Selective Deoxygenation of Sludge Palm Oil into Diesel Range Fuel over Mn-Mo Supported on Activated Carbon Catalyst

: Originating from deoxygenation (DO) technology, green diesel was innovated in order to act as a substitute for biodiesel, which contains unstable fatty acid alkyl ester owing to the existence of oxygenated species. Green diesel was manufactured following a process of catalytic DO of sludge palm oil (SPO). An engineered Mn (0.5%) -Mo (0.5%) /AC catalyst was employed in a hydrogen-free atmosphere. The inﬂuence of Manganese (Mn) species (0.1–1 wt.%) on DO reactivity and the dissemi-nation of the product were examined. The Mn (0.5%) -Mo (0.5%) /AC formulation gave rise to a superior harvest of approximately 89% liquid hydrocarbons; a higher proportion of diesel fraction selectivity n -(C 15 +C 17 ) was obtained in the region of 93%. Where acid and basic active sites were present on the Mn (0.5%) -Mo (0.5%) /AC catalyst, decarboxylation and decarbonylation reaction mechanisms of SPO to DO were enhanced. Evidence of the high degree of stability of the Mn (0.5%) -Mo (0.5%) /AC catalyst during ﬁve continuous runs was presented, which, in mild reaction conditions, gave rise to a consistent hydrocarbon harvest of >72% and >94% selectivity for n -(C 15 +C 17 ).


Introduction
Owing to current consternation regarding environmental and sustainability issues, renewable fuels have gained considerable attention. There is a significant requirement for fuel in the transportation domain; however, the manufacture of biofuel necessitates numerous feed sources. At present, large quantities of comestible feeds are utilised in order to diminish greenhouse gas emissions relative to those produced by liquid fossil fuels [1,2]. Nevertheless, such feeds are also a requisite to fulfil the nutritional needs of an expanding populace; when such food crops are diverted to fuel synthesis, their costs increase [3,4].

Deoxygenation Reaction Parameters Optimization
The appearances of the solid catalysts were additionally appraised in order to explore their configuration, pattern and surface particle contours. FESEM images for the made-up specimens were evaluated and demonstrated a homogeneous allocation of metal on the support (Figure 1a-c). The dimensions and form of the particles were notably altered following active metal doping. It can be seen that the preparation context has a marked impact on the carbon s appearance. The dimensions of the particles were diminished from 27 nm to 312 nm on the heated impregnated bimetallic catalysts by elevating the Mn and Mo doping proportion from 0.1 to 1 wt.%. In contrast, raising Mn to >0.5 wt.% was associated with particle enlargement from 92 nm to 312 nm owing to aggregation effects. These data were validated utilising BET and XRD, which demonstrated a reduction in surface area and volume of the pores, together with an augmentation in crystal dimensions. Catalysts which exhibit superior activity generally have a reasonable surface area and particle size; the latter, configuration and porous nature, have a significant impact on the reaction. Thus, the minute particle size of organised porous support would enhance surface area and generate a greater active catalytic surface, properties that would be advantageous for reaction performance [22,23]. The surface area was increased by increasing the element loading from 0.1 to 1 %, which is due to the metal sate acting as an activation agent to the activated carbon. On the other hand, the pore volume and size were reduced by increasing the doping percentage due to the fact that the active element will block the pores. Catalysis science has demonstrated the importance of the active site to the catalyst s activity [24].
The X-ray diffraction (XRD) pattern of AC-Sr evidenced no crystalline Sr 2 O phases (2a), suggesting that Strontium is either highly dispersed on the AC external surface or doped into the pore ( The contrast of the TPD-NH 3 data sets for the Mn/AC and Mn-Mo/AC catalyst specimens implied that the Mn support predominantly generated robust acid loci within Mn-Mo/AC ( Figure 3). The AC support on the Mn-Mo specimen evidenced an asymmetric data set of low acidity below a temperature of 550 • C, which was in keeping with the characteristics of the earlier-generated AC supported catalysts utilised for alternative purposes [25]. In general, the TPD-NH 3 parameters of the catalyst specimens suggested that there was a robust engagement between the AC support and the two metals. The most significant variations observed between the Mn/AC and Mn-Mo/AC specimens were associated with alterations in the acidity scale. This predominantly arose from the presence of Mo in Mn/AC. It can be gauged that in the process of loading with Mo, each acid has 6H + medium loci that are swapped with a single Mo +6 ion to maintain charge equilibrium, i.e., 6H + /Mn +6 = 1 [26]. This will give rise to the generation of a de novo NH 3 desorption zenith, i.e., the robust acid loci on the Mn-Mo/AC catalyst. Furthermore, the minimal alterations seen in the temperature sites and the strengths of the medium and concentrated acid loci in the spectra after Mn loading at 0.5 wt.% implied that the quantity and strength of the acid loci were conserved and thus maintained the integrity of the catalyst s performance for the typical DO reaction of SPO. Mn-doping enhanced the acid loci density, suggesting that Mo has higher acidity than Mn/AC.  The X-ray diffraction (XRD) pattern of AC-Sr evidenced no crystalline Sr2O phases (2a), suggesting that Strontium is either highly dispersed on the AC external surface or doped into the pore ( Figure 2   To determine the electronic states of Mo and Mn, X-ray photoelectron spectroscopy (XPS) measurements were carried out on the obtained metal states (Figure 4). The highresolution spectrum cantered on Mo +4 3d 5/2 and Mo +6 3d 5/2 /3d 3/2 can be deconvoluted into three contributions positioned at 228.9 eV, 232.1eV and 235.3 eV corresponding to Mo +4 3d 5/2 and Mo +6 3d 5/2 /3d 3/2, respectively( Figure 4A). The high-resolution spectrum cantered on Mn can be deconvoluted into two contributions positions at 653.70 eV and 642.05 eV ( Figure 4B). The Mn 2p spectra were placed at the same minimum background level and normalised to the maximum intensity of the higher peak in order to make the comparison easier. The Mn 2p spectra of the Mn (0.5%) -Mo (0.1%) /AC catalyst were practically identical, with the Mn 2p 1/2 peak maximum located in the 642.2-642.25 eV region and the Mn 2p3/2 peak maximum located in the 653.70−654.5 eV range. This synergic effect between Mn and Mo will lead to the enhancement of the catalyst's acidic properties, which will enhance the catalytic deoxygenation activity [27,28]. The contrast of the TPD-NH3 data sets for the Mn/AC and Mn-Mo/AC catalyst specimens implied that the Mn support predominantly generated robust acid loci within Mn-Mo/AC ( Figure 3). The AC support on the Mn-Mo specimen evidenced an asymmetric data set of low acidity below a temperature of 550 °C, which was in keeping with the characteristics of the earlier-generated AC supported catalysts utilised for alternative purposes [25]. In general, the TPD-NH3 parameters of the catalyst specimens suggested that there was a robust engagement between the AC support and the two metals. The most significant variations observed between the Mn/AC and Mn-Mo/AC specimens were associated with alterations in the acidity scale. This predominantly arose from the presence of Mo in Mn/AC. It can be gauged that in the process of loading with Mo, each acid has 6H + medium loci that are swapped with a single Mo +6 ion to maintain charge equilibrium, i.e., 6H + /Mn +6 = 1 [26]. This will give rise to the generation of a de novo NH3 desorption zenith, i.e., the robust acid loci on the Mn-Mo/AC catalyst. Furthermore, the minimal alterations seen in the temperature sites and the strengths of the medium and concentrated acid loci in the spectra after Mn loading at 0.5 wt.% implied that the quantity and strength of the acid loci were conserved and thus maintained the integrity of the catalyst′s performance for the typical DO reaction of SPO. Mn-doping enhanced the acid loci density, suggesting that Mo has higher acidity than Mn/AC.   To determine the electronic states of Mo and Mn, X-ray photoelectron spectroscopy (XPS) measurements were carried out on the obtained metal states ( Figure 4). The highresolution spectrum cantered on Mo +4 3d5/2 and Mo +6 3d5/2/3d3/2 can be deconvoluted into three contributions positioned at 228.9 eV, 232.1eV and 235.3 eV corresponding to Mo +4 3d5/2 and Mo +6 3d5/2/3d3/2, respectively( Figure 4A). The high-resolution spectrum cantered on Mn can be deconvoluted into two contributions positions at 653.70 eV and 642.05 eV ( Figure 4B). The Mn 2p spectra were placed at the same minimum background level and normalised to the maximum intensity of the higher peak in order to make the comparison easier. The Mn 2p spectra of the Mn(0.5%)-Mo(0.1%)/AC catalyst were practically identical, with the Mn 2p1/2 peak maximum located in the 642.2-642.25 eV region and the Mn 2p3/2 peak maximum located in the 653.70−654.5 eV range. This synergic effect between  Figure 4B). The Mn 2p spectra were placed at the same minimum background level and normalised to the maximum intensity of the higher peak in order to make the comparison easier. The Mn 2p spectra of the Mn(0.5%)-Mo(0.1%)/AC catalyst were practically identical, with the Mn 2p1/2 peak maximum located in the 642.2-642.25 eV region and the Mn 2p3/2 peak maximum located in the 653.70−654.5 eV range. This synergic effect between Mn and Mo will lead to the enhancement of the catalyst's acidic properties, which will enhance the catalytic deoxygenation activity [27,28].

Catalytic Deoxygenation Reaction of SPO
When SPO underwent the DO reaction on Mn/AC and Mn-Mo/AC catalyst specimens, the products encompassed liquid n-alkanes and alkene, i.e., n-C7-n-C20, and oxygenated intermediate substances, e.g., alcohol, aldehyde and ketones, together with vapourised CO and CO2. The SPO-CO2 pathway generates n-C17; oxygen was subtracted in the form of H2O, and/or alcohol was generated via the -CO2/-CO pathway of SPO and the oxygenated intermediates, with the oxygen being eliminated as CO. The manufactured

Catalytic Deoxygenation Reaction of SPO
When SPO underwent the DO reaction on Mn/AC and Mn-Mo/AC catalyst specimens, the products encompassed liquid n-alkanes and alkene, i.e., n-C 7 -n-C 20 , and oxygenated intermediate substances, e.g., alcohol, aldehyde and ketones, together with vapourised CO and CO 2 . The SPO-CO 2 pathway generates n-C 17 ; oxygen was subtracted in the form of H 2 O, and/or alcohol was generated via the -CO 2 /-CO pathway of SPO and the oxygenated intermediates, with the oxygen being eliminated as CO. The manufactured catalysts produced with either alone or two metal catalysts, i.e., Mn/AC and Mn-Mo/AC, offered the superior transformation and total differentiation of n-C 17 hydrocarbon during the DO of SPO. The performance of the catalyst for the reaction was predominantly a consequence of Mn and Mo surface density and the acidity of the catalyst. The DO reaction was conducted for 30 min at a reaction temperature of 300 • C with an agitation speed of 500 rpm within an inert N 2 atmosphere. The screening of the Mn and Mo loading percentage on the activated carbon show that loading the activated carbon by 0.5 wt.% increases the hydrocarbon yield from 31.9% to 37.9% compared to 0.1 wt.% and increases the Mo loading from 0.1 wt.% to 0.5 wt.% leading to an increase in the yield from 25.7% to 42.4%. The screening results show the best Mn loading percentage was 0.5 wt.%, and this percentage was selected. The effect of Mo on the Mn catalyst was studied from 0.1 to 1 wt.% loading percentage, and the results show the 0.5 wt.% of Mn and Mo was the best percentage, with a hydrocarbon yield of 74% ( Figure 5).

Optimisation Study of the Reaction Parameters
Pilot work demonstrated that the bimetallic catalyst specimen, Mn (0.5%) -Mo (0.5%) /AC, was the most efficacious for DO for SPO. Thus, it was utilised in order to evaluate the outcome for varying reaction indices, i.e., catalyst loading, temperature and time, on the hydrocarbon transformation and selectivity.

Effect of Catalyst Loading
The impact of catalyst loading on hydrocarbon transformation and the differentiation of products is presented in Figure 6a,b. The DO reaction was conducted for 30 min at a reaction temperature of 300 • C with an agitation speed of 500 rpm within an inert N 2 atmosphere. The impact of catalyst loading, i.e., 1-6 wt.%, was evaluated. The data demonstrated that DO performance and n-C 15 +C 17 differentiation were both elevated over a catalyst loading range of 1-2 wt.%, but then fell following catalyst loads >2 wt.%. HC yield and product selectivity for n-C 17 were superior, i.e.,47.13 % and 72.85%, respectively, when 2 wt.% was employed. In contrast, a drop in DO performance and n-C 15 +C 17 selectivity at catalyst loads over 2 wt.% may reflect overburdening of the catalyst, which will promote a drive towards secondary and concurrent reactions owing to the surplus active loci for different reactions [29]. Employment of 2 wt.% of catalyst alone was noted to be efficacious and cost-effective. 500 rpm within an inert N2 atmosphere. The screening of the Mn and Mo loading percent-age on the activated carbon show that loading the activated carbon by 0.5 wt.% increases the hydrocarbon yield from 31.9% to 37.9% compared to 0.1 wt.% and increases the Mo loading from 0.1 wt.% to 0.5 wt.% leading to an increase in the yield from 25.7% to 42.4%. The screening results show the best Mn loading percentage was 0.5 wt.%, and this percentage was selected. The effect of Mo on the Mn catalyst was studied from 0.1 to 1 wt.% loading percentage, and the results show the 0.5 wt.% of Mn and Mo was the best percentage, with a hydrocarbon yield of 74% ( Figure 5).

Optimisation Study of the Reaction Parameters
Pilot work demonstrated that the bimetallic catalyst specimen, Mn(0.5%)-Mo(0.5%)/AC, was the most efficacious for DO for SPO. Thus, it was utilised in order to evaluate the outcome for varying reaction indices, i.e., catalyst loading, temperature and time, on the hydrocarbon transformation and selectivity.

Effect of Catalyst Loading
The impact of catalyst loading on hydrocarbon transformation and the differentiation of products is presented in Figure 6a,b. The DO reaction was conducted for 30 min at a reaction temperature of 300 °C with an agitation speed of 500 rpm within an inert N2 at-

Effect of Reaction Time
The impact of reaction time on SPO DO performance was assessed (Figure 6c,d). The DO was conducted within a spectrum of reaction times, i.e., 30-240 min at a temperature of 300 • C. Catalyst loading was 0.5 wt.%, agitation speed was 500 rpm and the reaction was performed in an inert atmosphere. Hydrocarbon transformation rose with the prolongation of the reaction time as anticipated. Both the above and the required n-C 15 +C 17 selectivity became notably elevated from the first 30 min to 60 min, with rises from 29.72% to 64.27% and 55.93% to 87.84%, respectively. This implied that prolonged reaction times could promote DO performance through deCOx pathways by enhancing the capacity of the involved compounds to react with the surface of the catalyst. Above the 60 min reaction time, n-C 15 +C 17 hydrocarbon transformation diminished to 73%, which may be a result of the oxygenated liquid product cracking into lower weight segments, which, in turn, may give rise to the generation of vapourised substances and the deactivation of the active loci on the catalyst through a side reaction, i.e., an active locus with CO and CO 2 [30].
2 wt.% was employed. In contrast, a drop in DO performance and n-C15+C17 selectivity at catalyst loads over 2 wt.% may reflect overburdening of the catalyst, which will promote a drive towards secondary and concurrent reactions owing to the surplus active loci for different reactions [29]. Employment of 2 wt.% of catalyst alone was noted to be efficacious and cost-effective.

Effect of Temperature
The consequence of temperature, i.e., within the spectrum of 270 • C to 350 • C, on the SPO DO reaction was studied (Figure 6e,f). The reaction was conducted utilising catalyst loading of 2 wt.%, agitation speed of 500 rpm and 60 min reaction time in an inert environment. It became transparent that elevating the reaction temperature from 270 • C to 330 • C augmented hydrocarbon transformation from 85.22% to 96.37%. This was modestly diminished to 87.00% when the temperature of the reaction was raised to 350 • C. A comparable pattern was also evident rregarding the n-C 15 +C 17 (94.44 % selectivity) differentiation, with the highest degree seen at a temperature of 330 • C and a fall to 89.77% when the temperature was raised to 350 • C. It was reported that a higher content of FFA in the feedstock will lead to a decrease in DO activity and favour the cracking reaction [31]. In this work, we studied the catalyst activity using fresh palm oil (FFA < 0.05%) at the optimum reaction conditions, the DO results show that the hydrocarbon yield using the fresh pam oil was increased from 96.37% for the sludge palm oil to 98.19% for the fresh palm oil (with increasing in the hydrocarbon yield of 1.82%) ( Figure S1). This suggested that the Mn (0.5%) -Mo (0.5%) /AC were stable at high FFA content feedstocks.

Catalyst Reusability Study
A DO reaction in the batch reactor system state was examined in order to assess the reusability profile of the Mn (0.5%) -Mo (0.5%) /AC catalyst; conditions included 2 wt.% catalysts and a temperature of 330 • C over an hour. When an individual cycle was concluded, reactivation of the catalyst was carried out by rinsing in hexane; it could then be reutilised for the following cycle. Consistent activity of the Mn (0.5%) -Mo (0.5%) /AC catalyst was observed for five serial runs. A hydrocarbon yield of >94%, including n-C 15 +C 17 products with a selectivity of >70%, was achieved ( Figure 7a). These data suggest that the requisite mechanical attributes and chemical stability are present in the Mn (0.5%) -Mo (0.5%) /AC catalyst. There was a modest degree of leaching of Mn 3+ and Mo 3+ species from the Mn (0.5%) -Mo (0.5%) /AC catalyst within each cycle; this was confirmed by the elemental assessment. The change in quantities of Mn 3+ and Mo 3+ leaching into the liquid product from the original to the final run was determined by comparative analysis to slowly rise from 1 ppm to 10 ppm for Mn 3+ and from 2 ppm to 8 ppm for Mo +3 . The attrition in DO activity can therefore be attributed to the loss of the active metals into solution during serial runs. The degree of leaching is below the maximum level specified by the EN 12662 Standard Specification for Diesel Fuel Oils contamination content, i.e., 24 mg L −1 . This verifies that the catalyst used in this study has the potential to be resilient to leaching and demonstrates robust stability. NH 3 -TPD was then utilised in order to determine the properties of the spent catalyst ( Figure 7b). The data from this analysis revealed that there was a decrease in both catalyst acidity and acidity strength owing to the leaching of elements. Overall, the reduction of acidic sites and their strength demonstrated the importance of the Mn (0.5%) -Mo (0.5%) /AC catalyst's acidic properties in changing the relative rates of the deCOx mechanism, resulting in the formation of diesel range fuel. Evidently, a lack of acidic sites reduced the chances of C-O bond cleavage activity yet enhanced C-C bond cleavage, thereby yielding greater light fractions. This was in agreement with the reduction of the desired n-C 15 +C 17 fractions on the 5th run. The decarboxylation/decarbonation ratio was evaluated using Thermal Conductivity Detector-gas chromatography (GC-TCD) of the gases bioproduct for the first run and the fifth run at the optimum conditions. The GC-TCD results show that in the first run, the decarboxylation/decarbonation ratio was 31.98% and the decarboxylation was 66.2% for the decarbonation and about 1.82% for the thermal cracking. Additionally, the catalyst after the 5th run showed stability on the decarboxylation/decarbonation ratio with 29.93% for the decarboxylation (CO 2 ), 68.36% for the decarbonation (CO) and 1.71% (CH 4 ) for the thermal carking (Table S1).

Proposed
Reaction Pathways for Deoxygenation of SPO via Mn (0.5%) -Mo (0.5%) /AC Figure S3 depict the chemical equation for the catalytic deoxygenation of SPO as a summary of the current investigation. SPO was mostly made up of C 18 and C 16 fatty acid derivatives, according to its fatty acid composition profile. The carboxyl and carbonyl groups from C 18 and C 16 fatty acid derivatives are theoretically eliminated by deoxygenation, resulting in hydrocarbon fractions mostly constituted of n-heptadecenes (n-C 17 ) and n-pentadecenes (n-C 15 ), as well as by-products (CO 2 , CO and H 2 O). Instead of mixes of n-C 15 and n-C 17 , a large relative quantity of n-C 15 fraction was produced in this investigation, indicating that mild cracking is likely to occur and lead to C-C cleavage of the n-C 17 fraction moving into the n-C 15 fraction (by removing ethane). Bimetallic Mn-Mo phases are thought to enhance selected deoxygenation-mild cracking routes. The cracking ability of Mn (0.5%) -Mo (0.5%) /AC is due to the Mn and Mo, as shown in the cracking activity of Mn/AC and Mo/AC catalysts. Alternatively, C-C cleavage on fatty acid derivatives may occur, resulting in the creation of C 16 fatty acids, which then undergo a selective deoxygenation process to provide n-C 15 hydrocarbon compounds. Because the cracking process is inescapable, hydrocarbons frequently undergo C-C cleavage, resulting in short-chain hydrocarbon n-(C 7 -C 14 ) [32,33].
Catalysts 2022, 12, x FOR PEER REVIEW 10 of 15 catalyst acidity and acidity strength owing to the leaching of elements. Overall, the reduction of acidic sites and their strength demonstrated the importance of the Mn(0.5%)-Mo(0.5%)/AC catalyst's acidic properties in changing the relative rates of the deCOx mechanism, resulting in the formation of diesel range fuel. Evidently, a lack of acidic sites reduced the chances of C-O bond cleavage activity yet enhanced C-C bond cleavage, thereby yielding greater light fractions. This was in agreement with the reduction of the desired n-C15+C17 fractions on the 5th run. The decarboxylation/decarbonation ratio was evaluated using Thermal Conductivity Detector-gas chromatography (GC-TCD) of the gases bioproduct for the first run and the fifth run at the optimum conditions. The GC-TCD results show that in the first run, the decarboxylation/decarbonation ratio was 31.98% and the decarboxylation was 66.2% for the decarbonation and about 1.82% for the thermal cracking. Additionally, the catalyst after the 5th run showed stability on the decarboxylation/decarbonation ratio with 29.93% for the decarboxylation (CO2), 68.36% for the decarbonation (CO) and 1.71% (CH4) for the thermal carking (Table S1).
(a) (b)  Figure S3 depict the chemical equation for the catalytic deoxygenation of SPO as a summary of the current investigation. SPO was mostly made up of C18 and C16 fatty acid derivatives, according to its fatty acid composition profile. The carboxyl and carbonyl groups from C18 and C16 fatty acid derivatives are theoretically eliminated by deoxygenation, resulting in hydrocarbon fractions mostly constituted of n-heptadecenes (n-C17) and n-pentadecenes (n-C15), as well as by-products (CO2, CO and H2O). Instead of mixes of n-C15 and n-C17, a large relative quantity of n-C15 fraction was produced in this investigation, indicating that mild cracking is likely to occur and lead to C-C cleavage of the n-C17 fraction moving into the n-C15 fraction (by removing ethane). Bimetallic Mn-Mo phases are thought to enhance selected deoxygenation-mild cracking routes. The cracking ability of Mn(0.5%)-Mo(0.5%)/AC is due to the Mn and Mo, as shown in the cracking activity of Mn/AC and Mo/AC catalysts. Alternatively, C-C cleavage on fatty acid derivatives may occur, resulting in the creation of C16 fatty acids, which then undergo a selective deoxygenation process to provide n-C15 hydrocarbon compounds. Because the cracking process is inescapable, hydrocarbons frequently undergo C-C cleavage, resulting in short-chain hydrocarbon n-(C7-C14) [32,33].

Materials
Manganese (II) nitrate tetrahydrate (Mn(NO 3 ) 2 .4H 2 O), Molybdenum (II) acetate dimer (Mo 2 (OCOCH 3 ) 4 ) and Strontium nitrate (Sr(NO 3 ) 2 ) with 99.0% purity was purchased from Merck (Germany); Citric acid (HOC(COOH)(CH 2 COOH) 2 ) with 99.5% purity was purchased from Merck (Germany). The liquid products are alkane and alkene; hence, the standard of n-(C 7 -C 20 ) for gas chromatography analysis, and the internal standard used is 1-bromohexane. All the liquid standards were purchased from Sigma Aldrich and were utilised without further purification. For dilution, GC grade n-hexane with purity >98% (Merck, Darmstadt, Germany) was employed. N 2 gas (99% pure) was purchased from Linde Sdn. Bhd. Malaysia. Palm oil-based SPO (with FFA of 42.35%, Palmitic acid C16:0 of 45.68% Oleic acid, C18:1 of 40.19% were the major fatty acid composition) was used as the feedstock for the study, it was purchased from a restaurant at the Serdang, Selangor, Malaysia, and was employed for the reaction without any purification.

Catalyst Preparation
Palm pressed fibre (PPF) was rinsed in hot water in order to eradicate any dirt and additional contaminants and then dried in an oven. The desiccated PPF was then pulverised utilising the Pulverisette 4 vario-Planetary Mill. The main disc was set at 1200 rpm and the planet pair at 700 rpm; the duration of the milling procedure was 3 h. The powdered material was recovered and passed through a 200 µm laboratory test sieve (Endecotts, Ltd., London, UK) so as to procure the requisite grain. This was immersed in 10 mmol citric acid in ambient conditions for 6 h with ongoing agitation at 500 rpm. The resulting admixture was dried in a vacuum for 24 h at a temperature of 100 • C. The dried powder was introduced into a horizontal tubular furnace employing a perforated cylindrical stainless-steel reactor with dimensions of 30 × 10 cm 2 . The sample underwent pyrolysis at a temperature of 500 • C for 120 min using a water-steam flow rate with nitrogen of 100 cm 3 min −1 . Under continuing nitrogen steam flow, the temperature of the furnace was permitted to cool for a further 120 min. Then, the final product was washed with deionised water to pH 7 and dried in an electric oven, followed by the doping of an appropriate amount of Mn and Mo nanoparticles on the activated carbon. The process was decorated with Strontium(II) nitrate (as a promoter), Manganese (II) nitrate tetrahydrate and Molybdenum (II) acetate dimer according to the hot injection method [34,35]. The decoration was carried out in a Schlenk line setup in a 250 mL flask. In the process, 0.4 mL oleic acid, 0.4 mL oleylamine, 6.86 mg 1,2-hexadecanediol and 20 mL diphenyl ether were purged by vacuum and then charged with nitrogen and repeated 5 times. The mixture was then degassed together under vacuum for a period of 1 h at a temperature of 85 • C. The mixture was later placed under an argon atmosphere and heated to a temperature of 200 • C. Meanwhile, 5 g of AC were dispersed in dichlorobenzene and mixed with the required amount of Manganese (II) nitrate tetrahydrate and Molybdenum (II) acetate dimer and heated under sonication to 80 • C. The Mn-Mo/AC mixture was then injected into the three-neck flask and stirred for 10 min. The reaction was stopped, and the mixture was cooled in a water bath. The mixture was subsequently washed in a three-fold excess of MeOH and centrifuged (3500 rpm, 10 min) to remove the non-reacted chemicals and non-attached Mn and Mo nanoparticles. The supernatant was removed, and the resulting Mn-Mo/AC heterostructure was re-dispersed in toluene solution, which allowed the ligand exchange to occur.
Both the decorated Mn-Mo and the activated carbon were then transferred to an aqueous environment following a ligand exchange procedure. Typically, 5 g of the activated carbon were dispersed in 50 mL of toluene. In the meantime, 40 mL of anhydrous MeOH were mixed with 0.5 g of 2-mercaptopropionic acid (MPA). NaOH pellets were also added under the stirring condition until the pH was raised to above 10.5. The dispersion was then precipitated with acetone/MeOH (1:1, threefold excess) twice, and the new hydrophilic nanocrystals were mixed with toluene (10 mL) and precipitated to wash away the previous ligands (successfully ligand-exchanged nanocrystals are not dispersed). After disposing of the 4 supernatants and drying under N 2 , the crystals were readily dispersed in deionised water. Ultimately, the samples were filtered through a 0.45 µm pore filter and the residual reactants were evaporated (rotation evaporator~40 • C) and purged with N 2 .

Catalyst Characterisation
An X-ray diffraction (XRD) technique (Shimadzu, model XRD-6000, Kyoto, Japan) was employed in order to determine the chemical configuration and the dispersion status of the metal-doped AC catalysts prior to and following the chemical reaction [36]. The surface area measurement of the pulverised specimen was assessed utilising a nitrogen (N 2 ) adsorption/desorption analyser (Thermo-Finnigan Sorpmatic 1990 series, San Jose, CA, USA) via the Brunauer-Emmett-Teller (BET) method. Pore size and volume distribution of the specimens of produced catalyst were additionally appraised. In general, the catalyst specimen was degassed overnight at a temperature of 150 • C in order to eradicate any alien volatile materials and water from its veneer. The true analysis was conducted at a temperature of −196 • C. A vacuum chamber was used for the N 2 desorption and adsorption methods on the catalyst surfaces [31].
The acidic and basic characteristics of the catalyst were assayed using the temperatureprogrammed desorption (TPD) process. A pair of probe molecules, i.e., NH 3 for acid (TPD-NH 3 ), was utilised. The procedure was performed using a Thermo-Finnigan TPDRO 1100 model, which included a thermal conductivity detector (TCD). Approximately 50 mg of catalyst were pre-treated with N 2 gas flow for 30 min at a temperature of 250 • C. Subsequently, the catalyst was exposed to NH 3 gas adsorption for 60 min at a temperature of 50 • C, and then the TCD was employed in order to recognise the NH 3 desorption from the catalyst basic locus with a stream of helium gas at a rate of 30 mL/min between temperatures of 50 • C and 900 • C. The temperature was maintained at a steady level for 30 min. [37]. A LEO 1455 VP was used for the recording of the field emission scanning electron microscopy (FESEM) data.
A Perkin-Elmer Emission spectrometer model Plasma 100 was utilised for the inductively coupled plasma-atomic emission spectrometry (ICP-AES) analysis in order to establish the element constitutions of the specimens of catalyst, i.e., Mn and Mo [38].

Catalytic Activity Evaluation
SPO s DO reactions were performed in a 100 mL magnetically agitated batch reactor. Approximately 10 g of SPO were inserted into the reactor together with 0.1 wt.% of catalyst for each experiment. Before commencing the study, the reactor was cleared with inert gaseous N 2, and the admixture was repeatedly stirred so as to subtract surplus oxygen from the specimen. The combined compounds underwent unremitting agitation in the ongoing inert N 2 flow, the latter at 20 cc/min at atmospheric pressure in order to make certain that the extraction of oxygen was maintained throughout the DO reaction.
The temperature was gradually increased until the goal temperature of 300 • C was reached; the latter was sustained for 60 min. The condensation of relevant substances was achieved by the utilisation of a cooler. These were stored within a container within the batch reactor, which itself was permitted to cool to ambient temperature at the conclusion of the individual experiments via a cooling system reliant on the exchange of extrinsic water. The ultimate liquid products were analysed using gas chromatography, a flame ionisation detector (GC-FID), Fourier-transform infrared spectroscopy and gas chromatography-mass spectrometry (GC-MS).

Product Analysis
The resultant liquid products underwent quantitative appraisal utilising a Shimadzu GC-14B gas chromatograph, which was made up of an HP-5 capillary column 30 m in length, inner diameter and film thickness of 0.32 mm and 25 µm, respectively, and an FID, which operated at 300 • C.
The liquid products were diluted before conversion analysis with GC grade n-hexane and 1 µL of the specimen before conversion analysis assessment. The solution was then placed into the GC column. The temperature of the injection was maintained at 250 • C; the carrier gas selected was N 2 . The oven s true temperature was kept at 40 • C for 6 min; it was then turned up to 270 • C at a rate of 7 • C per min.
1-bromohexane was employed as an intrinsic reference for the quantitative assessments. Work conducted prior to the current experiments using CG-MS for the analysis of the liquid products had identified saturated and unsaturated hydrocarbon fractions, i.e., C 7 -C 20 . The latter was, therefore, additionally characterised by GC-FID analysis utilising reference substances from industrial saturated hydrocarbons within the C 7 -C 20 spectrum together with purchased unsaturated nonene [39].

Conclusions
In this study, the influence of diverse catalyst configurations on both deactivation and harvest were examined in depth through the DO of a number of catalysts, such as Mn (0.5%) -Mo (0.5%) /AC. SPO was the reactant feedstock utilised, which had a significant acid value; FFA components were over 95%. Both saturated and unsaturated fatty acid units made up the feedstock oil. The data suggest that the feedstock underwent efficacious DO with all three forms of catalyst; oxygen was extracted to yield carbon monoxide, carbon dioxide and water. The bimetallic catalyst shows a great effect on the catalyst activity due to the synergic effect between both the active element (Mn and Mo). An optimum DO condition for SPO over Mn (0.5%) -Mo (0.5%) /AC catalysts is by using a 2 wt.% catalyst and a temperature of 330 • C for over an hour with hydrocarbon yield of 96.37% and 94.44% n-C 15 +C 17 selectivity. The Mn (0.5%) -Mo (0.5%) /AC catalyst showed excellent catalyst stability since it can be used for up to five serial runs with a hydrocarbon yield of >72% and n-C 15 +C 17 products with a selectivity of >70%. It should be noted that the catalyst activity effectiveness reduces by reaction runs, owing to the loss of the active metals into the solution during serial runs.