NaTm(Pd3O4)2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Tm(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to one Na(1), one Tm(1), and three equivalent Pd(1) atoms to form a mixture of edge and corner-sharing ONaTmPd3 trigonal bipyramids.
NaTm(Pd3O4)2 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Na(1)-O(1) bond lengths are 2.60 Å. Tm(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. All Tm(1)-O(1) bond lengths are 2.37 Å. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Pd(1)-O(1) bond lengths are 2.03 Å. O(1) is bonded to one Na(1), one Tm(1), and three equivalent Pd(1) atoms to form a mixture of edge and corner-sharing ONaTmPd3 trigonal bipyramids.