CdMn2O4 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Mn(1) is bonded to six equivalent O(1) atoms to form distorted MnO6 octahedra that share corners with six equivalent Cd(1)O4 tetrahedra and edges with six equivalent Mn(1)O6 octahedra. Cd(1) is bonded to four equivalent O(1) atoms to form CdO4 tetrahedra that share corners with twelve equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. O(1) is bonded to three equivalent Mn(1) and one Cd(1) atom to form a mixture of distorted edge and corner-sharing OMn3Cd tetrahedra.
CdMn2O4 is Spinel structured and crystallizes in the tetragonal I4_1/amd space group. Mn(1) is bonded to six equivalent O(1) atoms to form distorted MnO6 octahedra that share corners with six equivalent Cd(1)O4 tetrahedra and edges with six equivalent Mn(1)O6 octahedra. There are four shorter (1.94 Å) and two longer (2.31 Å) Mn(1)-O(1) bond lengths. Cd(1) is bonded to four equivalent O(1) atoms to form CdO4 tetrahedra that share corners with twelve equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. All Cd(1)-O(1) bond lengths are 2.16 Å. O(1) is bonded to three equivalent Mn(1) and one Cd(1) atom to form a mixture of distorted edge and corner-sharing OMn3Cd tetrahedra.