  We have measured the effect of microwave irradiation on the dc
current-voltage characteristics of superconducting atomic contacts. The
interaction of the external field with the ac supercurrents leads to replicas
of the supercurrent peak, the well known Shapiro resonances. The observation of
supplementary fractional resonances for contacts containing highly transmitting
conduction channels reveals their non-sinusoidal current-phase relation. The
resonances sit on a background current which is itself deeply modified, as a
result of photon assisted multiple Andreev reflections. The results provide
firm support for the full quantum theory of transport between two
superconductors based on the concept of Andreev bound states.

Mesoscale and Nanoscale Physics;Superconductivity