V2Cu3Pb(O4Cl)2 crystallizes in the orthorhombic Ibam space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. In the second Cu site, Cu(2) is bonded in a trigonal planar geometry to two equivalent O(1) and one Cl(1) atom. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1), one Cu(2), and one Pb(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one Cu(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Cu(2) and two equivalent Pb(1) atoms.
V2Cu3Pb(O4Cl)2 crystallizes in the orthorhombic Ibam space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both V(1)-O(1) bond lengths are 1.75 Å. Both V(1)-O(2) bond lengths are 1.75 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. All Cu(1)-O(2) bond lengths are 1.86 Å. In the second Cu site, Cu(2) is bonded in a trigonal planar geometry to two equivalent O(1) and one Cl(1) atom. Both Cu(2)-O(1) bond lengths are 1.90 Å. The Cu(2)-Cl(1) bond length is 2.23 Å. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. All Pb(1)-O(1) bond lengths are 2.66 Å. All Pb(1)-Cl(1) bond lengths are 3.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1), one Cu(2), and one Pb(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one Cu(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Cu(2) and two equivalent Pb(1) atoms.