Several studies have investigated the health of children attending schools located near busy roads. In this study, we have measured personal exposure to traffic-related pollutants in children to validate exposure classification based on school location. Personal exposure to PM2.5, soot, NO x and NO2 was measured during four 48-h periods. The study involved 54 children attending four different schools, two of which were located within 100m of a major road (one ring road and one freeway) and the other two were located at a background location in the city of Utrecht, The Netherlands. Outdoor monitoring was conducted at all school sites, during the personal measurements. A questionnaire was administered on time activity patterns and indoor sources at home. The outdoor concentration of soot was 74% higher at the freeway school compared to its matched background school. Personal exposure to soot was 30% higher. For NO x the outdoor concentration was 52% higher at the freeway school compared to its background school. The personal concentration of NO x was 37% higher for children attending the freeway school. Differences were smaller and insignificant for PM2.5 and NO2. No elevated personal exposure to air pollutants was found for the children attending the school near the ring road. We conclude that the school's proximity to a freeway can be used as a valid estimate of exposure in epidemiological studies on the effects of the traffic-related air pollutants soot and NO x in children.