Mn(CO)5Cl is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four Mn(CO)5Cl clusters. Mn(1) is bonded in an octahedral geometry to one C(3), two equivalent C(1), two equivalent C(2), and one Cl(1) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom.
Mn(CO)5Cl is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four Mn(CO)5Cl clusters. Mn(1) is bonded in an octahedral geometry to one C(3), two equivalent C(1), two equivalent C(2), and one Cl(1) atom. The Mn(1)-C(3) bond length is 1.83 Å. Both Mn(1)-C(1) bond lengths are 1.90 Å. Both Mn(1)-C(2) bond lengths are 1.89 Å. The Mn(1)-Cl(1) bond length is 2.41 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. The C(1)-O(1) bond length is 1.15 Å. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. The C(2)-O(2) bond length is 1.15 Å. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(3) atom. The C(3)-O(3) bond length is 1.16 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom.