W2CO is Tungsten Carbide-derived structured and crystallizes in the hexagonal P-6m2 space group. W(1) is bonded to three equivalent C(1) and three equivalent O(1) atoms to form a mixture of distorted corner, face, and edge-sharing WC3O3 pentagonal pyramids. C(1) is bonded to six equivalent W(1) atoms to form distorted CW6 pentagonal pyramids that share corners with twelve equivalent O(1)W6 pentagonal pyramids, edges with six equivalent C(1)W6 pentagonal pyramids, and faces with two equivalent O(1)W6 pentagonal pyramids. O(1) is bonded to six equivalent W(1) atoms to form distorted OW6 pentagonal pyramids that share corners with twelve equivalent C(1)W6 pentagonal pyramids, edges with six equivalent O(1)W6 pentagonal pyramids, and faces with two equivalent C(1)W6 pentagonal pyramids.
W2CO is Tungsten Carbide-derived structured and crystallizes in the hexagonal P-6m2 space group. W(1) is bonded to three equivalent C(1) and three equivalent O(1) atoms to form a mixture of distorted corner, face, and edge-sharing WC3O3 pentagonal pyramids. All W(1)-C(1) bond lengths are 2.19 Å. All W(1)-O(1) bond lengths are 2.39 Å. C(1) is bonded to six equivalent W(1) atoms to form distorted CW6 pentagonal pyramids that share corners with twelve equivalent O(1)W6 pentagonal pyramids, edges with six equivalent C(1)W6 pentagonal pyramids, and faces with two equivalent O(1)W6 pentagonal pyramids. O(1) is bonded to six equivalent W(1) atoms to form distorted OW6 pentagonal pyramids that share corners with twelve equivalent C(1)W6 pentagonal pyramids, edges with six equivalent O(1)W6 pentagonal pyramids, and faces with two equivalent C(1)W6 pentagonal pyramids.