Cd(CoO2)2 crystallizes in the triclinic P1 space group. There are eight inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(13), one O(15), one O(4), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Cd(2)O6 pentagonal pyramids, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. In the second Co site, Co(2) is bonded to one O(1), one O(12), one O(13), one O(15), one O(4), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Cd(2)O6 pentagonal pyramid, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. In the third Co site, Co(3) is bonded to one O(14), one O(16), one O(2), one O(3), one O(6), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Cd(2)O6 pentagonal pyramids, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(11), one O(14), one O(16), one O(2), one O(3), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Cd(2)O6 pentagonal pyramid, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, edges with two equivalent Co(8)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. In the fifth Co site, Co(5) is bonded to one O(1), one O(10), one O(12), one O(13), one O(5), and one O(7) atom to form CoO6 octahedra that share edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. In the sixth Co site, Co(6) is bonded to one O(11), one O(14), one O(2), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(8)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. In the seventh Co site, Co(7) is bonded to one O(10), one O(12), one O(15), one O(4), one O(5), and one O(7) atom to form CoO6 octahedra that share edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. In the eighth Co site, Co(8) is bonded to one O(11), one O(16), one O(3), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. There are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(7), and one O(8) atom. In the second Cd site, Cd(2) is bonded to one O(1), one O(11), one O(12), one O(2), one O(3), and one O(4) atom to form distorted CdO6 pentagonal pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-17°. In the third Cd site, Cd(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(5), and one O(6) atom. In the fourth Cd site, Cd(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(9) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(2), one Co(5), one Cd(2), and one Cd(4) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(13)Cd2Co3 trigonal bipyramid, corners with two equivalent O(15)Cd2Co3 trigonal bipyramids, corners with two equivalent O(3)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, edges with two equivalent O(4)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the second O site, O(2) is bonded to one Co(3), one Co(4), one Co(6), one Cd(2), and one Cd(4) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(14)Cd2Co3 trigonal bipyramid, corners with two equivalent O(16)Cd2Co3 trigonal bipyramids, corners with two equivalent O(4)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid, edges with two equivalent O(3)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid. In the third O site, O(3) is bonded to one Co(3), one Co(4), one Co(8), one Cd(2), and one Cd(4) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(16)Cd2Co3 trigonal bipyramid, corners with two equivalent O(1)Cd2Co3 trigonal bipyramids, corners with two equivalent O(14)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid, edges with two equivalent O(2)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid. In the fourth O site, O(4) is bonded to one Co(1), one Co(2), one Co(7), one Cd(2), and one Cd(4) atom to form distorted OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(15)Cd2Co3 trigonal bipyramid, corners with two equivalent O(13)Cd2Co3 trigonal bipyramids, corners with two equivalent O(2)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid, edges with two equivalent O(1)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(5), one Co(7), and one Cd(3) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Co(3), one Co(6), one Co(8), and one Cd(3) atom. In the seventh O site, O(7) is bonded to one Co(2), one Co(5), one Co(7), and one Cd(1) atom to form distorted OCdCo3 trigonal pyramids that share  a cornercorner with one O(13)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(14)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(15)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(16)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid, corners with two equivalent O(10)CdCo3 trigonal pyramids,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid. In the eighth O site, O(8) is bonded to one Co(4), one Co(6), one Co(8), and one Cd(1) atom to form OCdCo3 trigonal pyramids that share  a cornercorner with one O(13)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(14)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(15)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(16)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(7)CdCo3 trigonal pyramid, corners with two equivalent O(9)CdCo3 trigonal pyramids,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid. In the ninth O site, O(9) is bonded to one Co(3), one Co(6), one Co(8), and one Cd(4) atom to form OCdCo3 trigonal pyramids that share  a cornercorner with one O(1)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(2)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(3)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(4)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(10)CdCo3 trigonal pyramid, corners with two equivalent O(8)CdCo3 trigonal pyramids,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid. In the tenth O site, O(10) is bonded to one Co(1), one Co(5), one Co(7), and one Cd(4) atom to form OCdCo3 trigonal pyramids that share  a cornercorner with one O(1)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(2)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(3)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(4)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid, corners with two equivalent O(7)CdCo3 trigonal pyramids,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(4), one Co(6), one Co(8), and one Cd(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Co(2), one Co(5), one Co(7), and one Cd(2) atom. In the thirteenth O site, O(13) is bonded to one Co(1), one Co(2), one Co(5), one Cd(1), and one Cd(3) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(1)Cd2Co3 trigonal bipyramid, corners with two equivalent O(16)Cd2Co3 trigonal bipyramids, corners with two equivalent O(4)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid, edges with two equivalent O(15)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Co(3), one Co(4), one Co(6), one Cd(1), and one Cd(3) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(2)Cd2Co3 trigonal bipyramid, corners with two equivalent O(15)Cd2Co3 trigonal bipyramids, corners with two equivalent O(3)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, edges with two equivalent O(16)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Co(1), one Co(2), one Co(7), one Cd(1), and one Cd(3) atom to form distorted OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(4)Cd2Co3 trigonal bipyramid, corners with two equivalent O(1)Cd2Co3 trigonal bipyramids, corners with two equivalent O(14)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid, edges with two equivalent O(13)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Co(3), one Co(4), one Co(8), one Cd(1), and one Cd(3) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(3)Cd2Co3 trigonal bipyramid, corners with two equivalent O(13)Cd2Co3 trigonal bipyramids, corners with two equivalent O(2)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid, edges with two equivalent O(14)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid.
Cd(CoO2)2 crystallizes in the triclinic P1 space group. There are eight inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(13), one O(15), one O(4), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Cd(2)O6 pentagonal pyramids, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(7)O6 octahedra. The Co(1)-O(1) bond length is 1.95 Å. The Co(1)-O(10) bond length is 1.95 Å. The Co(1)-O(13) bond length is 2.09 Å. The Co(1)-O(15) bond length is 1.92 Å. The Co(1)-O(4) bond length is 2.27 Å. The Co(1)-O(5) bond length is 1.89 Å. In the second Co site, Co(2) is bonded to one O(1), one O(12), one O(13), one O(15), one O(4), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Cd(2)O6 pentagonal pyramid, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. The Co(2)-O(1) bond length is 2.08 Å. The Co(2)-O(12) bond length is 1.89 Å. The Co(2)-O(13) bond length is 1.99 Å. The Co(2)-O(15) bond length is 2.22 Å. The Co(2)-O(4) bond length is 1.94 Å. The Co(2)-O(7) bond length is 1.94 Å. In the third Co site, Co(3) is bonded to one O(14), one O(16), one O(2), one O(3), one O(6), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Cd(2)O6 pentagonal pyramids, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Co(8)O6 octahedra. The Co(3)-O(14) bond length is 1.94 Å. The Co(3)-O(16) bond length is 2.07 Å. The Co(3)-O(2) bond length is 2.20 Å. The Co(3)-O(3) bond length is 1.98 Å. The Co(3)-O(6) bond length is 1.90 Å. The Co(3)-O(9) bond length is 1.95 Å. In the fourth Co site, Co(4) is bonded to one O(11), one O(14), one O(16), one O(2), one O(3), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Cd(2)O6 pentagonal pyramid, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, edges with two equivalent Co(8)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. The Co(4)-O(11) bond length is 1.90 Å. The Co(4)-O(14) bond length is 1.99 Å. The Co(4)-O(16) bond length is 2.18 Å. The Co(4)-O(2) bond length is 2.09 Å. The Co(4)-O(3) bond length is 1.94 Å. The Co(4)-O(8) bond length is 1.94 Å. In the fifth Co site, Co(5) is bonded to one O(1), one O(10), one O(12), one O(13), one O(5), and one O(7) atom to form CoO6 octahedra that share edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(7)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. The Co(5)-O(1) bond length is 2.03 Å. The Co(5)-O(10) bond length is 2.00 Å. The Co(5)-O(12) bond length is 2.02 Å. The Co(5)-O(13) bond length is 2.04 Å. The Co(5)-O(5) bond length is 2.02 Å. The Co(5)-O(7) bond length is 2.01 Å. In the sixth Co site, Co(6) is bonded to one O(11), one O(14), one O(2), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(8)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. The Co(6)-O(11) bond length is 2.00 Å. The Co(6)-O(14) bond length is 2.09 Å. The Co(6)-O(2) bond length is 2.01 Å. The Co(6)-O(6) bond length is 2.01 Å. The Co(6)-O(8) bond length is 2.02 Å. The Co(6)-O(9) bond length is 1.99 Å. In the seventh Co site, Co(7) is bonded to one O(10), one O(12), one O(15), one O(4), one O(5), and one O(7) atom to form CoO6 octahedra that share edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. The Co(7)-O(10) bond length is 1.99 Å. The Co(7)-O(12) bond length is 2.01 Å. The Co(7)-O(15) bond length is 2.07 Å. The Co(7)-O(4) bond length is 2.09 Å. The Co(7)-O(5) bond length is 2.01 Å. The Co(7)-O(7) bond length is 1.97 Å. In the eighth Co site, Co(8) is bonded to one O(11), one O(16), one O(3), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and  an edgeedge with one Cd(2)O6 pentagonal pyramid. The Co(8)-O(11) bond length is 2.03 Å. The Co(8)-O(16) bond length is 2.01 Å. The Co(8)-O(3) bond length is 2.09 Å. The Co(8)-O(6) bond length is 2.01 Å. The Co(8)-O(8) bond length is 1.97 Å. The Co(8)-O(9) bond length is 2.00 Å. There are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(7), and one O(8) atom. The Cd(1)-O(13) bond length is 2.36 Å. The Cd(1)-O(14) bond length is 2.43 Å. The Cd(1)-O(15) bond length is 2.39 Å. The Cd(1)-O(16) bond length is 2.35 Å. The Cd(1)-O(7) bond length is 2.33 Å. The Cd(1)-O(8) bond length is 2.32 Å. In the second Cd site, Cd(2) is bonded to one O(1), one O(11), one O(12), one O(2), one O(3), and one O(4) atom to form distorted CdO6 pentagonal pyramids that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-17°. The Cd(2)-O(1) bond length is 2.46 Å. The Cd(2)-O(11) bond length is 2.32 Å. The Cd(2)-O(12) bond length is 2.31 Å. The Cd(2)-O(2) bond length is 2.29 Å. The Cd(2)-O(3) bond length is 2.50 Å. The Cd(2)-O(4) bond length is 2.30 Å. In the third Cd site, Cd(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(15), one O(16), one O(5), and one O(6) atom. The Cd(3)-O(13) bond length is 2.44 Å. The Cd(3)-O(14) bond length is 2.50 Å. The Cd(3)-O(15) bond length is 2.35 Å. The Cd(3)-O(16) bond length is 2.30 Å. The Cd(3)-O(5) bond length is 2.31 Å. The Cd(3)-O(6) bond length is 2.32 Å. In the fourth Cd site, Cd(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(9) atom. The Cd(4)-O(1) bond length is 2.38 Å. The Cd(4)-O(10) bond length is 2.32 Å. The Cd(4)-O(2) bond length is 2.35 Å. The Cd(4)-O(3) bond length is 2.42 Å. The Cd(4)-O(4) bond length is 2.38 Å. The Cd(4)-O(9) bond length is 2.32 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(2), one Co(5), one Cd(2), and one Cd(4) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(13)Cd2Co3 trigonal bipyramid, corners with two equivalent O(15)Cd2Co3 trigonal bipyramids, corners with two equivalent O(3)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, edges with two equivalent O(4)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the second O site, O(2) is bonded to one Co(3), one Co(4), one Co(6), one Cd(2), and one Cd(4) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(14)Cd2Co3 trigonal bipyramid, corners with two equivalent O(16)Cd2Co3 trigonal bipyramids, corners with two equivalent O(4)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid, edges with two equivalent O(3)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid. In the third O site, O(3) is bonded to one Co(3), one Co(4), one Co(8), one Cd(2), and one Cd(4) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(16)Cd2Co3 trigonal bipyramid, corners with two equivalent O(1)Cd2Co3 trigonal bipyramids, corners with two equivalent O(14)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid, edges with two equivalent O(2)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid. In the fourth O site, O(4) is bonded to one Co(1), one Co(2), one Co(7), one Cd(2), and one Cd(4) atom to form distorted OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(15)Cd2Co3 trigonal bipyramid, corners with two equivalent O(13)Cd2Co3 trigonal bipyramids, corners with two equivalent O(2)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(10)CdCo3 trigonal pyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid, edges with two equivalent O(1)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(5), one Co(7), and one Cd(3) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Co(3), one Co(6), one Co(8), and one Cd(3) atom. In the seventh O site, O(7) is bonded to one Co(2), one Co(5), one Co(7), and one Cd(1) atom to form distorted OCdCo3 trigonal pyramids that share  a cornercorner with one O(13)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(14)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(15)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(16)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid, corners with two equivalent O(10)CdCo3 trigonal pyramids,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid. In the eighth O site, O(8) is bonded to one Co(4), one Co(6), one Co(8), and one Cd(1) atom to form OCdCo3 trigonal pyramids that share  a cornercorner with one O(13)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(14)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(15)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(16)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(7)CdCo3 trigonal pyramid, corners with two equivalent O(9)CdCo3 trigonal pyramids,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid. In the ninth O site, O(9) is bonded to one Co(3), one Co(6), one Co(8), and one Cd(4) atom to form OCdCo3 trigonal pyramids that share  a cornercorner with one O(1)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(2)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(3)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(4)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(10)CdCo3 trigonal pyramid, corners with two equivalent O(8)CdCo3 trigonal pyramids,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid. In the tenth O site, O(10) is bonded to one Co(1), one Co(5), one Co(7), and one Cd(4) atom to form OCdCo3 trigonal pyramids that share  a cornercorner with one O(1)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(2)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(3)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(4)Cd2Co3 trigonal bipyramid,  a cornercorner with one O(9)CdCo3 trigonal pyramid, corners with two equivalent O(7)CdCo3 trigonal pyramids,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid, and  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(4), one Co(6), one Co(8), and one Cd(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Co(2), one Co(5), one Co(7), and one Cd(2) atom. In the thirteenth O site, O(13) is bonded to one Co(1), one Co(2), one Co(5), one Cd(1), and one Cd(3) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(1)Cd2Co3 trigonal bipyramid, corners with two equivalent O(16)Cd2Co3 trigonal bipyramids, corners with two equivalent O(4)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(1)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(14)Cd2Co3 trigonal bipyramid, edges with two equivalent O(15)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Co(3), one Co(4), one Co(6), one Cd(1), and one Cd(3) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(2)Cd2Co3 trigonal bipyramid, corners with two equivalent O(15)Cd2Co3 trigonal bipyramids, corners with two equivalent O(3)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(13)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(2)Cd2Co3 trigonal bipyramid, edges with two equivalent O(16)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Co(1), one Co(2), one Co(7), one Cd(1), and one Cd(3) atom to form distorted OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(4)Cd2Co3 trigonal bipyramid, corners with two equivalent O(1)Cd2Co3 trigonal bipyramids, corners with two equivalent O(14)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(16)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(4)Cd2Co3 trigonal bipyramid, edges with two equivalent O(13)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(10)CdCo3 trigonal pyramid, and  an edgeedge with one O(7)CdCo3 trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Co(3), one Co(4), one Co(8), one Cd(1), and one Cd(3) atom to form OCd2Co3 trigonal bipyramids that share  a cornercorner with one O(3)Cd2Co3 trigonal bipyramid, corners with two equivalent O(13)Cd2Co3 trigonal bipyramids, corners with two equivalent O(2)Cd2Co3 trigonal bipyramids,  a cornercorner with one O(7)CdCo3 trigonal pyramid,  a cornercorner with one O(8)CdCo3 trigonal pyramid,  an edgeedge with one O(15)Cd2Co3 trigonal bipyramid,  an edgeedge with one O(3)Cd2Co3 trigonal bipyramid, edges with two equivalent O(14)Cd2Co3 trigonal bipyramids,  an edgeedge with one O(8)CdCo3 trigonal pyramid, and  an edgeedge with one O(9)CdCo3 trigonal pyramid.