NaVTeO5 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. V(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), and two equivalent O(1) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one Te(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent Na(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one V(1) atom.
NaVTeO5 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. The Na(1)-O(4) bond length is 2.75 Å. There is one shorter (2.48 Å) and one longer (2.86 Å) Na(1)-O(1) bond length. There is one shorter (2.50 Å) and one longer (2.65 Å) Na(1)-O(3) bond length. There is one shorter (2.42 Å) and one longer (2.49 Å) Na(1)-O(5) bond length. V(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom. The V(1)-O(2) bond length is 1.81 Å. The V(1)-O(3) bond length is 1.70 Å. The V(1)-O(4) bond length is 1.85 Å. The V(1)-O(5) bond length is 1.67 Å. Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), and two equivalent O(1) atoms. The Te(1)-O(2) bond length is 2.12 Å. The Te(1)-O(4) bond length is 1.95 Å. There is one shorter (1.94 Å) and one longer (2.14 Å) Te(1)-O(1) bond length. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Na(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one V(1) and one Te(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent Na(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one V(1) atom.