Li3CrCo3O8 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(3)O6 octahedra, corners with three equivalent Co(4)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(5)O6 octahedra, corners with three equivalent Co(6)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(8) atoms to form CrO6 octahedra that share edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. In the second Cr site, Cr(2) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CrO6 octahedra that share edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the fourth Co site, Co(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fifth Co site, Co(5) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the sixth Co site, Co(6) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Co(1), one Co(3), and one Co(5) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li2CrCo2 square pyramid,  an edgeedge with one O(6)Li2CrCo2 square pyramid,  an edgeedge with one O(8)Li2CrCo2 square pyramid, edges with three equivalent O(3)Li2CrCo2 square pyramids, edges with three equivalent O(5)Li2CrCo2 square pyramids, and edges with three equivalent O(7)Li2CrCo2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Co(6) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li2CrCo2 square pyramid,  an edgeedge with one O(5)Li2CrCo2 square pyramid,  an edgeedge with one O(7)Li2CrCo2 square pyramid, edges with three equivalent O(4)Li2CrCo2 square pyramids, edges with three equivalent O(6)Li2CrCo2 square pyramids, and edges with three equivalent O(8)Li2CrCo2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Cr(2), one Co(1), and one Co(3) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(4)Li2CrCo2 square pyramids, corners with three equivalent O(3)Li2CrCo2 square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(5)Li2CrCo2 square pyramids, and edges with two equivalent O(7)Li2CrCo2 square pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Cr(1), one Co(2), and one Co(4) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(3)Li2CrCo2 square pyramids, corners with three equivalent O(4)Li2CrCo2 square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(6)Li2CrCo2 square pyramids, and edges with two equivalent O(8)Li2CrCo2 square pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Cr(2), one Co(1), and one Co(5) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(6)Li2CrCo2 square pyramids, corners with three equivalent O(5)Li2CrCo2 square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2CrCo2 square pyramids, and edges with two equivalent O(7)Li2CrCo2 square pyramids. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Cr(1), one Co(2), and one Co(6) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(5)Li2CrCo2 square pyramids, corners with three equivalent O(6)Li2CrCo2 square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2CrCo2 square pyramids, and edges with two equivalent O(8)Li2CrCo2 square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Cr(2), one Co(3), and one Co(5) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid, corners with two equivalent O(8)Li2CrCo2 square pyramids, corners with three equivalent O(7)Li2CrCo2 square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2CrCo2 square pyramids, and edges with two equivalent O(5)Li2CrCo2 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Cr(1), one Co(4), and one Co(6) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid, corners with two equivalent O(7)Li2CrCo2 square pyramids, corners with three equivalent O(8)Li2CrCo2 square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2CrCo2 square pyramids, and edges with two equivalent O(6)Li2CrCo2 square pyramids.
Li3CrCo3O8 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(3)O6 octahedra, corners with three equivalent Co(4)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-11°. The Li(1)-O(1) bond length is 2.14 Å. The Li(1)-O(2) bond length is 2.10 Å. The Li(1)-O(3) bond length is 2.16 Å. The Li(1)-O(4) bond length is 2.19 Å. The Li(1)-O(7) bond length is 2.22 Å. The Li(1)-O(8) bond length is 2.16 Å. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(5)O6 octahedra, corners with three equivalent Co(6)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The Li(2)-O(1) bond length is 2.13 Å. The Li(2)-O(2) bond length is 2.10 Å. The Li(2)-O(5) bond length is 2.15 Å. The Li(2)-O(6) bond length is 2.17 Å. The Li(2)-O(7) bond length is 2.23 Å. The Li(2)-O(8) bond length is 2.17 Å. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. The Li(3)-O(1) bond length is 2.30 Å. The Li(3)-O(2) bond length is 2.08 Å. The Li(3)-O(3) bond length is 2.27 Å. The Li(3)-O(4) bond length is 2.21 Å. The Li(3)-O(5) bond length is 2.28 Å. The Li(3)-O(6) bond length is 2.21 Å. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(8) atoms to form CrO6 octahedra that share edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. Both Cr(1)-O(4) bond lengths are 2.00 Å. Both Cr(1)-O(6) bond lengths are 1.99 Å. Both Cr(1)-O(8) bond lengths are 2.00 Å. In the second Cr site, Cr(2) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CrO6 octahedra that share edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. Both Cr(2)-O(3) bond lengths are 1.99 Å. Both Cr(2)-O(5) bond lengths are 1.99 Å. Both Cr(2)-O(7) bond lengths are 2.00 Å. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. Both Co(1)-O(1) bond lengths are 1.96 Å. Both Co(1)-O(3) bond lengths are 1.90 Å. Both Co(1)-O(5) bond lengths are 1.90 Å. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. Both Co(2)-O(2) bond lengths are 2.10 Å. Both Co(2)-O(4) bond lengths are 1.94 Å. Both Co(2)-O(6) bond lengths are 1.93 Å. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. Both Co(3)-O(1) bond lengths are 2.04 Å. Both Co(3)-O(3) bond lengths are 2.06 Å. Both Co(3)-O(7) bond lengths are 1.96 Å. In the fourth Co site, Co(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. Both Co(4)-O(2) bond lengths are 2.04 Å. Both Co(4)-O(4) bond lengths are 2.05 Å. Both Co(4)-O(8) bond lengths are 1.99 Å. In the fifth Co site, Co(5) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. Both Co(5)-O(1) bond lengths are 2.04 Å. Both Co(5)-O(5) bond lengths are 2.06 Å. Both Co(5)-O(7) bond lengths are 1.97 Å. In the sixth Co site, Co(6) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. Both Co(6)-O(2) bond lengths are 2.04 Å. Both Co(6)-O(6) bond lengths are 2.09 Å. Both Co(6)-O(8) bond lengths are 1.97 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one Li(3), one Co(1), one Co(3), and one Co(5) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li2CrCo2 square pyramid,  an edgeedge with one O(6)Li2CrCo2 square pyramid,  an edgeedge with one O(8)Li2CrCo2 square pyramid, edges with three equivalent O(3)Li2CrCo2 square pyramids, edges with three equivalent O(5)Li2CrCo2 square pyramids, and edges with three equivalent O(7)Li2CrCo2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(3), one Co(2), one Co(4), and one Co(6) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li2CrCo2 square pyramid,  an edgeedge with one O(5)Li2CrCo2 square pyramid,  an edgeedge with one O(7)Li2CrCo2 square pyramid, edges with three equivalent O(4)Li2CrCo2 square pyramids, edges with three equivalent O(6)Li2CrCo2 square pyramids, and edges with three equivalent O(8)Li2CrCo2 square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Cr(2), one Co(1), and one Co(3) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(4)Li2CrCo2 square pyramids, corners with three equivalent O(3)Li2CrCo2 square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(5)Li2CrCo2 square pyramids, and edges with two equivalent O(7)Li2CrCo2 square pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one Cr(1), one Co(2), and one Co(4) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(3)Li2CrCo2 square pyramids, corners with three equivalent O(4)Li2CrCo2 square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(6)Li2CrCo2 square pyramids, and edges with two equivalent O(8)Li2CrCo2 square pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Cr(2), one Co(1), and one Co(5) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(6)Li2CrCo2 square pyramids, corners with three equivalent O(5)Li2CrCo2 square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2CrCo2 square pyramids, and edges with two equivalent O(7)Li2CrCo2 square pyramids. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Cr(1), one Co(2), and one Co(6) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(7)Li2CrCo2 square pyramid,  a cornercorner with one O(8)Li2CrCo2 square pyramid, corners with two equivalent O(5)Li2CrCo2 square pyramids, corners with three equivalent O(6)Li2CrCo2 square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2CrCo2 square pyramids, and edges with two equivalent O(8)Li2CrCo2 square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Cr(2), one Co(3), and one Co(5) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid, corners with two equivalent O(8)Li2CrCo2 square pyramids, corners with three equivalent O(7)Li2CrCo2 square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2CrCo2 square pyramids, and edges with two equivalent O(5)Li2CrCo2 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Cr(1), one Co(4), and one Co(6) atom to form OLi2CrCo2 square pyramids that share  a cornercorner with one O(3)Li2CrCo2 square pyramid,  a cornercorner with one O(4)Li2CrCo2 square pyramid,  a cornercorner with one O(5)Li2CrCo2 square pyramid,  a cornercorner with one O(6)Li2CrCo2 square pyramid, corners with two equivalent O(7)Li2CrCo2 square pyramids, corners with three equivalent O(8)Li2CrCo2 square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2CrCo2 square pyramids, and edges with two equivalent O(6)Li2CrCo2 square pyramids.