5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

import os
import sys
from io import BytesIO, IOBase
 
BUFSIZE = 8192
 
 
class FastIO(IOBase):
    newlines = 0
 
    def __init__(self, file):
        self._fd = file.fileno()
        self.buffer = BytesIO()
        self.writable = "x" in file.mode or "r" not in file.mode
        self.write = self.buffer.write if self.writable else None
 
    def read(self):
        while True:
            b = os.read(self._fd, max(os.fstat(self._fd).st_size, BUFSIZE))
            if not b:
                break
            ptr = self.buffer.tell()
            self.buffer.seek(0, 2), self.buffer.write(b), self.buffer.seek(ptr)
        self.newlines = 0
        return self.buffer.read()
 
    def readline(self):
        while self.newlines == 0:
            b = os.read(self._fd, max(os.fstat(self._fd).st_size, BUFSIZE))
            self.newlines = b.count(b"\n") + (not b)
            ptr = self.buffer.tell()
            self.buffer.seek(0, 2), self.buffer.write(b), self.buffer.seek(ptr)
        self.newlines -= 1
        return self.buffer.readline()
 
    def flush(self):
        if self.writable:
            os.write(self._fd, self.buffer.getvalue())
            self.buffer.truncate(0), self.buffer.seek(0)
 
 
class IOWrapper(IOBase):
    def __init__(self, file):
        self.buffer = FastIO(file)
        self.flush = self.buffer.flush
        self.writable = self.buffer.writable
        self.write = lambda s: self.buffer.write(s.encode("ascii"))
        self.read = lambda: self.buffer.read().decode("ascii")
        self.readline = lambda: self.buffer.readline().decode("ascii")
 
 
sys.stdin, sys.stdout = IOWrapper(sys.stdin), IOWrapper(sys.stdout)
input = lambda: sys.stdin.readline().rstrip("\r\n")
#######################################
from collections import deque,defaultdict as dd
n=int(input())
adj=[[] for i in range(n+1)]
v=[0]*(n+1)
q=deque()
q.append(1)
d=dd(int)
while len(q):
    a=q.popleft()
    if not v[a]:
        v[a]=1
        print('?',a,flush=True)
        l=list(map(int,input().split()))
        c=0
        for i in range(n):
            if l[i]==1:
                if not c and a==1:
                    q.appendleft(i+1)
                    c+=1
                else:
                    v[i+1]=1
                adj[a].append(i+1)
                adj[i+1].append(a)
            elif l[i]==2:
                if not v[i+1]:
                    q.append(i+1)
        
print('!',flush=True)
for i in range(1,n+1):
    for j in adj[i]:
        if i<j:
            if not d[i,j]:
                print(i,j,flush=True)
                d[i,j]=1
                
            

    
