Na2LiAu3 crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a 9-coordinate geometry to nine equivalent Au(1) atoms. Li(1) is bonded in a distorted hexagonal planar geometry to six equivalent Au(1) atoms. Au(1) is bonded in a 2-coordinate geometry to six equivalent Na(1) and two equivalent Li(1) atoms.
Na2LiAu3 crystallizes in the hexagonal P6_3/mmc space group. Na(1) is bonded in a 9-coordinate geometry to nine equivalent Au(1) atoms. All Na(1)-Au(1) bond lengths are 3.18 Å. Li(1) is bonded in a distorted hexagonal planar geometry to six equivalent Au(1) atoms. All Li(1)-Au(1) bond lengths are 2.70 Å. Au(1) is bonded in a 2-coordinate geometry to six equivalent Na(1) and two equivalent Li(1) atoms.