In this paper, the nano-sized Ag particles were coated on the surfaces of the spinel LiMn2O4 nanoparticles through a one-step combustion method. It was shown that the rate performance and cycling performance of LiMn2O4 could be effectively improved by the appropriate amount of Ag (5wt%) not only at room temperature (25°C) but also at high temperature (55°C). This was because the Ag particles dispersed on the surface of LiMn2O4 had dramatically increased its electronic conductivity. Definitely, the electrochemical performance of the Ag-coated LiMn2O4 particles at 55°C was not as excellent as that at 25°C. Besides, the Ag-coated LiMn2O4 displayed much better cycling performance at higher C-rates (2C and 5C) at 55°C, compared with that at lower C-rate (0.5C). This was because Ag was just dispersed rather than being densely coated on the surface of LiMn2O4, so the dissolution of LiMn2O4 at 55°C could not be completely inhibited by Ag. Moreover, the dissolution of LiMn2O4 at 2C and 5C at 55°C was much weaker than that at 0.5C, caused by the faster transformation between Mn3+ and Mn4+. As a result, the electrochemical performance of LiMn2O4 could be enhanced by the Ag-coating at high temperature.