LiO4Li13(WO4)7 crystallizes in the cubic P-43m space group. The structure consists of one lioh.3h2o molecule inside a Li13(WO4)7 framework. In the Li13(WO4)7 framework, there are three inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and  an edgeedge with one W(2)O4 tetrahedra. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(4) and three equivalent O(2) atoms. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to four equivalent O(2) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second W site, W(2) is bonded to four equivalent O(1) atoms to form WO4 tetrahedra that share edges with two equivalent Li(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one W(1) atom. In the second O site, O(4) is bonded to one Li(2) and three equivalent Li(1) atoms to form corner-sharing OLi4 tetrahedra. In the third O site, O(1) is bonded in an L-shaped geometry to one Li(1) and one W(2) atom.
LiO4Li13(WO4)7 crystallizes in the cubic P-43m space group. The structure consists of one lioh.3h2o molecule inside a Li13(WO4)7 framework. In the Li13(WO4)7 framework, there are three inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and  an edgeedge with one W(2)O4 tetrahedra. Both Li(1)-O(1) bond lengths are 2.02 Å. Both Li(1)-O(4) bond lengths are 1.85 Å. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(4) and three equivalent O(2) atoms. The Li(2)-O(4) bond length is 1.88 Å. All Li(2)-O(2) bond lengths are 2.33 Å. In the third Li site, Li(3) is bonded in a 4-coordinate geometry to four equivalent O(2) atoms. All Li(3)-O(2) bond lengths are 2.37 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. All W(1)-O(2) bond lengths are 1.83 Å. In the second W site, W(2) is bonded to four equivalent O(1) atoms to form WO4 tetrahedra that share edges with two equivalent Li(1)O4 tetrahedra. All W(2)-O(1) bond lengths are 1.82 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), and one W(1) atom. In the second O site, O(4) is bonded to one Li(2) and three equivalent Li(1) atoms to form corner-sharing OLi4 tetrahedra. In the third O site, O(1) is bonded in an L-shaped geometry to one Li(1) and one W(2) atom.