In order to synthesize a PPy/GO composite for supercapacitor applications, a pulse electro-polymerization method was proposed to direct incorporate graphene oxide (GO) into polypyrrole (PPy) films without any additional dopants. The PPy/GO prepared by the pulse electro-polymerization (PC PPy/GO) exhibits a higher specific capacitance. A shorter pulse on time (t on) results in higher specific capacitance, but there is an optimum pulse current amplitude (I A) related to the highest specific capacitance. The PC PPy/GO film (I A =4mAcm−2, t on =50ms) has a high specific capacitance of 660 F g−1 estimated from galvanostatic charge-discharge in 1M KCl at a current density of 0.5mAcm−2. Stability tests for the PPy/GO yield long cycling life up to 1000 cycles with 10% decay in specific capacitance at charge-discharge current density of 10mAcm−2 in the potential range of -0.5 to 0.5 VSCE.