These Guidelines define the scope, parameters and conditions for the effective application of the method nonexplosive destruction of oversized blocks, mass foundation, brick treasure, concrete and reinforced concrete structures. They contain regulatory requirements and recommendations for nonexplosive destruction of buildings in various conditions.
Recommendations developed by summarizing the experience of testing and use in the mining and construction business of physical explosions.
1.1. nonexplosive method is intended for destruction of objects in crowded conditions, ie in existing shops, near buildings, highways, industrial communications, settlements, etc.
1.2. process has full security to the environment, as destruction process does not cause noise, is not accompanied by seismic vibrations, emissions of solid or gaseous products. The method does not require any type of energy (either electrical or pneumatic).
1.3. non-explosive compounds are useful where it is impossible to use explosives.
The main application of the method is the loosening of the bases and cutting oversized blocks, demolition of buildings and structures in the physical liquidation of mines associated with the restructuring of the coal industry of Ukraine.
The method can also be used to eliminate some of the monolithic concrete and reinforced concrete structures in mining and civil engineering, as well as other industries, such as steel mills.
2. General characteristics of the material and the principle of destructive action.
2.1. Modern technology nonexplosive damage foundations, masonry and other concrete and reinforced concrete structures based on the use of modified quicklime. By co-grinding calcine calcium carbonate and modifiers are non-explosive destructive materials containing calcium oxide in the range of 65 to 90 .. 95% by weight.
2.3. non-explosive when mixed with water, destroying the material, a mixture (suspension), which, when filled in partially or completely closed cavity (eg, hole) in any object, gradually, as a result of hydration powder hardens and increases in the volume. The amount of water in the powder NRW -80 should not exceed 30 ... 35%. Otherwise, the expansion pressure drops. The increase is accompanied by development pressure from 50 to 150 MPa on the walls of the hole, the value of which depends on the content in the powder CaO. In the body of the destroyed object develop stress values ??may exceed its maximum tensile strength, which leads to the destruction of the object. The effect of destruction is expressed in the formation of cracks in the body of the object with their development over time.
2.4. Usually cracking occurs depending on the temperature of the object and its characteristics in the range of 12 to 20 hours. The higher tensile strength, the longer the cracking. Raising the temperature of the object speeds up the formation of cracks.
2.5. temperature gauging water HPB-80 in the summer should be (depending on the temperature of the destroyed object) from 10 to 20 degrees Celsius in the winter - from 20 to 50 degrees Celsius.
2.6. powder NRW Store in a dry place on wooden pallets at temperatures above 20 degrees Celsius. Shelf life - 6 months.
3. The main parameters of the technology by expanding non-explosive destruction of the object materials.
3.1. destroys the object must have a parallel to the holes at least two open surface (the best option contains a demand for freedom of all four sides of the object in that direction).
3.2. blasthole spacing should be 200 ... 500 mm. The main characteristics of the destroyed object to be considered when designing schemes hole drilling are: tensile strength of the material parameters of the object and its reinforcement. And the number of holes will be smaller, the larger the size of parts (units) formed in the destruction of the object, namely, manual disassembly lumpiness destroyed object should be less than for a showdown with the use of machinery. Reducing the distance between blast holes accelerates destruction of the object, but it causes an increased flow of powder. In all cases, the distance of the holes to the exposed surface should be less than the distance between the bore-hole.
3.3. blast holes should be placed in a line parallel to the exposed surface. If the surface of the object is such that at a time is not reached its full destruction, it is necessary to make the second cycle of destruction in compliance with all requirements under the scheme arrangement of holes.
3.4. larger hole depth and diameter, the greater the pressure developed extensions. Based on the practice rational hole depth should be 90 ... 95% of the planned depth of the destroyed object.
3.5. blasthole drill recommended diameter 25 ... 40 mm (when using a 40 mm diameter holes increases the probability of spontaneous emission of the material from the hole).
3.6. expanding non-explosive material consumption per 1 m of the hole diameter of 32 mm is 1.5 kg and 40 mm - 2.0 kg. Specific consumption of non-explosive material should be assumed to be 8.0 ... 16.7 kg / m 3 of the destroyed object. With the destruction of concrete structures flow must be increased by 30%.
3.7. If the object is characterized by high water absorption, the boreholes before filling in the mixture to saturate with water or an aqueous solution of surface - active agents (surfactants), ie 0.1% - aqueous wetting dB, which is widely used in coal mines. For this all boreholes filled with liquid to the mouth for 30 minutes, after which the liquid is removed from the hole with compressed air or other means, and themselves filled boreholes after working mixture. Aqueous solutions of surface - active substances (surfactants) should be preferred to the water for the following reasons: under the influence of the surfactant changes the mechanical properties of materials, which is due to reduced surface free energy and, therefore, reducing the work required to increase the cracking (surface) SAW getting into the area of ??micro-cracks due to the reduction of surface energy facilitates the development of micro-cracks in the crack fracture.
3.8. blast holes are filled with a mixture of working to the mouth. After pouring the mixture of working to protect the mouth of the holes from the action of water (eg, rain) and shielded from direct sunlight, heating.
3.9. recommended even after the appearance of hairline cracks, water the object water or aqueous surfactant. Spraying water, especially an aqueous solution of surfactant to the surface of the object being destroyed in the area of ??cracking (humidification zone) helps to increase the width.
4. Conditions and parameters of the effective application of quick-stemming from plaster.
4.2. Reactive tamping made of gypsum (TU-21-39-10-82). Gypsum binder or simply cast a white powder in bulk density of 1.18 ... 1.20 t / m 3 , and Cured 1.62 ... 1.66 t/m3. Optimum water content in the solution is 30 ... 31% of the dry weight. In this case, the setting starts at 6 ... 7 min., And ends at 27 ... 30 minutes. At the specified water content in plaster solution compressive strength is: 30 minutes. - 6.0 ... 7.0 MPa after 60 min. - Up to 11.0 MPa. Gypsum has the ability to slightly - to expand 1% hydration.
4.3. Equipment gypsum tamping should be made of polyethylene thickness of about 0.1 mm or paper GOST (66-62-53) with the number of turns equal to two just before the destruction of the object or centralized. Filled envelope must be delivered to the place of use in corrugated cardboard or wooden boxes, paper or plastic bags. While tamping in paper envelopes should be further put in plastic bags.
4.4. Reactive stemming from plaster should be stored in dry, specially designated place. To do this, the car is allowed to use, safe, container. Allowable storage time tamping one month.
4.5. before using fosfogipsovaya tamping should be saturated with water. For this purpose, the cover is punctured it, that is, on the surface of the hole formation. The distance between the holes for tamping, made in a paper envelope, should be less than 20 mm and the number of holes at least 0.2 units / cm 2 . Perforated shell immersed in water and allowed to stand 1.0 ... 2.0 min. End of water saturation is determined to stop the release of air bubbles from the water. After that, the shell is removed from the container and placed at the face on a piece of board or cut where they are for 30-40 seconds. During this time, excess water remaining on the surface and inside the shell, time to flow. Perforation shells filled with plaster can be made in the manufacturing process, in storage or prior to use.
4.6. Each shell with plaster, placed in the hole must be thoroughly crushed and drowned in it.
4.7. Number of shells with gypsum placed in one hole should be determined empirically, depending on the intensity and the probability of spontaneous emission of the alleged non-explosive material from the hole. Ease of crushing shells in the hole, and even saturation of gypsum water is ensured by the perforation on its surface. In all cases, the length of the self-hardening tamping should be 5 ... 10% of the length of the hole.
4.8. When applying inclined (60 0 to the horizon) or vertical boreholes allowed gypsum powder to put in the hole (on the surface of the non-explosive material in bulk form, and then adding to it (by gravity) of the appropriate amount of water.
4.9. allowed to use alabaster tamping, tamping or cement with liquid glass, made at the site of works in accordance with building nomes.
4.1. Procedure for destruction of the object.
The most labor-intensive work in the complex, is mainly determined by the duration, cost and unit labor costs destruction 1m 3 of the object is to drill holes.
5.2.1. Drilling holes in the object by means of drills. Working tool punch are different types of crowns.
5.2.2. Drilling holes optimal diameter (32 ... 40 mm) should be applied crowns special purpose for the holes diameter 42 ... 43 mm - crowns used during the horizontal and sloping mountain workings in the coal mines, 52 ... 53 mm - Crown, used in vertical shafts.
5.3. Preparing the mix and filling her holes.
5.3.2. Preparing the mix is ??as follows. In a bucket poured, for example, 2 liters of water and 150 ... 200 ml of plasticizer. Then slowly pour the bucket 6 kg powder working intensively stirring the mixture with a stick or hand mixer. Mixing leads to mass produce a good yield, with no visible lumps. Mixing time weight is less than 5 ... 8 min.
Keep in mind that the higher the temperature of the object, the cooler should be water for mixing the powder. At low (below 0 0 C) temperatures of the object should use the hot (up to +50 0 C) water.
increasing water content in the working mixture to slow the process of the formation of cracks in the destruction of the object and reduces the probability of spontaneous emission of the material from the hole.
- in contact with skin or eyes, rinse with abundant water is the place.
Beware of imitations! Beware of imitations! Beware of imitations! Beware of imitations!


The OED defines Arboretum as "A place devoted to the cultivation and exhibition of rare trees: a botanical tree garden".
Following the Second World War, students from the Forestry Commission's training school based in Lynford Hall commenced planting species, primarily of interest to commercial forestry, but also other types of trees to see how they fair in Breckland conditions. The site chosen was part of the Victorian, and earlier, parkland which surrounds the Hall. Initially the Commission's arboretum was confined between Lynford road and the old water tower, this was extended south to the lake and in the early 1980's, east to the boundary of the military training area.
Planting continued until the 1990's, and then in 2006 the Commission asked Friends of Thetford Forest to undertake the basic care of the arboretum. As a response to this request, in February 2007, the FoTF Lynford Arboretum was formed. The group's purpose is to nurture and improve the shrub layer, plant young specimen trees and foster the tranquillity of the place. As with most things in life other things emerge; the whole area teams with wildlife and effort is now being directed to sustain and enhance this. The Forestry Commission is also charged with assisting in the nation's efforts to counteract the affect of climate change. To this end it is looking to its arboreta for answers, though with trees this will take a lifetime or two. Lynford is the most easterly of the Commission's nine arboreta with the driest of conditions; it also has one of the least fertile soils, consequentially it is seen as ideal place to gauge the changes which may occur. Increasingly young trees are being sent to Lynford for planting out to assess their potential; these are being grown from seed collected from around the world, at the National Pinetum at Bedgebury in Kent.
FoTF Lynford Arboretum meets between 4 and 6 times a month on Wednesdays and Sundays. The schedule for 2016 is can be viewed here, and we invite FoTF members to assist in this project. If you are interested in becoming involved with this project, (gardening on a rather grand scale), please contact FoTF by email lynfordarboretum@fotf.org.uk.


text:
San Giovanni in Marignano (Sin Giàn o San Zvan en dialecte romagnol) est une commune italienne de la province de Rimini dans la région Émilie-Romagne en Italie.

Géographie
San Giovanni se trouve à l'entrée de la vallée du torrent Conca et à quelques kilomètres des plages de Cattolica et de la riviera romagnole. Située à 29 mètres d'altitude environ, sur la route provinciale SP17 qui mène de Cattolica () à  Morciano di Romagna ().
La commune est reliée, comme Cattolica, directement à l'autoroute italienne A14 et à la route nationale SS16 de Ravenne à Pesaro, en passant par Rimini ().

Histoire
Les anciennes fortifications (piazza Silvagni) témoignent de l'importance du bourg et du pays à l'époque des Malatesta. De sa proximité avec Rimini lui occasionne tous les aléas de l'histoire qu'a connu la province, principalement entre les familles régnantes, l'église et l'état pontifical, les vénitiens, les armées napoléoniennes, Garibaldi et la position de la commune sur la ligne gotique durant la seconde guerre mondiale.
À la suite d'une émigration massive d'après guerre, l'économie reprit de l'essor dans les années 1950 par le développement du tourisme balnéaire.

Économie
Depuis ses origines médiévales le pays, situé sur des zones alluvionnaires très fertiles de la vallée du Conca, était considéré comme le "grenier des Malatesta". Cette qualité est toujours exploitée aujourd'hui, principalement pour la cultures des céréales et de la vigne.
San Giovanni est aussi connu pour son artisanat relatif à la mode et sa proximité d'avec la côte Adriatique a favorisé l'essor de chantiers navals.

Administration

Hameaux
Santa Maria in Pietrafitta, Montalbano, Pianventena

Communes limitrophes
Cattolica, Gradara, Misano Adriatico, Morciano di Romagna, Saludecio, San Clemente, Tavullia

Population

Évolution de la population en janvier de chaque année

Ethnies et minorités étrangères
Selon les données de l'Institut national de statistique (ISTAT) au  la population étrangère résidente était de 663 personnes.
Les nationalités majoritairement représentatives étaient :

Fêtes et évènements
La fête de Sainte Lucie : foire agricole.
La Festa delle Streghe ou fête des sorcières, en juin : ancien mythe médiéval de magie noire et de sorcellerie dédié principalement au tourisme.
Fête annuelle du vin.
Marché d'antiquaire et vide-grenier, le quatrième dimanche de chaque mois.

Notes et références

Articles connexes
 Communes de la province de Rimini
 Province de Rimini
 Romagne (Italie)
 Émilie-Romagne
 Riviera romagnole

Liens externes
 site de la commune
 Histoire de San Giovanni

Commune dans la province de Rimini
Localité adhérant à l'association I Borghi più belli d'Italia

redpajama_set_name: RedPajamaWikipedia


text:
using System.Collections.Generic;
using System.IO;
using HydrantWiki.Daos;
using HydrantWiki.Interfaces;
using HydrantWiki.Objects;
using LiteDB;
using HydrantWiki.Constants;

namespace HydrantWiki.Managers
{
    public class HWManager
    {
        private static HWManager m_Manager;

        private LiteDatabase m_Database;
        private string m_DataFolder;
        private string m_DatabaseFile;

        private IPlatformManager m_PlatformManager;
        private ApiManager m_ApiManager;
        private SettingManager m_SettingManager;

        private HWManager()
        {
            m_ApiManager = new ApiManager(this);
            m_SettingManager = new SettingManager(this);

            m_DataFolder = HydrantWikiApp.DataFolder;
            m_DatabaseFile = Path.Combine(m_DataFolder, "HWMobile.db");
            m_Database = new LiteDatabase(m_DatabaseFile);
        }

        public static HWManager GetInstance()
        {
            if (m_Manager == null)
            {
                m_Manager = new HWManager();
            }

            return m_Manager;
        }

        public LiteDatabase Database
        {
            get
            {
                return m_Database;
            }
        }

        public IPlatformManager PlatformManager
        {
            get
            {
                return m_PlatformManager;
            }

            internal set
            {
                m_PlatformManager = value;
            }
        }

        public ApiManager ApiManager
        {
            get
            {
                return m_ApiManager;
            }
        }

        public SettingManager SettingManager
        {
            get
            {
                return m_SettingManager;
            }
        }

        public bool AreUserCredentialsCached()
        {
            string username = m_SettingManager.GetUsername();
            string authToken = m_SettingManager.GetAuthToken();

            if (string.IsNullOrWhiteSpace(username)
                || string.IsNullOrWhiteSpace(authToken))
            {
                return false;
            }

            return true;
        }

        public bool Login(string email, string password)
        {
            User user = m_ApiManager.Authenticate(email, password);

            if (user != null)
            {
                m_SettingManager.SetUser(user);
                HydrantWikiApp.User = user;

                ApiManager.Log(LogLevels.Info,
                               string.Format("Login by {0}", HydrantWikiApp.User.Username));

                return true;
            } else {
                return false;
            }
        }

        #region Tags
        public void Persist(Tag _tag)
        {
            TagDao dao = new TagDao(m_Database);
            dao.Persist(_tag);
        }

        public List<Tag> GetRecentTags()
        {
            TagDao dao = new TagDao(m_Database);
            return dao.GetRecent();
        }

        public List<Tag> GetTagsNotSentToServer()
        {
            TagDao dao = new TagDao(m_Database);
            return dao.GetNotSentToServer();
        }

        #endregion

    }
}

redpajama_set_name: RedPajamaGithub


Considering the interest that several people have expressed to us, we send information about the possibility of making bank transfers in favor of the victims of the tornado in Havana.
INFORMATION REQUIRED TO MAKE TRANSFERS FROM ABROAD TO THE DONATION ACCOUNT FOR AID TO VICTIMS OF THE TORNADO THAT HIT HAVANA.
If it's material donations, we mean that the sender must be in a position to assume the transportation costs to Havana and before sending it, he must send a written communication to the Embassy, in order to make the customs procedures possible in advance.
We thank the Habaneros and especially the affected families for the solidarity we have received.


A personal touch can make your marketing materials stand out from the crowd, which is the effect our direct mail personalisation services are designed to help you achieve. Personalisation includes both the marketing materials themselves and the envelopes, allowing you to alter your messaging for specific groups of people as needed.
Our facilities mean that we can manage the full creative process of printing and executing your direct mail campaign, which means that personalisation is much easier for us than it would be for a supplier who's only involved for part of the process. In addition, because we work with our clients to understand the goals of their campaigns, we know exactly what they're trying to achieve and can do our bit to ensure that the personalisation involved is serving the right purpose.
By extending our personalisation services to envelopes and polywrapping, we can be sure that every element of your mail campaign is consistent in its messaging and quality. When your target audience receives these fully-personalised materials, the potential impact will be much greater than if they see something that's clearly been sent out in bulk. Personalisation tells them that you've considered their needs and requirements and that you'll value them as a customer, which are important signals to send to people who may otherwise be on the fence about buying from or working with you.
If you want more information about exactly how our personalisation services could fit into the campaign that you have in mind, get in touch with us today. One of our dedicated account managers will speak with you and be able to talk through your questions and the considerations that go into a successful print campaign.


text:
And that's how it's done
This is the body positive reason why Vanessa Hudgens won't wear a shirt when she works out
You know that phrase, "when you got it, flaunt it?" Well, Vanessa Hudgens totally has it. In fact, Hudgens won't wear a shirt while working out — but it's not to show off.
The Powerless actress is Women's Health magazine's May cover star and with her rocking abs and healthy lifestyle, she totally deserves it. In her interview with the magazine, Hudgens revealed that she always works out in just a sports bra, and it's not because she's trying to show off her killer bod.
"I don't like to wear T-shirts when I work out because it's better motivation when I can see my body," Hudgens told Women's Health.
Okay, this is actually a brilliant idea. It seems like a knee-jerk reaction to just opt for a baggy tee when cycling or running, but we like Hudgens' style. She is so body positive, and we're now totally inspired. Show off your body, do you! Never be ashamed of whatever state your body is in.
While she doesn't rock a sports bra for the attention, she has been photographed wearing one. And those abs, well, they speak for themselves.
"I saw that picture," she explained. "I was like, 'Whoa! I'm impressed!'"
So how does the 28-year-old star get into shape and keep herself healthy and fit? Yoga, lots and lots of yoga.
"I don't consider it fitness," Hudgens says about her three-times-a-week routine. "It's more like therapy for me."
She dedicated herself to yoga after playing Agnes "Apple" Bailey in Gimme Shelter, which she had to gain weight for, and it clearly worked.
"I looked in the mirror and was like, 'Who am I?' It was definitely a journey back to myself, and yoga helped," she revealed.
When the High School Musical alum isn't doing yoga, she's all about SoulCycle. "It's like dancing without the stress of worrying if you look good," she admitted.
Whatever Hudgens is doing, clearly it's working. The best part, however, is the positive body image mentality she's putting out there. It's awesome.
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redpajama_set_name: RedPajamaCommonCrawl


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text:
1 Samuel, Chapter 13
More Chapters From 1 Samuel
(1) Saul reigned one year; and when he had reigned two years over Israel,	(2) Saul chose him three thousand men of Israel; whereof two thousand were with Saul in Michmash and in mount Bethel, and a thousand were with Jonathan in Gibeah of Benjamin: and the rest of the people he sent every man to his tent.	(3) And Jonathan smote the garrison of the Philistines that was in Geba, and the Philistines heard of it. And Saul blew the trumpet throughout all the land, saying, Let the Hebrews hear.	(4) And all Israel heard say that Saul had smitten a garrison of the Philistines, and that Israel also was had in abomination with the Philistines. And the people were called together after Saul to Gilgal.	(5) And the Philistines gathered themselves together to fight with Israel, thirty thousand chariots, and six thousand horsemen, and people as the sand which is on the sea shore in multitude: and they came up, and pitched in Michmash, eastward from Bethaven.	(6) When the men of Israel saw that they were in a strait, (for the people were distressed,) then the people did hide themselves in caves, and in thickets, and in rocks, and in high places, and in pits.	(7) And some of the Hebrews went over Jordan to the land of Gad and Gilead. As for Saul, he was yet in Gilgal, and all the people followed him trembling.	(8) And he tarried seven days, according to the set time that Samuel had appointed: but Samuel came not to Gilgal; and the people were scattered from him.	(9) And Saul said, Bring hither a burnt offering to me, and peace offerings. And he offered the burnt offering.	(10) And it came to pass, that as soon as he had made an end of offering the burnt offering, behold, Samuel came; and Saul went out to meet him, that he might salute him.	(11) And Samuel said, What hast thou done? And Saul said, Because I saw that the people were scattered from me, and that thou camest not within the days appointed, and that the Philistines gathered themselves together at Michmash;	(12) Therefore said I, The Philistines will come down now upon me to Gilgal, and I have not made supplication unto the LORD: I forced myself therefore, and offered a burnt offering.	(13) And Samuel said to Saul, Thou hast done foolishly: thou hast not kept the commandment of the LORD thy God, which he commanded thee: for now would the LORD have established thy kingdom upon Israel for ever.	(14) But now thy kingdom shall not continue: the LORD hath sought him a man after his own heart, and the LORD hath commanded him to be captain over his people, because thou hast not kept that which the LORD commanded thee.	(15) And Samuel arose, and gat him up from Gilgal unto Gibeah of Benjamin. And Saul numbered the people that were present with him, about six hundred men.	(16) And Saul, and Jonathan his son, and the people that were present with them, abode in Gibeah of Benjamin: but the Philistines encamped in Michmash.	(17) And the spoilers came out of the camp of the Philistines in three companies: one company turned unto the way that leadeth to Ophrah, unto the land of Shual:	(18) And another company turned the way to Bethhoron: and another company turned to the way of the border that looketh to the valley of Zeboim toward the wilderness.	(19) Now there was no smith found throughout all the land of Israel: for the Philistines said, Lest the Hebrews make them swords or spears:	(20) But all the Israelites went down to the Philistines, to sharpen every man his share, and his coulter, and his axe, and his mattock.	(21) Yet they had a file for the mattocks, and for the coulters, and for the forks, and for the axes, and to sharpen the goads.	(22) So it came to pass in the day of battle, that there was neither sword nor spear found in the hand of any of the people that were with Saul and Jonathan: but with Saul and with Jonathan his son was there found.	(23) And the garrison of the Philistines went out to the passage of Michmash.
The Promises To Our Lord To Saint Margaret Mary In Favor Of Those Devoted To The Sacred Heart.
I will give them all the graces necessary in their state of life. I will establish peace in their houses. I will comfort them in all their afflictions. I will be their secure refuge during life and, above all, in death. I will bestow a large blessing upon all their undertakings. Sinners shall find in my Heart the source and the infinite ocean of mercy. Tepid souls shall grow fervent. Fervent souls shall quickly mount to high perfection. I will bless every place where a picture of My Sacred Heart shall be set up and honored. I will give to Priest the gift of touching the most hardened hearts. Those who shall promote this devotion shall have their names written in My Heart, never to be blotted out. I promise You in the excessive mercy of My Heart that My all-powerful love will grant to all those who communicate on the First Friday of nine consecutive months the grace of final penitence; they shall not die in my displeasure nor without receiving the Sacraments; My Divine Heart shall be their safe refuge in this last moment. (this prayer is optional and may be said after all Glory Be to the Fathers while reciting the Rosary.....) O my Jesus, have mercy on us. Forgive us our sins. Save us from the fires of hell. Take all souls into heaven, especially, those most in need of thy mercy. Amen.


text:
Home › Harassment
St Catherine's College is committed to equal opportunities, and aims to provide an environment in which all students, employees, contractors, and visitors are treated with dignity and respect, and in which they can work and study free from any type of discrimination, harassment, or victimisation.
This section outlines the College's policy on harassment and – through links on the right hand side of this page – provides guidance for anyone who believes they are or have been the subject of harassment. Please note that wherever harassment is referred to below this should be taken to include bullying, which is a form of harassing behaviour.
Information concerning allegations of harassment should be treated in the strictest confidence. Breaches of confidentiality may give rise to disciplinary action.
All staff and students are responsible for upholding this policy and should act in accordance with the policy guidance in the course of their day-to-day work or study, ensuring an environment in which the dignity of other staff, students, and visitors is respected. Offensive behaviour will not be tolerated.
Harassment is a serious offence which is punishable under the College's disciplinary procedures.
Heads of department and their equivalents, those with significant supervisory duties, and others in positions of responsibility or seniority, including students who fall into these categories, have specific responsibilities. These include setting a good personal example, making it clear that harassment will not be tolerated, being familiar with, explaining, and offering guidance on this policy and the consequences of breaching it, investigating reports of harassment, taking corrective action if appropriate, and ensuring that victimisation does not occur as a result of a complaint. Instances of harassment should be brought to the attention of an appropriate person in authority, such as a head of department or a senior college officer.
Staff should also bring to the attention of their head of department any form of harassment or victimisation committed by third parties using College facilities (e.g. conference delegates, contractors, etc).
St Catherine's is committed to promoting awareness and understanding of this policy (and the accompanying guidance) amongst staff and students, and has therefore made this information available via its website.
The policy will form a part of every employment and student contract, and/ or relationship, and/ or contract for services. The College will endeavour to encourage a culture of non-tolerance of any form of harassment.
This policy and the accompanying guidance, which should be read in conjunction with the College's Equal Opportunity Policy and Race Equality Policy, will be the subject of regular review by the Governing Body in consultation with other appropriate committees, including the Equality Committee.
Defining harassment
Harassment FAQs


A new concealed carry seminar is set to take place for residents of the the 88th and 92nd legislative districts in Pennsylvania.
A new concealed carry seminar is set to take place for residents of the the 88th and 92nd legislative districts in Pennsylvania. It will be hosted by State Representatives Sheryl Delozier, R-Lower Allen Township, and Mike Regan, R-Dillsburg from 10 a.m. to noon Saturday, Sept. 13, at Christ Community Church, 1201 Slate Hill Road, Lower Allen Township.
According to the Sentinel, attendees will learn about Pennsylvania's concealed carry laws, as well as how to interact with law enforcement while carrying a concealed handgun. Matthew D. Menges of Trinity Law P.C. is scheduled to speak at the seminar, and a local law enforcement officer will be on hand to provide information and answer any questions you may have.
If you live in the 88th district, which includes Lower Allen Township, Monroe Township, Upper Allen Township, Lemoyne, Mechanicsburg, New Cumberland, Shiremanstown and precinct 1 of Wormleysburg, the Sentinel advises that you register with Delozier by filling out a form on www.repdelozier.com or by calling her district office at 717-761-4665.
Residents of the 92nd district, including South Middleton Township, Mount Holly Springs, Fairview Township, Dillsburg, Carroll Township and other parts of northern York County, can register with Regan by calling his district office at 717-432-0792, the Sentinel reported.
A Portland, Tennessee homeowner used his personal firearm to stop an intruder on his property.


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While the president celebrated the holidays at the White House, he apparently received some holiday greetings, and apparently they weren't all of the family-photo variety. Among the letters and cards, Russian President Vladimir Putin's Christmas message to President Donald Trump says he's open to talks, confirming his stance after a hiccup in their last scheduled meeting. The message strikes a similar tone as previous outreach by Putin toward the American president.
Trump was one of several former and current world leaders to receive a holiday greeting from Putin, including Chinese President Xi Jinping, British Prime Minister Theresa May, and Syrian President Bashar Al-Assad, per The New York Post. Elite Daily reached out to the White House for comment on the letter to Trump, but did not receive a response at time of publication. Differing translations of the same letter are in circulation, with the Post providing a slightly different interpretation.
The U.S. president spent the winter holidays holed up in the White House, per reports, after canceling his planned trip to his Mar-a-Lago resort in Florida with his family amid pushback about the government shutdown.
The greeting from the Kremlin comes a month after Trump had abruptly cancelled his scheduled meeting with Putin at the G20 Summit in November, citing a Russian takeover of Ukrainian war ships as the reason. However, on the same day, Nov. 29, the president's former attorney Michael Cohen pleaded guilty to lying to Congress about the timeline of the Trump Tower Moscow project and his own connections with Russian officials. Despite the cancellation, Putin, in his annual year-end press conference on Dec. 20, expressed a willingness to hold another meeting with Trump. He added, however, that it was unclear whether that would come to pass as a Democrat-controlled House of Representatives takes power in the new year.
"On multiple occasions I've said I am willing to meet, we have a number of issues to discuss, including our bilateral agenda," said Putin on Dec. 20 according to CNN. "Of course, now power in the Congress is changing and I'm sure that there will be more attacks on the president. Whether or not he will be able to have direct dialogue with Russia as a result of that, I don't know."
It also follows on the heels of a report from U.S. officials that Russia had tried to influence the 2018 midterm elections, as well as the release of a Senate report suggesting a wide scope of alleged Russian efforts to influence American voters on social media.
Putin's mention in the letter of ensuring international security is likely a reference to Russia's involvement in the Syrian war. Trump abruptly announced on Dec. 20 he'd be pulling U.S. troops from the region, a decision that was followed by the resignation of former Defense Secretary Jim Mattis. The decision was controversial in part because of the suddenness with which it was executed, and because it went against the stances American diplomatic and military officials had expressed to U.S. allies.
[S]erious global and regional challenges, which our countries have had to face in recent years, show that relations between Russia and the U.S. remain an important factor in ensuring stability and security of the modern world. I hope that after you assume the position of the President of the United States of America, we will be able — by acting in a constructive and pragmatic manner — to take real steps to restore the framework of bilateral cooperation in different areas as well as bring our level of collaboration on the international scene to a qualitatively new level.
It's not clear if or when Trump might agree to hold another talk with the Russian president, but it's apparent from this letter that at least one of the two sides is interested.


Ercel has been working as a General Practitioner in Sydney for over 12 years after graduating from Sydney University Medical School in 1999. As a GP, he aims is to provide compassionate, wholistic and long term care to his patients focusing on health as a concept that goes beyond the physical and encompasses psychological and social well being.
His professional interests include general medicine, psychiatry, children's health, management of a HIV and other sexually transmitted infections.
Personally, he is a keen chef at home and a student of Spanish language.


Combination issues. This author has combination issues that need to be cleared up.
Carole McGlynn is currently considered a "single author." If one or more works are by a distinct, homonymous authors, go ahead and split the author.
Carole McGlynn is composed of 3 names. You can examine and separate out names.


Happy weekend – not sure about you, but I'm real glad for it. This week was L O N G and I'm a happy camper sitting on my floor in a beanie and crewneck.
Lots of rad stuff on here: Sasha Sloan, Arcade Fire, MUNA, Ry-Lo, Bombay Bicycle Club, Post Malone (!) and some other jams. Listen and you'll see!
Ya know Steve from Stranger Things? Yeah, he's in a band called Post Animal and they're on here. Also, Gallant and Andra Day have this amazing cover of Cruisin' you gotta hear if you haven't already.
That's about all I have for words right now. Bye.


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KIDNAPPED - Forced to be involved in things not of one`s choosing that are forced upon the person by outside circumstances.
KILL&MURDER - You kill: You are fighting back against your fear or desire to eliminate something from your life. You are killed: You are removed from your emotions and feelings caused by the situation you are in.
KISSING - Someone you like and want: wish fulfillment. A faceless person: your basic desire being met. Someone you know casually and not romantically: recognition of harmonious vibrations. A celebrity: trying to boost your self worth. Adulterous passionate overtones: If you already have a mate, it may be time to spice up the romance. If you don`t, its wish fulfillment.
KNOCK - Loud knock on a door: You are becoming aware of spiritual truths and are reaching a new level of understanding. You are aware of certain spiritual powers that you have.
KETTLE - Kettles symbolize your heart, circulatory system and emotions due to the fact that they are used when sharing tea and coffee with visitors. Jug kettles are a particularly strong symbol because of their heart shape. Anything to do with sharing implies your heart.
KEY - Keys symbolize solutions to a problem and knowledge.
KITCHEN - A kitchen symbolizes your digestive system as it is a place where we prepare and eat food. It is probably the most common symbol used in dreams to indicate the digestive system. Many appliances and items in the kitchen indicate various parts of the digestive system. The state of the kitchen shows the state of your digestive system. If the room is moldy, it indicates that mould is growing inside your colon. If plaster or wall paper is falling off the walls, it indicates that the lining of your intestines is damaged.
A kitchen table is also about your digestive system.
Kitchen walls indicate the walls of your intestines. If the paper or plaster is falling off the walls it indicates the lining of your intestines is damaged.
Since most days start in your kitchen it can also symbolize facing the day or your outlook on the day.
KNIFE - A knife in dreams symbolizes anger. An angry person is said to be cutting.
KING - Respect, promotion, gain.


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text:
package sangria.benchmarks

import org.openjdk.jmh.annotations._
import sangria.util.StringUtil

@State(Scope.Thread)
class StringUtilBenchmark {
  @Param(Array("empty input", "empty options", "abc", "description", "length"))
  var testCase: String = _

  var input: String = _
  var options: Seq[String] = _
  var expected: Seq[String] = _

  @Setup
  def setup(): Unit =
    testCase match {
      case "empty input" =>
        input = ""
        options = Seq("ab", "e")
        expected = Seq("e")
      case "empty options" =>
        input = "abc"
        options = Nil
        expected = Nil
      case "abc" =>
        input = "abc"
        options = Seq("a", "ab", "abc")
        expected = Seq("abc", "ab")
      case "description" =>
        input = "descritpion"
        options = "description" :: (1 to 50).map(i => s"ab_$i").toList
        expected = Seq("description")
      case "length" =>
        input = "lenght"
        options = "length" :: (1 to 50).map(i => s"name_$i").toList
        expected = Seq("length")
    }

  @Benchmark
  def benchCurrent(): Unit = {
    val results = StringUtil.suggestionList(input, options)
    assert(results == expected, s"results = $results, expected = $expected")
  }
}


text:
<?php
namespace Thepsion5\Entities\Tests\Traits;

use Thepsion5\Entities\Tests\Stubs\StubEnum;
use Thepsion5\Entities\Tests\TestCase;

class EnumTest extends TestCase
{
    /** @test */
    public function it_can_be_converted_to_an_array()
    {
        $expected = array(
            'ENUM_VALUE_A'   => 1,
            'ENUM_VALUE_B'   => 2,
            'ENUM_VALUE_C'   => 3
        );

        $actual = StubEnum::toArray();

        $this->assertEquals($expected, $actual);
    }

    /**
     * @test
     * @expectedException \InvalidArgumentException
     */
    public function it_throws_an_exception_if_constructed_with_an_undefined_value()
    {
        new StubEnum(4);
    }

    /** @test */
    public function it_checks_to_see_if_it_matches_a_current_label()
    {
        $enum = new StubEnum(1);

        $results = array(
            $enum->is('ENUM_VALUE_A'),
            $enum->is('ENUM_VALUE_B')
        );

        $this->assertTrue($results[0]);
        $this->assertFalse($results[1]);
    }

    /**
     * @test
     * @expectedException \InvalidArgumentException
     */
    public function it_throws_an_exception_if_checked_with_an_invalid_label()
    {
        $enum = new StubEnum(1);
        $enum->is('INVALID_LABEL');
    }

    /** @test */
    public function it_creates_new_instances_if_called_statically_with_label()
    {
        $expectedEnums = array(
            new StubEnum(1),
            new StubEnum(2),
            new StubEnum(3)
        );

        $actualEnums = array(
            StubEnum::ENUM_VALUE_A(),
            StubEnum::ENUM_VALUE_B(),
            StubEnum::ENUM_VALUE_C()
        );

        $this->assertEquals($expectedEnums, $actualEnums);

    }

}


ENROLMENT FOR 2016/17 is now closed.
Thank you to all the schools that have enrolled their Primary 6 pupils to commence the Pope Francis Faith Award in Session 2016 (completing the award in P7 by April 2018). Over 4500 children in 150 schools will participate in the Pope Francis Faith Award across the next two years.
If you would like to enrol for session 2017/18 please revisit this page in May 2017 when the enrolment process will be open again.


text:
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text:
Home | Plugins | Rank Math SEO Review: Light weight SEO Champ
Last Updated on: January 8, 2023 by Bimal Raj Paudel
Rank Math is a popular WordPress plugin that aims to help users improve their website's Search Engine Optimization (SEO). It provides a variety of features that can help users optimize their website's content, structure, and technical SEO.
Some users have reported that Rank Math is easy to use and has helped them improve their website's search engine rankings. It provides a simple interface for setting up and managing SEO-related settings. Rank Math also allows users to customize their titles and meta descriptions, create and edit redirects, and generate rich snippets to improve the appearance of their website in search results. It is designed to be user-friendly and easy to use, with a simple setup process and clear, actionable recommendations for improving a website's SEO.
It also offers features such as keyword optimization and content analysis to help users optimize their website's content for search engines.
However, some users have also reported experiencing issues with Rank Math, such as conflicts with other plugins or problems with the plugin's performance. Additionally, some users have found the plugin to be somewhat resource-intensive, which can impact website performance.
Overall, it appears that Rank Math is a well-regarded SEO plugin that can be helpful for users looking to improve their website's search engine rankings. However, as with any plugin, it is important to thoroughly test and evaluate its performance and compatibility before fully implementing it on your website.
Deal: Get Rank Math Now!
Pros of Rank Math SEO
Free Plugin offers pro features: Even though Rank Math SEO has both free and paid plans; for most of the users the free plan is more than enough as it offers enough SEO features that other SEO plugin include in the paid version.
Easy setup and configuration: Rank Math provides a simple interface for setting up and managing SEO-related settings, including title tags, meta descriptions, and XML sitemaps. The initial setup of the plugin is quite easy as it is categorized into various modes as per the technical difficulty.
Content optimization: Rank Math offers features such as keyword optimization and content analysis to help users optimize their website's content for search engines. It also includes a feature that allows users to set up and manage structured data markup.
SEO analysis: Rank Math provides an SEO analysis tool that allows users to check their website's SEO performance and identify areas for improvement.
Local SEO: Rank Math includes a local SEO module that allows users to optimize their website for local search results.
404 monitoring & redirection: Rank math offers a feature that monitors 404 errors for broken links and helps you redirect them in automatic way. If you change the slug of existing post; using this feature, rank math will automatically redirect the previous URL of the post to the new one.
Content AI: Rank Math Content AI is a feature of the Rank Math WordPress plugin that uses artificial intelligence (AI) to help users optimize their website's content for search engines. It analyzes the content of a website's pages and posts and provides recommendations on how to improve its SEO, such as adding keywords, using header tags, and optimizing images. Rank Math Content AI also suggests related keywords and topics that users can incorporate into their content to make it more relevant and valuable to search engines and users.
Rank Math Content AI is designed to be easy to use and can be accessed from the Rank Math plugin dashboard in the WordPress admin area. Users can choose to optimize their content automatically, using the AI's recommendations, or they can customize the optimization process manually. The goal of Rank Math Content AI is to help users create high-quality, SEO-friendly content that is more likely to rank well in search results and attract traffic to their website.
Rank Tracking: Rank Tracking is a feature of the Rank Math SEO plugin that allows users to track their website's ranking in search engine results pages (SERPs) for specific keywords. This helps users understand how their website is performing in search results and identify opportunities for improvement.
To use Rank Tracking, users need to enter the keywords they want to track into the Rank Math plugin dashboard. The plugin will then monitor the ranking of the website for those keywords on a regular basis and provide updates on the website's performance. Users can see their website's ranking for different keywords over time and compare it to the ranking of other websites.
Rank Tracking can be a useful tool for businesses and individuals who want to monitor their website's performance in search results and make informed decisions about their SEO strategy. It can help users identify which keywords are driving traffic to their website, understand the competitive landscape for those keywords, and optimize their website's content and other factors to improve their ranking in search results.
Sitemap: The Sitemap feature in Rank Math is a tool that allows users to create and manage an XML sitemap for their website. An XML sitemap is a file that lists the URLs on a website, along with additional metadata about each page, such as its importance and how frequently it is updated. An XML sitemap helps search engines discover and index the pages on a website, making it easier for users to find the website in search results.
To use the Sitemap feature in Rank Math, users need to enable it in the plugin's settings and choose the options from pages, posts, categories, tags, authors and much more, they want to include in the sitemap. Rank Math will then generate an XML sitemap for the website and submit it to search engines, such as Google, to help them discover and index the website's content.
The Sitemap feature in Rank Math is an important tool for optimizing a website's visibility in search results and can be particularly useful for websites with a large number of pages or posts, or for websites with a complex structure. By creating and maintaining an up-to-date XML sitemap, users can help search engines discover and index their website's content more effectively and improve its ranking in search results.
Social media integration: Rank Math includes features that allow users to optimize their website's content for social media sharing. It includes options to customize meta title and images for Social Medias.
Multilingual support: Rank Math supports multilingual websites and includes features that allow users to optimize their website's content for different languages.
SEO for WooCommerce: Rank Math includes features specifically designed to help users optimize their WooCommerce stores for search engines.
Import and export: Rank Math allows users to import and export their SEO settings and configurations.
Regular updates: Rank Math is regularly updated to ensure that it remains compatible with the latest versions of WordPress and includes new features and improvements.
Cons of Rank Math SEO
Like any other WordPress plugin, the Rank Math SEO plugin has some limitations and potential drawbacks that users should be aware of. Some possible cons of using Rank Math include:
Limited support: The free version of the plugin does not offer as much support as the paid version. Users may have to rely on the plugin's documentation and online community for help with questions and issues.
Compatibility issues: As with any plugin, Rank Math may not be compatible with all themes and plugins, and users may experience conflicts or other issues when using it with other WordPress plugins or themes.
Risk of over-optimization: It is possible to over-optimize a website for search engines, which can result in poor user experience and may even lead to penalties from search engines. Users of Rank Math should be careful not to rely too heavily on the plugin's recommendations and to consider the needs of their website's users as well as its search engine optimization.
Too many updates: Users of Rank Math SEO have been complaining a lot about its too quick update. Although, you can enable the automatic updates for the plugin, some users feel this quick update troublesome.
Overall, while Rank Math is a powerful and user-friendly SEO plugin, users should be aware of its merits and limitations and consider whether it is the right tool for their needs.
Rank Math is a comprehensive and user-friendly WordPress plugin that helps users optimize their website for search engines. It provides a range of tools and features, including on-page analysis, XML sitemaps, rich snippets, and integration with Google Search Console, to help users improve their website's visibility in search results. Rank Math is regularly updated with new features and improvements and is free to use, making it an affordable and effective option for businesses and individuals looking to improve their website's SEO. However, it may have some limitations in terms of quick updates, compatibility and users should be careful not to over-optimize their website using the recommendations of the plugin.
I have been using Rank Math SEO on WP Tracer and other websites I own. Previously I used to go with other reputed SEO plugin but they were limited on features for a free plugin. Then I shifted to Rank Math SEO and there is no going back. I love how Rank Math has been helping me optimize my SEO easily like a pro. If you are having doubts on choosing from different plugin, go for Rank Math SEO , I bet it will be worth for you.
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Our unique fashion cuff prints coated on the scissor blades. Made from 420 surgical-grade stainless steel. Milled shear serrations. Autoclavable to 143 degrees farenheit or 290 degrees celcius. A portion of the sale of the Hope Pink Ribbons print is donated to the American Cancer Society.


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Arthur Obst (* 26. September 1866 in Wittenberge; † 30. Dezember 1936 in Hamburg) war ein deutscher Lehrer und Journalist.

Leben
Obst besuchte 1876‒86 die Gelehrtenschule des Johanneums und studierte in Tübingen und Berlin Geschichte, klassische Philologie und Philosophie. Er schloss seine Studien mit der Promotion zum Dr. phil. ab. Anschließend war er als Privatlehrer in Hamburg tätig. Ab Juni 1891 leitete er die Redaktion des Cuxhavener Tageblatts und war ab dem 1. Dezember 1892 Mitglied der Redaktion des Hamburger Fremdenblatts. Er war auch Vorsitzender des Verbandes deutscher Journalisten- und Schriftstellervereine.

Werke (Auswahl)
 Verfassungsgeschichte Hamburgs bis zum Jahre 1300

 Die Nachtigall (Märchendichtung nach Andersen), 1894.
 Landen und Stranden, 1904.

Literatur
 Franz Brümmer: Lexikon der deutschen Dichter und Prosaisten vom Beginn des 19. Jahrhunderts bis zur Gegenwart. 6. Auflage. Band 5. Leipzig 1913, S. 168 (Digitalisat).

Weblinks

 Staatsarchiv Hamburg Nachlass 622-2/45

Einzelnachweise

Lehrer
Journalist (Deutschland)
Person (Hamburg)
Deutscher
Geboren 1866
Mann
Gestorben 1936


The charity "Les Apprentis d'Auteuil" develops reception, education, training and integration programs to restore confidence among young people and vulnerable families, while passing on quality knowledge and know-how. More than five thousand families in difficulty are supported each year.
In 2018, the Carrefour Foundation decided to support the vocational school managed by "Les Apprentis d'Auteuil", in the west of Chartres in France. Every year, the vocational school Notre-Dame welcomes young people aged 15 to 19 to various apprenticeship programs, including the bakery sector. The bakery sector aims to prepare students for the CAP Boulanger or the Bac Pro Boulanger-Pâtissier and offers a professional training course, including two months in a company. In order to improve the employability of young people after their exams, the school wanted to set up two complementary training modules. A total of thirteen students received specific training on sandwiches and salty bakery products or a module on specific breads.


text:
Sexual Knowledge
A collaborative research unit investigating the construction and authorisation of sexual knowledge
The Sexual Knowledge unit brings together scholars from across the humanities, social sciences and biomedical sciences at the University of Exeter and beyond who are engaged in research about sex, gender and sexuality and who investigate the construction and authorisation of sexual knowledge. It fosters collaboration with practitioners outside of academia to develop new approaches to sexual health and wellbeing. Building on the international recognition of research activities within the unit, our ambition is to consolidate the University of Exeter as a world leader in interdisciplinary, engaged and applied research on a wide range of issues around sexual knowledge.
Key questions for research within the unit include:
What methodologies are there for studying sex?
What knowledge systems are applied to study of sex?
What variety of evidence is marshalled to document sexuality (e.g. from animal – human comparisons, patient case studies, statistics and surveys, neuroscientific data, cross-cultural comparison or historical material)?
How do different approaches (e.g. literary, medical, anthropological or religious) secure intellectual and cultural authority about sexual knowledge?
How do different forms of sexual knowledge inform practice (e.g. in diagnosis, therapeutic treatment, education, ethics, identity formation or law)?
How are the disciplinary bases and boundaries of such forms of sexual knowledge variously contested?
How have various forms of knowledge about sex evolved within different cultures and contexts?
How can we put disciplinary approaches in dialogue with each other?
How can we use this dialogue to improve health and wellbeing?
The unit is led by a group of scholars working within the humanities (Classics, English and History) with an network of scholars from other disciplines across the University of Exeter. It capitalises on and fosters Exeter's expertise in qualitative, historically sensitive and critical methodologies. Our remit is to explore and interrogate existing concepts and frameworks for understanding sex from cross-cultural and cross-historical perspectives. With collaborators from a variety of disciplines across and beyond the humanities, we aim to develop interdisciplinary frameworks to examine different perspectives on sexual health, sexual knowledge and sexual practices and the agendas that inform them. We will also build on our extensive collaborative work with practitioners outside academia, including doctors, youth workers, educators, charities and community groups.
We are committed above all to:
1) Developing new languages and practices of interdisciplinary collaboration
2) Developing world-leading research in dialogue and through collaboration with the world outside academia
3) Applying our research to address urgent challenges in the contemporary world
Our long-term aim is to build a network of partners across the South West region and beyond, with whom we work to shape the direction of our research and to test and develop the real-world relevance and application of our findings. As such, we aim to break down barriers between academic disciplines and to collapse the distinction between the critical and the applied, research and practice. A key objective is to develop a robust model for collaboration that will enable humanities scholars, social scientists, biomedical researchers and practitioners in clinical and non-clinical settings to find new and productive ways to address jointly the various complex challenges around health and wellbeing facing the modern world.
Find out about the unit directors and research network.
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Finding high-quality flooring at a great value has never been easier thanks to Carpet One near Eastlake. You can count on Carpet One near Eastlake to bring your interior design ideas to life with our expertise and superior selection. Just visit your Carpet One near Eastlake to get started and find out how easy it can be to have beautiful new flooring!


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Is cis-1,2-dimethylcyclohexane a meso compound?
I was watching a video lecture today on hydrocarbons and came across this. The instructor says that, as there is a plane of symmetry, cis-1,2-dimethylcyclohexane is a meso-compound:
However, the cyclohexane ring is never planar as it adopts a chair conformation. I cannot find any plane of symmetry in chair form. Like this:
Is the compound meso or not?
organic-chemistry stereochemistry cyclohexane
cis-1,2-Dimethylcyclohexane is achiral, not because there is a plane of symmetry, but because it consists of two enantiomeric conformations which interconvert rapidly via ring flipping at normal temperatures.
This is exactly the same case as amine inversion. "Chiral nitrogens" such as that in $\ce{NHMeEt}$ do not lead to chirality or optical activity because of rapid inversion of configuration at the nitrogen atom, leading to interconversion of the two enantiomeric forms 1a and 1b.
Likewise, the ring flip in cis-1,2-dimethylcyclohexane leads to two different conformers. I have deliberately chosen to depict the ring flip in the following fashion, to make the mirror image relationship more obvious. The green methyl group, equatorial in conformer 2a, is changed into an axial methyl group in conformer 2b. Likewise, the blue methyl group goes from axial to equatorial. The 1,2-cis relationship between the two methyl groups is retained in both conformers.
Each individual conformer can be said to be chiral, but just like how the amine is considered achiral, cis-1,2-dimethylcyclohexane as a whole is considered achiral.
Is the compound meso? According to the IUPAC Gold Book, a meso-compound is defined as:
A term for the achiral member(s) of a set of diastereoisomers which also includes one or more chiral members.
1,2-Dimethylcyclohexane possesses two diastereomers, one cis and one trans form. The trans form is chiral, but the cis form is achiral, as explained above. Therefore, the cis form satisfies the above definition and is considered a meso-compound.
orthocresol♦orthocresol
$\begingroup$ Can we get it cold enough to freeze the enantiomers long enough to detect them? Can we see evidence of non-racemization in an optically active environment? $\endgroup$
– Oscar Lanzi
$\begingroup$ @OscarLanzi I don't know. I presume it is possible, but for all intents and purposes it's achiral. $\endgroup$
– orthocresol ♦
$\begingroup$ Sir, I'd like to ask one thing, suppose we have the compound 1-(chloromethyl)-3,5-dimethylcyclohexane in which all three substituents (the 2 methyl and one chloromethyl) are coming out of the plane, is this compound meso? Due to the same reason as explained in this answer (flipping of ring)? It does have two stereogenic centres (the 3,5 positions)... $\endgroup$
– Vilakshan Gupta
$\begingroup$ @LightYagami Yes, it is the same thing. $\endgroup$
$\begingroup$ Is it wrong then to see "plane of symmetry" at all in the rings? Because that is not how in reality it exists, but is it a conicidence that if we answer according to the 2D picture (using POS idea), the answer still comes out to be the same. I am also not able to see why the same argument for the trans form cannot be applied in this case. $\endgroup$
I'd like to add a few points definition wise from the IUPAC goldbook.
(Because recently the original website seems to be broken I am using links via the internet archive.)
A prefix to indicate the presence of a symmetry element of the second kind (see chirality) in a chemical species which is usually one of a set of diastereoisomers that also includes a chiral member.
However, there is a more general definition, too:
meso-compound
The first part clearly does not apply to the cis-isomer, (1R,2S)-1,2-dimethylcyclohexane, the second does because of the definition of chirality.
The geometric property of a rigid object (or spatial arrangement of points or atoms) of being non-superposable on its mirror image; such an object has no symmetry elements of the second kind (a mirror plane, σ = S1, a centre of inversion, i = S2, a rotation-reflection axis, S2n). If the object is superposable on its mirror image the object is described as being achiral.
I think the key point of this definition is in this case, that the object needs to be rigid, which (1R,2S)-1,2-dimethylcyclohexane is not at room temperature. If you cool down the solution, inhibiting the ring flip, you would probably be able to find both configurations; that is a racemic mixture of them.
Since (1R,2R)-1,2-dimethylcyclohexane and (1S,2S)-1,2-dimethylcyclohexane, the trans-conformers, are both chiral (and enantiomers), the remaining member of the set (1R,2S)-1,2-dimethylcyclohexane can be considered a meso-compound, since it is achiral.
Martin - マーチン♦Martin - マーチン
Why does 1,2-dimethylcyclohexane only possess three stereoisomers?
Optical activity in cyclohexane
Is it correct to look at plane of symmetry in substituted cyclohexane for determining a meso compound?
How to pass a Plane of symmetry?
How are these two enantiomers?
Mirror planes of symmetry in bicyclo[2.2.2]octane?
Racemic mixture of meso compound
Reaction mechanism of glycerol with hydrogen iodide acid
Why is trans-1,2-dimethylcyclohexane an enantiomer?
How many gauche butane interactions are present in cis-1,2-dimethylcyclohexane?
Identifying a meso compound
Does 1,4-dimethylcyclohexane have a chiral center?


Mercedes-Benz is best known for its big sedans, but lately the German automaker has been looking into smaller and more efficient vehicles.
That lineup is expected to increase over the next few years, reports Automotive News.
Mercedes will expand its roster of front-wheel drive models when a new platform, announced by Daimler CEO Dieter Zetsche, debuts in 2018.
This follows the launch of the CLA-Class recently introduced in the U.S. While the CLA takes Mercedes into previously unexplored territory in the U.S, the marque's next front-drive model will be even further from home--the Mercedes-Benz B-Class Electric Drive.
The company had already confirmed the model for the U.S, but the Electric Drive has kept a fairly low profile outside of auto show appearances. We now know it should hit the U.S. in Spring 2014, a revision from the previous estimates of "early" 2014.
Based on the gasoline and diesel B-Class models sold in Europe and elsewhere, the Electric Drive features a 100-kilowatt (134 horsepower) and 228 lb-ft electric motor, which Mercedes says should match the torque of a 3-liter gasoline engine.
A 0-60 mph sprint of "considerably less than 10 seconds" is on the cards, as is a limited top speed of 100 mph. Range should be around 115 miles.
What we're most intrigued about is what the B-Class may cost. Mercedes hasn't revealed any estimates, but with BMW's i3 electric car now priced at $42,275, competition has just become a little tougher for the B-Class.
The next front-drive Mercedes model will be the next-generation GLK crossover, debuting in September 2014. From 2018, a whole new front-drive platform will debut, with both a CLA-based convertible and a two-door roadster mooted.
The compact A-Class, on which the CLA sedan is based, is still not planned for U.S. sales.


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Demi Rose Mawby shows off logic-defying curves in bikini with never-ending neckline
DEMI Rose appears to have the biggest swimwear collection known to man.
Demi Rose first shot to fame when she enjoyed a brief fling with Kylie Jenner's ex Tyga, 28 in 2016.
But the Birmingham-born beauty soon established a name for herself in her own right after she gained an impressive social media following for a flurry of sexy bikini and lingerie snaps.
Demi, who boasts 6.5 million Instagram followers was soon snapped up by an American modelling agency and has since posed for many sizzling shoots with publications such as Zoo, Nuts and FHM.
As well as stripping off for steamy shoots, the 22-year-old appears to be on one constant holiday if Demi Rose Instagram posts are anything to go by. Life really does seem to be a beach for the young star who has recently enjoyed the jet-set lifestyle to Mykonos, Milan and Venice. Ticking off even more holiday hotspots from her list, Demi is currently holiday in Capetown, South Africa.
Demi appears to have been making the most of her trip so far – undertaking activities such as wine-tasting and mountain-climbing. However, it appears that there's always time for an obligatory bikini selfie when it comes to Demi Rose and she didn't disappoint in her latest offering. Posting on her Instagram story, Demi appeared to channel her inner Lara Croft in her latest look. The brunette beauty donned a khaki tie-up bikini top which unleashed her sizeable assets.
She paired the crop with coordinating high-rise bottoms that perfectly framed her curvy derrière. Demi pulled her hair back off her face into a casual ponytail but added a glamorous feel with sultry flash lashes. Demi's loyal following were undoubtedly delighted by her latest display, but the young star is well and truly off-the-market, which she proved with a snap of her and her boyfriend which she captioned: "Missing my other half." The curvy model is currently dating DJ Chris Martinez – they were first spotted together when they were caught locking lips at Madrid airport in December.


I like the word "ontheemd", and unfortunately there is no English word that has quite the same meaning. It took me exactly 2 years and 2 months to realize that I am "ontheemd", or lets say uprooted.
In Belgium, the Stella (beer) slogan is "My home is where my Stella is". Stella is actually a very popular beer here. Which I don't drink. But a home is where your beloved are, where you can be happy, where you can be yourself. Where you don't need to be stressed for just any thing in daily live. There are lots of reasons why one country is better then another. It is not economy, it is not the expenses, it is not tradition. It is not the speed of the internet or the speed new movies come out. It is not the last model of certain car or the size of a house. It is what one expects from life and the personality one has that decides which country is best for him. And there is a big difference in say Latino's and Northern Europeans.
I must have some Latin genes in me, although my parents assure me I don't. I love the laid back way of living. You don't have to be deadly stressed if you arrive 5 minutes late. You don't have to eat at strict hours, go out when every one wants you to go out. You can invite friends out on the last minute. You can also cancel them last minute if something came up. You don't get killed when you forget something. People aren't constantly watching you to check if you are doing everything right. True, Argentines tend to complain a lot about how messed up their country and their government is, but it is like discussing the weather. A part of the daily conversation that always ends in a 'es lo sue hay' (what can we do about it). Argentines enjoy life more, although their lives aren't half as easy as Belgian's life. They live, no matter what.
I guess we argentines have some joie de vivre in us, still after everything we've been through as a society (or maybe we just suffer from collective Alzheimer's…or wait, maybe both! haha).
Alzheimer! That's a good one! A nice kind of Alzheimer anyway!
Nice blog Kati. Makes me a bit jealous of your life.
I heard my Bolivian son was coming over one of these days.
Thnx thierry! Komt Thomas ons bezoeken? Dat Zou cool zijn! Groetjes!!
Ik ken de details niet maar ik heb begrepen dat hij dat van plan is. Voor het ogenblik hebben we weinig contact door het feit dat hij helemaal Boliviano is geworden.
Ok super! We zullen hem wel zien verschijnen hier! Ik zal mijne zoon eens interpelleren.


God Bless Maddie on her First Holy Communion! I had so much fun capturing this special occasion, and doesn't she just look stunning? Maddie is an amazing dancer and of course we had to incorporate just a few ballet slipper shots for fun:) If I can showcase the beautiful, fun-loving, carefree, and just-a-bit goofy personalities of my clients, then I have done my job well! Maddie was just perfection!


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ELEMENTARY INSTRUCTION IN PHYSIOLOGY.
acterizes the succession of all other occurrences, and the statement of which we call a law of Nature.
Hence, I think, arises the want of heartiness of belief in the value of knowledge respecting the laws of health and disease, and of the foresight and care to which knowledge is the essential preliminary, which is so often noticeable; and a corresponding laxity and carelessness in practice, the results of which are too frequently lamentable.
It is said that, among the many religious sects of Russia, there is one which holds that all disease is brought about by the direct and special interference of the Deity, and which, therefore, looks with repugnance upon both preventive and curative measures, as alike blasphemous interferences with the will of God. Among ourselves, the "Peculiar People" are, I believe, the only persons who hold the like doctrine in its integrity, and carry it out with logical rigor. But many of us are old enough to recollect that the administration of chloroform in assuagement of the pangs of childbirth was, at its introduction, strenuously resisted upon similar grounds.
I am not sure that the feeling, of which the doctrine to which I have referred is the full expression, does not lie at the bottom of the minds of a great many people who would yet vigorously object to give a verbal assent to the doctrine itself. However this may be, the main point is that sufficient knowledge has now been acquired of vital phenomena to justify the assertion that the notion that there is anything exceptional about these phenomena receives not a particle of support from any known fact. On the contrary, there is a vast and an increasing mass of evidence that birth and death, health and disease, are as much parts of the ordinary stream of events as the rising and setting of the sun, or the changes of the moon; and that the living body is a mechanism the proper working of which we term health; its disturbance, disease; its stoppage, death. The activity of this mechanism is dependent upon many and complicated conditions, some of which are hopelessly beyond our control, while others are readily accessible and are capable of being indefinitely modified by our own actions. The business of the hygienist and of the physician is to know the range of these modifiable conditions, and how to influence them toward the maintenance of health and the prolongation of life; the business of the general public is to give an intelligent assent, and a ready obedience based upon that assent, to the rules laid down for their guidance by such experts. But an intelligent assent is an assent based upon knowledge, and the knowledge which is here in question means an acquaintance with the elements of physiology.
It is not difficult to acquire such knowledge. What is true, to a certain extent, of all the physical sciences, is eminently characteristic of physiology—the difficulty of the subject begins beyond the stage of elementary knowledge, and increases with every stage of progress. While the most highly-trained and best-furnished intellect may find


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