Cd(OH)F crystallizes in the monoclinic P2_1 space group. Cd(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing CdO3F3 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent Cd(1) and one H(1) atom. F(1) is bonded in a 3-coordinate geometry to three equivalent Cd(1) atoms.
Cd(OH)F crystallizes in the monoclinic P2_1 space group. Cd(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of corner and edge-sharing CdO3F3 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. There are two shorter (2.28 Å) and one longer (2.29 Å) Cd(1)-O(1) bond length. There is one shorter (2.36 Å) and two longer (2.39 Å) Cd(1)-F(1) bond lengths. H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent Cd(1) and one H(1) atom. F(1) is bonded in a 3-coordinate geometry to three equivalent Cd(1) atoms.