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It will have cooled down just enough to be warm to the touch, but not oven-hot.  Using a cake stand might make this action difficult for one person to complete alone.  If the cake doesn’t dislodge from the pan easily, tap the inverted Bundt pan a few times with your hand and try again.

Summary:
Transfer the batter to the Bundt pan and smooth out the top using the back of a tablespoon. Bake the cake for 40 to 45 minutes, or until a toothpick inserted in the cake comes out clean. Allow the cake to cool in the pan for 20 minutes. Once the cake is cooled, use a butter knife or a plastic spatula to gently separate the cake from the sides of the pan. Place an inverted cake plate on the top of your Bundt pan. Flip the cake plate and the Bundt pan over until the cake plate is resting on the counter with the inverted Bundt pan on top. Gently lift the Bundt pan to release the cake.