Cu3Ti4O12 crystallizes in the cubic Im-3 space group. Ti(1) is bonded to six equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 43°. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one Cu(1) atom.
Cu3Ti4O12 crystallizes in the cubic Im-3 space group. Ti(1) is bonded to six equivalent O(1) atoms to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Ti(1)-O(1) bond lengths are 1.99 Å. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Cu(1)-O(1) bond lengths are 1.89 Å. O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one Cu(1) atom.