Ni2InSbO6 is Corundum-derived structured and crystallizes in the trigonal R3 space group. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form NiO6 octahedra that share corners with three equivalent In(1)O6 octahedra, corners with six equivalent Ni(2)O6 octahedra, edges with three equivalent Sb(1)O6 octahedra, and  a faceface with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. In the second Ni site, Ni(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted NiO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with six equivalent Ni(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and  a faceface with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. In(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted InO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with six equivalent Sb(1)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and  a faceface with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. Sb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with three equivalent Ni(2)O6 octahedra, corners with six equivalent In(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and  a faceface with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OInNi2Sb trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom.
Ni2InSbO6 is Corundum-derived structured and crystallizes in the trigonal R3 space group. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form NiO6 octahedra that share corners with three equivalent In(1)O6 octahedra, corners with six equivalent Ni(2)O6 octahedra, edges with three equivalent Sb(1)O6 octahedra, and  a faceface with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. All Ni(1)-O(1) bond lengths are 2.15 Å. All Ni(1)-O(2) bond lengths are 2.05 Å. In the second Ni site, Ni(2) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted NiO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with six equivalent Ni(1)O6 octahedra, edges with three equivalent In(1)O6 octahedra, and  a faceface with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-58°. All Ni(2)-O(1) bond lengths are 2.08 Å. All Ni(2)-O(2) bond lengths are 2.16 Å. In(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form distorted InO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with six equivalent Sb(1)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and  a faceface with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. All In(1)-O(1) bond lengths are 2.29 Å. All In(1)-O(2) bond lengths are 2.13 Å. Sb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form SbO6 octahedra that share corners with three equivalent Ni(2)O6 octahedra, corners with six equivalent In(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and  a faceface with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. All Sb(1)-O(1) bond lengths are 2.00 Å. All Sb(1)-O(2) bond lengths are 2.06 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OInNi2Sb trigonal pyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one Ni(1), one Ni(2), one In(1), and one Sb(1) atom.