KZrSbO6Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a KZrSbO6 framework. In the KZrSbO6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with four equivalent Zr(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Zr(1) is bonded to six equivalent O(1) atoms to form ZrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Zr(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Zr(1), and one Sb(1) atom.
KZrSbO6Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a KZrSbO6 framework. In the KZrSbO6 framework, K(1) is bonded to twelve equivalent O(1) atoms to form KO12 cuboctahedra that share corners with twelve equivalent K(1)O12 cuboctahedra, faces with four equivalent Zr(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. All K(1)-O(1) bond lengths are 2.90 Å. Zr(1) is bonded to six equivalent O(1) atoms to form ZrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Zr(1)-O(1) bond lengths are 2.11 Å. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Zr(1)O6 octahedra and faces with four equivalent K(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Sb(1)-O(1) bond lengths are 2.00 Å. O(1) is bonded in a distorted linear geometry to two equivalent K(1), one Zr(1), and one Sb(1) atom.