Ga3NO3 crystallizes in the hexagonal P-6 space group. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one N(2), one O(2), and two equivalent O(1) atoms to form corner-sharing GaNO3 tetrahedra. In the second Ga site, Ga(2) is bonded to one N(1), one O(3), and two equivalent O(1) atoms to form corner-sharing GaNO3 tetrahedra. In the third Ga site, Ga(3) is bonded to one N(2), one O(1), one O(3), and one O(4) atom to form corner-sharing GaNO3 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to three equivalent Ga(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ga(1) and two equivalent Ga(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ga(1), one Ga(2), and one Ga(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to three equivalent Ga(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ga(2) and two equivalent Ga(3) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to three equivalent Ga(3) atoms.
Ga3NO3 crystallizes in the hexagonal P-6 space group. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one N(2), one O(2), and two equivalent O(1) atoms to form corner-sharing GaNO3 tetrahedra. The Ga(1)-N(2) bond length is 1.86 Å. The Ga(1)-O(2) bond length is 1.89 Å. Both Ga(1)-O(1) bond lengths are 1.92 Å. In the second Ga site, Ga(2) is bonded to one N(1), one O(3), and two equivalent O(1) atoms to form corner-sharing GaNO3 tetrahedra. The Ga(2)-N(1) bond length is 1.83 Å. The Ga(2)-O(3) bond length is 1.92 Å. Both Ga(2)-O(1) bond lengths are 1.90 Å. In the third Ga site, Ga(3) is bonded to one N(2), one O(1), one O(3), and one O(4) atom to form corner-sharing GaNO3 tetrahedra. The Ga(3)-N(2) bond length is 1.84 Å. The Ga(3)-O(1) bond length is 1.91 Å. The Ga(3)-O(3) bond length is 1.89 Å. The Ga(3)-O(4) bond length is 1.91 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to three equivalent Ga(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ga(1) and two equivalent Ga(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Ga(1), one Ga(2), and one Ga(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to three equivalent Ga(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ga(2) and two equivalent Ga(3) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to three equivalent Ga(3) atoms.