CsN2H5 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 8-coordinate geometry to one H(3), two equivalent H(1), two equivalent H(4), and three equivalent H(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one H(3) and two equivalent H(4) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom.
CsN2H5 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 8-coordinate geometry to one H(3), two equivalent H(1), two equivalent H(4), and three equivalent H(2) atoms. The Cs(1)-H(3) bond length is 3.19 Å. There is one shorter (2.99 Å) and one longer (3.17 Å) Cs(1)-H(1) bond length. Both Cs(1)-H(4) bond lengths are 3.11 Å. There is one shorter (2.95 Å) and two longer (3.02 Å) Cs(1)-H(2) bond lengths. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one H(3) and two equivalent H(4) atoms. The N(2)-H(3) bond length is 1.02 Å. Both N(2)-H(4) bond lengths are 1.04 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom.