SrLaTiMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), one O(6), and two equivalent O(3) atoms. Ti(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-25°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-25°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Ti(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one Ti(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom.
SrLaTiMnO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Sr(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There is one shorter (2.80 Å) and one longer (2.92 Å) Sr(1)-O(1) bond length. There is one shorter (2.65 Å) and one longer (2.87 Å) Sr(1)-O(2) bond length. There is one shorter (2.65 Å) and one longer (2.92 Å) Sr(1)-O(3) bond length. There is one shorter (2.50 Å) and one longer (3.19 Å) Sr(1)-O(4) bond length. There is one shorter (2.60 Å) and one longer (2.99 Å) Sr(1)-O(5) bond length. There is one shorter (2.59 Å) and one longer (3.04 Å) Sr(1)-O(6) bond length. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), one O(6), and two equivalent O(3) atoms. The La(1)-O(1) bond length is 2.46 Å. The La(1)-O(2) bond length is 2.50 Å. The La(1)-O(5) bond length is 2.53 Å. The La(1)-O(6) bond length is 2.52 Å. There is one shorter (2.48 Å) and one longer (3.13 Å) La(1)-O(3) bond length. Ti(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-25°. The Ti(1)-O(1) bond length is 2.03 Å. The Ti(1)-O(2) bond length is 1.95 Å. The Ti(1)-O(3) bond length is 1.97 Å. The Ti(1)-O(4) bond length is 1.98 Å. The Ti(1)-O(5) bond length is 1.95 Å. The Ti(1)-O(6) bond length is 1.98 Å. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-25°. The Mn(1)-O(1) bond length is 1.93 Å. The Mn(1)-O(2) bond length is 2.11 Å. The Mn(1)-O(3) bond length is 2.08 Å. The Mn(1)-O(4) bond length is 1.92 Å. The Mn(1)-O(5) bond length is 2.11 Å. The Mn(1)-O(6) bond length is 2.07 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent La(1), one Ti(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), one Ti(1), and one Mn(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one La(1), one Ti(1), and one Mn(1) atom.