The preparation and the structural, morphological and electrochemical characterization of a Silicon/V2O5 nanosheets composite (Si@V2O5), as an active anode material for Li-ion batteries, are here reported. The nanocomposite material, aimed at mitigating the morphological instability issues commonly plaguing Si-based anodes, is prepared by a H2O2-based low-impact synthesis, while the electrode processing involves the use of Polyacrylic Acid (PAA) binder. The electrolyte formulation is optimized as well, by employing Vinylene Carbonate (VC) additive, in order to maximize cycling stability and performance. Preliminary results report specific capacities of 932 mAhg−1 and 759 mAhg−1 after 50 cycles at 500 mA g−1 and 1000 mA g−1, respectively. The Si@V2O5 electrode also shows remarkable rate capability performance.