VFeP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Fe(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing FeP4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Fe(1) atoms.
VFeP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. There are a spread of V(1)-P(1) bond distances ranging from 2.46-2.52 Å. Fe(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted corner and edge-sharing FeP4 tetrahedra. There are a spread of Fe(1)-P(1) bond distances ranging from 2.21-2.24 Å. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Fe(1) atoms.