LiTiO2 is Caswellsilverite-like structured and crystallizes in the hexagonal P6_3mc space group. Li(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form LiO6 octahedra that share corners with nine equivalent Ti(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-46°. Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form TiO6 octahedra that share corners with nine equivalent Li(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, edges with six equivalent Ti(1)O6 octahedra, and  a faceface with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-46°. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing OLi3Ti3 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of corner and edge-sharing OLi3Ti3 octahedra.
LiTiO2 is Caswellsilverite-like structured and crystallizes in the hexagonal P6_3mc space group. Li(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form LiO6 octahedra that share corners with nine equivalent Ti(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, edges with six equivalent Li(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-46°. All Li(1)-O(1) bond lengths are 2.22 Å. All Li(1)-O(2) bond lengths are 2.09 Å. Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form TiO6 octahedra that share corners with nine equivalent Li(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, edges with six equivalent Ti(1)O6 octahedra, and  a faceface with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-46°. All Ti(1)-O(1) bond lengths are 2.06 Å. All Ti(1)-O(2) bond lengths are 2.07 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing OLi3Ti3 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 0-4°. In the second O site, O(2) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of corner and edge-sharing OLi3Ti3 octahedra.