(RbSO4)2N2 crystallizes in the orthorhombic Pnma space group. The structure consists of four ammonia atoms inside a RbSO4 framework. In the RbSO4 framework, Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), and six equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom.
(RbSO4)2N2 crystallizes in the orthorhombic Pnma space group. The structure consists of four ammonia atoms inside a RbSO4 framework. In the RbSO4 framework, Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), and six equivalent O(1) atoms. The Rb(1)-O(2) bond length is 2.85 Å. Both Rb(1)-O(3) bond lengths are 3.08 Å. There are a spread of Rb(1)-O(1) bond distances ranging from 3.18-3.34 Å. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.48 Å. Both S(1)-O(1) bond lengths are 1.50 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom.