WCrB2 is delta Molybdenum Boride-derived structured and crystallizes in the orthorhombic Amm2 space group. W(1) is bonded in a 11-coordinate geometry to four equivalent Cr(1), three equivalent B(1), and four equivalent B(2) atoms. Cr(1) is bonded in a 11-coordinate geometry to four equivalent W(1), three equivalent B(2), and four equivalent B(1) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to three equivalent W(1), four equivalent Cr(1), and two equivalent B(2) atoms. In the second B site, B(2) is bonded in a 9-coordinate geometry to four equivalent W(1), three equivalent Cr(1), and two equivalent B(1) atoms.
WCrB2 is delta Molybdenum Boride-derived structured and crystallizes in the orthorhombic Amm2 space group. W(1) is bonded in a 11-coordinate geometry to four equivalent Cr(1), three equivalent B(1), and four equivalent B(2) atoms. All W(1)-Cr(1) bond lengths are 2.74 Å. There are two shorter (2.32 Å) and one longer (2.33 Å) W(1)-B(1) bond length. All W(1)-B(2) bond lengths are 2.27 Å. Cr(1) is bonded in a 11-coordinate geometry to four equivalent W(1), three equivalent B(2), and four equivalent B(1) atoms. There are two shorter (2.23 Å) and one longer (2.46 Å) Cr(1)-B(2) bond length. All Cr(1)-B(1) bond lengths are 2.23 Å. There are two inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to three equivalent W(1), four equivalent Cr(1), and two equivalent B(2) atoms. Both B(1)-B(2) bond lengths are 1.81 Å. In the second B site, B(2) is bonded in a 9-coordinate geometry to four equivalent W(1), three equivalent Cr(1), and two equivalent B(1) atoms.