RhInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 42-45°. In(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of edge and corner-sharing OIn2Rh2 trigonal pyramids. In the second O site, O(2) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 trigonal pyramids.
RhInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 42-45°. Both Rh(1)-O(1) bond lengths are 2.13 Å. All Rh(1)-O(2) bond lengths are 2.05 Å. In(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. Both In(1)-O(1) bond lengths are 2.20 Å. There are two shorter (2.18 Å) and two longer (2.40 Å) In(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of edge and corner-sharing OIn2Rh2 trigonal pyramids. In the second O site, O(2) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 trigonal pyramids.