Tb(PO)2 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tb(PO)2 clusters. Tb(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one Tb(1) and one P(1) atom.
Tb(PO)2 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tb(PO)2 clusters. Tb(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. Both Tb(1)-O(1) bond lengths are 2.24 Å. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. The P(1)-O(1) bond length is 1.58 Å. O(1) is bonded in a water-like geometry to one Tb(1) and one P(1) atom.