Re3Se4O2F(O2)3 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of twelve hydrogen peroxide molecules and two Re3Se4O2F clusters. In each Re3Se4O2F cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one Se(1), one Se(2), two equivalent Se(4), and one F(1) atom. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one Se(1), one Se(2), two equivalent Se(3), and one O(7) atom. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one Se(1), one Se(2), one Se(3), one Se(4), and one O(8) atom. There are four inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second Se site, Se(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third Se site, Se(3) is bonded in a distorted T-shaped geometry to one Re(3) and two equivalent Re(2) atoms. In the fourth Se site, Se(4) is bonded in a 3-coordinate geometry to one Re(3) and two equivalent Re(1) atoms. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Re(3) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom.
Re3Se4O2F(O2)3 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of twelve hydrogen peroxide molecules and two Re3Se4O2F clusters. In each Re3Se4O2F cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a distorted single-bond geometry to one Se(1), one Se(2), two equivalent Se(4), and one F(1) atom. The Re(1)-Se(1) bond length is 2.53 Å. The Re(1)-Se(2) bond length is 2.51 Å. There is one shorter (2.54 Å) and one longer (2.56 Å) Re(1)-Se(4) bond length. The Re(1)-F(1) bond length is 1.99 Å. In the second Re site, Re(2) is bonded in a distorted single-bond geometry to one Se(1), one Se(2), two equivalent Se(3), and one O(7) atom. The Re(2)-Se(1) bond length is 2.53 Å. The Re(2)-Se(2) bond length is 2.53 Å. There is one shorter (2.49 Å) and one longer (2.64 Å) Re(2)-Se(3) bond length. The Re(2)-O(7) bond length is 1.73 Å. In the third Re site, Re(3) is bonded in a distorted single-bond geometry to one Se(1), one Se(2), one Se(3), one Se(4), and one O(8) atom. The Re(3)-Se(1) bond length is 2.59 Å. The Re(3)-Se(2) bond length is 2.60 Å. The Re(3)-Se(3) bond length is 2.52 Å. The Re(3)-Se(4) bond length is 2.52 Å. The Re(3)-O(8) bond length is 1.74 Å. There are four inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. In the second Se site, Se(2) is bonded in a distorted T-shaped geometry to one Re(1), one Re(2), and one Re(3) atom. In the third Se site, Se(3) is bonded in a distorted T-shaped geometry to one Re(3) and two equivalent Re(2) atoms. In the fourth Se site, Se(4) is bonded in a 3-coordinate geometry to one Re(3) and two equivalent Re(1) atoms. There are two inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Re(3) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom.