  Within the frame of macroscopic QED in linear, causal media, we study the
radiation force of Casimir-Polder type acting on an atom which is positioned
near dispersing and absorbing magnetodielectric bodies and initially prepared
in an arbitrary electronic state. It is shown that minimal and multipolar
coupling lead to essentially the same lowest-order perturbative result for the
force acting on an atom in an energy eigenstate. To go beyond perturbation
theory, the calculations are based on the exact center-of-mass equation of
motion. For a nondriven atom in the weak-coupling regime, the force as a
function of time is a superposition of force components that are related to the
electronic density-matrix elements at a chosen time. Even the force component
associated with the ground state is not derivable from a potential in the
ususal way, because of the position dependence of the atomic polarizability.
Further, when the atom is initially prepared in a coherent superposition of
energy eigenstates, then temporally oscillating force components are observed,
which are due to the interaction of the atom with both electric and magnetic
fields.

Quantum Physics