text:
Chemical vapor deposited silicon carbide articles
Chemical vapor deposited silicon carbide articles and the methods of making them are disclosed. The chemical vapor deposited silicon carbide articles are composed of multiple parts which are joined together by sintered ceramics joints. The joints strengthen and maintain tolerances at the joints of the articles. The articles may be used in semi-conductor processing.
Pickering, Michael A. (Dracut, MA, US)
Mayer, Jamie L. (Framingham, MA, US)
Lais, Kevin D. (Hillsboro, OR, US)
Rohm and Haas Electronic Materials LLC (Marlborough, MA, US)
AGC Electronic Materials (Hillsboro, OR, US)
156/89.28, 428/332, 428/368, 428/428
C04B37/02; B32B7/04
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EP0506052
EFTA, ALEX B
John J. Piskorski;Rohm and Haas Electronic Materials LLC (455 Forest Street, Marlborough, MA, 01752, US)
1. An article comprising at least two chemical vapor deposited silicon carbide parts joined together by sintered ceramics.
2. The article of claim 1, wherein at least the sintered ceramics are coated with chemical vapor deposited silicon carbide.
3. The article of claim 2, wherein the chemical vapor deposited silicon carbide coat is 0.5 to 3 mm thick.
4. An article comprising a plurality of rods joined at opposite ends to respective endplates by sintered ceramics, the plurality of rods and the endplates are of chemical vapor deposited silicon carbide.
6. The article of claim 4, wherein the true position of the endplates to each other is 2 mm or less.
7. An article comprising a plurality of rods joined at one of their respective ends to a base of a backplate by sintered ceramic joints, opposite ends of the plurality of rods are joined to a support rail by sintered ceramic joints, the plurality of rods, the backplate and the support rail are of chemical vapor deposited silicon carbide.
8. A method comprising: a) providing a paste, sol or slurry comprising one or more ceramics; b) applying the paste, sol or slurry comprising the one or more ceramics to two chemical vapor deposited silicon carbide parts to join the parts; c) drying the paste, sol or slurry to form a dried composition comprising the one or more ceramics around the two chemical vapor deposited silicon carbide parts; and d) sintering the dried composition comprising the one or more ceramics around the two chemical vapor deposited silicon carbide parts to form a sintered ceramic joint.
9. The method of claim 8, wherein the one or more ceramics comprises silicon carbide, metal oxides and raw mineral materials.
10. The method of claim 8, further comprising the step of depositing a layer of chemical vapor deposited silicon carbide on at least the sintered ceramic joint.
The present invention is directed to chemical vapor deposited silicon carbide articles. More specifically, the present invention is directed to chemical vapor deposited silicon carbide articles having improved strength and dimensional tolerances.
There are many types of silicon carbide known in the ceramics industry. Each type is classified according to the process by which it is made. Each process provides a silicon carbide having one or more different physical or structural properties. Examples of the different types of silicon carbide include chemical vapor deposited silicon carbide, reaction bonded silicon carbide, sintered silicon carbide, hot pressed silicon carbide and foamed silicon carbide. While the various types of silicon carbide may have one or more overlapping properties, they are not identical, and each is readily distinguishable by X-ray diffraction analysis and chemical analysis. The different physical and structural properties of the various silicon carbides often determine their applications.
Chemical vapor deposited silicon carbide (CVD-SiC) has a combination of properties which make it highly suitable for specialized materials applications. CVD-SiC may be highly thermally conductive, chemically and oxidatively stable, heat stable, hard, scratch-resistant, electrically resistive and theoretically dense. Examples of applications where CVD-SiC is highly suitable include wafer boats used in semi-conductor processing, wafer carriers used in wet bench cleanings, furniture used in semiconductor processing chambers, optical telescope structures, optical benches and end effectors to hold semi-conductor wafers during loading and unloading from semi-conductor furnaces.
For example, processing of semiconductor wafers involves harsh conditions such as exposure to corrosive conditions, such as with corrosive compounds, such as HF, high temperatures and rapid thermal cycling. Accordingly, furnace furniture and wafer boats need to withstand such harsh conditions. One method for processing semiconductor wafers involves rapid thermal processing (RTP). Such processes are performed in rapid thermal annealing apparatus (RTA). Semiconductor wafers are treated in an RTA from room temperature to temperatures of 400° C. to 1400° C. in periods of time on the order of a few seconds. Such harsh conditions often result in flaws and cracks forming in the furniture and wafer boats and the sloughing off of materials from the surfaces to the furniture and boats. Damage to the furniture and boats requires replacement, and sloughing off of materials from the surfaces results in contamination of the wafers resulting in loss and increased expense.
The semiconductor industry has recognized that CVD-SiC can withstand the harsh conditions involved in semiconductor processing and is a superior material for construction of furniture and wafer boats. Prior to CVD-SiC, quartz, and later sintered silicon carbide, was used as a material for furniture and boats. However, both of these materials were, in general, inadequate to withstand the harsh processing conditions and often have to be replaced. Also, thermal incompatibility with materials used in wafer manufacture resulted in damage to the wafers causing loss and extra expense in manufacturing.
While CVD-SiC has many properties highly desirable in specialized applications, some of these same properties render it a difficult material from which to fabricate articles. For example, its hardness renders CVD-SiC difficult to machine. CVD-SiC presents substantial difficulties in fabricating articles which are too complex in shape and bulky to be practically fabricated from a single, monolithic, deposited sheet or block. CVD-SiC's high density, i.e. theoretical density, provides minimal to no porosity. Porosity facilitates parts bonding with adhesives in other types of silicon carbides, such as sintered silicon carbide.
Several techniques have been proposed to bind parts of the various types of silicon carbide. These include direct bonding, codensification of interlayers and green bodies, hot pressing of suitable silicon carbide powders, bonding with polymeric precursors, brazing and reactive metal bonding, pressurized combustion reaction, reaction with and without the use of tape and microwave joining. These techniques have limited utility for semiconductor applications due to one or more drawbacks, such as use of filler material which contaminates the furnace environment, inability of joints to withstand high service temperatures, and the need for very high temperatures or pressures during joining processing.
U.S. Pat. No. 5,683,028 to Goela et al. discloses a chemical means of securing a male/female joint between two CVD-SiC parts. The patent discloses a wafer boat composed of four monolithic CVD-SiC rods. Each rod has two male joint members that slide into corresponding female ports in respective endplates to form a single article. The joint is secured with a solid-state silicon sealant. The silicon is applied in the joint as a powder where it is heated until it melts. It is then allowed to cool and solidify to hold the parts together. The joint may be further secured with a coating of CVD-SiC.
Although the article disclosed in U.S. Pat. No. 5,683,028 is an improvement over many conventional wafer boats, such articles require tight dimensional tolerances at the joints during manufacture. Typically, such dimensional tolerances must be precise within +/−0.01 mm to 0.05 mm. The more precise the tolerances required the less room there is for error in machining and mounting and handling to position the parts. Such articles are assembled using various types of fixture apparatus, which align the different parts of the article. However, some motion typically occurs between parts during the alignment process. This motion may result in some misalignment of the parts at their joints, thus increasing the tolerance range beyond +/−0.01 to 0.05 mm. This often results in defects at the joints such as gaps. Such gaps may decrease the strength of the joints, and cause parts, such as rails, to move slightly in relation to endplates where they are joined causing the boat to be tilted slightly or the endplates to be offcenter. This increases the magnitude of the true position (TP) of the endplates to each other, thus causing misalignment of the joints and rendering the wafer boat essentially useless for its intended purpose. This often results in the formation of cracks and breakage in the harsh conditions under which the article is used.
An increase in the TP affects the positioning of the article in semi-conductor wafer processing. For example, vertical wafer boats are positioned such that one endplate rests on a pedestal in the furnace. To achieve acceptable wafer processing the boats can not tilt in relation to the pedestal more than a few millimeters. TP values typically exceed 3 millimeters; however, TP values of 3 millimeters or less are sought, but are rarely and inconsistently achieved. Ideally the TP is 0.
Gaps also provide sites for the collection of contaminants prior to and during wafer processing. Cleaning processes often fail to remove such contaminants adequately before and after wafer processing, and ultimately result in contaminating and damaging semi-conductor wafers.
Dimensional tolerances may also be affected during application of adhesives between joints and any heating process, such as in the patent described above. Again, the strength of the joints joining the parts of the article together may be weakened resulting in flaws and cracks forming during use.
CVD-SiC is typically harder than the other types of silicon carbide. Accordingly, machining CVD-SiC parts is more difficult than machining the other types. More time and expense is required to achieve the tight tolerances desired at joints made of CVD-SiC.
Accordingly, there is a need for an improved chemical vapor deposited silicon carbide article and method of joining the parts of the article.
In one aspect an article includes at least two chemical vapor deposited silicon carbide parts joined together by sintered ceramics.
In another aspect an article includes a plurality of rods joined at opposite ends to respective endplates by sintered ceramics, the plurality of rods and the endplates are of chemical vapor deposited silicon carbide.
In an additional aspect an article includes a plurality of rods joined at one of their respective ends to a base of a backplate by sintered ceramic joints, opposite ends of the plurality of rods are joined to a support rail by sintered ceramic joints, the plurality of rods, the backplate and the support rail are of chemical vapor deposited silicon carbide.
In a further, aspect a method includes providing a paste, sol or slurry comprising one or more ceramics; applying the paste, sol, or slurry including the one or more ceramics to two chemical vapor deposited silicon carbide parts to join the parts; drying the paste, sol or slurry to form a dried composition comprising the one or more ceramics around the two chemical vapor deposited silicon carbide parts; and sintering the dried composition comprising the one or more ceramics around the two chemical vapor deposited silicon carbide parts to form a sintered ceramic joint.
In yet another aspect at least the sintered ceramics of the chemical vapor deposited silicon carbide article are coated with chemical vapor deposited silicon carbide.
The articles of chemical vapor deposited silicon carbide having parts joined together by sintered ceramics maintain tight tolerances during their assembly and prevent or reduce gap formation at the joints. The ceramics are applied as a slurry to the joints and form a seal around the joint parts preventing the gap formation. This prevents or reduces particle contamination of semi-conductor wafers during processing, reduces the difficulty in cleaning the articles, and increases the strength of the joints reducing the formation of flaws and cracks. Additionally, the TP of the articles are reduced at least at their most critical alignment position in contrast to many conventional articles composed of silicon carbide. Accordingly, mating parts do not have to be machined to tight tolerances.
FIG. 1 is a perspective view of a chemical vapor deposited silicon carbide wafer boat with rails secured to endplates by sintered ceramics;
FIG. 2 is a view of an endplate and rails secured to the endplate by sintered ceramics of a chemical vapor deposited silicon carbide wafer boat showing the teeth and grooves of the rails;
FIG. 3 illustrates a front view of a joint with a fillet radius;
FIG. 4 illustrates an open joint with a rectangular rod inserted into a port of an endplate;
FIG. 5 illustrates an open joint with a rod having a fissure at its base and an endplate which has three faces on each of its sides;
FIG. 6 illustrates another open joint with a rod having a wedge fissure and an endplate which has three faces on each of its sides;
FIG. 7 is a cross section of a closed joint showing the ceramic binder and a coat of CVD-SiC;
FIG. 8 Illustrates a front view of another embodiment of a closed joint and the location of the ceramic binder in the joint; and
FIG. 9 is a perspective view of a lifter for holding semiconductor wafers.
As used throughout this specification, the following abbreviations have the following meaning unless the context indicates otherwise: ° C.=degrees Celsius; mm=millimeters; cm=centimeters; 2.54 cm=1 inch; slpm=standard liters per minute; torr=pressure required to support 1 mm of mercury at 0° C.; 1 mm of mercury=0.00132 atmospheres (atm); 1 atm=1.01325×106 dynes/cm2; μm=micron; ppb=parts per billion; CVD=chemical vapor deposited; SiC=silicon carbide; RMS=root mean squared; OD=outer diameter; and TP=true position.
The term "true position" is defined as the perfect (exact) location of a point, line or plane (normally the center) of a feature in relationship to a datum reference feature. The term "monolithic" means a single solid piece of a material having a theoretical density of at least 98%. The term "joint" means an area at which at least two ends, surfaces or edges are attached. The term "joining" means to unify a plurality of parts.
All numerical ranges are inclusive and combinable in any order except where it is logical that such numerical ranges are constrained to add up to 100%.
Articles include at least two CVD-SiC parts joined together by sintered ceramics. Joints formed between CVD-SiC parts and sintered ceramics provide joints which are stronger than many conventional joints for articles made of silicon carbide, including CVD-SiC. Such joints can withstand the harsh conditions of semiconductor wafer processing, and have TPs of 3 mm or less. Additionally, the CVD-SiC and sintered ceramic joints enable assembly of the articles with increased dimensional tolerances without the formation of gaps in the joints, thus reducing the probability of damage to the articles under harsh semiconductor processing conditions.
Suitable CVD-SiC includes any CVD-SiCs known in the art. Typically, such CVD-SiC is high purity CVD-SiC with a total amount of metal impurities of 50 ppb, or such as 30 ppb or such as 10 ppb. Such CVD-SiC materials include, but are not limited to, β-crystalline CVD-SiC, α-CVD-SiC as well as CVD-SiC having mixtures of α and β-CVD SiC. This includes, but is not limited to, cubic β-CVD-SiC as well as β-CVD-SiC having cubic and hexagonal crystalline structures. Such CVD-SiC may be made by any suitable method known in the art and disclosed in the literature. Typically, the CVD-SiC is formed as a monolithic part. Such CVD-SiCs may have a theoretical density of at least 90%.
Typically the CVD-SiC used to make the parts of the articles is cubic P-crystalline SiC. Examples of methods of making cubic P-crystalline CVD-SiC are disclosed in U.S. Pat. No. 5,374,412 and U.S. Pat. No. 5,354,580. Gaseous reactants are deposited on a substrate, such as a mandrel, in a CVD furnace to form a monolithic cubic β-crystalline CVD-SiC part. Such methods provide cubic β-crystalline CVD-SiC which is pure cubic β-crystalline CVD-SiC as shown by X-ray diffraction analysis. No hexagonal crystalline structures are observable on an X-ray diffraction spectrum of such cubic β-crystalline CVD-SiC. Such cubic β-crystalline CVD-SiC has a theoretical density of at least 98%. Typically, the theoretical density is from 98% to 99%.
The CVD-SiC parts may be machined to provide a desired shape and roughness. Conventional machining may be used. Such methods are well know in the art and may be obtained by methods disclosed in the literature. Because higher dimensional tolerances are acceptable for the articles made by joining CVD-SiC parts together with sintered ceramic materials than conventional methods, less machining is done to match joining parts. This is highly desirable since CVD-SiC is a hard and difficult material to machine precisely. Typically, sections of the parts which make-up the joint are the least machined. Roughness and any protrusions from the surfaces of the joint sections are coated with sintered ceramics. Also, the roughness and protrusions increase surface area to further strengthen the joint. Average surface roughness Ra is from 0.2 μm to 5 μm. Rmax may range from 2 μm to 50 μm.
Any method for measuring surface roughness may be used. One suitable method is an autocovariance function. For a description of the application of an autocovariance function to the determination of surface topography, see Kiely et al., Quantification of Topographic Structure by Scanning Probe Microscopy, Journal of Vacuum Science Technology B, vol. 15, no. 4, July/August 1997, pp 1483-1493. Further descriptions of roughness parameters and methods of determining the values of these parameters are provided in Standard ASME B46.1-2002, Surface texture (Surface Roughness, Wavines and Lay), American Society of Mechanical Engineers, 2003. Typically, the directionality surface topography of the surface features are determined using atomic force spectroscopy (AFM) or an optical profilometer.
The methods may be used to join two or more CVD-SiC articles of various sizes and shapes. Such shapes include, but are not limited to, columnar shape, rod shaped, cylindrical shaped, plate shaped, sheet shaped, film shaped, square rod shaped, flat plate shaped, conical shaped, frustaconical shaped, pyramid shaped and rhomboid shaped. Joining may be carried out not only between parts of the same shape, but also between parts having different shapes.
Ceramic materials which may be used to form the joints of the articles include ceramics which enable the desired joint strength and dimensional tolerances. Such ceramic materials include, but are not limited to, silicon carbides, silicon nitride, various oxides and mixtures of the various oxides, including mixtures of the oxides with silicon carbide. Such oxides include, but are not limited to, oxides of aluminum, nickel, lanthanum, barium, zinc, lithium, cobalt, cadmium, cerium, chrome, antimony, iron, yttrium, tantalum, tungsten, strontium, calcium, bismuth, tin, manganese, magnesium, zirconium, titanium, lead, niobium and silicon.
Other suitable ceramics include, but are not limited to, raw mineral materials. Such raw mineral materials include, bur are not limited to, shale, stoneware, clay, bauxite, kyanite, bentonite, kaolin, pyrophilite, talc, feldspar, nepheline syenite, wollastonite, spodumene, flint (quartz), zircon, zirconates and corderite. Mixtures of such raw mineral materials may be used. The raw minerals may be mixed with one or more of the ceramic oxides, silicon nitride and silicon carbide.
The ceramics are applied to the joint in the form of a paste, sol or slurry. Conventional pastes, sols and slurries may be used as well as conventional methods of making them. The ceramics are included in conventional amounts. Typically, the ceramics are included in amounts of 20 wt % to 80 wt % of the composition.
In addition to one or more ceramics, pastes, sols and slurries include mixtures of such components as one or more binders, vehicles, plasticizers, dispersants, sintering aids and various conventional processing aids well known in the art. The amounts of each of the components are conventional and vary depending on whether it is a paste, sol or slurry. Amounts are well known to those of skill in the art.
Typically the binders are organic. Such organic binders include, but are not limited to, waxes, thermosetting resins, gums, polyvinyl alcohols, polyvinyl acetate, celluloses, polycarbosilanes, polyethylene glycols, thermoplastic resins and mixtures thereof. Typically, such binders are one or more of methyl cellulose, polyvinyl acetate, acrylic resins and dextrin. Binders may range in amounts of 0.5 wt % to 50 wt %.
Dispersing agents are used to distribute and suspend the ceramic materials. Such dispersing agents include, but are not limited to, polyacrylic acid, acrylic/maleic acid copolymer, lauryl sulfate, dodecylbenzenesulfonate, pyrophosphate and water-soluble salts, such as ammonium and alkali salts. Typically dispersing agents are used in amounts of 0.5 wt % to 10 wt % Plasticizers include both water-soluble and water-insoluble plasticizers. Such plasticizers include, but are not limited to, water, ethylene glycols, polyethylene glycols, glycerol, dibutyl phthalate, dimethyl phthalate and mixtures thereof. Typically, plasticizers are included in amounts of 1 wt % to 15 wt %.
Sintering aids typically include many of the organic compounds used as binders as well as other conventional organic sintering aids. Other sintering aids include, but are not limited to, inorganic compounds, such as boron carbide, Mg3N2, AlN and various oxides, such as MgO, CeO2, ZrO2, BeO, Y2O3 and La2O3. Typically, sintering aids are included in amounts of 0.5 wt % to 10 wt %.
Vehicles include water, organic solvents and mixtures thereof. Such organic solvents include, but are not limited to, dimethyl formamide, methoxyethanol, acetic acid, alcohols and glycols. Typically, the vehicles are aqueous. Sufficient amount of vehicle is added to the compositions to bring them to a desired volume and viscosity.
The components may be mixed using conventional apparatus. Mixing the components may be done at room temperature or may be heated to a sufficient temperature to uniformly disperse the components in the mixture and increase the ease of mixing the various components. The ceramic materials are used in powder or granular form and may be of any particle size which enables the formation of a uniform or homogeneous dispersion. Particle sizes are conventional. Typically, particle sizes range from 0.05 μm to 1000 μm, or such as from 10 μm to 500 μm or such as from 25 μm to 250 μm. As with the other components described above many of the particles are commercially available or may be made according to methods disclosed in the literature.
The paste, sol or slurry may be applied by any suitable means known in the art. Typically, they are applied to spaces between the parts which make-up the joint as well as covering the joint portions of the parts. The ceramic is applied with any suitable tool such as a brush or spatula. The ceramic is applied such that a smooth surface is formed without any gaps in spaces between the parts and covers any protruding parts. Any gaps may be coated with additional ceramic material and smoothed over. Such gaps may cause weak points in the joint resulting in misalignment of the article parts during handling and use. Two or more CVD-SiC parts may be joined with the ceramic paste, sol or slurry. If any of the parts of the joint do not match up, they may be covered with the ceramic material. Accordingly, the parts need not contact each other as in contrast to conventional articles which require tight tolerances. Accordingly, tight dimensional tolerances are not needed.
After the ceramic is applied it is dried at room temperature to form a dried composition. It is then sanded down to a smooth transition. Sanding may be done by any conventional method. Conventional grade sand paper may be used or any power sanding tool. Diamond tools having various grits may be used.
Conventional fixtures may be used to retain and align the two or more parts while the ceramic is applied. The parts are retained and aligned such that the TP for the most critical alignment is maintained at 3 mm or less, i.e. greater than 0, after sintering the joints. Typically, the TP for the most critical alignment is from 1.5 mm to 2 mm with a dimensional tolerance of +/−0.5 to 1 mm. For vertical wafer boats the most critical alignment is the TP of the top endplate and rails to the bottom endplate. For other articles, such as wet bench wafer carriers or lifters the critical dimensions are the perpendicularity of the rods to the backplate and the parallelism of the rods to each other. Any conventional method may be used to measure the TP of an article. Methods include, but are not limited to, coordinate measuring machines (CMM), FaroArm™ instrument, which is obtainable from Faro Technologies, Inc., laser tracker or other conventional 3-D measurement techniques.
Sintering may be done by any suitable method known in the art. Conventional methods may be used. In general, after the ceramic is applied to the joints, the article still fastened to the fixture is placed in a sintering furnace. The furnace is heated to a temperature of 1500° C. to 2100° C. Sintering is done for 30 minutes to 24 hours. Sintering drives off any moisture in the paste, sol or slurry containing the ceramic and carbonizes any organic binders and other organic material to solidify the joint. Additional examples of sintering methods which may be used to form the joint include, but are not limited, to those methods disclosed in U.S. Pat. No. 4,351,787, U.S. Pat. No. 6,065,615, Datta et al., Sintering of nano crystalline α silicon carbide by doping with boron carbide, Bull. Mater. Sci., Vol. 25, No. 3, June 2002, pp 181-189 and Zhou et al., Thermal conductivity of silicon carbide densified with rare-earth oxide additives, Journal of the European Ceramic Society 24 (2004) 265-270.
The sintered ceramic joint binding the two or more CVD-SiC parts has improved strength and stability over many conventional SiC joints whether from CVD-SiC or of the other types of SiC known in the art. The TP of the articles is maintained within a more narrow acceptable range than the TP of many conventional articles. Accordingly, the probability of large alignment error is reduced. This prevents gaps from forming in the joints, which weakens the joints, and reduces the probability of damage to the articles during handling and use under harsh conditions. Further, because the TP ranges are maintained from 3 mm or less, the difficulty of maintaining precise dimensional tolerances of +/−0.01 to 0.05 mm during manufacture is avoided.
Optionally, a coating of CVD-SiC may be deposited on at least the joints, but the entire article may be coated with a layer of CVD-SiC. The coating may have a thickness range of 0.5 mm to 3 mm. Typically, the thickness of the CVD-SiC coating may range from 1 mm to 2 mm. The CVD-SiC coating may be applied by any suitable method of depositing CVD-SiC known in the art. Examples of such methods are disclosed in U.S. Pat. No. 5,354,580 and U.S. Pat. No. 5,374,412.
Minor machining may be used to smooth and remove any undesired rough parts on the surface of the article after application of the CVD-SiC coating. Such minor machining does not alter the TP of the article significantly. Minor corrections may be needed to true up the article to provide the desired TP.
The types of articles which may be made by the methods include, but are not limited to, wafer boats, wafer carriers used in wet bench cleaning, furniture used in semiconductor processing chambers, optical telescope structures, optical benches and end effectors to hold wafers during loading and unloading.
FIGS. 1, 2 and 3 illustrate one embodiment of a wafer boat composed of monolithic CVD-SiC parts for holding a plurality of semiconductor wafers for semiconductor wafer processing. Wafer boat 100 includes a plurality of rods 112 inserted into ports at the sides of endplates 114. The rods 112 are secured to the endplates 114 by sintered ceramic joints 116. The sintered ceramic joints 116 as shown in FIGS. 1, 2 and 3 are closed joints. The endplates include holes 118 and 120 at their center for the passage of gases during semiconductor wafer processing. The sintered ceramic joints 116 form a concave fillet radius r at the junction of the plates and the rods. The fillet radius r has three faces 122. The sintered ceramic joints 116 have a 2 mm coating of CVD-SiC. The rods 112 include a plurality of teeth 124 with alternating grooves 126 for retaining semiconductor wafers.
FIGS. 1, 2 and 3 disclose one embodiment of the wafer boats. The wafer boats are not limited to the embodiment disclosed in the Figures. The number and the dimensions of the teeth and grooves may vary. Conventional machining techniques may be used to vary the number and dimensions of the teeth and grooves. Also, the holes are optional, and the number of rods may vary from 2 to 4. The wafer boats may have a joint which does not form a fillet radius at the junction of the rods and plates.
FIG. 4 illustrates one embodiment of an open joint of a wafer boat. The open joint 200 includes a rectangular rod 202 with four faces 204 of which only two are shown in the Figure. Rod 202 is inserted in port 206 of plate 208 such that it does not contact any of the three sides 210 of the port. The portion of the rod which is within the port has Ra of 0.05 μm to 0.5 μm. When the joint is completed, the open joint 200 is sealed with sintered ceramic material (not shown). The joint may be coated with CVD-SiC to provide further strength and durability to the joint.
FIG. 5 illustrates another embodiment of an open joint of a wafer boat. The open joint 300 includes a rectangular rod 302 with four faces 304 of which only two are shown in the Figure. The rectangular rod 302 has a base 306. The base 306 includes two concave fissures 308 on two opposing sides of the base. The concave fissures 308 extend along the length of the base and are perpendicular to the length of the rectangular rod. Each fissure 308 terminates at a flat surface 309 at a bottom portion of the base 306 of the rectangular rod. The rectangular rod is inserted into the port 310 at a side of endplate 312. The rectangular rod 302 is inserted into the port such that it does not touch the three sides 314 of the port 310. Each of the three sides 314 has three contiguous faces 316. The concave fissures and the three faces of the sides of the port increase the surface area of the joint, thus increasing the strength of the joint after the port is filled with sintered ceramic material to form the completed closed joint. Imaginary lines 318 illustrate where the ceramic material fills in the open joint 300. Optionally, the portions of the rectangular rod and sides of the port which are included in the joint may have a surface roughness of Ra from 0.05 μm to 0.5 μm.
FIG. 6 illustrates a further embodiment of an open joint of a wafer boat. Open joint 400 includes a rectangular rod 402 with four faces 404. Base 406 of rectangular rod 402 includes two wedge fissures 408 on opposite sides of the rectangular rod 402. Each wedge fissure 408 extends the length of the base 406 and is perpendicular to the length of the rectangular rod 402. Each wedge fissure includes two opposing faces, a top face 410 and a bottom face 412. Each face is joined at a common junction 414 opposite an opening of the wedge fissures. Each bottom fissure 412 terminates at a respective face 416 on each side of a bottom of base 406. The rectangular rod is inserted into port 418 of endplate 420 such that it does not contact any of the three sides 422 of the port of the endplate. Each side 422 has three contiguous faces 424. The open joint is filled with a paste, sol or slurry of ceramic material, dried and then sintered to secure the joint components. The wedge fissures and the faces of the sides which define the port increase the surface area where the ceramic material is applied to increase the strength of the joint. Optionally, the parts which compose the joint may be machined to have a roughness of 0.05 μm to 0.5 μm, which further strengthens the joint. The joint may be coated with CVD-SiC.
FIG. 7 is a cross section of a closed joint. The closed joint 500 includes a round rod 502 with a wedge fissure 504 having three faces, a top face 506, bottom face 508 and side face 510 where the top and bottom faces meet, the wedge fissure circumvallates the rod. The wedge fissure separates the main portion of the rod from its base 512. The round rod 502 is inserted in a port at a side of endplate 514. The rod does not contact the sides of the port. The port is defined by its three sides 516, two of which are shown in FIG. 7. Each side has three contiguous faces 518. The space between the rod and the sides of the port are filled with sintered ceramics 520. The entire joint as well as the rod and endplate are coated with a layer of CVD-SiC 322. A fillet radius r is formed at the junction of the rod and the endplate. Optionally, the portions of the rod which are included in the joint and the faces of the port may be machined to provide a roughness Ra of 0.05 μm to 0.5 μm.
FIG. 8 illustrates a further embodiment of a closed joint. This type of joint is found in the wet bench carrier or lifter as shown in FIG. 9. Closed joint 600 includes flat rod 602, which includes a port 604 near a base 606 of the flat rod 602 and two rectangular fissures 608 at the base 606 of the flat rod 602. The flat rod 602 is inserted into a backplate 610 in a backplate port which is filled with sintered ceramic 612 along with port 604 and rectangular fissures 608. Optionally, the parts composing the joint may be roughened to a desired surface roughness Ra, and coated with CVD-SiC.
FIG. 9 illustrates a wet bench carrier or lifter 700 for supporting semiconductor wafers during semiconductor wafer processing. Backplate 702 includes tooling holes 704 and 706 at an upper end of the backplate 702 for mounting the lifter on a mechanism which moves the lifter in and out of chemical solutions during wafer processing. Rods 708 and 710 are joined at one end to a base of the backplate 702 by sintered ceramic joints as shown in FIG. 8. Rods 708 and 710 include a plurality of alternating teeth 712 and gaps 714 for supporting semiconductor wafers (not shown). The rods are secured at ends opposite the backplate by a support rail 716, which is perpendicular to the length of the rods. The rail is joined to the rods by ceramic joints.
While the articles and joints have been described with typical embodiments, the articles and joint parts are not limited to the shapes described above, but are envisioned to include articles having parts of varying geometry. For example, endplates may not only be elliptical in shape, but polygonal such as rectangular and triangular. Rods may not only have two or four faces or rounded, but may have two or three or more faces. The rods, in general, are polygonal. Further, surfaces of the base of the rods and sides of the endplates which define the port are envisioned to include any protrusion which increases the surface area and further secures the joint when filled with sintered ceramic material.
The most critical alignment issue for wafer boats as described in FIGS. 1-7 is the TP of the endplates to each other. With respect to lifters, as described in FIGS. 8 and 9, the critical dimensions are the perpendicularity of the rods to the backplate and the parallelism of the rods to each other. Typically the TP is 2 mm or less with a dimensional tolerance of +/−0.5 to 1 mm. For example, when the wafer boat is a vertical boat, the TP is determined by measuring the position of the top endplate relative to the center line created by the bottom endplate using a FaroArm™ instrument. The instrument permits touching the boat at different locations and the different locations in space are calculated relative to a stationary point in space (reference point). The OD of the bottom plate and the bottom plate surface are measured to determine the center which runs through the center of the bottom plate and perpendicular to the bottom plate surface. The top plate OD is then measured and its center position relative to this center line is determined. The TP is then calculated by multiplying the distance by which the top plate is displaced from the center line by 2. Horizontal boats are measured by the same procedure as vertical boats. The horizontal boats are placed in a vertical position and the TP is determined by measuring the position of the top endplate relative to the center line created by the bottom endplate using a FaroArm™ instrument.
The following examples further illustrate the invention and are not intended to limit the scope of the invention.
Three types of joints were prepared to test their strength using a standard test method for testing the strength of joints. Two of the joint types included circular CVD-SiC endplates with corresponding rectangular CVD-SiC rods for insertion into the side ports of each endplate. The third type of joint was composed of circular sintered silicon carbide endplates and corresponding rectangular sintered silicon carbide rods for insertion into the side ports of the endplates. The CVD-SiC endplates and rods were made from a conventional CVD-SiC method and obtained from Rohm and Haas Company from its Advanced Materials business in Woburn, Mass., U.S.A. The sintered silicon carbide endplates and rods were made by a conventional sintering method with silicon impregnated in the sintered silicon carbide.
The first joint type was formed by inserting CVD-SiC rods into the ports of the CVD-SiC endplates to form a conventional male/female type joint. The tolerances were chosen such that a side gap between the rod and the port fell in the range of 0.01 to 0.05 mm. This gap was appropriate for capillary action to push molten silicon into the side gap.
Silicon powder was used to bind the joint components. The powder was purchased from Johnson Matthey (Asear). A small amount of the silicon powder was placed at the bottom of the plate in the port and the rod was inserted into the port. The assemblies were placed in one deposition box of a four-box production run. Conventional fixtures held the part together. The samples were heated to a temperature of 1360° C. in an argon atmosphere. Silicon carbide was deposited on the joints by passing a mixture of methyltrichlorosilane (MTS), hydrogen gas and argon through the deposition area. Deposition parameters were as shown in Table 1 below. Silicon carbide deposition continued until a coating of 2 mm was formed on the joints.
PROCESS PARAMETERS AMOUNT
Furnace Pressure 200 torr
Deposition Temperature 1360° C.
H2 gas flow rate 124 slpm
Ar gas flow rate 408 slpm
MTS gas flow rate 24.5 slpm
H2 gas partial pressure 44 torr
Ar gas partial pressure 147 torr
MTS partial pressure 9 torr
Deposition Rate 0.08 mm/hour
H2/MTS gas flow ratio 5
After deposition of the silicon carbide was completed, the deposition chamber temperature was increased to 1485° C. to bring the silicon to its molten state. The joints were maintained at 1485° C. for 0.5 hours. The deposition chamber was then allowed to cool down and the joints were removed from the chamber. All of the joints were then visually inspected for cracks. None of the joints showed any visible cracks or flaws. The joints were machined using 220 grit diamond impregnated grinding wheels and tools to form joints roughened to 0.5 μm RMS.
The second set of joints was prepared from slurries by mixing 75 wt % silicon carbide powder, 7 wt % methyl cellulose as a binder and 18 wt % water. The slurries were shaped in a gypsum mold by slip casting and then the shaped slurry was cut to obtain end palates and bars in a green body. An adhesive which was made from the same slurry used to prepare the joint parts was applied at the junction of the rods and the ports of the endplates. Assembly of the joints was done using a conventional fixture. Dimensional tolerances during assembly were maintained from 0.01 to 0.05 mm. The joints in their fixtures were than placed in a sintering furnace and fired for 60 minutes at 1800° C. to obtain sintered silicon carbide joints.
After sintering was completed the furnace was allowed to cool and the joints were removed and inspected. No flaws or cracks were visible. The joints were than machined using 220 grit diamond impregnated grinding wheel to form joints roughened to 0.5 μm RMS.
The third set of joints was formed by inserting CVD-SiC rods into ports of CVD-SiC endplates. The base of the rods and the sides of the ports were machined using 220 diamond impregnated grinding wheels such that the Ra was from 0.1 to 0.5 μm. The parts were aligned using a fixture such that the dimensional tolerances were from 0.1 to 0.5 mm. A silicon carbide slurry composed of 75 wt % silicon carbide, 7 wt % methyl cellulose and 18 wt % water was applied to the joints with a spatula. Excess was applied to the joints to fill in the spaces between the joint components and cover the portions of the rods and endplates which composed the joints. The slurry was smoothed around the joints to form a fillet radius. The slurry was allowed to dry at room temperature, and the dry composition was then sanded down to provide a smooth transition at the joints.
The joints, still in their fixtures, were placed in the sintering furnace. Sintering was done at 2000° C. for 24 hours. The furnace was then allowed to cool and the joints were removed from the furnace. No cracks or flaws were observed in the joints.
Graphoil™ masks (thin sheets of graphite) were then placed over the rods and endplates except at the joints, which remained exposed. The joints were then placed in the deposition chamber and coated with 2 mm of CVD-SiC. The deposition conditions and reactants were as disclosed in Table 1 above. After the chambered cooled the joints were removed and the CVD-SiC coatings on the joints were machined to an RMS of 0.5 μm using the 220 grit diamond wheel.
Each of the three types of joints was then placed in a standard Instron Mechanical Tester™ to test the amount of load the joints could tolerate before breaking. The endplate of each joint was secured into a fixture to hold the endplate with the rod protruding from the fixture horizontally such that the distance from the endplate to the point on the rod where the load (force) was applied was 2.5 inches (6.3 cm). The Instron Mechanical Tester™ head (load cell) was then set to move at a speed of 0.02 inches/minute (0.05 cm/minute) pushing down on the rod section. The load value in pounds and load rate (inches per minute) were recorded on a conventional chart recorder and the point at which the joint fractured was identified on the chart recorder and used to determine the load (force) on the rod that caused it to fracture.
The results showed that on the average the CVD-SiC coated joints with the parts joined by sintered silicon carbide were 35% stronger than the CVD-SiC coated joints with the molten silicon joints, and over 20% stronger than the joints composed entirely of sintered silicon carbide. Accordingly, the CVD-SiC coated joints with the CVD-SiC parts joined by sintered silicon carbide had improved strength over the conventional joints.
Three types of wafer boats distinguished by the types of joints which joined their parts were prepared from CVD-SiC to compare their TPs. The CVD-SiC parts were prepared by depositing silicon carbide on graphite mandrels having the appropriate shapes and sizes in a chemical vapor deposition furnace. The reaction components and parameters which were used were as disclosed in Table 2 below.
After the parts were formed on the mandrels, they were removed and machined using 220 grit diamond tools to remove any undesired rough surfaces formed during deposition and to shape the parts. The parts were then assembled to form three wafer boats each having a different type of joint assembly. Each boat included three rectangular rods joined at their opposite ends by endplates. All the boats were assembled in conventional fixtures to properly align their parts to desired dimensional tolerances.
The first type of boat had wedge joints to hold the rods to the endplates. Each rod was beveled at their ends and inserted in rectangular ports in the endplates. CVD-SiC wedges, which complement the beveled ends of the rods, are inserted on the opposite sides of the endplates to secure the rods in the endplates. After assembly small gaps were observed between the rods and the endplates at all of the joints
The second type of boat had rod ends which were inserted into complementary ports which opened at the side of the endplates. The rods were secured to the endplates by a CVD-SiC pin which was inserted into bores in the rods perpendicular to the lengths of the rods. Complimentary bores in the endplates enable the pins to pass through the bores in the rods and then into the endplates themselves to secure the rods to the endplates. After assembly small gaps were observed between the rods and the endplates at all of the joints.
The third type of boat had rod ends which were placed into side ports of endplates which were not complimentary to each other. The parts did not fit together such that the rods touched the sides of the ports as in the other two types of joints. There was open space between the rods and the sides of the endplates. The parts were secured in the joints by applying an excess of a slurry of 75 wt % silicon carbide powder, 7 wt % methyl cellulose and 18 wt % water. The entire joint was coated with the slurry and then smoothed to form a fillet radius around the joint. The slurry was allowed to dry at room temperature and then sanded down to make a smooth transition surface. The boat was then placed in its fixture in a sintering furnace and fired at 2000° C. for 24 hours. After the furnace cooled the boat was removed. No flaws, cracks or gaps were observed around any of the joints secured by sintered silicon carbide.
The TP of the endplates to each other of all three types of boats was determined using the conventional FaroArm™ 3-D measurement technique. In the measuring process each boat was treated as a vertical type wafer boat. The position of the top endplate was measured relative to the center line created by the bottom endplate. The OD of the bottom endplate and the bottom endplate surface were measured to determine the center which runs through the center of the bottom endplate and perpendicular to the bottom endplate surface. The top endplate OD was then determined and its center position relative to this center line was determined. The TP of the wedge joint boat was determined to be 5.10 mm, the TP of the boat with the pinned joint was 3.06 mm, and the TP of the boat with the sintered joint was 2.27 mm. The results showed that the sintered joint was 35% better than the pinned joint and 125% better than the wedge joint.
Further, no cracks, flaws or gaps were observed in the sintered joint as in the wedge joint and the pinned joint. The gaps observed in the joints of the wedge joint and the pinned joint enable the rods to move in relation to the endplates causing the boats to tilt or causing the endplates to be on different center lines. This in turn undesirably increases the TP of the boats as shown in the results above. Also, the gaps can cause misalignment during mounting, handling and heat up due to expansion of the rods and endplates. In contrast the boat with the sintered joint had no gaps. Accordingly, the TP is better and the probability of misalignment is reduced.
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Next Patent: METHODS OF JOINING STRUCTURES AND JOINTS FORMED THEREBY


So it has taken me about 10 years to get to this point in my life where I finally feel like ' I get it' with regard to food, health and nutrition. I don't purport to be an expert and I realise that everyone is different and our bodies react differently to food.
A friend of ours actually started on his Paleo journey early last year and I remember thinking he was crazy. "How can he give up gluten and all grain? He's not even a celiac! What about the wonders of wood fired pizza!!!" I said to Pete. Meanwhile, Dave was losing weight, getting fitter, feeling better and he had a certain glow and confidence about him that we all seemed to be lacking.
It's very easy to be resistant to things we don't understand or choose to ignore.
My road to good health has been a fairly long one, and I'm still on it. But, for the first time in a very long time I feel good, I have more energy, am no longer hungry between meals and I'm losing (my baby) weight.
As long as I can remember I have suffered with stomach pain, low platelets, and frequent and long lasting colds, flu & bronchitis.
The catalyst for change was a severe case of the flu where I literally couldn't get out of bed for several days. It was terrible. In the months ( and years) leading up to this point I had suffered through countless colds and my doctor could not offer any reason as to why I got them more than most. Not only did I get more colds than most but they lasted longer and often developed into secondary infections requiring antibiotics.
In my early 20's I started seeing a prominent Sydney dietitian - who not only cost me a small fortune, but after a series of tests, had me on a diet plan packed full of fibre, soy, lean meats and dairy. A healthy Thai takeaway (no curry) was also promoted and I'd often grab a stir fry on my way home from work or uni. I was actually quite fit at the time and was going to the gym at least daily sometimes twice and wanted to make sure I was eating the best I could for my body.
But my insides were struggling.
I would get up each morning, consult my expensive diet plan and have my bowl of All-bran or wholemeal toast, some low fat dairy or protein and a big glass of low fat soy milk and I'd head off to work or the gym. And whilst I looked pretty good on the outside, my insides began to rebel. I often had stomach pain so bad I would be doubled over in pain convinced that my appendix or gall bladder had burst.
After more tests including that for celiac disease - I was assured by my dietitian that I was on the right track and should continue on her plan. But things got worse. So much so that I ended up at the doctor one day crying in pain. An x-ray of my gut revealed a frightening image. My high fibre dietitian-endorsed diet was having the opposite effect.
After realising my dietitian wasn't helping, I decided to save my money and try and work it out myself. For years I was convinced coffee was to blame for some of my problems and so I went through periods of not drinking it. It didn't work though, I still got pain.
Busy working shift work and studying, I just battled through it.
Fast forward to 2011 and I went to my GP in tears and in pain begging for a solution. Blood tests revealed I had low platelets but nothing more and ultrasounds were all clear. He then sent me straight to an allergy and clinical immunology specialist.
Finally, I was getting somewhere.
After a series of specific food related tests I discovered I was allergic to soy and wheat products. This was my aha moment.
The specialist told me that most people have some level of wheat allergy mainly due to the highly processed grains we eat. She also told me that allergens can build up in our bodies for several days before symptoms present and therefore it can be hard to determine what is causing the problem without proper recording and testing.
I flashed back to years earlier when I trained with Steve Willis aka The Commando.
At the time, Steve told me that he avoided grain related carbs and instead preferred to get his carbs from vegetables and urged me to do the same.Whilst it wasn't referred to as Paleo back then, it is something which he strongly believed in - A good balance of protein, carbs from vegetables, healthy fats and some fruit. He also believed strongly in the success of the 80/20 rule - 80% comes down to what you eat and the remaining 20% relates to how you train and move. He also told me I should look at food as fuel for the body. I wish I had paid more attention to these principles back then.
I remember he told me that every now and again he would test his body - He told me of a time where he had dined out with his family at an Italian restaurant and had eaten pizza and pasta. He said it left him feeling heavy, bloated and depleted of energy for the next few days. I remember thinking that Steve was on to something but I was too young and busy (not disciplined) to really implement it. Instead I trained hard and ate some of the things Steve recommended and I lost weight and got pretty fit. I felt pretty good but still had pain and would get colds more frequently than most. I just put it down to shift work and being busy and kept going.
Getting influenza fuelled my interest and research. Enough was enough. Following on from what I had discovered through allergy testing, I had a chat with our friend Dave who directed me to some great podcasts, websites and general Paleo principles.
"In an (activated!) nutshell: the paleo way promotes the minimisation of sugary and starchy foods, moderation of protein intake, the liberal consumption of fibrous vegetables and greens (raw, lightly cooked and/or fermented/cultured), nuts, seeds, eggs (if tolerated) and as much dietary natural fat as needed to satisfy the appetite and support the brain and nervous system.
A small amount of seasonal fruit is optional.
The diet avoids grains, legumes, conventionally-raised meats, conventional dairy, non-organic produce, GMOs and processed foods.
We embrace 100 per cent organic, pasture-fed-and-finished meats, wild seafood from unpolluted waters, free-range poultry and pork (with no hormones or antibiotics), wild game (if available), organically-grown produce, nuts, seeds and healthy sources of natural fats" - Pete Evans.
I have been following these principles for a while now and feel the best I have ever felt. My choice to do so has been a means to heal my body from the inside. Once I started to investigate the the inflammatory effects grain and other foods can have on the body it all started to make sense. I am confident that this type of lifestyle best suits my body and I urge you to do your own research and hope you can join me.
In light of this new lifestyle, I'm excited to announce a new direction for this blog. The Food Mentalist will now examine the role of food on our health and include recipe favourites without gluten, grains, refined sugars or dairy. This new focus is great for those that follow Gluten-Free, Paleo, and Primal lifestyles. I hope this blog can help inspire you to get healthy and nourish your body. Even small changes can make a huge difference to our health and wellbeing.
I also urge anyone who suspects they may suffer from any form of food intolerance,allergy, related pain or reaction to go see a specialist like I did. There really is no need to suffer through it.
Welcome to the paleo trenches!
Great to hear you've had success with your health! So appalling to hear that the dietician's diet was making things worse too!


text:
Living Herstory
If you're a reader of this site, the odds are pretty slim that you're a fan of Hillary Clinton. But try for a moment to pretend that you believe the junior senator from New York is everything her supporters claim: a role model for our daughters, a tireless advocate for the dispossessed, the 21st-century equivalent of a Philosopher Queen. Then ask yourself: Would you still bother to read her book?
Now imagine — and this should be easier — that despite your better judgment you find yourself fascinated by the former first lady and her husband, their unbridled ambition, shameless lying, invincible self-righteousness, etc. Then ask yourself: Would you still bother to read her book?
Thanks to the diligence of the Associated Press, we now know the most startling revelations in Mrs. Clinton's forthcoming memoir, Living History:
* That for seven months in 1998, Bill Clinton pretended to his wife that the Monica Lewinsky story wasn't true.
* That when he told her the truth on August 15th of that year, she was "furious," "could hardly breath" and "[gulped] for air." (The quotations in the AP story suggest that what outraged her wasn't the confession of adultery but the news that "he would have to testify" about it.)
* That on a subsequent vacation to Martha's Vineyard, the first couple slept apart, and the "only member of our family" willing to keep the president company was the dog.
* That she "wanted to wring Bill's neck."
This is electrifying stuff, particularly the last bit, which ought to be grounds for a Secret Service investigation. But while readers may have been dying to know all this, now they know it for free. What possible reason could they have to cough up $28 and trudge through 562 pages about the noble lost cause of a national health plan, the insignificance of Whitewater, and the courageous decision to ban smoking from the White House?
Even readers intrigued by these topics must realize that Living History will merely reiterate the Clinton party line on them all. While political obsessives will read the book as a preview of Hillary's 2008 presidential campaign, surely most Americans can wait. Journalists and librarians will feel obliged to order it, but that's not the route to the bestseller lists.
So why did Simon & Schuster pay $8 million for Mrs. Clinton's book? The firm has been in business a long time, so let's assume they know what they're doing. Of course they don't care whether anyone actually reads the thing; they just want people to buy it. And there are millions out there who buy books for the same reason they give money to political parties and candidates — to make a statement and support a cause. If they fulfill the publisher's expectations for this title, we'll be reading a lot more about Hillary Clinton in the next few years, whether we like it or not.

redpajama_set_name: RedPajamaCommonCrawl


Andrew Todd is available through the company to provide on-site examination, conservation assessments and treatments as well as conservation training workshop planning for on-going maintenance. Examinations, assessments and consultations are undertaken directly for clients and reports are always provided. More extensive reports, planning and treatment, including teams for treatment, can be provided.
© Andrew Todd Conservators Ltd.


Mitzvot As Spiritual Practices: Enthusiastic Actions That Bring Us Together!
According to Rashi, the language "Tzav," is intended to indicate that relating to mitzvoth must be by acting with alacrity (ziruz), immediately and for eternity.
"Tzav" is derived from the word "tzavta," which means team, togetherness, and associated with "hitchabrut," a permanent and everlasting connection. We are meant to accelerate the pace and quality of serving Hashem through mitzvot and join with the Shechina, the Source of our Soul, as long as we are alive! The Chassam Sofer refers us to the quote in Devarim 4:4: "You that did cleave unto Hashem your G-d are alive every one of you this day." The fascinating use of words is reflected in the Hebrew word, "deveikim," meaning the cleaving and uniting of Jews with Hashem; the word "devek," in Modern Hebrew means glue. Our efforts toward this end will ensure our being inseparable.
Herein lies the secret of true bonding and an enduring relationship.
No matter how much we want to hear the bells and see the fireworks, the surest and most certain way to promote and achieve a loving union is through continuous passionate actions that are done with alacrity and with enthusiasm.
Hashem draws us b'tzavta, together, through the myriad and diverse mitzvoth (commandments) that shape our lives and guide our every move. We "glue ourselves" to Him by constantly fulfilling His commandments and wishes, consciously and enthusiastically.
This constant doing and desire to know Him and adopt His ways will result in the attachment of Myself to Him. Actions, the Mitzvot are Spiritual practices that promote and cultivate the process of bonding and unification.
This is a life long endeavor. As the Sefer Hachinuch tells us: our hearts follow our actions! Rav Dessler wisely points out that we love those to whom we give, and not as is commonly thought, that we give to those whom we love. It's the investment of myself that creates my love for another.
Similarly, the relationship so sought after between a man and a woman is a life long endeavor entailing a lot of work, investment of time, energy and vigor. We must never feel that we hit the "homerun" (after marriage) and can now sit back and relax.
The fact that I don't feel "this is the one" after a couple of dates is only natural. The ongoing investment has not yet been made; the time has not been spent. The commitment to be involved in continuous "doing" for another has not been proven with the test of time. Loving and caring is an ongoing process that increases the more I give and invest in the other. It is not magic!
In Shmoneh Esrei two of Hashem's attribures teach us a great lesson: first we say: "boneh Yersushalayim" and then "matzmiach yeshua." First comes the deliberate building, brick by brick, day by day, followed by the evolution and process of redemption.
This notion is reinforced with one of the sheva brachot: wishing the couple to build a binyan adei ad, that the (building) marriage last forever; alternatively, the building can be understood as a verb: the work of building is never-ending.
Hashem can bring redemption instantaneously, but He chooses not to in order to teach us the value of slow and painstaking steps that are part of the process of reaching closeness and unity.
As my dear friend and teacher Esse Chasin A"H said in her book, Mitzvot as Spiritual Practices: "The mitzvoth offer health and happiness-a silver platter of goodies that are Hashem's menu…the key to the gate of harmony, your way of keeping friends and treasuring relationships." Correspondingly, the term "Tzav" alludes to the enthusiastic deeds that we ought to devote to a relationship, which in turn empowers and nurtures it, joining two partners for eternity!
Sherrie is the SawYouAtSinai 'Article of the Week' writer as well as a dedicated SYAS matchmaker. Trained as an educational guidance counselor, group leader, pre-marital coach, matchmaker and Judaic Studies teacher, Sherrie is dedicated to promoting and enhancing emotional intelligence and communication skills in conjunction with Torah values.
Choices of the Heart, a preparation and enrichment program for nearly-wed and newly wed couples, run by Sherrie Miller, focuses on teaching communication skills between couples, using Jewish wisdom and Torah sources. The workshops offer tools to build skills and realistic goals that empower young couples with on their way to establish a Jewish home.
Having counseled singles and made a number of successful matches resulting in marriage, Sherrie volunteers as a matchmaker for SawYouAtSinai.


There is no sure way to good health than a glass of fresh fruit juice. Especially if it's made with the sleek and stylish Prestige juicers. Build to save you time, space and energy, its wide mouth lets you feed whole and semi-cut fruits into it, while the pulp separator allows you to juice non-stop. Surprise your family and friends with a tray full of juice, served in minutes.
Key Features : Large Capacity, Wide mouth, Advanced design sieve, detachable puple collector for continous juicing, Thermal over-load protector • 300 watts heavy duty motor.


text:
The New York and Long Island Traction Company was a street railway company in Queens and Nassau County, New York, United States. It was partially owned by  a holding company for the Long Island Rail Road and partially by the Interborough Rapid Transit Company. The company operated from New York City east to Freeport, Hempstead, and Mineola.

Lines
The railroad had two main lines.

Mineola Line
The Mineola Line (now the Nassau Inter-County Express n24 bus route) spanned from Queens Village to Mineola (in Nassau County) along Jamaica Avenue.

Brooklyn-Freeport Line
The Brooklyn-Freeport Line spanned from Brooklyn to Freeport (also in Nassau County) and ran mostly along Rockaway Boulevard, North Conduit Avenue, Atlantic Avenue and Merrick Road. The  route was mostly replaced by the Q7 and Q85 (operated by MTA Regional Bus Operations) and n4 (operated by Nassau Inter-County Express).

References

Streetcar lines in Queens, New York
Streetcar lines on Long Island
Defunct public transport operators in the United States
Defunct New York (state) railroads
Companies affiliated with the Long Island Rail Road
Predecessors and affiliates of the Interborough Rapid Transit Company

Railway companies disestablished in 1926

redpajama_set_name: RedPajamaWikipedia


College offers hostel facility for students but most of the students opt for shared flat/ PG. Living in Mumbai and that too in Vile Parle is bit expensive. Cost of living changes as per everyone's lifestyle but on an average, we can safely assume 20-25k/ month including accommodation, food, and all other expense. Canteen facilities at NMIMS are excellent and you will definitely get healthy and good food at our canteen. Quality of classrooms and labs, libraries, WiFi is excellent.
There are a total of 3 hostels with the most expensive accomodation at Rs 2.05 Lakhs per year.
The other option is to take a shared flat with individual expense at Rs 12-15k per month.
The food in college is decent with good hygiene. It costs roughly Rs 120 per meal.
The classes and other infrastructure is top notch.
The PGs outside college and the flats nearby are decent enough. However the rents of 2bhk and above are on the higher side.
Food in college is pretty awesome tastewise.The food provided is very hygenic.However the rates of some of the snacks are on the higher side.
The quality of classrooms,labs ,libraries, wifi are nice. The atmosphere is very encouraging for one who wants to learn and do well in his or her respective field.
One thing which ASMSOC at NMIMS really lags behind is the campus, if you can call it that. Being in Mumbai which is a supremely crowded city, SVKM (the parent group behind NMIMS and other colleges) has put a number of colleges within the same building. My building personally had 5 colleges, the most famous of which was Mithibai College.
There are two girls hostels which are pretty good and are situated within a 10-15 minutes walkin from college. They're situated in pretty safe areas, and the warden and security are always on alert. From what I have heard from my friends, the boys hostel may need some work to reach their level.
I personally rented an independent flat with some of my friends. The flat renting culture is pretty established in Mumbai, and most students choose to do that. Be warned however, that Mumbai real estate prices are super high. No decent 2 BHK will come under Rs. 40,000 per month.
The quality of classrooms which we did have was top notch. Air conditioned, with proper benches, white boards and projectors.
Infrastructure of NMIMS Mukesh Patel School of Technology, Management and Engineering is really niche above the rest. Recently constructed building adds to its fresh looks. Amazing classrooms with ultra modern facilities are the highlights of this college. Entertainment rooms equipped with a high end table tennis table, a carom board and a relaxing zone. Highly informative library is one more of the college's various goodies. Great place for a 2 night 3 day stay (Haha! But it's true).
Thankfully, the college has hostel facilities which are equally top notch. Since the college has over whelming response from all over the country, the hostel service is definitely a blessing in disguise for the non Mumbaikars.
NMIMS Mukesh Patel School of Technology, Management and Engineering has an excellent canteen which caters to the needs of all the taste buds. From Pav Bhaji to South Indian,Chaat to Chocolcate Milk Shakes, Lunch Plate to Chinese, Rolls to Parathas and mouthwatering lassis, lime water, cadburys and candies - the canteen has it all (still not satisfied? Go die!). And the best part is that the prices are dirt cheap while the quality is five star. Extremely spacious. Most of the students have their meals in the canteen followed by students of neighbouring SVKM insitutes who are seen in huge numbers. Parathas and a variety of juices are renowned. Great options among desserts are also available.
MPSTME has another canteen on the 8th floor of the building which serves more or less the same quality and quantity and hosts around 80 to 100 people at a time.
NMIMS provides separate hostels for both boys and girls.
The hostel facility includes two hostels and three rented residential accommodations.
Admission of the students will be done on first come first serve basis.
The preferences will be given to students from outside of Mumbai.
The hostel also provides mess facilities for the students.
The food is prepared by highly trained professional chefs.
NMIMS provides a well furnished and air-conditioned library.
It has a collection of more than 42000 volumes and has subscribed to 308 Indian and Foreign periodicals.
It also a collection of 521 video's, 319 audio's 187 CD's, 274 VCD's, annual reports and management games.
They also provide news clippings, newsletters and case studies for the students.
The open access system facilities free use of books on the shelf.
NMIMS provides laboratories with well-equipped equipment for the students.
It has a laboratory for Computer Engineering, Chemical Department, IT Department, Pharmacy Department and Science Department.
NMIMS provides air-conditioned classrooms with audio-visual like LCDs mounted in the ceiling.
The classrooms can accommodate around 60 students at a time.
How is the infrastructure/facilities of the college?
The college i well equiped with facilities for students.
All classrooms in the University are air-conditioned and have ceiling mounted LCDs. Most classrooms have a capacity of 60. In addition, the University has a well equipped seminar hall and a conference hall.
The Computer center is equipped with branded personal computers adequately supported by 3mbps shared leased line for Internet connectivity. It is also equipped with a wide range of licensed system software and applications software. The entire campus is connected with Wi-Fi network.
The well furnished and air conditioned NMIMS library has a stock of more than 42,000 volumes and subscribes to about 308 Indian and Foreign periodicals spanning all aspects of management. The library also houses 521 video's, 319 audio's, 187 CD's, 274 VCD's, annual reports, management games, news clippings, newsletters and case studies.
The library is a member of BCL (British Council Library), AIRC (American Information Resource Centre), BMA (Bombay Management Association), MANLIBNET (Management Library Network), AVEHI (Audio Video Edu Resource Centre), Advance Standard Council of India and ECCH (European Case Clearing House Ltd).
NMIMS houses a state-of-the-art Management Development Programme (MDP) hall.
NMIMS has pioneered the initiative of scientifically assisting students in preparing for Group Discussions or Job Interviews by developing an Audio Interactive Language Lab on the campus. This move is mainly directed towards making the students display the right internal personality driven message to their recruiters during a corporate placement, group discussions or interviews.


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Game Vs. Giants: CB Asante Samuel
On how he felt seeing the ball on the ground after picking the fumble: "That was the worst feeling ever. That was the first time I ever did that. And I can't do that anymore. When the defense gets the ball, we've got to keep it. That could have been deadly for the game.'
On getting more balls coming his way tonight: "Yes. Eli is a competitor and he's got some great receivers so he was confident and we're just going to go out there and compete."
On how it feels to have four interceptions against the Mannings: "It was awesome for me. I know they're competitors. I've got a lot of respect for those guys. They're Pro-Bowlers, Hall of Famers, one of them and one making his way, so it's a lot of respect. We're going to compete; we're going to play them again so it's another chance to compete."
On whether getting the ball comes naturally to him: "I work on this. This is all I focus on in the off-season. I've got my trainer and I've got my guys out there. We do drills and all we focus on is making plays doing your drills and making sure you go get the ball wherever it's at."
On why this defense seems more effective now than earlier in the season: "It could be a lot of things. We're clicking better, we've got a couple of fill-ins. I think we're just clicking better, calls are being made right, we're making plays and everybody's getting aggressive."
On how the defense managed to create so many turnovers tonight: "Like I said, we put pressure on the quarterback, try to get him off balance and off his rhythm. If you stop their running in the beginning, you make them one-dimensional and that's the most important thing. We pretty much did that for the most part. I think they had 202 total yards so it was a good job by the defensive linemen."
On what gives them momentum out of a bye week: "I think Andy (Reid) does a good job in practice keeping us fresh, keeping us motivated, not overdoing things. At the end of the day, he just wants us to come out on Sunday and be fresh, fly around, be fast as you can be and have fun. I think that's got a lot to do with it."
On how important it was for the defense to play strong when the buzz has been about Michael Vick and the offense: "Well, it's a team. Vick can't go out there and put 60 points up every game, 300 yards and six touchdowns. That's just not going to happen so it's a team thing. The defense stepped up tonight and we've got to continue to do that. The one thing I can say is that Vick sustains guys a lot. They keep the defense off the field. We're on the sideline a whole lot of the time so when we're ready to come back out, we're refreshed and ready to go."
On how he knows what the receiver will run: "I use my technique and I go what I was coached by since college. I had a good coach in Gene Chizik, who is at Auburn now. He taught me a lot. I just stick by my technique and it's what I work on every day in the off-season and in practice. It's something I try to master."
On whether he knows what the receiver is doing off the line: "No, it's technique. He has to run his route. The quarterback has to throw it to him. So, I'm looking at him and the quarterback so I'm timing the quarterback's throw and I'm timing the route so it's a combination of both."
On whether you got dinged when you wrapped up the tight end: "When I wrapped him up and I came down, my head landed on his knee. It just made me a little dizzy, but nothing major."
On whether the team is in a better position for the rest of the season because of their division wins: "When you keep winning the division wins, that's most important. We've got a couple more games. We have Dallas two times, we play the Giants one more time so we've got to keep chopping at the wood, not get complacent, go to practice and play hard."
On how it is to play with Michael Vick: "That's like anything. I didn't know him that well when he was in Atlanta. I didn't know his practice habits and all that but I can tell you now that he is a professional. He comes to work everyday and tries to perfect his game. He is a leader. He's yelling at people, telling them to get their stuff together, his offense and himself. Like I said, he is a professional and a leader and we're going to ride it behind him."
On how tough it was to see Hobbs down: "It was tough."
On whether he was surprised that Eli (Manning) did not slide when he was down: "I didn't really know what he was going to do. I didn't know if I should try to hit him or not and he dove forward. I just tried to stay off of him."


The Central Sunset is a great place to live, and the neighborhood offers homes that are affordable by San Francisco standards, although prices have been heading upwards precipitously in the past few years.
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WHAT IS YOUR FOUNDATION? If it is Faith, then faith in what?
Faith in men or yourself is a fools game. You will fail and your fellow man's power is limited to help you. On top of that how many people are really willing to lend you a hand when something goes slightly wrong? How about terribly wrong? Likely far less than you think. People have their limits both in compassion and resources.
Faith in an all powerful God is not a fools game. His power is unlimited. Unlimited power to orchestrate the things of this world to meet your physical and spiritual needs in his perfect timing. Additionally, his willingness to respond does not depend on the size of your problem. There are no "big problems" to God, they are all small in his eyes. He owns everything and loves us individually. What a great combination.
Get in the boat. Do your part. Have Faith!


Ramp up with the Pawn Stars when a Line Drive Pinball Machine bumps into the shop. Will Corey get the high score, or will it be game over? Then, don't count Rick out when he checks out an 1895 Morgan Dollar. Known as the "King of all Morgan Dollars," will it be worth every penny or will this coin break the bank? And later, when Chum takes over a shift at Corey's new bar, will he use this opportunity to call the shots or will it be closing time?


If you have ever longed to add a touch of shimmering personalization to your clothing, look no further than Silver Bow Sequin Iron-On Applique. This patch features shiny silver sequins in the shape of a large bow. Position it on a jacket, bag, or other chosen material, iron it on, and create a fashionable look that showcases your unique personality!


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