ZrSiAs crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent Si(1) and five equivalent As(1) atoms. Si(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1), two equivalent Si(1), and two equivalent As(1) atoms. As(1) is bonded in a 7-coordinate geometry to five equivalent Zr(1) and two equivalent Si(1) atoms.
ZrSiAs crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent Si(1) and five equivalent As(1) atoms. There are a spread of Zr(1)-Si(1) bond distances ranging from 2.79-2.87 Å. There are a spread of Zr(1)-As(1) bond distances ranging from 2.78-2.92 Å. Si(1) is bonded in a 8-coordinate geometry to four equivalent Zr(1), two equivalent Si(1), and two equivalent As(1) atoms. Both Si(1)-Si(1) bond lengths are 2.47 Å. Both Si(1)-As(1) bond lengths are 2.68 Å. As(1) is bonded in a 7-coordinate geometry to five equivalent Zr(1) and two equivalent Si(1) atoms.