The rational design of cathode host materials is significant in fulfilling high-efficiency sulfur electrochemistry as well as boosting the energy density of lithium–sulfur (Li–S) batteries. Herein, we develop a stringed “tube on cube” nanohybrid (CPZC) with a ternary hierarchical architecture, which contains a fibrous carbon skeleton, highly porous carbon cube filler, and abundant CNT tentacles as an advanced matrix for sulfur electrodes. The as-developed CPZC delivers excellent conductivity, abundant active interfaces, and strong confinement to polysulfide, and thus is capable of significantly expediting the sulfur redox kinetics and promoting battery durability. The fabricated sulfur electrode achieves a superb rate capability up to 10C, outstanding cyclability over 2000 cycles, and more importantly, excellent performance under high a sulfur loading and sparing electrolyte with a high energy density of 348.8 W h kg−1 and 327.6 W h L−1 at the system level, which reveals its potential in promoting the practical application of Li–S batteries.
