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Garnier commits to Green Beauty for all of us
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Consumer Products Division
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Garnier commits to Green Beauty, an end-to-end approach to sustainability. Green Beauty is set to transform Garnier, helping to reduce the brand's environmental impact at every stage of its value chain.
All Garnier products, globally, are now officially approved Cruelty Free International under the Leaping Bunny programme.
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To be officially approved by Cruelty Free International under the Leaping Bunny programme is a real milestone and was always an important part of our Green Beauty mission."
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Garnier Global Brand President
Today, Garnier is a recomposed family of brands in four categories: haircare, hair color, skincare and suncare.
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Garnier on Instagram
Garnier's Green Beauty initiative is a complete end to end approach to sustainability. The aim is to transform every stage of Garnier's value chain, reducing or eradicating the brand's environmental impact: from ingredients sourcing to formulas, as well as packaging and industries.
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By 2025 Garnier will have empowered 1,500 communities worldwide as part of our Solidarity sourcing programme.
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*based on Garnier plastic consumption in 2019.
Factories & Manufacturing
100% Carbon Neutral industrial sites by 2025, through the use of renewable energy.
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Since March 2021, all Garnier products are officially approved by Cruelty Free International under the Leaping Bunny Programme, the leading organisation working to end animal testing.
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The Green Beauty initiative includes a Sustainability Progress Report, offering complete transparency on Garnier's commitments, which can be tracked publicly via the Garnier website. This report states where Garnier stands today, mapping out the process of how the brand will reach ambitious targets by 2025. It provides a clear and trackable summary of Garnier's commitments, work which has been completed with the help of experts and scientists. All data in the progress report has also been assessed by an external auditor, PricewaterhouseCoopers.
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With content produced by National Geographic CreativeWorks, Garnier will give consumers access to expert knowledge and real-world advice. This is a first step in a new commitment, from Garnier, which aims to encourage and empower 250 million people to live greener on the planet, by 2025.

redpajama_set_name: RedPajamaCommonCrawl


As old as civilization, Varanasi is not just a place but an experience. Varanasi Tour Packages take you to one of the ancient cities of the world. One of the most revered Hindu pilgrim places, the holy city of Uttar Pradesh is one which is to be definitely visited once in a lifetime. Nestled on the banks of the sacred River Ganga, it is a land of divine spirituality.
If divine bliss is available on the human plane it is definitely in Varanasi. Pay respects to the mighty Lord Shiva, the revered deity of the city. Witness a glorious Sunrise at the Ganges, while you glide on a boat. Attend the world-famous Ganga Aarti. Visit various temples. Varanasi holiday packages will leave you spiritually enriched. You can also visit other holy sites nearby.
Taste divine bliss, choose from our collection of Varanasi Travel Packages.


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National Boston Bombing Might Provide Leads in 2011 Slaying of Two Jews
Boston Bombing Might Provide Leads in 2011 Slaying of Two Jews
Tuesday, April 23, 2013 at 11:34 pm | י"ג אייר תשע"ג
BOSTON (AP/Hamodia) -
Authorities in a Boston suburb said they would investigate if any links turn up between a suspect in last week's Boston Marathon bombing and an unsolved 2011 slaying.
On Sept. 12, 2011, the bodies of Brendan Mess, 25, of Waltham; Erik Weissman, 31, of Cambridge; and Raphael Teken, 37, of Cambridge, were found in Mess's apartment. All three had been killed by an unknown assailant. Weissman and Teken were Jewish.
Middlesex County District Attorney's Office spokeswoman MaryBeth Long told The Associated Press that her office will not reveal details of its investigation or say if there's new information, but said investigators would follow up if the bombing probe provides any new clues into the slaying.
Brendan Mess was a boxer and friend of Tamerlan Tsarnaev, the 26-year-old terrorist who was pronounced dead Friday after a shootout with police. Mess's brother Dylan told the AP on Saturday that he and his brother both knew Tsarnaev, but declined to talk about him.
A Boston Globe profile of the Tsarnaev brothers first made the possible connection to the triple murder.
This article appeared in print on page D10 of the April 24th, 2013 edition of Hamodia.
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Putin allows transport safety officers to use electric shocks for self-defense
Transport safety officers to be allowed to use electric shocks for self-defense - bill
Transport safety employees may be allowed to use electric shocks for self-defense
© RAPSI, Vladimir Burnov
Tags: Legislation, Self-defence, Transport, Safety rules, Vladimir Putin, Russia
MOSCOW, December 3 (RAPSI) - A bill permitting employees of transportation security units to bear and use electric shocks for self-defense has become law. A version of the document signed by President of Russia Vladimir Putin has been released on the official website of legal information.
Previously, such possibility was not provided for transportation security units. "Employees are not entitled to use electric shockers on duty," according to an explanatory note to the bill.
As transport safety employees work in places of mass gathering, where the use of firearms is prohibited, they may use electric shockers for "active self-defense and suppression of acts of unlawful interference," the law reads.
However, according to the document, the transport security officers would be obliged to report all use cases to senior executives.
The law also prohibits use of electric shocks against pregnant women, children and disabled persons if there is no threat to transport security officers' life and health.
Amendments are to be introduced into the Federal Law "On Transportation Security". The document will take effect in 90 days after its official publication.
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09:57 03/12/2019 A bill permitting employees of transportation security units to bear and use electric shocks for self-defense has become law. A version of the document signed by President of Russia Vladimir Putin has been released on the official website of legal information.
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The Vaktovian Teamspeak 3 is an important tool in the Vaktovian Arsenal. Though not a standard "Robloxian" place, it is application software used by groups of clients to communicate in a secure and calm environment. The Vaktovian Empire uses the application as a means of advanced communication, effectively replacing all in-game chat with the more secure voice-based communication. This allowes better communication and teamwork during important events, such as raids and defences, where such advantages give Vaktovians an edge in the field.
Started at the beginning of the Vaktovian-Arcadian War, the original teamspeak 3 was hosted by Robloxian user "Flatflow", as a means of contesting the teamspeak 3 that was already owned by Arcadia.
A number of Officers saw the huge advantage a teamspeak 3 could give Vaktovia in a war they were going to loose at the time, and took to it. Officers included Colonel Nitroniks , the then Captain SWATCOLE and Colonel Domeboybeene.
Ownership changed hands to Vaktovian User, Mordaux, and under better ownership the Teamspeak 3 saw major goals hit.
By the end of the war, the client capacities and activity on Teamspeak 3 had made it a large part of Vaktovian culture and structure. Average client activity soared from 8-9 users to 20-30 in a matter of months, today, the average client usage of the Vaktovian Teamspeak 3 peaks at 50, with multiple events and channels avaliable to cater to all users needs and requirements.
At the beginning of the RAT-VAK war , Teamspeak 3 was being used in all major offensives, including invasions and as a stand for the Commentators in the VWG/VSG events. Client capacity was maxxed during the RAT Invasion, seeing 75 clients, including 10 Officers and the Emperor Himself being present.
Raido Vaktovia - The Broadcast system used by users who wish to listen to music.
Current maximum client capacities are 512, though this number has never been reached, with server technicians and administrators ensuring the teamspeak 3 remains optimmally configured. Teamspeak 3's layout and stature means that multiple events can be hosted, with many people speaking with the people they need to speak to and no one else, in order to avoid unneccessary noise.
Security ensured clients who are not Vaktovian are prevented from entering the Teamspeak 3, with permissions only being avaliable through an Officer, who cross-checks their profile to verify the identity of the user.
With numbers set to rise in the near future, the Vaktovian Teamspeak 3 is set to add more channels and more opportunities for soldiers and users of Vaktovia. The rewards for using the teamspeak 3 are unparralelled and the experience brought by it has not just changed but revolutionised the community that is Vaktovia.


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MY BRIEFCASE (0)
Back to Policyholder Protection
Across State Lines: Fighting Back Against Your Carrier's Forum-Shopping
September 19, 2016 | Insurance, Policyholder Protection
+ADD TO E-BRIEFCASE
Abby A. Vineyard
Co-authored by John Fischer and Abby Vineyard. If you have ever been involved in a coverage dispute with your insurance carrier, you likely already know the importance of determining which state's law will apply. This is because different courts interpret the same policy language differently – what is covered under one state's law may be outside the scope of coverage under the law of a different state, even under identical policy language. Thus, the question of which state's law will apply is often decisive on the question of whether coverage exists. Insurance carriers know this, too, and will try to find a way to ensure that the law of the state that is friendlier to carriers will apply to the dispute. In general, a litigant has a better chance of having its preferred state's law applied if it has the ability to choose where the suit is filed. This is because each state has its own set of "choice of law" rules that govern how the forum decides what law applies to the interpretation of contracts. For example, some states follow the rule of lex loci contractus, which provides that the law of the state where the contract was made governs disputes related to the contract. Other states apply a "significant contacts" test that requires courts to examine a series of factors to determine which state has the strongest relationship to the contract (which may be different than the state where the contract was made). Because certain states are more favorable to carriers on certain coverage or bad faith issues, whereas other states favor policyholders on those same questions, you and your carrier will likely disagree as to which state is preferable for resolving the coverage dispute. This may lead to a "race to the courthouse," particularly in coverage disputes that touch more than one jurisdiction (e.g., where the policyholder is headquartered in one state, the policy was issued in a different state, and the events giving rise to the underlying insurance claim happened in yet another state). You might find yourself in a situation where the carrier has "beat you to the punch" and filed a declaratory judgment action against you in its preferred state before you were able to prepare and file your complaint for breach of contract, bad faith, or declaratory relief against the carrier in your preferred state. Even so, the carrier's filing of a suit in its preferred state does not preclude you from filing your own suit against the carrier in the jurisdiction of your choice. If you file your own suit in your preferred forum, the carrier will undoubtedly rely on the purported "first-filed rule," which the carrier will argue provides that, in cases of concurrent jurisdiction, courts will usually defer to the suit previously filed in the other forum so long as the parties and issues are largely the same. The good news is that all is not lost if you find yourself in this situation. Courts have held that this rule is not to be applied mechanically, and there are exceptions under which the court will actually defer to your second-filed suit. One of the more prominent exceptions is when the carrier filed its suit in bad faith, or in anticipation of you filing suit, in an effort to "forum shop." Forum shopping is not allowed and thus a court will not give deference to the carrier's first-filed suit if it finds that the carrier's motive was to circumvent the law of the policyholder's preferred state and preempt an imminent action by the policyholder. Courts are also persuaded by the fact that a policyholder's suit, which likely includes claims for breach of contract and possibly bad faith, will necessarily resolve the issues the carrier likely raised in its declaratory judgment action (e.g., if, in the policyholder's suit, the court finds that the carrier breached the policy or acted in bad faith, it likely also determined that the carrier should have defended the policyholder or has a duty to indemnify). A carrier's declaratory judgment action will almost certainly not dispose of all of the issues between the parties, and, therefore, the policyholder's suit is preferable. Some jurisdictions have even asserted an express preference for the dispute to be resolved in a coercive suit for damages rather than in a declaratory judgment action, or a preference for the policyholder as the "natural plaintiff" over an insurer that is more accurately characterized as a defendant. Our federal system of government makes these issues even more complex – different legal principles and standards apply to the determination of the proper forum if the competing suits are filed in two different federal courts; in a federal court and a state court; in the courts of two different states; and in the courts of the same state. Whether you succeed in your fight for the dispute to be decided in your preferred forum depends on having a thorough understanding of the nuances of each of these situations. Another option you have if your carrier files suit in a forum that is less than desirable for you is to file a motion to transfer the action to a more appropriate venue (so long as the other venue would have jurisdiction over the suit), at which point the transferee court should combine the suits. Some of the key factors courts consider when deciding whether the proposed venue is more appropriate are the parties' forum preferences; whether the claim arose in a different forum; and the convenience and location of the parties, witnesses, and relevant documents. Courts also examine certain public interest factors such as the forum's interest in deciding local controversies and the familiarity of the trial judge with the applicable state law. In contract disputes, courts often also consider where the contract was negotiated and executed. Finally, even if you are forced to litigate in your carrier's preferred forum, you may still find that the court applies a different choice of law analysis than that of the forum state, or it applies one state's law to the breach of contract claim and another state's law to the bad faith claim. In sum, even if your carrier wins the race to the courthouse, you are not necessarily stuck in an unfriendly forum or with unfavorable law. If the forum and choice of law are the deciding factors between having coverage and not having coverage, you still have the ability to fight the carrier's choice of forum, and very well might end up getting into your preferred venue and having your preferred state's law apply.
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washingtonpost.com > Arts & Living
When Photos, Memories Are A Little Hazy
By Hank Stuever
So you've maybe got a famous murderer in the family. Or you were married to one. He's extradited, he's very much in the news, and he's just as creepy as you remember him. You'd like to smack him upside the haid. You'd also like to prove to the world what a complete, dweeb-faced liar he is.
To do that, however, the world needs for you to please go into your spare closets and basements and look for old Christmas photos of him, specifically from Dec. 26, 1996, to prove he wasn't in Boulder, Colo., with the dying JonBenet Ramsey, as John Mark Karr claims he was. The 41-year-old confessionalist will appear in court Monday in Boulder, and he still has yet to have his odd I-am-responsible-for-her-death story completely blown apart by that most efficient means of truth-telling: the family fact-check.
Karr's second wife, Lara Knutson, is convinced that there was a never a Christmas in the '90s where she wasn't with him, and about this her lawyer is quite emphatic. Implied in this is how stuck she was with him, too. She is still reportedly rooting through old paperwork and/or pictures, looking for miserable, but helpful, proof.
Imagine how that feels -- the world drums its fingers while you try to locate old stuff that demonstrates that one Christmas really can be different from all the others.
Christmas 1996. Not 1993, not 1994, not 1997.
One thing about life is you can always count on your family to call you on your BS. If they won't, then the people you went to high school with will gladly chime in. (One of Karr's former classmates has already produced the yearbook he signed, with its eerie similarities to the ransom note the Ramseys said was left in their house on the day they found JonBenet dead.)
But where are those old Christmas videos anyway? Did we send them to Bob Saget? Did you ever convert them to DVD? Did we throw them out? We might have. Remember the garage sale? Remember when you forgot to pay rent on the storage unit and, yeah, well, let's not chat about that. Okay, what about some Visa receipts for plane tickets, that kind of thing? Show us something to disprove his claim to have done things to that poor little girl.
Go ahead. We'll wait.
Rock stars and fanciful memoirists are often exempt from the truth that your family is only too happy to publicly correct. Everyone else must pass muster with the people who know them best.
Karr's father and half brother are also on the case, letting the world know through their attorney and on "Good Morning America" that Karr never went to Boulder, never had a dime to spare for things like last-minute plane tickets, and just isn't the kind of fellow who could get it together enough to pull off a sophisticated, no-traces crime, and was either with one part of the family in Georgia, or with another part in Alabama on that holiday. "It's not as easy as you might think to remember 10 years ago," Nate Karr, the half brother, said on TV, according to the Associated Press. But he wanted to his brother to know: "We love you and we support you 100 percent. . . . Help's on the way."
This branch of the family also signed over the rights to a possible movie deal this week, which their attorney said is to help pay for college costs for Karr's three children. They also dug through pictures and came up with one of Karr's kids visiting with the family at Christmastime 1996, in Atlanta, which they say means Karr also had to be there.
Alas, he is not in the picture, they said. And anyhow, what about the picture proves that it was in 1996? (Are there Spice Girls in it?) So the family keeps searching, at cross-purposes: If you find evidence he was with you that Dec. 26, then you've also just soured your movie deal.
Pictures lie in all sorts of ways, and so they do not always aid those many families who specialize in a never-ending debate about what happened when. In some families, everyone is literally a lawyer, and so a get-together can collapse under the heated discussion of whether an event occurred in 1983 or 1982.
In many other families, everyone just acts like a lawyer. Evidence is submitted (photos, birth dates, graduation years, weddings, deeply held resentments over ill-received Christmas gifts, memories of a Top 40 song from a certain summer), and even then the jury can remain deadlocked. Mom, with all her authority, cannot solve these debates, and often she instigates them with her own fuzzy inaccuracy. Dad, who should be a Solomon, pretends not to listen.
Perhaps Karr did not grow up in one of these families. He lived among people for whom 1996 was just another damn year. There have been a lot of Christmases without him. Indeed, the family has said they wrote him off for dead -- without actually locating him, or filing some of the paperwork that could literally write a man off. In this way, they leave a lot to be desired as completionists, archivists, or the kind of folks who'd simply keep the photo albums organized. They are destined to disappoint the prosecutor and defense attorney who dwells within each cable-news viewer.
The Karrs obviously need some more scrapbookers in their lives. What JonBenet Ramsey had in terms of home videos and photographs, the Karrs do not seem to possess. In the course of writing feature stories or filming documentaries, a journalist will surely come to rely on the scrapbooker-aunt type, who excuses herself to a guest room mid-interview and will always emerge with the right evidence, the right picture, the right scrap of dress material or recital program, the right yearbook. Defense lawyers also adore this particular relative.
So you may have a murderer in the family.
Well, you'll show him. You'll show CNN, too. You'll go through every one of these shoeboxes, and then everyone will see how right you are.
An alibi: It can be such a nice thing to have, in most families.


If you're looking to snag some stylish shoes like me get the fashion scoop on a few trendy styles from these amazing stores. Check out my video feature!
Yes, I never really shopped there until they opened a new one near my house. I am in there at least once a week now.
Which style? The pom pom?
Yes so perfect for date night, LOVE.
Yes my favorite as well, love them!!
Those shoes are super cute! I love those poms poms, it'll be perfect in the summer and I can't believe how inexpensive they are.
Great video :) ! I definitely prefer chunky heals :) !
Great finds! You can't have enough shoes...I'm in the middle of updating my stash, so a great inspiration!
Who doesn't love shoes and for that price? Ugh wish I could go shopping for some summer goodies now.
Adore those strappy brown heels! Those are GORGEOUS for summer!!
Those sandals are adorable! You got some good finds!
Shoes are awesome but shoes for a great price are irresistable. Super cute sandals!
Oh gosh those are so cute!! Especially for short people like me lol! I'm always shopping there and rarely find shoes my size and they usually run big which is difficult for a size 6!
I know shoes are always a great buy.
The cage style!! Yes I am hoping to rock them a bit more.
Thanks, yes I definitely saved.
The flats from Chinese Laundry are super cute! I will be checking out Burlington. I had no ide what their selection was like! Thanks for sharing.
Yes, I need to make a run this week. Hope you fin something good.


A selection of hymn and song suggestions, based on themes from the Roman Catholic lectionary for the twenty ninth Sunday of Ordinary Time, Year A.
Most are free-to-use (ie public domain or copyright-free), so the words can be copied and sung to at least one tune with no concerns about copyright or performance licensing - sometimes in a limited setting. Many of these hymns are old / traditional - but where possible a variety of styles and genres are included.
A small selection of hymns which may still be copyright is also included, for items which are particularly relevant.
First: Isaiah - The Lord anoints Cyrus, who he has called by name ... so that all may know from the rising of the sun to the setting that apart from God there is nothing.
Psalm 95 - Give the Lord glory and power / O sing a new song to the Lord / The Lord is great and worthy of praise / Give the Lord you families of people / Worship the Lord in his temple.
Second: I Thessalonians - Paul greets the church, and says that they are constantly remembered in his prayers ... for their faith in action .. you have been chosen ... because the Good News came to you as power and the Holy Spirit.
Gospel: Matthew 22 - Give to Caesar what belongs to Caesar - and to God what belongs to God.
See lectionary art for this Sunday for suggested pictures and art-works based on today's readings.
Suggestions about hymns that could be included are welcome: please leave a comment below.


The World Trade Organization (WTO) is an organization that strives for free international trade. It replaced the General Agreement on Tariffs and Trade (GATT) in 1995. The WTO acts as an arbitrator for countries who are members and participate in the organization. Most of the world is or is willing to become a member of the WTO because of the benefits it can supposedly bring, but it's really an organization designed around protecting one's domestic markets, especially the larger countries.
The World Trade Organization was formed in 1995 replacing the General Agreement on Tariffs and Trade (GATT), which was formed in 1948. For over forty years the GATT lead trade agreements and mainly tariffs agreements. The WTO was formed to settle conflicts between trade based under the principles of being non-discrimination, reciprocity, transparency and binding and enforceable commitments. Most trade conflict come around high tariffs on particular goods or goods that country's think are potential dangerous. The WTO however has no actual power to enforce such ruling but relies on the larger more developed countries to enforce such rulings. Throughout the past 19 years there have been hundreds of cases brought to the attention of the WTO.
Is Altruism A Free Riding?


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PO-8518 Mr E complaint
Employer misrepresentation induced employee to agree a start date that acted to his detriment
Mr E complained that LBG had not provided him with a preserved pension following the transfer of his contract of employment to TSB under the Transfer of Undertakings (Protection of Employment) regulations (TUPE). He claimed that he was assured he would receive membership of the Scheme but ultimately his contributions were returned, with the consequence that he lost his employer contributions for a little under three months. The Pensions Ombudsman upheld his complaint.


As a Chief Petty Officer in the Navy, Shane Krueger has been to 37 different countries, so he knows something about being a stranger in a strange land. He takes this to a different extreme with his favorite football team, the Denver Broncos. Living deep in Seahawks country, Krueger is outflanked and outnumbered. But he's never out-spirited.


Written in England, 1777 (f. 74v).
Recipe book containing mostly recipes for wine, cooking, and preserving, plus a few medical and veterinary prescriptions; and a few recipes for cleaning plate, fumigating rooms, etc. In addition to English recipes are some that show continental influence, for example, those for French bread, French fritters, Paris curd, Dutch biscuits, and Portugal cakes. Includes a table of contents for 163 numbered recipes (f. 1r-2v). A leaf laid in the front from A.B. and addressed to Mrs. Edward Browne appears to be dated Feb. 1, [1808?] "To make a sweet jar;" the same recipe is copied in the same hand on f. 4v.
Two leaves laid in are shelved with the manuscript.
Paper, 74; [1-74]; modern foliation in pencil, upper right recto.


Pace Runners Inc is located at the address Po Box 1509 in Pelham, Alabama 35124. They can be contacted via phone at (205) 621-9013 for pricing, hours and directions.
For maps and directions to Pace Runners Inc view the map to the right. For reviews of Pace Runners Inc see below.


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text:
South River man charged with robbery, assault following social media tips
Susan Loyer
SAYREVILLE - Social media tips led to the arrest of a South River man, who was charged in an alleged assault and robbery of an elderly man in the restroom of the Cheesequake Service Area on the Garden State Parkway,
Luke Benneman, 46, was charged with robbery, aggravated assault and theft by unlawful taking in the alleged the Nov. 8 incident, according to the New Jersey State Police Facebook page. Benneman was lodged at the Middlesex County Adult Corrections Center in North Brunswick pending a bail detention hearing.
READ:NJ football: 22 players ejected in game between South River and Delran
READ:South Amboy ferry service to Manhattan one step closer to fruition
On Nov. 9, state police asked its social media followers to like and share a post that showed surveillance video of a suspect as he entered the service area on Nov. 8.
In the alleged incident, which occurred around 3:15 a.m., the suspect allegedly punched an elderly man several times in the bathroom and threw him to the ground, before stealing his wallet, the post said.
The suspect was then seen leaving the building wearing a black knit cap and safety glasses on his head. He then fled northbound on the Garden State Parkway in an unknown vehicle.
Thanks to tips, detectives from Troop "D" Criminal Investigations Office were able to identify Benneman, the post said.
On Monday, detectives located Benneman and arrested him without incident.
The New Jersey State Police thanked the public for the numerous calls and tips that led to the arrest.
Staff Writer Susan Loyer: 732-565-7243; sloyer@gannettnj.com


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\section{I: Band structures of the type I\hspace{-1pt}I film and thermal transport properties}

This section describes the band structures for the type I\hspace{-1 pt}I truncation case in TNLS films, and examines their thermal transport properties.
The band structure for the type I\hspace{-1 pt}I case is shown in Fig. \ref{type2} (a). The projected bulk nodal line is a gapless point, as in the type I case. However, in contrast to the type I case, midgap surface states were not found. We can explain this difference from the perspective of the topological materials.

In our model, the band inversion at the $\Gamma$ point occurs between two bands with different parities, so the $\mathbb{Z}_2$ index \cite{ fukane2007topological, kim2015dirac} is calculated as $(1;111)$. This index represents a TNLS in a case where spin-orbit coupling is negligible, and there is a strong topological insulator for a strongly spin-orbit coupled case. In TNLSs, the $\mathbb{Z}_2$ index is directly related to the Zak phase. In this case, the Zak phases at the surface $\Gamma$ point and the surface X points differ by $\pi$. This difference in the Zak phase corresponds to the difference in the number of occupied bands at the $\Gamma$ and X points. A band localized at the surface \cite{vanderbilt1993electric}, actually crosses the Fermi energy near the gapless points. However, the Zak phase does not guarantee that the band will be a ``midgap" surface state. The detailed energy of the band depends on the surface parameters. In our thin film model, we used the same parameters as the bulk model, so the band is located at the upper edge of the bulk occupied band spectrum in the type I\hspace{-1 pt}I case.

However, in realistic materials, the surface parameters may change when the surface is made. Therefore, the surface state tends to appear as an isolated midgap state. For example, in our model, the type I\hspace{-1 pt}I film does not have the same number of A and B sites. In realistic materials, this corresponds to an imbalance between donors and acceptors. This can change the one-body potential of A site on the surface, and the band localized on the surface at the X point (and M point) can shift towards the Fermi energy. This is why drumhead surface states in TNLSs have been experimentally observed and reported in many previous studies, as explained in the main text.

The thermoelectric transport properties and figure of merit ($ZT$) for type I\hspace{-1 pt}I films with various thicknesses are shown in Fig \ref{type2} (b) and (c). The temperature was set to approximately room temperature, $k_BT=2.5\times10^{-2}$. In contrast to the type I case, the absolute value of $S$ and the layer dependence are small, which results in a banal value of $ZT$. However, in realistic materials, we can expect large values of $S$ and $ZT$, even for the type I\hspace{-1 pt}I case, because of the surface reconstruction described above.

\begin{figure}[h]
  \centering
\rotatebox{0}{\includegraphics[width=0.8\linewidth]{figsupA.pdf}}
\caption{(a) Band structures of a 10-layer TNLS film with type I\hspace{-1pt}I truncation along the high symmetry points of the Brillouin zone. The coordinates of the high-symmetry points are given in the caption of Fig. 2. The dashed line represents the Fermi energy. The right panel shows the DOS. (b) Chemical potential dependence of the Seebeck coefficients $S$ and $ZT$ for the type I\hspace{-1 pt}I TNLS film. Red, green, and blue lines represent the results for 5-, 10-, and 20-layer films, respectively.}
\label{type2}
\end{figure}
\section{I\hspace{-1pt}I: Detailed derivation of $L_{11}$}
In this section, we present a detailed derivation of $L_{11}$. The electric conductivity $L_{11}$ under a uniform electric field is obtained from the equation
\begin{equation}
    L_{11}=\left.\frac{\Phi_{\mu\nu}(\omega)-\Phi_{\mu\nu}(0)}{i(\omega+i\delta)}\right|_{\omega\to0},
\end{equation}
where $\Phi_{\mu\nu}(\omega)=\left.\Phi_{\mu\nu}(i\omega_\lambda)\right|_{i\omega_\lambda\to\hbar\omega+i\delta}$. The quantities $\omega$ and $\omega_n$ are the frequency, and Matsubara frequency, respectively, and $i\omega_\lambda\to\hbar\omega+i\delta$ describes the analytic continuation.
If the vertex correction is negligible, then
\begin{equation}
  \begin{aligned}
    \Phi_{\mu\nu}(i\omega_\lambda)&=\frac{1}{V}\int_0^\beta d\tau\langle T_\tau\hat{j}_\mu(\tau)\hat{j}_\nu(0)\rangle e^{i\omega_\lambda\tau}\\
    &=-\frac{2e^2k_BT}{\hbar^2 V}\sum_{n,{\bm k}}\frac{\partial \epsilon_{\bm k}}{\partial k_\mu}{\mathcal{G}}({\bm k},i\epsilon_n-i\omega_\lambda)\frac{\partial \epsilon_{\bm k}}{\partial k_\nu}{\mathcal{G}}({\bm k},i\epsilon_n),
  \end{aligned}
\end{equation}
where the thermal Green's function within a constant relaxation time approximation is
\begin{equation}
{\mathcal{G}}({\bm k},i\epsilon_n)=\frac{1}{i\epsilon_n-\epsilon_{\bm k}+\mu+\frac{i\hbar}{2\tau}\text{sign}(\epsilon_n)}.
\end{equation}
Taking the Matsubara summation using a residue integral and analytical continuation $i\omega_\lambda\to\hbar\omega+i\delta$, we obtain
  \begin{equation}
    \begin{aligned}
      \Phi_{\mu\nu}(\omega)&=\frac{2e^2}{\hbar^2V}\sum_{\bm k}\frac{\partial \epsilon_{\bm k}}{\partial k_\mu}\frac{\partial \epsilon_{\bm k}}{\partial k_\nu}\times\\&\qquad\int_{-\infty}^\infty\frac{d\epsilon}{2\pi i}f(\epsilon)\left[G^R({\bm k},\epsilon)G^R({\bm k},\epsilon_+)-G^A({\bm k},\epsilon)G^R({\bm k},\epsilon_+)+G^A({\bm k},\epsilon_-)G^R({\bm k},\epsilon)-G^A({\bm k},\epsilon_-)G^A({\bm k},\epsilon)\right].
    \end{aligned}
  \end{equation}
Here, $G^A({\bm k},\epsilon)=G^{R*}({\bm k},\epsilon)$ and $\epsilon_\pm=\epsilon\pm\hbar\omega$. Therefore,
\begin{equation}
  \begin{aligned}
    L_{11}&=\frac{1}{i\omega}\frac{2e^2}{\hbar^2V}\sum_{\bm k}\frac{\partial \epsilon_{\bm k}}{\partial k_\mu}\frac{\partial \epsilon_{\bm k}}{\partial k_\nu}
    \int_{-\infty}^\infty\frac{d\epsilon}{2\pi i}f(\epsilon)(\hbar\omega)\left[(G^R-G^A)\frac{\partial}{\partial\epsilon}(G^R-G^A)\right]\\
    &=\frac{2e^2}{\pi\hbar V}\sum_{\bm k}\frac{\partial \epsilon_{\bm k}}{\partial k_\mu}\frac{\partial \epsilon_{\bm k}}{\partial k_\nu}\int_{-\infty}^\infty d\epsilon \left(-\frac{\partial f}{\partial \epsilon}\right)\left[{\mathrm{Im}}G^R({\bm k},\epsilon)\right]^2.
  \end{aligned}
\end{equation}
Inserting $G^R({\bm k},\epsilon)=1/(\epsilon-\epsilon_{\bm k}+i\hbar/2\tau)$ and executing a residue integral, finally gives
\begin{equation}
L_{11}=\frac{4\tau e^2}{\hbar^2V}\sum_{\bm k}\frac{\partial \epsilon_{\bm k}}{\partial k_\mu}\frac{\partial \epsilon_{\bm k}}{\partial k_\nu}(-f'(\epsilon_{\bm k})).
\end{equation}
\section{I\hspace{-1pt}I\hspace{-1pt}I: Mean Field Approximation}
In the mean-field approximation, the Hubbard interaction is decoupled into
\begin{equation}
  H_U\sim \sum_{i,\alpha=A,B}U_\alpha(\langle n_{i\uparrow}^\alpha\rangle n_{i\downarrow}^\alpha+n_{i\uparrow}^\alpha\langle  n_{i\downarrow}^\alpha\rangle-\langle n_{i\uparrow}^\alpha\rangle \langle n_{i\downarrow}^\alpha\rangle).
\end{equation}
When we ignore particle number deviations within the same layer, the mean-field parameters are the layer, sublattice, and spin indices. Then, the values of the 4$N_\ell$ parameters are determined by a self-consistent calculation, where $N_\ell$ is the number of layers, and we set $N_\ell=10$.

Once the self-consistent equations are solved, we can define the magnetization for each layer and sublattice as
\begin{equation}
  M_\ell^\alpha=\langle n_{\ell\uparrow}^\alpha \rangle-\langle n_{\ell\downarrow}^\alpha \rangle,
\end{equation}
where $\ell$ is the index of the layer. Moreover, the full Hamiltonian can be divided into
\begin{equation}
  H=H_\uparrow\oplus H_\downarrow.
\end{equation}
Then, the thermoelectric transport coefficients $L_{ij}^\sigma$ are calculated using the energy spectrum of $H_\sigma$.
\section{IV: Magnetic structures for the five phases in a TNLS film with correlations}

Fig. \ref{surfacemag_detail}(a) shows the correlation dependence of the surface and bulk magnetization.
When $U$ is small, the system remains in the nodal line semimetal state, and does not exhibit finite magnetization. Subsequently, it enters into a surface ferromagnetic phase, which we call the SF-I phase at $U/E_0=2.38$. In this phase, the magnetization of one side of the surface increases, and that of the other layers remains small (see the top panel of Fig. \ref{surfacemag_detail}(b)). Then, we encounter two phase transitions at $U/E_0=2.56,2.59$. Although the differences in the features of these two phases, which we name SF-I\hspace{-1 pt}I' and SF-I\hspace{-1 pt}I, respectively, are unclear, we find that the magnetization of both sides of the surface is more conspicuous than that of the bulk in the SF-I\hspace{-1 pt}I phase (see the bottom panel of Fig. \ref{surfacemag_detail}(b)). As $U$ increases, not only the surface magnetization but also the bulk magnetization grows, and the system enters into the N$\acute{\mathrm{e}}$el ordered phase at $U/E_0=2.87$. We note that even in this N$\acute{\mathrm{e}}$el ordered phase, the amplitude of magnetization for each layer is not uniform and a similar property of deviation to the SF phases remains, but the difference between the surface magnetization and the bulk magnetization is reduced.

\begin{figure}[H]
  \centering
\rotatebox{0}{\includegraphics[width=0.8\linewidth]{figsupB.pdf}}
\caption{(a) Correlation $U$ dependence of the surface and bulk magnetization. The blue solid (dashed) line describes the result for the sublattice A layer at the surface (bulk), and the orange lines describe the corresponding results for the sublattice B layer. Here, we adopt $\ell=10$ as the surface layer and $\ell = 5$ as the bulk layer. The inset shows an extended view around the phase transition points, and the phase boundaries are also presented. (b) Magnetization of each layer. Top: SF-I phase ($U/E_0=2.47$). Bottom: SF-I\hspace{-1 pt}I phase ($U/E_0=2.67$). The black squares (red circles) show the magnetization of sublattice A (B).}
\label{surfacemag_detail}
\end{figure}

redpajama_set_name: RedPajamaArXiv


text:
Weekly Times (Melbourne, Vic. : 1869 - 1954)
Sat 24 Aug 1912
Articles from page 27: Previous page Next page
GOLF IN THE COUNTRY: TOURNAMENT AT KILMANY PARK, SALE.
RICHMOND FOOTBALL CLUB.The youngest players of League football are found in the Richmond team, which recently visited Tasmania. The photograph was taken in Hobart. WARRNAMBOOL PIONEERS. ... [ILLUSTRATED]
(1912, August 24). Weekly Times (Melbourne, Vic. : 1869 - 1954), p. 27. Retrieved January 23, 2020, from http://nla.gov.au/nla.news-page23978658
Weekly Times (Melbourne, Vic. : 1869 - 1954) 24 August 1912: 27. Web. 23 Jan 2020 <http://nla.gov.au/nla.news-page23978658>.
1912, Weekly Times (Melbourne, Vic. : 1869 - 1954), 24 August, p. 27. , viewed 23 Jan 2020, http://nla.gov.au/nla.news-page23978658
{{cite news |url=http://nla.gov.au/nla.news-page23978658 |newspaper=[[Weekly Times]] | location=Victoria, Australia |date=24 August 1912 |access-date=23 January 2020 |page=27 |via=Trove }}
Weekly Times (Melbourne, Vic. : 1869 - 1954), Sat 24 Aug 1912, Page 27


text:
Todd Frazier: The Best is Yet to Come
Michael Maffie
According to modern thinking about player aging curves, hitters begin to decline as soon as they reach the big leagues. Yet, Todd Frazier, at the age of 29, seems to be beating the odds by posting a career best 143 wRC+ and 1.9 WAR though a quarter of the season. Is Frazier's new production destined to fall back to his 2014 levels or below, or as Frazier's New Jersey hero Frank Sinatra might say, is Todd Frazier's best yet to come? (Mandatory background music for reading this post)
2012-2014: Steady Production
Frazier's broke into the league with an outstanding .273/.331/.498 slash line in 2012. He experienced a sophomore slump, only batting .234/.314/.407 and his isolated power fell from .225 to .173. In 2014, Frazier bounced back, hitting .273/.336/.459 with an ISO of .186.  Was Frazier's down year in 2013 a function of bad luck? After all, Frazier's BABIP was .269 in 2013 compared to .316 in 2012 and .309 in 2014. Frazier's batted-ball profile, in fact, should have produced a BABIP of .309 in 2013. So his luck on balls hit in play explains almost all of Frazier's drop in average and on-base percentage. Frazier's strikeout (K%) and walk rate (BB%) stayed relatively constant from 2012-2014, as did his swinging strike (SwStr%) rate. Broadly speaking, Frazier's offensive performance from 2012 through 2014 appears largely steady.
2015: Promising Start
Frazier has jumped out to a big start in 2015. He's hitting .252/.347/.551 and on pace to hit 45 home runs. His isolated power is a career-best .299, third best in the National League. The obvious question arises, has Frazier been lucky or good? Well, the surprising news is that Frazier's underlying fundamentals are strong, and indicate a possible jump to a higher level of results. He's swinging at far fewer pitches out the strike zone. His O-Swing% is 30.9, a career low and substantially below his career average of 33.4 percent. His contact rate is a career high and swinging strike rate a career low. This has produced a strikeout rate (16.5 percent) far below his career average and easily his best. Same with Frazier's walk rate (10.6 percent), a career best and way below his average.
On top of all this, Frazier's BABIP (.236) is extremely low. Given his batted ball profile (number of line drives, ground balls and fly balls) his BABIP should be .329. In plain speaking, Frazier not only has been hitting the ball out of the park at a personal-best pace, he has been pounding it inside the park as well, with not much to show for it yet. This play from Wednesday night is an apt example:
Frazier's batting average may be a bit low, but given everything else that we know about his performance at the plate, that's nothing to worry about.
In terms of home runs, is the power spike believable? The early data supports an affirmative conclusion. Frazier's average batted ball distance continues to increase.
As you would expect, Frazier's hard hit ball numbers fall in line with higher home run numbers.
Frazier is still showing good coverage on the outer part of the plate. This was a crucial development last year that boosted Frazier's home run number from 19 to 29. He hit more home runs to center and right field.  Here is Frazier's heat map from this year, showing his isolated power (ISO) hot spots.
[Credit: ESPN Stats and Information]
But Frazier so far hasn't flashed as much opposite and centerfield power as he did last year, at least so far. Here's a comparison of his spray charts, with 2015 on the left.
Credit: FanGraphs
Yes, practically every shred of data points in the direction of higher production for Todd Frazier in 2015. But before we start celebrating too much, it's worth remembering a cautionary tale from 2014. Frazier showed similar gains in O-Swing, swinging strikes, line drive, walks and strikeouts last year. We even published an article like this one just about a year ago, only to see Frazier go through a massive slump in the second half of the year. At the All-Star break, he was hitting .290/.353/.500 with and ISO of .210. For seven weeks after that, Frazier cratered, along with many of his teammates. He averaged one extra-base hit a week during that stretch. He bounced back a bit the final three weeks of the season. At the end of the roller coaster, Frazier's numbers had settled back into his career norms.
So what does that say about 2015? On the one hand, it confirms that strong early starts, like the one Todd Frazier is enjoying right now, can be undone by late-season slumps. That career arcs are hard to budge. On the other hand, Frazier's numbers look crazy good right now. If he could find a way to avoid that terrible patch and if Alex Gordon would quit running through fences to catch Frazier's extra-base hits, SuperTodd could obliterate his career-best numbers, hang a sharp left on his aging curve and put himself at the top tier of NL leader boards.
Todd Frazier will remain under Reds team control through the 2017 season. He's signed for $7.5 million next year and is eligible for arbitration in 2017. If the Reds do pursue a serious rebuilding effort, will Frazier be a part of it? After trading Cueto, Leake, Chapman and more, the Reds might not be contenders again until 2017 or 2018, with Frazier gone off to free agency. Should the Reds entertain thoughts of trading Frazier at the end of 2015 to get maximum return? With two cost-controlled years remaining before SuperTodd reached free agency, he would bring back a huge windfall of players. On the other hand, he might be exactly the kind of cornerstone veteran the team needs in its next stage of competition.
But the good news is, all signs are pointing to an extremely productive year for Todd Frazier.
Behind Enemy Baselines: Kauffman Stadium
How to Hit for Power, or Double Trouble
Introducing the Trade Palatability Index (or why Trading Scooter Gennett is going to hurt so, so much)
Wesley Jenkins
The Reds front office must finish the rebuild | Steve Mancuso


text:
Stunning Transhumanism Dominates New 'Ghost in the Shell' Trailer
Paramount/Dreamworks
Ryan Britt
Though Blade Runner is coming back this fall, Ghost in the Shell will give it a run for its cyberpunk money. As the Major (Scarlett Johansson) regains her quasi-human memories, her story doesn't just dabble in cyberpunk, it revels in it.
The arresting new trailer for Ghost in the Shell makes previous cyborg or transhumanist cyberpunk movies — like The Matrix — seem quaint. Literally everyone in in this trailer sports some kind of biohacking or cyborg accoutrements. But Scarlett Johansson's "the Major" mashes up visual cyberpunk cues with a convincing and totally immersive aesthetic. It's not just that the new Ghost in the Shell trailer looks cool; its that it looks believable.
Giving audiences the most extensive visual details yet, the trailer also introduces what will probably be the film's primary baddie: the mysterious Kuze. In the narrative of previous iterations of Ghost in the Shell (a manga and an anime movie), the Major's human consciousness is put inside of robot body, making her a spiritual cyborg. In the new film, Kuze is seemingly at the center of the conspiracy surrounding her complex origin.
Ghost in the Shell opens on March 31.


text:
package org.apache.geode.internal.protocol.protobuf.v1.operations;

import static org.assertj.core.api.Assertions.assertThat;
import static org.assertj.core.api.Assertions.assertThatThrownBy;
import static org.mockito.ArgumentMatchers.any;
import static org.mockito.Mockito.mock;
import static org.mockito.Mockito.verify;
import static org.mockito.Mockito.when;

import org.junit.Before;
import org.junit.Test;
import org.junit.experimental.categories.Category;

import org.apache.geode.cache.Region;
import org.apache.geode.cache.RegionDestroyedException;
import org.apache.geode.internal.protocol.TestExecutionContext;
import org.apache.geode.internal.protocol.protobuf.v1.BasicTypes;
import org.apache.geode.internal.protocol.protobuf.v1.ClientProtocol;
import org.apache.geode.internal.protocol.protobuf.v1.ProtobufRequestUtilities;
import org.apache.geode.internal.protocol.protobuf.v1.ProtobufSerializationService;
import org.apache.geode.internal.protocol.protobuf.v1.RegionAPI;
import org.apache.geode.internal.protocol.protobuf.v1.Result;
import org.apache.geode.internal.protocol.protobuf.v1.Success;
import org.apache.geode.internal.protocol.protobuf.v1.serialization.exception.DecodingException;
import org.apache.geode.internal.protocol.protobuf.v1.serialization.exception.EncodingException;
import org.apache.geode.test.junit.categories.ClientServerTest;

@Category({ClientServerTest.class})
public class RemoveRequestOperationHandlerJUnitTest
    extends OperationHandlerJUnitTest<RegionAPI.RemoveRequest, RegionAPI.RemoveResponse> {
  private static final String TEST_KEY = "my key";
  private static final String TEST_VALUE = "my value";
  private static final String TEST_REGION = "test region";
  private static final String MISSING_REGION = "missing region";
  private static final String MISSING_KEY = "missing key";
  private Region<String, String> regionStub;

  @SuppressWarnings("unchecked")
  @Before
  public void setUp() {
    regionStub = mock(Region.class);
    when(regionStub.remove(TEST_KEY)).thenReturn(TEST_VALUE);
    when(regionStub.containsKey(TEST_KEY)).thenReturn(true);
    when(regionStub.containsKey(MISSING_KEY)).thenReturn(false);

    when(cacheStub.<String, String>getRegion(TEST_REGION)).thenReturn(regionStub);
    when(cacheStub.getRegion(MISSING_REGION)).thenReturn(null);
    operationHandler = new RemoveRequestOperationHandler();
  }

  @Test
  public void processValidKeyRemovesTheEntryAndReturnSuccess() throws Exception {
    RegionAPI.RemoveRequest removeRequest = generateTestRequest(false, false).getRemoveRequest();
    Result<?> result = operationHandler.process(serializationService, removeRequest,
        TestExecutionContext.getNoAuthCacheExecutionContext(cacheStub));

    assertThat(result).isInstanceOf(Success.class);
    verify(regionStub).remove(TEST_KEY);
  }

  @Test
  public void processReturnsUnsuccessfulResponseForInvalidRegion() {
    RegionAPI.RemoveRequest removeRequest = generateTestRequest(true, false).getRemoveRequest();
    assertThatThrownBy(() -> operationHandler.process(serializationService, removeRequest,
        TestExecutionContext.getNoAuthCacheExecutionContext(cacheStub)))
            .isInstanceOf(RegionDestroyedException.class);
  }

  @Test
  public void processReturnsSuccessWhenKeyIsNotFound() throws Exception {
    RegionAPI.RemoveRequest removeRequest = generateTestRequest(false, true).getRemoveRequest();
    Result<?> result = operationHandler.process(serializationService, removeRequest,
        TestExecutionContext.getNoAuthCacheExecutionContext(cacheStub));

    assertThat(result).isInstanceOf(Success.class);
  }

  @Test
  public void processThrowsExceptionWhenUnableToDecodeRequest() {
    Exception exception = new DecodingException("error finding codec for type");
    ProtobufSerializationService serializationServiceStub =
        mock(ProtobufSerializationService.class);
    when(serializationServiceStub.decode(any())).thenThrow(exception);

    BasicTypes.EncodedValue encodedKey = BasicTypes.EncodedValue.newBuilder()
        .setJsonObjectResult("{\"someKey\":\"someValue\"}").build();

    RegionAPI.RemoveRequest removeRequest =
        ProtobufRequestUtilities.createRemoveRequest(TEST_REGION, encodedKey).getRemoveRequest();
    assertThatThrownBy(() -> operationHandler.process(serializationServiceStub, removeRequest,
        TestExecutionContext.getNoAuthCacheExecutionContext(cacheStub)))
            .isInstanceOf(DecodingException.class);
  }

  private ClientProtocol.Message generateTestRequest(boolean missingRegion, boolean missingKey)
      throws EncodingException {
    String region = missingRegion ? MISSING_REGION : TEST_REGION;
    String key = missingKey ? MISSING_KEY : TEST_KEY;
    BasicTypes.EncodedValue testKey = serializationService.encode(key);
    return ProtobufRequestUtilities.createRemoveRequest(region, testKey);
  }
}

redpajama_set_name: RedPajamaGithub


Loki is fascinating. We don't quite have all of its genome, roughly 92% of it. There are bits missing for parts of ATP synthase and for the carbon monoxide dehydrogenase/acetyl-CoA synthase (CODH/ACS) complex but we can be pretty sure these are in that missing 8% of the genome which we have yet to find and sequence. After all, prokaryotes don't carry junk DNA. Having most of the genes for a functional complex suggests that the rest of those needed to make it work are present.
What is completely absent is anything suggesting any sort of respiratory chain. That's not so unusual, especially in anaerobes.
Or any sort of membrane pump.
No membrane pump? I suspect that there must be small ion pump of some sort either tucked away in the missing 8% of the genome or within some of the currently uninterpretable DNA. Certainly none of the large modern complex pumps are present in any part, so Ech, Rnf and MtrA-H are all out, although the MtrH gene alone is present. I'd assume MtrH is transferring methyl groups to somewhere other than to the absent MtrA-G Na+ pump, over to CODH/ACS seems most likely.
The core energy process appears to be based on using electron bifurcating hydrogenases to generate very low potential ferredoxins. This allows the CODH/ACS complex to generate acetyl phosphate or acetyl-CoA. Substrate level phosphorylation can then give ATP and it's all down hill, energetically speaking, from there onwards. This gives a strict anaerobic metabolism based on an external source of hydrogen.
Obviously a membrane gradient has many uses in addition to ATP synthesis so I wouldn't doubt for a moment that one is present. Keeping it energised is the trick.
It left me thinking about how you might generate a membrane potential in the absence of any obvious relative to modern day ion pumps. I recalled that Koonin had mentioned some very ancient sodium pumps based around either decarboxylation reactions or around pyrophosphate cleavage.
"These ancestral ATPases [ATP synthase in reverse] would pump Na+ along with the Na+-transporting pyrophosphatase  and chemically-driven Na+-pumps, such as Na+-transporting decarboxylase [29,63], which, being found in both bacteria and archaea, appear to antedate the divergence of the three domains of life".
"The role of Na+-PPase can be most easily conjectured in the thermophilic marine bacterium, T. maritima, which utilizes Na+ as the primary bioenergetic coupling ion and employs a Na+-ATP-synthase (35, 36). In this organism, Na+-PPase may work in concert with Na+-ATP-synthase to scavenge energy from biosynthetic waste (PPi) in order to maintain the Na+ gradient, especially under energy-limiting conditions".
"A prominent example is Propionigenium modestum, which grows from the fermentation of succinate to propionate and CO2 (Schink and Pfennig, 1982; Dimroth and Schink, 1998). The free energy of this reaction is about -20 kJ/mol whereas approximately -70 kJ/mol is required to support ATP synthesis in growing bacteria (Thauer et al., 1977). To solve this apparent paradox, 3–4 succinate molecules must be converted into propionate before one ATP molecule can be synthesized".
This last process is somewhat more complex than pyrophosphate hydrolysis and looks less of a candidate for "hidden" membrane potential generation than the Na+PPase. After all, CODH/ACS is providing ATP and many reactions which need to be "one-way" cleave ATP to AMP and PPi. The PPi "waste" would then be available to pump Na+.
Thank you Nicolás, sorry to be a bit slow, I got engrossed in the article and lost which post your comment had been added to!!
BTW, I would like to avail myself of this comment to express my admiration to you for share your enlightenment thoughts about biochemical and nutritional science for so many years.


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