Pd2BBr crystallizes in the cubic F-43m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(2) and four equivalent Br(1) atoms. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to four equivalent Pd(1), four equivalent B(1), and six equivalent Br(1) atoms. B(1) is bonded in a body-centered cubic geometry to four equivalent Pd(2) and four equivalent Br(1) atoms. Br(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(1), six equivalent Pd(2), and four equivalent B(1) atoms.
Pd2BBr crystallizes in the cubic F-43m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(2) and four equivalent Br(1) atoms. All Pd(1)-Pd(2) bond lengths are 2.74 Å. All Pd(1)-Br(1) bond lengths are 2.74 Å. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to four equivalent Pd(1), four equivalent B(1), and six equivalent Br(1) atoms. All Pd(2)-B(1) bond lengths are 2.74 Å. All Pd(2)-Br(1) bond lengths are 3.16 Å. B(1) is bonded in a body-centered cubic geometry to four equivalent Pd(2) and four equivalent Br(1) atoms. All B(1)-Br(1) bond lengths are 2.74 Å. Br(1) is bonded in a distorted body-centered cubic geometry to four equivalent Pd(1), six equivalent Pd(2), and four equivalent B(1) atoms.