NdOHCO3 crystallizes in the orthorhombic P2_12_12_1 space group. Nd(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(4), three equivalent O(2), and three equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. H(1) is bonded in a single-bond geometry to one O(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(1) atom.
NdOHCO3 crystallizes in the orthorhombic P2_12_12_1 space group. Nd(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(4), three equivalent O(2), and three equivalent O(3) atoms. There is one shorter (2.36 Å) and one longer (2.38 Å) Nd(1)-O(1) bond length. There is one shorter (2.55 Å) and one longer (2.57 Å) Nd(1)-O(4) bond length. There are two shorter (2.61 Å) and one longer (2.84 Å) Nd(1)-O(2) bond length. There are a spread of Nd(1)-O(3) bond distances ranging from 2.58-2.81 Å. C(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. The C(1)-O(2) bond length is 1.30 Å. The C(1)-O(3) bond length is 1.30 Å. The C(1)-O(4) bond length is 1.29 Å. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(1) atom.