WZnF6 crystallizes in the trigonal R-3 space group. W(1) is bonded to six equivalent F(1) atoms to form WF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent W(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. F(1) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(1) atom.
WZnF6 crystallizes in the trigonal R-3 space group. W(1) is bonded to six equivalent F(1) atoms to form WF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All W(1)-F(1) bond lengths are 1.98 Å. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent W(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Zn(1)-F(1) bond lengths are 2.02 Å. F(1) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(1) atom.