RbSrCO3F crystallizes in the hexagonal P-6m2 space group. Rb(1) is bonded in a distorted q6 geometry to six equivalent O(1) and three equivalent F(1) atoms. Sr(1) is bonded to six equivalent O(1) and two equivalent F(1) atoms to form corner-sharing SrO6F2 hexagonal bipyramids. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Sr(1), and one C(1) atom. F(1) is bonded to three equivalent Rb(1) and two equivalent Sr(1) atoms to form corner-sharing FRb3Sr2 trigonal bipyramids.
RbSrCO3F crystallizes in the hexagonal P-6m2 space group. Rb(1) is bonded in a distorted q6 geometry to six equivalent O(1) and three equivalent F(1) atoms. All Rb(1)-O(1) bond lengths are 3.03 Å. All Rb(1)-F(1) bond lengths are 3.10 Å. Sr(1) is bonded to six equivalent O(1) and two equivalent F(1) atoms to form corner-sharing SrO6F2 hexagonal bipyramids. All Sr(1)-O(1) bond lengths are 2.70 Å. Both Sr(1)-F(1) bond lengths are 2.43 Å. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All C(1)-O(1) bond lengths are 1.30 Å. O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Sr(1), and one C(1) atom. F(1) is bonded to three equivalent Rb(1) and two equivalent Sr(1) atoms to form corner-sharing FRb3Sr2 trigonal bipyramids.