Sr3LaTi2Mn2O12 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(11), one O(12), one O(14), one O(15), one O(17), one O(20), one O(21), one O(24), one O(7), one O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent La(2)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Ti(1)O6 octahedra, and faces with two equivalent Ti(3)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(11), one O(12), one O(13), one O(16), one O(18), one O(19), one O(22), one O(23), one O(7), one O(8), and two equivalent O(10) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(6)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(10), one O(12), one O(13), one O(14), one O(23), one O(24), one O(3), one O(5), one O(8), and two equivalent O(19) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(3)O12 cuboctahedra, corners with two equivalent Sr(6)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Ti(1)O6 octahedra, and faces with two equivalent Mn(4)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(11), one O(13), one O(14), one O(2), one O(23), one O(24), one O(4), one O(6), one O(7), one O(9), and two equivalent O(20) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(4)O12 cuboctahedra, corners with two equivalent Sr(5)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(6)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent Mn(2)O6 octahedra. In the fifth Sr site, Sr(5) is bonded to one O(1), one O(12), one O(15), one O(16), one O(21), one O(22), one O(4), one O(5), one O(8), one O(9), and two equivalent O(17) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(4)O12 cuboctahedra, corners with two equivalent Sr(5)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(6)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Ti(4)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the sixth Sr site, Sr(6) is bonded to one O(10), one O(11), one O(15), one O(16), one O(2), one O(21), one O(22), one O(3), one O(6), one O(7), and two equivalent O(18) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(3)O12 cuboctahedra, corners with two equivalent Sr(6)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Mn(1)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(14), one O(15), one O(18), one O(19), one O(2), one O(21), one O(24), one O(5), one O(6), and two equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(6)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(13), one O(16), one O(17), one O(2), one O(20), one O(22), one O(23), one O(5), one O(6), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent La(2)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(4)O6 octahedra. There are four inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(12), one O(14), one O(19), one O(24), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Ti site, Ti(2) is bonded to one O(10), one O(11), one O(13), one O(20), one O(23), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third Ti site, Ti(3) is bonded to one O(11), one O(15), one O(18), one O(21), one O(7), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(6)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fourth Ti site, Ti(4) is bonded to one O(10), one O(12), one O(16), one O(17), one O(22), and one O(8) atom to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(16), one O(18), one O(2), one O(22), one O(4), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(6)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Mn site, Mn(2) is bonded to one O(14), one O(2), one O(20), one O(24), one O(3), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third Mn site, Mn(3) is bonded to one O(1), one O(15), one O(17), one O(21), one O(3), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Ti(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(13), one O(19), one O(23), one O(4), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(3), one Sr(5), one La(1), one La(2), one Mn(3), and one Mn(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(4), one Sr(6), one La(1), one La(2), one Mn(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(3), one Sr(6), two equivalent La(1), one Mn(2), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(4), one Sr(5), two equivalent La(2), one Mn(1), and one Mn(4) atom. In the fifth O site, O(5) is bonded to one Sr(3), one Sr(5), one La(1), one La(2), one Mn(3), and one Mn(4) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(21)Sr3LaTiMn octahedra,  a cornercorner with one O(23)Sr3LaTiMn octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth O site, O(6) is bonded to one Sr(4), one Sr(6), one La(1), one La(2), one Mn(1), and one Mn(2) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(22)Sr3LaTiMn octahedra,  a cornercorner with one O(24)Sr3LaTiMn octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(11)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(6), one Ti(2), and one Ti(3) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(5), one Ti(1), and one Ti(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sr(4), one Sr(5), two equivalent Sr(1), one Ti(1), and one Ti(3) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sr(3), one Sr(6), two equivalent Sr(2), one Ti(2), and one Ti(4) atom. In the eleventh O site, O(11) is bonded to one Sr(1), one Sr(2), one Sr(4), one Sr(6), one Ti(2), and one Ti(3) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(21)Sr3LaTiMn octahedra,  a cornercorner with one O(23)Sr3LaTiMn octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the twelfth O site, O(12) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(5), one Ti(1), and one Ti(4) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(22)Sr3LaTiMn octahedra,  a cornercorner with one O(24)Sr3LaTiMn octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(11)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sr(2), one Sr(3), one Sr(4), one La(2), one Ti(2), and one Mn(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one La(1), one Ti(1), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to one Sr(1), one Sr(5), one Sr(6), one La(1), one Ti(3), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a distorted linear geometry to one Sr(2), one Sr(5), one Sr(6), one La(2), one Ti(4), and one Mn(1) atom. In the seventeenth O site, O(17) is bonded in a distorted linear geometry to one Sr(1), two equivalent Sr(5), one La(2), one Ti(4), and one Mn(3) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one Sr(2), two equivalent Sr(6), one La(1), one Ti(3), and one Mn(1) atom. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Sr(2), two equivalent Sr(3), one La(1), one Ti(1), and one Mn(4) atom. In the twentieth O site, O(20) is bonded in a distorted linear geometry to one Sr(1), two equivalent Sr(4), one La(2), one Ti(2), and one Mn(2) atom. In the twenty-first O site, O(21) is bonded to one Sr(1), one Sr(5), one Sr(6), one La(1), one Ti(3), and one Mn(3) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(11)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr3LaTiMn octahedra, corners with two equivalent O(24)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the twenty-second O site, O(22) is bonded to one Sr(2), one Sr(5), one Sr(6), one La(2), one Ti(4), and one Mn(1) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(12)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr3LaTiMn octahedra, corners with two equivalent O(23)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the twenty-third O site, O(23) is bonded to one Sr(2), one Sr(3), one Sr(4), one La(2), one Ti(2), and one Mn(4) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(11)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr3LaTiMn octahedra, corners with two equivalent O(24)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the twenty-fourth O site, O(24) is bonded to one Sr(1), one Sr(3), one Sr(4), one La(1), one Ti(1), and one Mn(2) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(12)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr3LaTiMn octahedra, corners with two equivalent O(23)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°.
Sr3LaTi2Mn2O12 is (Cubic) Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(11), one O(12), one O(14), one O(15), one O(17), one O(20), one O(21), one O(24), one O(7), one O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent La(2)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Ti(1)O6 octahedra, and faces with two equivalent Ti(3)O6 octahedra. The Sr(1)-O(11) bond length is 2.76 Å. The Sr(1)-O(12) bond length is 2.76 Å. The Sr(1)-O(14) bond length is 2.84 Å. The Sr(1)-O(15) bond length is 2.83 Å. The Sr(1)-O(17) bond length is 2.80 Å. The Sr(1)-O(20) bond length is 2.80 Å. The Sr(1)-O(21) bond length is 2.85 Å. The Sr(1)-O(24) bond length is 2.84 Å. The Sr(1)-O(7) bond length is 2.79 Å. The Sr(1)-O(8) bond length is 2.78 Å. There is one shorter (2.79 Å) and one longer (2.80 Å) Sr(1)-O(9) bond length. In the second Sr site, Sr(2) is bonded to one O(11), one O(12), one O(13), one O(16), one O(18), one O(19), one O(22), one O(23), one O(7), one O(8), and two equivalent O(10) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(6)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. The Sr(2)-O(11) bond length is 2.76 Å. The Sr(2)-O(12) bond length is 2.76 Å. The Sr(2)-O(13) bond length is 2.83 Å. The Sr(2)-O(16) bond length is 2.84 Å. The Sr(2)-O(18) bond length is 2.80 Å. The Sr(2)-O(19) bond length is 2.80 Å. The Sr(2)-O(22) bond length is 2.84 Å. The Sr(2)-O(23) bond length is 2.85 Å. The Sr(2)-O(7) bond length is 2.79 Å. The Sr(2)-O(8) bond length is 2.78 Å. There is one shorter (2.79 Å) and one longer (2.80 Å) Sr(2)-O(10) bond length. In the third Sr site, Sr(3) is bonded to one O(1), one O(10), one O(12), one O(13), one O(14), one O(23), one O(24), one O(3), one O(5), one O(8), and two equivalent O(19) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(3)O12 cuboctahedra, corners with two equivalent Sr(6)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Ti(1)O6 octahedra, and faces with two equivalent Mn(4)O6 octahedra. The Sr(3)-O(1) bond length is 2.75 Å. The Sr(3)-O(10) bond length is 2.81 Å. The Sr(3)-O(12) bond length is 2.78 Å. The Sr(3)-O(13) bond length is 2.82 Å. The Sr(3)-O(14) bond length is 2.76 Å. The Sr(3)-O(23) bond length is 2.76 Å. The Sr(3)-O(24) bond length is 2.75 Å. The Sr(3)-O(3) bond length is 2.76 Å. The Sr(3)-O(5) bond length is 2.74 Å. The Sr(3)-O(8) bond length is 2.81 Å. There is one shorter (2.77 Å) and one longer (2.81 Å) Sr(3)-O(19) bond length. In the fourth Sr site, Sr(4) is bonded to one O(11), one O(13), one O(14), one O(2), one O(23), one O(24), one O(4), one O(6), one O(7), one O(9), and two equivalent O(20) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(4)O12 cuboctahedra, corners with two equivalent Sr(5)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(6)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent Mn(2)O6 octahedra. The Sr(4)-O(11) bond length is 2.78 Å. The Sr(4)-O(13) bond length is 2.75 Å. The Sr(4)-O(14) bond length is 2.81 Å. The Sr(4)-O(2) bond length is 2.75 Å. The Sr(4)-O(23) bond length is 2.75 Å. The Sr(4)-O(24) bond length is 2.77 Å. The Sr(4)-O(4) bond length is 2.76 Å. The Sr(4)-O(6) bond length is 2.74 Å. The Sr(4)-O(7) bond length is 2.81 Å. The Sr(4)-O(9) bond length is 2.81 Å. There is one shorter (2.77 Å) and one longer (2.81 Å) Sr(4)-O(20) bond length. In the fifth Sr site, Sr(5) is bonded to one O(1), one O(12), one O(15), one O(16), one O(21), one O(22), one O(4), one O(5), one O(8), one O(9), and two equivalent O(17) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(4)O12 cuboctahedra, corners with two equivalent Sr(5)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Sr(6)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Ti(4)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. The Sr(5)-O(1) bond length is 2.75 Å. The Sr(5)-O(12) bond length is 2.78 Å. The Sr(5)-O(15) bond length is 2.82 Å. The Sr(5)-O(16) bond length is 2.76 Å. The Sr(5)-O(21) bond length is 2.76 Å. The Sr(5)-O(22) bond length is 2.75 Å. The Sr(5)-O(4) bond length is 2.76 Å. The Sr(5)-O(5) bond length is 2.74 Å. The Sr(5)-O(8) bond length is 2.81 Å. The Sr(5)-O(9) bond length is 2.81 Å. There is one shorter (2.77 Å) and one longer (2.81 Å) Sr(5)-O(17) bond length. In the sixth Sr site, Sr(6) is bonded to one O(10), one O(11), one O(15), one O(16), one O(2), one O(21), one O(22), one O(3), one O(6), one O(7), and two equivalent O(18) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(3)O12 cuboctahedra, corners with two equivalent Sr(6)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Sr(5)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Mn(1)O6 octahedra. The Sr(6)-O(10) bond length is 2.81 Å. The Sr(6)-O(11) bond length is 2.78 Å. The Sr(6)-O(15) bond length is 2.75 Å. The Sr(6)-O(16) bond length is 2.81 Å. The Sr(6)-O(2) bond length is 2.75 Å. The Sr(6)-O(21) bond length is 2.75 Å. The Sr(6)-O(22) bond length is 2.77 Å. The Sr(6)-O(3) bond length is 2.76 Å. The Sr(6)-O(6) bond length is 2.74 Å. The Sr(6)-O(7) bond length is 2.81 Å. There is one shorter (2.77 Å) and one longer (2.81 Å) Sr(6)-O(18) bond length. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(14), one O(15), one O(18), one O(19), one O(2), one O(21), one O(24), one O(5), one O(6), and two equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with two equivalent Sr(2)O12 cuboctahedra, corners with two equivalent La(1)O12 cuboctahedra, corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(6)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Ti(3)O6 octahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one Mn(4)O6 octahedra, faces with two equivalent Mn(2)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. The La(1)-O(1) bond length is 2.78 Å. The La(1)-O(14) bond length is 2.72 Å. The La(1)-O(15) bond length is 2.73 Å. The La(1)-O(18) bond length is 2.77 Å. The La(1)-O(19) bond length is 2.77 Å. The La(1)-O(2) bond length is 2.79 Å. The La(1)-O(21) bond length is 2.67 Å. The La(1)-O(24) bond length is 2.68 Å. The La(1)-O(5) bond length is 2.76 Å. The La(1)-O(6) bond length is 2.76 Å. There is one shorter (2.79 Å) and one longer (2.80 Å) La(1)-O(3) bond length. In the second La site, La(2) is bonded to one O(1), one O(13), one O(16), one O(17), one O(2), one O(20), one O(22), one O(23), one O(5), one O(6), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with two equivalent Sr(1)O12 cuboctahedra, corners with two equivalent La(2)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra,  a faceface with one Ti(2)O6 octahedra,  a faceface with one Ti(4)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(4)O6 octahedra. The La(2)-O(1) bond length is 2.78 Å. The La(2)-O(13) bond length is 2.73 Å. The La(2)-O(16) bond length is 2.72 Å. The La(2)-O(17) bond length is 2.77 Å. The La(2)-O(2) bond length is 2.79 Å. The La(2)-O(20) bond length is 2.77 Å. The La(2)-O(22) bond length is 2.68 Å. The La(2)-O(23) bond length is 2.67 Å. The La(2)-O(5) bond length is 2.76 Å. The La(2)-O(6) bond length is 2.76 Å. There is one shorter (2.79 Å) and one longer (2.80 Å) La(2)-O(4) bond length. There are four inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(12), one O(14), one O(19), one O(24), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Ti(1)-O(12) bond length is 2.00 Å. The Ti(1)-O(14) bond length is 1.98 Å. The Ti(1)-O(19) bond length is 1.98 Å. The Ti(1)-O(24) bond length is 1.92 Å. The Ti(1)-O(8) bond length is 1.95 Å. The Ti(1)-O(9) bond length is 1.95 Å. In the second Ti site, Ti(2) is bonded to one O(10), one O(11), one O(13), one O(20), one O(23), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Ti(2)-O(10) bond length is 1.95 Å. The Ti(2)-O(11) bond length is 2.00 Å. The Ti(2)-O(13) bond length is 1.98 Å. The Ti(2)-O(20) bond length is 1.98 Å. The Ti(2)-O(23) bond length is 1.92 Å. The Ti(2)-O(7) bond length is 1.95 Å. In the third Ti site, Ti(3) is bonded to one O(11), one O(15), one O(18), one O(21), one O(7), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(6)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Ti(3)-O(11) bond length is 1.99 Å. The Ti(3)-O(15) bond length is 1.98 Å. The Ti(3)-O(18) bond length is 1.98 Å. The Ti(3)-O(21) bond length is 1.93 Å. The Ti(3)-O(7) bond length is 1.95 Å. The Ti(3)-O(9) bond length is 1.95 Å. In the fourth Ti site, Ti(4) is bonded to one O(10), one O(12), one O(16), one O(17), one O(22), and one O(8) atom to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, and faces with two equivalent Sr(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Ti(4)-O(10) bond length is 1.95 Å. The Ti(4)-O(12) bond length is 1.99 Å. The Ti(4)-O(16) bond length is 1.98 Å. The Ti(4)-O(17) bond length is 1.98 Å. The Ti(4)-O(22) bond length is 1.93 Å. The Ti(4)-O(8) bond length is 1.95 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(16), one O(18), one O(2), one O(22), one O(4), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(6)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(1)-O(16) bond length is 1.93 Å. The Mn(1)-O(18) bond length is 1.91 Å. The Mn(1)-O(2) bond length is 1.96 Å. The Mn(1)-O(22) bond length is 2.05 Å. The Mn(1)-O(4) bond length is 1.93 Å. The Mn(1)-O(6) bond length is 1.98 Å. In the second Mn site, Mn(2) is bonded to one O(14), one O(2), one O(20), one O(24), one O(3), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(2)-O(14) bond length is 1.93 Å. The Mn(2)-O(2) bond length is 1.96 Å. The Mn(2)-O(20) bond length is 1.91 Å. The Mn(2)-O(24) bond length is 2.05 Å. The Mn(2)-O(3) bond length is 1.93 Å. The Mn(2)-O(6) bond length is 1.99 Å. In the third Mn site, Mn(3) is bonded to one O(1), one O(15), one O(17), one O(21), one O(3), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Ti(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(6)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with two equivalent Sr(5)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(3)-O(1) bond length is 1.96 Å. The Mn(3)-O(15) bond length is 1.93 Å. The Mn(3)-O(17) bond length is 1.91 Å. The Mn(3)-O(21) bond length is 2.05 Å. The Mn(3)-O(3) bond length is 1.93 Å. The Mn(3)-O(5) bond length is 1.98 Å. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(13), one O(19), one O(23), one O(4), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Sr(5)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. The Mn(4)-O(1) bond length is 1.96 Å. The Mn(4)-O(13) bond length is 1.93 Å. The Mn(4)-O(19) bond length is 1.91 Å. The Mn(4)-O(23) bond length is 2.06 Å. The Mn(4)-O(4) bond length is 1.94 Å. The Mn(4)-O(5) bond length is 1.99 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(3), one Sr(5), one La(1), one La(2), one Mn(3), and one Mn(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(4), one Sr(6), one La(1), one La(2), one Mn(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(3), one Sr(6), two equivalent La(1), one Mn(2), and one Mn(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(4), one Sr(5), two equivalent La(2), one Mn(1), and one Mn(4) atom. In the fifth O site, O(5) is bonded to one Sr(3), one Sr(5), one La(1), one La(2), one Mn(3), and one Mn(4) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(21)Sr3LaTiMn octahedra,  a cornercorner with one O(23)Sr3LaTiMn octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth O site, O(6) is bonded to one Sr(4), one Sr(6), one La(1), one La(2), one Mn(1), and one Mn(2) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(22)Sr3LaTiMn octahedra,  a cornercorner with one O(24)Sr3LaTiMn octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(11)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(4), one Sr(6), one Ti(2), and one Ti(3) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(5), one Ti(1), and one Ti(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sr(4), one Sr(5), two equivalent Sr(1), one Ti(1), and one Ti(3) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sr(3), one Sr(6), two equivalent Sr(2), one Ti(2), and one Ti(4) atom. In the eleventh O site, O(11) is bonded to one Sr(1), one Sr(2), one Sr(4), one Sr(6), one Ti(2), and one Ti(3) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(21)Sr3LaTiMn octahedra,  a cornercorner with one O(23)Sr3LaTiMn octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(12)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the twelfth O site, O(12) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(5), one Ti(1), and one Ti(4) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(22)Sr3LaTiMn octahedra,  a cornercorner with one O(24)Sr3LaTiMn octahedra, corners with two equivalent O(5)Sr2La2Mn2 octahedra, corners with two equivalent O(11)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr3LaTiMn octahedra,  an edgeedge with one O(22)Sr3LaTiMn octahedra,  an edgeedge with one O(23)Sr3LaTiMn octahedra, and  an edgeedge with one O(24)Sr3LaTiMn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sr(2), one Sr(3), one Sr(4), one La(2), one Ti(2), and one Mn(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one La(1), one Ti(1), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to one Sr(1), one Sr(5), one Sr(6), one La(1), one Ti(3), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a distorted linear geometry to one Sr(2), one Sr(5), one Sr(6), one La(2), one Ti(4), and one Mn(1) atom. In the seventeenth O site, O(17) is bonded in a distorted linear geometry to one Sr(1), two equivalent Sr(5), one La(2), one Ti(4), and one Mn(3) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one Sr(2), two equivalent Sr(6), one La(1), one Ti(3), and one Mn(1) atom. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one Sr(2), two equivalent Sr(3), one La(1), one Ti(1), and one Mn(4) atom. In the twentieth O site, O(20) is bonded in a distorted linear geometry to one Sr(1), two equivalent Sr(4), one La(2), one Ti(2), and one Mn(2) atom. In the twenty-first O site, O(21) is bonded to one Sr(1), one Sr(5), one Sr(6), one La(1), one Ti(3), and one Mn(3) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(11)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr3LaTiMn octahedra, corners with two equivalent O(24)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the twenty-second O site, O(22) is bonded to one Sr(2), one Sr(5), one Sr(6), one La(2), one Ti(4), and one Mn(1) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(12)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr3LaTiMn octahedra, corners with two equivalent O(23)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the twenty-third O site, O(23) is bonded to one Sr(2), one Sr(3), one Sr(4), one La(2), one Ti(2), and one Mn(4) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(5)Sr2La2Mn2 octahedra,  a cornercorner with one O(11)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr3LaTiMn octahedra, corners with two equivalent O(24)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the twenty-fourth O site, O(24) is bonded to one Sr(1), one Sr(3), one Sr(4), one La(1), one Ti(1), and one Mn(2) atom to form distorted OSr3LaTiMn octahedra that share  a cornercorner with one O(6)Sr2La2Mn2 octahedra,  a cornercorner with one O(12)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr3LaTiMn octahedra, corners with two equivalent O(23)Sr3LaTiMn octahedra,  an edgeedge with one O(5)Sr2La2Mn2 octahedra,  an edgeedge with one O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(11)Sr4Ti2 octahedra, and  an edgeedge with one O(12)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°.