IrAsTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Ir(1) is bonded to three equivalent As(1) and three equivalent Te(1) atoms to form IrTe3As3 octahedra that share corners with twelve equivalent Ir(1)Te3As3 octahedra, corners with three equivalent Te(1)AsIr3 tetrahedra, and corners with three equivalent As(1)TeIr3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 63-64°. As(1) is bonded to three equivalent Ir(1) and one Te(1) atom to form AsTeIr3 trigonal pyramids that share corners with three equivalent Ir(1)Te3As3 octahedra, corners with nine equivalent Te(1)AsIr3 tetrahedra, and corners with six equivalent As(1)TeIr3 trigonal pyramids. The corner-sharing octahedral tilt angles are 79°. Te(1) is bonded to three equivalent Ir(1) and one As(1) atom to form TeAsIr3 tetrahedra that share corners with three equivalent Ir(1)Te3As3 octahedra, corners with six equivalent Te(1)AsIr3 tetrahedra, and corners with nine equivalent As(1)TeIr3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°.
IrAsTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Ir(1) is bonded to three equivalent As(1) and three equivalent Te(1) atoms to form IrTe3As3 octahedra that share corners with twelve equivalent Ir(1)Te3As3 octahedra, corners with three equivalent Te(1)AsIr3 tetrahedra, and corners with three equivalent As(1)TeIr3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 63-64°. All Ir(1)-As(1) bond lengths are 2.52 Å. All Ir(1)-Te(1) bond lengths are 2.64 Å. As(1) is bonded to three equivalent Ir(1) and one Te(1) atom to form AsTeIr3 trigonal pyramids that share corners with three equivalent Ir(1)Te3As3 octahedra, corners with nine equivalent Te(1)AsIr3 tetrahedra, and corners with six equivalent As(1)TeIr3 trigonal pyramids. The corner-sharing octahedral tilt angles are 79°. The As(1)-Te(1) bond length is 2.62 Å. Te(1) is bonded to three equivalent Ir(1) and one As(1) atom to form TeAsIr3 tetrahedra that share corners with three equivalent Ir(1)Te3As3 octahedra, corners with six equivalent Te(1)AsIr3 tetrahedra, and corners with nine equivalent As(1)TeIr3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°.