The active materials of the secondary Zn electrode containing a mixture powder of zinc oxide (ZnO) and calcium hydroxide (Ca(OH)2) powders were prepared by a ball-milled method. The characteristic properties of active materials of ball-milled ZnO+Ca(OH)2 mixture powders were examined by scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) system, X-ray diffraction (XRD) analysis, and micro-Raman spectroscopy. The prepared Zn powder electrodes were by using the ball-milled active materials powder +2wt.% highly electronic conductive fillers, i.e., nano-copper or carbon nanotubes (CNTs) powder. The electrochemical properties of the secondary Zn electrodes without and with the conductive fillers were studied by using cyclic voltammetry (CV) and galvanostatic charge/discharge tests. It was found that the charge/discharge properties of the secondary Zn electrode could be improved when the nano-sized conductive fillers were added into the electrode. In fact, it may be due to the formation of a better electronic conduction path in the electrode matrix. In particular, it was found that the best electrochemical properties were the secondary Zn electrode with 2wt.% nano-copper fillers. According to the results, it is demonstrated here that the CV method is a quick technique to effectively evaluate the performance of a secondary Zn electrode.