With increasing interest in energy storage and conversion devices for automobile applications, the necessity to understand and predict life behavior of rechargeable batteries, PEM fuel cells and super capacitors is paramount. These electrochemical devices are most beneficial when used in hybrid configurations rather than as individual components. A system model helps us to understand the interactions between components and enables us to determine the response of the system as a whole. However, system models that are available predict just the performance and neglect degradation. The objective of this research is to provide a framework to account for the durability phenomena that are prevalent in fuel cells and batteries in a hybrid system. Toward this end, the methodology for development of surrogate models is provided, and Pt catalyst dissolution in proton exchange membrane fuel cells (PEMFCs) is used as an example to demonstrate the approach. Surrogate models are more easily integrated into higher level system models than the detailed physics-based models. As an illustration, the effects of changes in control strategies and power management approaches in mitigating platinum instability in fuel cells are reported. A system model that includes a fuel cell stack, a storage battery, power-sharing algorithm, and dc/dc converter has been developed; and preliminary results have been presented. These results show that platinum stability can be improved with only a small impact on system efficiency. Thus, this research will elucidate the importance of degradation issues in system design and optimization as opposed to just initial performance metrics.