IrC3Sb2O3F13 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two IrC3Sb2O3F13 clusters. Ir(1) is bonded to one C(1), one C(2), one C(3), one F(1), one F(2), and one F(8) atom to form IrC3F3 octahedra that share  a cornercorner with one Sb(1)F6 octahedra and  a cornercorner with one Sb(2)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Ir(1) and one O(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Ir(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Ir(1) and one O(3) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom to form SbF6 octahedra that share  a cornercorner with one Ir(1)C3F3 octahedra. The corner-sharing octahedral tilt angles are 39°. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(12), one F(13), one F(8), and one F(9) atom to form SbF6 octahedra that share  a cornercorner with one Ir(1)C3F3 octahedra. The corner-sharing octahedral tilt angles are 39°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Ir(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ir(1) and one Sb(2) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Sb(2) atom.
IrC3Sb2O3F13 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two IrC3Sb2O3F13 clusters. Ir(1) is bonded to one C(1), one C(2), one C(3), one F(1), one F(2), and one F(8) atom to form IrC3F3 octahedra that share  a cornercorner with one Sb(1)F6 octahedra and  a cornercorner with one Sb(2)F6 octahedra. The corner-sharing octahedral tilt angles are 39°. The Ir(1)-C(1) bond length is 1.88 Å. The Ir(1)-C(2) bond length is 2.00 Å. The Ir(1)-C(3) bond length is 1.99 Å. The Ir(1)-F(1) bond length is 1.95 Å. The Ir(1)-F(2) bond length is 2.09 Å. The Ir(1)-F(8) bond length is 2.10 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Ir(1) and one O(1) atom. The C(1)-O(1) bond length is 1.14 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Ir(1) and one O(2) atom. The C(2)-O(2) bond length is 1.14 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one Ir(1) and one O(3) atom. The C(3)-O(3) bond length is 1.13 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom to form SbF6 octahedra that share  a cornercorner with one Ir(1)C3F3 octahedra. The corner-sharing octahedral tilt angles are 39°. The Sb(1)-F(2) bond length is 2.09 Å. The Sb(1)-F(3) bond length is 1.91 Å. The Sb(1)-F(4) bond length is 1.90 Å. The Sb(1)-F(5) bond length is 1.91 Å. The Sb(1)-F(6) bond length is 1.91 Å. The Sb(1)-F(7) bond length is 1.89 Å. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(12), one F(13), one F(8), and one F(9) atom to form SbF6 octahedra that share  a cornercorner with one Ir(1)C3F3 octahedra. The corner-sharing octahedral tilt angles are 39°. The Sb(2)-F(10) bond length is 1.90 Å. The Sb(2)-F(11) bond length is 1.90 Å. The Sb(2)-F(12) bond length is 1.90 Å. The Sb(2)-F(13) bond length is 1.91 Å. The Sb(2)-F(8) bond length is 2.08 Å. The Sb(2)-F(9) bond length is 1.92 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. There are thirteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Ir(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ir(1) and one Sb(2) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Sb(2) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Sb(2) atom.