TiS2 is trigonal omega-like structured and crystallizes in the cubic Fd-3m space group. Ti(1) is bonded to six equivalent S(1) atoms to form edge-sharing TiS6 octahedra. S(1) is bonded in a distorted T-shaped geometry to three equivalent Ti(1) atoms.
TiS2 is trigonal omega-like structured and crystallizes in the cubic Fd-3m space group. Ti(1) is bonded to six equivalent S(1) atoms to form edge-sharing TiS6 octahedra. All Ti(1)-S(1) bond lengths are 2.43 Å. S(1) is bonded in a distorted T-shaped geometry to three equivalent Ti(1) atoms.