RbLiS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Rb(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing LiS4 tetrahedra. S(1) is bonded in a 4-coordinate geometry to five equivalent Rb(1) and four equivalent Li(1) atoms.
RbLiS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Rb(1) is bonded in a 5-coordinate geometry to five equivalent S(1) atoms. There are four shorter (3.34 Å) and one longer (3.52 Å) Rb(1)-S(1) bond length. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing LiS4 tetrahedra. All Li(1)-S(1) bond lengths are 2.54 Å. S(1) is bonded in a 4-coordinate geometry to five equivalent Rb(1) and four equivalent Li(1) atoms.