MnOF crystallizes in the triclinic P-1 space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 16-29°. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Mn(1) atoms.
MnOF crystallizes in the triclinic P-1 space group. Mn(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 16-29°. There are two shorter (1.91 Å) and one longer (1.92 Å) Mn(1)-O(1) bond length. There are a spread of Mn(1)-F(1) bond distances ranging from 1.96-2.27 Å. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Mn(1) atoms.