(CH3)2SO4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four dihydroxy(dimethoxy)-lambda4-sulfane molecules. C(1) is bonded to one H(1), one H(2), one H(3), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form SO4 tetrahedra that share corners with two equivalent C(1)H3O tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom.
(CH3)2SO4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four dihydroxy(dimethoxy)-lambda4-sulfane molecules. C(1) is bonded to one H(1), one H(2), one H(3), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra. The C(1)-H(1) bond length is 1.09 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-O(2) bond length is 1.46 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form SO4 tetrahedra that share corners with two equivalent C(1)H3O tetrahedra. Both S(1)-O(1) bond lengths are 1.44 Å. Both S(1)-O(2) bond lengths are 1.59 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom.