  Charge-transfer excitations are of paramount importance for understanding the
electronic structure of copper-oxide based high-temperature superconductors. In
this study, we investigate the response of a
Bi$_2$Sr$_2$CaCu$_2$O$_{\mathrm{8}+ \delta}$ crystal to the charge
redistribution induced by an infrared ultrashort pulse. Element-selective
time-resolved core-level photoelectron spectroscopy with a high energy
resolution allows disentangling the dynamics of oxygen ions with different
coordination and bonds thanks to their different chemical shifts. Our
experiment shows that the O\,$1s$ component arising from the Cu-O planes is
significantly perturbed by the infrared light pulse. Conversely, the apical
oxygen, also coordinated with Sr ions in the Sr-O planes, remains unaffected.
This result highlights the peculiar behavior of the electronic structure of the
Cu-O planes. It also unlocks the way to study the out-of-equilibrium electronic
structure of copper-oxide-based high-temperature superconductors by identifying
the O\,$1s$ core-level emission originating from the oxygen ions in the Cu-O
planes. This ability could be critical to gain information about the
strongly-correlated electron ultrafast dynamical mechanisms in the Cu-O plane
in the normal and superconducting phases.

Strongly Correlated Electrons;Superconductivity