All solid-state sheet lithium battery was developed using inorganic solid electrolyte, thio-LISICON (Li3.25Ge0.25P0.75S4), Li–Al anode, and Mo6S8 cathode materials, and the sheet manufacturing process was established. The new sheet-configuration was consisted of the cathode with the grid of current collector, electrolyte sheet with or without mechanical support, and aluminum/lithium composite sheet anode. A sheet battery with a dimension of 30mm×30mm showed good charge–discharge characteristics without any capacity fading at a current of 0.1mA.