CuC2(N2S)2 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuC2(N2S)2 clusters. Cu(1) is bonded in a square co-planar geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(4) and one S(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a linear geometry to one Cu(1) and one C(2) atom. In the second N site, N(1) is bonded in a single-bond geometry to one Cu(1) atom. In the third N site, N(2) is bonded in a linear geometry to one Cu(1) and one C(1) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one Cu(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom.
CuC2(N2S)2 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuC2(N2S)2 clusters. Cu(1) is bonded in a square co-planar geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cu(1)-N(1) bond length is 1.89 Å. The Cu(1)-N(2) bond length is 1.81 Å. The Cu(1)-N(3) bond length is 1.91 Å. The Cu(1)-N(4) bond length is 1.81 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. The C(1)-N(2) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.60 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(4) and one S(2) atom. The C(2)-N(4) bond length is 1.19 Å. The C(2)-S(2) bond length is 1.60 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a linear geometry to one Cu(1) and one C(2) atom. In the second N site, N(1) is bonded in a single-bond geometry to one Cu(1) atom. In the third N site, N(2) is bonded in a linear geometry to one Cu(1) and one C(1) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one Cu(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(2) atom.