NiSiN2 crystallizes in the hexagonal P6_3/mmc space group. Ni(1) is bonded in a linear geometry to two equivalent N(1) atoms. Si(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. N(1) is bonded in a rectangular see-saw-like geometry to one Ni(1) and three equivalent Si(1) atoms.
NiSiN2 crystallizes in the hexagonal P6_3/mmc space group. Ni(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Ni(1)-N(1) bond lengths are 1.82 Å. Si(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. All Si(1)-N(1) bond lengths are 1.93 Å. N(1) is bonded in a rectangular see-saw-like geometry to one Ni(1) and three equivalent Si(1) atoms.