HfSO is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Hf(1) is bonded in a 9-coordinate geometry to five equivalent S(1) and four equivalent O(1) atoms. S(1) is bonded in a 5-coordinate geometry to five equivalent Hf(1) atoms. O(1) is bonded to four equivalent Hf(1) atoms to form a mixture of corner and edge-sharing OHf4 tetrahedra.
HfSO is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Hf(1) is bonded in a 9-coordinate geometry to five equivalent S(1) and four equivalent O(1) atoms. There is one shorter (2.74 Å) and four longer (2.77 Å) Hf(1)-S(1) bond lengths. All Hf(1)-O(1) bond lengths are 2.18 Å. S(1) is bonded in a 5-coordinate geometry to five equivalent Hf(1) atoms. O(1) is bonded to four equivalent Hf(1) atoms to form a mixture of corner and edge-sharing OHf4 tetrahedra.