SbF6SBr3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SBr3 clusters and four SbF6 clusters. In each SBr3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Br(1), one Br(2), and one Br(3) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one S(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one S(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one S(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.
SbF6SBr3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SBr3 clusters and four SbF6 clusters. In each SBr3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Br(1), one Br(2), and one Br(3) atom. The S(1)-Br(1) bond length is 2.17 Å. The S(1)-Br(2) bond length is 2.17 Å. The S(1)-Br(3) bond length is 2.16 Å. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one S(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one S(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one S(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Sb(1)-F(1) bond length is 1.89 Å. The Sb(1)-F(2) bond length is 1.89 Å. The Sb(1)-F(3) bond length is 1.91 Å. The Sb(1)-F(4) bond length is 1.89 Å. The Sb(1)-F(5) bond length is 1.90 Å. The Sb(1)-F(6) bond length is 1.90 Å. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom.