Many people are concerned about products to remove acne, yet perhaps the more vital factor to think about is prevention. After all, an ounce of prevention deserves a pound of cure. So, here are five of the fundamental however crucial methods in order to treat and prevent acne build up.
Getting rid of the outside layer of the skin with natural oils is not really useful preventing or treating acne, or pimple for other people, for it establishes under the skin. Although it's a belief the people establish acne due to that they do not clean their skin thoroughly. For everyone's details, washing the skin too much can trigger irritation and produces more whiteheads and blackheads that turn into pimples after being contaminated. Mild washing is just required. Use moderate soaps or cleanser, an example is Cetaphil or acne bars. Another great sample is Neutrogena item that washes acne.
It is likewise vital to exfoliate; this assists remove the dead skin cells, to maintain a healthy and glowing skin. A mild cleanser will help exfoliate the face after washing. Scrubbing will also assist exfoliate the face, which can be done once or twice a week. This treatment will certainly aid in lowering dead layers skin cells that clog the pores, reason why more pimples or acne.
This removes the germs that worsens acne and it also disconnects oil secretions and helps pimples or acne to heal. This can be discovered in many non-prescription acne treatments. Start traditionalistically with a five percent moisturizer when everyday like after cleaning the face prior to going to sleep. After a week, make it two times daily if there are no other medications being taken or made use of. If the acne is not yet recovered after 4 to 6 weeks, try a ten per-cent mix. This can be bought non-prescription, however, there is a need to seek for a doctor's prescription. Simply make sure to request for a genuine type: the pharmacist can be asked which can be bought over-the-counter or which requires prescription.
These are offered only if there's a doctor's recommendation. Antibiotics are really handy aid for pimples or acne that is currently swelling and red and generally have pus, or for if it not those not any longer being treated with medications as anticipated. These prescription antibiotics get rid of the germs, which develop to whiteheads. Make it a point to follow the medical professional's suggested dosage and constantly take the antibiotic pills with adequate amount of water. A few of these bacteria eliminating medicines may likewise enhance the skin's level of sensitivity to the sun, for this use sunscreen when heading out to avoid any sunburn.
Accutane are antibiotics that are offered just under a doctor's order and recommendation. Accutane is an extremely enhanced pill that is meant for those with deep scars, or pimples that can no longer be dealt with by other medications or prescription antibiotics. Blood test is taken every once in a while when making use of Accutane as medication, as this can affect the levels blood cell and blood count. For women, the medical professional, possibly an obstetrician-gynecologist may need the intake of birth control pills prior to prescribing the Accutane. Extra care is really taken into consideration, as it can be extremely harmful to to pregnant females. However, until this time some doctors are not recommending Accutane.
The Treatment can spend some time which frequently takes six to eight weeks for the pimple to recover after there will certainly be another start of treatment. Some medications can trigger acne to obtain even larger or redder prior to it recovers, there are times when these might have pus too. If the acne still has not welled after numerous medications with other drugs, the medical professional may suggest that the patient take an oral medication. Physicians recommend this retinoid as a last treatment, due to its severe results and it is likewise extremely expensive. Often females are asked to take contraceptive pill regarding help them manage acne especially in females who state of mind swings even prior to their menstruations begin.
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Full-Text PDF [1296 KB]
Cerdas, F.
Titscher, P.
Bognar, N.
Schmuch, R.
Winter, M.
Kwade, A.
Herrmann, C.
post lithium-ion batteries
Felipe Cerdas
Paul Titscher
Nicolas Bognar
Richard Schmuch
Martin Winter
Arno Kwade
Christoph Herrmann
Open Access This article is
freely available
re-usable
Energies 2018, 11(1), 150; https://doi.org/10.3390/en11010150
Exploring the Effect of Increased Energy Density on the Environmental Impacts of Traction Batteries: A Comparison of Energy Optimized Lithium-Ion and Lithium-Sulfur Batteries for Mobility Applications
Felipe Cerdas 1,3,* , Paul Titscher 2,3 , Nicolas Bognar 1,3, Richard Schmuch 4 , Martin Winter 4,5, Arno Kwade 2,3 and Christoph Herrmann 1,3
Chair of Sustainable Manufacturing & Life Cycle Engineering, Institute of Machine Tools and Production Technology (IWF), Technische Universität Braunschweig, Langer Kamp 19b, 38106 Braunschweig, Germany
Institute for Particle Technology (iPAT), Technische Universität Braunschweig, Volkmaroder Straße 5, 38104 Braunschweig, Germany
Battery LabFactory Braunschweig (BLB), Technische Universität Braunschweig, Langer Kamp 19, 38106 Braunschweig, Germany
MEET Battery Research Center, Institute of Physical Chemistry, University of Münster, Corrensstraße 46, 48149 Münster, Germany
Helmholtz Institute Münster, IEK-12, Forschungszentrum Jülich GmbH, Corrensstraße 46, 48149 Münster, Germany
Received: 21 December 2017 / Accepted: 4 January 2018 / Published: 8 January 2018
The quest towards increasing the energy density of traction battery technologies has led to the emergence and diversification of battery materials. The lithium sulfur battery (LSB) is in this regard a promising material for batteries due to its specific energy. However, due to its low volumetric energy density, the LSB faces challenges in mobility applications such as electric vehicles but also other transportation modes. To understand the potential environmental implication of LSB batteries, a comparative Life Cycle Assessment (LCA) was performed. For this study, electrodes for both an NMC111 with an anode graphite and a LSB battery cell with a lithium metal foil as anode were manufactured. Data from disassembly experiments performed on a real battery system for a mid-size passenger vehicle were used to build the required life cycle inventory. The energy consumption during the use phase was calculated using a simulative approach. A set of thirteen impact categories was evaluated and characterized with the ReCiPe methodology. The results of the LCA in this study allow identification of the main sources of environmental problems as well as possible strategies to improve the environmental impact of LSB batteries. In this regard, the high requirements of N-Methyl-2-pyrrolidone (NMP) for the processing of the sulfur cathode and the thickness of the lithium foil were identified as the most important drivers. We make recommendations for necessary further research in order to broaden the understanding concerning the potential environmental implication of the implementation of LSB batteries for mobility applications.
lithium-ion batteries; post lithium-ion batteries; lithium-sulfur batteries; life cycle assessment; electric vehicles
1.1. Background and Motivation of the Study
Transport of goods and people brings numerous challenges to the global agenda concerning sustainability. On the one hand, transport is responsible for 25% of air pollution due to particulate matter in urban areas causing important human health impacts [1]. On the other hand, in 2013 the transport sector was responsible for over 23% of the overall energy-related greenhouse gas (GHG) emissions, 75% of which was particularly caused by road transport [2]. The international energy agency (IEA) estimated that the transportation sector could potentially achieve a reduction of 18% of GHG until 2050 [3]. In this regard, electric vehicles (EVs) offer several attractive advantages. EVs do not only produce no tailpipe emissions, they also operate at a power train efficiency ranging between 60% to 80% [4] in comparison to a 20% to 35% for internal combustion engine vehicles (ICEVs). As Hawkins and colleagues reported [5], assuming an average European electricity mix and a vehicle lifetime of 150,000 km, EVs present a reduced global warming potential (GWP) by approximately 20% compared to ICEVs based on a cradle to grave analysis. Unlike ICEVs, EVs rely solely on a battery system to store the complete energy required by the vehicle not only for propulsion, but also for numerous auxiliary functions such as on-board electronics, lighting, heating and air conditioning. The battery system of an EV plays a determinant role towards a successful implementation of electric mobility and the reduction of the life cycle environmental impacts compared to ICEVs. On the one side, a widespread adoption of EVs depends on the capability of the battery technology to increase energy and power density and prolong its lifetime while decreasing its cost [6]. On the other side, current commercial traction batteries are heavy and expensive devices that consist of raw materials, which are high in embodied energy (e.g., aluminum, copper, nickel, cobalt, graphite) [7]. These factors combined together with an increase in the demand for more capable energy storage systems technology, have motivated the rise of research efforts striving to overcome the technological boundaries on energy capacity and cost [6,8,9]. New energy storage systems imply changes in the material supply chains and production. Research regarding the environmental impact of battery systems for mobility applications is still an emerging field. Particularly the environmental assessment of emerging battery technologies remains, with very few exceptions, unexplored. In this paper, we explore the effect of increasing energy density to the environmental impacts of traction batteries for electromobility. Specifically, we studied the life cycle environmental impact of lithium sulfur batteries (LSB). In order to benchmark the results of our study, we estimated the life cycle environmental impacts of a lithium-ion battery (LIB) as this technology offers already a set of suitable characteristics for the mobility sector and is considered to be the reference point when comparing other technologies [8]. In this regard, we have modeled and calculated the environmental impacts of an NMC111/graphite battery system.
1.2. Towards Higher Energy Density Batteries: Lithium-Ion and Lithium Sulfur Batteries
Improvements in energy density and specific energy can be achieved mainly by: (i) optimizing the design, weight and integration of peripheral (inactive) components at cell and battery pack level; (ii) optimizing current active materials and (iii) developing of new active materials [6,8,9,10,11]. The LIB technology has achieved specific energy values of over 250 Wh/kg and energy density values as high as 697 Wh/L [8]. LIBs have been widely adopted and currently dominate both portable electronic devices and the electric vehicle market [8]. Among the different LIB technologies available, NMC-type layered oxides (LiNi1−x−yMnyCoxO2) are one of the most established positive electrode material in EVs as is evaluated in [12,13,14,15,16]. Research towards the improvement of NMC cathode materials have focused on the optimization of its specific energy by both increasing the amount of nickel and lithium within the cathode slurry [9]. The state of the art material used for the current generation of EVs is NMC 622 (60% Ni, 20% Co and 20% Mn) and the aim of current research is to increase the Ni content, while substituting further by simultaneously decreasing Co and Mn [8]. In addition to current LIBs, many other battery chemistries are promising regarding a potential improvement of the specific energy and energy density. These alternative technologies, also called post lithium ion batteries (PLIBs), are currently under active research since there is a common agreement in the literature that the limits of specific energy and energy density of current LIBs might soon be reached as reviewed by Placke and colleagues [8]. In this regard, the lithium sulfur (LSB) batteries are considered as a promising battery technology for future EVs [17] and even for other mobile applications such as space and aviation [18]. This results from a high theoretical specific energy of approximately 2500 Wh/kg [19]. Especially in terms of the specific energy lithium-sulfur cells are promising for weight sensitive application areas, such as aviation [18]. Approximately 350–400 Wh/kg are currently achievable in prototype cells and up to 600 Wh/kg on cell level are expected [20,21,22]. Sulfur, compared to the active materials commonly used for the lithium-ion technology, has a low density (2.07 kg/m³ vs. ~4.7 kg/m³ of NMC) [6]. This implies both an advantage and a disadvantage. On the one side, LSB offers the chance to manufacture batteries with a higher specific energy (i.e., able to store more energy per kilogram of battery). On the other side, LSB batteries have a lower volumetric energy density, which means that it requires more space per unit of energy stored. This is particularly critical in mobility applications, where the use of volume for technical components needs to be optimized. In any case, in order to take advantage (or reduce its volumetric disadvantage) of the characteristics offered by the LSB technology, all the other components within the cell have to be as light as possible. Inactive masses, such as housing and current collectors, as well as the amount of electrolyte and conductivity additives or sulfur host material has a big lever with regard to the overall cell mass [8,22]. Therefore, structurally integrated battery concepts have the potential to save inactive mass. Furthermore, the other components besides the sulfur cathode, such as the lithium metal anode, separator and electrolyte and its amount, have to be optimized to meet the requirements of power, specific energy and cycle life [23,24,25,26,27,28,29].
1.3. Life Cycle Assessment (LCA) and Its Application for Traction Batteries
LCA is a system analysis methodology standardized by ISO 14040, which enables the estimation of environmental impacts of product systems on a life cycle perspective [30,31]. It starts with the definition of the system boundaries and the selection of a functional unit, followed by a comprehensive collection of inventory data. Information regarding material and energy flows as well as emissions generated is gathered for all relevant phases in the supply chain of the product. These flows are then linked to potential environmental impacts through the application of impact pathway models that allow accounting for environmental effects (e.g., acidification and global warming) and, further, for ecological damages to the so-called areas of protection (e.g., ecological systems, natural resources and human health) [32]. Although the methodology faces several challenges, such as data availability and uncertainty, it can provide relevant insights to develop consistent strategies to reduce the environmental impact of technology and to avoid shifting environmental concerns from one life cycle stage to another within the supply chain. An overview of the application of the LCA methodology for the analysis of electric vehicles can be consulted in [33,34]. Numerous studies have addressed the environmental dimension of EVs [33,35,36,37,38,39,40,41]. The production phase has been identified in the literature to account for about half of the lifecycle GWP impact of EVs. Furthermore, all reviewed studies estimated that around 40–50% of the total GHG produced during this stage are caused by the production of the battery system [5,42,43,44,45,46]. In other impact categories such as human toxicity, ecotoxicity, eutrophication and metal depletion the battery system represents the largest contribution [5,33]. Nevertheless, only few studies have addressed in detailed the impact of the traction battery [7,12,13,14,36]. Current LCA studies on traction battery systems have accounted for cradle to gate GWP results ranging from 39–196 kg CO2-eq/kWh as shown in Table 1. The variation in the results obey mainly differences in the cell chemistry of the battery system being analyzed and to the different assumptions to build the life cycle inventories. A study conducted by Kim et al. uses primary data from a large scale battery production site to evaluate a real LiMn2O4 (LMO)/NMC with a capacity of 24 kWh batteries [12]. In their result, they estimated 140 kg CO2-eq/kWh. In general, batteries that contain nickel and cobalt have a higher cradle-to-gate energy intensity and results in higher GHG emissions than others such as LiFePO4 (LFP) and LMO [7]. In literature, only one study rates the environmental impact of LSB traction batteries. Deng et al. performed a LCA of LSB batteries for a graphene sulfur composite cathode and a lithium metal anode [47]. Data for the life cycle inventory is derived from a lab-scale battery production and literature, specifically the BatPac model 3.0, to deduce a battery pack of 61.3 kWh and a weight of 279 kg.
Their results show a relative environmental advantage the LSB battery compared to the conventional NMC-based battery system as described by Ellingsen et al. [14]. In their study, the specific CO2-emissions per km of the LSB battery were estimated to be approximately 10% below those of the NMC-based LIB (158 g vs. 174 g CO2-eq per km for the LIB). In their study, the authors assumed a decay rate of 0.028% capacity loss per cycle. The battery lifetime in consequence exceeds 200.000 km for the LSB battery system, which is not realistic today. The sensitivity analysis in this work indicates a critical dependency of the results to the decay rate of the battery capacity. Peters et al. [51] studied the environmental impacts of a sodium-ion battery system. An energy density of 102 Wh/kg on pack level with a battery cycle life of 2000 cycles was assumed. The resulting impact of the battery production on climate change is 140 kg CO2-eq/kWh and comparable to LIB results. In other impact categories such as eutrophication and human toxicity, they outperform current LIB batteries. Energy densities found in today LIB battery packs range from 90–140 kWh/kg. The energy required in the manufacturing phase of battery cells is one of the main discussion points throughout the LCA literature on traction batteries. As mentioned in the previous section, the energy demand during the manufacturing phase of the battery cells reported in the literature varies extremely. For instance, Ellingsen and colleagues reported a minimum demand of around 4330 kWh for the manufacturing of a battery pack with an energy density of 163 kWh/kg [14]. Other studies report energy demands varying in the range of ~95 kWh to 200 kWh per kWh energy content [13,52]. Schünemann et al. [52] followed a top down approach and estimated a total energy demand of 31.67 kWh per kWh capacity for the manufacturing of the battery cells. Finally, Yuan et al. [53] presented detailed insights regarding energy demand, process times and material throughput in an industrial manufacturing facility for LIB cells and reported a total energy demand of 50.17 kWh/kgbattery 38% of which is demanded during the electrode drying and 43% by the dry room. Regarding the difference on the cell material, the study by Kim and colleagues analyzed the production of 24 kWh traction battery in a cooperation with Ford and LG Chem [12]. The battery consists of LMO- and NMC-based LIB cells, but, as they argued, they did not find any significant difference in the energy demand for the production of the cells with different materials. While some studies have used primary data from companies, some questions regarding factory capacity and allocation of the energy demanded by the factories technical building services (TBS) are still open [12,14]. The reviewed LCA studies use EV traction LIB with pack weights of 210–300 kg, which accounts for 20–30% of the total EV weight. Disregarding the reported energy density of the battery system, this ratio of active to inactive material at a battery pack level was found to be comparable within the different studies available from literature. Ellingsen et al. [14] mainly built their life cycle inventory based on a bill of materials of a company manufacturing traction batteries. They reported a share of 60% of active materials for a battery pack with an energy density of around 105 Wh/kg. Diekmann and colleagues report a generic composition of a traction battery pack and in their study the share of active material to be 55% [54]. This same share is reported by Kim and colleagues whose battery pack had an energy density of around 80 Wh/kg [12]. Deng and colleagues modeled a LSB battery pack with an energy capacity of 220 Wh/kg and calculated a share of active material of 65.9% [47]. However, in their study they did not set any volume constraint for the active material. Finally, the battery modeled by Yuan and colleagues consisted on a 66% of active material [53]. Both, the studies from Deng and Yuan made used of the BatPac tool to configure their battery packs [55].
2. Goal and Scope
The goal of this study is to describe and compare the environmental impacts of an LIB system against a lithium-sulfur battery (LSB) for mobile applications (EV and electric aircraft). The analyzed LIB system is an energy-optimized NMC111 with a graphitic anode, whereas the LSB is composed of a sulfur cathode and lithium-metal as anode. The boundaries of the analyzed product systems are shown in Figure 1. In this study, we considered the whole life cycle of both battery systems. This includes the production of the materials required for the cell manufacturing and the peripheral components such as modules and pack housing, cooling system and battery management system (BMS). The production of the slurries was considered according to process data obtained from the Battery LabFactory Braunschweig (BLB), a pilot scale production facility for the research and development of battery cells. Electrode manufacturing and assembly of cells and the battery pack, particularly the energy demanded in these processes, has been modeled mostly based on literature data. Data from battery systems disassembled within the context of the LithoRec project were used to model the peripheral elements of the battery pack [54,56,57,58,59,60,61]. The total battery cell volume of the disassembled battery system was estimated and set as a constraint to model the evaluated systems in this study. In order to ensure the comparability of both systems, we have configured a battery system for one specific application using each of the technologies. Particularly, we have configured two battery packs to be able to power the same mid-size EV to which the disassembled battery pack actually belongs. As a starting point for the discussion, it was assumed that the production of the cells, the assembly of the battery and the use phase takes place in Europe. The use phase and the recycling of the battery system has also been included in the study. We have estimated the impact caused per km in each of the cases considering the particular effect of weight to the overall energy consumption of the EV. In this study, the results are presented for different functional units in order to be able to compare our results against the available literature. These are presented per unit (i.e., per pack), per kg of battery and per storage capacity.
A sensitivity analysis for three parameters is included in this study. We evaluated the effect of reducing the amount of the solvent N-Methyl-2-pyrrolidone (NMP) in the dispersion process of the sulfur cathode. The thickness of the metallic lithium foil was evaluated in a sensitivity analysis for LSB cells. Furthermore, the effect of regional electricity mixes used for the production of cells was investigated. The background database used was Ecoinvent 3.3 [62] and ReCiPe [63] for midpoint indicators was applied as the impact assessment method. In this study, a total of 13 impact categories where investigated: global warming potential (GWP) in kg CO2-eq, fossil depletion potential (FDP) in kg oil-eq, ozone depletion potential (ODP) in kg CFC-11-eq, photo oxidation formation potential (POFP) in kg NMVOC, particulate matter formation potential (PMFP) in kg PM10-eq, terrestrial acidification potential (TAP) in kg SO2-eq, freshwater eutrophication potential (FEP) in kg P-eq, marine eutrophication potential (MEP) in kg N-eq, freshwater toxicity potential (FETP) in kg 1.4-DCB-eq, marine toxicity potential (METP) in kg 1.4-DCB-eq, terrestrial eutrophication potential (TETP) in kg 1.4 DCB-eq, human toxicity potential (HTP) in kg 1.4-DCB-eq and metal depletion potential (MDP) in kg N-eq.
3. Life Cycle Inventory Analysis
3.1. Energy Density, Mass and Mass Distribution at Stack, Cell and Pack Level
Figure 1 shows the steps followed to build the life cycle inventory required for the study. The specific inputs and outputs for each of the considered processes can be consulted in the supplementary information. The first step was to determine the distribution of weight at stack level for each of the systems. For this purpose, several assumptions were made. For the calculation of the LIB cell, we used an NMC111-based cathode and a graphite-based anode. For the LSB cell, we used a sulfur cathode containing carbon-black as conductive additive and polyvinylidene difluoride (PVDF) as binder together with a lithium metal counter electrode. Material and energy inventories required for the production is reported in the supplementary information. The inventory used for the production of the LIB cathode, namely NMC111, has been taken from previous research approaches containing a comprehensive description of the manufacturing process [13,14]. Table 2 lists the main characteristics of the materials used for the calculation. Due to the pronounced electrolyte consumption of LSBs during operation we assumed a ratio of electrolyte to sulfur of approximately 6 mL/gsulfur [23,25]. Additional volume and mass of the material class "Separator + electrolyte" considers the needed excess electrolyte, which leads to an increase of energy density and specific energy.
The electrode properties were determined experimentally at the BLB. The electrodes were manufactured following a batch-dispersing process in a planetary mixer for LIB (PMH-10, Netzsch-Feinmahltechnik GmbH, Selb, Germany) and a continuous dispersing process in an extruder (ZSK 18 MEGAlab, Coperion GmbH, Stuttgart, Germany) for LSB. It is important to mention that the amount of NMP required for the slurry production was measured to be approximately 820 g per kg of NMC-electrode solids mixture and 4 kg per kg of sulfur-electrode solids for the LSB. Due to the high amount of carbon black within the sulfur cathode (see Table 3), only a low solid sulfur solids content of 20% can be used in order to achieve a processable slurry viscosity. In the next step, the electrodes were coated on a continuous coating machine (LabCo, Kroenert GmbH, Hamburg, Germany). The produced electrodes were calendared (GKL 400, Saueressig GmbH, Vreden, Germany) to the coating densities shown in Table 2. The material inventory of the electrode manufacturing process has been included in the supplementary information file in Tables S4.1–S4.3 and S5.1–S5.4.
From the results in Table 2 and Table 3, we estimated the areal mass loading, thickness and areal capacity at stack level for each battery technology. The results are shown in Table 4. For the lithium metal foil, we have used the thinnest lithium foil available on the market disregarding costs. As seen, the area capacity of lithium metal is approximately two times higher than that of the sulfur cathode. Reducing this excess is currently an important goal in current research.
With the measured electrode thicknesses, the resulting specific energies and energy densities of the manufactured LIB and LSB cells were estimated. To compare the LSB system on a stack level against the LIB system, a few assumptions had to be made. The thickness of the lithium foil was assumed with 50 µm. The lever of this assumption will be investigated in a sensitivity analysis. An identical separator thickness of 20 µm was assumed for both systems. The amount of electrolyte required was aggregated and reported as a combined density of separator and electrolyte as shown in Table 2. The electrolyte is stored within the void volume of anode and cathode, the separator, as well as the separator around the stack. Additionally, the void volume of the pouch housing has been also considered in the calculation. Because of the early stage of development, a protective layer on the lithium metal is not considered for this calculation. These calculations lead to the stack level energy in Table 5. As shown, the LSB system offers a specific energy of around 80% higher than the LIB and with about 23% increased volumetric energy density.
In order to estimate the mass and volume of a battery cell, we assumed a specific geometry based on current cell formats available at the BLB. The cell manufactured is composed of stacked electrodes as described in Figure S1. The material inventory of the cell produced for each of the battery systems is reported in Tables S4.1–S4.3 and S5.1–S5.4. Moving forward to the configuration of the battery pack, information regarding inactive mass and components of the traction battery was directly collected from disassembling and measuring several battery packs within the context of the project LithoRec [54,56,57,58,59,60,61]. From the disassembly experiments, it was found that for a battery pack with an energy density of around 76.4 kWh/kg, the share of battery cells ranges from 60% to 65%. The inactive mass share was found to be composed of ~33% housing and structural elements mainly of steel, plastics and aluminum and ~4% of electronics and cables. A more detailed description of the material inventory for the assembly of the assumed battery pack can be found in Table S1. Based on the disassembled battery system and the geometric information of the cell described in the section 1 of the supplementary information we estimated an available cell volume of 87 liters. This volume was set as a restriction to configure the battery systems to be compared in our study. Results regarding specific energy for the systems modeled at cell and battery pack level are shown in Figure 2.
In this regard, we modeled two different scenarios: (i) the battery packs conserve the original inactive mass as measured from the disassembly experiments. As the volume remains constant, we obtained a variation on the specific weight of each pack; (ii) the ratio between active and inactive material weight is adjusted. This scenario implies changes in the architecture of the pack or material changes of the peripheral materials and components. This adjustment resulted in an approximate 10% mass increase in the case of the LIB and a 10% mass reduction for the LSB battery.
3.2. Cell Manufacturing and Battery Assembly
The energy required for the manufacturing of the battery cells was estimated based on the work from Yuan and colleagues [53]. For this study, we estimated an approximate energy demand of 4320 kWh (~86 kWh per kWh of battery capacity or ~13 kWh per kg of battery) for the production of the LIB battery cells and 3610 kWh for the LSB cells (~73 kWh per kWh of battery energy content or 14 kWh per kg battery). The difference between both systems lies on the fact that, contrary to the LIB, the anode in the LSB system (i.e., lithium metal) does not need to go through any dispersion, coating or calendaring process and the energy consumption of these processes depend strongly on the material throughput. While our estimations regarding energy consumption are slightly lower than currently reported values in the literature, our battery systems present a higher energy density per amount of material. This issue will be discussed further in this paper concerning LSB batteries. The material inventory built for the cell assembly phase and the battery assembly can be found in Tables S2.1–S2.5 and S3.1–S3.9. For the assembly of the battery pack we based our estimation on the assumption done by Ellingsen et al. [14] and obtained a final value of 0.2 kWh per battery pack.
3.3. Use Phase
To model the use phase, a generic dataset of an EV without a battery system was used [64]. This dataset was adjusted to meet similar characteristics as the vehicle to which the disassembled battery system belongs. The analysis was restricted to the traction energy. This means energy demand due to heating, ventilation and air conditioning (HVAC) systems and other auxiliaries was not considered, assuming that the systems would not incur in different energy demands for different battery systems. The energy demand during the use phase was estimated following the simulative approach described by Bauer and colleagues [43] and by Hofer [42]. These approaches allow estimation of the energy demand per kilometer of the vehicle considering specific vehicle properties such as weight, frontal area, glider mass and components mass. This enables to estimate the difference in energy demanded per kilometer related to a particular change in the weight of the components. The electricity consumption has been estimated for the Worldwide Harmonized Light Vehicles Test Procedures (WLTP) average driving cycle and for the same vehicle with different battery systems. The difference due to the different weights of the batteries was found to be comparably low. For the LIB pack a consumption of 184.79 Wh/km was calculated whereas for the LSB pack the energy consumption was estimated to be 174.79 Wh/km.
3.4. Recycling and End-of-Life
Although the recycling phase was considered, we limited the study to estimate the environmental efforts of recycling. We did not calculate possible environmental credits that might arise from the different avoided burdens implied by the recovery of metals such as metallic lithium. Since we are dealing with an emerging technology, as it is the case of the LSB, we could hardly model a recycling process that allows retrieval of valuable materials from a spent LSB battery. Thus, we restricted this part of the study that evaluates the impacts rising from the efforts of separating a battery system and treating its parts. The data used for this part of the study has been taken from the LithoRec project, which is mostly composed of real measured data. Within LithoRec [56,57,58,59,60,61], it was obtained that 59 kWh of electricity are required to treat a 350 kg traction battery system.
Cradle-to-gate environmental impacts for the two analyzed battery systems are summarized in in Table 6. The compositions of the impacts in terms of their main contributors are shown in Figure 3. The results are reported for three different functional units in order to allow comparison of our results to other previous studies. The amount of carbon equivalent emissions generated by the production of both systems was found to be very similar. A total amount of 5.47 tons CO2-eq (16 kg CO2-eq per battery mass and 110 kg CO2-eq per kWh of battery capacity) and 3.03 tons CO2-eq (20 kg CO2-eq per battery mass and 117 kg CO2-eq per kWh of battery capacity) were estimated for the LIB and LSB, respectively. The results are within the range of the reported results in the literature as shown in Table 1. For example, Kim and colleagues [12] reported a total of 140 kg CO2-eq per kWh of battery for a battery system with an energy density of around 78 kWh/kg. For the LIB case, approximately 30% of the GWP impact was identified as generated during the production of the cathode active material.
Especially the production of NMP solvent has been identified to contribute 90% to the total GWP impact generated during the production of 1 kg of sulfur slurry and 70% of the GWP for the production of 1 kg of NMC slurry. Regarding other impact categories, evident advantages for the LSB can be found in toxicity related categories. For instance, the LSB presents a reduction of around 22% of marine toxicity potential METP, fresh water toxicity potential FETP and human toxicity potential HTP. For the LIB, sulfidic tailing from mining and production activities of nickel and cobalt sulfate mainly drives these categories, which are not a part of the LSB batteries. The production of the nickel sulfate is responsible for approx. 70% of the emissions causing PMFP per kilogram of active cathode material. PMFP was found in the LSB to be reduced on a 33% respecting the LIB. The LSB shows a significant advantage compared to the LIB pack in metal depletion potential (MDP). Around half of the total MDP impact in the LIB is driven by the cathode production. The MDP impact for the production of NMC is driven by the production of the manganese sulfate required for the synthesis of the cathode active material (70%). The largest difference found in the Life Cycle Impact Assessment (LCIA) results is in terms of terrestrial acidification potential mainly driven by sulfur dioxide emissions generated in the production process of nickel sulfate. Consistent to the current state of research, to the most important impact sources of a battery pack, the copper used as current collector in the cell was identified to force most of the toxicity related to impacts such as METP, HTP and FETP. Additionally, the sulfidic tailings and waste from mining and production processes of copper have a potent eutrophication effect in freshwater sources.
The energy consumption within the manufacturing stage of the battery cells has been found to be responsible of ~40% of the total GWP impact for the LIB and of approx. 30% for the LSB. This is consistent with the data reported in the literature as reviewed in Section 3.2. A sensitivity analysis was performed to evaluate the relevance of some of the assumptions to build the life cycle inventory for this study. In Figure 4 we plotted a curve describing the total amount of carbon emissions equivalent generated by the production of the two battery systems on a kilometer basis. In the figure, we show the number of kilometers achieved by both of the battery systems after the battery has completed 500 cycles. The difference in the number of cycles is directly related to the energy content of the battery pack that has been calculated for the vehicle assumed. The low volumetric energy density of the LSB limits, as seen in Figure 4, its lifespan for mobility applications such as EV. Due to its conversion-based kinetics, the life span of LSB cells (approximately ~500 cycles) is one of the main challenges to get the technology ready for the market. The effect of reducing the quantity of NMP processing solvent for the preparation process of the slurry is described. The amount of NMP was calculated to be 4 kg per kg of prepared slurry (Table S5.2). The amount of NMP was reduced by a 20% and by 40% from the initial value. Only small changes in the resulting values ranging between ~45 and 50 g CO2-eq per km for a driven distance of 60,000 km were found. A second analysis was done to evaluate the influence of the geographical location of the manufacturing facility. As mentioned, the energy demand during the manufacturing phase of the cell can produce up to 50% of the total GWP related emissions. This has been found to be a critical parameter. Changes in locations result in increased impact ranging from 20% to 45%.
The use of a metallic lithium foil as the anode for the LSB battery was estimated to contribute to approximately a 15% of the total GWP emissions of the battery as seen in Figure 3. Lithium mining activities are associated with a lower energy demand and reduced emissions compared to the mining of Ni or Co [7]. Li metal is manufactured through salt electrolysis of lithium chloride. Embodied energy for primary production of lithium ranges between 495 MJ and 546 MJ per kg Li with a commercial purity of 99% [65]. This component was found to have a relevant contribution to other impact categories, related to emissions produced for the supply of energy such as fossil depletion potential FDP and particulate matter formation PMFP. The two most important issues around the model of the lithium foil for the purpose of this paper, were first to identify the energy required for the manufacturing process and second to evaluate the effect of increasing and decreasing its thickness in the cell. Regarding the manufacturing energy, we varied the energy reported for the production of the lithium foil between the maximum and the minimum value. The energy required by a foil rolling process for lithium has been reported to vary between 0.62 MJ and 0.68 MJ per kg of foil rolled [65]. No significant difference was found between the environmental impacts resulting from both scenarios (this result is not shown in the figures).
Regarding the thickness of the lithium foil, we varied it from 29 µm to a maximum of 100 µm. No significant changes to the environmental impact of the battery system were identified after varying these parameters. However, this reduction of 21 µm causes an increase in the energy density at cell level leading subsequently to an increase of the potential driven distance of approximately 6000 km for a reference of 500 cycles. In the same way, increasing the Li foil thickness leads to reaching 500 cycles approx. 10,000 km earlier for the given use phase configuration.
5. Main Findings and Implications
In this paper, we aimed at analyzing the influence of increasing energy the density to the environmental impacts of traction batteries. In our study, we investigated a LSB battery and benchmarked the results against the environmental impacts of a standard LIB (NMC111/graphite) battery system. This study has a prospective character as LSB batteries are still under development. Nevertheless, the battery cells were manufactured and characterized in a pilot scale facility using industrial standards. While from the results it cannot be stated categorically whether a LSB battery system outperforms the LIB battery, we identified the aspects to which the impact of LSB depends. Following we provide insights of possible strategies to support its development and implementation.
5.1. Use of Water-Base Solvents
The use of NMP during the production of the sulfur cathode slurry, together with the amount of energy demanded in the manufacturing phase, has the largest environmental impact. As seen in Table S5.2, NMP represented up to 80 wt. % of the slurry mix for the LSB system. This issue faces several environmental challenges. On the one side, NMP it can be absorbed by the skin or inhaled causing serious health issues [66]. On the other side, not only the production of NMP is responsible of a large amount of GHG emissions on a kilogram basis, but also the preparation of the sulfur cathode demanded a huge amount of this processing solvent. According to Wood and colleagues [67] more energy is required to remove NMP during the drying process of the electrode than for other solvents such as water, due to the low vapor pressure of NMP. Zackrisson et al. [49] also evaluated the use of water-based solvents for the production of a NMC cathode, however their results are based on a hypothetical cell and the performance of the cell was not considered in the study. Another alternative is the recovery of NMP after the drying process. This strategy has been described as being expensive due to the infrastructure required and additional safety standards to which the equipment is required to be compliant with [67]. A further alternative is the development of solvent-free manufacturing processes for battery electrodes as described by Ludwig and colleagues [68] for the case of a lithium cobalt oxide-based (LCO) battery and by Thieme et al. for the case of LSB batteries [69].
5.2. Thickness of the Lithium Foil and Alternative Anodes
The use of metal lithium as the anode in the LSB battery was found to have a significant influence to both the energy density of the cell and the environmental impact of the battery system. The use of a thinner foil implies on the one side the requirement of larger amounts of other active materials. This causes an increase in impact categories such as GWP or ADP do to the additional amount of solvent required. However, this increase in energy density contributed to increase the number of kilometers available to be driven for a specific amount of battery cycles. This has therefore a positive repercussion on the environmental impact of the LSB battery system on a kilometer basis. Compared to the lithium anode, lithiated graphite anodes may offer important advantages regarding safety and cost issues [70,71], but it also might contribute to reducing the environmental impact of LSB.
5.3. Limitations and Future Work
This is a study limited to analyze the environmental impact of LSB batteries for mobility applications. Although this study followed an extensive procedure, the approach followed is based on several assumptions and future work is necessary to understand the environmental implications LSB batteries. Following we summarized the necessary future research to enhance the understanding regarding the environmental impacts of LSB batteries.
5.4. More Detailed Research on the Effect of Lithium Metal
While many of the environmental impacts from the production of lithium are already considered within the commercial databases such as Ecoinvent, the criticality issues of lithium are still not included in the ReCiPe methodology [72] and therefore its depletion potential are not reflected within the MDP results. This is important as the LSB battery analyzed contains much more lithium as the LIB. The amount of lithium in a LIB-based battery pack amounts to roughly a 1% [54], while for a LSB battery this amount increases to approximately a 10% on cell level as estimated in this paper. As seen in Table 6, MDP results for LSB are around 40% lower than the LIB. While the availability of lithium in the world to supply the mobility industry has been many times found to be sufficient [6], such analysis has been done for state of the art LIBs.
5.5. Manufacturing Energy for LSB
In order to improve the understanding of environmental impacts of LSB batteries, a more detailed energy analysis needs to be done. Our estimation of energy demanded (80 kWh/kWhbattery for the LIB and ~72 kWh/kWhbattery for the LSB) during this phase for the LSB cells are aligned to most of the bottom-up approaches in the literature [12,13,25,53] in the literature (90–162 kWh/kWhbattery). Nevertheless, the energy demanded by the manufacturing processes of the LSB are based on data reported by Yuan and colleagues [53] which refers to the production of a LIB battery. The production processes of LSB cells present some differences that might result in variations of the energy demanded. Some differences regarding the manufacturing of electrodes are to be considered. On the one side, neither coating nor dispersing processes are required to produce the anode. This implies significant energy savings as the drying process has been identified to be one of the highest energy demanders [53]. On the other side, the high amounts of NMP required to produce the sulfur slurry might cause an increase in the drying time of the cathode as all the solvent must be evaporated and therefore an increased amount of energy is consumed. Another important issue to mention in this matter is the fact that lithium metal is a very sensitive metal that reacts violently with ambient humidity and body moisture. This implies that to handle this material, special infrastructure is required in the factory (e.g., dry rooms, inert glove boxes).
5.6. Estimating the Effect of Avoided Burden Due to Recycling
In our study, we considered only the amount of energy required the recycling process. We did not include possible avoided burdens caused by the recovery of materials. This issue should research with more detail as the differences between the two systems might cause large differences in the results of the environmental assessment of the recycling step. While the recovery of sulfur from batteries might not be as economically attractive as from the cathode active materials found in the LIB (e.g., cobalt, nickel, etc.), recovering lithium can drive the development of specific recycling processes for LSB batteries in the future.
5.7. Extending the Scope to Other Mobility Systems Such as Aviation
Particularly for the case of private mobility, LSB batteries face a big challenge due to the volumetric constraint proper of the automotive industry. LSB batteries, although lighter, require much more volume. Nevertheless, that LSB energy density is further improved to meet the requirements of larger transportation vehicles such as aircrafts, it might be possible to allocate the space required by the cells and the inactive components in several parts of the vehicle leading to more energy capacity.
In this paper, we presented an evaluation of potential life cycle environmental impacts of LSB batteries. We benchmarked the results against the environmental impacts of a LIB battery using NMC111 as a case study. For our research, real electrodes for both LSB and LIB were manufactured and their properties were measured. To ensure comparability we configured two battery systems providing the same amount of energy for the same application, a mid-size European passenger car. The mass distribution of the two battery systems was estimated and configured based on disassembly data collected from the LithoRec project. The energy demanded within the manufacturing phase of the cells was estimated based on a top-down approach from the literature. To estimate the energy consumption during the use phase a simulative approach was followed that allowed calculating the energy demand per kilometer while considering the differences in the mass of the vehicle due to the differences of the battery packs. From our research, we did not find a large difference in the environmental impact of LSB compared to LIB. The amount of solvent required the processing of the sulfur cathode; the thickness of the lithium metallic foil and the demanded energy in the manufacturing processes were identified as the most significant drivers of environmental impacts for the LSB. A broader analysis scope could contribute to enhancing the understanding of the many dimensions in which LSB might affect the environment. In this regard, we identified possible further research on the production of metallic lithium and the comprehensibility of the commercial environmental databases and methodologies to assess it. Additionally, a more detailed analysis of manufacturing and recycling phases for LSB is recommended. Finally, the benefits of the implementation of LSB batteries in other mobility sectors such as aviation and space might become profitable as a smaller volumetric constraint might allow a more flexible use of the space for the active material and additionally an advantage over the specific energy of LIBs.
The following are available online at www.mdpi.com/1996-1073/11/1/150/s1. Life Cycle Inventories for both the LIB and LSB batteries.
The authors wish to thank the German Ministry of Education and Research (BMBF) for funding this work in the project "BenchBatt" (03XP0047C).
The experimental manufacturing of the LIB and LSB electrodes was carried out by Paul Titscher. The estimation of the electrochemical properties of the LIB and LSB batteries was performed in collaboration among Paul Titscher, Richard Schmuch and Felipe Cerdas. The modelling of life cycle inventories, the life cycle assessment and the analysis of results were performed by Felipe Cerdas. The article was written jointly by Felipe Cerdas, Paul Titscher, Nicolas Bognar, Richard Schmuch, Martin Winter, Arno Kwade and Christoph Herrmann. This article was prepared in a joint research consortium; all authors have contributed substantially to this publication.
LCA Life Cycle Assessment
LIB Lithium-ion battery
LSB Lithium-sulfur battery
NMP N-Methyl-2-pyrrolidone
IEA International Energy Agency
GHG green-house gas
EVs electric vehicles
GWP global warming potential
ICEVs internal combustion engine vehicles
NMC lithium manganese cobalt oxide
LMO lithium manganese oxide
LFP lithium iron phosphate
PVDF polyvinylidene difluoride
HVAC heating, ventilation and air conditioning
WLTP worldwide harmonized light vehicles test procedures
GWP global warming potential (kg CO2-eq)
FDP fossil depletion potential (kg oil-eq)
ODP ozone depletion potential (kg CFC-11-eq)
POFP photo oxidation formation potential (kg NMVOC)
PMFP particulate matter formation potential (kg PM10-eq)
TAP terrestrial acidification potential (kg SO2-eq)
FEP freshwater eutrophication potential (kg P-eq)
MEP marine eutrophication potential (kg N-eq)
FETP freshwater toxicity potential (kg 1.4-DCB-eq)
METP marine toxicity potential (kg 1.4-DCB-eq)
TETP terrestrial eutrophication potential (kg 1.4 DCB-eq)
HTP human toxicity potential (kg 1.4-DCB-eq)
MDP metal depletion potential (kg N-eq)
Subscripts
inf. infinite
100 100 years
Wt. % weight percent
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Figure 1. Description of the methodology followed and boundaries of the product systems. a The production of NMC was modeled based on the inventories provided in [13,14]; b metallic lithium only for the LSB. Ecoinvent is a commercial provider of datasets for the environmental assessment of products. SI refers to supplementary information.
Figure 2. Mass distribution and specific energies of the main battery components at stack, cell and battery pack level. * Inactive mass is conserved as in the disassembled battery pack; ** Inactive mass is adjusted to 40% of the whole battery pack mass.
Figure 3. Contribution analysis of the environmental impacts for the production of one battery pack. Impact categories as characterized in the ReCiPe method: global warming potential (GWP) in kg CO2-eq, fossil depletion potential (FDP) in kg oil-eq, ozone depletion potential (ODP) in kg CFC-11-eq, photo oxidation formation potential (POFP) in kg NMVOC, particulate matter formation potential (PMFP) in kg PM10-eq, terrestrial acidification potential (TAP) in kg SO2-eq, freshwater eutrophication potential (FEP) in kg P-eq, marine eutrophication potential (MEP) in kg N-eq, freshwater toxicity potential (FETP) in kg 1,4-DCB-eq, marine toxicity potential (METP) in kg 1,4-DCB-eq, terrestrial eutrophication potential (TETP) in kg 1,4 DCB-eq, human toxicity potential (HTP) in kg 1,4-DCB-eq and metal depletion potential (MDP) in kg N-eq.
Figure 4. Sensitivity analysis 1. Effect of reduced amount of solvent for the production sulfur (S8) slurry to the total GWP of a battery pack through its lifecycle in g CO2-eq per km. Effect of regional different geographical production locations to the total GWP of a battery through its lifecycle.
Table 1. Comparison of literature data.
Battery Chemistry
Battery Size (kWh)
Battery Pack Specific Energy (kWh/kgbattery)
Cradle-to-Gate GWP (kg CO2-eq/kWhbattery)
Notter et al. 2010 [48] LMO—graphite 34.2 0.114 53
Zackrisson et al. 2010 [49] LFP—graphite 10.0 0.093 160
Majeau-Bettez 2011 [13] NiMH, NMC, LFP—graphite 24.0 a 0.112 a 196 a
Dunn et al. 2012 [50] LMO—graphite 28.0 0.133 39
Ellingsen et al. 2013 [14] NMC—graphite 26.6 0.105 172
Kim et al. 2016 [12] LMO/NMC—graphite 24.0 0.08 140
Deng et al. 2017 [47] LSB 61.3 0.22 146
Peters et al. 2016 [51] Na-ion n.a. 0.102 140
a Values correspond to the NMC battery.
Table 2. Material characteristics used for the calculation of the specific energy and energy density of the battery stacks.
Material Characteristics
Active Material (AM) Discharge Capacity (mAh/g) Bulk Density (g/cm³) Average Discharge Potential (V)
NMC111 154 4.70 3.70
Graphite (Gr) 372 2.20 0.10
Sulfur (S8) 1672 2.07 2.10
Lithium metal 3884 0.53 0.00
vs. Li/Li+
Inactive Materials Thickness (µm) Density (g/cm³) Specific Mass (mg/cm²)
Binder - 1.80 -
Pos. current collector 10 2.70 2.70
Neg. current collector 5 8.96 4.48
Separator + electrolyte 20 1.05 2.10
Conductive additive (C65) - 2.25 -
Table 3. Electrode composition and properties use for the calculations (own data from experimental results).
Electrode Composition and Properties
(wt.%)
Porosity (%)
Density (g/cm³)
Density Incl. Electrolyte (g/cm³)
LIB—Cathode NMC111 96% C65 2% 5130 2% 37% 2.82 3.21
LIB—Anode SMGA4 92% C65 3% CMC/SBR 5% 32% 1.51 1.85
LSB—Cathode S8 60% C65 30% 5130 10% 60% 0.72 1.35
LSB—Anode Li-metal 100% - - - - 0% 0.53 0.53
CA = conductive additive
Table 4. Parameters of the full cells at stack level, which are assembled from the manufactured electrodes and are further, calculated for the LSB system (own data from experimental results).
Cell stacks Assembly
Nominal Cell Voltage (V)
Thickness (µm)
Areal Mass (mg/cm²)
Area Capacity (mAh/cm²)
Area Mass (mg/cm²)
NMC//Gr 3.7 55.7 15.70 2.32 53.8 7.33 2.51
S8//Li 2.1 63.6 4.87 5.33 50.0 2.46 9.54
Table 5. Thickness and area mass (including anode, separator, cathode and electrolyte) on stack level for LIB and LSB as well as following calculated specific energy and the energy density.
Total Stack Level
(µm)
Energy Density (Wh/L)
Specific Energy (Wh/kg)
NMC//Gr 148 37.5 594 229
S8//Li 293 36.9 382 303
Table 6. Total environmental impact of the production of a LIB and a LSB battery.
Impact Category *
Per Battery Pack
Per Battery Mass (kg−1)
Per Battery Capacity (kwh−1)
Ref. [14] (LIB)
GWP100 5.47 × 103 3.03 × 103 4.85 × 103 1.59 × 101 2.03 × 101 1.80 × 101 1.10 × 102 1.17 × 102 1.72 × 102
FDP 1.65 × 103 9.37 × 102 1.32 × 103 4.80 × 100 6.28 × 100 5.22 × 100 3.32 × 101 3.61 × 101 4.96 × 101
FETPinf 4.11 × 102 1.68 × 102 2.56 × 102 1.19 × 100 1.12 × 100 1.01 × 100 8.27 × 100 6.46 × 100 9.62 × 100
FEP 9.34 × 100 4.63 × 100 1.32 × 103 2.71 × 10−2 3.10 × 10−2 5.22 × 100 1.88 × 10−1 1.78 × 10−1 4.96 × 101
HTPinf 1.68 × 104 8.31 × 103 1.59 × 104 4.87 × 101 5.56 × 101 6.28 × 101 3.37 × 102 3.20 × 102 5.98 × 102
METPinf 4.21 × 102 1.74 × 102 2.76 × 102 1.22 × 100 1.16 × 100 1.09 × 100 8.46 × 100 6.69 × 100 1.04 × 101
MEP 8.73 × 100 4.14 × 100 6.40 × 100 2.54 × 10−2 2.78 × 10−2 2.53 × 10−2 1.76 × 10−1 1.59 × 10−1 2.41 × 10−1
MDP 5.11 × 103 1.40 × 103 4.10 × 103 1.48 × 101 9.37 × 100 1.62 × 101 1.03 × 102 5.38 × 101 1.54 × 102
ODPinf 5.75 × 10−4 3.11 × 10−4 2.80 × 10−4 1.67 × 10−6 2.08 × 10−6 1.11 × 10−6 1.16 × 10−5 1.20 × 10−5 1.05 × 10−5
PMFP 2.59 × 101 9.33 × 100 1.60 × 101 7.52 × 10−2 6.25 × 10−2 6.32 × 10−2 5.21 × 10−1 3.59 × 10−1 6.02 × 10−1
POFP 2.37 × 101 9.91 × 100 1.80 × 101 6.87 × 10−2 6.63 × 10−2 7.11 × 10−2 4.76 × 10−1 3.81 × 10−1 6.77 × 10−1
TAP100 8.62 × 101 2.26 × 101 5.10 × 101 2.50 × 10−1 1.51 × 10−1 2.02 × 10−1 1.73 × 100 8.69 × 10−1 1.92 × 100
TETPinf 1.37 × 100 7.48 × 10−1 5.20 × 10−3 3.99 × 10−3 5.01 × 10−3 2.06 × 10−5 2.76 × 10−2 2.88 × 10−2 1.95 × 10−4
* Impact categories as characterized in the ReCiPe method: global warming potential (GWP) in kg CO2-eq, fossil depletion potential (FDP) in kg oil-eq, ozone depletion potential (ODP) in kg CFC-11-eq, photo oxidation formation potential (POFP) in kg NMVOC, particulate matter formation potential (PMFP) in kg PM10-eq, terrestrial acidification potential (TAP) in kg SO2-eq, freshwater eutrophication potential (FEP) in kg P-eq, marine eutrophication potential (MEP) in kg N-eq, freshwater toxicity potential (FETP) in kg 1.4-DCB-eq, marine toxicity potential (METP) in kg 1.4-DCB-eq, terrestrial eutrophication potential (TETP) in kg 1.4 DCB-eq, human toxicity potential (HTP) in kg 1.4-DCB-eq and metal depletion potential (MDP) in kg N-eq.
© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Energies EISSN 1996-1073 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert

redpajama_set_name: RedPajamaCommonCrawl


More than 1,300 exclusions from secondary schools in Kimberley, Eastwood and Selston have taken place over the last five years, with almost 500 from one school.
The Kimberley School has seen 479 permanent and fixed exclusions in the last five years - the highest number out of the three local secondary schools.
In fact, the number of exclusions at the school on Newdigate Street was almost 100 more than that of nearby school Hall Park Academy (formerly Eastwood Comprehensive School).
Chris Teal, headteacher at The Kimberley School said they monitored exclusions very carefully, they always send home a letter detailing the standard of behaviour they expect from pupils when they are given a fixed term exclusion and they have not had any permanent exclusions so far this academic year.
He added: "We try very hard to avoid permanent exclusions at all costs, but if the individual gives us little choice then we do it for the benefit of the school community.
"I'm not sure whether we have a lower bar of tolerance to neighbouring schools, but I suspect not.
The main reason given for the exclusions from The Kimberley School was 'other' but the school also saw 100 incidents of pupils being excluded for physical assault against another pupil, and 64 cases of verbal abuse or threatening behaviour against an adult.
Selston High School had the second highest number of exclusions since 2009 with 443 cases recorded and they also quoted 'Other' as the main reason, while persistent disruptive behaviour was the main reason for exclusion from Hall Park Academy with a total of 393 incidents.
However, the Eastwood school recorded the highest number of permanent exclusions in 2012/13 with 0.57 per cent of the pupil population expelled.
John Slater, Service Director for Education at Nottinghamshire County Council, said because all three of the schools are academies, they are not under county council control and so each of them will make up their own rules, decisions and policies around discipline.
He added: "It is important to recognise that the label 'fixed term exclusion' covers a multitude of things - from being asked not to attend a particular lesson, to a requirement not to enter school premises for a prescribed number of days (in the majority of cases from one to five days).


text:
Битва при Дамгане — сражение между персидскими войсками Надир-шаха и афганцами Ашраф-шаха в районе города Дамган на севере Ирана. Победа персов не закончила правление Ашрафа в Персии, но привела к дальнейшим успехам в следующих сражениях кампании по восстановлению Тахмаспа II на троне. Гильзаи были вынуждены вернуться на свою территорию на юге Афганистана. Сражение также доказало превосходство военной системы Надира (кавалерия, стрелки и артиллерия) по сравнению со старой системой афганцев, построенной исключительно на кавалерии. Хотя Ашраф пытался исправить положение в последующем сражении при Мундшахаре, он не сумел построить адекватную военную структуру, чтобы противостоять армии Надира.

Предпосылки
Гильзай Ашраф-шах, придя к власти в период после переворота против своего предшественника Мир Махмуд-шаха, достиг больших успехов в войне с турками: с гораздо меньшими силами он разбил превосходящую турецкую армию и согласился на перемирие, получив земли к западу от бывший империи Сефевидов, а также заручившись турецкой поддержкой и добившись признания в качестве законного правителя Персии.

В то же время Надир и Тахмасп II создали базу на северо-востоке Персии, из которой они оспаривали претензии Ашрафа на недавно приобретенные территории. Узнав, что Надир собирается идти на Герат, Ашраф отправился из Исфахана в августе 1729 года с 30000 солдат в надежде на завоевание Хорасана, в то время, пока Надир будет вести войну с афганцами абдали далеко на восток. К сожалению для Ашрафа, Надир быстро подчинил Герат и вернулся в Мешхед прежде, чем Ашраф смог вторгнуться в Хорасан. Узнав о подходе Ашрафа, Надир собрал своих солдат и занял дороги через Сабзевар 12 сентября 1729 года.

К тому времени Ашраф достиг и осадил Семнан, его армия увеличилась до 40,000 по сравнению с 25-тсячным войском Надира. Оставив позади часть сил, чтобы возобновить осаду Семнана, Ашраф двинулся на восток в сторону Шахруда и послал вперед отряд, чтобы найти и уничтожить артиллерию Надира. Первое столкновение между двумя сторонами произошло к юго-востоку от Шахруда: 14 афганцев были взяты в плен и доставлены к Надиру для допроса. Сам Надир продолжал продвигаться вперед до сумерек и встал лагерем к востоку от деревни под названием Михмандуст. Той ночью Тахмасп обещал ему руку своей сестры, если Надир одержит победу в сражении на следующий день.

Битва

Подготовка
Утром 29 сентября Ашраф развернул свою армию традиционным способом, в три отдельных подразделения — центр, левый и правый фланги, в отличие от персидской армии, которую Надир разделил на четыре части. Ашраф был настолько уверен в своей победе, что он выделил 2-3 тысячи всадников, чтобы выследить и захватить Тахмаспа и Надира после победы.

На своем правом фланге Надир выдвинул вперед арьергард, чтобы занять скалы Таль, где можно было разместить артиллерию. Афганцы узнали об этом маневре и атаковали арьергард персов. Стычка не дала значимого результата: Надир велел арьергарду вернуться на исходные позиции, Ашраф также отдал приказ своим отрядам занять позиции для атаки. Пользуясь временем, занятым этим маневром, Надир расположил свою артиллерию за спинами своих стрелков для их прикрытия. По команде Ашрафа орда афганских всадников рванулась вперед с невероятной скоростью.

Провал афганской атаки
Как только афганцы устремились в атаку, раздались залпы персидской артиллерии, которая, находясь на вершине холма, стала косить афганских всадников сотнями. По мере того, как фланги афганской армии вошли в зону обстрела персидских стрелков, они были расстреляны, афганцам даже не удалось приблизиться к позициям персов для рукопашного боя. Слаженную стрельбу из мушкетов Надир оттачивал годами, и большинство его стрелков были опытными ветеранами. Импульс афганской атаки был утрачен: афганские всадники падали на землю, под копыта коней, поле боя заволокло дымом, ряды атакующих смешались. Штандарт Ашрафа был скошен пушечным ядром, его свита оказалась под огнем, а афганская легкая артиллерия, установленная на верблюдах, была бессильна против тяжелой персидской артиллерии.

Контратака Надир-шаха
Надир начал свою контратаку: персидские стрелки с саблями наголо атаковали дезорганизованного врага. В завязавшейся схватке им удалось пройти через центр афганских позиций и тем самым рассечь армию Ашрафа на две части, заставив оставшихся в живых афганцев в панике бежать. Погоня была краткой, только на несколько километров, и большей части персидской армии не было разрешено продолжить преследование, так как Надир подозревал возможную засаду в районе Семнана.

Последствия
Оставив 12000 солдат убитыми под Дамганом, Ашраф-шах поспешно удалился на запад, но не сдался и сделал ставку на организацию засады на персов в ущелье Хвар. В то же время между Надиром и Тахмаспом активизировались споры: Надир выступил за возвращение в Мешхед, а Тахмасп требовал продолжения отвоевания севера Персии. Тахмасп демонстративно покинул лагерь армии, что вынудило Надира послать эмиссаров для примирения. В итоге Надир оставил шаха в Тегеране и возобновил кампанию.

Примечания

Литература
 Michael Axworthy, The Sword of Persia: Nader Shah, from Tribal Warrior to Conquering Tyrant Hardcover 348 pages (26 July 2006) Publisher: I.B. Tauris Language: English ISBN 1-85043-706-8

Сражения по алфавиту
Сражения державы Сефевидов
Сражения Афганистана
Сентябрь 1729 года
Октябрь 1729 года
Дамган
Сражения 1729 года
Походы Надир Шаха Афшара

redpajama_set_name: RedPajamaWikipedia


In an effort to create a caring and empowering environment for its rapidly ageing population, Singapore hopes to double its volunteerism rate from one in three currently to 70 per cent in five years' time.
"We hope for Singapore to grow as a giving nation with a volunteer in every household," Minister for Culture, Community and Youth Grace Fu said in a keynote address on Tuesday (June 5) at the Asian Venture Philanthropy Network's (AVPN) conference.
"We believe technology can empower and enable citizens to do good by providing time, money and resources to meet the needs of their neighbours and build stronger social bonds," she added.
The conference at Suntec Singapore, which began on Monday, is the largest gathering of social investors in Asia, bringing together 1,000 delegates from 40 countries to address critical issues related to climate action, education and wealth disparity, among other things.
To that end, the National Volunteer and Philanthropy Centre's (NVPC) Giving.SG portal has grown over the past few years to more than 150,000 members who use the platform to find opportunities to volunteer and make donations.
More than S$100 million has been directed to charities through the portal, with over S$50 million distributed in the past 2½ years alone.
She said collaboration across the private and public sectors is key to achieving impact in the social sector.
"Business leaders should move beyond conducting ad hoc, one-off sponsorship or events to incorporating sustained giving programmes as an integral part of their corporate strategy and identity. Companies benefit from the shared public assets of the societies in which they operate and should therefore in return deliver benefit to all these constituencies," Ms Fu added.
She said social enterprises can play a critical role to achieve inclusive growth.
She said: "Social enterprises play an integral role in the ecosystem, by achieving social impact in an economically sustainable way. They bridge the people and private sectors, and deliver on both purpose and profit.
The NVPC and the Community Foundation of Singapore recently started Colabs, an initiative that brings together the public, private and social sectors to tackle complex social issues together at the same forum.
It provides a platform for philanthropists, businesses, foundations, non-profits and sector experts to focus on co-creating solutions for specific social needs.
The first Colabs series on children and youth catalysed two foundations, a multinational company and local non-profits to form a collective venture to help disadvantaged youth transit from school life to work life, with an initial pledge of more than $500,000.
Ms Fu said: "It is a targeted phase in youth and education, which needs very targeted outcomes to plug gaps, that sometimes impact the effectiveness of our programmes.
"So we know that there is a gap, the gap needs more than just financial resources; you will need expertise, networks and opportunities and that's where the collaboration of various sectors make impactful interventions.
By bringing resources and expertise together, the platform allows for better coordination, clearer focus and customised solutions that the beneficiaries require, she added. Read more.


text:
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redpajama_set_name: RedPajamaGithub


text:
Q: How to remove technical noise by discarding several leading PCA components? I have a large metabolomics dataset, 6000 samples and 3300 features.
For the samples the only thing that differentiates each sample from the rest is that one gene was knocked out, which will not affect most of the metabolites.  The features are metabolite concentrations.
There are some 'known'/measured batch and technical variables such as different Mass Spec runs, differential growth of the bacteria in the samples.  However, I also want to adjust for the unknown variables.
It has been suggested that I perform PCA then throw out the first few principal components.  However, I'm not sure how I can use the PCA information to predict values for the original features using the remaining principal components.
df.pca <- prcomp(as.matrix(df.rw),
             center = TRUE,
             scale. = TRUE)

df.pca.x.minus12<-df.pca$x[,-c(1,2)]

How to predict values of the original 3300 features after removing the first 2 components?

A: Actually you might like to take a look into Surrogate Variable Analysis to determine unknown batch effects (link).
And also the author (J.Leek) is currently teaching a MOOC "Statistics for Genomic Data Science"

redpajama_set_name: RedPajamaStackExchange


• No enrollment/registration fee, only the monthly fee is to be paid in advance in the first week of every month.
• Fee amount is charged as per the student's / guardian's occupation, affordability and everyday expenditure incur by the Quran Guide.
• Discount / Concession of 10% of the fee amount would be granted if immediate blood relative is enrolled.
• Free of any fee amount enrollments are also made in order to help the less privileged people.
• Students / Guardians are requested to disclose the real status of their occupation and affordability as their payment also let the less fortunate people learn and this makes the righteous deeds of the fortunate ones double or more than that even inshaAllah.
• On good performance student would be awarded with extra free lessons for the fundamentals of Islam or any other lesson chosen by the student after consultation with the Quran Guide.
By onlinequranguide in Fee Policy on February 2, 2013 .


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Bounce to new heights with a trampoline! Kids will love the hours of fun they can have on our huge trampolines. Invite friends over and bounce until you drop! Our selection of trampolines come with nets for added jumping safety. Now letís get outside and jump for fun!


Welcome to Glequip - the global directory of equipment services! To get you started, we have picked the ones nearest to your location below. Click on each in the list below the map for more information.
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Michael J. Dobert (Mike) has more than 25 years private industry human resource experience across several business sectors including Healthcare, Information Technology, Engineering, Finance/Insurance Services, Retail, Restaurants & Entertainment, Non-Profits, Import/Exports, Professional Services, Franchise, Oil & Gas, Manufacturing, and Construction.
During his career, Mike has held many dual roles in addition to Senior Human Resources Leadership roles including additional appointments as Director of Finance, State Operations Director, Quality & Strategy, and Multicultural Marketing having led to high degree of business acumen and the ability to leverage HR services as a strategic business partner.
Mike also volunteers his time facilitating Board Retreats for area Non-Profits.
In addition, Mike is a certified facilitator for Leadership, Change Management and Diversity training.
Mike received his BBA in Finance from Stephen F. Austin State University and has earned his certification as a Senior Human Resource Professional ( S.P.H.R. ), and SHRM – SCP.
Mike supports his community having served on the Board of Governors at The Center, as well as serving other United Way Agencies and proudly serving the Fort Bend Chamber of Commerce including Chairman of the Board 2016.


So – in the next few days we have 3 of the 4 children starting new schools – all a bit of a new school daze here!!!
Today children 1 and 2 have their 'first days'. For number 2 this shouldn't be too much of a stress – he's moving from First School to Middle School which is in the same building, and all of his friends are moving too. Some other First Schools feed in, so the classes will be bigger (yet more potential girlfriends – he is his father's son after all!), but it shouldn't be too much of a change. I am slightly concerned that he'll now be responsible for his own homework / planning etc – and even getting him to do his reading in First School was a battle – but hopefully he will rise to the challenge – we shall see!
First day at first school – cheeky chap!
For eldest daughter it's all a bit more complicated. Husband had wanted the kids to go to private school from day one – but I have dug my heels in saying I would prefer for them to go to the village schools, where we can walk to school and they can build a friendship group of people in the village. This is totally what's happened – and the support network to us all as a family of other village families is fabulous, However, I'd always said we'd reconsider at 11. In our bit of Worcestershire we have the Middle School system – so she could have stayed in the village for another 2 years – but this was the best time to move her, if that was to be the plan. She did AMAZINGLY well in all of her 11+ and entrance exams – passing for the local grammar school (where I went, and husband's first wife went, there's a whole other post in that one day?!), the high-flying academic private school in the middle of Birmingham, got a scholarship for another all girls private school in Solihull – and in the end is going to a small all girls school in Droitwich. The dealings we've had with them so far have been great – and everyone I know with girls there is really happy. She can go on the train every day (eek!) and be more independent. She is beyond excited.
Best of luck to them in their new schools. Sounds like they are going to have a great time and do well.
Love that he wanted to recreate the photo, what a fun thing to do!
I blame his father for the exhibitionist genes!!
I think it's great that they went to the village school for a few years – nothing can beat a real sense of belonging to a place and being fully a part of the community. When they are older they can travel to meet up with their friends but little ones need local friends whom they can meet in the park. Good luck for the new schools this year.


This hike takes you southwest to Ustetind mountain, on the Hardangervidda mountain plateau. The peak provides views of the plateau and on a fine summer's day you can see Gaustatoppen.
Some of our recommended roundtrips and signature adventures includes Ustetind.


The Foxes suffered their first defeat of the season at the hands of Worcestershire CCC in the Specsavers County Championship, with the visitors winning by an innings.
The Foxes entered the final day with Colin Ackermann and Chris Wright at the crease as they looked to bat for as long as possible and build up a lead for the visitors to chase for the victory.
However, with the lunch interval delayed by 30 minutes, Worcestershire confirmed the victory as the last wicket of Tom Taylor saw the Foxes number 16's 57-run stand come to an end.
The Foxes won the toss at the beginning of the first day, and chose to bowl – a decision, that many were questioning after Worcestershire posted a first innings score of 553-6d.
Head Coach Paul Nixon said: "It was an interesting one with half of the coaching staff thinking one thing, and the other half thinking another.
"In the end, we ended up choosing to bowl. We felt it would do enough by way of seam movement. There are still green areas away from the wicket. It is early April, it's still chilly and the ground can still be a bit damp in the mornings, and we thought that there might have been enough seam movement.
"To be fair, I think there was enough seam movement early on.
More on the defeat, Nixon said: "We are bitterly disappointed because we have come into this game full of confidence and on a high.
"We did not do the basics well enough on a pitch which is very good.
The Foxes managed to post five half-centuries over the course of the fixture and amongst those half-centuries were a number of positive performances at the crease: "It is great to see a bit of resilience from the guys.
"A few of the guys were in a good place and almost felt too good.
"They felt so good that they went after balls that weren't there, but it is a great lesson for them.
After a quick start to the red ball campaign, the County Championship now takes a back seat as the Royal London One-Day Cup gets underway on Wednesday 17 April away at Yorkshire, and Nico can't wait for it to start: "It is exciting.
"We had a heavy white ball emphasis this winter, we looked at the way we were last year and had a great de-brief of the players individually and the game plans.
"There was a heavy emphasis on expanding our white ball game this winter – up until Christmas was basically white ball.
*Click HERE to watch the full interview with Nico.