KWF6(NH4)2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonium molecules inside a KWF6 framework. In the KWF6 framework, K(1) is bonded to six equivalent F(1) atoms to form KF6 octahedra that share corners with six equivalent W(1)F6 octahedra. The corner-sharing octahedra are not tilted. W(1) is bonded to six equivalent F(1) atoms to form WF6 octahedra that share corners with six equivalent K(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one K(1) and one W(1) atom.
KWF6(NH4)2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonium molecules inside a KWF6 framework. In the KWF6 framework, K(1) is bonded to six equivalent F(1) atoms to form KF6 octahedra that share corners with six equivalent W(1)F6 octahedra. The corner-sharing octahedra are not tilted. All K(1)-F(1) bond lengths are 2.56 Å. W(1) is bonded to six equivalent F(1) atoms to form WF6 octahedra that share corners with six equivalent K(1)F6 octahedra. The corner-sharing octahedra are not tilted. All W(1)-F(1) bond lengths are 2.10 Å. F(1) is bonded in a linear geometry to one K(1) and one W(1) atom.