NaLi2N crystallizes in the hexagonal P6/mmm space group. Na(1) is bonded in a linear geometry to six equivalent Li(1) and two equivalent N(1) atoms. Li(1) is bonded in a hexagonal planar geometry to three equivalent Na(1) and three equivalent Li(1) atoms. N(1) is bonded in a linear geometry to two equivalent Na(1) atoms.
NaLi2N crystallizes in the hexagonal P6/mmm space group. Na(1) is bonded in a linear geometry to six equivalent Li(1) and two equivalent N(1) atoms. All Na(1)-Li(1) bond lengths are 2.95 Å. Both Na(1)-N(1) bond lengths are 2.06 Å. Li(1) is bonded in a hexagonal planar geometry to three equivalent Na(1) and three equivalent Li(1) atoms. All Li(1)-Li(1) bond lengths are 2.95 Å. N(1) is bonded in a linear geometry to two equivalent Na(1) atoms.