Ba2CaV2CuF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(2), one F(3), one F(5), one F(6), two equivalent F(1), two equivalent F(4), and two equivalent F(7) atoms. Ca(1) is bonded in a 8-coordinate geometry to two equivalent F(2), two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. V(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom. Cu(1) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a 1-coordinate geometry to two equivalent Ba(1) and one V(1) atom. In the second F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Ba(1), one V(1), and one Cu(1) atom. In the third F site, F(2) is bonded in a 2-coordinate geometry to one Ba(1), one Ca(1), and one V(1) atom. In the fourth F site, F(3) is bonded in a 2-coordinate geometry to one Ba(1), one V(1), and one Cu(1) atom. In the fifth F site, F(4) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Ca(1), and one V(1) atom. In the sixth F site, F(5) is bonded in a 3-coordinate geometry to one Ba(1), one Ca(1), and one V(1) atom. In the seventh F site, F(6) is bonded in a distorted trigonal planar geometry to one Ba(1), one Ca(1), and one Cu(1) atom.
Ba2CaV2CuF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(2), one F(3), one F(5), one F(6), two equivalent F(1), two equivalent F(4), and two equivalent F(7) atoms. The Ba(1)-F(2) bond length is 2.93 Å. The Ba(1)-F(3) bond length is 2.98 Å. The Ba(1)-F(5) bond length is 2.72 Å. The Ba(1)-F(6) bond length is 2.73 Å. There is one shorter (2.78 Å) and one longer (2.86 Å) Ba(1)-F(1) bond length. There is one shorter (2.80 Å) and one longer (2.87 Å) Ba(1)-F(4) bond length. There is one shorter (2.73 Å) and one longer (3.05 Å) Ba(1)-F(7) bond length. Ca(1) is bonded in a 8-coordinate geometry to two equivalent F(2), two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. Both Ca(1)-F(2) bond lengths are 2.34 Å. Both Ca(1)-F(4) bond lengths are 2.60 Å. Both Ca(1)-F(5) bond lengths are 2.37 Å. Both Ca(1)-F(6) bond lengths are 2.31 Å. V(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom. The V(1)-F(1) bond length is 1.98 Å. The V(1)-F(2) bond length is 1.97 Å. The V(1)-F(3) bond length is 1.98 Å. The V(1)-F(4) bond length is 2.01 Å. The V(1)-F(5) bond length is 1.95 Å. The V(1)-F(7) bond length is 1.93 Å. Cu(1) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. Both Cu(1)-F(1) bond lengths are 2.55 Å. Both Cu(1)-F(3) bond lengths are 2.02 Å. Both Cu(1)-F(6) bond lengths are 1.91 Å. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a 1-coordinate geometry to two equivalent Ba(1) and one V(1) atom. In the second F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Ba(1), one V(1), and one Cu(1) atom. In the third F site, F(2) is bonded in a 2-coordinate geometry to one Ba(1), one Ca(1), and one V(1) atom. In the fourth F site, F(3) is bonded in a 2-coordinate geometry to one Ba(1), one V(1), and one Cu(1) atom. In the fifth F site, F(4) is bonded in a 4-coordinate geometry to two equivalent Ba(1), one Ca(1), and one V(1) atom. In the sixth F site, F(5) is bonded in a 3-coordinate geometry to one Ba(1), one Ca(1), and one V(1) atom. In the seventh F site, F(6) is bonded in a distorted trigonal planar geometry to one Ba(1), one Ca(1), and one Cu(1) atom.