CuSCN crystallizes in the hexagonal P6_3mc space group. Cu(1) is bonded to one N(1) and three equivalent S(1) atoms to form corner-sharing CuS3N tetrahedra. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a linear geometry to one Cu(1) and one C(1) atom. S(1) is bonded to three equivalent Cu(1) and one C(1) atom to form corner-sharing SCu3C tetrahedra.
CuSCN crystallizes in the hexagonal P6_3mc space group. Cu(1) is bonded to one N(1) and three equivalent S(1) atoms to form corner-sharing CuS3N tetrahedra. The Cu(1)-N(1) bond length is 1.89 Å. All Cu(1)-S(1) bond lengths are 2.34 Å. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.66 Å. N(1) is bonded in a linear geometry to one Cu(1) and one C(1) atom. S(1) is bonded to three equivalent Cu(1) and one C(1) atom to form corner-sharing SCu3C tetrahedra.