Li4Ti5O12 particles are synthesized coated with very thin graphene-like sheets in situ using liquid-polyacrylonitrile (LPAN) as the carbon source and added utilized conductivity additives to improve the conductivity of the electrode materials. The crystalline structures of Li4Ti5O12 with 20% LPAN and different conductivity additives composites were examined by XRD. The structure and electrochemical performance of the graphene-like sheets coated Li4Ti5O12, with conductivity additives added, was systematically investigated. The electrochemical performance also revealed that the graphene-like sheets significantly improved the discharge capacity and cycling stability of Li4Ti5O12. In particular, the coated Li4Ti5O12 with 20wt% LPAN and 1% acetylene black (CB) reached 166.2mAhg−1 at 10C. The performance improvement is a result of the graphene-like nanosheet conformal coating, which creates an electrically conductive network for the electrode.