LiV4OF11 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(10), one F(11), one F(4), and one F(9) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one F(11), one F(2), one F(3), one F(4), one F(6), and one F(8) atom. In the second V site, V(2) is bonded in a 4-coordinate geometry to one F(1), one F(11), one F(4), one F(5), and one F(8) atom. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(10), one F(5), one F(7), and one F(9) atom. In the fourth V site, V(4) is bonded in a 4-coordinate geometry to one O(1), one F(10), one F(2), one F(3), one F(6), and one F(7) atom. O(1) is bonded in a bent 120 degrees geometry to one V(3) and one V(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one V(1) and one V(4) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(1), and one V(2) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 120 degrees geometry to one V(1) and one V(2) atom. In the ninth F site, F(9) is bonded in a distorted single-bond geometry to one Li(1) and one V(3) atom. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Li(1), one V(3), and one V(4) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one V(2) atom.
LiV4OF11 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one F(1), one F(10), one F(11), one F(4), and one F(9) atom. The Li(1)-F(1) bond length is 2.32 Å. The Li(1)-F(10) bond length is 2.16 Å. The Li(1)-F(11) bond length is 2.32 Å. The Li(1)-F(4) bond length is 2.48 Å. The Li(1)-F(9) bond length is 1.99 Å. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one F(11), one F(2), one F(3), one F(4), one F(6), and one F(8) atom. The V(1)-F(11) bond length is 2.29 Å. The V(1)-F(2) bond length is 1.65 Å. The V(1)-F(3) bond length is 2.36 Å. The V(1)-F(4) bond length is 2.52 Å. The V(1)-F(6) bond length is 2.11 Å. The V(1)-F(8) bond length is 1.65 Å. In the second V site, V(2) is bonded in a 4-coordinate geometry to one F(1), one F(11), one F(4), one F(5), and one F(8) atom. The V(2)-F(1) bond length is 2.01 Å. The V(2)-F(11) bond length is 2.05 Å. The V(2)-F(4) bond length is 2.55 Å. The V(2)-F(5) bond length is 1.60 Å. The V(2)-F(8) bond length is 1.61 Å. In the third V site, V(3) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(10), one F(5), one F(7), and one F(9) atom. The V(3)-O(1) bond length is 1.60 Å. The V(3)-F(1) bond length is 2.21 Å. The V(3)-F(10) bond length is 2.43 Å. The V(3)-F(5) bond length is 1.72 Å. The V(3)-F(7) bond length is 2.17 Å. The V(3)-F(9) bond length is 2.58 Å. In the fourth V site, V(4) is bonded in a 4-coordinate geometry to one O(1), one F(10), one F(2), one F(3), one F(6), and one F(7) atom. The V(4)-O(1) bond length is 1.58 Å. The V(4)-F(10) bond length is 2.58 Å. The V(4)-F(2) bond length is 1.70 Å. The V(4)-F(3) bond length is 2.68 Å. The V(4)-F(6) bond length is 2.03 Å. The V(4)-F(7) bond length is 2.03 Å. O(1) is bonded in a bent 120 degrees geometry to one V(3) and one V(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one V(3) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one V(1) and one V(4) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(1), and one V(2) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 120 degrees geometry to one V(1) and one V(2) atom. In the ninth F site, F(9) is bonded in a distorted single-bond geometry to one Li(1) and one V(3) atom. In the tenth F site, F(10) is bonded in a distorted T-shaped geometry to one Li(1), one V(3), and one V(4) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one V(2) atom.