FeV3 crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Fe(1) atoms. Fe(1) is bonded to twelve equivalent V(1) atoms to form a mixture of edge and face-sharing FeV12 cuboctahedra.
FeV3 crystallizes in the cubic Pm-3n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1) and four equivalent Fe(1) atoms. Both V(1)-V(1) bond lengths are 2.31 Å. All V(1)-Fe(1) bond lengths are 2.58 Å. Fe(1) is bonded to twelve equivalent V(1) atoms to form a mixture of edge and face-sharing FeV12 cuboctahedra.