AuSb2(XeF6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuSb2(XeF6)2 cluster. Xe(1) is bonded in a single-bond geometry to one Au(1) atom. Au(1) is bonded in a linear geometry to two equivalent Xe(1) and two equivalent F(1) atoms. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom.
AuSb2(XeF6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuSb2(XeF6)2 cluster. Xe(1) is bonded in a single-bond geometry to one Au(1) atom. The Xe(1)-Au(1) bond length is 2.77 Å. Au(1) is bonded in a linear geometry to two equivalent Xe(1) and two equivalent F(1) atoms. Both Au(1)-F(1) bond lengths are 2.18 Å. Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Sb(1)-F(1) bond length is 2.04 Å. The Sb(1)-F(2) bond length is 1.90 Å. The Sb(1)-F(3) bond length is 1.92 Å. The Sb(1)-F(4) bond length is 1.90 Å. The Sb(1)-F(5) bond length is 1.91 Å. The Sb(1)-F(6) bond length is 1.91 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom.