PtV is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. V(1) is bonded to four equivalent V(1) and eight equivalent Pt(1) atoms to form distorted VV4Pt8 cuboctahedra that share corners with twelve equivalent V(1)V4Pt8 cuboctahedra, edges with eight equivalent V(1)V4Pt8 cuboctahedra, edges with sixteen equivalent Pt(1)V8Pt4 cuboctahedra, faces with eight equivalent Pt(1)V8Pt4 cuboctahedra, and faces with ten equivalent V(1)V4Pt8 cuboctahedra. Pt(1) is bonded to eight equivalent V(1) and four equivalent Pt(1) atoms to form distorted PtV8Pt4 cuboctahedra that share corners with twelve equivalent Pt(1)V8Pt4 cuboctahedra, edges with eight equivalent Pt(1)V8Pt4 cuboctahedra, edges with sixteen equivalent V(1)V4Pt8 cuboctahedra, faces with eight equivalent V(1)V4Pt8 cuboctahedra, and faces with ten equivalent Pt(1)V8Pt4 cuboctahedra.
PtV is Tetraauricupride structured and crystallizes in the tetragonal P4/mmm space group. V(1) is bonded to four equivalent V(1) and eight equivalent Pt(1) atoms to form distorted VV4Pt8 cuboctahedra that share corners with twelve equivalent V(1)V4Pt8 cuboctahedra, edges with eight equivalent V(1)V4Pt8 cuboctahedra, edges with sixteen equivalent Pt(1)V8Pt4 cuboctahedra, faces with eight equivalent Pt(1)V8Pt4 cuboctahedra, and faces with ten equivalent V(1)V4Pt8 cuboctahedra. All V(1)-V(1) bond lengths are 2.69 Å. All V(1)-Pt(1) bond lengths are 2.72 Å. Pt(1) is bonded to eight equivalent V(1) and four equivalent Pt(1) atoms to form distorted PtV8Pt4 cuboctahedra that share corners with twelve equivalent Pt(1)V8Pt4 cuboctahedra, edges with eight equivalent Pt(1)V8Pt4 cuboctahedra, edges with sixteen equivalent V(1)V4Pt8 cuboctahedra, faces with eight equivalent V(1)V4Pt8 cuboctahedra, and faces with ten equivalent Pt(1)V8Pt4 cuboctahedra. All Pt(1)-Pt(1) bond lengths are 2.69 Å.