Li9Mn2Co5O16 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(4), one O(5), one O(8), and two equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the second Li site, Li(2) is bonded to one O(2), one O(4), one O(5), one O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the third Li site, Li(3) is bonded to one O(1), one O(5), one O(6), one O(8), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the fourth Li site, Li(4) is bonded to one O(4), one O(6), one O(7), one O(8), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the fifth Li site, Li(5) is bonded to two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the second Co site, Co(2) is bonded to one O(1), one O(3), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), two equivalent Li(1), one Mn(1), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(4)Li3MnCo2 octahedra, corners with two equivalent O(8)Li4Co2 octahedra, corners with two equivalent O(7)Li4MnCo octahedra,  an edgeedge with one O(1)Li3MnCo2 octahedra,  an edgeedge with one O(2)Li3MnCo2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, edges with two equivalent O(5)Li4MnCo octahedra, and edges with three equivalent O(3)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second O site, O(2) is bonded to one Li(2), two equivalent Li(4), one Mn(1), one Co(1), and one Co(3) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(2)Li3MnCo2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra, corners with two equivalent O(6)Li3Co3 octahedra, corners with two equivalent O(3)Li3MnCo2 octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(1)Li3MnCo2 octahedra,  an edgeedge with one O(2)Li3MnCo2 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, edges with two equivalent O(8)Li4Co2 octahedra, edges with two equivalent O(5)Li4MnCo octahedra, and edges with three equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the third O site, O(3) is bonded to one Li(1), two equivalent Li(3), one Mn(1), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(6)Li3Co3 octahedra,  a cornercorner with one O(1)Li3MnCo2 octahedra, corners with two equivalent O(2)Li3MnCo2 octahedra, corners with two equivalent O(5)Li4MnCo octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, edges with two equivalent O(8)Li4Co2 octahedra, and edges with three equivalent O(1)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), one Mn(1), and two equivalent Co(2) atoms to form OLi3MnCo2 octahedra that share  a cornercorner with one O(1)Li3MnCo2 octahedra,  a cornercorner with one O(5)Li4MnCo octahedra, corners with two equivalent O(6)Li3Co3 octahedra, corners with two equivalent O(7)Li4MnCo octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(5)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(1)Li3MnCo2 octahedra, edges with two equivalent O(2)Li3MnCo2 octahedra, and edges with two equivalent O(3)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one Mn(1), and one Co(3) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(4)Li3MnCo2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra, corners with two equivalent O(3)Li3MnCo2 octahedra, corners with two equivalent O(5)Li4MnCo octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra, edges with two equivalent O(1)Li3MnCo2 octahedra, edges with two equivalent O(2)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4MnCo octahedra, and edges with three equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(4), one Co(1), and two equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra, corners with two equivalent O(2)Li3MnCo2 octahedra, corners with two equivalent O(4)Li3MnCo2 octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(2)Li3MnCo2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(5)Li4MnCo octahedra, edges with two equivalent O(1)Li3MnCo2 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh O site, O(7) is bonded to one Li(4), one Li(5), two equivalent Li(2), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(5)Li4MnCo octahedra,  a cornercorner with one O(7)Li4MnCo octahedra, corners with two equivalent O(1)Li3MnCo2 octahedra, corners with two equivalent O(4)Li3MnCo2 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(8)Li4Co2 octahedra, edges with two equivalent O(5)Li4MnCo octahedra, and edges with three equivalent O(2)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Co(1), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(6)Li3Co3 octahedra,  a cornercorner with one O(2)Li3MnCo2 octahedra, corners with two equivalent O(1)Li3MnCo2 octahedra, corners with two equivalent O(8)Li4Co2 octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(1)Li3MnCo2 octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra, edges with two equivalent O(2)Li3MnCo2 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4MnCo octahedra, and edges with three equivalent O(5)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-9°.
Li9Mn2Co5O16 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(4), one O(5), one O(8), and two equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. The Li(1)-O(3) bond length is 2.16 Å. The Li(1)-O(4) bond length is 2.11 Å. The Li(1)-O(5) bond length is 2.00 Å. The Li(1)-O(8) bond length is 2.12 Å. There is one shorter (2.14 Å) and one longer (2.17 Å) Li(1)-O(1) bond length. In the second Li site, Li(2) is bonded to one O(2), one O(4), one O(5), one O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. The Li(2)-O(2) bond length is 2.36 Å. The Li(2)-O(4) bond length is 2.23 Å. The Li(2)-O(5) bond length is 2.09 Å. The Li(2)-O(6) bond length is 2.13 Å. There is one shorter (2.05 Å) and one longer (2.08 Å) Li(2)-O(7) bond length. In the third Li site, Li(3) is bonded to one O(1), one O(5), one O(6), one O(8), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. The Li(3)-O(1) bond length is 2.13 Å. The Li(3)-O(5) bond length is 2.05 Å. The Li(3)-O(6) bond length is 2.11 Å. The Li(3)-O(8) bond length is 2.15 Å. There is one shorter (2.12 Å) and one longer (2.43 Å) Li(3)-O(3) bond length. In the fourth Li site, Li(4) is bonded to one O(4), one O(6), one O(7), one O(8), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with three equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. The Li(4)-O(4) bond length is 2.17 Å. The Li(4)-O(6) bond length is 2.13 Å. The Li(4)-O(7) bond length is 2.08 Å. The Li(4)-O(8) bond length is 2.14 Å. There is one shorter (2.11 Å) and one longer (2.15 Å) Li(4)-O(2) bond length. In the fifth Li site, Li(5) is bonded to two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-10°. Both Li(5)-O(5) bond lengths are 2.03 Å. Both Li(5)-O(7) bond lengths are 2.06 Å. Both Li(5)-O(8) bond lengths are 2.19 Å. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. The Mn(1)-O(1) bond length is 1.98 Å. The Mn(1)-O(2) bond length is 1.96 Å. The Mn(1)-O(3) bond length is 1.99 Å. The Mn(1)-O(4) bond length is 1.98 Å. The Mn(1)-O(5) bond length is 1.88 Å. The Mn(1)-O(7) bond length is 1.89 Å. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. The Co(1)-O(1) bond length is 2.19 Å. The Co(1)-O(2) bond length is 1.97 Å. The Co(1)-O(3) bond length is 1.97 Å. The Co(1)-O(6) bond length is 1.93 Å. The Co(1)-O(7) bond length is 2.12 Å. The Co(1)-O(8) bond length is 1.88 Å. In the second Co site, Co(2) is bonded to one O(1), one O(3), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. The Co(2)-O(1) bond length is 1.91 Å. The Co(2)-O(3) bond length is 1.96 Å. There is one shorter (1.91 Å) and one longer (2.17 Å) Co(2)-O(4) bond length. There is one shorter (1.92 Å) and one longer (2.17 Å) Co(2)-O(6) bond length. In the third Co site, Co(3) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. Both Co(3)-O(2) bond lengths are 1.96 Å. Both Co(3)-O(5) bond lengths are 2.16 Å. Both Co(3)-O(8) bond lengths are 1.91 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), two equivalent Li(1), one Mn(1), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(4)Li3MnCo2 octahedra, corners with two equivalent O(8)Li4Co2 octahedra, corners with two equivalent O(7)Li4MnCo octahedra,  an edgeedge with one O(1)Li3MnCo2 octahedra,  an edgeedge with one O(2)Li3MnCo2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, edges with two equivalent O(5)Li4MnCo octahedra, and edges with three equivalent O(3)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the second O site, O(2) is bonded to one Li(2), two equivalent Li(4), one Mn(1), one Co(1), and one Co(3) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(2)Li3MnCo2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra, corners with two equivalent O(6)Li3Co3 octahedra, corners with two equivalent O(3)Li3MnCo2 octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(1)Li3MnCo2 octahedra,  an edgeedge with one O(2)Li3MnCo2 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, edges with two equivalent O(8)Li4Co2 octahedra, edges with two equivalent O(5)Li4MnCo octahedra, and edges with three equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the third O site, O(3) is bonded to one Li(1), two equivalent Li(3), one Mn(1), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share  a cornercorner with one O(6)Li3Co3 octahedra,  a cornercorner with one O(1)Li3MnCo2 octahedra, corners with two equivalent O(2)Li3MnCo2 octahedra, corners with two equivalent O(5)Li4MnCo octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, edges with two equivalent O(8)Li4Co2 octahedra, and edges with three equivalent O(1)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(4), one Mn(1), and two equivalent Co(2) atoms to form OLi3MnCo2 octahedra that share  a cornercorner with one O(1)Li3MnCo2 octahedra,  a cornercorner with one O(5)Li4MnCo octahedra, corners with two equivalent O(6)Li3Co3 octahedra, corners with two equivalent O(7)Li4MnCo octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(5)Li4MnCo octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(1)Li3MnCo2 octahedra, edges with two equivalent O(2)Li3MnCo2 octahedra, and edges with two equivalent O(3)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one Mn(1), and one Co(3) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(4)Li3MnCo2 octahedra,  a cornercorner with one O(7)Li4MnCo octahedra, corners with two equivalent O(3)Li3MnCo2 octahedra, corners with two equivalent O(5)Li4MnCo octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra, edges with two equivalent O(1)Li3MnCo2 octahedra, edges with two equivalent O(2)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4MnCo octahedra, and edges with three equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(4), one Co(1), and two equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(3)Li3MnCo2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra, corners with two equivalent O(2)Li3MnCo2 octahedra, corners with two equivalent O(4)Li3MnCo2 octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(2)Li3MnCo2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra,  an edgeedge with one O(5)Li4MnCo octahedra, edges with two equivalent O(1)Li3MnCo2 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(4)Li3MnCo2 octahedra, and edges with two equivalent O(7)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh O site, O(7) is bonded to one Li(4), one Li(5), two equivalent Li(2), one Mn(1), and one Co(1) atom to form OLi4MnCo octahedra that share  a cornercorner with one O(5)Li4MnCo octahedra,  a cornercorner with one O(7)Li4MnCo octahedra, corners with two equivalent O(1)Li3MnCo2 octahedra, corners with two equivalent O(4)Li3MnCo2 octahedra,  an edgeedge with one O(3)Li3MnCo2 octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li4MnCo octahedra, edges with two equivalent O(6)Li3Co3 octahedra, edges with two equivalent O(8)Li4Co2 octahedra, edges with two equivalent O(5)Li4MnCo octahedra, and edges with three equivalent O(2)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Co(1), and one Co(3) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(6)Li3Co3 octahedra,  a cornercorner with one O(2)Li3MnCo2 octahedra, corners with two equivalent O(1)Li3MnCo2 octahedra, corners with two equivalent O(8)Li4Co2 octahedra,  an edgeedge with one O(6)Li3Co3 octahedra,  an edgeedge with one O(1)Li3MnCo2 octahedra,  an edgeedge with one O(4)Li3MnCo2 octahedra, edges with two equivalent O(2)Li3MnCo2 octahedra, edges with two equivalent O(3)Li3MnCo2 octahedra, edges with two equivalent O(7)Li4MnCo octahedra, and edges with three equivalent O(5)Li4MnCo octahedra. The corner-sharing octahedral tilt angles range from 0-9°.