Co(NO5)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Co(NO5)2 cluster. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom.
Co(NO5)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Co(NO5)2 cluster. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Co(1)-O(1) bond lengths are 1.75 Å. Both Co(1)-O(2) bond lengths are 1.75 Å. Both Co(1)-O(3) bond lengths are 2.22 Å. N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The N(1)-O(3) bond length is 1.28 Å. The N(1)-O(4) bond length is 1.24 Å. The N(1)-O(5) bond length is 1.25 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(1) atom.