NaGaBP2H3O10 crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Ga(1) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(5) atoms. B(1) is bonded in a linear geometry to two equivalent O(2) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to two equivalent O(4) atoms. In the second H site, H(2) is bonded in a linear geometry to one O(1) and one O(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ga(1), one P(1), and one H(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one B(1) and one H(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Na(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Na(1), one P(1), and one H(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom.
NaGaBP2H3O10 crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Both Na(1)-O(3) bond lengths are 2.32 Å. Both Na(1)-O(4) bond lengths are 2.69 Å. Ga(1) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(5) atoms. Both Ga(1)-O(1) bond lengths are 2.01 Å. Both Ga(1)-O(5) bond lengths are 1.88 Å. B(1) is bonded in a linear geometry to two equivalent O(2) atoms. Both B(1)-O(2) bond lengths are 1.25 Å. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. The P(1)-O(1) bond length is 1.63 Å. The P(1)-O(3) bond length is 1.52 Å. The P(1)-O(4) bond length is 1.53 Å. The P(1)-O(5) bond length is 1.55 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to two equivalent O(4) atoms. Both H(1)-O(4) bond lengths are 1.19 Å. In the second H site, H(2) is bonded in a linear geometry to one O(1) and one O(2) atom. The H(2)-O(1) bond length is 1.14 Å. The H(2)-O(2) bond length is 1.25 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ga(1), one P(1), and one H(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one B(1) and one H(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Na(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Na(1), one P(1), and one H(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom.