ZrN is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Zr(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing ZrN6 pentagonal pyramids. N(1) is bonded to six equivalent Zr(1) atoms to form a mixture of edge, face, and corner-sharing NZr6 octahedra. The corner-sharing octahedral tilt angles are 47°.
ZrN is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Zr(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing ZrN6 pentagonal pyramids. All Zr(1)-N(1) bond lengths are 2.30 Å. N(1) is bonded to six equivalent Zr(1) atoms to form a mixture of edge, face, and corner-sharing NZr6 octahedra. The corner-sharing octahedral tilt angles are 47°.