Ba(PdO2)2 crystallizes in the tetragonal I4_1/a space group. Ba(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Ba(1) and two equivalent Pd(1) atoms to form a mixture of distorted edge and corner-sharing OBa2Pd2 tetrahedra.
Ba(PdO2)2 crystallizes in the tetragonal I4_1/a space group. Ba(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. There are four shorter (2.73 Å) and four longer (2.77 Å) Ba(1)-O(1) bond lengths. Pd(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. There are two shorter (1.96 Å) and two longer (1.98 Å) Pd(1)-O(1) bond lengths. O(1) is bonded to two equivalent Ba(1) and two equivalent Pd(1) atoms to form a mixture of distorted edge and corner-sharing OBa2Pd2 tetrahedra.