V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(4), one F(2), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(3)O3F3 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O3F3 octahedra,  an edgeedge with one V(5)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the second V site, V(2) is bonded to one O(3), two equivalent O(1), one F(1), one F(2), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the third V site, V(3) is bonded to one O(3), two equivalent O(2), one F(2), one F(3), and one F(5) atom to form VO3F3 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the fourth V site, V(4) is bonded to one O(3), two equivalent O(2), two equivalent O(4), and one F(1) atom to form distorted VO5F octahedra that share corners with two equivalent V(2)O3F3 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(3)O3F3 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. In the fifth V site, V(5) is bonded to two equivalent O(1), two equivalent O(2), one F(3), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O3F3 octahedra, corners with three equivalent V(3)O3F3 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-53°. In the sixth V site, V(6) is bonded to two equivalent O(4), one F(1), one F(3), one F(4), and one F(5) atom to form VO2F4 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(2)O3F3 octahedra, and  an edgeedge with one V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one V(2), one V(4), and one V(6) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(6) atom.
V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(4), one F(2), and one F(5) atom to form VO4F2 octahedra that share corners with two equivalent V(3)O3F3 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O3F3 octahedra,  an edgeedge with one V(5)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-52°. Both V(1)-O(1) bond lengths are 1.99 Å. Both V(1)-O(4) bond lengths are 2.01 Å. The V(1)-F(2) bond length is 2.11 Å. The V(1)-F(5) bond length is 2.12 Å. In the second V site, V(2) is bonded to one O(3), two equivalent O(1), one F(1), one F(2), and one F(4) atom to form VO3F3 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. The V(2)-O(3) bond length is 2.05 Å. Both V(2)-O(1) bond lengths are 1.93 Å. The V(2)-F(1) bond length is 2.10 Å. The V(2)-F(2) bond length is 2.05 Å. The V(2)-F(4) bond length is 2.06 Å. In the third V site, V(3) is bonded to one O(3), two equivalent O(2), one F(2), one F(3), and one F(5) atom to form VO3F3 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with three equivalent V(5)O4F2 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(6)O2F4 octahedra, and  an edgeedge with one V(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. The V(3)-O(3) bond length is 1.99 Å. Both V(3)-O(2) bond lengths are 1.96 Å. The V(3)-F(2) bond length is 2.07 Å. The V(3)-F(3) bond length is 2.09 Å. The V(3)-F(5) bond length is 2.04 Å. In the fourth V site, V(4) is bonded to one O(3), two equivalent O(2), two equivalent O(4), and one F(1) atom to form distorted VO5F octahedra that share corners with two equivalent V(2)O3F3 octahedra, corners with three equivalent V(6)O2F4 octahedra, corners with three equivalent V(3)O3F3 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. The V(4)-O(3) bond length is 1.82 Å. Both V(4)-O(2) bond lengths are 1.96 Å. Both V(4)-O(4) bond lengths are 1.99 Å. The V(4)-F(1) bond length is 2.39 Å. In the fifth V site, V(5) is bonded to two equivalent O(1), two equivalent O(2), one F(3), and one F(4) atom to form VO4F2 octahedra that share corners with two equivalent V(6)O2F4 octahedra, corners with three equivalent V(2)O3F3 octahedra, corners with three equivalent V(3)O3F3 octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 47-53°. Both V(5)-O(1) bond lengths are 1.99 Å. Both V(5)-O(2) bond lengths are 2.02 Å. The V(5)-F(3) bond length is 2.13 Å. The V(5)-F(4) bond length is 2.12 Å. In the sixth V site, V(6) is bonded to two equivalent O(4), one F(1), one F(3), one F(4), and one F(5) atom to form VO2F4 octahedra that share corners with two equivalent V(5)O4F2 octahedra, corners with three equivalent V(1)O4F2 octahedra, corners with three equivalent V(4)O5F octahedra,  an edgeedge with one V(2)O3F3 octahedra, and  an edgeedge with one V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. Both V(6)-O(4) bond lengths are 1.95 Å. The V(6)-F(1) bond length is 2.03 Å. The V(6)-F(3) bond length is 2.04 Å. The V(6)-F(4) bond length is 2.05 Å. The V(6)-F(5) bond length is 2.05 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one V(2), one V(4), and one V(6) atom. In the second F site, F(2) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(6) atom.