AgSbTe2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form AgTe6 octahedra that share corners with six equivalent Ag(1)Te6 octahedra, edges with four equivalent Ag(1)Te6 octahedra, and edges with eight equivalent Sb(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to two equivalent Te(2) and four equivalent Te(1) atoms to form SbTe6 octahedra that share corners with six equivalent Sb(1)Te6 octahedra, edges with four equivalent Sb(1)Te6 octahedra, and edges with eight equivalent Ag(1)Te6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent Ag(1) and four equivalent Sb(1) atoms to form TeAg2Sb4 octahedra that share corners with six equivalent Te(1)Ag2Sb4 octahedra, edges with four equivalent Te(1)Ag2Sb4 octahedra, and edges with eight equivalent Te(2)Ag4Sb2 octahedra. The corner-sharing octahedra are not tilted. In the second Te site, Te(2) is bonded to four equivalent Ag(1) and two equivalent Sb(1) atoms to form TeAg4Sb2 octahedra that share corners with six equivalent Te(2)Ag4Sb2 octahedra, edges with four equivalent Te(2)Ag4Sb2 octahedra, and edges with eight equivalent Te(1)Ag2Sb4 octahedra. The corner-sharing octahedra are not tilted.
AgSbTe2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form AgTe6 octahedra that share corners with six equivalent Ag(1)Te6 octahedra, edges with four equivalent Ag(1)Te6 octahedra, and edges with eight equivalent Sb(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Both Ag(1)-Te(1) bond lengths are 3.03 Å. All Ag(1)-Te(2) bond lengths are 3.08 Å. Sb(1) is bonded to two equivalent Te(2) and four equivalent Te(1) atoms to form SbTe6 octahedra that share corners with six equivalent Sb(1)Te6 octahedra, edges with four equivalent Sb(1)Te6 octahedra, and edges with eight equivalent Ag(1)Te6 octahedra. The corner-sharing octahedra are not tilted. Both Sb(1)-Te(2) bond lengths are 3.03 Å. All Sb(1)-Te(1) bond lengths are 3.08 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to two equivalent Ag(1) and four equivalent Sb(1) atoms to form TeAg2Sb4 octahedra that share corners with six equivalent Te(1)Ag2Sb4 octahedra, edges with four equivalent Te(1)Ag2Sb4 octahedra, and edges with eight equivalent Te(2)Ag4Sb2 octahedra. The corner-sharing octahedra are not tilted. In the second Te site, Te(2) is bonded to four equivalent Ag(1) and two equivalent Sb(1) atoms to form TeAg4Sb2 octahedra that share corners with six equivalent Te(2)Ag4Sb2 octahedra, edges with four equivalent Te(2)Ag4Sb2 octahedra, and edges with eight equivalent Te(1)Ag2Sb4 octahedra. The corner-sharing octahedra are not tilted.