AgSnO3 crystallizes in the orthorhombic Cmmm space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of edge and corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded to two equivalent Ag(2) and two equivalent Sn(1) atoms to form a mixture of distorted edge and corner-sharing OAg2Sn2 tetrahedra.
AgSnO3 crystallizes in the orthorhombic Cmmm space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Ag(1)-O(1) bond lengths are 2.05 Å. In the second Ag site, Ag(2) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Ag(2)-O(1) bond lengths are 2.69 Å. All Ag(2)-O(2) bond lengths are 2.50 Å. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of edge and corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 47°. Both Sn(1)-O(2) bond lengths are 2.06 Å. All Sn(1)-O(1) bond lengths are 2.13 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded to two equivalent Ag(2) and two equivalent Sn(1) atoms to form a mixture of distorted edge and corner-sharing OAg2Sn2 tetrahedra.