5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

//Utilities
import java.io.*;
import java.util.*;

public class Main {
	static int t;
	static int n;
	static boolean[][] edge;
	static int[] distArr, a;
	static int leafDist = -1;
	static int edgeCnt = 0;
	static ArrayList<Integer> res1, res2;
	
	public static void main(String[] args) throws IOException {
		n = in.iscan(); res1 = new ArrayList<Integer>(); res2 = new ArrayList<Integer>();
		Queue<Integer> q = new LinkedList<Integer>();
		q.add(1); distArr = new int[n+1];
		edge = new boolean[n+1][n+1]; a = new int[n+1];
		dfs(1);
		out.close();
	}
	
	static void dfs(int cur) throws IOException{
		out.println("? " + cur);
		out.flush();
		int oneCnt = 0, twoCnt = 0;
		for (int i = 1; i <= n; i++) {
			a[i] = in.iscan();
			if (a[i] == 1 && (cur == 1 || distArr[i] > distArr[cur])) {
				oneCnt++;
			}
			else if (a[i] == 2 && (cur == 1 || distArr[i] > distArr[cur])) {
				twoCnt++;
			}
		}
		if (cur == 1) {
			for (int i = 1; i <= n; i++) {
				distArr[i] = a[i];
			}
		}
		for (int i = 1; i <= n; i++) {
			if (a[i] == 1 && !edge[cur][i]) {
				res1.add(cur); res2.add(i);
				edge[cur][i] = edge[i][cur] = true;
				edgeCnt++;
				if (edgeCnt == n-1) {
					out.println("!");
					for (int j = 0; j < n-1; j++) {
						out.println(res1.get(j) + " " + res2.get(j));
						out.flush();
					}
					out.close();
					System.exit(0);
				}
			}
		}
		if (twoCnt <= oneCnt) {
			for (int i = 1; i <= n; i++) {
				if (a[i] == 2 && distArr[i] > distArr[cur]) {
					dfs(i);
				}
			}
		}
		else {
			for (int i = 1; i <= n; i++) {
				if (a[i] == 1 && distArr[i] > distArr[cur]) {
					dfs(i);
				}
			}
		}
	}
	
	static INPUT in = new INPUT(System.in);
	static PrintWriter out = new PrintWriter(System.out);
	private static class INPUT {

		private InputStream stream;
		private byte[] buf = new byte[1024];
		private int curChar, numChars;

		public INPUT (InputStream stream) {
			this.stream = stream;
		}

		public INPUT (String file) throws IOException {
			this.stream = new FileInputStream (file);
		}

		public int cscan () throws IOException {
			if (curChar >= numChars) {
				curChar = 0;
				numChars = stream.read (buf);
			}
			
			if (numChars == -1)
				return numChars;

			return buf[curChar++];
		}

		public int iscan () throws IOException {
			int c = cscan (), sgn = 1;
			
			while (space (c))
				c = cscan ();

			if (c == '-') {
				sgn = -1;
				c = cscan ();
			}

			int res = 0;

			do {
				res = (res << 1) + (res << 3);
				res += c - '0';
				c = cscan ();
			}
			while (!space (c));

			return res * sgn;
		}

		public String sscan () throws IOException {
			int c = cscan ();
			
			while (space (c))
				c = cscan ();

			StringBuilder res = new StringBuilder ();

			do {
				res.appendCodePoint (c);
				c = cscan ();
			}
			while (!space (c));

			return res.toString ();
		}

		public double dscan () throws IOException {
			int c = cscan (), sgn = 1;
			
			while (space (c))
				c = cscan ();

			if (c == '-') {
				sgn = -1;
				c = cscan ();
			}

			double res = 0;

			while (!space (c) && c != '.') {
				if (c == 'e' || c == 'E')
					return res * UTILITIES.fast_pow (10, iscan ());
				
				res *= 10;
				res += c - '0';
				c = cscan ();
			}

			if (c == '.') {
				c = cscan ();
				double m = 1;

				while (!space (c)) {
					if (c == 'e' || c == 'E')
						return res * UTILITIES.fast_pow (10, iscan ());

					m /= 10;
					res += (c - '0') * m;
					c = cscan ();
				}
			}

			return res * sgn;
		}

		public long lscan () throws IOException {
			int c = cscan (), sgn = 1;
			
			while (space (c))
				c = cscan ();

			if (c == '-') {
				sgn = -1;
				c = cscan ();
			}

			long res = 0;

			do {
				res = (res << 1) + (res << 3);
				res += c - '0';
				c = cscan ();
			}
			while (!space (c));

			return res * sgn;
		}

		public boolean space (int c) {
			return c == ' ' || c == '\n' || c == '\r' || c == '\t' || c == -1;
		}
	}

	public static class UTILITIES {

		static final double EPS = 10e-6;

		public static int lower_bound (int[] arr, int x) {
			int low = 0, high = arr.length, mid = -1;

			while (low < high) {
				mid = (low + high) / 2;

				if (arr[mid] >= x)
					high = mid;
				else
					low = mid + 1;
			}

			return low;
		}

		public static int upper_bound (int[] arr, int x) {
			int low = 0, high = arr.length, mid = -1;

			while (low < high) {
				mid = (low + high) / 2;

				if (arr[mid] > x)
					high = mid;
				else
					low = mid + 1;
			}

			return low;
		}

		public static long gcd (long a, long b) {
			return b == 0 ? a : gcd (b, a % b);
		}

		public static long lcm (long a, long b) {
			return a * b / gcd (a, b);
		}

		public static long fast_pow_mod (long b, long x, int mod) {
			if (x == 0) return 1;
			if (x == 1) return b;
			if (x % 2 == 0) return fast_pow_mod (b * b % mod, x / 2, mod) % mod;

			return b * fast_pow_mod (b * b % mod, x / 2, mod) % mod;
		}

		public static int fast_pow (int b, int x) {
			if (x == 0) return 1;
			if (x == 1) return b;
			if (x % 2 == 0) return fast_pow (b * b, x / 2);

			return b * fast_pow (b * b, x / 2);
		}

		public static long choose (long n, long k) {
			k = Math.min (k, n - k);
			long val = 1;

			for (int i = 0; i < k; ++i)
				val = val * (n - i) / (i + 1);

			return val;
		}

		public static long permute (int n, int k) {
			if (n < k) return 0;
			long val = 1;

			for (int i = 0; i < k; ++i)
				val = (val * (n - i));

			return val;
		}
	}
}
