KYWO6Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a KYWO6 framework. In the KYWO6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with four equivalent Y(1)O6 octahedra, and faces with four equivalent W(1)O6 octahedra. Y(1) is bonded to six equivalent O(1) atoms to form YO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Y(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Y(1), and one W(1) atom.
KYWO6Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a KYWO6 framework. In the KYWO6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with four equivalent Y(1)O6 octahedra, and faces with four equivalent W(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.97 Å. Y(1) is bonded to six equivalent O(1) atoms to form YO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Y(1)-O(1) bond lengths are 2.24 Å. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Y(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All W(1)-O(1) bond lengths are 1.95 Å. O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Y(1), and one W(1) atom.