PtCl6(RuN5H15Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms, two PtCl6 clusters, and four RuN5H15Cl clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1,3) is bonded in a single-bond geometry to one Pt(1) atom. In each RuN5H15Cl cluster, Ru(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(1), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(7), and two equivalent H(3) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(2), one H(6), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. Cl(2) is bonded in a single-bond geometry to one Ru(1) atom.
PtCl6(RuN5H15Cl)2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms, two PtCl6 clusters, and four RuN5H15Cl clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,3) atoms. Both Pt(1)-Cl(4) bond lengths are 2.34 Å. There are two shorter (2.35 Å) and two longer (2.36 Å) Pt(1)-Cl(1,3) bond lengths. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1,3) is bonded in a single-bond geometry to one Pt(1) atom. In each RuN5H15Cl cluster, Ru(1) is bonded in an octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(2) atom. The Ru(1)-N(2) bond length is 2.12 Å. Both Ru(1)-N(1) bond lengths are 2.14 Å. Both Ru(1)-N(3) bond lengths are 2.14 Å. The Ru(1)-Cl(2) bond length is 2.32 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(1), one H(4), and one H(5) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-H(4) bond length is 1.03 Å. The N(1)-H(5) bond length is 1.03 Å. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(7), and two equivalent H(3) atoms. The N(2)-H(7) bond length is 1.04 Å. Both N(2)-H(3) bond lengths are 1.03 Å. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(2), one H(6), and one H(8) atom. The N(3)-H(2) bond length is 1.03 Å. The N(3)-H(6) bond length is 1.03 Å. The N(3)-H(8) bond length is 1.03 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. Cl(2) is bonded in a single-bond geometry to one Ru(1) atom.