5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

import java.io.*;
import java.util.*;

public class Main2{
	static void main() throws Exception{
		int n=sc.nextInt();
		pw.println("? 1");
		pw.flush();
		int[]d=sc.intArr(n);
		int[]cnt=new int[2];
		StringBuilder sb=new StringBuilder();
		
		for(int i=0;i<n;i++) {
			cnt[(d[i]&1)]++;
			if(d[i]==1) {
				sb.append("1 "+(i+1)+"\n");
			}
		}
		cnt[0]--;
		int min=cnt[0]<cnt[1]?0:1;
		for(int i=1;i<n;i++) {
			if((d[i]&1)==min) {
				pw.println("? "+(i+1));
				pw.flush();
				for(int j=0;j<n;j++) {
					if(sc.nextInt()==1 && j!=0) {
						sb.append((i+1)+" "+(j+1)+"\n");
					}
				}
				
			}
		}
		pw.println("!");
		pw.println(sb);
	}
	public static void main(String[] args) throws Exception{
		sc=new MScanner(System.in);
		pw = new PrintWriter(System.out);
		int tc=1;
//        tc=sc.nextInt();
		for(int i=1;i<=tc;i++) {
//			pw.printf("Case #%d: ", i);
			main();
		}
		
		pw.flush();
	}
	static PrintWriter pw;
	static MScanner sc;
	static class MScanner {
		StringTokenizer st;
		BufferedReader br;
		public MScanner(InputStream system) {
			br = new BufferedReader(new InputStreamReader(system));
		}
	 
		public MScanner(String file) throws Exception {
			br = new BufferedReader(new FileReader(file));
		}
	 
		public String next() throws IOException {
			while (st == null || !st.hasMoreTokens())
				st = new StringTokenizer(br.readLine());
			return st.nextToken();
		}
		public int[] intArr(int n) throws IOException {
	        int[]in=new int[n];for(int i=0;i<n;i++)in[i]=nextInt();
	        return in;
		}
		public long[] longArr(int n) throws IOException {
	        long[]in=new long[n];for(int i=0;i<n;i++)in[i]=nextLong();
	        return in;
		}
		public int[] intSortedArr(int n) throws IOException {
	        int[]in=new int[n];for(int i=0;i<n;i++)in[i]=nextInt();
	        shuffle(in);
	        Arrays.sort(in);
	        return in;
		}
		public long[] longSortedArr(int n) throws IOException {
	        long[]in=new long[n];for(int i=0;i<n;i++)in[i]=nextLong();
	        shuffle(in);
	        Arrays.sort(in);
	        return in;
		}
		public Integer[] IntegerArr(int n) throws IOException {
	        Integer[]in=new Integer[n];for(int i=0;i<n;i++)in[i]=nextInt();
	        return in;
		}
		public Long[] LongArr(int n) throws IOException {
	        Long[]in=new Long[n];for(int i=0;i<n;i++)in[i]=nextLong();
	        return in;
		}
		public String nextLine() throws IOException {
			return br.readLine();
		}
	 
		public int nextInt() throws IOException {
			return Integer.parseInt(next());
		}
	 
		public double nextDouble() throws IOException {
			return Double.parseDouble(next());
		}
	 
		public char nextChar() throws IOException {
			return next().charAt(0);
		}
	 
		public long nextLong() throws IOException {
			return Long.parseLong(next());
		}
	 
		public boolean ready() throws IOException {
			return br.ready();
		}
	 
		public void waitForInput() throws InterruptedException {
			Thread.sleep(3000);
		}
		
	}
	static void dbg(int[]in) {
		System.out.println(Arrays.toString(in));
	}
	static void dbg(long[]in) {
		System.out.println(Arrays.toString(in));
	}
	static void sort(int[]in) {
		shuffle(in);
		Arrays.sort(in);
	}
	static void sort(long[]in) {
		shuffle(in);
		Arrays.sort(in);
	}
	static void shuffle(int[]in) {
		for(int i=0;i<in.length;i++) {
			int idx=(int)(Math.random()*in.length);
			int tmp=in[i];
			in[i]=in[idx];
			in[idx]=tmp;
		}
	}
	static void shuffle(long[]in) {
		for(int i=0;i<in.length;i++) {
			int idx=(int)(Math.random()*in.length);
			long tmp=in[i];
			in[i]=in[idx];
			in[idx]=tmp;
		}
	}
}