In this study, we evaluated the emissions of pollutants generated from the combustion of syngas in the gasification of Municipal Solid Waste (MSW) in Brazil using a mobile grille gasifier fed with domestic waste without any previous separation or grinding. The basic syngas composition (H2, CH4 and CO) was analyzed by gas chromatography and the Lower Calorific Value was calculated, which ranged from 1.9 to 10.2 MJ/kg. In the monitoring of combustion gases (CO2, CO, NO, NO2, SO2 and Total Hydrocarbon Content), values were found for these pollutants that were lower than the values established by the Brazilian legislation, except for SO2. Regarding the determination of the emission of metals, values lower than those permissible in the legislation were found for the most toxic metals grouped as class I (Cd, Hg, Tl). Therefore, it was evident that gasification followed by the combustion of syngas from MSW without prior segregation at source has the advantages of having fewer process steps, allowing the low emission of pollutants into the environment and it avoids that the residues are deposited in landfills, which are generators of leachate and greenhouse gas (methane).