Does vinegar react with tap water? In an effort to prevent mold in my humidifier, I added a little white vinegar to the tap water in the tank. This creates a white bloom that floats in the water. It is odourless and, despite its appearance, is not slimy. It feels more like paper pulp. After a while it adheres to the sides of the tank as a transparent sort of gel. Is this a known phenomenon? What is the white stuff?
Acidic acid (vinegar) does not react with water, and it is not soluble in water. The gel and white bloom may come from a reaction the acidic acid with minerals such as calcium that may be present in the dehumidifier. the gel could also come from the breakdown of the chitin cell wall of the fungi. If the white bloom appeared within a minute or two of the addition of acidic acid it was most likely a reaction with minerals or other compounds.