NH5OBr is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four azane;hydrate;hydrobromide molecules. N(1) is bonded in a trigonal non-coplanar geometry to one H(3), one H(4), and one H(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. O(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. Br(1) is bonded in a distorted water-like geometry to one H(2) and one H(5) atom.
NH5OBr is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four azane;hydrate;hydrobromide molecules. N(1) is bonded in a trigonal non-coplanar geometry to one H(3), one H(4), and one H(5) atom. The N(1)-H(3) bond length is 1.07 Å. The N(1)-H(4) bond length is 1.06 Å. The N(1)-H(5) bond length is 1.07 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 1.00 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. The H(2)-O(1) bond length is 1.01 Å. The H(2)-Br(1) bond length is 2.19 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. The H(5)-Br(1) bond length is 2.18 Å. O(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. Br(1) is bonded in a distorted water-like geometry to one H(2) and one H(5) atom.