CaV2O4 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Ca(1) is bonded to four equivalent O(1) atoms to form CaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Ca(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. O(1) is bonded to one Ca(1) and three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OCaV3 tetrahedra.
CaV2O4 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Ca(1) is bonded to four equivalent O(1) atoms to form CaO4 tetrahedra that share corners with twelve equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. All Ca(1)-O(1) bond lengths are 2.21 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Ca(1)O4 tetrahedra and edges with six equivalent V(1)O6 octahedra. There are four shorter (2.05 Å) and two longer (2.14 Å) V(1)-O(1) bond lengths. O(1) is bonded to one Ca(1) and three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing OCaV3 tetrahedra.