Ag3VO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(2), and two equivalent Ag(1) atoms to form distorted corner-sharing OVAg3 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one V(1), one Ag(2), and two equivalent Ag(1) atoms.
Ag3VO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both V(1)-O(1) bond lengths are 1.75 Å. Both V(1)-O(2) bond lengths are 1.73 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There is one shorter (2.15 Å) and one longer (2.46 Å) Ag(1)-O(1) bond length. There is one shorter (2.17 Å) and one longer (2.53 Å) Ag(1)-O(2) bond length. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ag(2)-O(1) bond lengths are 2.33 Å. Both Ag(2)-O(2) bond lengths are 2.40 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(2), and two equivalent Ag(1) atoms to form distorted corner-sharing OVAg3 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one V(1), one Ag(2), and two equivalent Ag(1) atoms.