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Product information "Finished barrel in the white | 6,5x65 | MuD:16.5 mm | L:600 mm | Cr-Moly Steel | ord. nr. 1009"
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Stir yeast in water; let stand 5 to 10 minutes.
Cream butter thoroughly; gradually blend in flour.
Add yeast to butter and flour.
Form dough by teaspoonful into a ball.
Press each ball flat in granulated sugar (sprinkled on foil); first one side, then the other.
Bake on ungreased cookie sheet for 15 to 20 minutes.


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There are eight games tonight on the main NBA slate at FanDuel.
Tonight we have Russell Westbrook ($11,800) taking on the Minnesota Timberwolves and we also have James Harden ($11,700) taking on the Atlanta Hawks. They are the only players on this slate over $10,000 dollars.
Neither of these two have what I would call an "ideal" matchup but the reality is if you want to win tonight you will probably need to roster one if not both of these Fantasy studs to win tonight.
If you are going to roll out these two we are going to need to find some value tonight. Let's see if we can five Saturday night specials and go win some cash with the Flash tonight at FanDuel.
Minnesota Timberwolves PG Kris Dunn ($4900) is running the point for the T-Wolves and is averging 20 FanDuel points for the season and nearly 28 FanDuel points since he became the starter due to an injury to PG Rickey Rubio. The Thunder are allowing PG's to average 49.86 Fantasy points a game this season and Dunn is exactly what we are looking for tonight in salary relief.
Detroit Pistons SG Kentavious Caldwell-Pope ($4800) has a very solid matchup at home against a Denver Nuggets defense allowing SG's to average 41.98 Fantasy points a game. Over his past three games Caldwell-Pope is averaging 31.5 FanDuel points a game. I like the matchup and the price tonight.
Orlando Magic SF Aaron Gordon ($5900) has a interesting home matchup tonight against a Washington Wizards team averaging just 33.84 Fantasy points a game. This will be the Wizards second game of a back to back and its on the road which is always a nice thing to take advantage of. This season Gordon is averaging 26.3 FanDuel points a game for the Magic and has a 32.5 point ceiling. The price is right and the potential is nice to see tonight.
Philadelphia 76ers PF Richaun Holmes ($3800) has an interesting matchup with a Cleveland Cavaliers defense allowing PF's to average 38.34 Fantasy points a game. Holmes has been steady averaging 16.8 FanDuel points a game this season and he won't have to do all that much to make value tonight.
I'm going to stay with the 76ers and look to their young center Joel Embiid ($4800) tonight and his matchup with a Cleveland Cavalier team allowing centers to average 45.46 Fantasy points a game. Embiid is on a minutes restriction and will only play between 20-24 minutes and even with that restriction Embiid and is currently averaging 29.3 FanDuel points. We'll take that and his price all day long and twice on Sunday!


text:
Jared Burton
Recent transplant to DC metro area, originally from the purple mountain majesty of Colorado. Jared chases stories, leads, lore, jokes, anecdotes, and legends—and would love nothing more than to discuss that book, movie, or game you just consumed and loved.
Story Published
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redpajama_set_name: RedPajamaCommonCrawl


text:
Last edited by Dasida
Saturday, August 1, 2020 | History
6 edition of The Historical Atlas of New York City found in the catalog.
A Visual Celebration of Nearly 400 Years of New York City"s History (Historical Atlas)
by Eric Homberger
Published May 15, 1998 by Owl Books .
American history,
Local history,
Places & peoples: general interest,
New York - Local History,
Historical Atlases,
United States - State & Local - Middle Atlantic,
History: American,
Atlases - Historical,
United States - Mid Atlantic - New York City,
History / United States / State & Local,
Atlases - General,
United States - State & Local - General
Contributions Alice Hudson (Illustrator)
The Resource The historical atlas of New York City: a visual celebration of nearly years of New York City's history, Eric Homberger ; Alice Hudson, cartographic consultant. The Historical Atlas of New York City: A Visual Celebration of Years of New York City's History by Dr. Eric Homberger starting at $ The Historical Atlas of New York City: A Visual Celebration of Years of New York City's History has 2 available editions to buy at Half Price Books Marketplace.
Big Deals The Historical Atlas of New York City, Third Edition: A Visual Celebration of Years. COUPON: Rent The Historical Atlas of New York City, Third Edition A Visual Celebration of Years of New York City's History 3rd edition () and save up to 80% on textbook rentals and 90% on used textbooks. Get FREE 7-day instant eTextbook access!
The Historical Atlas of New York City, Third Edition (Paperback) A Visual Celebration of Years of New York City's History. By Eric Homberger. St. Martin's Griffin, , pp. Publication Date: J The Historical Atlas of New York City, third edition, takes us, neighborhood by neighborhood, through four hundred years of Gotham's rich past, describing such crucial events as the city's initial settlement of people in thirty log houses; John Jacob Astor's meteoric rise from humble fur trader to the richest, most powerful man in the city.
On foot in Devon
Organisations, professions and bureaucracies.
St. Louis (Mississippian) oil production in Jasper County, Illinois
world of music
Common Market and economic development
Business programming on your Spectrum
American Catholics and civic engagement
Catalogue of selected compact galaxies and of post-eruptive galaxies.
Developmental Psychopathology, Risk, Disorder, and Adaptation, Volume 3
African socialism.
Men of other planets
The Little Book of Truffles (Little Book of . . .)
Introduction to Indian art
Bert Monroy
The Art of Money
Watermills & windmills
An essay upon the faith of assurance
The Historical Atlas of New York City by Eric Homberger Download PDF EPUB FB2
Now in its third edition, The Historical Atlas of New York City, takes us, neighborhood by neighborhood, through four hundred years of Gotham's rich past, from the city's initial settlement of people in thirty log houses; to John Jacob Astor's meteoric rise from humble fur trader to the richest, most powerful man in the city; the fascinating ethnic mixture that is modern Queens; and the /5(32).
The Historical Atlas of New York City, second edition, takes us, neighborhood by neighborhood, through four hundred years of Gotham's rich past, describing such crucial events as the city's initial settlement of people in thirty log houses; John Jacob Astor's meteoric rise from humble fur trader to the richest, most powerful man in the city Cited by: The Historical Atlas of New York City, second edition, takes us, neighbourhood by neighbourhood, through four hundred years of Gotham's rich past, describing such crucial events as the city's initial settlement of people in thirty log houses; John Jacob Astor's meteoric rise from humble fur trader to the richest most powerful man in the city; and the fascinating ethnic mixture that is /5(50).
A Visual Celebration of Years of New York City's History. Author: Eric Homberger; Publisher: St. Martin's Griffin ISBN: Category: History Page: View: DOWNLOAD NOW» Now in its third edition, The Historical Atlas of New York City, takes us, neighborhood by neighborhood, through four hundred years of Gotham's rich past, from the city's initial settlement of.
"The Historical Atlas of New York City is a full-color visual guide through four hundred years of Gotham's rich past. In this handsome second edition, Eric Homberger describes the city's most pivotal moments, including the initial settlement of people in 30 log houses and the arrival of the United Nations in Turtle Bay inillustrating each with illuminating anecdotes, maps, and graphics.
A New York Public Library Outstanding Reference BookThe rich and eminently browsable visual guide to the history of New York, in an all-new second editionThe Historical Atlas of New York City, second edition, takes us, neighborhood by neighborhood, through four hundred years of Gotham's rich past, describing such crucial events as the city's initial settlement of people in thirty log.
Description of the book "The Historical Atlas of New York City: A Visual Celebration of Nearly Years of New York City's History": The Historical Atlas of New York City, second edition, takes us, neighbourhood by neighbourhood, through four hundred years of Gotham's rich past, describing such crucial events as the city's initial settlement of people in thirty log houses; John Jacob.
Atlases of New York City. Previous; New York City and Vicinity ; Bronx ; Brooklyn ; Manhattan ; Queens ; Staten Island ; Atlas of the city of New York, borough of the Bronx, Annexed district: from actual surveys and official plans [] 52; Atlas of the city of New York: from official records, private plans & actual surveys 1.
Old Historical Atlas Maps of New York. This Historical New York Map Collection are from original copies. Most historical maps of New York were published in atlases and spans over years of growth for the state. Some New York maps years have cities, railroads, P.O.
locations, township outlines, and other features useful to the New York researcher. The New York Times Book Review raved that The Historical Atlas of New York City "may be as close to a printed CD-ROM A visual celebration of nearly years of New York City's history.
To celebrate the one-hundredth anniversay of Greater New York, what Alfred Kazin calls "a treasure of a book" is now a gorgeous paperback/5. Buy The Historical Atlas of New York City: A Visual Celebration of Years of New York City's History 3rd ed. by Homberger, Dr Eric (ISBN: ) from Amazon's Book Store.
Everyday low prices and free delivery on eligible s: New York Harbor. / / / or /. / / / / / / / / / ii / / ii / / / / / Manhattan. 17th century - / / / / 18th century - / / / / / / 19th century - The New York Times Book Review raved that The Historical Atlas of New York City "may be as close to a printed CD-ROM as paper can get." Now, this visual cornucopia of full-color maps, charts, photographs, and drawings covering four hundred years of the city's history is a trade paperback.
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Others are rare antique maps, part of the collection by an exclusive arrangement with the Osher.The Historical Atlas of New York City, second edition, takes us, neighborhood by neighborhood, through four hundred years of Gotham's rich past, describing such crucial events as the city's initial settlement of people in thirty log houses; John Jacob Astor's meteoric rise from humble fur trader to the richest, most powerful man in the city; and the fascinating ethnic mixture that is.
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Aww shucks, they love him. They really love him.
Canadian Traveller magazine recently released a list of their Top 40 Under 40 within the Canadian tourism industry and our very own Adriano Ciotoli has made the list!
"The idea for this initiative came about at a monthly round-table our team hosts with travel professionals representing every sector of the industry," says Terrilyn Kunopaski, Editor-in-Chief for Canadian Traveller.
This is an absolute honour not just for Adriano, but, for WindsorEats as a whole to be recognized at a national level for the work, dedication and determination put into promoting Windsor, Ontario to the rest of the world.
Click here to read the magazine. Adriano can be found on page 11.
If you see him, congratulate him and help us spread the word about how great Windsor-Essex is!


Right-click or ctrl-click on the MacTracker application and select "Show Package Contents."
Open Contents->Resources->iPod and copy "MactrackeriPod.tgz" to the Desktop.
Extract "MactrackeriPod.tgz" (double-click). It will make a folder called "MacTracker" on the Desktop.
Get rid of the first, topmost list (it's just the directory names).
In other words, wherever there is a carriage return, turn it into the HTML for ending a table cell, creating another cell with a [ ] in it (this will be where I put the checkmarks for the machines I have), end THAT cell, end the row, retain the carriage return for readability, start a new row and a new cell.
All the directory names start with ./ (Unix-ese for "in this directory") and end with a colon. They do double-duty here as category names, so we want to boldface them and make them stretch across both columns.
Gets rid of the extra checkbox and turns it into a blank line (empty row) for spacing.
Manual cleanup -- you will have to manually fix the first and last lines of the file, since the first is missing a CR and the last has one too many.
Add opening and closing <table> tags, apply styles as you see fit.
Now you have one loooooong skinny table. To make two columns, simply add an enclosing table with one row and two cells, and put approximately half of the list in each cell.
Now go through and replace the [  ]'s with [✓] -- the HTML entity for a checkmark -- wherever you want to check off an item.
The only bummer here is that the initial list generated by ls -R is in alphabetical order, not in the nice chronological order of the MacTracker interface. Oh well.


Skirt from Y.A.S. A-line design. Elastic at waist. One pocket at each side. Lined.Made of 100% Suede..
Five pocket jeans from Pieces. Tight, stretchy fit. Tapered, raw-edged hems. Belt loops at waist.Mad..
Sweatshirt from Polo Ralph Lauren. Long-sleeved design. Rounded neckline. Print at front. Ribbed nec..


Want to lose weight but get bored at the gym? Maybe Zumba is the solution to your fitness problems. More and more people are joining Zumba every day to shed those annoying pounds. Don't worry about embarrassing yourself, or not having any rhythm. Zumba is all about having fun while working out and just moving. Even those who hate working out find themselves working up a sweat and having fun while taking zumba.
Even though zumba is the new craze, it has actually been around since the mid 90's. Zumba fitness has exploded and is quickly becoming one of the most sought after and most profitable fitness classes in the world, with more than 10 million American women making use of it. There is nothing like getting in shape and having fun while doing it. Zumba is actually a workout program that combines Latin tempos and simple to follow moves into an extremely fun work out for folks of every age and all fitness levels. The dance steps in zumba are inspired by a wide array of musical influences including all the popular salsa, merengue, mambo, samba, belly dancing, hip hop, tango, and those are to name just a few! Zumba has been the talk of the fitness industry when it comes to burning calories; it has been said to burn between 500-800 calories a class!!
Zumba may be the health and fitness phenomenon taking over the country. Zumba brand has released its own DVD's, CD's, and Wii game at home; but nothing beats the excitement and energy of a real live class. So are you ready to have some fun? Come shimmy off the pounds, and experience the excitement for yourself with one of our Zumba classes. All class schedules are posted on our website (MeiFitness.com).


The UX & Web Design team at HardScrabble is collaborating with the Wintergreen Community Arts Center to offer KidzCode beginning September 17, 2018.
KidzCode introduces children to coding fun! We explore computer programming concepts with a different theme each week. Lessons include plugged and unplugged activities that reinforce abstract coding concepts.
"It adds amazing things to the kids who are already coming and will bring a whole new demographic into Wintergreen," Hutchins said.
Additionally, KidzCode/Scratch will be offered by HardScrabble Solutions Founder, Lillie Lavado, through the SAD1 Adult & Community Education department beginning October 2, 2018. This KidzCode series will primarily use Massachusetts Institute of Technology drag-and-drop programming software. Students in grades 4-6 are welcome to enroll for the eight-week session. Only $45!
The HardScrabble team is offering several other computer technology courses through SAD1 this Fall. The roster includes: SmartPhone Basics, Computer Basics, Facebook for Fun, Facebook for Business, and Microsoft Office.
KidzCode Afterschool Arts at Wintergreen follows a different schedule. Grades K-3 meet Tuesdays and Thursdays, 3:00 pm to 5:00 pm; Grades 4-8 meet Mondays and Wednesdays, 3:00 pm to 5:00 pm. Only $50 per 6-Week Session!


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Home>CBD News>The US Government Secretly Illegalized Delta-8 THC
The US Government Secretly Illegalized Delta-8 THC
CBD Nerd CBD News Comments Off on The US Government Secretly Illegalized Delta-8 THC 304 Views
If you've been following along, you already know that delta-8 THC has been creating a bit of a legal conundrum in the United States, with lots of ideas about it flying from every corner, but very little to back anything up officially. A recent article published a story that got very little coverage, but which makes things clear (even if the article writers got it wrong). The US federal government added delta-8 THC to its list of Controlled Substances, quietly, but officially, illegalizing it.
Editor's Note: Delta-8 THC may have been added to the DEA's Controlled Substances list, however, the federal government has not enforced this change, yet. As a result, Delta-8 is still available for sale, and should be for quite some time. This is great for you if you're looking to buy anything delta-8 related. The government can take a long time to respond, and this means you still get access to your favorite delta-8 THC products.
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A little backstory
For those following along, you already know. However, if you haven't been, here's a little backstory on the whole fiasco, and how the US government is dealing with delta-8 THC. First and foremost, what is the stuff?
Delta-8 is a naturally occurring isomer and analogue of delta-9 THC, the THC generally associated with the cannabis plant. Its an isomer because it has the exact same chemical structure, but with a slightly different configuration of atoms, and its an analogue because it's structurally and functionally almost identical to delta-9. By naturally occurring, it means delta-8 can be seen in nature. This is because, when delta-9 comes into contact with oxygen, it oxidizes, or loses electrons, to form a more stable compound.
This more stable compound is nearly identical except for one thing, the placement of a double carbon bond. In delta-9 THC it sits on the 9th carbon atom in the chain, in delta-8, on the 8th. The reason delta-8 became a topic of conversation is due to the 2018 US Farm Bill, and a perceived loophole to sell legal THC. The Farm Bill legalized the cultivation of hemp, and production of hemp products, so long as THC levels (specifically delta-9 and its precursor THCA), do not exceed more than .3% in dry weight from the original plant. It was later clarified that this .3% has to be maintained all throughout processing, with any elevated level constituting a break with the law. It applies to the final product as well.
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While the law technically defines the THC as delta-9 THC, this doesn't preclude delta-8. And the reason for that, is that delta-8 THC is an analogue of delta-9, and analogues were never covered under the definition of 'hemp'. Analogues are federally illegal if they are analogues of a federally illegal drug, due to the 1986 Controlled Substances Analogue Act. Delta-9 is illegalized as a Schedule I drug according to the 1970 Controlled Substances Act, and between the two laws, delta-8 is included.
The other thing specifically not covered under the definition of 'hemp' is synthetics, and this is the other issue with the delta-8 loophole. Delta-8 does occur naturally, but it oxidizes so slowly from delta-9, that in order to use it for products, it must be processed with human help. This means it's not simply being extracted, but actually synthesized to a degree, and that effects the definition of what's going on.
If human processing help constitutes creating a synthetic, then delta-8 can't be legal. If it being able to occur naturally in nature maintains it as non-synthetic, then this would not apply. The main issue with counting it as a synthetic, is that then it calls into question the safety of processing methods, which without a structure of regulation, leaves consumers at the mercy of producers who want to make a buck. No one is saying that delta-8 itself is dangerous, and in fact, everything (except possible processing techniques) points to it being one of the better versions of cannabis.
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US government response to delta-8 on the state level
Confusion has abounded on this since the US government came out with the Farm Bill, which brought delta-8 to light. First the government put out the DEA Interim Final Rule, followed by the USDA Final Rule, neither of which clarified if human processing help constitutes a synthetic, but both repeating that synthetics remain schedule I illegal substances, regardless of the definition of hemp.
Local governments have been more willing to make bigger statements. So far, 13 states have made laws to ban delta-8 THC: Alaska, Arizona, Arkansas, Colorado, Delaware, Idaho, Iowa, Mississippi, Montana, Rhode Island, Utah, and Vermont. The reason cited by state governments, is that delta-8 must be synthesized. They go on to talk about how this creates danger, exemplified by Colorado's Health Department, which made this statement, backing up the idea of delta-8 as a synthetic:
"…chemically modifying or converting any naturally occurring cannabinoids from industrial hemp is non-compliant with the statutory definition of 'industrial hemp product'… Insufficient evidence exists to determine whether or not any toxic or otherwise harmful substances are produced during these reactions and may remain in the regulated industrial hemp products ingested or applied/used by consumers… Therefore, these tetrahydrocannabinol isomers are not allowed in food, dietary supplements or cosmetics."
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Did the US Government Secretly Illegalized Delta-8 THC?
US federal government response to delta-8
It feels like the US federal government didn't do anything, or at least, not anything that made a lot of headlines. The DEA and USDA didn't give a definition for what constitutes synthetic, only reiterating that synthetics are illegal. It also made no official move to ban, or back up a ban, of the compound. Not arresting producers or suppliers, not stopping businesses, and not rounding up and arresting buyers. In that way, the US federal government has done absolutely nothing about it. Which is probably why individual states have.
But the government DID do something, and it wasn't a small something. A recent article (one of two to mention it at all) reported how the DEA updated its Orange Book on May 10th to include delta-8 THC under Controlled Substances, as a different name for tetrahydrocannabinols. Tetrahydrocannabinols are illegal, as per the laws and regulations mentioned previously.
What is the 'Orange Book', and what does this all mean? The Orange Book, officially known as Approved Drug Products with Therapeutic Equivalence Evaluations, is a publication put out by the FDA (not the DEA) which identifies products based on safety and effectiveness, with FDA approval. It also has therapeutic equivalence evaluations for generic drugs, and patent lists for drugs. What it doesn't have, is a controlled substances list, or any mention of delta-8 THC. The Controlled Substances list is under the DEA, but it has never been identified as the 'Orange Book'.
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What the article writer did get right (amongst a large amount of misinformation), is that the name 'delta-8 THC' now resides on page 17 of the DEA's Controlled Substances list as another name for tetrahydrocannabinols, regulated by Criminal Code 7370, ending any discussion about legality. As a note, the criminal code only uses the word 'tetrahydrocannabinols', however the Controlled Substances list, which also references relevant criminal codes, has the updated terms that can count for tetrahydrocannabinols. The article writer who wrote about this, seems to be extremely confused about the two separate publications by the two separate government agencies, applying details about the Orange Book, unnecessarily to the Controlled Substances list.
The Orange Book, for example, is not law, but merely advice to drug prescribers. The Controlled Substances list is law. By confusing the two, the author made it sound like the addition of delta-8 THC to the Controlled Substances list, is only advice, when in fact, it is law. Whether this was done out of misunderstanding, or for any other reason is hard to say. What isn't hard to say, is that the US federal government made delta-8 THC illegal.
I can't verify the date delta-8 was added – as no official statement was made. It might have happened sometime in April, as referenced by this article a month ago, which looks to be the first mention of the update. (The update can be seen in the May Department of Justice List of Scheduling Actions, Controlled Substances, Regulated Chemicals, where it shows up on pages: 8, 10 and 17.) The article I just mentioned, was written by the same lawyer who was quoted in the first article I sourced on the topic. To be clear, this lawyer also confused the FDA and the DEA, and suggested that the Controlled Substances list isn't law, and that producers and vendors aren't committing a federal crime. To me, this is very dangerous reporting. The real question now, why was it done so quietly?
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This took place last month, and until I checked the lists myself, I didn't know. No announcement was made, no press statement, and no articles written about it, other than the two I sourced, which got all the information wrong. Was it kept quiet because the US government doesn't plan to do anything about it? Or are there about to be some arrests made? It has now become a prosecutable crime to make delta-8 or sell it, as delta-8 is now a Schedule I controlled substance. The fact it was done so quietly, with such bad reporting, is unfortunate, but it doesn't change certain things.
Cannabis is going in the direction of complete legality. It's also incredibly expensive to fight drug wars. And this particular drug issue doesn't have a death count to spur on the public. It would likely be a losing battle to go after the whole industry, but that doesn't mean that isolated producers and vendors won't feel the burn. It remains to be seen how the US government will handle this, but it already started it in a strange way, by adding to the Controlled Substances list, while making absolutely no public announcement about it. Interested, or cynical, parties should check the attached links to verify this for themselves.
Not all news makes it to the news. And not all news stories are written well. For whatever reason the US government illegalized delta-8 THC without saying anything, or that two news stories appeared with very obviously wrong information about it, it looks like the truth of it will take some time to make the rounds. But, at least there is finally an answer to a question that has caused much confusion.
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By adding delta-8 THC to the Controlled Substances list (check page 17), as an alternate name for tetrahydrocannabinols, the US government put delta-8 THC under regulation of criminal code 7370, making delta-8 fall in line with delta-9 THC, being 100% federally illegal, except for that which fits under the definition of hemp. If someone has a question or concern about this information, please check the attached Controlled Substances list, criminal code 7370, and the other legal documentation attached for verification.
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How do I identify the null pointer exception in completable future?
I have a completable future code which throws NPE. I am unable to reproduce the exception in my local.
I have tried acceptance test and unit test for the code but it's not giving the exact error response.
Browse other questions tagged rest spring-boot asynchronous java-11 completable-future or ask your own question.
Map exception in completable future to a different exception type?
How can I test exception in completable future?
Scala Futures: How to guarantee a non-null result?
Is there a way to delay the execution of the completable future?
How to handle error responses from in any step of a completable future chain?


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EPR Spectroscopic Studies of the Active Sites of Some Heme- and Copper-Containing, Oxygen-Binding Proteins
Morse, Randall Heywood (1981) EPR Spectroscopic Studies of the Active Sites of Some Heme- and Copper-Containing, Oxygen-Binding Proteins. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/7cva-0k93. https://resolver.caltech.edu/CaltechTHESIS:03132018-112023831
All oxygen-utilizing proteins contain copper, iron, or both, at the oxygen-bonding sites. The ligand environment and geometry about the metal centers in these proteins must be crucial in determining their individual functions. This thesis reports studies in which the ligand nitric oxide is used as a spin probe to investigate the structure of the oxygen-binding sites of myoglobin and some inorganic heme analogues, and of tree and fungal laccase and cytochrome c oxidase.
Nitric oxide reacts with heme iron in ferrous hemeproteins such as hemoglobin and myoglobin, to form six-coordinate paramagnetic complexes. Chapter II reports investigations on the EPR spectra of the nitric oxide complexes of ferrous myoglobin, cytochrome c, and Fe(II) protoporphyrin IX-imidazole, which change with temperature over the range 30-180 K. This temperature dependence could be due to motional/relaxation effects or to a chemical equilibrium. To resolve this matter, the technique of factor analysis was used to deconvolute the temperature-dependent EPR spectra. By this method it has been found that all of the spectra for any given complex can be reproduced by adding together varied amounts of two signals, demonstrating that the variation of the EPR spectra with temperature is due to an equilibrium between two species. The two species differ in enthalpy by no more than about 2 kcal/mol. The observed signals are interpreted as arising from two six-coordinate conformers of the nitrosylheme∙nitrogen base complexes, differing primarily in the position of the iron with respect to the ligands and to the heme plane. The anomalous behavior of the terminal respiratory enzyme cytochrome c oxidase, which exhibits only one EPR signal independent of temperature, suggests that the NO-oxygen may interact with the cuprous ion at the cytochrome a3-Cua3 site of the enzyme. These results have implications for studies in general on oxygen-carrying proteins.
In addition to being a strong-field ligand, NO is also a reactive molecule which can be oxidized to NO-2 and NO-3, and reduced to N2O, N2 and NH3. Chapter III details investigations of the reactions of NO with the copper-containing oxidases tree and fungal laccase, as well as with tree laccase depleted in type 2 copper. The oxidation states of the enzymes were monitored by EPR and optical spectroscopy, and the reaction products of NO were determined by NMR and mass spectroscopy. These studies show that NO reduces all three copper sites of fungal laccase. In addition, NO forms a specific complex with the reduced type 2 copper. NO similarly reduces all of the copper sites in tree laccase, but it also oxidizes the reduced sites produced by ascorbate or NO reduction. A catalytic cycle is set up in which N2O, NO-2 and various forms of the enzyme are produced. On freezing of fully reduced tree laccase in the presence of NO, the type 1 copper becomes reoxidized. This reaction does not occur with the enzyme depleted in type 1 copper, suggesting that it involves intramolecular electron transfer from the type 1 copper to NO bound to the type 2 copper. When the half-oxidized tree laccase is formed in the presence of NO, a population of molecules exists which exhibits a type 3 EPR signal. A triplet EPR signal is also seen in the same preparation, and is attributed to a population of the enzyme molecules in which NO is bound to the reduced copper of a half-oxidized type 3 copper site. The implications of these results towards the structures of tree and fungal laccase are discussed.
Nitric oxide has also been used to probe the structure of the metal centers of cytochrome c oxidase, resulting in the discovery of three stable conformations of the oxidized enzyme [G. W. Brudvig, T. H. Stevens, R. H. Morse and S. I. Chan (1981) Biochemistry 20, in press]. These conformat1onsdiffer in the structure of the cytochrome a3-Cua3 site, which is the site of oxygen reduction, and are distinguishable by EPR spectroscopy. Two of the diagnostic EPR signals are unusual in that they cannot be interpreted simply in terms of normal Cu(II) or Fe(III) EPR signals. The "g5" conformation identified as a transient species occurring upon reoxidation of the reduced enzyme by O2 [R. W. Shaw, R. E. Hansen and H. Beinert (1978) J. Biol. Chem. 253, 6637-6640] similarly exhibits an EPR signal not subject to simple interpretation. In view of the complexity of these three EPR signals, they are most likely due to the coupled cytochrome a3+3-Cua3+2 site of the oxidized enzyme. Chapter IV describes calculations of the energy levels of, and allowed EPR transitions from, the cytochrome a3-Cua3 site under various conditions of exchange coupling and dipolar coupling, as a function of other parameters such as the magnitude of the rhombic zero-field splitting of the heme iron and distance between the two metal ions. On the basis of these calculations, one of the three unusual EPR signals from oxidized cytochrome c oxidase is deduced to arise from a strongly exchange-coupled (|J| > 200 cm-1) cytochrome a3+3-Cua3+2 site, one from a weakly exchange-coupled (|J| > 0.25 cm-1) cytochrome a3+3-Cua3+2 site, and one from an admixture of S = 5/2 and S = 3/2 states of the cytochrome a3+3 site.
Roberts, John D.
Chan, Sunney I. (chair)
Goddard, William A., III
10.7907/7cva-0k93
Mel Ray


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Editors' note: This is the second in a series of respectful conversations about Amherst issues from two different points of view. Click here to read Part 1.
By Meg Gage and Andy Churchill
Andy: Well, some people never learn! Here we are again, taking another whack at our different opinions about Amherst's downtown. I understand you actually lived downtown as a child, up through your high school graduation. What was that like?
Meg: Yes, but I'm not into glorifying my Amherst childhood. Sometimes it seems there's some merit in having been around a long time, some kind of extra credit. That's not my thing.
Andy: Aw, c'mon – how about doing it in a nice, Amherst-y, non-competitive way?
Photo credit Sarah Marshall
Meg: Well, OK. Here's a quick memory of growing up on North Pleasant Street. We lived across from the Dairy Queen that was next to the Mobil station, where Zanna is now. On summer evenings I'd look across the street from my bedroom window at the college students sitting on the hoods of their cars, eating ice cream cones together. I thought that was the most wonderful thing a college student could do. But it turned out as a Brandeis student I wasn't the sort to sit on a car hood eating ice cream!
Andy: Wow – a Dairy Queen downtown – I could go for that. I might even sit on a car hood!
Meg: Another memory is of the White sisters, two elderly women who lived across the street, just about where 1 East Pleasant is now. They were the first Amherst girls to have bicycles and were quick to share with pride a framed newspaper article with a picture of them in bloomers with their bikes. Really dating myself here!
Andy: Great memories. And, of course, you've seen a lot of change since then. I wonder, does that make you in some way resistant to development downtown? I get the sense that some folks on "your side" are nostalgic for simpler times, when UMass was smaller, there was a grocery store downtown, etc. So, they are reflexively against more change, regardless of potential benefits of downtown vibrancy and revenues to support town services.
Meg: Indeed, I've seen a lot of change. But I am not particularly nostalgic for those days, and there were some not-so-great things, particularly related to gender and race. I'm not at all against change, and frankly, I can't think of anyone I know who opposes all change. Nothing stays the same, and change is an opportunity to make things better, in my opinion. (BTW, there were TWO grocery stores downtown; Louis was where the CVS is now, and across the street, next to the Unitarian Church, was the A&P. There were two shoe stores, Bowles and Mathews, and a hardware store. Also, a drugstore with a soda fountain where Subway is now!)
Meg's childhood home; Photo credit Sarah Marshall
Andy: Well, Amherst certainly has changed since then!
Meg: The big catalyst for the very rapid change that came to Amherst in the 1960s was the rapid expansion of the UMass student body, from 7,600 in 1963 to over 23,000 undergrads and 4,500 graduate students in 1970. Before then, there was no Echo Hill, no Amherst Woods, no residential areas to the east and west of East Pleasant Street.
Andy: So, whole new family neighborhoods sprang up, presumably to accommodate faculty and staff supporting all those new students. And the malls and supermarkets weren't in place on Route 9 yet. Once those arrived, the old stores downtown couldn't compete, I guess. And then, more recently, the big box stores sealed the deal.
Meg: One of the big mistakes Amherst made back then, IMHO, was to zone the big box stores out of Amherst rather than creating terms for them to be built in Amherst, with design standards for signage, scale, set-backs, etc. Perhaps they could have been built along what is now University Drive – or any number of other places away from the center of town. Amherst has always been the customer base for the malls in Hadley, so near the Amherst line. What a shame we don't reap the tax benefits! An example of Amherst not adapting to changing circumstances.
Andy: So downtown Amherst evolved. It came to feature more restaurants, bars, and small, boutique-style retail, with a smattering of offices and apartments in those buildings that had upstairs space. The recent Archipelago buildings by Kendrick Park have added some housing to the mix. So, the question now is: What's next?
Meg: Yes, exactly! Let's do "what's next," with a plan! I am very enthusiastic about the Business Improvement District's interest in developing the arts in downtown Amherst. The benefits of what has become known as the Creative Economy are well established – creative arts as a magnifier of economic success. It is an evolving concept focused on the relationship between creativity, business, technology, ideas and the arts. North Adams is one of the best examples around. In 1991, before MASS MoCA was established, North Adams had an unemployment rate of almost 13 percent. In November 2019 (just before Covid), it was 3 percent. Granted, many of the new jobs were in the service sector, but they were jobs that weren't there before.
Andy: I would add, there's also room for more people living and working downtown, to provide ready customers for downtown establishments and tax revenues for our town's infrastructure. But that will require more development, more densification of the downtown with housing and office space, as our master plan suggests.
Meg: Sounds good, Andy, but I don't see many people moving into the new apartment buildings who work downtown. They are mostly students.
Andy: Do you actually know that? I don't, and I'm not sure it matters that much. It's not like the new buildings are fraternities! More people living downtown is a good thing for the vibrancy of downtown and for tax revenue. We live in a college town; we need to get used to having college students in it, maybe even (gasp) see that as a benefit! More taxable rental units for students would generate more revenues for the town. They don't all have to be downtown, though – maybe more development on Olympia Drive, or a "student village" approach to University Drive. A topic for another column!
Meg: I enjoy living around college students – although I can do without the Blarney Blowout! And housing is a fine idea, but what kind of housing and for whom and where? I'm sounding like a stuck record, but all this needs to be based on a plan! Ideally, Amherst's new housing would help people in Amherst acquire wealth – one of my big disappointments of building so much rental housing. Rental housing is extractive and profits only the owners and builders – no one else is gaining wealth.
Andy: So, would you prefer condos downtown? Not sure those would be accessible to people without wealth in the first place. And what's to prevent rich parents from buying them for their college kids? I hear you, but not everyone wants to buy property and be chained to it that way. There is a place for rental units, and for more office space. I agree with your point about needing a plan, though.
Meg: BTW, it may surprise you that I am a big fan of the master plan. I wish the Town were using it as more of a guide than it seems to me is the case. My other gripe about our recent development (and some not so recent) downtown is the architecture of the new buildings. We desperately need design standards that encourage attractive buildings that support a lively downtown.
Photo by Kane Reinholdtsen on Unsplash
Andy: I agree – we need design standards to guide development, technically known as "form-based code." Interestingly, Northampton has just started a process of public discussion about it. And a few years ago, Amherst actually had a form-based code proposal on the table. It would have set design guardrails for the town – and likely prevented the most complained-about aspects of the new buildings. Unfortunately, as you know, Town Meeting voted it down.
Meg: I actually voted for the form-based code proposal in Town Meeting and agree we should look at it again. But back then, it had both technical and emotional aspects and a perceived lack of transparency on the part of the Town that made it difficult to get a two-thirds majority in Town Meeting. Form-based design is perhaps a topic for another column, but at this point I'd rather look forward than backward. It's way past time to stop bashing Town Meeting!!
Andy: In its later years, Town Meeting richly earned any bashing it gets, most egregiously by voting down the elementary school project (a project I know we both supported).
Meg: Andy, the school vote was more complicated. A majority of Town Meeting supported the school proposal, but state law required two-thirds support. Can we agree it is time to stop bashing – and praising – Town Meeting?
Andy: I will say that Town Meeting is now irrelevant, and I'm glad that it is. But I do think we need to continue to take some lessons from that experience, in which a minority of townspeople decided they knew best, overstepped their role (which was simply to approve the borrowing based on whether the Town could afford the project), and used a variety of insider techniques to frustrate the will of the majority. I worry that we haven't seen the last of that I-know-best approach, which makes it hard for people to trust each other enough to come together on a generally accepted vision for moving forward.
Screen shot of website designed by Anser Advisory Management, LLC
Meg: Well, I hope we can build more trust through better communication, and develop a plan for the future that does have broad support. Thinking about the elementary school situation, I am impressed with how hard the new Elementary School Building Committee and School Committee are working to build trust and transparency and to listen to people's concerns and wishes for the new school, early in the process and continuously as the process advances. I think people feeling they've been heard and their ideas considered goes a long way toward people accepting change, even if their ideas are not followed.
Andy: How about for the next part of this discussion we get more specific about future design standards? Let's take our readers on a virtual walk downtown. What aspects do we like, and want to see more of? What elements would we prefer to never see again?
Meg: Great idea! See you on the sidewalk!
In Part 3 of "A civil conversation," Meg and Andy will walk around downtown Amherst and exchange views on the buildings.
Posted on March 7, 2022 March 9, 2022 Author The Amherst CurrentCategories Business, Development & Housing, Zoning
5 thoughts on "A civil conversation, Part 2"
Pingback: Opinion: A Civil Conversation, Part 2 - Amherst Indy
Matthew Blumenfeld says:
It is terrific to have our very own Gail Collins and Brett Stephens debate, and I really appreciate Meg and Andy for their willingness to engage.
The spirit of this dialogue is so spot on. We are, in many ways, all on the same Amherst team, and there is space to vigorously disagree and still stay teammates.
Thank you Meg, Andy and Amherst Current.
Richard B. Morse says:
Well, I still think it's worth asking just what is it in our specific political culture in Amherst that is so damned self-destructive, since it might be living on here beyond Town Meeting. All the beneficial changes that Meg cites that did not happen, the forks in the road where we took the path of less development, or simply decided to do nothing, came about through political decisions at key moments. We do not have form-based zoning, even though there seems to be agreement NOW that we should.
Jonathan Tucker says:
A great conversation that raised a lot of necessary issues.
Downtown residential uses, for instance. From the age of about 2 until age 6, my parents, my two siblings and I lived in a second floor apartment in a house owned by the Tufts family on North Prospect Street. The edges of downtown Amherst were already filled with apartment uses, and had been since the mid-19th century. I don't remember going downtown much, but I remember Mr. Tufts, who was very kind, and would crack pecans and walnuts for my brother and myself on a splitting stump in his barn/garage out back. He had his office in that building, and once showed me a boxed set of fancy Colt revolvers that he said had belonged to President Chester Arthur, who he claimed was a distant relative. We moved to former farmscape South Amherst when I was 6 and my world changed.
Downtown Architecture – The new downtown buildings are examples of what might be called Pacific Rim architecture using indigenous New England materials. It is a perfectly valid architectural choice for downtown Amherst, a sentiment with which the Design Review Board, the Amherst Historical Commission, and the Planning Board all agreed. Until the new wooden building behind the former (and much-lamented) Judie's was built, downtown Amherst had not seen a new building in 30 years. If you were to survey and document the architecture of downtown buildings (something that has been done at least twice–check with the Planning Department), you would find a highly diverse range of architectural periods and styles represented in downtown buildings. The fact that people are so used to looking at them that they no longer really see them does not mean those buildings were all designed to be compatible or even vaguely similar, except in terms of materials and scale, characteristics that were dictated more by building technology and period economics than by aesthetics.
One of my favorites is the Richardsonian Romanesque Town Hall, a building whose scale and architecture were bitterly fought over at the time (look it up). It was, of course, something new for Amherst, and a wee bit more prominent and grand than some citizens felt was necessary (they put Austin Dickinson on the building committee, what did they expect?). The new Town Hall caused no end of distress among those who found change too uncomfortable. Quite aside from the need for all communities to allow themselves to grow and change, the architecture of a given downtown does not belong solely to those for whom it is long familiar, particularly as we reach into our sixth and seventh decades. Our communities increasingly belong to our children and grandchildren and new incoming residents, who may have–and are allowed to have–their own entirely different vision for their community. Hanging on to a specific narrow vision of our surroundings for our own comfort for too long is not at all the same as appreciating architectural history. With all respect, it is closer to a form of group pathology.
Finally, in the interest of amity, I will restrain myself and only echo Andy's comment that by its last two decades, Amherst's representative Town Meeting had richly earned whatever bashing citizens cared to direct its way, then or now. However, I agree with Meg that rehashing those issues does not get the community any further forward.
Steve Schreiber says:
Northampton is looking at Amherst–those Archipelago buildings!—for examples of good downtown development. ( see page 35)
http://archive.northamptonma.gov/WebLink/ElectronicFile.aspx?docid=599233&dbid=0&repo=CityOfNorthampton
Previous Previous post: Designing for education
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An account called Hen Broon added: "Anas, you are not successful as a politician because you are a sly, devious liar who plays the race card.
But before anyone plays the race card, let's take a look at what actually happened, and at those who were involved in the violence.
Now, however, when she will actually have consequences for her actions, she plays the race card and attacks the police officer in the face of numerous videotapes and an unbiased witness.


Before sowing any seeds I first fill some 7cm (3in) square pots with finely sieved soil-less multipurpose compost. I then lightly firm down the soil before watering it with a can fitted with a fine rose until the pots are fully charged with water. I leave them to stand for an hour to drain. As already mentioned, begonia seed is very fine and needs light to germinate, so the seed must be sown evenly over the surface of the compost and must not be covered with any more compost or vermiculite.


text:
Back to former Florida governors
Gov. Daniel Thomas McCarty
Terms January 6, 1953 - September 28, 1953
Party Democratic
Birth State Florida
School University of Florida
Family Married Ollie Brown; three children
Status Died in office
Military Service Army
Awards Bronze Star, Purple Heart, Legion of Merit, Croix de Guerre
DANIEL THOMAS MCCARTY, Florida's 31st Governor, was born in Fort Pierce, Florida, on January 18, 1912. He attended Florida's public school system and in 1934 graduated from the University of Florida. After finishing his education, McCarty became a cattleman and citrus grower in Fort Pierce. During World War II, he served in the U.S. Army, was promoted to the rank of Colonel, and was decorated with the Bronze Star, the Purple Heart, the Legion of Merit, and the French Croix de Guerre. McCarty entered politics as a member of the Florida House of Representatives, a position he held from 1937 to 1941. He also served as speaker of the house in 1941. He ran unsuccessfully for the governor's office in 1948, but five years later was victorious and became Governor of Florida. During his tenure, educational scholarships for future teachers were established, the road department was restructured, teacher salaries were increased, aid programs for the disabled were created, and a primary state construction plan was initiated. Early in his term, McCarty experienced a heart attack and subsequently passed away on September 28, 1953. Governor Daniel T. McCarty is buried at the Palms Cemetery near Ankona, Florida.
Florida State Archives holds the official papers of Governor Daniel T. McCarty.
S. 569 Governor Daniel T. McCarty, Correspondence, 1953-1955
Museum of Florida History: Florida Governors' Portraits
Current Florida Governor
Recent Florida Governors
Gov. Rick Scott
Gov. Charlie Crist
Gov. Jeb Bush
Gov. Kenneth Hood Mackay
Gov. Lawton Chiles
Gov. Robert Martinez
Gov. Daniel Robert Graham
Gov. Reubin O'Donovan Askew
Gov. Claude Roy Kirk
Gov. Haydon Burns


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text:
E. R. Cobb Elementary School memorabilia
Collection — Box: SC
University of Minnesota Duluth Archives and Special Collections
The collection consists of the program issued on the occasion of the formal re-opening of E.R. Cobb School, May 29, 1919, and a photo of the school.
E. R. Cobb Elementary School (Duluth, Minn.) (Organization)
Duluth (Minn.) Public Schools (Organization)
Open for use in the Kathryn A. Martin Library, Archives and Special Collections.
Cobb Elementary School was located at 110 W Redwing St. in Duluth, Minnesota. The school was built in 1913 and opened in January, 1914. An addition to the building was started in 1918. Cobb School was gutted by fire during the 1918 forest fire. The school was rebuilt and reopened in January, 1919.
E.R. Cobb was a member of the Duluth Board of Education for eighteen years and was a resident of the Woodland neighborhood where the school was located.
This collection is located at the University of Minnesota Duluth Archives. For more information about this collection or to make an appointment, contact us at libarchives@d.umn.edu or 218-726-8526.
This collection is part of the Northeast Minnesota Historical Collections, which are housed in the University of Minnesota Duluth Archives at the Kathryn A. Martin Library.
Duluth Public Schools (Duluth, Minn.)
Elementary school students Subject Source: Library of Congress Subject Headings
Elementary schools Subject Source: Library of Congress Subject Headings
Families Subject Source: Library of Congress Subject Headings
Teachers Subject Source: Library of Congress Subject Headings
Woodland (Duluth, Minn.) Subject Source: Local sources
Guide to the E. R. Cobb Elementary School memorabilia
Finding Aid Authors: Staff.
Box: SC (Mixed Materials)
Contact The University of Minnesota Duluth Archives and Special Collections Collecting Area
https://lib.d.umn.edu/research-collections/archives
Kathryn A. Martin Library
University of Minnesota Duluth
416 Library Drive
libarchives@d.umn.edu
E. R. Cobb Elementary School memorabilia, S2259, Northeast Minnesota Historical Collections, Archives and Special Collections, Martin Library, University of Minnesota Duluth.
E. R. Cobb Elementary School memorabilia, S2259, Northeast Minnesota Historical Collections, Archives and Special Collections, Martin Library, University of Minnesota Duluth. https://archives.lib.umn.edu/repositories/22/resources/8233 Accessed January 31, 2023.


text:
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The term "campus carry" refers to the licensed, concealed carry of handguns on college campuses. The key words there are "licensed" and "concealed." There is no movement to let everybody carry guns on campus or to let licensees carry visible handguns—aka "open carry"—on campus.
Even in gun-loving Texas, less than 4% of the population is licensed to carry a handgun. Among Texans of typical college age, the rate is less than 1%. Those license holders, age 21 and above, have passed a training course, a shooting test, and extensive background checks and are authorized to carry guns virtually everywhere else, including at college parties, which almost always take place off campus.
Campus carry is about personal protection, not campus protection. The question isn't whether it lowers on-campus crime rates or serves as a deterrent to crime; the question is whether there is justification to deny licensees on campus the same measure of self-defense they enjoy at movie theaters, shopping malls, churches, and museums. The question is whether there is a fundamental difference between carrying a gun at a municipal library and carrying a gun at a university library.
The preponderance of peer-reviewed studies on licensed carry have concluded that it cannot be shown to lead to an increase in violent crime. Furthermore, there is little or no evidence that it negatively impacts free speech in the places where it's allowed, including more than 100 U.S. college campuses and several state capitols.
Put simply, the evidence strongly suggests that licensed concealed carry will have no detrimental effect on Texas college campuses and that there is no justification to deny licensed students, faculty, staff, or guests on those campuses the same measure of personal protection they enjoy throughout the rest of the state.


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