LiAgF2 crystallizes in the orthorhombic Cmcm space group. Li(1) is bonded to two equivalent F(1) and two equivalent F(2) atoms to form corner-sharing LiF4 tetrahedra. Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted linear geometry to two equivalent Li(1) and four equivalent Ag(1) atoms.
LiAgF2 crystallizes in the orthorhombic Cmcm space group. Li(1) is bonded to two equivalent F(1) and two equivalent F(2) atoms to form corner-sharing LiF4 tetrahedra. Both Li(1)-F(1) bond lengths are 1.88 Å. Both Li(1)-F(2) bond lengths are 1.88 Å. Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(2) atoms. Both Ag(1)-F(1) bond lengths are 2.51 Å. All Ag(1)-F(2) bond lengths are 2.60 Å. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted linear geometry to two equivalent Li(1) and four equivalent Ag(1) atoms.