LiAgF3 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), and one F(6) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. In the third Ag site, Ag(3) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(5) atoms. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one Ag(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(2), and one Ag(4) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Ag(1), and one Ag(3) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(2), one Ag(2), and one Ag(4) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(3) atom.
LiAgF3 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), and one F(6) atom. The Li(1)-F(1) bond length is 2.10 Å. The Li(1)-F(2) bond length is 1.94 Å. The Li(1)-F(3) bond length is 2.02 Å. The Li(1)-F(6) bond length is 1.97 Å. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), and one F(6) atom. The Li(2)-F(3) bond length is 1.97 Å. The Li(2)-F(4) bond length is 1.94 Å. The Li(2)-F(5) bond length is 2.09 Å. The Li(2)-F(6) bond length is 2.02 Å. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(4) atoms. Both Ag(1)-F(1) bond lengths are 2.12 Å. Both Ag(1)-F(4) bond lengths are 2.09 Å. In the second Ag site, Ag(2) is bonded in an octahedral geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Both Ag(2)-F(2) bond lengths are 2.47 Å. Both Ag(2)-F(3) bond lengths are 2.19 Å. Both Ag(2)-F(5) bond lengths are 2.17 Å. In the third Ag site, Ag(3) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(4), and two equivalent F(6) atoms. Both Ag(3)-F(1) bond lengths are 2.17 Å. Both Ag(3)-F(4) bond lengths are 2.48 Å. Both Ag(3)-F(6) bond lengths are 2.18 Å. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(5) atoms. Both Ag(4)-F(2) bond lengths are 2.09 Å. Both Ag(4)-F(5) bond lengths are 2.12 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one Ag(3) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(2), and one Ag(4) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Ag(1), and one Ag(3) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(2), one Ag(2), and one Ag(4) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(1), one Li(2), and one Ag(3) atom.