Rb4Bi is Silicon tetrafluoride-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Rb4Bi clusters. Rb(1) is bonded in a single-bond geometry to one Bi(1) atom. Bi(1) is bonded in a tetrahedral geometry to four equivalent Rb(1) atoms.
Rb4Bi is Silicon tetrafluoride-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Rb4Bi clusters. Rb(1) is bonded in a single-bond geometry to one Bi(1) atom. The Rb(1)-Bi(1) bond length is 3.46 Å. Bi(1) is bonded in a tetrahedral geometry to four equivalent Rb(1) atoms.