Li7Co5O12 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the third Li site, Li(3) is bonded to one O(11), one O(21), one O(23), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(22), one O(24), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the fifth Li site, Li(5) is bonded to one O(1), one O(13), one O(15), one O(17), one O(19), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. In the sixth Li site, Li(6) is bonded to one O(14), one O(16), one O(18), one O(2), one O(20), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(13), one O(18), one O(23), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the eighth Li site, Li(8) is bonded to one O(12), one O(14), one O(17), one O(2), one O(24), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the ninth Li site, Li(9) is bonded to one O(1), one O(15), one O(20), one O(21), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. In the tenth Li site, Li(10) is bonded to one O(10), one O(16), one O(19), one O(2), one O(22), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the eleventh Li site, Li(11) is bonded to one O(15), one O(19), one O(22), one O(3), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the twelfth Li site, Li(12) is bonded to one O(10), one O(16), one O(20), one O(21), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(13), one O(17), one O(24), one O(3), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fourteenth Li site, Li(14) is bonded to one O(12), one O(14), one O(18), one O(23), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(18), one O(20), one O(21), one O(23), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the second Co site, Co(2) is bonded to one O(17), one O(19), one O(2), one O(22), one O(24), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the third Co site, Co(3) is bonded to one O(11), one O(16), one O(18), one O(21), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the fourth Co site, Co(4) is bonded to one O(12), one O(15), one O(17), one O(22), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the fifth Co site, Co(5) is bonded to one O(10), one O(14), one O(2), one O(20), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. In the sixth Co site, Co(6) is bonded to one O(10), one O(13), one O(19), one O(24), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the seventh Co site, Co(7) is bonded to one O(14), one O(20), one O(23), one O(6), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the eighth Co site, Co(8) is bonded to one O(1), one O(11), one O(15), one O(17), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. In the ninth Co site, Co(9) is bonded to one O(12), one O(16), one O(18), one O(2), one O(22), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. In the tenth Co site, Co(10) is bonded to one O(1), one O(13), one O(19), one O(23), one O(3), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(7), one Li(9), one Co(1), one Co(10), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the second O site, O(2) is bonded to one Li(10), one Li(6), one Li(8), one Co(2), one Co(5), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the third O site, O(3) is bonded to one Li(11), one Li(13), one Li(3), one Co(10), one Co(2), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the fourth O site, O(4) is bonded to one Li(12), one Li(14), one Li(4), one Co(1), one Co(5), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra, and  an edgeedge with one O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(11), one Li(13), one Li(4), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the sixth O site, O(6) is bonded to one Li(12), one Li(14), one Li(2), one Li(3), one Co(3), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh O site, O(7) is bonded to one Li(1), one Li(6), one Li(7), one Li(9), one Co(3), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the eighth O site, O(8) is bonded to one Li(10), one Li(2), one Li(5), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra, and  an edgeedge with one O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. In the ninth O site, O(9) is bonded to one Li(1), one Li(11), one Li(3), one Li(9), one Co(10), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the tenth O site, O(10) is bonded to one Li(10), one Li(12), one Li(2), one Li(4), one Co(5), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(13), one Li(3), one Li(7), one Co(3), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the twelfth O site, O(12) is bonded to one Li(14), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(13), one Li(5), one Li(7), one Co(10), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the fourteenth O site, O(14) is bonded to one Li(14), one Li(2), one Li(6), one Li(8), one Co(5), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(11), one Li(5), one Li(9), one Co(4), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(12), one Li(2), one Li(6), one Co(3), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the seventeenth O site, O(17) is bonded to one Li(13), one Li(5), one Li(8), one Co(2), one Co(4), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the eighteenth O site, O(18) is bonded to one Li(14), one Li(6), one Li(7), one Co(1), one Co(3), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(11), one Li(5), one Co(10), one Co(2), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the twentieth O site, O(20) is bonded to one Li(12), one Li(6), one Li(9), one Co(1), one Co(5), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-first O site, O(21) is bonded to one Li(12), one Li(3), one Li(9), one Co(1), one Co(3), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(11), one Li(4), one Co(2), one Co(4), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the twenty-third O site, O(23) is bonded to one Li(14), one Li(3), one Li(7), one Co(1), one Co(10), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the twenty-fourth O site, O(24) is bonded to one Li(13), one Li(4), one Li(8), one Co(2), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°.
Li7Co5O12 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(15), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. The Li(1)-O(11) bond length is 2.06 Å. The Li(1)-O(13) bond length is 2.08 Å. The Li(1)-O(15) bond length is 2.07 Å. The Li(1)-O(5) bond length is 2.05 Å. The Li(1)-O(7) bond length is 2.15 Å. The Li(1)-O(9) bond length is 2.10 Å. In the second Li site, Li(2) is bonded to one O(10), one O(12), one O(14), one O(16), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Li(2)-O(10) bond length is 2.04 Å. The Li(2)-O(12) bond length is 2.10 Å. The Li(2)-O(14) bond length is 2.07 Å. The Li(2)-O(16) bond length is 2.08 Å. The Li(2)-O(6) bond length is 2.10 Å. The Li(2)-O(8) bond length is 2.02 Å. In the third Li site, Li(3) is bonded to one O(11), one O(21), one O(23), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-13°. The Li(3)-O(11) bond length is 2.01 Å. The Li(3)-O(21) bond length is 2.30 Å. The Li(3)-O(23) bond length is 2.24 Å. The Li(3)-O(3) bond length is 2.26 Å. The Li(3)-O(6) bond length is 2.04 Å. The Li(3)-O(9) bond length is 2.04 Å. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(22), one O(24), one O(4), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Li(4)-O(10) bond length is 2.19 Å. The Li(4)-O(12) bond length is 2.05 Å. The Li(4)-O(22) bond length is 2.20 Å. The Li(4)-O(24) bond length is 2.17 Å. The Li(4)-O(4) bond length is 2.18 Å. The Li(4)-O(5) bond length is 2.00 Å. In the fifth Li site, Li(5) is bonded to one O(1), one O(13), one O(15), one O(17), one O(19), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Li(5)-O(1) bond length is 2.20 Å. The Li(5)-O(13) bond length is 2.06 Å. The Li(5)-O(15) bond length is 2.06 Å. The Li(5)-O(17) bond length is 2.19 Å. The Li(5)-O(19) bond length is 2.22 Å. The Li(5)-O(8) bond length is 2.01 Å. In the sixth Li site, Li(6) is bonded to one O(14), one O(16), one O(18), one O(2), one O(20), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. The Li(6)-O(14) bond length is 2.14 Å. The Li(6)-O(16) bond length is 2.04 Å. The Li(6)-O(18) bond length is 2.24 Å. The Li(6)-O(2) bond length is 2.19 Å. The Li(6)-O(20) bond length is 2.25 Å. The Li(6)-O(7) bond length is 2.02 Å. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(13), one O(18), one O(23), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Li(7)-O(1) bond length is 2.14 Å. The Li(7)-O(11) bond length is 2.04 Å. The Li(7)-O(13) bond length is 2.16 Å. The Li(7)-O(18) bond length is 2.12 Å. The Li(7)-O(23) bond length is 2.07 Å. The Li(7)-O(7) bond length is 2.18 Å. In the eighth Li site, Li(8) is bonded to one O(12), one O(14), one O(17), one O(2), one O(24), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. The Li(8)-O(12) bond length is 2.07 Å. The Li(8)-O(14) bond length is 2.22 Å. The Li(8)-O(17) bond length is 2.06 Å. The Li(8)-O(2) bond length is 2.24 Å. The Li(8)-O(24) bond length is 2.08 Å. The Li(8)-O(8) bond length is 2.09 Å. In the ninth Li site, Li(9) is bonded to one O(1), one O(15), one O(20), one O(21), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. The Li(9)-O(1) bond length is 2.13 Å. The Li(9)-O(15) bond length is 2.09 Å. The Li(9)-O(20) bond length is 2.23 Å. The Li(9)-O(21) bond length is 2.09 Å. The Li(9)-O(7) bond length is 2.21 Å. The Li(9)-O(9) bond length is 2.02 Å. In the tenth Li site, Li(10) is bonded to one O(10), one O(16), one O(19), one O(2), one O(22), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. The Li(10)-O(10) bond length is 2.11 Å. The Li(10)-O(16) bond length is 2.23 Å. The Li(10)-O(19) bond length is 2.07 Å. The Li(10)-O(2) bond length is 2.09 Å. The Li(10)-O(22) bond length is 2.20 Å. The Li(10)-O(8) bond length is 2.08 Å. In the eleventh Li site, Li(11) is bonded to one O(15), one O(19), one O(22), one O(3), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. The Li(11)-O(15) bond length is 2.08 Å. The Li(11)-O(19) bond length is 2.22 Å. The Li(11)-O(22) bond length is 2.08 Å. The Li(11)-O(3) bond length is 2.07 Å. The Li(11)-O(5) bond length is 2.08 Å. The Li(11)-O(9) bond length is 2.28 Å. In the twelfth Li site, Li(12) is bonded to one O(10), one O(16), one O(20), one O(21), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. The Li(12)-O(10) bond length is 2.14 Å. The Li(12)-O(16) bond length is 2.04 Å. The Li(12)-O(20) bond length is 2.04 Å. The Li(12)-O(21) bond length is 2.11 Å. The Li(12)-O(4) bond length is 2.23 Å. The Li(12)-O(6) bond length is 2.17 Å. In the thirteenth Li site, Li(13) is bonded to one O(11), one O(13), one O(17), one O(24), one O(3), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. The Li(13)-O(11) bond length is 2.21 Å. The Li(13)-O(13) bond length is 2.09 Å. The Li(13)-O(17) bond length is 2.18 Å. The Li(13)-O(24) bond length is 2.21 Å. The Li(13)-O(3) bond length is 2.07 Å. The Li(13)-O(5) bond length is 2.10 Å. In the fourteenth Li site, Li(14) is bonded to one O(12), one O(14), one O(18), one O(23), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. The Li(14)-O(12) bond length is 2.18 Å. The Li(14)-O(14) bond length is 2.06 Å. The Li(14)-O(18) bond length is 2.07 Å. The Li(14)-O(23) bond length is 2.08 Å. The Li(14)-O(4) bond length is 2.13 Å. The Li(14)-O(6) bond length is 2.15 Å. There are ten inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(18), one O(20), one O(21), one O(23), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. The Co(1)-O(1) bond length is 1.94 Å. The Co(1)-O(18) bond length is 2.02 Å. The Co(1)-O(20) bond length is 2.06 Å. The Co(1)-O(21) bond length is 2.02 Å. The Co(1)-O(23) bond length is 2.03 Å. The Co(1)-O(4) bond length is 2.01 Å. In the second Co site, Co(2) is bonded to one O(17), one O(19), one O(2), one O(22), one O(24), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. The Co(2)-O(17) bond length is 1.93 Å. The Co(2)-O(19) bond length is 1.89 Å. The Co(2)-O(2) bond length is 1.92 Å. The Co(2)-O(22) bond length is 1.90 Å. The Co(2)-O(24) bond length is 1.94 Å. The Co(2)-O(3) bond length is 1.89 Å. In the third Co site, Co(3) is bonded to one O(11), one O(16), one O(18), one O(21), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. The Co(3)-O(11) bond length is 1.90 Å. The Co(3)-O(16) bond length is 1.90 Å. The Co(3)-O(18) bond length is 1.94 Å. The Co(3)-O(21) bond length is 1.92 Å. The Co(3)-O(6) bond length is 1.86 Å. The Co(3)-O(7) bond length is 1.93 Å. In the fourth Co site, Co(4) is bonded to one O(12), one O(15), one O(17), one O(22), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. The Co(4)-O(12) bond length is 1.96 Å. The Co(4)-O(15) bond length is 1.97 Å. The Co(4)-O(17) bond length is 1.98 Å. The Co(4)-O(22) bond length is 1.98 Å. The Co(4)-O(5) bond length is 1.93 Å. The Co(4)-O(8) bond length is 1.93 Å. In the fifth Co site, Co(5) is bonded to one O(10), one O(14), one O(2), one O(20), one O(24), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-9°. The Co(5)-O(10) bond length is 1.85 Å. The Co(5)-O(14) bond length is 1.86 Å. The Co(5)-O(2) bond length is 1.92 Å. The Co(5)-O(20) bond length is 1.93 Å. The Co(5)-O(24) bond length is 1.93 Å. The Co(5)-O(4) bond length is 1.95 Å. In the sixth Co site, Co(6) is bonded to one O(10), one O(13), one O(19), one O(24), one O(5), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Co(6)-O(10) bond length is 1.94 Å. The Co(6)-O(13) bond length is 1.97 Å. The Co(6)-O(19) bond length is 1.97 Å. The Co(6)-O(24) bond length is 1.97 Å. The Co(6)-O(5) bond length is 1.93 Å. The Co(6)-O(8) bond length is 1.92 Å. In the seventh Co site, Co(7) is bonded to one O(14), one O(20), one O(23), one O(6), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. The Co(7)-O(14) bond length is 1.94 Å. The Co(7)-O(20) bond length is 1.94 Å. The Co(7)-O(23) bond length is 1.94 Å. The Co(7)-O(6) bond length is 1.92 Å. The Co(7)-O(7) bond length is 1.84 Å. The Co(7)-O(9) bond length is 1.85 Å. In the eighth Co site, Co(8) is bonded to one O(1), one O(11), one O(15), one O(17), one O(21), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. The Co(8)-O(1) bond length is 2.09 Å. The Co(8)-O(11) bond length is 1.97 Å. The Co(8)-O(15) bond length is 1.87 Å. The Co(8)-O(17) bond length is 2.03 Å. The Co(8)-O(21) bond length is 2.06 Å. The Co(8)-O(3) bond length is 2.07 Å. In the ninth Co site, Co(9) is bonded to one O(12), one O(16), one O(18), one O(2), one O(22), and one O(4) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-15°. The Co(9)-O(12) bond length is 1.85 Å. The Co(9)-O(16) bond length is 1.96 Å. The Co(9)-O(18) bond length is 2.01 Å. The Co(9)-O(2) bond length is 2.11 Å. The Co(9)-O(22) bond length is 2.03 Å. The Co(9)-O(4) bond length is 2.09 Å. In the tenth Co site, Co(10) is bonded to one O(1), one O(13), one O(19), one O(23), one O(3), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. The Co(10)-O(1) bond length is 2.06 Å. The Co(10)-O(13) bond length is 1.86 Å. The Co(10)-O(19) bond length is 2.05 Å. The Co(10)-O(23) bond length is 2.02 Å. The Co(10)-O(3) bond length is 2.07 Å. The Co(10)-O(9) bond length is 2.00 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(5), one Li(7), one Li(9), one Co(1), one Co(10), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the second O site, O(2) is bonded to one Li(10), one Li(6), one Li(8), one Co(2), one Co(5), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the third O site, O(3) is bonded to one Li(11), one Li(13), one Li(3), one Co(10), one Co(2), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the fourth O site, O(4) is bonded to one Li(12), one Li(14), one Li(4), one Co(1), one Co(5), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra, and  an edgeedge with one O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth O site, O(5) is bonded to one Li(1), one Li(11), one Li(13), one Li(4), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the sixth O site, O(6) is bonded to one Li(12), one Li(14), one Li(2), one Li(3), one Co(3), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-6°. In the seventh O site, O(7) is bonded to one Li(1), one Li(6), one Li(7), one Li(9), one Co(3), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the eighth O site, O(8) is bonded to one Li(10), one Li(2), one Li(5), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra, and  an edgeedge with one O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-3°. In the ninth O site, O(9) is bonded to one Li(1), one Li(11), one Li(3), one Li(9), one Co(10), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the tenth O site, O(10) is bonded to one Li(10), one Li(12), one Li(2), one Li(4), one Co(5), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(13), one Li(3), one Li(7), one Co(3), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the twelfth O site, O(12) is bonded to one Li(14), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the thirteenth O site, O(13) is bonded to one Li(1), one Li(13), one Li(5), one Li(7), one Co(10), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-8°. In the fourteenth O site, O(14) is bonded to one Li(14), one Li(2), one Li(6), one Li(8), one Co(5), and one Co(7) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(11), one Li(5), one Li(9), one Co(4), and one Co(8) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(12), one Li(2), one Li(6), one Co(3), and one Co(9) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the seventeenth O site, O(17) is bonded to one Li(13), one Li(5), one Li(8), one Co(2), one Co(4), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the eighteenth O site, O(18) is bonded to one Li(14), one Li(6), one Li(7), one Co(1), one Co(3), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, and  an edgeedge with one O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the nineteenth O site, O(19) is bonded to one Li(10), one Li(11), one Li(5), one Co(10), one Co(2), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(22)Li3Co3 octahedra,  a cornercorner with one O(23)Li3Co3 octahedra,  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(13)Li4Co2 octahedra,  a cornercorner with one O(16)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the twentieth O site, O(20) is bonded to one Li(12), one Li(6), one Li(9), one Co(1), one Co(5), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(21)Li3Co3 octahedra,  a cornercorner with one O(24)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra,  a cornercorner with one O(14)Li4Co2 octahedra,  a cornercorner with one O(15)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the twenty-first O site, O(21) is bonded to one Li(12), one Li(3), one Li(9), one Co(1), one Co(3), and one Co(8) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(23)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the twenty-second O site, O(22) is bonded to one Li(10), one Li(11), one Li(4), one Co(2), one Co(4), and one Co(9) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(24)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(15)Li4Co2 octahedra,  an edgeedge with one O(16)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the twenty-third O site, O(23) is bonded to one Li(14), one Li(3), one Li(7), one Co(1), one Co(10), and one Co(7) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co3 octahedra,  a cornercorner with one O(18)Li3Co3 octahedra,  a cornercorner with one O(19)Li3Co3 octahedra,  a cornercorner with one O(12)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  a cornercorner with one O(9)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Co3 octahedra,  an edgeedge with one O(18)Li3Co3 octahedra,  an edgeedge with one O(20)Li3Co3 octahedra,  an edgeedge with one O(21)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(11)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, and  an edgeedge with one O(9)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the twenty-fourth O site, O(24) is bonded to one Li(13), one Li(4), one Li(8), one Co(2), one Co(5), and one Co(6) atom to form OLi3Co3 octahedra that share  a cornercorner with one O(17)Li3Co3 octahedra,  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(20)Li3Co3 octahedra,  a cornercorner with one O(10)Li4Co2 octahedra,  a cornercorner with one O(11)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(17)Li3Co3 octahedra,  an edgeedge with one O(19)Li3Co3 octahedra,  an edgeedge with one O(2)Li3Co3 octahedra,  an edgeedge with one O(22)Li3Co3 octahedra,  an edgeedge with one O(3)Li3Co3 octahedra,  an edgeedge with one O(4)Li3Co3 octahedra,  an edgeedge with one O(10)Li4Co2 octahedra,  an edgeedge with one O(12)Li4Co2 octahedra,  an edgeedge with one O(13)Li4Co2 octahedra,  an edgeedge with one O(14)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, and  an edgeedge with one O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°.