(ReOCl3)3O2 is Indium-derived structured and crystallizes in the orthorhombic Ama2 space group. The structure is zero-dimensional and consists of eight water atoms and four ReOCl3 clusters. In each ReOCl3 cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(4), one Cl(6), and two equivalent Cl(1) atoms. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one O(3), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms. In the third Re site, Re(3) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one Cl(4), one Cl(5), and two equivalent Cl(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(3) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a bent 120 degrees geometry to one Re(2) and one Re(3) atom. In the sixth Cl site, Cl(6) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom.
(ReOCl3)3O2 is Indium-derived structured and crystallizes in the orthorhombic Ama2 space group. The structure is zero-dimensional and consists of eight water atoms and four ReOCl3 clusters. In each ReOCl3 cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(4), one Cl(6), and two equivalent Cl(1) atoms. The Re(1)-O(1) bond length is 1.68 Å. The Re(1)-Cl(4) bond length is 2.55 Å. The Re(1)-Cl(6) bond length is 2.42 Å. Both Re(1)-Cl(1) bond lengths are 2.27 Å. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one O(3), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms. The Re(2)-O(3) bond length is 1.69 Å. The Re(2)-Cl(5) bond length is 2.45 Å. The Re(2)-Cl(6) bond length is 2.50 Å. Both Re(2)-Cl(3) bond lengths are 2.27 Å. In the third Re site, Re(3) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one Cl(4), one Cl(5), and two equivalent Cl(2) atoms. The Re(3)-O(2) bond length is 1.69 Å. The Re(3)-Cl(4) bond length is 2.40 Å. The Re(3)-Cl(5) bond length is 2.47 Å. Both Re(3)-Cl(2) bond lengths are 2.28 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(3) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a bent 120 degrees geometry to one Re(2) and one Re(3) atom. In the sixth Cl site, Cl(6) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom.