KZrGeBiO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Bi(1)O12 cuboctahedra, faces with four equivalent Zr(1)O6 octahedra, and faces with four equivalent Ge(1)O6 octahedra. Zr(1) is bonded to six equivalent O(1) atoms to form ZrO6 octahedra that share corners with six equivalent Ge(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Ge(1) is bonded to six equivalent O(1) atoms to form GeO6 octahedra that share corners with six equivalent Zr(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Bi(1) is bonded to twelve equivalent O(1) atoms to form BiO12 cuboctahedra that share corners with twelve equivalent Bi(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent Zr(1)O6 octahedra, and faces with four equivalent Ge(1)O6 octahedra. O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Zr(1), one Ge(1), and two equivalent Bi(1) atoms.
KZrGeBiO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with six equivalent Bi(1)O12 cuboctahedra, faces with four equivalent Zr(1)O6 octahedra, and faces with four equivalent Ge(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.83 Å. Zr(1) is bonded to six equivalent O(1) atoms to form ZrO6 octahedra that share corners with six equivalent Ge(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Zr(1)-O(1) bond lengths are 2.09 Å. Ge(1) is bonded to six equivalent O(1) atoms to form GeO6 octahedra that share corners with six equivalent Zr(1)O6 octahedra, faces with four equivalent K(1)O12 cuboctahedra, and faces with four equivalent Bi(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ge(1)-O(1) bond lengths are 1.91 Å. Bi(1) is bonded to twelve equivalent O(1) atoms to form BiO12 cuboctahedra that share corners with twelve equivalent Bi(1)O12 cuboctahedra, faces with six equivalent K(1)O12 cuboctahedra, faces with four equivalent Zr(1)O6 octahedra, and faces with four equivalent Ge(1)O6 octahedra. All Bi(1)-O(1) bond lengths are 2.83 Å. O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Zr(1), one Ge(1), and two equivalent Bi(1) atoms.