TiZnF5 crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing TiF6 octahedra. The corner-sharing octahedral tilt angles are 37°. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ti(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Ti(1) atoms.
TiZnF5 crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing TiF6 octahedra. The corner-sharing octahedral tilt angles are 37°. The Ti(1)-F(1) bond length is 2.01 Å. The Ti(1)-F(2) bond length is 1.97 Å. The Ti(1)-F(3) bond length is 1.95 Å. The Ti(1)-F(4) bond length is 1.99 Å. Both Ti(1)-F(5) bond lengths are 2.00 Å. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. The Zn(1)-F(1) bond length is 2.04 Å. The Zn(1)-F(2) bond length is 2.08 Å. The Zn(1)-F(3) bond length is 1.96 Å. The Zn(1)-F(4) bond length is 1.94 Å. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ti(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ti(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Ti(1) atoms.