RuN2Cl3N2(NO)2 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, eight nitroxyl molecules, and four RuN2Cl3 clusters. In each RuN2Cl3 cluster, Ru(1) is bonded in a 4-coordinate geometry to one N(4), one N(6), one Cl(1), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one Cl(3) atom. In the second N site, N(6) is bonded in a single-bond geometry to one Ru(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one N(4) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom.
RuN2Cl3N2(NO)2 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, eight nitroxyl molecules, and four RuN2Cl3 clusters. In each RuN2Cl3 cluster, Ru(1) is bonded in a 4-coordinate geometry to one N(4), one N(6), one Cl(1), and one Cl(2) atom. The Ru(1)-N(4) bond length is 1.90 Å. The Ru(1)-N(6) bond length is 1.64 Å. The Ru(1)-Cl(1) bond length is 2.30 Å. The Ru(1)-Cl(2) bond length is 2.27 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one Cl(3) atom. The N(4)-Cl(3) bond length is 1.66 Å. In the second N site, N(6) is bonded in a single-bond geometry to one Ru(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one N(4) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Ru(1) atom.