CsO3Cl is Potassium chlorate-like structured and crystallizes in the trigonal R3m space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.
CsO3Cl is Potassium chlorate-like structured and crystallizes in the trigonal R3m space group. Cs(1) is bonded in a 9-coordinate geometry to nine equivalent O(1) atoms. There are three shorter (3.21 Å) and six longer (3.39 Å) Cs(1)-O(1) bond lengths. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.51 Å. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.