W2C9NHO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two W2C9NHO10 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to one C(2), one C(3), one C(5), one C(6), one N(1), and one H(1) atom to form corner-sharing WHC4N octahedra. The corner-sharing octahedral tilt angles are 53°. In the second W site, W(2) is bonded to one C(1), one C(4), one C(7), one C(8), one C(9), and one H(1) atom to form corner-sharing WHC5 octahedra. The corner-sharing octahedral tilt angles are 53°. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(2) and one O(3) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one W(1) and one O(7) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(6) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one W(1) and one O(4) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one W(2) and one O(8,9) atom. In the ninth C site, C(9) is bonded in a distorted linear geometry to one W(2) and one O(8,9) atom. N(1) is bonded in a linear geometry to one W(1) and one O(10) atom. H(1) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2,5) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(3) atom. In the seventh O site, O(8,9) is bonded in a single-bond geometry to one C(9) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one N(1) atom.
W2C9NHO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two W2C9NHO10 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to one C(2), one C(3), one C(5), one C(6), one N(1), and one H(1) atom to form corner-sharing WHC4N octahedra. The corner-sharing octahedral tilt angles are 53°. The W(1)-C(2) bond length is 2.10 Å. The W(1)-C(3) bond length is 2.09 Å. The W(1)-C(5) bond length is 2.10 Å. The W(1)-C(6) bond length is 2.10 Å. The W(1)-N(1) bond length is 1.88 Å. The W(1)-H(1) bond length is 1.94 Å. In the second W site, W(2) is bonded to one C(1), one C(4), one C(7), one C(8), one C(9), and one H(1) atom to form corner-sharing WHC5 octahedra. The corner-sharing octahedral tilt angles are 53°. The W(2)-C(1) bond length is 2.07 Å. The W(2)-C(4) bond length is 2.07 Å. The W(2)-C(7) bond length is 2.08 Å. The W(2)-C(8) bond length is 2.07 Å. The W(2)-C(9) bond length is 2.03 Å. The W(2)-H(1) bond length is 1.93 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(2) and one O(3) atom. The C(1)-O(3) bond length is 1.16 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. The C(2)-O(1) bond length is 1.15 Å. In the third C site, C(3) is bonded in a distorted linear geometry to one W(1) and one O(7) atom. The C(3)-O(7) bond length is 1.16 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. The C(4)-O(2,5) bond length is 1.16 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(6) atom. The C(5)-O(6) bond length is 1.15 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one W(1) and one O(4) atom. The C(6)-O(4) bond length is 1.15 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. The C(7)-O(2,5) bond length is 1.16 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one W(2) and one O(8,9) atom. The C(8)-O(8,9) bond length is 1.17 Å. In the ninth C site, C(9) is bonded in a distorted linear geometry to one W(2) and one O(8,9) atom. The C(9)-O(8,9) bond length is 1.17 Å. N(1) is bonded in a linear geometry to one W(1) and one O(10) atom. The N(1)-O(10) bond length is 1.18 Å. H(1) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2,5) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(3) atom. In the seventh O site, O(8,9) is bonded in a single-bond geometry to one C(9) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one N(1) atom.