CrOF4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one F(1), one F(3), one F(5), and one F(7) atom. O(1) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Cr(1) atom.
CrOF4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one F(1), one F(3), one F(5), and one F(7) atom. The Cr(1)-O(1) bond length is 1.56 Å. The Cr(1)-F(1) bond length is 1.76 Å. The Cr(1)-F(3) bond length is 1.76 Å. The Cr(1)-F(5) bond length is 1.78 Å. The Cr(1)-F(7) bond length is 1.76 Å. O(1) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Cr(1) atom.