SmPdP is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Sm(1) is bonded to six equivalent Pd(1) and six equivalent P(1) atoms to form a mixture of edge and face-sharing SmP6Pd6 cuboctahedra. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Sm(1) and three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to six equivalent Sm(1) and three equivalent Pd(1) atoms.
SmPdP is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6_3/mmc space group. Sm(1) is bonded to six equivalent Pd(1) and six equivalent P(1) atoms to form a mixture of edge and face-sharing SmP6Pd6 cuboctahedra. All Sm(1)-Pd(1) bond lengths are 3.10 Å. All Sm(1)-P(1) bond lengths are 3.10 Å. Pd(1) is bonded in a 9-coordinate geometry to six equivalent Sm(1) and three equivalent P(1) atoms. All Pd(1)-P(1) bond lengths are 2.42 Å. P(1) is bonded in a 9-coordinate geometry to six equivalent Sm(1) and three equivalent Pd(1) atoms.