VCrP2(O4F)2 crystallizes in the triclinic P-1 space group. V(1) is bonded in a distorted hexagonal planar geometry to two equivalent P(1), two equivalent O(3), and two equivalent O(4) atoms. Cr(1) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent O(2) atoms. P(1) is bonded in a 2-coordinate geometry to one V(1), one Cr(1), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one F(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cr(1) and one P(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(1) and one F(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one V(1) and one P(1) atom. F(1) is bonded in a water-like geometry to one O(1) and one O(3) atom.
VCrP2(O4F)2 crystallizes in the triclinic P-1 space group. V(1) is bonded in a distorted hexagonal planar geometry to two equivalent P(1), two equivalent O(3), and two equivalent O(4) atoms. Both V(1)-P(1) bond lengths are 2.16 Å. Both V(1)-O(3) bond lengths are 2.46 Å. Both V(1)-O(4) bond lengths are 2.64 Å. Cr(1) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent O(2) atoms. Both Cr(1)-P(1) bond lengths are 2.26 Å. Both Cr(1)-O(2) bond lengths are 2.23 Å. P(1) is bonded in a 2-coordinate geometry to one V(1), one Cr(1), one O(2), and one O(4) atom. The P(1)-O(2) bond length is 1.86 Å. The P(1)-O(4) bond length is 1.56 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one F(1) atom. The O(1)-F(1) bond length is 1.11 Å. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cr(1) and one P(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(1) and one F(1) atom. The O(3)-F(1) bond length is 1.79 Å. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one V(1) and one P(1) atom. F(1) is bonded in a water-like geometry to one O(1) and one O(3) atom.