SrMgLaRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Sr(1) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-27°. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one O(6), two equivalent O(2), and two equivalent O(4) atoms. Ru(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form RuO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-27°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Sr(1), one Mg(1), two equivalent La(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(1), and one Ru(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Sr(1), one Mg(1), two equivalent La(1), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(1), and one Ru(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(1), and one Ru(1) atom.
SrMgLaRuO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Sr(1) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. The Sr(1)-O(2) bond length is 2.55 Å. The Sr(1)-O(4) bond length is 2.53 Å. The Sr(1)-O(6) bond length is 2.48 Å. There is one shorter (2.70 Å) and one longer (2.87 Å) Sr(1)-O(1) bond length. There is one shorter (2.73 Å) and one longer (2.83 Å) Sr(1)-O(3) bond length. There is one shorter (2.68 Å) and one longer (3.06 Å) Sr(1)-O(5) bond length. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-27°. The Mg(1)-O(1) bond length is 2.08 Å. The Mg(1)-O(2) bond length is 2.09 Å. The Mg(1)-O(3) bond length is 2.09 Å. The Mg(1)-O(4) bond length is 2.08 Å. The Mg(1)-O(5) bond length is 2.09 Å. The Mg(1)-O(6) bond length is 2.08 Å. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one O(6), two equivalent O(2), and two equivalent O(4) atoms. The La(1)-O(1) bond length is 2.46 Å. The La(1)-O(3) bond length is 2.46 Å. The La(1)-O(5) bond length is 2.42 Å. The La(1)-O(6) bond length is 2.58 Å. There is one shorter (2.61 Å) and one longer (2.89 Å) La(1)-O(2) bond length. There is one shorter (2.60 Å) and one longer (2.89 Å) La(1)-O(4) bond length. Ru(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form RuO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-27°. The Ru(1)-O(1) bond length is 1.99 Å. The Ru(1)-O(2) bond length is 1.98 Å. The Ru(1)-O(3) bond length is 1.99 Å. The Ru(1)-O(4) bond length is 1.99 Å. The Ru(1)-O(5) bond length is 2.00 Å. The Ru(1)-O(6) bond length is 1.97 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Sr(1), one Mg(1), two equivalent La(1), and one Ru(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(1), and one Ru(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Sr(1), one Mg(1), two equivalent La(1), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(1), and one Ru(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(1), and one Ru(1) atom.