Mo3N2O9O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four water atoms and two Mo3N2O9 clusters. In each Mo3N2O9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to one N(1), one O(1), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent N(1), one O(2), and one O(3) atom. N(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one O(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one O(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one O(2) atom.
Mo3N2O9O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four water atoms and two Mo3N2O9 clusters. In each Mo3N2O9 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to one N(1), one O(1), one O(4), and one O(5) atom. The Mo(1)-N(1) bond length is 2.10 Å. The Mo(1)-O(1) bond length is 2.10 Å. The Mo(1)-O(4) bond length is 1.73 Å. The Mo(1)-O(5) bond length is 1.75 Å. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent N(1), one O(2), and one O(3) atom. Both Mo(2)-N(1) bond lengths are 1.94 Å. The Mo(2)-O(2) bond length is 2.00 Å. The Mo(2)-O(3) bond length is 1.69 Å. N(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one O(1) atom. The N(1)-O(1) bond length is 1.32 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one O(7) atom. The O(2)-O(7) bond length is 1.27 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one O(2) atom.