Ce3Au3Bi4 crystallizes in the cubic I-43d space group. Ce(1) is bonded in a 12-coordinate geometry to four equivalent Au(1) and eight equivalent Bi(1) atoms. Au(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(1) atoms. Bi(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Au(1) atoms.
Ce3Au3Bi4 crystallizes in the cubic I-43d space group. Ce(1) is bonded in a 12-coordinate geometry to four equivalent Au(1) and eight equivalent Bi(1) atoms. All Ce(1)-Au(1) bond lengths are 3.17 Å. There are four shorter (3.50 Å) and four longer (3.66 Å) Ce(1)-Bi(1) bond lengths. Au(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(1) atoms. All Au(1)-Bi(1) bond lengths are 2.92 Å. Bi(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1) and three equivalent Au(1) atoms.