Cs2Pd(IBr2)2 crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a 8-coordinate geometry to four equivalent I(1) and eight equivalent Br(1) atoms. Pd(1) is bonded in an octahedral geometry to two equivalent I(1) and four equivalent Br(1) atoms. I(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Pd(1), and one I(1) atom. Br(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Pd(1) atom.
Cs2Pd(IBr2)2 crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a 8-coordinate geometry to four equivalent I(1) and eight equivalent Br(1) atoms. All Cs(1)-I(1) bond lengths are 4.43 Å. All Cs(1)-Br(1) bond lengths are 3.88 Å. Pd(1) is bonded in an octahedral geometry to two equivalent I(1) and four equivalent Br(1) atoms. Both Pd(1)-I(1) bond lengths are 3.13 Å. All Pd(1)-Br(1) bond lengths are 2.48 Å. I(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Pd(1), and one I(1) atom. The I(1)-I(1) bond length is 2.88 Å. Br(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Pd(1) atom.