LiIrF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Ir(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. Ir(1) is bonded to six equivalent F(1) atoms to form IrF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Ir(1) atom.
LiIrF6 crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent F(1) atoms to form LiF6 octahedra that share corners with six equivalent Ir(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Li(1)-F(1) bond lengths are 1.98 Å. Ir(1) is bonded to six equivalent F(1) atoms to form IrF6 octahedra that share corners with six equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. All Ir(1)-F(1) bond lengths are 1.90 Å. F(1) is bonded in a bent 150 degrees geometry to one Li(1) and one Ir(1) atom.