FeCl4ClN3 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four ClN3 clusters. In each ClN3 cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Cl(3) atom. In the second N site, N(1) is bonded in a single-bond geometry to one Cl(3) atom. Cl(3) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(2) atoms.
FeCl4ClN3 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four ClN3 clusters. In each ClN3 cluster, there are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Cl(3) atom. The N(2)-Cl(3) bond length is 1.50 Å. In the second N site, N(1) is bonded in a single-bond geometry to one Cl(3) atom. The N(1)-Cl(3) bond length is 1.45 Å. Cl(3) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(2) atoms.