(Na)2NaTlF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaTlF6 framework. In the NaTlF6 framework, Na(2) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Na(2)F6 octahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a linear geometry to one Na(2) and one Tl(1) atom.
(Na)2NaTlF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaTlF6 framework. In the NaTlF6 framework, Na(2) is bonded to six equivalent F(1) atoms to form NaF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra. The corner-sharing octahedra are not tilted. All Na(2)-F(1) bond lengths are 2.20 Å. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Na(2)F6 octahedra. The corner-sharing octahedra are not tilted. All Tl(1)-F(1) bond lengths are 2.17 Å. F(1) is bonded in a linear geometry to one Na(2) and one Tl(1) atom.