Cs2Ti(AgS2)2 crystallizes in the tetragonal P4_2/mcm space group. Cs(1) is bonded in a distorted body-centered cubic geometry to eight equivalent S(1) atoms. Ti(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Ti(1), and two equivalent Ag(1) atoms.
Cs2Ti(AgS2)2 crystallizes in the tetragonal P4_2/mcm space group. Cs(1) is bonded in a distorted body-centered cubic geometry to eight equivalent S(1) atoms. There are four shorter (3.62 Å) and four longer (3.84 Å) Cs(1)-S(1) bond lengths. Ti(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All Ti(1)-S(1) bond lengths are 2.31 Å. Ag(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All Ag(1)-S(1) bond lengths are 2.58 Å. S(1) is bonded in a 7-coordinate geometry to four equivalent Cs(1), one Ti(1), and two equivalent Ag(1) atoms.