Poly(2,5-di-(2-thienyl)-furan) (PSOS) was synthesized via anodic polymerization of 2,5-di-(2-thienyl)-furan (SOS) in ethanol solution containing 0.2M LiClO4 as supporting electrolyte. The electrochemical and spectroelectrochemical properties were investigated using electroanalytical and UV–vis spectroscopic techniques, respectively. The band gap of the polymer film was found as 2.22eV and the film was successfully switched between black oxidized state and orange neutral state. Fluorescence and electrochemical impedance spectroscopy (EIS) studies were also performed.