NaOsO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Os(1)O6 octahedra. Os(1) is bonded to six equivalent O(1) atoms to form OsO6 octahedra that share corners with six equivalent Os(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Na(1) and two equivalent Os(1) atoms to form a mixture of distorted corner, edge, and face-sharing ONa4Os2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
NaOsO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent Os(1)O6 octahedra. All Na(1)-O(1) bond lengths are 2.74 Å. Os(1) is bonded to six equivalent O(1) atoms to form OsO6 octahedra that share corners with six equivalent Os(1)O6 octahedra and faces with eight equivalent Na(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Os(1)-O(1) bond lengths are 1.94 Å. O(1) is bonded to four equivalent Na(1) and two equivalent Os(1) atoms to form a mixture of distorted corner, edge, and face-sharing ONa4Os2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°.