BP4(SBr)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two BP4(SBr)3 clusters. B(1) is bonded in a tetrahedral geometry to one P(2), one Br(1), and two equivalent Br(2) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one S(2) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one B(1), one S(1), and two equivalent S(2) atoms. In the third P site, P(3) is bonded in a distorted single-bond geometry to one S(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one P(2) and one P(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(1) and one P(2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one B(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one B(1) atom.
BP4(SBr)3 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two BP4(SBr)3 clusters. B(1) is bonded in a tetrahedral geometry to one P(2), one Br(1), and two equivalent Br(2) atoms. The B(1)-P(2) bond length is 2.02 Å. The B(1)-Br(1) bond length is 2.03 Å. Both B(1)-Br(2) bond lengths are 2.00 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one S(2) atom. The P(1)-S(2) bond length is 2.11 Å. In the second P site, P(2) is bonded in a tetrahedral geometry to one B(1), one S(1), and two equivalent S(2) atoms. The P(2)-S(1) bond length is 2.09 Å. Both P(2)-S(2) bond lengths are 2.09 Å. In the third P site, P(3) is bonded in a distorted single-bond geometry to one S(1) atom. The P(3)-S(1) bond length is 2.10 Å. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one P(2) and one P(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(1) and one P(2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one B(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one B(1) atom.