N2(NSO3)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight ammonia atoms and eight NSO3 clusters. In each NSO3 cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(2), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom.
N2(NSO3)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight ammonia atoms and eight NSO3 clusters. In each NSO3 cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. The N(2)-S(1) bond length is 1.66 Å. S(1) is bonded in a tetrahedral geometry to one N(2), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.46 Å. The S(1)-O(3) bond length is 1.47 Å. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom.