Ce(RuB)4 crystallizes in the tetragonal I4_1/acd space group. Ce(1) is bonded in a 24-coordinate geometry to twelve equivalent Ru(1) and twelve equivalent B(1) atoms. Ru(1) is bonded in a 5-coordinate geometry to three equivalent Ce(1) and five equivalent B(1) atoms. B(1) is bonded in a 6-coordinate geometry to three equivalent Ce(1), five equivalent Ru(1), and one B(1) atom.
Ce(RuB)4 crystallizes in the tetragonal I4_1/acd space group. Ce(1) is bonded in a 24-coordinate geometry to twelve equivalent Ru(1) and twelve equivalent B(1) atoms. There are a spread of Ce(1)-Ru(1) bond distances ranging from 2.93-3.24 Å. There are a spread of Ce(1)-B(1) bond distances ranging from 2.99-3.21 Å. Ru(1) is bonded in a 5-coordinate geometry to three equivalent Ce(1) and five equivalent B(1) atoms. There are a spread of Ru(1)-B(1) bond distances ranging from 2.14-2.29 Å. B(1) is bonded in a 6-coordinate geometry to three equivalent Ce(1), five equivalent Ru(1), and one B(1) atom. The B(1)-B(1) bond length is 1.79 Å.