C2AsN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2AsN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(4) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. As(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(5), and one F(6) atom. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one As(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom.
C2AsN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2AsN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(4) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-O(2) bond length is 1.24 Å. The C(1)-F(4) bond length is 1.32 Å. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. The C(2)-N(1) bond length is 1.24 Å. The C(2)-O(1) bond length is 1.16 Å. As(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(5), and one F(6) atom. The As(1)-O(2) bond length is 2.07 Å. The As(1)-F(1) bond length is 1.75 Å. The As(1)-F(2) bond length is 1.76 Å. The As(1)-F(3) bond length is 1.75 Å. The As(1)-F(5) bond length is 1.74 Å. The As(1)-F(6) bond length is 1.75 Å. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one As(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom.