5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

import java.awt.Point;
import java.util.ArrayList;
import java.util.HashSet;
import java.util.TreeSet;

public class Main {

	public static void main(String[] args) {
		new Main();
	}

	public Main() {
		FastScanner fs = new FastScanner();
		java.io.PrintWriter out = new java.io.PrintWriter(System.out);
		solve(fs, out);
		out.flush();
	}

	public void solve(FastScanner fs, java.io.PrintWriter out) {
		int n = fs.nextInt();
		out.println("? 1");
		out.flush();
		TreeSet<Integer> set = new TreeSet<>();
		HashSet<Point> list = new HashSet<>();
		{
			ArrayList<Integer> odd = new ArrayList<>(), even = new ArrayList<>();
			for (int i = 1;i <= n;++ i) {
				int d = fs.nextInt();
				if (d == 1) list.add(new Point(1, i));
				if (i == 1) continue;
				if (d % 2 == 0) even.add(i);
				else odd.add(i);
			}
			if (odd.size() < even.size()) set.addAll(odd);
			else set.addAll(even);
		}

		while(!set.isEmpty()) {
			int tmp = set.pollFirst();
			out.println("? " + tmp);
			out.flush();
			for (int i = 1;i <= n;++ i) {
				if (fs.nextInt() == 1) {
					list.add(new Point(Math.min(tmp, i), Math.max(tmp, i)));
					set.remove(i);
				}
			}
		}
		out.println("!");
		for (Point p : list) out.println(p.x + " " + p.y);
	}
}

class FastScanner {

	private final java.io.InputStream in = System.in;
	private final byte[] buffer = new byte[8192];
	private int ptr = 0;
	private int buflen = 0;

	private boolean hasNextByte() {
		if (ptr < buflen) return true;
		ptr = 0;
		try {
			buflen = in.read(buffer);
		} catch (java.io.IOException e) {
			e.printStackTrace();
		}
		return buflen > 0;
	}

	private byte readByte() {
		return hasNextByte() ? buffer[ptr++ ] : -1;
	}

	private static boolean isPrintableChar(byte c) {
		return 32 < c || c < 0;
	}

	private static boolean isNumber(int c) {
		return '0' <= c && c <= '9';
	}

	public boolean hasNext() {
		while (hasNextByte() && !isPrintableChar(buffer[ptr]))
			ptr++ ;
		return hasNextByte();
	}

	public String next() {
		if (!hasNext()) throw new java.util.NoSuchElementException();
		StringBuilder sb = new StringBuilder();
		byte b;
		while (isPrintableChar(b = readByte()))
			sb.appendCodePoint(b);
		return sb.toString();
	}

	public final char nextChar() {
		if (!hasNext()) throw new java.util.NoSuchElementException();
		return (char)readByte();
	}

	public final long nextLong() {
		if (!hasNext()) throw new java.util.NoSuchElementException();
		long n = 0;
		try {
			byte b = readByte();
			if (b == '-') {
				while (isNumber(b = readByte()))
					n = n * 10 + '0' - b;
				return n;
			} else if (!isNumber(b)) throw new NumberFormatException();
			do
				n = n * 10 + b - '0';
			while (isNumber(b = readByte()));
		} catch (java.util.NoSuchElementException e) {}
		return n;
	}

	public final int nextInt() {
		if (!hasNext()) throw new java.util.NoSuchElementException();
		int n = 0;
		try {
			byte b = readByte();
			if (b == '-') {
				while (isNumber(b = readByte()))
					n = n * 10 + '0' - b;
				return n;
			} else if (!isNumber(b)) throw new NumberFormatException();
			do
				n = n * 10 + b - '0';
			while (isNumber(b = readByte()));
		} catch (java.util.NoSuchElementException e) {}
		return n;
	}

	public double nextDouble() {
		return Double.parseDouble(next());
	}
}

class Arrays {

	public static void sort(final int[] array) {
		sort(array, 0, array.length);
	}

	public static void sort(final int[] array, int fromIndex, int toIndex) {
		if (toIndex - fromIndex  <= 512) {
			java.util.Arrays.sort(array, fromIndex, toIndex);
			return;
		}
		sort(array, fromIndex, toIndex, 0, new int[array.length]);
	}

	private static final void sort(int[] a, final int from, final int to, final int l, final int[] bucket) {
		if (to - from  <= 512) {
			java.util.Arrays.sort(a, from, to);
			return;
		}
		final int BUCKET_SIZE = 256;
		final int INT_RECURSION = 4;
		final int MASK = 0xff;
		final int shift = l << 3;
		final int[] cnt = new int[BUCKET_SIZE + 1];
		final int[] put = new int[BUCKET_SIZE];
		for (int i = from; i < to; i++) ++ cnt[(a[i] >>> shift & MASK) + 1];
		for (int i = 0; i < BUCKET_SIZE; i++) cnt[i + 1] += cnt[i];
		for (int i = from; i < to; i++) {
			int bi = a[i] >>> shift & MASK;
			bucket[cnt[bi] + put[bi]++] = a[i];
		}
		for (int i = BUCKET_SIZE - 1, idx = from; i >= 0; i--) {
			int begin = cnt[i];
			int len = cnt[i + 1] - begin;
			System.arraycopy(bucket, begin, a, idx, len);
			idx += len;
	    }
		final int nxtL = l + 1;
		if (nxtL < INT_RECURSION) {
			sort(a, from, to, nxtL, bucket);
			if (l == 0) {
				int lft, rgt;
				lft = from - 1; rgt = to;
				while (rgt - lft > 1) {
					int mid = lft + rgt >> 1;
					if (a[mid] < 0) lft = mid;
					else rgt = mid;
				}
				reverse(a, from, rgt);
				reverse(a, rgt, to);
	        }
	    }
	}

	public static void sort(final long[] array) {
		sort(array, 0, array.length);
	}

	public static void sort(final long[] array, int fromIndex, int toIndex) {
		if (toIndex - fromIndex  <= 512) {
			java.util.Arrays.sort(array, fromIndex, toIndex);
			return;
		}
		sort(array, fromIndex, toIndex, 0, new long[array.length]);
	}

	private static final void sort(long[] a, final int from, final int to, final int l, final long[] bucket) {
		final int BUCKET_SIZE = 256;
		final int LONG_RECURSION = 8;
		final int MASK = 0xff;
		final int shift = l << 3;
		final int[] cnt = new int[BUCKET_SIZE + 1];
		final int[] put = new int[BUCKET_SIZE];
		for (int i = from; i < to; i++) ++ cnt[(int) ((a[i] >>> shift & MASK) + 1)];
		for (int i = 0; i < BUCKET_SIZE; i++) cnt[i + 1] += cnt[i];
		for (int i = from; i < to; i++) {
			int bi = (int) (a[i] >>> shift & MASK);
			bucket[cnt[bi] + put[bi]++] = a[i];
		}
		for (int i = BUCKET_SIZE - 1, idx = from; i >= 0; i--) {
			int begin = cnt[i];
			int len = cnt[i + 1] - begin;
			System.arraycopy(bucket, begin, a, idx, len);
			idx += len;
	    }
		final int nxtL = l + 1;
		if (nxtL < LONG_RECURSION) {
			sort(a, from, to, nxtL, bucket);
			if (l == 0) {
				int lft, rgt;
				lft = from - 1; rgt = to;
				while (rgt - lft > 1) {
					int mid = lft + rgt >> 1;
					if (a[mid] < 0) lft = mid;
					else rgt = mid;
				}
				reverse(a, from, rgt);
				reverse(a, rgt, to);
	        }
	    }
	}

	public static void reverse(int[] array) {
		reverse(array, 0, array.length);
	}

	public static void reverse(int[] array, int fromIndex, int toIndex) {
		for (-- toIndex;fromIndex < toIndex;++ fromIndex, -- toIndex) {
			int swap = array[fromIndex];
			array[fromIndex] = array[toIndex];
			array[toIndex] = swap;
		}
	}

	public static void reverse(long[] array) {
		reverse(array, 0, array.length);
	}

	public static void reverse(long[] array, int fromIndex, int toIndex) {
		for (-- toIndex;fromIndex < toIndex;++ fromIndex, -- toIndex) {
			long swap = array[fromIndex];
			array[fromIndex] = array[toIndex];
			array[toIndex] = swap;
		}
	}
}

class IntMath {

	public static int gcd(int a, int b) {
		while (a != 0)
			if ((b %= a) != 0) a %= b;
			else return a;
		return b;
	}

	public static int gcd(int... array) {
		int ret = array[0];
		for (int i = 1; i < array.length; ++i)
			ret = gcd(ret, array[i]);
		return ret;
	}

	public static long gcd(long a, long b) {
		while (a != 0)
			if ((b %= a) != 0) a %= b;
			else return a;
		return b;
	}

	public static long gcd(long... array) {
		long ret = array[0];
		for (int i = 1; i < array.length; ++i)
			ret = gcd(ret, array[i]);
		return ret;
	}

	public static long lcm(long a, long b) {
		return a / gcd(a, b) * b;
	}

	public static int pow(int a, int b) {
		int ans = 1;
		for (int mul = a; b > 0; b >>= 1, mul *= mul)
			if ((b & 1) != 0) ans *= mul;
		return ans;
	}

	public static long pow(long a, long b) {
		long ans = 1;
		for (long mul = a; b > 0; b >>= 1, mul *= mul)
			if ((b & 1) != 0) ans *= mul;
		return ans;
	}

	public static int pow(int a, long b, int mod) {
		if (b < 0) b = b % (mod - 1) + mod - 1;
		long ans = 1;
		for (long mul = a; b > 0; b >>= 1, mul = mul * mul % mod)
			if ((b & 1) != 0) ans = ans * mul % mod;
		return (int)ans;
	}

	public static int pow(long a, long b, int mod) {
		return pow((int)(a % mod), b, mod);
	}

	public static int floorsqrt(long n) {
		return (int)Math.sqrt(n + 0.1);
	}

	public static int ceilsqrt(long n) {
		return n <= 1 ? (int)n : (int)Math.sqrt(n - 0.1) + 1;
	}
}
