PbCO3 crystallizes in the monoclinic P2_1/c space group. Pb(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Pb(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Pb(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Pb(1) and one C(1) atom.
PbCO3 crystallizes in the monoclinic P2_1/c space group. Pb(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. There are a spread of Pb(1)-O(1) bond distances ranging from 2.59-2.81 Å. There are a spread of Pb(1)-O(2) bond distances ranging from 2.60-2.83 Å. There are a spread of Pb(1)-O(3) bond distances ranging from 2.65-2.83 Å. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.30 Å. The C(1)-O(3) bond length is 1.30 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Pb(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Pb(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Pb(1) and one C(1) atom.