AsF6(SeBr)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three SeBr clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(15), one F(16), one F(5), one F(6), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(15) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(16) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In one of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(5) is bonded in a water-like geometry to one Se(9) and one Br(1) atom. In the second Se site, Se(6) is bonded in a distorted water-like geometry to one Se(9), one Br(2), and one Br(9) atom. In the third Se site, Se(9) is bonded in a water-like geometry to one Se(5) and one Se(6) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Se(5) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Se(6) atom. In the third Br site, Br(9) is bonded in a single-bond geometry to one Se(6) atom. In two of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one Se(3) and one Se(7) atom. In the second Se site, Se(3) is bonded in a distorted water-like geometry to one Se(1), one Br(3), and one Br(7) atom. In the third Se site, Se(7) is bonded in a water-like geometry to one Se(1) and one Br(5) atom. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Se(3) atom. In the second Br site, Br(5) is bonded in a single-bond geometry to one Se(7) atom. In the third Br site, Br(7) is bonded in a single-bond geometry to one Se(3) atom.
AsF6(SeBr)3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three SeBr clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(15), one F(16), one F(5), one F(6), one F(7), and one F(8) atom. The As(1)-F(15) bond length is 1.77 Å. The As(1)-F(16) bond length is 1.77 Å. The As(1)-F(5) bond length is 1.79 Å. The As(1)-F(6) bond length is 1.79 Å. The As(1)-F(7) bond length is 1.78 Å. The As(1)-F(8) bond length is 1.78 Å. There are six inequivalent F sites. In the first F site, F(15) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(16) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In one of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(5) is bonded in a water-like geometry to one Se(9) and one Br(1) atom. The Se(5)-Se(9) bond length is 2.22 Å. The Se(5)-Br(1) bond length is 2.36 Å. In the second Se site, Se(6) is bonded in a distorted water-like geometry to one Se(9), one Br(2), and one Br(9) atom. The Se(6)-Se(9) bond length is 2.67 Å. The Se(6)-Br(2) bond length is 2.32 Å. The Se(6)-Br(9) bond length is 2.29 Å. In the third Se site, Se(9) is bonded in a water-like geometry to one Se(5) and one Se(6) atom. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Se(5) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Se(6) atom. In the third Br site, Br(9) is bonded in a single-bond geometry to one Se(6) atom. In two of the SeBr clusters, there are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one Se(3) and one Se(7) atom. The Se(1)-Se(3) bond length is 2.68 Å. The Se(1)-Se(7) bond length is 2.21 Å. In the second Se site, Se(3) is bonded in a distorted water-like geometry to one Se(1), one Br(3), and one Br(7) atom. The Se(3)-Br(3) bond length is 2.29 Å. The Se(3)-Br(7) bond length is 2.31 Å. In the third Se site, Se(7) is bonded in a water-like geometry to one Se(1) and one Br(5) atom. The Se(7)-Br(5) bond length is 2.38 Å. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Se(3) atom. In the second Br site, Br(5) is bonded in a single-bond geometry to one Se(7) atom. In the third Br site, Br(7) is bonded in a single-bond geometry to one Se(3) atom.