DyPd3B is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Dy(1) is bonded to twelve equivalent Pd(1) atoms to form DyPd12 cuboctahedra that share corners with twelve equivalent Dy(1)Pd12 cuboctahedra, faces with six equivalent Dy(1)Pd12 cuboctahedra, and faces with eight equivalent B(1)Pd6 octahedra. Pd(1) is bonded to four equivalent Dy(1) and two equivalent B(1) atoms to form a mixture of distorted edge, face, and corner-sharing PdDy4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. B(1) is bonded to six equivalent Pd(1) atoms to form BPd6 octahedra that share corners with six equivalent B(1)Pd6 octahedra and faces with eight equivalent Dy(1)Pd12 cuboctahedra. The corner-sharing octahedra are not tilted.
DyPd3B is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Dy(1) is bonded to twelve equivalent Pd(1) atoms to form DyPd12 cuboctahedra that share corners with twelve equivalent Dy(1)Pd12 cuboctahedra, faces with six equivalent Dy(1)Pd12 cuboctahedra, and faces with eight equivalent B(1)Pd6 octahedra. All Dy(1)-Pd(1) bond lengths are 3.05 Å. Pd(1) is bonded to four equivalent Dy(1) and two equivalent B(1) atoms to form a mixture of distorted edge, face, and corner-sharing PdDy4B2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. Both Pd(1)-B(1) bond lengths are 2.16 Å. B(1) is bonded to six equivalent Pd(1) atoms to form BPd6 octahedra that share corners with six equivalent B(1)Pd6 octahedra and faces with eight equivalent Dy(1)Pd12 cuboctahedra. The corner-sharing octahedra are not tilted.