Ag3SbS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a distorted T-shaped geometry to three equivalent S(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to three equivalent S(1) atoms. S(1) is bonded to three equivalent Ag(1) and one Sb(1) atom to form corner-sharing SAg3Sb trigonal pyramids.
Ag3SbS3 crystallizes in the trigonal R3c space group. Ag(1) is bonded in a distorted T-shaped geometry to three equivalent S(1) atoms. There are a spread of Ag(1)-S(1) bond distances ranging from 2.43-2.79 Å. Sb(1) is bonded in a 3-coordinate geometry to three equivalent S(1) atoms. All Sb(1)-S(1) bond lengths are 2.48 Å. S(1) is bonded to three equivalent Ag(1) and one Sb(1) atom to form corner-sharing SAg3Sb trigonal pyramids.