The difference in capacitive performance between high and low surface area RuO2 electrodes, synthesized with and without a mesoporous silica template, respectively, was investigated in aqueous solutions of sulfuric acid and sulfates by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). RuO2 synthesized with the template was crystalline and the formation of the mesoporous structure with a 6.5nm diameter was confirmed using a transmission electron microscope and the nitrogen adsorption and desorption isotherm. From the CV at the scan rate of 1mVs−1, the specific capacitance of the high surface area electrode in H2SO4(aq) was determined to be 200Fg−1. The high surface area RuO2 has a three times higher BET specific surface area (140m2 g−1) than the low surface area sample (39m2 g−1). Introducing the mesoporous structure was proved effective for increasing the capacitance per mass of the RuO2, though not all the surface functions as a capacitor. Both the CV and EIS suggest that by increasing the charging rate or frequency, the mesoporous structure of the electrode leads to a lower capacitance decrease (higher capacitance retention) than the low surface area electrode. The EIS also indicates that the response time of the capacitor is hardly influenced by the presence of the mesoporous structure.