In order to improve the discharge capacity in lithium ion microbatteries, a thick-film cathode was fabricated by a screen printing using LiCoO2 pastes. The printed cathode showed a different discharge curves when the cell was tested using various (liquid, gel and solid-state) electrolytes. When a cell test was performed with organic liquid electrolyte, the maximum discharge capacity was 200μAhcm−2, which corresponded to approximately 133mAhg−1 when the loading weight of LiCoO2 was calculated. An all-solid-state microbattery could be assembled using sputtered LiPON electrolyte, an evaporated Li anode, and printed LiCoO2 cathode films without delamination or electrical problems. However, the highest discharge capacity showed a very small value (7μAhcm−2). This problem could be improved using a poly(vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) gel electrolyte, which enhanced the contact area and adhesion force between cathode and electrolyte. The discharge value of this cell was measured as approximately 164μAhcm−2 (≈110mAhg−1). As the PVDF-HFP electrolyte had a relatively soft contact property with higher ionic conductance, the cell performance was improved. In addition, the cell can be fabricated in a leakage-free process, which can resolve many safety problems. According to these results, there is a significant possibility that a film prepared using the aforementioned paste with screen printing and PVDF-HFP gel electrolyte is feasible for a microbattery.