KSbClF3 crystallizes in the orthorhombic Pbca space group. K(1) is bonded in a 8-coordinate geometry to three equivalent Cl(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms. Sb(1) is bonded in a 3-coordinate geometry to two equivalent Cl(1), one F(1), one F(2), and one F(3) atom. Cl(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing ClK3Sb2 square pyramids. There are three inequivalent F sites. In the first F site, F(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Sb(1) atom. In the second F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Sb(1) atom. In the third F site, F(1) is bonded in a bent 120 degrees geometry to one K(1) and one Sb(1) atom.
KSbClF3 crystallizes in the orthorhombic Pbca space group. K(1) is bonded in a 8-coordinate geometry to three equivalent Cl(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are a spread of K(1)-Cl(1) bond distances ranging from 3.39-3.46 Å. The K(1)-F(1) bond length is 2.75 Å. There is one shorter (2.67 Å) and one longer (2.97 Å) K(1)-F(2) bond length. There is one shorter (2.70 Å) and one longer (2.78 Å) K(1)-F(3) bond length. Sb(1) is bonded in a 3-coordinate geometry to two equivalent Cl(1), one F(1), one F(2), and one F(3) atom. There is one shorter (3.04 Å) and one longer (3.07 Å) Sb(1)-Cl(1) bond length. The Sb(1)-F(1) bond length is 1.99 Å. The Sb(1)-F(2) bond length is 2.00 Å. The Sb(1)-F(3) bond length is 1.99 Å. Cl(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing ClK3Sb2 square pyramids. There are three inequivalent F sites. In the first F site, F(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Sb(1) atom. In the second F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Sb(1) atom. In the third F site, F(1) is bonded in a bent 120 degrees geometry to one K(1) and one Sb(1) atom.