(Na)2NaSbBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaSbBr6 framework. In the NaSbBr6 framework, Na(2) is bonded to six equivalent Br(1) atoms to form NaBr6 octahedra that share corners with six equivalent Sb(1)Br6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent Br(1) atoms to form SbBr6 octahedra that share corners with six equivalent Na(2)Br6 octahedra. The corner-sharing octahedra are not tilted. Br(1) is bonded in a linear geometry to one Na(2) and one Sb(1) atom.
(Na)2NaSbBr6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaSbBr6 framework. In the NaSbBr6 framework, Na(2) is bonded to six equivalent Br(1) atoms to form NaBr6 octahedra that share corners with six equivalent Sb(1)Br6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-Br(1) bond lengths are 2.86 Å. Sb(1) is bonded to six equivalent Br(1) atoms to form SbBr6 octahedra that share corners with six equivalent Na(2)Br6 octahedra. The corner-sharing octahedra are not tilted. All Sb(1)-Br(1) bond lengths are 2.79 Å. Br(1) is bonded in a linear geometry to one Na(2) and one Sb(1) atom.