HgOF crystallizes in the orthorhombic P2_12_12_1 space group. Hg(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing HgO3F3 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. O(1) is bonded in a trigonal planar geometry to three equivalent Hg(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Hg(1) atoms.
HgOF crystallizes in the orthorhombic P2_12_12_1 space group. Hg(1) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing HgO3F3 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. There are a spread of Hg(1)-O(1) bond distances ranging from 2.13-2.19 Å. There are a spread of Hg(1)-F(1) bond distances ranging from 2.13-2.51 Å. O(1) is bonded in a trigonal planar geometry to three equivalent Hg(1) atoms. F(1) is bonded in a 3-coordinate geometry to three equivalent Hg(1) atoms.