In this study, novel electrolyte mixtures for Li-ion cells are presented which are composed of ethylene carbonate/dimethyl sulfone (80:20 wt./wt.) as a solvent mixture and LiPF6, lithium bis(oxalato)borate and lithium difluoro(oxalato)borate as conducting salts. The main advantages of the solvent mixture are high flash points of >140 °C which enhance the intrinsic safety of Li-ion cells while maintaining good cell performance above 0–5 °C. The movability of the lithium ions in the electrolyte is investigated via programmed current derivative chronopotentiometry. It is found that pure electrolyte properties cannot necessarily predict the electrolyte behavior in real Li-ion cells but the complex interplay between electrolytes, electrode materials and separators has to be taken into account. Using the newly developed electrolytes, it is possible to achieve C-rates up to 1.5C with >80% of the initial specific discharge capacity (25 °C). Within 200 cycles during one month in cell tests (C||NMC) it is proven that the retention of the specific capacity is >98% of the third discharge cycle in dependence of the conducting salt.