Li7Mn4CoO12 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(11), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Mn(5)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the second Li site, Li(2) is bonded to one O(12), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the third Li site, Li(3) is bonded to one O(17), one O(18), one O(19), one O(20), one O(21), and one O(24) atom to form LiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the fourth Li site, Li(4) is bonded to one O(17), one O(18), one O(19), one O(20), one O(22), and one O(23) atom to form LiO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the fifth Li site, Li(5) is bonded to one O(17), one O(20), one O(21), one O(22), one O(23), and one O(24) atom to form LiO6 octahedra that share corners with three equivalent Li(11)O6 octahedra, corners with three equivalent Li(14)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-16°. In the sixth Li site, Li(6) is bonded to one O(18), one O(19), one O(21), one O(22), one O(23), and one O(24) atom to form LiO6 octahedra that share corners with three equivalent Li(12)O6 octahedra, corners with three equivalent Li(13)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(12), one O(15), one O(2), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the eighth Li site, Li(8) is bonded to one O(1), one O(11), one O(12), one O(16), one O(2), and one O(5) atom to form LiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. In the ninth Li site, Li(9) is bonded to one O(10), one O(13), one O(3), one O(4), one O(8), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(3)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the tenth Li site, Li(10) is bonded to one O(10), one O(14), one O(3), one O(4), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the eleventh Li site, Li(11) is bonded to one O(13), one O(14), one O(17), one O(23), one O(24), and one O(4) atom to form LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the twelfth Li site, Li(12) is bonded to one O(13), one O(14), one O(18), one O(23), one O(24), and one O(3) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the thirteenth Li site, Li(13) is bonded to one O(15), one O(16), one O(19), one O(2), one O(21), and one O(22) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-13°. In the fourteenth Li site, Li(14) is bonded to one O(1), one O(15), one O(16), one O(20), one O(21), and one O(22) atom to form distorted LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(16), one O(19), one O(2), one O(20), and one O(21) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the second Mn site, Mn(2) is bonded to one O(1), one O(15), one O(19), one O(2), one O(20), and one O(22) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(7)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the third Mn site, Mn(3) is bonded to one O(13), one O(17), one O(18), one O(23), one O(3), and one O(4) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(17), one O(18), one O(24), one O(3), and one O(4) atom to form MnO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(15), one O(16), one O(2), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(12), one O(15), one O(16), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(14)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(14), one O(4), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(11)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(13), one O(14), one O(3), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(12)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(11), one O(12), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(12), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(14), one Li(7), one Li(8), one Mn(1), one Mn(2), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(12)Li3MnCo2 octahedra, corners with three equivalent O(20)Li4Mn2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(15)Li3Mn3 octahedra, edges with two equivalent O(16)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the second O site, O(2) is bonded to one Li(13), one Li(7), one Li(8), one Mn(1), one Mn(2), and one Mn(5) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(11)Li3MnCo2 octahedra, corners with three equivalent O(19)Li4Mn2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(15)Li3Mn3 octahedra, and edges with two equivalent O(16)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the third O site, O(3) is bonded to one Li(10), one Li(12), one Li(9), one Mn(3), one Mn(4), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(10)Li3MnCo2 octahedra, corners with three equivalent O(18)Li4Mn2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth O site, O(4) is bonded to one Li(10), one Li(11), one Li(9), one Mn(3), one Mn(4), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(9)Li3MnCo2 octahedra, corners with three equivalent O(17)Li4Mn2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, and edges with two equivalent O(3)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(8), one Mn(5), one Mn(6), and one Co(1) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(7)Li3Mn2Co octahedra, corners with three equivalent O(16)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(11)Li3MnCo2 octahedra, and edges with two equivalent O(12)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(7), one Mn(5), one Mn(6), and one Co(2) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(8)Li3Mn2Co octahedra, corners with three equivalent O(15)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra, edges with two equivalent O(5)Li3Mn2Co octahedra, edges with two equivalent O(11)Li3MnCo2 octahedra, and edges with two equivalent O(12)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the seventh O site, O(7) is bonded to one Li(1), one Li(10), one Li(2), one Mn(7), one Mn(8), and one Co(1) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(5)Li3Mn2Co octahedra, corners with three equivalent O(14)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra, edges with two equivalent O(8)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3MnCo2 octahedra, and edges with two equivalent O(9)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Li(9), one Mn(7), one Mn(8), and one Co(2) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(6)Li3Mn2Co octahedra, corners with three equivalent O(13)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra, edges with two equivalent O(7)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3MnCo2 octahedra, and edges with two equivalent O(9)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the ninth O site, O(9) is bonded to one Li(10), one Li(2), one Li(9), one Mn(7), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(4)Li3Mn3 octahedra, corners with three equivalent O(12)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra, edges with two equivalent O(7)Li3Mn2Co octahedra, edges with two equivalent O(8)Li3Mn2Co octahedra, and edges with two equivalent O(10)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the tenth O site, O(10) is bonded to one Li(1), one Li(10), one Li(9), one Mn(8), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(3)Li3Mn3 octahedra, corners with three equivalent O(11)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra, edges with two equivalent O(7)Li3Mn2Co octahedra, edges with two equivalent O(8)Li3Mn2Co octahedra, and edges with two equivalent O(9)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(7), one Li(8), one Mn(5), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(2)Li3Mn3 octahedra, corners with three equivalent O(10)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra, edges with two equivalent O(5)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, and edges with two equivalent O(12)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the twelfth O site, O(12) is bonded to one Li(2), one Li(7), one Li(8), one Mn(6), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(1)Li3Mn3 octahedra, corners with three equivalent O(9)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra, edges with two equivalent O(5)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, and edges with two equivalent O(11)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the thirteenth O site, O(13) is bonded to one Li(11), one Li(12), one Li(9), one Mn(3), one Mn(7), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(8)Li3Mn2Co octahedra, corners with three equivalent O(23)Li5Mn octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(11), one Li(12), one Mn(4), one Mn(7), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(7)Li3Mn2Co octahedra, corners with three equivalent O(24)Li5Mn octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(14), one Li(7), one Mn(2), one Mn(5), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(6)Li3Mn2Co octahedra, corners with three equivalent O(22)Li5Mn octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(16)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the sixteenth O site, O(16) is bonded to one Li(13), one Li(14), one Li(8), one Mn(1), one Mn(5), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(5)Li3Mn2Co octahedra, corners with three equivalent O(21)Li5Mn octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(15)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the seventeenth O site, O(17) is bonded to one Li(11), one Li(3), one Li(4), one Li(5), one Mn(3), and one Mn(4) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(4)Li3Mn3 octahedra, corners with three equivalent O(20)Li4Mn2 octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(18)Li4Mn2 octahedra, edges with two equivalent O(23)Li5Mn octahedra, and edges with two equivalent O(24)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the eighteenth O site, O(18) is bonded to one Li(12), one Li(3), one Li(4), one Li(6), one Mn(3), and one Mn(4) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(3)Li3Mn3 octahedra, corners with three equivalent O(19)Li4Mn2 octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(17)Li4Mn2 octahedra, edges with two equivalent O(23)Li5Mn octahedra, and edges with two equivalent O(24)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the nineteenth O site, O(19) is bonded to one Li(13), one Li(3), one Li(4), one Li(6), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(2)Li3Mn3 octahedra, corners with three equivalent O(18)Li4Mn2 octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(20)Li4Mn2 octahedra, edges with two equivalent O(21)Li5Mn octahedra, and edges with two equivalent O(22)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twentieth O site, O(20) is bonded to one Li(14), one Li(3), one Li(4), one Li(5), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(1)Li3Mn3 octahedra, corners with three equivalent O(17)Li4Mn2 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(19)Li4Mn2 octahedra, edges with two equivalent O(21)Li5Mn octahedra, and edges with two equivalent O(22)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the twenty-first O site, O(21) is bonded to one Li(13), one Li(14), one Li(3), one Li(5), one Li(6), and one Mn(1) atom to form OLi5Mn octahedra that share corners with three equivalent O(16)Li3Mn3 octahedra, corners with three equivalent O(24)Li5Mn octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra, edges with two equivalent O(19)Li4Mn2 octahedra, edges with two equivalent O(20)Li4Mn2 octahedra, and edges with two equivalent O(22)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the twenty-second O site, O(22) is bonded to one Li(13), one Li(14), one Li(4), one Li(5), one Li(6), and one Mn(2) atom to form OLi5Mn octahedra that share corners with three equivalent O(15)Li3Mn3 octahedra, corners with three equivalent O(23)Li5Mn octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(19)Li4Mn2 octahedra, edges with two equivalent O(20)Li4Mn2 octahedra, and edges with two equivalent O(21)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the twenty-third O site, O(23) is bonded to one Li(11), one Li(12), one Li(4), one Li(5), one Li(6), and one Mn(3) atom to form OLi5Mn octahedra that share corners with three equivalent O(13)Li3Mn3 octahedra, corners with three equivalent O(22)Li5Mn octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra, edges with two equivalent O(17)Li4Mn2 octahedra, edges with two equivalent O(18)Li4Mn2 octahedra, and edges with two equivalent O(24)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-fourth O site, O(24) is bonded to one Li(11), one Li(12), one Li(3), one Li(5), one Li(6), and one Mn(4) atom to form OLi5Mn octahedra that share corners with three equivalent O(14)Li3Mn3 octahedra, corners with three equivalent O(21)Li5Mn octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(17)Li4Mn2 octahedra, edges with two equivalent O(18)Li4Mn2 octahedra, and edges with two equivalent O(23)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 1-6°.
Li7Mn4CoO12 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(11), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Mn(5)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. The Li(1)-O(10) bond length is 2.14 Å. The Li(1)-O(11) bond length is 2.22 Å. The Li(1)-O(5) bond length is 2.22 Å. The Li(1)-O(6) bond length is 2.09 Å. The Li(1)-O(7) bond length is 2.15 Å. The Li(1)-O(8) bond length is 2.07 Å. In the second Li site, Li(2) is bonded to one O(12), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. The Li(2)-O(12) bond length is 2.28 Å. The Li(2)-O(5) bond length is 2.43 Å. The Li(2)-O(6) bond length is 2.25 Å. The Li(2)-O(7) bond length is 2.03 Å. The Li(2)-O(8) bond length is 2.12 Å. The Li(2)-O(9) bond length is 2.05 Å. In the third Li site, Li(3) is bonded to one O(17), one O(18), one O(19), one O(20), one O(21), and one O(24) atom to form LiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. The Li(3)-O(17) bond length is 2.19 Å. The Li(3)-O(18) bond length is 2.17 Å. The Li(3)-O(19) bond length is 2.21 Å. The Li(3)-O(20) bond length is 2.34 Å. The Li(3)-O(21) bond length is 2.31 Å. The Li(3)-O(24) bond length is 2.12 Å. In the fourth Li site, Li(4) is bonded to one O(17), one O(18), one O(19), one O(20), one O(22), and one O(23) atom to form LiO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. The Li(4)-O(17) bond length is 2.17 Å. The Li(4)-O(18) bond length is 2.22 Å. The Li(4)-O(19) bond length is 2.29 Å. The Li(4)-O(20) bond length is 2.21 Å. The Li(4)-O(22) bond length is 2.29 Å. The Li(4)-O(23) bond length is 2.15 Å. In the fifth Li site, Li(5) is bonded to one O(17), one O(20), one O(21), one O(22), one O(23), and one O(24) atom to form LiO6 octahedra that share corners with three equivalent Li(11)O6 octahedra, corners with three equivalent Li(14)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-16°. The Li(5)-O(17) bond length is 2.06 Å. The Li(5)-O(20) bond length is 2.11 Å. The Li(5)-O(21) bond length is 2.15 Å. The Li(5)-O(22) bond length is 2.12 Å. The Li(5)-O(23) bond length is 2.08 Å. The Li(5)-O(24) bond length is 2.10 Å. In the sixth Li site, Li(6) is bonded to one O(18), one O(19), one O(21), one O(22), one O(23), and one O(24) atom to form LiO6 octahedra that share corners with three equivalent Li(12)O6 octahedra, corners with three equivalent Li(13)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. The Li(6)-O(18) bond length is 2.05 Å. The Li(6)-O(19) bond length is 2.07 Å. The Li(6)-O(21) bond length is 2.11 Å. The Li(6)-O(22) bond length is 2.18 Å. The Li(6)-O(23) bond length is 2.11 Å. The Li(6)-O(24) bond length is 2.07 Å. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(12), one O(15), one O(2), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. The Li(7)-O(1) bond length is 2.20 Å. The Li(7)-O(11) bond length is 2.12 Å. The Li(7)-O(12) bond length is 2.08 Å. The Li(7)-O(15) bond length is 2.15 Å. The Li(7)-O(2) bond length is 2.44 Å. The Li(7)-O(6) bond length is 2.06 Å. In the eighth Li site, Li(8) is bonded to one O(1), one O(11), one O(12), one O(16), one O(2), and one O(5) atom to form LiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. The Li(8)-O(1) bond length is 2.37 Å. The Li(8)-O(11) bond length is 2.04 Å. The Li(8)-O(12) bond length is 2.04 Å. The Li(8)-O(16) bond length is 2.14 Å. The Li(8)-O(2) bond length is 2.20 Å. The Li(8)-O(5) bond length is 2.07 Å. In the ninth Li site, Li(9) is bonded to one O(10), one O(13), one O(3), one O(4), one O(8), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(3)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. The Li(9)-O(10) bond length is 2.17 Å. The Li(9)-O(13) bond length is 2.16 Å. The Li(9)-O(3) bond length is 2.44 Å. The Li(9)-O(4) bond length is 2.17 Å. The Li(9)-O(8) bond length is 2.12 Å. The Li(9)-O(9) bond length is 2.09 Å. In the tenth Li site, Li(10) is bonded to one O(10), one O(14), one O(3), one O(4), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. The Li(10)-O(10) bond length is 2.05 Å. The Li(10)-O(14) bond length is 2.17 Å. The Li(10)-O(3) bond length is 2.15 Å. The Li(10)-O(4) bond length is 2.44 Å. The Li(10)-O(7) bond length is 2.10 Å. The Li(10)-O(9) bond length is 2.08 Å. In the eleventh Li site, Li(11) is bonded to one O(13), one O(14), one O(17), one O(23), one O(24), and one O(4) atom to form LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. The Li(11)-O(13) bond length is 2.27 Å. The Li(11)-O(14) bond length is 2.25 Å. The Li(11)-O(17) bond length is 2.06 Å. The Li(11)-O(23) bond length is 2.01 Å. The Li(11)-O(24) bond length is 2.06 Å. The Li(11)-O(4) bond length is 2.09 Å. In the twelfth Li site, Li(12) is bonded to one O(13), one O(14), one O(18), one O(23), one O(24), and one O(3) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Li(12)-O(13) bond length is 2.21 Å. The Li(12)-O(14) bond length is 2.24 Å. The Li(12)-O(18) bond length is 2.07 Å. The Li(12)-O(23) bond length is 2.06 Å. The Li(12)-O(24) bond length is 2.02 Å. The Li(12)-O(3) bond length is 2.11 Å. In the thirteenth Li site, Li(13) is bonded to one O(15), one O(16), one O(19), one O(2), one O(21), and one O(22) atom to form LiO6 octahedra that share corners with three equivalent Li(6)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-13°. The Li(13)-O(15) bond length is 2.18 Å. The Li(13)-O(16) bond length is 2.23 Å. The Li(13)-O(19) bond length is 2.06 Å. The Li(13)-O(2) bond length is 2.17 Å. The Li(13)-O(21) bond length is 2.00 Å. The Li(13)-O(22) bond length is 2.03 Å. In the fourteenth Li site, Li(14) is bonded to one O(1), one O(15), one O(16), one O(20), one O(21), and one O(22) atom to form distorted LiO6 octahedra that share corners with three equivalent Li(5)O6 octahedra, corners with three equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-16°. The Li(14)-O(1) bond length is 2.17 Å. The Li(14)-O(15) bond length is 2.29 Å. The Li(14)-O(16) bond length is 2.48 Å. The Li(14)-O(20) bond length is 2.03 Å. The Li(14)-O(21) bond length is 1.97 Å. The Li(14)-O(22) bond length is 1.97 Å. There are eight inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(16), one O(19), one O(2), one O(20), and one O(21) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. The Mn(1)-O(1) bond length is 2.03 Å. The Mn(1)-O(16) bond length is 2.07 Å. The Mn(1)-O(19) bond length is 1.93 Å. The Mn(1)-O(2) bond length is 2.00 Å. The Mn(1)-O(20) bond length is 1.94 Å. The Mn(1)-O(21) bond length is 1.80 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(15), one O(19), one O(2), one O(20), and one O(22) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(7)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Li(13)O6 octahedra, edges with two equivalent Li(14)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. The Mn(2)-O(1) bond length is 2.01 Å. The Mn(2)-O(15) bond length is 2.05 Å. The Mn(2)-O(19) bond length is 1.95 Å. The Mn(2)-O(2) bond length is 2.01 Å. The Mn(2)-O(20) bond length is 1.94 Å. The Mn(2)-O(22) bond length is 1.81 Å. In the third Mn site, Mn(3) is bonded to one O(13), one O(17), one O(18), one O(23), one O(3), and one O(4) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-12°. The Mn(3)-O(13) bond length is 2.06 Å. The Mn(3)-O(17) bond length is 1.95 Å. The Mn(3)-O(18) bond length is 1.96 Å. The Mn(3)-O(23) bond length is 1.83 Å. The Mn(3)-O(3) bond length is 2.01 Å. The Mn(3)-O(4) bond length is 2.00 Å. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(17), one O(18), one O(24), one O(3), and one O(4) atom to form MnO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(11)O6 octahedra, edges with two equivalent Li(12)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-13°. The Mn(4)-O(14) bond length is 2.04 Å. The Mn(4)-O(17) bond length is 1.97 Å. The Mn(4)-O(18) bond length is 1.95 Å. The Mn(4)-O(24) bond length is 1.83 Å. The Mn(4)-O(3) bond length is 2.00 Å. The Mn(4)-O(4) bond length is 2.00 Å. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(15), one O(16), one O(2), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. The Mn(5)-O(11) bond length is 1.94 Å. The Mn(5)-O(15) bond length is 2.19 Å. The Mn(5)-O(16) bond length is 1.97 Å. The Mn(5)-O(2) bond length is 1.99 Å. The Mn(5)-O(5) bond length is 1.97 Å. The Mn(5)-O(6) bond length is 2.19 Å. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(12), one O(15), one O(16), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with three equivalent Li(14)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent Li(8)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. The Mn(6)-O(1) bond length is 1.98 Å. The Mn(6)-O(12) bond length is 1.92 Å. The Mn(6)-O(15) bond length is 1.92 Å. The Mn(6)-O(16) bond length is 1.96 Å. The Mn(6)-O(5) bond length is 1.95 Å. The Mn(6)-O(6) bond length is 1.94 Å. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(14), one O(4), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(11)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. The Mn(7)-O(13) bond length is 1.92 Å. The Mn(7)-O(14) bond length is 2.16 Å. The Mn(7)-O(4) bond length is 2.06 Å. The Mn(7)-O(7) bond length is 2.15 Å. The Mn(7)-O(8) bond length is 1.95 Å. The Mn(7)-O(9) bond length is 2.05 Å. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(13), one O(14), one O(3), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(12)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, edges with two equivalent Li(10)O6 octahedra, edges with two equivalent Li(9)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. The Mn(8)-O(10) bond length is 2.02 Å. The Mn(8)-O(13) bond length is 2.18 Å. The Mn(8)-O(14) bond length is 1.92 Å. The Mn(8)-O(3) bond length is 2.03 Å. The Mn(8)-O(7) bond length is 1.94 Å. The Mn(8)-O(8) bond length is 2.21 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(11), one O(12), one O(5), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(10)O6 octahedra, corners with three equivalent Li(8)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. The Co(1)-O(10) bond length is 2.06 Å. The Co(1)-O(11) bond length is 2.10 Å. The Co(1)-O(12) bond length is 2.16 Å. The Co(1)-O(5) bond length is 2.12 Å. The Co(1)-O(7) bond length is 2.07 Å. The Co(1)-O(9) bond length is 2.10 Å. In the second Co site, Co(2) is bonded to one O(10), one O(11), one O(12), one O(6), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. The Co(2)-O(10) bond length is 1.99 Å. The Co(2)-O(11) bond length is 2.06 Å. The Co(2)-O(12) bond length is 2.07 Å. The Co(2)-O(6) bond length is 2.08 Å. The Co(2)-O(8) bond length is 2.06 Å. The Co(2)-O(9) bond length is 1.98 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(14), one Li(7), one Li(8), one Mn(1), one Mn(2), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(12)Li3MnCo2 octahedra, corners with three equivalent O(20)Li4Mn2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(15)Li3Mn3 octahedra, edges with two equivalent O(16)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the second O site, O(2) is bonded to one Li(13), one Li(7), one Li(8), one Mn(1), one Mn(2), and one Mn(5) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(11)Li3MnCo2 octahedra, corners with three equivalent O(19)Li4Mn2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(15)Li3Mn3 octahedra, and edges with two equivalent O(16)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the third O site, O(3) is bonded to one Li(10), one Li(12), one Li(9), one Mn(3), one Mn(4), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(10)Li3MnCo2 octahedra, corners with three equivalent O(18)Li4Mn2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth O site, O(4) is bonded to one Li(10), one Li(11), one Li(9), one Mn(3), one Mn(4), and one Mn(7) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(9)Li3MnCo2 octahedra, corners with three equivalent O(17)Li4Mn2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, and edges with two equivalent O(3)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(8), one Mn(5), one Mn(6), and one Co(1) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(7)Li3Mn2Co octahedra, corners with three equivalent O(16)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, edges with two equivalent O(11)Li3MnCo2 octahedra, and edges with two equivalent O(12)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(7), one Mn(5), one Mn(6), and one Co(2) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(8)Li3Mn2Co octahedra, corners with three equivalent O(15)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra, edges with two equivalent O(5)Li3Mn2Co octahedra, edges with two equivalent O(11)Li3MnCo2 octahedra, and edges with two equivalent O(12)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the seventh O site, O(7) is bonded to one Li(1), one Li(10), one Li(2), one Mn(7), one Mn(8), and one Co(1) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(5)Li3Mn2Co octahedra, corners with three equivalent O(14)Li3Mn3 octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra, edges with two equivalent O(8)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3MnCo2 octahedra, and edges with two equivalent O(9)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Li(9), one Mn(7), one Mn(8), and one Co(2) atom to form OLi3Mn2Co octahedra that share corners with three equivalent O(6)Li3Mn2Co octahedra, corners with three equivalent O(13)Li3Mn3 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra, edges with two equivalent O(7)Li3Mn2Co octahedra, edges with two equivalent O(10)Li3MnCo2 octahedra, and edges with two equivalent O(9)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the ninth O site, O(9) is bonded to one Li(10), one Li(2), one Li(9), one Mn(7), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(4)Li3Mn3 octahedra, corners with three equivalent O(12)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra, edges with two equivalent O(7)Li3Mn2Co octahedra, edges with two equivalent O(8)Li3Mn2Co octahedra, and edges with two equivalent O(10)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the tenth O site, O(10) is bonded to one Li(1), one Li(10), one Li(9), one Mn(8), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(3)Li3Mn3 octahedra, corners with three equivalent O(11)Li3MnCo2 octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra, edges with two equivalent O(7)Li3Mn2Co octahedra, edges with two equivalent O(8)Li3Mn2Co octahedra, and edges with two equivalent O(9)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(7), one Li(8), one Mn(5), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(2)Li3Mn3 octahedra, corners with three equivalent O(10)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra, edges with two equivalent O(5)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, and edges with two equivalent O(12)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the twelfth O site, O(12) is bonded to one Li(2), one Li(7), one Li(8), one Mn(6), one Co(1), and one Co(2) atom to form OLi3MnCo2 octahedra that share corners with three equivalent O(1)Li3Mn3 octahedra, corners with three equivalent O(9)Li3MnCo2 octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra, edges with two equivalent O(5)Li3Mn2Co octahedra, edges with two equivalent O(6)Li3Mn2Co octahedra, and edges with two equivalent O(11)Li3MnCo2 octahedra. The corner-sharing octahedral tilt angles range from 3-11°. In the thirteenth O site, O(13) is bonded to one Li(11), one Li(12), one Li(9), one Mn(3), one Mn(7), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(8)Li3Mn2Co octahedra, corners with three equivalent O(23)Li5Mn octahedra,  an edgeedge with one O(7)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(14)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(11), one Li(12), one Mn(4), one Mn(7), and one Mn(8) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(7)Li3Mn2Co octahedra, corners with three equivalent O(24)Li5Mn octahedra,  an edgeedge with one O(8)Li3Mn2Co octahedra,  an edgeedge with one O(10)Li3MnCo2 octahedra,  an edgeedge with one O(9)Li3MnCo2 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra, edges with two equivalent O(13)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, and edges with two equivalent O(4)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(14), one Li(7), one Mn(2), one Mn(5), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(6)Li3Mn2Co octahedra, corners with three equivalent O(22)Li5Mn octahedra,  an edgeedge with one O(5)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(16)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the sixteenth O site, O(16) is bonded to one Li(13), one Li(14), one Li(8), one Mn(1), one Mn(5), and one Mn(6) atom to form OLi3Mn3 octahedra that share corners with three equivalent O(5)Li3Mn2Co octahedra, corners with three equivalent O(21)Li5Mn octahedra,  an edgeedge with one O(6)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3MnCo2 octahedra,  an edgeedge with one O(12)Li3MnCo2 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(1)Li3Mn3 octahedra, edges with two equivalent O(15)Li3Mn3 octahedra, and edges with two equivalent O(2)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the seventeenth O site, O(17) is bonded to one Li(11), one Li(3), one Li(4), one Li(5), one Mn(3), and one Mn(4) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(4)Li3Mn3 octahedra, corners with three equivalent O(20)Li4Mn2 octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(18)Li4Mn2 octahedra, edges with two equivalent O(23)Li5Mn octahedra, and edges with two equivalent O(24)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the eighteenth O site, O(18) is bonded to one Li(12), one Li(3), one Li(4), one Li(6), one Mn(3), and one Mn(4) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(3)Li3Mn3 octahedra, corners with three equivalent O(19)Li4Mn2 octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(17)Li4Mn2 octahedra, edges with two equivalent O(23)Li5Mn octahedra, and edges with two equivalent O(24)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the nineteenth O site, O(19) is bonded to one Li(13), one Li(3), one Li(4), one Li(6), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(2)Li3Mn3 octahedra, corners with three equivalent O(18)Li4Mn2 octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(20)Li4Mn2 octahedra, edges with two equivalent O(21)Li5Mn octahedra, and edges with two equivalent O(22)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twentieth O site, O(20) is bonded to one Li(14), one Li(3), one Li(4), one Li(5), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share corners with three equivalent O(1)Li3Mn3 octahedra, corners with three equivalent O(17)Li4Mn2 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(19)Li4Mn2 octahedra, edges with two equivalent O(21)Li5Mn octahedra, and edges with two equivalent O(22)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the twenty-first O site, O(21) is bonded to one Li(13), one Li(14), one Li(3), one Li(5), one Li(6), and one Mn(1) atom to form OLi5Mn octahedra that share corners with three equivalent O(16)Li3Mn3 octahedra, corners with three equivalent O(24)Li5Mn octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(15)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(23)Li5Mn octahedra, edges with two equivalent O(19)Li4Mn2 octahedra, edges with two equivalent O(20)Li4Mn2 octahedra, and edges with two equivalent O(22)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the twenty-second O site, O(22) is bonded to one Li(13), one Li(14), one Li(4), one Li(5), one Li(6), and one Mn(2) atom to form OLi5Mn octahedra that share corners with three equivalent O(15)Li3Mn3 octahedra, corners with three equivalent O(23)Li5Mn octahedra,  an edgeedge with one O(1)Li3Mn3 octahedra,  an edgeedge with one O(16)Li3Mn3 octahedra,  an edgeedge with one O(2)Li3Mn3 octahedra,  an edgeedge with one O(17)Li4Mn2 octahedra,  an edgeedge with one O(18)Li4Mn2 octahedra,  an edgeedge with one O(24)Li5Mn octahedra, edges with two equivalent O(19)Li4Mn2 octahedra, edges with two equivalent O(20)Li4Mn2 octahedra, and edges with two equivalent O(21)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the twenty-third O site, O(23) is bonded to one Li(11), one Li(12), one Li(4), one Li(5), one Li(6), and one Mn(3) atom to form OLi5Mn octahedra that share corners with three equivalent O(13)Li3Mn3 octahedra, corners with three equivalent O(22)Li5Mn octahedra,  an edgeedge with one O(14)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(21)Li5Mn octahedra, edges with two equivalent O(17)Li4Mn2 octahedra, edges with two equivalent O(18)Li4Mn2 octahedra, and edges with two equivalent O(24)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the twenty-fourth O site, O(24) is bonded to one Li(11), one Li(12), one Li(3), one Li(5), one Li(6), and one Mn(4) atom to form OLi5Mn octahedra that share corners with three equivalent O(14)Li3Mn3 octahedra, corners with three equivalent O(21)Li5Mn octahedra,  an edgeedge with one O(13)Li3Mn3 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(19)Li4Mn2 octahedra,  an edgeedge with one O(20)Li4Mn2 octahedra,  an edgeedge with one O(22)Li5Mn octahedra, edges with two equivalent O(17)Li4Mn2 octahedra, edges with two equivalent O(18)Li4Mn2 octahedra, and edges with two equivalent O(23)Li5Mn octahedra. The corner-sharing octahedral tilt angles range from 1-6°.