AgIn(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Ag(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. Ag(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form distorted AgO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-56°. In(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form distorted InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent W(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent In(1) atoms.
AgIn(WO4)2 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Ag(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. The W(1)-O(2) bond length is 1.74 Å. The W(1)-O(4) bond length is 1.87 Å. There is one shorter (1.97 Å) and one longer (2.21 Å) W(1)-O(1) bond length. There is one shorter (1.88 Å) and one longer (2.06 Å) W(1)-O(3) bond length. Ag(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form distorted AgO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-56°. Both Ag(1)-O(3) bond lengths are 2.37 Å. There are two shorter (2.40 Å) and two longer (2.47 Å) Ag(1)-O(2) bond lengths. In(1) is bonded to two equivalent O(1) and four equivalent O(4) atoms to form distorted InO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-57°. Both In(1)-O(1) bond lengths are 2.10 Å. There are two shorter (2.16 Å) and two longer (2.28 Å) In(1)-O(4) bond lengths. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one In(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent W(1) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent In(1) atoms.