Ag3AsS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a distorted T-shaped geometry to three equivalent S(1) atoms. As(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent S(1) atoms. S(1) is bonded to three equivalent Ag(1) and one As(1) atom to form corner-sharing SAg3As trigonal pyramids.
Ag3AsS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a distorted T-shaped geometry to three equivalent S(1) atoms. There are two shorter (2.44 Å) and one longer (2.78 Å) Ag(1)-S(1) bond length. As(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent S(1) atoms. All As(1)-S(1) bond lengths are 2.28 Å. S(1) is bonded to three equivalent Ag(1) and one As(1) atom to form corner-sharing SAg3As trigonal pyramids.