ScOF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sc(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing ScO4F3 pentagonal bipyramids. O(1) is bonded to four equivalent Sc(1) atoms to form a mixture of edge and corner-sharing OSc4 tetrahedra. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sc(1) atoms.
ScOF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sc(1) is bonded to four equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing ScO4F3 pentagonal bipyramids. There are a spread of Sc(1)-O(1) bond distances ranging from 2.07-2.14 Å. There are a spread of Sc(1)-F(1) bond distances ranging from 2.14-2.28 Å. O(1) is bonded to four equivalent Sc(1) atoms to form a mixture of edge and corner-sharing OSc4 tetrahedra. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sc(1) atoms.