HfZrO4 crystallizes in the tetragonal I4_1/a space group. Hf(1) is bonded in a distorted body-centered cubic geometry to eight equivalent O(1) atoms. Zr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. O(1) is bonded to two equivalent Hf(1) and two equivalent Zr(1) atoms to form a mixture of distorted corner and edge-sharing OHf2Zr2 tetrahedra.
HfZrO4 crystallizes in the tetragonal I4_1/a space group. Hf(1) is bonded in a distorted body-centered cubic geometry to eight equivalent O(1) atoms. There are four shorter (2.05 Å) and four longer (2.42 Å) Hf(1)-O(1) bond lengths. Zr(1) is bonded in a body-centered cubic geometry to eight equivalent O(1) atoms. There are four shorter (2.13 Å) and four longer (2.35 Å) Zr(1)-O(1) bond lengths. O(1) is bonded to two equivalent Hf(1) and two equivalent Zr(1) atoms to form a mixture of distorted corner and edge-sharing OHf2Zr2 tetrahedra.