Wet ball-milling route is employed to prepare sulfur-carbon nanotubes composites. The influences of solvents, including ethanol and chloroform, on the structure and electrochemical performance of the composites are firstly investigated. As compared to the conventional dry-milling process, high loose structure and uniform distribution of sulfur can be obtained by adding ethanol during the ball-milling process, and significant enhancement of electrochemical performance is presented. At the current density of 800mAg−1, the discharge capacity can be stably retained at 861.6mAhg−1 after 150 cycles for the composite prepared by adding ethanol, showing obvious advantages over the dry-milling sample and the composite prepared by adding chloroform. When the current density increase to 1600mAg−1, it can still demonstrate a high reversible capacity of 640.9mAhg−1 after 200 cycles. Furthermore, the influence of ball-milling speed is also investigated, but a low utilization of sulfur active materials is obtained after high-energy ball milling process.