BaMnSbF is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Ba(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent F(1) atoms. Mn(1) is bonded to four equivalent Sb(1) atoms to form a mixture of edge and corner-sharing MnSb4 tetrahedra. Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Mn(1) atoms. F(1) is bonded to four equivalent Ba(1) atoms to form a mixture of edge and corner-sharing FBa4 tetrahedra.
BaMnSbF is Parent of FeAs superconductors structured and crystallizes in the tetragonal P4/nmm space group. Ba(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1) and four equivalent F(1) atoms. All Ba(1)-Sb(1) bond lengths are 3.74 Å. All Ba(1)-F(1) bond lengths are 2.72 Å. Mn(1) is bonded to four equivalent Sb(1) atoms to form a mixture of edge and corner-sharing MnSb4 tetrahedra. All Mn(1)-Sb(1) bond lengths are 2.88 Å. Sb(1) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Mn(1) atoms. F(1) is bonded to four equivalent Ba(1) atoms to form a mixture of edge and corner-sharing FBa4 tetrahedra.