LiMnRhO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Mn(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent Rh(1)O6 octahedra. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Rh(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Mn(1), and one Rh(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Mn(1), and two equivalent Rh(1) atoms.
LiMnRhO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Mn(1)O6 octahedra and corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. Both Li(1)-O(1) bond lengths are 2.04 Å. Both Li(1)-O(2) bond lengths are 1.94 Å. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with four equivalent Rh(1)O6 octahedra. Both Mn(1)-O(2) bond lengths are 1.90 Å. All Mn(1)-O(1) bond lengths are 1.93 Å. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Rh(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. Both Rh(1)-O(1) bond lengths are 2.05 Å. All Rh(1)-O(2) bond lengths are 2.03 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Mn(1), and one Rh(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Mn(1), and two equivalent Rh(1) atoms.