TiMnP crystallizes in the hexagonal P-62m space group. Ti(1) is bonded in a 5-coordinate geometry to one P(2) and four equivalent P(1) atoms. Mn(1) is bonded to two equivalent P(1) and two equivalent P(2) atoms to form a mixture of distorted corner and edge-sharing MnP4 tetrahedra. There are two inequivalent P sites. In the first P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Ti(1) and six equivalent Mn(1) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Ti(1) and three equivalent Mn(1) atoms.
TiMnP crystallizes in the hexagonal P-62m space group. Ti(1) is bonded in a 5-coordinate geometry to one P(2) and four equivalent P(1) atoms. The Ti(1)-P(2) bond length is 2.54 Å. All Ti(1)-P(1) bond lengths are 2.52 Å. Mn(1) is bonded to two equivalent P(1) and two equivalent P(2) atoms to form a mixture of distorted corner and edge-sharing MnP4 tetrahedra. Both Mn(1)-P(1) bond lengths are 2.37 Å. Both Mn(1)-P(2) bond lengths are 2.28 Å. There are two inequivalent P sites. In the first P site, P(2) is bonded in a 9-coordinate geometry to three equivalent Ti(1) and six equivalent Mn(1) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to six equivalent Ti(1) and three equivalent Mn(1) atoms.