Uniform and spherical Li(Ni1/3Co1/3Mn1/3)O(2−δ)F δ powders were synthesized via NH3 and F− coordination hydroxide co-precipitation. The effect of F− coordination agent on the morphology, structure and electrochemical properties of the Li(Ni1/3Co1/3Mn1/3)O(2−δ)F δ were studied. The morphology, size, and distribution of (Ni1/3Co1/3Mn1/3)(OH)(2−δ)F δ particle diameter were improved in a shorter reaction time through the addition of F−. The study suggested that the added F improves the layered characteristics of the lattice and the cyclic performance of Li(Ni1/3Co1/3Mn1/3)O2 in the voltage range of 2.8–4.6V. The initial capacity of the Li(Ni1/3Co1/3Mn1/3)O1.96F0.04 was 178mAhg−1, the maximum capacity was 186mAhg−1 and the capacity after 50 cycles was 179mAhg−1 in the voltage range of 2.8–4.6V.