In this work, a simple and effective method to activate graphite felt (GF) electrode by using KOH as etching agent is studied for vanadium flow battery (VFB) application. The surface of GF is etched by KOH at 800°C to generate micropores and attain oxygen-containing functional groups, resulting in greatly improved electrolyte accessibility. Surface morphology, oxygen distribution and microstructure of the KOH etched graphite felts (eGFs) are characterized by SEM, EDX, XPS, XRD and Raman techniques. Due to the abundant exposed edge carbon sites and oxygen-containing functional groups introduced by KOH activation, electrochemical activity of eGFs towards both VO2+/VO2 + and V2+/V3+ redox couples are remarkably improved comparing with GF. In particular, eGF-2 (mass ratio of KOH/GF=1.25) exhibits the best electrochemical activity and VFB performance among all eGFs. Moreover, the VFB with eGF-2 electrode can run at current density up to 250mAcm−2 with the energy efficiency of 64%. Long-term cycle life test at higher current density of 150mAcm−2 confirms the outstanding stability of eGF-2 electrode.