Li9Mn7O16 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-17°. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. In the fourth Li site, Li(4) is bonded to one O(4), one O(8), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. In the second Mn site, Mn(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the third Mn site, Mn(3) is bonded to one O(3), one O(4), one O(7), one O(8), and two equivalent O(6) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-17°. In the fourth Mn site, Mn(4) is bonded to two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with four equivalent Li(4)O6 octahedra, and edges with four equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(5), two equivalent Li(1), and two equivalent Mn(1) atoms to form distorted OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with three equivalent O(5)Li4Mn2 octahedra, and edges with four equivalent O(2)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the second O site, O(2) is bonded to one Li(2), one Li(5), two equivalent Li(1), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with three equivalent O(5)Li4Mn2 octahedra, and edges with four equivalent O(1)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Mn(1), one Mn(2), and one Mn(3) atom to form distorted OLi3Mn3 octahedra that share  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra, and edges with two equivalent O(5)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-14°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra, edges with two equivalent O(7)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra, and edges with two equivalent O(5)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with three equivalent O(1)Li4Mn2 octahedra, and edges with three equivalent O(2)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the sixth O site, O(6) is bonded to one Li(3), two equivalent Li(4), one Mn(4), and two equivalent Mn(3) atoms to form OLi3Mn3 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra, edges with three equivalent O(8)Li3Mn3 octahedra, and edges with four equivalent O(7)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the seventh O site, O(7) is bonded to one Li(3), two equivalent Li(4), one Mn(2), one Mn(3), and one Mn(4) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with three equivalent O(8)Li3Mn3 octahedra, and edges with four equivalent O(6)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Li(4), one Mn(2), one Mn(3), and one Mn(4) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with three equivalent O(6)Li3Mn3 octahedra, and edges with three equivalent O(7)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-11°.
Li9Mn7O16 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-17°. The Li(1)-O(3) bond length is 2.19 Å. The Li(1)-O(5) bond length is 2.05 Å. There is one shorter (2.07 Å) and one longer (2.54 Å) Li(1)-O(1) bond length. There is one shorter (2.08 Å) and one longer (2.12 Å) Li(1)-O(2) bond length. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The Li(2)-O(1) bond length is 2.13 Å. The Li(2)-O(2) bond length is 2.13 Å. The Li(2)-O(3) bond length is 2.18 Å. The Li(2)-O(4) bond length is 2.20 Å. The Li(2)-O(5) bond length is 2.12 Å. The Li(2)-O(8) bond length is 2.19 Å. In the third Li site, Li(3) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-9°. The Li(3)-O(3) bond length is 2.55 Å. The Li(3)-O(4) bond length is 2.13 Å. The Li(3)-O(5) bond length is 2.02 Å. The Li(3)-O(6) bond length is 2.15 Å. The Li(3)-O(7) bond length is 2.12 Å. The Li(3)-O(8) bond length is 2.15 Å. In the fourth Li site, Li(4) is bonded to one O(4), one O(8), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. The Li(4)-O(4) bond length is 2.16 Å. The Li(4)-O(8) bond length is 2.19 Å. There is one shorter (2.12 Å) and one longer (2.21 Å) Li(4)-O(6) bond length. There is one shorter (2.15 Å) and one longer (2.16 Å) Li(4)-O(7) bond length. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with four equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. Both Li(5)-O(1) bond lengths are 2.07 Å. Both Li(5)-O(2) bond lengths are 2.26 Å. Both Li(5)-O(5) bond lengths are 2.06 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. The Mn(1)-O(2) bond length is 1.98 Å. The Mn(1)-O(3) bond length is 2.04 Å. The Mn(1)-O(4) bond length is 1.96 Å. The Mn(1)-O(5) bond length is 1.89 Å. There is one shorter (1.92 Å) and one longer (1.94 Å) Mn(1)-O(1) bond length. In the second Mn site, Mn(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. The Mn(2)-O(2) bond length is 1.92 Å. The Mn(2)-O(3) bond length is 2.00 Å. The Mn(2)-O(4) bond length is 1.96 Å. The Mn(2)-O(5) bond length is 2.17 Å. The Mn(2)-O(7) bond length is 1.98 Å. The Mn(2)-O(8) bond length is 2.37 Å. In the third Mn site, Mn(3) is bonded to one O(3), one O(4), one O(7), one O(8), and two equivalent O(6) atoms to form MnO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-17°. The Mn(3)-O(3) bond length is 2.00 Å. The Mn(3)-O(4) bond length is 2.27 Å. The Mn(3)-O(7) bond length is 1.95 Å. The Mn(3)-O(8) bond length is 1.95 Å. There is one shorter (1.98 Å) and one longer (2.29 Å) Mn(3)-O(6) bond length. In the fourth Mn site, Mn(4) is bonded to two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with four equivalent Li(4)O6 octahedra, and edges with four equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. Both Mn(4)-O(6) bond lengths are 1.97 Å. Both Mn(4)-O(7) bond lengths are 2.27 Å. Both Mn(4)-O(8) bond lengths are 1.95 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(5), two equivalent Li(1), and two equivalent Mn(1) atoms to form distorted OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with three equivalent O(5)Li4Mn2 octahedra, and edges with four equivalent O(2)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the second O site, O(2) is bonded to one Li(2), one Li(5), two equivalent Li(1), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(4)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with three equivalent O(5)Li4Mn2 octahedra, and edges with four equivalent O(1)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(3), one Mn(1), one Mn(2), and one Mn(3) atom to form distorted OLi3Mn3 octahedra that share  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(6)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra, edges with two equivalent O(1)Li4Mn2 octahedra, edges with two equivalent O(2)Li4Mn2 octahedra, and edges with two equivalent O(5)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-14°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), one Mn(1), one Mn(2), and one Mn(3) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(1)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra, edges with two equivalent O(7)Li3Mn3 octahedra, edges with two equivalent O(8)Li3Mn3 octahedra, and edges with two equivalent O(5)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-5°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one Mn(1), and one Mn(2) atom to form OLi4Mn2 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(8)Li3Mn3 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with three equivalent O(1)Li4Mn2 octahedra, and edges with three equivalent O(2)Li4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the sixth O site, O(6) is bonded to one Li(3), two equivalent Li(4), one Mn(4), and two equivalent Mn(3) atoms to form OLi3Mn3 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with two equivalent O(6)Li3Mn3 octahedra, edges with three equivalent O(8)Li3Mn3 octahedra, and edges with four equivalent O(7)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the seventh O site, O(7) is bonded to one Li(3), two equivalent Li(4), one Mn(2), one Mn(3), and one Mn(4) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(3)Li3Mn3 octahedra,  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(3)Li3Mn3 octahedra,  an edgeedge with one O(7)Li3Mn3 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with three equivalent O(8)Li3Mn3 octahedra, and edges with four equivalent O(6)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Li(4), one Mn(2), one Mn(3), and one Mn(4) atom to form OLi3Mn3 octahedra that share  a cornercorner with one O(4)Li3Mn3 octahedra,  a cornercorner with one O(6)Li3Mn3 octahedra,  a cornercorner with one O(7)Li3Mn3 octahedra,  a cornercorner with one O(8)Li3Mn3 octahedra,  a cornercorner with one O(1)Li4Mn2 octahedra,  a cornercorner with one O(5)Li4Mn2 octahedra,  an edgeedge with one O(2)Li4Mn2 octahedra,  an edgeedge with one O(5)Li4Mn2 octahedra, edges with two equivalent O(3)Li3Mn3 octahedra, edges with two equivalent O(4)Li3Mn3 octahedra, edges with three equivalent O(6)Li3Mn3 octahedra, and edges with three equivalent O(7)Li3Mn3 octahedra. The corner-sharing octahedral tilt angles range from 0-11°.