VCuN2 crystallizes in the orthorhombic Cmcm space group. V(1) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms. Cu(1) is bonded in a distorted linear geometry to six equivalent N(1) atoms. N(1) is bonded in a 5-coordinate geometry to one V(1), three equivalent Cu(1), and one N(1) atom.
VCuN2 crystallizes in the orthorhombic Cmcm space group. V(1) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms. Both V(1)-N(1) bond lengths are 1.82 Å. Cu(1) is bonded in a distorted linear geometry to six equivalent N(1) atoms. There are two shorter (1.98 Å) and four longer (2.41 Å) Cu(1)-N(1) bond lengths. N(1) is bonded in a 5-coordinate geometry to one V(1), three equivalent Cu(1), and one N(1) atom. The N(1)-N(1) bond length is 1.29 Å.