Sc(MnN)3 crystallizes in the monoclinic P2_1/m space group. Sc(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(2), one N(3), and two equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing MnN4 trigonal pyramids. In the second Mn site, Mn(2) is bonded in a distorted square co-planar geometry to one N(1), one N(3), and two equivalent N(2) atoms. In the third Mn site, Mn(3) is bonded to one N(1), one N(2), and two equivalent N(3) atoms to form a mixture of distorted corner and edge-sharing MnN4 trigonal pyramids. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Sc(1), one Mn(2), one Mn(3), and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing NScMn4 square pyramids. In the second N site, N(2) is bonded to one Sc(1), one Mn(1), one Mn(3), and two equivalent Mn(2) atoms to form a mixture of distorted corner and edge-sharing NScMn4 square pyramids. In the third N site, N(3) is bonded to one Sc(1), one Mn(1), one Mn(2), and two equivalent Mn(3) atoms to form a mixture of distorted corner and edge-sharing NScMn4 square pyramids.
Sc(MnN)3 crystallizes in the monoclinic P2_1/m space group. Sc(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The Sc(1)-N(1) bond length is 2.08 Å. The Sc(1)-N(2) bond length is 2.08 Å. The Sc(1)-N(3) bond length is 2.08 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(2), one N(3), and two equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing MnN4 trigonal pyramids. The Mn(1)-N(2) bond length is 1.98 Å. The Mn(1)-N(3) bond length is 1.99 Å. Both Mn(1)-N(1) bond lengths are 1.95 Å. In the second Mn site, Mn(2) is bonded in a distorted square co-planar geometry to one N(1), one N(3), and two equivalent N(2) atoms. The Mn(2)-N(1) bond length is 1.99 Å. The Mn(2)-N(3) bond length is 1.99 Å. Both Mn(2)-N(2) bond lengths are 1.95 Å. In the third Mn site, Mn(3) is bonded to one N(1), one N(2), and two equivalent N(3) atoms to form a mixture of distorted corner and edge-sharing MnN4 trigonal pyramids. The Mn(3)-N(1) bond length is 1.99 Å. The Mn(3)-N(2) bond length is 1.98 Å. Both Mn(3)-N(3) bond lengths are 1.95 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Sc(1), one Mn(2), one Mn(3), and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing NScMn4 square pyramids. In the second N site, N(2) is bonded to one Sc(1), one Mn(1), one Mn(3), and two equivalent Mn(2) atoms to form a mixture of distorted corner and edge-sharing NScMn4 square pyramids. In the third N site, N(3) is bonded to one Sc(1), one Mn(1), one Mn(2), and two equivalent Mn(3) atoms to form a mixture of distorted corner and edge-sharing NScMn4 square pyramids.