VF5 is Copper structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two VF5 clusters. V(1) is bonded to one F(2), one F(3), one F(4), one F(5), and two equivalent F(1) atoms to form edge-sharing VF6 octahedra. There are five inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom.
VF5 is Copper structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two VF5 clusters. V(1) is bonded to one F(2), one F(3), one F(4), one F(5), and two equivalent F(1) atoms to form edge-sharing VF6 octahedra. The V(1)-F(2) bond length is 1.74 Å. The V(1)-F(3) bond length is 1.74 Å. The V(1)-F(4) bond length is 1.77 Å. The V(1)-F(5) bond length is 1.77 Å. There is one shorter (2.00 Å) and one longer (2.03 Å) V(1)-F(1) bond length. There are five inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom.