MgTi2O4 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. In the second Ti site, Ti(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing TiO6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ti(1) and two equivalent Ti(2) atoms. In the second O site, O(2) is bonded in a square co-planar geometry to two equivalent Mg(1) and two equivalent Ti(2) atoms. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one Ti(2), and two equivalent Ti(1) atoms.
MgTi2O4 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. Both Mg(1)-O(2) bond lengths are 1.93 Å. Both Mg(1)-O(3) bond lengths are 2.04 Å. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. The Ti(1)-O(1) bond length is 1.88 Å. All Ti(1)-O(3) bond lengths are 2.08 Å. In the second Ti site, Ti(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing TiO6 octahedra. Both Ti(2)-O(1) bond lengths are 2.06 Å. Both Ti(2)-O(2) bond lengths are 2.12 Å. Both Ti(2)-O(3) bond lengths are 2.02 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ti(1) and two equivalent Ti(2) atoms. In the second O site, O(2) is bonded in a square co-planar geometry to two equivalent Mg(1) and two equivalent Ti(2) atoms. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one Ti(2), and two equivalent Ti(1) atoms.