Ca3AsN is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure consists of one ammonia atom inside a Ca3As framework. In the Ca3As framework, Ca(1) is bonded in a linear geometry to two equivalent As(1) atoms. As(1) is bonded to six equivalent Ca(1) atoms to form corner-sharing AsCa6 octahedra. The corner-sharing octahedra are not tilted.
Ca3AsN is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure consists of one ammonia atom inside a Ca3As framework. In the Ca3As framework, Ca(1) is bonded in a linear geometry to two equivalent As(1) atoms. Both Ca(1)-As(1) bond lengths are 2.71 Å. As(1) is bonded to six equivalent Ca(1) atoms to form corner-sharing AsCa6 octahedra. The corner-sharing octahedra are not tilted.