Redox supercapacitors using polyaniline (PANI) coated, stainless-steel (SS) electrodes have been assembled and characterized. PANI has been deposited on SS substrate by a potentiodynamic method from an acidic electrolyte which contains aniline monomer. By employing stacks of electrodes, each with a geometrical area of 24cm2, in acidic perchlorate electrolyte, a capacitance value of about 450F has been obtained over a long cycle-life. Characterization studies have been carried out by galvanostatic charge–discharge cycling of the capacitors singly, as well as in series and parallel configurations. Various electrical parameters have been evaluated. Use of the capacitors in parallel with a battery for pulse-power loads, and also working of a toy fan connected to the charged capacitors have been demonstrated. A specific capacitance value of about 1300Fg−1 of PANI has been obtained at a discharge power of about 0.5kWkg−1. This value is several times higher than those reported in the literature for PANI and is, perhaps, the highest value known for a capacitor material. The inexpensive SS substrate and the high-capacitance PANI are favorable factors for commercial exploitation.