Cd2C4H10O13H2O crystallizes in the triclinic P1 space group. The structure consists of one water molecule inside a Cd2C4H10O13 framework. In the Cd2C4H10O13 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(1), one O(10), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form edge-sharing CdO7 pentagonal bipyramids. In the second Cd site, Cd(2) is bonded to one O(11), one O(12), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form edge-sharing CdO7 pentagonal bipyramids. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(13) and one O(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) and one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) and one O(2) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(11) and one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(13) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(1), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(2), and one H(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1), one C(3), and one H(3) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(2) and one C(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(4) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Cd(2), one H(5), and one H(6) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Cd(2), one H(7), and one H(8) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one H(1), one H(10), and one H(9) atom.
Cd2C4H10O13H2O crystallizes in the triclinic P1 space group. The structure consists of one water molecule inside a Cd2C4H10O13 framework. In the Cd2C4H10O13 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(1), one O(10), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form edge-sharing CdO7 pentagonal bipyramids. The Cd(1)-O(1) bond length is 2.37 Å. The Cd(1)-O(10) bond length is 2.39 Å. The Cd(1)-O(3) bond length is 2.38 Å. The Cd(1)-O(5) bond length is 2.45 Å. The Cd(1)-O(6) bond length is 2.46 Å. The Cd(1)-O(8) bond length is 2.39 Å. The Cd(1)-O(9) bond length is 2.31 Å. In the second Cd site, Cd(2) is bonded to one O(11), one O(12), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form edge-sharing CdO7 pentagonal bipyramids. The Cd(2)-O(11) bond length is 2.36 Å. The Cd(2)-O(12) bond length is 2.41 Å. The Cd(2)-O(2) bond length is 2.37 Å. The Cd(2)-O(4) bond length is 2.37 Å. The Cd(2)-O(5) bond length is 2.36 Å. The Cd(2)-O(7) bond length is 2.45 Å. The Cd(2)-O(8) bond length is 2.45 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(2)-O(3) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(3)-O(5) bond length is 1.27 Å. The C(3)-O(6) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(4)-O(7) bond length is 1.26 Å. The C(4)-O(8) bond length is 1.27 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(13) and one O(9) atom. The H(1)-O(13) bond length is 1.62 Å. The H(1)-O(9) bond length is 1.01 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. The H(2)-O(9) bond length is 0.98 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(10) and one O(6) atom. The H(3)-O(10) bond length is 1.00 Å. The H(3)-O(6) bond length is 1.70 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(10) and one O(2) atom. The H(4)-O(10) bond length is 1.00 Å. The H(4)-O(2) bond length is 1.72 Å. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(11) and one O(3) atom. The H(5)-O(11) bond length is 1.01 Å. The H(5)-O(3) bond length is 1.63 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(11) atom. The H(6)-O(11) bond length is 1.00 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(12) atom. The H(7)-O(12) bond length is 0.98 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(12) atom. The H(8)-O(12) bond length is 0.98 Å. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(13) atom. The H(9)-O(13) bond length is 0.98 Å. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(13) atom. The H(10)-O(13) bond length is 0.99 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(1), and one H(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(2), and one H(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1), one C(3), and one H(3) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(2) and one C(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(2) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(4) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Cd(2), one H(5), and one H(6) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Cd(2), one H(7), and one H(8) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one H(1), one H(10), and one H(9) atom.