MgPbF6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent F(1) atoms to form MgF6 octahedra that share corners with six equivalent Pb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 42°. Pb(1) is bonded to six equivalent F(1) atoms to form PbF6 octahedra that share corners with six equivalent Mg(1)F6 octahedra. The corner-sharing octahedral tilt angles are 42°. F(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one Pb(1) atom.
MgPbF6 crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent F(1) atoms to form MgF6 octahedra that share corners with six equivalent Pb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 42°. All Mg(1)-F(1) bond lengths are 1.98 Å. Pb(1) is bonded to six equivalent F(1) atoms to form PbF6 octahedra that share corners with six equivalent Mg(1)F6 octahedra. The corner-sharing octahedral tilt angles are 42°. All Pb(1)-F(1) bond lengths are 2.08 Å. F(1) is bonded in a bent 150 degrees geometry to one Mg(1) and one Pb(1) atom.