Sc3V2Si3 crystallizes in the hexagonal P6_3/mcm space group. Sc(1) is bonded in a 5-coordinate geometry to four equivalent V(1) and five equivalent Si(1) atoms. V(1) is bonded in a 14-coordinate geometry to six equivalent Sc(1), two equivalent V(1), and six equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to five equivalent Sc(1) and four equivalent V(1) atoms.
Sc3V2Si3 crystallizes in the hexagonal P6_3/mcm space group. Sc(1) is bonded in a 5-coordinate geometry to four equivalent V(1) and five equivalent Si(1) atoms. All Sc(1)-V(1) bond lengths are 3.21 Å. There are a spread of Sc(1)-Si(1) bond distances ranging from 2.67-2.86 Å. V(1) is bonded in a 14-coordinate geometry to six equivalent Sc(1), two equivalent V(1), and six equivalent Si(1) atoms. Both V(1)-V(1) bond lengths are 2.59 Å. All V(1)-Si(1) bond lengths are 2.66 Å. Si(1) is bonded in a 9-coordinate geometry to five equivalent Sc(1) and four equivalent V(1) atoms.