PtBiTe is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Pt(1) is bonded to three equivalent Bi(1) and three equivalent Te(1) atoms to form PtBi3Te3 octahedra that share corners with twelve equivalent Pt(1)Bi3Te3 octahedra, corners with three equivalent Bi(1)TePt3 trigonal pyramids, and corners with three equivalent Te(1)BiPt3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 62-63°. Bi(1) is bonded to three equivalent Pt(1) and one Te(1) atom to form distorted BiTePt3 trigonal pyramids that share corners with three equivalent Pt(1)Bi3Te3 octahedra, corners with six equivalent Bi(1)TePt3 trigonal pyramids, and corners with nine equivalent Te(1)BiPt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°. Te(1) is bonded to three equivalent Pt(1) and one Bi(1) atom to form distorted TeBiPt3 trigonal pyramids that share corners with three equivalent Pt(1)Bi3Te3 octahedra, corners with six equivalent Te(1)BiPt3 trigonal pyramids, and corners with nine equivalent Bi(1)TePt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.
PtBiTe is Ilmenite-like structured and crystallizes in the cubic P2_13 space group. Pt(1) is bonded to three equivalent Bi(1) and three equivalent Te(1) atoms to form PtBi3Te3 octahedra that share corners with twelve equivalent Pt(1)Bi3Te3 octahedra, corners with three equivalent Bi(1)TePt3 trigonal pyramids, and corners with three equivalent Te(1)BiPt3 trigonal pyramids. The corner-sharing octahedral tilt angles range from 62-63°. All Pt(1)-Bi(1) bond lengths are 2.80 Å. All Pt(1)-Te(1) bond lengths are 2.76 Å. Bi(1) is bonded to three equivalent Pt(1) and one Te(1) atom to form distorted BiTePt3 trigonal pyramids that share corners with three equivalent Pt(1)Bi3Te3 octahedra, corners with six equivalent Bi(1)TePt3 trigonal pyramids, and corners with nine equivalent Te(1)BiPt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°. The Bi(1)-Te(1) bond length is 3.00 Å. Te(1) is bonded to three equivalent Pt(1) and one Bi(1) atom to form distorted TeBiPt3 trigonal pyramids that share corners with three equivalent Pt(1)Bi3Te3 octahedra, corners with six equivalent Te(1)BiPt3 trigonal pyramids, and corners with nine equivalent Bi(1)TePt3 trigonal pyramids. The corner-sharing octahedral tilt angles are 81°.