Ag2S(NO)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(1) and one N(2) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one S(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom.
Ag2S(NO)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(1) and one N(2) atom. The Ag(1)-N(1) bond length is 2.07 Å. The Ag(1)-N(2) bond length is 2.06 Å. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Ag(2)-N(1) bond length is 2.09 Å. The Ag(2)-N(2) bond length is 2.13 Å. The Ag(2)-O(1) bond length is 2.45 Å. The Ag(2)-O(2) bond length is 2.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one S(1) atom. The N(1)-S(1) bond length is 1.58 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. The N(2)-S(1) bond length is 1.58 Å. S(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. The S(1)-O(1) bond length is 1.49 Å. The S(1)-O(2) bond length is 1.49 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom.