In the past decade, long-term sorption and thermochemical heat storage has generated lot of interest. This paper presents the state of the art in this field of research, materials used in these systems and technological difficulties that researchers are set against. An emphasis is put on recent demonstrative projects including absorption and adsorption for long-term solar energy storage. It emerges that considerable breakthrough have been made. Even though there is no mature long-term sorption or thermochemical energy storage yet, primarily due to the high cost of materials, the suitability of this technology to long-term storage remains its main power of attracting.