NaInO2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent In(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Na(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. O(1) is bonded to three equivalent Na(1) and three equivalent In(1) atoms to form a mixture of corner and edge-sharing ONa3In3 octahedra. The corner-sharing octahedra are not tilted.
NaInO2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Na(1) is bonded to six equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent In(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. All Na(1)-O(1) bond lengths are 2.43 Å. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Na(1)O6 octahedra, edges with six equivalent Na(1)O6 octahedra, and edges with six equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. All In(1)-O(1) bond lengths are 2.21 Å. O(1) is bonded to three equivalent Na(1) and three equivalent In(1) atoms to form a mixture of corner and edge-sharing ONa3In3 octahedra. The corner-sharing octahedra are not tilted.