CsLi2(HO)3 crystallizes in the monoclinic P2_1/m space group. Cs(1) is bonded in a 7-coordinate geometry to one H(1), two equivalent H(3), one O(1), one O(2), and two equivalent O(3) atoms. Li(1) is bonded in a distorted trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one O(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cs(1), two equivalent Li(1), and one H(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(1), two equivalent Li(1), and one H(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cs(1), two equivalent Li(1), and one H(1) atom.
CsLi2(HO)3 crystallizes in the monoclinic P2_1/m space group. Cs(1) is bonded in a 7-coordinate geometry to one H(1), two equivalent H(3), one O(1), one O(2), and two equivalent O(3) atoms. The Cs(1)-H(1) bond length is 3.19 Å. Both Cs(1)-H(3) bond lengths are 3.23 Å. The Cs(1)-O(1) bond length is 3.27 Å. The Cs(1)-O(2) bond length is 3.06 Å. There is one shorter (3.13 Å) and one longer (3.17 Å) Cs(1)-O(3) bond length. Li(1) is bonded in a distorted trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The Li(1)-O(1) bond length is 1.89 Å. The Li(1)-O(2) bond length is 1.95 Å. The Li(1)-O(3) bond length is 1.88 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Cs(1) and one O(3) atom. The H(1)-O(3) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.97 Å. In the third H site, H(3) is bonded in a single-bond geometry to two equivalent Cs(1) and one O(1) atom. The H(3)-O(1) bond length is 0.97 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cs(1), two equivalent Li(1), and one H(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(1), two equivalent Li(1), and one H(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cs(1), two equivalent Li(1), and one H(1) atom.