Ba3BiP is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ba(1) is bonded in a linear geometry to four equivalent Bi(1) and two equivalent P(1) atoms. Bi(1) is bonded to twelve equivalent Ba(1) atoms to form BiBa12 cuboctahedra that share corners with twelve equivalent Bi(1)Ba12 cuboctahedra, faces with six equivalent Bi(1)Ba12 cuboctahedra, and faces with eight equivalent P(1)Ba6 octahedra. P(1) is bonded to six equivalent Ba(1) atoms to form PBa6 octahedra that share corners with six equivalent P(1)Ba6 octahedra and faces with eight equivalent Bi(1)Ba12 cuboctahedra. The corner-sharing octahedra are not tilted.
Ba3BiP is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. Ba(1) is bonded in a linear geometry to four equivalent Bi(1) and two equivalent P(1) atoms. All Ba(1)-Bi(1) bond lengths are 4.34 Å. Both Ba(1)-P(1) bond lengths are 3.07 Å. Bi(1) is bonded to twelve equivalent Ba(1) atoms to form BiBa12 cuboctahedra that share corners with twelve equivalent Bi(1)Ba12 cuboctahedra, faces with six equivalent Bi(1)Ba12 cuboctahedra, and faces with eight equivalent P(1)Ba6 octahedra. P(1) is bonded to six equivalent Ba(1) atoms to form PBa6 octahedra that share corners with six equivalent P(1)Ba6 octahedra and faces with eight equivalent Bi(1)Ba12 cuboctahedra. The corner-sharing octahedra are not tilted.