Ba2CuZnSb2F14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Cu(1) is bonded in a square co-planar geometry to two equivalent F(4) and two equivalent F(7) atoms. Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent F(1) and two equivalent F(6) atoms. Sb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Sb(1) atom. In the second F site, F(6) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Zn(1), and one Sb(1) atom. In the third F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Cu(1), and one Sb(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Zn(1), and one Sb(1) atom. In the fifth F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Sb(1) atom. In the sixth F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Sb(1) atom. In the seventh F site, F(4) is bonded in a 2-coordinate geometry to one Ba(1) and one Cu(1) atom.
Ba2CuZnSb2F14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. The Ba(1)-F(1) bond length is 2.78 Å. The Ba(1)-F(4) bond length is 2.65 Å. The Ba(1)-F(6) bond length is 2.77 Å. The Ba(1)-F(7) bond length is 2.86 Å. There is one shorter (2.94 Å) and one longer (3.05 Å) Ba(1)-F(2) bond length. There is one shorter (2.68 Å) and one longer (3.10 Å) Ba(1)-F(3) bond length. There is one shorter (2.87 Å) and one longer (2.88 Å) Ba(1)-F(5) bond length. Cu(1) is bonded in a square co-planar geometry to two equivalent F(4) and two equivalent F(7) atoms. Both Cu(1)-F(4) bond lengths are 1.94 Å. Both Cu(1)-F(7) bond lengths are 1.94 Å. Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent F(1) and two equivalent F(6) atoms. Both Zn(1)-F(1) bond lengths are 2.02 Å. Both Zn(1)-F(6) bond lengths are 1.98 Å. Sb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. The Sb(1)-F(1) bond length is 2.29 Å. The Sb(1)-F(2) bond length is 2.09 Å. The Sb(1)-F(3) bond length is 2.11 Å. The Sb(1)-F(5) bond length is 2.08 Å. The Sb(1)-F(6) bond length is 2.42 Å. The Sb(1)-F(7) bond length is 2.38 Å. There are seven inequivalent F sites. In the first F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Sb(1) atom. In the second F site, F(6) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Zn(1), and one Sb(1) atom. In the third F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Cu(1), and one Sb(1) atom. In the fourth F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Zn(1), and one Sb(1) atom. In the fifth F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Sb(1) atom. In the sixth F site, F(3) is bonded in a 3-coordinate geometry to two equivalent Ba(1) and one Sb(1) atom. In the seventh F site, F(4) is bonded in a 2-coordinate geometry to one Ba(1) and one Cu(1) atom.