As2OCl3F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four As2OCl3F5 clusters. There are two inequivalent As sites. In the first As site, As(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing AsOF5 octahedra. In the second As site, As(2) is bonded to one O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form corner-sharing AsCl3O tetrahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a bent 120 degrees geometry to one As(1) and one As(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(2) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom.
As2OCl3F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four As2OCl3F5 clusters. There are two inequivalent As sites. In the first As site, As(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing AsOF5 octahedra. The As(1)-O(1) bond length is 1.93 Å. The As(1)-F(1) bond length is 1.77 Å. The As(1)-F(2) bond length is 1.78 Å. The As(1)-F(3) bond length is 1.76 Å. The As(1)-F(4) bond length is 1.77 Å. The As(1)-F(5) bond length is 1.76 Å. In the second As site, As(2) is bonded to one O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form corner-sharing AsCl3O tetrahedra. The corner-sharing octahedral tilt angles are 53°. The As(2)-O(1) bond length is 1.70 Å. The As(2)-Cl(1) bond length is 2.11 Å. The As(2)-Cl(2) bond length is 2.11 Å. The As(2)-Cl(3) bond length is 2.10 Å. O(1) is bonded in a bent 120 degrees geometry to one As(1) and one As(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(2) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom.