N4Te2S4Cl3TeS2(NCl)2AsF5AsF6N2TeS2ClF is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one AsF5 cluster, one AsF6 cluster, one N2TeS2ClF cluster, one N4Te2S4Cl3 cluster, and one TeS2(NCl)2 cluster. In the AsF5 cluster, As(1) is bonded in a trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the AsF6 cluster, As(2) is bonded in an octahedral geometry to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one As(2) atom. In the third F site, F(8) is bonded in a single-bond geometry to one As(2) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one As(2) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one As(2) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(2) atom. In the N2TeS2ClF cluster, there are two inequivalent N sites. In the first N site, N(6) is bonded in a bent 120 degrees geometry to one Te(4) and one S(7) atom. In the second N site, N(8) is bonded in a bent 120 degrees geometry to one S(1) and one S(7) atom. Te(4) is bonded in a 4-coordinate geometry to one N(6), one S(1), one Cl(1), and one F(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(8) and one Te(4) atom. In the second S site, S(7) is bonded in a bent 120 degrees geometry to one N(6) and one N(8) atom. Cl(1) is bonded in a single-bond geometry to one Te(4) atom. F(12) is bonded in a single-bond geometry to one Te(4) atom. In the N4Te2S4Cl3 cluster, there are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(8) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(4) and one S(6) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one Te(1) and one S(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Te(3) and one S(4) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one N(3), one S(8), one Cl(5), and one Cl(6) atom. In the second Te site, Te(3) is bonded in a 4-coordinate geometry to one N(4), one S(6), one Cl(4), and one Cl(5) atom. There are four inequivalent S sites. In the first S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one N(2) and one N(4) atom. In the third S site, S(6) is bonded in a water-like geometry to one N(2) and one Te(3) atom. In the fourth S site, S(8) is bonded in a distorted water-like geometry to one N(1) and one Te(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Te(3) atom. In the second Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one Te(3) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Te(1) atom. In the TeS2(NCl)2 cluster, there are two inequivalent N sites. In the first N site, N(5) is bonded in a bent 120 degrees geometry to one Te(2) and one S(5) atom. In the second N site, N(7) is bonded in a bent 120 degrees geometry to one S(3) and one S(5) atom. Te(2) is bonded in a 4-coordinate geometry to one N(5), one S(3), one Cl(2), and one Cl(3) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one N(7) and one Te(2) atom. In the second S site, S(5) is bonded in a bent 120 degrees geometry to one N(5) and one N(7) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Te(2) atom.
N4Te2S4Cl3TeS2(NCl)2AsF5AsF6N2TeS2ClF is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one AsF5 cluster, one AsF6 cluster, one N2TeS2ClF cluster, one N4Te2S4Cl3 cluster, and one TeS2(NCl)2 cluster. In the AsF5 cluster, As(1) is bonded in a trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. The As(1)-F(1) bond length is 1.73 Å. The As(1)-F(2) bond length is 1.74 Å. The As(1)-F(3) bond length is 1.74 Å. The As(1)-F(4) bond length is 1.73 Å. The As(1)-F(5) bond length is 1.72 Å. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the AsF6 cluster, As(2) is bonded in an octahedral geometry to one F(10), one F(11), one F(6), one F(7), one F(8), and one F(9) atom. The As(2)-F(10) bond length is 1.77 Å. The As(2)-F(11) bond length is 1.77 Å. The As(2)-F(6) bond length is 1.79 Å. The As(2)-F(7) bond length is 1.78 Å. The As(2)-F(8) bond length is 1.79 Å. The As(2)-F(9) bond length is 1.78 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one As(2) atom. In the third F site, F(8) is bonded in a single-bond geometry to one As(2) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one As(2) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one As(2) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(2) atom. In the N2TeS2ClF cluster, there are two inequivalent N sites. In the first N site, N(6) is bonded in a bent 120 degrees geometry to one Te(4) and one S(7) atom. The N(6)-Te(4) bond length is 2.02 Å. The N(6)-S(7) bond length is 1.56 Å. In the second N site, N(8) is bonded in a bent 120 degrees geometry to one S(1) and one S(7) atom. The N(8)-S(1) bond length is 1.63 Å. The N(8)-S(7) bond length is 1.58 Å. Te(4) is bonded in a 4-coordinate geometry to one N(6), one S(1), one Cl(1), and one F(12) atom. The Te(4)-S(1) bond length is 2.52 Å. The Te(4)-Cl(1) bond length is 2.56 Å. The Te(4)-F(12) bond length is 2.00 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one N(8) and one Te(4) atom. In the second S site, S(7) is bonded in a bent 120 degrees geometry to one N(6) and one N(8) atom. Cl(1) is bonded in a single-bond geometry to one Te(4) atom. F(12) is bonded in a single-bond geometry to one Te(4) atom. In the N4Te2S4Cl3 cluster, there are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(8) atom. The N(1)-S(2) bond length is 1.58 Å. The N(1)-S(8) bond length is 1.61 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(4) and one S(6) atom. The N(2)-S(4) bond length is 1.57 Å. The N(2)-S(6) bond length is 1.62 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one Te(1) and one S(2) atom. The N(3)-Te(1) bond length is 2.01 Å. The N(3)-S(2) bond length is 1.56 Å. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Te(3) and one S(4) atom. The N(4)-Te(3) bond length is 2.02 Å. The N(4)-S(4) bond length is 1.56 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one N(3), one S(8), one Cl(5), and one Cl(6) atom. The Te(1)-S(8) bond length is 2.49 Å. The Te(1)-Cl(5) bond length is 2.92 Å. The Te(1)-Cl(6) bond length is 2.38 Å. In the second Te site, Te(3) is bonded in a 4-coordinate geometry to one N(4), one S(6), one Cl(4), and one Cl(5) atom. The Te(3)-S(6) bond length is 2.49 Å. The Te(3)-Cl(4) bond length is 2.38 Å. The Te(3)-Cl(5) bond length is 2.95 Å. There are four inequivalent S sites. In the first S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(3) atom. In the second S site, S(4) is bonded in a bent 120 degrees geometry to one N(2) and one N(4) atom. In the third S site, S(6) is bonded in a water-like geometry to one N(2) and one Te(3) atom. In the fourth S site, S(8) is bonded in a distorted water-like geometry to one N(1) and one Te(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Te(3) atom. In the second Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one Te(3) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Te(1) atom. In the TeS2(NCl)2 cluster, there are two inequivalent N sites. In the first N site, N(5) is bonded in a bent 120 degrees geometry to one Te(2) and one S(5) atom. The N(5)-Te(2) bond length is 2.04 Å. The N(5)-S(5) bond length is 1.56 Å. In the second N site, N(7) is bonded in a bent 120 degrees geometry to one S(3) and one S(5) atom. The N(7)-S(3) bond length is 1.62 Å. The N(7)-S(5) bond length is 1.58 Å. Te(2) is bonded in a 4-coordinate geometry to one N(5), one S(3), one Cl(2), and one Cl(3) atom. The Te(2)-S(3) bond length is 2.48 Å. The Te(2)-Cl(2) bond length is 2.75 Å. The Te(2)-Cl(3) bond length is 2.41 Å. There are two inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one N(7) and one Te(2) atom. In the second S site, S(5) is bonded in a bent 120 degrees geometry to one N(5) and one N(7) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Te(2) atom.