LiVF3 crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. V(1) is bonded to six equivalent F(1) atoms to form distorted face-sharing VF6 octahedra. F(1) is bonded in a distorted T-shaped geometry to one Li(1) and two equivalent V(1) atoms.
LiVF3 crystallizes in the hexagonal P6_3/mmc space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. All Li(1)-F(1) bond lengths are 1.84 Å. V(1) is bonded to six equivalent F(1) atoms to form distorted face-sharing VF6 octahedra. All V(1)-F(1) bond lengths are 2.13 Å. F(1) is bonded in a distorted T-shaped geometry to one Li(1) and two equivalent V(1) atoms.