LiVTe(WO6)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. V(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-38°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-38°. In the second W site, W(2) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form WO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-41°. Te(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-41°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one W(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one W(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one W(2), and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one W(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(1) and one W(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom.
LiVTe(WO6)2 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. The Li(1)-O(10) bond length is 2.45 Å. The Li(1)-O(2) bond length is 2.54 Å. The Li(1)-O(5) bond length is 1.98 Å. The Li(1)-O(6) bond length is 1.98 Å. The Li(1)-O(8) bond length is 2.46 Å. The Li(1)-O(9) bond length is 2.02 Å. V(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-38°. The V(1)-O(10) bond length is 1.73 Å. The V(1)-O(11) bond length is 2.12 Å. The V(1)-O(2) bond length is 1.74 Å. The V(1)-O(3) bond length is 2.09 Å. The V(1)-O(5) bond length is 2.04 Å. The V(1)-O(8) bond length is 1.81 Å. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-38°. The W(1)-O(10) bond length is 2.11 Å. The W(1)-O(3) bond length is 1.80 Å. The W(1)-O(5) bond length is 1.88 Å. The W(1)-O(6) bond length is 2.07 Å. The W(1)-O(7) bond length is 1.93 Å. The W(1)-O(8) bond length is 1.98 Å. In the second W site, W(2) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form WO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-41°. The W(2)-O(1) bond length is 1.94 Å. The W(2)-O(11) bond length is 1.78 Å. The W(2)-O(12) bond length is 1.96 Å. The W(2)-O(2) bond length is 2.10 Å. The W(2)-O(4) bond length is 1.92 Å. The W(2)-O(9) bond length is 2.01 Å. Te(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-41°. The Te(1)-O(1) bond length is 1.92 Å. The Te(1)-O(12) bond length is 1.93 Å. The Te(1)-O(4) bond length is 1.95 Å. The Te(1)-O(6) bond length is 1.93 Å. The Te(1)-O(7) bond length is 1.93 Å. The Te(1)-O(9) bond length is 1.95 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one W(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one W(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one W(2), and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one W(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(1) and one W(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom.