RuN(OCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuN(OCl2)2 clusters. In each RuN(OCl2)2 cluster, Ru(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom.
RuN(OCl2)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four RuN(OCl2)2 clusters. In each RuN(OCl2)2 cluster, Ru(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. The Ru(1)-N(1) bond length is 1.99 Å. The Ru(1)-O(1) bond length is 1.72 Å. The Ru(1)-Cl(1) bond length is 2.37 Å. The Ru(1)-Cl(2) bond length is 2.35 Å. The Ru(1)-Cl(3) bond length is 2.34 Å. The Ru(1)-Cl(4) bond length is 2.32 Å. N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. The N(1)-O(2) bond length is 1.15 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ru(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ru(1) atom.