In this work, carbon-coated lithium-ion intercalated compound LiTi2(PO4)3 and MnO2 have been synthesized and they deliver a capacity of 90 and 60mAh/g in 1M Li2SO4 neutral aqueous electrolyte within safe potentials without O2 and H2 evolution, respectively. The novel hybrid supercapacitor in which MnO2 was used as a positive electrode and carbon-coated LiTi2(PO4)3 as a negative electrode was assembled and the LiTi2(PO4)3/MnO2 hybrid supercapacitor showed a sloping voltage profile from 0.7 to 1.9V, at an average voltage near 1.3V, and delivers a capacity of 36mAh/g and an energy density of 47Wh/kg based on the total weight of the active electrode materials. It exhibits a desirable profile and maintains over 80% of its initial energy density after 1000 cycles. The hybrid supercapacitor also exhibit an excellent rate capability, even at a power density of 1000W/kg, it has a specific energy 25Wh/kg compared with 43Wh/kg at the power density about 200W/kg.