TiS is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent S(1) atoms to form a mixture of corner, edge, and face-sharing TiS6 octahedra. The corner-sharing octahedral tilt angles are 45°. S(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing STi6 pentagonal pyramids.
TiS is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. Ti(1) is bonded to six equivalent S(1) atoms to form a mixture of corner, edge, and face-sharing TiS6 octahedra. The corner-sharing octahedral tilt angles are 45°. All Ti(1)-S(1) bond lengths are 2.48 Å. S(1) is bonded to six equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing STi6 pentagonal pyramids.