V2NiSb2 crystallizes in the hexagonal P-6m2 space group. V(1) is bonded in a 11-coordinate geometry to two equivalent V(1), three equivalent Ni(1), three equivalent Sb(1), and three equivalent Sb(2) atoms. Ni(1) is bonded in a 11-coordinate geometry to six equivalent V(1), two equivalent Sb(1), and three equivalent Sb(2) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to six equivalent V(1) and two equivalent Ni(1) atoms. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to six equivalent V(1) and three equivalent Ni(1) atoms.
V2NiSb2 crystallizes in the hexagonal P-6m2 space group. V(1) is bonded in a 11-coordinate geometry to two equivalent V(1), three equivalent Ni(1), three equivalent Sb(1), and three equivalent Sb(2) atoms. There is one shorter (2.61 Å) and one longer (2.86 Å) V(1)-V(1) bond length. All V(1)-Ni(1) bond lengths are 2.86 Å. All V(1)-Sb(1) bond lengths are 2.80 Å. All V(1)-Sb(2) bond lengths are 2.86 Å. Ni(1) is bonded in a 11-coordinate geometry to six equivalent V(1), two equivalent Sb(1), and three equivalent Sb(2) atoms. Both Ni(1)-Sb(1) bond lengths are 2.73 Å. All Ni(1)-Sb(2) bond lengths are 2.48 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to six equivalent V(1) and two equivalent Ni(1) atoms. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to six equivalent V(1) and three equivalent Ni(1) atoms.