Pr2SbO2 is alpha bismuth trifluoride-derived structured and crystallizes in the orthorhombic Immm space group. Pr(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent O(1) atoms. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Pr(1) atoms. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of edge and corner-sharing OPr4 tetrahedra.
Pr2SbO2 is alpha bismuth trifluoride-derived structured and crystallizes in the orthorhombic Immm space group. Pr(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent O(1) atoms. All Pr(1)-Sb(1) bond lengths are 3.63 Å. There are two shorter (2.34 Å) and two longer (2.35 Å) Pr(1)-O(1) bond lengths. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Pr(1) atoms. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of edge and corner-sharing OPr4 tetrahedra.