 A poly(ortho toluidine-co-aniline)/SiO2 nanocomposite electrode (Poly(oT-co-ANI)/SiO2) was fabricated in one step using electrodeposition polymerization. The polymer layer was characterized using UV–Vis spectroscopy, FTIR spectroscopy, and SEM/EDX. The electrochemical performance of the nanocomposite electrode was tested in 1 M H2SO4