FeS is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Fe(1) is bonded to six equivalent S(1) atoms to form a mixture of face, corner, and edge-sharing FeS6 octahedra. The corner-sharing octahedral tilt angles are 48°. S(1) is bonded to six equivalent Fe(1) atoms to form a mixture of distorted corner and edge-sharing SFe6 pentagonal pyramids.
FeS is Molybdenum Carbide MAX Phase-like structured and crystallizes in the hexagonal P6_3/mmc space group. Fe(1) is bonded to six equivalent S(1) atoms to form a mixture of face, corner, and edge-sharing FeS6 octahedra. The corner-sharing octahedral tilt angles are 48°. All Fe(1)-S(1) bond lengths are 2.43 Å. S(1) is bonded to six equivalent Fe(1) atoms to form a mixture of distorted corner and edge-sharing SFe6 pentagonal pyramids.