LiAsO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. As(1) is bonded to six equivalent O(1) atoms to form edge-sharing AsO6 octahedra. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Li(1) and two equivalent As(1) atoms.
LiAsO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Li(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. There are three shorter (1.99 Å) and three longer (2.32 Å) Li(1)-O(1) bond lengths. As(1) is bonded to six equivalent O(1) atoms to form edge-sharing AsO6 octahedra. There are three shorter (1.82 Å) and three longer (1.86 Å) As(1)-O(1) bond lengths. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Li(1) and two equivalent As(1) atoms.