CePd2In4 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), one In(2), three equivalent In(1), three equivalent In(3), and three equivalent In(4) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(3), three equivalent In(2), and three equivalent In(4) atoms. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(2), three equivalent In(1), and three equivalent In(3) atoms. There are four inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Ce(1), one Pd(2), and three equivalent Pd(1) atoms. In the third In site, In(3) is bonded in a 4-coordinate geometry to three equivalent Ce(1), one Pd(1), and three equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(1) atoms.
CePd2In4 crystallizes in the orthorhombic Pnma space group. Ce(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), one In(2), three equivalent In(1), three equivalent In(3), and three equivalent In(4) atoms. Both Ce(1)-Pd(1) bond lengths are 3.25 Å. Both Ce(1)-Pd(2) bond lengths are 3.36 Å. The Ce(1)-In(2) bond length is 3.69 Å. There are two shorter (3.25 Å) and one longer (3.41 Å) Ce(1)-In(1) bond length. There are two shorter (3.28 Å) and one longer (3.46 Å) Ce(1)-In(3) bond length. All Ce(1)-In(4) bond lengths are 3.31 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(3), three equivalent In(2), and three equivalent In(4) atoms. The Pd(1)-In(3) bond length is 2.74 Å. There is one shorter (2.77 Å) and two longer (3.06 Å) Pd(1)-In(2) bond lengths. There are two shorter (2.75 Å) and one longer (2.82 Å) Pd(1)-In(4) bond length. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), one In(2), three equivalent In(1), and three equivalent In(3) atoms. The Pd(2)-In(2) bond length is 2.80 Å. There is one shorter (2.72 Å) and two longer (2.75 Å) Pd(2)-In(1) bond lengths. There is one shorter (2.74 Å) and two longer (2.79 Å) Pd(2)-In(3) bond lengths. There are four inequivalent In sites. In the first In site, In(1) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to one Ce(1), one Pd(2), and three equivalent Pd(1) atoms. In the third In site, In(3) is bonded in a 4-coordinate geometry to three equivalent Ce(1), one Pd(1), and three equivalent Pd(2) atoms. In the fourth In site, In(4) is bonded in a 3-coordinate geometry to three equivalent Ce(1) and three equivalent Pd(1) atoms.