Abstract In the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone, we found that, besides the normal Baylis-Hillman reaction product 1, the diadduct 2 can also be formed at the same time and the yield of 2 can reach 55% by increasing the amount of methyl vinyl ketone; but for acrylonitrile and methyl acylate, only the normal Baylis-Hillman adduct was obtained; the substitutent's effects were also examined and a plausible reaction mechanis was proposed for the formation of 2.
GB/T 7714 Shi M,Li CQ,Jiang JK,et al. New discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone[J]. Chem. Commun.,2001(9):833-834.
APA Shi M,Li CQ,Jiang JK,&施敏.(2001).New discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.Chem. Commun.(9),833-834.
MLA Shi M,et al."New discovery in the traditional Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone".Chem. Commun. .9(2001):833-834.