N2Se3AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2Se3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(10), one F(12), one F(2), one F(4), and one F(5) atom. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(12) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each N2Se3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(5) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(5) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(3) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) atom. In the third Se site, Se(5) is bonded in a water-like geometry to one N(1) and one N(3) atom.
N2Se3AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four AsF6 clusters and four N2Se3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(10), one F(12), one F(2), one F(4), and one F(5) atom. The As(1)-F(1) bond length is 1.76 Å. The As(1)-F(10) bond length is 1.79 Å. The As(1)-F(12) bond length is 1.78 Å. The As(1)-F(2) bond length is 1.76 Å. The As(1)-F(4) bond length is 1.78 Å. The As(1)-F(5) bond length is 1.81 Å. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(12) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each N2Se3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one Se(5) atom. The N(1)-Se(2) bond length is 1.77 Å. The N(1)-Se(5) bond length is 1.75 Å. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one Se(1) and one Se(5) atom. The N(3)-Se(1) bond length is 1.77 Å. The N(3)-Se(5) bond length is 1.75 Å. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(3) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) atom. In the third Se site, Se(5) is bonded in a water-like geometry to one N(1) and one N(3) atom.