SV1 is Modderite structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of distorted edge, face, and corner-sharing VS6 octahedra. The corner-sharing octahedral tilt angles range from 41-54°. S(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.
SV1 is Modderite structured and crystallizes in the orthorhombic Pnma space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of distorted edge, face, and corner-sharing VS6 octahedra. The corner-sharing octahedral tilt angles range from 41-54°. There are a spread of V(1)-S(1) bond distances ranging from 2.33-2.51 Å. S(1) is bonded in a 6-coordinate geometry to six equivalent V(1) atoms.