Abstract Climate change mitigation requires the development of new processes to reduce the amount of carbon dioxide in the atmosphere. The products of CO2 utilization can supplement or replace chemical feedstocks, fine chemicals, pharmaceutical, and polymers. Carbon capture and utilization based on innovative electroreduction processes is one of the suggested routes to reduce the use of coal and oil as carbon sources due to the recycling of carbon. Some chemicals may be produced using carbon dioxide, decreasing the use of natural resources. The electrocatalytic processes to obtain formate and methanol as derived products from CO2 are discussed in this chapter, taking into account the electro-catalysts and the reactor design in the development of innovative processes.