La3WO6Cl3 crystallizes in the hexagonal P6_3/m space group. La(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. W(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent O(1) atoms. O(1) is bonded to three equivalent La(1) and one W(1) atom to form a mixture of edge and corner-sharing OLa3W tetrahedra. Cl(1) is bonded in a see-saw-like geometry to four equivalent La(1) atoms.
La3WO6Cl3 crystallizes in the hexagonal P6_3/m space group. La(1) is bonded in a 10-coordinate geometry to six equivalent O(1) and four equivalent Cl(1) atoms. There are a spread of La(1)-O(1) bond distances ranging from 2.43-2.68 Å. There are a spread of La(1)-Cl(1) bond distances ranging from 2.98-3.08 Å. W(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent O(1) atoms. All W(1)-O(1) bond lengths are 1.94 Å. O(1) is bonded to three equivalent La(1) and one W(1) atom to form a mixture of edge and corner-sharing OLa3W tetrahedra. Cl(1) is bonded in a see-saw-like geometry to four equivalent La(1) atoms.