VS2 crystallizes in the tetragonal I-42d space group. V(1) is bonded to four equivalent S(1) atoms to form corner-sharing VS4 tetrahedra. S(1) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms.
VS2 crystallizes in the tetragonal I-42d space group. V(1) is bonded to four equivalent S(1) atoms to form corner-sharing VS4 tetrahedra. All V(1)-S(1) bond lengths are 2.22 Å. S(1) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms.