KLaTiO4 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 9-coordinate geometry to two equivalent O(2), two equivalent O(4), and five equivalent O(3) atoms. La(1) is bonded in a 9-coordinate geometry to two equivalent O(2), two equivalent O(4), and five equivalent O(1) atoms. Ti(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to five equivalent La(1) and one Ti(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent K(1), two equivalent La(1), and two equivalent Ti(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to five equivalent K(1) and one Ti(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent La(1), and two equivalent Ti(1) atoms.
KLaTiO4 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 9-coordinate geometry to two equivalent O(2), two equivalent O(4), and five equivalent O(3) atoms. Both K(1)-O(2) bond lengths are 3.07 Å. Both K(1)-O(4) bond lengths are 3.19 Å. There are a spread of K(1)-O(3) bond distances ranging from 2.73-2.76 Å. La(1) is bonded in a 9-coordinate geometry to two equivalent O(2), two equivalent O(4), and five equivalent O(1) atoms. Both La(1)-O(2) bond lengths are 2.56 Å. Both La(1)-O(4) bond lengths are 2.55 Å. There are a spread of La(1)-O(1) bond distances ranging from 2.35-3.00 Å. Ti(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms. The Ti(1)-O(1) bond length is 2.64 Å. The Ti(1)-O(3) bond length is 1.76 Å. Both Ti(1)-O(2) bond lengths are 1.97 Å. Both Ti(1)-O(4) bond lengths are 1.98 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to five equivalent La(1) and one Ti(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent K(1), two equivalent La(1), and two equivalent Ti(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to five equivalent K(1) and one Ti(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent La(1), and two equivalent Ti(1) atoms.