We can achieve this bound as follows: first sort the edges by weight using a comparison sort in O(E log E) time; this allows the step "remove an edge with minimum weight from S" to operate in constant time. Next, we use a disjoint-set data structure (Union&Find) to keep track of which vertices are in which components. We need to perform O(V) operations, as in each iteration we connect a vertex to the spanning tree, two 'find' operations and possibly one union for each edge.