Website makers often use 'cookies' to make their website work properly. Cookies are helpful little text files that we can place on your device (computer, tablet or mobile phone). They allow Mirabeau to identify you and to remember things about you, which in turn enables us to potentially personalize our website content and to analyze your behavior as you navigate through the website.
The other option is to do nothing. The banner will stay in place, but no cookies (at least not cookies that legally require consent) will be placed. We are working on a cookie banner that gives you more control over the cookies that are placed. We need to replace some of our systems to make this happen.
How would you like us to use your data?
We use our website, blog, newsletters and whitepapers to share our knowledge and insights. The website is also a great way to get in touch with us or to apply for a job.
Mirabeau creates whitepapers on a broad number of topics, and we make them available for download from this website.
For some of our whitepapers, we have decided to ask for your contact information. If we think our services can be relevant for you and your business, one of our colleagues from Mirabeau or Cognizant, our mother company, may use your details to contact you and see if it's interesting for you to continue the conversation about the topic.
One of our most frequently used pages is the contact page. It shows the contact information of our different office locations, but also features as a contact form that allows you to send us a contact request.
We are still growing fast, and our scope is increasingly international. This means that we will always have job openings for a broad range of functions as well as opportunities for internships.
• How it is used: We will only use this data for the purpose of handling your application. If you want, we can also use it to approach you for future job opportunities. We will offer you to save it for this optional, second purpose during the application process.
• How to give consent: By clicking the submit button beneath the form.
• Lifespan: We will delete your data immediately after we handled your application (unless you give us permission to save it to approach you for future job opportunities).
Our general newsletter or industry newsletters contain articles about our latest projects and industry trends. We send it max. 6 times a year to everyone who subscribed to our mailing list.
We do not personalize the site today - everybody sees exactly the same content.
However, we intend to start experimenting with showing you more of the content that you are interested in, and less of the topics that we believe you are less interested in. We can learn a lot about your interests by looking at where you came from, which articles you've read on the site, and on which links you have clicked. This is called 'implicit data'. Every visitor could have a unique profile based just on their individual interests.
Let's say you've been reading the article about our work on the Transavia voice assistant. That could mean you're interested in the technology of voice assistants, or in the Travel & Hospitality industry, or maybe our approach to innovation. We could then show you more articles related to those topics, and less articles related to, say, cloud technologies, the Retail industry, or our DevOps approach.
Today we are trying to get ready for this. We try to find out which topics are important to personalize on. In the example given we talked about technologies, industries, and way of working. That is why we are already building up anonymous visitor profiles today. These profiles contain information about the pages you've visited, how much time you've spent on the site, and how often you've visited the site. And more technically, it also contains information about the profile matches, the different 'campaigns' you've triggered, and whitepapers you have downloaded.
If you provide what's called 'explicit' information, for instance by filling in your name or company type on a contact form, that explicit data will be added to your visitor profile. In effect, the profile will no longer be anonymous.
• Data involved: Implicit (anonymous) and explicit (after making yourself known) behavior.
• How to give consent: Click 'Accept' in the Cookie banner. If you decide not to click 'Accept', the cookie we will still be able to provide you with relevant content, based on implicit behavior and build an anonymous profile, but only within the current session. What this means is that we can still make the website more relevant by displaying personalized content based on where the visitor came from and which pages they visited during their visit on the website, however all the data will no longer be associated with the visitor as soon as the session ends.
• How it is used: We would only use this data for the purpose of personalizing your experience on Mirabeau.nl.
We want to make sure that you can easily find what you're looking for. By monitoring website behavior, we can optimize our website. To monitor people's behavior as they use the site, our Insights team uses two types of 'analytics' software: Google Analytics, and Hotjar.
• Google Analytics tells us more about how our website is being used (how much time people have spent on the site, which pages are frequently visited, what kind of browsers are most used, etc) and by whom (we don't know your name).
• Hotjar takes representative samples of the total number visits, and creates overviews of which areas of a page have been clicked/visited the most (so called 'heatmaps'). It can also create screen recordings of people's mouse devices moving over the website.
This may sound a bit spooky, but it is completely anonymous and not linked to other data that we have of you.
• Data involved: Which pages you visited, which type of device you used, which browser you used, and which operating system you used, if you've been here before, etc.
• How to give consent: At the moment, this analysis function is always 'on' and cannot be turned 'off'. Legally, websites do not need people's consent to do place cookies for anonymous analytics; however, we believe that you should have this option and we are working to make this happen soon.
• How it is used: We will only use this data for the purpose of optimizing our website. And even though we use analytics software from Google and Hotjar, we will not share your data with either party.
Once in a while we run a survey on our website. This helps us with getting your honest opinion on certain topics. You might also see a black window popping up on the bottom of your screen now and then. This is for the purpose of getting feedback on the content we deliver.
• How it is used: We will only use this data for the purpose of optimizing our website and written content. It is not shared with or used by Hotjar (the software supplier).
Throughout the website we want to show videos of our work. This requires video player software. At the moment, we use the ready-to-go video player of YouTube as it is free, easy to implement and a user-friendly solution.
• How it is used: We don't use this data, but the 'social media' cookies will share information about your activities on our site with YouTube.
• Interestingly, we don't actually place a cookie, but YouTube stores your viewing behavior. It does that to give personalized video recommendations after the video has ended.
Obviously, we keep your data very safe. In the unlikely event of anyone accessing your personal information without your authorization, or when we suspect that such a data breach has occurred, we will inform you and all parties involved as quickly as possible.
We may change this policy from time to time and if we do, we'll post any changes on this page. If you visit and use Mirabeau.nl after those changes are in effect, you agree to the new policy. If the changes are significant, we may provide a more prominent notice or get your consent.
We welcome your questions and comments on this policy and will be happy to assist you in exercising your rights to privacy. The best way to get in touch is by phone via (+31) 20 595 0550 or via email at marcom@mirabeau.nl.


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List of Affiliated Unions
Collective agreements models
UITBB
Home Latin America CTB National Political Council Resolution
CTB National Political Council Resolution
The CTB National Political Council gathered in Sao Paulo on 3 may 2016 with the purpose to analyze the political conjuncture and adopted the following resolution:
1- Brazil is going through a serious political moment and particularly dangerous for the Brazilian workers;
2- There is currently a coup d 'état underway in the country, concealed by an impeachment process without any legal basis, which constitutes a serious threat to democracy, the national sovereignty, the CLT (Consolidation of Labor Laws) and the secular achievements of the working class;
3- The putschist conspiracy comes from afar, it was present in the 2013 and 2014 demonstrations (under the slogan "the World Cup won´t happen"), manipulated in order to create an environment of social chaos and to weaken and destabilize Dilma´s Government. The offensive was redoubled after the re-election of Dilma with the impeachment process led by a defendant in the Supreme Court;
4- A more comprehensive analysis of the reality suggests that it is not a movement restricted to our country, but a much more extensive conservative wave, that has as a background the economic and geopolitical crisis of capitalism and international imperialism hegemonized by the US. Recent electoral setbacks for the democratic forces in Argentina, Venezuela and Bolivia, as well as coups in Honduras (2009) and Paraguay (2012), are events that are part of the same phenomenon;
5-Here, as in other countries of our America, the union of the bourgeoisies and the local landowners with the international financial aristocracy, is captained by the US imperialism in a reactionary enterprise. Those are the same social classes who were behind the military coup of 1964. The unclear goals of the scammers appear between the lines of their government projects;
6-In the document titled "bridge to the future" (PMDB party) vice-president Temer promises the patronage to end with the CLT (Consolidation of Labor Laws), establishing primacy of the market over the law and imposing unrestricted and widespread outsourcing of the economy. It beckons a a tough fiscal adjustment, expansion of the DRU and consequently the reduction of the the already scarce resources for health, education and social programs; the end of the policy of valorization of the minimum wage, reduction of the social security benefits and the fixing of a minimum age for retirement. The right-wing PSDB party follows the same path with a letter of 15 points forwarded to the putschist vice-president. It was not without reason that the FIESP- Federation of Industries of the State of São Paulo, NCA- National Confederation of Agriculture and NCINational Confederation of Industry and hundreds of business entities supported and sponsored the impeachment;
7- The foreign capital, and particularly the US (who remained silent about the coup, supporting it behind the scenes), would be rewarded with the delivery of the pre-salt oil, privatization (including Petrobras), and notably the change of foreign policy, which tends to turn his back on Latin American and Caribbean integration, sabotage of the MERCOSUR, the CELAC (Community of Latin American and Caribbean States) and the BRICS, to restore the diplomacy of the former Brazilian president Fernando Henrique Cardoso. Therefore, the coup goes along with the US strategy to recompose its imperialist hegemony in the Americas and around the world;
8-By interdicting a democratic, patriotic and popular project that, rightly or wrongly, was being implemented in Brazil since 2003, the pro-coup Consortium intends to restore a neoliberal program that confronts the national interests and the social rights. The process that is taking over the Presidency is illegitimate and markedly anti-democratic. We should have no doubt that to impose the conservative agenda they will appeal to the criminalization of the struggles and the social movements, restricting democracy and increasingly resorting to authoritarianism. The undemocratic, anti-national and anti-popular character of the coup is obvious.
9-Before this reality, the CTB National Political Council guides the entire militancy and leadership of our class-oriented Central to intensify the efforts of enlightenment and mobilization of the bases to fight relentlessly against the scammers, in defense of democracy, the national sovereignty and the social rights. In this sense, it is necessary to organize in the trade unions and in the grassroot committees the defense of the CLT-Consolidation of Labor Laws, and to begin immediately the preparations for the national day of Fight and Paralysis on 10 may organized by the Brazilian Popular Front and People Without Fear Front. Only through great class struggles, will we be able to reopen the way for a new National Development Project with Democracy, sovereignty and valorization of work proposed by the CONCLAT (National Congress of the Working Class)
São Paulo, 3 may 2016
CTB* National Political Council (*Central of Male and Female Workers of Brazil)
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Gerd-Dieter Mirtl (* 24. September 1944) ist ein österreichischer Jurist, Betriebswirt, Unternehmer, Wirtschaftsprüfer und Steuerberater.

Leben und Wirken
Er maturierte in Linz, studierte Recht und Betriebswirtschaft an der Universität Wien und an der Johannes Kepler Universität Linz und promovierte 1969. Bis Ende März 2005 war Mirtl Gesellschafter und Partner bei der KPMG Wirtschaftsprüfungs- und Steuerberatungsgesellschaft, wo er ab 1980 tätig war.
Auf Grund seiner Funktion als Aufsichtsratsvorsitzender der börsennotierten HTI High Tech Industries AG waren seine Stellungnahmen zum Unternehmen von medialem Interesse.

Funktionen
 Inhaber von Aufsichtsratsmandaten in mehreren Unternehmen, darunter Aufsichtsratsvorsitzender der HTI High Tech Industries AG (ab 2004 bis 2012), der Trierenberg Holding AG (ab 2008), CTI Invest AG - Holding (ab 2008)
 Präsident und Vizepräsident der Kammer der Wirtschaftstreuhänder Oberösterreich (1998 bis 2003)
 Landesobmann der Österreichischen Gesellschaft der Wirtschaftstreuhänder in Oberösterreich
 Präsident der Künstlervereinigung Zülow Gruppe (seit 2000)
 Kuratoriumsmitglied Evangelisches Diakoniewerk Gallneukirchen
 Geschäftsführer und Gesellschafter der K/H/W Wirtschaftstreuhand GmbH Steuerberatungsgesellschaft [6]

Auszeichnungen
 Großes Goldenes Ehrenzeichen der Stadt Linz (2005)

Privates
Er hat eine Tochter und einen Sohn. Sein Sohn  Alexander Mirtl ist ein Linzer Top-Anwalt. In seiner Freizeit sammelt er Oldtimer und Sportwagen. Außerdem nimmt er an renommierten Oldtimer Rallys teil (Ennstalclassic, Mille Miglia, uvm.)

Einzelnachweise

Wirtschaftsjurist

Steuerberater
Person (Linz)
Österreicher
Geboren 1944
Mann
Wirtschaftsprüfer

redpajama_set_name: RedPajamaWikipedia


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What Mel Wants
Melanie Suzanne Wilson's personal blog shares opinions and discoveries from life.
Are you a fan of Flickr?
Flickr is one of the most popular sites used to put entire photo albums online. There are galleries within a photo stream to organise the pics. A paid subscription will allow you to watch stats of the popularity of your pictures. This is definitely useful for major brands, but I'll stay with the free version because it provides what I need.
You can even create a customised alias, also known as the URL address. Simply go into account settings and change it. Flickr only lets you do this once. This is important because the address helps to form your online identity.
Although there is very little editing of photos, some settings add a bit extra to each picture. The site automatically adds a copyright sign to protect your intellectual property. We can choose who sees the pictures in case we want tighter security. Titles and descriptions explain more context to audiences. Categories like 'favourites' further organise the photos. Oh how times have changed since printed photos were stuck into big heavy albums.
Have a look at Flickr and maybe even sign up. Facebook accounts can be used to sign up, so you don't have the fuss of providing details. And definitely have a look at my pictures here.
You are very welcome to post any friendly comments after blog posts. Both sides of all discussions are welcome. Keep it nice and constructive and join the conversation.
The Seekers Golden Jubilee
The Seekers are celebrating a very special time in their lives, and including their fans in the festivities. Dudith Durham, Bruce Woodley, Keith Potger, and Athol Guy have been a band for 50 years. That's right, a Golden Jubilee means 50 years in show biz. Before we have a look at the latest media attention, here's a quick background into the world of Seekers tours.
Judith Durham said on 60 minutes that they really had an easy career. Judith now realises she took for granted the instant TV coverage they received just a day after they arrived in England. Success welcomed the group whenever they wanted it. Judith then chose time off from the group for independence and to find her own identity. But the memory of The Seekers stayed with the public. And hence the later tours.
Judith has continually been able to return to the group with the same support from fans ever since. Their 25th anniversary Silver Jubilee (when I was 4) sparked a decade of performances. They united aft…
Playing an artist on Pinterest
On the seriously popular app Pinterest, we can all be an artist. Or a cook. Pinterest allows egalitarian sharing of crafty creations and web sites with absolutely anyone. This how-to-DIY-guide of the social networking world is changing creative expressions of thousands of people.
Pinterest is a potential shopping mall of the future. Amazingly unique and exotic gifts can be found on the site and ordered by price. Why wander around the shopping mall in search of something different when we can buy it at the click of a button? When we don't want to wait around for an auction on Ebay, there's always this collection of references to bargain sites.
This R2D2 bin was sold on Etsy (& so was its image above) after some free advertisement on Pinterest.
The DIY world is another reason to join the crowd at Pinterest. I took a bit of getting used to the technology (I'm getting old fashioned), but you just click on the picture and the referenced web page will appear.
This cocktail w…
News Should Not Be Restricted
The Sydney Morning Herald has implemented a monthly charge for users to access articles on their web site. Only the first 30 articles are free. Under the current system, readers would pay up to $300 a year. This dollar value assumes such a news source is not substitutable. Or is it? There was talk of this being planned for quite a while. But it is still a massive shock to the loyal readers.
The good old SMH has kept a flow of revenue from advertisements for some time. That should be enough. Sometimes a pop up would grab our attention before being closed. A banner in the footer of the home page (that is an attempt at descriptive techie lingo) is all about American Express. Links on the right hand side promoted anything and everything. That should have been enough. Our favourite brands would have paid big bucks for exposure on a very popular online site.
Let's hope there is a very good reason for the SMH to suddenly restrict the site to subscriptions. A monthly payment is too much…
(c) Copyright Melanie Suzanne Wilson 2012
Visualising Food Goals
Subscribing to this blog by email
How did "Will it blend" get so popular?
Are connected through Linkedin yet?
Anyone can comment on the blog What Mel Wants
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Timeless hippie fashion
A movie every twenty something should see
App Addicts Anonymous
Sydney is finally getting a real summer
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I still miss Gilmore Girls
Market Marvels
Obsessive Compulsive Editing
Must See DVD: Mad Men
New web address for What Mel Wants
Where the bloody hell is Lara Bingle?
Useful Links: Intro to Asperger's Syndrome
Bridesmaids is an awesome movie!
My favourite music videos of The Seekers on Youtub...
Social Media: a two-way conversation
Finding a Calling
Viral: Rhonda and Ketut
U.S. Election: who is Abigael Evans?
We're doing the Time Warp today!
Dana LaMon
early twenties
Elizabeth Leigh Wilson
Kidult Guides
late twenties
Madge Fountain
Marjorie Collins
Melanie Suzanne Wilson
Order of Australia
Melanie's Other Web Sites
Official Web Site of Melanie Suzanne Wilson
Hourglass Apparel Shopping
Shake Up Your Style


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Tiesioginė televizija > TV kanalai > Mianmaras > MRTV
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Myanmar Radio and Television (မြန်မာ့အသံနှင့်ရုပ်မြင်သံကြာ), formerly the Burma Broadcasting Service (BBS), is the parent of state-run Myanmar Radio National Service, and a television channel. The television channels are broadcast from its broadcast centre in Kamayut, Yangon. The radio service is now broadcast primarily from Naypyidaw.
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There are many wonderful support services and websites that offer information and guidance for you in your role as a parent. Check out some of our links for families.
Another great site is The Parenting Place website - a fantastic source of 'Hot Tips' for parenting. From time to time our Kindergartens host 'Toolbox' courses for parents, run by facilitators from Parents Inc. Talk to your teaching team about what might be coming up.
Some of our other links will take you to fun sites that introduce you to a wide range of activities you can get involved in with your child.
You might also like to try out some of our recipes for having fun at home!


mnt/archive/ where my .SAFE folder is.
Where would you place the Demmnaccs results to use them on the automated Sen2agri page?
What is the correct tree structure?
In this .SAFE product you should have the two .DIR folders and 4 other files. The S2B_MSIL2A_20190205T100219_N0207_R122_T33UWR_20190205T151131.SAFE (in our example) is actually the L2A product.
The only important thing is to import them into the database using the script insert_l2a_product_to_db.py and providing the path "/my_dir/x/y/" to the script, using the multi mode.
The L3B processor in automated mode will use the locations that it finds in the database.


text:
Q: How to find the original content when the folder is already "replaced"? I'm new to mac and I made a big mistake. I was trying to back up internal HD (macbook pro). While I wanted to save what was on internal HD's "Folder A", there was already a folder named "Folder A" on my external HD. What I wanted to do was to merge the 2 to make a folder (in ext HD) that contain ALL the file together in "Folder A". When I dragged the folder from int. HD onto ext. HD, the pop up window asked: "this folder name already exist, do you want to replace?" and I clicked on "replace". Only 2 seconds after, I realized that the contents on my ext HD "folder A" was actually more recent (because I was editing 3 video projects directly from this ext. HD "folder A" during the last 3 days). So I clicked on "stop copying" immediately, but it had started replacing "folder A" to my int HD version thus my original content in "folder A" on ext Hd was all gone.
Is there any way to restore the original content of "folder A"?

A: Depends on the filesystem. If it was HFS+, it's probably gone for good. If it was FAT32 there's a really small chance an undelete utility can find the files intact. You may have to plug the drive into a Windows computer to find a good utility.

Glary Undelete works great (if the files are intact and if you can find a Windows PC).

redpajama_set_name: RedPajamaStackExchange


text:
RELEASE LIST
NERDCAST ORIGINALS
Featured StoryNewsPCPS4SwitchXbox One
ToeJam & Earl: Back in the Groove to be released by Thanksgiving
HumaNature Studios will self-publish game after parting ways with Adult Swim Games
Chris Powell July 18, 2018
To say it's been a rocky road of development for ToeJam & Earl: Back in the Groove certainly is an understatement, as the game has seen several delays, leaving many of its Kickstarter backers upset by the lack of communication between HumaNature Studios and the community.
However, things have really picked up over the past couple months, with the game finally going into closed beta. More recently, HumaNature issued a Kickstarter update confirming that Back in the Groove will indeed release this year and committed to having the game shipped by Thanksgiving 2018.
They didn't give an exact date, and the game could release before that, but it's great to finally get a confirmed timeframe when the game will make it into fan's hands.
In a previous Kickstarter update, series co-creator Greg Johnson announced that his development team and the game's publisher Adult Swim Games mutually agreed to part ways, and HumaNature will self-publish Back in the Groove.
"Adult Swim Games has some other big titles they plan to launch this summer so when Back in the Groove pushed back, we both agreed that it made sense for them to hand us the reigns, rather than taking a chance on this getting pushed back any more," the Kickstarter update read. "Also I'd like to say how deeply grateful I and all of us here at HNS are to Adult Swim Games. We wouldn't have gotten this game to this point without them… seriously."
ToeJam & Earl: Back in the Groove raised more than $500,000 on Kickstarter after the campaign was launched in late February, 2015. The game will be released on the PlayStation 4, Xbox One, Nintendo Switch, PC, Mac and Linux.
Chris Powell
Chris is the editor-in-chief at SEGA Nerds and Mega Visions Magazine. Over the years, he's written for publications like Joystiq, PSP Fanboy, RETRO magazine, among others. Oh yeah, he's also been a diehard SEGA Nerd his entire life.
ToeJam & Earl: Back in the Groove is coming this fall, new trailer released
Saying goodbye to a SEGA legend [Parody/News]
Humble Store slashes Sonic games by 75%
Top 5 SEGA original Xbox exclusives that deserve ports on Steam
Could Sonic Team Racing Take The Esports World By Storm?
Sonic Mania Plus PS4
PC July 17, 2018
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Yakuza Kiwami 2 PS4 Aug. 28, 2018
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NS Sept. 25, 2018
Fist of the North Star: Lost Star PS4 Oct. 22, 2018
Monster Boy and the Cursed Kingdom PS4
13 Sentinels: Aegis Rim PS4
Vita 2018
Toejam and Earl Back in the Groove NS
Shenmue 3 PS4
Two Point Hospital PC 2018
See complete list of games here.
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text:
Koch, Andreas (105)
Kleinpeter, Erich (97)
Heydenreich, Matthias (24)
Neuvonen, Kari (10)
Fülöp, Ferenc (9)
Neuvonen, Helmi (9)
Pihlaja, Kalevi (9)
Szatmari, Istvan (7)
Starke, Ines (6)
Shainyan, Bagrat A. (5)
Monograph/Edited Volume (1)
Conformational analysis (5)
Theoretical calculations (5)
NMR spectroscopy (4)
Anisotropy effect (3)
ICSS (3)
Ring current effect (3)
TSNMRS (3)
(Anti)aromaticity (2)
Anisotropic effect (2)
Aromaticity (2)
Hyperconjugation and the increasing bulk of OCOCX3 substituents in trans-1,4-disubstituted cyclohexanes destabilize the diequatorial conformer (2006)
Kleinpeter, Erich ; Rolla, Nadja ; Koch, Andreas ; Taddei, Fernando
The trans diesters of 1,4-cyclohexanediol with a number of acetic acid analogues, CX3COOH, of varying steric hindrance and polarity (CX3 = Me, Et, iso-Pr, tert-Bu, CF3, CH2Cl, CHCl2, CCl3, CH2Br, CHBr2, CBr3) were synthesized, and the axial, axial/equatorial, equatorial conformational equilibria were studied by low-temperature H-1 NMR spectroscopy in CD2Cl2. The structures and relative energies of the axial, axial and equatorial, equatorial conformers were calculated at both the MP2/6-311G* and the MP2/6-311+G* levels of theory, and it was only by including diffuse functions that a good correlation of Delta G degrees(calcd) vs Delta G(exptl) could be obtained. Both the structures and the energy differences of the axial, axial and equatorial, equatorial conformers are discussed with respect to the established models of conformational analysis, viz., steric 1,3-diaxial and hyperconjugative interactions. Interestingly, the hyperconjugative interactions sigma(C-C)/sigma(C-H)->sigma*(C-O), together with a steric effect which also destabilizes the equatorial, equatorial conformers on increasing bulk of the substituents, proved to dominate the position of the conformational equilibria. In addition, the preference of the axial, axial conformers with respect to their equatorial, equatorial analogues was greater than expected from the conformational energies of the corresponding substituents in the monosubstituted cyclohexyl esters. The reason for this very interesting and unexpected result is also discussed
Synthesis and conformational analysis of naphth[1,2-e][1,3]oxazino[4,3-a][1,3]isoquinoline and naphth[2,1- e][1,3]oxazino[4,3-a]isoquinoline derivatives (2008)
Heydenreich, Matthias ; Koch, Andreas ; Szatmári, István ; Fülöp, Ferenc ; Kleinpeter, Erich
Through the cyclization of 1-(;-hydroxynaphthyl)-1,2,3,4-tetrahydroisoquinoline and 1-(;- hydroxynaphthyl)-1,2,3,4-tetrahydroisoquinoline with formaldehyde, phosgene, p-nitrobenzaldehyde or p-chlorophenyl isothiocyanate, 8-substituted 10,11-dihydro-8H,15bH-naphth[1,2-e][1,3]oxazino[4,3-a]isoquinolines (3 and 4) and 10,11- dihydro-8H,15bH-naphth[2,1-e][1,3]oxazino[4,3-a]isoquinolines (15 and 16) were prepared. Conformational analysis of both the piperidine and the 1,3-oxazine moieties of these heterocycles by NMR spectroscopy and an accompanying theoretical study revealed that these two conformationally flexible six-membered ring moieties prefer twisted chair conformers.
Tautomerism, regioisomerism, and cyclization reactions of acridinyl thiosemicarbazides (2006)
Klinka, Karel D. ; Balentova, Eva ; Bernát, Juraj ; Imrich, Jan ; Vavrusova, Martina ; Kleinpeter, Erich ; Pihlaja, Kalevi ; Koch, Andreas
The regioselectivities of methyl- and phenylhydrazine with acridin-9-yl isothiocyanate (thus yielding thiosemicarbazides with acridine substituted on the urea-type side) were examined. Methythydrazine regioselectivity was high with the alpha-nitrogen atom overwhelmingly more nucleophilic than the beta-nitrogen atom; phenylhydrazine regioselectivity was poor but varied with the solvent and only in the case of ethanol was nucleophilic predominance of the alpha-nitrogen atom pronounced. Of note, whilst both phenyl thiosemicarbazides were present in solution only as spiro forms, the methyl product was present as an equilibrium mixture of open-chain and spiro thiosemicarbazides. Reactions on the NH2 blocked analogue of methyl acridin-9-ylthiosemicarbazide (1-isopropylidene-2- methylthiosemicarbazide) were also examined. Interestingly, present in the starting material itself was a structural motif of novelty wherein a triazolethione represented the major species of an equilibrium between cyclic and open-chain forms
Electronic effects of heterocyclic ring systems as evaluated with the aid of 13C and 15N NMR chemical shifts and NBO analysis (2008)
Neuvonen, Helmi ; Fülöp, Ferenc ; Neuvonen, Kari ; Koch, Andreas ; Kleinpeter, Erich
The electronic effects of the 5- and 6-membered heterocyclic rings on the C=N-N unit of five different hydrazone derivatives of pyridine-2-, -3- and -4-carbaldehydes, pyrrole-2-carbaldehyde, furan-2- and -3-carbaldehydes and thiophene-2- and -3-carbaldehydes have been studied with the aid of 13C and 15N NMR measurements together with the natural bond orbital (NBO) analysis. As model compounds are used the corresponding substituted benzaldehyde derivatives. The polarization of the C=N unit of the hydrazone functionality of the heteroaryl derivatives occurs in an analogous manner with that of phenyl derivatives. The electron-withdrawing heteroaryl groups destabilize and the electron-donating groups stabilize the positive charge development at the CN carbon while the effect on the negative charge development is opposite. The 15N NMR chemical shift of the C=N and C=N-N nitrogens and the NBO charges at C=N-N unit can be correlated with the replacement substituent constants of the heteroaryl groups. 13C NMR shifts of the C=N carbon of N,N- dialkylhydrazones of the heteroarenecarbaldehydes can be correlated with a dual parameter equation possessing the polar substituent constant ;* of the heteroaryl group and the electronegativity of the heteroatom as variables.
Synthesis and conformational analysis of naphth[1', 2':5,6][1,3]oxazino[3,2-c][1,3]benzoxazine and naphth[1', 2':5,6][1,3]oxazino[3,4-c][1,3]benzoxazine derivatives (2006)
Heydenreich, Matthias ; Koch, Andreas ; Klod, Sabrina ; Szatmari, Istvan ; Fülöp, Ferenc ; Kleinpeter, Erich
A new functional group, the hydroxy group, was inserted into a Betti base by reaction with salicylaldehyde, and the naphthoxazine derivatives thus obtained were converted by ring-closure reactions with formaldehyde, acetaldehyde, propionaldehyde or phosgene to the corresponding naphth[1',2':5,6][1,3]oxazino[3,2-c][1,3]benzoxazine derivatives. Further, the conformational analysis of these polycyclic compounds by NMR spectroscopy and an accompanying molecular modelling are reported; especially, both quantitative anisotropic ring current effects of the aromatic moieties in these compounds and steric substituent effects were employed to determine the stereochemistry of the naphthoxazinobenzoxazine derivatives.
DFT study of the substituent cross-interaction effects on the conformation of substituted N-benzylideneanilines : Models of liquid crystal forming compounds ; use of C-13 Nmr chemcal shift of the C=N carbon as a tool to predict the conformation of the molecule (2007)
Neuvonen, Helmi ; Neuvonen, Kari ; Koch, Andreas ; Kleinpeter, Erich
The conformations of N-benzylideneani lines p-X-C6H4-CH=N-C6H4 p-Y (X, Y = NO2, CN, CF3, F, Cl, Br, H, Me, OMe, NMe2) have been studied by B3LYP density functional (DFT) hybrid method in combination with the 6-31G* or 6-311G* split valence basis set. The twist of the plane of the aniline ring with respect to the other part of the molecule (tau(2)) is systematically controlled by substituents X and Y, the effect of Y being larger. The value of the dihedral angle tau(2), correlates nicely with equation tau(2) = rho(F)(Y)(x)sigma(F)(Y)+rho(+R)(Y)(x)sigma(+)(R)(Y) + k(x) or tau(2) = rho(F)(X)(y)sigma(F)(X)+rho(-)(R)(X)(y)sigma(+)(R)(X) + k(y), respectively, when aniline or benzylidene substituent is varied. ED substituents X diminish the sensitivity of tau(2) to the aniline substituent Y[rho(F)(Y)(x) and rho(+)(R)(Y)(x)] while ED substituents Y increase the sensitivity Of T2 to the benzylidene substituent X[rho(F)(X)(y) and rho(+)(R)(X)(y)]. There seems to be two competitive conjugative interactions for the aniline ring n electrons: one with the nitrogen lone pair and one with the C=N unit. Substituents X and Y adjust the extent of these interactions and therefore the conformation of the molecule. A good correlation is observed between the dihedral angle tau(2) and the experimental C-13 NMR chemical shift of the C=N carbon of N-benzylideneanilines in CDCl3 (C) 2007 Elsevier B.V. All rights reserved.
Quantification of the push-pull character of the isophorone chromophore as a measure of molecular hyperpolarizability for NLO applications (2008)
Kleinpeter, Erich ; Koch, Andreas ; Mikhova, Bozhana ; Stamboliyska, Bistra A. ; Kolev, Tsonko M.
The push-pull character of a series of para-phenyl substituted isophorone chromophores has been quantified by the 13C chemical shift difference of the three conjugated partial C=C double bonds and the quotient of the occupations of both the bonding and anti-bonding orbitals of these C=C double bonds as well. The correlations of the two push-pull quantifying parameters, and to the corresponding bond lengths, strongly recommend ;*c=c/ ;c=c as the general parameter to estimate charge alternation and as a very useful indication of the molecular hyperpolarizabilities for NLO application of the compounds studied.
The stereodynamics of 3,5-bis(trifluoromethylsulfonyl)-1,3,5-oxadiazinane and 1,3,5- tris(trifluoromethylsulfonyl)-1,3,5-triazinane- an experimental and theoretical study (2007)
Shainyan, Bagrat A. ; Ushakov, Igor A. ; Meshcheryakov, Vladimir I. ; Schilde, Uwe ; Koch, Andreas ; Kleinpeter, Erich
Multinuclear dynamic NMR spectroscopy of 3,5-bis(trifluoromethylsulfonyl)-1,3,5-oxadiazinane (3) revealed the existence of two conformers with differently oriented CF3 groups with respect to the ring, and two dynamic processes: ring inversion and restricted rotation about the N-S bond. Two transition states connecting the two conformers and corresponding to clockwise and counterclockwise rotations about the N-S bond were found; the calculated activation barriers of about 12 kcal/mol are in excellent agreement with those measured experimentally for the related molecule 1,3,5-tris(trifluoromethylsulfonyl)-1,3,5-triazinane (1). X-ray analysis proved the existence of the symmetric isomer of 3, which is the minor isomer in solutions but the only one in the crystal due to packing effects. The normal Perlin effect (JCHax < JCHeq)observed for 2(6)-CH2 in 3, whereas the reversed Perlin effect was found for the 4-CH2 group in 3 as well as for all CH2 groups in 1 both experimentally and theoretically. The latter effect in compounds 1, 3, and 1- (methylsulfonyl)-3,5-bis(trifluoromethylsulfonyl)-1,3,5-triazinane (2) can be considered as a genuine reverse Perlin effect since larger values of 1JCH are observed for longer C-H bonds.
Structural revision of products resulting from the reaction of methylhydrazine with acridin-9-yl isothiocyanate due to unexpected acridinyl migration And further reactions (2006)
Klinka, Karel D. ; Balentova, Eva ; Bernát, Juraj ; Imrich, Ján ; Vavrusová, Martina ; Pihlaja, Kalevi ; Koch, Andreas ; Kleinpeter, Erich ; Kelling, Alexandra ; Schilde, Uwe
The reaction of methyl acridin-9-ylthiosemicarbazide under basic conditions with methyl bromoacetate resulted in a 1,3-thiazolin-4-one structure as provided by X-ray crystallography. The structure forced a re-evaluation of the reactant methyl acridin-9-ylthiosemicarbazide, originally thought to be 2-methyl 4-acridin-9-ylthiosemicarbazide based on synthetic expectations, but which when examined by X-ray crystallography was found to be in fact the isomeric 2- methyl 1-acridin-9-ylthiosemicarbazide resulting from rearrangement via a spiro form which it is in equilibrium with in solution. The product resulting from reaction with methyl iodide was also studied and the previously reported semicarbazide produced by reaction with MNO was re-examined. In both cases, the 1,2 isomer rather than the 2,4 isomer was found to be present based on the sign of the 3JCH3,N11 coupling. Full characterization of the compounds was rendered by 1H, 13C, and 15N solution-state NMR, and in the solid state, by both 13C and 15N NMR.
Propagation of polar substituent effects in 1-(substituted phenyl)-6,7-dimethoxy-3,4-dihydro- and -1,2,3,4- tetrahydroisoquinolines as explained by resonance polarization concept (2005)
Neuvonen, Kari ; Fulop, F ; Neuvonen, Helmi ; Koch, Andreas ; Kleinpeter, Erich ; Pihlaja, Kalevi
Propagation of inductive and resonance effects of phenyl substituents within 1-(substituted phenyl)-6,7- dimethoxy-3,4-dihydro- and -1,2,3,4-tetrahydroisoquinolines were studied with the aid of C-13 and N-15 NMR chemical shifts and ab initio calculations. The substituent-induced changes in the chemical shift (SCS) were correlated with a dual substituent parameter equation. The contributions of conjugative (rho(R)) and nonconjugative effects (rho(F)) were analyzed, and mapping of the substituent-induced changes is given over the entire isoquinoline moiety for both series. The experimental results can be rationalized with the aid of the resonance polarization concept. This means the consideration of the substituent-sensitive balance of different resonance structures, i.e., electron delocalization, and the effect of the aromatic ring substituents on their relative contributions. With tetrahydroisoquinolines, the delocalization of the nitrogen lone pair (stereoelectronic effect) particularly contributes. Correlation analysis of the Mulliken atomic charges for the dihydroisoquinoline derivatives was also performed. The results support the concept of the substituent-sensitive polarization of the isoquinoline moiety even if the polarization pattern achieved via the NMR approach is not quite the same as that predicted by the computational charges. Previously the concepts of localized pi- polarization and extended polarization have been used to explain polar substituent effects within aromatic side-chain derivatives. We consider that the resonance polarization model effectively contributes to the understanding of the polar substituent effects


text:
Personal Narrative: Air Force Basic Training
Did I make it? That was the question I was asking myself the night before what was going to be one of the most special days of my life. After being called to leave for Air Force Basic Training on a short 8-day notice, I was now finally at the end of my journey and tomorrow I would graduate and become an Airmen. The nerves and excitement were running through my body as I was unable to sleep in anticipation of the big day. Now the day is here and I get to celebrate all my hard work by seeing my family and earning the title of an Air Force Airmen.
It's been a long eight and a half weeks and today is finally the day. As Reveille on the bugle blasted through the squad bay, we all jumped out of bed with pure joy and excitement knowing that all our…show more content…
This was a moment to show everyone how far we had come during our time at basic training. After changing into our uniform, we were all presented with the Airmen's Coin which symbolized that we had passed basic training and were now a part of the United States Airforce. This moment was both exciting and made me speechless to know that now I was going to have the opportunity to serve my country in a new way.
Now that I was officially an Airmen, I was able to go reunite with my parents. This experience was a flood of emotions as I now could hug and talk to my mom and dad. My parents being there to watch me gain my greatest success thus far in life meant everything and I could not have done it without their love and support. Being able to be a part of something so important to our country is so humbling and the day I graduated from Air Force Basic Training is a day of success that I will carry with me for the rest of my…show more content…
Going through and graduating Air Force Basic Training changed me both physically and mentally as a person. First, physically the experience taught me how to push my self in ways that I had never before and accomplish tasks that before seemed impossible. Also, my experience changed me mentally by teaching me how to be strong in stressful situations and how to handle situations in a calm and collected manner. My experience of graduating from basic training did not change my perception on society, but instead it gave me a group of people that have been through the same experience and have the same passions to serve our
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choose is U.S Army. The reason I choose the Army is because the Special Forces they have are more appealing than the Marine Corp, or the Navy. The Army has; the Green Beret, the Rangers, and the one I want to join: 1st Special Forces Operational Detachment - Delta, this branch is more commonly known as Delta Force. The U.S Army has a ton of different jobs with the Army, there is; Infantry Branch, Military Police Branch, Air Defense Artillery Branch, Military Intelligence Branch, and a lot more
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text:
The World Education Summit recognises Early Learning Village with 'Emerging Standalone Preschool Award'
The World Education Summit recognises Early Learning Village with "Emerging Standalone Preschool Award"
Last Updated: Thu, Dec 13, 2018 18:05 hrs
[India], Dec 13 (ANI): Early Learning village (ELV) wins its first nationwide honor with the '13th World Education Awards 2018' in the category of "Emerging Standalone Preschool" at the World Education Summit.
The award was presented at Bombay Exhibition Centre and collected by Priya Saxena, Co-Founder and Principal - Early Learning Village.
"It's an honor and a privilege for Team ELV to receive the Best Standalone Preschool award. ELV has been created by deeply dedicated and passionate early educators who are all aligned to one single purpose- 'Child first'! In our journey so far, we have never compromised on children's learning and all decisions are taken keeping in mind our children's well-being," said co-founder & Principal - Early Learning Village, Priya Saxena.
"We will continue to celebrate childhood each and every single day. The award is a recognition and endorsement of all the hard work put together by the entire Team of ELV, from our security staff, to our housekeeping staff, to our Gardeners to the Kitchen staff and to the wonderful set of teachers," added Saxena.
The World Education Summit Delhi 2018 aims to recognise, highlight, honor and encourage leading models/projects/processes of excellence and sustainable innovation in school and higher education. The awards also saw entrepreneurs in the education space getting recognised. The summit has, in its past too, brought to fore unique initiatives and projects that have brought a paradigm shift in the education sphere within various parts of the country.
ELV believes in delivering the highest standard of early years education through an internationally accredited curriculum, high-quality facilities and an outstanding team of educators to prepare young children to be lifelong learners and global citizens of the world. This recognition is a reminder to the efforts made to make a difference to the teaching environment in the city with the focus on experiential and play-based learning.
Every child is curious, and the preschool's goal is to provide a learning environment that nurtures the child's natural love of discovery and develop them into self-motivated learners. (ANI)
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talking point on sify finance


At the Los Angeles Auto Show (November 18–27), Porsche is set to light the touch paper for the next stage of the Panamera. At the end of the year, four Executive models will celebrate their world premieres: the Panamera Turbo Executive (404 kW/550 hp), Panamera 4S Executive (324 kW/440 hp), Panamera 4 E-Hybrid Executive (340 kW/462 hp) and Panamera 4 Executive (243 kW/330 hp). One innovation is the basic engine of the four-door models. The fully redesigned 3.0-litre V6 turbo engine is the new entry-level model for the Gran Turismo class, and is used in the Panamera 4 Executive, the Panamera with rear-wheel drive and the Panamera 4 with all-wheel drive. Porsche will also unveil the 911 RSR racing car, yet another world innovation that will compete in the international arena in 2017.
The sportscar manufacturer will present the new, highly luxurious versions, with a wheelbase extended by 150 millimetres, at the Porsche press conference to be held in the Petree Hall at the Convention Center on November 16 at 10:15 a.m. (Pacific Standard Time; 7:15 p.m. CET).
The USA remains one of Porsche's main sales markets. Up to and including October 2016, the sportscar manufacturer delivered 178,314 vehicles around the world, representing a three-percent increase over the same period in the previous year. This success can be attributed to the excellent reputation the company enjoys among its customers: In 2016, Porsche once again triumphed in the overall classification of the renowned J.D. Power APEAL study conducted by the US market research institute J.D. Power. In addition, the Porsche 911, Boxster and Macan achieved first place in their respective categories.


PGP stands for Pretty Good Privacy. [ We now use an equivalent program GNU Privacy Guard ( gnupg.org ). ] It is a program used to encrypt messages such that they can only be decrypted by one person who has a 'private key' and (usually) a password to use that key.
Because that private key is typically stored on YOUR computer, and not on our webserver, data that is encrypted FOR your private key can not be captured if someone is 'eavesdropping' when you receive that data, or if someone breaks into our webserver.
The PGP International site has a lot more information about how PGP works.
Getting setup to use PGP is a little bit complex.
Then you need to install it, and generate a public/private key key-pair for yourself. When you've got that done, we need you to send us your PUBLIC key ... once we've got that installed in the webserver, you can send yourself encrypted messages from our webserver.


Last Fall, the senior staff in my Centre for Teaching and Learning suggested we should take a look at our mission. Other units at UBC Okanagan have been updating their "Mission, Vision, Values" – perhaps to align and synchronize with the new UBC Strategic Plan.
I have to admit, I wasn't enthusiastic about the "MVV" exercise but one of my Centre colleagues volunteered to take the lead, so we went ahead with focus groups, summaries, drafts, and follow-up discussions.
In the end, I'm really glad we did it. As expected, it bought us all together, helped us identity what we care about, how we want to enact it, and lets our campus partners know what they can expect from us.
Here's the result, with a description and commentary below.
We advocate for and support evidence-informed approaches to teaching and learning.
We provide ongoing and valuable professional development for all those who teach.
Our approach is based on respect, inclusion, equity, and compassion.
One of the biggest changes to our mission is what we left out. The mission used to say we'd lead and support teaching excellence, scholarship, and other components of teaching and learning. The new mission very deliberately takes a step back: demonstrating educational leadership is required for merit, tenure, and promotion for a stream of teaching faculty at UBC (and it certainly contributes to promotion of faculty in the research stream.) There are projects and tasks the people in my Centre are entirely capable of leading, like reviewing papers, leading faculty learning communities, or organizing parts of our annual conference. There are excellent opportunities for faculty in the teaching stream to have impact beyond their classrooms, though. So rather that us doing it, we're promoting these opportunities to our community and then supporting them.
It's natural and expected that we'll "promote" and "support" components of teaching and learning. From the focus groups and our own discussions, we recognized something we love to do: "inspire" those in our teaching and learning community. We have the privilege of interacting with a lot of people and projects, so when we're consulting with course instructors, we can weave exciting and creative opportunities into our discussions. Sometimes that's all it takes to get a faculty member inspired – it's not that they're not creative, curious, or enthusiastic but they just don't have the time to survey what's out there.
This promote-inspire-support strategy definitely applies to the scholarship of teaching and learning, too. While there's nothing stopping Centre staff from writing and publishing SoTL, it's not required for promotion (none of us are faculty members.) We're thrilled to spark projects and be co-investigators and co-authors. It's critical, though, that we support educational research done by faculty members.
"technology" or "technologies"? There isn't just one technology and technologies (plural) gives us more flexibility.
Wait, do we really "…inspire…technologies…in teaching and learning"? What does that even mean? We decided to let that one thread of the mission slide. Recasting the sentence to eliminate it would make things worse.
So, we recast the mission statement to better communicate there are many aspects of teaching and learning that we promote, inspire, and support. This is why you include focus groups in developing these things!
People typically talk about their organization's mission, vision, and values. After we were happy with where the our new mission statement was heading, we turned to vision and values. And quickly concluded we couldn't say much about how we envision the Centre promoting, inspiring, and supporting teaching and learning without a set of values to build from.
Moving on, then, we quickly realized we were all a bit uncomfortable with "values." Who's values, the Centre's? (Can a Centre have values?) And what if someone's personal values conflict with the Centre's values – we certainly don't want to exclude a Centre staff member because their own values are different!
At some point, I said supporting evidence-informed pedagogies has got to be one of the principles we follow. I think that's when another senior staff suggested we have guiding principles instead of values. Everyone immediately agreed, and all the anxiety and hesitation around "values" disappeared.
We chose "evidence-informed" rather than "evidence-based" to allow for experimentation and innovation. Limiting ourselves to approaches that have conclusive evidence and peer-reviewed literature would be, well, limiting. We're definitely not saying anything goes, though. For example, if a faculty member comes to us for help creating a syllabus or curriculum based on their students' learning styles, we'll be having a frank conversation with them. The "meshing hypothesis" of learning styles – that an instructor tailor their instruction to individual student's learning style (visual, auditory, tactile, etc.) – is not a valid pedagogy. Would we refuse to work with that instructor? No. We'd let them know that learning styles are not a valid model, we'd inform them of the valid research about how people learn that shows all students benefit from seeing the same concepts in more than one context, and help them develop lessons where every student sees concepts more than once and in more than one format.
this is "professional development" not "training". It's not that we train course instructors how to teach – it's way too complicated for that. Instead, we provide opportunities for these professionals to develop their skills and practices, if they choose to pursue those opportunities.
I've been to enough workshops and, yes, led enough workshops where participants get nothing valuable out of the time and effort they invested in coming and participating. Here's the typical scenario, something all Centres for Teaching are struggling with: You promote and prepare a 1-hour workshop on learning outcomes. And no one comes. Why not? Because the content has so generic – to not exclude any particular discipline – that nothing is applicable. That's not a valuable hour.By demanding our programs be valuable, we're thoughtful about discipline-specific content, even if that means running the same learning outcomes workshop in 4 different Faculties, altering the context and examples to their disciplines. We also work hard to deliver workshops in their spaces – if someone is looking for an excuse to skip the workshop, having to trek across campus in the cold or heat is enough. Our goal is to offer workshops down the hall from their office. We also work hard to collaborate with the Faculty, rather than parachuting in. This includes enlisting the support of the Dean, Director, or Department Head to promote the opportunities. First, when the message comes from the Dean, it carries more weight than spam from the Centre. Second, potential participants know that their Dean, Director, or Department Head recognizes this is a valuable opportunity and it's a legitimate use of the participants time to attend the workshop. This guiding principle helps us make decisions about what, where, when, why, and how to offer workshops. Instead of doing things "the ways it's always been done," we question and revise.
I could write a entire blog post about each of the words respect, inclusion, equity, and compassion. Maybe I'll do that someday. In the meantime, here are a few thoughts that drove us to select these values.
Nothing gets my hackles up like deliberate disrespect for students. Punching down, starting from an assumption that students are dishonest or lazy, intolerance of anything but full and unwavering attention. I think it's easier to identify disrespectful actions, so I need my team to be vigilante about being disrespectful to our colleagues.
We need to be compassionate with our colleagues and the complicated lives they lead. If we're running a series and a participant has to miss a session because of, well, life, that's fine. If workshop participants need to keep their phones handy because there's a sick kid, fine. Need to eat your lunch during our meeting because this is the only hour you have all day, sure, no problem. I deliberately and honestly express my gratitude that they're making time to participate in our programs even if, especially if, they can't fully participate.
All these values – respect, inclusion, equity, compassion – need to extend to the students in the courses we're supporting. For example, I struggle to support course instructors who want to implement reading quizzes at the beginning of each class because that's how they punish students who don't attend or arrive late. I'm 100% behind reading quizzes as part of a flipped learning model because they help students prepare for class and reward them for that effort.
This guiding principle means we're committing to have difficult conversations with course instructors when their teaching practices appear to be disrespectful, to exclude any student, to treat students unfairly, or to show a lack of care.
As we were finalizing our mission and guiding principles, I was reading "The Culture Code" by Daniel Coyle. Great book – I highly recommend it for Centre directors and others in leadership / management positions. He tells powerful stories about the importance of making an organization's mission visible. Not (just) to the public but to the employees. If the employees don't know what their organization stands for, how can they possibly support it?
That's why I put our mission and guiding principles on the wall at the front entrance to my Centre. It lets visitors know this is what we stand for and what they can expect from us. More importantly, Centre staff – including me – see this every time we walk in and out. We're reminded, many times each day, what we stand for and what we expect can from each other and from ourselves.
Was is worth all the effort?
There isn't a day that I don't refer to the mission and guiding principles when chatting with Centre colleagues about projects, initiatives, or opportunities we could be involved in. The mission and guiding principles give us a shared language and a simple but powerful tool for evaluating and assessing what we can do to promote, inspire, and support excellence, leadership, scholarship, and technologies in teaching and learning.
If you're a Centre for Teaching director and you're thinking about establishing a centre mission, vision, and values, feel free to contact me – I'm happy to elaborate on anything here.


to the youth of Eswatini.
Help us reinforce the message!
Eswatini (formerly known as Swaziland) in Southern Africa has the highest rate of HIV/AIDS infection in the world. SKRUM's mission is to reduce these figures and offer hope to the youth of Eswatini.


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Have you ever wondered how startups like Evernote, Dropbox, Instagram, or even Pinterest took off like a rocket and left their competition sucking dust even though they were out-gunned and out -financed? Do you think the services went viral simply because they built a better product?
Growth Hacking is a calculated and data-driven model with a clear destination in mind and Ryan Holiday explains the new marketing precisely in his book Growth Hacker Marketing.
I originally started my Growth Hacker Marketing book review off by stating that anyone working an online business with limited resources needs to read it. In reality, it's actually much more powerful than that.
Lack of funding may have been what ignited Growth Hacker Marketing in the beginning but now that it's outperforming traditional marketing on almost every level, I believe anyone with an online presence should be paying very close attention.
Let's try this: I assumed every time I signed up for a new online service and they wanted me to connect my email or Facebook account to their service that they were just trying to gain access for data-mining and to advertise to my connections.
It's actually MUCH smarter than that. That would have been a "traditional marketing" way of thinking. Data and access might be a secondary consideration but the power lies in trackable action and understanding what triggers the desired growth.
I'm right on the edge of adding Growth Hacker Marketing to my top picks, but it's not quite there. It's not quite at the "Crush It" or "The One Thing" level but almost.
I just might add it to the list later if it starts looking like the book is relevant to more people. Don't get me wrong, I think anyone working online should read the Growth Hacker Marketing book and put the lessons AND the thinking behind it and grow big.
BONUS: Near the end of the book, author Ryan Holiday tells how to gain several pretty cool bonuses such as a chapter of his first book, "Trust Me, I'm Lying" and a redemption code for a free month of Growth Hacker TV.
First, what exactly is Growth Hacking?
Ryan Holiday starts with a short story on how he was introduced to Growth Hacker Marketing at the age of just 25 working as the Director of Marketing for American Apparel. Mr Holiday first seen the term in an article by Andrew Change called "Growth Hacker is the new VP of Marketing" and even as a top marketing executive for a multi-million dollar corporation, he had no idea what growth hacking was. I'd say it's fair to say that since that day, Growth Hacker Marketing has changed Ryan Holiday's life along with thousands of others.


text:
Rediff.com » News » Kim vows complete denuclearisation at historic summit with Trump
Kim vows complete denuclearisation at historic summit with Trump
By Gurdip Singh
Last updated on: June 12, 2018 21:56 IST
Trump announced that US would halt military exercises in South Korea, something widely seen as a concession as Pyongyang has long claimed they are invasion rehearsals.
The president, however, said the sanctions on North Korea for its nuclear tests will remain for now.
When Trump gave Kim Jong Un a thumbs-up
Timeline of Trump-Kim summit
IMAGE: US President Donald Trump shakes hands with North Korea's leader Kim Jong Un before their bilateral meeting at the Capella Hotel on Sentosa island in Singapore on Tuesday. Photograph: Jonathan Ernst/Reuters
North Korean leader Kim Jong Un on Tuesday pledged to work toward the 'complete denuclearisation' in return for security guarantees from the United States as Donald Trump wrapped up his historic summit with outcomes that could ease tensions and reshape the geopolitics of the Asia-Pacific region.
"Yesterday's conflict does not have to be tomorrow's war," Trump said following more than four hours of intense talks with Kim, which he described as 'honest, direct and productive'.
Trump said Kim 'reaffirmed' his commitment to denuclearisation of the Korean Peninsula and also agreed to destroy a missile engine test site.
IMAGE: Trump speaks while Kim looks at the signed document that acknowledge the progress of the talks and pledge to keep momentum going, after their summit at the Capella Hotel. Photograph: Johnathan Ernst/Reuters
"We are ready to write a new chapter between our nations," Trump told reporters after the much talked about summit -- the first between a sitting US president and North Korea's top leader.
He also announced that he would halt US military exercises in South Korea, something widely seen as a concession as Pyongyang has long claimed they are invasion rehearsals.
Trump and Kim conducted a comprehensive, in-depth, and sincere exchange of opinions on the issues related to the establishment of new relations between the two countries and the building of a lasting and robust peace regime on the Korean Peninsula, according to a joint statement signed by Trump and Kim.
IMAGE: Kim, Trump meet at the Capella hotel. Photograph: Jonathan Ernst/Reuters
'President Trump committed to provide security guarantees to the DPRK (Democratic People's Republic of Korea), and Chairman Kim Jong Un reaffirmed his firm and unwavering commitment to complete denuclearisation of the Korean Peninsula,' the statement said.
It said the two sides committed to recovering POW/MIA (prisoners of war and missing in action) remains including the immediate repatriation of those already identified.
The document was signed after the two leaders had a one-on-one meeting, with translators only, followed by an expanded meeting including their top aides and a working lunch at Capella Singapore hotel in Sentosa Island after months of diplomatic twists and turns.
"We signed a joint statement that is an unwavering commitment to complete denuclearisation of North Korea," Trump said.
WATCH: Trump and Kim share historic handshake
He said the US is 'prepared to start a new history' with North Korea.
"Kim told me that North Korea has already destroyed a major missile engine testing site," he said, without elaborating on it.
In response to a question about denuclearisation, Trump said, "We're starting that process... very quickly."
Trump said there will be a meeting next week to go over the details of the denuclearisation process.
"We are working with the regional countries on getting this deal going. We are sitting with (National Security Advisor) John Bolton next week to go over the details, to get this stuff done. We are working with South Korea, Japan, China to a lesser extent," he said, while addressing an hour-long press conference.
IMAGE: Trump and Kim before their expanded bilateral meeting. Photograph: Johnathan Ernst/Reuters
When asked about North Korea's future economic model, Trump said it is for the country and its people to decide. He pointed out the real estate potential of its 'great beaches' which can be seen on missile test footage.
Earlier, Trump said the summit went 'better than anybody could have expected'.
"We have decided to leave the past behind," Kim said through a translator, after signing the statement.
"The world will see a major change," he added.
Trump said he was very proud of what took place today and the two leaders would 'take care of a very dangerous problem for the world'.
IMAGE: The two leaders shared a 12-second handshake against a backdrop of American and North Korean flags. They then appeared to share a few light-hearted words as they walked down a corridor to the hotel's library. Photograph: Jonathan Ernst/Reuters
The 71-year-old Trump said he has developed a 'very special bond' with 34-year-old Kim.
Trump said Kim is 'a very talented man' and he will invite him to the White House at the 'appropriate time', and he will also travel to Pyongyang at a certain time.
Earlier on Tuesday morning, the summit began with the two leaders arriving separately at the luxurious hotel.
IMAGE: The motorcade of US President Donald Trump travels towards Sentosa for his meeting with North Korean leader Kim Jong-un. Photograph: Feline Lim/Reuters
They walked towards each other, stood face to face for the first time and shared a 12-second handshake against a backdrop of American and North Korean flags.
They then appeared to share a few light-hearted words as they walked down a corridor to the hotel's library.
The two leaders held one-on-one meeting for around 45-minutes with just translators present.
IMAGE: Trump speaks during a news conference after the meeting. Photograph: Jonathan Ernst/Reuters
According to North Korean media, Kim actually arrived at the venue seven minutes earlier than Trump to show respect as it's cultural, the young one should arrive earlier than the elder one.
The red tie that Trump wears may also show some respect to Kim as well, it's the colour that North Koreans like.
Later, they held delegation-level talks. Kim was asked at least three times if he would give up his nuclear weapons. In response, he just smiled.
IMAGE: Chef Abraham Tan of Royal Plaza on Scotts' Carousel restaurant puts finishing touches to his creation, the Trump Kim burger in Singapore. Photograph: Edgar Su/Reuters
"There will be challenges ahead but we will work with Trump. We overcame all kinds of skepticism and speculation about this summit and I believe that this is good for the peace," Kim said.
After the delegation-level meeting, Trump joined Kim for a working lunch which had a mix of Western and Asian dishes, such as Korean stuffed cucumber and beef short rib confit with some Haagen-Dazs ice cream to top things off.
The two leaders then took a post-lunch stroll in the courtyard of the hotel.
On the eve of the summit at Sentosa, the US had offered 'unique' security guarantees to North Korea in return for a 'complete, verifiable and irreversible' denuclearisation.
What's for lunch
US President Donald Trump joined North Korean leader Kim Jong Un for a working lunch which had a mix of Western and Asian dishes, such as Korean stuffed cucumber and beef short rib confit with some Haagen-Dazs ice cream to top things off.
After their bilateral meeting at the Capella hotel in Singapore's Sentosa island, Trump and Kim met for a working lunch along with their aides.
As the two men entered the room, photographs were taken, with Trump joking about wanting to get a "beautiful picture" in which he looked good.
The two leaders and their respective delegation were seated on either side of a long white table facing one another. The table was decorated with green and white flowers.
The full menu includes:
Starters: Prawn cocktail with avocado salad, green mango kerabu or "oiseon," a Korean stuffed cucumber.
Main course: Beef short rib confit, Sweet and sour crispy pork with Yangzhou Fried Rice or "Daegu jorim," a Korean soy braised cod fish
Desserts: Dark chocolate tartlet ganache, Vanilla ice cream or "Tropezienne," a pastry dessert.
Gurdip Singh in Singapore
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