GaTeO3F crystallizes in the monoclinic P2_1/c space group. Ga(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent F(1) atoms to form edge-sharing GaO4F2 octahedra. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ga(1) and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ga(1) and two equivalent Te(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one Te(1) atom. F(1) is bonded in a water-like geometry to two equivalent Ga(1) atoms.
GaTeO3F crystallizes in the monoclinic P2_1/c space group. Ga(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent F(1) atoms to form edge-sharing GaO4F2 octahedra. The Ga(1)-O(2) bond length is 1.97 Å. The Ga(1)-O(3) bond length is 1.94 Å. There is one shorter (1.96 Å) and one longer (2.01 Å) Ga(1)-O(1) bond length. There is one shorter (1.98 Å) and one longer (2.07 Å) Ga(1)-F(1) bond length. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. The Te(1)-O(1) bond length is 1.97 Å. The Te(1)-O(3) bond length is 1.90 Å. There is one shorter (1.93 Å) and one longer (2.60 Å) Te(1)-O(2) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ga(1) and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ga(1) and two equivalent Te(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one Te(1) atom. F(1) is bonded in a water-like geometry to two equivalent Ga(1) atoms.