NaClO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded to six equivalent O(1) atoms to form corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles are 64°. O(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.
NaClO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded to six equivalent O(1) atoms to form corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles are 64°. There are three shorter (2.45 Å) and three longer (2.53 Å) Na(1)-O(1) bond lengths. O(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.51 Å. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms.