LiSH crystallizes in the orthorhombic Ama2 space group. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of edge and corner-sharing LiS4 tetrahedra. H(1) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded to four equivalent Li(1) and one H(1) atom to form a mixture of distorted edge and corner-sharing SLi4H square pyramids.
LiSH crystallizes in the orthorhombic Ama2 space group. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of edge and corner-sharing LiS4 tetrahedra. There are two shorter (2.48 Å) and two longer (2.49 Å) Li(1)-S(1) bond lengths. H(1) is bonded in a single-bond geometry to one S(1) atom. The H(1)-S(1) bond length is 1.34 Å. S(1) is bonded to four equivalent Li(1) and one H(1) atom to form a mixture of distorted edge and corner-sharing SLi4H square pyramids.