Raoult's Law and Mole Fraction Raoult's Law states that the partial vapor pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component multiplied by its mole fraction in the mixture.

As we know that the liquid and vapour in a container are at dynamic equilibrium,

So the mole fraction which is mentioned in Raoult's Law is measured at equilibrium or initially?
Raoults Law says that, for an ideal liquid mixture, the partial pressure of each component in the gas phase is equal to the vapor pressure of the pure component (at the temperature of the system) times the  mole fraction of that component in the liquid phase.  If the system is at equilibrium, the mole fraction to use in the equation is the current mole fraction.