TiNiO6 crystallizes in the trigonal R3 space group. Ti(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. Ni(1) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one Ni(1) atom. In the second O site, O(1) is bonded in a water-like geometry to one Ti(1) and one Ni(1) atom.
TiNiO6 crystallizes in the trigonal R3 space group. Ti(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. All Ti(1)-O(1) bond lengths are 2.14 Å. All Ti(1)-O(2) bond lengths are 1.84 Å. Ni(1) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(2) atoms. All Ni(1)-O(1) bond lengths are 1.85 Å. All Ni(1)-O(2) bond lengths are 1.83 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ti(1) and one Ni(1) atom. In the second O site, O(1) is bonded in a water-like geometry to one Ti(1) and one Ni(1) atom.