Ca3N2 crystallizes in the cubic Pm-3m space group. The structure consists of one ammonia atom inside a Ca3N framework. In the Ca3N framework, Ca(1) is bonded in a linear geometry to two equivalent N(2) atoms. N(2) is bonded to six equivalent Ca(1) atoms to form corner-sharing NCa6 octahedra. The corner-sharing octahedra are not tilted.
Ca3N2 crystallizes in the cubic Pm-3m space group. The structure consists of one ammonia atom inside a Ca3N framework. In the Ca3N framework, Ca(1) is bonded in a linear geometry to two equivalent N(2) atoms. Both Ca(1)-N(2) bond lengths are 2.30 Å. N(2) is bonded to six equivalent Ca(1) atoms to form corner-sharing NCa6 octahedra. The corner-sharing octahedra are not tilted.