Caffeine boiling and melting points According to both caffeine's PubChem page and ChemSpider page its boiling point lies at $\pu{173 °C}$ and its melting point at $\pu{\sim 235 °C}.$ How can it melt at that temperature if it already sublimated at $\pu{173 °C}?$ Or is that the temperature of the triple point? If so, how come none of those pages gives any pressure specifications for that temperature?
I heated up some anhydrous caffeine at home, and at my home atmospheric pressure it appears to melt (not sublimate) and starts creating vapors immediately after (but not before) melting. This is based just on what I can see with the naked eye.
Anhydrous caffeine occurs in two different polymorphic crystal forms, with a transition between the two forms occurring at $\pu{136 °C}.$ The high temperature form has a melting point of $\pu{236 °C}.$
The vapor pressure of the high temperature solid form is described by the equation:
$$\log P[\pu{Pa}] = -\frac{5477}{T[\pu{K}]} + 14.395,\tag{1}$$
and for the liquid
$$\log P[\pu{Pa}] = -\frac{3918}{T[\pu{K}]} + 11.14.\tag{2}$$
So, $\pu{173 °C}$ is incorrect; the boiling point is more like $\pu{365 °C}.$
References

Griesser, U. J.; Szelagiewicz, M.; Hofmeier, U. Ch.; Pitt, C.; Cianferani, S. Vapor Pressure and Heat of Sublimation of Crystal Polymorphs. Journal of Thermal Analysis and Calorimetry 1999, 57 (1), 45–60. DOI: 10.1023/A:1010188923713.
Bothe, H.; Cammenga, H. K. Phase Transitions and Thermodynamic Properties of Anhydrous Caffeine. Journal of Thermal Analysis 1979, 16 (2), 267–275. DOI: 10.1007/BF01910688.