Vanadium oxide prepared by plasma-enhanced chemical vapor deposition was cycled in different voltage ranges in a lithium battery. Electrochemical cycling results show a surprisingly low irreversibility during the first discharge and good stability for close to 1000 cycles between 4 and 0V. Raman spectroscopy results indicate that a major structural transformation takes place when the films are cycled down to 1.8V, after which the structural features remain intact even after cycling to 0V. Degradation of the electrode only occurs after extended cycling.