Carbon-dispersed LiFePO4 materials were routinely prepared by heating metal-salt-containing pastes of organogels to temperatures at 300 and 700°C to benefit the intrinsic conductivity, and we ultimately discerned the optimized carbon content, 4.55wt%. Carbon doping will decrease tap density of prepared cathode material and then bring about electrode preparing difficulty, so we tried different kinds of organogels to make out the densest carbon composite. They were polyacrylamide (PAM), sugar and phenolic resin. The most excellent pyrolyzed PAM paste was found increasingly electrochemical reversible, exhibiting 113.2mAh/g at C/6 and 95mAh/g at C/3. And we found a good cycliability of 95mAh/g at 0.2mAcm−2 at room temperature. Seen from atomic force microscopy, this composite was far more different from other pyrolyzed pastes in morphology, which contained judicious designed hiberarchy and highly dispersed nanoparticles. Decreased 2θ in XRD spectra also showed the varied cell parameters, though no exact figures of the varied cell parameters could be given due to a potential existence of an unknown second phase with electrochemical activity.