InCrO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Cr(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 39-42°. In(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Cr(1) and two equivalent In(1) atoms to form distorted corner-sharing OCr2In2 trigonal pyramids. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Cr(1) and two equivalent In(1) atoms.
InCrO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Cr(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 39-42°. Both Cr(1)-O(1) bond lengths are 2.07 Å. There are two shorter (2.00 Å) and two longer (2.01 Å) Cr(1)-O(2) bond lengths. In(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. There is one shorter (2.17 Å) and one longer (2.22 Å) In(1)-O(1) bond length. There are two shorter (2.18 Å) and two longer (2.43 Å) In(1)-O(2) bond lengths. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Cr(1) and two equivalent In(1) atoms to form distorted corner-sharing OCr2In2 trigonal pyramids. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Cr(1) and two equivalent In(1) atoms.