β-FeOOH thin film was prepared on the surface of a foamed Ni substrate by liquid phase deposition (LPD) method with a chemical equilibrium reaction between metal-fluoro complex and oxyhydroxide to make a low-cost and environmentally friendly positive electrode for high-power batteries. The new film electrode, with a thickness of 316nm, was found out to give a large discharge capacity of 260mAhg−1 at 0.05C rate even without an electro-conductive material. Furthermore, the electrode also showed good discharge performance with the retention of 69.9% at 10–0.05C current rate, which means a promising positive active material for high-power use.