ZnGeP2 is Chalcopyrite-like structured and crystallizes in the tetragonal P-4m2 space group. Zn(1) is bonded to four equivalent P(1) atoms to form ZnP4 tetrahedra that share corners with four equivalent Zn(1)P4 tetrahedra and corners with eight equivalent Ge(1)P4 tetrahedra. Ge(1) is bonded to four equivalent P(1) atoms to form GeP4 tetrahedra that share corners with four equivalent Ge(1)P4 tetrahedra and corners with eight equivalent Zn(1)P4 tetrahedra. P(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form corner-sharing PZn2Ge2 tetrahedra.
ZnGeP2 is Chalcopyrite-like structured and crystallizes in the tetragonal P-4m2 space group. Zn(1) is bonded to four equivalent P(1) atoms to form ZnP4 tetrahedra that share corners with four equivalent Zn(1)P4 tetrahedra and corners with eight equivalent Ge(1)P4 tetrahedra. All Zn(1)-P(1) bond lengths are 2.35 Å. Ge(1) is bonded to four equivalent P(1) atoms to form GeP4 tetrahedra that share corners with four equivalent Ge(1)P4 tetrahedra and corners with eight equivalent Zn(1)P4 tetrahedra. All Ge(1)-P(1) bond lengths are 2.38 Å. P(1) is bonded to two equivalent Zn(1) and two equivalent Ge(1) atoms to form corner-sharing PZn2Ge2 tetrahedra.