C2Te(NO2)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2Te(NO2)4 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one O(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one O(1) atom. Te(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Te(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Te(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one Te(1) atom.
C2Te(NO2)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2Te(NO2)4 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one O(4) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.38 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one O(4) atom. The N(1)-O(4) bond length is 1.53 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one O(1) atom. The N(2)-O(1) bond length is 1.27 Å. Te(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Te(1)-O(1) bond lengths are 2.52 Å. Both Te(1)-O(2) bond lengths are 1.89 Å. Both Te(1)-O(3) bond lengths are 1.88 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Te(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Te(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one Te(1) atom.