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Wednesday, April 20, 2016

NRL Reveals Novel Uniform Coating Process of p-ALD

Scientists at the U.S. Naval Research Laboratory (NRL) have devised a
clever combination of materials - when used during the thin-film growth process
- to reveal that particle atomic layer deposition, or p-ALD, deposits a uniform
nanometer-thick shell on core particles regardless of core size, a discovery
having significant impacts for many applications since most large scale powder
production techniques form powder batches that are made up of a range of
particles sizes.

Artistic
depiction of prior understanding of p-ALD (left) and new understanding
of p-ALD (right) gained by NRL’s work, as well as implications for
proactive applications using particle atomic layer deposition, which as
UV, are captured in solar cells and abrasion resistance paints. (U.S. Naval Research Laboratory)
- See more at:
http://www.nrl.navy.mil/media/news-releases/2016/NRL-Reveals-Novel-Uniform-Coating-Process-of-pALD#sthash.RLSdtwyU.dpuf

Artistic depiction of prior understanding of p-ALD (left) and new
understanding of p-ALD (right) gained by NRL’s work, as well as implications
for proactive applications using particle atomic layer deposition, which as UV,
are captured in solar cells and abrasion resistance paints. (U.S. Naval
Research Laboratory)

- See more at: http://www.nrl.navy.mil/media/news-releases/2016/NRL-Reveals-Novel-Uniform-Coating-Process-of-pALD#sthash.RLSdtwyU.dpuf

The original journal publication in JVSTA is given below as an abstract.

Growth per cycle of alumina atomic layer deposition on nano- and micro-powders

Core–shell powders consisting of a tungsten particle core and thin alumina shell have been synthesized using atomic layer deposition in a rotary reactor. Standard atomic layer deposition of trimethylaluminum/water at 150 °C utilizing a microdosing technique was performed on four different batches of powder with different average particle sizes. The particle size of the powders studied ranges from ∼25 to 1500 nm. The high mass-thickness contrast between alumina and tungsten in transmission electron microscopy
images demonstrates that the particle core/shell interface is abrupt.
This allows for the uncomplicated measurement of alumina thickness and
therefore the accurate determination of growth per cycle. In agreement with prior works, the highest growth per cycle of ∼2 Å/cycle occurred on the batch of powder with the smallest average particle size and the growth per cycle decreased with increasing average particle size of a powder batch. However, the growth
per cycle of the alumina film on an individual particle in a batch is
shown to be independent of the size of an individual particle, and
therefore, a powder batch which
consists of particles size spanning orders of magnitude has constant
shell thickness on all particles. This uniformity of thickness on
different particle sizes in a particular batch is determined to be due
to the difficulty of removing residual water molecules from the powder during the purging cycle of the atomic layer deposition(ALD) process. Therefore, rotary ALD on a single batch of powder
with wide particle size distribution provides the same shell thickness
regardless of individual particle size, which may have positive
implications for particle ALD
applications where the shell thickness determines critical parameters,
such as particle passivation and manipulation of optical properties.