Sr3ZnRhO6 crystallizes in the trigonal R-3c space group. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Rh(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. Zn(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded to four equivalent Sr(1), one Rh(1), and one Zn(1) atom to form a mixture of distorted corner, edge, and face-sharing OSr4ZnRh octahedra. The corner-sharing octahedral tilt angles range from 0-65°.
Sr3ZnRhO6 crystallizes in the trigonal R-3c space group. Sr(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are a spread of Sr(1)-O(1) bond distances ranging from 2.50-2.73 Å. Rh(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. All Rh(1)-O(1) bond lengths are 2.04 Å. Zn(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. All Zn(1)-O(1) bond lengths are 2.22 Å. O(1) is bonded to four equivalent Sr(1), one Rh(1), and one Zn(1) atom to form a mixture of distorted corner, edge, and face-sharing OSr4ZnRh octahedra. The corner-sharing octahedral tilt angles range from 0-65°.