NO2AsF6 is Tetraauricupride structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom.
NO2AsF6 is Tetraauricupride structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. Both As(1)-F(1) bond lengths are 1.78 Å. All As(1)-F(2) bond lengths are 1.76 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom.