ZrCdF7Tl crystallizes in the orthorhombic Cmcm space group. The structure consists of four 7440-28-0 atoms inside a ZrCdF7 framework. In the ZrCdF7 framework, Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Cd(1)F7 pentagonal bipyramids and edges with two equivalent Cd(1)F7 pentagonal bipyramids. Cd(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form CdF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. There are four inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Zr(1) and one Cd(1) atom. In the second F site, F(2) is bonded in a water-like geometry to one Zr(1) and one Cd(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Zr(1) and one Cd(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Cd(1) atom.
ZrCdF7Tl crystallizes in the orthorhombic Cmcm space group. The structure consists of four 7440-28-0 atoms inside a ZrCdF7 framework. In the ZrCdF7 framework, Zr(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Cd(1)F7 pentagonal bipyramids and edges with two equivalent Cd(1)F7 pentagonal bipyramids. The Zr(1)-F(4) bond length is 2.06 Å. Both Zr(1)-F(1) bond lengths are 2.05 Å. Both Zr(1)-F(2) bond lengths are 2.13 Å. Both Zr(1)-F(3) bond lengths are 2.14 Å. Cd(1) is bonded to one F(4), two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form CdF7 pentagonal bipyramids that share corners with three equivalent Zr(1)F7 pentagonal bipyramids and edges with two equivalent Zr(1)F7 pentagonal bipyramids. The Cd(1)-F(4) bond length is 2.28 Å. Both Cd(1)-F(1) bond lengths are 2.28 Å. Both Cd(1)-F(2) bond lengths are 2.37 Å. Both Cd(1)-F(3) bond lengths are 2.29 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Zr(1) and one Cd(1) atom. In the second F site, F(2) is bonded in a water-like geometry to one Zr(1) and one Cd(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Zr(1) and one Cd(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Cd(1) atom.