Ce2WO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Ce(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CeO6 octahedra that share corners with four equivalent Ce(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra,  an edgeedge with one Ce(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with eight equivalent Ce(1)O6 octahedra and edges with two equivalent Ce(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Ce(1) and one W(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ce(1) and one W(1) atom.
Ce2WO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Ce(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CeO6 octahedra that share corners with four equivalent Ce(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra,  an edgeedge with one Ce(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. Both Ce(1)-O(1) bond lengths are 2.29 Å. There are two shorter (2.25 Å) and two longer (2.28 Å) Ce(1)-O(2) bond lengths. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form WO6 octahedra that share corners with eight equivalent Ce(1)O6 octahedra and edges with two equivalent Ce(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-50°. Both W(1)-O(1) bond lengths are 2.08 Å. All W(1)-O(2) bond lengths are 2.09 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Ce(1) and one W(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ce(1) and one W(1) atom.