(SmN3H8O14)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two water atoms and one SmN3H8O14 cluster. In the SmN3H8O14 cluster, Sm(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(13), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(10) and one O(14) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(11) and one O(14) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(13) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sm(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sm(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sm(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sm(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Sm(1) and one N(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Sm(1) and one N(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Sm(1), one H(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Sm(1), one H(3), and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Sm(1), one H(5), and one H(6) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Sm(1), one H(7), and one H(8) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one H(1) and one H(3) atom.
(SmN3H8O14)2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two water atoms and one SmN3H8O14 cluster. In the SmN3H8O14 cluster, Sm(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(13), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. The Sm(1)-O(1) bond length is 2.65 Å. The Sm(1)-O(10) bond length is 2.50 Å. The Sm(1)-O(11) bond length is 2.43 Å. The Sm(1)-O(12) bond length is 2.40 Å. The Sm(1)-O(13) bond length is 2.47 Å. The Sm(1)-O(2) bond length is 2.59 Å. The Sm(1)-O(4) bond length is 2.59 Å. The Sm(1)-O(5) bond length is 2.65 Å. The Sm(1)-O(7) bond length is 2.55 Å. The Sm(1)-O(8) bond length is 2.51 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.26 Å. The N(1)-O(2) bond length is 1.29 Å. The N(1)-O(3) bond length is 1.25 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. The N(2)-O(4) bond length is 1.29 Å. The N(2)-O(5) bond length is 1.27 Å. The N(2)-O(6) bond length is 1.25 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. The N(3)-O(7) bond length is 1.29 Å. The N(3)-O(8) bond length is 1.29 Å. The N(3)-O(9) bond length is 1.23 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(10) and one O(14) atom. The H(1)-O(10) bond length is 1.03 Å. The H(1)-O(14) bond length is 1.52 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 0.98 Å. In the third H site, H(3) is bonded in a distorted linear geometry to one O(11) and one O(14) atom. The H(3)-O(11) bond length is 1.01 Å. The H(3)-O(14) bond length is 1.60 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(11) atom. The H(4)-O(11) bond length is 1.00 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(12) atom. The H(5)-O(12) bond length is 0.98 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(12) atom. The H(6)-O(12) bond length is 0.98 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(13) atom. The H(7)-O(13) bond length is 0.99 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(13) atom. The H(8)-O(13) bond length is 0.99 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sm(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sm(1) and one N(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sm(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sm(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Sm(1) and one N(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Sm(1) and one N(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Sm(1), one H(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Sm(1), one H(3), and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Sm(1), one H(5), and one H(6) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Sm(1), one H(7), and one H(8) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one H(1) and one H(3) atom.