  New metal-ordered manganites RBaMn_{2}O_{6} have been synthesized and
investigated in the structures and electromagnetic properties. RBaMn_{2}O_{6}
can be classified into three groups from the structural and electromagnetic
properties. The first group (R = La, Pr and Nd) has a metallic ferromagnetic
transition, followed by an A-type antiferromagnetic transition in
PrBaMn_{2}O_{6}. The second group (R = Sm, Eu and Gd) exhibits a charge-order
transition, followed by an antiferromagnetic long range ordering. The third
group (R = Tb, Dy and Ho) shows successive three phase transitions, the
structural, charge/orbital-order and magnetic transitions, as observed in
YBaMn_{2}O_{6}. Comparing to the metal-disordered manganites
(R^{3+}_{0.5}A^{2+}_{0.5})MnO_{3}, two remarkable features can be recognized in
RBaMn_{2}O_{6}; (1) relatively high charge-order transition temperature and (2)
the presence of structural transition above the charge-order temperature in the
third group. We propose a possible orbital ordering at the structural
transition, that is a possible freezing of the orbital, charge and spin degrees
of freedom at the independent temperatures in the third group. These features
are closely related to the peculiar structure that the MnO_{2} square-lattice
is sandwiched by the rock-salt layers of two kinds, RO and BaO with extremely
different lattice-sizes.

Strongly Correlated Electrons