NHS2(O2Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four imidodisulfuryl chloride molecules. N(1) is bonded in a trigonal planar geometry to one H(1), one S(1), and one S(2) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(2), and one Cl(1) atom to form distorted corner-sharing SNClO2 tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(3), one O(4), and one Cl(2) atom to form distorted corner-sharing SNClO2 tetrahedra. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(2) atom.
NHS2(O2Cl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four imidodisulfuryl chloride molecules. N(1) is bonded in a trigonal planar geometry to one H(1), one S(1), and one S(2) atom. The N(1)-H(1) bond length is 1.03 Å. The N(1)-S(1) bond length is 1.67 Å. The N(1)-S(2) bond length is 1.66 Å. H(1) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(2), and one Cl(1) atom to form distorted corner-sharing SNClO2 tetrahedra. The S(1)-O(1) bond length is 1.43 Å. The S(1)-O(2) bond length is 1.43 Å. The S(1)-Cl(1) bond length is 2.03 Å. In the second S site, S(2) is bonded to one N(1), one O(3), one O(4), and one Cl(2) atom to form distorted corner-sharing SNClO2 tetrahedra. The S(2)-O(3) bond length is 1.43 Å. The S(2)-O(4) bond length is 1.44 Å. The S(2)-Cl(2) bond length is 2.02 Å. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(2) atom.