5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

#!/usr/bin/env python
from __future__ import division, print_function

import os
import sys
from io import BytesIO, IOBase

if sys.version_info[0] < 3:
    from __builtin__ import xrange as range
    from future_builtins import ascii, filter, hex, map, oct, zip


def main():
    n = int(input())

    def query(r):
        print('?', r + 1, flush=True)
        return [int(i) for i in input().split()]

    d = query(0)
    parity = 1 - (sum(i % 2 == 0 for i in d) <= (n + 1) // 2)

    done = set()
    sol = [[0, 0] for _ in range(n - 1)]
    idx = 0

    if parity == 0:
        done.add(0)
        for i, di in enumerate(d):
            if di == 1:
                sol[idx] = [0, i]
                idx += 1

    for i, di in enumerate(d):
        if di % 2 == parity and i != 0:
            for j, k in enumerate(query(i)):
                if k == 1:
                    sol[idx] = [i, j]
                    idx += 1

    print('!')
    for edge in sol:
        print(*[i + 1 for i in edge])
    print(end='', flush=True)


# region fastio

BUFSIZE = 8192


class FastIO(IOBase):
    newlines = 0

    def __init__(self, file):
        self._fd = file.fileno()
        self.buffer = BytesIO()
        self.writable = "x" in file.mode or "r" not in file.mode
        self.write = self.buffer.write if self.writable else None

    def read(self):
        while True:
            b = os.read(self._fd, max(os.fstat(self._fd).st_size, BUFSIZE))
            if not b:
                break
            ptr = self.buffer.tell()
            self.buffer.seek(0, 2), self.buffer.write(b), self.buffer.seek(ptr)
        self.newlines = 0
        return self.buffer.read()

    def readline(self):
        while self.newlines == 0:
            b = os.read(self._fd, max(os.fstat(self._fd).st_size, BUFSIZE))
            self.newlines = b.count(b"\n") + (not b)
            ptr = self.buffer.tell()
            self.buffer.seek(0, 2), self.buffer.write(b), self.buffer.seek(ptr)
        self.newlines -= 1
        return self.buffer.readline()

    def flush(self):
        if self.writable:
            os.write(self._fd, self.buffer.getvalue())
            self.buffer.truncate(0), self.buffer.seek(0)


class IOWrapper(IOBase):
    def __init__(self, file):
        self.buffer = FastIO(file)
        self.flush = self.buffer.flush
        self.writable = self.buffer.writable
        self.write = lambda s: self.buffer.write(s.encode("ascii"))
        self.read = lambda: self.buffer.read().decode("ascii")
        self.readline = lambda: self.buffer.readline().decode("ascii")


def print(*args, **kwargs):
    """Prints the values to a stream, or to sys.stdout by default."""
    sep, file = kwargs.pop("sep", " "), kwargs.pop("file", sys.stdout)
    at_start = True
    for x in args:
        if not at_start:
            file.write(sep)
        file.write(str(x))
        at_start = False
    file.write(kwargs.pop("end", "\n"))
    if kwargs.pop("flush", False):
        file.flush()


if sys.version_info[0] < 3:
    sys.stdin, sys.stdout = FastIO(sys.stdin), FastIO(sys.stdout)
else:
    sys.stdin, sys.stdout = IOWrapper(sys.stdin), IOWrapper(sys.stdout)

input = lambda: sys.stdin.readline().rstrip("\r\n")

# endregion

if __name__ == "__main__":
    main()
