AgHgO2 crystallizes in the triclinic P-1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to two equivalent O(2) atoms. In the second Hg site, Hg(2) is bonded in a linear geometry to two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Hg(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Hg(1) atom.
AgHgO2 crystallizes in the triclinic P-1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ag(1)-O(1) bond lengths are 2.16 Å. Both Ag(1)-O(2) bond lengths are 2.18 Å. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Ag(2)-O(1) bond lengths are 2.15 Å. Both Ag(2)-O(2) bond lengths are 2.16 Å. There are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to two equivalent O(2) atoms. Both Hg(1)-O(2) bond lengths are 2.08 Å. In the second Hg site, Hg(2) is bonded in a linear geometry to two equivalent O(1) atoms. Both Hg(2)-O(1) bond lengths are 2.07 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Hg(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Hg(1) atom.