La3WMn(SO2)3 crystallizes in the hexagonal P6_3/m space group. La(1) is bonded in a 10-coordinate geometry to four equivalent S(1) and six equivalent O(1) atoms. W(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent O(1) atoms. Mn(1) is bonded to six equivalent S(1) atoms to form face-sharing MnS6 octahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent Mn(1) atoms. O(1) is bonded to three equivalent La(1) and one W(1) atom to form a mixture of corner and edge-sharing OLa3W tetrahedra.
La3WMn(SO2)3 crystallizes in the hexagonal P6_3/m space group. La(1) is bonded in a 10-coordinate geometry to four equivalent S(1) and six equivalent O(1) atoms. There are a spread of La(1)-S(1) bond distances ranging from 3.04-3.19 Å. There are a spread of La(1)-O(1) bond distances ranging from 2.45-2.77 Å. W(1) is bonded in a distorted pentagonal pyramidal geometry to six equivalent O(1) atoms. All W(1)-O(1) bond lengths are 1.97 Å. Mn(1) is bonded to six equivalent S(1) atoms to form face-sharing MnS6 octahedra. All Mn(1)-S(1) bond lengths are 2.46 Å. S(1) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent Mn(1) atoms. O(1) is bonded to three equivalent La(1) and one W(1) atom to form a mixture of corner and edge-sharing OLa3W tetrahedra.