SrMgLa9Ga9O29 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 1-coordinate geometry to one O(1), one O(3), one O(4), one O(9), and two equivalent O(7) atoms. Mg(1) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(4), one O(7), and one O(9) atom. There are nine inequivalent La sites. In the first La site, La(1) is bonded in a 1-coordinate geometry to one O(2), one O(28), one O(29), one O(9), and two equivalent O(1) atoms. In the second La site, La(2) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(3) atom. In the third La site, La(3) is bonded in a 1-coordinate geometry to one O(11), one O(15), one O(4), one O(7), and two equivalent O(3) atoms. In the fourth La site, La(4) is bonded in a 1-coordinate geometry to one O(14), one O(16), one O(19), one O(8), and two equivalent O(21) atoms. In the fifth La site, La(5) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(21) atom. In the sixth La site, La(6) is bonded in a 1-coordinate geometry to one O(14), one O(22), one O(25), and two equivalent O(26) atoms. In the seventh La site, La(7) is bonded in a 1-coordinate geometry to one O(16), one O(19), one O(21), one O(26), and two equivalent O(14) atoms. In the eighth La site, La(8) is bonded in a 1-coordinate geometry to one O(1), one O(20), one O(28), and two equivalent O(29) atoms. In the ninth La site, La(9) is bonded in a 1-coordinate geometry to one O(22), one O(25), one O(26), and one O(29) atom. There are nine inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), one O(7), and one O(9) atom. In the second Ga site, Ga(2) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(15), one O(3), one O(4), and one O(6) atom. In the third Ga site, Ga(3) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(17), one O(19), one O(21), and one O(8) atom. In the fourth Ga site, Ga(4) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(17), and one O(6) atom. In the fifth Ga site, Ga(5) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(23), one O(25), and one O(26) atom. In the sixth Ga site, Ga(6) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(16), one O(19), one O(21), and one O(23) atom. In the seventh Ga site, Ga(7) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(24), one O(27), one O(28), and one O(29) atom. In the eighth Ga site, Ga(8) is bonded in a 4-coordinate geometry to one O(18), one O(22), one O(25), one O(26), and one O(27) atom. In the ninth Ga site, Ga(9) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(24), one O(28), one O(29), and one O(5) atom. There are twenty-nine inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(1), one La(8), two equivalent La(1), one Ga(1), and one Ga(9) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Ga(1), and one Ga(9) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), one Mg(1), one La(2), two equivalent La(3), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(3), and one Ga(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ga(1) and one Ga(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(3), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one La(4) and one Ga(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(1), and one Ga(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(3), and one Ga(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mg(1), one La(3), and one Ga(2) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(6) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(2), and one Ga(4) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(4), one La(6), two equivalent La(7), one Ga(5), and one Ga(6) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one La(3) and one Ga(2) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(5), and one Ga(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(8) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(3), and one Ga(6) atom. In the twentieth O site, O(20) is bonded in a 1-coordinate geometry to one La(8) and one Ga(7) atom. In the twenty-first O site, O(21) is bonded in a 6-coordinate geometry to one La(5), one La(7), two equivalent La(4), one Ga(3), and one Ga(6) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(7), and one Ga(8) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(9) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(5), and one Ga(8) atom. In the twenty-sixth O site, O(26) is bonded in a 6-coordinate geometry to one La(7), one La(9), two equivalent La(6), one Ga(5), and one Ga(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(8) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one La(1), one La(8), one Ga(7), and one Ga(9) atom. In the twenty-ninth O site, O(29) is bonded in a 6-coordinate geometry to one La(1), one La(9), two equivalent La(8), one Ga(7), and one Ga(9) atom.
SrMgLa9Ga9O29 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 1-coordinate geometry to one O(1), one O(3), one O(4), one O(9), and two equivalent O(7) atoms. The Sr(1)-O(1) bond length is 2.19 Å. The Sr(1)-O(3) bond length is 2.70 Å. The Sr(1)-O(4) bond length is 2.60 Å. The Sr(1)-O(9) bond length is 2.65 Å. There is one shorter (2.65 Å) and one longer (2.96 Å) Sr(1)-O(7) bond length. Mg(1) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(4), one O(7), and one O(9) atom. The Mg(1)-O(11) bond length is 1.53 Å. The Mg(1)-O(3) bond length is 2.53 Å. The Mg(1)-O(4) bond length is 2.08 Å. The Mg(1)-O(7) bond length is 2.08 Å. The Mg(1)-O(9) bond length is 2.57 Å. There are nine inequivalent La sites. In the first La site, La(1) is bonded in a 1-coordinate geometry to one O(2), one O(28), one O(29), one O(9), and two equivalent O(1) atoms. The La(1)-O(2) bond length is 2.49 Å. The La(1)-O(28) bond length is 2.59 Å. The La(1)-O(29) bond length is 2.75 Å. The La(1)-O(9) bond length is 2.07 Å. There is one shorter (2.76 Å) and one longer (2.88 Å) La(1)-O(1) bond length. In the second La site, La(2) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(3) atom. The La(2)-O(10) bond length is 2.69 Å. The La(2)-O(13) bond length is 2.45 Å. The La(2)-O(3) bond length is 2.09 Å. In the third La site, La(3) is bonded in a 1-coordinate geometry to one O(11), one O(15), one O(4), one O(7), and two equivalent O(3) atoms. The La(3)-O(11) bond length is 2.38 Å. The La(3)-O(15) bond length is 1.99 Å. The La(3)-O(4) bond length is 2.38 Å. The La(3)-O(7) bond length is 2.78 Å. There is one shorter (2.76 Å) and one longer (2.83 Å) La(3)-O(3) bond length. In the fourth La site, La(4) is bonded in a 1-coordinate geometry to one O(14), one O(16), one O(19), one O(8), and two equivalent O(21) atoms. The La(4)-O(14) bond length is 2.81 Å. The La(4)-O(16) bond length is 2.65 Å. The La(4)-O(19) bond length is 2.42 Å. The La(4)-O(8) bond length is 2.06 Å. There is one shorter (2.71 Å) and one longer (2.91 Å) La(4)-O(21) bond length. In the fifth La site, La(5) is bonded in a 1-coordinate geometry to one O(10), one O(13), and one O(21) atom. The La(5)-O(10) bond length is 2.47 Å. The La(5)-O(13) bond length is 2.54 Å. The La(5)-O(21) bond length is 2.11 Å. In the sixth La site, La(6) is bonded in a 1-coordinate geometry to one O(14), one O(22), one O(25), and two equivalent O(26) atoms. The La(6)-O(14) bond length is 2.06 Å. The La(6)-O(22) bond length is 2.68 Å. The La(6)-O(25) bond length is 2.42 Å. There is one shorter (2.72 Å) and one longer (2.90 Å) La(6)-O(26) bond length. In the seventh La site, La(7) is bonded in a 1-coordinate geometry to one O(16), one O(19), one O(21), one O(26), and two equivalent O(14) atoms. The La(7)-O(16) bond length is 2.45 Å. The La(7)-O(19) bond length is 2.58 Å. The La(7)-O(21) bond length is 2.79 Å. The La(7)-O(26) bond length is 2.10 Å. There is one shorter (2.71 Å) and one longer (2.93 Å) La(7)-O(14) bond length. In the eighth La site, La(8) is bonded in a 1-coordinate geometry to one O(1), one O(20), one O(28), and two equivalent O(29) atoms. The La(8)-O(1) bond length is 2.80 Å. The La(8)-O(20) bond length is 2.04 Å. The La(8)-O(28) bond length is 2.38 Å. There is one shorter (2.80 Å) and one longer (2.81 Å) La(8)-O(29) bond length. In the ninth La site, La(9) is bonded in a 1-coordinate geometry to one O(22), one O(25), one O(26), and one O(29) atom. The La(9)-O(22) bond length is 2.46 Å. The La(9)-O(25) bond length is 2.60 Å. The La(9)-O(26) bond length is 2.79 Å. The La(9)-O(29) bond length is 2.10 Å. There are nine inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(5), one O(7), and one O(9) atom. The Ga(1)-O(1) bond length is 2.30 Å. The Ga(1)-O(2) bond length is 2.20 Å. The Ga(1)-O(5) bond length is 1.65 Å. The Ga(1)-O(7) bond length is 2.05 Å. The Ga(1)-O(9) bond length is 2.28 Å. In the second Ga site, Ga(2) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(15), one O(3), one O(4), and one O(6) atom. The Ga(2)-O(11) bond length is 1.63 Å. The Ga(2)-O(13) bond length is 2.25 Å. The Ga(2)-O(15) bond length is 2.41 Å. The Ga(2)-O(3) bond length is 2.33 Å. The Ga(2)-O(4) bond length is 2.11 Å. The Ga(2)-O(6) bond length is 1.72 Å. In the third Ga site, Ga(3) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(17), one O(19), one O(21), and one O(8) atom. The Ga(3)-O(10) bond length is 2.17 Å. The Ga(3)-O(12) bond length is 1.73 Å. The Ga(3)-O(17) bond length is 1.70 Å. The Ga(3)-O(19) bond length is 2.21 Å. The Ga(3)-O(21) bond length is 2.35 Å. The Ga(3)-O(8) bond length is 2.32 Å. In the fourth Ga site, Ga(4) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(17), and one O(6) atom. The Ga(4)-O(10) bond length is 2.00 Å. The Ga(4)-O(13) bond length is 1.99 Å. The Ga(4)-O(17) bond length is 1.65 Å. The Ga(4)-O(6) bond length is 1.65 Å. In the fifth Ga site, Ga(5) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(18), one O(23), one O(25), and one O(26) atom. The Ga(5)-O(14) bond length is 2.32 Å. The Ga(5)-O(16) bond length is 2.18 Å. The Ga(5)-O(18) bond length is 1.73 Å. The Ga(5)-O(23) bond length is 1.71 Å. The Ga(5)-O(25) bond length is 2.20 Å. The Ga(5)-O(26) bond length is 2.35 Å. In the sixth Ga site, Ga(6) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(16), one O(19), one O(21), and one O(23) atom. The Ga(6)-O(12) bond length is 1.65 Å. The Ga(6)-O(14) bond length is 2.55 Å. The Ga(6)-O(16) bond length is 2.01 Å. The Ga(6)-O(19) bond length is 1.99 Å. The Ga(6)-O(21) bond length is 2.50 Å. The Ga(6)-O(23) bond length is 1.65 Å. In the seventh Ga site, Ga(7) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(24), one O(27), one O(28), and one O(29) atom. The Ga(7)-O(20) bond length is 2.33 Å. The Ga(7)-O(22) bond length is 2.16 Å. The Ga(7)-O(24) bond length is 1.74 Å. The Ga(7)-O(27) bond length is 1.71 Å. The Ga(7)-O(28) bond length is 2.18 Å. The Ga(7)-O(29) bond length is 2.35 Å. In the eighth Ga site, Ga(8) is bonded in a 4-coordinate geometry to one O(18), one O(22), one O(25), one O(26), and one O(27) atom. The Ga(8)-O(18) bond length is 1.65 Å. The Ga(8)-O(22) bond length is 2.01 Å. The Ga(8)-O(25) bond length is 1.99 Å. The Ga(8)-O(26) bond length is 2.50 Å. The Ga(8)-O(27) bond length is 1.65 Å. In the ninth Ga site, Ga(9) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(24), one O(28), one O(29), and one O(5) atom. The Ga(9)-O(1) bond length is 2.53 Å. The Ga(9)-O(2) bond length is 2.00 Å. The Ga(9)-O(24) bond length is 1.64 Å. The Ga(9)-O(28) bond length is 2.02 Å. The Ga(9)-O(29) bond length is 2.57 Å. The Ga(9)-O(5) bond length is 1.65 Å. There are twenty-nine inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(1), one La(8), two equivalent La(1), one Ga(1), and one Ga(9) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one Ga(1), and one Ga(9) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), one Mg(1), one La(2), two equivalent La(3), and one Ga(2) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(3), and one Ga(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ga(1) and one Ga(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one Ga(4) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one Mg(1), one La(3), and one Ga(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one La(4) and one Ga(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(1), one Mg(1), one La(1), and one Ga(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(3), and one Ga(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mg(1), one La(3), and one Ga(2) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(6) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one La(2), one La(5), one Ga(2), and one Ga(4) atom. In the fourteenth O site, O(14) is bonded in a 6-coordinate geometry to one La(4), one La(6), two equivalent La(7), one Ga(5), and one Ga(6) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one La(3) and one Ga(2) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(5), and one Ga(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Ga(3) and one Ga(4) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(8) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to one La(4), one La(7), one Ga(3), and one Ga(6) atom. In the twentieth O site, O(20) is bonded in a 1-coordinate geometry to one La(8) and one Ga(7) atom. In the twenty-first O site, O(21) is bonded in a 6-coordinate geometry to one La(5), one La(7), two equivalent La(4), one Ga(3), and one Ga(6) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(7), and one Ga(8) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one Ga(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(9) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one La(6), one La(9), one Ga(5), and one Ga(8) atom. In the twenty-sixth O site, O(26) is bonded in a 6-coordinate geometry to one La(7), one La(9), two equivalent La(6), one Ga(5), and one Ga(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 150 degrees geometry to one Ga(7) and one Ga(8) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to one La(1), one La(8), one Ga(7), and one Ga(9) atom. In the twenty-ninth O site, O(29) is bonded in a 6-coordinate geometry to one La(1), one La(9), two equivalent La(8), one Ga(7), and one Ga(9) atom.