CoZnF4 is Fluorite-derived structured and crystallizes in the monoclinic C2/c space group. Co(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. Zn(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra. In the second F site, F(2) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra.
CoZnF4 is Fluorite-derived structured and crystallizes in the monoclinic C2/c space group. Co(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two shorter (2.09 Å) and two longer (2.35 Å) Co(1)-F(1) bond lengths. There are two shorter (2.11 Å) and two longer (2.27 Å) Co(1)-F(2) bond lengths. Zn(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two shorter (2.15 Å) and two longer (2.26 Å) Zn(1)-F(1) bond lengths. There are two shorter (2.17 Å) and two longer (2.24 Å) Zn(1)-F(2) bond lengths. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra. In the second F site, F(2) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra.