AgSbS2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Ag(1) is bonded to six S(1,1,1) atoms to form AgS6 octahedra that share corners with two equivalent Sb(1)S6 octahedra, corners with four equivalent Ag(1)S6 octahedra, edges with four equivalent Ag(1)S6 octahedra, and edges with eight equivalent Sb(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. Sb(1) is bonded to six S(1,1) atoms to form SbS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with four equivalent Sb(1)S6 octahedra, edges with four equivalent Sb(1)S6 octahedra, and edges with eight equivalent Ag(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are four inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fourth S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°.
AgSbS2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Ag(1) is bonded to six S(1,1,1) atoms to form AgS6 octahedra that share corners with two equivalent Sb(1)S6 octahedra, corners with four equivalent Ag(1)S6 octahedra, edges with four equivalent Ag(1)S6 octahedra, and edges with eight equivalent Sb(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are four shorter (2.75 Å) and two longer (2.95 Å) Ag(1)-S(1,1,1) bond lengths. Sb(1) is bonded to six S(1,1) atoms to form SbS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with four equivalent Sb(1)S6 octahedra, edges with four equivalent Sb(1)S6 octahedra, and edges with eight equivalent Ag(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are four shorter (2.75 Å) and two longer (2.77 Å) Sb(1)-S(1,1) bond lengths. There are four inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are two shorter (2.75 Å) and one longer (2.77 Å) S(1)-Sb(1) bond length. In the fourth S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are two shorter (2.75 Å) and one longer (2.95 Å) S(1)-Ag(1) bond length. There are two shorter (2.75 Å) and one longer (2.77 Å) S(1)-Sb(1) bond length.