Cu4N4OBr6 is Indium structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two Cu4N4OBr6 clusters. Cu(1) is bonded to one N(1), one O(1), one Br(1), and two equivalent Br(2) atoms to form distorted edge-sharing CuBr3NO trigonal bipyramids. N(1) is bonded in a single-bond geometry to one Cu(1) atom. O(1) is bonded in a tetrahedral geometry to four equivalent Cu(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms.
Cu4N4OBr6 is Indium structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two Cu4N4OBr6 clusters. Cu(1) is bonded to one N(1), one O(1), one Br(1), and two equivalent Br(2) atoms to form distorted edge-sharing CuBr3NO trigonal bipyramids. The Cu(1)-N(1) bond length is 1.77 Å. The Cu(1)-O(1) bond length is 1.93 Å. The Cu(1)-Br(1) bond length is 2.49 Å. There is one shorter (2.49 Å) and one longer (2.50 Å) Cu(1)-Br(2) bond length. N(1) is bonded in a single-bond geometry to one Cu(1) atom. O(1) is bonded in a tetrahedral geometry to four equivalent Cu(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms.