Sr10Mn5Zn9(AsO)10 crystallizes in the triclinic P1 space group. There are ten inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 4-coordinate geometry to one As(3), one As(8), one O(2), one O(5), one O(6), and one O(7) atom. In the second Sr site, Sr(2) is bonded in a distorted L-shaped geometry to one Zn(6), one As(5), one As(8), one O(4), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 2-coordinate geometry to one Zn(1), one As(1), one As(2), one As(4), one As(9), one O(4), one O(8), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 3-coordinate geometry to one As(6), one O(1), one O(6), and one O(9) atom. In the fifth Sr site, Sr(5) is bonded in a 3-coordinate geometry to one As(10), one As(2), one As(8), one O(1), one O(10), and one O(6) atom. In the sixth Sr site, Sr(6) is bonded in a 5-coordinate geometry to one As(1), one As(4), one As(9), one O(10), one O(2), and one O(7) atom. In the seventh Sr site, Sr(7) is bonded in a distorted bent 120 degrees geometry to one As(2), one As(3), one As(4), one As(5), one As(9), one O(3), and one O(8) atom. In the eighth Sr site, Sr(8) is bonded in a 3-coordinate geometry to one As(5), one As(6), one O(4), one O(5), and one O(9) atom. In the ninth Sr site, Sr(9) is bonded in a 3-coordinate geometry to one As(5), one O(2), one O(3), and one O(5) atom. In the tenth Sr site, Sr(10) is bonded in a 3-coordinate geometry to one As(3), one As(6), one O(10), one O(2), and one O(7) atom. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted bent 120 degrees geometry to one As(2), one As(7), one O(1), and one O(3) atom. In the second Mn site, Mn(2) is bonded in a 3-coordinate geometry to one As(1), one O(1), one O(10), and one O(2) atom. In the third Mn site, Mn(3) is bonded in a distorted bent 120 degrees geometry to one As(1), one O(4), and one O(7) atom. In the fourth Mn site, Mn(4) is bonded in a 3-coordinate geometry to one Zn(6), one As(7), one O(5), one O(6), and one O(9) atom. In the fifth Mn site, Mn(5) is bonded in a distorted bent 150 degrees geometry to one As(3), one As(8), one As(9), one O(10), and one O(8) atom. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one Sr(3), one Zn(9), one As(2), one As(4), and one As(9) atom. In the second Zn site, Zn(2) is bonded in a distorted single-bond geometry to one As(10), one As(3), one As(6), and one O(5) atom. In the third Zn site, Zn(3) is bonded in a distorted single-bond geometry to one As(1), one As(10), one As(3), and one O(8) atom. In the fourth Zn site, Zn(4) is bonded in a 3-coordinate geometry to one As(3), one As(5), and one As(8) atom. In the fifth Zn site, Zn(5) is bonded in a 4-coordinate geometry to one As(2), one As(4), one As(5), and one As(6) atom. In the sixth Zn site, Zn(6) is bonded in a 5-coordinate geometry to one Sr(2), one Mn(4), one As(5), one As(7), and one As(9) atom. In the seventh Zn site, Zn(7) is bonded in a 3-coordinate geometry to one As(1), one As(10), and one As(7) atom. In the eighth Zn site, Zn(8) is bonded in a distorted trigonal planar geometry to one As(1), one As(8), and one As(9) atom. In the ninth Zn site, Zn(9) is bonded in a distorted single-bond geometry to one Zn(1), one As(10), and one O(3) atom. There are ten inequivalent As sites. In the first As site, As(1) is bonded in a 7-coordinate geometry to one Sr(3), one Sr(6), one Mn(2), one Mn(3), one Zn(3), one Zn(7), and one Zn(8) atom. In the second As site, As(2) is bonded in a 7-coordinate geometry to one Sr(3), one Sr(5), one Sr(7), one Mn(1), one Zn(1), one Zn(5), and one As(4) atom. In the third As site, As(3) is bonded in a 7-coordinate geometry to one Sr(1), one Sr(10), one Sr(7), one Mn(5), one Zn(2), one Zn(3), and one Zn(4) atom. In the fourth As site, As(4) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(6), one Sr(7), one Zn(1), one Zn(5), and one As(2) atom. In the fifth As site, As(5) is bonded in a 7-coordinate geometry to one Sr(2), one Sr(7), one Sr(8), one Sr(9), one Zn(4), one Zn(5), and one Zn(6) atom. In the sixth As site, As(6) is bonded in a 5-coordinate geometry to one Sr(10), one Sr(4), one Sr(8), one Zn(2), and one Zn(5) atom. In the seventh As site, As(7) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(4), one Zn(6), and one Zn(7) atom. In the eighth As site, As(8) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(5), one Mn(5), one Zn(4), and one Zn(8) atom. In the ninth As site, As(9) is bonded in a 7-coordinate geometry to one Sr(3), one Sr(6), one Sr(7), one Mn(5), one Zn(1), one Zn(6), and one Zn(8) atom. In the tenth As site, As(10) is bonded in a 5-coordinate geometry to one Sr(5), one Zn(2), one Zn(3), one Zn(7), and one Zn(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Sr(4), one Sr(5), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded to one Sr(1), one Sr(10), one Sr(6), one Sr(9), and one Mn(2) atom to form distorted corner-sharing OSr4Mn trigonal bipyramids. In the third O site, O(3) is bonded to one Sr(7), one Sr(9), one Mn(1), and one Zn(9) atom to form OSr2MnZn trigonal pyramids that share  a cornercorner with one O(8)Sr3MnZn trigonal bipyramid and  a cornercorner with one O(2)Sr4Mn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Sr(2), one Sr(3), one Sr(8), and one Mn(3) atom to form OSr3Mn tetrahedra that share  an edgeedge with one O(9)Sr3Mn tetrahedra and  an edgeedge with one O(8)Sr3MnZn trigonal bipyramid. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(8), one Sr(9), one Mn(4), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Sr(1), one Sr(4), one Sr(5), and one Mn(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Sr(1), one Sr(10), one Sr(6), and one Mn(3) atom. In the eighth O site, O(8) is bonded to one Sr(2), one Sr(3), one Sr(7), one Mn(5), and one Zn(3) atom to form distorted OSr3MnZn trigonal bipyramids that share  a cornercorner with one O(9)Sr3Mn tetrahedra,  a cornercorner with one O(3)Sr2MnZn trigonal pyramid, and  an edgeedge with one O(4)Sr3Mn tetrahedra. In the ninth O site, O(9) is bonded to one Sr(3), one Sr(4), one Sr(8), and one Mn(4) atom to form distorted OSr3Mn tetrahedra that share  a cornercorner with one O(8)Sr3MnZn trigonal bipyramid and  an edgeedge with one O(4)Sr3Mn tetrahedra. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(10), one Sr(5), one Sr(6), one Mn(2), and one Mn(5) atom.
Sr10Mn5Zn9(AsO)10 crystallizes in the triclinic P1 space group. There are ten inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 4-coordinate geometry to one As(3), one As(8), one O(2), one O(5), one O(6), and one O(7) atom. The Sr(1)-As(3) bond length is 3.42 Å. The Sr(1)-As(8) bond length is 3.31 Å. The Sr(1)-O(2) bond length is 2.74 Å. The Sr(1)-O(5) bond length is 2.57 Å. The Sr(1)-O(6) bond length is 2.54 Å. The Sr(1)-O(7) bond length is 2.60 Å. In the second Sr site, Sr(2) is bonded in a distorted L-shaped geometry to one Zn(6), one As(5), one As(8), one O(4), and one O(8) atom. The Sr(2)-Zn(6) bond length is 3.27 Å. The Sr(2)-As(5) bond length is 3.39 Å. The Sr(2)-As(8) bond length is 3.12 Å. The Sr(2)-O(4) bond length is 2.37 Å. The Sr(2)-O(8) bond length is 2.50 Å. In the third Sr site, Sr(3) is bonded in a 2-coordinate geometry to one Zn(1), one As(1), one As(2), one As(4), one As(9), one O(4), one O(8), and one O(9) atom. The Sr(3)-Zn(1) bond length is 3.28 Å. The Sr(3)-As(1) bond length is 3.28 Å. The Sr(3)-As(2) bond length is 3.19 Å. The Sr(3)-As(4) bond length is 3.35 Å. The Sr(3)-As(9) bond length is 3.48 Å. The Sr(3)-O(4) bond length is 2.46 Å. The Sr(3)-O(8) bond length is 3.00 Å. The Sr(3)-O(9) bond length is 2.35 Å. In the fourth Sr site, Sr(4) is bonded in a 3-coordinate geometry to one As(6), one O(1), one O(6), and one O(9) atom. The Sr(4)-As(6) bond length is 3.21 Å. The Sr(4)-O(1) bond length is 2.54 Å. The Sr(4)-O(6) bond length is 2.39 Å. The Sr(4)-O(9) bond length is 2.48 Å. In the fifth Sr site, Sr(5) is bonded in a 3-coordinate geometry to one As(10), one As(2), one As(8), one O(1), one O(10), and one O(6) atom. The Sr(5)-As(10) bond length is 3.11 Å. The Sr(5)-As(2) bond length is 3.31 Å. The Sr(5)-As(8) bond length is 3.42 Å. The Sr(5)-O(1) bond length is 2.56 Å. The Sr(5)-O(10) bond length is 2.74 Å. The Sr(5)-O(6) bond length is 2.40 Å. In the sixth Sr site, Sr(6) is bonded in a 5-coordinate geometry to one As(1), one As(4), one As(9), one O(10), one O(2), and one O(7) atom. The Sr(6)-As(1) bond length is 3.51 Å. The Sr(6)-As(4) bond length is 3.05 Å. The Sr(6)-As(9) bond length is 3.25 Å. The Sr(6)-O(10) bond length is 2.72 Å. The Sr(6)-O(2) bond length is 2.53 Å. The Sr(6)-O(7) bond length is 2.42 Å. In the seventh Sr site, Sr(7) is bonded in a distorted bent 120 degrees geometry to one As(2), one As(3), one As(4), one As(5), one As(9), one O(3), and one O(8) atom. The Sr(7)-As(2) bond length is 3.17 Å. The Sr(7)-As(3) bond length is 3.57 Å. The Sr(7)-As(4) bond length is 3.27 Å. The Sr(7)-As(5) bond length is 3.33 Å. The Sr(7)-As(9) bond length is 3.42 Å. The Sr(7)-O(3) bond length is 2.53 Å. The Sr(7)-O(8) bond length is 2.58 Å. In the eighth Sr site, Sr(8) is bonded in a 3-coordinate geometry to one As(5), one As(6), one O(4), one O(5), and one O(9) atom. The Sr(8)-As(5) bond length is 3.61 Å. The Sr(8)-As(6) bond length is 3.26 Å. The Sr(8)-O(4) bond length is 2.42 Å. The Sr(8)-O(5) bond length is 2.70 Å. The Sr(8)-O(9) bond length is 2.37 Å. In the ninth Sr site, Sr(9) is bonded in a 3-coordinate geometry to one As(5), one O(2), one O(3), and one O(5) atom. The Sr(9)-As(5) bond length is 3.33 Å. The Sr(9)-O(2) bond length is 2.38 Å. The Sr(9)-O(3) bond length is 2.49 Å. The Sr(9)-O(5) bond length is 2.40 Å. In the tenth Sr site, Sr(10) is bonded in a 3-coordinate geometry to one As(3), one As(6), one O(10), one O(2), and one O(7) atom. The Sr(10)-As(3) bond length is 3.27 Å. The Sr(10)-As(6) bond length is 3.05 Å. The Sr(10)-O(10) bond length is 2.51 Å. The Sr(10)-O(2) bond length is 2.48 Å. The Sr(10)-O(7) bond length is 2.45 Å. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted bent 120 degrees geometry to one As(2), one As(7), one O(1), and one O(3) atom. The Mn(1)-As(2) bond length is 2.80 Å. The Mn(1)-As(7) bond length is 2.79 Å. The Mn(1)-O(1) bond length is 2.02 Å. The Mn(1)-O(3) bond length is 1.99 Å. In the second Mn site, Mn(2) is bonded in a 3-coordinate geometry to one As(1), one O(1), one O(10), and one O(2) atom. The Mn(2)-As(1) bond length is 2.70 Å. The Mn(2)-O(1) bond length is 2.04 Å. The Mn(2)-O(10) bond length is 2.13 Å. The Mn(2)-O(2) bond length is 2.08 Å. In the third Mn site, Mn(3) is bonded in a distorted bent 120 degrees geometry to one As(1), one O(4), and one O(7) atom. The Mn(3)-As(1) bond length is 2.66 Å. The Mn(3)-O(4) bond length is 1.95 Å. The Mn(3)-O(7) bond length is 1.92 Å. In the fourth Mn site, Mn(4) is bonded in a 3-coordinate geometry to one Zn(6), one As(7), one O(5), one O(6), and one O(9) atom. The Mn(4)-Zn(6) bond length is 2.75 Å. The Mn(4)-As(7) bond length is 2.82 Å. The Mn(4)-O(5) bond length is 2.27 Å. The Mn(4)-O(6) bond length is 1.96 Å. The Mn(4)-O(9) bond length is 1.98 Å. In the fifth Mn site, Mn(5) is bonded in a distorted bent 150 degrees geometry to one As(3), one As(8), one As(9), one O(10), and one O(8) atom. The Mn(5)-As(3) bond length is 3.41 Å. The Mn(5)-As(8) bond length is 2.76 Å. The Mn(5)-As(9) bond length is 2.88 Å. The Mn(5)-O(10) bond length is 1.98 Å. The Mn(5)-O(8) bond length is 2.07 Å. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one Sr(3), one Zn(9), one As(2), one As(4), and one As(9) atom. The Zn(1)-Zn(9) bond length is 2.41 Å. The Zn(1)-As(2) bond length is 2.72 Å. The Zn(1)-As(4) bond length is 2.47 Å. The Zn(1)-As(9) bond length is 2.64 Å. In the second Zn site, Zn(2) is bonded in a distorted single-bond geometry to one As(10), one As(3), one As(6), and one O(5) atom. The Zn(2)-As(10) bond length is 2.46 Å. The Zn(2)-As(3) bond length is 2.87 Å. The Zn(2)-As(6) bond length is 2.53 Å. The Zn(2)-O(5) bond length is 2.01 Å. In the third Zn site, Zn(3) is bonded in a distorted single-bond geometry to one As(1), one As(10), one As(3), and one O(8) atom. The Zn(3)-As(1) bond length is 2.65 Å. The Zn(3)-As(10) bond length is 2.68 Å. The Zn(3)-As(3) bond length is 2.57 Å. The Zn(3)-O(8) bond length is 2.02 Å. In the fourth Zn site, Zn(4) is bonded in a 3-coordinate geometry to one As(3), one As(5), and one As(8) atom. The Zn(4)-As(3) bond length is 2.50 Å. The Zn(4)-As(5) bond length is 2.58 Å. The Zn(4)-As(8) bond length is 2.47 Å. In the fifth Zn site, Zn(5) is bonded in a 4-coordinate geometry to one As(2), one As(4), one As(5), and one As(6) atom. The Zn(5)-As(2) bond length is 2.59 Å. The Zn(5)-As(4) bond length is 2.50 Å. The Zn(5)-As(5) bond length is 2.53 Å. The Zn(5)-As(6) bond length is 2.45 Å. In the sixth Zn site, Zn(6) is bonded in a 5-coordinate geometry to one Sr(2), one Mn(4), one As(5), one As(7), and one As(9) atom. The Zn(6)-As(5) bond length is 2.48 Å. The Zn(6)-As(7) bond length is 2.57 Å. The Zn(6)-As(9) bond length is 2.44 Å. In the seventh Zn site, Zn(7) is bonded in a 3-coordinate geometry to one As(1), one As(10), and one As(7) atom. The Zn(7)-As(1) bond length is 2.58 Å. The Zn(7)-As(10) bond length is 2.44 Å. The Zn(7)-As(7) bond length is 2.48 Å. In the eighth Zn site, Zn(8) is bonded in a distorted trigonal planar geometry to one As(1), one As(8), and one As(9) atom. The Zn(8)-As(1) bond length is 2.49 Å. The Zn(8)-As(8) bond length is 2.41 Å. The Zn(8)-As(9) bond length is 2.57 Å. In the ninth Zn site, Zn(9) is bonded in a distorted single-bond geometry to one Zn(1), one As(10), and one O(3) atom. The Zn(9)-As(10) bond length is 2.55 Å. The Zn(9)-O(3) bond length is 1.98 Å. There are ten inequivalent As sites. In the first As site, As(1) is bonded in a 7-coordinate geometry to one Sr(3), one Sr(6), one Mn(2), one Mn(3), one Zn(3), one Zn(7), and one Zn(8) atom. In the second As site, As(2) is bonded in a 7-coordinate geometry to one Sr(3), one Sr(5), one Sr(7), one Mn(1), one Zn(1), one Zn(5), and one As(4) atom. The As(2)-As(4) bond length is 2.60 Å. In the third As site, As(3) is bonded in a 7-coordinate geometry to one Sr(1), one Sr(10), one Sr(7), one Mn(5), one Zn(2), one Zn(3), and one Zn(4) atom. In the fourth As site, As(4) is bonded in a 6-coordinate geometry to one Sr(3), one Sr(6), one Sr(7), one Zn(1), one Zn(5), and one As(2) atom. In the fifth As site, As(5) is bonded in a 7-coordinate geometry to one Sr(2), one Sr(7), one Sr(8), one Sr(9), one Zn(4), one Zn(5), and one Zn(6) atom. In the sixth As site, As(6) is bonded in a 5-coordinate geometry to one Sr(10), one Sr(4), one Sr(8), one Zn(2), and one Zn(5) atom. In the seventh As site, As(7) is bonded in a 4-coordinate geometry to one Mn(1), one Mn(4), one Zn(6), and one Zn(7) atom. In the eighth As site, As(8) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one Sr(5), one Mn(5), one Zn(4), and one Zn(8) atom. In the ninth As site, As(9) is bonded in a 7-coordinate geometry to one Sr(3), one Sr(6), one Sr(7), one Mn(5), one Zn(1), one Zn(6), and one Zn(8) atom. In the tenth As site, As(10) is bonded in a 5-coordinate geometry to one Sr(5), one Zn(2), one Zn(3), one Zn(7), and one Zn(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Sr(4), one Sr(5), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded to one Sr(1), one Sr(10), one Sr(6), one Sr(9), and one Mn(2) atom to form distorted corner-sharing OSr4Mn trigonal bipyramids. In the third O site, O(3) is bonded to one Sr(7), one Sr(9), one Mn(1), and one Zn(9) atom to form OSr2MnZn trigonal pyramids that share  a cornercorner with one O(8)Sr3MnZn trigonal bipyramid and  a cornercorner with one O(2)Sr4Mn trigonal bipyramid. In the fourth O site, O(4) is bonded to one Sr(2), one Sr(3), one Sr(8), and one Mn(3) atom to form OSr3Mn tetrahedra that share  an edgeedge with one O(9)Sr3Mn tetrahedra and  an edgeedge with one O(8)Sr3MnZn trigonal bipyramid. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(8), one Sr(9), one Mn(4), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Sr(1), one Sr(4), one Sr(5), and one Mn(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Sr(1), one Sr(10), one Sr(6), and one Mn(3) atom. In the eighth O site, O(8) is bonded to one Sr(2), one Sr(3), one Sr(7), one Mn(5), and one Zn(3) atom to form distorted OSr3MnZn trigonal bipyramids that share  a cornercorner with one O(9)Sr3Mn tetrahedra,  a cornercorner with one O(3)Sr2MnZn trigonal pyramid, and  an edgeedge with one O(4)Sr3Mn tetrahedra. In the ninth O site, O(9) is bonded to one Sr(3), one Sr(4), one Sr(8), and one Mn(4) atom to form distorted OSr3Mn tetrahedra that share  a cornercorner with one O(8)Sr3MnZn trigonal bipyramid and  an edgeedge with one O(4)Sr3Mn tetrahedra. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(10), one Sr(5), one Sr(6), one Mn(2), and one Mn(5) atom.