Ag2SnO3 crystallizes in the hexagonal P6_322 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share edges with three equivalent Sn(1)O6 octahedra and edges with three equivalent Sn(2)O6 octahedra. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share edges with three equivalent Ag(2)O6 octahedra and edges with three equivalent Sn(2)O6 octahedra. In the second Sn site, Sn(2) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share edges with three equivalent Ag(2)O6 octahedra and edges with three equivalent Sn(1)O6 octahedra. O(1) is bonded to one Ag(1), one Ag(2), one Sn(1), and one Sn(2) atom to form a mixture of distorted edge and corner-sharing OAg2Sn2 trigonal pyramids.
Ag2SnO3 crystallizes in the hexagonal P6_322 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.08 Å. In the second Ag site, Ag(2) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share edges with three equivalent Sn(1)O6 octahedra and edges with three equivalent Sn(2)O6 octahedra. All Ag(2)-O(1) bond lengths are 2.46 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share edges with three equivalent Ag(2)O6 octahedra and edges with three equivalent Sn(2)O6 octahedra. All Sn(1)-O(1) bond lengths are 2.08 Å. In the second Sn site, Sn(2) is bonded to six equivalent O(1) atoms to form SnO6 octahedra that share edges with three equivalent Ag(2)O6 octahedra and edges with three equivalent Sn(1)O6 octahedra. All Sn(2)-O(1) bond lengths are 2.08 Å. O(1) is bonded to one Ag(1), one Ag(2), one Sn(1), and one Sn(2) atom to form a mixture of distorted edge and corner-sharing OAg2Sn2 trigonal pyramids.