Li3SbS3 crystallizes in the trigonal R3m space group. Li(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. Sb(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent S(1) atoms. S(1) is bonded to four equivalent Li(1) and one Sb(1) atom to form a mixture of distorted edge and corner-sharing SLi4Sb trigonal bipyramids.
Li3SbS3 crystallizes in the trigonal R3m space group. Li(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. There are a spread of Li(1)-S(1) bond distances ranging from 2.50-2.58 Å. Sb(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent S(1) atoms. All Sb(1)-S(1) bond lengths are 2.47 Å. S(1) is bonded to four equivalent Li(1) and one Sb(1) atom to form a mixture of distorted edge and corner-sharing SLi4Sb trigonal bipyramids.