Å) and two longer (3.80 Å) K(1)-Cl(1) bond lengths. There are two shorter (3.48 Å) and two longer (3.70 Å) K(1)-Cl(2) bond lengths. There are two shorter (3.50 Å) and two longer (3.54 Å) K(1)-Cl(3) bond lengths. Sb(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. Both Sb(1)-Cl(1) bond lengths are 2.40 Å. Both Sb(1)-Cl(2) bond lengths are 2.39 Å. Both Sb(1)-Cl(3) bond lengths are 2.39 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Sb(1) atom.