Mn2SbAs is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the hexagonal P-6m2 space group. Mn(1) is bonded to three equivalent Sb(1) and three equivalent As(1) atoms to form a mixture of distorted corner, face, and edge-sharing MnSb3As3 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. Sb(1) is bonded in a 6-coordinate geometry to six equivalent Mn(1) atoms. As(1) is bonded in a 6-coordinate geometry to six equivalent Mn(1) atoms.
Mn2SbAs is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the hexagonal P-6m2 space group. Mn(1) is bonded to three equivalent Sb(1) and three equivalent As(1) atoms to form a mixture of distorted corner, face, and edge-sharing MnSb3As3 octahedra. The corner-sharing octahedral tilt angles range from 49-51°. All Mn(1)-Sb(1) bond lengths are 2.75 Å. All Mn(1)-As(1) bond lengths are 2.66 Å. Sb(1) is bonded in a 6-coordinate geometry to six equivalent Mn(1) atoms. As(1) is bonded in a 6-coordinate geometry to six equivalent Mn(1) atoms.