 Due to the depletion of fossil resources and their environmental impact, woody biomass has received much attention as an alternative resource. Lignin, as the third most abundant biopolymer from biomass, is now considered as an excellent alternative feedstock for chemicals and materials. The conversion of lignin to the value-added products is a key process to achieve an integrated biorefinery of woody biomass. Among these value-added products, lignin-based derivatives with good surface activity can be applied to enhance the conversion of cellulose into fermentable sugars, which not only decrease the cost of bioethanol production, but also reduce the environmental pollution and green house effect resulting from the burning of fossil resources.