Sb3F16(Br)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7726-95-6 molecules and four Sb3F16 clusters. In each Sb3F16 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the second Sb site, Sb(2) is bonded to two equivalent F(4) and four equivalent F(5,6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are seven inequivalent F sites. In the first F site, F(5,6) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(4) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom.
Sb3F16(Br)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7726-95-6 molecules and four Sb3F16 clusters. In each Sb3F16 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. The Sb(1)-F(1) bond length is 1.87 Å. The Sb(1)-F(2) bond length is 1.86 Å. The Sb(1)-F(3) bond length is 1.88 Å. The Sb(1)-F(4) bond length is 2.10 Å. The Sb(1)-F(7) bond length is 1.88 Å. The Sb(1)-F(8) bond length is 1.89 Å. In the second Sb site, Sb(2) is bonded to two equivalent F(4) and four equivalent F(5,6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. Both Sb(2)-F(4) bond lengths are 2.00 Å. All Sb(2)-F(5,6) bond lengths are 1.87 Å. There are seven inequivalent F sites. In the first F site, F(5,6) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(4) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom.