C6F5 crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of forty-eight fluoromethane molecules and eight C3F2 clusters. In each C3F2 cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one F(3) atom. In the second C site, C(4) is bonded in a single-bond geometry to one C(5) and one F(1) atom. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(4) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(1) atom.
C6F5 crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of forty-eight fluoromethane molecules and eight C3F2 clusters. In each C3F2 cluster, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one F(3) atom. The C(1)-C(5) bond length is 1.40 Å. The C(1)-F(3) bond length is 1.35 Å. In the second C site, C(4) is bonded in a single-bond geometry to one C(5) and one F(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-F(1) bond length is 1.35 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. The C(5)-C(5) bond length is 1.47 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(4) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(1) atom.