Fe2O3-reduced graphene oxide (RGO) composites were successfully fabricated via a facile microwave-assisted reduction of graphite oxide in Fe2O3 precursor solution using a microwave system, and investigated as anode material for sodium ion batteries (SIBs). Their morphologies, structures and electrochemical performance were characterized by transmission electron microscopy, X-ray diffraction, Raman spectroscopy, cyclic voltammetry and electrochemical impedance spectroscopy, respectively. The results show that the RGO addition can enhance the electrochemical performance of Fe2O3-RGO composites. Fe2O3-RGO composite with 30wt.% RGO exhibits a maximum reversible capacity of 289mAhg−1 at a current density of 50mAg−1 after 50 cycles and excellent rate performance due to the synergistic effect between Fe2O3 and RGO. The high capacity, good rate capability and excellent cycle performance of Fe2O3-RGO composites enable them a potential electrode material for SIBs.