TiRhSi crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1) and five equivalent Si(1) atoms. Rh(1) is bonded in a 10-coordinate geometry to six equivalent Ti(1) and four equivalent Si(1) atoms. Si(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Rh(1) atoms.
TiRhSi crystallizes in the orthorhombic Pnma space group. Ti(1) is bonded in a 11-coordinate geometry to six equivalent Rh(1) and five equivalent Si(1) atoms. There are a spread of Ti(1)-Rh(1) bond distances ranging from 2.85-2.94 Å. There are three shorter (2.68 Å) and two longer (2.70 Å) Ti(1)-Si(1) bond lengths. Rh(1) is bonded in a 10-coordinate geometry to six equivalent Ti(1) and four equivalent Si(1) atoms. There are a spread of Rh(1)-Si(1) bond distances ranging from 2.38-2.43 Å. Si(1) is bonded in a 9-coordinate geometry to five equivalent Ti(1) and four equivalent Rh(1) atoms.