K2InH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. In(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent H(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one In(1) atom. In the third Cl site, Cl(3) is bonded in a 5-coordinate geometry to four equivalent K(1) and one In(1) atom. In the fourth Cl site, Cl(4) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids.
K2InH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. There is one shorter (3.37 Å) and one longer (3.51 Å) K(1)-Cl(1) bond length. There is one shorter (3.40 Å) and one longer (3.50 Å) K(1)-Cl(2) bond length. There is one shorter (3.35 Å) and one longer (3.58 Å) K(1)-Cl(3) bond length. There is one shorter (3.42 Å) and one longer (3.45 Å) K(1)-Cl(4) bond length. In(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. The In(1)-O(1) bond length is 2.26 Å. The In(1)-Cl(1) bond length is 2.54 Å. The In(1)-Cl(3) bond length is 2.51 Å. The In(1)-Cl(4) bond length is 2.53 Å. Both In(1)-Cl(2) bond lengths are 2.53 Å. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. O(1) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent H(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one In(1) atom. In the third Cl site, Cl(3) is bonded in a 5-coordinate geometry to four equivalent K(1) and one In(1) atom. In the fourth Cl site, Cl(4) is bonded to four equivalent K(1) and one In(1) atom to form a mixture of distorted corner, face, and edge-sharing ClK4In square pyramids.