Significant efforts have been made to eliminate the shuttle effect created by the surface modification of separator or by adding interlayers. However, much of the research so far requires elaborate and costly material processing steps that did not necessarily result in substantially improved cell performances. In this contribution, a three-dimensional carbon fiber cloth (CFC) is placed between the separator and the sulfur cathode to accommodate and capture the soluble polysulfide intermediates. The cells with this interlayer show an initial discharge capacity of 6.89mAhcm−2, which remains substantial after 100 cycles at 1C (6.69mAhcm−2). CFC interlayers provide an efficient and cost effective route for developing promising lithium-sulfur batteries with long cycle stability and good rate capability.