NiIn2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ni(1) is bonded to four equivalent S(1) atoms to form NiS4 tetrahedra that share corners with twelve equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles are 55°. In(1) is bonded to six equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Ni(1)S4 tetrahedra and edges with six equivalent In(1)S6 octahedra. S(1) is bonded in a rectangular see-saw-like geometry to one Ni(1) and three equivalent In(1) atoms.
NiIn2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Ni(1) is bonded to four equivalent S(1) atoms to form NiS4 tetrahedra that share corners with twelve equivalent In(1)S6 octahedra. The corner-sharing octahedral tilt angles are 55°. All Ni(1)-S(1) bond lengths are 2.28 Å. In(1) is bonded to six equivalent S(1) atoms to form InS6 octahedra that share corners with six equivalent Ni(1)S4 tetrahedra and edges with six equivalent In(1)S6 octahedra. All In(1)-S(1) bond lengths are 2.65 Å. S(1) is bonded in a rectangular see-saw-like geometry to one Ni(1) and three equivalent In(1) atoms.