LiMnF3 crystallizes in the hexagonal P6_322 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Mn(1)F6 octahedra, edges with three equivalent Mn(1)F6 octahedra, and faces with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 46°. Mn(1) is bonded to six equivalent F(1) atoms to form MnF6 octahedra that share corners with six equivalent Li(1)F6 octahedra, corners with six equivalent Mn(1)F6 octahedra, and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. F(1) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1) and two equivalent Mn(1) atoms.
LiMnF3 crystallizes in the hexagonal P6_322 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Mn(1)F6 octahedra, edges with three equivalent Mn(1)F6 octahedra, and faces with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 46°. All Li(1)-F(1) bond lengths are 2.02 Å. Mn(1) is bonded to six equivalent F(1) atoms to form MnF6 octahedra that share corners with six equivalent Li(1)F6 octahedra, corners with six equivalent Mn(1)F6 octahedra, and edges with three equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. All Mn(1)-F(1) bond lengths are 2.17 Å. F(1) is bonded in a rectangular see-saw-like geometry to two equivalent Li(1) and two equivalent Mn(1) atoms.