The effect of δ-Al2O3 nanoparticles (size∼10nm) on the ionic conductivity and related properties of a solid polymer electrolyte (SPE) that consists of low molecular weight (M w=2000) poly(ethylene) glycol (PEG) complexed with LiClO4 is studied in detail using XRD, DSC, TPD, NMR, and complex impedance methods. The maximum ionic conductivity σ=7.3×10−7 Scm−1 observed for pristine (PEG)46LiClO4 is found to be dependent on the content of δ-Al2O3 filter; it shows a peak value of σ=4.5×10−6 Scm−1 for 10mol% filler. This is nearly an order of magnitude enhancement of the ionic conductivity and is found by DSC studies to be related to a decrease in the crystalline regions in the SPE, while the glass transition temperature T g and the melting temperature T m remain essentially unchanged. 7Li NMR motional narrowing points to an increase in the effective mobility of the lithium ions on doping with the nanoparticles. The temperature dependence of σ can be divided into two regions, one consistent with the Arrhenius behavior and the other with the Vogel, Tamman and Fulcher equation. The activation energy is found to be the lowest for the 10mol% doped sample. It is concluded that doping with nanoparticles leads to an enhancement of conductivity due to a decrease in the crystallinity and the activation energy, as well as to an increase in the effective mobility of Li ions.