As2V crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent As(2) and five equivalent As(1) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms. In the second As site, As(2) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent As(2) atoms.
As2V crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent As(2) and five equivalent As(1) atoms. There are two shorter (2.53 Å) and one longer (2.58 Å) V(1)-As(2) bond length. There are a spread of V(1)-As(1) bond distances ranging from 2.60-2.66 Å. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms. In the second As site, As(2) is bonded in a 6-coordinate geometry to three equivalent V(1) and three equivalent As(2) atoms. There is one shorter (2.45 Å) and two longer (2.71 Å) As(2)-As(2) bond lengths.