ZrRhBi is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Bi(1) atoms. Rh(1) is bonded to four equivalent Zr(1) atoms to form distorted RhZr4 tetrahedra that share corners with four equivalent Bi(1)Zr4 tetrahedra, corners with twelve equivalent Rh(1)Zr4 tetrahedra, and edges with six equivalent Bi(1)Zr4 tetrahedra. Bi(1) is bonded to four equivalent Zr(1) atoms to form distorted BiZr4 tetrahedra that share corners with four equivalent Rh(1)Zr4 tetrahedra, corners with twelve equivalent Bi(1)Zr4 tetrahedra, and edges with six equivalent Rh(1)Zr4 tetrahedra.
ZrRhBi is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded in a body-centered cubic geometry to four equivalent Rh(1) and four equivalent Bi(1) atoms. All Zr(1)-Rh(1) bond lengths are 2.88 Å. All Zr(1)-Bi(1) bond lengths are 2.88 Å. Rh(1) is bonded to four equivalent Zr(1) atoms to form distorted RhZr4 tetrahedra that share corners with four equivalent Bi(1)Zr4 tetrahedra, corners with twelve equivalent Rh(1)Zr4 tetrahedra, and edges with six equivalent Bi(1)Zr4 tetrahedra. Bi(1) is bonded to four equivalent Zr(1) atoms to form distorted BiZr4 tetrahedra that share corners with four equivalent Rh(1)Zr4 tetrahedra, corners with twelve equivalent Bi(1)Zr4 tetrahedra, and edges with six equivalent Rh(1)Zr4 tetrahedra.