Pt(NH3)4SnCl6 is Halite, Rock Salt structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four Pt(NH3)4 clusters and four SnCl6 clusters. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each SnCl6 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom.
Pt(NH3)4SnCl6 is Halite, Rock Salt structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four Pt(NH3)4 clusters and four SnCl6 clusters. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Pt(1)-N(1) bond lengths are 2.07 Å. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each SnCl6 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. Both Sn(1)-Cl(2) bond lengths are 2.45 Å. All Sn(1)-Cl(1) bond lengths are 2.49 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom.