Lithium-selenium (Li-Se) batteries are of great interest as a representative family of electrochemical energy storage systems because of their high theoretical volumetric capacity and considerable electronic conductivity. However, the main drawback of Se electrodes is the rapid capacity fading caused by the dissolution of polyselenides upon cycling. Here, we report a simple, economical, and effective method for the synthesis of three-dimensional (3D) hierarchical porous carbon with a hollow tubular structure as a host matrix for loading Se and trapping polyselenides. The as-obtained porous tubular carbon shows a superior specific surface area of 1786 m2 g−1, a high pore volume of 0.79 cm3 g−1, and many nanostructured pores. Benefiting from the unique structural characteristics, the resulting hierarchical porous carbon/Se composite exhibits a high capacity of 515 mAh g−1 at 0.2 C. More importantly, a remarkable cycling stability over 900 cycles at 2 C with a capacity fading rate of merely 0.02% per cycle can be achieved. The 3D hollow porous tubular carbon can be also used for other high-performance electrodes of electrochemical energy storage.