MnOF crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to three equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing MnO3F2 trigonal bipyramids. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms.
MnOF crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to three equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing MnO3F2 trigonal bipyramids. All Mn(1)-O(1) bond lengths are 1.92 Å. There is one shorter (1.90 Å) and one longer (2.10 Å) Mn(1)-F(1) bond length. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms.