ZrVMo crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent V(1) and six equivalent Mo(1) atoms. V(1) is bonded to six equivalent Zr(1), two equivalent V(1), and four equivalent Mo(1) atoms to form distorted VZr6V2Mo4 cuboctahedra that share corners with eight equivalent Mo(1)Zr6V4Mo2 cuboctahedra, corners with ten equivalent V(1)Zr6V2Mo4 cuboctahedra, edges with six equivalent V(1)Zr6V2Mo4 cuboctahedra, faces with six equivalent V(1)Zr6V2Mo4 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6V4Mo2 cuboctahedra. Mo(1) is bonded to six equivalent Zr(1), four equivalent V(1), and two equivalent Mo(1) atoms to form distorted MoZr6V4Mo2 cuboctahedra that share corners with eight equivalent V(1)Zr6V2Mo4 cuboctahedra, corners with ten equivalent Mo(1)Zr6V4Mo2 cuboctahedra, edges with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, faces with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, and faces with twelve equivalent V(1)Zr6V2Mo4 cuboctahedra.
ZrVMo crystallizes in the orthorhombic Imma space group. Zr(1) is bonded in a 12-coordinate geometry to six equivalent V(1) and six equivalent Mo(1) atoms. There are four shorter (3.08 Å) and two longer (3.09 Å) Zr(1)-V(1) bond lengths. There are two shorter (3.08 Å) and four longer (3.12 Å) Zr(1)-Mo(1) bond lengths. V(1) is bonded to six equivalent Zr(1), two equivalent V(1), and four equivalent Mo(1) atoms to form distorted VZr6V2Mo4 cuboctahedra that share corners with eight equivalent Mo(1)Zr6V4Mo2 cuboctahedra, corners with ten equivalent V(1)Zr6V2Mo4 cuboctahedra, edges with six equivalent V(1)Zr6V2Mo4 cuboctahedra, faces with six equivalent V(1)Zr6V2Mo4 cuboctahedra, and faces with twelve equivalent Mo(1)Zr6V4Mo2 cuboctahedra. Both V(1)-V(1) bond lengths are 2.68 Å. All V(1)-Mo(1) bond lengths are 2.64 Å. Mo(1) is bonded to six equivalent Zr(1), four equivalent V(1), and two equivalent Mo(1) atoms to form distorted MoZr6V4Mo2 cuboctahedra that share corners with eight equivalent V(1)Zr6V2Mo4 cuboctahedra, corners with ten equivalent Mo(1)Zr6V4Mo2 cuboctahedra, edges with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, faces with six equivalent Mo(1)Zr6V4Mo2 cuboctahedra, and faces with twelve equivalent V(1)Zr6V2Mo4 cuboctahedra. Both Mo(1)-Mo(1) bond lengths are 2.62 Å.