Ba2OsCdO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Os(1)O6 octahedra, and faces with four equivalent Cd(1)O6 octahedra. Os(1) is bonded to six equivalent O(1) atoms to form OsO6 octahedra that share corners with six equivalent Cd(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent Os(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to four equivalent Ba(1), one Os(1), and one Cd(1) atom to form a mixture of distorted corner, edge, and face-sharing OBa4CdOs octahedra. The corner-sharing octahedral tilt angles range from 0-60°.
Ba2OsCdO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Ba(1) is bonded to twelve equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with twelve equivalent Ba(1)O12 cuboctahedra, faces with six equivalent Ba(1)O12 cuboctahedra, faces with four equivalent Os(1)O6 octahedra, and faces with four equivalent Cd(1)O6 octahedra. All Ba(1)-O(1) bond lengths are 2.99 Å. Os(1) is bonded to six equivalent O(1) atoms to form OsO6 octahedra that share corners with six equivalent Cd(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Os(1)-O(1) bond lengths are 1.95 Å. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent Os(1)O6 octahedra and faces with eight equivalent Ba(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. All Cd(1)-O(1) bond lengths are 2.28 Å. O(1) is bonded to four equivalent Ba(1), one Os(1), and one Cd(1) atom to form a mixture of distorted corner, edge, and face-sharing OBa4CdOs octahedra. The corner-sharing octahedral tilt angles range from 0-60°.