Li3Co4SnO8 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Sn(1)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(4)O6 octahedra, corners with three equivalent Co(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the second Co site, Co(2) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. In the third Co site, Co(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the fourth Co site, Co(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the fifth Co site, Co(5) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the sixth Co site, Co(6) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. In the second Sn site, Sn(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Li(4), one Co(5), one Co(6), and one Sn(2) atom to form OLi3Co2Sn octahedra that share corners with three equivalent O(1)Li3Co2Sn octahedra, corners with three equivalent O(2)Li3Co2Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(8)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co4 octahedra, edges with three equivalent O(5)Li2Co3Sn octahedra, edges with three equivalent O(7)Li2Co3Sn octahedra, and edges with three equivalent O(3)Li2Co4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(4), one Co(4), one Co(6), and one Sn(1) atom to form OLi3Co2Sn octahedra that share corners with three equivalent O(1)Li3Co2Sn octahedra, corners with three equivalent O(2)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li2Co3Sn octahedra,  an edgeedge with one O(7)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li2Co4 octahedra, edges with three equivalent O(6)Li2Co3Sn octahedra, edges with three equivalent O(8)Li2Co3Sn octahedra, and edges with three equivalent O(4)Li2Co4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Co(1), one Co(3), one Co(5), and one Co(6) atom to form OLi2Co4 octahedra that share corners with three equivalent O(3)Li2Co4 octahedra, corners with three equivalent O(4)Li2Co4 octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(8)Li2Co3Sn octahedra,  an edgeedge with one O(2)Li3Co2Sn octahedra, edges with three equivalent O(5)Li2Co3Sn octahedra, edges with three equivalent O(7)Li2Co3Sn octahedra, and edges with three equivalent O(1)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fourth O site, O(4) is bonded to one Li(2), one Li(4), one Co(2), one Co(3), one Co(4), and one Co(6) atom to form OLi2Co4 octahedra that share corners with three equivalent O(3)Li2Co4 octahedra, corners with three equivalent O(4)Li2Co4 octahedra,  an edgeedge with one O(5)Li2Co3Sn octahedra,  an edgeedge with one O(7)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with three equivalent O(6)Li2Co3Sn octahedra, edges with three equivalent O(8)Li2Co3Sn octahedra, and edges with three equivalent O(2)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Co(1), one Co(3), one Co(6), and one Sn(2) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(5)Li2Co3Sn octahedra, corners with three equivalent O(6)Li2Co3Sn octahedra,  an edgeedge with one O(8)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co4 octahedra,  an edgeedge with one O(2)Li3Co2Sn octahedra, edges with three equivalent O(7)Li2Co3Sn octahedra, edges with three equivalent O(3)Li2Co4 octahedra, and edges with three equivalent O(1)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Co(2), one Co(3), one Co(6), and one Sn(1) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(5)Li2Co3Sn octahedra, corners with three equivalent O(6)Li2Co3Sn octahedra,  an edgeedge with one O(7)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li2Co4 octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with three equivalent O(8)Li2Co3Sn octahedra, edges with three equivalent O(4)Li2Co4 octahedra, and edges with three equivalent O(2)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Co(1), one Co(3), one Co(5), and one Sn(2) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(7)Li2Co3Sn octahedra, corners with three equivalent O(8)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co4 octahedra,  an edgeedge with one O(2)Li3Co2Sn octahedra, edges with three equivalent O(5)Li2Co3Sn octahedra, edges with three equivalent O(3)Li2Co4 octahedra, and edges with three equivalent O(1)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Co(2), one Co(3), one Co(4), and one Sn(1) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(7)Li2Co3Sn octahedra, corners with three equivalent O(8)Li2Co3Sn octahedra,  an edgeedge with one O(5)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li2Co4 octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with three equivalent O(6)Li2Co3Sn octahedra, edges with three equivalent O(4)Li2Co4 octahedra, and edges with three equivalent O(2)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°.
Li3Co4SnO8 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Sn(1)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. The Li(1)-O(1) bond length is 2.19 Å. The Li(1)-O(2) bond length is 2.15 Å. The Li(1)-O(5) bond length is 2.22 Å. The Li(1)-O(6) bond length is 2.22 Å. The Li(1)-O(7) bond length is 2.20 Å. The Li(1)-O(8) bond length is 2.21 Å. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. Both Li(2)-O(2) bond lengths are 2.21 Å. Both Li(2)-O(4) bond lengths are 2.20 Å. Both Li(2)-O(6) bond lengths are 2.09 Å. In the third Li site, Li(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Co(6)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. Both Li(3)-O(1) bond lengths are 2.18 Å. Both Li(3)-O(3) bond lengths are 2.20 Å. Both Li(3)-O(5) bond lengths are 2.14 Å. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(4)O6 octahedra, corners with three equivalent Co(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. The Li(4)-O(1) bond length is 2.43 Å. The Li(4)-O(2) bond length is 2.11 Å. The Li(4)-O(3) bond length is 2.45 Å. The Li(4)-O(4) bond length is 2.12 Å. The Li(4)-O(7) bond length is 2.04 Å. The Li(4)-O(8) bond length is 2.10 Å. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. Both Co(1)-O(3) bond lengths are 2.13 Å. Both Co(1)-O(5) bond lengths are 2.16 Å. Both Co(1)-O(7) bond lengths are 2.17 Å. In the second Co site, Co(2) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Co(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-4°. Both Co(2)-O(4) bond lengths are 1.95 Å. Both Co(2)-O(6) bond lengths are 2.14 Å. Both Co(2)-O(8) bond lengths are 2.17 Å. In the third Co site, Co(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. The Co(3)-O(3) bond length is 2.12 Å. The Co(3)-O(4) bond length is 2.31 Å. The Co(3)-O(5) bond length is 2.12 Å. The Co(3)-O(6) bond length is 2.19 Å. The Co(3)-O(7) bond length is 2.14 Å. The Co(3)-O(8) bond length is 2.17 Å. In the fourth Co site, Co(4) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. Both Co(4)-O(2) bond lengths are 2.11 Å. Both Co(4)-O(4) bond lengths are 2.14 Å. Both Co(4)-O(8) bond lengths are 2.15 Å. In the fifth Co site, Co(5) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(6)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. Both Co(5)-O(1) bond lengths are 1.96 Å. Both Co(5)-O(3) bond lengths are 1.94 Å. Both Co(5)-O(7) bond lengths are 2.22 Å. In the sixth Co site, Co(6) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with three equivalent Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sn(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. The Co(6)-O(1) bond length is 2.15 Å. The Co(6)-O(2) bond length is 2.11 Å. The Co(6)-O(3) bond length is 2.12 Å. The Co(6)-O(4) bond length is 2.12 Å. The Co(6)-O(5) bond length is 2.12 Å. The Co(6)-O(6) bond length is 2.14 Å. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-4°. Both Sn(1)-O(2) bond lengths are 2.07 Å. Both Sn(1)-O(6) bond lengths are 2.10 Å. Both Sn(1)-O(8) bond lengths are 2.11 Å. In the second Sn site, Sn(2) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form SnO6 octahedra that share corners with six equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(5)O6 octahedra, and edges with two equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. Both Sn(2)-O(1) bond lengths are 2.10 Å. Both Sn(2)-O(5) bond lengths are 2.09 Å. Both Sn(2)-O(7) bond lengths are 2.08 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Li(4), one Co(5), one Co(6), and one Sn(2) atom to form OLi3Co2Sn octahedra that share corners with three equivalent O(1)Li3Co2Sn octahedra, corners with three equivalent O(2)Li3Co2Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(8)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co4 octahedra, edges with three equivalent O(5)Li2Co3Sn octahedra, edges with three equivalent O(7)Li2Co3Sn octahedra, and edges with three equivalent O(3)Li2Co4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Li(4), one Co(4), one Co(6), and one Sn(1) atom to form OLi3Co2Sn octahedra that share corners with three equivalent O(1)Li3Co2Sn octahedra, corners with three equivalent O(2)Li3Co2Sn octahedra,  an edgeedge with one O(5)Li2Co3Sn octahedra,  an edgeedge with one O(7)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li2Co4 octahedra, edges with three equivalent O(6)Li2Co3Sn octahedra, edges with three equivalent O(8)Li2Co3Sn octahedra, and edges with three equivalent O(4)Li2Co4 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Co(1), one Co(3), one Co(5), and one Co(6) atom to form OLi2Co4 octahedra that share corners with three equivalent O(3)Li2Co4 octahedra, corners with three equivalent O(4)Li2Co4 octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(8)Li2Co3Sn octahedra,  an edgeedge with one O(2)Li3Co2Sn octahedra, edges with three equivalent O(5)Li2Co3Sn octahedra, edges with three equivalent O(7)Li2Co3Sn octahedra, and edges with three equivalent O(1)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fourth O site, O(4) is bonded to one Li(2), one Li(4), one Co(2), one Co(3), one Co(4), and one Co(6) atom to form OLi2Co4 octahedra that share corners with three equivalent O(3)Li2Co4 octahedra, corners with three equivalent O(4)Li2Co4 octahedra,  an edgeedge with one O(5)Li2Co3Sn octahedra,  an edgeedge with one O(7)Li2Co3Sn octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with three equivalent O(6)Li2Co3Sn octahedra, edges with three equivalent O(8)Li2Co3Sn octahedra, and edges with three equivalent O(2)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Co(1), one Co(3), one Co(6), and one Sn(2) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(5)Li2Co3Sn octahedra, corners with three equivalent O(6)Li2Co3Sn octahedra,  an edgeedge with one O(8)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co4 octahedra,  an edgeedge with one O(2)Li3Co2Sn octahedra, edges with three equivalent O(7)Li2Co3Sn octahedra, edges with three equivalent O(3)Li2Co4 octahedra, and edges with three equivalent O(1)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Co(2), one Co(3), one Co(6), and one Sn(1) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(5)Li2Co3Sn octahedra, corners with three equivalent O(6)Li2Co3Sn octahedra,  an edgeedge with one O(7)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li2Co4 octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with three equivalent O(8)Li2Co3Sn octahedra, edges with three equivalent O(4)Li2Co4 octahedra, and edges with three equivalent O(2)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Co(1), one Co(3), one Co(5), and one Sn(2) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(7)Li2Co3Sn octahedra, corners with three equivalent O(8)Li2Co3Sn octahedra,  an edgeedge with one O(6)Li2Co3Sn octahedra,  an edgeedge with one O(4)Li2Co4 octahedra,  an edgeedge with one O(2)Li3Co2Sn octahedra, edges with three equivalent O(5)Li2Co3Sn octahedra, edges with three equivalent O(3)Li2Co4 octahedra, and edges with three equivalent O(1)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Co(2), one Co(3), one Co(4), and one Sn(1) atom to form OLi2Co3Sn octahedra that share corners with three equivalent O(7)Li2Co3Sn octahedra, corners with three equivalent O(8)Li2Co3Sn octahedra,  an edgeedge with one O(5)Li2Co3Sn octahedra,  an edgeedge with one O(3)Li2Co4 octahedra,  an edgeedge with one O(1)Li3Co2Sn octahedra, edges with three equivalent O(6)Li2Co3Sn octahedra, edges with three equivalent O(4)Li2Co4 octahedra, and edges with three equivalent O(2)Li3Co2Sn octahedra. The corner-sharing octahedral tilt angles range from 0-7°.