The lithium/sulfur (Li–S) batteries consist of a composite cathode, a polymer electrolyte, and a lithium anode. The composite cathode is made from elemental sulfur (or lithium sulfide), carbon black, PEO, LiClO4, and acetonitrile. The polymer electrolyte is made of gel-type linear poly(ethylene oxide) (PEO) with tetra ethylene glycol dimethyl ether. Cells based on Li2S or sulfur have open-circuit voltages of about 2.2 and 2.5V, respectively. The former cell shows two reduction peaks and one oxidation peak. It is suggested that the first reduction peak is caused by the change from polysulfide to short lithium polysulfide, and the second reduction peak by the change from short lithium polysulfide to lithium sulfide (Li2S, Li2S2). The cell based on sulfur has the same reduction mechanism as that of Li2S, which is caused by the multi process (first and second reduction) of lithium polysulfide. On charge–discharge cycling, the first discharge has a higher capacity than subsequent discharges and the flat discharge voltage is about 2.0V. As the current load is increased, the discharge capacity decreases. One reason for this fading capacity and low sulfur utilization is the aggregation of sulfur (or polysulfide) with cycling.