NaPrTe2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent Te(1) atoms to form NaTe6 octahedra that share corners with six equivalent Pr(1)Te6 octahedra, edges with six equivalent Na(1)Te6 octahedra, and edges with six equivalent Pr(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 1°. Pr(1) is bonded to six equivalent Te(1) atoms to form PrTe6 octahedra that share corners with six equivalent Na(1)Te6 octahedra, edges with six equivalent Na(1)Te6 octahedra, and edges with six equivalent Pr(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 1°. Te(1) is bonded to three equivalent Na(1) and three equivalent Pr(1) atoms to form a mixture of edge and corner-sharing TeNa3Pr3 octahedra. The corner-sharing octahedra are not tilted.
NaPrTe2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Na(1) is bonded to six equivalent Te(1) atoms to form NaTe6 octahedra that share corners with six equivalent Pr(1)Te6 octahedra, edges with six equivalent Na(1)Te6 octahedra, and edges with six equivalent Pr(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 1°. All Na(1)-Te(1) bond lengths are 3.27 Å. Pr(1) is bonded to six equivalent Te(1) atoms to form PrTe6 octahedra that share corners with six equivalent Na(1)Te6 octahedra, edges with six equivalent Na(1)Te6 octahedra, and edges with six equivalent Pr(1)Te6 octahedra. The corner-sharing octahedral tilt angles are 1°. All Pr(1)-Te(1) bond lengths are 3.21 Å. Te(1) is bonded to three equivalent Na(1) and three equivalent Pr(1) atoms to form a mixture of edge and corner-sharing TeNa3Pr3 octahedra. The corner-sharing octahedra are not tilted.