VIn3S4 crystallizes in the cubic I-43m space group. The structure consists of a VIn3S4 framework. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. In(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded to one V(1) and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing SVIn3 trigonal pyramids.
VIn3S4 crystallizes in the cubic I-43m space group. The structure consists of a VIn3S4 framework. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. All V(1)-S(1) bond lengths are 2.17 Å. In(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. All In(1)-S(1) bond lengths are 3.05 Å. S(1) is bonded to one V(1) and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing SVIn3 trigonal pyramids.