LiCu(HO)4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Cu(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Li(1), one Cu(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Li(1), one Cu(1), and one H(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Cu(1), and one H(3) atom.
LiCu(HO)4 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Li(1)-O(1) bond length is 2.03 Å. The Li(1)-O(2) bond length is 2.00 Å. The Li(1)-O(3) bond length is 2.13 Å. The Li(1)-O(4) bond length is 2.04 Å. Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 1.84 Å. The Cu(1)-O(2) bond length is 1.85 Å. The Cu(1)-O(3) bond length is 1.84 Å. The Cu(1)-O(4) bond length is 1.87 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.97 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. The H(3)-O(4) bond length is 0.99 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. The H(4)-O(3) bond length is 0.99 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Cu(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Li(1), one Cu(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Li(1), one Cu(1), and one H(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Cu(1), and one H(3) atom.