Na3CuCAsO7 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. Cu(1) is bonded to one O(2), one O(5), one O(6), and two equivalent O(4) atoms to form distorted CuO5 square pyramids that share corners with four equivalent As(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. As(1) is bonded to one O(5), one O(6), and two equivalent O(4) atoms to form AsO4 tetrahedra that share corners with four equivalent Cu(1)O5 square pyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Na(1), two equivalent Na(2), and one C(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(2), one Cu(1), and one C(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Na(1), two equivalent Na(2), and one C(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(2), one Cu(1), and one As(1) atom. In the fifth O site, O(5) is bonded in a distorted tetrahedral geometry to two equivalent Na(2), one Cu(1), and one As(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(2), one Cu(1), and one As(1) atom.
Na3CuCAsO7 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. The Na(1)-O(2) bond length is 2.48 Å. The Na(1)-O(3) bond length is 2.41 Å. There is one shorter (2.60 Å) and one longer (2.71 Å) Na(1)-O(1) bond length. Both Na(1)-O(4) bond lengths are 2.50 Å. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. The Na(2)-O(1) bond length is 2.32 Å. The Na(2)-O(2) bond length is 2.72 Å. The Na(2)-O(3) bond length is 2.45 Å. The Na(2)-O(5) bond length is 2.52 Å. The Na(2)-O(6) bond length is 2.26 Å. There is one shorter (2.54 Å) and one longer (2.89 Å) Na(2)-O(4) bond length. Cu(1) is bonded to one O(2), one O(5), one O(6), and two equivalent O(4) atoms to form distorted CuO5 square pyramids that share corners with four equivalent As(1)O4 tetrahedra. The Cu(1)-O(2) bond length is 2.08 Å. The Cu(1)-O(5) bond length is 1.99 Å. The Cu(1)-O(6) bond length is 2.22 Å. Both Cu(1)-O(4) bond lengths are 2.06 Å. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.32 Å. The C(1)-O(3) bond length is 1.29 Å. As(1) is bonded to one O(5), one O(6), and two equivalent O(4) atoms to form AsO4 tetrahedra that share corners with four equivalent Cu(1)O5 square pyramids. The As(1)-O(5) bond length is 1.75 Å. The As(1)-O(6) bond length is 1.69 Å. Both As(1)-O(4) bond lengths are 1.74 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Na(1), two equivalent Na(2), and one C(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(2), one Cu(1), and one C(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Na(1), two equivalent Na(2), and one C(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(1), two equivalent Na(2), one Cu(1), and one As(1) atom. In the fifth O site, O(5) is bonded in a distorted tetrahedral geometry to two equivalent Na(2), one Cu(1), and one As(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(2), one Cu(1), and one As(1) atom.