5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

import java.util.*;
import java.io.*;
public class EdD {
	static long[] mods = {1000000007, 998244353, 1000000009};
	static long mod = mods[0];
	public static MyScanner sc;
    public static PrintWriter out;
	public static void main(String[] havish) throws Exception{
		// TODO Auto-generated method stub
 		sc = new MyScanner();
 		out = new PrintWriter(System.out);
 		int n = sc.nextInt();
 		ArrayList<ArrayList<Integer>> edges;
 		edges = new ArrayList<>();
 		out.println("?  " + 1);
 		out.flush();
 		int[] arr = readArrayInt1(n);
 		Set<Integer> even = new HashSet<>();
 		Set<Integer> odd = new HashSet<>();
 		for(int j = 1;j<=n;j++){
 			if (arr[j]%2 == 0){
 				even.add(j);
 			}
 			else{
 				odd.add(j);
 			}
 		}
 		if (even.size() <= odd.size()) {
 			for(int j : even) {
 				out.println("? " + j);
 				out.flush();
 				int[] arr1 = readArrayInt1(n);
 				for(int k=  1;k<=n;k++){
 					if (arr1[k] == 1) {
 						ArrayList<Integer> temp = new ArrayList<>();
 						temp.add(j);
 						temp.add(k);
 						edges.add(temp);
 					}
 				}
 				
 			}
 		}
 		else{
 			for(int j : odd) {
 				out.println("? " + j);
 				out.flush();
 				int[] arr1 = readArrayInt1(n);
 				for(int k=  1;k<=n;k++){
 					if (arr1[k] == 1) {
 						ArrayList<Integer> temp = new ArrayList<>();
 						temp.add(j);
 						temp.add(k);
 						edges.add(temp);
 					}
 				}
 				
 			}
 		}
 		out.println("!");
 		for(ArrayList<Integer> temp : edges) {
 			out.println(temp.get(0) + " " + temp.get(1));
 		}
 		
 		out.close();
 		
 	}
	
	public static void sort(int[] array){
		ArrayList<Integer> copy = new ArrayList<>();
		for (int i : array)
			copy.add(i);
		Collections.sort(copy);
		for(int i = 0;i<array.length;i++)
			array[i] = copy.get(i);
	}
	static String[] readArrayString(int n){
		String[] array = new String[n];
		for(int j =0 ;j<n;j++)
			array[j] = sc.next();
		return array;
	}
	static int[] readArrayInt(int n){
    	int[] array = new int[n];
    	for(int j = 0;j<n;j++)
    		array[j] = sc.nextInt();
    	return array;
    }
	static int[] readArrayInt1(int n){
		int[] array = new int[n+1];
		for(int j = 1;j<=n;j++){
			array[j] = sc.nextInt();
		}
		return array;
	}
	static long[] readArrayLong(int n){
		long[] array = new long[n];
		for(int j =0 ;j<n;j++)
			array[j] = sc.nextLong();
		return array;
	}
	static double[] readArrayDouble(int n){
		double[] array = new double[n];
		for(int j =0 ;j<n;j++)
			array[j] = sc.nextDouble();
		return array;
	}
	static int minIndex(int[] array){
		int minValue = Integer.MAX_VALUE;
		int minIndex = -1;
		for(int j = 0;j<array.length;j++){
			if (array[j] < minValue){
				minValue = array[j];
				minIndex = j;
			}
		}
		return minIndex;
	}
	static int minIndex(long[] array){
		long minValue = Long.MAX_VALUE;
		int minIndex = -1;
		for(int j = 0;j<array.length;j++){
			if (array[j] < minValue){
				minValue = array[j];
				minIndex = j;
			}
		}
		return minIndex;
	}
	static int minIndex(double[] array){
		double minValue = Double.MAX_VALUE;
		int minIndex = -1;
		for(int j = 0;j<array.length;j++){
			if (array[j] < minValue){
				minValue = array[j];
				minIndex = j;
			}
		}
		return minIndex;
	}
	static long power(long x, long y){
		if (y == 0)
			return 1;
		if (y%2 == 1)
			return (x*power(x, y-1))%mod;
		return power((x*x)%mod, y/2)%mod;
	}
	static void verdict(boolean a){
        out.println(a ? "YES" : "NO");
    }
    public static class MyScanner {
        BufferedReader br;
        StringTokenizer st;
        public MyScanner() {
            br = new BufferedReader(new InputStreamReader(System.in));
        }
        String next() {
            while (st == null || !st.hasMoreElements()) {
                try {
                    st = new StringTokenizer(br.readLine());
                } 
                catch (IOException e) {
                    e.printStackTrace();
                }
            }
            return st.nextToken();
        }
        int nextInt() {
            return Integer.parseInt(next());
        }
        long nextLong() {
            return Long.parseLong(next());
        }
        double nextDouble() {
            return Double.parseDouble(next());
        }
        String nextLine() {
            String str = "";
            try{
                str = br.readLine();
            } 
            catch (IOException e) {
                e.printStackTrace();
            }
            return str;
        }
        
    }	
}

//StringJoiner sj = new StringJoiner(" "); 
//sj.add(strings)
//sj.toString() gives string of those stuff w spaces or whatever that sequence is