Cd(CoO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Cd(1)O4 tetrahedra and edges with six equivalent Co(1)O6 octahedra. Cd(1) is bonded to four equivalent O(1) atoms to form CdO4 tetrahedra that share corners with twelve equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. O(1) is bonded to three equivalent Co(1) and one Cd(1) atom to form a mixture of edge and corner-sharing OCdCo3 tetrahedra.
Cd(CoO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Cd(1)O4 tetrahedra and edges with six equivalent Co(1)O6 octahedra. All Co(1)-O(1) bond lengths are 1.93 Å. Cd(1) is bonded to four equivalent O(1) atoms to form CdO4 tetrahedra that share corners with twelve equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 62°. All Cd(1)-O(1) bond lengths are 2.12 Å. O(1) is bonded to three equivalent Co(1) and one Cd(1) atom to form a mixture of edge and corner-sharing OCdCo3 tetrahedra.