SV1 is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of edge, face, and corner-sharing VS6 octahedra. The corner-sharing octahedral tilt angles are 45°. S(1) is bonded to six equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing SV6 pentagonal pyramids.
SV1 is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded to six equivalent S(1) atoms to form a mixture of edge, face, and corner-sharing VS6 octahedra. The corner-sharing octahedral tilt angles are 45°. All V(1)-S(1) bond lengths are 2.39 Å. S(1) is bonded to six equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing SV6 pentagonal pyramids.