CoOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. Co(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing CoO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-53°. O(1) is bonded in a trigonal planar geometry to three equivalent Co(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Co(1) atoms.
CoOF is Hydrophilite-derived structured and crystallizes in the tetragonal P4_12_12 space group. Co(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of edge and corner-sharing CoO3F3 octahedra. The corner-sharing octahedral tilt angles range from 47-53°. There is one shorter (1.85 Å) and two longer (1.91 Å) Co(1)-O(1) bond lengths. There is one shorter (1.94 Å) and two longer (2.08 Å) Co(1)-F(1) bond lengths. O(1) is bonded in a trigonal planar geometry to three equivalent Co(1) atoms. F(1) is bonded in a distorted trigonal planar geometry to three equivalent Co(1) atoms.