V2O3F is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent F(2) atoms to form VO4F2 octahedra that share corners with four equivalent V(5)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra, and edges with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(6)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the third V site, V(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with two equivalent V(5)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent V(6)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the fifth V site, V(5) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent F(2) atoms to form VO4F2 octahedra that share corners with four equivalent V(1)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the sixth V site, V(6) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(2)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra, and edges with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-53°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one V(5) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(6) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom.
V2O3F is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent F(2) atoms to form VO4F2 octahedra that share corners with four equivalent V(5)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra, and edges with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-55°. Both V(1)-O(2) bond lengths are 2.07 Å. Both V(1)-O(3) bond lengths are 1.96 Å. Both V(1)-F(2) bond lengths are 2.04 Å. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(6)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 50-54°. Both V(2)-O(1) bond lengths are 2.08 Å. Both V(2)-O(4) bond lengths are 1.96 Å. Both V(2)-F(1) bond lengths are 2.04 Å. In the third V site, V(3) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one F(2) atom to form VO5F octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with two equivalent V(5)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. The V(3)-O(1) bond length is 1.92 Å. The V(3)-O(2) bond length is 2.02 Å. The V(3)-O(4) bond length is 1.87 Å. The V(3)-O(5) bond length is 1.92 Å. The V(3)-O(6) bond length is 2.05 Å. The V(3)-F(2) bond length is 2.12 Å. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent V(6)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra,  an edgeedge with one V(2)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. The V(4)-O(1) bond length is 2.04 Å. The V(4)-O(2) bond length is 1.93 Å. The V(4)-O(3) bond length is 1.87 Å. The V(4)-O(5) bond length is 2.04 Å. The V(4)-O(6) bond length is 1.90 Å. The V(4)-F(1) bond length is 2.12 Å. In the fifth V site, V(5) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent F(2) atoms to form VO4F2 octahedra that share corners with four equivalent V(1)O4F2 octahedra, corners with four equivalent V(3)O5F octahedra, and edges with two equivalent V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-53°. Both V(5)-O(3) bond lengths are 1.99 Å. Both V(5)-O(5) bond lengths are 2.04 Å. Both V(5)-F(2) bond lengths are 1.97 Å. In the sixth V site, V(6) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with four equivalent V(2)O4F2 octahedra, corners with four equivalent V(4)O5F octahedra, and edges with two equivalent V(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-53°. Both V(6)-O(4) bond lengths are 2.00 Å. Both V(6)-O(6) bond lengths are 2.04 Å. Both V(6)-F(1) bond lengths are 1.98 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one V(3), one V(4), and one V(5) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(6) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom.