5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5

#!/usr/bin/env python
import os
import sys
from io import BytesIO, IOBase
import math
from collections import Counter


def func(n):
    print(f"? {1}")
    sys.stdout.flush()
    result = [int(i) for i in parse_input().split()]
    even = set()
    odd = set()
    edges = set()
    for i, val in enumerate(result):
        if val == 1:
            edges.add((1, i + 1))
        if val > 0 and val % 2 == 0:
            even.add(i + 1)
        if val % 2 == 1:
            odd.add(i + 1)
    if len(even) < len(odd):
        choose = even
    else:
        choose = odd
    while choose:
        node = choose.pop()
        print(f"? {node}")
        sys.stdout.flush()
        result = [int(i) for i in parse_input().split()]
        for i, val in enumerate(result):
            if val == 1:
                edges.add(tuple(sorted([node, i + 1])))
    return edges


def main():
    n = int(parse_input())
    edges = func(n)
    print("!")
    for val in edges:
        print(f"{val[0]}  {val[1]}")
    sys.stdout.flush()


# region fastio

# BUFSIZE = 8192


# class FastIO(IOBase):
#     newlines = 0

#     def __init__(self, file):
#         self._fd = file.fileno()
#         self.buffer = BytesIO()
#         self.writable = "x" in file.mode or "r" not in file.mode
#         self.write = self.buffer.write if self.writable else None

#     def read(self):
#         while True:
#             b = os.read(self._fd, max(os.fstat(self._fd).st_size, BUFSIZE))
#             if not b:
#                 break
#             ptr = self.buffer.tell()
#             self.buffer.seek(0, 2), self.buffer.write(b), self.buffer.seek(ptr)
#         self.newlines = 0
#         return self.buffer.read()

#     def readline(self):
#         while self.newlines == 0:
#             b = os.read(self._fd, max(os.fstat(self._fd).st_size, BUFSIZE))
#             self.newlines = b.count(b"\n") + (not b)
#             ptr = self.buffer.tell()
#             self.buffer.seek(0, 2), self.buffer.write(b), self.buffer.seek(ptr)
#         self.newlines -= 1
#         return self.buffer.readline()

#     def flush(self):
#         if self.writable:
#             os.write(self._fd, self.buffer.getvalue())
#             self.buffer.truncate(0), self.buffer.seek(0)


# class IOWrapper(IOBase):
#     def __init__(self, file):
#         self.buffer = FastIO(file)
#         self.flush = self.buffer.flush
#         self.writable = self.buffer.writable
#         self.write = lambda s: self.buffer.write(s.encode("ascii"))
#         self.read = lambda: self.buffer.read().decode("ascii")
#         self.readline = lambda: self.buffer.readline().decode("ascii")


# sys.stdin, sys.stdout = IOWrapper(sys.stdin), IOWrapper(sys.stdout)
parse_input = lambda: sys.stdin.readline().rstrip("\r\n")

# endregion

if __name__ == "__main__":
    main()
