WOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two WOF4 clusters. W(1) is bonded in a 6-coordinate geometry to one O(1), one F(2), one F(3), one F(4), and two equivalent F(1) atoms. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to two equivalent W(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom.
WOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two WOF4 clusters. W(1) is bonded in a 6-coordinate geometry to one O(1), one F(2), one F(3), one F(4), and two equivalent F(1) atoms. The W(1)-O(1) bond length is 1.71 Å. The W(1)-F(2) bond length is 1.88 Å. The W(1)-F(3) bond length is 1.88 Å. The W(1)-F(4) bond length is 1.87 Å. There is one shorter (1.98 Å) and one longer (2.45 Å) W(1)-F(1) bond length. O(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to two equivalent W(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom.