(Na)2NiTlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NiTlF6 framework. In the NiTlF6 framework, Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Ni(1) and one Tl(1) atom.
(Na)2NiTlF6 crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NiTlF6 framework. In the NiTlF6 framework, Ni(1) is bonded to six equivalent F(1) atoms to form NiF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Ni(1)-F(1) bond lengths are 1.95 Å. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Ni(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-F(1) bond lengths are 2.38 Å. F(1) is bonded in a linear geometry to one Ni(1) and one Tl(1) atom.