The acid begins to attach the surface of the glass particles, as well as the adjacent tooth substrate, thus precipitating their outer layers but also neutralising itself. As the pH of the aqueous solution rises, the polyacrylic acid begins to ionise, and becoming negatively charged it sets up a diffusion gradient and helps draw cations out of the glass and dentine. The alkalinity also induces the polymers to dissociate, increasing the viscosity of the aqueous solution.