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text:
Liverpool Target keen on european football
Date: 2nd May 2016 at 5:51pm
Colombian striker Marlos Moreno has described the possibility of playing in Europe as "a dream."
The 19 year old, who plays for Atletico Nacional in his native Colombia has been linked with Liverpool, Benfica, Sevilla, Santos, Deportivo la Coruna, Genoa and Paris Saint-Germain in the last month, and the pacey forward commented to O Jogo when asked about playing for a team like Benfica in Europe:
"Of course, playing in Europe is a dream. All Colombian players have this goal. Benfica are a very important team, one of the best in Portugal and would be a dream to represent it."
Moreno has helped his Atletico Nacional to the Colombian league Finalizacion title and the Superliga Colombiana this campaign, and he has also been given his international debut by manager Jose Pekerman in a 3-2 victory over Bolivia in a World Cup qualifying match back in March, assisting Juan Cuadrado to score Colombia's winning goal.

redpajama_set_name: RedPajamaCommonCrawl


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Advertising Week Asia, which makes its return to Tokyo from May 29 – June 1, has just announced three more speakers as part of the featured Keynote Series. The newly announced lineup of speakers will join previously announced names such as Facebook's Chris Cox, Google's Dan Taylor and Isobar's Jean Lin.
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Two sneak peek clips from "Mattress" are roaming the internet, and they're conveniently embedded below for your viewing pleasure! First we've got Kurt's explaining a plan to save the Gleeks from yearbook embarrassment, and secondly we've got a cute rendition of Lily Allen's "Smile" from Rachel and Finn.
I promised you full song previews, and although they took a bit longer than expected to track down, here they are on the New York Post. I think right now I'm most partial to the Charlie Chaplin version of "Smile," but as we all know, sometimes seeing the video attached to the song can make all the difference!
And in other news, Glee co-creator Brad Falchuk has signed a seven-figure, multi-year deal with FOX. He will continue working on Glee, as well as develop new FOX projects on the side. Congrats, Brad!
Hope you all enjoy tonight's episode! As the lead-up to the fall finale, it's sure to be a big one! See you back here tomorrow morning for the recap!


text:
package com.netflix.atlas.eval.stream

import com.netflix.atlas.core.model.DataExpr
import com.netflix.atlas.core.util.RefIntHashMap
import com.netflix.atlas.eval.model.EvalDataRate
import com.netflix.atlas.eval.model.EvalDataSize

import scala.collection.mutable

class EvalDataRateCollector(timestamp: Long, step: Long) {

  private val inputCounts = mutable.Map.empty[String, RefIntHashMap[DataExpr]]
  private val intermediateCounts = mutable.Map.empty[String, RefIntHashMap[DataExpr]]
  private val outputCounts = new RefIntHashMap[String]

  def incrementOutput(id: String, amount: Int): Unit = {
    outputCounts.increment(id, amount)
  }

  def incrementIntermediate(id: String, dataExpr: DataExpr, amount: Int): Unit = {
    increment(intermediateCounts, id, dataExpr, amount)
  }

  def incrementInput(id: String, dataExpr: DataExpr, amount: Int): Unit = {
    increment(inputCounts, id, dataExpr, amount)
  }

  def getAll: Map[String, EvalDataRate] = {
    inputCounts.map {
      case (id, _) => {
        id -> EvalDataRate(
          timestamp,
          step,
          getDataRate(inputCounts, id),
          getDataRate(intermediateCounts, id),
          EvalDataSize(outputCounts.get(id, 0))
        )
      }
    }.toMap
  }

  private def getDataRate(
    counts: mutable.Map[String, RefIntHashMap[DataExpr]],
    id: String
  ): EvalDataSize = {
    counts.get(id) match {
      case Some(v: RefIntHashMap[DataExpr]) =>
        var total = 0
        val builder = Map.newBuilder[String, Int]
        v.foreach { (dataExpr, count) =>
          builder += dataExpr.toString -> count
          total += count
        }
        EvalDataSize(total, builder.result())
      case None => EvalDataRateCollector.EmptyRate
    }
  }

  private def increment(
    counts: mutable.Map[String, RefIntHashMap[DataExpr]],
    id: String,
    dataExpr: DataExpr,
    amount: Int
  ): Unit = {
    counts.getOrElseUpdate(id, new RefIntHashMap[DataExpr]).increment(dataExpr, amount)
  }
}

object EvalDataRateCollector {
  val EmptyRate = EvalDataSize(0)
}

redpajama_set_name: RedPajamaGithub


text:
Show Me The Money – Funding Opportunities for SMEs
March 26, 2019 @ 8:30 am - 11:00 am
« Finding Talent, Onboarding New Hires, and Performance Management for Start-ups
Niagara Women in STEM »
2019 BREAKFAST & LEARN SERIES
Finding and applying for government grants or loans can be a time-consuming, complex process. This Breakfast & Learn at Niagara College will help you navigate the complexity.
Canadian federal, provincial, and municipal government bodies can help your business through grants, loans, or other forms of financing.
There are many misconceptions about government grants for small businesses. The government isn't just giving away money – they've created publicly funded programs to help the Canadian economy. Some programs are available to businesses all over Canada, while others are restricted to certain business types or regions. Most funding programs have strict requirements for use of funds and reporting requirements.
Come find out:
what opportunities are available from those who administer these grants
if there is a fit for your application of business
if, through the application of advanced manufacturing technologies, the college may become part of this process.
Hear from representatives of:
National Research Council of Canada: Hugh Scholaert, Industry Technology Advisor, IRAP
Ontario Centres of Excellence: Julie Lukkarila, Business Development Manager
Ministry of Economic Development, Job Creation and Trade: Marika Swain, Senior Business Advisory for Niagara
(Full bios for each included below)
What are my parking options for the workshop?
Parking passes and a campus map will be emailed to all registered guests prior to the event
Contact Niagara College Research & Innovation
What's the refund policy?
Refunds are possible if initiated by 12 noon on Monday, March 25, 2019. Refund inquiries can be processed through your Eventbrite account or by contacting research @niagaracollege.ca
Is my registration fee or ticket transferrable?
Yes. Tickets can be transferred until 12 noon on Monday, March 25, 2019.Registration amendments can be processed through your Eventbrite account or by contact [email protected]
The name on my ticket/registration doesn't match the attendee. Is that okay?
Yes, it is okay if the name on the registration/ticket does not match the attendee. However, we would appreciate being notified of any changes to attendee information as soon as possible. Please contact [email protected] with registration updates.
HUGH SCHOLAERT
Industrial Technology Advisor, Industrial Research Assistance Program, National Research Council Canada
Hugh holds a Bachelor and Master's degree in Aerospace Engineering from the University of Toronto. Upon graduation he co-founded Aastra Technologies, a company involved in business communications equipment and applications. The firm was eventually listed on the TSE and grew to have a global footprint. In 2012, Aastra was merged with Mitel and Mr. Scholaert bought a farm in Pelham where he briefly retired from his position as Regional President.
He has now been acting as Industrial Technology Advisor for the National Research Council, Industrial Research Assistance Program, serving the Niagara region since 2016.
JULIE LUKKARILA
Business Development Manager, Ontario Centres of Excellence, Southwestern Ontario Region
As a Business Development Manager at the Ontario Centres of Excellence, Julie's primary role is to initiate and cultivate academic and industry partnerships within the South Western Ontario Region. Her areas of expertise range from advanced manufacturing and materials to advanced health technologies.
Prior to joining OCE, Julie worked as Client Services Liaison at HalTech Regional Innovation Centre where she worked with start-up, pre-revenue and small to medium sized companies within multiple sectors to help them start, grow and thrive.
Julie holds a PhD in Polymers and Materials and a HBSc (Specialist Chemistry, Minor Biology) from the University of Toronto. She has also worked at the University of Toronto as a postdoctoral fellow designing and synthesizing novel cancer therapeutics and as a sessional lecturer at the University of Toronto and Sheridan College.
MARIKA SWAIN
Senior Business Advisor for Niagara, Ministry of Economic Development, Job Creation and Trade.
Marika has been with the Ministry for less than a year but is loving the new challenge and the opportunity to meet with, learn about and assist businesses across the region. Her most recent position was as Business Development Manager for Fleet Canada, a Tier One aerospace structures manufacturer in Fort Erie.
Marika has an undergraduate degree and a Master's of Business Administration degree; both from Brock University. She currently sits on the Niagara College Program Advisory Committee for the Business Program at Niagara and serves as a Board Member for Innovate Niagara.
Community, Community Event
Niagara College, NOTL Campus Ventures Training Room
Niagara-on-the Lake, ON L0S 1J0 Canada + Google Map
http://innovationfactory.ca/venue/niagara-college-notl-campus-ventures-training-room/


Since 1958, Sharp Bros. Seed Co. has been a leader in the native grass industry. Call us for all your CPR, wildlife plots, pasture, sorghum, wheat, lawn or wildflower needs.
It's worth a try to become pain-free!
SCDC works with citizens and partners to ensure Scott County progresses toward its "Preferred Future". Collaboration across industry sectors, across cultures and across all ages is key to success!


Working in the mining industry, you can be sure that there are endless things to learn and discover within the earth. I, for one, know that with any industry, comes a process. When it comes to mining, there are many types of tubes that can be used in many different ways. From the specialized vehicles to basic drainage the necessity for custom tube bending is prevalent. Before we discuss our relationship with the Mining Industry, here is a little info on some methods of mining we thought were interesting.
Surface mining is the process of seam mining ore and coal from the land. With this technique, any unwanted soil is stripped from the ground. From there, it is then sought after and found relatively close to the surface of the site. When dealing with surface mining, it is helpful to utilize the strength of the Bucket-Wheel Excavators. Due to the land decimation that happens during surface mining, this type of mining is very controversial. In fact, surface mining quite often leaves large areas of infertile land and waste of up to 70% behind.
Underground (or Subsurface) mining includes the digging of tunnels and shafts into the earth to reach and withdraw the deposit of mineral and ore beneath the earth. In contrast to some other mining methods, underground mines are much more dangerous for those working within them. However, it can be less impactful on the environment. Shovels, axes and carts that were once used by underground miners have been replaced with ventilation machines. This not only helps to retrieve valuable materials, but it also ensures that the workplace is safer. The process of underground mining is a lot more difficult and expensive than all of the other forms. This is because underground mines excrete much less waste rock when the ore is being accessed.
Open-Pit mining involves mining minerals or ore that can be seen at the surface layer of the site. This form of mining does not require tunneling and is an easy method of mining that yields high rates of production. Open-Pits are typically converted to recreational areas and can be reused for other purposes as well.
Make parts for specialized mining vehicles, like exhausts or engine connections etc.
If you are in learning more about the industries we've served, please feel free to contact or call us at 313.841.0300. We look forward in hearing from you.


Welcome to the Military Books Online Site.
This site has been a long project of mine and it is to allow others to gain more knowledge of what happened in World War 2.
The goal of this site is to provide information on topics from World War 2. From battles to weapons.
And also to provide more sources of information if any is needed for those who have a more detailed interest in it.
I am dedicating long hours into this site because World War 2 has facinated me since my childhood.
Been a while since I made an update. Yeah long while. Alright. I am studying to be an engineer so I haven't really had time. My computer also keeps on hanging on me so I keep losing my work and all. I apologize for that. Hopefully, this will take up my time.
I am working on adding more articles on interesting topics of World War 2. If you have any nice topics I could research on in my library. Just e-mail it to me at gte357z@ prism.gatech.edu. Just remove the space after the @. This decision comes after the vast traffic I receive from including the article I wrote about Vassili Zaitsev. The sniper in the movie "Enemy of the Gates". I shall work towards clearing up things that I find interesting.
Saw "Enemy at the Gates" and thought it was an excellent movie. I tried looking for more information on Vassili Zaitsev(the sniper) on the internet, but was disappointed so i went a did some research on some of my WWII books and foudn some exerpts of the man. They are in my new snipers section. Here is a link.
22/03/01 Just fixed up some problems in the HTML code and added more books. The site was down for 3 days before because of a mistake at Tripod.com. It has been solved and we are back.
Just fixed up the site and added more books into the Holocaust section.
14/9/00 cleaned up and site and added an affiliate program to the site. Amazon and Barnes and Noble will be the honored today. also decided on a new system today...system of book distribution will be that books will be found under the subjects listed....any further changes will be made once I figure out my long term uses for this site.
Added a poll to rate site among visitors. Added are also Guestsbooks and various other books to the increasing big collection. 25 books listed so far!!


text:
Donald Trump Was Obsessed With Invading Venezuela
BY James Kosur July 4, 2018
President Donald Trump was trigger happy last August when, during an Oval Office meeting, he stunned his own aides by asking why the United States doesn't just invade Venezuela.
Photo Credit: WhiteHouse.gov
Trump was speaking about increased sanctions against the country with National Security Adviser H.R. McMaster and Secretary of State Rex Tillerson, among other members of his staff.
According to the Associated Press, Trump's advisers had to explain that an invasion would alienate Latin American governments who have been working to punish Venezuelan dictator Nicolas Maduro.
The conversation lasted five minutes and included several comments by Trump about the success of the Panama and Grenada invasions in the 1980s.
Despite pushback from his own administration, Trump announced the next day that an invasion was on the table.
Breaking: President Trump says, "I'm not going to rule out a military option" in Venezuela https://t.co/wJSgobFywz https://t.co/pkXIXHYAl6
— The Situation Room (@CNNSitRoom) August 11, 2017
Congress was having none of Trump's shenanigans and said an escalation in the area would be "an act of craziness.
Despite pushback from his own administration, Trump continued the conversation with Colombian President Juan Manuel Santos.
In September, Trump again talked to Santos about a possible invasion during a dinner with world leaders following the U.N. General Assembly. During that dinner meeting, The Guardian notes that Trump stepped outside of his own counsel's advice.
"My staff told me not to say this," Trump said. He then asked each Latin American leader at the table if they were against an invasion and they all said it would be a bad move. Trump pushed back on the leaders but was again told they didn't' approve of the invasion suggestion.
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Next: Next post: Donald Trump's 2020 Campaign Gear: Made In China?
Venezuela Invasion


Food: Excellent lunch boxes for the kids and very practical having an outside stall which meant minimal queuing for food. Not so keen on being exiled to al fresco eating in -5 degrees as the restaurant was waitress service.
Grounds: the house is stunningly ugly, arrestingly so. The kids even commented on it so I suppose that counts as a cultural experience. There was an aviary with some very shy birds. Also a hilarious statue of a woman fellating a gourd (see above).
Accessibility: Concrete paths all the way and there were specific mobility buses visible around the grounds for wheelchair users as well as standard shuttle buses. There were wooden walkways between playground areas but I imagine the woodchips might get a bit treacherous if self-propelled.


To know him was to love him, and the world is an emptier place without him. Robert Lee Savaglio Jr. was called to the Lord on March 18, 2019 peacefully at his home in Byron Center, MI. Robert Lee Savaglio Jr. was born October 4, 1979 in Racine, WI to Pamela Ann Mertins and Dr. Robert Lee Savaglio.
As he grew up, Robert became Rocky and Rocky attended Trinity Lutheran School where he began his love of playing sports and grew his Christian values.
As a boy, Rocky started a baseball card collection that he continued his whole life. What started as a hobby became a prized sports memorabilia collection.
As a teenager, Rocky became Rob and Rob started at Lutheran High School then followed his football coach, Scott Smith to St Catherine's High School (Class of '98).
He excelled at both basketball and football, setting school records along the way and as a Senior was awarded Racine's Defensive Player of the Year.
Rob moved on to UW-LaCrosse where he received his BA in Accounting followed by a Masters in Accounting from UW-Milwaukee.
Rob chose accounting because he would go with his Dad to visit our Uncle Al at work – Dairyland Racetrack in Kenosha, WI.
There Rob learned gaming odds and statistics. With this love of the gaming industry Rob decided he could work in a sports book, but would often say, "Why should I be a bookie when I can run the casino?" He took his own advice and moved to the glamorous city where an accountant could find exciting work – Las Vegas. Rob started at MGM Grand and Caesar's Palace casinos and eventually worked his way up to Casino Controller at Treasure Island where he became known as "Hombre De La Gente" for his friendly talkative nature and ability to strike up a conversation with any employee. Rob then went on to be the Director of Finance at Red Rock Hotel and Casino.
After about a decade in Las Vegas, Rob wanted a change and decided to take a position as CFO for Gun Lake Casino in Wayland, MI. Rob was able to parlay this position into a larger role as CFO of the Gun Lake Tribe which was his final position.
Other than sports memorabilia, Rob also had a vast collection of mint condition Nikes. Rob enjoyed watching basketball, baseball, football, UFC & golfing. There was not a sport Rob wouldn't watch or play. When Rob was not watching or playing he was coaching. He coached high school teams in Wisconsin and volunteer coached for a kids basketball team in Las Vegas.
Music was something Rob had a variety of tastes for. His favorite was the Beastie Boys and he went to many concerts. In his life, Rob was lucky to travel to many different places and make so many dear lifelong friends.
Rob leaves behind his prized companion, Gigi, his Bison Frise- he would not allow you to call her "the dog". He is survived by his parents Dr. Robert Lee and Pamela (Mertins) Savaglio of Sun City, AZ. His sisters Amy Savaglio (Vincent Niemi) of Peoria AZ, Melissa Kim (Dr Kyu) of Tualatin, OR, and Joy Hulsey of Denver, CO. His nephews Gavin, Kai, and Jakobi Kim who will truly miss fun Uncle Rob.
A Celebration of Rob's life will be held Saturday, April 13, 2019, 2:00 pm at the funeral home with Rev. Jim Olson officiating. Relatives and friends may meet with the family Saturday from 12:00 pm until time of service at 2:00 pm. In lieu of flowers, the family request donations to Racine Youth Sports.


Oscar winning actress Lupita Nyong'o is the latest name to be attached to Star Wars Episode VII, with a new report claiming that she met with J.J. Abrams only a few weeks ago, just before her big win at the Academy Awards.
Nyong'o is said to be "extremely close" to signing a deal after reading for the mysterious role several times over the past month or so. While there has been speculation that she could play a descendent of Obi-Wan Kenobi (which was originally described as being a non-Caucasian character), it is instead believed the actress is up for the part of a Sith.
They're all the details we have for now, but with the hunt for the male lead being narrowed down to five and Girls star Adam Driver set to play the lead male villain, things are getting very interesting indeed!
The news was originally reported by Latino-Review, with The Hollywood Reporter later confirming their story.


Blackjack E Live provides players with a combination of thrill and excitement. If you are a connoisseur of table games and also want to have a real-life experience of gaming, this is an ideal game to play. Like the other live games that you play, this game also has a design that gives you the feeling of playing in a brick and mortar casino. The interface and the design have a completely realistic setting along with a 3D look and feel. The dealing studios from where the game takes place are located in Europe and South America. The default language is English, while you can also switch on to Spanish.
Blackjack E Live can be played with two variants of blackjack: 7 seat blackjack and unlimited blackjack. Based on your level of skill, you can play the games. The rules in both the games are quite simpler so that even novices can take part. The game can be played directly on the mobile browser without having to download it. Also, it can be played on the desktops. A good attribute about the game is the dealer hand statistics that is displayed as part of the interface. This enables the players to view the last 10 hands of the dealers.
In case of the Blackjack E Live 7 seat, a player will need to use 8 decks of cards. It follows the Vegas rule that allows the dealer to take two cards. If the dealer shows an Ace card, the player will be able to surrender the hand. He or she will also be able to double on the splits. There are no limiting rules and you will be able to double on any stake. The dealer will stand on all the 17's and the insurance payment is 2:1.
In case of the unlimited variant of the Blackjack E Live, auto splits play a significant role. One hand of the player is dealt on which an unlimited number of players can place their bet. Each player will be able to make the decisions related to double, split, hit or stand. A unique aspect of this variant is the auto-splitting of hands 2-2, 3-3, 6-6, 7-7, 8-8 or A-A. A player can wish to use just one hand or can play both hands. In the case of the latter, the bet will be doubled.


text:
First Trailer for Australian Western 'High Ground' Starring Simon Baker
"What have you bloody done?" Madman Films has unveiled a teaser trailer for the anticipated Australian action western High Ground, which is premiering at the Berlin Film Festival this month. Set in the 1930s, High Ground is inspired by true events, telling the story of a policeman in Northern Australia and the local aboriginals he attempts to befriend. After a terrible massacre leaves many dead without justice, years later he is forced to return and confront the same aboriginals when they start attacking outposts. Described as "a frontier western about colonial violence and misunderstandings that deeply resonates in today's Australia – and indeed all over the world – the film explores the nature of loyalty and the ability to distinguish freely between right and wrong, in opposition to the dogmas of the age in which you live." This co-stars Simon Baker and Jacob Junior Nayinggul, with Jack Thompson, Callan Mulvey, Witiyana Marika, and Caren Pistorius. This isn't the best teaser, but it does setup the stakes and the key characters in this film.
Here's the first teaser trailer for Stephen Johnson's High Ground, direct from Madman's YouTube:
After fighting in The Great War as a sniper, Travis (Simon Baker), now a policeman in the vast empty spaces of Northern Australia, loses control of an operation that results in the massacre of an Indigenous tribe. When his superiors insist on burying the truth, Travis leaves in disgust, only to be forced back 12 years later to help hunt down Baywara, an Aboriginal warrior whose attacks on new settlers are causing havoc. When Travis, now a bounty hunter, recruits as his tracker the young mission-raised Gutjuk (Jacob Junior Nayinggul), the only known survivor of the massacre, memories threaten to resurface and turn the white man from hunter into the hunted. High Ground is directed by Australian filmmaker Stephen Johnson, his second feature film after Yolngu Boy previously, and the "Dead Gorgeous" TV series as well as other TV work. The screenplay is by Chris Anastassiades. This is premiering at the Berlin Film Festival this month. No official release dates for Johnson's High Ground are set - stay tuned for updates. Thoughts?
Find more posts: To Watch, Trailer


text:
Dortmund writers exchange stories with Leeds
Posted by Leeds 2023
Peter Spafford is a writer based in Leeds. Following the outcome of the UK referendum Peter had a strong desire to reach out to writers in other countries, mainly in Europe, to investigate the possibility of working with a writer from a different country with a different language. Supported by the international relations team at Leeds City Council, the first exchange took place this year with Leeds' twin city, Dortmund, Germany. Peter wrote a blog for us about the exchange and his plans to develop the project going forward.
In September, Ralf Thenior, poet of Dortmund, one of our twinned cities, visited Leeds for a week. This was the first stage of Writers in Transit, a project I set up this year with the intention of making contact with writers in other European cities.
Ralf did three public readings in Leeds during his stay, as well as a live broadcast and a schools visit. But apart from doing this public work, he spent many hours pacing the pavements of the city making notes for an extensive 'Leeds Diary'. How does a poet from Germany see a British city at this moment in our history?
And, reciprocally, how does a British poet see a German city? Because the second stage of this pilot project, my visit to Dortmund, happened in October. During my time there, I spoke to two groups of university students and academics, and did two public readings (one at the Dortmund Literaturhaus – enviably many German cities have one of these!). Apart from doing the public events, I also made many notes on the places I visited, the things I saw, and the people I met.
I have to say I had a fascinating time in Dortmund and my working friendship with Ralf has so far been one of the most satisfying and pleasurable collaborations I have ever undertaken.
The next stage is to write up our separate notes. He will translate mine, I will translate his (with quite a bit of help at my end….). We will then read highlights from both works in April next year both in Dortmund and in Leeds. In addition, the performances will be accompanied by a published version of both diaries in both languages.
At every stage I've been acutely aware of how important this kind of cross-border cultural work feels at the moment, especially in the light of what's happened recently with the 2023 bid. Ralf and I are absolutely determined both to carry on with our own collaboration and to extend the contact between our cities to other Leeds and Dortmund writers and writing communities.
This could include young writers through an organisation like Chapel FM or The Writing Squad; writing groups who meet in libraries; university creative writing courses; and city-wide reading groups. The British-German Association is strong in Yorkshire and there is potential there. Meanwhile, Ralf's draft Diary has just popped into my email box. I look forward to reading it…
Culture, sports and the arts all represented as Leeds 2023 announces its board of trustees
Leeds 2023 has unveiled its board of trustees, bringing together a wealth of expertise from across the arts, academia, business, marketing, popular culture and sport.
Executive Director appointed for Leeds 2023
Mark Hollander, former Executive Director for Phoenix Dance will be Leeds 2023's new Executive Director.
New creative director returns to Yorkshire to kickstart the next phase of Leeds 2023
Ground-breaking and highly respected theatre director Kully Thiarai will return to Leeds to oversee a major cultural investment programme culminating in a spectacular one year cultural festival for the city in 2023
More than a million people saw Yorkshire's first ever sculpture festival
Visitor figures have revealed that more than a million people saw Yorkshire's first ever sculpture festival which ran for 100 days this summer.
Get the latest news on Leeds 2023
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4. Write about what interests you, excites you. That's what admissions staff wants to read.
1. Don't include information that doesn't support your thesis.
2. Don't start your essay with "I was born in…" or "My parents came from..."
3. Don't write an autobiography, itinerary, or resume in prose.
4. Don't try to be a clown (but gentle humor is ok).
5. Don't be afraid to start over if the essay just isn't working or doesn't answer the essay question.
6. Don't try to impress your reader with your vocabulary.
7. Don't rely exclusively on your computer to check your spelling.
8. Don't provide a collection of generic statements and platitudes.
9. Don't give mealy-mouthed, weak excuses for your GPA or test scores.
10. Don't make things up.


text:
Il punto di equivalenza, o punto stechiometrico, di una reazione chimica è il punto in cui quantità equivalenti di un acido e di una base sono miscelate. In altre parole, le moli di acido sono equivalenti alle moli di base, secondo l'equazione (questo non necessariamente implica un rapporto molare 1:1 di acido:base, semplicemente il rapporto è lo stesso dell'equazione). Può essere trovato tramite l'impiego di un indicatore, per esempio la fenoftaleina o il metil arancio.

In una reazione, l'equivalenza dei reagenti come dei prodotti è conservata.

Il punto finale (relazionato al punto equivalente ma non coincidente) si riferisce al punto in cui l'indicatore cambia colore in una titolazione colorimetrica.

Metodi per determinare il punto equivalente
Tra i vari metodi per la determinazione del punto equivalente troviamo:
Indicatore di pHÈ una sostanza che cambia colore in risposta a un cambiamento chimico. Un indicatore acido-base (esempio fenolftaleina) cambia colore in base al pH. Gli indicatori redox sono frequentemente impiegati. Una goccia di indicatore nella soluzione è aggiunto all'inizio della titolazione, quando il colore cambia significa che si è giunti al termine. Questa è un'approssimazione del punto di equivalenza.

Conduttività La conduttività ionica di una soluzione dipende dagli ioni che sono presenti al suo interno. Durante molte titolazioni, la conducibilità cambia significativamente. (Per esempio durante una titolazione acido-base, gli ioni H3O+ e OH− reagiscono per formare H2O neutra. Questo cambia la conduttività della soluzione.) La conducibilità totale della soluzione dipende anche dagli altri ioni presenti in soluzione (come i controioni). Non tutti gli ioni contribuiscono egualmente alla conducibilità, questo anche dipende dalla mobilità elettroforetica di ciascuno ione e dalla concentrazione totale degli ioni (forza ionica). Quindi, predire il cambiamento nella conducibilità  è più difficile che semplicemente misurarla.

Cambio di colore In alcune reazioni, la soluzione cambia colore senza alcun indicatore aggiuntivo. Questo si osserva di solito nelle titolazioni redox, per esempio, quando i differenti stati di ossidazione del prodotto e i reagenti producono differenti colori.

Precipitazione Se la reazione forma un solido, allora si formerà un precipitato durante la titolazione. Un classico esempio è la reazione tra Ag+ e Cl− a formare il sale altamente insolubile AgCl. Sorprendentemente, questo di solito rende difficoltoso determinare il punto finale con precisione. Come risultato, le titolazioni per precipitazione devono essere spesso fatte come titolazioni al contrario.

Titolazioni calorimetriche isoterme Una calorimetria isotermica di titolazione usa il calore prodotto o consumato dalla reazione per determinare il punto di equivalenza. Questo è importante nelle titolazioni biochimiche, come la determinazioni di come un substrato si lega a un enzima.

Titolazione termometrica La titolazione termometrica è una tecnica straordinariamente versatile. Questa si differenzia dalla titolazione calorimetrica da l fatto che il calore di reazione (come indicato dall'aumento o diminuzione della temperatura) non è impiegato per determinare la quantità di analita nella soluzione campione. Invece, il punto equivalente è determinato tramite "il rapporto di cambiamento della temperatura",. Dato che la titolazione termometrica è una tecnica relativa, non è necessario condurla sotto condizioni isoterme, e le titolazioni possono essere svolte in contenitori di plastica o persino di vetro, nonostante questi contenitori siano generalmente chiusi per prevenire che schizzi casuali producano rumore e disturbino il punto finale. Dato che le titolazioni termometriche possono essere condotte in condizioni ambiente, sono adatte specialmente per processi di routine e di controllo qualità nell'industria. Dipendentemente se la reazione tra titolante e analità è esotermica o endotermica, la temperatura può ulteriormente aumentare o diminuire durante la titolazione. Quando tutti gli analiti sono stati consumati dalla reazione con il titolante, un cambio nell'aumento o diminuzione del rapporto della temperatura rivela il punto di equivalenza e un flesso nella curva della temperatura può essere osservato. Il punto equivalente è localizzato precisamente calcolando la derivata seconda della curva di temperatura. Il software usato nei moderni sistemi automatizzati di titolazione termometrica impiegano sofisticati algoritmi di levigatura così che il "rumore" risultante dalla sonda di temperatura altamente sensibile non interferisca con la generazione di un "picco" in derivata seconda levigato e simmetrico che definisce il punto di endpoint. La tecniche è in grado di restituire una elevata precisione, e i coefficienti della varianza (CV) inferiori a 0,1 sono comuni. Le moderni sonde di temperatura per titolazioni termometriche consistono in un termistore che forma un braccio di un ponte di Wheastone. Accoppiati con elettronica ad alta risoluzione, i migliori sistemi di titolazione termometrica possono risolvere temperature fino a 10−5K. Punti di equivalenza stretti sono ottenuti nelle titolazioni dove il cambiamento di temperatura è inferiore a 0,001 K. La tecnica può essere applicata essenzialmente a ogni reazione chimica in un fluido dove c'è un cambio di entalpia, nonostante le cinetiche di reazione possano giocare un ruolo importante nella nitidezza del endpoint. La titolazione termometrica è applicata con successo a titolazioni acido-base, redox, EDTA e gravimetriche. Esempi di titolazioni per precipitazione riuscite sono il solfato titolato tramite ioni bario, fosfato titolato tramite magnesio in una soluzione di ammoniaca, cloruro titolato con nitrato di argento, nickel titolato con dimetilgliossima e fluoruro titolato con alluminio (come K2NaAlF6). Dato che le sonde di temperatura non devono essere elettricamente connesse alla soluzione (come nelle titolazioni potenziometriche), possono essere portate a termine titolazioni in soluzioni non acquose facilmente come nelle equivalenti acquose. Le soluzioni che sono fortemente colorate o torbide possono essere analizzate tramite termometria senza ulteriori trattamenti del campione. La sonda è essenzialmente esente da manutenzione. Usando burette guidate da motori ad alta precisione, le titolazioni termometriche automizzate sono di solito completate in pochi minuti, rendendola la tecnica una scelta ideale dove un'alta produttività di laboratorio è richiesta.

Spettroscopia Può essere impiegata per misurare l'assorbimento di luce della soluzione durante la titolazione, se lo spettro di reagente, titolante o prodotti sono noti. Le quantità relativa del prodotto e del reagente possono essere usate per determinare il punto equivalente. In alternativa, la presenza di titolante libero (indicante che la reazione è completa) può essere rivelato a livelli di concentrazione molto bassi. Un esempio di detectore robusto del punto finale per acqua forte di semiconduttori è il EPD-6 un sistema che rivela fino a sei differenti lunghezze d'onda
Amperometria Può essere impiegata come tecnica di rivelazione(titolazione amperometrica). La corrente dovuta all'ossidazione o riduzione di ciascuno dei reagenti o prodotti a un elettrodo lavorante dipende dalla concentrazione di quella specie in soluzione. Il punto equivalente può essere rivelato come cambiamento nella corrente. Questo metodo è molto impiegato quando l'eccesso di titolante può essere ridotto, come nella titolazione di alogenuri con Ag+. (È anche comodo che si ignorano i precipitati.)

Note

Voci correlate
Titolazione (chimica)

Collegamenti esterni
Equivalence points of virtual and real acid-base titrations - Software Program
Example of robust industrial endpoint detector
Graphical method to solve acid-base problems, including titrations
Graphic and numerical solver for acid-base problems -Software Program for phone and tablets

Chimica analitica

redpajama_set_name: RedPajamaWikipedia


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What's The Void In WCAG 2.0 That The Proposed "Change in Content" Success Criterion 3.2.6 Attempts To Bridge?
I strongly believe that the proposed success criterion 3.2.6 in WCAG 2.1 that deals with changes in content is unnecessary as WCAG 2.0 addresses all the contemplated situations very effectively. All that is really needed is to provide additional guidance via the Understanding WCAG 2.0 and Techniques for WCAG 2.0 documentation.
The change of content both is not a result of a user action and is not related to the primary purpose of the page.
with continual changes of content such as games and simulations and seeks additional input from reviewers on this point.
A newly inserted definition for "change of content" reads, "changes made to a web page after it has been delivered to the user agent, whether or not initiated by the user ".
The above is per the latest editor's draft of the proposed WCAG 2.1[ Oct. 4, 2017].
on selecting a different pagination link, and so forth.
The definition of "change of context" in WCAG 2.0 includes a change in focus or content that changes the meaning of the Web page. The drafters of WCAG 2.0 have included "major changes if made without user awareness, can disorient users who are not able to view the entire page simultaneously" within the normative definition of the term. Obviously this situation is something that was contemplated and is within the scope of WCAG 2.0, else they would have crafted an SC to address this.
The definition further notes, "A change of content is not always a change of context". Only a change in content that causes a change of context is an accessibility problem. When content added to or altered on a page does not cause a major change in the meaning of the Web page, there is no change in context and consequently no accessibility problem. It only implies that the manner in which the change is presented is deficient in terms of markup (i.e. for instance, an absent role or attribute) resulting in "unannounced changes" -the reason for the proposed success criterion as suggested in the description section of Github Issue 2.
Furthermore, in the context of SC 3.2.2, right from the beginning the Understanding WCAG 2.0 documentation has had a statement, "Clicking on links or tabs in a tab control is activating the control, not changing the setting of that control". This validates the above interpretation that the authors of WCAG 2.0 debated extensively about what types of changes in content cause an accessibility problem and expressly decided to exclude changes in content caused as a result of activating UI elements such as links and controls.
Few accessibility consultants will fail to call an accessibility violation if a button causes a popup to be displayed on the page that goes undetected by a screen reader. Maybe it is just a list of "products you may also like" displayed in the popup with an ok button. Obviously the popup was not exposed as a dialog, it lacked a name and focus was not managed right.
The content is presented very distinctively in a manner that it arrests a sighted user's attention.
In the first instance, the website's goal for displaying "Products you may also like" is not being achieved. It is also poor usability as most users do not notice this section of content or are unaware that this has been added to the page. This needs fixing at the design / usability level.
The second scenario wherein the content is styled distinctly and is eye-catching is a situation where the markup is deficient. This content needs to be within a container with a proper role and name. It is not unlike an image that conveys information to a sighted user but is not perceivable by a non-sighted user because the image lacks an assistive technology-interpretable text alternative. Likewise, the container for "Products you may also like" lacks a name and a suitable role (e.g. alert) or aria-live property with an appropriate degree of politeness. This can be done with an ARIA technique already defined for WCAG 2.0, namely, ARIA4 whose stated objective is, "define the role of an element using the role attribute with one of the non-abstract values defined in the WAI-ARIA Definition of Roles".
Opening up additional choices below the point of action was discussed and was clearly not felt to qualify. Adding information above the point of action was felt to be a problem. Dynamic pages – which are really other pages generated on the fly by the page script, is clearly a change of context.
In other words, in my opinion: If the script creates "other pages on the fly" it is simply another page to which all of WCAG 2.0 applies. For example, consider error messages i.e. new content, added by employing client side scripting to a page. While the page displayed may comply with WCAG 2.0 on page-load, the newly reported validation errors must also be held to the same standard, namely WCAG 2.0 in order to gauge the conformance of the page post-validation.
That is perhaps why some accessibility consultants agree that when only some content on the page has been altered or is freshly introduced, such content must be positioned in a logical focus order or reading order so as to maintain the accessibility of the page. In fact these instructions are also included in official training and guidance material of leading accessibility consulting firms.
A user enters an invalid email address in the email field and tabs off. Instantly a message pops up and is placed above the form, "Email address is not valid".
If that message has aria-live, it will be read by a supporting screen reader even when the focus is on the control that follows the email field and there is no programmatic determinable relationship between the email field and the error message.
If that message is merely associated with the email field via aria-describedby, no screen reader will read it unless the user tabs back to the email field assuming it suddenly dawns on the user that the text entered is invalid.
Interestingly, this success criterion is believed to fall under the "Perceivable" principle as per Github Issue 2 and is yet listed under the "Understanding" list of success criteria on latest editor's draft of the proposed WCAG 2.1[ Oct. 4, 2017].
Consider a page contains such information (example: stock indices / stock price updates, score updates for a sporting event, update to incoming text messages, and the like) that happen at random intervals. At the outset, one would expect such content to occupy a designated portion of the page. One would then expect the section to have suitable semantics and structural markup. This is not very different from landmark regions like banner, main navigation, secondary navigation, breadcrumb navigation, search region, main content, footer section. Maybe this continually updating content could be a complementary region with a suitable heading. Then, depending on the intent of the page and the content author's objectives, the updates should be exposed via suitable aria-live properties. This would enable a user to navigate to and direct attention to that specific section of the page as needed. This again, this is something that does not need a success criterion but merely a supporting technique under the heading, "Situation A: The technology provides semantic structure to make information and relationships conveyed through presentation programmatically determinable" on How to meet SC 1.3.1.
Needless to say, auto-updating content already has explicit requirements in WCAG 2.0 SC 2.2.2. How Auto-Updating Content Is Fully Addressed By WCAG 2.0?
This unequivocally conveys that changes in content as contemplated by the proposed success criterion need to be made accessible only by organizations which adopt WCAG 2.1 and not those that seek conformance with WCAG 2.0.
It tantamounts to proclaiming that the drafters of WCAG 2.0 failed to include a specific success criterion to address a serious accessibility issue even after recognizing in the normative text that, "major changes if made without user awareness, can disorient users who are not able to view the entire page simultaneously". This is patently not true I believe.
Just as an image on a page is rendered imperceivable because of a missing accessibility attribute, newly added content on a page goes undetected simply because suitable accessibility markup is not programmatically set, as a result of which, user agents and assistive technologies are unable to notify users of change in content. Accessibility evaluators today routinely flag such content addition issues as WCAG 2.0 accessibility violations. Techniques that address such situations have been in use for a while now. The techniques and understanding suite of WCAG 2.0 supporting documentation has lagged behind in this regard. These need to be updated with references to existing WCAG 2.0 success criteria in order to provide guidance to developers and evaluators alike. No new success criterion is needed.