Active carbon@La2NiO4/NiO hybrid coatings are synthesized using different molar ratios of La/Ni to improve the electrochemical performance of active carbon materials. The morphology and microstructure of the composites are investigated via scanning electron microscopy (SEM), X-ray diffraction (XRD), and high-resolution transmission electron microscopy (HRTEM). Cyclic voltammetry (CV), galvanostatic charge/discharge test (GCD), and electrochemical impedance spectroscopy (EIS) are performed to characterize electrochemical performance. At a molar ratio of La/Ni 1:2, the electrochemical electrode shows that the resistance of the composite is 2.97Ω, which is half of that in pure active carbon. The highest energy density of 70.37Whkg−1 is obtained at a current density of 1Ag−1, whereas the highest power density of 32.4kWkg−1 is achieved at a current density of 10Ag−1. The CV results present a high specific capacitance of 710.48Fg−1 at a scan rate of 1mVs−1 in 7M KOH aqueous solution.