The Ca3(PO4)2 coating was attempted to improve the oxygen evolution of Ni(OH)2. The Ca3(PO4)2 and Co(OH)2 coated Ni(OH)2 was prepared by coating of Ca3(PO4)2 on the surface of Ni(OH)2, followed by coating of Co(OH)2 on its surface. The cyclic voltammetry analysis showed that the oxygen evolution potential increased after the coating both at room temperature and 60°C, indicating that the coating could effectively enhance the oxygen evolution potential in the charge process. The difference between oxygen evolution potential and oxidative potential increased from 26mV to 47mV at 60°C, leading to the improvement of charge acceptance at 60°C.