Although peer-reviewed health-based OELs are preferred for establishing safe levels of exposure or for implementing adequate controls to provide worker protection, the lack of publicly available OELs have led to other sources of safe levels to protect workers. Industrial or Occupational Hygienists are often on the front line of anticipating and recognizing the hazards of chemical exposure for workers, and must assess the risk of exposure through the use of OELs so that proper control strategies can be implemented to keep workers below the OEL values. In the absence of OELs however, there are a variety of tools that can and should be used to assess exposure potential of workers.