V2Mn3CoGa2 is Tungsten-derived structured and crystallizes in the trigonal R3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to one Mn(3), three equivalent Mn(1), three equivalent Mn(2), and one Co(1) atom. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to one Mn(1), one Mn(2), three equivalent Mn(3), and three equivalent Co(1) atoms. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a body-centered cubic geometry to one V(2), three equivalent V(1), one Ga(1), and three equivalent Ga(2) atoms. In the second Mn site, Mn(2) is bonded in a distorted body-centered cubic geometry to one V(2), three equivalent V(1), one Ga(2), and three equivalent Ga(1) atoms. In the third Mn site, Mn(3) is bonded in a distorted body-centered cubic geometry to one V(1), three equivalent V(2), one Ga(1), and three equivalent Ga(2) atoms. Co(1) is bonded in a distorted body-centered cubic geometry to one V(1), three equivalent V(2), one Ga(2), and three equivalent Ga(1) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted body-centered cubic geometry to one Mn(1), one Mn(3), three equivalent Mn(2), and three equivalent Co(1) atoms. In the second Ga site, Ga(2) is bonded in a distorted body-centered cubic geometry to one Mn(2), three equivalent Mn(1), three equivalent Mn(3), and one Co(1) atom.
V2Mn3CoGa2 is Tungsten-derived structured and crystallizes in the trigonal R3m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a distorted body-centered cubic geometry to one Mn(3), three equivalent Mn(1), three equivalent Mn(2), and one Co(1) atom. The V(1)-Mn(3) bond length is 2.48 Å. All V(1)-Mn(1) bond lengths are 2.50 Å. All V(1)-Mn(2) bond lengths are 2.51 Å. The V(1)-Co(1) bond length is 2.52 Å. In the second V site, V(2) is bonded in a distorted body-centered cubic geometry to one Mn(1), one Mn(2), three equivalent Mn(3), and three equivalent Co(1) atoms. The V(2)-Mn(1) bond length is 2.49 Å. The V(2)-Mn(2) bond length is 2.54 Å. All V(2)-Mn(3) bond lengths are 2.50 Å. All V(2)-Co(1) bond lengths are 2.51 Å. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a body-centered cubic geometry to one V(2), three equivalent V(1), one Ga(1), and three equivalent Ga(2) atoms. The Mn(1)-Ga(1) bond length is 2.52 Å. All Mn(1)-Ga(2) bond lengths are 2.51 Å. In the second Mn site, Mn(2) is bonded in a distorted body-centered cubic geometry to one V(2), three equivalent V(1), one Ga(2), and three equivalent Ga(1) atoms. The Mn(2)-Ga(2) bond length is 2.51 Å. All Mn(2)-Ga(1) bond lengths are 2.51 Å. In the third Mn site, Mn(3) is bonded in a distorted body-centered cubic geometry to one V(1), three equivalent V(2), one Ga(1), and three equivalent Ga(2) atoms. The Mn(3)-Ga(1) bond length is 2.50 Å. All Mn(3)-Ga(2) bond lengths are 2.50 Å. Co(1) is bonded in a distorted body-centered cubic geometry to one V(1), three equivalent V(2), one Ga(2), and three equivalent Ga(1) atoms. The Co(1)-Ga(2) bond length is 2.49 Å. All Co(1)-Ga(1) bond lengths are 2.50 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted body-centered cubic geometry to one Mn(1), one Mn(3), three equivalent Mn(2), and three equivalent Co(1) atoms. In the second Ga site, Ga(2) is bonded in a distorted body-centered cubic geometry to one Mn(2), three equivalent Mn(1), three equivalent Mn(3), and one Co(1) atom.