MnAs2S2(OF3)4 crystallizes in the orthorhombic Fdd2 space group. Mn(1) is bonded to two equivalent O(1), two equivalent F(1), and two equivalent F(2) atoms to form MnO2F4 octahedra that share corners with four equivalent As(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. As(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form AsF6 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one As(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom.
MnAs2S2(OF3)4 crystallizes in the orthorhombic Fdd2 space group. Mn(1) is bonded to two equivalent O(1), two equivalent F(1), and two equivalent F(2) atoms to form MnO2F4 octahedra that share corners with four equivalent As(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. Both Mn(1)-O(1) bond lengths are 2.19 Å. Both Mn(1)-F(1) bond lengths are 2.18 Å. Both Mn(1)-F(2) bond lengths are 2.15 Å. As(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form AsF6 octahedra that share corners with two equivalent Mn(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 23-32°. The As(1)-F(1) bond length is 1.84 Å. The As(1)-F(2) bond length is 1.84 Å. The As(1)-F(3) bond length is 1.74 Å. The As(1)-F(4) bond length is 1.74 Å. The As(1)-F(5) bond length is 1.76 Å. The As(1)-F(6) bond length is 1.76 Å. S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.44 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one As(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom.