SrSnO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Sr(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-24°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1) and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Sr(1) and two equivalent Sn(1) atoms.
SrSnO3 is Orthorhombic Perovskite-like structured and crystallizes in the orthorhombic Imma space group. Sr(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. The Sr(1)-O(2) bond length is 2.51 Å. All Sr(1)-O(1) bond lengths are 2.62 Å. Sn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 18-24°. Both Sn(1)-O(2) bond lengths are 2.06 Å. All Sn(1)-O(1) bond lengths are 2.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1) and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Sr(1) and two equivalent Sn(1) atoms.