5
5 3
2 4
3 1
4 5
 4
2 4
3 2
2 1
 5
5 3
2 4
3 1
4 5
 2
1 2
 4
3 4
2 3
3 1
 10
8 10
2 9
7 8
4 1
7 3
4 7
2 5
2 4
4 6
 5
3 4
3 2
3 1
1 5
 3
1 2
2 3
 5
1 2
1 3
1 4
1 5

1 2
2 3
2 4
 1 3
2 4
3 5
4 5
 1 2
 1 3
2 3
3 4
 1 4
2 4
2 5
2 9
3 7
4 6
4 7
7 8
8 10
 1 3
1 5
2 3
3 4
 1 2
2 3
 1 2
1 3
1 4
1 5


/**
* @author: Prasad Chaudhari
* @linkedIn: https://www.linkedin.com/in/prasad-chaudhari-841655a6/
* @git: https://github.com/Prasad-Chaudhari
*/
import java.io.BufferedReader;
import java.io.BufferedWriter;
import java.io.File;
import java.io.FileInputStream;
import java.io.FileOutputStream;
import java.io.IOException;
import java.io.InputStreamReader;
import java.io.OutputStreamWriter;
import java.util.ArrayList;
import java.util.Arrays;
import java.util.LinkedList;
import java.util.Stack;

public class Main {

    public static void main(String[] args) throws Exception {
        FastIO in = new FastIO(args);
        // int t = in.ni();
        // while (t-- > 0) {
        int n = in.ni();
        ArrayList<LinkedList<int[]>> l = new ArrayList<>();
        for (int i = 0; i <= n; i++)
            l.add(new LinkedList<>());
        Stack<Integer> st = new Stack<>();
        st.push(1);
        while (!st.isEmpty()) {
            int root = st.pop();
            in.println("? " + root);
            in.bw.flush();
            for (int i = 0; i < n; i++) {
                int d = in.ni();
                if (d == 1) {
                    l.get(root).add(new int[] { root, i + 1 });
                } else if (d == 2) {
                    st.push(i + 1);
                }
            }
        }
        in.println("!");
        for (int i = 1; i <= n; i++)
            for (int[] j : l.get(i))
                in.println(j[0] + " " + j[1]);
        in.bw.flush();
        // }
        in.bw.flush();
    }

    static class Expo {

        static long a_pow_n_mod_m(long a, long n, long m) {
            long ans = 1;
            while (n > 0) {
                if ((n & 1) == 1)
                    ans = (ans * a) % m;
                a = (a * a) % m;
                n >>= 1;
            }
            return ans;
        }

        static long a_pow_n(long a, long n) {
            long ans = 1;
            while (n > 0) {
                if ((n & 1) == 1)
                    ans *= a;
                a *= a;
                n >>= 1;
            }
            return ans;
        }
    }

    static class Data implements Comparable<Data> {

        int a, b;

        public Data(int a, int b) {
            this.a = a;
            this.b = b;
        }

        @Override
        public int compareTo(Data o) {
            if (a == o.a) {
                return Integer.compare(b, o.b);
            }
            return Integer.compare(a, o.a);
        }

        public static void sort(int a[]) {
            Data d[] = new Data[a.length];
            for (int i = 0; i < a.length; i++) {
                d[i] = new Data(a[i], 0);
            }
            Arrays.sort(d);
            for (int i = 0; i < a.length; i++) {
                a[i] = d[i].a;
            }
        }
    }

    static class FastIO {

        private final BufferedReader br;
        private final BufferedWriter bw;
        private String s[];
        private int index;

        public FastIO(String[] args) throws IOException {
            if (args.length > 1) {
                br = new BufferedReader(new InputStreamReader(new FileInputStream(new File(args[0]))));
                bw = new BufferedWriter(new OutputStreamWriter(new FileOutputStream(new File(args[1]))));
            } else {
                br = new BufferedReader(new InputStreamReader(System.in));
                bw = new BufferedWriter(new OutputStreamWriter(System.out, "UTF-8"));
            }
            s = br.readLine().split(" ");
            index = 0;
        }

        public int ni() throws IOException {
            return Integer.parseInt(nextToken());
        }

        public double nd() throws IOException {
            return Double.parseDouble(nextToken());
        }

        public long nl() throws IOException {
            return Long.parseLong(nextToken());
        }

        public String next() throws IOException {
            return nextToken();
        }

        public String nli() throws IOException {
            try {
                return br.readLine();
            } catch (IOException ex) {

            }
            return null;
        }

        public int[] gia(int n) throws IOException {
            int a[] = new int[n];
            for (int i = 0; i < n; i++) {
                a[i] = ni();
            }
            return a;
        }

        public int[] gia(int n, int start, int end) throws IOException {
            validate(n, start, end);
            int a[] = new int[n];
            for (int i = start; i < end; i++) {
                a[i] = ni();
            }
            return a;
        }

        public double[] gda(int n) throws IOException {
            double a[] = new double[n];
            for (int i = 0; i < n; i++) {
                a[i] = nd();
            }
            return a;
        }

        public double[] gda(int n, int start, int end) throws IOException {
            validate(n, start, end);
            double a[] = new double[n];
            for (int i = start; i < end; i++) {
                a[i] = nd();
            }
            return a;
        }

        public long[] gla(int n) throws IOException {
            long a[] = new long[n];
            for (int i = 0; i < n; i++) {
                a[i] = nl();
            }
            return a;
        }

        public long[] gla(int n, int start, int end) throws IOException {
            validate(n, start, end);
            long a[] = new long[n];
            for (int i = start; i < end; i++) {
                a[i] = nl();
            }
            return a;
        }

        public void print(String s) throws IOException {
            bw.write(s);
        }

        public void println(String s) throws IOException {
            bw.write(s);
            bw.newLine();
        }

        public void print(int s) throws IOException {
            bw.write(s + "");
        }

        public void println(int s) throws IOException {
            bw.write(s + "");
            bw.newLine();
        }

        public void print(long s) throws IOException {
            bw.write(s + "");
        }

        public void println(long s) throws IOException {
            bw.write(s + "");
            bw.newLine();
        }

        public void print(double s) throws IOException {
            bw.write(s + "");
        }

        public void println(double s) throws IOException {
            bw.write(s + "");
            bw.newLine();
        }

        private String nextToken() throws IndexOutOfBoundsException, IOException {
            if (index == s.length) {
                s = br.readLine().split(" ");
                index = 0;
            }
            return s[index++];
        }

        private void validate(int n, int start, int end) {
            if (start < 0 || end >= n) {
                throw new IllegalArgumentException();
            }
        }
    }
}
