NaReO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Re(1)O6 octahedra. Re(1) is bonded to six equivalent O(1) atoms to form ReO6 octahedra that share corners with six equivalent Re(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Na(1) and two equivalent Re(1) atoms to form a mixture of distorted corner, edge, and face-sharing ONa4Re2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
NaReO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Re(1)O6 octahedra. All Na(1)-O(1) bond lengths are 2.75 Å. Re(1) is bonded to six equivalent O(1) atoms to form ReO6 octahedra that share corners with six equivalent Re(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Re(1)-O(1) bond lengths are 1.94 Å. O(1) is bonded to four equivalent Na(1) and two equivalent Re(1) atoms to form a mixture of distorted corner, edge, and face-sharing ONa4Re2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.