Mn6OF11 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(13), one F(18), one F(19), one F(3), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(7)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(11)F6 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. In the second Mn site, Mn(2) is bonded to one O(1), one F(12), one F(17), one F(19), one F(2), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)F6 octahedra, corners with two equivalent Mn(11)F6 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(3)F6 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the third Mn site, Mn(3) is bonded to one F(1), one F(11), one F(17), one F(2), one F(20), and one F(5) atom to form MnF6 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(10)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-56°. In the fourth Mn site, Mn(4) is bonded to one O(2), one F(16), one F(21), one F(22), one F(4), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(7)OF5 octahedra, corners with four equivalent Mn(12)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-60°. In the fifth Mn site, Mn(5) is bonded to one O(2), one F(14), one F(18), one F(22), one F(3), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(11)F6 octahedra, corners with two equivalent Mn(12)F6 octahedra, corners with four equivalent Mn(7)OF5 octahedra,  an edgeedge with one Mn(1)OF5 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-60°. In the sixth Mn site, Mn(6) is bonded to one F(1), one F(10), one F(15), one F(20), one F(21), and one F(4) atom to form MnF6 octahedra that share corners with two equivalent Mn(10)F6 octahedra, corners with two equivalent Mn(12)F6 octahedra, corners with four equivalent Mn(8)F6 octahedra,  an edgeedge with one Mn(3)F6 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the seventh Mn site, Mn(7) is bonded to one O(2), one F(14), one F(16), one F(18), one F(7), and one F(8) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(1)OF5 octahedra, corners with two equivalent Mn(4)OF5 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(11)F6 octahedra, and  an edgeedge with one Mn(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the eighth Mn site, Mn(8) is bonded to one F(1), one F(10), one F(11), one F(15), one F(21), and one F(9) atom to form MnF6 octahedra that share corners with two equivalent Mn(3)F6 octahedra, corners with two equivalent Mn(4)OF5 octahedra, corners with four equivalent Mn(6)F6 octahedra,  an edgeedge with one Mn(10)F6 octahedra, and  an edgeedge with one Mn(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. In the ninth Mn site, Mn(9) is bonded to one O(1), one F(12), one F(13), one F(17), one F(5), and one F(6) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(3)F6 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)F6 octahedra, and  an edgeedge with one Mn(11)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. In the tenth Mn site, Mn(10) is bonded to one F(10), one F(11), one F(12), one F(2), one F(20), and one F(5) atom to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with four equivalent Mn(3)F6 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the eleventh Mn site, Mn(11) is bonded to one F(13), one F(14), one F(19), one F(3), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the twelfth Mn site, Mn(12) is bonded to one F(15), one F(16), one F(22), one F(4), one F(8), and one F(9) atom to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the fifteenth F site, F(15) is bonded in a trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the sixteenth F site, F(16) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the seventeenth F site, F(17) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the nineteenth F site, F(19) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the twentieth F site, F(20) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the twenty-first F site, F(21) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the twenty-second F site, F(22) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(5) atom.
Mn6OF11 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(13), one F(18), one F(19), one F(3), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(7)OF5 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(11)F6 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. The Mn(1)-O(1) bond length is 2.08 Å. The Mn(1)-F(13) bond length is 2.13 Å. The Mn(1)-F(18) bond length is 2.18 Å. The Mn(1)-F(19) bond length is 2.24 Å. The Mn(1)-F(3) bond length is 2.24 Å. The Mn(1)-F(7) bond length is 2.10 Å. In the second Mn site, Mn(2) is bonded to one O(1), one F(12), one F(17), one F(19), one F(2), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)F6 octahedra, corners with two equivalent Mn(11)F6 octahedra, corners with four equivalent Mn(9)OF5 octahedra,  an edgeedge with one Mn(3)F6 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. The Mn(2)-O(1) bond length is 1.87 Å. The Mn(2)-F(12) bond length is 2.05 Å. The Mn(2)-F(17) bond length is 2.17 Å. The Mn(2)-F(19) bond length is 2.07 Å. The Mn(2)-F(2) bond length is 2.09 Å. The Mn(2)-F(6) bond length is 2.11 Å. In the third Mn site, Mn(3) is bonded to one F(1), one F(11), one F(17), one F(2), one F(20), and one F(5) atom to form MnF6 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(9)OF5 octahedra, corners with four equivalent Mn(10)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-56°. The Mn(3)-F(1) bond length is 2.15 Å. The Mn(3)-F(11) bond length is 2.10 Å. The Mn(3)-F(17) bond length is 2.16 Å. The Mn(3)-F(2) bond length is 2.22 Å. The Mn(3)-F(20) bond length is 2.18 Å. The Mn(3)-F(5) bond length is 2.11 Å. In the fourth Mn site, Mn(4) is bonded to one O(2), one F(16), one F(21), one F(22), one F(4), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(7)OF5 octahedra, corners with four equivalent Mn(12)F6 octahedra,  an edgeedge with one Mn(6)F6 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-60°. The Mn(4)-O(2) bond length is 2.09 Å. The Mn(4)-F(16) bond length is 2.14 Å. The Mn(4)-F(21) bond length is 2.19 Å. The Mn(4)-F(22) bond length is 2.24 Å. The Mn(4)-F(4) bond length is 2.21 Å. The Mn(4)-F(9) bond length is 2.10 Å. In the fifth Mn site, Mn(5) is bonded to one O(2), one F(14), one F(18), one F(22), one F(3), and one F(8) atom to form MnOF5 octahedra that share corners with two equivalent Mn(11)F6 octahedra, corners with two equivalent Mn(12)F6 octahedra, corners with four equivalent Mn(7)OF5 octahedra,  an edgeedge with one Mn(1)OF5 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-60°. The Mn(5)-O(2) bond length is 1.86 Å. The Mn(5)-F(14) bond length is 2.03 Å. The Mn(5)-F(18) bond length is 2.18 Å. The Mn(5)-F(22) bond length is 2.05 Å. The Mn(5)-F(3) bond length is 2.07 Å. The Mn(5)-F(8) bond length is 2.12 Å. In the sixth Mn site, Mn(6) is bonded to one F(1), one F(10), one F(15), one F(20), one F(21), and one F(4) atom to form MnF6 octahedra that share corners with two equivalent Mn(10)F6 octahedra, corners with two equivalent Mn(12)F6 octahedra, corners with four equivalent Mn(8)F6 octahedra,  an edgeedge with one Mn(3)F6 octahedra, and  an edgeedge with one Mn(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. The Mn(6)-F(1) bond length is 2.18 Å. The Mn(6)-F(10) bond length is 2.13 Å. The Mn(6)-F(15) bond length is 2.10 Å. The Mn(6)-F(20) bond length is 2.17 Å. The Mn(6)-F(21) bond length is 2.22 Å. The Mn(6)-F(4) bond length is 2.14 Å. In the seventh Mn site, Mn(7) is bonded to one O(2), one F(14), one F(16), one F(18), one F(7), and one F(8) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(1)OF5 octahedra, corners with two equivalent Mn(4)OF5 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(11)F6 octahedra, and  an edgeedge with one Mn(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. The Mn(7)-O(2) bond length is 2.04 Å. The Mn(7)-F(14) bond length is 2.41 Å. The Mn(7)-F(16) bond length is 2.11 Å. The Mn(7)-F(18) bond length is 2.16 Å. The Mn(7)-F(7) bond length is 2.14 Å. The Mn(7)-F(8) bond length is 2.23 Å. In the eighth Mn site, Mn(8) is bonded to one F(1), one F(10), one F(11), one F(15), one F(21), and one F(9) atom to form MnF6 octahedra that share corners with two equivalent Mn(3)F6 octahedra, corners with two equivalent Mn(4)OF5 octahedra, corners with four equivalent Mn(6)F6 octahedra,  an edgeedge with one Mn(10)F6 octahedra, and  an edgeedge with one Mn(12)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. The Mn(8)-F(1) bond length is 2.12 Å. The Mn(8)-F(10) bond length is 2.23 Å. The Mn(8)-F(11) bond length is 2.17 Å. The Mn(8)-F(15) bond length is 2.18 Å. The Mn(8)-F(21) bond length is 2.13 Å. The Mn(8)-F(9) bond length is 2.15 Å. In the ninth Mn site, Mn(9) is bonded to one O(1), one F(12), one F(13), one F(17), one F(5), and one F(6) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(3)F6 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)F6 octahedra, and  an edgeedge with one Mn(11)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. The Mn(9)-O(1) bond length is 2.03 Å. The Mn(9)-F(12) bond length is 2.39 Å. The Mn(9)-F(13) bond length is 2.12 Å. The Mn(9)-F(17) bond length is 2.15 Å. The Mn(9)-F(5) bond length is 2.14 Å. The Mn(9)-F(6) bond length is 2.21 Å. In the tenth Mn site, Mn(10) is bonded to one F(10), one F(11), one F(12), one F(2), one F(20), and one F(5) atom to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with two equivalent Mn(2)OF5 octahedra, corners with four equivalent Mn(3)F6 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(9)OF5 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. The Mn(10)-F(10) bond length is 2.16 Å. The Mn(10)-F(11) bond length is 2.18 Å. The Mn(10)-F(12) bond length is 2.22 Å. The Mn(10)-F(2) bond length is 2.14 Å. The Mn(10)-F(20) bond length is 2.11 Å. The Mn(10)-F(5) bond length is 2.16 Å. In the eleventh Mn site, Mn(11) is bonded to one F(13), one F(14), one F(19), one F(3), one F(6), and one F(7) atom to form a mixture of edge and corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. The Mn(11)-F(13) bond length is 2.18 Å. The Mn(11)-F(14) bond length is 2.19 Å. The Mn(11)-F(19) bond length is 2.09 Å. The Mn(11)-F(3) bond length is 2.12 Å. The Mn(11)-F(6) bond length is 2.21 Å. The Mn(11)-F(7) bond length is 2.15 Å. In the twelfth Mn site, Mn(12) is bonded to one F(15), one F(16), one F(22), one F(4), one F(8), and one F(9) atom to form MnF6 octahedra that share corners with two equivalent Mn(6)F6 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(4)OF5 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. The Mn(12)-F(15) bond length is 2.16 Å. The Mn(12)-F(16) bond length is 2.19 Å. The Mn(12)-F(22) bond length is 2.10 Å. The Mn(12)-F(4) bond length is 2.10 Å. The Mn(12)-F(8) bond length is 2.17 Å. The Mn(12)-F(9) bond length is 2.18 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. There are twenty-two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the seventh F site, F(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the fifteenth F site, F(15) is bonded in a trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the sixteenth F site, F(16) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the seventeenth F site, F(17) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the nineteenth F site, F(19) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the twentieth F site, F(20) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the twenty-first F site, F(21) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the twenty-second F site, F(22) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(5) atom.