TiO2 is Hydrophilite-like structured and crystallizes in the tetragonal I4/m space group. Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ti(1) atoms.
TiO2 is Hydrophilite-like structured and crystallizes in the tetragonal I4/m space group. Ti(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles are 48°. There is one shorter (1.89 Å) and two longer (2.01 Å) Ti(1)-O(1) bond lengths. There are two shorter (1.92 Å) and one longer (2.06 Å) Ti(1)-O(2) bond length. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ti(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ti(1) atoms.