NaVO2 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and faces with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with twelve equivalent Na(1)O6 octahedra, edges with six equivalent V(1)O6 octahedra, and faces with two equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. O(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent V(1) atoms.
NaVO2 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 octahedra that share corners with twelve equivalent V(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and faces with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are two shorter (2.43 Å) and four longer (2.44 Å) Na(1)-O(1) bond lengths. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with twelve equivalent Na(1)O6 octahedra, edges with six equivalent V(1)O6 octahedra, and faces with two equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are four shorter (2.06 Å) and two longer (2.11 Å) V(1)-O(1) bond lengths. O(1) is bonded in a 6-coordinate geometry to three equivalent Na(1) and three equivalent V(1) atoms.