CuF2 crystallizes in the monoclinic P2_1/c space group. Cu(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Cu(1) atoms.
CuF2 crystallizes in the monoclinic P2_1/c space group. Cu(1) is bonded to six equivalent F(1) atoms to form a mixture of corner and edge-sharing CuF6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are a spread of Cu(1)-F(1) bond distances ranging from 1.91-2.28 Å. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Cu(1) atoms.