Ce8Pd24In crystallizes in the cubic Pm-3m space group. Ce(1) is bonded to three equivalent Pd(2), three equivalent Pd(3), and six equivalent Pd(1) atoms to form CePd12 cuboctahedra that share corners with twelve equivalent Ce(1)Pd12 cuboctahedra, faces with six equivalent Ce(1)Pd12 cuboctahedra, and  a faceface with one In(1)Pd6 octahedra. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to four equivalent Ce(1) and two equivalent Pd(2) atoms. In the second Pd site, Pd(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Ce(1), four equivalent Pd(1), and four equivalent Pd(2) atoms. In the third Pd site, Pd(3) is bonded in a 5-coordinate geometry to four equivalent Ce(1) and one In(1) atom. In(1) is bonded to six equivalent Pd(3) atoms to form InPd6 octahedra that share faces with eight equivalent Ce(1)Pd12 cuboctahedra.
Ce8Pd24In crystallizes in the cubic Pm-3m space group. Ce(1) is bonded to three equivalent Pd(2), three equivalent Pd(3), and six equivalent Pd(1) atoms to form CePd12 cuboctahedra that share corners with twelve equivalent Ce(1)Pd12 cuboctahedra, faces with six equivalent Ce(1)Pd12 cuboctahedra, and  a faceface with one In(1)Pd6 octahedra. All Ce(1)-Pd(2) bond lengths are 3.02 Å. All Ce(1)-Pd(3) bond lengths are 3.05 Å. All Ce(1)-Pd(1) bond lengths are 3.01 Å. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to four equivalent Ce(1) and two equivalent Pd(2) atoms. Both Pd(1)-Pd(2) bond lengths are 2.94 Å. In the second Pd site, Pd(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Ce(1), four equivalent Pd(1), and four equivalent Pd(2) atoms. All Pd(2)-Pd(2) bond lengths are 2.94 Å. In the third Pd site, Pd(3) is bonded in a 5-coordinate geometry to four equivalent Ce(1) and one In(1) atom. The Pd(3)-In(1) bond length is 2.67 Å. In(1) is bonded to six equivalent Pd(3) atoms to form InPd6 octahedra that share faces with eight equivalent Ce(1)Pd12 cuboctahedra.