(Co(NO2)6)2(N2)3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3 space group. The structure is zero-dimensional and consists of twelve ammonia atoms and four Co(NO2)6 clusters. In each Co(NO2)6 cluster, Co(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one N(1) atom.
(Co(NO2)6)2(N2)3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3 space group. The structure is zero-dimensional and consists of twelve ammonia atoms and four Co(NO2)6 clusters. In each Co(NO2)6 cluster, Co(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. All Co(1)-N(1) bond lengths are 2.05 Å. N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. Both N(1)-O(1) bond lengths are 1.22 Å. O(1) is bonded in a single-bond geometry to one N(1) atom.