Radioluminescence (RL) characterization of the yttrium stannate (Y2Sn2O7) phosphors doped with 1mol% Tb, Eu and Dy was carried out and significant electronic transitions corresponding to doped rare earth ions were observed. It was seen that all parts of these rare earth ions are included in the phosphor material in their trivalent state. The RL measurement indicates that the series of the emission-state 5D4→7F6, 5D4→7F4, 5D4→7F3, corresponding to the characteristic 4f→4f intra-configuration forbidden transitions of Tb3+are appeared and that main emission peak occurs at about 542nm. There are in fact multiple emission lines at each of these due to the crystal field splitting of the ground state of the emitting ions. Eu-doped Y2Sn2O7 sample displayed intense and predominant emission peaks located at 580−650nm corresponding to the 5D0→7Fj (j=l, 2, 3 and 4) transitions. Red emission coming from the hypersensitive Dy doped phosphor presented luminescence emissions with dominating transitions at 4F9/2→6Hj (j=9/2, 11/2, 13/2 and 15/2). The sharp emission properties show that the Y2Sn2O7 is a suitable host for rare-earth ion doped phosphor material.