(Na)2NaPrCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaPrCl6 framework. In the NaPrCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Pr(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Pr(1) is bonded to six equivalent Cl(1) atoms to form PrCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Na(2) and one Pr(1) atom.
(Na)2NaPrCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaPrCl6 framework. In the NaPrCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Pr(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-Cl(1) bond lengths are 2.71 Å. Pr(1) is bonded to six equivalent Cl(1) atoms to form PrCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Pr(1)-Cl(1) bond lengths are 2.73 Å. Cl(1) is bonded in a linear geometry to one Na(2) and one Pr(1) atom.