  Measurements of the heat capacity C(T,H) of the one-dimensional quantum
magnet TiOCl are presented for temperatures 2K < T < 300K and magnetic fields
up to 5T. Distinct anomalies at 91K and 67K signal two subsequent phase
transitions. The lower of these transitions clearly is of first order and seems
to be related to the spin degrees of freedom. The transition at 92K probably
involves the lattice and/or orbital moments. A detailed analysis of the data
reveals that the entropy change through both transitions is surprisingly small
(~ 0.1R), pointing to the existence strong fluctuations well into the
non-ordered high-temperature phase. No significant magnetic field dependence
was detected.

Strongly Correlated Electrons;Materials Science