(Mo2NO7)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one Mo2NO7 cluster. In the Mo2NO7 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(6) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(5), and one O(7) atom. N(2) is bonded in a single-bond geometry to one O(5) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(2) and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one O(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom.
(Mo2NO7)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one Mo2NO7 cluster. In the Mo2NO7 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), and two equivalent O(6) atoms. The Mo(1)-O(1) bond length is 1.92 Å. The Mo(1)-O(2) bond length is 1.72 Å. The Mo(1)-O(3) bond length is 1.71 Å. There is one shorter (2.02 Å) and one longer (2.28 Å) Mo(1)-O(6) bond length. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(5), and one O(7) atom. The Mo(2)-O(1) bond length is 1.93 Å. The Mo(2)-O(4) bond length is 1.72 Å. The Mo(2)-O(5) bond length is 2.01 Å. The Mo(2)-O(7) bond length is 1.72 Å. N(2) is bonded in a single-bond geometry to one O(5) atom. The N(2)-O(5) bond length is 1.26 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(2) and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one O(6) atom. The O(6)-O(6) bond length is 1.54 Å. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom.