Pt(N2I3)2 is Copper structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two Pt(N2I3)2 clusters. Pt(1) is bonded in an octahedral geometry to two equivalent I(1), two equivalent I(2), and two equivalent I(3) atoms. N(1) is bonded in a bent 120 degrees geometry to one I(1) and one I(2) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a distorted T-shaped geometry to one Pt(1) and two equivalent N(1) atoms. In the second I site, I(2) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and two equivalent N(1) atoms. In the third I site, I(3) is bonded in a single-bond geometry to one Pt(1) atom.
Pt(N2I3)2 is Copper structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two Pt(N2I3)2 clusters. Pt(1) is bonded in an octahedral geometry to two equivalent I(1), two equivalent I(2), and two equivalent I(3) atoms. Both Pt(1)-I(1) bond lengths are 2.54 Å. Both Pt(1)-I(2) bond lengths are 2.82 Å. Both Pt(1)-I(3) bond lengths are 2.74 Å. N(1) is bonded in a bent 120 degrees geometry to one I(1) and one I(2) atom. The N(1)-I(1) bond length is 2.39 Å. The N(1)-I(2) bond length is 1.99 Å. There are three inequivalent I sites. In the first I site, I(1) is bonded in a distorted T-shaped geometry to one Pt(1) and two equivalent N(1) atoms. In the second I site, I(2) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and two equivalent N(1) atoms. In the third I site, I(3) is bonded in a single-bond geometry to one Pt(1) atom.