The tubular and layered structure of titanate nanotubes facilitate ion movement and provide a high rate capability. Moreover, expansion of the material can enhance its performance. In this study, regular titanate nanotubes and expanded titanate nanotubes were synthesized. To expand the nanotubes, dodecylamine were used under hydrothermal conditions. SEM, TEM, BET, and XRD were utilized to characterize these materials. In addition to that, electrochemical characterizations like cyclic voltammetry, rate capability, and cycle stability tests were made to understand the effect of titanate expansion on Li-ion electrode performance. After the expansion, the d-spacing increased from 8.1Å to 9.5Å and parallel to that, the specific surface area reached to 297m2 g−1 from 204m2 g−1. Cyclic voltammograms had broad peaks and suggested a pseudocapacitive character; which is common for titanate nanotubes. Sloping potential-capacity profiles also supported this character. The first discharge capacity of regular nanotubes was 823mAhg−1. However, after the expansion, it increased to 1017mAhg−1. Above all, both of the nanotubes had superior rate capabilities and stabilities due to their high aspect ratios. Moreover, dodecylamine created a protective layer on the titanate surface and enhanced the stability. Finally, it was realized that the expansion of the structure is crucial and enhances the electrode performance.