VOSb2O4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(2) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2) and three equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom.
VOSb2O4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(2) atoms. The V(1)-O(3) bond length is 1.64 Å. There are two shorter (2.00 Å) and two longer (2.02 Å) V(1)-O(2) bond lengths. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2) and three equivalent O(1) atoms. The Sb(1)-O(2) bond length is 2.05 Å. There are two shorter (2.03 Å) and one longer (2.61 Å) Sb(1)-O(1) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom.