Ti2FeRh5B2 crystallizes in the tetragonal P4/mbm space group. Ti(1) is bonded in a 13-coordinate geometry to two equivalent Rh(2), eight equivalent Rh(1), and three equivalent B(1) atoms. Fe(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to four equivalent Ti(1), two equivalent Fe(1), and two equivalent B(1) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent B(1) atoms. B(1) is bonded in a 9-coordinate geometry to three equivalent Ti(1), two equivalent Rh(2), and four equivalent Rh(1) atoms.
Ti2FeRh5B2 crystallizes in the tetragonal P4/mbm space group. Ti(1) is bonded in a 13-coordinate geometry to two equivalent Rh(2), eight equivalent Rh(1), and three equivalent B(1) atoms. Both Ti(1)-Rh(2) bond lengths are 2.75 Å. There are four shorter (2.78 Å) and four longer (2.92 Å) Ti(1)-Rh(1) bond lengths. There is one shorter (2.56 Å) and two longer (2.77 Å) Ti(1)-B(1) bond lengths. Fe(1) is bonded in a body-centered cubic geometry to eight equivalent Rh(1) atoms. All Fe(1)-Rh(1) bond lengths are 2.58 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to four equivalent Ti(1), two equivalent Fe(1), and two equivalent B(1) atoms. Both Rh(1)-B(1) bond lengths are 2.19 Å. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent B(1) atoms. All Rh(2)-B(1) bond lengths are 2.24 Å. B(1) is bonded in a 9-coordinate geometry to three equivalent Ti(1), two equivalent Rh(2), and four equivalent Rh(1) atoms.