IO6 is alpha La structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four IO6 clusters. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one I(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one I(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one I(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom.
IO6 is alpha La structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four IO6 clusters. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one I(1) atom. The O(1)-I(1) bond length is 1.91 Å. In the second O site, O(2) is bonded in a single-bond geometry to one I(1) atom. The O(2)-I(1) bond length is 1.88 Å. In the third O site, O(3) is bonded in a single-bond geometry to one I(1) atom. The O(3)-I(1) bond length is 1.88 Å. In the fourth O site, O(4) is bonded in a single-bond geometry to one I(1) atom. The O(4)-I(1) bond length is 1.91 Å. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(1) atom. The O(5)-I(1) bond length is 1.90 Å. In the sixth O site, O(6) is bonded in a single-bond geometry to one I(1) atom. The O(6)-I(1) bond length is 1.89 Å. I(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom.