AgClO3 crystallizes in the tetragonal I4/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted trigonal pyramidal geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1) and two equivalent O(2) atoms.
AgClO3 crystallizes in the tetragonal I4/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. All Ag(1)-O(1) bond lengths are 2.75 Å. All Ag(1)-O(2) bond lengths are 2.62 Å. In the second Ag site, Ag(2) is bonded in a distorted trigonal pyramidal geometry to four equivalent O(2) atoms. All Ag(2)-O(2) bond lengths are 2.41 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one Cl(1) atom. The O(1)-Cl(1) bond length is 1.51 Å. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Cl(1) atom. The O(2)-Cl(1) bond length is 1.52 Å. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(1) and two equivalent O(2) atoms.