VOF is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), two equivalent O(3), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with two equivalent V(4)O2F4 octahedra, corners with six equivalent V(3)O3F3 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(3) atoms to form VO4F2 octahedra that share corners with four equivalent V(4)O2F4 octahedra, corners with four equivalent V(3)O3F3 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one F(2), and two equivalent F(1) atoms to form VO3F3 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with six equivalent V(1)O3F3 octahedra,  an edgeedge with one V(4)O2F4 octahedra, and  an edgeedge with one V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. In the fourth V site, V(4) is bonded to two equivalent O(1), two equivalent F(2), and two equivalent F(3) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom.
VOF is Hydrophilite-derived structured and crystallizes in the triclinic P-1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), two equivalent O(3), one F(1), one F(2), and one F(3) atom to form VO3F3 octahedra that share corners with two equivalent V(4)O2F4 octahedra, corners with six equivalent V(3)O3F3 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. The V(1)-O(2) bond length is 1.99 Å. There is one shorter (1.95 Å) and one longer (2.01 Å) V(1)-O(3) bond length. The V(1)-F(1) bond length is 2.07 Å. The V(1)-F(2) bond length is 2.06 Å. The V(1)-F(3) bond length is 2.13 Å. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(3) atoms to form VO4F2 octahedra that share corners with four equivalent V(4)O2F4 octahedra, corners with four equivalent V(3)O3F3 octahedra, and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. Both V(2)-O(1) bond lengths are 2.06 Å. Both V(2)-O(2) bond lengths are 2.03 Å. Both V(2)-F(3) bond lengths are 2.09 Å. In the third V site, V(3) is bonded to one O(1), one O(2), one O(3), one F(2), and two equivalent F(1) atoms to form VO3F3 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with six equivalent V(1)O3F3 octahedra,  an edgeedge with one V(4)O2F4 octahedra, and  an edgeedge with one V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-55°. The V(3)-O(1) bond length is 1.96 Å. The V(3)-O(2) bond length is 1.99 Å. The V(3)-O(3) bond length is 1.99 Å. The V(3)-F(2) bond length is 2.09 Å. There is one shorter (2.07 Å) and one longer (2.17 Å) V(3)-F(1) bond length. In the fourth V site, V(4) is bonded to two equivalent O(1), two equivalent F(2), and two equivalent F(3) atoms to form VO2F4 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O4F2 octahedra, and edges with two equivalent V(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. Both V(4)-O(1) bond lengths are 1.97 Å. Both V(4)-F(2) bond lengths are 2.05 Å. Both V(4)-F(3) bond lengths are 1.99 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom.