CoPdP is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Co(1) is bonded to four equivalent Pd(1) and four equivalent P(1) atoms to form a mixture of distorted edge and face-sharing CoP4Pd4 tetrahedra. Pd(1) is bonded in a 13-coordinate geometry to four equivalent Co(1), four equivalent Pd(1), and five equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to four equivalent Co(1) and five equivalent Pd(1) atoms.
CoPdP is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Co(1) is bonded to four equivalent Pd(1) and four equivalent P(1) atoms to form a mixture of distorted edge and face-sharing CoP4Pd4 tetrahedra. All Co(1)-Pd(1) bond lengths are 2.84 Å. All Co(1)-P(1) bond lengths are 2.20 Å. Pd(1) is bonded in a 13-coordinate geometry to four equivalent Co(1), four equivalent Pd(1), and five equivalent P(1) atoms. All Pd(1)-Pd(1) bond lengths are 2.89 Å. There is one shorter (2.32 Å) and four longer (2.70 Å) Pd(1)-P(1) bond lengths. P(1) is bonded in a 9-coordinate geometry to four equivalent Co(1) and five equivalent Pd(1) atoms.