  Lattice and magnetic dynamics of NiWO$_4$ single crystals were studied with
the use of polarized Raman spectroscopy in a wide temperature range of 10-300 K
including the antiferromagnetic ordering temperature $T_N$=62 K. Static
magnetic measurements were used for characterizing the single crystals. All
Raman-active phonons predicted by the group theory were observed and
characterized. Magnetic symmetry analysis was used to determine possible
magnetic space groups for NiWO$_4$ which can be also applied to any other
isostructural crystal with the same magnetic propagation vector k=(1/2,0,0).
Though the magnetic structure of NiWO$_4$ is relatively simple, a rich set of
narrow and broad magnetic excitations with different polarization properties
and temperature behavior in the very broad frequency range of 10-200 cm$^{-1}$
was observed, with some modes surviving at temperatures much higher than $T_N$
up to 220 K. Part of the magnetic excitations was identified as acoustic and
optical spin-wave branches which allow us to construct exchange structure and
estimate exchange and anisotropy constants with the use of linear spin-wave
theory. Since the magnetic structure can be described as exchange-coupled AFM
chains of $S=1$ ions, previously unobserved magnetic excitation at 24 cm$^{-1}$
is tentatively assigned to a Haldane gap mode.

Materials Science