(V3Pb5O12)2F2 crystallizes in the hexagonal P6_3/m space group. The structure consists of two hydrofluoric acid atoms inside a V3Pb5O12 framework. In the V3Pb5O12 framework, V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the second Pb site, Pb(2) is bonded in a distorted pentagonal planar geometry to one O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1), one Pb(2), and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(2) atoms.
(V3Pb5O12)2F2 crystallizes in the hexagonal P6_3/m space group. The structure consists of two hydrofluoric acid atoms inside a V3Pb5O12 framework. In the V3Pb5O12 framework, V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. The V(1)-O(1) bond length is 1.74 Å. The V(1)-O(2) bond length is 1.76 Å. Both V(1)-O(3) bond lengths are 1.74 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. All Pb(1)-O(1) bond lengths are 2.49 Å. All Pb(1)-O(2) bond lengths are 2.76 Å. In the second Pb site, Pb(2) is bonded in a distorted pentagonal planar geometry to one O(2) and four equivalent O(3) atoms. The Pb(2)-O(2) bond length is 2.43 Å. There are two shorter (2.60 Å) and two longer (2.61 Å) Pb(2)-O(3) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1), one Pb(2), and two equivalent Pb(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(2) atoms.