Ti2CdC is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded in a 3-coordinate geometry to three equivalent Cd(1) and three equivalent C(1) atoms. Cd(1) is bonded to six equivalent Ti(1) and six equivalent Cd(1) atoms to form CdTi6Cd6 cuboctahedra that share corners with six equivalent Cd(1)Ti6Cd6 cuboctahedra, corners with six equivalent C(1)Ti6 octahedra, edges with six equivalent Cd(1)Ti6Cd6 cuboctahedra, edges with six equivalent C(1)Ti6 octahedra, and faces with six equivalent Cd(1)Ti6Cd6 cuboctahedra. The corner-sharing octahedral tilt angles are 22°. C(1) is bonded to six equivalent Ti(1) atoms to form CTi6 octahedra that share corners with six equivalent Cd(1)Ti6Cd6 cuboctahedra, edges with six equivalent Cd(1)Ti6Cd6 cuboctahedra, and edges with six equivalent C(1)Ti6 octahedra.
Ti2CdC is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded in a 3-coordinate geometry to three equivalent Cd(1) and three equivalent C(1) atoms. All Ti(1)-Cd(1) bond lengths are 3.06 Å. All Ti(1)-C(1) bond lengths are 2.11 Å. Cd(1) is bonded to six equivalent Ti(1) and six equivalent Cd(1) atoms to form CdTi6Cd6 cuboctahedra that share corners with six equivalent Cd(1)Ti6Cd6 cuboctahedra, corners with six equivalent C(1)Ti6 octahedra, edges with six equivalent Cd(1)Ti6Cd6 cuboctahedra, edges with six equivalent C(1)Ti6 octahedra, and faces with six equivalent Cd(1)Ti6Cd6 cuboctahedra. The corner-sharing octahedral tilt angles are 22°. All Cd(1)-Cd(1) bond lengths are 3.09 Å. C(1) is bonded to six equivalent Ti(1) atoms to form CTi6 octahedra that share corners with six equivalent Cd(1)Ti6Cd6 cuboctahedra, edges with six equivalent Cd(1)Ti6Cd6 cuboctahedra, and edges with six equivalent C(1)Ti6 octahedra.