SrWO2N is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. Sr(1) is bonded to four equivalent N(1) and eight equivalent O(1) atoms to form SrN4O8 cuboctahedra that share corners with twelve equivalent Sr(1)N4O8 cuboctahedra, faces with six equivalent Sr(1)N4O8 cuboctahedra, and faces with eight equivalent W(1)N2O4 octahedra. W(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form WN2O4 octahedra that share corners with six equivalent W(1)N2O4 octahedra and faces with eight equivalent Sr(1)N4O8 cuboctahedra. The corner-sharing octahedra are not tilted. N(1) is bonded to four equivalent Sr(1) and two equivalent W(1) atoms to form distorted NSr4W2 octahedra that share corners with six equivalent N(1)Sr4W2 octahedra, corners with sixteen equivalent O(1)Sr4W2 octahedra, edges with four equivalent N(1)Sr4W2 octahedra, and faces with eight equivalent O(1)Sr4W2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. O(1) is bonded to four equivalent Sr(1) and two equivalent W(1) atoms to form OSr4W2 octahedra that share corners with eight equivalent N(1)Sr4W2 octahedra, corners with fourteen equivalent O(1)Sr4W2 octahedra, edges with four equivalent O(1)Sr4W2 octahedra, faces with four equivalent N(1)Sr4W2 octahedra, and faces with four equivalent O(1)Sr4W2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°.
SrWO2N is (Cubic) Perovskite-derived structured and crystallizes in the tetragonal P4/mmm space group. Sr(1) is bonded to four equivalent N(1) and eight equivalent O(1) atoms to form SrN4O8 cuboctahedra that share corners with twelve equivalent Sr(1)N4O8 cuboctahedra, faces with six equivalent Sr(1)N4O8 cuboctahedra, and faces with eight equivalent W(1)N2O4 octahedra. All Sr(1)-N(1) bond lengths are 2.91 Å. All Sr(1)-O(1) bond lengths are 2.87 Å. W(1) is bonded to two equivalent N(1) and four equivalent O(1) atoms to form WN2O4 octahedra that share corners with six equivalent W(1)N2O4 octahedra and faces with eight equivalent Sr(1)N4O8 cuboctahedra. The corner-sharing octahedra are not tilted. Both W(1)-N(1) bond lengths are 2.00 Å. All W(1)-O(1) bond lengths are 2.06 Å. N(1) is bonded to four equivalent Sr(1) and two equivalent W(1) atoms to form distorted NSr4W2 octahedra that share corners with six equivalent N(1)Sr4W2 octahedra, corners with sixteen equivalent O(1)Sr4W2 octahedra, edges with four equivalent N(1)Sr4W2 octahedra, and faces with eight equivalent O(1)Sr4W2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. O(1) is bonded to four equivalent Sr(1) and two equivalent W(1) atoms to form OSr4W2 octahedra that share corners with eight equivalent N(1)Sr4W2 octahedra, corners with fourteen equivalent O(1)Sr4W2 octahedra, edges with four equivalent O(1)Sr4W2 octahedra, faces with four equivalent N(1)Sr4W2 octahedra, and faces with four equivalent O(1)Sr4W2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°.