YBi(OF)2 is Fluorite-derived structured and crystallizes in the tetragonal P-4m2 space group. Y(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. Bi(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to two equivalent Y(1) and two equivalent Bi(1) atoms to form OY2Bi2 tetrahedra that share corners with four equivalent F(1)Y2Bi2 tetrahedra, corners with twelve equivalent O(1)Y2Bi2 tetrahedra, and edges with six equivalent F(1)Y2Bi2 tetrahedra. F(1) is bonded to two equivalent Y(1) and two equivalent Bi(1) atoms to form FY2Bi2 tetrahedra that share corners with four equivalent O(1)Y2Bi2 tetrahedra, corners with twelve equivalent F(1)Y2Bi2 tetrahedra, and edges with six equivalent O(1)Y2Bi2 tetrahedra.
YBi(OF)2 is Fluorite-derived structured and crystallizes in the tetragonal P-4m2 space group. Y(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. All Y(1)-O(1) bond lengths are 2.43 Å. All Y(1)-F(1) bond lengths are 2.32 Å. Bi(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. All Bi(1)-O(1) bond lengths are 2.40 Å. All Bi(1)-F(1) bond lengths are 2.52 Å. O(1) is bonded to two equivalent Y(1) and two equivalent Bi(1) atoms to form OY2Bi2 tetrahedra that share corners with four equivalent F(1)Y2Bi2 tetrahedra, corners with twelve equivalent O(1)Y2Bi2 tetrahedra, and edges with six equivalent F(1)Y2Bi2 tetrahedra. F(1) is bonded to two equivalent Y(1) and two equivalent Bi(1) atoms to form FY2Bi2 tetrahedra that share corners with four equivalent O(1)Y2Bi2 tetrahedra, corners with twelve equivalent F(1)Y2Bi2 tetrahedra, and edges with six equivalent O(1)Y2Bi2 tetrahedra.