GdRh3B2 crystallizes in the hexagonal P6/mmm space group. Gd(1) is bonded in a 20-coordinate geometry to two equivalent Gd(1), twelve equivalent Rh(1), and six equivalent B(1) atoms. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Gd(1) and four equivalent B(1) atoms. B(1) is bonded in a 6-coordinate geometry to three equivalent Gd(1) and six equivalent Rh(1) atoms.
GdRh3B2 crystallizes in the hexagonal P6/mmm space group. Gd(1) is bonded in a 20-coordinate geometry to two equivalent Gd(1), twelve equivalent Rh(1), and six equivalent B(1) atoms. Both Gd(1)-Gd(1) bond lengths are 3.14 Å. All Gd(1)-Rh(1) bond lengths are 3.12 Å. All Gd(1)-B(1) bond lengths are 3.12 Å. Rh(1) is bonded in a distorted square co-planar geometry to four equivalent Gd(1) and four equivalent B(1) atoms. All Rh(1)-B(1) bond lengths are 2.21 Å. B(1) is bonded in a 6-coordinate geometry to three equivalent Gd(1) and six equivalent Rh(1) atoms.