The all-solid-state Li–In/Li4Ti5O12 cell using the 80Li2S·20P2S5 (mol%) solid electrolyte was assembled to investigate rate performances. It was difficult to obtain the stable performance at the charge current density of 3.8mAcm−2 in the all-solid-state cell. In order to improve the rate performance, the pulverized Li4Ti5O12 particles were applied to the all-solid-state cell, which retained the reversible capacity of about 90mAhg−1 at 3.8mAcm−2. The 70Li2S·27P2S5·3P2O5 glass–ceramic, which exhibits the higher lithium ion conductivity than the 80Li2S·20P2S5 solid electrolyte, was also used. The Li–In/70Li2S·27P2S5·3P2O5 glass–ceramic/pulverized Li4Ti5O12 cell was charged at a current density higher than 3.8mAcm−2 and showed the reversible capacity of about 30mAhg−1 even at 10mAcm−2 at room temperature.