LiVWTe2O12 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. V(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-36°. W(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-39°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-39°. In the second Te site, Te(2) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-37°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Te(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one Te(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Li(1), one V(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one Te(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a T-shaped geometry to one Li(1), one V(1), and one Te(2) atom.
LiVWTe2O12 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. The Li(1)-O(1) bond length is 1.99 Å. The Li(1)-O(11) bond length is 2.01 Å. The Li(1)-O(12) bond length is 2.27 Å. The Li(1)-O(3) bond length is 2.05 Å. The Li(1)-O(4) bond length is 2.27 Å. The Li(1)-O(7) bond length is 2.39 Å. V(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-36°. The V(1)-O(1) bond length is 1.97 Å. The V(1)-O(12) bond length is 1.88 Å. The V(1)-O(4) bond length is 1.94 Å. The V(1)-O(6) bond length is 1.84 Å. The V(1)-O(7) bond length is 2.01 Å. The V(1)-O(9) bond length is 1.83 Å. W(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Te(2)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-39°. The W(1)-O(10) bond length is 1.91 Å. The W(1)-O(11) bond length is 1.96 Å. The W(1)-O(2) bond length is 1.89 Å. The W(1)-O(3) bond length is 1.97 Å. The W(1)-O(5) bond length is 1.92 Å. The W(1)-O(8) bond length is 1.93 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-39°. The Te(1)-O(10) bond length is 1.94 Å. The Te(1)-O(3) bond length is 1.95 Å. The Te(1)-O(5) bond length is 1.95 Å. The Te(1)-O(6) bond length is 1.95 Å. The Te(1)-O(7) bond length is 1.90 Å. The Te(1)-O(8) bond length is 1.94 Å. In the second Te site, Te(2) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-37°. The Te(2)-O(1) bond length is 1.92 Å. The Te(2)-O(11) bond length is 1.96 Å. The Te(2)-O(12) bond length is 1.94 Å. The Te(2)-O(2) bond length is 1.93 Å. The Te(2)-O(4) bond length is 1.92 Å. The Te(2)-O(9) bond length is 1.96 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Te(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one Te(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Li(1), one V(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one Te(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a T-shaped geometry to one Li(1), one V(1), and one Te(2) atom.