LiAg2F4 crystallizes in the orthorhombic Ccce space group. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form edge-sharing AgF6 pentagonal pyramids. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), and two equivalent Ag(1) atoms.
LiAg2F4 crystallizes in the orthorhombic Ccce space group. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Li(1)-F(1) bond lengths are 1.99 Å. Both Li(1)-F(2) bond lengths are 1.93 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form edge-sharing AgF6 pentagonal pyramids. Both Ag(1)-F(1) bond lengths are 2.36 Å. There are two shorter (2.33 Å) and two longer (2.56 Å) Ag(1)-F(2) bond lengths. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. Both Ag(2)-F(1) bond lengths are 2.15 Å. Both Ag(2)-F(2) bond lengths are 2.23 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), and two equivalent Ag(1) atoms.