(PdCOCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two PdCOCl2 clusters. In each PdCOCl2 cluster, Pd(1) is bonded in a rectangular see-saw-like geometry to two equivalent C(1), one Cl(1), and one Cl(2) atom. C(1) is bonded in a distorted single-bond geometry to two equivalent Pd(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pd(1) atom.
(PdCOCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two PdCOCl2 clusters. In each PdCOCl2 cluster, Pd(1) is bonded in a rectangular see-saw-like geometry to two equivalent C(1), one Cl(1), and one Cl(2) atom. There is one shorter (2.08 Å) and one longer (2.09 Å) Pd(1)-C(1) bond length. The Pd(1)-Cl(1) bond length is 2.30 Å. The Pd(1)-Cl(2) bond length is 2.29 Å. C(1) is bonded in a distorted single-bond geometry to two equivalent Pd(1) and one O(1) atom. The C(1)-O(1) bond length is 1.15 Å. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pd(1) atom.