Ti(PbN)4 crystallizes in the monoclinic C2/c space group. Ti(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. In the second Pb site, Pb(2) is bonded in a distorted T-shaped geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one Ti(1), two equivalent Pb(1), and two equivalent Pb(2) atoms. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Ti(1), one Pb(2), and two equivalent Pb(1) atoms.
Ti(PbN)4 crystallizes in the monoclinic C2/c space group. Ti(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ti(1)-N(1) bond lengths are 1.95 Å. Both Ti(1)-N(2) bond lengths are 1.94 Å. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. There is one shorter (2.63 Å) and one longer (2.84 Å) Pb(1)-N(1) bond length. There is one shorter (2.40 Å) and one longer (2.41 Å) Pb(1)-N(2) bond length. In the second Pb site, Pb(2) is bonded in a distorted T-shaped geometry to one N(2) and two equivalent N(1) atoms. The Pb(2)-N(2) bond length is 2.37 Å. There is one shorter (2.40 Å) and one longer (2.44 Å) Pb(2)-N(1) bond length. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 1-coordinate geometry to one Ti(1), two equivalent Pb(1), and two equivalent Pb(2) atoms. In the second N site, N(2) is bonded in a distorted rectangular see-saw-like geometry to one Ti(1), one Pb(2), and two equivalent Pb(1) atoms.