SnC4H14(NBr2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnC4H14(NBr2)2 clusters. Sn(1) is bonded to two equivalent N(1), two equivalent Br(1), and two equivalent Br(2) atoms to form SnBr4N2 octahedra that share corners with two equivalent C(1)H3N tetrahedra and corners with two equivalent C(2)H3N tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(2)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. In the second C site, C(2) is bonded to one N(1), one H(1), one H(6), and one H(7) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(1)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. N(1) is bonded in a 1-coordinate geometry to one Sn(1), one C(1), one C(2), and one H(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Sn(1) atom.
SnC4H14(NBr2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnC4H14(NBr2)2 clusters. Sn(1) is bonded to two equivalent N(1), two equivalent Br(1), and two equivalent Br(2) atoms to form SnBr4N2 octahedra that share corners with two equivalent C(1)H3N tetrahedra and corners with two equivalent C(2)H3N tetrahedra. Both Sn(1)-N(1) bond lengths are 2.34 Å. Both Sn(1)-Br(1) bond lengths are 2.61 Å. Both Sn(1)-Br(2) bond lengths are 2.65 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(2)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(2) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.09 Å. The C(1)-H(4) bond length is 1.10 Å. In the second C site, C(2) is bonded to one N(1), one H(1), one H(6), and one H(7) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(1)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. The C(2)-N(1) bond length is 1.48 Å. The C(2)-H(1) bond length is 1.10 Å. The C(2)-H(6) bond length is 1.10 Å. The C(2)-H(7) bond length is 1.10 Å. N(1) is bonded in a 1-coordinate geometry to one Sn(1), one C(1), one C(2), and one H(5) atom. The N(1)-H(5) bond length is 1.03 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Sn(1) atom.