LiCuVO4 crystallizes in the orthorhombic Imma space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. V(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cu(1) atoms.
LiCuVO4 crystallizes in the orthorhombic Imma space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Li(1)-O(1) bond lengths are 2.17 Å. V(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both V(1)-O(1) bond lengths are 1.69 Å. Both V(1)-O(2) bond lengths are 1.84 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. All Cu(1)-O(2) bond lengths are 1.95 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cu(1) atoms.