Zn(WO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra and edges with six equivalent W(1)O6 octahedra. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. O(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent W(1) and one Zn(1) atom.
Zn(WO2)2 is Spinel structured and crystallizes in the cubic Fd-3m space group. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra and edges with six equivalent W(1)O6 octahedra. All W(1)-O(1) bond lengths are 2.20 Å. Zn(1) is bonded to four equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with twelve equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Zn(1)-O(1) bond lengths are 2.07 Å. O(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent W(1) and one Zn(1) atom.