CsNaTiO3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Na(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. Ti(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Na(1), and one Ti(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Ti(1) atoms.
CsNaTiO3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two shorter (2.93 Å) and two longer (3.05 Å) Cs(1)-O(1) bond lengths. Na(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. The Na(1)-O(1) bond length is 2.53 Å. All Na(1)-O(2) bond lengths are 2.41 Å. Ti(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. The Ti(1)-O(1) bond length is 1.77 Å. All Ti(1)-O(2) bond lengths are 1.99 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Na(1), and one Ti(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Ti(1) atoms.