MnSb2O4 crystallizes in the tetragonal P4_2/mbc space group. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form edge-sharing MnO6 octahedra. Sb(1) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. In the second O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Mn(1) and one Sb(1) atom.
MnSb2O4 crystallizes in the tetragonal P4_2/mbc space group. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form edge-sharing MnO6 octahedra. Both Mn(1)-O(2) bond lengths are 2.20 Å. All Mn(1)-O(1) bond lengths are 2.14 Å. Sb(1) is bonded in a distorted T-shaped geometry to one O(1) and two equivalent O(2) atoms. The Sb(1)-O(1) bond length is 1.95 Å. Both Sb(1)-O(2) bond lengths are 2.01 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. In the second O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Mn(1) and one Sb(1) atom.