An optimization of the specific capacity exhibited by the best layered lithiated cobalt nitride Li2.20Co0.40N is proposed by using a conditioning electrochemical oxidation up to 1.1V before cycling in the 1.1V–0.02V potential range. This initial charge process allows the Co3+/Co2+ redox couple to be involved in the cycling process in addition to the Co2+/Co+ couple as in the 1V–0.02V voltage range. A new electrochemical fingerprint is obtained with a single step at 0.4/0.8V for the discharge-charge process and a specific capacity of 300mAhg−1 at C/5 which constitutes a huge improvement compared to 130mAhg−1 recovered in the conventional 1V–0.02V potential window. This high capacity value and the excellent capacity retention of 100% over at least 75 cycles make Li2.20Co0.40N a promising anode material for Li-ion batteries.