The present investigation describes the results of a research project (P.R.I.M.E.) aimed at testing the performance and the environmental impact of an electric city car in Italian cities. The vehicle considered in the project is the Daimler AG Smart ForTwo Electric Drive. A Smart ED vehicle was tested at the University of Salento for six months over different driving conditions (routes, traffic, use of auxiliaries). A data acquisition system has been designed on purpose and assembled on board to provide information about driving cycle and energy flows. The system was also used to evaluate the losses of energy during recharges due to the battery cooling system. The experimental tests were used to identify the average, minimum and maximum consumption of electricity in the Smart ED in Lecce according to driving conditions and in particular according to the usage of auxiliaries. The measured data of electric consumption have been used to quantify the emissions of CO2 and pollution of the vehicle using information about the Italian electricity production mix of each recharging event and the emissions factors of the Italian power plants with an innovative and comprehensive methodology.