(SbF6)3(AsF3)2S14I3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two arsenic trifluoride molecules, one S14I3 cluster, and three SbF6 clusters. In the S14I3 cluster, there are seven inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(5) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(6) and one S(7) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one S(2), one S(7), and one I(2) atom. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(3), and one I(1) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one S(6) atom. In the second I site, I(2) is bonded in a linear geometry to two equivalent S(5) atoms. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom.
(SbF6)3(AsF3)2S14I3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two arsenic trifluoride molecules, one S14I3 cluster, and three SbF6 clusters. In the S14I3 cluster, there are seven inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(6) atom. The S(1)-S(4) bond length is 2.00 Å. The S(1)-S(6) bond length is 2.13 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(5) atom. The S(2)-S(4) bond length is 2.12 Å. The S(2)-S(5) bond length is 2.00 Å. In the third S site, S(3) is bonded in a water-like geometry to one S(6) and one S(7) atom. The S(3)-S(6) bond length is 2.43 Å. The S(3)-S(7) bond length is 1.90 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one S(2), one S(7), and one I(2) atom. The S(5)-S(7) bond length is 2.33 Å. The S(5)-I(2) bond length is 2.65 Å. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(3), and one I(1) atom. The S(6)-I(1) bond length is 2.34 Å. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one S(6) atom. In the second I site, I(2) is bonded in a linear geometry to two equivalent S(5) atoms. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. The Sb(1)-F(1) bond length is 1.94 Å. The Sb(1)-F(2) bond length is 1.92 Å. The Sb(1)-F(3) bond length is 1.92 Å. The Sb(1)-F(4) bond length is 1.92 Å. The Sb(1)-F(6) bond length is 1.93 Å. The Sb(1)-F(7) bond length is 1.92 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom.