As4S5(SAs)4 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two tetraarsenic tetrasulfide molecules and two As4S5 clusters. In each As4S5 cluster, there are two inequivalent As sites. In the first As site, As(1) is bonded in a distorted water-like geometry to one S(1) and one S(3) atom. In the second As site, As(2) is bonded in a trigonal non-coplanar geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to two equivalent As(2) atoms. In the third S site, S(3) is bonded in a water-like geometry to one As(1) and one As(2) atom.
As4S5(SAs)4 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two tetraarsenic tetrasulfide molecules and two As4S5 clusters. In each As4S5 cluster, there are two inequivalent As sites. In the first As site, As(1) is bonded in a distorted water-like geometry to one S(1) and one S(3) atom. The As(1)-S(1) bond length is 2.25 Å. The As(1)-S(3) bond length is 2.24 Å. In the second As site, As(2) is bonded in a trigonal non-coplanar geometry to one S(1), one S(2), and one S(3) atom. The As(2)-S(1) bond length is 2.26 Å. The As(2)-S(2) bond length is 2.26 Å. The As(2)-S(3) bond length is 2.25 Å. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to two equivalent As(2) atoms. In the third S site, S(3) is bonded in a water-like geometry to one As(1) and one As(2) atom.