Ag3SBr crystallizes in the monoclinic Pm space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. S(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms to form distorted corner-sharing SAg6 pentagonal pyramids. Br(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms.
Ag3SBr crystallizes in the monoclinic Pm space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. Both Ag(1)-S(1) bond lengths are 2.52 Å. There is one shorter (2.94 Å) and one longer (3.20 Å) Ag(1)-Br(1) bond length. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. There is one shorter (2.53 Å) and one longer (2.55 Å) Ag(2)-S(1) bond length. Both Ag(2)-Br(1) bond lengths are 3.11 Å. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent S(1) and two equivalent Br(1) atoms. There is one shorter (2.48 Å) and one longer (2.53 Å) Ag(3)-S(1) bond length. Both Ag(3)-Br(1) bond lengths are 3.10 Å. S(1) is bonded to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms to form distorted corner-sharing SAg6 pentagonal pyramids. Br(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent Ag(2), and two equivalent Ag(3) atoms.