AgAsBr4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Ag(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form AgBr6 octahedra that share edges with two equivalent Ag(1)Br6 octahedra and edges with four equivalent As(1)Br6 octahedra. As(1) is bonded to two equivalent Br(1) and four equivalent Br(2) atoms to form AsBr6 octahedra that share edges with two equivalent As(1)Br6 octahedra and edges with four equivalent Ag(1)Br6 octahedra. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted T-shaped geometry to two equivalent Ag(1) and one As(1) atom. In the second Br site, Br(2) is bonded in a distorted T-shaped geometry to one Ag(1) and two equivalent As(1) atoms.
AgAsBr4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Ag(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form AgBr6 octahedra that share edges with two equivalent Ag(1)Br6 octahedra and edges with four equivalent As(1)Br6 octahedra. Both Ag(1)-Br(2) bond lengths are 3.15 Å. All Ag(1)-Br(1) bond lengths are 2.84 Å. As(1) is bonded to two equivalent Br(1) and four equivalent Br(2) atoms to form AsBr6 octahedra that share edges with two equivalent As(1)Br6 octahedra and edges with four equivalent Ag(1)Br6 octahedra. Both As(1)-Br(1) bond lengths are 2.67 Å. All As(1)-Br(2) bond lengths are 2.71 Å. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted T-shaped geometry to two equivalent Ag(1) and one As(1) atom. In the second Br site, Br(2) is bonded in a distorted T-shaped geometry to one Ag(1) and two equivalent As(1) atoms.