Sr2CoWO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom.
Sr2CoWO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. There are a spread of Sr(1)-O(1) bond distances ranging from 2.57-3.16 Å. There are a spread of Sr(1)-O(2) bond distances ranging from 2.60-3.16 Å. There are a spread of Sr(1)-O(3) bond distances ranging from 2.60-3.15 Å. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. Both W(1)-O(1) bond lengths are 1.95 Å. Both W(1)-O(2) bond lengths are 1.95 Å. Both W(1)-O(3) bond lengths are 1.95 Å. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-18°. Both Co(1)-O(1) bond lengths are 2.09 Å. Both Co(1)-O(2) bond lengths are 2.12 Å. Both Co(1)-O(3) bond lengths are 2.11 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom.