(K)2NaSbI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaSbI6 framework. In the NaSbI6 framework, Na(1) is bonded to six equivalent I(1) atoms to form NaI6 octahedra that share corners with six equivalent Sb(1)I6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent I(1) atoms to form SbI6 octahedra that share corners with six equivalent Na(1)I6 octahedra. The corner-sharing octahedra are not tilted. I(1) is bonded in a linear geometry to one Na(1) and one Sb(1) atom.
(K)2NaSbI6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-09-7 atoms inside a NaSbI6 framework. In the NaSbI6 framework, Na(1) is bonded to six equivalent I(1) atoms to form NaI6 octahedra that share corners with six equivalent Sb(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Na(1)-I(1) bond lengths are 3.13 Å. Sb(1) is bonded to six equivalent I(1) atoms to form SbI6 octahedra that share corners with six equivalent Na(1)I6 octahedra. The corner-sharing octahedra are not tilted. All Sb(1)-I(1) bond lengths are 3.02 Å. I(1) is bonded in a linear geometry to one Na(1) and one Sb(1) atom.