V6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), one O(6), one F(2), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(3)O3F3 octahedra, corners with three equivalent V(6)O3F3 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(4), one O(6), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra,  an edgeedge with one V(3)O3F3 octahedra, and  an edgeedge with one V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the third V site, V(3) is bonded to one O(3), one O(4), one O(7), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(6)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the fourth V site, V(4) is bonded to one O(2), one O(4), one O(5), one O(7), one F(1), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O3F3 octahedra, corners with three equivalent V(6)O3F3 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the fifth V site, V(5) is bonded to one O(1), one O(6), one O(7), one F(1), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(6)O3F3 octahedra, corners with three equivalent V(3)O3F3 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. In the sixth V site, V(6) is bonded to one O(2), one O(3), one O(5), one F(3), one F(4), and one F(5) atom to form VO3F3 octahedra that share corners with two equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(3)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom.
V6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), one O(6), one F(2), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(3)O3F3 octahedra, corners with three equivalent V(6)O3F3 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. The V(1)-O(1) bond length is 1.98 Å. The V(1)-O(3) bond length is 1.80 Å. The V(1)-O(5) bond length is 1.97 Å. The V(1)-O(6) bond length is 1.86 Å. The V(1)-F(2) bond length is 2.20 Å. The V(1)-F(5) bond length is 2.16 Å. In the second V site, V(2) is bonded to one O(1), one O(2), one O(4), one O(6), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(4)O4F2 octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra,  an edgeedge with one V(3)O3F3 octahedra, and  an edgeedge with one V(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. The V(2)-O(1) bond length is 2.01 Å. The V(2)-O(2) bond length is 2.01 Å. The V(2)-O(4) bond length is 2.04 Å. The V(2)-O(6) bond length is 2.02 Å. The V(2)-F(2) bond length is 2.07 Å. The V(2)-F(4) bond length is 2.07 Å. In the third V site, V(3) is bonded to one O(3), one O(4), one O(7), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O3F3 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(6)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. The V(3)-O(3) bond length is 2.05 Å. The V(3)-O(4) bond length is 1.91 Å. The V(3)-O(7) bond length is 1.91 Å. The V(3)-F(1) bond length is 2.08 Å. The V(3)-F(2) bond length is 2.12 Å. The V(3)-F(3) bond length is 2.16 Å. In the fourth V site, V(4) is bonded to one O(2), one O(4), one O(5), one O(7), one F(1), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with three equivalent V(3)O3F3 octahedra, corners with three equivalent V(6)O3F3 octahedra,  an edgeedge with one V(5)O3F3 octahedra, and  an edgeedge with one V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. The V(4)-O(2) bond length is 2.00 Å. The V(4)-O(4) bond length is 2.03 Å. The V(4)-O(5) bond length is 2.01 Å. The V(4)-O(7) bond length is 1.99 Å. The V(4)-F(1) bond length is 2.15 Å. The V(4)-F(5) bond length is 2.14 Å. In the fifth V site, V(5) is bonded to one O(1), one O(6), one O(7), one F(1), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(6)O3F3 octahedra, corners with three equivalent V(3)O3F3 octahedra, corners with three equivalent V(2)O4F2 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. The V(5)-O(1) bond length is 1.95 Å. The V(5)-O(6) bond length is 2.02 Å. The V(5)-O(7) bond length is 1.97 Å. The V(5)-F(1) bond length is 2.13 Å. The V(5)-F(3) bond length is 2.01 Å. The V(5)-F(4) bond length is 2.03 Å. In the sixth V site, V(6) is bonded to one O(2), one O(3), one O(5), one F(3), one F(4), and one F(5) atom to form VO3F3 octahedra that share corners with two equivalent V(5)O3F3 octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(4)O4F2 octahedra,  an edgeedge with one V(3)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-56°. The V(6)-O(2) bond length is 1.95 Å. The V(6)-O(3) bond length is 2.07 Å. The V(6)-O(5) bond length is 1.91 Å. The V(6)-F(3) bond length is 2.09 Å. The V(6)-F(4) bond length is 2.06 Å. The V(6)-F(5) bond length is 2.11 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom.