LiPd2As is Heusler structured and crystallizes in the cubic Fm-3m space group. Li(1) is bonded in a body-centered cubic geometry to eight equivalent Pd(1) and six equivalent As(1) atoms. Pd(1) is bonded to four equivalent Li(1) and four equivalent As(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdLi4As4 tetrahedra. As(1) is bonded in a 14-coordinate geometry to six equivalent Li(1) and eight equivalent Pd(1) atoms.
LiPd2As is Heusler structured and crystallizes in the cubic Fm-3m space group. Li(1) is bonded in a body-centered cubic geometry to eight equivalent Pd(1) and six equivalent As(1) atoms. All Li(1)-Pd(1) bond lengths are 2.64 Å. All Li(1)-As(1) bond lengths are 3.05 Å. Pd(1) is bonded to four equivalent Li(1) and four equivalent As(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdLi4As4 tetrahedra. All Pd(1)-As(1) bond lengths are 2.64 Å. As(1) is bonded in a 14-coordinate geometry to six equivalent Li(1) and eight equivalent Pd(1) atoms.