KTeF5 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 10-coordinate geometry to two equivalent F(1), four equivalent F(2), and four equivalent F(3) atoms. Te(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Te(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Te(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Te(1) atom.
KTeF5 crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 10-coordinate geometry to two equivalent F(1), four equivalent F(2), and four equivalent F(3) atoms. Both K(1)-F(1) bond lengths are 2.87 Å. There are two shorter (2.69 Å) and two longer (2.84 Å) K(1)-F(2) bond lengths. There are two shorter (2.66 Å) and two longer (2.82 Å) K(1)-F(3) bond lengths. Te(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. The Te(1)-F(1) bond length is 1.90 Å. Both Te(1)-F(2) bond lengths are 1.98 Å. Both Te(1)-F(3) bond lengths are 1.98 Å. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Te(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Te(1) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Te(1) atom.