ZrPdF6 crystallizes in the trigonal R-3 space group. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Pd(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom.
ZrPdF6 crystallizes in the trigonal R-3 space group. Zr(1) is bonded to six equivalent F(1) atoms to form ZrF6 octahedra that share corners with six equivalent Pd(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Zr(1)-F(1) bond lengths are 2.02 Å. Pd(1) is bonded to six equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Zr(1)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. All Pd(1)-F(1) bond lengths are 2.17 Å. F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom.