CsLi2C is Heusler structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded in a 14-coordinate geometry to eight equivalent Li(1) and six equivalent C(1) atoms. Li(1) is bonded to four equivalent Cs(1) atoms to form a mixture of distorted corner and edge-sharing LiCs4 tetrahedra. C(1) is bonded in a 6-coordinate geometry to six equivalent Cs(1) atoms.
CsLi2C is Heusler structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded in a 14-coordinate geometry to eight equivalent Li(1) and six equivalent C(1) atoms. All Cs(1)-Li(1) bond lengths are 2.91 Å. All Cs(1)-C(1) bond lengths are 3.37 Å. Li(1) is bonded to four equivalent Cs(1) atoms to form a mixture of distorted corner and edge-sharing LiCs4 tetrahedra. C(1) is bonded in a 6-coordinate geometry to six equivalent Cs(1) atoms.