TlWSbO6 crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-41°. Sb(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom.
TlWSbO6 crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-41°. There is one shorter (1.93 Å) and one longer (1.98 Å) W(1)-O(1) bond length. Both W(1)-O(3) bond lengths are 1.92 Å. Both W(1)-O(4) bond lengths are 1.94 Å. Sb(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. Both Sb(1)-O(2) bond lengths are 1.99 Å. Both Sb(1)-O(3) bond lengths are 2.00 Å. Both Sb(1)-O(4) bond lengths are 2.01 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom.