CoC2N4H8(O2Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CoC2N4H8(O2Cl)2 clusters. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Co(1) atom.
CoC2N4H8(O2Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CoC2N4H8(O2Cl)2 clusters. Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms. Both Co(1)-O(1) bond lengths are 2.02 Å. Both Co(1)-O(2) bond lengths are 2.13 Å. Both Co(1)-Cl(1) bond lengths are 2.40 Å. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(2) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.38 Å. The C(1)-O(2) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. The N(1)-H(3) bond length is 1.02 Å. The N(1)-H(4) bond length is 1.02 Å. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.99 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. Cl(1) is bonded in a distorted single-bond geometry to one Co(1) atom.