PtC2(N2S)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PtC2(N2S)2 clusters. Pt(1) is bonded in a 4-coordinate geometry to one N(3), one N(4), one S(1), and one S(2) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one Pt(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pt(1) and one C(2) atom.
PtC2(N2S)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PtC2(N2S)2 clusters. Pt(1) is bonded in a 4-coordinate geometry to one N(3), one N(4), one S(1), and one S(2) atom. The Pt(1)-N(3) bond length is 1.80 Å. The Pt(1)-N(4) bond length is 1.79 Å. The Pt(1)-S(1) bond length is 2.56 Å. The Pt(1)-S(2) bond length is 2.28 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.18 Å. The C(1)-S(1) bond length is 1.66 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(2) bond length is 1.68 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth N site, N(3) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one Pt(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pt(1) and one C(2) atom.