C3H8S2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four bis(methylthio)methane molecules. There are three inequivalent C sites. In the first C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(2), one H(5), one H(8), and one S(2) atom. In the second C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(3), one H(4), and one S(1) atom. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(6), one H(7), one S(1), and one S(2) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one C(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one C(3) atom.
C3H8S2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four bis(methylthio)methane molecules. There are three inequivalent C sites. In the first C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(2), one H(5), one H(8), and one S(2) atom. The C(2)-H(2) bond length is 1.10 Å. The C(2)-H(5) bond length is 1.10 Å. The C(2)-H(8) bond length is 1.10 Å. The C(2)-S(2) bond length is 1.81 Å. In the second C site, C(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(3), one H(4), and one S(1) atom. The C(1)-H(1) bond length is 1.10 Å. The C(1)-H(3) bond length is 1.10 Å. The C(1)-H(4) bond length is 1.10 Å. The C(1)-S(1) bond length is 1.81 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one H(6), one H(7), one S(1), and one S(2) atom. The C(3)-H(6) bond length is 1.10 Å. The C(3)-H(7) bond length is 1.10 Å. The C(3)-S(1) bond length is 1.81 Å. The C(3)-S(2) bond length is 1.82 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one C(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one C(3) atom.