Ni(N3O2)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two Ni(N3O2)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ni(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom.
Ni(N3O2)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two Ni(N3O2)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. Both Ni(1)-N(1) bond lengths are 2.14 Å. All Ni(1)-N(2) bond lengths are 1.81 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one O(1), and one O(2) atom. The N(1)-O(1) bond length is 1.21 Å. The N(1)-O(2) bond length is 1.21 Å. In the second N site, N(2) is bonded in a single-bond geometry to one Ni(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom.