Ag3Sn2(GeP2)3 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Sn(1) and two equivalent P(1) atoms. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. Ge(1) is bonded to four equivalent P(1) atoms to form corner-sharing GeP4 tetrahedra. P(1) is bonded to one Ag(1), one Sn(1), and two equivalent Ge(1) atoms to form corner-sharing PAgSnGe2 tetrahedra.
Ag3Sn2(GeP2)3 crystallizes in the cubic I-43m space group. Ag(1) is bonded in a distorted L-shaped geometry to two equivalent Sn(1) and two equivalent P(1) atoms. Both Ag(1)-Sn(1) bond lengths are 3.09 Å. Both Ag(1)-P(1) bond lengths are 2.60 Å. Sn(1) is bonded in a 6-coordinate geometry to three equivalent Ag(1) and three equivalent P(1) atoms. All Sn(1)-P(1) bond lengths are 2.65 Å. Ge(1) is bonded to four equivalent P(1) atoms to form corner-sharing GeP4 tetrahedra. All Ge(1)-P(1) bond lengths are 2.36 Å. P(1) is bonded to one Ag(1), one Sn(1), and two equivalent Ge(1) atoms to form corner-sharing PAgSnGe2 tetrahedra.