  Micro-solid oxide fuel cells based on thin films have strong potential for
use in portable power devices. However, devices based on silicon substrates
typically involve thin-film metallic electrodes which are unstable at high
temperatures. Devices based on bulk metal substrates overcome these
limitations, though performance is hindered by the challenge of growing
state-of-the-art epitaxial materials on metals. Here, we demonstrate for the
first time the growth of epitaxial cathode materials on metal substrates
(stainless steel) commercially supplied with epitaxial electrolyte layers (1.5
{um (Y2O3)0.15(ZrO2)0.85 (YSZ) + 50 nm CeO2). We create epitaxial mesoporous
cathodes of (La0.60Sr0.40)0.95Co0.20Fe0.80O3 (LSCF) on the substrate by growing
LSCF/MgO vertically aligned nanocomposite films by pulsed laser deposition,
followed by selectively etching out the MgO. To enable valid comparison with
the literature, the cathodes are also grown on single-crystal substrates,
confirming state-of-the-art performance with an area specific resistance of
100ohmegacm2 at 500dC and activation energy down to 0.97 eV. The work marks an
important step toward the commercialization of high-performance micro-solid
oxide fuel cells for portable power applications.

Applied Physics;Materials Science