PrPtF7 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 8-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), and two equivalent F(7) atoms. Pt(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a bent 150 degrees geometry to two equivalent Pr(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the third F site, F(2) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the fourth F site, F(3) is bonded in a linear geometry to one Pr(1) and one Pt(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the sixth F site, F(5) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the seventh F site, F(6) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom.
PrPtF7 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 8-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), one F(6), and two equivalent F(7) atoms. The Pr(1)-F(1) bond length is 2.46 Å. The Pr(1)-F(2) bond length is 2.39 Å. The Pr(1)-F(3) bond length is 2.40 Å. The Pr(1)-F(4) bond length is 2.44 Å. The Pr(1)-F(5) bond length is 2.42 Å. The Pr(1)-F(6) bond length is 2.38 Å. There is one shorter (2.29 Å) and one longer (2.30 Å) Pr(1)-F(7) bond length. Pt(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Pt(1)-F(1) bond length is 1.95 Å. The Pt(1)-F(2) bond length is 1.95 Å. The Pt(1)-F(3) bond length is 1.94 Å. The Pt(1)-F(4) bond length is 1.95 Å. The Pt(1)-F(5) bond length is 1.94 Å. The Pt(1)-F(6) bond length is 1.94 Å. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a bent 150 degrees geometry to two equivalent Pr(1) atoms. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the third F site, F(2) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the fourth F site, F(3) is bonded in a linear geometry to one Pr(1) and one Pt(1) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the sixth F site, F(5) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom. In the seventh F site, F(6) is bonded in a bent 150 degrees geometry to one Pr(1) and one Pt(1) atom.