  The real-time broadening of density profiles starting from non-equilibrium
states is at the center of transport in condensed-matter systems and dynamics
in ultracold atomic gases. Initial profiles close to equilibrium are expected
to evolve according to linear response, e.g., as given by the current
correlator evaluated exactly at equilibrium. Significantly off equilibrium,
linear response is expected to break down and even a description in terms of
canonical ensembles is questionable. We unveil that single pure states with
density profiles of maximum amplitude yield a broadening in perfect agreement
with linear response, if the structure of these states involves randomness in
terms of decoherent off-diagonal density-matrix elements. While these states
allow for spin diffusion in the XXZ spin-1/2 chain at large exchange
anisotropies, coherences yield entirely different behavior.

Strongly Correlated Electrons;Statistical Mechanics