Ba2LuRuO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Lu(1)O6 octahedra, and faces with four equivalent Ru(1)O6 octahedra. Lu(1) is bonded to six equivalent O(1) atoms to form LuO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Lu(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Ba(1), one Lu(1), and one Ru(1) atom to form a mixture of distorted edge, corner, and face-sharing OBa4LuRu octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
Ba2LuRuO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Lu(1)O6 octahedra, and faces with four equivalent Ru(1)O6 octahedra. All Ba(1)-O(1) bond lengths are 2.96 Å. Lu(1) is bonded to six equivalent O(1) atoms to form LuO6 octahedra that share corners with six equivalent Ru(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Lu(1)-O(1) bond lengths are 2.19 Å. Ru(1) is bonded to six equivalent O(1) atoms to form RuO6 octahedra that share corners with six equivalent Lu(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ru(1)-O(1) bond lengths are 1.99 Å. O(1) is bonded to four equivalent Ba(1), one Lu(1), and one Ru(1) atom to form a mixture of distorted edge, corner, and face-sharing OBa4LuRu octahedra. The corner-sharing octahedral tilt angles range from 0-60°.