MnOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-63°. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Mn(1) atoms.
MnOF is Hydrophilite-derived structured and crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-63°. There are a spread of Mn(1)-O(1) bond distances ranging from 1.93-2.02 Å. There are a spread of Mn(1)-F(1) bond distances ranging from 2.00-2.15 Å. O(1) is bonded in a trigonal planar geometry to three equivalent Mn(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Mn(1) atoms.