LiCeGe2 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 5-coordinate geometry to two equivalent Ge(1) and three equivalent Ge(2) atoms. Ce(1) is bonded in a 9-coordinate geometry to four equivalent Ge(2) and five equivalent Ge(1) atoms. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Li(1), five equivalent Ce(1), and two equivalent Ge(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Li(1), four equivalent Ce(1), and two equivalent Ge(1) atoms.
LiCeGe2 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a 5-coordinate geometry to two equivalent Ge(1) and three equivalent Ge(2) atoms. There is one shorter (2.56 Å) and one longer (2.74 Å) Li(1)-Ge(1) bond length. There is one shorter (2.63 Å) and two longer (2.64 Å) Li(1)-Ge(2) bond lengths. Ce(1) is bonded in a 9-coordinate geometry to four equivalent Ge(2) and five equivalent Ge(1) atoms. There are a spread of Ce(1)-Ge(2) bond distances ranging from 3.14-3.31 Å. There are a spread of Ce(1)-Ge(1) bond distances ranging from 3.11-3.42 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 9-coordinate geometry to two equivalent Li(1), five equivalent Ce(1), and two equivalent Ge(2) atoms. Both Ge(1)-Ge(2) bond lengths are 2.52 Å. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to three equivalent Li(1), four equivalent Ce(1), and two equivalent Ge(1) atoms.