Autopsy of an old reverse osmosis membrane from Mauritania: case study of Teichitt
Currently used reverse osmosis (RO) membranes from desalination units are burned at the end of their life as membranes for seawater desalination. In the future, a possible alternative would be to reuse the old RO membranes as nanofiltration (NF), ultrafiltration (UF) or microfiltration (MF) membranes, i.e. for wastewater treatments, but before reuse, the level of RO membrane degradation must be evaluated by autopsy studies. Our goal in the present study was to demonstrate for the first time that a used RO membrane could be used for nanofiltration. The used RO membrane was purchased from a desalination bench scale unit based in the town of Teichitt (in north-west Nouakchott, Mauritania). Membrane autopsy studies showed an increase in its hydraulic permeability (25%) and a concurrent decrease in its salt rejection behaviour (10% to 30%). We also studied the modification of mass transfer before and after ageing, and demonstrated the onset of a convective component in the mass transfer of salts and an increase in membrane hydraulic permeability. Furthermore, the determination of the isoelectric point (IEP) of the membrane, using streaming potential measurements across the membranes, showed no change in IEP, with a value of 2.5 ± 0.2 . A preliminary study, based on a statistical evaluation of membrane degradation from hydraulic permeability and salt rejection experiments, showed heterogeneous wear of the membrane (most important in the centre). Finally, we observed for the first time that after two years of use for desalination, a used RO membrane had acquired a microporosity that corresponded to the properties of a new NF membrane.