An organic template assisted synthesis was developed to obtain highly ordered porous LiFePO4 cathode material. The developed synthesis enabled the use of polystyrene (PS) as template by modifying its surface with a surfactant (Brij 78) to render it hydrophilic. The material was synthesized in high yield and purity as confirmed by X-ray powder diffraction. The TEM and SEM images clearly confirmed the presence of a highly ordered porous structure and the latter showed that the structure has an average pore diameter of 400nm and a wall thickness and depth of ∼100nm. Thermal scans and elemental analysis showed that the material contains a high amount of carbon reaching 23–28% by weight. The surface area was calculated using the BET method and found to be 7.71m2 g−1. Li/LiFePO4 half cells were tested and gave satisfactory discharge capacities; an initial capacity (158mAhg−1) close to the theoretical value and recoverable capacities at high C-rates (2–5C).