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import Policy from 'runtime-core/src/policy/Policy.js'

  public
  class

  | source

Policy

Constructor Summary

Public Constructor

      public

          constructor(key: *, rules: *, actions: *, combiningAlgorithm: *)

Member Summary

Public Members

      public

          actions: *

      public

          combiningAlgorithm: *

      public

          key: *

      public

          rules: *[]

Method Summary

Public Methods

      public

          addAction(method: *, param: *)

      public

          createRule(decision: *, condition: *, scope: *, target: *, priority: *)

      public

          deleteRule(rule: *)

      public

          enforceActions(context: *, message: *): *

      public

          evaluateRules(context: *, message: *, isIncoming: *): *

      public

          getLastPriority(): *

      public

          getRuleByPriority(priority: *): *

      public

          sortRules(): *

Public Constructors

    public

    constructor(key: *, rules: *, actions: *, combiningAlgorithm: *)

      source

Params:

Name	Type	Attribute	Description

      key
      *

      rules
      *

      actions
      *

      combiningAlgorithm
      *

Public Members

    public

    actions: *

      source

    public

    combiningAlgorithm: *

      source

    public

    key: *

      source

    public

    rules: *[]

      source

Public Methods

    public

    addAction(method: *, param: *)

      source

Params:

Name	Type	Attribute	Description

      method
      *

      param
      *

    public

    createRule(decision: *, condition: *, scope: *, target: *, priority: *)

      source

Params:

Name	Type	Attribute	Description

      decision
      *

      condition
      *

      scope
      *

      target
      *

      priority
      *

    public

    deleteRule(rule: *)

      source

Params:

Name	Type	Attribute	Description

      rule
      *

    public

    enforceActions(context: *, message: *): *

      source

Params:

Name	Type	Attribute	Description

      context
      *

      message
      *

Return:

          *

    public

    evaluateRules(context: *, message: *, isIncoming: *): *

      source

Params:

Name	Type	Attribute	Description

      context
      *

      message
      *

      isIncoming
      *

Return:

          *

    public

    getLastPriority(): *

      source

Return:

          *

    public

    getRuleByPriority(priority: *): *

      source

Params:

Name	Type	Attribute	Description

      priority
      *

Return:

          *

    public

    sortRules(): *

      source

Return:

          *

  Generated by ESDoc(0.5.2)


Entering his 22nd season on the soccer staff at UMBC in the fall of 2018, Anthony Adams also began his eighth season as associate head men's soccer coach.
On eight occasions, Adams has been named one of the nation's top assistant coaches by collegesoccernews.com. He just earned his most recent accolade after the 2014 season, and in 2003, he was one of 27 college coaches in the nation to be honored as an Assistant Coach of the Year by AFLAC. Two seasons later, Adams was recognized by the NSCAA as the Assistant Coach of the Year in the Atlantic region.
Adams earned four letters for UMBC from 1992-95 and was a starter in the backfield in his final three seasons. The Dundalk, Md., native (Calvert Hall) has been an extremely successful coach at the club level. As coach of the Soccer Club of Baltimore and the Baltimore Bays, he won 10 state championships, two regional titles and made two national final four appearances from 1996-2007.
Adams was a member of the coaching staff of the USSF Development Academy's Baltimore Bays from 2008-13 and had five teams place in the Academy Final Eight over that time. He has been coaching with the Baltimore Celtic SC since 2013.
In 2013, Adams was inducted into the Greater Dundalk Hall of Fame and received the Edward Finzel Honor Award for outstanding contributions to soccer in Maryland.
Adams earned the 1995 Retriever Club Scholarship Award, given each year to a junior student-athlete who demonstrates academic and athletic excellence and a commitment to UMBC's community service program.
He has also served as the program's recruiting coordinator since 1997. In the 21 year run, he has helped recruit 92 student-athletes that earned all-conference honors, 18 of which earned the conference's Player of the Year award. Twenty-five Retrievers have earned All-Region honors and seven were tabbed to All-America teams. Moreover, 28 members of the black-and-gold have signed professional soccer contracts.
The longest-tenured UMBC assistant coach holds a USSF "A" coaching license. He earned a degree in history and a certificate in secondary education from UMBC in 1997 and completed his master's degree in management from the University of Maryland, University College in 2007.
His wife, Stephanie, was a former member of the sports medicine staff at UMBC. The couple had their first child, Isabella Marika, in July 2007 and also welcomed Caroline Marie to the family in August 2010.


In a small skillet, toast the celery seed over moderate heat, shaking the pan until fragrant, about 30 seconds; let cool. In a large bowl, combine the toasted celery seed with the tomatoes, cucumbers, jalapeños, yellow pepper, celery, red onion, tomato juice, Worcestershire sauce, hot sauce and lime zest. Refrigerate the gazpacho for at least 1 hour or for up to 2 hours.
In a food processor, puree the avocado with the lime juice until smooth. Scrape the avocado mousse into a small bowl and season with salt. Cover and refrigerate.
In a medium skillet, heat 1 tablespoon of oil. Add the scallions and red onion, season with salt and pepper and cook over low heat until softened, about 8 minutes. Transfer the scallions and red onion to a medium bowl and let cool to room temperature. Beat in the egg with a fork, then mix in the mustard, lime juice, Worcestershire sauce and hot sauce. With a spatula, gently fold in the crabmeat, then fold in the bread crumbs and season with salt and pepper. Form the mixture into 8 crab cakes and transfer to a platter. Refrigerate until firm, about 20 minutes.
Preheat the oven to 300°. In a medium saucepan, heat 2 inches of vegetable oil to 350°. Set a wire rack over a rimmed baking sheet. When the oil is hot, add 4 crab cakes at a time and fry them until golden brown, about 2 minutes per side. With a slotted spoon, transfer the crab cakes to the wire rack and keep them warm in the oven while you fry the rest.
Just before serving, stir the horseradish, lime juice and cilantro into the gazpacho and season with salt. Ladle the gazpacho into large, shallow bowls. Add 2 hot crab cakes and a dollop of avocado mousse to each bowl and serve immediately.
The avocado mousse and the uncooked crab cakes can be refrigerated overnight.


text:
ChemicalBook >> CAS DataBase List >>Phosphoric acid
中国福彩网双色球走势图:Phosphoric acid
Phosphoric acid structure
Chemical Name:
NFB;H3PO4;EVITs;Sonac;Marphos;linsuan;FEMA 2900;U.N. 1805;PHOS ACID;Phosphoric
CB3854273
H3O4P
Formula Weight:
MOL File:
7664-38-2.mol
The username will be used as the login user name and retrieve the password
Properties Safety Price56 Uses Suppliers 481
Phosphoric acid Properties
Melting point:
~40 °C(lit.)
158 °C(lit.)
1.685 g/mL at 25 °C(lit.)
3.4 (vs air)
2.2 mm Hg ( 20 °C)
2900 | PHOSPHORIC ACID
n20/D 1.433
Store below +30°C.
H2O: soluble
Solid or Viscous Liquid
2.1-7.2-12.3(at 25℃)
≤10(APHA)
<0.5 (100g/l, H2O, 20℃)
λmax
λ: 260 nm Amax: ≤0.05
Exposure limits
TLV-TWA 1 mg/m3 (ACGIH, MSHA, and OSHA); TLV-STEL 3 mg/m3 (ACGIH).
NBIIXXVUZAFLBC-UHFFFAOYSA-N
CAS DataBase Reference
7664-38-2(CAS DataBase Reference)
NIST Chemistry Reference
Phosphoric acid(7664-38-2)
EPA Substance Registry System
Phosphoric acid (7664-38-2)
Risk and Safety Statements
Symbol(GHS)
H318-H290-H314
P260h-P301+P330+P331-P405-P501a-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P310-P260
Hazard Codes
C,Xn,T,F
Risk Statements
34-35-22-39/23/24/25-36/38-23/24/25-11
Safety Statements
7-16-26-36/37-45-36/37/39-1/2-24/25
UN 3453 8/PG 3
HazardClass
PackingGroup
ADI 0 to 70 mg / kg (total phosphate content in terms of phosphorus, FAO / WHO, 2001).
GRAS (FDA, § 182.1073, 2000).
LD501530mg / kg (rat, oral).
In case of daily intake of 2 ~ 4 g, it can cause mild diarrhea. The amount of sour agent used as a cola drink is 0.02% to 0.06%.
Phosphoric acid price More Price(56)
Sigma-Aldrich 03366 Phosphate atomic spectroscopy standard concentrate 1.00 g PO43- 1.00 g/L, for 1L standard solution, analytical standard 7664-38-2 1ea $294 2019-12-02 Buy
Sigma-Aldrich 04107 Phosphoric acid puriss., meets analytical specification of Ph. Eur., BP, NF, FCC, 85.0-88.0% 7664-38-2 6x1l $488.5 2019-12-02 Buy
Alfa Aesar 033266 Phosphoric acid, 85% w/w aq. soln., ACS 7664-38-2 *4x1kg $115 2019-12-02 Buy
Alfa Aesar 033266 Phosphoric acid, 85% w/w aq. soln., ACS 7664-38-2 1kg $42.7 2019-12-02 Buy
Strem Chemicals 93-1541 Phosphoric acid (ACS), 85% 7664-38-2 1kg $55 2019-12-02 Buy
Phosphoric acid Chemical Properties,Uses,Production
It has many uses, including the manufacture of soaps and detergents, sugar refining, water treatment, animal feeds, electroplating, gasoline additive, and binder for foods, to name a few.
Phosphoric acid was prepared first by Robert Boyle in 1694 by dissolving phosphorus pentoxide in water. Phosphoric acid is probably the most important compound of phosphorus. It is the second largest inorganic chemical by volume, after sulfuric acid, marketed in the United States.
The single most important application of Phosphoric acid is manufacturing phosphate salts for fertilizers. Such fertilizer phosphates include sodium, calcium, ammonium, and potassium phosphates. Other applications are in metal pickling and surface treatment for removal of metal oxides from metal surfaces; electropolishing of aluminum; as a bonding agent in various refractory products such as alumina and magnesia; as a catalyst in making nylon and gasoline; as a dehydrating agent; in fireproofing wood and fabrics; in lithographic engraving; in textile dyeing; in dental cement; in coagulating rubber latex; in purifying hydrogen peroxide; and as a laboratory reagent. Dilute solutions of phosphoric acid are used as additives to carbonated beverages for a pleasing sour taste. Also, dilute acid is used in refining sugar; as a nutrient; and as a buffering agent in preparing jam, jelly, and antibiotics. The commercial phosphoric acid is 85% (w/w) in strength.
Phosphoric acid is a colourless, odourless chemical substance.
Phosphoric acid on combustion forms toxic fumes (phosphorous oxides) and decomposes on contact with alcohols, aldehydes, cyanides, ketones, phenols, esters, sulphides, and halogenated organics producing toxic fumes. It violently polymerises under the influence of azo compounds and epoxides attacks many metals forming flammable/explosive gas. Phosphoric acid violently polymerises under the influence of azo compounds and epoxides, reacting violently with bases. It has wide-scale application in industries, in the manufacture of superphosphates for fertilisers, phosphate salts, polyphosphates, and detergents, as a catalyst in ethylene manufacture and hydrogen peroxide purification as a flavour, acidulant, synergistic anti-oxidant, and sequestrant in food. In dental cements, in process engraving, metal rustproofing, latex coagulation, analytical reagent, and as a veterinary product in the treatment of lead poisoning. Food-grade phosphoric acid is used to acidify foods and beverages. It provides a tangy or sour taste and, being a mass-produced chemical, is available cheaply and in large quantities. Phosphoric acid, used in many soft drinks, has been linked to lower bone density in epidemiological studies. In brief, phosphoric acid is a strong acid and common industrial chemical used in the manufacture of a wide number of products, notably porcelain and metal cleaners, detergents, and fertilisers. It is also used as a food additive and is a major constituent of many soft drinks. Low phosphate concentrations are found in drinking water to which it is added in some areas in order to reduce lead solubility.
Phosphoric acid is a colorless, odorless, crystalline solid or a thick syrupy liquid. Physical state is strength and temperature dependent.
Concentrated phosphoric acid occurs as a colorless, odorless, syrupy liquid.
Phosphoric acid is odorless. It has a pleasing acid taste when suitably diluted. For a detailed description of this compound, refer to Burdock (1997).
Pure phosphoric acid, also called orthophosphoric acid, is a clear, colorless, mineral acid with moderate strength. It is normally marketed as an aqueous solution of 75–85% in which it exists as a clear, viscous liquid.
Chemists refer to orthophosphoric acid as phosphoric acid, which is the IUPAC name for this compound. The prefix "ortho" is used to distinguish the acid from other phosphoric acids, which are generally called polyphosphoric acids. Orthophosphoric acid is a nontoxic, rather weak triprotic acid. When pure, it is a solid at STP. Orthophosphoric acid is a very polar molecule which makes it highly soluble in water. The valence state of phosphorous in orthophosphoric acid and other phosphoric acids is +5. Triprotic means that the orthophosphoric acid molecule can dissociate up to three times, producing a hydrogen cation, H+, each time.
Phosphoric acid is a natural constituent of many fruits and their juices.
Phosphoric acid was produced but not identified by alchemists in ancient times. It derives its name from the element phosphorus, which was discovered in 1669 by Henning Brand (1630 1710).Scheele subsequently isolated phosphorus from bone ash and produced phosphoric acid by reacting phosphorus and nitric acid. Scheele's method replaced bone as the main source of phosphorus rather than urine.
John Bennett Lawes (1814 1900) patented a process in 1841 of making superphosphate from bones and later extended his process to phosphates obtained from rock. Superphosphates are made by treating Ca3(PO4)2 with sulfuric acid to make more soluble calcium hydrogen phosphates: Ca3(PO4)2 + 2H2SO4 Ca(H2PO4)2 + 2CaSO4. In this reaction Ca(H2PO4)2 is monobasic calcium phosphate, which is also called superphosphate. Calcium hydrogen phosphates (superphosphates) are more water soluble and therefore more readily available to plants.
Phosphoric acid is second only to sulfuric acid as an industrial acid and consistently ranksin the top 10 chemicals used globally.States, but it is used in a number of other applications. Phosphateswere used as builders and water softeners. A builder is a substance added to soaps or detergentsto increase their cleansing power.
Phosphoric acid is used as an intermediate in the production of animal feed supplements,water treatment chemicals, metal surface treatments, etching agent, and personal care productssuch as toothpaste. It is used as a catalyst in the petroleum and polymer industry. Phosphoricacid is used in food as a preservative, an acidulant, and flavor enhancer; it acidifies carbonateddrinks such as Coca Cola and Pepsi, giving them a tangy flavor. Phosphoric acid is used as arust remover and metal cleaner. Naval Jelly is approximately 25% phosphoric acid. Other usesfor phosphoric acid include opacity control in glass production, textile dyeing, rubber latexcoagulation, and dental cements.
Phosphoric acid (H3PO4) is the most important oxoacid of phosphorus and its main use is in the manufacture of fertilisers .
Within the human body, phosphate is the main phosphorus-containing compound. Phosphate is an inorganic compound and is the salt of phosphoric acid. It can form organic esters with a variety of compounds and these are important in many biochemical processes. Phosphate has the empirical formula PO43-. It is a tetrahedral molecule, where the central phosphorus atom is surrounded by four oxygen atoms.
In biological systems, phosphate is often found either as the free ion (inorganic phosphate) or as an ester after reaction with organic compounds (often referred to as organic phosphates). Inorganic phosphate (mostly denoted as Pi) is a mixture of HPO42- and H2PO4- at physiological pH.
Phosphoric anhydride is a solid, which is very strongly moisture absorbing and is mainly used as a desiccant.
Phosphoric acid is one of the most widelyused chemicals. Among its most importantapplications are its use in fertilizers anddetergents, in pickling and rustproofing metals, as a catalyst, and as an analytical reagent.
phosphoric acid is a preservative and an anti-oxidant. It is irritating to the skin in concentrated solutions.
In the manufacture of superphosphates for fertilizers, other phosphate salts, polyphosphates, detergents. Acid catalyst in making ethylene, purifying hydrogen peroxide. As acidulant and flavor, synergistic antioxidant and sequestrant in food. Pharmaceutic aid (solvent). In dental cements; process engraving; rustproofing of metals before painting; coagulating rubber latex; as analytical reagent.
Phosphoric Acid is an acidulant that is an inorganic acid produced by burning phosphorus in an excess of air, producing phosphorus pentoxide which is dissolved in water to form orthophosphoric acid of varying concentrations. it is a strong acid which is soluble in water. the acid salts are termed phosphates. it is used as a flavoring acid in cola and root beer beverages to provide desirable acidity and sourness. it is used as a synergistic antioxidant in vegetable shorten- ings. in yeast manufacture, it is used to maintain the acidic ph and provide a source for phosphorus. it also functions as an acidulant in cheese. it is also termed orthophosphoric acid.
Phosphorous acid is used for reaction with inorganic and organic products, for water treatment, industrial and agricultural uses. It is also used to bleach industrial and cleaning supplies. Contact
ChEBI: A phosphorus oxoacid that consits of one oxo and three hydroxy groups joined covalently to a central phosphorus atom.
Low-purity technical grade phosphoric acid for use in fertilizers is produced from phosphate rocks by digestion with concentrated sulfuric acid. The apatite types, primarily consisting of calcium phosphate phosphate rocks, are used: Ca3(PO4)2 + 3H2SO4 + 6H2O → 2H3PO4 + 3(CaSO4•2H2O)
The insoluble calcium sulfate slurry is filtered out. Acid from this wet process is impure but can be purified by various methods. Purification steps involve precipitation, solvent extraction, crystallization, and ion exchange techniques.
Phosphoric acid also can be made by many different methods. Dissolution of phosphorus pentoxide in water and boiling yields phosphoric acid. Pure phosphoric acid can be obtained by burning phosphorus in a mixture of air and steam:
P4 (l) + 5O2 (g) →P4O10 (s)
P4O10 (s) + H2O (g) → 4H3PO4 (l)
The acid also may be prepared by heating violet phosphorus with 33% nitric acid:
4P + 10HNO3 + H2O → 4H3PO4 + 5NO ↑ + 5NO2 ↑
or by heating red phosphorus with nitric acid (1:1). The overall equation is:
P + 3HNO3 → H3PO4 + NO + 2NO2
Production Methods
The majority of phosphoric acid is made by digesting phosphate rock (essentially tricalcium phosphate) with sulfuric acid; the phosphoric acid is then separated by slurry filtration. Purification is achieved via chemical precipitation, solvent extraction, crystallization, or ion exchange.
Pharmaceutic aid (solvent).
A clear colorless liquid or transparent crystalline solid. The pure solid melts at 42.35°C and has a density of 1.834 g / cm3. Liquid is usually an 85% aqueous solution. Shipped as both a solid and liquid. Corrosive to metals and tissue. Used in making fertilizers and detergents and in food processing.
Air & Water Reactions
Soluble in water with small release of heat.
Reactivity Profile
Phosphorous acid reacts exothermically with bases. May react with active metals, including such structural metals as aluminum and iron, to release hydrogen, a flammable gas. Can initiate the polymerization of certain classes of organic compounds. Reacts with cyanide compounds to release gaseous hydrogen cyanide. May generate flammable and/or toxic gases in contact with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and strong reducing agents. Forms explosive mixture with nitromethane. Reacts violently with sodium tetrahydroborate. In the presence of chlorides can corrode stainless steel to form explosive hydrogen gas. Emits toxic and irritating fumes of oxides of phosphorus when heated to decomposition [Lewis, 3rd ed., 1993, p. 1029].
Burns on mouth and lips, sour acrid taste, severe gastrointestinal irritation, nausea, vomiting, bloody diarrhea, difficult swallowing, severe abdominal pains, thirst, acidemia, difficult breathing, convulsions, collapse, shock, death.
Phosphoric acid is less corrosive and hazardous than is concentrated sulfuric or nitricacid. Its concentrated solutions are irritantsto the skin and mucous membranes. Thevapors (P2O5 fumes) can cause irritation tothe throat and coughing but could be tolerated at <10 mg/m3.The acute oral toxicity in rats is reported tobe low, the LD50 value being 1530 mg/kg(NIOSH 1986).
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Pharmaceutical Applications
Phosphoric acid is widely used as an acidifying agent in a variety of pharmaceutical formulations. It is used in pharmaceutical products as part of a buffer system when combined with a phosphate salt such as sodium phosphate, monobasic or dibasic. It is also widely used in food preparations as an acidulant, flavor, and synergistic antioxidant (0.001–0.005%) and sequestrant.
Therapeutically, dilute phosphoric acid has been used welldiluted in preparations used in the treatment of nausea and vomiting. Phosphoric acid 35% gel has also been used to etch tooth enamel and to enhance delivery of drugs through the nail.
) Nanosized hydroxyapatite powder was made by combining phosphoric acid with egg shells.
Agricultural Uses
Orthophosphoric acid is obtained by reacting phosphorus pentoxide with water or by reacting rock phosphate with concentrated sulphuric acid. Salts of ammonium,calcium or potassium with this acid are called orthophosphates, and these are used as fertilizers. Nearly 80% of the phosphorus pentoxide in fertilizers is derived from orthophosphoric acid. Commercial phosphates based on orthophosphoric acid, also known as phosphoric acid, are triple superphosphate, ammonium phosphate, ammonium polyphosphate, nitrophosphate, orthophosphate fertilizer and liquid fertilizers.
Phosphoric acid (H3PO4), also known as orthophosphoric acid, is the most significant source of phosphate fertilizers. Phosphoric acid based fertilizers mainly include ammonium phosphate, diammonium phosphate and monoammonium phosphate.
Phosphoric acid is deliquescent and commercially the most important derivative of phosphorus, accounting for over 90% of the phosphate rock mined. The white rhombic solid is highly soluble in water and ethanol, and the concentrated aqueous solution is generally available for use.
Phosphoric acid is used in several industries other than the fertilizer industry. Most elemental phosphorus is converted into phosphoric acid for non-fertilizer use. There are two basic processes for the production of phosphoric acid.
Metaphosphoric acid is obtained by heating phosphoric acid until dense white fumes begin to appear. The product is highly deliquescent and glassy in appearance. Its salts are known as metaphosphates. Orthophosphoric acid is the most common and is used as an important phosphate ingredient in commercial fertilizers.
Industrial uses
As a cleanser for metals, phosphoric acid produces a light etch on steel, aluminum, or zinc, which aids paint adhesion. Deoxidine is a phosphoric acid cleanser for metals. Nielite D is phosphoric acid with a rust inhibitor, used as a nonfuming pickling acid for steel. Albrite is available in 75, 80, and 85% concentrations in food and electronic grades, both high-purity specifications. DAB and Phosbrite are called Bright Dip grades, for cleaning applications. Phosphoric anhydride, or phosphorus pentoxide, P2O5, is a white, water-soluble powder used as a dehydrating agent and also as an opalizer for glass. It is also used as a catalyst in asphalt coatings to prevent softening at elevated temperatures and brittleness at low temperatures.
Safety Profile
Human poison by ingestion. Moderately toxic by skin contact. A corrosive irritant to eyes, skin, and mucous membranes, and a systemic irritant by inhalation. A common air contaminant. A strong acid. Mixtures with nitromethane are explosive. Reacts with chlorides + stainless steel to form explosive hydrogen gas. Potentially violent reaction with solum tetrahydroborate. Dangerous; when heated to decomposition it emits toxic fumes of POx
In the concentrated form, phosphoric acid is an extremely corrosive and harmful acid. However, when used in pharmaceutical formulations it is usually very diluted and is generally regarded as an essentially nontoxic and nonirritant material.
The lowest lethal oral dose of concentrated phosphoric acid in humans is reported to be 1286 mL/kg.
(rabbit, skin): 2.74 g/kg
(rat, oral): 1.53 g/kg
The elemental phosphorus is burned to produce phosphorous pentoxide (P2O5), which is then hydrated. The heat is then removed and the phosphoric acid (H3PO4) is collected as a fine mist. Another important source of phosphoric acid is from phosphate rocks by treatment with sulfuric acid; this is the so-called wet-acid process. The synthesis of pure phosphoric acid involves several steps including a time-consuming, expensive step, the sublimation of white phosphorus.
Potential Exposure
Phosphoric acid is used in the manufacture of fertilizers, phosphate salts; polyphosphates, detergents, activated carbon; animal feed; ceramics, dental cement; pharmaceuticals, soft drinks; gelatin, rust inhibitors; wax, and rubber latex. Exposure may also occur during electropolishing, engraving, photoengraving, lithographing, metal cleaning; sugar refining; and water-treating.
When stored at a low temperature, phosphoric acid may solidify, forming a mass of colorless crystals, comprising the hemihydrate, which melts at 28°C. Phosphoric acid should be stored in an airtight container in a cool, dry place. Stainless steel containers may be used.
UN1805 Phosphoric acid solution, Hazard class: 8; Labels: 8-Corrosive material. UN3543 Phosphoric acid solid, Hazard class: 8; Labels: 8-Corrosive material.
The substance is a medium strong acid. Incompatible with strong caustics; most metals. Readily attacks and reacts with metals forming flammable hydrogen gas. Do not mix with solutions containing bleach or ammonia. Violently polymerizes on contact with azo compounds; epoxides, and other polymerizable compounds. Decomposes on contact with metals, alcohols, aldehydes, cyanides, ketones, phenols, esters, sulfides, halogenated organics; producing toxic fumes. Corrosive to common metals and possibly to some rubbers and plastics.
Phosphoric acid is a strong acid and reacts with alkaline substances. Mixtures with nitromethane are explosive.
Add slowly to solution of soda ash and slaked lime with stirring, then flush to sewer with large volumes of water.
GRAS listed. Accepted as a food additive in Europe. Included in the FDA Inactive Ingredients Database (infusions, injections, oral solutions, topical creams, lotions, ointments and solutions, and vaginal preparations). Included in nonparenteral and parenteral medicines licensed in the UK. Included in the Canadian List of Acceptable Non-medicinal Ingredients.
Phosphoric acid Preparation Products And Raw materials
Phosphate rock powder Sodium molybdate dihydrate Food grade phosphoric acid Hydrogen peroxide ROCK PHOSPHATE Barium hydroxide CALCIUM SULFATE HEMIHYDRATE Microvoid filter film Ammonium hydrogen sulfate phosphoric acid by wet process White phosphorus Phosphorus High purity Celite
Phosphatizing agent Tetrabutylammonium phosphate 2-ACETYL-5-IODOTHIOPHENE Aluminum triphosphate ZINC DIHYDROGEN PHOSPHATE Ferric pyrophosphate IODOCYCLOHEXANE Pyrophosphoric acid 2-(2-Bromoethyl)-1,3-dioxolane amphoteric polyacrylamide alcohol polyoxyethylene ether phosphoric monoester ethanolamine 4,4'-BIS(BROMOMETHYL)BIPHENYL MAGNESIUM PHOSPHATE 2-Acetyl-3-methylthiophene ZINC PHOSPHATE, MONOBASIC Sewerage inhibitor Starch, phosphate non-dip adhesive nodule-holeless honeycomb structural adhesive J-23-2 Alendronic acid Cefcapene pivoxil 4-Chromanone Phosphomolybdic Acid Monosodium phosphate Aluminium phosphate Disodium hydrogen phosphate dihydrate TSP hydration catalyst for propylene Acid modified starch 4'-Ethoxyacetophenone Phosphatizing liquid SODIUM PHOSPHOTUNGSTATE AMMONIUM PHOSPHOMOLYBDATE Sodium dihydrogen phosphate Maddrell's salt for food Aluminum dihydrogen phosphate 3-METHYLTHIOPHENE-2-CARBONYL CHLORIDE 2-ACETYL-5-CYANOTHIOPHENE Conditioner for metal surface MAGNESIUM HYDROGEN PHOSPHATE TRIHYDRATE Calcium phosphate
Phosphoric acid Suppliers
Global( 481)Suppliers Belgium 2 Canada 2 China 369 Czech Republic 2 Europe 2 Germany 5 Hungary 1 India 5 Italy 2 Japan 7 Mexico 1 Singapore 1 Slovakia 1 South Korea 2 Switzerland 2 The Netherlands 1 United Kingdom 12 United States 64 Global 481
ProdList
Hangzhou Bayee Chemical Co., Ltd. 0086-571-86990109
0086-571-85775919 [email protected] China 105 55
Henan Tianfu Chemical Co.,Ltd. 0371-55170693
0371-55170693 [email protected] CHINA 22631 55
Hefei TNJ Chemical Industry Co.,Ltd. 86-0551-65418684 18949823763
86-0551-65418684 [email protected] China 1892 55
career henan chemical co +86-371-86658258
[email protected] CHINA 30057 58
Chemwill Asia Co.,Ltd. 86-21-51086038
86-21-51861608 [email protected];[email protected];[email protected];[email protected] CHINA 23978 58
Hubei Jusheng Technology Co.,Ltd. 86-18871470254
027-59599243 [email protected] CHINA 28235 58
Hebei Guanlang Biotechnology Co., Ltd. +8619930501651
whatsapp: +8619930501651 [email protected] CHINA 2370 58
hdzhl biotechnology co., ltd 86-13032617415
[email protected] CHINA 1278 58
Xiamen AmoyChem Co., Ltd +86 592-605 1114
Hubei xin bonus chemical co. LTD 86-13657291602
Synthesize and Applications of Phosphoric acid
Phosphoric acid is a mineral inorganic acid. Orthophosphoric acid refers to phosphoric acid in which the prefix ortho is used ....
View Lastest Price from Phosphoric acid manufacturers
2019-04-02 Phosphoric acid Manufacturer; In stock GMP Factory
7664-38-2 US $1.00 / KG 1KG High quality manufacturer TOP 3 largest production factory in China Chemwill Asia Co.,Ltd.
2019-11-11 Phosphoric acid
7664-38-2 US $99.00 / KG 1KG 85% 5000 Metric Ton/Metric Tons per Month Hebei Xibaijie Biotechnology Co., Ltd.
7664-38-2 US $1.00 / kg 1kg AR,85 wt. % in H2O 1000kg career henan chemical co
7664-38-2(Phosphoric acid)Related Search:
Clindamycin phosphate Fludarabine phosphate Orthophosphoric acid butyl ester Tetrasodium pyrophosphate Orthophosphoric acid hexyl ester Ascoric Acid Potassium dihydrogen phosphate phosphoric acid ACETYL PHOSPHATE LITHIUM POTASSIUM SALT Triphenyl phosphate Glycine Phosphoric acid Citric acid Sodium phosphate tribasic dodecahydrate Ethyl 2-(Chlorosulfonyl)acetate Folic acid Stearic acid Ammonium phosphate dibasic
PHOSPHORIC ACID, 85%, REAGENT (ACS)PHOSPHORIC ACID, 85%, REAGENT (ACS)PHOSPHORIC ACID, 85%, REAGENT (ACS)PHOSPHORIC ACID, 85%, REAGENT (ACS)
PHOSPHORIC ACID, 85%, SUPERIOR REAGENT (ACS)PHOSPHORIC ACID, 85%, SUPERIOR REAGENT (ACS)PHOSPHORIC ACID, 85%, SUPERIOR REAGENT (ACS)PHOSPHORIC ACID, 85%, SUPERIOR REAGENT (ACS)
PHOSPHORIC ACID, 99.999%, 85% SOLUTIONPHOSPHORIC ACID, 99.999%, 85% SOLUTIONPHOSPHORIC ACID, 99.999%, 85% SOLUTIONPHOSPHORIC ACID, 99.999%, 85% SOLUTION
PHOSPHORIC ACID, SOLUTION, 15%PHOSPHORIC ACID, SOLUTION, 15%PHOSPHORIC ACID, SOLUTION, 15%
phosophoric Acid
Phosphoric acid, ≥85 wt. % in H2O, ≥99.99% metals basis
FEMA 2900
EXTRAN(R) AP 21
EXTRAN(R) AP21, ACID RINSE DETERGENT WITH PHOSPHORIC ACID
EXTRAN(R) AP21 DETERGENT
EXTRAN AP 21
H3PO4
U.N. 1805
Acide phosphorique
acidephosphorique
acidephosphorique(french)
acidephosphoriquesolutions
Acido fosforico
acidofosforico
EVITs
Fosforzuuroplossingen
hydrogenphosphate
Marphos
ortho-phosphoramide
phosphoricacid(non-specificname)
PHOSPHORICE ACID
PHOSPHOROUS ACID FLAKE
PHOSPHORIC ACID FOOD GRADE
PHOSPHORIC ACID 85
PHOSPHORIC ACID TECH GRAD
PHOSPHORIC ACID TECHNICAL GRAD
PHOSPHORICE ACID 85PCT TECH GRADE
PHOSPHORIC ACID (TECHNICAL GRADE)
PHOSPHORIC ACID FOOD GRAD
PHOSPHORIC ACID F.
PHOSPHORIC ACID 85 % TECH. GRADE
PHOSPHORIC ACID 85% MIN
PHOS ACID
PHOSPHORIC ACI
PHAOSPHORIC ACID
FOOD PHOSPHATES
Orthophosporic acid
NMR STD/85% PHOSPHORIC ACID/D20(W/V) 5MM
PHOSPHATE ATOMIC SPECTROSCOPY STD. CONC. 10.00 G PO(4)(3-)
ORTHO-PHOSPHORIC ACID 85%, FOR LUMINESCE NCE
PHOSPHORIC ACID, >=85 WT.% SOLUTION IN WATER, A.C.S. REAGENT
ORTHO-PHOSPHORIC ACID 85%, 0.5 L
ORTHO-PHOSPHORIC ACID 85 %, R. G., REAG. ACS, REAG. ISO, REAG. PH. EUR.
PHOSPHORIC ACID >=85 WT.% SOLUTION IN &
PHOSPHORIC ACID SOLUTION FOR HPCE, 20 MM PHOSPHORIC AC
ORTHO-PHOSPHORIC ACID 85%, ACS
LABCONCO LABSOLUTIONS NEUTRALIZING ACID&
PHOSPHORIC ACID, 99.999+%, 85+ WT. % SOLUTION IN WATER
ORTHO-PHOSPHORIC ACID 85%, 4X25 ML
ORTHO-PHOSPHORIC ACID 85%, FOR TRACE ANA LYSIS
Phosphoric acid, crystals, 99.999+% metals basis
中国福彩网论坛 www.hoaemj.tw Product Name*
中国福彩网论坛

redpajama_set_name: RedPajamaCommonCrawl


Crime writer: Why Is PBA Silent on Cuomo and Parole?
Patrolmen's Benevolent Association President Pat Lynch has been performing "handsprings and cartwheels" to try and delay or overturn the scheduled parole of Black Liberation Army cop-killer Herman Bell, reports Len Levitt at amNY. He's railed against the Parole Board and state Attorney General Eric Schneiderman. Yet, notes Levitt, "there is one person Lynch has avoided criticizing": Gov. Cuomo, who not only appointed the current board, but also "reversed the board's priorities when deciding parole" to de-emphasize the circumstances of the crime. Cuomo's said he opposes Bell's parole, but his statement "pales in comparison" to that of Mayor de Blasio, with whom Lynch "has feuded for years." Lynch has even remained silent about Cuomo's refusal to meet with Diane Piagentini, widow of one of Bell's victims.


text:
ArtsNL says it denied funding for 3 groups because of botched applications, risk of audits
Nfld. & Labrador
The arts council released a statement Thursday evening, just a week after saying it was retaining legal counsel in preparation with a legal battle with the Folks Arts Society.
Arts NL says it is subject to finance and AG audits, so incomplete applications can't be accepted
CBC News · Posted: Apr 06, 2018 6:26 AM NT | Last Updated: April 6, 2018
ArtsNL is a non-profit Crown agency that serves as Newfoundland and Labrador arts council. (ArtsNL)
ArtsNL is defending its decision to deny three organizations grant funding, saying the groups didn't properly complete the paperwork in their applications.
The provincial arts council released a statement Thursday evening, just over a week after it said it was retaining legal counsel in preparation for a legal battle with the Folks Arts Society.
The Folks Arts Society, which runs the popular Newfoundland and Labrador Folk Festival, lost $44,000 in expected funding for the next two years as a result of failing to fill out a yearly online database report in its application to ArtsNL.
One of the groups denied funding is the Folks Arts Society, which runs the annual Newfoundland and Labrador Folk Festival at Bannerman Park. (Ted Blades/CBC)
That group, along with the Gros Morne Summer Music and Riddle Fence, lost their second year of funding in a three-year program.
Arts NL says in each case there were significant omissions in support materials or they hadn't complied with the regulations.
The council says it can be audited by the Finance Department and the province's auditor general, so it can't relax the rules.
Hands are tied
In its statement, ArtsNL said it understands how concerned the arts community is about the funding rejections, but that it did what it could to let the three organizations know what was expected in its applications.
"ArtsNL's general practice has always been to offer every applicant any possible support prior to deadlines, and applicants are made aware there is no leeway to extend deadlines," ArtsNL Chair Stan Hill wrote in a statement.
"All three organizations affected were notified that they were eligible to alternatively apply to the Annual Operating Program for Professional Arts Organizations, which provided them all with equal opportunity to continued access to ArtsNL funding in the event their applications were successful."
ArtsNL retains legal counsel in battle with Folk Arts Society over denied funding


Disability Management Service (DMS) is a FREE program to assist those with short term illness or injury back into the workforce. This service is now available from Ability Options | Olympus Solutions location as of the 1st July 2018.
Training information and awareness activities for employers and staff.
Ben was living with chronic health issues and low self-esteem. With the support of an Ability Options Consultant and by continually working on improving his health, Ben has been able to secure employment.
We are now offering this life-changing service across all of our offices as of the 1st of July 2018. See Where to find us for details.
Whether you are a person looking for employment or an Employer looking to assist a person back into the workforce, click on the link below. Please complete your details and we will contact you to arrange an appointment at your local Ability Options office.


Microsoft .NET Framework 2019 is an exceptional software framework for developers and users of XML Web services and applications. Microsoft.Net Framework is often required by programs to allow for the create environment required for runtimes of certain programs. Developers will be turning cartwheels over the multiple features that are included in this software.


Below impression of pups at age 2 weeks, pictures and video taken on May 22 2014. Mom and her kids are doing well. Pups growing fast and their eyes are starting to open. Pretty soon they will experience solid food, porridge plus. Colors pups that are detected for now will be mostly Blue Belton, with a possible tricolor and 2 or 3 of the pups will be Orange Belton.
Further information and inquiries are welcome at/through: Kennel Blazing Bronze, LINK.
Pictures, app. age 2 weeks.


text:
A19 – Flood water going down, causeway now visible
The photograph above was taken on Monday 25 January and shows shallow flood water across part of the A19 causeway which is being reconstructed. Overnight the flood water has steadily gone down and is now 45cm below the peak reached on Saturday. The top of the causeway is now clear of the flood water.
NYCC and Balfour Beatty warned that such an event was possible during the site meeting on 12 January. See the previous report. They said that the planned completion date of 25 June 2021 included contingency for an interruption of this type. They also said that the causeway was being rebuilt so that it would not be damaged if flooded. This event will have put the design to the test.
NYCC have been asked to confirm that despite this interruption that the end date will still be met or even improved upon.
Yesterday NYCC issued a brief press release which can be found here. As soon as further information is received from NYCC it will be posted here.
NYCC Press release Christoph 25 January.pdf 1.04 MB
Boris backs Selby men's new mercy mission
Loading up for Ukraine in Burn: from left, Mitch Mitchell, Katrina Markovska, MP Nigel Adams and Stuart Davison.


text:
Q: Reading web-based JSON I'm writing code that needs to reach out to this JSON file that's online, query it for data, and return the results of the search.
I tried the following code:
    adsb_data = urllib2.urlopen('http://website.com')

That will throw a urllib2.HTTPError: HTTP Error 403: Forbidden
So obviously I'm not going about it the best way.
What would be the best way to open that JSON page, scrape it, and display results? I feel like there's a much more elegant and pythonic way to do this.

A: Looks like that particular server is blocking Python's User Agent. This should work for you:
url = "http://public-api.adsbexchange.com/VirtualRadar/AircraftList.json"
dummy_ua = "Mozilla/5.0 (X11; U; Linux i686) Gecko/20071127 Firefox/2.0.0.11"
request = urllib2.Request(url, headers={'User-Agent' : dummy_ua})
urllib2.urlopen(request).read()

A: All good answers! Thank you everyone for input.
I fixed the issue by using requests instead of urllib2.
Here is what my request looked like:
 adsb_data = http_request('http://public-api.adsbexchange.com/VirtualRadar/AircraftList.json', 'GET')

From there, I created a list and parsed out the data I wanted out of it.

redpajama_set_name: RedPajamaStackExchange


Seven different bills have been pre-filed related to addressing the scourge of heroin in the state. Lawmakers on both sides of the aisle in each chamber have filed pieces of legislation with the same goal of dealing with the epidemic. The issue was debated in the 2014 session but no legislation was passed after disputes over provisions dealing with prosecution of heroin dealers and the idea of setting up a needle exchange.
Five separate pieces of legislation have been filed by lawmakers looking to restore the voting rights of felons. Each pre-filed bill has different criteria for that restoration, mainly focused on excluding certain felony charges. Offender re-entry and felon expungement—issues dealing with the employment opportunities of those convicted of a low-level offense—are also topics with pre-filed bills.
Addressing the ongoing problems in the state pensions systems is the subject of many pre-filed bills, including acts related to: the Kentucky Retirement System, the Kentucky Teachers Retirement System, Legislators' Retirement Plan and others.
A bill prohibiting smoking in public places and places of employment has been pre-filed by Rep. Susan Westrom, D-Lexington. The idea of a statewide smoking ban has come up in many previous sessions but has yet to receive a vote on the floor of either chamber.
Bills related to energy issues include legislation to allow the construction of nuclear power plants as well as legislation to create Energy Project Assessment Districts—ePADS for short—to spark investment in energy efficient upgrades for commercial properties.
Reginald Meeks, D-Louisville, has pre-filed a bill to permit local governments to raise the minimum wage above the state rate. The legislation comes as Louisville metro council recently voted to raise the rate to $9 over a three year period. However, Rep. Meek's legislation implies the practice is not legal under current statute.
Legislation requiring all coal severance revenues be distributed back to the coal producing counties has been filed by Rep. Fitz Steele, D-Hazard.
Steele has also pre-filed a bill that would create a three day tax free holiday during the first weekend in August each year to exempt clothing, school supplies, computers and other items from sales and use taxes.
Tom Kerr, R-Taylor Mill, has filed legislation that seeks to repeal the common core standards—an act which would throw out Chamber-supported rigorous academic standards and cost the state at least $35 million, according to Education Commissioner Terry Holliday.
A full list of pre-filed bills with details of each piece of legislation can be found on the Legislative Research Commission website.
The Kentucky Chamber will be closely monitoring the progress of all legislation throughout the session. Stay up to date with all the latest news by checking the blog and following us on twitter @KyChamber.
To give feedback about any legislation, contact us at legislative@kychamber.com.


Our client, a leading construction company in Galway are currently looking to recruit a HR Administrator/ Accounts Assistant for their site.
To maintain employee records i.e. to meet new employees, get copies of safe pass cards, qualifications, issue contracts of employment, get SIPTU forms completed, deal with any issues employees may have, keep a records of holidays and maintain/update a company calendar of same.
To create a template for employee appraisal and performance record.
To complete a SIPTU membership record - and a spreadsheet of employees contributions.
Complete and record - travel and subsistence records and ensure they are signed and all files are up to date.
To be willing to process payroll on an adhoc basis - to be familiar with Payroll software - Thesaurus.
To be familiar with Revenue and ROS regarding registering of new employees and tax deduction certificates.
To help with the accounts on a regular basis - i.e. filing invoices, inputting invoices and getting invoices signed off and cleared for payment.
Ad hoc duties on a regular basis - account reconciliations etc.
To be familiar with Accounts software packages - QuickBooks etc.
Ideally CIPD or HR Qualification and Accounting Technician qualification.
2 years' experience in a previous supporting role of HR or Accounts.


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text:
NGC 472 este o galaxie lenticulară situată în constelația Peștii. A fost descoperită în 22 noiembrie 1827 de către John Herschel. De asemenea, a fost observată încă o dată în 29 august 1862 de către Heinrich Louis d'Arrest.

Note

Vezi și
 NGC 471
 NGC 473

Legături externe
 NGC 472 pe WikiSky
 NGC 472 pe spider.seds.org

Galaxii lenticulare
Obiecte NGC
Constelația Peștii
Obiecte astronomice descoperite în 1827
Obiecte astronomice descoperite de John Herschel

redpajama_set_name: RedPajamaWikipedia


decoration on the rim. Rarely do I lose a platter to cracks.
through the top of the piece. The plastic beneath inhibited drying.
Failure rate was fairly high.
drys, so there is no cracking.
it onto paper with a bat under it.
complete the firing to bisque.
This is my method and it works for me. I might lose two a year to cracking.
>them to cracking. Sometimes the crack shows after the bisque firing and sometimes after the glaze firing. Sometimes it is a smallish "s" type crack, but often it is larger & all the way through the piece.
>My husband thinks it is usually recycled clay in the pieces that crack, but I think it happens more often than that.
>I dry my pieces slowly, thoroughly & usually upside down.
>I'm a mostly self-taught potter and so would really appreciate any suggestions that might help cure this problem. It has gotten so bad that I am discouraged from throwing large pieces since 95% of the time, they end up being hammered.
I've been wanting to ask.
it is larger & all the way through the piece.
but I think it happens more often than that.
they end up being hammered.
tthe clay is a bit harder to center.
> I've been wanting to ask.
> When I throw largish bowls or platters, I often lose them to cracking.
> it is larger & all the way through the piece.
> but I think it happens more often than that.
> I dry my pieces slowly, thoroughly & usually upside down.
> they end up being hammered.
with big platters and bowls this size.
When I throw largish bowls or platters, I often lose them to cracking.
larger & all the way through the piece.
I think it happens more often than that.
I dry my pieces slowly, thoroughly & usually upside down.
.....When I throw largish bowls or platters, I often lose them to cracking.
The first thing I would suspect would be the clay body.
addition of grog, but I'd better things to do with my time.
my plates and pie pans.
By the way, you are welcome to come visit me at Fox Hollow.
Fire much slower and hold at the end (if you have a digital kiln).
created during forming, not drying or firing.
up only in large pieces.
forth really compressing the bottom.
This is best done standing up; you get more leverage.
a larger platter, this could be done with an added coil.
have already been adequately covered here.
that look like yours and it will be explained.
it open or closed after the bisque firing?
Am I right in assuming these cracks are across the bottom of the piece?
during throwing and/or more even drying up to and after trimming.
>I've been wanting to ask.
>When I throw largish bowls or platters, I often lose them to cracking.
>larger & all the way through the piece.
>but I think it happens more often than that.


text:
Q: count occurrence of value in multiple fields independently (awk) I have seen numerous posts to achieve this task for individual fields, but I am struggling to apply it on multiple field separately.
input:
group1|apple|orange|lemon
group1|apple|kiwi|banana
group1|orange|cherry| lemon
group1|apple|orange|pear

(The real file has many more fields, so I need to use a loop to process each fields)
output:
Field|Fruit|Count
2|apple|3
2|orange|1
3|orange|2
3|kiwi|1
3|cherry|1
4|lemon|2
4|banana|1
4|pear|1

What I tried so far, but returns the entire count for all the fields:
awk '
    BEGIN{FS=OFS="|"; print "Field|Fruit|Count"}
    {
      for(i=2; i<=NF; i++){
        a[$i]=$i
        count[$i]++
      }
    }
    END{
      for(j in count) print j OFS count[j]
    }'

A: Use the field number as part of the key in the count array.
awk '
    BEGIN{FS=OFS="|"; print "Field|Fruit|Count"}
    {
        for (i = 2; i <= NF; i++) {
            count[i OFS $i]++;
        }
    }
    END {
        for (j in count) {
            print j, count[j];
        }
    }'


text:
Meet the KENS 5 Team: Mike Vigil
Visual Storyteller Journalist
Credit: KENS 5
Author: KENS5.com Staff (KENS 5)
Published: 12:07 AM CST February 24, 2020
Updated: 12:07 AM CST February 24, 2020
Mike Vigil is a photojournalist at KENS 5 in San Antonio, Texas. He joined the KENS 5 team in September 2019.
Mike came to KENS 5 after spending two and a half years working along the border in El Paso, Texas, as a photojournalist and assignments editor. While there, he extensively covered immigration issues throughout West Texas and Southern New Mexico, as well as anything and everything affecting the border community.
Before his time in El Paso, Mike worked in radio at KSWV in Santa Fe, New Mexico, doing everything from co-hosting the morning show to producing commercials and running social media from the radio station.
Since starting in news, Mike mostly enjoys telling the stories of unique people doing unique things to make our community a better place, whether it be art, music or entrepreneurship.
Born and raised in Taos, New Mexico, Mike grew up playing sports and skiing every chance he got. After graduating from Taos High School in 2015, Mike attended New Mexico State University, where he earned his bachelor's degree in journalism and mass communications in May 2019.
While not working, Mike enjoys taking photos, playing basketball and exploring everything that San Antonio and its surrounding communities have to offer.
If you have any story ideas, feel free to send an email to mvigil@kens5.com.
Stories I Like to Tell: Jeremy Baker


Goodness gracious, nobody told me what the last day of school can be like. Julian was in kindergarten for two years and the last day was a non-event, perhaps because we missed it for both years? The first for camping? Details are fuzzy. Last year we missed the whole last week (and therefore all of the "picnics" and "graduations" and "special activities"--best decision i ever made) and also, maybe because it's kindergarten? Maybe? But first grade is veeeery different, as we all know.
I don't know about you, and maybe you're still in it, but for us, the last week of school was never.ending. Man alive! Every day felt like Friday. "Certainly it must be Friday NOW..." Sooo sloowwwww. I knew Julian was feeling some trepidation for one reason and one reason only: having to say goodbye to his dear teacher. Turns out Mrs. R was universally beloved. It wasn't the number of children who loved her (which was every one I talked to) but the way they loved her. Like, at the mention of her name, there was a certain look in their eyes, their expression immediately changed, softened, for fondness. Tenderness. She had carved herself a permanent place in each little 7-year-old heart and it was truly a thing to behold. Every now and then, throughout the year, Julian would randomly say things to me like, "You know. I think Mrs. R is really starting to become part of my life." It was unlike anything I'd ever seen, that's all i can really say about it. I felt like I was witnessing true love. True first grade teacher love-- just how it should be. Based on that alone I shall sing her praises forevermore with the utmost gratitude.
Today is the last day of first grade. I didn't think it would be that big of deal. not as big as the first day, right? Wrong. We walked to school together and the air was thick with last day jitters and excitement. "Last day! I can't believe it! Finally!" we exclaimed, over and over. We said goodbye and that was that.
Then it was time for pick-up. As I stood outside the school, waiting for you, I could feel some emotions bubbling up my throat (ew). I saw a big receiving line of parents with cameras at the ready, just outside the main doors. I stood back on my little patch of cement where I always go for pick-up and thought maybe I should get my camera out too and capture the "last day of school" faces. But of course I thought better of it, knowing that in so doing, I take myself out of the moment, and it did feel like a big moment. So I stood and waited and when the bell rang, an enormous mass cheer could be heard from inside and the kids started pouring out.
I won't cry, I said to myself. That's silly. Why would I cry? So I took a breath and held it together and I was fine. And then I saw you. Like so many times before, I observed your face, trying to ascertain your emotional state. Today it was a bit somber and strained as you desperately tried to just get to me. And as you ran into my arms, you burst into tears, completely overcome by the emotions-- of the day and the beautiful heartache of loving a teacher so much and having to say goodbye. And so of course I cried, knowing perfectly well it is NOT silly. And we walked away together and I laugh-cried through your gut-wrenching tears, and that was the last day of first grade.
"I just want the end of the school year to be pushed back farther, or not happen at all!"
"I want to go to school for the rest of my life!"
"I'll never make it through the summer!"
"I'll never see Mrs. R again!"
"This has been the most wonderful year! 100's club, parties, field trips... Second grade won't be the same!"
"Mrs. R became such a part of my life. First she teached us and then we had to say goodbye. I miss her so much already."
Honestly I'm getting a little teary just transcribing here. What a thing! Why did no one tell me? I assumed he'd run out, kicking his heels and never look back. But then, I did know the kid loves hard, loves deeply. We didn't give Mrs. R an end-of-year gift or anything, but I know she'll be receiving a mid-summer love letter with some pretty great quotes and maybe a school pic I have no idea what she'd do with.
I was laughing more than this pic lets on, but man, we just feel what we feel! And we cannot hide.
Also, I just spotted this touching little story.


text:
US Head of Verticals, Gaming, Auto, Tech & Entertainment
Eric joined Roku as Director of Ad Sales in November 2021 after more than 20 years working across multiple disciplines within the media and entertainment space. Prior to Roku, Smith led West Coast distribution for Sony Pictures Television syndication portfolio across 50 TV markets, several cable outlets and digital networks. He holds a BA from Kenyon College.
11:30 a.m. - 12:30 p.m. Silicon Beach and Beyond: What Can OTT Services Learn From Tech Startups?


Christian rehabilitation therapy facilities could be found throughout the US and assist in healing making use of Christian doctrine integrated with emotional, therapeutic as well as occasionally 12-step-modeled recuperation programs. Christian rehab functions hand-in-hand with the client and those close to them to assist in total sobriety and also healing. The distinction with regular drug rehab is that the approach is Bible based, utilizing Christ to lead the way towards dealing with emotional issues, getting out of rejection and also finding out how to forgive. In Christian rehab, as recuperating addicts are overcoming the 12 steps, they are also creating their personal Christian belief as well as partnership with Christ. In addition to traditional treatment methods, we harness a faith-based method that begins and also ends with God's forgiveness, healing, and repair. This means that along with Christian rehab to get over the addiction, they call for additional care to deal with a condition that is most likely enhancing the addiction.
Christian rehab facilities depend on the concept that faith and also spirituality can assist an addict or alcoholic recover from those addictions. The really basis of the therapy technique is that an individual cannot overcome addiction by himself but could via the guidance of a community and the strength of God. Holistic health and wellness, meditation, looking for assistance as well as help via petition, looking for aid from others, aiding other people – these are main themes to any type of recovery program, whether it is spiritual based or otherwise.
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Addiction to alcohol isn't a sign of weakness and does not suggest they do not have self-control. The good news is, dependency therapy programs could assist you conquer compulsive actions and also minimize your desire to use drugs or alcohol. Preferably, these treatment programs ought to have established aftercare programs for people to have less complicated shifts right into the normal lives and also routines. Daily meditation and also regular prayer are just a few of the important things you could experience. Your increased spiritual awareness will certainly lead you with recuperation.
They provide you the possibility to discover your spirituality while working on recouping from alcohol or medication addiction so you could create a stronger spiritual connection at the same time you conquer your addictions. These facilities strive to be respectful of all Christian beliefs as their utmost goal is recovery and also at their core all Christian beliefs are really comparable. Intensive therapy, group classes as well as education all assist and aid in creating a path toward wellness repair. Our clients are not alone in their trip, literally or emotionally. After treatment, recovering addicts continue to make use of prayer and also belief in God to get them via whatever comes their path. These aftercare steps, when incorporated with an energetic belief stroll, assist recovering addicts stay on track, prevent relapse, and obtain aid when brand-new triggers tempt them. These partnerships can be practical progressing and also maintaining them focused on making the right choices.
To put it simply, Christian rehabilitation is not so different from typical addiction treatment programs, specifically when we come down to the standard mechanics of long term sobriety. This may consist of rage management, stress decrease, nourishment, art, equine therapy, fitness, and several various other choices. The frequency of the sessions, and also the success of the program, depends on both the addict and also the program. By supplying programs and therapies that concentrate on the body, spirit, and also partnerships to construct even more assistance. There are large amounts of methods wherein people may enlist in amongst these facilities. Therefore, Christian rehabilitation centers are a fantastic option for these having a hard time addicts.
A lot of spiritual rehabilitation programs are designed for people that already have a specific religion. One of the means to discover a Christian drug rehab facility is to speak to Christian leaders such as priests, preachers or the controling body of a church. If you think finding God will certainly help you to recoup, after that we encourage you to follow your path.


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The Aetrex Gramercy Slip On is an elegant and modern loafer perfect for all occasions.
The Aetrex Men's Slip On Black is a sophisticated addition to any contemporary wardrobe. This style features a luxurious leather uppers in a classic slip-on design. This shoe will look great with dressy or casual attire. The soft, cowhide leather lining will help keep you cool and dry all day long. Aetrex's trademarked Mozaic Customization Technology helps to relieve the pain caused by pressure points. Pair these with a tailored suit or dark jeans, and a crisp button down shirt for a look that's fashionable and update.


THE NATIONAL TRANSPORT Authority has confirmed that the Metrolink project will not continue south of the Charlemont Luas stop in Dublin.
The move had been widely expected, following reports last month that the route, which had been due to run to Sandyford in the south of the county, would terminate at the south city stop due to planned disruption of the Luas Green Line lasting up to four years.
The announcement this afternoon follows a public consultation on an initial route last year, when the National Transport Authority received over 8,000 submissions on the matter.
Now, the mostly underground route, due to connect Dublin Airport to the city centre will stop at Charlemont, just to the south of the Ranelagh Luas stop.
A proposed upgrade of the Luas Green Line will instead occur "at an appropriate point in the future", although the authority said this may not happen for up to 20 years.
Other changes to the proposal mean the acquisition of the pitch belonging to Na Fianna GAA club will no longer be required for construction in the Glasnevin area.
O'Connell Street will also have an "integrated station" under the Carlton Cinema site, while the number of homes to be acquired by the authority has been reduced from 105 to 85.
A spokesman for Transport Infrastructure Ireland told TheJournal.ie that Dublin City Council planned to move the swimming pool at the leisure centre elsewhere.
Chief executive of the National Transport Authority Anne Graham said the project would be a "significant economic driver" and create around 4,000 jobs.
"It is also of benefit in providing a more sustainable transport alternative and by providing a great incentive to get people out of their cars and on to public transport," she added.
There was mixed reaction to the proposed changes to the route among local groups.
A spokesman for Na Fianna told TheJournal.ie that the northside GAA club "greatly welcomed" the announcement that its grounds would no longer be used as a boring site.
However, a spokesman for the Save the Markievicz Pool and Gym campaign questioned the assurance that the club's swimming pool would be moved elsewhere, adding that the club's facilities existed in an area which did not have many other local amenities.
The line is expected to open in 2027, with construction likely to take up to seven years.
With additional reporting from Daragh Brophy.
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Wood always has a story to tell; the age, the lines, the colour adds value to the wood more than anything. Especially a time piece handcrafted in wood would be a fabulous piece of jewelry to own, and pass on to the generations to come. One such niche brand to have created artistic time pieces in wood is this brand named Jord. They do create a new line of timepiece from time to time, which are modern enough to suit your lifestyle; are sustainable, efficient and experimental in their approach.
Disclaimer: This is a sponsored post, my views remain honest and unbiased.
So happy that I got a the chance to own this lovely time piece from Jord's Ely Line in Maple wood. What I particularly love about this one is the colour of the wood and the simple, timeless design. The Maple is pre-treated with tung oil, that adds the light gold tinge to the wood making the watch a befitting piece of jewelry. Don't worry if you by mistake splash a little water on it, the watch is splash proof; although don't really try to go swimming in it!
Watch care : For cleaning natural wood, Lemon or orange oil extract is the best. Make sure to avoid extreme hot, cold and excessively dry/humid environments, when storing this timepiece. It is under a limited 1 year warranty too.
Do check their website by clicking on the above banner.
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Archive for Black Alice
Comics Smorgasbord
Tiny Titans #23
Robin's having to share his home with a whole lot of penguins and bunnies. Bad enough they're filling his bathtub with ice and trying to get him to eat carrots and fish for breakfast, but they've scared all the bats out of the Batcave. And Batman wants his bats back in the Batcave ASAP! Can Batgirl, Batmite, two familiar toddlers, and a bunch of miniature Batman costumes fool the Dark Knight Detective? And where did all those bats go anyway?
Verdict: Thumbs up. It's an awesome and hilarious story, and that should be enough, but then Baltazar and Franco show us, on the Bat-Computer, the Tiny Titans version of Two-Face:
That may be the coolest Two-Face ever.
And there's this:
The Tiny Titans versions of Jason Todd and Tim Drake, the first two post-Dick Grayson Robins. I laughed out loud when I saw that. Does this mean we can look forward to Stepanie Brown, Damian Wayne, and Carrie Kelly showing up in "Tiny Titans"?
Batgirl #5
There are a series of arsons targeting a building development on the rougher end of Gotham, and Batgirl tracks down the arsonist, a weirdo named Diesel who has gasoline for blood. Batman and Robin (Dick Grayson and bratty Damian Wayne) show up to grab the glory, and to stop Diesel from torching Robin, Batgirl hits both of them with some freeze-arangs. As expected, this makes both Dick and Damian very snippy, which makes Barbara Gordon, Stephanie's mentor, very snippy. Once they're off the clock, Barbara meets a cop that her dad is trying to set her up with and proceeds to get snippy on him for no real reason, and Stephanie spies on a dishy classmate whose dad may be involved in shady business connected to the arsons. Stephanie later has an amusing argument with Damian and tries to meet up with her classmate for an improvised date, only to run into a bunch of kidnappers with murder on their minds.
Verdict: Thumbs up. Outstanding dialogue, funny situations, and top-notch superheroics. Stephanie is an extremely charming lead, Barbara is almost as much fun as she was in "Birds of Prey," and even the normally insufferable Damian comes across as merely a ten-year-old pill. This book is getting some of the best buzz of any DC series right now, and it's still early in its run, so there's time for you to jump aboard and enjoy the ride.
Secret Six #16
The Six get hired to help a serial killer escape from the police? But it turns out that one of his victims actually hired the Six, so too bad about your drastically shortened lifespan, Mr. Serial Killer! But they've been found out by Black Alice, a somewhat nutty gothpunk with the power to duplicate the powers of any magic-based superhero or villain. And she's willing to blackmail them into letting her join the group. They stop off at the nudie bar where Scandal's sweetie works when the rest of the team shows up and tells Alice to get lost. Then the cops show up, Black Alice steals Jeanette's banshee powers and beats up on the cops… and the rest of the Six. Is there any way to calm her down and get her to lay off?
Verdict: Thumbs up. Good grief, Black Alice is awesome. I mean, the rest of the group is fine — Ragdoll gets to crack his usual ton of great one-liners. But Black Alice is just the bee's knees.
December 18, 2009 · Filed under Batgirl, Black Alice, Secret Six, Tiny Titans
Friday Night Fights: Fight Fest!
Let's see… Friday? Check. Night? Yah, close enough. Fights? Comin' right up. Looks like it's the perfect time for FRIDAY NIGHT FIGHTS!
Tonight, we go back to Birds of Prey #118 by Tony Bedard, Nicola Scott, and Doug Hazlewood, from earlier this year. It's Misfit vs. Black Alice!
Short and simple? Sure thing. Best way to start the weekend.
September 26, 2008 · Filed under Birds of Prey, Black Alice, Friday Night Fights, Misfit