Personal exposure to particulate matter of aerodynamic diameter under 2.5 μm (PM2.5) was monitored using a DustTrak nephelometer. The battery-operated unit, worn by an adult individual for a period of approximately one year, logged integrated average PM2.5 concentrations over 5 min intervals. A detailed time-activity diary was used to record the experimental subject’s movement and the microenvironments visited. Altogether 239 days covering all the months (except April) were available for the analysis. In total, 60 463 acceptable 5-min averages were obtained. The dataset was divided into 7 indoor and 4 outdoor microenvironments. Of the total time, 84% was spent indoors, 10.9% outdoors and 5.1% in transport. The indoor 5-min PM2.5 average was higher (55.7 μg m−3) than the outdoor value (49.8 μg m−3). The highest 5-min PM2.5 average concentration was detected in restaurant microenvironments (1103 μg m−3), the second highest 5-min average concentration was recorded in indoor spaces heated by stoves burning solid fuels (420 μg m−3). The lowest 5-min mean aerosol concentrations were detected outdoors in rural/natural environments (25 μg m−3) and indoors at the monitored person’s home (36 μg m−3). Outdoor and indoor concentrations of PM2.5 measured by the nephelometer at home and during movement in the vicinity of the experimental subject’s home were compared with those of the nearest fixed-site monitor of the national air quality monitoring network. The high correlation coefficient (0.78) between the personal and fixed-site monitor aerosol concentrations suggested that fixed-site monitor data can be used as proxies for personal exposure in residential and some other microenvironments. Collocated measurements with a reference method (β-attenuation) showed a non-linear systematic bias of the light-scattering method, limiting the use of direct concentration readings for exact exposure analysis.