K(IrAs)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent As(1) atoms. Ir(1) is bonded to four equivalent As(1) atoms to form a mixture of distorted edge and corner-sharing IrAs4 tetrahedra. As(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Ir(1) atoms.
K(IrAs)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent As(1) atoms. All K(1)-As(1) bond lengths are 3.46 Å. Ir(1) is bonded to four equivalent As(1) atoms to form a mixture of distorted edge and corner-sharing IrAs4 tetrahedra. All Ir(1)-As(1) bond lengths are 2.45 Å. As(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Ir(1) atoms.