Cs2Mn(TeS3)2 crystallizes in the trigonal P-3c1 space group. Cs(1) is bonded in a 10-coordinate geometry to one Te(1) and nine equivalent S(1) atoms. Mn(1) is bonded in an octahedral geometry to six equivalent S(1) atoms. Te(1) is bonded in a 3-coordinate geometry to one Cs(1) and three equivalent S(1) atoms. S(1) is bonded in a 2-coordinate geometry to three equivalent Cs(1), one Mn(1), and one Te(1) atom.
Cs2Mn(TeS3)2 crystallizes in the trigonal P-3c1 space group. Cs(1) is bonded in a 10-coordinate geometry to one Te(1) and nine equivalent S(1) atoms. The Cs(1)-Te(1) bond length is 3.94 Å. There are a spread of Cs(1)-S(1) bond distances ranging from 3.57-4.15 Å. Mn(1) is bonded in an octahedral geometry to six equivalent S(1) atoms. All Mn(1)-S(1) bond lengths are 2.61 Å. Te(1) is bonded in a 3-coordinate geometry to one Cs(1) and three equivalent S(1) atoms. All Te(1)-S(1) bond lengths are 2.38 Å. S(1) is bonded in a 2-coordinate geometry to three equivalent Cs(1), one Mn(1), and one Te(1) atom.