Rank Fortune 500 rank Name Industry Revenue (USD millions) Profits (USD millions) Employees Headquarters 1 74 Petrobras Oil and Gas 95,584 7,173 63,361 Rio de Janeiro 2 191 Banco Itaú Unibanco Banking 54,662 6,815 100,335 São Paulo 3 219 JBS S.A. Food production 49,709 6.9 230,086 São Paulo 4 221 Banco Bradesco Banking 49,612 4,538 86,772 Osasco 5 269 Banco do Brasil Banking 43,333 3,783 96,889 Brasília 6 305 Caixa Econômica Federal Finance 40,240 2,833 84,952 Brasília 7 336 Vale Mining 36,696 6,860 70,270 Rio de Janeiro 8 499 Ultrapar Conglomerate 24,816 315 17,034 São Paulo