TiNi2Cu is beta Cu3Ti-derived structured and crystallizes in the orthorhombic Pmmn space group. Ti(1) is bonded to eight equivalent Ni(1) and four equivalent Cu(1) atoms to form TiCu4Ni8 cuboctahedra that share corners with two equivalent Ti(1)Cu4Ni8 cuboctahedra, corners with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, corners with eight equivalent Cu(1)Ti4Ni8 cuboctahedra, edges with six equivalent Ti(1)Cu4Ni8 cuboctahedra, edges with twelve equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, faces with six equivalent Ti(1)Cu4Ni8 cuboctahedra, faces with six equivalent Cu(1)Ti4Ni8 cuboctahedra, and faces with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra. Ni(1) is bonded to four equivalent Ti(1), four equivalent Ni(1), and four equivalent Cu(1) atoms to form distorted NiTi4Cu4Ni4 cuboctahedra that share corners with four equivalent Ti(1)Cu4Ni8 cuboctahedra, corners with four equivalent Cu(1)Ti4Ni8 cuboctahedra, corners with ten equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, edges with six equivalent Ti(1)Cu4Ni8 cuboctahedra, edges with six equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, edges with six equivalent Cu(1)Ti4Ni8 cuboctahedra, faces with four equivalent Ti(1)Cu4Ni8 cuboctahedra, faces with four equivalent Cu(1)Ti4Ni8 cuboctahedra, and faces with twelve equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra. Cu(1) is bonded to four equivalent Ti(1) and eight equivalent Ni(1) atoms to form CuTi4Ni8 cuboctahedra that share corners with two equivalent Cu(1)Ti4Ni8 cuboctahedra, corners with eight equivalent Ti(1)Cu4Ni8 cuboctahedra, corners with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, edges with six equivalent Cu(1)Ti4Ni8 cuboctahedra, edges with twelve equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, faces with six equivalent Ti(1)Cu4Ni8 cuboctahedra, faces with six equivalent Cu(1)Ti4Ni8 cuboctahedra, and faces with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra.
TiNi2Cu is beta Cu3Ti-derived structured and crystallizes in the orthorhombic Pmmn space group. Ti(1) is bonded to eight equivalent Ni(1) and four equivalent Cu(1) atoms to form TiCu4Ni8 cuboctahedra that share corners with two equivalent Ti(1)Cu4Ni8 cuboctahedra, corners with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, corners with eight equivalent Cu(1)Ti4Ni8 cuboctahedra, edges with six equivalent Ti(1)Cu4Ni8 cuboctahedra, edges with twelve equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, faces with six equivalent Ti(1)Cu4Ni8 cuboctahedra, faces with six equivalent Cu(1)Ti4Ni8 cuboctahedra, and faces with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra. There are two shorter (2.55 Å) and six longer (2.58 Å) Ti(1)-Ni(1) bond lengths. There are two shorter (2.59 Å) and two longer (2.64 Å) Ti(1)-Cu(1) bond lengths. Ni(1) is bonded to four equivalent Ti(1), four equivalent Ni(1), and four equivalent Cu(1) atoms to form distorted NiTi4Cu4Ni4 cuboctahedra that share corners with four equivalent Ti(1)Cu4Ni8 cuboctahedra, corners with four equivalent Cu(1)Ti4Ni8 cuboctahedra, corners with ten equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, edges with six equivalent Ti(1)Cu4Ni8 cuboctahedra, edges with six equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, edges with six equivalent Cu(1)Ti4Ni8 cuboctahedra, faces with four equivalent Ti(1)Cu4Ni8 cuboctahedra, faces with four equivalent Cu(1)Ti4Ni8 cuboctahedra, and faces with twelve equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra. There is one shorter (2.58 Å) and three longer (2.60 Å) Ni(1)-Ni(1) bond lengths. There are a spread of Ni(1)-Cu(1) bond distances ranging from 2.50-2.63 Å. Cu(1) is bonded to four equivalent Ti(1) and eight equivalent Ni(1) atoms to form CuTi4Ni8 cuboctahedra that share corners with two equivalent Cu(1)Ti4Ni8 cuboctahedra, corners with eight equivalent Ti(1)Cu4Ni8 cuboctahedra, corners with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, edges with six equivalent Cu(1)Ti4Ni8 cuboctahedra, edges with twelve equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra, faces with six equivalent Ti(1)Cu4Ni8 cuboctahedra, faces with six equivalent Cu(1)Ti4Ni8 cuboctahedra, and faces with eight equivalent Ni(1)Ti4Cu4Ni4 cuboctahedra.