NdV2O2 crystallizes in the tetragonal I4_1/amd space group. Nd(1) is bonded in a linear geometry to two equivalent O(1) atoms. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Nd(1) and three equivalent V(1) atoms.
NdV2O2 crystallizes in the tetragonal I4_1/amd space group. Nd(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Nd(1)-O(1) bond lengths are 2.28 Å. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. There is one shorter (2.03 Å) and two longer (2.34 Å) V(1)-O(1) bond lengths. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Nd(1) and three equivalent V(1) atoms.