KMoF6(NH4)2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonium molecules inside a KMoF6 framework. In the KMoF6 framework, K(1) is bonded to six equivalent F(1) atoms to form KF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedra are not tilted. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent K(1)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one K(1) and one Mo(1) atom.
KMoF6(NH4)2 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight ammonium molecules inside a KMoF6 framework. In the KMoF6 framework, K(1) is bonded to six equivalent F(1) atoms to form KF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra. The corner-sharing octahedra are not tilted. All K(1)-F(1) bond lengths are 2.57 Å. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent K(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Mo(1)-F(1) bond lengths are 2.09 Å. F(1) is bonded in a linear geometry to one K(1) and one Mo(1) atom.