Pd3S crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a bent 150 degrees geometry to two equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a linear geometry to two equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to two equivalent Pd(2) and four equivalent Pd(1) atoms.
Pd3S crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a bent 150 degrees geometry to two equivalent S(1) atoms. There is one shorter (2.34 Å) and one longer (2.40 Å) Pd(1)-S(1) bond length. In the second Pd site, Pd(2) is bonded in a linear geometry to two equivalent S(1) atoms. Both Pd(2)-S(1) bond lengths are 2.30 Å. S(1) is bonded in a 6-coordinate geometry to two equivalent Pd(2) and four equivalent Pd(1) atoms.