Ag(AuS)2 crystallizes in the monoclinic Pc space group. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 5-coordinate geometry to two equivalent Au(2), one Ag(1), one S(1), and one S(2) atom. In the second Au site, Au(2) is bonded in a 5-coordinate geometry to two equivalent Au(1), one Ag(1), and two equivalent S(1) atoms. Ag(1) is bonded in a 6-coordinate geometry to one Au(1), one Au(2), one S(1), and three equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Au(1), two equivalent Au(2), and one Ag(1) atom to form distorted SAgAu3 tetrahedra that share corners with two equivalent S(1)AgAu3 tetrahedra and corners with four equivalent S(2)Ag3Au tetrahedra. In the second S site, S(2) is bonded to one Au(1) and three equivalent Ag(1) atoms to form distorted SAg3Au tetrahedra that share corners with four equivalent S(1)AgAu3 tetrahedra and corners with six equivalent S(2)Ag3Au tetrahedra.
Ag(AuS)2 crystallizes in the monoclinic Pc space group. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 5-coordinate geometry to two equivalent Au(2), one Ag(1), one S(1), and one S(2) atom. There is one shorter (3.05 Å) and one longer (3.07 Å) Au(1)-Au(2) bond length. The Au(1)-Ag(1) bond length is 3.14 Å. The Au(1)-S(1) bond length is 2.34 Å. The Au(1)-S(2) bond length is 2.32 Å. In the second Au site, Au(2) is bonded in a 5-coordinate geometry to two equivalent Au(1), one Ag(1), and two equivalent S(1) atoms. The Au(2)-Ag(1) bond length is 3.28 Å. Both Au(2)-S(1) bond lengths are 2.33 Å. Ag(1) is bonded in a 6-coordinate geometry to one Au(1), one Au(2), one S(1), and three equivalent S(2) atoms. The Ag(1)-S(1) bond length is 2.97 Å. There are a spread of Ag(1)-S(2) bond distances ranging from 2.50-2.52 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Au(1), two equivalent Au(2), and one Ag(1) atom to form distorted SAgAu3 tetrahedra that share corners with two equivalent S(1)AgAu3 tetrahedra and corners with four equivalent S(2)Ag3Au tetrahedra. In the second S site, S(2) is bonded to one Au(1) and three equivalent Ag(1) atoms to form distorted SAg3Au tetrahedra that share corners with four equivalent S(1)AgAu3 tetrahedra and corners with six equivalent S(2)Ag3Au tetrahedra.