BaSb2 crystallizes in the orthorhombic Cmmm space group. Ba(1) is bonded in a 14-coordinate geometry to two equivalent Ba(1) and twelve equivalent Sb(1) atoms. Sb(1) is bonded in a 8-coordinate geometry to six equivalent Ba(1) and two equivalent Sb(1) atoms.
BaSb2 crystallizes in the orthorhombic Cmmm space group. Ba(1) is bonded in a 14-coordinate geometry to two equivalent Ba(1) and twelve equivalent Sb(1) atoms. Both Ba(1)-Ba(1) bond lengths are 3.61 Å. There are four shorter (3.59 Å) and eight longer (3.97 Å) Ba(1)-Sb(1) bond lengths. Sb(1) is bonded in a 8-coordinate geometry to six equivalent Ba(1) and two equivalent Sb(1) atoms. Both Sb(1)-Sb(1) bond lengths are 3.04 Å.