Os2OCl10(N2)2 is Indium-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of eight ammonia atoms and two Os2OCl10 clusters. In each Os2OCl10 cluster, Os(1) is bonded to one O(1), one Cl(1), and four equivalent Cl(2) atoms to form corner-sharing OsCl5O octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to two equivalent Os(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Os(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Os(1) atom.
Os2OCl10(N2)2 is Indium-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of eight ammonia atoms and two Os2OCl10 clusters. In each Os2OCl10 cluster, Os(1) is bonded to one O(1), one Cl(1), and four equivalent Cl(2) atoms to form corner-sharing OsCl5O octahedra. The corner-sharing octahedra are not tilted. The Os(1)-O(1) bond length is 1.86 Å. The Os(1)-Cl(1) bond length is 2.26 Å. All Os(1)-Cl(2) bond lengths are 2.31 Å. O(1) is bonded in a linear geometry to two equivalent Os(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Os(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Os(1) atom.