Ag2Br3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ag(1) is bonded to six equivalent Br(1) atoms to form a mixture of edge, face, and corner-sharing AgBr6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. Br(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Ag(1) atoms.
Ag2Br3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ag(1) is bonded to six equivalent Br(1) atoms to form a mixture of edge, face, and corner-sharing AgBr6 octahedra. The corner-sharing octahedral tilt angles range from 48-53°. There are three shorter (2.77 Å) and three longer (2.81 Å) Ag(1)-Br(1) bond lengths. Br(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Ag(1) atoms.