NaTb(Pd3O4)2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1) atoms. Tb(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1) atoms. Pd(1) is bonded in a square co-planar geometry to four O(1,1,1,1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids. In the second O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids. In the third O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids. In the fourth O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids.
NaTb(Pd3O4)2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1) atoms. All Na(1)-O(1,1,1,1) bond lengths are 2.62 Å. Tb(1) is bonded in a body-centered cubic geometry to eight O(1,1,1,1) atoms. All Tb(1)-O(1,1,1,1) bond lengths are 2.44 Å. Pd(1) is bonded in a square co-planar geometry to four O(1,1,1,1) atoms. All Pd(1)-O(1,1,1,1) bond lengths are 2.07 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids. In the second O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids. In the third O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids. In the fourth O site, O(1) is bonded to one Na(1), one Tb(1), and three equivalent Pd(1) atoms to form a mixture of corner and edge-sharing ONaTbPd3 trigonal bipyramids.