LiSbF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Sb(1) atom.
LiSbF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Li(1)-F(1) bond lengths are 1.99 Å. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Sb(1)-F(1) bond lengths are 1.89 Å. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Sb(1) atom.