AuCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four SCl3 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(6), and one Cl(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom.
AuCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four SCl3 clusters. In each AuCl4 cluster, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. The Au(1)-Cl(2) bond length is 2.29 Å. The Au(1)-Cl(3) bond length is 2.30 Å. The Au(1)-Cl(4) bond length is 2.31 Å. The Au(1)-Cl(5) bond length is 2.30 Å. There are four inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(6), and one Cl(7) atom. The S(1)-Cl(1) bond length is 2.02 Å. The S(1)-Cl(6) bond length is 2.01 Å. The S(1)-Cl(7) bond length is 2.00 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom.