AgBiO2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Bi(1) is bonded in a 5-coordinate geometry to two equivalent O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(2) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OAgBi3 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ag(1) and two equivalent Bi(1) atoms.
AgBiO2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. Both Ag(1)-O(2) bond lengths are 2.09 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(2)-O(1) bond lengths are 2.08 Å. Bi(1) is bonded in a 5-coordinate geometry to two equivalent O(2) and three equivalent O(1) atoms. Both Bi(1)-O(2) bond lengths are 2.30 Å. There is one shorter (2.20 Å) and two longer (2.47 Å) Bi(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(2) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OAgBi3 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ag(1) and two equivalent Bi(1) atoms.