  (Abbrev.) We present high-resolution spectroscopy of the oxygen K-shell
interstellar absorption edge in 7 X-ray binaries using the HETGS onboard
Chandra. Using the brightest sources as templates, we found a best-fit model of
2 absorption edges and 5 Gaussian absorption lines. All of these features can
be explained by the recent predictions of K-shell absorption from neutral and
ionized atomic oxygen. We identify the K alpha and K beta absorption lines from
neutral oxygen, as well as the S=3/2 absorption edge. The expected S=1/2 edge
is not detected in these data due to overlap with instrumental features. We
also identify the K alpha absorption lines from singly and doubly ionized
oxygen. The OI K alpha absorption line is used as a benchmark with which to
adjust the absolute wavelength scale for theoretical predictions of the
absorption cross-sections. We find that shifts of 30-50 mA are required,
consistent with differences previously noticed from comparisons of the theory
with laboratory measurements. Significant oxygen features from dust or
molecular components, as suggested in previous studies, are not required by our
HETGS spectra. With these spectra, we can begin to measure the large-scale
properties of the ISM. We place a limit on the velocity dispersion of the
neutral lines of <200 km s^{-1}, consistent with measurements at other
wavelengths. We also make the first measurement of the oxygen ionization
fractions in the ISM. We constrain the interstellar ratio of OII/OI to ~0.1 and
the ratio of OIII/OI to <0.1.

Astrophysics