MoAg2(O7I2)2 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent O(5), and two equivalent O(7) atoms. Ag(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), and two equivalent O(1) atoms. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one Mo(1), one Ag(1), and one I(1) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to one Ag(1) and two equivalent I(1) atoms. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one I(1), and one I(2) atom. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one I(2) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(1) and one I(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1), one I(1), and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), and two equivalent O(3) atoms. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom.
MoAg2(O7I2)2 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent O(5), and two equivalent O(7) atoms. Both Mo(1)-O(2) bond lengths are 1.99 Å. Both Mo(1)-O(5) bond lengths are 2.23 Å. Both Mo(1)-O(7) bond lengths are 1.76 Å. Ag(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), and two equivalent O(1) atoms. The Ag(1)-O(2) bond length is 2.63 Å. The Ag(1)-O(3) bond length is 2.58 Å. The Ag(1)-O(4) bond length is 2.68 Å. The Ag(1)-O(6) bond length is 2.44 Å. There is one shorter (2.43 Å) and one longer (2.66 Å) Ag(1)-O(1) bond length. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal planar geometry to one Mo(1), one Ag(1), and one I(1) atom. The O(2)-I(1) bond length is 1.96 Å. In the second O site, O(3) is bonded in a 3-coordinate geometry to one Ag(1) and two equivalent I(1) atoms. There is one shorter (1.86 Å) and one longer (2.37 Å) O(3)-I(1) bond length. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one I(1), and one I(2) atom. The O(4)-I(1) bond length is 2.47 Å. The O(4)-I(2) bond length is 1.84 Å. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one I(2) atom. The O(5)-I(2) bond length is 1.88 Å. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(1) and one I(2) atom. The O(6)-I(2) bond length is 1.82 Å. In the sixth O site, O(7) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1), one I(1), and one I(2) atom. The O(1)-I(1) bond length is 1.85 Å. The O(1)-I(2) bond length is 2.70 Å. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), and two equivalent O(3) atoms. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(1), one O(4), one O(5), and one O(6) atom.