Cu2Te2O5Cl2 crystallizes in the tetragonal P-4 space group. Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(3), two equivalent O(2), and one Cl(1) atom. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cu(1) and two equivalent Te(1) atoms. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom.
Cu2Te2O5Cl2 crystallizes in the tetragonal P-4 space group. Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(3), two equivalent O(2), and one Cl(1) atom. The Cu(1)-O(3) bond length is 1.96 Å. There is one shorter (1.97 Å) and one longer (2.00 Å) Cu(1)-O(2) bond length. The Cu(1)-Cl(1) bond length is 2.24 Å. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. The Te(1)-O(1) bond length is 1.97 Å. The Te(1)-O(2) bond length is 1.94 Å. There is one shorter (1.91 Å) and one longer (2.53 Å) Te(1)-O(3) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cu(1) and two equivalent Te(1) atoms. Cl(1) is bonded in a single-bond geometry to one Cu(1) atom.