Ga2P3(NO4)3 crystallizes in the monoclinic C2/c space group. Ga(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form GaO5 trigonal bipyramids that share corners with two equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with four equivalent Ga(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent Ga(1)O5 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to two equivalent N(2) atoms. In the second N site, N(2) is bonded in a distorted single-bond geometry to one N(1) and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one N(2) atom.
Ga2P3(NO4)3 crystallizes in the monoclinic C2/c space group. Ga(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form GaO5 trigonal bipyramids that share corners with two equivalent P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. The Ga(1)-O(1) bond length is 1.90 Å. The Ga(1)-O(2) bond length is 2.09 Å. The Ga(1)-O(3) bond length is 1.86 Å. The Ga(1)-O(4) bond length is 1.96 Å. The Ga(1)-O(5) bond length is 1.89 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with four equivalent Ga(1)O5 trigonal bipyramids. Both P(1)-O(3) bond lengths are 1.56 Å. Both P(1)-O(4) bond lengths are 1.55 Å. In the second P site, P(2) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent Ga(1)O5 trigonal bipyramids. The P(2)-O(1) bond length is 1.52 Å. The P(2)-O(2) bond length is 1.50 Å. The P(2)-O(5) bond length is 1.52 Å. The P(2)-O(6) bond length is 1.75 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to two equivalent N(2) atoms. Both N(1)-N(2) bond lengths are 1.23 Å. In the second N site, N(2) is bonded in a distorted single-bond geometry to one N(1) and one O(6) atom. The N(2)-O(6) bond length is 1.34 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one N(2) atom.