Al10V is Bergman Structure: Mg32(Al,Zn)49 Bergman-derived structured and crystallizes in the cubic Fd-3m space group. V(1) is bonded to six equivalent Al(2) and six equivalent Al(3) atoms to form VAl12 cuboctahedra that share corners with six equivalent V(1)Al12 cuboctahedra and edges with six equivalent Al(1)Al12 cuboctahedra. There are three inequivalent Al sites. In the first Al site, Al(1) is bonded to twelve equivalent Al(3) atoms to form AlAl12 cuboctahedra that share edges with six equivalent V(1)Al12 cuboctahedra and edges with six equivalent Al(1)Al12 cuboctahedra. In the second Al site, Al(3) is bonded in a 11-coordinate geometry to one V(1), two equivalent Al(1), three equivalent Al(2), and five equivalent Al(3) atoms. In the third Al site, Al(2) is bonded in a 12-coordinate geometry to two equivalent V(1), four equivalent Al(2), and six equivalent Al(3) atoms.
Al10V is Bergman Structure: Mg32(Al,Zn)49 Bergman-derived structured and crystallizes in the cubic Fd-3m space group. V(1) is bonded to six equivalent Al(2) and six equivalent Al(3) atoms to form VAl12 cuboctahedra that share corners with six equivalent V(1)Al12 cuboctahedra and edges with six equivalent Al(1)Al12 cuboctahedra. All V(1)-Al(2) bond lengths are 2.54 Å. All V(1)-Al(3) bond lengths are 2.81 Å. There are three inequivalent Al sites. In the first Al site, Al(1) is bonded to twelve equivalent Al(3) atoms to form AlAl12 cuboctahedra that share edges with six equivalent V(1)Al12 cuboctahedra and edges with six equivalent Al(1)Al12 cuboctahedra. All Al(1)-Al(3) bond lengths are 3.04 Å. In the second Al site, Al(3) is bonded in a 11-coordinate geometry to one V(1), two equivalent Al(1), three equivalent Al(2), and five equivalent Al(3) atoms. There is one shorter (2.67 Å) and two longer (2.83 Å) Al(3)-Al(2) bond lengths. There are a spread of Al(3)-Al(3) bond distances ranging from 2.64-2.92 Å. In the third Al site, Al(2) is bonded in a 12-coordinate geometry to two equivalent V(1), four equivalent Al(2), and six equivalent Al(3) atoms. All Al(2)-Al(2) bond lengths are 2.83 Å.