(Na)2CeCuCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a CeCuCl6 framework. In the CeCuCl6 framework, Ce(1) is bonded to six equivalent Cl(1) atoms to form CeCl6 octahedra that share corners with six equivalent Cu(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cu(1) is bonded to six equivalent Cl(1) atoms to form CuCl6 octahedra that share corners with six equivalent Ce(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Ce(1) and one Cu(1) atom.
(Na)2CeCuCl6 is alpha Rhenium trioxide-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a CeCuCl6 framework. In the CeCuCl6 framework, Ce(1) is bonded to six equivalent Cl(1) atoms to form CeCl6 octahedra that share corners with six equivalent Cu(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Ce(1)-Cl(1) bond lengths are 2.72 Å. Cu(1) is bonded to six equivalent Cl(1) atoms to form CuCl6 octahedra that share corners with six equivalent Ce(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. All Cu(1)-Cl(1) bond lengths are 2.50 Å. Cl(1) is bonded in a linear geometry to one Ce(1) and one Cu(1) atom.