(RbO6)2RbIrN6 crystallizes in the cubic Fm-3m space group. The structure consists of one RbIrN6 framework and one RbO6 framework. In the RbIrN6 framework, Rb(1) is bonded to six equivalent N(1) atoms to form RbN6 octahedra that share corners with six equivalent Ir(1)N6 octahedra. The corner-sharing octahedra are not tilted. Ir(1) is bonded to six equivalent N(1) atoms to form IrN6 octahedra that share corners with six equivalent Rb(1)N6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a single-bond geometry to one Rb(1) and one Ir(1) atom. In the RbO6 framework, Rb(2) is bonded in a distorted q4 geometry to twelve equivalent O(1) atoms. O(1) is bonded in a distorted T-shaped geometry to two equivalent Rb(2) and one O(1) atom.
(RbO6)2RbIrN6 crystallizes in the cubic Fm-3m space group. The structure consists of one RbIrN6 framework and one RbO6 framework. In the RbIrN6 framework, Rb(1) is bonded to six equivalent N(1) atoms to form RbN6 octahedra that share corners with six equivalent Ir(1)N6 octahedra. The corner-sharing octahedra are not tilted. All Rb(1)-N(1) bond lengths are 3.65 Å. Ir(1) is bonded to six equivalent N(1) atoms to form IrN6 octahedra that share corners with six equivalent Rb(1)N6 octahedra. The corner-sharing octahedra are not tilted. All Ir(1)-N(1) bond lengths are 2.00 Å. N(1) is bonded in a single-bond geometry to one Rb(1) and one Ir(1) atom. In the RbO6 framework, Rb(2) is bonded in a distorted q4 geometry to twelve equivalent O(1) atoms. All Rb(2)-O(1) bond lengths are 2.90 Å. O(1) is bonded in a distorted T-shaped geometry to two equivalent Rb(2) and one O(1) atom. The O(1)-O(1) bond length is 1.29 Å.