AlPb3H2OF9 crystallizes in the triclinic P-1 space group. Al(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), one F(1), one F(3), one F(4), one F(5), one F(6), and one F(9) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent F(7) and two equivalent F(8) atoms. In the third Pb site, Pb(3) is bonded in a 7-coordinate geometry to one F(1), one F(2), one F(9), two equivalent F(7), and two equivalent F(8) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to two equivalent Pb(1), one H(1), and one H(2) atom. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Al(1), one Pb(1), and one Pb(3) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Al(1) and one Pb(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the seventh F site, F(7) is bonded to two equivalent Pb(2) and two equivalent Pb(3) atoms to form a mixture of corner and edge-sharing FPb4 tetrahedra. In the eighth F site, F(8) is bonded to two equivalent Pb(2) and two equivalent Pb(3) atoms to form a mixture of corner and edge-sharing FPb4 tetrahedra. In the ninth F site, F(9) is bonded in a bent 120 degrees geometry to one Pb(1) and one Pb(3) atom.
AlPb3H2OF9 crystallizes in the triclinic P-1 space group. Al(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The Al(1)-F(1) bond length is 1.84 Å. The Al(1)-F(2) bond length is 1.87 Å. The Al(1)-F(3) bond length is 1.81 Å. The Al(1)-F(4) bond length is 1.85 Å. The Al(1)-F(5) bond length is 1.86 Å. The Al(1)-F(6) bond length is 1.81 Å. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), one F(1), one F(3), one F(4), one F(5), one F(6), and one F(9) atom. There is one shorter (2.69 Å) and one longer (2.73 Å) Pb(1)-O(1) bond length. The Pb(1)-F(1) bond length is 2.60 Å. The Pb(1)-F(3) bond length is 2.72 Å. The Pb(1)-F(4) bond length is 2.56 Å. The Pb(1)-F(5) bond length is 2.49 Å. The Pb(1)-F(6) bond length is 2.56 Å. The Pb(1)-F(9) bond length is 2.48 Å. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent F(7) and two equivalent F(8) atoms. There is one shorter (2.47 Å) and one longer (2.53 Å) Pb(2)-F(7) bond length. There is one shorter (2.53 Å) and one longer (2.54 Å) Pb(2)-F(8) bond length. In the third Pb site, Pb(3) is bonded in a 7-coordinate geometry to one F(1), one F(2), one F(9), two equivalent F(7), and two equivalent F(8) atoms. The Pb(3)-F(1) bond length is 2.76 Å. The Pb(3)-F(2) bond length is 2.63 Å. The Pb(3)-F(9) bond length is 2.41 Å. There is one shorter (2.52 Å) and one longer (2.63 Å) Pb(3)-F(7) bond length. There is one shorter (2.50 Å) and one longer (2.71 Å) Pb(3)-F(8) bond length. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.99 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. The H(2)-O(1) bond length is 0.98 Å. O(1) is bonded in a water-like geometry to two equivalent Pb(1), one H(1), and one H(2) atom. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Al(1), one Pb(1), and one Pb(3) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Al(1) and one Pb(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the sixth F site, F(6) is bonded in a distorted single-bond geometry to one Al(1) and one Pb(1) atom. In the seventh F site, F(7) is bonded to two equivalent Pb(2) and two equivalent Pb(3) atoms to form a mixture of corner and edge-sharing FPb4 tetrahedra. In the eighth F site, F(8) is bonded to two equivalent Pb(2) and two equivalent Pb(3) atoms to form a mixture of corner and edge-sharing FPb4 tetrahedra. In the ninth F site, F(9) is bonded in a bent 120 degrees geometry to one Pb(1) and one Pb(3) atom.