Pd5Pr crystallizes in the trigonal P321 space group. Pr(1) is bonded to three equivalent Pd(1), three equivalent Pd(2), three equivalent Pd(3), and three equivalent Pd(4) atoms to form a mixture of corner and edge-sharing PrPd12 cuboctahedra. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Pr(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Pr(1) atoms. In the third Pd site, Pd(3) is bonded in a distorted trigonal planar geometry to three equivalent Pr(1) atoms. In the fourth Pd site, Pd(4) is bonded in a distorted trigonal planar geometry to three equivalent Pr(1) atoms.
Pd5Pr crystallizes in the trigonal P321 space group. Pr(1) is bonded to three equivalent Pd(1), three equivalent Pd(2), three equivalent Pd(3), and three equivalent Pd(4) atoms to form a mixture of corner and edge-sharing PrPd12 cuboctahedra. All Pr(1)-Pd(1) bond lengths are 2.93 Å. All Pr(1)-Pd(2) bond lengths are 2.92 Å. All Pr(1)-Pd(3) bond lengths are 2.95 Å. All Pr(1)-Pd(4) bond lengths are 2.95 Å. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Pr(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Pr(1) atoms. In the third Pd site, Pd(3) is bonded in a distorted trigonal planar geometry to three equivalent Pr(1) atoms. In the fourth Pd site, Pd(4) is bonded in a distorted trigonal planar geometry to three equivalent Pr(1) atoms.