RbSO2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. S(1) is bonded in a water-like geometry to two equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one S(1) atom.
RbSO2 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are a spread of Rb(1)-O(1) bond distances ranging from 2.94-3.09 Å. S(1) is bonded in a water-like geometry to two equivalent O(1) atoms. Both S(1)-O(1) bond lengths are 1.53 Å. O(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one S(1) atom.