ZrTcCl is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded to four equivalent Cl(1) atoms to form distorted ZrCl4 tetrahedra that share corners with four equivalent Tc(1)Cl4 tetrahedra, corners with twelve equivalent Zr(1)Cl4 tetrahedra, and edges with six equivalent Tc(1)Cl4 tetrahedra. Tc(1) is bonded to four equivalent Cl(1) atoms to form distorted TcCl4 tetrahedra that share corners with four equivalent Zr(1)Cl4 tetrahedra, corners with twelve equivalent Tc(1)Cl4 tetrahedra, and edges with six equivalent Zr(1)Cl4 tetrahedra. Cl(1) is bonded in a body-centered cubic geometry to four equivalent Zr(1) and four equivalent Tc(1) atoms.
ZrTcCl is half-Heusler structured and crystallizes in the cubic F-43m space group. Zr(1) is bonded to four equivalent Cl(1) atoms to form distorted ZrCl4 tetrahedra that share corners with four equivalent Tc(1)Cl4 tetrahedra, corners with twelve equivalent Zr(1)Cl4 tetrahedra, and edges with six equivalent Tc(1)Cl4 tetrahedra. All Zr(1)-Cl(1) bond lengths are 2.59 Å. Tc(1) is bonded to four equivalent Cl(1) atoms to form distorted TcCl4 tetrahedra that share corners with four equivalent Zr(1)Cl4 tetrahedra, corners with twelve equivalent Tc(1)Cl4 tetrahedra, and edges with six equivalent Zr(1)Cl4 tetrahedra. All Tc(1)-Cl(1) bond lengths are 2.59 Å. Cl(1) is bonded in a body-centered cubic geometry to four equivalent Zr(1) and four equivalent Tc(1) atoms.