The complex (2,2-dimethyl-1,3-propanediaminebis(salicylideneaminato))–nickel(II), [Ni(saldMp)], was oxidatively electropolymerized on activated carbon (AC) electrode in acetonitrile solution. The poly[Ni(saldMp)] presented an incomplete coated film on the surface of carbon particles of AC electrode by field emission scanning electron microscopy. The electrochemical behaviors of poly[Ni(saldMp)] modified activated carbon (PAC) electrode were evaluated in different potential ranges by cyclic voltammetry. Counterions and solvent swelling mainly occurred up to 0.6V for PAC electrode by the comparison of D 1/2 C values calculated from chronoamperometry experiments. Both the Ohmic resistance and Faraday resistance of PAC electrode gradually approached to those of AC electrode when its potential was ranging from 1.2V to 0.0V. Galvanostatic charge/discharge experiments indicated that both the specific capacitance and energy density were effectively improved by the reversible redox reaction of poly[Ni(saldMp)] film under the high current density up to 10mAcm−2 for AC electrode. The specific capacitance of PAC electrode decreased during the first 50 cycles but thereafter it remained constant for the next 200 cycles. This study showed the redox polymer may be an attractive material in supercapacitors.