FeTiP crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Fe(1) and five equivalent P(1) atoms. Fe(1) is bonded to six equivalent Ti(1) and four equivalent P(1) atoms to form a mixture of distorted corner, edge, and face-sharing FeTi6P4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Fe(1) atoms.
FeTiP crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Fe(1) and five equivalent P(1) atoms. There are a spread of Ti(1)-Fe(1) bond distances ranging from 2.71-2.79 Å. There are two shorter (2.55 Å) and three longer (2.56 Å) Ti(1)-P(1) bond lengths. Fe(1) is bonded to six equivalent Ti(1) and four equivalent P(1) atoms to form a mixture of distorted corner, edge, and face-sharing FeTi6P4 tetrahedra. There are a spread of Fe(1)-P(1) bond distances ranging from 2.24-2.30 Å. P(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Fe(1) atoms.