TcAgO2 crystallizes in the tetragonal I4_1/amd space group. Tc(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Ag(1) is bonded to six equivalent O(1) atoms to form edge-sharing AgO6 octahedra. O(1) is bonded in a 5-coordinate geometry to two equivalent Tc(1) and three equivalent Ag(1) atoms.
TcAgO2 crystallizes in the tetragonal I4_1/amd space group. Tc(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. All Tc(1)-O(1) bond lengths are 2.03 Å. Ag(1) is bonded to six equivalent O(1) atoms to form edge-sharing AgO6 octahedra. There are two shorter (2.37 Å) and four longer (2.45 Å) Ag(1)-O(1) bond lengths. O(1) is bonded in a 5-coordinate geometry to two equivalent Tc(1) and three equivalent Ag(1) atoms.