Tm2I2F is Cyanogen Chloride-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Tm2I2F cluster. Tm(1) is bonded in a distorted linear geometry to one I(1) and one F(1) atom. I(1) is bonded in a single-bond geometry to one Tm(1) atom. F(1) is bonded in a linear geometry to two equivalent Tm(1) atoms.
Tm2I2F is Cyanogen Chloride-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one Tm2I2F cluster. Tm(1) is bonded in a distorted linear geometry to one I(1) and one F(1) atom. The Tm(1)-I(1) bond length is 2.74 Å. The Tm(1)-F(1) bond length is 2.15 Å. I(1) is bonded in a single-bond geometry to one Tm(1) atom. F(1) is bonded in a linear geometry to two equivalent Tm(1) atoms.