TlGeF3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TlGeF3 cluster. Tl(1) is bonded in a 1-coordinate geometry to one F(3) atom. Ge(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Tl(1) and one Ge(1) atom.
TlGeF3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TlGeF3 cluster. Tl(1) is bonded in a 1-coordinate geometry to one F(3) atom. The Tl(1)-F(3) bond length is 2.76 Å. Ge(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. The Ge(1)-F(1) bond length is 1.90 Å. The Ge(1)-F(2) bond length is 1.90 Å. The Ge(1)-F(3) bond length is 1.91 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Tl(1) and one Ge(1) atom.