ZnMn2O4/C nanoparticles are synthesized by one step polyol assisted pyro-synthesis for use as the anode in rechargeable lithium ion batteries without any post heat treatment. The as-prepared ZnMn2O4/C is tetragonal with a spherical particle size in the range of 10–30nm. Electrochemical measurements were performed using the as-prepared powders as the active material for a lithium-ion cell. The nanoparticle electrode delivered an initial charge capacity of 666.1mAhg−1 and exhibited a capacity retention of ∼81% (539.4mAhg−1) after 50 cycles. The capacity enhancement in the as-prepared ZnMn2O4/C may be explained on the basis of the polyol medium that enables to develop a sufficient carbon network that can act as electrical conduits during electrochemical reactions. The carbon network appears to enhance the particle-connectivity and hence improve the electronic conductivities.