WMnZn2O6 crystallizes in the monoclinic Pc space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra. In the sixth O site, O(6) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra.
WMnZn2O6 crystallizes in the monoclinic Pc space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. The W(1)-O(1) bond length is 1.93 Å. The W(1)-O(2) bond length is 1.94 Å. The W(1)-O(3) bond length is 1.94 Å. The W(1)-O(4) bond length is 1.94 Å. The W(1)-O(5) bond length is 2.02 Å. The W(1)-O(6) bond length is 2.02 Å. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra, corners with four equivalent Zn(1)O4 tetrahedra, and corners with four equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-54°. The Mn(1)-O(1) bond length is 2.29 Å. The Mn(1)-O(2) bond length is 2.28 Å. The Mn(1)-O(3) bond length is 2.10 Å. The Mn(1)-O(4) bond length is 2.10 Å. The Mn(1)-O(5) bond length is 2.31 Å. The Mn(1)-O(6) bond length is 2.31 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. The Zn(1)-O(2) bond length is 2.00 Å. The Zn(1)-O(4) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 2.07 Å. The Zn(1)-O(6) bond length is 2.07 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-87°. The Zn(2)-O(1) bond length is 2.00 Å. The Zn(2)-O(3) bond length is 2.05 Å. The Zn(2)-O(5) bond length is 2.07 Å. The Zn(2)-O(6) bond length is 2.07 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra. In the sixth O site, O(6) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OMnZn2W tetrahedra.