LiLu2W2(O4Cl)2 crystallizes in the triclinic P1 space group. Li(1) is bonded to one O(3), one O(5), one O(6), and one Cl(2) atom to form distorted LiClO3 tetrahedra that share  a cornercorner with one W(1)O4 tetrahedra and corners with two equivalent W(2)O4 tetrahedra. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(5), one O(7), one O(8), one Cl(1), and one Cl(2) atom. In the second Lu site, Lu(2) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(6), one O(7), one O(8), and one Cl(1) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(4), one O(6), and one O(7) atom to form WO4 tetrahedra that share  a cornercorner with one Li(1)ClO3 tetrahedra. In the second W site, W(2) is bonded to one O(2), one O(3), one O(5), and one O(8) atom to form WO4 tetrahedra that share corners with two equivalent Li(1)ClO3 tetrahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Lu(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Lu(2) and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Lu(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Lu(2) and one W(1) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one Lu(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one Lu(2), and one W(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Lu(1), one Lu(2), and one W(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Lu(1) and one Lu(2) atom. In the second Cl site, Cl(2) is bonded in a distorted water-like geometry to one Li(1) and one Lu(1) atom.
LiLu2W2(O4Cl)2 crystallizes in the triclinic P1 space group. Li(1) is bonded to one O(3), one O(5), one O(6), and one Cl(2) atom to form distorted LiClO3 tetrahedra that share  a cornercorner with one W(1)O4 tetrahedra and corners with two equivalent W(2)O4 tetrahedra. The Li(1)-O(3) bond length is 1.87 Å. The Li(1)-O(5) bond length is 1.89 Å. The Li(1)-O(6) bond length is 2.06 Å. The Li(1)-Cl(2) bond length is 2.21 Å. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(5), one O(7), one O(8), one Cl(1), and one Cl(2) atom. The Lu(1)-O(1) bond length is 2.24 Å. The Lu(1)-O(3) bond length is 2.33 Å. The Lu(1)-O(5) bond length is 2.18 Å. The Lu(1)-O(7) bond length is 2.40 Å. The Lu(1)-O(8) bond length is 2.23 Å. The Lu(1)-Cl(1) bond length is 2.80 Å. The Lu(1)-Cl(2) bond length is 2.66 Å. In the second Lu site, Lu(2) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(6), one O(7), one O(8), and one Cl(1) atom. The Lu(2)-O(2) bond length is 2.09 Å. The Lu(2)-O(4) bond length is 2.27 Å. The Lu(2)-O(6) bond length is 2.27 Å. The Lu(2)-O(7) bond length is 2.23 Å. The Lu(2)-O(8) bond length is 2.30 Å. The Lu(2)-Cl(1) bond length is 2.67 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(4), one O(6), and one O(7) atom to form WO4 tetrahedra that share  a cornercorner with one Li(1)ClO3 tetrahedra. The W(1)-O(1) bond length is 1.80 Å. The W(1)-O(4) bond length is 1.80 Å. The W(1)-O(6) bond length is 1.83 Å. The W(1)-O(7) bond length is 1.86 Å. In the second W site, W(2) is bonded to one O(2), one O(3), one O(5), and one O(8) atom to form WO4 tetrahedra that share corners with two equivalent Li(1)ClO3 tetrahedra. The W(2)-O(2) bond length is 1.85 Å. The W(2)-O(3) bond length is 1.88 Å. The W(2)-O(5) bond length is 1.89 Å. The W(2)-O(8) bond length is 1.94 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Lu(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Lu(2) and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Lu(1), and one W(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Lu(2) and one W(1) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one Lu(1), and one W(2) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(1), one Lu(2), and one W(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Lu(1), one Lu(2), and one W(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Lu(1) and one Lu(2) atom. In the second Cl site, Cl(2) is bonded in a distorted water-like geometry to one Li(1) and one Lu(1) atom.