CN2CN2SC2TeS2(N2Br)2TeSBr2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one cyanamide molecule, one C2TeS2(N2Br)2 cluster, one CN2S cluster, and one TeSBr2 cluster. In the C2TeS2(N2Br)2 cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a 3-coordinate geometry to one N(3), one N(7), and one S(3) atom. In the second C site, C(4) is bonded in a 3-coordinate geometry to one N(4), one N(8), and one S(4) atom. There are four inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to one C(3) and one N(7) atom. In the second N site, N(4) is bonded in a 2-coordinate geometry to one C(4) and one N(8) atom. In the third N site, N(7) is bonded in a 2-coordinate geometry to one C(3) and one N(3) atom. In the fourth N site, N(8) is bonded in a 2-coordinate geometry to one C(4) and one N(4) atom. Te(2) is bonded in a distorted rectangular see-saw-like geometry to one S(3), one S(4), one Br(3), and one Br(4) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one C(3) and one Te(2) atom. In the second S site, S(4) is bonded in a water-like geometry to one C(4) and one Te(2) atom. There are two inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Te(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one Te(2) atom. In the CN2S cluster, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(5), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(5) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the second N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(5) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. In the TeSBr2 cluster, Te(1) is bonded in a trigonal non-coplanar geometry to one S(2), one Br(1), and one Br(2) atom. S(2) is bonded in a single-bond geometry to one Te(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom.
CN2CN2SC2TeS2(N2Br)2TeSBr2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one cyanamide molecule, one C2TeS2(N2Br)2 cluster, one CN2S cluster, and one TeSBr2 cluster. In the C2TeS2(N2Br)2 cluster, there are two inequivalent C sites. In the first C site, C(3) is bonded in a 3-coordinate geometry to one N(3), one N(7), and one S(3) atom. The C(3)-N(3) bond length is 1.39 Å. The C(3)-N(7) bond length is 1.39 Å. The C(3)-S(3) bond length is 1.60 Å. In the second C site, C(4) is bonded in a 3-coordinate geometry to one N(4), one N(8), and one S(4) atom. The C(4)-N(4) bond length is 1.39 Å. The C(4)-N(8) bond length is 1.40 Å. The C(4)-S(4) bond length is 1.59 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to one C(3) and one N(7) atom. The N(3)-N(7) bond length is 1.30 Å. In the second N site, N(4) is bonded in a 2-coordinate geometry to one C(4) and one N(8) atom. The N(4)-N(8) bond length is 1.31 Å. In the third N site, N(7) is bonded in a 2-coordinate geometry to one C(3) and one N(3) atom. In the fourth N site, N(8) is bonded in a 2-coordinate geometry to one C(4) and one N(4) atom. Te(2) is bonded in a distorted rectangular see-saw-like geometry to one S(3), one S(4), one Br(3), and one Br(4) atom. The Te(2)-S(3) bond length is 3.08 Å. The Te(2)-S(4) bond length is 2.98 Å. The Te(2)-Br(3) bond length is 2.58 Å. The Te(2)-Br(4) bond length is 2.57 Å. There are two inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to one C(3) and one Te(2) atom. In the second S site, S(4) is bonded in a water-like geometry to one C(4) and one Te(2) atom. There are two inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Te(2) atom. In the second Br site, Br(4) is bonded in a single-bond geometry to one Te(2) atom. In the CN2S cluster, C(1) is bonded in a 3-coordinate geometry to one N(1), one N(5), and one S(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-N(5) bond length is 1.40 Å. The C(1)-S(1) bond length is 1.59 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. The N(5)-N(1) bond length is 1.30 Å. In the second N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(5) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. In the TeSBr2 cluster, Te(1) is bonded in a trigonal non-coplanar geometry to one S(2), one Br(1), and one Br(2) atom. The Te(1)-S(2) bond length is 2.24 Å. The Te(1)-Br(1) bond length is 2.60 Å. The Te(1)-Br(2) bond length is 2.58 Å. S(2) is bonded in a single-bond geometry to one Te(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Te(1) atom.