LiCoPO4, a high voltage cathode material, was synthesized by supercritical solvothermal method at 400°C for 4min of reaction time. The synthesized plate like particles showed 50–200nm in width, 100–300nm in length and side length from 5 to 15nm. The single phase of pristine particles was confirmed by powder X-ray diffraction analysis; the morphology and size were investigated by transmission electron microscopy. The use of oleylamine played a vital role in designing the plate like morphology. The electrochemical property was investigated for carbon coated plate like LiCoPO4 cathode by galvanostatic charge–discharge method. The carbon coated LiCoPO4 particles exhibited 130mAhg−1 for the first cycle and 98mAhg−1 for the 10th cycle. The capacity fade was observed with cycle performance and rate performance was also investigated.