Cr3As crystallizes in the cubic Pm-3n space group. Cr(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent As(1) atoms. As(1) is bonded to twelve equivalent Cr(1) atoms to form a mixture of face and edge-sharing AsCr12 cuboctahedra.
Cr3As crystallizes in the cubic Pm-3n space group. Cr(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent As(1) atoms. Both Cr(1)-Cr(1) bond lengths are 2.27 Å. All Cr(1)-As(1) bond lengths are 2.54 Å. As(1) is bonded to twelve equivalent Cr(1) atoms to form a mixture of face and edge-sharing AsCr12 cuboctahedra.