Plug-in Electric Vehicles (PEVs) provide new opportunities to reduce fuel consumption and exhaust emission. PEVs need to draw and store energy from an electrical grid to supply propulsive energy for the vehicle. As a result, it is important to know when PEVs batteries are available for charging and discharging. Furthermore, battery energy management and control is imperative for PEVs as the vehicle operation and even the safety of passengers depend on the battery system. Thus, scheduling the grid power electricity with parking lots would be needed for efficient charging and discharging of PEV batteries. This paper aims to propose a new intelligent battery energy management and control scheduling service charging that utilize Cloud computing networks. The proposed intelligent vehicle-to-grid scheduling service offers the computational scalability required to make decisions necessary to allow PEVs battery energy management systems to operate efficiently when the number of PEVs and charging devices are large. Experimental analyses of the proposed scheduling service as compared to a traditional scheduling service are conducted through simulations. The results show that the proposed intelligent battery energy management scheduling service substantially reduces the required number of interactions of PEV with parking lots and grid as well as predicting the load demand calculated in advance with regards to their limitations. Also it shows that the intelligent scheduling service charging using Cloud computing network is more efficient than the traditional scheduling service network for battery energy management and control.