LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(6), one O(7), two equivalent O(2), and two equivalent O(5) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(7) atom. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(6) atom. S(1) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one H(1), and one O(7) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent La(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one La(1), one N(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one La(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent La(1) and one N(1) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one La(1), one H(2), and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one La(1), one H(1), and one O(1) atom.
LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(6), one O(7), two equivalent O(2), and two equivalent O(5) atoms. The La(1)-O(1) bond length is 2.24 Å. The La(1)-O(3) bond length is 2.58 Å. The La(1)-O(4) bond length is 2.50 Å. The La(1)-O(6) bond length is 2.77 Å. The La(1)-O(7) bond length is 2.50 Å. There is one shorter (2.49 Å) and one longer (3.06 Å) La(1)-O(2) bond length. There is one shorter (2.73 Å) and one longer (3.15 Å) La(1)-O(5) bond length. N(1) is bonded in a bent 120 degrees geometry to one O(3) and one O(5) atom. The N(1)-O(3) bond length is 1.30 Å. The N(1)-O(5) bond length is 1.26 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(7) atom. The H(1)-O(1) bond length is 1.56 Å. The H(1)-O(7) bond length is 1.03 Å. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(6) atom. The H(2)-O(3) bond length is 1.59 Å. The H(2)-O(6) bond length is 1.03 Å. S(1) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. The S(1)-O(2) bond length is 1.54 Å. The S(1)-O(4) bond length is 1.51 Å. The S(1)-O(6) bond length is 1.66 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one H(1), and one O(7) atom. The O(1)-O(7) bond length is 1.47 Å. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent La(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one La(1), one N(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one La(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent La(1) and one N(1) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one La(1), one H(2), and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one La(1), one H(1), and one O(1) atom.