InGa(AgTe2)2 is Stannite-like structured and crystallizes in the tetragonal I-4 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Te(1) atoms to form AgTe4 tetrahedra that share corners with four equivalent Ag(2)Te4 tetrahedra, corners with four equivalent In(1)Te4 tetrahedra, and corners with four equivalent Ga(1)Te4 tetrahedra. In the second Ag site, Ag(2) is bonded to four equivalent Te(1) atoms to form AgTe4 tetrahedra that share corners with four equivalent Ag(1)Te4 tetrahedra, corners with four equivalent In(1)Te4 tetrahedra, and corners with four equivalent Ga(1)Te4 tetrahedra. In(1) is bonded to four equivalent Te(1) atoms to form InTe4 tetrahedra that share corners with four equivalent Ag(1)Te4 tetrahedra, corners with four equivalent Ag(2)Te4 tetrahedra, and corners with four equivalent Ga(1)Te4 tetrahedra. Ga(1) is bonded to four equivalent Te(1) atoms to form GaTe4 tetrahedra that share corners with four equivalent Ag(1)Te4 tetrahedra, corners with four equivalent Ag(2)Te4 tetrahedra, and corners with four equivalent In(1)Te4 tetrahedra. Te(1) is bonded to one Ag(1), one Ag(2), one In(1), and one Ga(1) atom to form corner-sharing TeInGaAg2 tetrahedra.
InGa(AgTe2)2 is Stannite-like structured and crystallizes in the tetragonal I-4 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to four equivalent Te(1) atoms to form AgTe4 tetrahedra that share corners with four equivalent Ag(2)Te4 tetrahedra, corners with four equivalent In(1)Te4 tetrahedra, and corners with four equivalent Ga(1)Te4 tetrahedra. All Ag(1)-Te(1) bond lengths are 2.82 Å. In the second Ag site, Ag(2) is bonded to four equivalent Te(1) atoms to form AgTe4 tetrahedra that share corners with four equivalent Ag(1)Te4 tetrahedra, corners with four equivalent In(1)Te4 tetrahedra, and corners with four equivalent Ga(1)Te4 tetrahedra. All Ag(2)-Te(1) bond lengths are 2.81 Å. In(1) is bonded to four equivalent Te(1) atoms to form InTe4 tetrahedra that share corners with four equivalent Ag(1)Te4 tetrahedra, corners with four equivalent Ag(2)Te4 tetrahedra, and corners with four equivalent Ga(1)Te4 tetrahedra. All In(1)-Te(1) bond lengths are 2.84 Å. Ga(1) is bonded to four equivalent Te(1) atoms to form GaTe4 tetrahedra that share corners with four equivalent Ag(1)Te4 tetrahedra, corners with four equivalent Ag(2)Te4 tetrahedra, and corners with four equivalent In(1)Te4 tetrahedra. All Ga(1)-Te(1) bond lengths are 2.68 Å. Te(1) is bonded to one Ag(1), one Ag(2), one In(1), and one Ga(1) atom to form corner-sharing TeInGaAg2 tetrahedra.