CP3(NCl3)3SbCl6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CP3(NCl3)3 clusters and two SbCl6 clusters. In each CP3(NCl3)3 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one N(2), one Cl(11), one Cl(12), and one Cl(6) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one N(3), one Cl(15), one Cl(8), and one Cl(9) atom. In the third P site, P(3) is bonded in a tetrahedral geometry to one N(1), one Cl(10), one Cl(2), and one Cl(7) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one P(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(15) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(3) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one P(3) atom. In the fifth Cl site, Cl(8) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(9) is bonded in a single-bond geometry to one P(2) atom. In the seventh Cl site, Cl(10) is bonded in a single-bond geometry to one P(3) atom. In the eighth Cl site, Cl(11) is bonded in a single-bond geometry to one P(1) atom. In the ninth Cl site, Cl(12) is bonded in a single-bond geometry to one P(1) atom. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(1), one Cl(13), one Cl(14), one Cl(3), one Cl(4), and one Cl(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(1) atom.
CP3(NCl3)3SbCl6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CP3(NCl3)3 clusters and two SbCl6 clusters. In each CP3(NCl3)3 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.35 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one N(2), one Cl(11), one Cl(12), and one Cl(6) atom. The P(1)-N(2) bond length is 1.56 Å. The P(1)-Cl(11) bond length is 1.96 Å. The P(1)-Cl(12) bond length is 1.98 Å. The P(1)-Cl(6) bond length is 1.98 Å. In the second P site, P(2) is bonded in a tetrahedral geometry to one N(3), one Cl(15), one Cl(8), and one Cl(9) atom. The P(2)-N(3) bond length is 1.57 Å. The P(2)-Cl(15) bond length is 1.97 Å. The P(2)-Cl(8) bond length is 1.97 Å. The P(2)-Cl(9) bond length is 1.98 Å. In the third P site, P(3) is bonded in a tetrahedral geometry to one N(1), one Cl(10), one Cl(2), and one Cl(7) atom. The P(3)-N(1) bond length is 1.57 Å. The P(3)-Cl(10) bond length is 1.98 Å. The P(3)-Cl(2) bond length is 1.97 Å. The P(3)-Cl(7) bond length is 1.98 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one P(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(15) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(3) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one P(3) atom. In the fifth Cl site, Cl(8) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(9) is bonded in a single-bond geometry to one P(2) atom. In the seventh Cl site, Cl(10) is bonded in a single-bond geometry to one P(3) atom. In the eighth Cl site, Cl(11) is bonded in a single-bond geometry to one P(1) atom. In the ninth Cl site, Cl(12) is bonded in a single-bond geometry to one P(1) atom. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(1), one Cl(13), one Cl(14), one Cl(3), one Cl(4), and one Cl(5) atom. The Sb(1)-Cl(1) bond length is 2.40 Å. The Sb(1)-Cl(13) bond length is 2.41 Å. The Sb(1)-Cl(14) bond length is 2.41 Å. The Sb(1)-Cl(3) bond length is 2.38 Å. The Sb(1)-Cl(4) bond length is 2.38 Å. The Sb(1)-Cl(5) bond length is 2.39 Å. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(1) atom.