PuS3 crystallizes in the tetragonal I4/mmm space group. Pu(1) is bonded to four equivalent S(2) and eight equivalent S(1) atoms to form a mixture of face, corner, and edge-sharing PuS12 cuboctahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 8-coordinate geometry to four equivalent Pu(1) and four equivalent S(1) atoms. In the second S site, S(2) is bonded in a square co-planar geometry to four equivalent Pu(1) atoms.
PuS3 crystallizes in the tetragonal I4/mmm space group. Pu(1) is bonded to four equivalent S(2) and eight equivalent S(1) atoms to form a mixture of face, corner, and edge-sharing PuS12 cuboctahedra. All Pu(1)-S(2) bond lengths are 2.74 Å. All Pu(1)-S(1) bond lengths are 3.08 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 8-coordinate geometry to four equivalent Pu(1) and four equivalent S(1) atoms. All S(1)-S(1) bond lengths are 2.74 Å. In the second S site, S(2) is bonded in a square co-planar geometry to four equivalent Pu(1) atoms.