PdBi2O4 crystallizes in the tetragonal I4cm space group. Pd(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. O(1) is bonded in a trigonal non-coplanar geometry to one Pd(1) and two equivalent Bi(1) atoms.
PdBi2O4 crystallizes in the tetragonal I4cm space group. Pd(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. All Pd(1)-O(1) bond lengths are 2.04 Å. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are two shorter (2.24 Å) and two longer (2.26 Å) Bi(1)-O(1) bond lengths. O(1) is bonded in a trigonal non-coplanar geometry to one Pd(1) and two equivalent Bi(1) atoms.