Ag2SO2 crystallizes in the orthorhombic Fddd space group. Ag(1) is bonded in a 5-coordinate geometry to two equivalent Ag(1), two equivalent S(1), and one O(1) atom. S(1) is bonded in a linear geometry to four equivalent Ag(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one Ag(1) and one S(1) atom.
Ag2SO2 crystallizes in the orthorhombic Fddd space group. Ag(1) is bonded in a 5-coordinate geometry to two equivalent Ag(1), two equivalent S(1), and one O(1) atom. There is one shorter (2.75 Å) and one longer (2.76 Å) Ag(1)-Ag(1) bond length. There is one shorter (2.64 Å) and one longer (2.72 Å) Ag(1)-S(1) bond length. The Ag(1)-O(1) bond length is 2.85 Å. S(1) is bonded in a linear geometry to four equivalent Ag(1) and two equivalent O(1) atoms. Both S(1)-O(1) bond lengths are 1.53 Å. O(1) is bonded in a single-bond geometry to one Ag(1) and one S(1) atom.