Ba3Ir(CN)3 is Indium-like structured and crystallizes in the hexagonal P6_3/m space group. The structure is zero-dimensional and consists of two Ba3Ir(CN)3 clusters. Ba(1) is bonded in a 1-coordinate geometry to one N(1) atom. Ir(1) is bonded in a trigonal planar geometry to three equivalent C(1) atoms. C(1) is bonded in a 1-coordinate geometry to one Ir(1) and one N(1) atom. N(1) is bonded in a distorted single-bond geometry to one Ba(1) and one C(1) atom.
Ba3Ir(CN)3 is Indium-like structured and crystallizes in the hexagonal P6_3/m space group. The structure is zero-dimensional and consists of two Ba3Ir(CN)3 clusters. Ba(1) is bonded in a 1-coordinate geometry to one N(1) atom. The Ba(1)-N(1) bond length is 2.78 Å. Ir(1) is bonded in a trigonal planar geometry to three equivalent C(1) atoms. All Ir(1)-C(1) bond lengths are 1.91 Å. C(1) is bonded in a 1-coordinate geometry to one Ir(1) and one N(1) atom. The C(1)-N(1) bond length is 1.24 Å. N(1) is bonded in a distorted single-bond geometry to one Ba(1) and one C(1) atom.