Thrive After School Community (TASC) caters to young adults, ages 17-25, aiming to build on their solid social, learning, and physical accomplishments. Activities are ever-changing to meet the interests of these young women and men. Our mission is to create well-lived moments for participants, leading to enhanced self-esteem, self-confidence, and empowerment.
Questions? Contact youth@icanthrive.org or contact us here.
Because by helping others, we help ourselves.
© 2018 Thrive Support & Advocacy, Inc.


Experience, innovation and flexibility well describe our engineering attitude.
Flexibility to adapt our experience and skills to all kind of projects.
We invest constantly in acquiring and updating the most modern software packages to improve efficiency and enhance control of quality.
The design process is conducted through software like SACS, MOSES, TEKLA, SOLIDWORKS and AUTOCAD 3D with close integration of calculation, modeling and drafting phases and back.


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UD2014
Three Days of Creativity and Diversity
Call for Papers and Abstracts
Instructions to presenters*
Programme Overview for UD2014
Preconference Workshop
Exhibitions at UD2014
Keynote: Patricia A Moore
Keynote: Hubert Froyen
Keynote: Bodil Jönsson
Keynote: Ivor Ambrose
Keynote: Finn Petrén
Keynote: Stefan Johansson
About UD2014
You are here: UD2014 > About UD2014 > Lund University
Lund University seeks to be a world-class university that works to understand, explain and improve our world and the human condition. The University is ranked as one of the top 100 in the world. It tackles complex problems and global challenges and work to ensure that knowledge and innovations benefit society. It provides education and research in engineering, science, law, social sciences, economics and management, medicine, humanities, theology, fine art, music and drama.
47 000 students and 7 200 employees are based at the campuses of Lund University in Lund, Malmö and Helsingborg. The University has a turnover of around EUR 750 million, of which two thirds is in research and one third in education.
Lund University is a international university with global recruitment. It cooperates with 680 partner universities in over 50 countries and is the only Swedish university to be a member of the strong international networks LERU (the League of European Research Universities) and Universitas 21.
Two major facilities for materials research are currently under construction in Lund: the MAX IV Laboratory, which will be a world-leading synchrotron radiation laboratory and ESS, a European facility that will be home to the world's most powerful neutron source. These will be of decisive importance for materials and life sciences and for industrial development. In Lund, Medicon Village has also been established and will offer a unique environment for life sciences; integrating research, innovation and enterprise creates the conditions for improved health and quality of life.
Learn more about Lund university at http://www.lunduniversity.lu.se/
LTH is the Faculty of Engineering.
Campus LTH
The Faculty of Engineering at Lund University, Lunds Tekniska Högskola or "LTH" in Swedish , is among the leading engineering faculties in Europe, with more than 9 000 undergraduates and 800 postgraduates based both in Lund and at Campus Helsingborg. Founded in 1961, as an independent institute, it today belongs to Lund University, which is one of Scandinavia's largest institutions for education and research with about 35 000 students and 6 000 employees.
LTH is one of few complete engineering faculties in Sweden. Besides the traditional engineering programmes we offer architecture, industrial design and fire safety engineering.
The research carried out is of high international standard and is world-leading in several areas, such as nano-technology, combusting engineering and mobile communications, water resources, automatic control, laser physics and biotechnology.
Thanks to the fact that LTH belongs to a large university, cooperation between different disciplines is stimulated in a unique way. Consequently, LTH is recognized for its cross disciplinary research, e.g. between the medical and technical sciences.
LTH has close contact to business life. Ideon, Sweden's first Research Park, is our neighbour. Moreover, international companies as Alfa Laval, Ericsson, Gambro and Tetra Pak are based in Lund.
The venue for UD 2014 is at Campus LTH in Lund.
Learn more about LTH at http://www.lth.se//english
Submission system is now closed.
March 1, 2014 - Notification of acceptance
April 1, 2014 - Deadline for camera ready submissions
April 1, 2014 - Early bird rate on registration fee ends
June 15, 2014 - Preconference Workshops
June 16-18, 2014 - The UD2014 conference
Email: ud2014@design.lth.se
Twitter: @ud2014
Facebook: UD2014
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Samsung Galaxy A3 (2017), A5 (2017), A7 (2017) released in Indonesia; when will they be launched in India?
Samsung has launched the Galaxy A3 (2017), Galaxy A5 (2017) and Galaxy A3 (2017) in Indonesia. They come with metal-clad body having full HD super AMOLED display and also boast IP67 water-and-dust resistant certifications similar to the Galaxy S7 series.
By : Raymond Ronamai
Feb 8, 2017 09:20 IST
Samsung Galaxy A5 (2017)Samsung UK
Samsung has released its latest A-series smartphones, the Galaxy A3 (2017), Galaxy A5 (2017) and Galaxy A3 (2017), in Indonesia. The company is yet to announce the release dates in India but it should happen soon as the devices have finally come to Asia.
The South Korean technology giant released the Galaxy A3 (2017) and Galaxy A5 (2017) in the United Kingdom (UK) earlier this month but didn't release the Galaxy A7 (2017) though all the devices were announced at a same event.
[READ: Samsung Galaxy A7 (2017) won't be released in Europe]
Samsung Galaxy A3 (2017) specifications:
The device sports a 4.7-inch HD super AMOLED touchscreen with 1,280x720 pixels, powered by a 1.6GHz octa-core Exynos 7870 processor, and runs Android 6.0.16 Marshmallow operating system. It features a 2GB RAM, a 16GB internal memory (expandable up to 1256GB), a 13MP main camera with f/1.9 aperture and LED flash, an 8MP front-snapper with f/1.9 aperture, and a 2,350mAh battery.
The Galaxy A3 (2017) comes with a price tag of Rp 3,999 million / £279 (around $299/ Rs 20,140).
The Galaxy A5 (2017) sports a 5.2-inch full HD super AMOLED touchscreen with 1,920x1,080p resolution, powered by an Exynos 7880 processor clocking 1.9GHz, and runs Android 6.0.16 Marshmallow operating system. It also features a 3GB RAM, a 32GB internal memory (expandable up to 256GB), a 16MP main camera with f/1.9 aperture and LED flash, a 16MP selfie camera with f/1.9 aperture, and a 3,000mAh battery with fast charging technology.
It is priced at Rp 4,999 million / £369 (around $375 / Rs 25,260).
The device features a 5.7-inch Super AMOLED capacitive touchscreen with 1,080x1,920 pixels (386 ppi pixel density), an Exynos 7880 processor, an Android 6.0.1 Marshmallow operating system, a 32GB internal memory expandable up to 256GB via microSD card, and a 3GB RAM. It also has a 16MP main camera with f/1.9 aperture, 27mm, autofocus and LED flash, a 16MP front-snapper with f/1.9 aperture, and a 3,600mAh battery.
It is priced at Rp 5,999 million (around $450 / Rs 30,313).


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Enbridge Donations Helps Walpole Island Land Trust Preserve Natural Heritage
.@Enbridge helps #WalpoleIsland Land Trust preserve natural heritage #csr http://3bl.me/3zn8bz
Multimedia from this Release
Friday, June 21, 2013 - 11:15am
NEWSROOM: Enbridge, Inc.
CAMPAIGN: Community Investment at Enbridge
CONTENT: Article
This week, in honour of National Aboriginal Day in Canada (Friday, June 21) Enbridge will be sharing stories about our dedication to partnering with Aboriginal communities along our rights-of-way.
Enbridge and a First Nation environmental organization are teaming up to protect fragile wetlands within the St. Clair River watershed in southern Ontario.
In May 2011, Enbridge awarded $20,000 to the Walpole Island Land Trust through the company's Natural Legacy Program, which supports community environmental initiatives along the pipeline rights-of-way.
The donation will help the Land Trust conserve the natural habitat of a 171-acre wetland marsh on St. Anne Island, just south of Sarnia. Through this partnership, Enbridge and the Land Trust will also be supporting the goals identified under the St. Clair River Remedial Action Plan by protecting additional acres of fragile habitat within the river watershed.
"A donation likes this one will go a long way to helping us begin to restore the marsh's ecological functions and enhance the wildlife diversity while taking steps to control invasive, non-native plants," said Clint Jacobs, President of the Walpole Island Land Trust.
The Walpole Island Land Trust, the first Aboriginal land trust to receive charitable status in Canada, was formed in 2008 to conserve and protect the land and natural resources of the Walpole Island First Nation or "Bkejwanong," meaning "where the waters divide" in Ojibwe. The region includes some of the most biologically diverse areas in Canada, including 17,000 acres of wetlands.
"Our area is considered one of the largest freshwater deltas in the world. It's an important area for migratory birds," explained Jacobs, a local naturalist.
Enbridge's donation will support a pilot project to conserve and restore the marsh area which was dyked more than a hundred years ago by duck hunting clubs. So far, the Land Trust, in cooperation with various community partners, has leased the marsh area on the island for a 10-year period and has begun pumping water into the marsh to maintain water flow and encourage suitable habitat for fish spawning. The Land Trust has also mapped invasive species such as the Common Reed at the site, and is exploring ways to control this plant from spreading throughout the marsh.
"We want to restore the site to its old glory so that it's not only a good spot for ducks but a rich environment that supports other wildlife, including muskrats, bullfrogs, turtles and fish," said Jacobs.
Another goal is to use the project to educate Aboriginal youth about traditional culture, including how to fish and hunt in the marsh in a sustainable way.
"We want to bring our elders, hunters and youth together, so that we can mentor our youth regarding good hunting practices and help them to better understand the value of the marsh to our traditional way of life," said Jacobs, whose grandfather once used the marsh for hunting and fishing.
"My grandfather was a hunter, fisherman and trapper and lived his entire life out on the marsh. He used to call the marsh his 'grocery store' because it provided for his family."
The Land Trust also plans to train members of the First Nation community on how to conduct wildlife surveys and water quality assessments.
Click here to read more about the Walpole Island Trust.
More From Enbridge, Inc.
Enbridge Inc.'s 2013 Annual Review
Power, Influence and Energy
Monday, May 5, 2014 - 12:00pm
Enbridge Again Named a Top Employer for Canadians Over 40
Friday, May 2, 2014 - 12:45pm
Videos from Enbridge, Inc.
Enbridge Ride: Personal Experience Fuels Passion
Eco-Kids Gives Inner City Children New Aspirations
Enbridge Ride to Conquer Cancer


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A magic number
5:00 AM PDT 3/20/2007 by Todd Wasserman , AP
19 Entertainment's worldwide success is a whole song-and-dance routine
If media moguls had to be screened by the judges of Fox's "American Idol," Simon Fuller wouldn't make it past the first stage.
"Too dull. He's essentially nothing better than a karaoke performer," Simon Cowell would intone.
"He's a little pitchy," Randy Jackson would offer.
Paula Abdul would just giggle.
Indeed, Fuller, the 46-year-old CEO of 19 Entertainment and the man behind the "Idol" franchise (which is known as "Pop Idol" in other parts of the world), doesn't fit the central casting description of the job. He's never ballooned around the world. He doesn't have a discernible political agenda.
In truth, Fuller, who is as central to the 150-person 19 as Donald Trump is to the Trump Organization, is known more for his accomplishments than his personality. "I want to be judged by what I do rather than what I say," Fuller explains. "I was a music manager, and it's always been all about the artist. It's in my genes not to say much."
That ethic has served 19 well. Think of any major British act that's crossed over in the past couple of decades, and it's likely Fuller and his 21-year-old firm is behind it, including the Spice Girls.
Fuller conceived of "Idol" in 1998 as a mechanism to find new artists, expose them and then promote them, all on television. The franchise has reaped untold millions. Fuller himself says he doesn't know its true value. "It's probably impossible to gauge it," he says, rattling off all the ways in which "Idol's" ratings help Fox promote shows like "House," and how sponsors Coca-Cola, Ford and Cingular (now AT&T) all benefit from "Idol." "You can really go on and on," Fuller says.
The value of 19 is a little easier to gauge. CKX, the entertainment firm owned by billionaire Robert Sillerman, bought 19 in March 2005 for about $190 million. From that time until Sept. 30, 2006, the last time CKX reported financial results, 19 has taken in about $205.5 million. The unit makes most of its money from "Idol's" TV production (from licensing fees) as well as foreign syndication, sponsorship, merchandise and touring. But 19's latest venture, "So You Think You Can Dance," also on Fox, has proved to be a hit, and 19 derives additional income from albums from "Idol" graduates such as Kelly Clarkson and Ruben Studdard.
Although 19 has an exclusive joint venture with Brit soccer phenom David Beckham and also has launched fashion lines with Claudia Schiffer and Victoria Beckham, those who are bearish on the unit's prospects say it is too dependent on "Idol," which, for all its ratings and pop-culture glory, might be just a fad. Indeed, in late February, the stock price for CKX, which also holds 85% of the rights to the name, image and likeness of Elvis Presley and 80% of such rights for Muhammad Ali, was down about 50% from its high in mid-2005.
Mark Argento, an equity research analyst with Craig-Hallum Capital in Minneapolis, says the falloff in stock price probably had nothing to do with 19 and was more an issue of a lack of visibility among Wall Street analysts. "It's an eclectic business model," Argento says of CKX. "You really have to sit down and explain it, and management hasn't spent a lot of time talking to the Street."
Argento says it's likely that "Idol's" ratings will eventually fall off, but if Fox is selling $500 million in advertising every season against "Idol," such degradation wouldn't really hurt. "If it's only at 70%, it's still $400 million, which is still huge."
Fuller sees any ratings fluctuations as irrelevant: "I would like to think now that it's at the status of the Super Bowl or the Oscars, where ratings vary from year to year depending on who's nominated or who's playing, but it's always a big event."
And Fuller's not content to let 19 be known as a one-trick pony. The company has several projects in the works, including an American translation of the British comedy series "Little Britain" on HBO and a sitcom starring Victoria Beckham on NBC. Plus, there's "Dance." While 19 U.S. president Iain Pirie acknowledges that though a show about dancing is not going to spawn any recording contracts, "Dance" tours have been very lucrative so far.
Time will tell if Fuller ever tops "Idol," but those who know him well have a cultish faith in his judgment. To them, Fuller is still at heart the A&R man with the golden ear that he was in the early 1980s for Chrysalis Records. (19 is named after the 1986 hit song by one of Fuller's discoveries, Paul Hardcastle.)
After all, Fuller did create the entertainment industry's equivalent of Google -- a search engine for talent.
Todd Wasserman


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Director's reflection: How to build peace
August 29, 2014 | PJALS
This spring, as we sat down with our 2013-2014 community organizing interns to talk about their experience with us, we realized that somehow none of them had led chants into a bullhorn, none of them had held banners while we marched, none of them had managed sign-in at a rally. We were shocked when we realized we hadn't held a major march or rally since our rapid response in September which was part of the successful national push-back against US war on Syria.
Stop the Spiral of Violence: End these Endless Wars
This summer has looked far different! Starting with a Global Day Against Military Spending action, we've mobilized in April rain, May sun, June heat, July 4th weekend traffic, and late July wildfire smoke for actions calling to "End the Spiral of Violence: End these Endless Wars" with a focus on opposing increased US military presence in Iraq, extending our occupation of Afghanistan into 2016, and US-funded military attacks on Gaza.
Repeatedly as we get ready to mobilize, I look for the writings of thought-leaders and opinion-makers on what to call for instead of the latest proposal to bomb. This is especially necessary because the pro-war extremists have been pretty consistent about adding a humanitarian talking point to their list of reasons war is the answer, and that talking point is effective.
No War! Sign-waving action
People across the political spectrum respond to the "we need to bomb to protect vulnerable people" talking point, because people across the political spectrum are genuinely compassionate for members of our human family. Unfortunately, that compassion can be used to manipulate support for policies that do not benefit civilians and people in need but instead just drive fear and war.
I've begun to be able to see patterns in the writings of smart folks like Phyllis Bennis of the Institute for Policy Studies and Sarah Van Gelding of YES magazine. So I want to share with you some gleanings:
What to do instead of bomb, deploy drones, invade, send arms, send troops, or otherwise intervene militarily:
Help people get their basic needs met. Drop food, provide housing, move them out of harm's way. Don't mix humanitarian aid with military operations. It makes humanitarian efforts seem aligned with military goals, and that demolishes trust and puts humanitarian workers at risk. Will this require additional funding of non-military humanitarian structures and groups? That's not a bad thing at all.
Talk to everyone. Negotiations must include all parties; that's the most likely way to end a conflict. A group that is excluded has no reason to abide by agreements. De-escalate, and de-polarize. Bombing does the opposite.
Support international structures for conflict resolution and for accountability, such as the UN, weapons conventions, and the International Criminal Court. Yes, this means our country too needs to abide by international law. Yes, this means we have to walk our talk all the time. That's not a bad thing either.
Linda Greene & Ray Torne say, "NO WAR!"
Don't bomb. Bombing always puts civilians in danger and inevitably kills innocents. Women and children feel the brunt of the fall-out. It nearly always recruits more opponents, hardens the commitment of true believers, and escalates the conflict. Bombing doesn't prevent humanitarian crises; bombing creates and exacerbates humanitarian crises!
Advanced version: Prioritize meeting the needs of vulnerable peoples before there is a hint of an argument to do so through bombing.Pro-actively reduce desperation and the organizing tactics of pro-war extremists in any country find less fertile ground. We can make choices to address the drivers of future–and current–desperation. The UN's Millennium Development Goals, for example, lay out eight key accomplishments to reduce desperation and create the pre-conditions for peac
eradicate extreme poverty and hunger
achieve universal primary education
promote gender equality and empower women
reduce child mortality
improve maternal health
combat HIV/AIDS, malaria, and other diseases
ensure environmental sustainability
global partnership for development
I am repeatedly drawn to Gandhi's quote about the power of creativity in the name of nonviolence and justice: "We are constantly being astonished these days at the amazing discoveries in the field of violence. But I maintain that far more un-dreampt-of and seemingly impossible discoveries will be made in the field of nonviolence."
First we have to assert that it's possible to respond to a crisis with tools other than violence. Let's trumpet what's possible, to teach ourselves and others how we can practically build peace.
Die-in in solidarity with Gaza
Tags: costs of war, militarism, nonviolence, peace, violence, war


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Name: 01-2-2011 -- Gone But Not Forgotten
Updated: 05-15-2019 05:05:59. Owner: GEORGE
Name: John Reed Caudill
Birth: 21 JAN 1846 in Magoffin County, Kentucky
Death: 4 SEP 1916 in Magoffin County, Kentucky
Search for John Reed Caudill in Fold3 Civil War Records
Search for John Reed Caudill in Newspapers
Benjamin Caudill: Birth: 1799 in Wilkes County, North Carolina. Death: 27 FEB 1850 in Magoffin County, Kentucky
Abigail Pennington: Birth: 9 MAY 1803 in Lee County, Virginia. Death: 1887 in Magoffin County, Kentucky
Married: Elizabeth F Conley at Magoffin County, Kentucky.
Elizabeth F Conley: Birth: 31 MAR 1849 in Floyd County, Kentucky. Death: 5 MAR 1922 in Magoffin County, Kentucky
Benjamin Lewis Caudill: Birth: 31 AUG 1869 in Magoffin County, Kentucky. Death: 1 JUL 1942
Mary Alice Caudill: Birth: 11 DEC 1871 in Magoffin County, Kentucky. Death: 11 AUG 1944
Martha E Caudill: Birth: 17 DEC 1873 in Magoffin County, Kentucky. Death: 14 MAR 1953 in Magoffin County, Kentucky
Robert B Caudill: Birth: 11 APR 1876 in Magoffin County, Kentucky. Death: 11 DEC 1958
Leonard Taylor Caudill: Birth: 14 OCT 1878 in Magoffin County, Kentucky. Death: 15 JUN 1967 in Wenatchee, Washington
Elizabeth Abigail Caudill: Birth: 19 SEP 1880 in Magoffin County, Kentucky. Death: 23 JAN 1952 in Magoffin County, Kentucky
Lillie Margaret Caudill: Birth: 24 DEC 1881 in Magoffin County, Kentucky. Death: 6 JUN 1955 in Magoffin County, Kentucky
Easter Evaline Caudill: Birth: 24 DEC 1883 in Magoffin County, Kentucky. Death: 26 OCT 1973
William J Caudill: Birth: 27 JAN 1888 in Magoffin County, Kentucky. Death: 17 AUG 1961 in Magoffin County, Kentucky
John Reed Caudill: Birth: 5 MAY 1892 in Magoffin County, Kentucky. Death: 5 SEP 1927 in Magoffin County, Kentucky


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Kill Screen Versions The Meta
Kill Screen – Previously
The apocalyptic fandom of No Man's Sky
According to American evangelist Harold Camping, the Rapture was supposed to have occurred on May 21, 2011—the date was moved back five months to October when nothing happened. Apocalyptic preacher Ronald Weinland predicted that the world would end on September 30, 2008. This date was also revised to May 27, 2012, and then May 19, 2013. In a similar vein, No Man's Sky was supposed to have been released on June 21, 2016—that particular rapture was pushed back to August 9. Though the fact of fandom is hardly unique to No Man's Sky, the degree of devotion the game's fans…
Have a little more faith in That Dragon, Cancer
The most interesting part of the discussion surrounding this year's That Dragon, Cancer is the reaction on the part of its audience to its religious element. The Telegraph's review, for example, expressed puzzlement at the faith itself, but not at faith as a coping mechanism. Kill Screen's own review discussed the way in which elements of that belief were incomprehensible to those who do not buy into the essential premise. A common theme in these reviews is that grief is eminently relatable; while faith, or at least the specific permutation found in the game, is considered potentially alienating. These same…
You can only play this upcoming iOS game if you believe in it
When Jamaican artist Robert Morrison Jnr. talks about waiting he is really talking about faith. It's not necessarily a religious practice that he refers to either, more of a universal concept, a feature of the human condition. "I think our faith is constantly tested in our daily lives," Morrison says. "Some tests being more apparent than others; some tests being more easily overcome than others." faith manifests in the game as an absence He's musing on the value of faith to justify it as a game mechanic. For in his upcoming iOS experiment Substance of Things, all that you'll be able…
Essay (111)
freeware (238)
Let's talk about Rosa Var Attre, the impossible romance of The Witcher 3
This web app picassofies your pictures into abstract cubist collages
Understanding the sublime architecture of Bloodborne


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Muslimah Montage
Platform for Muslim Women
Changing the Muslim Women Narrative
Forgotten Heroines
Kulsoom Abdullah
I have been Olympic Weightlifting for four years, and participating in Crossfit for two. I launched my website LiftingCovered.com to document my experiences weightlifting in U.S. national competitions.
I was born in Kansas City but my family comes from the Khyber Pukhtunkhwa region of Pakistan. I grew up visiting Pakistan, and much of my extended family live there. My family speaks Pushto, so that is the language I know (though don't speak very fluently, I have better listening skills) and know very little Urdu.
I have been Olympic Weightlifting for four years, and participating in Crossfit for two. I launched my website LiftingCovered.com to document my experiences weightlifting in U.S. national competitions. I was able to compete in my first U.S. national competition in Iowa in July 2011.
Later in 2011, I was chosen to represent Pakistan as their first female weightlifter in the 2011 World Weightlifting Championships in Paris, France. That competition also marked the first time that any weightlifter had competed while wearing hijab internationally. In 2012, I went on to represent Pakistan once more at the Asian Weightlifting Championships in South Korea. In 2013, I took a break from major competitions. I still train and went to a few local competitions. 2014 is undecided for me, but if things fall into place, I might try to compete again.
I received my PhD in electrical/computer engineering from the Georgia Institute of Technology. I currently work as a visiting scholar at Georgia Tech. My research in my PhD thesis and now is in information visualization for network security, specifically for analysts to better understand and interact with the data. I am also currently consulting on a project at Georgia State in understanding the role of technology in CSEM – Commercial Sexual Exploitation of Minors. Earlier last year I have gotten interested in machine learning and data science and am working on learning and practicing these skills. My goal is to find full time employment, part-time or contract work, while I works on these projects in the interim.
What are your favorite quotes?
"I love myself when I am laughing. . . and then again when I am looking mean and impressive."
"Sometimes, I feel discriminated against, but it does not make me angry. It merely astonishes me. How can any deny themselves the pleasure of my company? It's beyond me." – Zora Neale Hurston
"Do your little bit of good where you are; it's those little bits of good put together that overwhelm the world." – Desmond Tutu
"The fight is won or lost far away from witnesses – behind the lines, in the gym, and out there on the road, long before I dance under those lights." – Muhammad Ali
"The only dream worth having is to dream that you will live while you are alive, and die only when you are dead. To love, to be loved. To never forget your own insignificance. To never get used to the unspeakable violence and vulgar disparity of the life around you. To seek joy in the saddest places. To pursue beauty to its lair. To never simplify what is complicated or complicate what is simple. To respect strength, never power. Above all to watch. To try and understand. To never look away. And never, never to forget." – Arundhati Roy
Islamic Perspective:
What Ayah of the Quran do you hold close to your heart? Why?
Surat Aţ-Ţalāq (The Divorce)
65:7 "…God does not burden any soul with more than He has given it– after hardship, God will bring ease."
This along with many of the other ayat about hardships: the benefits, the mercy, the learning from them – helpful reminders, especially with having a positive outlook on life. There are many in the world suffering hardships that are worse that I can even imagine which also puts things into perspective.
What Hadith do you wish more non-Muslims knew about? Why?
"The Messenger of Allah (ﷺ) said: 'The strong believer is better and more beloved to Allah than the weak believer, although both are good. Strive for that which will benefit you, seek the help of Allah, and do not feel helpless. If anything befalls you, do not say, "if only I had done such and such" rather say "Qaddara Allahu wa ma sha'a fa'ala (Allah has decreed and whatever he wills, He does)." For (saying) 'If' opens (the door) to the deeds of Satan.'" Abu Huraira
The "Ten":
What is your favorite book?
When I got deep into my engineering studies, my reading of books outside of the curriculum and research went down, unfortunately. But of the books I have read, I could go with Pride and Prejudice by Jane Austen. I related to the experiences and environment of the characters. I admit a crush on Mr Darcy, in spite of his flaws. My crush on Darcy has been over and my main crush is on Mr. Thornton from Elizabeth Gaskell's book, North and South. I saw the BBC series but have never finished reading North and South, so I can't list it, hence Pride and Prejudice.
2. Who inspires/inspired you?
I can't name one as I draw inspiration from so many great people, but you I am currently really taken with Nelson Mandela. His death made me reexamine his autobiography which is a great story of courage, patience, and forgiveness in the face of adversity.
My personal role model is Aminah Assilmi who I had the honor to meet twice when I had started my graduate studies. She was the strongest, kindest, most amazing Muslim woman I knew, who I felt, in spite of so many obstacles, accomplished a lot. Being able to speak to her and get her encouragement made a difference in my life, especially in dealing with the struggle of not letting others define you and achieving the goals that you desire in face of patriarchal and cultural criticisms which are outside of the spirit of Islam.
3. What is the best lesson your mother/mother figure taught you?
I'm impressed when I think of how she came from Pakistan to a new country (the USA) in the early 70's with a "strange" man 🙂 from an arranged marriage. She did not know the English language and had only lived in the village in the Khyber Pukhtunkhwa province. Then she had to manage a house and life then soon after, kids, eventually having five of us. And to have done it so well which must have been a challenge because we were like the Brady Bunch kids on crack. She had slowly learned from my father and taught herself English and about the culture and history herein the USA but still held to her religion and culture. I know it was traumatic for her losing both parents who died in Pakistan while living far away. I learned that we have an inner strength and can accomplish more than you think you can, in spite of the odds and challenges you face if you are determined.
4./5. What advice would you give your 13 year old self?/What are your hopes for future children?
Try not to care about others think. It's going to be hard, people can bring you down, but screw them. Don't be pressured to fit into a box, seriously. Education is REALLY important and don't let anyone or anything try to stop you. Aim for a career or work that inspires you and you enjoy, not by what is defined for you, so you will be happy and won't be bored. It might be difficult, because people want to put us in a box and it is easier to be in one. Learn from your struggles, keep trying things and experiment. Go ahead cry and get back up again. There are going to be times you will feel very alone, and you will feel like you dont know what you are doing or where you are going, because you are taking a path no one might have and there is no guide. But ultimately, be with those who are like-minded, supportive and you will be happier. I learned that we have an inner strength and can accomplish more than you think you can, in spite of the odds and challenges you face if you are determined.
6. What is the biggest trial you went through in your life and how has that changed you?
My father passing which was sudden and traumatic. Losing someone in your life is very difficult, but you learn from the pain and how to heal and cope. Naming a second one, when my weightlifting controversy became public. That was also very sudden and unexpected. It threw me into roles and work I never thought would happen to be, I had very little guidance but the support of friends, and I think if it was not sudden and I could have known the future, it is possible I could have never wanted to weightlift in the first place. The brute force made me learn a lot about myself, and all that I was capable of accomplishing as one person.
7. Any regrets? What's something that you wish you'd thought about more before you did it?
I think my regrets come mostly from other people saying crap to me and letting it get to me. I do wish I was better at keeping in touch with people, especially my dear friends. Usually, I think A LOT!!! Less thinking, in my case, would be more helpful.
8. How do you bring about real change?
Unintentionally. Doings things, living my life. It does not sound stable or structured, but that is how its resulted for me, just going with the flow and seeing where life takes me.
9. How do you stay grounded?
I do not feel currently grounded, at least in comparison to times in my life that I have been grounded. For me, it is a challenging, and some points in my life it can be very difficult. The problem is my brain. It is so used to being in a state of problem solving, thinking, analyzing, and on top of that, I absorb my environment and that can create additional emotions and sensitivities. I also care about others, which I know is a good quality, but the downside to that is because I think and feel so much, it can bring my energy level down and cause stress. I have to remind myself to remember to take care of myself and not burn out. Most importantly, I have to remember God, who I believe in. There is a reason for the things that happen in your life that we will never fully understand. But I hope I can do the best to learn from the past, respect the thoughts and feeling that may come up, but not to sit with them for so long, and keep moving forward.
What do you hope to be remembered for?
I dont know. But YOLO! LOL
Video Message from Kulsoom:
More about Kulsoom:
My weight lifting blog archiving my journey: http://liftingcovered.com/
Facebook athlete page: https://www.facebook.com/LiftingCovered
My academic website: http://kulsoom.net/
LinkedIn profile: http://www.linkedin.com/pub/kulsoom-abdullah/1/488/311
Links to my press coverage category page (from my website) which includes everything I am aware of:
http://www.liftingcovered.com/category/press-coverage/
http://www.liftingcovered.com/press-videos/
April 6, 2014 by muslimahmontage
Welcome to Muslimah Montage
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Sylvia Chan-Malik
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With a great range of leather shoes for baby girls and toddlers online, Babyshoes is your one stop shop for high quality shoes for young children. From 6 months up to 3 years we have a great range of leather shoes for baby girls to choose from. Some of the brands that we stock include; Fofito, We Do, Panyno and our own brand Borboleta. Whether you are looking for red patent shoes, sandals or boots we have a great choice of leather shoes for toddlers.


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9 swimming pools and waterparks in North Wales that families could visit this summer
Swimming pools have been allowed to reopen, though with some restrictions, and these are just some of the venues in the region that families may want to visit
Joel LeaverTrends Writer / Entertainment Reporter
Parents and guardians may be considering taking kids swimming over the summer holidays (Image: Getty Images/iStockphoto)
The school holidays are almost upon us and so parents are now likely to be planning activities to do with their children once they're finished for the summer break.
We're particularly lucky in the region as there are plenty of options for a day out with attractions like GreenWood Family Park and the Zip World sites often proving popular.
Another activity that many families will be considering is going swimming and there are various locations in the local area which are suitable for this.
READ MORE: The most breathtaking swimming spots in North Wales - and how to stay safe while you're there
With this in mind, we've put together a guide of just some of the pools and waterparks in the region that should be open over the coming weeks, though subject to change.
There may be restrictions due to Covid-19 with booking likely required. Some may be temporarily only allowing those with membership to attend, so check directly in advance and contact them for further details.
And if your favourite swimming location isn't listed then feel free to mention it in the comments section.
Plas Arthur Leisure Centre
This leisure centre in Llangefni has a large 25m swimming pool and a small pool for infants. Like many other venues, activities must be pre-booked at the present moment.
It's website states: "If you wish to use the Online Booking Service, you must be a leisure card holder and are required to complete the online registration before using the Service."
Additionally, only "children and young people over the age of 8 and are members can currently attend our public swim sessions." You can find out more here.
Plas Menai
Plas Menai, the National Outdoor Centre for Wales, is located on the banks of the Menai Strait, "conveniently placed between Bangor and Caernarfon."
A number of different options are available to visitors including lane swimming, family access as well as parent and toddler sessions.
Family swim sessions are for up to 6 participants from the same household, or extended household. They're currently priced at £20 for the group.
Parent and child sessions are aimed at those with pre-school aged children. This option costs £5 per 45-minute session. You can find out more here.
Llandudno Swimming Centre
This venue in Llandudno is home to a 25m competition pool which has eight lanes. It also has a 20m training pool that has four lanes.
The Conwy Council website states: "Both pools feature a moveable floor which gives greater flexibility for how the pool is used."
It's understood that prices are around £5.70 for an adult. Junior and senior citizen access is priced at £3.40.
Colwyn Leisure Centre
The leisure centre in Colwyn Bay "offers a varied number of swimming sessions for the general public and a vast swimming lesson programme for all ages."
Visitors can enjoy spending time in the 25m pool which has six lanes. There's also a 10m teaching pool and a beach area at the facility.
Prices are understood to be around £5.70 for an adult. Junior and senior citizen access is priced at £3.40.
SC2 waterpark (Image: Daily Post Wales)
The waterpark at SC2 in Rhyl as it offers water play and slides. It's best suited to families as there's lots of water features for younger visitors and toddler slides. It also has three slides for adults and older children.
It's worth noting that the main indoor pool is said to be "deep enough to swim in" though it's been designed for play rather than traditional lane swimming.
An hour at the waterpark costs £9.50 for an adult (over 15) and £7.50 for a child, with free entry for children under 3.
There's a separate outdoor paddling pool at SC2 which is "ideal for younger children, toddlers and infants." Access costs £5 for adults (over 3) and £3 for those under 3 - except those under 1 who go free. Find out more here.
The Nova in Prestatyn offers a standard swimming pool. The 25m swimming pool in Denbighshire has four lanes and there's also a small splash pool on site, which is considered "ideal for little swimmers and learners."
The venue is said to be perfect for experienced and novice swimmers alike, promising that it "allows everyone to enjoy the fun of water, regardless of their level of ability."
Prices start from £4.10 for adults, £2.60 for children and those under 3 have free entry. Find out more here.
Sign up to the Love North Wales newsletter
Did you know we offer a free Love North Wales newsletter?
Whether you live in the region or just like to visit the area, our weekly newsletter will bring you inspiration for the best places to visit, eat, shop and have fun in North Wales.
To sign up to the weekly Love North Wales newsletter click here.
Holywell Leisure Centre
This leisure facility in Holywell has three pools which offer visitors of all ages the chance to enjoy a session of swimming.
The main pool is 25m with six lanes. There are two smaller pools, both 6m by 6m, which are referred to on its website as 'baby and splash pools.'
It adds: "Public sessions are now Lane sessions in the main pool with Household sessions in the small pools."
Access is £4.60 for an adult and £2.90 for a junior. Concessions are available. You can find out more here.
Wrexham Waterworld Leisure Centre (Image: Daily Post Wales)
Wrexham Waterworld
This centre in Wrexham promises that it's the "perfect place to take your family for a swim," with its main pool offering plenty of space for youngsters to play and swim.
There are also facilities to keep older children entertained including rapids and a water slide.
Tickets are priced at £5.55 for an adult and £3.70 for a junior. Concessions are available. You can find out more here.
Plas Madoc Leisure Centre
This facility is best known for its leisure swimming pool which even has a wave machine. The venue is suitable for families as there's something for everyone.
Young children can enjoy a slide and "fun pool activities," usually available during the school holidays, whilst there's a spiral water slide for older children and adults.
Tickets for the venue, which is located in Acrefair, are priced at around £5.10 for an adult and £3.30 for a junior or concession. You can find out more here.
You can share your thoughts in the comments section.
8 of the best hotspots for paddleboarding located in North Wales
7 wonderful North Wales pubs which are perfect for a pint this summer
Things To Do North Wales
Love North Wales
IYA Alert County


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Retiree Debt February 22, 2022
When To Borrow From Your 401K To Pay Debt
Chris Kissell
Most of us know the uncomfortable feeling of sinking ever more deeply into debt. The average American household carries more than $90,000 in mortgage, credit card, student loan, personal loan and other forms of debt, according to one recent report.
At some point, those obligations can become overwhelming.
If debts are keeping you awake at night, you may be looking for debt relief options like debt consolidation or taking a loan from your 401(k) plan to wipe the slate clean. While the latter might seem like an attractive option, is it ever wise?
"Borrowing from a 401(k) plan is risky, especially given the challenge that many people face of saving enough money for retirement," says Matthew Imes, an assistant professor of finance in the School of Business at Stetson University.
However, there still may be situations where tapping a 401(k) loan makes sense.
Is It Smart To Use Your 401(k) To Pay Off Debt?
Chances are good that your workplace retirement account has tens of thousands of dollars built up — or even more — if you've contributed to it regularly over the years.
"For many people, retirement assets represent a sizable chunk of their overall wealth," Imes says.
Because these accounts often contain a lot of money, there are situations where it might make sense to tap them to pay off certain types of debt. Imes says all of the following are circumstances where borrowing from a 401(k) can be helpful:
To cover the costs of life-threatening medical emergencies
To avoid bankruptcy
To prevent foreclosure on your home
To provide for essential daily needs during difficult times
However, while borrowing from your 401(k) plan can help you in desperate times, using this option still comes with a major cost: It diverts funds away from your retirement savings, potentially putting your golden years at risk.
What Are The Pros And Cons Of Using Your 401(k) To Pay Off Debt?
In general, the risks of borrowing from your 401(k) plan are significant, and often outweigh the potential benefits.
Most importantly, taking a 401(k) loan can permanently reduce the size of your retirement savings. For starters, "a 401(k) loan creates an opportunity cost," Imes says.
"For any investor that takes out a 401(k) loan during a rising stock market, they are foregoing the performance that the underlying assets of the loan would have realized," he says.
Missing out on those gains can have long-lasting consequences, robbing you of compounding earnings and leaving you thousands of dollars — possibly even hundreds of thousands of dollars — poorer in retirement.
It's also important to note that if you take out a 401(k) and separate from your company before the loan is paid back, there's a good chance that all the money you've borrowed will become due immediately.
If you can't pay back the money, you may be forced to treat the loan as a distribution. If this happens, you'll also owe income tax and an early withdrawal penalty of 10% on the money.
Consequences such as these can put some large and possibly irreparable cracks in your nest egg. Because of these major drawbacks, people should think twice before borrowing from their 401(k) plan.
Imes says flatly that the decision to borrow from your 401(k) plan "puts the prospect of having a suitable and comfortable retirement at risk."
However, there may be times — such as the emergencies Imes cited above — when borrowing from your plan is the best option you have.
Imes notes that there are even situations when a 401(k) loan can pay off in ways you might not expect.
For example, if a debtor takes out a 401(k) loan and the stock market declines sharply after he or she has withdrawn the money, the debtor will "actually have benefitted from reducing their exposure to the stock," Imes says.
What Is The Maximum Amount You Can Withdraw From Your 401(k)?
Retirement plans have the option of allowing participants to take loans, but such plans are not required to offer this perk. So, it's possible that you won't be allowed to withdraw any money from your 401(k). Ask your administrator to explain the rules that pertain to your plan.
The IRS says that if your plan does offer a loan option, the maximum amount that participants can borrow is whichever of the following is less:
The greater of $10,000 or 50% of your vested account balance
That means that if your account balance is $50,000, you can only withdraw $25,000. If you have a balance of $100,000 or more, the most you can borrow is $50,000.
How Much Interest Does Withdrawing From A 401(k) Cost?
When you take out a loan of any kind, you typically have interest rates on the loan. That's true of a 401(k) loan, too. But there's a twist with the 401(k) loan: The interest you pay goes back into your retirement account.
So, you essentially pay the interest costs back to yourself. However, note that unlike standard, pre-tax contributions to a 401(k) plan, the interest you pay on the loan goes back into your account on a post-tax basis.
How much interest will you pay on your 401(k) loan? Generally, the 401(k) plan administrator determines this rate, and it's often based on the Prime Rate. Most banks use the Prime Rate to set their own rates for different types of loans and lines of credit.
Does Withdrawing From Your 401(k) Affect Your Credit Score?
Borrowing from your 401(k) can put your retirement at risk, but it won't hurt your credit score.
Unlike applying for a credit card, no lender will do a credit check if you borrow from your retirement fund. And even if you miss payments or default on your loan, this information won't be submitted to credit-reporting agencies.
Is There A Penalty For Paying Off 401(k) Loans Early?
Generally, there's no penalty for paying off a 401(k) loan early. However, each plan's rules differ, so it's important to check with your plan administrator.
For example, some plans may only allow you to pay off the balance in full, rather than making large repayments over a period.
What Are Some Alternatives To 401(k) Loans?
While a 401(k) loan might make sense in some situations, it can potentially put your retirement savings at risk. Imes says there are other options to consider before making such a withdrawal.
For example, if you own a home, it might make more sense to take out a home equity loan or apply for a personal loan to pay off your debts.
"These types of loans do not impact investor's retirement capital, unless they are planning to use their home to fund retirement," Imes says.
If your debts are overwhelming, you can also seek out the help of experts. These may include nonprofit credit counseling services or debt-settlement companies that can assist you with financial planning to overcome debt.
At National Debt Relief, we take pride in empowering people to regain their financial stability through our proven debt relief program. Contact us and talk to a financial expert who will work with you to find the best option to settle your debt and help you achieve financial independence.
Chris Kissell has been a writer and editor for more than two decades. His work has appeared in numerous newspapers and magazines, and on many news websites, including U.S. News & World Report, MSN and Fox Business. He lives in Denver, Colorado.
Debt Relief November 15, 2022
How To Pay Off Debt By Borrowing From Yourself
Retiree Debt November 20, 2012
Should You Use Your 401(k) Money To Pay Off Debt?
Should I Use My 401K to Pay Off Debt?


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The Organometallic Reader
Dedicated to the teaching and learning of modern organometallic chemistry.
β-Elimination Reactions
In organic chemistry class, one learns that elimination reactions involve the cleavage of a σ bond and formation of a π bond. A nucleophilic pair of electrons (either from another bond or a lone pair) heads into a new π bond as a leaving group departs. This process is called β-elimination because the bond β to the nucleophilic pair of electrons breaks. Transition metal complexes can participate in their own version of β-elimination, and metal alkyl complexes famously do so. Almost by definition, metal alkyls contain a nucleophilic bond—the M–C bond! This bond can be so polarized toward carbon, in fact, that it can promote the elimination of some of the world's worst leaving groups, like –H and –CH3. Unlike the organic case, however, the leaving group is not lost completely in organometallic β-eliminations. As the metal donates electrons, it receives electrons from the departing leaving group. When the reaction is complete, the metal has picked up a new π-bound ligand and exchanged one X-type ligand for another.
Comparing organic and organometallic β-eliminations. A nucleophilic bond or lone pair promotes loss or migration of a leaving group.
In this post, we'll flesh out the mechanism of β-elimination reactions by looking at the conditions required for their occurrence and their reactivity trends. Many of the trends associated with β-eliminations are the opposite of analogous trends in 1,2-insertion reactions. A future post will address other types of elimination reactions.
β-Hydride Elimination
The most famous and ubiquitous type of β-elimination is β-hydride elimination, which involves the formation of a π bond and an M–H bond. Metal alkyls that contain β-hydrogens experience rapid elimination of these hydrogens, provided a few other conditions are met. Read the rest of this entry »
Written by Michael Evans
Posted in content, reactivity
Tagged with backbonding, beta-elimination, beta-hydride elimination, dehydrogenation, diastereomers, electron counting, frontier molecular orbital theory, oxidation, reduction, stereoselectivity, stereospecificity, transfer hydrogenation
Migratory Insertion: 1,2-Insertions
Insertions of π systems into M-X bonds are appealing in the sense that they establish two new σ bonds in one step, in a stereocontrolled manner. As we saw in the last post, however, we should take care to distinguish these fully intramolecular migratory insertions from intermolecular attack of a nucleophile or electrophile on a coordinated π-system ligand. The reverse reaction of migratory insertion, β-elimination, is not the same as the reverse of nucleophilic or electrophilic attack on a coordinated π system.
1,2-Insertion is dinstinct from nucleophilic/electrophilic attack on coordinated ligands.
Like 1,1-insertions, 1,2-insertions generate a vacant site on the metal, which is usually filled by external ligand. For unsymmetrical alkenes, it's important to think about site selectivity: which atom of the alkene will end up bound to metal, and which to the other ligand? To make predictions about site selectivity we can appeal to the classic picture of the M–X bond as M+X–. Asymmetric, polarized π ligands contain one atom with excess partial charge; this atom hooks up with the complementary atom in the M–R bond during insertion. Resonance is our best friend here!
The site selectivity of 1,2-insertion can be predicted using resonance forms and partial charges.
A nice study by Yu and Spencer illustrates these effects in homogeneous palladium- and rhodium-catalyzed hydrogenation reactions. Unactivated alkenes generally exhibit lower site selectivity than activated ones, although steric differences between the two ends of the double bond can promote selectivity. Read the rest of this entry »
Tagged with 1-2-insertion, beta-elimination, beta-hydride elimination, external attack, migratory insertion, olefin polymerization, site selectivity, stereoselectivity
Migratory Insertion: Introduction & CO Insertions
We've seen that the metal-ligand bond is generally polarized toward the ligand, making it nucleophilic. When a nucleophilic, X-type ligand is positioned cis to an unsaturated ligand in an organometallic complex, an interesting process that looks a bit like nucleophilic addition can occur.
Migratory insertion into a metal-carbon bond.
On the whole, the unsaturated ligand appears to insert itself into the M–X bond; hence, the process is called migratory insertion. An open coordination site shows up in the complex, and is typically filled by an added ligand. The open site may appear where the unsaturated ligand was or where the X-type ligand was, depending on which group actually moved (see below). There is no change in oxidation state at the metal (unless the ligand is an alkylidene/alkylidyne), but the total electron count of the complex decreases by two during the actual insertion event—notice in the above example that the complex goes from 18 to 16 total electrons after insertion. A dative ligand comes in to fill that empty coordination site, but stay flexible here: L could be a totally different ligand or a Lewis base in the X-type ligand. L can even be the carbonyl oxygen itself!
X can migrate onto unsaturated ligand Y, or Y onto X. The former is more common for CO insertions.
We can distinguish between two types of insertions, which differ in the number of atoms in the unsaturated ligand involved in the step. Insertions of CO, carbenes, and other η1 unsaturated ligands are called 1,1-insertions because the X-type ligand moves from its current location on the metal to one spot over, on the atom bound to the metal. η2 ligands like alkenes and alkynes can also participate in migratory insertion; these reactions are called 1,2-insertions because the X-type ligand slides two atoms over, from the metal to the distal atom of the unsaturated ligand.
1,2-insertion of an alkene and hydride. In some cases, an agostic interaction has been observed in the unsaturated intermediate.
This is really starting to look like the addition of M and X across a π bond! However, we should take care to distinguish this completely intramolecular process from the attack of a nucleophile or electrophile on a coordinated π system, which is a different beast altogether. Confusingly, chemists often jumble up all of these processes using words like "hydrometalation," "carbometalation," "aminometalation," etc. Another case of big words being used to obscure ignorance! We'll look at nucleophilic and electrophilic attack on coordinated ligands in separate posts.
Tagged with carbon monoxide, migratory insertion, periodic trends, stereoselectivity, steric factors
Reductive Elimination: General Ideas
Reductive elimination is the microscopic reverse of oxidative addition. It is literally oxidative addition run in reverse—oxidative addition backwards in time! My favorite analogy for microscopic reversibility is the video game Braid, in which "resurrection is the microscopic reverse of death." The player can reverse time to "undo" death; viewed from the forward direction, "undoing death" is better called "resurrection." Chemically, reductive elimination and oxidative addition share the same reaction coordinate. The only difference between their reaction coordinate diagrams relates to what we call "reactants" and "products." Thus, their mechanisms depend on one another, and trends in the speed and extent of oxidative additions correspond to opposite trends in reductive eliminations. In this post, we'll address reductive elimination in a general sense, as we did for oxidative addition in a previous post.
A general reductive elimination. The oxidation state of the metal decreases by two units, and open coordination sites become available.
During reductive elimination, the electrons in the M–X bond head toward ligand Y, and the electrons in M–Y head to the metal. The eliminating ligands are always X-type! On the whole, the oxidation state of the metal decreases by two units, two new open coordination sites become available, and an X–Y bond forms. What does the change in oxidation state suggest about changes in electron density at the metal? As suggested by the name "reductive," the metal gains electrons. The ligands lose electrons as the new X–Y bond cannot possibly be polarized to both X and Y, as the original M–X and M–Y bonds were. Using these ideas, you may already be thinking about reactivity trends in reductive elimination…hold that thought. Read the rest of this entry »
Tagged with electronic factors, geometry, hydrocyanation, reductive elimination, steric factors
Oxidative Addition of Polar Reagents
Organometallic chemistry has vastly expanded the practicing organic chemist's notion of what makes a good nucleophile or electrophile. Pre-cross-coupling, for example, using unactivated aryl halides as electrophiles was largely a pipe dream (or possible only under certain specific circumstances). Enter the oxidative addition of polarized bonds: all of a sudden, compounds like bromobenzene started looking a lot more attractive as starting materials. Cross-coupling reactions involving sp2– and sp-hybridized C–X bonds beautifully complement the "classical" substitution reactions at sp3 electrophilic carbons. Oxidative addition of the C–X bond is the step that kicks off the magic of these methods. In this post, we'll explore the mechanisms and favorability trends of oxidative additions of polar reagents. The landscape of mechanistic possibilities for polarized bonds is much more rich than in the non-polar case—concerted, ionic, and radical mechanisms have all been observed.
Concerted Mechanisms
Oxidative additions of aryl and alkenyl Csp2–X bonds, where X is a halogen or sulfonate, proceed through concerted mechanisms analogous to oxidative additions of dihydrogen. Reactions of N–H and O–H bonds in amines, alcohols, and water also appear to be concerted. A π complex involving η2-coordination is an intermediate in the mechanism of insertion into aryl halides at least, and probably vinyl halides too. As two open coordination sites are necessary for concerted oxidative addition, loss of a ligand from a saturated metal complex commonly precedes the actual oxidative addition event.
Concerted oxidative addition of aryl halides and sulfonates.
Tagged with binuclear oxidative addition, concerted oxidative addition, cross-coupling, oxidative addition, oxidative ligations, radical chains, radical reactions, SN2
OM Web Resources
Budzelaar's Course Materials
Fu's Course Materials
Organometallic Chemistry @ VIPER
Shaugnessy's Course Materials
The Organometallic HyperTextBook
UW Catalysis Center Videos
White's Course Materials
18-electron rule acidity agostic interactions alkyls alpha-arylation associative substitution atomic size backbonding beta-elimination beta-hydride elimination bond strength bridging carbon monoxide chelation complexes concerted oxidative addition cone angle crystal field theory cyclopentadienyls diastereomers electron counting electronic factors fluxionality formal charge frontier molecular orbital theory general announcements geometry hydroformylation hydrogenation infrared spectroscopy ionization energy kinetics lanthanide contraction lecture notes ligand field theory ligands ligand substitution metal carbenes microscopic reversibility migratory insertion motivation number of d electrons olefin metathesis olefin polymerization orbital character orbitals organometallic chemistry oxidation oxidation state oxidative addition oxidative ligations periodic trends philosophy of science pi systems principles problem sets radical chains radical reactions reaction mechanisms reduction reductive elimination resources sigma complexes site selectivity SN2 spectrochemical series stereoselectivity steric factors structure Suzuki reaction total electron count trans effect transition metals transmetalation tungsten hexacarbonyl


Today here in Australia, the 2011 short-listed titles for the Prime Minister's Literary Awards were announced.
I have read three of the five titles (click on the title for my review) and while I really liked all three, my vote goes to Cath Crowley's Graffiti Moon.
I have only read Flyaway by Lucy Christopher, although Morris Gleitzman's Now has been on my TBR list for a long time.
The winners will be announced in the first week of July. To view the adult short-listed books click here.
Like you I have only read 3 of the top 5 in the YA. And I loved all three. I am glad I don't have to pick!
we have read the same three. i loved them all but i picked graffiti moon as my fave book last year!
Ahhh yes all three were good but I am just so in love with Graffiti Moon.


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US is a 'country of mushrooms' when it comes to cybersecurity
Shamoil T. Shipchandler, partner at Bracewell & Giuliani LLP
Published 2:17 PM ET Thu, 12 March 2015 CNBC.com
weerapatkiatdumrong | Getty Images
North Korea just came up with a list of 310 new political slogans to commemorate its 70th anniversary, among which are "play sports games in an offensive way!" and "let us turn ours into a country of mushrooms!" Seriously. I laughed about how ridiculously frivolous those slogans are as I watched the Arizona llama drama (llamas on the llam! Alpaca suitcase!) and determined that the dress was white and gold.
The dress is white and gold. OK? Good.
But then the more that I thought about it, the more that I began to think that "a country of mushrooms" might not be all that ridiculous when it comes to describing certain circumstances—like the way that we currently approach cybersecurity, for example. Mushrooms are no doubt a delightful fungus, but there is a saying about them that is often apropos: they are kept in the dark and fed manure.
And that's kind of how we approach cybersecurity, isn't it?
Think about it. We give colossal amounts of personal information to companies. If you shop on Amazon, you've likely handed over your address, phone number, credit card information, email address ... and a record of the kind of things that you like to read. Shop online at Banana Republic? Same information as well as your size and perhaps your preferred style of undergarments. And if any of the systems at these places are breached, we just ... well, what is it that we do, exactly?
Read More14-year-old hacked a car with $15 worth of parts
We denounce Target's massive data breach (more than 100 lawsuits against it) but continue to shop there (3.1 percent increase in profits). Home Depot is breached on a larger scale than Target (56 million credit cards compromised) but sees a 36 percent increase in profits. Anthem suffered the largest breach of all and ... crickets. Globally, cybercrimes cost business between $375 billion and $575 billion, and caused a net loss of 200,000 jobs in the United States alone.
In an Association of Corporate Counsel annual survey, 27 percent of chief legal officers reported that their employers had suffered a data breach; within that total was 50 percent reporting a breach in the health-care sector and 64 percent reporting a breach in larger companies with 100 to 200 employers. But nearly a quarter of these chief legal officers claimed that data breach issues were "not at all important" as a department priority. Who the heck are these folks, anyway?
Heck, we'd never do that with our own personal information. We would certainly take appropriate steps to protect it. Like passwords. We'd obviously use a strong password for our online adventures bank accounts, right? Here is the countdown to 2014's top five most common passwords on the Internet in reverse order: (5) qwerty; (4) 12345678; (3) 12345; (2) password; and (1) 123456. Good grief! Hackers can barely type as their drool puddles up on their keyboards. Is it any wonder that at least 47 percent of American adults had their personal information compromised in 2014?
And then, we continue to innovate in ways that can only create more cyber risks, like with Internet-connected televisions that eyeball you while you are watching them, or Internet-connected cars that can communicate your whereabouts, schedule and open your garage doors remotely. Do you know what your car company is doing to protect your personal information? Your television company? More importantly, do you care? Or did you click on another version of the World's Longest Disclaimer without reading a single word?
Read More This Android update may stop your phone being stolen
Cybersecurity issues are here to stay—in fact, the issues are only going to worsen as we develop more and more connectivity. But chief legal officers are hiding from cybersecurity despite exponentially increasing risks. And people are paying very little attention to who handles their information, how they protect it and what they are using it for, but are content to continue to trade privacy for convenience. So, I guess that makes us mushrooms all around.
And maybe that dress is black and blue after all.
Shamoil T. Shipchandler is a partner at Bracewell & Giuliani LLP, where he handles white-collar criminal matters and cybersecurity. Shamoil was formerly a deputy criminal chief in the U.S. Attorney's Office for the Eastern District of Texas.


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