CsK2VF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to six equivalent F(1) atoms to form CsF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedra are not tilted. K(1) is bonded in a 12-coordinate geometry to twelve equivalent F(1) atoms. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Cs(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted linear geometry to one Cs(1), four equivalent K(1), and one V(1) atom.
CsK2VF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to six equivalent F(1) atoms to form CsF6 octahedra that share corners with six equivalent V(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Cs(1)-F(1) bond lengths are 2.77 Å. K(1) is bonded in a 12-coordinate geometry to twelve equivalent F(1) atoms. All K(1)-F(1) bond lengths are 3.37 Å. V(1) is bonded to six equivalent F(1) atoms to form VF6 octahedra that share corners with six equivalent Cs(1)F6 octahedra. The corner-sharing octahedra are not tilted. All V(1)-F(1) bond lengths are 1.96 Å. F(1) is bonded in a distorted linear geometry to one Cs(1), four equivalent K(1), and one V(1) atom.