CsDyS2 is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. Dy(1) is bonded to six equivalent S(1) atoms to form edge-sharing DyS6 octahedra. S(1) is bonded to three equivalent Cs(1) and three equivalent Dy(1) atoms to form a mixture of distorted face, corner, and edge-sharing SCs3Dy3 octahedra. The corner-sharing octahedral tilt angles range from 0-40°.
CsDyS2 is H-Phase structured and crystallizes in the hexagonal P6_3/mmc space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent S(1) atoms. All Cs(1)-S(1) bond lengths are 3.48 Å. Dy(1) is bonded to six equivalent S(1) atoms to form edge-sharing DyS6 octahedra. All Dy(1)-S(1) bond lengths are 2.77 Å. S(1) is bonded to three equivalent Cs(1) and three equivalent Dy(1) atoms to form a mixture of distorted face, corner, and edge-sharing SCs3Dy3 octahedra. The corner-sharing octahedral tilt angles range from 0-40°.