BiH(NO3)3(H2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 atoms and two BiH(NO3)3 clusters. In each BiH(NO3)3 cluster, Bi(1) is bonded in a 6-coordinate geometry to one H(1), one O(1), one O(2), one O(4), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(7), and one O(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. H(1) is bonded in a single-bond geometry to one Bi(1) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(9) is bonded in a distorted single-bond geometry to one Bi(1) and one N(2) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Bi(1) and one N(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In the sixth O site, O(4) is bonded in a distorted water-like geometry to one Bi(1) and one N(3) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the eighth O site, O(6) is bonded in a distorted water-like geometry to one Bi(1) and one N(1) atom. In the ninth O site, O(7) is bonded in a single-bond geometry to one N(2) atom.
BiH(NO3)3(H2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 atoms and two BiH(NO3)3 clusters. In each BiH(NO3)3 cluster, Bi(1) is bonded in a 6-coordinate geometry to one H(1), one O(1), one O(2), one O(4), one O(6), and one O(9) atom. The Bi(1)-H(1) bond length is 1.89 Å. The Bi(1)-O(1) bond length is 2.40 Å. The Bi(1)-O(2) bond length is 2.49 Å. The Bi(1)-O(4) bond length is 2.54 Å. The Bi(1)-O(6) bond length is 2.37 Å. The Bi(1)-O(9) bond length is 2.54 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(8) atom. The N(1)-O(2) bond length is 1.29 Å. The N(1)-O(6) bond length is 1.31 Å. The N(1)-O(8) bond length is 1.22 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(7), and one O(9) atom. The N(2)-O(1) bond length is 1.31 Å. The N(2)-O(7) bond length is 1.22 Å. The N(2)-O(9) bond length is 1.29 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. The N(3)-O(3) bond length is 1.24 Å. The N(3)-O(4) bond length is 1.30 Å. The N(3)-O(5) bond length is 1.25 Å. H(1) is bonded in a single-bond geometry to one Bi(1) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(9) is bonded in a distorted single-bond geometry to one Bi(1) and one N(2) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Bi(1) and one N(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In the sixth O site, O(4) is bonded in a distorted water-like geometry to one Bi(1) and one N(3) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the eighth O site, O(6) is bonded in a distorted water-like geometry to one Bi(1) and one N(1) atom. In the ninth O site, O(7) is bonded in a single-bond geometry to one N(2) atom.