CeCo2Ge2 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to eight equivalent Co(1) and eight equivalent Ge(1) atoms. Co(1) is bonded in a 4-coordinate geometry to four equivalent Ce(1) and four equivalent Ge(1) atoms. Ge(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), four equivalent Co(1), and one Ge(1) atom.
CeCo2Ge2 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to eight equivalent Co(1) and eight equivalent Ge(1) atoms. All Ce(1)-Co(1) bond lengths are 3.18 Å. All Ce(1)-Ge(1) bond lengths are 3.21 Å. Co(1) is bonded in a 4-coordinate geometry to four equivalent Ce(1) and four equivalent Ge(1) atoms. All Co(1)-Ge(1) bond lengths are 2.34 Å. Ge(1) is bonded in a 9-coordinate geometry to four equivalent Ce(1), four equivalent Co(1), and one Ge(1) atom. The Ge(1)-Ge(1) bond length is 2.63 Å.