KSrLaWO6 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pnnn space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(3) atoms. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. In the second Sr site, Sr(2) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form SrO12 cuboctahedra that share faces with four equivalent La(1)O6 octahedra and faces with four equivalent W(1)O6 octahedra. La(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LaO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 18-24°. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent La(1)O6 octahedra and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 18-24°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one K(1), one Sr(1), one Sr(2), one La(1), and one W(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Sr(2), one La(1), and one W(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(2), one Sr(1), one Sr(2), one La(1), and one W(1) atom.
KSrLaWO6 is Orthorhombic Perovskite-derived structured and crystallizes in the orthorhombic Pnnn space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All K(1)-O(1) bond lengths are 3.15 Å. All K(1)-O(2) bond lengths are 2.71 Å. In the second K site, K(2) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(3) atoms. All K(2)-O(2) bond lengths are 3.13 Å. All K(2)-O(3) bond lengths are 2.69 Å. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. All Sr(1)-O(1) bond lengths are 2.60 Å. All Sr(1)-O(3) bond lengths are 3.09 Å. In the second Sr site, Sr(2) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form SrO12 cuboctahedra that share faces with four equivalent La(1)O6 octahedra and faces with four equivalent W(1)O6 octahedra. All Sr(2)-O(1) bond lengths are 2.97 Å. All Sr(2)-O(2) bond lengths are 2.97 Å. All Sr(2)-O(3) bond lengths are 3.01 Å. La(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form LaO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 18-24°. Both La(1)-O(1) bond lengths are 2.39 Å. Both La(1)-O(2) bond lengths are 2.38 Å. Both La(1)-O(3) bond lengths are 2.38 Å. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent La(1)O6 octahedra and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 18-24°. Both W(1)-O(1) bond lengths are 1.98 Å. Both W(1)-O(2) bond lengths are 1.95 Å. Both W(1)-O(3) bond lengths are 1.95 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one K(1), one Sr(1), one Sr(2), one La(1), and one W(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one K(1), one K(2), one Sr(2), one La(1), and one W(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(2), one Sr(1), one Sr(2), one La(1), and one W(1) atom.