The penetration of renewable sources into the grid, particularly wind and solar, have been increasing in recent years. As a consequence, there have been serious concerns over reliable and safety operation of power systems. One possible solution, to improve grid stability, is to integrate energy storage devices into power system network: storing energy produced in periods of low demand to later use, ensuring full exploitation of intermittent available sources. Focusing on stand-alone photovoltaic (PV) energy system, energy storage is needed with the purpose of ensuring continuous power flow, to minimize or, if anything, to neglect electrical grid supply. A comprehensive study on a hybrid stand-alone photovoltaic power system using two different energy storage technologies has been performed. The study examines the feasibility of replacing electricity provided by the grid with hybrid system to meet household demand. In particular, this paper presents first results for photovoltaic (PV)/battery (B) hybrid configuration. The main objective of this paper is focused on PV/B system, to recommend hybrid system optimal design in terms of PV module number, PV module tilt, number and capacity of batteries to minimize or, if possible, to neglect grid supply. This paper is the early stage of a theoretical and experimental study in which two different hybrid power system configurations will be evaluated and compared: (i) PV/B system and (ii) PV/B/fuel cell (FC) system. The aim of the overall study will be the definition of the optimal size, depending on utility characteristics in order to realize the complete grid independency.