(RuN3H6)2(NH4)2(N3H12Cl)2(ClO4)4Cl2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ammonium molecules, two hydrochloric acid atoms, four hypochlorous acid;trihydrate molecules, two triazanium;hydrochloride molecules, and two RuN3H6 clusters. In each RuN3H6 cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ru(1), one H(3), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1) and two equivalent H(4) atoms. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom.
(RuN3H6)2(NH4)2(N3H12Cl)2(ClO4)4Cl2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ammonium molecules, two hydrochloric acid atoms, four hypochlorous acid;trihydrate molecules, two triazanium;hydrochloride molecules, and two RuN3H6 clusters. In each RuN3H6 cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. The Ru(1)-N(2) bond length is 1.94 Å. Both Ru(1)-N(1) bond lengths are 1.88 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ru(1), one H(3), and one H(5) atom. The N(1)-H(3) bond length is 1.03 Å. The N(1)-H(5) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1) and two equivalent H(4) atoms. Both N(2)-H(4) bond lengths are 1.03 Å. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom.