BeF4 is Silicon tetrafluoride-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BeF4 clusters. Be(1) is bonded in a tetrahedral geometry to one F(2), one F(3), and two equivalent F(1) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Be(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Be(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Be(1) atom.
BeF4 is Silicon tetrafluoride-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four BeF4 clusters. Be(1) is bonded in a tetrahedral geometry to one F(2), one F(3), and two equivalent F(1) atoms. The Be(1)-F(2) bond length is 1.53 Å. The Be(1)-F(3) bond length is 1.53 Å. Both Be(1)-F(1) bond lengths are 1.54 Å. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Be(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Be(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Be(1) atom.