TiIrZn2O6 crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TiO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-43°. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-43°. Zn(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent Ti(1)O6 octahedra, corners with four equivalent Ir(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-84°. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Ti(1), one Ir(1), and two equivalent Zn(1) atoms to form distorted corner-sharing OTiZn2Ir tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ir(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ir(1), and one Zn(1) atom.
TiIrZn2O6 crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TiO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-43°. Both Ti(1)-O(1) bond lengths are 2.05 Å. Both Ti(1)-O(2) bond lengths are 1.96 Å. Both Ti(1)-O(3) bond lengths are 1.97 Å. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-43°. Both Ir(1)-O(1) bond lengths are 2.05 Å. Both Ir(1)-O(2) bond lengths are 2.02 Å. Both Ir(1)-O(3) bond lengths are 2.00 Å. Zn(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent Ti(1)O6 octahedra, corners with four equivalent Ir(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-84°. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 2.04 Å. There is one shorter (2.05 Å) and one longer (2.12 Å) Zn(1)-O(1) bond length. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Ti(1), one Ir(1), and two equivalent Zn(1) atoms to form distorted corner-sharing OTiZn2Ir tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ir(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ti(1), one Ir(1), and one Zn(1) atom.