Ag2ZnC4(NS)4 crystallizes in the monoclinic C2/c space group. Ag(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(2) atom.
Ag2ZnC4(NS)4 crystallizes in the monoclinic C2/c space group. Ag(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing AgS4 tetrahedra. There is one shorter (2.59 Å) and one longer (2.60 Å) Ag(1)-S(1) bond length. There is one shorter (2.64 Å) and one longer (2.67 Å) Ag(1)-S(2) bond length. Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Zn(1)-N(1) bond lengths are 1.97 Å. Both Zn(1)-N(2) bond lengths are 1.97 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(1)-N(2) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.64 Å. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one S(2) atom. The C(2)-N(1) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.64 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(2) atom.