CNH6F is gamma nitrogen structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four methylazanium;hydrofluoride molecules. C(1) is bonded in a tetrahedral geometry to one N(1), one H(3), and two equivalent H(4) atoms. N(1) is bonded in a tetrahedral geometry to one C(1), one H(1), and two equivalent H(2) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one H(1) atom.
CNH6F is gamma nitrogen structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four methylazanium;hydrofluoride molecules. C(1) is bonded in a tetrahedral geometry to one N(1), one H(3), and two equivalent H(4) atoms. The C(1)-N(1) bond length is 1.48 Å. The C(1)-H(3) bond length is 1.10 Å. Both C(1)-H(4) bond lengths are 1.09 Å. N(1) is bonded in a tetrahedral geometry to one C(1), one H(1), and two equivalent H(2) atoms. The N(1)-H(1) bond length is 1.08 Å. Both N(1)-H(2) bond lengths are 1.04 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(1) and one F(1) atom. The H(1)-F(1) bond length is 1.53 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one H(1) atom.