Sb3O4F crystallizes in the monoclinic C2/c space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a rectangular see-saw-like geometry to one O(1), two equivalent O(2), and one F(1) atom. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms.
Sb3O4F crystallizes in the monoclinic C2/c space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a rectangular see-saw-like geometry to one O(1), two equivalent O(2), and one F(1) atom. The Sb(1)-O(1) bond length is 2.07 Å. There is one shorter (1.99 Å) and one longer (2.05 Å) Sb(1)-O(2) bond length. The Sb(1)-F(1) bond length is 2.53 Å. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (2.09 Å) and two longer (2.29 Å) Sb(2)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms.