KCeF4 is Fluorite-derived structured and crystallizes in the tetragonal P4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent F(1) atoms. Ce(1) is bonded in a body-centered cubic geometry to eight equivalent F(1) atoms. F(1) is bonded to two equivalent K(1) and two equivalent Ce(1) atoms to form a mixture of corner and edge-sharing FK2Ce2 tetrahedra.
KCeF4 is Fluorite-derived structured and crystallizes in the tetragonal P4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent F(1) atoms. All K(1)-F(1) bond lengths are 2.68 Å. Ce(1) is bonded in a body-centered cubic geometry to eight equivalent F(1) atoms. All Ce(1)-F(1) bond lengths are 2.41 Å. F(1) is bonded to two equivalent K(1) and two equivalent Ce(1) atoms to form a mixture of corner and edge-sharing FK2Ce2 tetrahedra.