ReN2 is Corundum-like structured and crystallizes in the orthorhombic Pbcm space group. Re(1) is bonded to six equivalent N(1) atoms to form edge-sharing ReN6 octahedra. N(1) is bonded in a rectangular see-saw-like geometry to three equivalent Re(1) and one N(1) atom.
ReN2 is Corundum-like structured and crystallizes in the orthorhombic Pbcm space group. Re(1) is bonded to six equivalent N(1) atoms to form edge-sharing ReN6 octahedra. There are a spread of Re(1)-N(1) bond distances ranging from 2.10-2.12 Å. N(1) is bonded in a rectangular see-saw-like geometry to three equivalent Re(1) and one N(1) atom. The N(1)-N(1) bond length is 1.36 Å.