TiF2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. Ti(1) is bonded in a body-centered cubic geometry to eight equivalent F(1) atoms. F(1) is bonded to four equivalent Ti(1) atoms to form a mixture of edge and corner-sharing FTi4 tetrahedra.
TiF2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. Ti(1) is bonded in a body-centered cubic geometry to eight equivalent F(1) atoms. All Ti(1)-F(1) bond lengths are 2.25 Å. F(1) is bonded to four equivalent Ti(1) atoms to form a mixture of edge and corner-sharing FTi4 tetrahedra.