NdCPH3O6H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a NdCPH3O6 framework. In the NdCPH3O6 framework, Nd(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(7) atoms. C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(6) atom. P(1) is bonded in a distorted tetrahedral geometry to one H(5), one O(1), one O(3), and one O(7) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one P(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one C(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Nd(1) and one P(1) atom. In the fourth O site, O(5) is bonded in a distorted water-like geometry to one Nd(1), one H(2), and one H(4) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one Nd(1) and one C(1) atom. In the sixth O site, O(7) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one P(1) atom.
NdCPH3O6H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a NdCPH3O6 framework. In the NdCPH3O6 framework, Nd(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(7) atoms. The Nd(1)-O(2) bond length is 2.49 Å. The Nd(1)-O(3) bond length is 2.40 Å. The Nd(1)-O(5) bond length is 2.46 Å. The Nd(1)-O(6) bond length is 2.51 Å. There is one shorter (2.42 Å) and one longer (2.55 Å) Nd(1)-O(1) bond length. There is one shorter (2.45 Å) and one longer (2.56 Å) Nd(1)-O(7) bond length. C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(6) atom. The C(1)-O(2) bond length is 1.26 Å. The C(1)-O(6) bond length is 1.27 Å. P(1) is bonded in a distorted tetrahedral geometry to one H(5), one O(1), one O(3), and one O(7) atom. The P(1)-H(5) bond length is 1.41 Å. The P(1)-O(1) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.53 Å. The P(1)-O(7) bond length is 1.56 Å. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(5) atom. The H(2)-O(5) bond length is 1.00 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(5) atom. The H(4)-O(5) bond length is 0.99 Å. In the third H site, H(5) is bonded in a single-bond geometry to one P(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Nd(1) and one C(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Nd(1) and one P(1) atom. In the fourth O site, O(5) is bonded in a distorted water-like geometry to one Nd(1), one H(2), and one H(4) atom. In the fifth O site, O(6) is bonded in a distorted single-bond geometry to one Nd(1) and one C(1) atom. In the sixth O site, O(7) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one P(1) atom.