Sr2PdN2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded to five equivalent N(1) atoms to form a mixture of edge and corner-sharing SrN5 square pyramids. Pd(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to five equivalent Sr(1) and one Pd(1) atom to form a mixture of edge and corner-sharing NSr5Pd octahedra. The corner-sharing octahedral tilt angles range from 0-1°.
Sr2PdN2 crystallizes in the tetragonal I4/mmm space group. Sr(1) is bonded to five equivalent N(1) atoms to form a mixture of edge and corner-sharing SrN5 square pyramids. There is one shorter (2.63 Å) and four longer (2.72 Å) Sr(1)-N(1) bond lengths. Pd(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Pd(1)-N(1) bond lengths are 1.94 Å. N(1) is bonded to five equivalent Sr(1) and one Pd(1) atom to form a mixture of edge and corner-sharing NSr5Pd octahedra. The corner-sharing octahedral tilt angles range from 0-1°.