Ni(H3O2)2NiH6(NO5)2(NH2O3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ncimech_000224 molecules, one Ni(H3O2)2 cluster, and one NiH6(NO5)2 cluster. In the Ni(H3O2)2 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(8) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ni(1) and one H(8) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(3), and one H(4) atom. In the NiH6(NO5)2 cluster, Ni(2) is bonded in a square co-planar geometry to two equivalent O(6) and two equivalent O(7) atoms. N(2) is bonded in a trigonal planar geometry to one O(10), one O(8), and one O(9) atom. There are three inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(7) is bonded in a distorted bent 150 degrees geometry to one O(6) and one O(9) atom. There are five inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal planar geometry to one Ni(2), one H(6), and one H(7) atom. In the second O site, O(7) is bonded in a distorted water-like geometry to one Ni(2) and one H(5) atom. In the third O site, O(8) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(9) is bonded in a water-like geometry to one N(2) and one H(7) atom. In the fifth O site, O(10) is bonded in a single-bond geometry to one N(2) atom.
Ni(H3O2)2NiH6(NO5)2(NH2O3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ncimech_000224 molecules, one Ni(H3O2)2 cluster, and one NiH6(NO5)2 cluster. In the Ni(H3O2)2 cluster, Ni(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ni(1)-O(1) bond lengths are 1.84 Å. Both Ni(1)-O(2) bond lengths are 1.91 Å. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(2) atom. The H(3)-O(2) bond length is 0.99 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(2) atom. The H(4)-O(2) bond length is 0.99 Å. In the third H site, H(8) is bonded in a single-bond geometry to one O(1) atom. The H(8)-O(1) bond length is 0.98 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ni(1) and one H(8) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ni(1), one H(3), and one H(4) atom. In the NiH6(NO5)2 cluster, Ni(2) is bonded in a square co-planar geometry to two equivalent O(6) and two equivalent O(7) atoms. Both Ni(2)-O(6) bond lengths are 1.81 Å. Both Ni(2)-O(7) bond lengths are 1.80 Å. N(2) is bonded in a trigonal planar geometry to one O(10), one O(8), and one O(9) atom. The N(2)-O(10) bond length is 1.25 Å. The N(2)-O(8) bond length is 1.21 Å. The N(2)-O(9) bond length is 1.38 Å. There are three inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(7) atom. The H(5)-O(7) bond length is 0.98 Å. In the second H site, H(6) is bonded in a single-bond geometry to one O(6) atom. The H(6)-O(6) bond length is 0.98 Å. In the third H site, H(7) is bonded in a distorted bent 150 degrees geometry to one O(6) and one O(9) atom. The H(7)-O(6) bond length is 1.56 Å. The H(7)-O(9) bond length is 1.05 Å. There are five inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal planar geometry to one Ni(2), one H(6), and one H(7) atom. In the second O site, O(7) is bonded in a distorted water-like geometry to one Ni(2) and one H(5) atom. In the third O site, O(8) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(9) is bonded in a water-like geometry to one N(2) and one H(7) atom. In the fifth O site, O(10) is bonded in a single-bond geometry to one N(2) atom.