MnSnF6 crystallizes in the trigonal R-3 space group. Mn(1) is bonded to six equivalent F(1) atoms to form MnF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Mn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. F(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one Sn(1) atom.
MnSnF6 crystallizes in the trigonal R-3 space group. Mn(1) is bonded to six equivalent F(1) atoms to form MnF6 octahedra that share corners with six equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. All Mn(1)-F(1) bond lengths are 2.10 Å. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Mn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. All Sn(1)-F(1) bond lengths are 1.98 Å. F(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one Sn(1) atom.