VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing VO4F3 hexagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of edge and corner-sharing OV4 tetrahedra. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms.
VOF is Baddeleyite-derived structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing VO4F3 hexagonal pyramids. There are a spread of V(1)-O(1) bond distances ranging from 2.03-2.07 Å. There are two shorter (2.15 Å) and one longer (2.17 Å) V(1)-F(1) bond length. O(1) is bonded to four equivalent V(1) atoms to form a mixture of edge and corner-sharing OV4 tetrahedra. F(1) is bonded in a trigonal planar geometry to three equivalent V(1) atoms.