Sr3WN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded in a 5-coordinate geometry to five equivalent N(1) atoms. W(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. N(1) is bonded to five equivalent Sr(1) and one W(1) atom to form a mixture of distorted edge and corner-sharing NSr5W octahedra. The corner-sharing octahedral tilt angles range from 21-42°.
Sr3WN3 crystallizes in the hexagonal P6_3/m space group. Sr(1) is bonded in a 5-coordinate geometry to five equivalent N(1) atoms. There are a spread of Sr(1)-N(1) bond distances ranging from 2.72-3.05 Å. W(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. All W(1)-N(1) bond lengths are 1.86 Å. N(1) is bonded to five equivalent Sr(1) and one W(1) atom to form a mixture of distorted edge and corner-sharing NSr5W octahedra. The corner-sharing octahedral tilt angles range from 21-42°.