Ti3Os3As2P crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 11-coordinate geometry to two equivalent Os(1), four equivalent Os(2), four equivalent As(1), and one P(1) atom. In the second Ti site, Ti(2) is bonded in a 11-coordinate geometry to two equivalent Os(1), four equivalent Os(2), four equivalent As(1), and one P(1) atom. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 10-coordinate geometry to two equivalent Ti(1), four equivalent Ti(2), two equivalent As(1), and two equivalent P(1) atoms. In the second Os site, Os(2) is bonded in a 10-coordinate geometry to two equivalent Ti(1), four equivalent Ti(2), two equivalent As(1), and two equivalent P(1) atoms. As(1) is bonded in a 9-coordinate geometry to two equivalent Ti(1), four equivalent Ti(2), one Os(1), and two equivalent Os(2) atoms. P(1) is bonded in a 9-coordinate geometry to one Ti(1), two equivalent Ti(2), two equivalent Os(1), and four equivalent Os(2) atoms.
Ti3Os3As2P crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 11-coordinate geometry to two equivalent Os(1), four equivalent Os(2), four equivalent As(1), and one P(1) atom. Both Ti(1)-Os(1) bond lengths are 2.86 Å. All Ti(1)-Os(2) bond lengths are 2.83 Å. All Ti(1)-As(1) bond lengths are 2.70 Å. The Ti(1)-P(1) bond length is 2.63 Å. In the second Ti site, Ti(2) is bonded in a 11-coordinate geometry to two equivalent Os(1), four equivalent Os(2), four equivalent As(1), and one P(1) atom. Both Ti(2)-Os(1) bond lengths are 2.83 Å. There are two shorter (2.81 Å) and two longer (2.86 Å) Ti(2)-Os(2) bond lengths. There are two shorter (2.69 Å) and two longer (2.70 Å) Ti(2)-As(1) bond lengths. The Ti(2)-P(1) bond length is 2.65 Å. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 10-coordinate geometry to two equivalent Ti(1), four equivalent Ti(2), two equivalent As(1), and two equivalent P(1) atoms. Both Os(1)-As(1) bond lengths are 2.56 Å. Both Os(1)-P(1) bond lengths are 2.52 Å. In the second Os site, Os(2) is bonded in a 10-coordinate geometry to two equivalent Ti(1), four equivalent Ti(2), two equivalent As(1), and two equivalent P(1) atoms. There is one shorter (2.56 Å) and one longer (2.57 Å) Os(2)-As(1) bond length. Both Os(2)-P(1) bond lengths are 2.53 Å. As(1) is bonded in a 9-coordinate geometry to two equivalent Ti(1), four equivalent Ti(2), one Os(1), and two equivalent Os(2) atoms. P(1) is bonded in a 9-coordinate geometry to one Ti(1), two equivalent Ti(2), two equivalent Os(1), and four equivalent Os(2) atoms.