text:
documentation.suse.com › SUSE Linux Enterprise Server Documentation › Deployment Guide › Initial System Configuration › Installing Modules, Extensions, and Third Party Add-On Products
1 Planning for SUSE Linux Enterprise Server
I Installation Preparation
2 Installation on AMD64 and Intel 64
3 Installation on IBM POWER
4 Installation on IBM z Systems
5 Installation on ARM AArch64
II The Installation Workflow
6 Installation with YaST
7 Cloning Disk Images
III Setting Up an Installation Server
8 Setting Up the Server Holding the Installation Sources
9 Preparing the Boot of the Target System
IV Remote Installation
10 Remote Installation
V Initial System Configuration
11 Setting Up Hardware Components with YaST
12 Advanced Disk Setup
13 Installing or Removing Software
14 Installing Modules, Extensions, and Third Party Add-On Products
15 Installing Multiple Kernel Versions
16 Managing Users with YaST
17 Changing Language and Country Settings with YaST
VI Updating and Upgrading SUSE Linux Enterprise
18 Life Cycle and Support
19 Upgrading SUSE Linux Enterprise
20 Upgrading Offline
21 Upgrading Online
22 Backporting Source Code
A Documentation Updates
B GNU Licenses
14 Installing Modules, Extensions, and Third Party Add-On Products #Edit source
Modules and extensions add parts or functionality to the system. Modules are fully supported parts of SUSE Linux Enterprise Server with a different life cycle and update timeline. They are a set of packages, have a clearly defined scope and are delivered via online channel only.
Extensions, such as the Workstation Extension or the High Availability Extension, add extra functionality to the system and require an own registration key that is liable for costs. Extensions are delivered via online channel or physical media. Registering at the SUSE Customer Center or a local registration server is a prerequisite for subscribing to the online channels. The Package Hub (Section 14.6, "SUSE Package Hub") and SUSE Software Development Kit (Section 14.5, "SUSE Software Development Kit (SDK) 12 SP4") extensions are exceptions which do not require a registration key and are not covered by SUSE support agreements.
A list of modules and extensions for your product is available after having registered your system at SUSE Customer Center or a local registration server. If you skipped the registration step during the installation, you can register your system at any time using the SUSE Customer Center Configuration module in YaST. For details, refer to Section 20.8, "Registering Your System".
Some add-on products are also provided by third parties, for example, binary-only drivers that are needed by certain hardware to function properly. If you have such hardware, refer to the release notes for more information about availability of binary drivers for your system. The release notes are available from http://www.suse.com/releasenotes/, from YaST or from /usr/share/doc/release-notes/ in your installed system.
14.1 List of Optional Modules
14.2 List of Available Extensions
14.3 Installing Modules and Extensions from Online Channels
14.4 Installing Extensions and Third Party Add-On Products from Media
14.5 SUSE Software Development Kit (SDK) 12 SP4
14.6 SUSE Package Hub
14.1 List of Optional Modules #Edit source
Besides the base server operating system, SUSE Linux Enterprise Server 12 provides optional modules included in the subscription. Each module has a different lifecycle. This approach offers faster integration with upstream updates. Below is a list of all optional modules together with brief descriptions:
This is the Software Development Kit (SDK) for the family of SUSE Linux Enterprise products. It is a free of charge extension for partners and customers working with SUSE Linux Enterprise Server, Desktop, and derived products.
For more information about SUSE Software Development Kit, refer to Section 14.5, "SUSE Software Development Kit (SDK) 12 SP4".
SUSE Package Hub provides access to community maintained packages built to run on SUSE Linux Enterprise Server. Built from the same sources used in the openSUSE distributions, these quality packages provide additional software to what is found in SUSE Linux Enterprise Server.
For more information about SUSE Package Hub, refer to Section 14.6, "SUSE Package Hub".
Advanced Systems Management Module
This module contains three components to support system administrators in automating tasks in the data center and cloud: the configuration management tools 'CFEngine' and 'puppet', and the new "machinery" infrastructure. Machinery is a systems management toolbox that allows you to inspect systems remotely, store their system descriptions, and create new system images to deploy in data centers and clouds.
For more information about the Machinery project, see http://machinery-project.org/.
Containers Module
This module contains several packages revolving around containers and related tools, including the Docker Open Source Engine and prepackaged images for SUSE Linux Enterprise Server 11 and SUSE Linux Enterprise Server 12.
HPC Module
The HPC Module provides a selected set of tools and components used in High Performance Computing environments. To fulfill changing customer needs for leading edge HPC support on both hardware and software, this module provides software components frequently updated to the latest versions available. The selection of software components has been inspired by (but not limited to) what is provided by the OpenHPC community project at http://openhpc.community/.
Legacy Module
The Legacy Module helps you migrate applications from older systems to SUSE Linux Enterprise Server 12. For organizations moving from UNIX to Linux, this module may be essential. Many older applications require packages that are no longer available with the latest SUSE Linux Enterprise Server version. This module provides those packages. It includes packages such as sendmail, syslog-ng, IBM Java6 and a number of libraries (for example, openssl-0.9.8).
Public Cloud Module
The Public Cloud Module is a collection of tools to create and manage public cloud images from the command line. When building your own images with KIWI or SUSE Studio, initialization code specific to the target cloud is included in that image.
The Public Cloud Module contains four patterns:
Amazon–Web–Services (aws–cli, cloud–init)
Microsoft–Azure (WALinuxAgent)
Google–Cloud–Platform (gcimagebundle, google–api–python–client, google–cloud–sdk, google–daemon, google–startup–scripts)
OpenStack (OpenStack–heat–cfntools, cloud–init)
SUSE Cloud Application Platform Tools Module
The SUSE Cloud Application Platform Tools Module is a collection of tools that enables you to interact with the SUSE Cloud Application Platform product itself, providing the commandline client for instance.
The module has a different lifecycle than SUSE Linux Enterprise Server itself; please check the Release Notes for further details.
Toolchain Module
This module offers software developers a current toolchain consisting of GNU Compiler Collection (GCC) and related packages as well as updated applications, improvements, new standards and additional hardware features. It allows software developers to benefit of new features of the most recent GCC release and brings improvements in language support, like for most C++14 changes and more Fortran 2008 and 2015 support, as well as many new optimizations. For more details, see https://gcc.gnu.org/gcc-5/changes.html.
Web and Scripting Module
The Web and Scripting Module delivers a comprehensive set of scripting languages, frameworks and related tools to help developers and system administrators accelerate the creation of stable, modern web applications. The module includes recent versions of dynamic languages, such as PHP and Python. If you intend to run a web server or host applications that have web portals or require server-side scripts, then the Web and Scripting Module is a must.
14.2 List of Available Extensions #Edit source
Extensions provide advanced capabilities for tasks such as live patching and high availability clustering to SUSE Linux Enterprise Server. They are offered as subscriptions and require a registration key that is liable for costs. Usually, extensions have their own release notes that are available from https://www.suse.com/releasenotes.
SUSE Linux Enterprise High Availability provides mature, industry-leading open-source high-availability clustering technologies that are easy to set up and use. It can be deployed in physical and/or virtual environments, and can cluster physical servers, virtual servers, or any combination of the two to suit your business needs.
High Availability support is included in subscriptions for SUSE Linux Enterprise Server for SAP Applications and SUSE Linux Enterprise High Performance Computing and also available as an extension for SUSE Linux Enterprise Server.
High Availability Geo Clustering
GEO Clustering for SUSE Linux Enterprise High Availability Extension is an industry-leading open source high availability system designed to manage cluster servers in data centers anywhere in the world.
Live Patching
With SUSE Linux Enterprise Live Patching, you can perform critical kernel patching without shutting down your system, reducing the need for planned downtime and increasing service availability.
Workstation Extension
The Workstation Extension extends the functionality of SUSE Linux Enterprise Server with packages of SUSE Linux Enterprise Desktop, like additional desktop applications and libraries. It allows to combine both products to create a full featured workstation.
SUSE Manager Server
SUSE Manager lets you efficiently manage physical, virtual, and cloud-based Linux systems. It provides automated and cost-effective configuration and software management, asset management, and system provisioning.
SUSE Manager Proxy
SUSE Manager Proxies extend large and/or geographically dispersed SUSE Manager environments to reduce load on the SUSE Manager Server, lower bandwidth needs, and provide faster local updates.
SUSE OpenStack Cloud 9
SUSE OpenStack Cloud is powered by OpenStack, the leading community driven, open source, cloud infrastructure project, and packaged with SUSE Linux Enterprise Server. The product is fully integrated with SUSE maintenance and support infrastructure. It is an ideal solution for customers looking to deploy a cloud with enterprise levels of stability and support.
SUSE OpenStack Cloud Crowbar 9
SUSE OpenStack Cloud Crowbar is an open source software solution that provides the fundamental capabilities to deploy and manage a cloud infrastructure powered by OpenStack, the leading community-driven, open source cloud infrastructure project. It seamlessly manages and provisions workloads across a heterogeneous cloud environment in a secure, compliant, and fully-supported manner.
14.3 Installing Modules and Extensions from Online Channels #Edit source
Tip: SUSE Linux Enterprise Desktop
As of SUSE Linux Enterprise 12, SUSE Linux Enterprise Desktop is not only available as a separate product, but also as a Workstation Extension for SUSE Linux Enterprise Server. If you register at the SUSE Customer Center, the Workstation Extension can be selected for installation. Note that installing it requires a valid registration key.
The following procedure requires that you have registered your system with SUSE Customer Center, or a local registration server. When registering your system, you will see a list of extensions and modules immediately after having completed Step 4 of Section 20.8, "Registering Your System". In that case, skip the next steps and proceed with Step 2.
Note: Viewing Already Installed Add-Ons
To view already installed add-ons, start YaST and select Software › Add-Ons
Procedure 14.1: Installing Add-ons and Extensions from Online Channels with YaST #
Start YaST and select Software › Add System Extensions or Modules.
YaST connects to the registration server and displays a list of Available Extensions and Modules.
Note: Available Extensions and Modules
The amount of available extensions and modules depends on the registration server. A local registration server may only offer update repositories and no additional extensions.
Note: Module Life Cycles
Life cycle end dates of modules are available at https://scc.suse.com/docs/lifecycle/sle/12/modules.
Click an entry to see its description.
Select one or multiple entries for installation by activating their check marks.
Figure 14.1: Installation of System Extensions #
Click Next to proceed.
Depending on the repositories to be added for the extension or module, you may be prompted to import the repository's GPG key or asked to agree to a license.
After confirming these messages, YaST will download and parse the metadata. The repositories for the selected extensions will be added to your system—no additional installation sources are required.
If needed, adjust the repository Properties as described in Section 13.4.2, "Managing Repository Properties".
Note: For More Information
White paper SUSE Linux Enterprise Server 12 Modules.
14.4 Installing Extensions and Third Party Add-On Products from Media #Edit source
When installing an extension or add-on product from media, you can select various types of product media, like DVD/CD, removable mass storage devices (such as flash disks), or a local directory or ISO image. The media can also be provided by a network server, for example, via HTTP, FTP, NFS, or Samba.
Start YaST and select Software › Add-On Products. Alternatively, start the YaST Add-On Products module from the command line with sudo yast2 add-on.
The dialog will show an overview of already installed add-on products, modules and extensions.
Figure 14.2: List of Installed Add-on Products, Modules and Extensions #
Choose Add to install a new add-on product.
In the Add-On Product dialog, select the option that matches the type of medium from which you want to install:
Figure 14.3: Installation of an Add-on Product or an Extension #
To scan your network for installation servers announcing their services via SLP, select Scan Using SLP and click Next.
To add a repository from a removable medium, choose the relevant option and insert the medium or connect the USB device to the machine, respectively. Click Next to start the installation.
For most media types, you will prompted to specify the path (or URL) to the media after selecting the respective option and clicking Next. Specifying a Repository Name is optional. If none is specified, YaST will use the product name or the URL as the repository name.
The option Download Repository Description Files is activated by default. If you deactivate the option, YaST will automatically download the files later, if needed.
Depending on the repository you have added, you may be prompted to import the repository's GPG key or asked to agree to a license.
After confirming these messages, YaST will download and parse the metadata. It will add the repository to the list of Configured Repositories.
Confirm your changes with OK to close the configuration dialog.
After having successfully added the repository for the add-on media, the software manager starts and you can install packages. For details, refer to Chapter 13, Installing or Removing Software.
14.5 SUSE Software Development Kit (SDK) 12 SP4 #Edit source
SUSE Software Development Kit 12 SP4 is an extension for SUSE Linux Enterprise 12 SP4. It is a complete tool kit for application development. In fact, to provide a comprehensive build system, SUSE Software Development Kit 12 SP4 includes all the open source tools that were used to build the SUSE Linux Enterprise Server product. It provides you as a developer, independent software vendor (ISV), or independent hardware vendor (IHV) with all the tools needed to port applications to all the platforms supported by SUSE Linux Enterprise Desktop and SUSE Linux Enterprise Server.
The SUSE Software Development Kit does not require a registration key and is not covered by SUSE support agreements.
SUSE Software Development Kit also contains integrated development environments (IDEs), debuggers, code editors, and other related tools. It supports most major programming languages, including C, C++, Java, and most scripting languages. For your convenience, SUSE Software Development Kit includes multiple Perl packages that are not included in SUSE Linux Enterprise.
The SDK extension is available via an online channel from the SUSE Customer Center. Alternatively, go to http://download.suse.com/, search for SUSE Linux Enterprise Software Development Kit and download it from there. Refer to Chapter 14, Installing Modules, Extensions, and Third Party Add-On Products for details.
14.6 SUSE Package Hub #Edit source
In the list of Available Extensions and Modules you find the SUSE Package Hub. It is available without any additional fee. It provides a large set of additional community packages for SUSE Linux Enterprise that can easily be installed but are not supported by SUSE.
More information about SUSE Package Hub and how to contribute is available at https://packagehub.suse.com/
Important: SUSE Package Hub is Not Supported
Be aware that packages provided in the SUSE Package Hub are not officially supported by SUSE. SUSE only provides support for enabling the Package Hub repository and help with installation or deployment of the RPM packages.
→Chapter 15 Installing Multiple Kernel Versions←Chapter 13 Installing or Removing Software


Until one moment—one mistake—changes everything. To save his career, Cory must go back to the town where it all began. His plan is simple: coach the local baseball team, complete a recovery program, and get out as fast as possible. Instead, he runs headfirst into memories he can't escape … and the love he left behind.
That's because I enjoyed it more than I thought I would, and I'm glad I read it.
It's a story of redemption and restoration.
Cory Brand was quite the character. His personality represents a lot of people in our world today. His pain and struggles were so real it was hard not to relate to him in some way. I loved how Travis showed the rawness and depth of an addiction and how it could deceitfully hinder a victim from sooner recovery. This story made it pretty clear what every child of God learns sooner or later: it takes grace to get past the pain of the past so that we overcome our struggles. Only then can we enjoy the gift of life He has given us.
Other characters, Emma, Clay and Karen—though I enjoyed their part in the story, their personalities were not as well developed as Cory's and Helene. Helene was indeed very striking. You could easily shape her personality through the pages.
Also, Cory's thought-process throughout the book was adequately filled with his pain and struggles, but I would have also loved to see his thoughts about the possibility of turning to God, build from somewhere as the story went along, so that when he finally admitted that he needed God, it didn't seem so sudden.
Overall I found this book very engaging. I read this over-400 page work in three sittings but all the hours put together were less than 24. Seriously. I kept trying to hurry myself along so I could grab the whole story. I found myself laughing with some characters, scoffing at others and plain shaking my head, arms crossed and so annoyed with some others. Like they were real people. It was fun.
The end is not like any typical romance read, but very satisfying. That's probably because it was novelized from a movie. And from a movie's point of view, it was a wonderful end. It was finished with so much hope in the lives of the characters.
Any lover of Karen Kingsbury's work, especially 'Between Sundays' would love this book. This book and 'Between Sundays' are distinct enough, but the similarities don't go unnoticed.
Travis Thrasher is the author of over twenty works of fiction in a variety of genres. He has collaborated with musicians, filmmakers, and pastors. His stories all feature broken characters on journeys toward redemption. Upcoming books for 2013 include the novelization of Home Run and Are You Gonna Kiss Me Or Not? co-authored with the band Thompson Square.


Destination Docklands are running the 'Shades of winter' photo competition this July and August.
Entry is free and open to all, whether you're a budding amateur snapper or seasoned professional photographer; we want to see Docklands through your eyes. The competition aims to capture Docklands in winter from a range of perspectives and in different lights; images can comprise of anything in Docklands – scenery, people, places, activities, sport, shopping, animals, dining, entertainment, water – the list is endless.
A cash prize of $1,000 will be awarded to the winner of the adult category and $500 will be awarded to the winner of the youth category (under 16 years) along with the opportunity to feature in a Docklands photo exhibition later this year.
Kelly Jensen Events and Engagement Manager at Destination Docklands said "There are many great opportunities to capture Docklands beauty this winter; with dazzling fireworks presented by City of Melbourne taking place on Victoria Harbour every Friday night in July and August, cute and cosy markets every Sunday on New Quay Promenade, winter school holiday excitement at Wonderland Fun Park and Harbour Town Shopping Centre, the best AFL teams in the league firing up at Etihad Stadium every week and monthly state ice hockey matches at Medibank Icehouse, there is always something happening in Docklands".
So, take a flight on the Melbourne Star and capture Docklands from a greater angle, sit waterfront at some of Melbourne's best cafes, bars and restaurants and capture the beauty of our Harbour, lay in the grass in one of the many Docklands green areas or show us your sporting prowess on one of the free sporting courts. Take a snap of your favourite piece of public artwork, bridges and personalities or simply seize the opportunity to show us how you enjoy Docklands, inspiring others to do the same.
For your chance to win, submit your entries to info@destinationdocklands.com.au as attached JPEG files with the subject line 'Shades of winter' and indicate if it is a youth or adult entry. Please include your name, address, phone number, photo title and a short description of the photo along with the date it was taken in the body of the email. All entries must be copyright free, taken between the dates of July 1 and August 31 2014 and be the work of the entrant.


December's big initially reported gain of 312,000 was knocked all the way down to 222,000, while November's rose from 176,000 to 196,000. On net, that took the two months down by 70,000, bringing the three-month average to 241,000. That's still well above the trend that would be common this far into an economic expansion dating back nine and a half years.
The job creation saw muted wage growth, with average hourly earnings rising just three cents on the month, or 0.1 percent, well below the 0.3 percent expected gain. On a year-over-year basis, though, that still amounted to a 3.2 percent increase, consistent with the past few months and around the highest levels of the recovery.


text:
Antropologia
 Moltiplicatore di Petrie – esperimento mentale proposto da Karen Petrie, che rivela come una minoranza di donne in un gruppo ricevono una quantità sproporzionata di interazioni sessiste, anche se uomini e donne sono ugualmente sessisti

Astronomia
 Cratere Petrie – cratere lunare di 32,86 km situato nella parte nord-occidentale della faccia nascosta della Luna
 21476 Petrie – asteroide della fascia principale

Geografia
 Petrie – sobborgo di Brisbane, Queensland, Australia

Persone
 Alistair Petrie (1970) – attore inglese
 Anthony Petrie (1983) – cestista australiano
 Charles Petrie (1895-1977) – srotico britannico
 Daniel Petrie (1920-2004) – regista cinematografico e televisivo canadese
 Donald Petrie (1954) – regista, attore, produttore televisivo e produttore cinematografico statunitense
 Douglas Petrie (...) – produttore televisivo, sceneggiatore e regista statunitense
 Flinders Petrie (1853-1942) – egittologo e archeologo britannico
 Geoff Petrie (1948) – ex cestista e dirigente sportivo statunitense
 George Petrie (1790-1866) – pittore, musicista e archeologo irlandese
 George Petrie (George O. Petrie, 1912-1997) – attore statunitense
 Jon Petrie (1976) –  ex rugbista a 15 scozzese
 Mark Petrie (1979) – compositore neozelandese

redpajama_set_name: RedPajamaWikipedia


text:
OSTI.GOV Journal Article: Gaussian basis sets for use in correlated molecular calculations. XI. Pseudopotential-based and all-electron relativistic basis sets for alkali metal (K–Fr) and alkaline earth (Ca–Ra) elements
Title: Gaussian basis sets for use in correlated molecular calculations. XI. Pseudopotential-based and all-electron relativistic basis sets for alkali metal (K–Fr) and alkaline earth (Ca–Ra) elements
New correlation consistent basis sets based on pseudopotential (PP) Hamiltonians have been developed from double- to quintuple-zeta quality for the late alkali (K–Fr) and alkaline earth (Ca–Ra) metals. These are accompanied by new all-electron basis sets of double- to quadruple-zeta quality that have been contracted for use with both Douglas-Kroll-Hess (DKH) and eXact 2-Component (X2C) scalar relativistic Hamiltonians. Sets for valence correlation (ms), cc-pVnZ-PP and cc-pVnZ-(DK,DK3/X2C), in addition to outer-core correlation [valence + (m-1)sp], cc-p(w)CVnZ-PP and cc-pwCVnZ-(DK,DK3/X2C), are reported. The –PP sets have been developed for use with small-core PPs [I. S. Lim et al., J. Chem. Phys. 122, 104103 (2005) and I. S. Lim et al., J. Chem. Phys. 124, 034107 (2006)], while the all-electron sets utilized second-order DKH Hamiltonians for 4s and 5s elements and third-order DKH for 6s and 7s. The accuracy of the basis sets is assessed through benchmark calculations at the coupled-cluster level of theory for both atomic and molecular properties. Not surprisingly, it is found that outer-core correlation is vital for accurate calculation of the thermodynamic and spectroscopic properties of diatomic molecules containing these elements.
Hill, J. Grant [1];
Search OSTI.GOV for author "Hill, J. Grant"
Search OSTI.GOV for ORCID "0000-0002-6457-5837"
Peterson, Kirk A. [2]
Search OSTI.GOV for author "Peterson, Kirk A."
Univ. of Sheffield (United Kingdom). Dept. of Chemistry
Washington State Univ., Pullman, WA (United States). Dept. of Chemistry
Washington State Univ., Pullman, WA (United States)
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Alternate Identifier(s):
OSTI ID: 1414607
SC0008501; FG02-12ER16329
Journal Article: Accepted Manuscript
Journal of Chemical Physics
Journal Volume: 147; Journal Issue: 24; Journal ID: ISSN 0021-9606
American Institute of Physics (AIP)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Hill, J. Grant, and Peterson, Kirk A. Gaussian basis sets for use in correlated molecular calculations. XI. Pseudopotential-based and all-electron relativistic basis sets for alkali metal (K–Fr) and alkaline earth (Ca–Ra) elements. United States: N. p., 2017. Web. doi:10.1063/1.5010587.
Hill, J. Grant, & Peterson, Kirk A. Gaussian basis sets for use in correlated molecular calculations. XI. Pseudopotential-based and all-electron relativistic basis sets for alkali metal (K–Fr) and alkaline earth (Ca–Ra) elements. United States. https://doi.org/10.1063/1.5010587
Hill, J. Grant, and Peterson, Kirk A. Thu . "Gaussian basis sets for use in correlated molecular calculations. XI. Pseudopotential-based and all-electron relativistic basis sets for alkali metal (K–Fr) and alkaline earth (Ca–Ra) elements". United States. https://doi.org/10.1063/1.5010587. https://www.osti.gov/servlets/purl/1529220.
title = {Gaussian basis sets for use in correlated molecular calculations. XI. Pseudopotential-based and all-electron relativistic basis sets for alkali metal (K–Fr) and alkaline earth (Ca–Ra) elements},
author = {Hill, J. Grant and Peterson, Kirk A.},
abstractNote = {New correlation consistent basis sets based on pseudopotential (PP) Hamiltonians have been developed from double- to quintuple-zeta quality for the late alkali (K–Fr) and alkaline earth (Ca–Ra) metals. These are accompanied by new all-electron basis sets of double- to quadruple-zeta quality that have been contracted for use with both Douglas-Kroll-Hess (DKH) and eXact 2-Component (X2C) scalar relativistic Hamiltonians. Sets for valence correlation (ms), cc-pVnZ-PP and cc-pVnZ-(DK,DK3/X2C), in addition to outer-core correlation [valence + (m-1)sp], cc-p(w)CVnZ-PP and cc-pwCVnZ-(DK,DK3/X2C), are reported. The –PP sets have been developed for use with small-core PPs [I. S. Lim et al., J. Chem. Phys. 122, 104103 (2005) and I. S. Lim et al., J. Chem. Phys. 124, 034107 (2006)], while the all-electron sets utilized second-order DKH Hamiltonians for 4s and 5s elements and third-order DKH for 6s and 7s. The accuracy of the basis sets is assessed through benchmark calculations at the coupled-cluster level of theory for both atomic and molecular properties. Not surprisingly, it is found that outer-core correlation is vital for accurate calculation of the thermodynamic and spectroscopic properties of diatomic molecules containing these elements.},
doi = {10.1063/1.5010587},
url = {https://www.osti.gov/biblio/1529220}, journal = {Journal of Chemical Physics},
month = {12}
Relativistic Dirac-Fock expectation values for atoms with Z = 1 to Z = 120
Desclaux, J. P.
Atomic Data and Nuclear Data Tables, Vol. 12, Issue 4
https://doi.org/10.1016/0092-640x(73)90020-x
Measurement of the electron affinity of potassium
Andersson, Karin T.; Sandström, Joakim; Kiyan, Igor Yu.
Physical Review A, Vol. 62, Issue 2
https://doi.org/10.1103/physreva.62.022503
Cold controlled chemistry
Krems, R. V.
Physical Chemistry Chemical Physics, Vol. 10, Issue 28
https://doi.org/10.1039/b802322k
Laser cooling and slowing of CaF molecules
Zhelyazkova, V.; Cournol, A.; Wall, T. E.
Ab initio relativistic effective potentials with spin-orbit operators. VI. Fr through Pu
Ermler, W. C.; Ross, R. B.; Christiansen, P. A.
International Journal of Quantum Chemistry, Vol. 40, Issue 6
https://doi.org/10.1002/qua.560400611
Laser-induced fluorescence of the Rb2 molecule the X 1Σg+ electronic state up to ν = 72
Amiot, C.; Crozet, P.; Vergès, J.
Chemical Physics Letters, Vol. 121, Issue 4-5
Molpro: a general-purpose quantum chemistry program package: Molpro
Werner, Hans-Joachim; Knowles, Peter J.; Knizia, Gerald
Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 2, Issue 2
https://doi.org/10.1002/wcms.82
Relativistic Double-Zeta, Triple-Zeta, and Quadruple-Zeta Basis Sets for the 4s, 5s, 6s, and 7s Elements †
Dyall, Kenneth G.
https://doi.org/10.1021/jp905057q
Mixing of ionic and covalent configurations for sodium hydride, potassium hydride, and hydromagnesium(1+). Potential energy curves and couplings between molecular states
Numrich, Robert W.; Truhlar, Donald G.
https://doi.org/10.1021/j100592a010
The dissociation energies of the diatomic alkali hydrides
Yang, S. C.; Nelson, D. D.; Stwalley, William C.
The Journal of Chemical Physics, Vol. 78, Issue 7
A b i n i t i o study of the alkali and alkaline‐earth monohydroxides
Bauschlicher, Charles W.; Langhoff, Stephen R.; Partridge, Harry
Four-component and scalar relativistic Douglas-Kroll calculations for static dipole polarizabilities of the alkaline-earth-metal elements and their ions from Ca n to Ra n ( n = 0 ,+1,+2)
Lim, Ivan S.; Schwerdtfeger, Peter
Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
Hay, P. Jeffrey; Wadt, Willard R.
The Journal of Chemical Physics, Vol. 82, Issue 1, p. 299-310
Fourier transform emission spectroscopy of the E2Π–X2Σ+ transition of BaH
Ram, R. S.; Bernath, P. F.
Journal of Molecular Spectroscopy, Vol. 283
https://doi.org/10.1016/j.jms.2012.12.004
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen
Dunning, Thom H.
Gaussian basis sets for molecular applications
Hill, J. Grant
International Journal of Quantum Chemistry, Vol. 113, Issue 1
https://doi.org/10.1002/qua.24355
Electron affinities of the first‐row atoms revisited. Systematic basis sets and wave functions
Kendall, Rick A.; Dunning, Thom H.; Harrison, Robert J.
Revised Basis Sets for the LANL Effective Core Potentials
Roy, Lindsay E.; Hay, P. Jeffrey; Martin, Richard L.
Journal of Chemical Theory and Computation, Vol. 4, Issue 7
https://doi.org/10.1021/ct8000409
Determination of dissociation constants and heats of formation of simple molecules by flame photometry. Part 8.—Stabilities of the gaseous diatomic halides of certain metals
Bulewicz, E. M.; Phillips, L. F.; Sugden, T. M.
Trans. Faraday Soc., Vol. 57, Issue 0
https://doi.org/10.1039/tf9615700921
Comment on: "Estimating the Hartree–Fock limit from finite basis set calculations" [Jensen F (2005) Theor Chem Acc 113:267]
Karton, Amir; Martin, Jan M. L.
Theoretical Chemistry Accounts, Vol. 115, Issue 4
Simplest Molecules as Candidates for Precise Optical Clocks
Schiller, S.; Bakalov, D.; Korobov, V. I.
Physical Review Letters, Vol. 113, Issue 2
https://doi.org/10.1103/physrevlett.113.023004
Laser resonance photoionization spectroscopy of Rydberg levels in Fr
Andreev, S. V.; Letokhov, V. S.; Mishin, V. I.
Physical Review Letters, Vol. 59, Issue 12
https://doi.org/10.1103/physrevlett.59.1274
Ab Initio Potential Energy Surface and Vibrational−Rotational Energy Levels of X 2 Σ + CaOH
Koput, Jacek; Peterson, Kirk A.
https://doi.org/10.1021/jp026283u
The dissociation energy of the cesium dimer
Raab, M.; Weickenmeier, H.; Demtröder, W.
Chemical Physics Letters, Vol. 88, Issue 4
The Energy Levels of a Rotating Vibrator
Dunham, J. L.
Physical Review, Vol. 41, Issue 6
https://doi.org/10.1103/physrev.41.721
Alkali and alkaline earth metal compounds: core—valence basis sets and importance of subvalence correlation
Iron, Mark A.; Oren, Mikhal; Martin, Jan M. L.
https://doi.org/10.1080/0026897031000094498
Two-Color Photoassociation Spectroscopy of Ground State Rb 2
Tsai, C. C.; Freeland, R. S.; Vogels, J. M.
Physical Review Letters, Vol. 79, Issue 7
Mass Spectrometric Studies at High Temperatures. III. Dissociation Energies of the Alkaline Earth Monofluorides
Ehlert, T. C.; Blue, G. D.; Green, J. W.
All-electron and relativistic pseudopotential studies for the group 1 element polarizabilities from K to element 119
Lim, Ivan S.; Schwerdtfeger, Peter; Metz, Bernhard
The Journal of Chemical Physics, Vol. 122, Issue 10
Pair natural orbital and canonical coupled cluster reaction enthalpies involving light to heavy alkali and alkaline earth metals: the importance of sub-valence correlation
Minenkov, Yury; Bistoni, Giovanni; Riplinger, Christoph
https://doi.org/10.1039/c7cp00836h
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
Weigend, Florian; Ahlrichs, Reinhart
Physical Chemistry Chemical Physics, Vol. 7, Issue 18, p. 3297-3305
https://doi.org/10.1039/b508541a
Accurate relativistic Gaussian basis sets for H through Lr determined by atomic self-consistent field calculations with the third-order Douglas–Kroll approximation
Tsuchiya, Takashi; Abe, Minori; Nakajima, Takahito
Laser-induced fluorescence of CsH: The X1Σ+ state dissociation energy
Crepin, C.; Verges, J.; Amiot, C.
Chemical Physics Letters, Vol. 112, Issue 1
Dissociation Energies of the Alkaline Earth Monofluorides
Blue, Gary D.; Green, John W.; Ehlert, Thomas C.
Nature, Vol. 199, Issue 4895
https://doi.org/10.1038/199804a0
Online complete basis set limit extrapolation calculator
Vasilyev, Vladislav
Computational and Theoretical Chemistry, Vol. 1115
https://doi.org/10.1016/j.comptc.2017.06.001
Core-valence correlating basis sets for alkali and alkaline earth metal atoms
Noro, Takeshi; Sekiya, Masahiro; Koga, Toshikatsu
Theoretical Chemistry Accounts, Vol. 121, Issue 5-6
On the effectiveness of CCSD(T) complete basis set extrapolations for atomization energies
Feller, David; Peterson, Kirk A.; Grant Hill, J.
The Journal of Chemical Physics, Vol. 135, Issue 4
Systematically convergent basis sets with relativistic pseudopotentials. I. Correlation consistent basis sets for the post- d group 13–15 elements
Peterson, Kirk A.
Gaussian basis sets for use in correlated molecular calculations. VII. Valence, core-valence, and scalar relativistic basis sets for Li, Be, Na, and Mg
Prascher, Brian P.; Woon, David E.; Peterson, Kirk A.
Relativistic atomic natural orbital type basis sets for the alkaline and alkaline-earth atoms applied to the ground-state potentials for the corresponding dimers
Roos, Björn O.; Veryazov, Valera; Widmark, Per-Olof
Benchmark calculations of electron affinities of the alkali atoms sodium to eka-francium (element 119)
Landau, Arie; Eliav, Ephraim; Ishikawa, Yasuyuki
Comment on 'Pople versus Dunning basis sets for group IA metal hydrides and some other second row hydrides: The case against a De Facto standard' by R.A. Klein and M.A. Zottola [Chem. Phys. Lett. 419 (2006) 254–258]
Feller, David; Peterson, Kirk A.
Quantum-state-controlled Penning-ionization reactions between ultracold alkali-metal and metastable helium atoms
Flores, A. S.; Vassen, W.; Knoop, S.
Gaussian basis sets for use in correlated molecular calculations. V. Core‐valence basis sets for boron through neon
Woon, David E.; Dunning, Thom H.
Raman Spectroscopic Investigation of Matrix Isolated Rubidium and Cesium Molecules: Rb 2 , Rb 3 , Cs 2 , and Cs 3 † , 1
Kornath, Andreas; Zoermer, Anja; Ludwig, Ralf
Inorganic Chemistry, Vol. 38, Issue 21
https://doi.org/10.1021/ic990506m
General contraction of Gaussian basis sets. I. Atomic natural orbitals for first‐ and second‐row atoms
Almlöf, Jan; Taylor, Peter R.
Thermochemical Data for Gaseous Monoxides
Pedley, J. B.; Marshall, E. M.
Journal of Physical and Chemical Reference Data, Vol. 12, Issue 4
The long‐range potential of the K 2 X 1 Σ + g ground electronic state up to 15 Å
Amiot, Claude; Vergès, Jean; Fellows, Carlos E.
High resolution laser spectroscopy of Cs2. I. Ground state constants and potential curve
Höning, G.; Czajkowski, M.; Stock, M.
Atomic orbital basis sets: Atomic orbital basis sets
Jensen, Frank
https://doi.org/10.1002/wcms.1123
Quasirelativistic theory equivalent to fully relativistic theory
Kutzelnigg, Werner; Liu, Wenjian
Basis sets in correlated effective potential calculations
Christiansen, P. A.
Correlation consistent, Douglas–Kroll–Hess relativistic basis sets for the 5p and 6p elements
Bross, David H.; Peterson, Kirk A.
Segmented Contracted Error-Consistent Basis Sets of Double- and Triple-ζ Valence Quality for One- and Two-Component Relativistic All-Electron Calculations
Pollak, Patrik; Weigend, Florian
Journal of Chemical Theory and Computation, Vol. 13, Issue 8
https://doi.org/10.1021/acs.jctc.7b00593
Creation of Ultracold Rb 87 Cs 133 Molecules in the Rovibrational Ground State
Molony, Peter K.; Gregory, Philip D.; Ji, Zhonghua
Physical Review Letters, Vol. 113, Issue 25
Accurate correlation consistent basis sets for molecular core–valence correlation effects: The second row atoms Al–Ar, and the first row atoms B–Ne revisited
Peterson, Kirk A.; Dunning, Thom H.
High resolution photodetachment from the rubidium negative ion around the Rb(5p 1/2 ) threshold
Frey, P.; Breyer, F.; Holop, H.
Journal of Physics B: Atomic and Molecular Physics, Vol. 11, Issue 19
https://doi.org/10.1088/0022-3700/11/19/005
Correlation consistent basis sets for explicitly correlated wavefunctions: Pseudopotential-based basis sets for the post- d main group elements Ga–Rn
Hill, J. Grant; Peterson, Kirk A.
Relativistic small-core energy-consistent pseudopotentials for the alkaline-earth elements from Ca to Ra
Lim, Ivan S.; Stoll, Hermann; Schwerdtfeger, Peter
Atomic orbital basis sets for use with effective core potentials
Blaudeau, J. -P.; Brozell, S. R.; Matsika, S.
https://doi.org/10.1002/(sici)1097-461x(2000)77:2<516::aid-qua2>3.0.co;2-u
Parallel Douglas–Kroll energy and gradients in NWChem: Estimating scalar relativistic effects using Douglas–Kroll contracted basis sets
de Jong, W. A.; Harrison, R. J.; Dixon, D. A.
Basis-set convergence in correlated calculations on Ne, N2, and H2O
Halkier, Asger; Helgaker, Trygve; Jørgensen, Poul
Perspective: Stimulated Raman adiabatic passage: The status after 25 years
Bergmann, Klaas; Vitanov, Nikolay V.; Shore, Bruce W.
Segmented contracted basis sets for one- and two-component Dirac–Fock effective core potentials
Weigend, Florian; Baldes, Alexander
Basis-set convergence of correlated calculations on water
Helgaker, Trygve; Klopper, Wim; Koch, Henrik
The alkaline earth dimer cations (Be 2 + , Mg 2 + , Ca 2 + , Sr 2 + , and Ba 2 + ). Coupled cluster and full configuration interaction studies †
Li, Huidong; Feng, Hao; Sun, Weiguo
Molecular Physics, Vol. 111, Issue 14-15
https://doi.org/10.1080/00268976.2013.802818
The standard molar enthalpies of formation of BaO(g) and SrO(g)
Huntelaar, M. E.; Cordfunke, E. H. P.
The Journal of Chemical Thermodynamics, Vol. 29, Issue 7
https://doi.org/10.1006/jcht.1997.0206
Quantum Computation with Trapped Polar Molecules
DeMille, D.
https://doi.org/10.1103/physrevlett.88.067901
Correlation consistent basis sets for lanthanides: The atoms La–Lu
Lu, Qing; Peterson, Kirk A.
Experimental Evidence that the 6 s 6 p 3 P J States of Cs − Are Shape Resonances
Scheer, M.; Thøgersen, J.; Bilodeau, R. C.
https://doi.org/10.1103/physrevlett.80.684
Exact decoupling of the relativistic Fock operator
Peng, Daoling; Reiher, Markus
Electronic and vibrational spectroscopy of the low-lying states of potassium mono-sulphide KS, and comparison in the series of MS (M = Li, Na, K, Rb, Cs)
Hendaoui, Hamza; Linguerri, Roberto; Chambaud, Gilberte
Molecular Physics, Vol. 117, Issue 13
Microhydration of caesium metaborate: structural and thermochemical properties of CsBO2 + n H2O (n = 1–4) aggregates
Khiri, Dorra; Vandeputte, Romain; Taamalli, Sonia
Journal of Molecular Modeling, Vol. 25, Issue 7
A review on non‐relativistic, fully numerical electronic structure calculations on atoms and diatomic molecules
Lehtola, Susi
International Journal of Quantum Chemistry, Vol. 119, Issue 19
Vibrational frequencies, structures, and energetics of the highly challenging alkali metal trifluorides MF 3 (M = Li, Na, K, Rb, and Cs)
Sun, Zhi; Schaefer, Henry F.
https://doi.org/10.1039/c8cp03434f
Towards a rational design of laser-coolable molecules: insights from equation-of-motion coupled-cluster calculations
Ivanov, Maxim V.; Bangerter, Felix H.; Krylov, Anna I.
https://doi.org/10.1039/c9cp03914g
Ab initio studies of the ground and first excited states of the Sr–H 2 and Yb–H 2 complexes
Cybulski, Hubert
Ab initio interaction potentials of the Ba, Ba + complexes with Ar, Kr, and Xe in the lowest excited states
Bezrukov, Dmitry S.; Kleshchina, Nadezhda N.; Kalinina, Inna S.
Evaluation of experimental alkali metal ion–ligand noncovalent bond strengths with DLPNO-CCSD(T) method
Maity, Bholanath; Minenkov, Yury; Cavallo, Luigi
A new generation of effective core potentials from correlated calculations: 4s and 4p main group elements and first row additions
Wang, Guangming; Annaberdiyev, Abdulgani; Melton, Cody A.
Polarizabilities, dispersion coefficients, and retardation functions at the complete basis set CCSD limit: From Be to Ba plus Yb
Visentin, Giorgio; Buchachenko, Alexei A.
Midbond basis functions for weakly bound complexes
Shaw, Robert A.; Hill, J. Grant
Correlation consistent basis sets for actinides. II. The atoms Ac and Np–Lr
Journal Article Feng, Rulin ; Peterson, Kirk A. - Journal of Chemical Physics
New correlation consistent basis sets optimized using the all-electron third-order Douglas-Kroll-Hess (DKH3) scalar relativistic Hamiltonian are reported for the actinide elements Ac and Np through Lr. These complete the series of sets reported previously for Th–U [K. A. Peterson, J. Chem. Phys. 142, 074105 (2015); M. Vasiliu et al., J. Phys. Chem. A 119, 11422 (2015)]. The new sets range in size from double- to quadruple-zeta and encompass both those optimized for valence (6s6p5f7s6d) and outer-core electron correlations (valence + 5s5p5d). The final sets have been contracted for both the DKH3 and eXact 2-component (X2C) Hamiltonians, yielding cc-pVnZ-DK3/cc-pVnZ-X2C sets formore » valence correlation and cc-pwCVnZ-DK3/cc-pwCVnZ-X2C sets for outer-core correlation (n = D, T, Q in each case). In order to test the effectiveness of the new basis sets, both atomic and molecular benchmark calculations have been carried out. In the first case, the first three atomic ionization potentials (IPs) of all the actinide elements Ac–Lr have been calculated using the Feller-Peterson-Dixon (FPD) composite approach, primarily with the multireference configuration interaction (MRCI) method. Excellent convergence towards the respective complete basis set (CBS) limits is achieved with the new sets, leading to good agreement with experiment, where these exist, after accurately accounting for spin-orbit effects using the 4-component Dirac-Hartree-Fock method. For a molecular test, the IP and atomization energy (AE) of PuO 2 have been calculated also using the FPD method but using a coupled cluster approach with spin-orbit coupling accounted for using the 4-component MRCI. The present calculations yield an IP 0 for PuO 2 of 159.8 kcal/mol, which is in excellent agreement with the experimental electron transfer bracketing value of 162 ± 3 kcal/mol. Likewise, the calculated 0 K AE of 305.6 kcal/mol is in very good agreement with the currently accepted experimental value of 303.1 ± 5 kcal/mol. The ground state of PuO 2 is predicted to be the 5Σ$$+\atop{0g}$$ state.« less
Journal Article Lu, Qing ; Peterson, Kirk A., E-mail: kipeters@wsu.edu - Journal of Chemical Physics
Using the 3rd-order Douglas-Kroll-Hess (DKH3) Hamiltonian, all-electron correlation consistent basis sets of double-, triple-, and quadruple-zeta quality have been developed for the lanthanide elements La through Lu. Basis sets designed for the recovery of valence correlation (defined here as 4f5s5p5d6s), cc-pVnZ-DK3, and outer-core correlation (valence + 4s4p4d), cc-pwCVnZ-DK3, are reported (n = D, T, and Q). Systematic convergence of both Hartree-Fock and correlation energies towards their respective complete basis set (CBS) limits are observed. Benchmark calculations of the first three ionization potentials (IPs) of La through Lu are reported at the DKH3 coupled cluster singles and doubles with perturbative triples,more » CCSD(T), level of theory, including effects of correlation down through the 4s electrons. Spin-orbit coupling is treated at the 2-component HF level. After extrapolation to the CBS limit, the average errors with respect to experiment were just 0.52, 1.14, and 4.24 kcal/mol for the 1st, 2nd, and 3rd IPs, respectively, compared to the average experimental uncertainties of 0.03, 1.78, and 2.65 kcal/mol, respectively. The new basis sets are also used in CCSD(T) benchmark calculations of the equilibrium geometries, atomization energies, and heats of formation for Gd{sub 2}, GdF, and GdF{sub 3}. Except for the equilibrium geometry and harmonic frequency of GdF, which are accurately known from experiment, all other calculated quantities represent significant improvements compared to the existing experimental quantities. With estimated uncertainties of about ±3 kcal/mol, the 0 K atomization energies (298 K heats of formation) are calculated to be (all in kcal/mol): 33.2 (160.1) for Gd{sub 2}, 151.7 (−36.6) for GdF, and 447.1 (−295.2) for GdF{sub 3}.« less
Correlation consistent basis sets for actinides. I. The Th and U atoms
Journal Article Peterson, Kirk A., E-mail: kipeters@wsu.edu - Journal of Chemical Physics
New correlation consistent basis sets based on both pseudopotential (PP) and all-electron Douglas-Kroll-Hess (DKH) Hamiltonians have been developed from double- to quadruple-zeta quality for the actinide atoms thorium and uranium. Sets for valence electron correlation (5f6s6p6d), cc − pV nZ − PP and cc − pV nZ − DK3, as well as outer-core correlation (valence + 5s5p5d), cc − pwCV nZ − PP and cc − pwCV nZ − DK3, are reported (n = D, T, Q). The -PP sets are constructed in conjunction with small-core, 60-electron PPs, while the -DK3 sets utilized the 3rd-order Douglas-Kroll-Hess scalar relativistic Hamiltonian. Bothmore » series of basis sets show systematic convergence towards the complete basis set limit, both at the Hartree-Fock and correlated levels of theory, making them amenable to standard basis set extrapolation techniques. To assess the utility of the new basis sets, extensive coupled cluster composite thermochemistry calculations of ThF{sub n} (n = 2 − 4), ThO{sub 2}, and UF{sub n} (n = 4 − 6) have been carried out. After accurately accounting for valence and outer-core correlation, spin-orbit coupling, and even Lamb shift effects, the final 298 K atomization enthalpies of ThF{sub 4}, ThF{sub 3}, ThF{sub 2}, and ThO{sub 2} are all within their experimental uncertainties. Bond dissociation energies of ThF{sub 4} and ThF{sub 3}, as well as UF{sub 6} and UF{sub 5}, were similarly accurate. The derived enthalpies of formation for these species also showed a very satisfactory agreement with experiment, demonstrating that the new basis sets allow for the use of accurate composite schemes just as in molecular systems composed only of lighter atoms. The differences between the PP and DK3 approaches were found to increase with the change in formal oxidation state on the actinide atom, approaching 5-6 kcal/mol for the atomization enthalpies of ThF{sub 4} and ThO{sub 2}. The DKH3 atomization energy of ThO{sub 2} was calculated to be smaller than the DKH2 value by ∼1 kcal/mol.« less
Accurate correlation consistent basis sets for molecular core-valence correlation effects: The second row atoms Al-Ar and the first row atoms B-Ne revisited
Journal Article Peterson, Kirk A ; Dunning, Thom H - Journal of Chemical Physics
Correlation consistent basis sets for accurately describing core-core and core-valence correlation effects in atoms and molecules have been developed for the second row atoms Al - Ar. Two different optimization strategies were investigated, which led to two families of core-valence basis sets when the optimized functions were added to the standard correlation consistent basis sets (cc-pVnZ). In the first case, the exponents of the augmenting primitive Gaussian functions were optimized with respect to the difference between all-electron and valence-electron correlated calculations, i.e., for the core-core plus core-valence correlation energy. This yielded the cc-pCVnZ family of basis sets, which are analogousmore » to the sets developed previously for the first row atoms[D.E. Woon and T.H. Dunning, Jr., J. Chem. Phys. 103, 4572 (1995)]. Although the cc-pCVnZ sets exhibit systematic convergence to the all-electron correlation energy at the complete basis set limit, the intershell (core-valence ) correlation energy converges more slowly than the intrashell (core-core) correlation energy. Since the effect of including the core electrons on the calculation of molecular properties tends to be dominated by core-valence correlation effects, a second scheme for determining the augmenting functions was investigated. In this approach, the exponents of the functions to be added to the cc-pVnZ sets were optimized with respect to just the core-valence (intershell) correlation energy, except that a small amount of core-core correlation energy was included in order to ensure systematic convergence to the complete basis set limit. These new sets, denoted weighted core-valence basis sets (cc-pwCVnZ), significantly improve the convergence of many molecular properties with n. Optimum cc-pwCVnZ sets for the first-row atoms were also developed and show similar advantages.« less
Correlation consistent basis sets for explicitly correlated wavefunctions: Pseudopotential-based basis sets for the post-d main group elements Ga–Rn
Journal Article Hill, J. Grant, E-mail: grant.hill@sheffield.ac.uk, E-mail: kipeters@wsu.edu ; Peterson, Kirk A., E-mail: grant.hill@sheffield.ac.uk, E-mail: kipeters@wsu.edu - Journal of Chemical Physics
New correlation consistent basis sets, cc-pVnZ-PP-F12 (n = D, T, Q), for all the post-d main group elements Ga–Rn have been optimized for use in explicitly correlated F12 calculations. The new sets, which include not only orbital basis sets but also the matching auxiliary sets required for density fitting both conventional and F12 integrals, are designed for correlation of valence sp, as well as the outer-core d electrons. The basis sets are constructed for use with the previously published small-core relativistic pseudopotentials of the Stuttgart-Cologne variety. Benchmark explicitly correlated coupled-cluster singles and doubles with perturbative triples [CCSD(T)-F12b] calculations of themore » spectroscopic properties of numerous diatomic molecules involving 4p, 5p, and 6p elements have been carried out and compared to the analogous conventional CCSD(T) results. In general the F12 results obtained with a n-zeta F12 basis set were comparable to conventional aug-cc-pVxZ-PP or aug-cc-pwCVxZ-PP basis set calculations obtained with x = n + 1 or even x = n + 2. The new sets used in CCSD(T)-F12b calculations are particularly efficient at accurately recovering the large correlation effects of the outer-core d electrons.« less

redpajama_set_name: RedPajamaCommonCrawl


It doesn't matter how many seasons we get through, the speed in which time just vanishes between them never ceases to amaze me but even more so then when the press day invites are coming through - how could it possibly be that time again already?
We were very lucky to be invited to a few to get some sneak peaks of the amazing product that's on it's way to the high street and here's what we've got in store..
Across the aw14 catwalk and now filtering down to the masses, the trends aren't too far from what aw13 had to offer but if anyone has stepped these trends up a gear it's Boohoo. They have given last seasons faves that fresh lease of life that they totally deserve with incredible pastel fur bombers replacing the pale pink coat and sports luxe getting even more, well, luxe. Boohoo are a company we have watched get bigger and better every single season and this one is no exception - not only have they outdone themselves but they're out doing everyone else when it comes to affordable fashion too.
Magpie alert! Expect sparkle sparkle sparkles from New Look next season! The thing I love about New Look Press Days is being excited for product across the board - the clothing is always good but we were also excited by the wall of underwear sets and the large amounts of amazing accessories.
Definitely the most beautiful Press Day, it even smelt amazing! Having come from display-related backgrounds, we were in awe of the thought process behind the pyramid of coffee mugs, street style florist and of course the beautiful product that went with it! I am adoring the navy and lime colour palettes in the day way collection rich jewellery box colours in the occasion wear - perfect for dare I say it.. Christmas.
When it comes to collabs, Littlewoods are killing it. At another beautifully presented Press Day by the guys at Lee Publicity, the Coleen and Mylene collections were fashionable and wearable which is perfect for their key demographic. Coords are still going strong, and luxe military seemed to be a key trend for these guys.
oh wow love this post!
I'm bringing Ivy to every press day in future! we got so much more attention with her!
You both look gorgeous! Little baba is obviously starting early with the fashions! Thanks for the insight. Looks like its a very pink/subtle A/W coming up!


text:
package main

import (
	"context"
	"fmt"

	hello "github.com/asim/go-micro/examples/v4/greeter/srv/proto/hello"
	"go-micro.dev/v4"
)

func main() {
	// create a new service
	service := micro.NewService()

	// parse command line flags
	service.Init()

	// Use the generated client stub
	cl := hello.NewSayService("go.micro.srv.greeter", service.Client())

	// Make request
	rsp, err := cl.Hello(context.Background(), &hello.Request{
		Name: "John",
	})
	if err != nil {
		fmt.Println(err)
		return
	}

	fmt.Println(rsp.Msg)
}

redpajama_set_name: RedPajamaGithub


Several different private investors and investor groups currently use Real Restaurant Solutions, Inc. due to it's reputation as a top restaurant consulting firm in San Diego, to find exciting and dynamic restaurant projects for investment purposes.
Some of our investors are looking for cause-type investments and others are looking for strong returns.
We will meet with you, help you fashion your business plan and pro-forma in a format that is preferred by investors. We will prepare you for investor meetings and if your project fits the criteria set by the investors, we will facilitate funding meetings.
We will also assist you with best in class industry support professionals to provide guidance and support throughout the process.
We do this for no fee. Our company may participate at times in the project on a case by case basis depending on the details of the deal.
Contact us to learn more and get you moving towards realizing your vision.
Real Restaurant Solutions takes an active role in matching EB-5 Investors with investment only opportunities or investment and operator opportunities. We understand the process, and will help navigate the proceedings including identifying, qualifying, negotiating, taking possession and running your new investment.
To set up a meeting, please contact Tom directly.
© Copyright 2015. Real Restaurant Solutions. All Rights Reserved.


Whether you decorate T-shirts, team uniforms, or corporate wear, hats make great add-on sales. Plus, decorating hats with a hat press is a fast, clean, and easy process. Interchangeable cap platens make decorating caps easier.
Ideal cap press platen for printing low-profile caps. Sturdy aluminum base with a 3/8" thick silicone pad. Installs simply by slipping platen into place.
Great for printing low-crown caps. Sturdy aluminum base with a 3/8" thick silicone pad. Installs simply by slipping platen into place.
Ideal cap press platen for printing full-crown caps. Sturdy aluminum base with a 3/8" thick silicone pad. Installs simply by slipping platen into place.
Terrific for printing oversize caps. Sturdy aluminum base with a 3/8" thick silicone pad. Installs simply by slipping platen into place.
Set of all 4 - Best Value!
Set of four Cap Press Platens. Includes 2 3/4" x 6 1/2", 3" x 5 3/4", 4" x 6 1/2", and 4" x 8" platens.
Whether you decorate T-shirts, team uniforms, or corporate wear, hats make great add-on sales. Plus, decorating hats with a hat press is a fast, clean, and easy process.


For the first time, five to six mass communication students will spend their spring break touring and experiencing New York City's media outlets.
To participate in the trip, formally called the 2013 Media Discovery Trip to New York City, students must turn in an application with a letter describing their interest in participating and how the tour will benefit their career goals. Associate Professor of Mass Communication Maria Lundberg, who will oversee the trip, said she is excited to experience NYC with the selected students.
A QEP grant will be covering most of the trip's expenses, which include the train ticket, hotel room, subway card and media admissions. Lundberg said that each student should expect to pay a minimum of 250 dollars for meals that will not be covered by the QEP grant.
The group will tour the Paley Center for Media Arts and the Museum of the Moving Image. They will also attend at least one live broadcast of a major television program such as The View, the Today Show, and Late Night with David Letterman or The Talk. They will also visit and tour one or more network news organizations like the NBC Studio Tour.
Lundberg explained the significance of the trip.
Lundberg applied for a QEP grant in mid November. In December, she learned the proposal was approved. Lundberg said this trip was a way to see knowledge put into practice.
"I'm very pleased that the committee acknowledged that this trip will be a valuable experience for our majors who are pursuing careers in mass communication and journalism," Lundberg said.
Lundberg said she hopes the trip will continue for the years ahead for all mass communication majors to experience.


2008 Pontiac Solstice Reviews. 2008 pontiac solstice review ratings specs prices and. 2008 pontiac solstice review top speed. 2008 pontiac solstice reviews specs and prices. 2008 pontiac solstice reviews and rating motor trend. 2008 pontiac solstice pricing ratings reviews. 2008 pontiac solstice pictures cargurus. 2008 pontiac solstice prices reviews and pictures u s. 2008 pontiac solstice expert reviews specs and photos. 2008 pontiac solstice convertible prices reviews autos post. car review 2008 pontiac solstice gxp driving. [Dinarjat.com].


text:
American Samoa Senate agrees to raise marriage age to 18
Pago Pago, AMERICAN SAMOA — The bill to raise the marriage age for girls in American Samoa from 14 to 18 has cleared the Senate.
All the bill was passed unanimously, winning the support of those who rejected it in the last Fono session.
During discussions earlier this week, Senators said 14 was too young for girls to marry, bear children or raise families.
They also agreed the current marriage age conflicted with laws on statutory rape.
The only change they made to the House bill was to remove language which said those between 16 and 18 could marry with parental permission.
The bill is expected to pass the House again, before being sent to the Governor for his approval.


Everyone in our firm is active in our community, from being involved in our local bar associations to presenting at Continuing Legal Education Programs and assisting in other non-profit endeavors.
Mary Baker and Darius Dugas are officers of the Douglas-Elbert County Bar Association. Laura Page is an officer of the Family Law Section of the Colorado Bar Association. Mary Jane Cox and Laura Page are both members of the Executive Council, the elected body of the Family Law Section.
Recently, Laura Page presented on Temporary Orders hearings at the annual Family Law Institute (August 2015).
Over the years, the entire firm has been involved with the Douglas/Elbert High School Mock Trial tournament, including being active in running the tournament, being a volunteer during the competition and coaching high school teams. Specifically, Jane Cox has been coaching a high school team since 2014.


text:
Fan Works, Humor, Music
Walk on the Ceiling – Theme of Sonic the Hedgehog 4
As tribute to Takashi Iizuka's hallowing vision of Sonic the Hedgehog 4, I've recrafted the beautiful lyrics of Reach for the Stars, and elevated them to new heights. Brand new, never explored, never walked-on heights, to create a theme song worthy of being called the theme of Sonic the Hedgehog 4. It is truly the Sonic 4 theme song as you imagined it. Real talk.
November 29, 2010 by Katzu Niku
Fan Works, Music
Sonic 3 & Knuckles Soundtrack Remade in Famitracker
Have you ever wondered what Sonic 3 & Knuckles might sound like if it were using the NES sound hardware and its expansion chips to produce the music? YouTube user 8BitDanooct1 did; so much so, in fact, that he spent over 200 working hours–that's about a month and a half–tirelessly making it a reality. The results are a real treat:
Pretty cool, right? Get the full soundtrack in both NSF and MP3 format here.
November 29, 2010 by Tweaker


text:
The Lionel Gelber Prize – The Munk School of Global Affairs and Public Policy
Rules for Eligibility
Lionel Gelber Biography
2021 Lionel Gelber Prize
Prize by Years
A Rage for Order: The Middle East in Turmoil, from Tahrir Square to ISIS
Author: Robert F. Worth
Published by Farrar, Straus and Giroux
Gelber Prize Winner
A Rage for Order tracks the tormented legacy of what was once called the Arab Spring. Combining dramatic storytelling with an original analysis of the Arab world today, Worth captures the psychic and actual civil wars raging throughout the Middle East and explains how the dream of an Arab renaissance gave way to a new age of discord.
Contact the Lionel Gelber Prize
Munk School of Global Affairs and Public Policy, University of Toronto
gelberprize.munk@utoronto.ca
Canada M5S 0A7
For media-related inquiries, please contact: gelberprize.munk@utoronto.ca
@. All rights reserved. The Lionel Gelber Prize at the Munk School of Global Affairs and Public Policy in the University of Toronto.


A concrete patio can enhance a backyard and add value to your home.
Concrete patios are prepared in the same manner as other flat work. The patio site is first excavated and prepped with a Class #5 base fill. The walkway is then formed to dimension with rigid steel forms and stakes that prevent bowing.
A bendable material is used to create interesting curves when needed or requested. Reinforced rebar is then placed and tied into its self for added strength and durability. The concrete is typically poured 4-5 inches thick and is hand finished to a non-skid surface. Your new patio is ready for use in 2-3 days.
For a different and more interesting look consider exposed aggregate or colored concrete.


Ken produces a range of hand built functional ceramics in his Brighton Studio. Having originally studied printed textiles in Liverpool, Ken then went on to do a Masters degree in ceramics at the royal college of art. This love of strong patterns and colour can still be seen in the pieces he produces today.


The invention aimed at supporting the work of navigators has been tested on board ferries Wawel and Mazovia since the beginning of 2016. Now he will also go to Baltivia, flying from Swinoujscie to Ystad. PŻB decided to equip ferries in Navdec to increase the safety of passengers and transported loads.
The tool collects all data specifying the current situation of the ship, and in the event of collision threat proposes a safe course.


text:
Kent based cab firm invests £200,000 on new booking app to compete against Uber
A Kent based cab firm has invested £200,000 in technology in a bid to fight off competition from Uber drivers. Long established Vokes in Medway, which now incorporates Windmill Taxis and Rainham Cabs, has installed an automated dispatch system accepting bookings by app, web and by phone.
Vokes Taxis Medway supplies a range of vehicles including 4 to 8 seat saloon, estate, and purpose-built taxi cabs and minicabs, as well as executive, limousine and wedding cars.
Established in 1958, Vokes Taxis use the motto: "Your job is not too small or too big for us". The new app will allow customers to track their booked vehicle via a smartphone and will be given the driver and vehicle details prior to arrival.
According to a report by KentOnline, drivers working on the ride-sharing giant's app, Uber, have been operating in the area, with most not having the sufficient knowledge to do so.
There are suggestions that around 200 drivers from Uber work in the area.
Mark Robinson, a partner at Vokes, has said that their new app offers everything and "very much more" that Uber's does - under the watchful eye of the local authority.
He added: "All our drivers have to meet the very high standards set by Medway Council, all intended to ensure a safe, consistent and reliable service to the general public."
Mr Robinson said that many local drivers are really struggling since the introduction of Uber, with some claiming their income is down by as much as 30%.
He stressed that Medway's licensed drivers have to undergo regular stringent health, safety and driving checks along with having to demonstrate their local knowledge of the roads. "To overcome this, they are working longer hours but it's fair to say that a few have given up the trade and if the situation doesn't change we expect more to follow. "Taxi services are an important part of Medway's transport policy and we need more drivers, not less, entering the trade" he went on to add.
Image: Source; Pixabay


The Legacy Center for Community Success provides evidence-based learning and developmental strategies, in collaboration with other organizations, to help individuals reach their full potential.
We're helping people in our community realize their full potential through improved understanding and comprehension of the English language, reading and math.
We're helping young people realize their full potential by instilling the tools they need for healthy, positive youth development.
We're helping local nonprofits realize their full potential by helping them establish outcome goals and measurements and by evaluating their programs for effectiveness against those outcomes.
Contact one of our staff members to learn more.


text:
Q: Invalid Variant Operation Exception Trying to Access OleVariant in Delphi - Works in C# I'm trying to access an OleVariant in a callback that is coming from an ActiveX library.
Here's what the event handler is defined as in the TLB:
procedure(ASender: TObject; var structQSnap: {??structVTIQSnap}OleVariant) of object;

Here's the definition of structVTIQSnap in the TLB:
structVTIQSnap = packed record
  bstrSymbol: WideString;
  bstrListingExch: WideString;
  bstrLastExch: WideString;
  fLastPrice: Double;
  nLastSize: Integer;
  bstrBbo: WideString;
  bstrBidExch: WideString;
  fBidPrice: Double;
  nBidSize: Integer;
  bstrAskExch: WideString;
  fAskPrice: Double;
  nAskSize: Integer;
  fHighPrice: Double;
  fLowPrice: Double;
  fOpenPrice: Double;
  fClosePrice: Double;
  nCumVolume: Integer;
  bstrTradeCondition: WideString;
  nQuoteCondition: Integer;
  bstrCompanyName: WideString;
  f52WeekHigh: Double;
  f52WeekLow: Double;
  fEps: Double;
  nSharesOutstanding: Integer;
  nSpCode: Integer;
  fBeta: Double;
  bstrExDivDate: WideString;
  nDivFreq: Integer;
  fDivAmt: Double;
  nAvgVolume: Integer;
  bstrCusip: WideString;
  fVwap: Double;
  bstrUpdateTime: WideString;
  bstrExch: WideString;
  nSharesPerContract: Integer;
end;

It compiles fine, but everytime I try to access the bstrSymbol, I get an "Invalid Variant Operation":
 procedure TForm1.HandleVTIQuoteSnap(ASender: TObject; var structQSnap: OleVariant);
 var
    symbol: WideString;
 begin
    symbol := structQSnap.bstrSymbol; // this line causes the exception
 end;

How do I access structQSnap and its properties in Delphi?
In C#, this function works fine for the event handler:
    void vtiQ_OnVTIQSnap(ref vtiLib.structVTIQSnap structQSnap)
    {
        MessageBox.Show("Got qsnap for " + structQuoteSnap.bstrSymbol);
    }

Any ideas?

A: I think that Delphi's ActiveX import wizard doesn't know how to handle the structVTIQSnap type (which seems to be a record) properly and just uses the default OleVariant.
Is there a type declaration named structVTIQSnap or similar in the generated ..._TLB.pas file? Try using that instead of OleVariant, e.g.
procedure (ASender: TObject; var structQSnap: structVTIQSnap) of object;

The type will probably be declared as a "packed record".

A: You could try to typecast the structQSnap to a pointer to this struct.  Something like
PstructVTIQSnap = ^structVTIQSnap;
structVTIQSnap = packed record
   bstrSymbol: WideString;
   // other stuff...
end;

and
procedure TForm1.HandleVTIQuoteSnap(ASender: TObject;
  var structQSnap: OleVariant);
var
  ps: PstructVTIQSnap;
  symbol: WideString;
begi
  ps := PstructVTIQSnap(structQSnap.VPointer^);
  symbol := ps.bstrSymbol;
  ...
end;

What I do not understand however is the following: I take it from the ref in the C# code that the structure should be marshalled twice, once from the library to the callback, second back to the library. This would mean that the varByRef flag ($4000) needs to be set in VType, but the value you gave in your comment (3484) is much too small?

A: try to look what returns in TVarData(structQSnap).VType ?
may be it will work:
 var
   symbol: WideString;
   rec: structVTIQSnap;
 begin
    rec := structVTIQSnap(structQSnap);
    symbol := rec.bstrSymbol;
 end;

A: I'm not sure why you are considering the "structVTIQSnap" to be an "OleVariant". Seems an odd translation to me. Could it be that it has been placed into an OleVariant in some form, either as an array or similar?

redpajama_set_name: RedPajamaStackExchange


text:
W.S.J. Adams
Full Name: W. S. J. Adams
H 70 Apr 18, 1876 - Aug 3, 1876 15th (1) (2) (3) (4) Democrat Comanche / Comanche Callahan, Comanche, Eastland, Erath, Jones, Palo Pinto, Shackelford, Stephens, Taylor
(2) W.J.S. Adams, Comanche County. Resignation letter and Gov. Coke's transmittal letter to Speaker, 8/3/1876, pp. 755-756. House Journal. April 18, 1876 August 3, 1876
(3) Adams resigned 8/3/1876. Members of the Texas Congress 1836-1845; Members of the Texas Legislature 1846-2004, 2005.
(4) Democrat. Texas Legal Directory for 1876-77, 1877.
Biography, W.S.J. Adams, born in Bourbon County, Kentucky in 1843, pp. 137-139. Sketches of Legislators and State Officers, Fifteenth Legislature, 1876-1878, 1876.
"Over the state - Colorado," 12/10/1883, p. 1. Col. W.J.S. Adams, prominent lawyer of "this place" and ex-member of state legislature, died 12/10/1883. Galveston Daily News.
W.S.J. Adams, "Ready to make laws . . . Eighty members present (House)" (organization of the 15th Legislature), 4/19/1876, p. 1. Galveston Daily News.
Entry for wife Ora Alice Kingsbery, p. 456, mentions late Col. W.S.J. Adams, born in Bourbon County, Kentucky, prominent lawyer, died in Colorado, Texas, 12/10/1883. The genealogy of the descendants of Henry Kingsbury, of Ipswich and Haverhill, Mass., 1905.
W.S.J. Adams. Members of the Texas Congress 1836-1845; Members of the Texas Legislature 1846-2004, 2005.
W.S.J. Adams. Texas House of Representatives: A Pictorial Roster 1846-1992, 1992.
Photograph. W.S.J. Adams, 15th Legislature, State Preservation Board
Arrangements, Prepare for Reception of Portrait of General Tom Green on the 4th of July
Capitol Grounds, Investigation of Superintendent F. Voigt
Penitentiary
Privileges and Elections
State Penitentiary


text:
Part 3: Addressing concerns from Save Greeley's…
Part 3: Addressing concerns from Save Greeley's Water about the Terry Ranch project
Exploratory bores in the distance are drilled at Terry Ranch. They've been used to confirm water quality and the possibility to inject and store water in a massive underground aquifer near the Wyoming border. Greeley is considering finalizing a purchase of the Terry Ranch aquifer, which contains about 1.2 million acre feet of water and would operate as storage for dry years and preparation for future growth. Courtesy Greeley Water and Sewer Department
By Cuyler Meade | cmeade@greeleytribune.com | Greeley Tribune
February 20, 2021 at 6:30 p.m.
Editor's Note: This is Part 3 of a three-part series on the city's decision on whether to approve the Terry Ranch project. It was originally intended as a two-part series but new information presented after the publication of Part 1 necessitated a third part. Part 1 is available here and Part 2 is available here.
The Greeley City Council will soon vote to endorse moving forward with an ambitious water project, called Terry Ranch, in which the city would purchase access to a massive aquifer under land near the Wyoming border. Some have serious concerns about this decision.
That group, led by former city water department employees Paul Wood and John Gauthiere, is called Save Greeley's Water. Their concerns can be found on savegreeleyswater.com, and Wood spoke with the Tribune Friday by phone to explain several of the fears the group has about the Terry Ranch project.
Below is the final part of a conversation with Greeley Water and Sewer Department deputy director Adam Jokerst, including answers to questions raised on the website and by Wood himself, as well as other questions that have been raised about the project.
SGW, via Paul Wood to the Tribune: There's an old missile site in Wyoming, and it's leaking trichloroethylene. It's spreading and widening, and I know they claim they've done due diligence on the geology, but the ground has different ways of acting than you can predict. Water, any kind of liquid, and (TCE) is more aggressive than water, it'll see a crack and go where it wants to go. There's a stream running through that area that can pick up TCE and take it through the property of Terry Ranch. If it does that, all kinds of ways that gets into the aquifer.
AJ, via email: Regarding trichloroethylene (TCE), its source is from the Atlas D nuclear Missile Site 4 located about approximately 15 miles north-west of Terry Ranch and west of Cheyenne. TCE is a recognized carcinogen with a regulatory limit of 5 micrograms per liter (ug/L or parts per billion) in drinking water (EPA 2021). The Atlas D location is a former defense site that was in operation from 1959 to 1962. The property is now owned by the City of Cheyenne for grazing purposes. During historic operations, trichloroethylene (TCE) was used and disposed of in ponds surrounding the Site. The Wyoming Department of Environmental Quality (WDEQ) and the Army Corps of Engineers (USACE) has overseen the cleanup and characterization of the Missile Site TCE plume since 2003. Through an extensive monitoring program, the WDEQ and USACE have characterized the extent of the TCE plume (Final Area RI 2019). The direction of plume travel is eastwards and not in the direction of the Terry Ranch Project.
We are well aware of the TCE plume, and have studied its potential to contaminate Terry Ranch groundwater in depth. TCE is a Dense Non-Aqueous Phase Liquid (DNAPL) and is denser than water, meaning it sinks when interacting with water. The USACE has found that the highest concentrations of TCE are at the base of the Ogallala Aquifer and the upper unit of the White River Formation, terminating at the relatively impermeable Brule Member of the White River Formation. The Brule Member acts as a barrier to downward migration of the TCE and protects the underlying Upper Laramie Aquifer. Reports indicate that the eastern edge of the TCE plume (Site B) is moving at a rate of approximately 0.1 feet/day (approximately 1 mile per 145 years) in the White River Formation (Final Area RI 2019), and 1.3 feet/day in the Ogallala Aquifer (approximately 1 mile per 11 years). The closest monitoring well with an exceedance of 5 ug/l of TCE is 6.2 miles from the northern edge of the Terry Ranch property. Based on the velocity of the plume migration, it would take approximately 900 years for TCE in the White River Formation and 69 years in the Ogallala to reach Terry Ranch. If TCE were to reach Terry Ranch in the Ogallala, it would be of minimal concern because the Upper Laramie Aquifer is protected by the Brule Formation. Additionally, in that amount of time, and over that distance, it is likely that the TCE that is not actively remediated would partially or fully attenuate naturally by a combination of 1) dechlorinization by dehalogenating bacteria, 2) enzymes produced by certain bacteria that dechlorinate, and/or 3) Abiotic degradation in the presence of iron-rich soils/rocks (Schwarzenbach, 2002). In addition, the plume would have to change direction and migrate to the south.
Our consultants have determined the TCE plume is not a contamination risk to the Terry Ranch Project because Terry Ranch is located sufficiently far away, the plume is migrating slowly and not in the direction of Terry Ranch, the plume is well-characterized and actively being remediated, and the Upper Laramie Aquifer is hydraulically separated by the overlying Brule Member. A technical report on potential risks of groundwater contamination, including TCE, can be found on the project website: https://greeleygov.com/docs/default-source/default-document-library/contamination-risk-report.pdf. A significant amount of research is available on the TCE plume here: http://www.atlassite4.com/.
SGW: This would be the largest transfer of wealth from the citizens of Greeley in its history. By assigning. A value of $34,000 per credit for 12,121 credits, we are transferring $412,144,000 to Wingfoot.
AJ: Let's break down what Wingfoot gets versus Greeley. It's clearest to break it down by who gets what: Greeley gets the groundwater rights and access to an easement over the surface land to develop the groundwater rights, an exclusive lease; five wells. andan option to recall those; and $125 million. Wingfoot gets 12,121 credits, and that put option to call it back, to sell credits back to Greeley. They get certain revenue sharing if Greeley elects to sell this water to any user outside of the city of Greeley, or should we generate hydropower from this in the future. All those are at Greeley's discretion.
Wingfoot, in those 12,121 credits, are going to be able to sell those to developers at a price they determine. We set the ceiling through our cash-in-lieu rate, currently at $34,000, but going up later this year. So, multiplying that, assuming they get maximum value, you get that $400 million mark that's been spoken of.
Greeley is not paying that amount, that's revenue we're forgoing in the future. Revenue we won't collect in the future. It's important, though, really important, to realize that that revenue we're giving up is uncertain revenue. We know Greeley will grow, so we expect over time we would receive that revenue, but the timing of receiving it is unknown.
So another example: Say we were to build Milton Seaman. The way to do that is a very large bond. We borrow money. We'd pay that back in part by the cash-in-lieu revenue we receive from developers. Imagine we issue that bond, we're on the hook for annual payments, and then we go through a housing crisis, like 2008-2012, and the revenue disappears. All of a sudden, we're in trouble. We're raising rates substantially to make up for that lost revenue.
In paying for this project the way we proposed, we've taken that risk and given it to Wingfoot. The timing that Wingfoot's ability to sell those credits on a timeline that is uncertain is the risk that we're pushing off.
One other key point is that the purpose of having a cash-in-lieu program is to buy water and storage. We're getting water and storage up front. We're forgoing revenue and we're getting to buy the thing we want upfront. We're an enterprise fund, we manage budget, we buy water. We spent $14 million last year buying water from private companies. This is what our charter directs us to do. We buy water and storage.
Jack Schneider, in a column published in the Tribune Friday, expressed a separate set of concerns, among them that the city would be limited to only 12,121 acre-feet of withdrawal from Terry Ranch and that Terry Ranch's decree does not allow recharge of water to the aquifer.
AJ, via email: The decree for the Terry Ranch water rights limits extraction to 12,121 acre-feet a year, which is based on a 1% usage of the total decreed volume of approximately 1.2 million acre-feet. However, any amount unused in one year rolls-over to the next year (in fact, the 12,121 acre-feet limit has been rolling forward since 2017). In this way, the actual annual volumetric limit is far higher than Greeley's need. In short, Greeley will not face limitations on our ability to extract groundwater.
A Water Court decree is not necessary to recharge and store water in a non-tributary aquifer. The owners of the Terry Bison Ranch conveyed to Wingfoot both a right to extract non-tributary groundwater and a right to recharge and later withdraw injected water from the Upper Laramie Aquifer underlying the ranch. The easement granting such rights in attached. The state has promulgated rules on recharge and extraction of water from aquifers, and the State Engineer, not Water Court, has the authority to approve aquifer storage projects in non-tributary basins. The State Engineer's Artificial Recharge Extraction Rules (2 CCR 402-11) may be found here, the obligations and permitting requirements of which are not burdensome. Greeley would not need to apply for a permit from the State Engineer to recharge the aquifer until it has actually built the infrastructure to deliver water to and from the ranch. As part of its diligence, Greeley met with the State Engineer's staff to confirm there will be no permitting obstacles in our ability to recharge water.
Cuyler Meade | Public Money reporter
Cuyler Meade is the public money reporter at the Greeley Tribune. Reach him at 970-392-4487 or cmeade@greeleytribune.com, or follow him on Twitter @CuylerMeade.
cmeade@greeleytribune.com
Follow Cuyler Meade @CuylerMeade
Colorado Secretary of State Office moves to dismiss campaign finance law violations against Greeley-Evans District 6


text:
Home » The Young And The Restless Recap For February 11, 2022: Ashland Comes Clean, Adam And Sally's Discussion
The Young And The Restless Recap For February 11, 2022: Ashland Comes Clean, Adam And Sally's Discussion
By Chandni February 12, 2022
The Young and The Restless recap reveals that Friday's episode of the CBS soap was full of family fun and drama. This episode was about family discussions, and some characters were still settling in with their new work environment.
First, Victor updated Nikki on the Ashland drama while Ashland also made some confessions to Victoria. The February 11, 2022 episode also witnessed Adam and Sally discussing business and their relationship. What was all that about? Keep reading to find out.
Victor Gives Updates
Starting off the episode was Victor giving updates on Ashland's past to Nikki Newman. Victor told Nikki that the funding from Ashland's shell company to the clinic in Peru got doubled right before Ashland's experimental treatment. Victor understood something was wrong, but Nikki asked him to stop thinking about Ashland and reminded him of the season of love.
He also assured Nikki that he had not forgotten about Valentine's day and he had a surprise planned for her. But, Nikki seemed worried about Victor digging for information on Ashland's past. To which, Victor tells her that he wants to get to the bottom of all this Peru clinic drama.
The Young And The Restless: Victoria And Ashland Celebrate V-Day
The episode also saw Victoria catching Ashland arranging flowers for her in the office. Then, Ashland asked for a gift for himself on the occasion of Valentine's day. So, Victoria gifted him a ring with a Scottish lord's crest with the Locke name. Y&R fans know that Ashland is not a true Locke, but Victoria thinks that the ring represents who he is now.
Obviously, Ashland loved the ring and hugged Victoria with immense love. He started to list why he doesn't deserve Victoria's love, but he also thanked her for coming into his life. Then the couple decided to take the rest of the day off and go out to celebrate.
The Newman Family Lunch
The Young And The Restless spoilers suggest that after Victoria and Ashland decided to take the day off, they met Victor and Nikki for lunch. At lunch, Ashland showed his ring to Victor and Nikki; then, Victor made a toast to talk about Ashland's recovery. While making the toast, Victor also mentioned how his daughter and his son-in-law seem to be in so much love.
Then, the 'seem' part caught Victoria's attention, and she assured her father that she was very much in love. Victor added that he's happy to see her daughter so happy, which means the world to him.
The Young And The Restless: Ashland Comes Clean
Furthermore, when Ashland and Victoria returned to the office from lunch, Ashland made a confession. He mentioned how Victor kept bringing up the topic of his treatment during lunch. He told Victoria the story about a sick colleague and came clean about funding the clinic when it was in trouble. Ashland explained to Victoria that he used a shell corporation and didn't tell anyone, including Victoria, to protect her and the company from any tax fraud.
After listening to all this, Victoria burst out. She was angry about Ashland still keeping secrets from her. Ashland begged for her forgiveness and told her that she means everything to him. Regardless, Victoria forgave him as she felt that Ashland was doing better than before. So, she took his hand and smiled as things calmed down.
Adam And Sally's Discussion
Later in the episode, Adam was surprised when he found flowers and chocolates at his desk. Sally told him that some advertiser had sent those. Sally started discussing the chocolate, but she realized that this meeting is about work.
Adam mentioned that the press release is going out about Sally's new role as COO at the fashion platform. Sally told Adam that the job was not a gift and that they needed to talk. But, Adam clarified to her that he was talking about the press release and Sally admitted that she was kidding.
Adam also appreciated Sally's work for Newman Media. Sally commended Adam for everything he has done so far, and then they discussed business. After a while, Adam opened the Champagne bottle. And he cleared that this was work-related and not something for Valentine's day. They both thanked each other for the support they had offered to each other. Sally proposed a toast saying, "two wrongs making something very right".
Valentine's Day Looms in Genoa City
Rounding off Friday's episode was Devon Hamilton apologizing to Amanda for forgetting the special day. But, Amanda told Devon not to worry. She knows that Devon is going through a lot with Dominic's health getting worse. So, she cut him that slack. Later on, Devon met Billy and Lily as they were celebrating Valentine's day.
As Billy and Lily celebrated, Devon also brought some flowers, balloons, and gifts for Amanda to express his love. Amanda cooked his favorite dinner, They spent some time together and enjoyed each other's company.
While this episode was full of drama, The Young And The Restless spoilers suggest that the next episodes will bring more action. Y&R characters are in for many confrontations in the upcoming weeks. What is that? Only time will tell. Until then, Stay tuned. TV Season & Spoilers will bring you all the updates. The Young & The Restless airs on CBS all weekdays.


The island of Kythira has a low-key rural vibe that has drawn us back to the island again and again over the years. While we gravitate to the seaside villages and beaches, we can't help but also explore the inland villages filled with rustic charm. At times our curious nature for exploring the small villages has gotten us into sticky situations.
When in Kythira this past September, we were on a quest to find what we call our "goat village," a place where years ago we had an almost disastrous encounter with a herd of goats. You can read about our crazy experience in an earlier post, A quest to find our "goat village" in Kythira, Greece. One of the villages we explored in the quest to find our "goat village" was the mid-sized village of Aroniadika.
Located near the center of the island, Aroniadika is known for its traditional houses and honey production. The village has narrow alleys, a mix of restored buildings and ruins, arched passages, and centuries-old walls and trees. Learning our lesson after our past encounter with goats in the village of Aloizianika, we parked our car outside of town and explored Aroniadika on foot. Please enjoy a few photos of buildings and doors from our walking tour of this village founded in the early 1500s.
A narrow alley passes through the mostly abandoned side of the village.
The bright whitewashed Kamares Apartments enlivens the lane of old abandoned stone buildings.
This time-worn blue door is on its way to the developing the dull patina of the wooden shutter.
Where did the doors and windows of this skeleton of a building go, or were they never installed?
I love all these doors, but that first one is a spectacular combination of beautiful blue door and stunning flowers!!
Thank you, Janet. I love that one too.
Love your pictures! I was in Kythira for a few days and I totally remember seeing goats inland!


I experienced living in a large city for the first time in Frankfurt, Germany in the early 1990s. My apartment was across from a 10 acre park, a block from an UBahn station, a bicycle ride away from everything. I carried my Canon AE-1 with me everywhere, and fell in love with architecture and public spaces. This experience was the pivot-point that steered me towards architecture as an education and profession.
I've now lived in several major metropolitan areas, including Houston, Texas, and the San Francisco Bay Area. I've also lived in some glorious smaller communities, such as Portland, Oregon and Savannah, Georgia. While they've each instilled specific lessons on architectural fabric, trials of transportation or weather woes, all have provided insight and inspiration on what it means to live in the urban context – and how varied that context might be. My blogposts range from reviewing public art for SFMetblogs to giving bike-sharing a whirl in Paris and Copenhagen. Some are just commentary on glimpses I've captured of the world whizzing by.
Hola, me gusta mucho su aporte, y su Blog, me ayuda mucho, Gracias, recuerde que puede visitar mi sitio Directorio de enlaces VIP le aseguro que le sera muy útil.
Pingback: Can Charlie Be Trusted This Time?
Pingback: top up to rich ????
Pingback: "Create your website FAST with one of our 10,000 Templates"
Pingback: Shop for 14k Yellow Gold 3 mm Diamond-cut Rope with Lobster Clasp Chain 7 Inch on sale at JewelBerries.
Pingback: Shop for 14k Gold I Love You Charm Q10191 on sale at JewelBerries.
Pingback: What's the difference between Government and Conventional Loans?
Pingback: Viele Menschen leiden unter Parodontitis - wir können in unserer Zahnarztpraxis in Ludwigsburg helfen!
Pingback: Fantasy Globe Lightroom Preset $10!


People who face losing their jobs in the oil and gas sector will be helped to transition into other energy industry and manufacturing employment through a new £12 million fund, First Minister Nicola Sturgeon announced yesterday.
The First Minister made the announcement on a visit to Aberdeen, where she met senior executives of BP and other sector figures before attending the latest meeting of the task force.
"The conditions facing the North Sea oil and gas sector are certainly challenging for more than just those individuals affected—indeed it has a larger impact on the industry. The significant job losses are deeply concerning, as is the risk that the highly skilled workforce is lost to the sector as they look for other opportunities.


This Prisoner Convict Orange Jumpsuit Costume is awesome! If you are into your prisoner TV shows and you want to dress as one of the characters, this is a great choice, especially if you love the show Orange is the New Black! If you want to be arresting at your next dressing up party then we recommend this outfit, along with some handcuffs. You will be surprised at the amount of people that will want to be handcuffed when you rock up to party in this ensemble! We recommend going to a party with a friend that has dressed up as a cop.
This outfit works well at most dressing up parties, but particularly well at Cops & Robbers, Hero & Villains and Halloween parties.


dunk n dine - Sauro Motel	• Sauro Motel - The Collected Writings of Bobby Sauro.
This entry was posted on Saturday, January 26th, 2013 at 9:54 am	and is filed under . You can follow any responses to this entry through the RSS 2.0 feed. Responses are currently closed, but you can trackback from your own site.


Selling program book advertising for specific performances is always a good selling strategy.
And sometimes some performances are going to be easier to sell into than others.
Traditional holiday performances are always great to sell into because of the increased distribution that a potential advertiser will realize just by buying into one program book issue.
Think Nutcracker or Christmas Carol. The program book print run for these performances are sometimes double or triple the normal print run of other performances throughout the season. And these types of performances are going to appeal to a much broader range of businesses because they're wanting the large print run exposure more than anything.
But sometimes the season line up is with some more riskier, off-Broadway performances that not all advertisers are going to be familiar with. And the print runs on these types of performances are usually the average distribution, if not smaller.
In cases like these, we like to target niche businesses that would be a good fit for a certain performance. In this way, we are tailoring the program book to performance specific advertisers.
It's almost a sponsored content advertising approach that we take, but without all the additional work true sponsored ads take.
One of the leaders in this type of print advertising is Forbes Magazine. If you've ever picked up an issue, you will see advertising that almost looks like content, but is presented in such a way that it actually engages the reader.
With tailoring ads to specific performances, we're doing a bit of the same thing. The only difference being that the ad speaks for itself, instead of the costly customized content that Forbes Magazine creates for their sponsored advertisers.
To tailor specific businesses to specific performances simply look at the plot or theme of the performance and start calling businesses that have this same type of theme as well.
This gives your program book sales reps the ability to expose businesses to performing arts program book advertising that may never have thought about it before.
On the flip-side, this gets your program book sales reps to think a little more creatively and call on businesses that they may never have thought of as being a good fit for the program book product in the first place.
Now that's a win-win! Good selling.


AKRON, Ohio, Jan. 18, 2011 /PRNewswire/ -- Knotice, the leading provider of direct digital marketing software and services, today published "Harnessing the Power of the Mobile Web," providing marketers with actionable tips, insight, and examples for creating a purposeful and relevant mobile web strategy.
The mobile web continues to evolve and change rapidly, and marketers must keep pace. When used properly, the mobile web can offer deeper reach to mobile consumers at each stage of the customer life cycle, from awareness to retention, with the right approach.
Featuring tips for developing a mobile web strategy, best practices, mobile web campaign examples and more, "Harnessing the Power of the Mobile Web" offers a step-by-step guide to creating and providing valuable mobile web experiences to consumers.
-- Strategy for creating purposeful mobile web experiences.
Knotice (pronounced "notice") maximizes the ROI of direct digital marketing - interactive marketing communications that can be addressed to a specific individual - through process automation, increased relevance and improved performance. Working with clients throughout North America, Knotice provides efficient, effective delivery of highly-targeted marketing communications through today's primary digital channels. Founded in 2003, Knotice is headquartered in Akron, Ohio, along the banks of the Ohio-Erie Canal. For more information, visit http://www.knotice.com.