CsRe(OCl2)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent Cl(1), two equivalent Cl(2), three equivalent Cl(3), and three equivalent Cl(4) atoms. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cs(1) and one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Re(1) atom.
CsRe(OCl2)2 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent Cl(1), two equivalent Cl(2), three equivalent Cl(3), and three equivalent Cl(4) atoms. The Cs(1)-O(1) bond length is 3.60 Å. There is one shorter (3.75 Å) and one longer (3.82 Å) Cs(1)-Cl(1) bond length. There is one shorter (3.79 Å) and one longer (4.07 Å) Cs(1)-Cl(2) bond length. There are a spread of Cs(1)-Cl(3) bond distances ranging from 3.58-3.70 Å. There are two shorter (3.69 Å) and one longer (3.76 Å) Cs(1)-Cl(4) bond length. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Re(1)-O(1) bond length is 1.73 Å. The Re(1)-O(2) bond length is 1.72 Å. The Re(1)-Cl(1) bond length is 2.34 Å. The Re(1)-Cl(2) bond length is 2.32 Å. The Re(1)-Cl(3) bond length is 2.51 Å. The Re(1)-Cl(4) bond length is 2.51 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cs(1) and one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one Re(1) atom.