VTiO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with three equivalent V(1)O6 octahedra, corners with six equivalent Ti(1)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and  a faceface with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra, corners with six equivalent V(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Ti(1) and two equivalent V(1) atoms.
VTiO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with three equivalent V(1)O6 octahedra, corners with six equivalent Ti(1)O6 octahedra, edges with three equivalent V(1)O6 octahedra, and  a faceface with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-57°. There are three shorter (1.92 Å) and three longer (2.13 Å) Ti(1)-O(1) bond lengths. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with three equivalent Ti(1)O6 octahedra, corners with six equivalent V(1)O6 octahedra, edges with three equivalent Ti(1)O6 octahedra, and  a faceface with one Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. There are three shorter (2.05 Å) and three longer (2.09 Å) V(1)-O(1) bond lengths. O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Ti(1) and two equivalent V(1) atoms.