Pd3In is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent Pd(1), four equivalent Pd(2), and four equivalent In(1) atoms to form distorted PdIn4Pd8 cuboctahedra that share corners with twelve equivalent Pd(1)In4Pd8 cuboctahedra, edges with eight equivalent Pd(1)In4Pd8 cuboctahedra, edges with eight equivalent Pd(2)In4Pd8 cuboctahedra, edges with eight equivalent In(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)In4Pd8 cuboctahedra, faces with four equivalent In(1)Pd12 cuboctahedra, and faces with ten equivalent Pd(1)In4Pd8 cuboctahedra. In the second Pd site, Pd(2) is bonded to eight equivalent Pd(1) and four equivalent In(1) atoms to form PdIn4Pd8 cuboctahedra that share corners with four equivalent Pd(2)In4Pd8 cuboctahedra, corners with eight equivalent In(1)Pd12 cuboctahedra, edges with eight equivalent Pd(2)In4Pd8 cuboctahedra, edges with sixteen equivalent Pd(1)In4Pd8 cuboctahedra, faces with four equivalent Pd(2)In4Pd8 cuboctahedra, faces with six equivalent In(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)In4Pd8 cuboctahedra. In(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form InPd12 cuboctahedra that share corners with four equivalent In(1)Pd12 cuboctahedra, corners with eight equivalent Pd(2)In4Pd8 cuboctahedra, edges with eight equivalent In(1)Pd12 cuboctahedra, edges with sixteen equivalent Pd(1)In4Pd8 cuboctahedra, faces with four equivalent In(1)Pd12 cuboctahedra, faces with six equivalent Pd(2)In4Pd8 cuboctahedra, and faces with eight equivalent Pd(1)In4Pd8 cuboctahedra.
Pd3In is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent Pd(1), four equivalent Pd(2), and four equivalent In(1) atoms to form distorted PdIn4Pd8 cuboctahedra that share corners with twelve equivalent Pd(1)In4Pd8 cuboctahedra, edges with eight equivalent Pd(1)In4Pd8 cuboctahedra, edges with eight equivalent Pd(2)In4Pd8 cuboctahedra, edges with eight equivalent In(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)In4Pd8 cuboctahedra, faces with four equivalent In(1)Pd12 cuboctahedra, and faces with ten equivalent Pd(1)In4Pd8 cuboctahedra. All Pd(1)-Pd(1) bond lengths are 2.92 Å. All Pd(1)-Pd(2) bond lengths are 2.79 Å. All Pd(1)-In(1) bond lengths are 2.79 Å. In the second Pd site, Pd(2) is bonded to eight equivalent Pd(1) and four equivalent In(1) atoms to form PdIn4Pd8 cuboctahedra that share corners with four equivalent Pd(2)In4Pd8 cuboctahedra, corners with eight equivalent In(1)Pd12 cuboctahedra, edges with eight equivalent Pd(2)In4Pd8 cuboctahedra, edges with sixteen equivalent Pd(1)In4Pd8 cuboctahedra, faces with four equivalent Pd(2)In4Pd8 cuboctahedra, faces with six equivalent In(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)In4Pd8 cuboctahedra. All Pd(2)-In(1) bond lengths are 2.92 Å. In(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form InPd12 cuboctahedra that share corners with four equivalent In(1)Pd12 cuboctahedra, corners with eight equivalent Pd(2)In4Pd8 cuboctahedra, edges with eight equivalent In(1)Pd12 cuboctahedra, edges with sixteen equivalent Pd(1)In4Pd8 cuboctahedra, faces with four equivalent In(1)Pd12 cuboctahedra, faces with six equivalent Pd(2)In4Pd8 cuboctahedra, and faces with eight equivalent Pd(1)In4Pd8 cuboctahedra.