AgRhO2 crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to six equivalent O(1) atoms to form edge-sharing RhO6 octahedra. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to three equivalent Rh(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OAgRh3 tetrahedra.
AgRhO2 crystallizes in the hexagonal P6_3/mmc space group. Rh(1) is bonded to six equivalent O(1) atoms to form edge-sharing RhO6 octahedra. All Rh(1)-O(1) bond lengths are 2.07 Å. Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. Both Ag(1)-O(1) bond lengths are 2.15 Å. O(1) is bonded to three equivalent Rh(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OAgRh3 tetrahedra.