WMoN3 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one N(2), one N(5), and two equivalent N(3) atoms to form distorted WN5 trigonal bipyramids that share corners with two equivalent Mo(1)N4 tetrahedra, corners with two equivalent W(2)N4 trigonal pyramids,  an edgeedge with one W(1)N5 trigonal bipyramid, and  an edgeedge with one W(2)N4 trigonal pyramid. In the second W site, W(2) is bonded to one N(1), one N(3), one N(4), and one N(5) atom to form distorted WN4 trigonal pyramids that share corners with two equivalent Mo(1)N4 tetrahedra, corners with two equivalent W(1)N5 trigonal bipyramids, and  an edgeedge with one W(1)N5 trigonal bipyramid. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one N(2), one N(4), one N(5), and one N(6) atom to form MoN4 tetrahedra that share corners with two equivalent W(1)N5 trigonal bipyramids and corners with two equivalent W(2)N4 trigonal pyramids. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a T-shaped geometry to one W(1), one W(2), and one Mo(2) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Mo(1) atom. In the third N site, N(3) is bonded in a distorted see-saw-like geometry to one W(2), two equivalent W(1), and one Mo(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one W(2) and one Mo(1) atom. In the fifth N site, N(5) is bonded in a distorted T-shaped geometry to one W(1), one W(2), and one Mo(1) atom. In the sixth N site, N(6) is bonded in a water-like geometry to one Mo(1) and one Mo(2) atom.
WMoN3 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one N(2), one N(5), and two equivalent N(3) atoms to form distorted WN5 trigonal bipyramids that share corners with two equivalent Mo(1)N4 tetrahedra, corners with two equivalent W(2)N4 trigonal pyramids,  an edgeedge with one W(1)N5 trigonal bipyramid, and  an edgeedge with one W(2)N4 trigonal pyramid. The W(1)-N(1) bond length is 2.10 Å. The W(1)-N(2) bond length is 1.92 Å. The W(1)-N(5) bond length is 2.04 Å. There is one shorter (1.94 Å) and one longer (2.16 Å) W(1)-N(3) bond length. In the second W site, W(2) is bonded to one N(1), one N(3), one N(4), and one N(5) atom to form distorted WN4 trigonal pyramids that share corners with two equivalent Mo(1)N4 tetrahedra, corners with two equivalent W(1)N5 trigonal bipyramids, and  an edgeedge with one W(1)N5 trigonal bipyramid. The W(2)-N(1) bond length is 1.89 Å. The W(2)-N(3) bond length is 2.11 Å. The W(2)-N(4) bond length is 1.85 Å. The W(2)-N(5) bond length is 2.03 Å. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one N(2), one N(4), one N(5), and one N(6) atom to form MoN4 tetrahedra that share corners with two equivalent W(1)N5 trigonal bipyramids and corners with two equivalent W(2)N4 trigonal pyramids. The Mo(1)-N(2) bond length is 1.83 Å. The Mo(1)-N(4) bond length is 1.91 Å. The Mo(1)-N(5) bond length is 1.94 Å. The Mo(1)-N(6) bond length is 1.91 Å. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one N(6) atom. The Mo(2)-N(1) bond length is 2.00 Å. The Mo(2)-N(3) bond length is 2.19 Å. The Mo(2)-N(6) bond length is 1.78 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a T-shaped geometry to one W(1), one W(2), and one Mo(2) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Mo(1) atom. In the third N site, N(3) is bonded in a distorted see-saw-like geometry to one W(2), two equivalent W(1), and one Mo(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one W(2) and one Mo(1) atom. In the fifth N site, N(5) is bonded in a distorted T-shaped geometry to one W(1), one W(2), and one Mo(1) atom. In the sixth N site, N(6) is bonded in a water-like geometry to one Mo(1) and one Mo(2) atom.