PdGa2Br8 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two PdGa2Br8 clusters. Pd(1) is bonded in a square co-planar geometry to four equivalent Br(1) atoms. Ga(1) is bonded in a tetrahedral geometry to one Br(2), one Br(3), and two equivalent Br(1) atoms. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one Pd(1) and one Ga(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Ga(1) atom.
PdGa2Br8 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two PdGa2Br8 clusters. Pd(1) is bonded in a square co-planar geometry to four equivalent Br(1) atoms. All Pd(1)-Br(1) bond lengths are 2.46 Å. Ga(1) is bonded in a tetrahedral geometry to one Br(2), one Br(3), and two equivalent Br(1) atoms. The Ga(1)-Br(2) bond length is 2.27 Å. The Ga(1)-Br(3) bond length is 2.30 Å. Both Ga(1)-Br(1) bond lengths are 2.43 Å. There are three inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one Pd(1) and one Ga(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Ga(1) atom.