To achieve a high-energy-density lithium electrode, high-density LiFePO4/C composite cathode material for a lithium-ion battery was synthesized using self-produced high-density FePO4 as a precursor, glucose as a C source, and Li2CO3 as a Li source, in a pipe furnace under an atmosphere of 5% H2–95% N2. The structure of the synthesized material was analyzed and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The electrochemical properties of the synthesized LiFePO4/carbon composite were investigated by cyclic voltammetry (CV) and the charge/discharge process. The tap-density of the synthesized LiFePO4/carbon composite powder with a carbon content of 7% reached 1.80gm−3. The charge/discharge tests show that the cathode material has initial charge/discharge capacities of 190.5 and 167.0mAhg−1, respectively, with a volume capacity of 300.6mAhcm−3, at a 0.1C rate. At a rate of 5C, the LiFePO4/carbon composite shows a high discharge capacity of 98.3mAhg−1 and a volume capacity of 176.94mAhcm−3.