The electrochemical performances of (LiMn0.6Fe0.4PO4/C)//LiV3O8 ARLB in different aqueous electrolyte, i.e. 0.5M Li2SO4, 2M Li2SO4, saturated Li2SO4 with pH value of 7, 2M LiNO3, 5M LiNO3, saturated LiNO3, saturated LiNO3 with pH value of 7, are studied. The results infer that (LiMn0.6Fe0.4PO4/C)//LiV3O8 ARLB in 5M LiNO3 or saturated LiNO3 aqueous electrolyte with pH value of 7 has favorable specific capacity and rate performance. According to the energy density calculations, the electrochemical performance of (LiMn0.6Fe0.4PO4/C)//LiV3O8 ARLB in the saturated LiNO3 with pH value of 7 is better than that in 5M LiNO3 solution.