VNH4(OF2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four VNH4(OF2)2 clusters. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. N(1) is bonded in a distorted tetrahedral geometry to one H(2), one H(3), one H(4), and one O(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one N(1) and one H(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one H(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one V(1) atom.
VNH4(OF2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four VNH4(OF2)2 clusters. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. The V(1)-O(1) bond length is 1.60 Å. The V(1)-F(1) bond length is 1.84 Å. The V(1)-F(2) bond length is 1.85 Å. The V(1)-F(3) bond length is 1.87 Å. The V(1)-F(4) bond length is 1.86 Å. N(1) is bonded in a distorted tetrahedral geometry to one H(2), one H(3), one H(4), and one O(2) atom. The N(1)-H(2) bond length is 1.03 Å. The N(1)-H(3) bond length is 1.04 Å. The N(1)-H(4) bond length is 1.04 Å. The N(1)-O(2) bond length is 1.42 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. The H(1)-O(2) bond length is 1.00 Å. The H(1)-F(3) bond length is 1.60 Å. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one N(1) and one H(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one H(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one V(1) atom.