BiOF is Fluorite-derived structured and crystallizes in the monoclinic P2_1 space group. Bi(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Bi(1) atoms to form OBi4 tetrahedra that share corners with four equivalent O(1)Bi4 tetrahedra, corners with twelve equivalent F(1)Bi4 tetrahedra, edges with two equivalent F(1)Bi4 tetrahedra, and edges with four equivalent O(1)Bi4 tetrahedra. F(1) is bonded to four equivalent Bi(1) atoms to form FBi4 tetrahedra that share corners with four equivalent F(1)Bi4 tetrahedra, corners with twelve equivalent O(1)Bi4 tetrahedra, edges with two equivalent O(1)Bi4 tetrahedra, and edges with four equivalent F(1)Bi4 tetrahedra.
BiOF is Fluorite-derived structured and crystallizes in the monoclinic P2_1 space group. Bi(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. There are two shorter (2.36 Å) and two longer (2.38 Å) Bi(1)-O(1) bond lengths. There are a spread of Bi(1)-F(1) bond distances ranging from 2.56-2.63 Å. O(1) is bonded to four equivalent Bi(1) atoms to form OBi4 tetrahedra that share corners with four equivalent O(1)Bi4 tetrahedra, corners with twelve equivalent F(1)Bi4 tetrahedra, edges with two equivalent F(1)Bi4 tetrahedra, and edges with four equivalent O(1)Bi4 tetrahedra. F(1) is bonded to four equivalent Bi(1) atoms to form FBi4 tetrahedra that share corners with four equivalent F(1)Bi4 tetrahedra, corners with twelve equivalent O(1)Bi4 tetrahedra, edges with two equivalent O(1)Bi4 tetrahedra, and edges with four equivalent F(1)Bi4 tetrahedra.