A thermal management system is necessary to control the operating temperature of the lithium ion batteries in battery packs for electrical and hybrid electrical vehicles. This paper proposes a new battery thermal management system based on one type of phase change material for the battery packs in hybrid electrical vehicles and develops a three dimensional electrochemical thermal model. The temperature distributions of the batteries are investigated under various operating conditions for comparative evaluations. The proposed system boils liquid propane to remove the heat generated by the batteries, and the propane vapor is used to cool the part of the battery that is not covered with liquid propane. The effect on the thermal behavior of the battery pack of the height of the liquid propane inside the battery pack, relative to the height of the battery, is analyzed. The results show that the propane based thermal management system provides good cooling control of the temperature of the batteries under high and continuous charge and discharge cycles at 7.5C.