W2NCl9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two W2NCl9 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in an octahedral geometry to one N(1), one Cl(1), one Cl(2), one Cl(4), one Cl(5), and one Cl(6) atom. In the second W site, W(2) is bonded in a 6-coordinate geometry to one N(1), one Cl(3), one Cl(8), one Cl(9), and two equivalent Cl(7) atoms. N(1) is bonded in a linear geometry to one W(1) and one W(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one W(1) atom. In the seventh Cl site, Cl(7) is bonded in a water-like geometry to two equivalent W(2) atoms. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one W(2) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one W(2) atom.
W2NCl9 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two W2NCl9 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded in an octahedral geometry to one N(1), one Cl(1), one Cl(2), one Cl(4), one Cl(5), and one Cl(6) atom. The W(1)-N(1) bond length is 1.97 Å. The W(1)-Cl(1) bond length is 2.29 Å. The W(1)-Cl(2) bond length is 2.29 Å. The W(1)-Cl(4) bond length is 2.29 Å. The W(1)-Cl(5) bond length is 2.29 Å. The W(1)-Cl(6) bond length is 2.29 Å. In the second W site, W(2) is bonded in a 6-coordinate geometry to one N(1), one Cl(3), one Cl(8), one Cl(9), and two equivalent Cl(7) atoms. The W(2)-N(1) bond length is 1.74 Å. The W(2)-Cl(3) bond length is 2.27 Å. The W(2)-Cl(8) bond length is 2.29 Å. The W(2)-Cl(9) bond length is 2.29 Å. There is one shorter (2.40 Å) and one longer (2.84 Å) W(2)-Cl(7) bond length. N(1) is bonded in a linear geometry to one W(1) and one W(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one W(1) atom. In the seventh Cl site, Cl(7) is bonded in a water-like geometry to two equivalent W(2) atoms. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one W(2) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one W(2) atom.