MnWO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted WO6 octahedra that share corners with eight equivalent Mn(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MnO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent W(1) and one Mn(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Mn(1) atoms.
MnWO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted WO6 octahedra that share corners with eight equivalent Mn(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. Both W(1)-O(1) bond lengths are 1.81 Å. There are two shorter (1.92 Å) and two longer (2.14 Å) W(1)-O(2) bond lengths. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MnO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. Both Mn(1)-O(2) bond lengths are 2.10 Å. There are two shorter (2.12 Å) and two longer (2.23 Å) Mn(1)-O(1) bond lengths. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent W(1) and one Mn(1) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Mn(1) atoms.