IrV crystallizes in the orthorhombic Cmcm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to one V(3), two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms. In the third V site, V(3) is bonded to one V(1), one V(3), two equivalent V(4), two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms to form a mixture of distorted corner and face-sharing VV4Ir8 cuboctahedra. In the fourth V site, V(4) is bonded in a 8-coordinate geometry to two equivalent V(3), two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms. There are four inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms. In the third Ir site, Ir(3) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms. In the fourth Ir site, Ir(4) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms.
IrV crystallizes in the orthorhombic Cmcm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to one V(3), two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms. The V(1)-V(3) bond length is 2.60 Å. Both V(1)-Ir(1) bond lengths are 2.61 Å. Both V(1)-Ir(2) bond lengths are 2.73 Å. Both V(1)-Ir(3) bond lengths are 2.60 Å. Both V(1)-Ir(4) bond lengths are 2.63 Å. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms. Both V(2)-Ir(1) bond lengths are 2.55 Å. Both V(2)-Ir(2) bond lengths are 2.54 Å. Both V(2)-Ir(3) bond lengths are 2.56 Å. Both V(2)-Ir(4) bond lengths are 2.63 Å. In the third V site, V(3) is bonded to one V(1), one V(3), two equivalent V(4), two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms to form a mixture of distorted corner and face-sharing VV4Ir8 cuboctahedra. The V(3)-V(3) bond length is 2.60 Å. There is one shorter (2.51 Å) and one longer (2.76 Å) V(3)-V(4) bond length. Both V(3)-Ir(1) bond lengths are 2.71 Å. Both V(3)-Ir(2) bond lengths are 2.79 Å. Both V(3)-Ir(3) bond lengths are 2.79 Å. Both V(3)-Ir(4) bond lengths are 2.68 Å. In the fourth V site, V(4) is bonded in a 8-coordinate geometry to two equivalent V(3), two equivalent Ir(1), two equivalent Ir(2), two equivalent Ir(3), and two equivalent Ir(4) atoms. Both V(4)-Ir(1) bond lengths are 2.74 Å. Both V(4)-Ir(2) bond lengths are 2.58 Å. Both V(4)-Ir(3) bond lengths are 2.70 Å. Both V(4)-Ir(4) bond lengths are 2.71 Å. There are four inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms. In the third Ir site, Ir(3) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms. In the fourth Ir site, Ir(4) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent V(4) atoms.