KTcO2 crystallizes in the tetragonal I4_1/amd space group. K(1) is bonded to six equivalent O(1) atoms to form edge-sharing KO6 octahedra. Tc(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent K(1) and two equivalent Tc(1) atoms to form a mixture of distorted edge and corner-sharing OK3Tc2 square pyramids.
KTcO2 crystallizes in the tetragonal I4_1/amd space group. K(1) is bonded to six equivalent O(1) atoms to form edge-sharing KO6 octahedra. There are four shorter (2.59 Å) and two longer (2.87 Å) K(1)-O(1) bond lengths. Tc(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. All Tc(1)-O(1) bond lengths are 2.05 Å. O(1) is bonded to three equivalent K(1) and two equivalent Tc(1) atoms to form a mixture of distorted edge and corner-sharing OK3Tc2 square pyramids.