Herein, we present a new strategy for the mass production of high-quality reduced graphene oxide (RGO) with a surface area of 354 m2 g−1 using high pressure hydrogen as a reducing agent under hydrothermal conditions. The high pressure used is solely generated from the packing of the gas cylinder itself and a pressure meter could simply fulfil the role of monitoring pressure. The reduction process is green without chemical wastes produced. Comparing to other reported methods, the significant advancements of our strategy lie not only in the high-quality RGO with high C/O ratio, conductivity and surface area, but also in the most environment-friendliness and cost-effectiveness, which make the large scale fabrication feasible. Moreover, clean noble metal nanocrystals such as Pt could be easily in situ deposited onto the surface of RGO nanosheets when noble metal salts are introduced into the system. In particular, the prepared RGO and Pt/RGO show exceptional electrochemical performances in supercapacitors and lithium oxygen batteries because of their clean electrochemical surface, good conductivity and large surface area. Our results reveal that the obtained RGO have a specific capacitance of 884.4 F g−1 at a current density of 0.5 A g−1, and the Pt/RGO electrode can deliver discharge–charge capacities of 1000 mAh g−1 for 40 cycles with a high round-trip efficiencies of 74.9% at 50 mA g−1 when used as Li–O2 battery electrodes.