SbN3S4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SbN3S4 cluster. Sb(1) is bonded in a 3-coordinate geometry to one N(2), one S(1), and one S(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one S(1) and one S(3) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one Sb(1) and one S(4) atom. In the third N site, N(3) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one Sb(1), one N(1), and one N(3) atom. In the second S site, S(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(1) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(2) atom.
SbN3S4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SbN3S4 cluster. Sb(1) is bonded in a 3-coordinate geometry to one N(2), one S(1), and one S(2) atom. The Sb(1)-N(2) bond length is 2.18 Å. The Sb(1)-S(1) bond length is 2.62 Å. The Sb(1)-S(2) bond length is 2.55 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one S(1) and one S(3) atom. The N(1)-S(1) bond length is 1.21 Å. The N(1)-S(3) bond length is 2.09 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one Sb(1) and one S(4) atom. The N(2)-S(4) bond length is 1.34 Å. In the third N site, N(3) is bonded in a single-bond geometry to one S(1) atom. The N(3)-S(1) bond length is 1.60 Å. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one Sb(1), one N(1), and one N(3) atom. In the second S site, S(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(1) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one N(2) atom.