Si(AgP)2 crystallizes in the tetragonal I-42d space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent P(1) atoms. Si(1) is bonded to four equivalent P(1) atoms to form corner-sharing SiP4 tetrahedra. P(1) is bonded to three equivalent Ag(1) and two equivalent Si(1) atoms to form distorted corner-sharing PSi2Ag3 trigonal bipyramids.
Si(AgP)2 crystallizes in the tetragonal I-42d space group. Ag(1) is bonded in a trigonal planar geometry to three equivalent P(1) atoms. There is one shorter (2.51 Å) and two longer (2.55 Å) Ag(1)-P(1) bond lengths. Si(1) is bonded to four equivalent P(1) atoms to form corner-sharing SiP4 tetrahedra. All Si(1)-P(1) bond lengths are 2.25 Å. P(1) is bonded to three equivalent Ag(1) and two equivalent Si(1) atoms to form distorted corner-sharing PSi2Ag3 trigonal bipyramids.