LiSr2CN2Br3 crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent Br(1) atoms to form corner-sharing LiBr6 octahedra. The corner-sharing octahedral tilt angles are 44°. Sr(1) is bonded in a 6-coordinate geometry to three equivalent N(1) and six equivalent Br(1) atoms. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to three equivalent Sr(1) and one C(1) atom to form a mixture of distorted corner and edge-sharing NSr3C tetrahedra. Br(1) is bonded in a 6-coordinate geometry to two equivalent Li(1) and four equivalent Sr(1) atoms.
LiSr2CN2Br3 crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent Br(1) atoms to form corner-sharing LiBr6 octahedra. The corner-sharing octahedral tilt angles are 44°. All Li(1)-Br(1) bond lengths are 2.81 Å. Sr(1) is bonded in a 6-coordinate geometry to three equivalent N(1) and six equivalent Br(1) atoms. All Sr(1)-N(1) bond lengths are 2.59 Å. There are three shorter (3.27 Å) and three longer (3.67 Å) Sr(1)-Br(1) bond lengths. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both C(1)-N(1) bond lengths are 1.23 Å. N(1) is bonded to three equivalent Sr(1) and one C(1) atom to form a mixture of distorted corner and edge-sharing NSr3C tetrahedra. Br(1) is bonded in a 6-coordinate geometry to two equivalent Li(1) and four equivalent Sr(1) atoms.