BaBrCl is Cotunnite-derived structured and crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 7-coordinate geometry to four equivalent Br(1) and three equivalent Cl(1) atoms. Br(1) is bonded to four equivalent Ba(1) atoms to form a mixture of corner and edge-sharing BrBa4 tetrahedra. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent Ba(1) atoms.
BaBrCl is Cotunnite-derived structured and crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 7-coordinate geometry to four equivalent Br(1) and three equivalent Cl(1) atoms. There are a spread of Ba(1)-Br(1) bond distances ranging from 3.32-3.35 Å. There is one shorter (3.11 Å) and two longer (3.18 Å) Ba(1)-Cl(1) bond lengths. Br(1) is bonded to four equivalent Ba(1) atoms to form a mixture of corner and edge-sharing BrBa4 tetrahedra. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent Ba(1) atoms.