LiMnPO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Mn(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. Mn(1) is bonded to four equivalent O(1) atoms to form distorted MnO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Mn(1)O4 tetrahedra. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom.
LiMnPO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Mn(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. All Li(1)-O(1) bond lengths are 2.04 Å. Mn(1) is bonded to four equivalent O(1) atoms to form distorted MnO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. All Mn(1)-O(1) bond lengths are 2.07 Å. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Mn(1)O4 tetrahedra. All P(1)-O(1) bond lengths are 1.56 Å. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom.