The Republic of Kiribati, formerly known as the Gilbert Islands, is a Micronesian (One of the three groups of islands in the Pacific. The eight territories that make up Micronesia are Commonwealth of the Northern Mariana Islands, Federated States of Micronesia, Republic of Kiribati, Republic of the Marshall Islands, Republic of Nauru, Republic of Palau, Territory of Guam and Territory of Wake Island. The other two groups of islands in the Pacific are Melanesia and Polynesia) country in the Pacific. The energy sources utilised in Kiribati include petroleum products, biomass, solar energy and wind power. Solar energy was introduced in Kiribati in the early 1980s (Wade H. Survey of RESCO projects – prepared for OPRET, Fiji Department of Energy, 2003; p. 36). Currently, it makes a very insignificant (less than 1%) contribution to the total annual primary energy supply (South Pacific Regional Environment Programme (SPREP). Pacific Islands Renewable Energy Project (PIREP) – Pacific Regional Energy Assessment (PREA) 2004. Kiribati national report, Vol. 5, 2005). Solar energy in Kiribati is used mostly in the form of solar photovoltaic (PV) technologies for the provision of lighting and electricity. This study examines the role of PV technologies in the sustainable development process in Kiribati, with particular reference to remote atoll communities. Initial results from on-site surveys carried out are reported in this paper. These surveys have sought to identify the reasons why people use or do not use PV systems.