ReN is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. Re(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted corner, face, and edge-sharing ReN6 octahedra. The corner-sharing octahedral tilt angles are 43°. N(1) is bonded to six equivalent Re(1) atoms to form a mixture of distorted corner and edge-sharing NRe6 pentagonal pyramids.
ReN is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. Re(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted corner, face, and edge-sharing ReN6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Re(1)-N(1) bond lengths are 2.19 Å. N(1) is bonded to six equivalent Re(1) atoms to form a mixture of distorted corner and edge-sharing NRe6 pentagonal pyramids.