RhAsTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent As(1) and three equivalent Te(1) atoms to form RhTe3As3 octahedra that share corners with twelve equivalent Rh(1)Te3As3 octahedra, corners with three equivalent Te(1)AsRh3 tetrahedra, and corners with three equivalent As(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 63-64°. As(1) is bonded to three equivalent Rh(1) and one Te(1) atom to form AsTeRh3 trigonal pyramids that share corners with three equivalent Rh(1)Te3As3 octahedra, corners with nine equivalent Te(1)AsRh3 tetrahedra, and corners with six equivalent As(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 79°. Te(1) is bonded to three equivalent Rh(1) and one As(1) atom to form TeAsRh3 tetrahedra that share corners with three equivalent Rh(1)Te3As3 octahedra, corners with six equivalent Te(1)AsRh3 tetrahedra, and corners with nine equivalent As(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°.
RhAsTe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent As(1) and three equivalent Te(1) atoms to form RhTe3As3 octahedra that share corners with twelve equivalent Rh(1)Te3As3 octahedra, corners with three equivalent Te(1)AsRh3 tetrahedra, and corners with three equivalent As(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 63-64°. All Rh(1)-As(1) bond lengths are 2.53 Å. All Rh(1)-Te(1) bond lengths are 2.65 Å. As(1) is bonded to three equivalent Rh(1) and one Te(1) atom to form AsTeRh3 trigonal pyramids that share corners with three equivalent Rh(1)Te3As3 octahedra, corners with nine equivalent Te(1)AsRh3 tetrahedra, and corners with six equivalent As(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 79°. The As(1)-Te(1) bond length is 2.65 Å. Te(1) is bonded to three equivalent Rh(1) and one As(1) atom to form TeAsRh3 tetrahedra that share corners with three equivalent Rh(1)Te3As3 octahedra, corners with six equivalent Te(1)AsRh3 tetrahedra, and corners with nine equivalent As(1)TeRh3 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°.