AgMnO4 crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. Ag(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mn(1) and two equivalent Ag(1) atoms.
AgMnO4 crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. The Mn(1)-O(1) bond length is 1.63 Å. The Mn(1)-O(2) bond length is 1.64 Å. Both Mn(1)-O(3) bond lengths are 1.63 Å. Ag(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), and four equivalent O(3) atoms. The Ag(1)-O(1) bond length is 2.20 Å. The Ag(1)-O(2) bond length is 2.17 Å. There are two shorter (2.76 Å) and two longer (2.77 Å) Ag(1)-O(3) bond lengths. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mn(1) and two equivalent Ag(1) atoms.