Rb(CrS2)2 crystallizes in the tetragonal I4_1/amd space group. Rb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Cr(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing CrS6 octahedra. S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and three equivalent Cr(1) atoms.
Rb(CrS2)2 crystallizes in the tetragonal I4_1/amd space group. Rb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. There are four shorter (2.93 Å) and four longer (3.54 Å) Rb(1)-S(1) bond lengths. Cr(1) is bonded to six equivalent S(1) atoms to form distorted edge-sharing CrS6 octahedra. There are two shorter (2.40 Å) and four longer (2.50 Å) Cr(1)-S(1) bond lengths. S(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and three equivalent Cr(1) atoms.