NSF is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two NSF clusters. N(1) is bonded in a bent 120 degrees geometry to two equivalent S(1) atoms. S(1) is bonded in a trigonal non-coplanar geometry to two equivalent N(1) and one F(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom.
NSF is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of two NSF clusters. N(1) is bonded in a bent 120 degrees geometry to two equivalent S(1) atoms. There is one shorter (1.55 Å) and one longer (1.67 Å) N(1)-S(1) bond length. S(1) is bonded in a trigonal non-coplanar geometry to two equivalent N(1) and one F(1) atom. The S(1)-F(1) bond length is 1.67 Å. F(1) is bonded in a single-bond geometry to one S(1) atom.