PrYbO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Yb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing YbO6 octahedra. The corner-sharing octahedral tilt angles range from 42-47°. Pr(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Yb(1) and two equivalent Pr(1) atoms. In the second O site, O(2) is bonded to two equivalent Yb(1) and two equivalent Pr(1) atoms to form corner-sharing OYb2Pr2 trigonal pyramids.
PrYbO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Yb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing YbO6 octahedra. The corner-sharing octahedral tilt angles range from 42-47°. Both Yb(1)-O(2) bond lengths are 2.33 Å. There are two shorter (2.23 Å) and two longer (2.28 Å) Yb(1)-O(1) bond lengths. Pr(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There is one shorter (2.37 Å) and one longer (2.45 Å) Pr(1)-O(2) bond length. There are two shorter (2.38 Å) and two longer (2.63 Å) Pr(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Yb(1) and two equivalent Pr(1) atoms. In the second O site, O(2) is bonded to two equivalent Yb(1) and two equivalent Pr(1) atoms to form corner-sharing OYb2Pr2 trigonal pyramids.