V6GeSi crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Ge(1), and two equivalent Si(1) atoms. Ge(1) is bonded to twelve equivalent V(1) atoms to form GeV12 cuboctahedra that share edges with six equivalent Ge(1)V12 cuboctahedra and faces with eight equivalent Si(1)V12 cuboctahedra. Si(1) is bonded to twelve equivalent V(1) atoms to form SiV12 cuboctahedra that share edges with six equivalent Si(1)V12 cuboctahedra and faces with eight equivalent Ge(1)V12 cuboctahedra.
V6GeSi crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Ge(1), and two equivalent Si(1) atoms. There is one shorter (2.30 Å) and one longer (2.41 Å) V(1)-V(1) bond length. Both V(1)-Ge(1) bond lengths are 2.65 Å. Both V(1)-Si(1) bond lengths are 2.62 Å. Ge(1) is bonded to twelve equivalent V(1) atoms to form GeV12 cuboctahedra that share edges with six equivalent Ge(1)V12 cuboctahedra and faces with eight equivalent Si(1)V12 cuboctahedra. Si(1) is bonded to twelve equivalent V(1) atoms to form SiV12 cuboctahedra that share edges with six equivalent Si(1)V12 cuboctahedra and faces with eight equivalent Ge(1)V12 cuboctahedra.