NSCl is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two NSCl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent N(2) and one Cl(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(2) atom.
NSCl is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two NSCl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. Both N(1)-S(2) bond lengths are 1.61 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. The N(2)-S(1) bond length is 1.61 Å. The N(2)-S(2) bond length is 1.61 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent N(2) and one Cl(1) atom. The S(1)-Cl(1) bond length is 2.15 Å. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. The S(2)-Cl(2) bond length is 2.18 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(2) atom.