GdY3V4O16 is Zircon-derived structured and crystallizes in the orthorhombic C222 space group. Gd(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. In the third V site, V(3) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(3) atom.
GdY3V4O16 is Zircon-derived structured and crystallizes in the orthorhombic C222 space group. Gd(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. All Gd(1)-O(1) bond lengths are 2.34 Å. All Gd(1)-O(3) bond lengths are 2.48 Å. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. All Y(1)-O(2) bond lengths are 2.33 Å. All Y(1)-O(4) bond lengths are 2.47 Å. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both Y(2)-O(1) bond lengths are 2.47 Å. Both Y(2)-O(2) bond lengths are 2.47 Å. Both Y(2)-O(3) bond lengths are 2.33 Å. Both Y(2)-O(4) bond lengths are 2.33 Å. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Both V(1)-O(1) bond lengths are 1.74 Å. Both V(1)-O(2) bond lengths are 1.74 Å. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. All V(2)-O(3) bond lengths are 1.74 Å. In the third V site, V(3) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. All V(3)-O(4) bond lengths are 1.74 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(3) atom.