TiAs is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent As(1) atoms to form a mixture of face, corner, and edge-sharing TiAs6 octahedra. The corner-sharing octahedral tilt angles are 48°. As(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing AsTi6 pentagonal pyramids.
TiAs is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent As(1) atoms to form a mixture of face, corner, and edge-sharing TiAs6 octahedra. The corner-sharing octahedral tilt angles are 48°. All Ti(1)-As(1) bond lengths are 2.60 Å. As(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing AsTi6 pentagonal pyramids.