Ce2RhPdIn2 crystallizes in the monoclinic Pm space group. There are six inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 11-coordinate geometry to one Rh(2), two equivalent Pd(2), two equivalent Pd(3), two equivalent In(1), two equivalent In(4), and two equivalent In(5) atoms. In the second Ce site, Ce(2) is bonded in a 11-coordinate geometry to one Rh(3), two equivalent Rh(1), two equivalent Pd(1), two equivalent In(2), two equivalent In(3), and two equivalent In(6) atoms. In the third Ce site, Ce(3) is bonded in a 11-coordinate geometry to one Rh(2), two equivalent Pd(1), two equivalent Pd(3), two equivalent In(1), two equivalent In(3), and two equivalent In(5) atoms. In the fourth Ce site, Ce(4) is bonded in a 11-coordinate geometry to one Rh(3), two equivalent Rh(1), two equivalent Pd(2), two equivalent In(2), two equivalent In(4), and two equivalent In(6) atoms. In the fifth Ce site, Ce(5) is bonded in a 11-coordinate geometry to one Rh(3), two equivalent Pd(1), two equivalent Pd(3), two equivalent In(2), two equivalent In(3), and two equivalent In(5) atoms. In the sixth Ce site, Ce(6) is bonded in a 11-coordinate geometry to one Rh(2), two equivalent Rh(1), two equivalent Pd(2), two equivalent In(1), two equivalent In(4), and two equivalent In(6) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to two equivalent Ce(2), two equivalent Ce(4), two equivalent Ce(6), one In(2), one In(4), and one In(6) atom. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Ce(1), one Ce(3), one Ce(6), two equivalent In(1), two equivalent In(4), and two equivalent In(5) atoms. In the third Rh site, Rh(3) is bonded in a 9-coordinate geometry to one Ce(2), one Ce(4), one Ce(5), two equivalent In(2), two equivalent In(3), and two equivalent In(6) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(2), two equivalent Ce(3), two equivalent Ce(5), one In(2), one In(3), and one In(5) atom. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(4), two equivalent Ce(6), one In(1), one In(4), and one In(6) atom. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), two equivalent Ce(5), one In(1), one In(3), and one In(5) atom. There are six inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), two equivalent Ce(6), two equivalent Rh(2), one Pd(2), and one Pd(3) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent Ce(2), two equivalent Ce(4), two equivalent Ce(5), one Rh(1), two equivalent Rh(3), and one Pd(1) atom. In the third In site, In(3) is bonded in a 10-coordinate geometry to two equivalent Ce(2), two equivalent Ce(3), two equivalent Ce(5), two equivalent Rh(3), one Pd(1), and one Pd(3) atom. In the fourth In site, In(4) is bonded in a 10-coordinate geometry to two equivalent Ce(1), two equivalent Ce(4), two equivalent Ce(6), one Rh(1), two equivalent Rh(2), and one Pd(2) atom. In the fifth In site, In(5) is bonded in a 10-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), two equivalent Ce(5), two equivalent Rh(2), one Pd(1), and one Pd(3) atom. In the sixth In site, In(6) is bonded in a 10-coordinate geometry to two equivalent Ce(2), two equivalent Ce(4), two equivalent Ce(6), one Rh(1), two equivalent Rh(3), and one Pd(2) atom.
Ce2RhPdIn2 crystallizes in the monoclinic Pm space group. There are six inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 11-coordinate geometry to one Rh(2), two equivalent Pd(2), two equivalent Pd(3), two equivalent In(1), two equivalent In(4), and two equivalent In(5) atoms. The Ce(1)-Rh(2) bond length is 3.16 Å. Both Ce(1)-Pd(2) bond lengths are 3.07 Å. Both Ce(1)-Pd(3) bond lengths are 3.09 Å. Both Ce(1)-In(1) bond lengths are 3.33 Å. Both Ce(1)-In(4) bond lengths are 3.40 Å. Both Ce(1)-In(5) bond lengths are 3.41 Å. In the second Ce site, Ce(2) is bonded in a 11-coordinate geometry to one Rh(3), two equivalent Rh(1), two equivalent Pd(1), two equivalent In(2), two equivalent In(3), and two equivalent In(6) atoms. The Ce(2)-Rh(3) bond length is 3.19 Å. Both Ce(2)-Rh(1) bond lengths are 3.02 Å. Both Ce(2)-Pd(1) bond lengths are 3.13 Å. Both Ce(2)-In(2) bond lengths are 3.31 Å. Both Ce(2)-In(3) bond lengths are 3.44 Å. Both Ce(2)-In(6) bond lengths are 3.38 Å. In the third Ce site, Ce(3) is bonded in a 11-coordinate geometry to one Rh(2), two equivalent Pd(1), two equivalent Pd(3), two equivalent In(1), two equivalent In(3), and two equivalent In(5) atoms. The Ce(3)-Rh(2) bond length is 3.07 Å. Both Ce(3)-Pd(1) bond lengths are 3.09 Å. Both Ce(3)-Pd(3) bond lengths are 3.11 Å. Both Ce(3)-In(1) bond lengths are 3.40 Å. Both Ce(3)-In(3) bond lengths are 3.33 Å. Both Ce(3)-In(5) bond lengths are 3.41 Å. In the fourth Ce site, Ce(4) is bonded in a 11-coordinate geometry to one Rh(3), two equivalent Rh(1), two equivalent Pd(2), two equivalent In(2), two equivalent In(4), and two equivalent In(6) atoms. The Ce(4)-Rh(3) bond length is 3.09 Å. Both Ce(4)-Rh(1) bond lengths are 3.05 Å. Both Ce(4)-Pd(2) bond lengths are 3.14 Å. Both Ce(4)-In(2) bond lengths are 3.35 Å. Both Ce(4)-In(4) bond lengths are 3.31 Å. Both Ce(4)-In(6) bond lengths are 3.45 Å. In the fifth Ce site, Ce(5) is bonded in a 11-coordinate geometry to one Rh(3), two equivalent Pd(1), two equivalent Pd(3), two equivalent In(2), two equivalent In(3), and two equivalent In(5) atoms. The Ce(5)-Rh(3) bond length is 3.06 Å. Both Ce(5)-Pd(1) bond lengths are 3.10 Å. Both Ce(5)-Pd(3) bond lengths are 3.10 Å. Both Ce(5)-In(2) bond lengths are 3.38 Å. Both Ce(5)-In(3) bond lengths are 3.42 Å. Both Ce(5)-In(5) bond lengths are 3.33 Å. In the sixth Ce site, Ce(6) is bonded in a 11-coordinate geometry to one Rh(2), two equivalent Rh(1), two equivalent Pd(2), two equivalent In(1), two equivalent In(4), and two equivalent In(6) atoms. The Ce(6)-Rh(2) bond length is 3.09 Å. Both Ce(6)-Rh(1) bond lengths are 3.03 Å. Both Ce(6)-Pd(2) bond lengths are 3.16 Å. Both Ce(6)-In(1) bond lengths are 3.42 Å. Both Ce(6)-In(4) bond lengths are 3.38 Å. Both Ce(6)-In(6) bond lengths are 3.31 Å. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to two equivalent Ce(2), two equivalent Ce(4), two equivalent Ce(6), one In(2), one In(4), and one In(6) atom. The Rh(1)-In(2) bond length is 2.89 Å. The Rh(1)-In(4) bond length is 2.90 Å. The Rh(1)-In(6) bond length is 2.93 Å. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Ce(1), one Ce(3), one Ce(6), two equivalent In(1), two equivalent In(4), and two equivalent In(5) atoms. Both Rh(2)-In(1) bond lengths are 2.79 Å. Both Rh(2)-In(4) bond lengths are 2.81 Å. Both Rh(2)-In(5) bond lengths are 2.80 Å. In the third Rh site, Rh(3) is bonded in a 9-coordinate geometry to one Ce(2), one Ce(4), one Ce(5), two equivalent In(2), two equivalent In(3), and two equivalent In(6) atoms. Both Rh(3)-In(2) bond lengths are 2.80 Å. Both Rh(3)-In(3) bond lengths are 2.81 Å. Both Rh(3)-In(6) bond lengths are 2.81 Å. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to two equivalent Ce(2), two equivalent Ce(3), two equivalent Ce(5), one In(2), one In(3), and one In(5) atom. The Pd(1)-In(2) bond length is 2.91 Å. The Pd(1)-In(3) bond length is 2.92 Å. The Pd(1)-In(5) bond length is 2.91 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(4), two equivalent Ce(6), one In(1), one In(4), and one In(6) atom. The Pd(2)-In(1) bond length is 2.89 Å. The Pd(2)-In(4) bond length is 2.92 Å. The Pd(2)-In(6) bond length is 2.91 Å. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), two equivalent Ce(5), one In(1), one In(3), and one In(5) atom. The Pd(3)-In(1) bond length is 2.92 Å. The Pd(3)-In(3) bond length is 2.93 Å. The Pd(3)-In(5) bond length is 2.92 Å. There are six inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), two equivalent Ce(6), two equivalent Rh(2), one Pd(2), and one Pd(3) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent Ce(2), two equivalent Ce(4), two equivalent Ce(5), one Rh(1), two equivalent Rh(3), and one Pd(1) atom. In the third In site, In(3) is bonded in a 10-coordinate geometry to two equivalent Ce(2), two equivalent Ce(3), two equivalent Ce(5), two equivalent Rh(3), one Pd(1), and one Pd(3) atom. In the fourth In site, In(4) is bonded in a 10-coordinate geometry to two equivalent Ce(1), two equivalent Ce(4), two equivalent Ce(6), one Rh(1), two equivalent Rh(2), and one Pd(2) atom. In the fifth In site, In(5) is bonded in a 10-coordinate geometry to two equivalent Ce(1), two equivalent Ce(3), two equivalent Ce(5), two equivalent Rh(2), one Pd(1), and one Pd(3) atom. In the sixth In site, In(6) is bonded in a 10-coordinate geometry to two equivalent Ce(2), two equivalent Ce(4), two equivalent Ce(6), one Rh(1), two equivalent Rh(3), and one Pd(2) atom.