  The modification of the boundary condition for polyelectrolyte adsorption on
charged surface with short-ranged interaction is investigated under two
regimes. For weakly charged Gaussian polymer in which the short-ranged
attraction dominates, the boundary condition is the same as that of the neutral
polymer adsorption. For highly charged polymer (compressed state) in which the
electrostatic interaction dominates, the linear relationship (electrostatic
boundary condition) between the surface monomer density and the surface charge
density needs to be modified.

Soft Condensed Matter;Statistical Mechanics;Chemical Physics