SrBiO2Cl is lead oxide-derived structured and crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 4-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Sr(1) and two equivalent Bi(1) atoms to form OSr2Bi2 tetrahedra that share corners with four equivalent O(1)Sr2Bi2 tetrahedra, corners with eight equivalent Cl(1)Sr4 tetrahedra, and edges with four equivalent O(1)Sr2Bi2 tetrahedra. Cl(1) is bonded to four equivalent Sr(1) atoms to form ClSr4 tetrahedra that share corners with four equivalent Cl(1)Sr4 tetrahedra, corners with sixteen equivalent O(1)Sr2Bi2 tetrahedra, and edges with four equivalent Cl(1)Sr4 tetrahedra.
SrBiO2Cl is lead oxide-derived structured and crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 4-coordinate geometry to four equivalent O(1) and four equivalent Cl(1) atoms. All Sr(1)-O(1) bond lengths are 2.50 Å. There are two shorter (3.33 Å) and two longer (3.45 Å) Sr(1)-Cl(1) bond lengths. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Bi(1)-O(1) bond lengths are 2.22 Å. O(1) is bonded to two equivalent Sr(1) and two equivalent Bi(1) atoms to form OSr2Bi2 tetrahedra that share corners with four equivalent O(1)Sr2Bi2 tetrahedra, corners with eight equivalent Cl(1)Sr4 tetrahedra, and edges with four equivalent O(1)Sr2Bi2 tetrahedra. Cl(1) is bonded to four equivalent Sr(1) atoms to form ClSr4 tetrahedra that share corners with four equivalent Cl(1)Sr4 tetrahedra, corners with sixteen equivalent O(1)Sr2Bi2 tetrahedra, and edges with four equivalent Cl(1)Sr4 tetrahedra.