VSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent Sb(1) atoms.
VSbO4 is Hydrophilite-derived structured and crystallizes in the orthorhombic Cmmm space group. V(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form VO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Both V(1)-O(2) bond lengths are 2.04 Å. All V(1)-O(1) bond lengths are 2.04 Å. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with eight equivalent V(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Both Sb(1)-O(1) bond lengths are 1.97 Å. All Sb(1)-O(2) bond lengths are 2.05 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1) and two equivalent Sb(1) atoms.