CsNbN2 crystallizes in the cubic Fd-3m space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent N(1) atoms. Nb(1) is bonded to four equivalent N(1) atoms to form corner-sharing NbN4 tetrahedra. N(1) is bonded in a linear geometry to six equivalent Cs(1) and two equivalent Nb(1) atoms.
CsNbN2 crystallizes in the cubic Fd-3m space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent N(1) atoms. All Cs(1)-N(1) bond lengths are 3.72 Å. Nb(1) is bonded to four equivalent N(1) atoms to form corner-sharing NbN4 tetrahedra. All Nb(1)-N(1) bond lengths are 1.94 Å. N(1) is bonded in a linear geometry to six equivalent Cs(1) and two equivalent Nb(1) atoms.