CsAg2Cu(CN)4 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent C(1), two equivalent C(2), four equivalent N(1), and four equivalent N(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent C(2) atoms. Cu(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Cs(1), one Ag(1), and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Cs(1), one Ag(2), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to two equivalent Cs(1), one Cu(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Cs(1), one Cu(1), and one C(2) atom.
CsAg2Cu(CN)4 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent C(1), two equivalent C(2), four equivalent N(1), and four equivalent N(2) atoms. Both Cs(1)-C(1) bond lengths are 3.44 Å. Both Cs(1)-C(2) bond lengths are 3.42 Å. There are two shorter (3.40 Å) and two longer (3.48 Å) Cs(1)-N(1) bond lengths. All Cs(1)-N(2) bond lengths are 3.45 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. Both Ag(1)-C(1) bond lengths are 2.06 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent C(2) atoms. Both Ag(2)-C(2) bond lengths are 2.06 Å. Cu(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 1.97 Å. Both Cu(1)-N(2) bond lengths are 1.99 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Cs(1), one Ag(1), and one N(1) atom. The C(1)-N(1) bond length is 1.18 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one Cs(1), one Ag(2), and one N(2) atom. The C(2)-N(2) bond length is 1.17 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to two equivalent Cs(1), one Cu(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Cs(1), one Cu(1), and one C(2) atom.