Pr(PdO2)2 crystallizes in the tetragonal I4_1/a space group. Pr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Pr(1) and two equivalent Pd(1) atoms to form a mixture of corner and edge-sharing OPr2Pd2 tetrahedra.
Pr(PdO2)2 crystallizes in the tetragonal I4_1/a space group. Pr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are four shorter (2.45 Å) and four longer (2.53 Å) Pr(1)-O(1) bond lengths. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. There are two shorter (2.00 Å) and two longer (2.01 Å) Pd(1)-O(1) bond lengths. O(1) is bonded to two equivalent Pr(1) and two equivalent Pd(1) atoms to form a mixture of corner and edge-sharing OPr2Pd2 tetrahedra.