RhBi crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to two equivalent Rh(1) and six equivalent Bi(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhBi6Rh2 octahedra. The corner-sharing octahedral tilt angles range from 0-51°. Bi(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms.
RhBi crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to two equivalent Rh(1) and six equivalent Bi(1) atoms to form a mixture of distorted edge, corner, and face-sharing RhBi6Rh2 octahedra. The corner-sharing octahedral tilt angles range from 0-51°. Both Rh(1)-Rh(1) bond lengths are 2.84 Å. All Rh(1)-Bi(1) bond lengths are 2.78 Å. Bi(1) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms.