LiOsF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Os(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. Os(1) is bonded to six equivalent F(1) atoms to form OsF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Os(1) atom.
LiOsF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Os(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. All Li(1)-F(1) bond lengths are 1.99 Å. Os(1) is bonded to six equivalent F(1) atoms to form OsF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 38°. All Os(1)-F(1) bond lengths are 1.90 Å. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Os(1) atom.