You would lose the bet. In fact, you weren't even close.

"Published reviews of the scientific literature by Mörner and Etiope (2002) and Kerrick (2001) report a minimum-maximum range of emission of 65 to 319 million tonnes of CO2 per year. Counter claims that volcanoes, especially submarine volcanoes, produce vastly greater amounts of CO2 than these estimates are not supported by any papers published by the scientists who study the subject.  

The burning of fossil fuels and changes in land use results in the emission into the atmosphere of approximately 30 billion tonnes of carbon dioxide per year worldwide, according to the EIA. The fossil fuels emissions numbers are about 100 times bigger than even the maximum estimated volcanic CO2 fluxes."
 https://www.skepticalscience.com/volcanoes-and-global-warming.htm