Dy2Mn3Cu9P7 crystallizes in the hexagonal P-6 space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 6-coordinate geometry to six equivalent P(2) atoms. In the second Dy site, Dy(2) is bonded in a 6-coordinate geometry to six equivalent P(1) atoms. Mn(1) is bonded in a 5-coordinate geometry to one P(2), two equivalent P(1), and two equivalent P(3) atoms. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent P(1) and two equivalent P(2) atoms to form distorted corner-sharing CuP4 tetrahedra. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one P(1), one P(3), and two equivalent P(2) atoms. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent P(2) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Dy(2), two equivalent Mn(1), one Cu(2), two equivalent Cu(1), and two equivalent Cu(3) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Mn(1), two equivalent Cu(1), two equivalent Cu(2), and two equivalent Cu(3) atoms. In the third P site, P(3) is bonded in a 9-coordinate geometry to six equivalent Mn(1) and three equivalent Cu(2) atoms.
Dy2Mn3Cu9P7 crystallizes in the hexagonal P-6 space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 6-coordinate geometry to six equivalent P(2) atoms. All Dy(1)-P(2) bond lengths are 2.90 Å. In the second Dy site, Dy(2) is bonded in a 6-coordinate geometry to six equivalent P(1) atoms. All Dy(2)-P(1) bond lengths are 2.88 Å. Mn(1) is bonded in a 5-coordinate geometry to one P(2), two equivalent P(1), and two equivalent P(3) atoms. The Mn(1)-P(2) bond length is 2.40 Å. Both Mn(1)-P(1) bond lengths are 2.64 Å. Both Mn(1)-P(3) bond lengths are 2.62 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent P(1) and two equivalent P(2) atoms to form distorted corner-sharing CuP4 tetrahedra. There is one shorter (2.32 Å) and one longer (2.43 Å) Cu(1)-P(1) bond length. Both Cu(1)-P(2) bond lengths are 2.39 Å. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one P(1), one P(3), and two equivalent P(2) atoms. The Cu(2)-P(1) bond length is 2.33 Å. The Cu(2)-P(3) bond length is 2.30 Å. Both Cu(2)-P(2) bond lengths are 2.41 Å. In the third Cu site, Cu(3) is bonded in a 4-coordinate geometry to two equivalent P(1) and two equivalent P(2) atoms. Both Cu(3)-P(1) bond lengths are 2.40 Å. There is one shorter (2.37 Å) and one longer (2.44 Å) Cu(3)-P(2) bond length. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Dy(2), two equivalent Mn(1), one Cu(2), two equivalent Cu(1), and two equivalent Cu(3) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Mn(1), two equivalent Cu(1), two equivalent Cu(2), and two equivalent Cu(3) atoms. In the third P site, P(3) is bonded in a 9-coordinate geometry to six equivalent Mn(1) and three equivalent Cu(2) atoms.