Cs2MoAgF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Mo(1)F6 octahedra, and faces with four equivalent Ag(1)F6 octahedra. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded to four equivalent Cs(1), one Mo(1), and one Ag(1) atom to form a mixture of distorted face, corner, and edge-sharing FCs4AgMo octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
Cs2MoAgF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Mo(1)F6 octahedra, and faces with four equivalent Ag(1)F6 octahedra. All Cs(1)-F(1) bond lengths are 3.25 Å. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Mo(1)-F(1) bond lengths are 2.09 Å. Ag(1) is bonded to six equivalent F(1) atoms to form AgF6 octahedra that share corners with six equivalent Mo(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. All Ag(1)-F(1) bond lengths are 2.50 Å. F(1) is bonded to four equivalent Cs(1), one Mo(1), and one Ag(1) atom to form a mixture of distorted face, corner, and edge-sharing FCs4AgMo octahedra. The corner-sharing octahedral tilt angles range from 0-60°.