One step process for direct laser writing carbonization of NH4H2PO4 treated cellulose paper and its use for facile fabrication of multifunctional force sensors with corrugated structures
It is highly desired to be able to readily and robustly fabricate carbon patterns on cellulose paper (CellP) with complicated 3D structures, which would allow for cost effectively developing a variety of resilient and stable paper based sensors. Upon a pretreatment of CellP with NH4H2PO4, herein, we present a one step direct laser writing carbonization (DLWc) method capable of in situ creating electrically conductive carbon features on the NH4H2PO4 treated CellP. With assistance of infrared spectroscopy, thermogravimetry and differential scanning calorimetry, the role of NH4H2PO4 in the pyrolysis/carbonization of cellulose paper to enhance the resultant carbon yield was investigated. The loadings of NH4H2PO4 in CellP and the laser processing conditions were studied for their effects on morphology/structure and electrical property of the carbon line features created by DLWc on the NH4H2PO4 treated CellP. Upon taking advantage of the unique mechanical characteristics of corrugated paper sheets, we further utilized the one step DLWc process to fabricate disposable, lightweight, and low cost paper based sensors and demonstrated their use for sensing force, displacement, wind flow and finger tapping position recognition. The one step DLWc of CellP will lead a way towards large scale, environmental benign and cost effective production of multifunctional paper based sensors.
Cellulose