AgCuF3 crystallizes in the trigonal R-3c space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. Cu(1) is bonded to six equivalent F(1) atoms to form corner-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles are 22°. F(1) is bonded in a 3-coordinate geometry to one Ag(1) and two equivalent Cu(1) atoms.
AgCuF3 crystallizes in the trigonal R-3c space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. All Ag(1)-F(1) bond lengths are 2.42 Å. Cu(1) is bonded to six equivalent F(1) atoms to form corner-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles are 22°. All Cu(1)-F(1) bond lengths are 2.00 Å. F(1) is bonded in a 3-coordinate geometry to one Ag(1) and two equivalent Cu(1) atoms.