AgClO4 crystallizes in the tetragonal I-42m space group. Ag(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. O(1) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms.
AgClO4 crystallizes in the tetragonal I-42m space group. Ag(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are four shorter (2.46 Å) and four longer (2.77 Å) Ag(1)-O(1) bond lengths. O(1) is bonded in a 2-coordinate geometry to two equivalent Ag(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.45 Å. Cl(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms.