PdC4H16(N2S)4(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one PdC4H16(N2S)4 cluster. In the PdC4H16(N2S)4 cluster, Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(5), and one S(2) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2), one N(4), and one S(1) atom. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(2), and one H(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one C(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(1) atom.
PdC4H16(N2S)4(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one PdC4H16(N2S)4 cluster. In the PdC4H16(N2S)4 cluster, Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. Both Pd(1)-S(1) bond lengths are 2.35 Å. Both Pd(1)-S(2) bond lengths are 2.38 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(5), and one S(2) atom. The C(1)-N(3) bond length is 1.33 Å. The C(1)-N(5) bond length is 1.33 Å. The C(1)-S(2) bond length is 1.76 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2), one N(4), and one S(1) atom. The C(2)-N(2) bond length is 1.33 Å. The C(2)-N(4) bond length is 1.34 Å. The C(2)-S(1) bond length is 1.72 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(2), and one H(7) atom. The N(5)-H(2) bond length is 1.03 Å. The N(5)-H(7) bond length is 1.03 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(3) atom. The N(2)-H(1) bond length is 1.03 Å. The N(2)-H(3) bond length is 1.02 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(6) atom. The N(3)-H(4) bond length is 1.02 Å. The N(3)-H(6) bond length is 1.02 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(8) atom. The N(4)-H(5) bond length is 1.02 Å. The N(4)-H(8) bond length is 1.01 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one C(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(1) atom.