  A computational procedure that allows the detection of a new type of
high-dimensional chaotic saddle in Hamiltonian systems with three degrees of
freedom is presented. The chaotic saddle is associated with a so-called
normally hyperbolic invariant manifold (NHIM). The procedure allows to compute
appropriate homoclinic orbits to the NHIM from which we can infer the existence
a chaotic saddle. NHIMs control the phase space transport across an equilibrium
point of saddle-centre-...-centre stability type, which is a fundamental
mechanism for chemical reactions, capture and escape, scattering, and, more
generally, ``transformation'' in many different areas of physics. Consequently,
the presented methods and results are of broad interest. The procedure is
illustrated for the spatial Hill's problem which is a well known model in
celestial mechanics and which gained much interest e.g. in the study of the
formation of binaries in the Kuiper belt.

Chaotic Dynamics