(NTeO7I)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of three hydrogen peroxide molecules and two NTeO7I clusters. In each NTeO7I cluster, N(1) is bonded in a water-like geometry to one O(6) and one O(7) atom. Te(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(6) atom. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Te(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Te(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Te(1) and one I(1) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one N(1) and one Te(1) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one I(1) atom. In the seventh O site, O(9) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in a trigonal non-coplanar geometry to one O(4), one O(8), and one O(9) atom.
(NTeO7I)2(O2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of three hydrogen peroxide molecules and two NTeO7I clusters. In each NTeO7I cluster, N(1) is bonded in a water-like geometry to one O(6) and one O(7) atom. The N(1)-O(6) bond length is 1.72 Å. The N(1)-O(7) bond length is 1.14 Å. Te(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(6) atom. The Te(1)-O(2) bond length is 1.80 Å. The Te(1)-O(3) bond length is 1.81 Å. The Te(1)-O(4) bond length is 1.95 Å. The Te(1)-O(6) bond length is 1.92 Å. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Te(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Te(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Te(1) and one I(1) atom. The O(4)-I(1) bond length is 2.05 Å. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one N(1) and one Te(1) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one I(1) atom. The O(8)-I(1) bond length is 1.79 Å. In the seventh O site, O(9) is bonded in a single-bond geometry to one I(1) atom. The O(9)-I(1) bond length is 1.78 Å. I(1) is bonded in a trigonal non-coplanar geometry to one O(4), one O(8), and one O(9) atom.