V6FeNi crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Fe(1), and two equivalent Ni(1) atoms. Fe(1) is bonded to twelve equivalent V(1) atoms to form FeV12 cuboctahedra that share edges with six equivalent Fe(1)V12 cuboctahedra and faces with eight equivalent Ni(1)V12 cuboctahedra. Ni(1) is bonded to twelve equivalent V(1) atoms to form NiV12 cuboctahedra that share edges with six equivalent Ni(1)V12 cuboctahedra and faces with eight equivalent Fe(1)V12 cuboctahedra.
V6FeNi crystallizes in the cubic Pm-3 space group. V(1) is bonded in a 6-coordinate geometry to two equivalent V(1), two equivalent Fe(1), and two equivalent Ni(1) atoms. There is one shorter (2.30 Å) and one longer (2.33 Å) V(1)-V(1) bond length. Both V(1)-Fe(1) bond lengths are 2.58 Å. Both V(1)-Ni(1) bond lengths are 2.59 Å. Fe(1) is bonded to twelve equivalent V(1) atoms to form FeV12 cuboctahedra that share edges with six equivalent Fe(1)V12 cuboctahedra and faces with eight equivalent Ni(1)V12 cuboctahedra. Ni(1) is bonded to twelve equivalent V(1) atoms to form NiV12 cuboctahedra that share edges with six equivalent Ni(1)V12 cuboctahedra and faces with eight equivalent Fe(1)V12 cuboctahedra.