C2N2S9 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two (cyanooctasulfanyl) thiocyanate molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(2) atom. There are nine inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(5) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(6) and one S(8) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one S(7) and one S(9) atom. In the ninth S site, S(9) is bonded in a water-like geometry to one C(2) and one S(8) atom.
C2N2S9 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two (cyanooctasulfanyl) thiocyanate molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(1) and one S(1) atom. The C(1)-N(1) bond length is 1.17 Å. The C(1)-S(1) bond length is 1.69 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(9) atom. The C(2)-N(2) bond length is 1.18 Å. The C(2)-S(9) bond length is 1.68 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(2) atom. There are nine inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one S(2) atom. The S(1)-S(2) bond length is 2.10 Å. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. The S(2)-S(3) bond length is 2.04 Å. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. The S(3)-S(4) bond length is 2.08 Å. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. The S(4)-S(5) bond length is 2.06 Å. In the fifth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. The S(5)-S(6) bond length is 2.06 Å. In the sixth S site, S(6) is bonded in a water-like geometry to one S(5) and one S(7) atom. The S(6)-S(7) bond length is 2.08 Å. In the seventh S site, S(7) is bonded in a water-like geometry to one S(6) and one S(8) atom. The S(7)-S(8) bond length is 2.04 Å. In the eighth S site, S(8) is bonded in a water-like geometry to one S(7) and one S(9) atom. The S(8)-S(9) bond length is 2.10 Å. In the ninth S site, S(9) is bonded in a water-like geometry to one C(2) and one S(8) atom.