Cd(AsO3)2 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with twelve equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. As(1) is bonded to six equivalent O(1) atoms to form AsO6 octahedra that share corners with six equivalent Cd(1)O6 octahedra and edges with three equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a distorted trigonal planar geometry to one Cd(1) and two equivalent As(1) atoms.
Cd(AsO3)2 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with twelve equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. All Cd(1)-O(1) bond lengths are 2.32 Å. As(1) is bonded to six equivalent O(1) atoms to form AsO6 octahedra that share corners with six equivalent Cd(1)O6 octahedra and edges with three equivalent As(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. All As(1)-O(1) bond lengths are 1.84 Å. O(1) is bonded in a distorted trigonal planar geometry to one Cd(1) and two equivalent As(1) atoms.