NaMgVO3 crystallizes in the trigonal R3m space group. Na(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. Mg(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. V(1) is bonded to six equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 8°. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Mg(1), and two equivalent V(1) atoms.
NaMgVO3 crystallizes in the trigonal R3m space group. Na(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.26 Å. Mg(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. All Mg(1)-O(1) bond lengths are 1.94 Å. V(1) is bonded to six equivalent O(1) atoms to form corner-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 8°. There are three shorter (2.01 Å) and three longer (2.20 Å) V(1)-O(1) bond lengths. O(1) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Mg(1), and two equivalent V(1) atoms.