A commercial graphite is ball-milled and the pristine and ball-milled graphites are characterised for use as negative electrodes in lithium-ion capacitors (LICs). Ball milling graphite results in a decrease in discharge capacity when the charge rate is relatively slow, whereas, it leads to an increase in discharge capacity when the charge rate is high. When charged at 0.1C, the discharge capacities of pristine, 3h, 10h and 30h-milled materials at 6C are 75, 69, 67 and 66% of theoretical capacity, respectively; however, when charged at 60C, the discharge capacities of pristine, 3h, 10h and 30h-milled materials, at 60C, fall to 0.9, 13, 23 and 24% of theoretical capacity, respectively (theoretical capacity: 372mAhg−1, for LiC6 stoichiometry). This difference in the discharge rate capability behaviour of the pristine and ball-milled graphites with charge rate is attributed to the interplay of two different charge storage mechanisms: Li-ion intercalation and Li-ion adsorption that co-exist; but the later becomes more significant for milled samples. In terms of cycle-life performance, pristine and ball-milled graphites follow similar trends observed for their rate capability behaviour.