This work aims to study the reasons for the rapid capacity fading in the field of lithium-sulphur batteries. It is found that the formation of non-soluble and insulating lithium sulphide, Li2S, upon sulphur reduction is one of the main reasons to account for the capacity fade due to its relatively low electrochemical activity and blocking of the carbon framework. A variety of analytical techniques are used to assess the formation of Li2S and visualize the resulting morphological changes in a mesoporous carbon/sulphur composite (MCS) during battery operation. It is shown that simply changing the cut-off voltages can alter retention and resistance of the cells during cycling. Since the electrochemical activity of lithium polysulphides decreases with the order, elimination of low order of polysulphides is considered critical. Thus, in order to oxidize the least sulphur reduction specie, Li2S, two different additives are suggested; namely an electrolyte additive, LiI, or an electrode additive, V2O5. Incorporation of the one of these components into the MCS composite enables the delivery of higher capacities (i.e. as compared to a bare C/S composite). The increased capacity is linked not only to the co-cathode materials, which contribute to the total capacity, but also to the oxidizing agent and internal redox mediator role of the additives.