LiReO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Re(1) is bonded to six equivalent O(1) atoms to form corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles are 35°. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Li(1) and two equivalent Re(1) atoms.
LiReO3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (2.06 Å) and three longer (2.36 Å) Li(1)-O(1) bond lengths. Re(1) is bonded to six equivalent O(1) atoms to form corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles are 35°. There are three shorter (1.94 Å) and three longer (1.97 Å) Re(1)-O(1) bond lengths. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Li(1) and two equivalent Re(1) atoms.