SnCl6(H2(NS)3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four H2(NS)3 clusters and two SnCl6 clusters. In each H2(NS)3 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one H(1), one H(2), and one S(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. In each SnCl6 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom.
SnCl6(H2(NS)3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four H2(NS)3 clusters and two SnCl6 clusters. In each H2(NS)3 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. The N(1)-S(2) bond length is 1.63 Å. The N(1)-S(3) bond length is 1.60 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. The N(2)-S(1) bond length is 1.61 Å. The N(2)-S(3) bond length is 1.57 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one H(1), one H(2), and one S(2) atom. The N(3)-H(1) bond length is 1.02 Å. The N(3)-H(2) bond length is 1.03 Å. The N(3)-S(2) bond length is 1.61 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. In each SnCl6 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. Both Sn(1)-Cl(1) bond lengths are 2.50 Å. Both Sn(1)-Cl(2) bond lengths are 2.48 Å. Both Sn(1)-Cl(3) bond lengths are 2.47 Å. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom.