KPrWZnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Pr(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. Pr(1) is bonded to twelve equivalent O(1) atoms to form PrO12 cuboctahedra that share corners with twelve equivalent Pr(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent K(1), two equivalent Pr(1), one W(1), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OK2Pr2ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
KPrWZnO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Pr(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.84 Å. Pr(1) is bonded to twelve equivalent O(1) atoms to form PrO12 cuboctahedra that share corners with twelve equivalent Pr(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent W(1)O6 octahedra, and faces with four equivalent Zn(1)O6 octahedra. All Pr(1)-O(1) bond lengths are 2.84 Å. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All W(1)-O(1) bond lengths are 1.94 Å. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Pr(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Zn(1)-O(1) bond lengths are 2.07 Å. O(1) is bonded to two equivalent K(1), two equivalent Pr(1), one W(1), and one Zn(1) atom to form a mixture of distorted edge, face, and corner-sharing OK2Pr2ZnW octahedra. The corner-sharing octahedral tilt angles range from 0-60°.