CaV2O2 crystallizes in the tetragonal I4_1/amd space group. Ca(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. V(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded to three equivalent Ca(1) and one V(1) atom to form a mixture of distorted edge and corner-sharing OCa3V tetrahedra.
CaV2O2 crystallizes in the tetragonal I4_1/amd space group. Ca(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are two shorter (2.43 Å) and four longer (2.66 Å) Ca(1)-O(1) bond lengths. V(1) is bonded in a single-bond geometry to one O(1) atom. The V(1)-O(1) bond length is 1.77 Å. O(1) is bonded to three equivalent Ca(1) and one V(1) atom to form a mixture of distorted edge and corner-sharing OCa3V tetrahedra.