LiMnO2 is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra, corners with eight equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with four equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. Mn(1) is bonded to six equivalent O(1) atoms to form distorted MnO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with eight equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and faces with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. O(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Mn(1) atoms.
LiMnO2 is High Pressure (4-7GPa) Tellurium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra, corners with eight equivalent Li(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with four equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. There are two shorter (2.12 Å) and four longer (2.20 Å) Li(1)-O(1) bond lengths. Mn(1) is bonded to six equivalent O(1) atoms to form distorted MnO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with eight equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and faces with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-48°. There are a spread of Mn(1)-O(1) bond distances ranging from 1.95-2.34 Å. O(1) is bonded in a 6-coordinate geometry to three equivalent Li(1) and three equivalent Mn(1) atoms.