FeCl4FeO3Cl2O2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules, four tetrachloroferrat(iii) molecules, and four FeO3Cl2 clusters. In each FeO3Cl2 cluster, Fe(2) is bonded in a distorted trigonal bipyramidal geometry to one O(3), one O(4), one O(5), one Cl(5), and one Cl(6) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Fe(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Fe(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Fe(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Fe(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Fe(2) atom.
FeCl4FeO3Cl2O2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules, four tetrachloroferrat(iii) molecules, and four FeO3Cl2 clusters. In each FeO3Cl2 cluster, Fe(2) is bonded in a distorted trigonal bipyramidal geometry to one O(3), one O(4), one O(5), one Cl(5), and one Cl(6) atom. The Fe(2)-O(3) bond length is 1.70 Å. The Fe(2)-O(4) bond length is 1.63 Å. The Fe(2)-O(5) bond length is 1.79 Å. The Fe(2)-Cl(5) bond length is 2.26 Å. The Fe(2)-Cl(6) bond length is 2.19 Å. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Fe(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Fe(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Fe(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Fe(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Fe(2) atom.