BaAg2Te2 crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent Ag(1), three equivalent Ag(2), three equivalent Te(1), and four equivalent Te(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 8-coordinate geometry to two equivalent Ba(1), two equivalent Ag(1), one Te(1), and three equivalent Te(2) atoms. In the second Ag site, Ag(2) is bonded to three equivalent Ba(1), one Te(2), and three equivalent Te(1) atoms to form a mixture of distorted corner and edge-sharing AgBa3Te4 tetrahedra. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 7-coordinate geometry to three equivalent Ba(1), one Ag(1), and three equivalent Ag(2) atoms. In the second Te site, Te(2) is bonded in a 8-coordinate geometry to four equivalent Ba(1), one Ag(2), and three equivalent Ag(1) atoms.
BaAg2Te2 crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent Ag(1), three equivalent Ag(2), three equivalent Te(1), and four equivalent Te(2) atoms. There is one shorter (3.77 Å) and one longer (3.78 Å) Ba(1)-Ag(1) bond length. There is one shorter (3.93 Å) and two longer (4.13 Å) Ba(1)-Ag(2) bond lengths. There is one shorter (3.49 Å) and two longer (3.53 Å) Ba(1)-Te(1) bond lengths. There are two shorter (3.73 Å) and two longer (3.76 Å) Ba(1)-Te(2) bond lengths. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 8-coordinate geometry to two equivalent Ba(1), two equivalent Ag(1), one Te(1), and three equivalent Te(2) atoms. Both Ag(1)-Ag(1) bond lengths are 2.89 Å. The Ag(1)-Te(1) bond length is 2.85 Å. There are two shorter (2.89 Å) and one longer (2.93 Å) Ag(1)-Te(2) bond length. In the second Ag site, Ag(2) is bonded to three equivalent Ba(1), one Te(2), and three equivalent Te(1) atoms to form a mixture of distorted corner and edge-sharing AgBa3Te4 tetrahedra. The Ag(2)-Te(2) bond length is 2.87 Å. There are two shorter (2.81 Å) and one longer (2.92 Å) Ag(2)-Te(1) bond length. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 7-coordinate geometry to three equivalent Ba(1), one Ag(1), and three equivalent Ag(2) atoms. In the second Te site, Te(2) is bonded in a 8-coordinate geometry to four equivalent Ba(1), one Ag(2), and three equivalent Ag(1) atoms.