  We present Keck HIRES spectra of 6 late-M dwarfs and 11 L dwarfs. Our goal is
to assign effective temperatures to the objects using detailed atmospheric
models and fine analysis of the alkali resonance absorption lines of CsI and
RbI. These yield mutually consistent results (+-150 K) when we use
``cleared-dust'' models, which account for the removal of refractory species
from the molecular states but do not include dust opacities. We find a tendency
for the RbI line to imply a slightly higher temperature, which we ascribe to an
incomplete treatment of the overlying molecular opacities. The final effective
temperatures we adopt are based on the CsI fits alone, though the RbI fits
support the CsI temperature sequence. This work, in combination with results
from the infrared, hints that dust in these atmospheres has settled out of the
high atmosphere but is present in the deep photosphere. We also derive radial
and rotational velocities for all the objects, finding that the previously
discovered trend of rapid rotation for very low mass objects is quite
pervasive. To improve on our analysis, there is a clear need for better
molecular line lists and a more detailed understanding of dust formation and
dynamics.

Astrophysics