PdN4RhN5O8NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, two nitrous acid molecules, and two RhN5O8 clusters. In each RhN5O8 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(7), two equivalent N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Rh(1), one O(3), and one O(4) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Rh(1), one O(5), and one O(6) atom. In the third N site, N(7) is bonded in a single-bond geometry to one Rh(1) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(2) atom.
PdN4RhN5O8NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, two nitrous acid molecules, and two RhN5O8 clusters. In each RhN5O8 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(7), two equivalent N(2), and two equivalent N(3) atoms. The Rh(1)-N(7) bond length is 1.66 Å. Both Rh(1)-N(2) bond lengths are 2.21 Å. Both Rh(1)-N(3) bond lengths are 2.20 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Rh(1), one O(3), and one O(4) atom. The N(2)-O(3) bond length is 1.22 Å. The N(2)-O(4) bond length is 1.23 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one Rh(1), one O(5), and one O(6) atom. The N(3)-O(5) bond length is 1.22 Å. The N(3)-O(6) bond length is 1.22 Å. In the third N site, N(7) is bonded in a single-bond geometry to one Rh(1) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(2) atom.