Can Pain read minds with his Rinnegan? Can Akatsuki's leader Pain (Nagato) read minds with the ocular powers of his Rinnegan?
Source:
NARUTO WIKIA

The Rinnegan user is bestowed with the Six Paths power. And weirdly, there are seven paths:


  1. Deva Path: 
  Allows one to manipulate attractive and repulsive forces.
  
  2. Asura Path:
  Grants the user mechanized limbs, weaponry and armor.
  
  3. Human Path:
  Gives the ability to remove a soul and so, read a person's mind.
  
  4. Animal Path:
  Lets the user summon a wide variety of creatures.
  
  5. Preta Path:
  Which can absorb all forms of chakra, including most ninjutsu.
  
  6. Naraka Path:
  Through which one can summon and control the King Of Hell.
  
  7. Outer Path:
  Through which one rules over both life and death.


As Nagato was crippled, he used the Outer Path to manipulate the six corpses (the Pain who fought Naruto &amp; Jiraiya), and channeled other Paths through the Chakra Rods.

And so, by using the Human Path, Pain can read other people's minds.