PdCu crystallizes in the trigonal R-3m space group. Pd(1) is bonded to six equivalent Pd(1) and six equivalent Cu(1) atoms to form distorted PdCu6Pd6 cuboctahedra that share corners with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra, faces with six equivalent Pd(1)Cu6Pd6 cuboctahedra, and faces with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra. Cu(1) is bonded to six equivalent Pd(1) and six equivalent Cu(1) atoms to form distorted CuCu6Pd6 cuboctahedra that share corners with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra, faces with six equivalent Cu(1)Cu6Pd6 cuboctahedra, and faces with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra.
PdCu crystallizes in the trigonal R-3m space group. Pd(1) is bonded to six equivalent Pd(1) and six equivalent Cu(1) atoms to form distorted PdCu6Pd6 cuboctahedra that share corners with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra, faces with six equivalent Pd(1)Cu6Pd6 cuboctahedra, and faces with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra. All Pd(1)-Pd(1) bond lengths are 2.71 Å. All Pd(1)-Cu(1) bond lengths are 2.63 Å. Cu(1) is bonded to six equivalent Pd(1) and six equivalent Cu(1) atoms to form distorted CuCu6Pd6 cuboctahedra that share corners with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra, edges with twelve equivalent Cu(1)Cu6Pd6 cuboctahedra, faces with six equivalent Cu(1)Cu6Pd6 cuboctahedra, and faces with twelve equivalent Pd(1)Cu6Pd6 cuboctahedra. All Cu(1)-Cu(1) bond lengths are 2.71 Å.