ZrNF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Zr(1) is bonded to four equivalent N(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing ZrN4F3 pentagonal bipyramids. N(1) is bonded to four equivalent Zr(1) atoms to form a mixture of edge and corner-sharing NZr4 tetrahedra. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Zr(1) atoms.
ZrNF is Baddeleyite-derived structured and crystallizes in the monoclinic P2_1/c space group. Zr(1) is bonded to four equivalent N(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing ZrN4F3 pentagonal bipyramids. There are a spread of Zr(1)-N(1) bond distances ranging from 2.11-2.16 Å. There are a spread of Zr(1)-F(1) bond distances ranging from 2.21-2.41 Å. N(1) is bonded to four equivalent Zr(1) atoms to form a mixture of edge and corner-sharing NZr4 tetrahedra. F(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Zr(1) atoms.