ZnF2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Zn(1) is bonded to six equivalent F(1) atoms to form a mixture of edge and corner-sharing ZnF6 octahedra. The corner-sharing octahedral tilt angles are 50°. F(1) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms.
ZnF2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. Zn(1) is bonded to six equivalent F(1) atoms to form a mixture of edge and corner-sharing ZnF6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two shorter (2.02 Å) and four longer (2.04 Å) Zn(1)-F(1) bond lengths. F(1) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms.