KP(OF)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to six equivalent O(1), one F(1), and one F(2) atom. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one K(1) and one P(1) atom.
KP(OF)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to six equivalent O(1), one F(1), and one F(2) atom. There are a spread of K(1)-O(1) bond distances ranging from 2.71-3.02 Å. The K(1)-F(1) bond length is 2.73 Å. The K(1)-F(2) bond length is 3.08 Å. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. Both P(1)-O(1) bond lengths are 1.47 Å. The P(1)-F(1) bond length is 1.58 Å. The P(1)-F(2) bond length is 1.58 Å. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one K(1) and one P(1) atom.