OsCl6(IrN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two hexachloro osmium molecules, and four IrN3Cl2 clusters. In each IrN3Cl2 cluster, Ir(1) is bonded in a tetrahedral geometry to one N(1), two equivalent N(2), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(5) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom.
OsCl6(IrN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two hexachloro osmium molecules, and four IrN3Cl2 clusters. In each IrN3Cl2 cluster, Ir(1) is bonded in a tetrahedral geometry to one N(1), two equivalent N(2), and one Cl(2) atom. The Ir(1)-N(1) bond length is 2.00 Å. Both Ir(1)-N(2) bond lengths are 1.73 Å. The Ir(1)-Cl(2) bond length is 2.27 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(5) atom. The N(1)-Cl(5) bond length is 1.67 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one N(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom.