Non-spherical Li(Ni1/3Co1/3Mn1/3)O2 powders have been synthesized using a two-step drying method with 5% excess LiOH at 800°C for 20h. The tap-density of the powder obtained is 2.95gcm−3. This value is remarkably higher than that of the Li(Ni1/3Co1/3Mn1/3)O2 powders obtained by other methods, which range from 1.50gcm−3 to 2.40gcm−3. The precursor and Li(Ni1/3Co1/3Mn1/3)O2 are characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM). XPS studies show that the predominant oxidation states of Ni, Co and Mn in the precursor are 2+, 3+ and 4+, respectively. XRD results show that the Li(Ni1/3Co1/3Mn1/3)O2 material obtained by the two-step drying method has a well-layered structure with a small amount of cation mixing. SEM confirms that the Li(Ni1/3Co1/3Mn1/3)O2 particles obtained by this method are uniform. The initial discharge capacity of 167mAhg−1 is obtained between 3V and 4.3V at a current of 0.2C rate. The capacity of 159mAhg−1 is retained at the end of 30 charge–discharge cycle with a capacity retention of 95%.