RhZrSn crystallizes in the hexagonal P-62m space group. Zr(1) is bonded in a 11-coordinate geometry to one Rh(2), four equivalent Rh(1), and six equivalent Sn(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 9-coordinate geometry to three equivalent Zr(1) and six equivalent Sn(1) atoms. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent Zr(1) and three equivalent Sn(1) atoms. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.
RhZrSn crystallizes in the hexagonal P-62m space group. Zr(1) is bonded in a 11-coordinate geometry to one Rh(2), four equivalent Rh(1), and six equivalent Sn(1) atoms. The Zr(1)-Rh(2) bond length is 2.92 Å. All Zr(1)-Rh(1) bond lengths are 2.90 Å. There are two shorter (3.07 Å) and four longer (3.17 Å) Zr(1)-Sn(1) bond lengths. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 9-coordinate geometry to three equivalent Zr(1) and six equivalent Sn(1) atoms. All Rh(2)-Sn(1) bond lengths are 2.69 Å. In the second Rh site, Rh(1) is bonded in a 9-coordinate geometry to six equivalent Zr(1) and three equivalent Sn(1) atoms. All Rh(1)-Sn(1) bond lengths are 2.72 Å. Sn(1) is bonded in a 10-coordinate geometry to six equivalent Zr(1), two equivalent Rh(1), and two equivalent Rh(2) atoms.