5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

//package currentContest;

import java.io.BufferedReader;
import java.io.IOException;
import java.io.InputStreamReader;
import java.util.ArrayDeque;
import java.util.ArrayList;
import java.util.Arrays;
import java.util.HashSet;
import java.util.Random;
import java.util.StringTokenizer;

public class P4 {

	public static void main(String[] args) {
		// TODO Auto-generated method stub
		FastReader sc = new FastReader();
		int n=sc.nextInt();
		int ask=n/2+n%2;
		HashSet<Integer> set=new HashSet<Integer>();
		set.add(0);
		ArrayDeque<Integer> tf=new ArrayDeque<>();
		tf.add(0);
		int edge[][]=new int[n][n];
		for(int i=0;i<n;i++) {
			for(int j=0;j<n;j++) {
				edge[i][j]=0;
			}
		}
		int dist=2;
		while(set.size()!=n&&ask--!=0) {
			System.out.println("? "+(tf.getFirst()+1));
			System.out.println();
			System.out.flush();
			int a[]=new int[n];
			for(int i=0;i<n;i++) {
				a[i]=sc.nextInt();
			}
			for(int i=0;i<n;i++) {
				if(a[i]==1) {
					edge[i][tf.getFirst()]=1;
					edge[tf.getFirst()][i]=1;
					set.add(i);
				}else if(a[i]==2&&!set.contains(i)) {
					tf.addLast(i);
				}
			}
			tf.removeFirst();
		}
		System.out.println();
		System.out.println("!");
		for(int i=0;i<n;i++) {
			for(int j=i+1;j<n;j++) {
				if(edge[i][j]==1) {
					System.out.println((i+1)+" "+(j+1));
				}
			}
		}
		System.out.flush();
	}

	static FastReader sc = new FastReader();

	public static void solvegraph() {
		int n = sc.nextInt();

		int edge[][] = new int[n - 1][2];
		for (int i = 0; i < n - 1; i++) {
			edge[i][0] = sc.nextInt() - 1;
			edge[i][1] = sc.nextInt() - 1;
		}
		ArrayList<ArrayList<Integer>> ad = new ArrayList<>();
		for (int i = 0; i < n; i++) {
			ad.add(new ArrayList<Integer>());
		}
		for (int i = 0; i < n - 1; i++) {
			ad.get(edge[i][0]).add(edge[i][1]);
			ad.get(edge[i][1]).add(edge[i][0]);
		}
		int parent[] = new int[n];
		Arrays.fill(parent, -1);
		parent[0] = n;
		ArrayDeque<Integer> queue = new ArrayDeque<>();
		queue.add(0);
		int child[] = new int[n];
		Arrays.fill(child, 0);
		ArrayList<Integer> lv = new ArrayList<Integer>();
		while (!queue.isEmpty()) {
			int toget = queue.getFirst();
			queue.removeFirst();
			child[toget] = ad.get(toget).size() - 1;
			for (int i = 0; i < ad.get(toget).size(); i++) {
				if (parent[ad.get(toget).get(i)] == -1) {
					parent[ad.get(toget).get(i)] = toget;
					queue.addLast(ad.get(toget).get(i));
				}
			}
			lv.add(toget);
		}

		child[0]++;
	}

	static void sort(int[] A) {
		int n = A.length;
		Random rnd = new Random();
		for (int i = 0; i < n; ++i) {
			int tmp = A[i];
			int randomPos = i + rnd.nextInt(n - i);
			A[i] = A[randomPos];
			A[randomPos] = tmp;
		}
		Arrays.sort(A);
	}

	static void sort(long[] A) {
		int n = A.length;
		Random rnd = new Random();
		for (int i = 0; i < n; ++i) {
			long tmp = A[i];
			int randomPos = i + rnd.nextInt(n - i);
			A[i] = A[randomPos];
			A[randomPos] = tmp;
		}
		Arrays.sort(A);
	}

	static String sort(String s) {
		Character ch[] = new Character[s.length()];
		for (int i = 0; i < s.length(); i++) {
			ch[i] = s.charAt(i);
		}
		Arrays.sort(ch);
		StringBuffer st = new StringBuffer("");
		for (int i = 0; i < s.length(); i++) {
			st.append(ch[i]);
		}
		return st.toString();
	}

	public static long gcd(long a, long b) {
		if (a == 0) {
			return b;
		}
		return gcd(b % a, a);
	}

	static class FastReader {
		BufferedReader br;
		StringTokenizer st;

		public FastReader() {
			br = new BufferedReader(new InputStreamReader(System.in));
		}

		String next() {
			while (st == null || !st.hasMoreElements()) {
				try {
					st = new StringTokenizer(br.readLine());
				} catch (IOException e) {
					e.printStackTrace();
				}
			}
			return st.nextToken();
		}

		int nextInt() {
			return Integer.parseInt(next());
		}

		long nextLong() {
			return Long.parseLong(next());
		}

		double nextDouble() {
			return Double.parseDouble(next());
		}

		String nextLine() {
			String str = "";
			try {
				str = br.readLine();
			} catch (IOException e) {
				e.printStackTrace();
			}
			return str;
		}
	}
}
