Cs(TeO3)2 crystallizes in the cubic Fd-3m space group. Cs(1) is bonded to six equivalent O(1) atoms to form CsO6 octahedra that share corners with twelve equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 69°. Te(1) is bonded to six equivalent O(1) atoms to form TeO6 octahedra that share corners with six equivalent Cs(1)O6 octahedra and corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-69°. O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Te(1) atoms.
Cs(TeO3)2 crystallizes in the cubic Fd-3m space group. Cs(1) is bonded to six equivalent O(1) atoms to form CsO6 octahedra that share corners with twelve equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles are 69°. All Cs(1)-O(1) bond lengths are 3.21 Å. Te(1) is bonded to six equivalent O(1) atoms to form TeO6 octahedra that share corners with six equivalent Cs(1)O6 octahedra and corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-69°. All Te(1)-O(1) bond lengths are 1.97 Å. O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Te(1) atoms.