We evaluated poly(acrylonitrile-methyl methacrylate) (AMMA, AN/MMA=94:6) as a binder for the graphite anode and the LiMn2O4 cathode of Li-ion batteries by studying the cycling performance of lithium half-cells. The results showed that, using AMMA binder, both graphite and LiMn2O4 could be cycled well in 1m LiPF6 3:3:4 (weight) PC/EC/EMC electrolyte with less capacity fading. AMMA is chemically more stable than poly(vinylidene fluoride) (PVDF) against the lithiated graphite. More importantly, AMMA can help graphite to form a stable solid electrolyte interface (SEI) film. An impedance study showed that the SEI film formed with AMMA is more stable than the one formed with PVDF. Therefore, self-delithiation of the lithiated graphite can be reduced by use of AMMA instead of PVDF, which improves the storage performance of Li-ion batteries.