LiSrPrTeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. Sr(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. Pr(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. Te(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TeO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Sr(1), one Pr(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), two equivalent Pr(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), two equivalent Pr(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Sr(1), one Pr(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom.
LiSrPrTeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Pc space group. Li(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form LiO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. The Li(1)-O(1) bond length is 2.16 Å. The Li(1)-O(2) bond length is 2.24 Å. The Li(1)-O(3) bond length is 2.22 Å. The Li(1)-O(4) bond length is 2.20 Å. The Li(1)-O(5) bond length is 2.15 Å. The Li(1)-O(6) bond length is 2.13 Å. Sr(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. The Sr(1)-O(2) bond length is 2.55 Å. The Sr(1)-O(3) bond length is 2.53 Å. The Sr(1)-O(5) bond length is 2.62 Å. The Sr(1)-O(6) bond length is 2.52 Å. There is one shorter (2.75 Å) and one longer (2.82 Å) Sr(1)-O(1) bond length. There is one shorter (2.76 Å) and one longer (2.82 Å) Sr(1)-O(4) bond length. Pr(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. The Pr(1)-O(1) bond length is 2.45 Å. The Pr(1)-O(4) bond length is 2.48 Å. The Pr(1)-O(5) bond length is 2.43 Å. The Pr(1)-O(6) bond length is 2.46 Å. There is one shorter (2.71 Å) and one longer (2.73 Å) Pr(1)-O(2) bond length. There is one shorter (2.61 Å) and one longer (2.84 Å) Pr(1)-O(3) bond length. Te(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TeO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. The Te(1)-O(1) bond length is 1.95 Å. The Te(1)-O(2) bond length is 1.96 Å. The Te(1)-O(3) bond length is 1.96 Å. The Te(1)-O(4) bond length is 1.95 Å. The Te(1)-O(5) bond length is 1.96 Å. The Te(1)-O(6) bond length is 1.95 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Sr(1), one Pr(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), two equivalent Pr(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(1), one Sr(1), two equivalent Pr(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), two equivalent Sr(1), one Pr(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(1), one Sr(1), one Pr(1), and one Te(1) atom.