CrZnF5 crystallizes in the monoclinic C2/c space group. Cr(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing CrF6 octahedra. The corner-sharing octahedral tilt angles are 36°. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent F(2) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a linear geometry to one Cr(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Cr(1) and one Zn(1) atom.
CrZnF5 crystallizes in the monoclinic C2/c space group. Cr(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing CrF6 octahedra. The corner-sharing octahedral tilt angles are 36°. Both Cr(1)-F(1) bond lengths are 1.97 Å. Both Cr(1)-F(2) bond lengths are 1.94 Å. Both Cr(1)-F(3) bond lengths are 1.94 Å. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent F(2) and two equivalent F(3) atoms. Both Zn(1)-F(2) bond lengths are 1.93 Å. Both Zn(1)-F(3) bond lengths are 2.07 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a linear geometry to one Cr(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Cr(1) and one Zn(1) atom.