(UH14O7Cl2)2Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and one UH14O7Cl2 cluster. In the UH14O7Cl2 cluster, U(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent Cl(1) atoms. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one U(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one U(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one U(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one U(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one U(1), one H(13), and one H(14) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent U(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one H(2) atom.
(UH14O7Cl2)2Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and one UH14O7Cl2 cluster. In the UH14O7Cl2 cluster, U(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent Cl(1) atoms. The U(1)-O(1) bond length is 2.58 Å. The U(1)-O(2) bond length is 2.56 Å. The U(1)-O(3) bond length is 2.62 Å. The U(1)-O(4) bond length is 2.53 Å. The U(1)-O(5) bond length is 2.54 Å. The U(1)-O(6) bond length is 2.53 Å. The U(1)-O(7) bond length is 2.52 Å. There is one shorter (2.89 Å) and one longer (2.90 Å) U(1)-Cl(1) bond length. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Cl(2) atom. The H(2)-O(1) bond length is 1.00 Å. The H(2)-Cl(2) bond length is 2.07 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. The H(5)-O(3) bond length is 0.99 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.99 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. The H(7)-O(4) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. The H(8)-O(4) bond length is 0.98 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) atom. The H(9)-O(5) bond length is 0.98 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. The H(10)-O(5) bond length is 0.99 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. The H(11)-O(6) bond length is 0.99 Å. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. The H(12)-O(6) bond length is 0.99 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(7) atom. The H(13)-O(7) bond length is 0.98 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. The H(14)-O(7) bond length is 0.98 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one U(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one U(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one U(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one U(1), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one U(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one U(1), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one U(1), one H(13), and one H(14) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent U(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one H(2) atom.