Ga(NO3)4NO2 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two Ga(NO3)4 clusters. In each Ga(NO3)4 cluster, Ga(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one N(1) atom.
Ga(NO3)4NO2 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two Ga(NO3)4 clusters. In each Ga(NO3)4 cluster, Ga(1) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. All Ga(1)-O(3) bond lengths are 1.90 Å. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The N(1)-O(1) bond length is 1.24 Å. The N(1)-O(2) bond length is 1.23 Å. The N(1)-O(3) bond length is 1.36 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one N(1) atom.