B2H5BCH2O is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two boranylmethanol molecules and two B2H5 clusters. In each B2H5 cluster, there are two inequivalent B sites. In the first B site, B(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one H(5) atom. In the second B site, B(3) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one H(7) atom. There are five inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the third H site, H(5) is bonded in an L-shaped geometry to one B(2) and one B(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one B(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one B(3) atom.
B2H5BCH2O is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two boranylmethanol molecules and two B2H5 clusters. In each B2H5 cluster, there are two inequivalent B sites. In the first B site, B(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one H(5) atom. The B(2)-H(3) bond length is 1.21 Å. The B(2)-H(4) bond length is 1.20 Å. The B(2)-H(5) bond length is 1.33 Å. In the second B site, B(3) is bonded in a distorted trigonal non-coplanar geometry to one H(5), one H(6), and one H(7) atom. The B(3)-H(5) bond length is 1.32 Å. The B(3)-H(6) bond length is 1.20 Å. The B(3)-H(7) bond length is 1.20 Å. There are five inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one B(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one B(2) atom. In the third H site, H(5) is bonded in an L-shaped geometry to one B(2) and one B(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one B(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one B(3) atom.