Pt(NCl2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pt(NCl2)2 clusters. Pt(1) is bonded in a distorted see-saw-like geometry to two equivalent N(1) and two equivalent Cl(1) atoms. N(1) is bonded in an L-shaped geometry to one Pt(1) and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.
Pt(NCl2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pt(NCl2)2 clusters. Pt(1) is bonded in a distorted see-saw-like geometry to two equivalent N(1) and two equivalent Cl(1) atoms. Both Pt(1)-N(1) bond lengths are 1.96 Å. Both Pt(1)-Cl(1) bond lengths are 2.35 Å. N(1) is bonded in an L-shaped geometry to one Pt(1) and one Cl(2) atom. The N(1)-Cl(2) bond length is 1.69 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom.