Li2PrGe crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to four equivalent Pr(1) and three equivalent Ge(1) atoms. Pr(1) is bonded in a 14-coordinate geometry to eight equivalent Li(1) and six equivalent Ge(1) atoms. Ge(1) is bonded in a distorted hexagonal planar geometry to six equivalent Li(1) and six equivalent Pr(1) atoms.
Li2PrGe crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to four equivalent Pr(1) and three equivalent Ge(1) atoms. There is one shorter (3.03 Å) and three longer (3.10 Å) Li(1)-Pr(1) bond lengths. All Li(1)-Ge(1) bond lengths are 2.61 Å. Pr(1) is bonded in a 14-coordinate geometry to eight equivalent Li(1) and six equivalent Ge(1) atoms. All Pr(1)-Ge(1) bond lengths are 3.50 Å. Ge(1) is bonded in a distorted hexagonal planar geometry to six equivalent Li(1) and six equivalent Pr(1) atoms.