TiAg2(O3I)6 crystallizes in the trigonal R-3 space group. Ti(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. Ag(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one I(1) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to two equivalent I(1) atoms. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one I(1) atom. I(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms.
TiAg2(O3I)6 crystallizes in the trigonal R-3 space group. Ti(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Ti(1)-O(1) bond lengths are 1.97 Å. Ag(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. All Ag(1)-O(2) bond lengths are 2.58 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one I(1) atom. The O(2)-I(1) bond length is 1.84 Å. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to two equivalent I(1) atoms. There is one shorter (1.84 Å) and one longer (2.37 Å) O(3)-I(1) bond length. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one I(1) atom. The O(1)-I(1) bond length is 1.91 Å. I(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms.