PdAg2H6S2(NO3)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent S(1) atoms. Ag(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted corner-sharing AgO4 trigonal pyramids. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one S(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one S(1) atom.
PdAg2H6S2(NO3)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent S(1) atoms. Both Pd(1)-N(1) bond lengths are 2.08 Å. Both Pd(1)-S(1) bond lengths are 2.33 Å. Ag(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted corner-sharing AgO4 trigonal pyramids. The Ag(1)-O(2) bond length is 2.35 Å. The Ag(1)-O(3) bond length is 2.49 Å. There is one shorter (2.34 Å) and one longer (2.51 Å) Ag(1)-O(1) bond length. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), one H(2), and one H(3) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.03 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.53 Å. The S(1)-O(2) bond length is 1.51 Å. The S(1)-O(3) bond length is 1.51 Å. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one S(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one S(1) atom.