Weiming Qian, Lei Qian, Qin Xu, Lijun Lu
The effects of Roy's adaptation model and the forgetting curve in the clinical instruction of operating room nursing interns
American journal of translational research
rate constants reactions dimethyl amine dma no2 accurately determined using advanced multipath canonical variational theory smallcurvature tunneling correction select suitable method direct kinetic calculations various combinations nine dft methods seven basis sets evaluated m08hxmatzvp method identified best one current reaction system mean unsigned deviation 11 kcal mol1 comparison benchmark ccsdtf12junccpvtz total 13 elementary reactions found habstraction reactions kinetically favorable included kinetic calculations recrossing tunneling effects different among various habstraction reaction channels well different reaction paths recrossing effects comparably significant reactions nsite tunneling coefficients reaction channels producing transhono largest higherenergy reaction paths much higher tunneling coefficients considered rate constant calculation especially low temperatures branching ratio analysis demonstrates important products ch3nch3 cishono 2002000 k additionally comparing calculations available literature data importance investigated reactions discussed combustion atmospheric temperatures