TaBr5 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of six TaBr5 clusters. Ta(1) is bonded to two equivalent Br(6), two equivalent Br(8), and two equivalent Br(9) atoms to form edge-sharing TaBr6 octahedra. There are three inequivalent Br sites. In the first Br site, Br(9) is bonded in a water-like geometry to two equivalent Ta(1) atoms. In the second Br site, Br(8) is bonded in a single-bond geometry to one Ta(1) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one Ta(1) atom.
TaBr5 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of six TaBr5 clusters. Ta(1) is bonded to two equivalent Br(6), two equivalent Br(8), and two equivalent Br(9) atoms to form edge-sharing TaBr6 octahedra. Both Ta(1)-Br(6) bond lengths are 2.48 Å. Both Ta(1)-Br(8) bond lengths are 2.42 Å. Both Ta(1)-Br(9) bond lengths are 2.72 Å. There are three inequivalent Br sites. In the first Br site, Br(9) is bonded in a water-like geometry to two equivalent Ta(1) atoms. In the second Br site, Br(8) is bonded in a single-bond geometry to one Ta(1) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one Ta(1) atom.