Singapore scientists develop ethylene using solar energy
Scientists at the National University of Singapore's Department of Chemistry have developed a low-cost, energy-efficient way to produce ethylene from carbon dioxide and water. In an article published in ACS Sustainable Chemistry & Engineering, the team simulated photosynthesis using benign chemical reagents at room temperature and pressure, achieving an unprecedented 1.5% solar-to-ethylene energy efficiency. The team said its work would further the development of "a scalable artificial photosynthesis system to produce clean fuels sustainably".
An artificial photosynthesis device developed by a team of of scientists from the National University of Singapore (NUS) could provide a greener alternative to current ethylene production, employing a completely renewable energy source, while simultaneously converting CO2 with the help of copper catalysts.

According to the findings published in ACS Sustainable Chemistry & Engineering, NUS achieved an unprecedented 1.5% solar-to-ethylene energy efficiency (the total solar-to-carbon-fuels energy efficiency is 2.9%).

Current industrial production of ethylene employs steam cracking of saturated hydrocarbons at 750°C to 950°C, which translates to an enormous consumption of energy, emitting about two tons of carbon dioxide for every ton of ethylene produced.The process, developed by the NUS team, takes place at room temperature and pressure, with only the use of benign chemical reagents.

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The researchers have also added a battery to store excess solar energy, thus ensuring stable and continuous production of ethylene, and are now developing suitable catalysts that can be used in similar systems to produce liquid fuels such as ethanol from CO2 and H2O.

“We believe that our work, which is a product of efforts for the last two years, will play a crucial role to address key challenges in the realization of a scalable artificial photosynthesis system to produce clean fuels sustainably,” said assistant Professor Jason Yeo Boon Siang.