KIO4 is Zircon-like structured and crystallizes in the triclinic P-1 space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. I(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom.
KIO4 is Zircon-like structured and crystallizes in the triclinic P-1 space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There is one shorter (2.77 Å) and one longer (2.83 Å) K(1)-O(1) bond length. There is one shorter (2.77 Å) and one longer (2.83 Å) K(1)-O(2) bond length. There is one shorter (2.77 Å) and one longer (2.82 Å) K(1)-O(3) bond length. There is one shorter (2.77 Å) and one longer (2.83 Å) K(1)-O(4) bond length. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. The O(1)-I(1) bond length is 1.78 Å. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. The O(2)-I(1) bond length is 1.78 Å. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. The O(3)-I(1) bond length is 1.78 Å. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one I(1) atom. The O(4)-I(1) bond length is 1.77 Å. I(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom.