Carbon coated flower like Bi2S3 on nickel foam are simply fabricated by a solvothermal synthesis method accompanying with glucose as a precursor of subsequent carbonization. The architectures are directly used as electrodes for electrochemical hydrogen and Li-ion storage. Such architectures display high electrochemical hydrogen storage and the discharging capacity of 165mAhg−1 is obtained. When used as anode material, the binder free Bi2S3@C/Ni electrode delivers superior cycling stability and rate capability. Discharge capacity reaches as high as 698mAhg−1 after 50 cycles at a current density of 100mAg−1. Even at 1000mAg−1, the capacity still remains at 510mAhg−1 after 40 cycles. The superior performance can be ascribed to the unique electrode. The porous electrode gives more reaction sites and accommodates volume change during cycling; while the carbon shell improves electronic conductivity and suppresses particle aggregation.