Li2CuP crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a 7-coordinate geometry to three equivalent Cu(1) and four equivalent P(1) atoms. Cu(1) is bonded in a 9-coordinate geometry to six equivalent Li(1) and three equivalent P(1) atoms. P(1) is bonded in a 11-coordinate geometry to eight equivalent Li(1) and three equivalent Cu(1) atoms.
Li2CuP crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a 7-coordinate geometry to three equivalent Cu(1) and four equivalent P(1) atoms. All Li(1)-Cu(1) bond lengths are 2.63 Å. There is one shorter (2.58 Å) and three longer (2.63 Å) Li(1)-P(1) bond lengths. Cu(1) is bonded in a 9-coordinate geometry to six equivalent Li(1) and three equivalent P(1) atoms. All Cu(1)-P(1) bond lengths are 2.30 Å. P(1) is bonded in a 11-coordinate geometry to eight equivalent Li(1) and three equivalent Cu(1) atoms.