LiV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(1) atom.
LiV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. All Li(1)-O(1) bond lengths are 2.21 Å. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. All V(1)-O(1) bond lengths are 2.06 Å. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All C(1)-O(1) bond lengths are 1.30 Å. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(1) atom.