Ce3AlN is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ce(1) is bonded in a linear geometry to four equivalent Al(1) and two equivalent N(1) atoms. Al(1) is bonded to twelve equivalent Ce(1) atoms to form AlCe12 cuboctahedra that share corners with twelve equivalent Al(1)Ce12 cuboctahedra, faces with six equivalent Al(1)Ce12 cuboctahedra, and faces with eight equivalent N(1)Ce6 octahedra. N(1) is bonded to six equivalent Ce(1) atoms to form NCe6 octahedra that share corners with six equivalent N(1)Ce6 octahedra and faces with eight equivalent Al(1)Ce12 cuboctahedra. The corner-sharing octahedra are not tilted.
Ce3AlN is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ce(1) is bonded in a linear geometry to four equivalent Al(1) and two equivalent N(1) atoms. All Ce(1)-Al(1) bond lengths are 3.47 Å. Both Ce(1)-N(1) bond lengths are 2.45 Å. Al(1) is bonded to twelve equivalent Ce(1) atoms to form AlCe12 cuboctahedra that share corners with twelve equivalent Al(1)Ce12 cuboctahedra, faces with six equivalent Al(1)Ce12 cuboctahedra, and faces with eight equivalent N(1)Ce6 octahedra. N(1) is bonded to six equivalent Ce(1) atoms to form NCe6 octahedra that share corners with six equivalent N(1)Ce6 octahedra and faces with eight equivalent Al(1)Ce12 cuboctahedra. The corner-sharing octahedra are not tilted.