Ba10Ce(Bi3O10)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 5-coordinate geometry to one O(1), one O(12), one O(4), one O(6), one O(7), and two equivalent O(11) atoms. In the second Ba site, Ba(2) is bonded in a 11-coordinate geometry to one O(10), one O(13), one O(7), one O(8), one O(9), two equivalent O(14), two equivalent O(2), and two equivalent O(4) atoms. In the third Ba site, Ba(3) is bonded in a 11-coordinate geometry to one O(1), one O(12), one O(13), one O(15), one O(3), one O(6), one O(9), two equivalent O(10), and two equivalent O(5) atoms. In the fourth Ba site, Ba(4) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(12), one O(15), one O(4), and two equivalent O(8) atoms. In the fifth Ba site, Ba(5) is bonded in a 11-coordinate geometry to one O(1), one O(13), one O(14), one O(15), one O(3), one O(6), one O(8), two equivalent O(5), and two equivalent O(7) atoms. Ce(1) is bonded to two equivalent O(12), two equivalent O(3), and two equivalent O(6) atoms to form CeO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra, corners with two equivalent Bi(2)O6 octahedra, and corners with two equivalent Bi(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. There are five inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent O(1), two equivalent O(15), and two equivalent O(6) atoms to form BiO6 octahedra that share corners with two equivalent Ce(1)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with two equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. In the second Bi site, Bi(2) is bonded to one O(10), one O(12), one O(13), one O(2), one O(5), and one O(7) atom to form BiO6 octahedra that share  a cornercorner with one Ce(1)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with three equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. In the third Bi site, Bi(3) is bonded to one O(11), one O(14), one O(3), one O(4), one O(8), and one O(9) atom to form BiO6 octahedra that share  a cornercorner with one Ce(1)O6 octahedra, corners with two equivalent Bi(5)O6 octahedra, and corners with three equivalent Bi(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. In the fourth Bi site, Bi(4) is bonded to one O(1), one O(11), one O(13), one O(2), one O(8), and one O(9) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. In the fifth Bi site, Bi(5) is bonded to one O(10), one O(14), one O(15), one O(4), one O(5), and one O(7) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(3), one Ba(4), one Ba(5), one Bi(1), and one Bi(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Ba(2), one Bi(2), and one Bi(4) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ba(3), one Ba(5), one Ce(1), and one Bi(3) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(4), two equivalent Ba(2), one Bi(3), and one Bi(5) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(3), two equivalent Ba(5), one Bi(2), and one Bi(5) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(3), one Ba(5), one Ce(1), and one Bi(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(2), two equivalent Ba(5), one Bi(2), and one Bi(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ba(2), one Ba(5), two equivalent Ba(4), one Bi(3), and one Bi(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Ba(2), one Ba(3), one Bi(3), and one Bi(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Ba(2), two equivalent Ba(3), one Bi(2), and one Bi(5) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Ba(4), two equivalent Ba(1), one Bi(3), and one Bi(4) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Ba(1), one Ba(3), one Ba(4), one Ce(1), and one Bi(2) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(5), one Bi(2), and one Bi(4) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Ba(5), two equivalent Ba(2), one Bi(3), and one Bi(5) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one Ba(3), one Ba(4), one Ba(5), one Bi(1), and one Bi(5) atom.
Ba10Ce(Bi3O10)3 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 5-coordinate geometry to one O(1), one O(12), one O(4), one O(6), one O(7), and two equivalent O(11) atoms. The Ba(1)-O(1) bond length is 2.89 Å. The Ba(1)-O(12) bond length is 3.18 Å. The Ba(1)-O(4) bond length is 2.85 Å. The Ba(1)-O(6) bond length is 2.92 Å. The Ba(1)-O(7) bond length is 2.88 Å. There is one shorter (2.76 Å) and one longer (3.14 Å) Ba(1)-O(11) bond length. In the second Ba site, Ba(2) is bonded in a 11-coordinate geometry to one O(10), one O(13), one O(7), one O(8), one O(9), two equivalent O(14), two equivalent O(2), and two equivalent O(4) atoms. The Ba(2)-O(10) bond length is 2.90 Å. The Ba(2)-O(13) bond length is 3.15 Å. The Ba(2)-O(7) bond length is 3.36 Å. The Ba(2)-O(8) bond length is 3.38 Å. The Ba(2)-O(9) bond length is 2.89 Å. There is one shorter (2.76 Å) and one longer (3.17 Å) Ba(2)-O(14) bond length. There is one shorter (2.89 Å) and one longer (2.90 Å) Ba(2)-O(2) bond length. There is one shorter (3.37 Å) and one longer (3.39 Å) Ba(2)-O(4) bond length. In the third Ba site, Ba(3) is bonded in a 11-coordinate geometry to one O(1), one O(12), one O(13), one O(15), one O(3), one O(6), one O(9), two equivalent O(10), and two equivalent O(5) atoms. The Ba(3)-O(1) bond length is 3.38 Å. The Ba(3)-O(12) bond length is 3.19 Å. The Ba(3)-O(13) bond length is 3.12 Å. The Ba(3)-O(15) bond length is 2.76 Å. The Ba(3)-O(3) bond length is 2.92 Å. The Ba(3)-O(6) bond length is 3.41 Å. The Ba(3)-O(9) bond length is 2.89 Å. There is one shorter (2.87 Å) and one longer (3.37 Å) Ba(3)-O(10) bond length. There is one shorter (2.88 Å) and one longer (3.34 Å) Ba(3)-O(5) bond length. In the fourth Ba site, Ba(4) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(12), one O(15), one O(4), and two equivalent O(8) atoms. The Ba(4)-O(1) bond length is 2.89 Å. The Ba(4)-O(11) bond length is 3.15 Å. The Ba(4)-O(12) bond length is 2.77 Å. The Ba(4)-O(15) bond length is 3.16 Å. The Ba(4)-O(4) bond length is 2.87 Å. There is one shorter (2.88 Å) and one longer (2.89 Å) Ba(4)-O(8) bond length. In the fifth Ba site, Ba(5) is bonded in a 11-coordinate geometry to one O(1), one O(13), one O(14), one O(15), one O(3), one O(6), one O(8), two equivalent O(5), and two equivalent O(7) atoms. The Ba(5)-O(1) bond length is 3.36 Å. The Ba(5)-O(13) bond length is 2.74 Å. The Ba(5)-O(14) bond length is 3.14 Å. The Ba(5)-O(15) bond length is 3.15 Å. The Ba(5)-O(3) bond length is 2.90 Å. The Ba(5)-O(6) bond length is 2.91 Å. The Ba(5)-O(8) bond length is 3.35 Å. There is one shorter (2.90 Å) and one longer (3.38 Å) Ba(5)-O(5) bond length. There is one shorter (2.91 Å) and one longer (3.37 Å) Ba(5)-O(7) bond length. Ce(1) is bonded to two equivalent O(12), two equivalent O(3), and two equivalent O(6) atoms to form CeO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra, corners with two equivalent Bi(2)O6 octahedra, and corners with two equivalent Bi(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. Both Ce(1)-O(12) bond lengths are 2.26 Å. Both Ce(1)-O(3) bond lengths are 2.26 Å. Both Ce(1)-O(6) bond lengths are 2.23 Å. There are five inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent O(1), two equivalent O(15), and two equivalent O(6) atoms to form BiO6 octahedra that share corners with two equivalent Ce(1)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with two equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. Both Bi(1)-O(1) bond lengths are 2.20 Å. Both Bi(1)-O(15) bond lengths are 2.21 Å. Both Bi(1)-O(6) bond lengths are 2.23 Å. In the second Bi site, Bi(2) is bonded to one O(10), one O(12), one O(13), one O(2), one O(5), and one O(7) atom to form BiO6 octahedra that share  a cornercorner with one Ce(1)O6 octahedra, corners with two equivalent Bi(4)O6 octahedra, and corners with three equivalent Bi(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. The Bi(2)-O(10) bond length is 2.18 Å. The Bi(2)-O(12) bond length is 2.22 Å. The Bi(2)-O(13) bond length is 2.21 Å. The Bi(2)-O(2) bond length is 2.18 Å. The Bi(2)-O(5) bond length is 2.19 Å. The Bi(2)-O(7) bond length is 2.19 Å. In the third Bi site, Bi(3) is bonded to one O(11), one O(14), one O(3), one O(4), one O(8), and one O(9) atom to form BiO6 octahedra that share  a cornercorner with one Ce(1)O6 octahedra, corners with two equivalent Bi(5)O6 octahedra, and corners with three equivalent Bi(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. The Bi(3)-O(11) bond length is 2.19 Å. The Bi(3)-O(14) bond length is 2.19 Å. The Bi(3)-O(3) bond length is 2.21 Å. The Bi(3)-O(4) bond length is 2.20 Å. The Bi(3)-O(8) bond length is 2.18 Å. The Bi(3)-O(9) bond length is 2.18 Å. In the fourth Bi site, Bi(4) is bonded to one O(1), one O(11), one O(13), one O(2), one O(8), and one O(9) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. The Bi(4)-O(1) bond length is 2.27 Å. The Bi(4)-O(11) bond length is 2.32 Å. The Bi(4)-O(13) bond length is 2.28 Å. The Bi(4)-O(2) bond length is 2.29 Å. The Bi(4)-O(8) bond length is 2.29 Å. The Bi(4)-O(9) bond length is 2.29 Å. In the fifth Bi site, Bi(5) is bonded to one O(10), one O(14), one O(15), one O(4), one O(5), and one O(7) atom to form corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles range from 16-22°. The Bi(5)-O(10) bond length is 2.28 Å. The Bi(5)-O(14) bond length is 2.31 Å. The Bi(5)-O(15) bond length is 2.28 Å. The Bi(5)-O(4) bond length is 2.28 Å. The Bi(5)-O(5) bond length is 2.31 Å. The Bi(5)-O(7) bond length is 2.29 Å. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(3), one Ba(4), one Ba(5), one Bi(1), and one Bi(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Ba(2), one Bi(2), and one Bi(4) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ba(3), one Ba(5), one Ce(1), and one Bi(3) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(4), two equivalent Ba(2), one Bi(3), and one Bi(5) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Ba(3), two equivalent Ba(5), one Bi(2), and one Bi(5) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(3), one Ba(5), one Ce(1), and one Bi(1) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Ba(1), one Ba(2), two equivalent Ba(5), one Bi(2), and one Bi(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ba(2), one Ba(5), two equivalent Ba(4), one Bi(3), and one Bi(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Ba(2), one Ba(3), one Bi(3), and one Bi(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Ba(2), two equivalent Ba(3), one Bi(2), and one Bi(5) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one Ba(4), two equivalent Ba(1), one Bi(3), and one Bi(4) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Ba(1), one Ba(3), one Ba(4), one Ce(1), and one Bi(2) atom. In the thirteenth O site, O(13) is bonded in a 5-coordinate geometry to one Ba(2), one Ba(3), one Ba(5), one Bi(2), and one Bi(4) atom. In the fourteenth O site, O(14) is bonded in a 5-coordinate geometry to one Ba(5), two equivalent Ba(2), one Bi(3), and one Bi(5) atom. In the fifteenth O site, O(15) is bonded in a 5-coordinate geometry to one Ba(3), one Ba(4), one Ba(5), one Bi(1), and one Bi(5) atom.