AgH8(CN2)4BF4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AgH8(CN2)4 clusters and two BF4 clusters. In each AgH8(CN2)4 cluster, Ag(1) is bonded in a linear geometry to one N(1) and one N(5) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(5) and one N(6) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(3), one N(4), and one N(8) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2), one N(6), and one N(7) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Ag(1) and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(4), one H(1), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(3), one H(2), and one H(4) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the fifth N site, N(5) is bonded in a linear geometry to one Ag(1) and one C(1) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(1) and one C(4) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(4), one H(5), and one H(6) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(3), one H(7), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(8) atom. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom.
AgH8(CN2)4BF4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AgH8(CN2)4 clusters and two BF4 clusters. In each AgH8(CN2)4 cluster, Ag(1) is bonded in a linear geometry to one N(1) and one N(5) atom. The Ag(1)-N(1) bond length is 2.06 Å. The Ag(1)-N(5) bond length is 2.06 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(5) and one N(6) atom. The C(1)-N(5) bond length is 1.17 Å. The C(1)-N(6) bond length is 1.29 Å. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(4) atom. The C(2)-N(1) bond length is 1.17 Å. The C(2)-N(4) bond length is 1.29 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(3), one N(4), and one N(8) atom. The C(3)-N(3) bond length is 1.33 Å. The C(3)-N(4) bond length is 1.35 Å. The C(3)-N(8) bond length is 1.33 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2), one N(6), and one N(7) atom. The C(4)-N(2) bond length is 1.33 Å. The C(4)-N(6) bond length is 1.35 Å. The C(4)-N(7) bond length is 1.33 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Ag(1) and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(4), one H(1), and one H(3) atom. The N(2)-H(1) bond length is 1.01 Å. The N(2)-H(3) bond length is 1.01 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(3), one H(2), and one H(4) atom. The N(3)-H(2) bond length is 1.01 Å. The N(3)-H(4) bond length is 1.01 Å. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the fifth N site, N(5) is bonded in a linear geometry to one Ag(1) and one C(1) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(1) and one C(4) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(4), one H(5), and one H(6) atom. The N(7)-H(5) bond length is 1.01 Å. The N(7)-H(6) bond length is 1.01 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(3), one H(7), and one H(8) atom. The N(8)-H(7) bond length is 1.02 Å. The N(8)-H(8) bond length is 1.01 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(8) atom. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. The B(1)-F(1) bond length is 1.40 Å. The B(1)-F(2) bond length is 1.41 Å. The B(1)-F(3) bond length is 1.42 Å. The B(1)-F(4) bond length is 1.41 Å. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom.