LiMn9CdO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(4), one O(5), and one O(9) atom. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Mn(7)O5 square pyramid,  a cornercorner with one Mn(9)O5 trigonal bipyramid,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Cd(1)O5 square pyramids,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. In the third Mn site, Mn(3) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(6), one O(7), and one O(8) atom. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(2), one O(4), one O(6), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Cd(1)O5 square pyramid, corners with two equivalent Mn(7)O5 square pyramids,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid,  an edgeedge with one Cd(1)O5 square pyramid, and edges with two equivalent Mn(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 9-76°. In the fifth Mn site, Mn(5) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(8), and one O(9) atom. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one Mn(4)O5 trigonal bipyramid,  a cornercorner with one Mn(9)O5 trigonal bipyramid, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid, and  an edgeedge with one Cd(1)O5 square pyramid. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form MnO5 square pyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(9)O5 trigonal bipyramid, corners with two equivalent Mn(4)O5 trigonal bipyramids,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Cd(1)O5 square pyramid,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 8°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Cd(1)O5 square pyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(7)O5 square pyramids,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O5 square pyramid, corners with two equivalent Cd(1)O5 square pyramids,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid,  an edgeedge with one Cd(1)O5 square pyramid, and edges with two equivalent Mn(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 4-67°. Cd(1) is bonded to one O(1), one O(10), one O(6), one O(7), and one O(8) atom to form distorted CdO5 square pyramids that share  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, corners with two equivalent Mn(9)O5 trigonal bipyramids,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 8°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Cd(1) atom. In the second O site, O(2) is bonded to one Li(1), one Mn(1), one Mn(4), one Mn(6), one Mn(7), and one Mn(8) atom to form distorted OLiMn5 octahedra that share  a cornercorner with one O(3)LiMn5 octahedra,  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(8)Mn5Cd octahedra,  a cornercorner with one O(6)Mn4Cd trigonal bipyramid, corners with two equivalent O(9)Mn5 trigonal bipyramids,  an edgeedge with one O(3)LiMn5 octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(10)Mn5Cd octahedra, edges with two equivalent O(4)Mn5 square pyramids,  an edgeedge with one O(9)Mn5 trigonal bipyramid, and  a faceface with one O(5)LiMn5 octahedra. The corner-sharing octahedral tilt angles range from 9-84°. In the third O site, O(3) is bonded to one Li(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form distorted OLiMn5 octahedra that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(10)Mn5Cd octahedra, corners with three equivalent O(5)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  a cornercorner with one O(9)Mn5 trigonal bipyramid, corners with two equivalent O(6)Mn4Cd trigonal bipyramids,  an edgeedge with one O(2)LiMn5 octahedra,  an edgeedge with one O(5)LiMn5 octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, and  an edgeedge with one O(9)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-55°. In the fourth O site, O(4) is bonded to one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom to form distorted OMn5 square pyramids that share  a cornercorner with one O(3)LiMn5 octahedra,  a cornercorner with one O(7)Mn5Cd octahedra,  a cornercorner with one O(8)Mn5Cd octahedra, corners with two equivalent O(5)LiMn5 octahedra, corners with three equivalent O(10)Mn5Cd octahedra,  a cornercorner with one O(9)Mn5 trigonal bipyramid,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(2)LiMn5 octahedra,  an edgeedge with one O(6)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(9)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-83°. In the fifth O site, O(5) is bonded to one Li(1), one Mn(1), one Mn(2), one Mn(5), one Mn(6), and one Mn(8) atom to form distorted OLiMn5 octahedra that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(7)Mn5Cd octahedra,  a cornercorner with one O(8)Mn5Cd octahedra, corners with three equivalent O(3)LiMn5 octahedra, corners with two equivalent O(4)Mn5 square pyramids,  a cornercorner with one O(6)Mn4Cd trigonal bipyramid,  an edgeedge with one O(3)LiMn5 octahedra,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(9)Mn5 trigonal bipyramids, and  a faceface with one O(2)LiMn5 octahedra. The corner-sharing octahedral tilt angles range from 6-84°. In the sixth O site, O(6) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(9), and one Cd(1) atom to form distorted OMn4Cd trigonal bipyramids that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(10)Mn5Cd octahedra, corners with two equivalent O(3)LiMn5 octahedra, corners with three equivalent O(7)Mn5Cd octahedra,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, and  an edgeedge with one O(4)Mn5 square pyramid. The corner-sharing octahedral tilt angles range from 7-85°. In the seventh O site, O(7) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(7), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  a cornercorner with one O(9)Mn5 trigonal bipyramid, corners with three equivalent O(6)Mn4Cd trigonal bipyramids,  an edgeedge with one O(2)LiMn5 octahedra,  an edgeedge with one O(3)LiMn5 octahedra, edges with two equivalent O(10)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra,  an edgeedge with one O(4)Mn5 square pyramid, and  an edgeedge with one O(6)Mn4Cd trigonal bipyramid. The corner-sharing octahedral tilt angles are 6°. In the eighth O site, O(8) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  an edgeedge with one O(5)LiMn5 octahedra,  an edgeedge with one O(10)Mn5Cd octahedra, edges with two equivalent O(3)LiMn5 octahedra, edges with two equivalent O(7)Mn5Cd octahedra,  an edgeedge with one O(9)Mn5 trigonal bipyramid, and edges with two equivalent O(6)Mn4Cd trigonal bipyramids. The corner-sharing octahedral tilt angles range from 9-71°. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form distorted OMn5 trigonal bipyramids that share  a cornercorner with one O(3)LiMn5 octahedra,  a cornercorner with one O(10)Mn5Cd octahedra,  a cornercorner with one O(7)Mn5Cd octahedra, corners with two equivalent O(2)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  an edgeedge with one O(2)LiMn5 octahedra,  an edgeedge with one O(3)LiMn5 octahedra,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(5)LiMn5 octahedra, and  an edgeedge with one O(4)Mn5 square pyramid. The corner-sharing octahedral tilt angles range from 6-79°. In the tenth O site, O(10) is bonded to one Mn(1), one Mn(4), one Mn(7), one Mn(8), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share  a cornercorner with one O(3)LiMn5 octahedra, corners with three equivalent O(4)Mn5 square pyramids,  a cornercorner with one O(6)Mn4Cd trigonal bipyramid,  a cornercorner with one O(9)Mn5 trigonal bipyramid,  an edgeedge with one O(5)LiMn5 octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(2)LiMn5 octahedra, edges with two equivalent O(7)Mn5Cd octahedra,  an edgeedge with one O(4)Mn5 square pyramid,  an edgeedge with one O(6)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(9)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 3°.
LiMn9CdO10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. The Li(1)-O(1) bond length is 1.95 Å. The Li(1)-O(2) bond length is 1.99 Å. The Li(1)-O(3) bond length is 1.93 Å. The Li(1)-O(5) bond length is 2.10 Å. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(4), one O(5), and one O(9) atom. The Mn(1)-O(10) bond length is 2.12 Å. The Mn(1)-O(2) bond length is 2.30 Å. The Mn(1)-O(4) bond length is 2.21 Å. The Mn(1)-O(5) bond length is 2.26 Å. The Mn(1)-O(9) bond length is 2.15 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Mn(7)O5 square pyramid,  a cornercorner with one Mn(9)O5 trigonal bipyramid,  an edgeedge with one Mn(8)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Cd(1)O5 square pyramids,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. The Mn(2)-O(1) bond length is 2.36 Å. The Mn(2)-O(3) bond length is 2.27 Å. The Mn(2)-O(5) bond length is 2.29 Å. The Mn(2)-O(6) bond length is 2.20 Å. The Mn(2)-O(7) bond length is 2.38 Å. The Mn(2)-O(8) bond length is 2.33 Å. In the third Mn site, Mn(3) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(6), one O(7), and one O(8) atom. The Mn(3)-O(1) bond length is 2.30 Å. The Mn(3)-O(3) bond length is 2.27 Å. The Mn(3)-O(6) bond length is 2.27 Å. The Mn(3)-O(7) bond length is 2.16 Å. The Mn(3)-O(8) bond length is 2.24 Å. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(2), one O(4), one O(6), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Cd(1)O5 square pyramid, corners with two equivalent Mn(7)O5 square pyramids,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid,  an edgeedge with one Cd(1)O5 square pyramid, and edges with two equivalent Mn(9)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 9-76°. The Mn(4)-O(10) bond length is 2.33 Å. The Mn(4)-O(2) bond length is 2.16 Å. The Mn(4)-O(4) bond length is 2.17 Å. The Mn(4)-O(6) bond length is 2.20 Å. The Mn(4)-O(7) bond length is 2.47 Å. In the fifth Mn site, Mn(5) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(8), and one O(9) atom. The Mn(5)-O(1) bond length is 2.15 Å. The Mn(5)-O(3) bond length is 2.40 Å. The Mn(5)-O(5) bond length is 2.15 Å. The Mn(5)-O(8) bond length is 2.16 Å. The Mn(5)-O(9) bond length is 2.18 Å. In the sixth Mn site, Mn(6) is bonded to one O(1), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one Mn(4)O5 trigonal bipyramid,  a cornercorner with one Mn(9)O5 trigonal bipyramid, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid, and  an edgeedge with one Cd(1)O5 square pyramid. The Mn(6)-O(1) bond length is 2.26 Å. The Mn(6)-O(2) bond length is 2.27 Å. The Mn(6)-O(3) bond length is 2.23 Å. The Mn(6)-O(5) bond length is 2.31 Å. The Mn(6)-O(8) bond length is 2.20 Å. The Mn(6)-O(9) bond length is 2.39 Å. In the seventh Mn site, Mn(7) is bonded to one O(10), one O(2), one O(4), one O(7), and one O(9) atom to form MnO5 square pyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(9)O5 trigonal bipyramid, corners with two equivalent Mn(4)O5 trigonal bipyramids,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra,  an edgeedge with one Cd(1)O5 square pyramid,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 8°. The Mn(7)-O(10) bond length is 2.37 Å. The Mn(7)-O(2) bond length is 2.18 Å. The Mn(7)-O(4) bond length is 2.22 Å. The Mn(7)-O(7) bond length is 2.18 Å. The Mn(7)-O(9) bond length is 2.16 Å. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(2), one O(3), one O(4), one O(5), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Cd(1)O5 square pyramid,  a cornercorner with one Mn(4)O5 trigonal bipyramid,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Mn(7)O5 square pyramids,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. The Mn(8)-O(10) bond length is 2.20 Å. The Mn(8)-O(2) bond length is 2.48 Å. The Mn(8)-O(3) bond length is 2.18 Å. The Mn(8)-O(4) bond length is 2.19 Å. The Mn(8)-O(5) bond length is 2.45 Å. The Mn(8)-O(9) bond length is 2.24 Å. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O5 square pyramid, corners with two equivalent Cd(1)O5 square pyramids,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid,  an edgeedge with one Cd(1)O5 square pyramid, and edges with two equivalent Mn(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 4-67°. The Mn(9)-O(10) bond length is 2.21 Å. The Mn(9)-O(4) bond length is 2.26 Å. The Mn(9)-O(6) bond length is 2.11 Å. The Mn(9)-O(7) bond length is 2.16 Å. The Mn(9)-O(8) bond length is 2.27 Å. Cd(1) is bonded to one O(1), one O(10), one O(6), one O(7), and one O(8) atom to form distorted CdO5 square pyramids that share  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(4)O5 trigonal bipyramid, corners with two equivalent Mn(9)O5 trigonal bipyramids,  an edgeedge with one Mn(6)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Mn(7)O5 square pyramid,  an edgeedge with one Mn(4)O5 trigonal bipyramid, and  an edgeedge with one Mn(9)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 8°. The Cd(1)-O(1) bond length is 2.37 Å. The Cd(1)-O(10) bond length is 2.49 Å. The Cd(1)-O(6) bond length is 2.43 Å. The Cd(1)-O(7) bond length is 2.47 Å. The Cd(1)-O(8) bond length is 2.63 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Cd(1) atom. In the second O site, O(2) is bonded to one Li(1), one Mn(1), one Mn(4), one Mn(6), one Mn(7), and one Mn(8) atom to form distorted OLiMn5 octahedra that share  a cornercorner with one O(3)LiMn5 octahedra,  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(8)Mn5Cd octahedra,  a cornercorner with one O(6)Mn4Cd trigonal bipyramid, corners with two equivalent O(9)Mn5 trigonal bipyramids,  an edgeedge with one O(3)LiMn5 octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(10)Mn5Cd octahedra, edges with two equivalent O(4)Mn5 square pyramids,  an edgeedge with one O(9)Mn5 trigonal bipyramid, and  a faceface with one O(5)LiMn5 octahedra. The corner-sharing octahedral tilt angles range from 9-84°. In the third O site, O(3) is bonded to one Li(1), one Mn(2), one Mn(3), one Mn(5), one Mn(6), and one Mn(8) atom to form distorted OLiMn5 octahedra that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(10)Mn5Cd octahedra, corners with three equivalent O(5)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  a cornercorner with one O(9)Mn5 trigonal bipyramid, corners with two equivalent O(6)Mn4Cd trigonal bipyramids,  an edgeedge with one O(2)LiMn5 octahedra,  an edgeedge with one O(5)LiMn5 octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, and  an edgeedge with one O(9)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-55°. In the fourth O site, O(4) is bonded to one Mn(1), one Mn(4), one Mn(7), one Mn(8), and one Mn(9) atom to form distorted OMn5 square pyramids that share  a cornercorner with one O(3)LiMn5 octahedra,  a cornercorner with one O(7)Mn5Cd octahedra,  a cornercorner with one O(8)Mn5Cd octahedra, corners with two equivalent O(5)LiMn5 octahedra, corners with three equivalent O(10)Mn5Cd octahedra,  a cornercorner with one O(9)Mn5 trigonal bipyramid,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(2)LiMn5 octahedra,  an edgeedge with one O(6)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(9)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-83°. In the fifth O site, O(5) is bonded to one Li(1), one Mn(1), one Mn(2), one Mn(5), one Mn(6), and one Mn(8) atom to form distorted OLiMn5 octahedra that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(7)Mn5Cd octahedra,  a cornercorner with one O(8)Mn5Cd octahedra, corners with three equivalent O(3)LiMn5 octahedra, corners with two equivalent O(4)Mn5 square pyramids,  a cornercorner with one O(6)Mn4Cd trigonal bipyramid,  an edgeedge with one O(3)LiMn5 octahedra,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(9)Mn5 trigonal bipyramids, and  a faceface with one O(2)LiMn5 octahedra. The corner-sharing octahedral tilt angles range from 6-84°. In the sixth O site, O(6) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(9), and one Cd(1) atom to form distorted OMn4Cd trigonal bipyramids that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(10)Mn5Cd octahedra, corners with two equivalent O(3)LiMn5 octahedra, corners with three equivalent O(7)Mn5Cd octahedra,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(7)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra, and  an edgeedge with one O(4)Mn5 square pyramid. The corner-sharing octahedral tilt angles range from 7-85°. In the seventh O site, O(7) is bonded to one Mn(2), one Mn(3), one Mn(4), one Mn(7), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  a cornercorner with one O(9)Mn5 trigonal bipyramid, corners with three equivalent O(6)Mn4Cd trigonal bipyramids,  an edgeedge with one O(2)LiMn5 octahedra,  an edgeedge with one O(3)LiMn5 octahedra, edges with two equivalent O(10)Mn5Cd octahedra, edges with two equivalent O(8)Mn5Cd octahedra,  an edgeedge with one O(4)Mn5 square pyramid, and  an edgeedge with one O(6)Mn4Cd trigonal bipyramid. The corner-sharing octahedral tilt angles are 6°. In the eighth O site, O(8) is bonded to one Mn(2), one Mn(3), one Mn(5), one Mn(6), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share  a cornercorner with one O(2)LiMn5 octahedra,  a cornercorner with one O(5)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  an edgeedge with one O(5)LiMn5 octahedra,  an edgeedge with one O(10)Mn5Cd octahedra, edges with two equivalent O(3)LiMn5 octahedra, edges with two equivalent O(7)Mn5Cd octahedra,  an edgeedge with one O(9)Mn5 trigonal bipyramid, and edges with two equivalent O(6)Mn4Cd trigonal bipyramids. The corner-sharing octahedral tilt angles range from 9-71°. In the ninth O site, O(9) is bonded to one Mn(1), one Mn(5), one Mn(6), one Mn(7), and one Mn(8) atom to form distorted OMn5 trigonal bipyramids that share  a cornercorner with one O(3)LiMn5 octahedra,  a cornercorner with one O(10)Mn5Cd octahedra,  a cornercorner with one O(7)Mn5Cd octahedra, corners with two equivalent O(2)LiMn5 octahedra,  a cornercorner with one O(4)Mn5 square pyramid,  an edgeedge with one O(2)LiMn5 octahedra,  an edgeedge with one O(3)LiMn5 octahedra,  an edgeedge with one O(10)Mn5Cd octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(5)LiMn5 octahedra, and  an edgeedge with one O(4)Mn5 square pyramid. The corner-sharing octahedral tilt angles range from 6-79°. In the tenth O site, O(10) is bonded to one Mn(1), one Mn(4), one Mn(7), one Mn(8), one Mn(9), and one Cd(1) atom to form OMn5Cd octahedra that share  a cornercorner with one O(3)LiMn5 octahedra, corners with three equivalent O(4)Mn5 square pyramids,  a cornercorner with one O(6)Mn4Cd trigonal bipyramid,  a cornercorner with one O(9)Mn5 trigonal bipyramid,  an edgeedge with one O(5)LiMn5 octahedra,  an edgeedge with one O(8)Mn5Cd octahedra, edges with two equivalent O(2)LiMn5 octahedra, edges with two equivalent O(7)Mn5Cd octahedra,  an edgeedge with one O(4)Mn5 square pyramid,  an edgeedge with one O(6)Mn4Cd trigonal bipyramid, and  an edgeedge with one O(9)Mn5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 3°.