LiVCSO7 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. V(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share corners with four equivalent S(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. S(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form SO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-40°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom.
LiVCSO7 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The Li(1)-O(1) bond length is 1.90 Å. The Li(1)-O(2) bond length is 1.91 Å. The Li(1)-O(3) bond length is 1.94 Å. V(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share corners with four equivalent S(1)O4 tetrahedra. The V(1)-O(2) bond length is 2.05 Å. The V(1)-O(3) bond length is 2.01 Å. The V(1)-O(4) bond length is 2.04 Å. The V(1)-O(5) bond length is 2.03 Å. The V(1)-O(6) bond length is 2.06 Å. The V(1)-O(7) bond length is 2.08 Å. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.32 Å. The C(1)-O(3) bond length is 1.34 Å. S(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form SO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-40°. The S(1)-O(4) bond length is 1.48 Å. The S(1)-O(5) bond length is 1.49 Å. The S(1)-O(6) bond length is 1.48 Å. The S(1)-O(7) bond length is 1.48 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom.