Mathematical Fundamentals Exercise \(\PageIndex{1a}\) Define the following: Commutative property of addition Associative property of addition Distributive property of multiplication Answer a The order of addition does not matter: A+B=B+A Answer b the sum of three or more numbers is the same, no matter how you add them. (A+B)+C=(B+C)+A=(C+A)+B... Answer c The product of multiplying the sum of two numbers by a third number is the same as the sum of multiplying both numbers by the third and summing the two products. A(B+C)=AB+AC Algebra review Exercise \(\PageIndex{2a}\) Solve For \(A\) for each of the following equations: a. \(A(X+Y)=Z\) b. \((AX+Y)=Z\) c. \((AX+AY)=Z\) d. \((AX+Y)Z=1\) e. \(\frac{A}{X+Y}=Z\) f. \(\frac{1}{AX+AY}=Z\) g.\(\frac{1}{X+AY}=Z\) h.\(\frac{A}{X+Y}=ZA+3\) i.\(\frac{A}{X+Y}=ZA+D\) Answer a \(A(X+Y)=Z\\\frac{A(X+Y)}{X+Y}=\frac{Z}{X+Y} \text{ divide both sides by X+Y}\\ \frac{A\cancel{(X+Y)}}{\cancel{X+Y}}=\frac{Z}{X+Y} \text{ anything divided by itself = 1, so }\frac{X+Y}{X+Y}=1\\ A=\frac{Z}{X+Y}\) Answer b \((AX+Y)=Z \text{; subtract Y from both sides}\\(AX+Y)-Y=Z-Y \text{; note that Y-Y=0}\\(AX+\cancel{Y})-\cancel{Y}=Z-Y \text{; divide both sides by X}\\ \frac{AX}{X}=\frac{Z-Y}{X} \text{; x/x cancels}\\ \frac{A\cancel{X}}{\cancel{X}}=\frac{Z-Y}{X}\\A=\frac{Z-Y}{X}\) Answer c \((AX+AY)=Z\\A(X+Y)=Z \text{; factor out the common term A}\\ \frac{A(X+Y)}{(X+Y)}=\frac{Z}{X+Y} \text{; divide both sides by X+Y and cancel it on the left}\\ A=\frac{Z}{X+Y}\) Answer d \((AX+Y)Z=1 \text{; divide both sides by Z and cancel the z/z term on the left} \\ AX+Y=\frac{1}{Z} \text{; subtract Y from both sides and cancel on the left} \\ AX=\frac{1}{Z}-Y \text{; divide both sides by x and cancel on the left} \\A=\frac{\frac{1}{Z}-Y}{X}\) Answer e \(\frac{A}{X+Y}=Z \text{; multiply both sides by (X+Y)} \\ \frac{A}{X+Y}(X+Y)=Z(X+Y) \text{; rearrange and cancel}\\ A\frac{\cancel{(X+Y)}}{\cancel{X+Y}}=Z(X+Y)\\A=Z(X+Y)\) Answer f \(\frac{1}{AX+AY}=Z \text{ (take the reciprocal of both sides to put A on the numerator)} \\AX+AY=\frac{1}{Z}\\A(X+Y)=\frac{1}{Z} \text{; divide both sides by (X+Y) and cancel} \\\frac{A\cancel{(X+Y)}}{\cancel{(X+Y)}}=\frac{1}{Z(X+Y)}\\A=\frac{1}{Z(X+Y)}\) Answer g \(\frac{1}{X+AY}=Z \text{ take the reciprocal of both sides to put A on the numerator} \\X+AY=\frac{1}{Z} \text{; subtract X from both sides to cancel on left}\\ \cancel{X}+AY\cancel{-X}=\frac{1}{Z}-X \text{; divide both sides by Y and cancel on left}\\\frac{A\cancel{Y}}{\cancel{Y}}=\frac{\frac{1}{Z}-X}{Y}\)\\A=\frac{\frac{1}{Z}-X}{Y}\) Answer h \(\frac{A}{X+Y}=ZA+3\\\frac{A}{X+Y}-A =3 \\(A)[\frac{1}{X+Y}-A]=3 \\ A= \frac{3}{[\frac{1}{X+Y}-A]}\) Answer i \(\frac{A}{X+Y}=ZA+D\\\frac{A}{X+Y}-A =D \\(A)[\frac{1}{X+Y}-A]=3 \\ A= \frac{D}{[\frac{1}{X+Y}-A]}\) Exercise \(\PageIndex{2b}\) \(P V=n R T\) Solve the equation above for: P V n T Answer a \[\begin{aligned} &P V=n R T\\ &\text { Step 1: Divide both sides by V: }\\ &P\left(\frac{V}{V}\right)=\frac{n R T}{V}\\ &\text { Note: }\left(\frac{\mathrm{V}}{\mathrm{V}}\right)=1\\ &P=\frac{n R T}{V} \end{aligned}\nonumber\] Answer b \[\begin{aligned} &P V=n R T\\ &\text { Step 1: Divide both sides by P: }\\ &V\left(\frac{P}{P}\right)=\frac{n R T}{P}\\ &\text { Note: }\left(\frac{\mathrm{P}}{\mathrm{P}}\right)=1\\ &V=\frac{n R T}{P} \end{aligned}\nonumber\] Answer c \[\begin{aligned} &P V=n R T\\ &\text { Step 1: Divide both sides by RT: }\\ &\frac{PV}{RT}=n\left(\frac{RT}{RT}\right)\\ &\text { Note: }\left(\frac{\mathrm{RT}}{\mathrm{RT}}\right)=1\\ &n=\frac{PV}{RT} \end{aligned}\nonumber\] Answer d \[\begin{aligned} &P V=n R T\\ &\text { Step 1: Divide both sides by nR: }\\ &\frac{PV}{nR}=\left(\frac{nR}{nR}\right)T\\ &\text { Note: }\left(\frac{\mathrm{nR}}{\mathrm{nR}}\right)=1\\ &T=\frac{PV}{nR} \end{aligned}\nonumber\] Exercise \(\PageIndex{2c}\) \(T_{F}=T_{C}\left(\frac{9}{5}\right)+32\) Solve the equation above for T c : Answer \(T_{F}=T_{C}\left(\frac{9}{5}\right)+32\) Step 1: Bring all things with T C to one side of the eq. and everything else to the other by subtracting 32 from sides and rearranging (note 32-32=0 ) \(T_{C}\left(\frac{9}{5}\right)=T_{F}-32\) Step 2. multiply both sides by \(\frac{5}{9}\) noting: \(\left(\frac{9}{5}\right)\left(\frac{5}{9}\right)=\left(\frac{9}{9}\right)\left(\frac{5}{5}\right)=(1)(1)=1\) \(T_{C}=\left(T_{F}-32\right)\left(\frac{5}{9}\right)\) Exercise \(\PageIndex{2d}\) \(q=mc(T_{F}-T_{i})\) Solve the equation above for T F : Answer Separate T f from all other variables by dividing both sides by mc and adding T i to both sides \[\begin{align} q&=mc(T_{f}-T_{i})\nonumber\\ \frac{q}{mc}&=\frac{mc}{mc}(T_{f}-T_{i})\nonumber\\ \frac{q}{mc}+T_{i}&=T_{f}-T_{i}+T_{i}=T_{f}\nonumber\\ T_{f}&=T_{i}+\frac{q}{mc} \nonumber\end{align} \] Exercise \(\PageIndex{2e}\) Solve the following equation for: \[ m_Cc_C (T_F-T _C) =- m_Hc_H (T_F- T_H) \nonumber\] c H c c T c T F Answer a \[\begin{aligned} \text { Divide both sides by } m_{H}\left(T_{F}-T_{H}\right)\\ \frac{m_{c} c_{c}\left(T_{F}-T_{C}\right)}{-m_{H}\left(T_{F}-T_{H}\right)}&=c_{H}\left(\frac{m_{H}\left(T_{F}-T_{H}\right)}{m_{H}\left(T_{F}-T_{H}\right)}\right)\\ c_{H}&=\frac{-m_{C} c_{C}\left(T_{F}-T_{C}\right)}{m_{H}\left(T_{F}-T_{H}\right)} \end{aligned}\] Answer b \[\begin{aligned} \text { Divide both sides by } m_{C}\left(T_{F}-T_{C}\right)\\ c_{C}\left(\frac{m_{C}\left(T_{F}-T_{C}\right)}{m_{C}\left(T_{F}-T_{C}\right)}\right)&=\frac{-m_{H} c_{H}\left(T_{F}-T_{H}\right)}{m_{C}\left(T_{F}-T_{C}\right)}\\ c_{C}&=\frac{-m_{H} c_{H}\left(T_{F}-T_{H}\right)}{m_{C}\left(T_{F}-T_{C}\right)} \end{aligned}\] Answer c Step 1: Place all terms with T C on one side of the equal sign and everything else on the other side \[\begin{aligned} m_{C} c_{C}\left(T_{F}-T_{C}\right)&=-m_{H}c_{H}\left(T_{F}-T_{H}\right)\\ m_{C} c_{C}T_{F}-m_{C} c_{C}T_{C}&=-m_{H}c_{H}(T_{F}-T_{H})\\ -m_{C} c_{C}T_{C}&=m_{C} c_{C}T_{F}-m_{H}c_{H}(T_{F}-T_{H}) \end{aligned}\nonumber\] Step 2: Solve for T C by dividing both sides by \(-m_{C} c_{c}\) \[\begin{aligned} \frac{-m_{C} c_{C}T_{C}}{-m_{C} c_{C}}&=\frac{m_{C} c_{C}T_{F}-m_{H}c_{H}(T_{F}-T_{H})}{-m_{C} c_{C}}\\ T_{C}&=T_{F}+\frac{m_{H}c_{H}(T_{F}-T_{H})}{m_{C} c_{C}} \end{aligned}\nonumber\] Answer d Step 1: Place all terms with T F on one side of the equal sign and everything else on the other side \[\begin{aligned} m_{C} c_{C}\left(T_{F}-T_{C}\right)&=-m_{H}c_{H}\left(T_{F}-T_{H}\right)\\ m_{C} c_{C}T_{F}-m_{C} c_{C}T_{C}&=-m_{H} c_{H}T_{F}-m_{H} c_{H}T_{H}\\ m_{C} c_{C}T_{F}+m_{H} c_{H}T_{F}&=m_{C} c_{C}T_{C}+m_{H} c_{H}T_{H}\\ T_{F}(m_{C} c_{C}+m_{H} c_{H})&=m_{C} c_{C}T_{C}+m_{H} c_{H}T_{H}\\ \end{aligned}\nonumber\] Step 2: Solve for T C by dividing both sides by \(m_{C} c_{C}+m_{H} c_{H}\) \[T_{F}=\frac{m_{C} c_{C}T_{C}+m_{H} c_{H}T_{H}}{(m_{C} c_{C}+m_{H} c_{H})}\nonumber\] Numbers This section was just an introduction to the 4 ways commonly used to express numbers, and each way will be gone over in turn, and that is where practice problems will exist. Exercise \(\PageIndex{3a}\) Identified the following as measured, defined or a counted numbers, and if there is uncertainty. mass = 3 kg water 3 feet = 1 yard 3 eggs 3 dozen eggs Answer a measured, there is uncertainty Answer b defined, there is no uncertainty Answer c counted, there is no uncertainty Answer d counted and defined, a dozen is defined as 12 eggs, so there are 36 eggs, and this is an exact number with no uncertainty Units of Measurement Exercise \(\PageIndex{4a}\) Give the SI Base Unit for each of the following time mass quantity temperature length Answer a second (s) Answer b kilogram (k) Answer c mole (n) Answer d kelvin (K) Answer e meter (m) Measured Numbers & Significant Digits Exercise \(\PageIndex{5a}\) Give the number of significant figures in each measured value. 5.87 0.031 52.90 0.2001 500 Answer a 3 ( see section 2.4 ) Answer b 2 (see see section 2.4) Answer c 4 ( see section 2.4 ) Answer d 4 ( see section 2.4 ) Answer e 1( see section 2.4 ), note, some texts will say it is not determined. That is, you do not know. We will use the convention that trailing zeros are not significant if there is not a decimal, but if your instructor uses a different convention, play the game and use the rules your class uses. Exercise \(\PageIndex{5b}\) Give the number of significant figures in each measured value. 0.0053 2300 32.00 34.483 3450000 Answer a 2 ( see section 2.4 ) Answer b 2 ( see section 2.4 ) Answer c 4 ( see section 2.4 ) Answer d 5 ( see section 2.4 ) Answer e 3( see section 2.4 ) Exercise \(\PageIndex{5c}\) Give the number of significant figures in each measured value. 0.00204 g 20400 g 0.0020400 kg 20103 mL 100 students 0.00001 miles 2.00x10 4 Answer a 3 sig figs Answer b 3 sig figs Answer c 5 sig figs Answer d 5 sig figs Answer e 3 sig figs Answer f 1 sig figs Answer g 3 sig figs Exercise \(\PageIndex{5d}\) Solve the following problems: \(3.03860 +3.7+36.8 \) \(95.7 +4.41+0.111\) Answer a \(\begin{align} \nonumber & 3.03860 \\ \nonumber &3.7 \\ + \;\; \nonumber 3 &6.8 \\ \hline 4 &3.5386 \end{align} \) The answer is 43.5 because 3.7 is only known to the 10ths position ( see section 2.5.3 ) Answer b \(\begin{align} \nonumber 9 & 5.7 \\ \nonumber & 4.4 \\ + \;\; \nonumber &0.111 \\ \hline 10 &0.211 \end{align} \) The answer is 100.2 because 95.7 is only known to the 10ths position ( see section 2.5.3 ) Exercise \(\PageIndex{5e}\) Solve the following problems: \( \frac{(3.03860)(3.7)}{36.8} \) \(\frac{95.7}{(4.41)(0.111)}\) Answer a 0.3055=0.30 round down because preceding digit to the truncated five is even. ( see section 2.5.3 ) Answer b 195.5016=196 round up because the preceding to the truncated five is odd ( see section 2.5.3 ) Exercise \(\PageIndex{5f}\) Solve the following problems: \( \frac{(3.03860+8.7)}{36.8} \) \(\frac{95.7}{(9.4+0.7)}\) Answer a 0.318983696=0.319 Answer b 9.475247525=9.48 Round up because the preceding digit to the truncated 5 is odd Exercise \(\PageIndex{5g}\) Consider all of the following values to be measured numbers. Review your rules on significant figures and be sure you can do these without a calculator. 12.56 + 2.4 98.3-89.4 82.0 + 34.4 312.56 X 2.4 Answer a 15.0 Review the Rules for Addition and Subtraction: The exact answer is 14.96 but 2.4 is only known to the 10ths position, so you truncate the answer there. You round up because the 6 (in the 100ths position) is greater than or equal to 5. Answer b 8.9 Review the Rules for Addition and Subtraction: Although both numbers have 3 significant figures the answer has 2 because they are only known to the 10th position. Answer c 116.4 Review the Rules for Addition and Subtraction: Although both numbers are known to 3 significant figures the answer has 4 because they are all known to the 10th position. Answer d 750 Review the Rules for Division and Multiplication: The answer will have the number of significant digits as the number with the least. Exercise \(\PageIndex{5h}\) Consider all of the following values to be measured numbers. Review your rules on significant figures and be sure you can do these without a calculator. Solve the following to the correct number of significant figures: \(\frac{198.1}{12.1+198.1}\) \(\frac{12.1}{12.1+198.1}\) \(\frac{4.12}{384}\) \(412-0.4\) Answer a 0.9424 Note the denominator has 4 not 3 sig figs \(\frac{198.1}{12.1+198.1}=\frac{198.1\text{(4 sig figs)}}{ 210.2 \text{(4 sig figs)}}=0.9424\) final answer has four sig figs Answer b 0.0576 \(\frac{12.1}{12.1+198.1}=\frac{12.1\text{(3 sig figs)}}{ 210.2 \text{(4 sig figs)}}=0.0576\) final answer has three sig figs Answer c 0.0107 Answer d 412 Scientific Notation Exercise \(\PageIndex{6a}\) Solve the following problems: \begin{equation} 3.03860 \times 10^{32}+3.7 \times 10^{30}+3.68 \times 10^{31} \end{equation} \begin{equation} 3.03860 \times 10^{-32}+3.7 \times 10^{-30}+3.68 \times 10^{-31} \end{equation} Answer a \( \begin{align}\nonumber & 3.03860 \times 10^{32}\\\nonumber &0.037 \times 10^{32}\\\nonumber+& 0.368\times 10^{32}\\ \hline & 3.4436 \times 10^{32} \end{align}\) The answer is \(3.444\times 10^{32}\) because two of the least precise value was known to the thousandths ( see section 2.6 ) Answer b \( \begin{align}\nonumber & 3.7 \times 10^{-30}\\\nonumber &0.368 \times 10^{-30}\\\nonumber+& 0.0303860\times 10^{-30}\\ \hline & 4.098386\times 10^{-30} \end{align}\) The answer is \(4.1\times 10^{-30}\) because two of the least precise value was known to the thousandths ( see section 2.6 ) Exercise \(\PageIndex{6b}\) Solve the following problems: \begin{equation} \frac{\left(9.7 \times 10^{583}\right)\left(7.339 \times 10^{98}\right)}{\left(5.432 \times 10^{-645}\right)\left(3.446 \times 10^{-4484}\right)} \end{equation} \begin{equation} \frac{\left(9.7 \times 10^{583}\right)\left(7.339 \times 10^{-98}\right)}{\left(5.432 \times 10^{-645}\right)\left(3.446 \times 10^{4484}\right)} \end{equation} Answer a \(\frac{(9.7\times10^{583})(7.339\times10^{98})}{(5.432\times10^{-645})(3.446\times10^{-4484})}\\(\frac{9.7\times7.339}{5.432\times3.446})(10^{583+98-(-645)-4484})\\3.80306\times10^{5810}\) The answer is \(3.8\times 10^{5810}\) ( see section 2.6 ) Answer b \(\frac{(9.7\times10^{583})(7.339\times10^{-98})}{(5.432\times10^{-645})(3.446\times10^{4484})}\\(\frac{9.7\times7.339}{5.432\times3.446})(10^{583-98-(-645)-4484})\\3.80306\times10^{-3354}\) The answer is \(3.8\times 10^{-3354}\) ( see section 2.6 ) Exercise \(\PageIndex{6c}\) Solve the following problems: \begin{equation} \frac{\left(9.7 \times 10^{-583}\right)\left(7.339 \times 10^{-98}\right)}{\left(5.432 \times 10^{645}\right)\left(3.446 \times 10^{4484}\right)} \end{equation} \begin{equation} \frac{\left(9.70 \times 10^{5}+6.3 \times 10^{4}\right)\left(3.33 \times 10^{5}\right)}{\left(5.00 \times 10^{45}\right)\left(3.20 \times 10^{-5}\right)} \end{equation} Answer a \(\frac{(9.7\times10^{-583})(6.3\times10^{-98})}{(5.432\times10^{645})(3.446\times10^{4484})}\\(\frac{9.7\times7.339}{5.432\times3.446})(10^{-583-98-645-4484})\\3.80306\times10^{-5810}\) The answer is \(3.8\times 10^{-5810}\) ( see section 2.6 ) Answer b \(\frac{(9.70\times10^5\;+\;6.30\times10^4)(3.33\times10^5)}{(5.00\times10^{45})(3.20\times10^{-5})}\\\frac{(9.70\times10^5\;+\;0.63\times10^5)(3.33\times10^5)}{(5.00\times10^{45})(3.20\times10^{-5})}\\\frac{(10.33\times10^5)(3.33\times10^5)}{(5.00\times10^{45})(3.20\times10^{-5})}\\(\frac{10.33\times3.33}{5.00\times3.20})(10^{5+5-45-(-5)})\\2.1499\times10^{-30}\) The answer is \(2.15\times 10^{-30}\) ( see section 2.6 ) Exercise \(\PageIndex{6d}\) Solve the following problems: \begin{equation} 6.13833 \times 10^{52}+6.9 \times 10^{50}+6.77 \times 10^{51} \end{equation} \begin{equation} \frac{\left(1.7 \times 10^{984}\right)\left(7.469 \times 10^{998}\right)}{\left(5.432 \times 10^{-645}\right)\left(3.446 \times 10^{-4484}\right)} \end{equation} Answer a \( \begin{align}\nonumber & 6.13833 \times 10^{52}\\\nonumber &0.068 \times 10^{52}\\\nonumber+& 0.677\times 10^{52}\\ \hline & 6.88333 \times 10^{52} \end{align}\) The answer is \(6.883\times 10^{52}\) because two of the added numbers had a least precise value was known to the thousandths ( see section 2.6 ) Answer b (\(\frac{1.7\times7.469}{5.432\times3.446})(10^{984+998-(-645)-(-4484)})\\0.678322693\times10^{7111}\) The answer is \(6.8\times 10^{7110}\) ( see section 2.6 ) Exercise \(\PageIndex{6e}\) Solve the following problems: \begin{equation} \frac{\left(2.27 \times 10^{577}\right)\left(7.6 \times 10^{498}\right)}{\left(5.432 \times 10^{-945}\right)\left(3.446 \times 10^{-44484}\right)} \end{equation} \begin{equation} 4.238 \times 10^{-22}+7.896 \times 10^{-20}+9.99 \times 10^{-21} \end{equation} Answer a (\(\frac{2.27\times7.6}{5.432\times3.446})(10^{577+498-(-945)-(-44484)})\\0.9216465783\times10^{46504}\) The answer is \(9.2\times 10^{46503}\) ( see section 2.6 ) Answer b \( \begin{align}\nonumber & 7.896 \times 10^{-20}\\\nonumber &0.04238 \times 10^{-20}\\\nonumber+& 0.999\times 10^{-20}\\ \hline & 8.89738\times 10^{-20} \end{align}\) The answer is \(8.897\times 10^{-20}\) because two of the least precise value was known to the thousandths ( see section 2.6 ) Exercise \(\PageIndex{6f}\) Solve the following problems: \begin{equation} 4.03807 \times 10^{42}+3.8 \times 10^{40}+6.28 \times 10^{41} \end{equation} \begin{equation} \frac{\left(1.77 \times 10^{1577}\right)\left(8.3 \times 10^{1984}\right)}{\left(5.32 \times 10^{-1945}\right)\left(3.46 \times 10^{-44}\right)} \end{equation} Answer a \( \begin{align}\nonumber & 4.03807 \times 10^{42}\\\nonumber &0.038 \times 10^{42}\\\nonumber+& 0.628\times 10^{42}\\ \hline & 4.7047 \times 10^{42} \end{align}\) The answer is \(4.705\times 10^{42}\) ( see section 2.6 ) Answer b (\(\frac{1.77\times8.3}{5.32\times3.46})(10^{1577+1984-(-1945)-(-44)})\\0.7981116085\times10^{5550}\) The answer is \(8.0\times 10^{5549}\) ( see section 2.6 ) SI Prefixes Exercise \(\PageIndex{7a}\) Give the name of the prefix and the quantity indicated by the following symbols that are used with SI base units. c d G k Answer a centi-, × 10 −2 Answer b deci-, × 10 −1 Answer c Giga-, × 10 9 Answer d kilo-, × 10 3 Exercise \(\PageIndex{7b}\) Give the name of the prefix and the quantity indicated by the following symbols that are used with SI base units. m n p T Answer a milli-, × 10 −3 Answer b nano-, × 10 −9 Answer c pico-, × 10 −12 Answer d tera-, × 10 12 Unit Conversions Exercise \(\PageIndex{8a}\) How many dm are in an object which is 2.450 feet long? 12in = 1 ft Answer \(2.450 f t\left(\frac{12 i n}{f t}\right)\left(\frac{2.54 c m}{i n}\right)\left(\frac{10^{1} d m}{10^{2} c m}\right)=7.4676 d m=7.468 d m\) Exercise \(\PageIndex{8b}\) How many gallons are in a cuboid can that is 2.05 ft wide, 12.4 inches long and 1.30 yards deep? 4 qt = 1 gal, 1.057qt=1L, 12in = 1 ft, 3 ft = 1 yd Answer \(2.05 f t(12.4 i n)(1.30 y d)\left(\frac{3 f t}{y d}\right)\left(\frac{12 i n}{f t}\right)^{2}\left(\frac{2.54 c m}{i n}\right)^{3}\left(\frac{1 m L}{1 c m^{3}}\right)\left(\frac{1 L}{1000 m L}\right)\left(\frac{1.057 q t}{1 L}\right)\left(\frac{g a l}{4 q t}\right)=61.8 g a l\) Exercise \(\PageIndex{8c}\) How many square inches are in a rectangle which is 3.24ft by 2.67 yd? Answer \(3.24 f(2.67 y d)\left(\frac{3 f t}{y d}\right)\left(\frac{12 i n}{f t}\right)^{2}=3737.1456 i n^{2}=3740 i n^{2}\) Exercise \(\PageIndex{8d}\) How many cubic inches are in 1.00 mL? Answer \(1.00 m l\left(\frac{c m^{3}}{1 m l}\right)\left(\frac{i n}{2.54 c m}\right)^{3}=0.0610 i n^{3}\) Exercise \(\PageIndex{8e}\) How many cubic feet are in 1.00 TL? Answer \(1.00 T l\left(\frac{10^{3} m L}{10^{-12} T L}\right)\left(\frac{1 c m^{3}}{1 m L}\right)\left(\frac{i n}{2.54 c m}\right)^{3}\left(\frac{f t}{12 i n}\right)^{3}=3.53 \times 10^{10} f^{3}\) Exercise \(\PageIndex{8f}\) How many kL are in a cube which is 3.24x10 21 mm on each side? Answer \(\left(3.24 \times 10^{21} \mathrm{mm}\right)^{3}\left(\frac{10^{2} \mathrm{cm}}{10^{3} \mathrm{mm}}\right)^{3}\left(\frac{\mathrm{mL}}{1 \mathrm{cm}^{3}}\right)\left(\frac{10^{-3} \mathrm{kL}}{10^{3} \mathrm{mL}}\right)=3.40 \times 10^{55} \mathrm{kL}\) Exercise \(\PageIndex{8g}\) How many square inches are in a rectangle which is 1.75x10 11 mm by 7.34x10 - 13 km Answer \(1.75 \times 10^{11} \mathrm{mm}\left(7.34 \times 10^{-13} \mathrm{km}\right)\left(\frac{\mathrm{cm}}{10 \mathrm{mm}}\right)\left(\frac{10^{2} \mathrm{cm}}{10^{-3} \mathrm{km}}\right)\left(\frac{\mathrm{in}}{2.54 \mathrm{cm}}\right)^{2}=199 \mathrm{in}^{2}\) Exercise \(\PageIndex{8h}\) How many mL are in an cuboid that is 2.00x10 21 mm by 3.00x10 2 yard by 5.00x10 18 ft? Answer \(2.00 x 10^{21} m m\left(3.00 \times 10^{2} y d\right)\left(5.00 x 10^{18} f\right)\left(\frac{3 f t}{y d}\right)\left(\frac{12 i n}{f t}\right)^{2}\left(\frac{1 c m}{10 m m}\right)\left(\frac{2.54 c m}{1 i n}\right)^{2}\left(\frac{m L}{1 c m^{3}}\right)=8.36 x 10^{44} m L\) Exercise \(\PageIndex{8i}\) How many liters is the volume of 5.873 kg of Mercury? Use 13.6 g/mL as the density of Mercury Answer \(5.873kg\left(\frac{1000 g}{1 kg}\right)\left(\frac{1 mL}{13.6g}\right)\left(\frac{1 L}{1000mL}\right)=0.431L\) Exercise \(\PageIndex{8j}\) How many gallons is the volume of 14.0 kg of Gallium? Use 5.9 g/mL as the density of Gallium Answer \(14.0kg\left(\frac{1000 g}{1 kg}\right)\left(\frac{1 mL}{5.9g}\right)\left(\frac{1 L}{1000mL}\right)\left ( \frac{1.057qt}{1 L} \right )\left ( \frac{1gal}{4qt} \right )=0.62703gal=0.63gal\) Exercise \(\PageIndex{8k}\) How many pounds would 3.789 gallons of water weight if at a given temperature the water has a density of 0.96g/mL? Answer \(\left ( 3.789gal \right )\left ( \frac{4qt}{1gal} \right )\left ( \frac{1L}{1.057qt} \right )\left ( \frac{1000mL}{1L} \right )\left ( \frac{0.96g}{mL} \right )\left ( \frac{1lb}{453.6g} \right )= 5.392lb= 5.4lb\) Exercise \(\PageIndex{8l}\) How many pounds would 135 liters of water weight if at a given temperature the water has a density of 0.99g/mL? Answer \(\left ( 135L \right )\left ( \frac{1000mL}{1L} \right )\left ( \frac{0.99g}{mL} \right )\left ( \frac{1lb}{453.6g} \right )= 294.64lb= 295lb\) Exercise \(\PageIndex{8m}\) You have a rectangular metal surface that is 3.81X10 23 in long by 4.22x10 - 2 yards wide that you wish to make a platinum catalyst with. To do this you need to coat the surface with platinum and wish to use the minimum amount of platinum. Using the process of chemical vapor deposition you will make a layer that is the thickness of a single layer of platinum atoms, which have a depth of 175 pm. The current price is $908/oz, 28.3495g=1 ounce and the density of platinum is 24.15 g/ml. What would be the cost of the platinum to make this surface? Answer \[3.81x10^{23}\left ( 0.0422yd \right )\left ( 175pm \right ) \left ( \frac{36in}{yd} \right ) \left ( \frac{2.54cm}{in} \right )^2 \left ( \frac{10^2cm}{10^{12}pm} \right ) \left ( \frac{1ml}{cm^3} \right ) \left ( \frac{24.15g}{ml} \right ) \left ( \frac{1 oz}{28.3495g} \right ) \left ( \frac{\$908}{oz} \right ) \\ =\$5.06806x10^{19}=\$5.07x10^{19} \nonumber\] Exercise \(\PageIndex{8n}\) How many square yards are in a rectangle which is 2.00x10 21 cm by 3.00x10 2 nm?? Answer \((2.00x10^{21}cm)(3.00x10^2nm)\left(\frac{10^2cm}{10^9nm}\right)\left(\frac{in}{2.54cm}\right)^{2}\left ( \frac{1ft}{12in} \right )^2\left ( \frac{1yd}{3ft} \right )^2=7.1759x10^{12}yd^{2}=7.18x10^{12}yd^{2}\) Fractions and Percent Exercise \(\PageIndex{9a}\) What mass of Water do you need to add to 20.6g of salt to make a solution that is 25.0% Salt? Hint: Solve this in terms of fractions, where fraction of salt = \(\frac{\%salt}{100}\) Answer f s =fraction salt, m s =mass salt, m w =mass water, if percent salt = 25.0%, the f s = 0.250 \(f_{s}=\frac{m_{s}}{m_{s}+m_{w}} \\ \; \\ \text{solve for }m_w \\ \; \\ f_{s}\left(m_{s}+m_{w}\right)=m_{s} \\ \; \\ f_{s} m_{s}+f_{s} m_{w}=m_{s} \\ \; \\ f_{s} m_{w}=m_{s}-f_{s} m_{s}=m_{s}\left(1-f_{s}\right) \\ \; \\ m_{w}=\frac{\left(1-f_{s}\right)}{f_{s}} m_{s}=\frac{(1-.250)}{.250} 20.6 g=\frac{.750}{.250} 20.6 g=61.8 g \) Exercise \(\PageIndex{9b}\) What mass of Water do you need to add to 47.5g of salt to make a solution that is 5.0% Salt? Hint: Solve this in terms of fractions, where fraction of salt = \(\frac{\%salt}{100}\) Answer f s =fraction salt, m s =mass salt, m w =mass water, if percent salt = 5.0%, the f s = 0.050 \(f_{s}=\frac{m_{s}}{m_{s}+m_{w}} \\ \; \\ \text{solve for }m_w \\ \; \\ f_{s}\left(m_{s}+m_{w}\right)=m_{s} \\ \; \\ f_{s} m_{s}+f_{s} m_{w}=m_{s} \\ \; \\ f_{s} m_{w}=m_{s}-f_{s} m_{s}=m_{s}\left(1-f_{s}\right) \\ \; \\ m_{w}=\frac{\left(1-f_{s}\right)}{f_{s}} m_{s}=\frac{(1-.050)}{.050} 47.5 g=\frac{.950}{.050} 47.5 g=902.5 g = 902 g \) Exercise \(\PageIndex{9c}\) What mass of Water do you need to add to 0.840g of salt to make a solution that is 32.0% Salt? Hint: Solve this in terms of fractions, where fraction of salt = \(\frac{\%salt}{100}\) Answer f s =fraction salt, m s =mass salt, m w =mass water, if percent salt = 32.0%, the f s = 0.320 \(f_{s}=\frac{m_{s}}{m_{s}+m_{w}} \\ \; \\ \text{solve for }m_w \\ \; \\ f_{s}\left(m_{s}+m_{w}\right)=m_{s} \\ \; \\ f_{s} m_{s}+f_{s} m_{w}=m_{s} \\ \; \\ f_{s} m_{w}=m_{s}-f_{s} m_{s}=m_{s}\left(1-f_{s}\right) \\ \; \\ m_{w}=\frac{\left(1-f_{s}\right)}{f_{s}} m_{s}=\frac{(1-.320)}{.320} 0.840 g=\frac{.680}{.320} 0.840 g=1.785 g = 1.79 g \) Exercise \(\PageIndex{9d}\) Consider Mixing 55.4 g of table salt (NaCl) with 102 g of water What is the percent salt? What is the percent water? Answer a \( \% \; salt = \frac{m_{salt}}{m_{salt}+m_{water}}(100) = \frac{55.4g}{55.4g+102g}(100) = \frac{55.4g}{157.4g}(100)=35.196 \%=35.2\% \) Answer b \( \% \; water = \frac{m_{water}}{m_{salt}+m_{water}}(100) = \frac{102g}{55.4g+102g}(100) = \frac{102g}{157.4g}(100)=64.803 \% =64.8 \% \) Exercise \(\PageIndex{9e}\) Consider Mixing 15.2 g of table salt (NaCl) with 87 g of water What is the percent salt? What is the percent water? Answer a \( \% \; salt = \frac{m_{salt}}{m_{salt}+m_{water}}(100) = \frac{15.2g}{15.2g+87g}(100) = \frac{15.2g}{102.2g}(100)=14.872 \%=14.9\% \) Answer b \( \% \; water = \frac{m_{water}}{m_{salt}+m_{water}}(100) = \frac{87g}{15.2g+87g}(100) = \frac{87g}{102.2g}(100)=85.127 \% = 85 \% \) Exercise \(\PageIndex{9f}\) Consider Mixing 4.7 g of table salt (NaCl) with 25.0 g of water What is the percent salt? What is the percent water? Answer a \( \% \; salt = \frac{m_{salt}}{m_{salt}+m_{water}}(100) = \frac{4.7g}{4.7g+25.0g}(100) = \frac{4.7g}{29.7g}(100)=15.824 \%=16\% \) Answer b \( \% \; water = \frac{m_{water}}{m_{salt}+m_{water}}(100) = \frac{25.0g}{4.7g+25.0g}(100) = \frac{25.0g}{29.7g}(100)=84.175 \% = 84.2 \% \) Exercise \(\PageIndex{9g}\) Consider Mixing 55.4 g of table salt (NaCl) with 102 g of water What is the fraction salt? What is the fraction water? Answer a \( \text{fraction salt = } \frac{m_{salt}}{m_{salt}+m_{water}} = \frac{55.4g}{55.4g+102g} = \frac{55.4g}{157.4g}=0.3519695=0.352 \nonumber \) Answer b \( \text{fraction water = } \frac{m_{water}}{m_{salt}+m_{water}} = \frac{102g}{55.4g+102g} = \frac{102g}{157.4g}=0.6480305 = 0.648 \nonumber \) Exercise \(\PageIndex{9h}\) Consider Mixing 15.2 g of table salt (NaCl) with 87 g of water What is the fraction salt? What is the fraction water? Answer a \( \text{fraction salt = } \frac{m_{salt}}{m_{salt}+m_{water}} = \frac{15.2g}{15.2g+87g} = \frac{15.2g}{102.2g}=0.14872798=0.149 \nonumber \) Answer b \( \text{fraction water = } \frac{m_{water}}{m_{salt}+m_{water}} = \frac{87g}{15.2g+87g} = \frac{87g}{102.2g}=0.85127202 = 0.85 \nonumber \) Exercise \(\PageIndex{9i}\) Consider Mixing 4.7 g of table salt (NaCl) with 25.0 g of water What is the fraction salt? What is the fraction water? Answer a \( \text{fraction salt = } \frac{m_{salt}}{m_{salt}+m_{water}} = \frac{4.7g}{4.7g+25.0g} = \frac{4.7g}{29.7g}=0.15824916=0.16 \nonumber \) Answer b \( \text{fraction water = } \frac{m_{water}}{m_{salt}+m_{water}} = \frac{25.0g}{4.7g+25.0g} = \frac{25.0g}{29.7g}=0.84175084 = 0.842 \nonumber \) Graphing and Temperature Conversion Exercise \(\PageIndex{10a}\) Convert the following: 37.0 ºC to _____ K 331 K to _____ ºC Answer a 310.2 K \[(37.0+273.15)=310.2K\] (see section 1B.1.5 ) Answer b 57.9 ºC \begin{equation} (331-273.15)=57.9^{\circ} \mathrm{C} \end{equation} (see section 1B.1.5 ) Exercise \(\PageIndex{10b}\) Convert the following: 57.8 ºC to _____ ºF -129 ºF to _____ ºC Answer a 136 ºF \begin{equation} [(57.8+40) 1.8]-40=136^{\circ} \mathrm{F} \end{equation} (see section 1B.1.5 ) Answer b -89.4 ºC \begin{equation} \left(\frac{(-129+40)}{1.8}\right)-40=-89.4^{\circ} \mathrm{C} \end{equation} (see section 1B.1.5 ) Exercise \(\PageIndex{10c}\) Convert the boiling temperature of gold, 2966 °C, into degrees Fahrenheit and Kelvin. Answer \(\left [\left (2966^{\circ}C+40 \right ) 1.8 \right ]-40=5371^{\circ}F\) \(2966 ^{\circ} C +273.15 = 3239K\) (see section 1B.1.5 ) Exercise \(\PageIndex{10d}\) Convert the temperature of scalding water, 54 °C, into degrees Fahrenheit and Kelvin. Answer \(\left [\left (54^{\circ}C+40 \right ) 1.8 \right ]-40=130^{\circ}F\) \(54 ^{\circ} C +273.15 = 330\) 130 °F, 330 K (see section 1B.1.5 ) Exercise \(\PageIndex{10e}\) Convert the temperature of the coldest area in a freezer, −10 °F, to degrees Celsius and Kelvin. Answer \( [(\frac{10 ^\circ F\;+\;40)}{1.6}]-40\;=\;-23 ^{\circ} C \) \( [(\frac{10 ^\circ F\;+\;40)}{1.6}]-40\;+\;273.15\;=\;250\;K\) −23 °C, 250 K (see section 1B.1.5 )