NaPF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent P(1)F6 octahedra. The corner-sharing octahedra are not tilted. P(1) is bonded to six equivalent F(1) atoms to form PF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Na(1) and one P(1) atom.
NaPF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. Na(1) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent P(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-F(1) bond lengths are 2.24 Å. P(1) is bonded to six equivalent F(1) atoms to form PF6 octahedra that share corners with six equivalent Na(1)F6 octahedra. The corner-sharing octahedra are not tilted. All P(1)-F(1) bond lengths are 1.61 Å. F(1) is bonded in a linear geometry to one Na(1) and one P(1) atom.