Li5V2Ni3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(5), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth Li site, Li(5) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the second V site, V(2) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the second Ni site, Ni(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the third Ni site, Ni(3) is bonded to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra, corners with two equivalent O(10)Li4VNi octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(2), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra, corners with two equivalent O(9)Li4VNi octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the third O site, O(3) is bonded to one Li(4), one Li(5), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, and edges with two equivalent O(8)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(5)Li4V2 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, and edges with two equivalent O(7)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(4)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(6)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(3)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(5), one V(2), one Ni(1), and one Ni(3) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(8)Li3VNi2 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(6)Li4V2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(1), one Ni(1), and one Ni(2) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(7)Li3VNi2 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one Ni(2) atom to form OLi4VNi octahedra that share  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(2), and one Ni(3) atom to form OLi4VNi octahedra that share  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°.
Li5V2Ni3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. The Li(1)-O(10) bond length is 2.11 Å. The Li(1)-O(5) bond length is 2.05 Å. The Li(1)-O(6) bond length is 2.08 Å. The Li(1)-O(7) bond length is 2.17 Å. The Li(1)-O(8) bond length is 2.15 Å. The Li(1)-O(9) bond length is 2.12 Å. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. The Li(2)-O(10) bond length is 2.16 Å. The Li(2)-O(2) bond length is 2.12 Å. The Li(2)-O(5) bond length is 2.27 Å. The Li(2)-O(6) bond length is 2.16 Å. The Li(2)-O(7) bond length is 2.07 Å. The Li(2)-O(9) bond length is 2.13 Å. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(5), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. The Li(3)-O(1) bond length is 2.13 Å. The Li(3)-O(10) bond length is 2.09 Å. The Li(3)-O(5) bond length is 2.11 Å. The Li(3)-O(6) bond length is 2.19 Å. The Li(3)-O(8) bond length is 2.06 Å. The Li(3)-O(9) bond length is 2.21 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. The Li(4)-O(1) bond length is 2.13 Å. The Li(4)-O(3) bond length is 2.06 Å. The Li(4)-O(4) bond length is 2.24 Å. The Li(4)-O(5) bond length is 2.19 Å. The Li(4)-O(8) bond length is 2.19 Å. The Li(4)-O(9) bond length is 2.08 Å. In the fifth Li site, Li(5) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The Li(5)-O(10) bond length is 2.08 Å. The Li(5)-O(2) bond length is 2.11 Å. The Li(5)-O(3) bond length is 2.30 Å. The Li(5)-O(4) bond length is 2.08 Å. The Li(5)-O(6) bond length is 2.28 Å. The Li(5)-O(7) bond length is 2.19 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. The V(1)-O(1) bond length is 1.93 Å. The V(1)-O(3) bond length is 2.01 Å. The V(1)-O(5) bond length is 1.94 Å. The V(1)-O(6) bond length is 1.86 Å. The V(1)-O(8) bond length is 1.97 Å. The V(1)-O(9) bond length is 1.83 Å. In the second V site, V(2) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. The V(2)-O(10) bond length is 1.85 Å. The V(2)-O(2) bond length is 1.99 Å. The V(2)-O(4) bond length is 2.03 Å. The V(2)-O(5) bond length is 1.99 Å. The V(2)-O(6) bond length is 2.06 Å. The V(2)-O(7) bond length is 1.95 Å. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. The Ni(1)-O(1) bond length is 2.22 Å. The Ni(1)-O(2) bond length is 2.13 Å. The Ni(1)-O(3) bond length is 2.06 Å. The Ni(1)-O(4) bond length is 2.06 Å. The Ni(1)-O(7) bond length is 2.08 Å. The Ni(1)-O(8) bond length is 2.06 Å. In the second Ni site, Ni(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Ni(2)-O(1) bond length is 2.08 Å. The Ni(2)-O(2) bond length is 2.11 Å. The Ni(2)-O(3) bond length is 2.07 Å. The Ni(2)-O(4) bond length is 2.08 Å. The Ni(2)-O(8) bond length is 2.06 Å. The Ni(2)-O(9) bond length is 2.11 Å. In the third Ni site, Ni(3) is bonded to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. The Ni(3)-O(1) bond length is 2.14 Å. The Ni(3)-O(10) bond length is 2.10 Å. The Ni(3)-O(2) bond length is 2.07 Å. The Ni(3)-O(3) bond length is 2.10 Å. The Ni(3)-O(4) bond length is 2.06 Å. The Ni(3)-O(7) bond length is 2.07 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra, corners with two equivalent O(10)Li4VNi octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(2), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra, corners with two equivalent O(9)Li4VNi octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the third O site, O(3) is bonded to one Li(4), one Li(5), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, and edges with two equivalent O(8)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(5)Li4V2 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, and edges with two equivalent O(7)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(4)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(6)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(3)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(5), one V(2), one Ni(1), and one Ni(3) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(8)Li3VNi2 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(6)Li4V2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(1), one Ni(1), and one Ni(2) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(7)Li3VNi2 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one Ni(2) atom to form OLi4VNi octahedra that share  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(2), and one Ni(3) atom to form OLi4VNi octahedra that share  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°.