Zn(NH3)(CO3) crystallizes in the orthorhombic Pna2_1 space group. Zn(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. N(1) is bonded in a distorted tetrahedral geometry to one Zn(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom.
Zn(NH3)(CO3) crystallizes in the orthorhombic Pna2_1 space group. Zn(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. The Zn(1)-N(1) bond length is 1.99 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.98 Å. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.27 Å. N(1) is bonded in a distorted tetrahedral geometry to one Zn(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.02 Å. The N(1)-H(2) bond length is 1.02 Å. The N(1)-H(3) bond length is 1.02 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom.