Strontium (Sr)-doped perovskite oxide La1-xSrxMnO3 (x=0, 0.2, 0.6) composites are prepared by sol-gel process assisted with chelating effect of citric acid, which was used as catalysts for oxygen cathode in rechargeable lithium−air batteries. Sr-doped perovskite oxide La1-xSrxMnO3 composites demonstrate higher catalytic activities than that of the pure LaMnO3. In particular, the La0.4Sr0.6MnO3 had a lower total over potential between the oxygen evolution reaction (OER) and the oxygen reduction reaction (ORR) than that of the La0.8Sr0.2MnO3 and LaMnO3 .When the Li-O2 cells were tested at the current density of 50mAg−1, the discharge capacities of the oxygen cathode with different La1-xSrxMnO3 (x=0, 0.2, 0.6) catalysts were 3573, 4408, and 5624mAhg−1，respectively. Additionally, the cell employed La0.4Sr0.6MnO3 as catalyst can be cycled at a limited capacity of 200mAhg−1 for about 71cycles, which is much higher than the 42 cycles for LaMnO3 electrode.