LiAg(CO2)2 is Antimony trioxide-derived structured and crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(3), and two equivalent O(2) atoms. Ag(1) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(1) and one C(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1), two equivalent Ag(1), and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(2) atom.
LiAg(CO2)2 is Antimony trioxide-derived structured and crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(3), and two equivalent O(2) atoms. The Li(1)-O(1) bond length is 2.00 Å. The Li(1)-O(3) bond length is 1.95 Å. There is one shorter (1.98 Å) and one longer (2.08 Å) Li(1)-O(2) bond length. Ag(1) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(3), and two equivalent O(4) atoms. The Ag(1)-O(1) bond length is 2.28 Å. There is one shorter (2.58 Å) and one longer (2.82 Å) Ag(1)-O(3) bond length. There is one shorter (2.33 Å) and one longer (2.64 Å) Ag(1)-O(4) bond length. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(2)-O(3) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Li(1) and one C(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1), two equivalent Ag(1), and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one C(2) atom.