LiTiO2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with eight equivalent Ti(1)O6 octahedra. The corner-sharing octahedra are not tilted. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, edges with four equivalent Ti(1)O6 octahedra, and edges with eight equivalent Li(1)O6 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of corner and edge-sharing OLi3Ti3 octahedra. The corner-sharing octahedra are not tilted.
LiTiO2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with eight equivalent Ti(1)O6 octahedra. The corner-sharing octahedra are not tilted. There are four shorter (2.02 Å) and two longer (2.11 Å) Li(1)-O(1) bond lengths. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, edges with four equivalent Ti(1)O6 octahedra, and edges with eight equivalent Li(1)O6 octahedra. The corner-sharing octahedra are not tilted. There are four shorter (2.02 Å) and two longer (2.10 Å) Ti(1)-O(1) bond lengths. O(1) is bonded to three equivalent Li(1) and three equivalent Ti(1) atoms to form a mixture of corner and edge-sharing OLi3Ti3 octahedra. The corner-sharing octahedra are not tilted.