Ce2Cu2In crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent Cu(1) and four equivalent In(1) atoms. Cu(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Cu(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Ce(1) and four equivalent Cu(1) atoms to form a mixture of corner and face-sharing InCe8Cu4 cuboctahedra.
Ce2Cu2In crystallizes in the tetragonal P4/mbm space group. Ce(1) is bonded in a 10-coordinate geometry to six equivalent Cu(1) and four equivalent In(1) atoms. There are two shorter (2.91 Å) and four longer (3.00 Å) Ce(1)-Cu(1) bond lengths. All Ce(1)-In(1) bond lengths are 3.40 Å. Cu(1) is bonded in a 9-coordinate geometry to six equivalent Ce(1), one Cu(1), and two equivalent In(1) atoms. The Cu(1)-Cu(1) bond length is 2.55 Å. Both Cu(1)-In(1) bond lengths are 3.06 Å. In(1) is bonded to eight equivalent Ce(1) and four equivalent Cu(1) atoms to form a mixture of corner and face-sharing InCe8Cu4 cuboctahedra.