ThV2PbO8 crystallizes in the triclinic P-1 space group. Th(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(7), one O(8), two equivalent O(3), and two equivalent O(6) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(7) atom. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(6), and one O(8) atom. Pb(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(7), one O(8), two equivalent O(4), and two equivalent O(5) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Th(1), one V(2), and one Pb(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Th(1), one V(1), and one Pb(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Th(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Pb(1) atoms. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Th(1) and one V(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Th(1), one V(1), and one Pb(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Th(1), one V(2), and one Pb(1) atom.
ThV2PbO8 crystallizes in the triclinic P-1 space group. Th(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(7), one O(8), two equivalent O(3), and two equivalent O(6) atoms. The Th(1)-O(1) bond length is 2.38 Å. The Th(1)-O(2) bond length is 2.41 Å. The Th(1)-O(7) bond length is 2.39 Å. The Th(1)-O(8) bond length is 2.39 Å. There is one shorter (2.50 Å) and one longer (2.59 Å) Th(1)-O(3) bond length. There is one shorter (2.43 Å) and one longer (2.62 Å) Th(1)-O(6) bond length. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(7) atom. The V(1)-O(2) bond length is 1.73 Å. The V(1)-O(3) bond length is 1.76 Å. The V(1)-O(5) bond length is 1.69 Å. The V(1)-O(7) bond length is 1.71 Å. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(6), and one O(8) atom. The V(2)-O(1) bond length is 1.74 Å. The V(2)-O(4) bond length is 1.67 Å. The V(2)-O(6) bond length is 1.74 Å. The V(2)-O(8) bond length is 1.72 Å. Pb(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(7), one O(8), two equivalent O(4), and two equivalent O(5) atoms. The Pb(1)-O(1) bond length is 2.72 Å. The Pb(1)-O(2) bond length is 2.73 Å. The Pb(1)-O(7) bond length is 2.84 Å. The Pb(1)-O(8) bond length is 2.56 Å. There is one shorter (2.46 Å) and one longer (2.75 Å) Pb(1)-O(4) bond length. There is one shorter (2.49 Å) and one longer (2.50 Å) Pb(1)-O(5) bond length. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Th(1), one V(2), and one Pb(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one Th(1), one V(1), and one Pb(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Th(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Pb(1) atoms. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(1) atoms. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Th(1) and one V(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Th(1), one V(1), and one Pb(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Th(1), one V(2), and one Pb(1) atom.