Lu2WO6 crystallizes in the monoclinic P2/c space group. There are three inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Lu site, Lu(2) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. In the third Lu site, Lu(3) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. W(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the second O site, O(2) is bonded to one Lu(1), two equivalent Lu(2), and one W(1) atom to form a mixture of corner and edge-sharing OLu3W tetrahedra. In the third O site, O(3) is bonded to one Lu(1), one Lu(2), one Lu(3), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLu3W tetrahedra. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Lu(2), one Lu(3), and one W(1) atom. In the fifth O site, O(5) is bonded to one Lu(1), one Lu(2), one Lu(3), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLu3W tetrahedra. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Lu(2), one Lu(3), and one W(1) atom.
Lu2WO6 crystallizes in the monoclinic P2/c space group. There are three inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. Both Lu(1)-O(1) bond lengths are 2.30 Å. Both Lu(1)-O(2) bond lengths are 2.22 Å. Both Lu(1)-O(3) bond lengths are 2.46 Å. Both Lu(1)-O(5) bond lengths are 2.20 Å. In the second Lu site, Lu(2) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. The Lu(2)-O(1) bond length is 2.17 Å. The Lu(2)-O(3) bond length is 2.32 Å. The Lu(2)-O(4) bond length is 2.25 Å. The Lu(2)-O(5) bond length is 2.18 Å. The Lu(2)-O(6) bond length is 2.21 Å. There is one shorter (2.19 Å) and one longer (2.36 Å) Lu(2)-O(2) bond length. In the third Lu site, Lu(3) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Both Lu(3)-O(3) bond lengths are 2.26 Å. Both Lu(3)-O(4) bond lengths are 2.25 Å. Both Lu(3)-O(5) bond lengths are 2.42 Å. Both Lu(3)-O(6) bond lengths are 2.34 Å. W(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The W(1)-O(1) bond length is 1.88 Å. The W(1)-O(2) bond length is 2.02 Å. The W(1)-O(3) bond length is 1.96 Å. The W(1)-O(4) bond length is 1.85 Å. The W(1)-O(5) bond length is 2.05 Å. The W(1)-O(6) bond length is 1.87 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Lu(1), one Lu(2), and one W(1) atom. In the second O site, O(2) is bonded to one Lu(1), two equivalent Lu(2), and one W(1) atom to form a mixture of corner and edge-sharing OLu3W tetrahedra. In the third O site, O(3) is bonded to one Lu(1), one Lu(2), one Lu(3), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLu3W tetrahedra. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Lu(2), one Lu(3), and one W(1) atom. In the fifth O site, O(5) is bonded to one Lu(1), one Lu(2), one Lu(3), and one W(1) atom to form a mixture of distorted corner and edge-sharing OLu3W tetrahedra. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Lu(2), one Lu(3), and one W(1) atom.