FeF2-reduced graphene oxide nanocomposite is in-situ synthesized and assembled into electrode with poly (acrylic acid) binder as a novel sodium ion cathode, which exhibits greatly improved electrochemical performance. The mechanism for the improved performance of the electrode is studied by ex-situ morphology and phase analysis, before and after cycling. The results show that poly (acrylic acid) binder with high adhesion ability can stabilize the electrode structure, thus increase the utilization of active materials. The in-situ hybridization of FeF2 nanoparticles with reduced graphene oxide can confine the sizes of particles, and restrain the particles agglomeration. As a result, the electrode can attain high capacity and stability. The electrode exhibits superior electrochemical performance: high capacity of 175 mAh g−1 at 0.2 A g−1, high rate capability of 78 mAh g−1 at 10 A g−1, and good cycling stability. The results demonstrate the electrochemical performance of metal fluoride electrode can be enhanced by using highly adhesive materials as binders and the nanostructure construction.