Li(CuN)3 crystallizes in the cubic Pm-3m space group. Li(1) is bonded to six equivalent N(1) atoms to form corner-sharing LiN6 octahedra. The corner-sharing octahedra are not tilted. Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded to two equivalent Li(1) and four equivalent Cu(1) atoms to form a mixture of corner and edge-sharing NLi2Cu4 octahedra. The corner-sharing octahedra are not tilted.
Li(CuN)3 crystallizes in the cubic Pm-3m space group. Li(1) is bonded to six equivalent N(1) atoms to form corner-sharing LiN6 octahedra. The corner-sharing octahedra are not tilted. All Li(1)-N(1) bond lengths are 2.02 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.02 Å. N(1) is bonded to two equivalent Li(1) and four equivalent Cu(1) atoms to form a mixture of corner and edge-sharing NLi2Cu4 octahedra. The corner-sharing octahedra are not tilted.