AgIn2Te3I crystallizes in the monoclinic Cm space group. Ag(1) is bonded to one Te(2), two equivalent Te(3), and one I(1) atom to form AgTe3I tetrahedra that share corners with two equivalent Ag(1)Te3I tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent In(2)Te4 tetrahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to one Te(3), two equivalent Te(1), and one I(1) atom to form InTe3I tetrahedra that share corners with two equivalent In(1)Te3I tetrahedra, corners with three equivalent Ag(1)Te3I tetrahedra, and corners with three equivalent In(2)Te4 tetrahedra. In the second In site, In(2) is bonded to one Te(1), one Te(3), and two equivalent Te(2) atoms to form InTe4 tetrahedra that share corners with two equivalent In(2)Te4 tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent Ag(1)Te3I tetrahedra. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a trigonal non-coplanar geometry to one In(2) and two equivalent In(1) atoms. In the second Te site, Te(2) is bonded in a trigonal non-coplanar geometry to one Ag(1) and two equivalent In(2) atoms. In the third Te site, Te(3) is bonded to two equivalent Ag(1), one In(1), and one In(2) atom to form corner-sharing TeIn2Ag2 tetrahedra. I(1) is bonded in a water-like geometry to one Ag(1) and one In(1) atom.
AgIn2Te3I crystallizes in the monoclinic Cm space group. Ag(1) is bonded to one Te(2), two equivalent Te(3), and one I(1) atom to form AgTe3I tetrahedra that share corners with two equivalent Ag(1)Te3I tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent In(2)Te4 tetrahedra. The Ag(1)-Te(2) bond length is 2.79 Å. Both Ag(1)-Te(3) bond lengths are 2.80 Å. The Ag(1)-I(1) bond length is 2.91 Å. There are two inequivalent In sites. In the first In site, In(1) is bonded to one Te(3), two equivalent Te(1), and one I(1) atom to form InTe3I tetrahedra that share corners with two equivalent In(1)Te3I tetrahedra, corners with three equivalent Ag(1)Te3I tetrahedra, and corners with three equivalent In(2)Te4 tetrahedra. The In(1)-Te(3) bond length is 2.82 Å. Both In(1)-Te(1) bond lengths are 2.88 Å. The In(1)-I(1) bond length is 2.79 Å. In the second In site, In(2) is bonded to one Te(1), one Te(3), and two equivalent Te(2) atoms to form InTe4 tetrahedra that share corners with two equivalent In(2)Te4 tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent Ag(1)Te3I tetrahedra. The In(2)-Te(1) bond length is 2.90 Å. The In(2)-Te(3) bond length is 2.86 Å. Both In(2)-Te(2) bond lengths are 2.83 Å. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a trigonal non-coplanar geometry to one In(2) and two equivalent In(1) atoms. In the second Te site, Te(2) is bonded in a trigonal non-coplanar geometry to one Ag(1) and two equivalent In(2) atoms. In the third Te site, Te(3) is bonded to two equivalent Ag(1), one In(1), and one In(2) atom to form corner-sharing TeIn2Ag2 tetrahedra. I(1) is bonded in a water-like geometry to one Ag(1) and one In(1) atom.