KLi2BO3 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form a mixture of distorted edge and corner-sharing LiO4 tetrahedra. B(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), two equivalent Li(1), and one B(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one K(1), four equivalent Li(1), and one B(1) atom.
KLi2BO3 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. The K(1)-O(2) bond length is 2.64 Å. Both K(1)-O(1) bond lengths are 2.79 Å. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form a mixture of distorted edge and corner-sharing LiO4 tetrahedra. There is one shorter (1.89 Å) and one longer (2.01 Å) Li(1)-O(1) bond length. There is one shorter (1.99 Å) and one longer (2.08 Å) Li(1)-O(2) bond length. B(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. The B(1)-O(2) bond length is 1.41 Å. Both B(1)-O(1) bond lengths are 1.39 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), two equivalent Li(1), and one B(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one K(1), four equivalent Li(1), and one B(1) atom.