Low-frequency geoelectrical methods include mainly self-potential, resistivity, and induced polarization techniques, which have potential in many environmental and hydrogeological applications. They provide complementary information to each other and to in-situ measurements. The self-potential method is a passive measurement of the electrical response associated with the in-situ generation of electrical current due to the flow of pore water in porous media, a salinity gradient, and/or the concentration of redox-active species. Under some conditions, this method can be used to visualize groundwater flow, to determine permeability, and to detect preferential flow paths. Electrical resistivity is dependent on the water content, the temperature, the salinity of the pore water, and the clay content and mineralogy. Time-lapse resistivity can be used to assess the permeability and dispersivity distributions and to monitor contaminant plumes. Induced polarization characterizes the ability of rocks to reversibly store electrical energy. It can be used to image permeability and to monitor chemistry of the pore water–minerals interface. These geophysical methods, reviewed in this paper, should always be used in concert with additional in-situ measurements (e.g. in-situ pumping tests, chemical measurements of the pore water), for instance through joint inversion schemes, which is an area of fertile on-going research.
