La2ZnTiO6 crystallizes in the trigonal R-3 space group. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 26°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 26°. O(1) is bonded in a 3-coordinate geometry to three equivalent La(1), one Ti(1), and one Zn(1) atom.
La2ZnTiO6 crystallizes in the trigonal R-3 space group. La(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. There are a spread of La(1)-O(1) bond distances ranging from 2.38-2.86 Å. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 26°. All Ti(1)-O(1) bond lengths are 1.97 Å. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 26°. All Zn(1)-O(1) bond lengths are 2.11 Å. O(1) is bonded in a 3-coordinate geometry to three equivalent La(1), one Ti(1), and one Zn(1) atom.