Manuela Waldner, Alexandra Diehl, Denis Gracanin, Rainer Splechtna, Claudio Delrieux, Kresimir Matkovic
A Comparison of Radial and Linear Charts for Visualizing Daily Patterns
IEEE transactions on visualization and computer graphics
quantitative rate determination elementary reactions major task study chemical kinetics ensure fidelity determination progressively tightened constraints need placed measurement especially development various notable experimental techniques however evaluation reaction rates uncertainties frequently conducted substantial subjectivity due data source thermodynamic conditions sampling range sparsity reduce extent biased rate evaluation propose herein approach uncertaintyweighted statistical analysis utilizing weighted average weighted leastsquare regression statistical inference based backbone h2o2 chemistry rate data elementary reaction collected timehistory profile shock tube experiments highlevel theoretical calculations assigned weight inversely depending uncertainty would overall avoid subjective assessments provide accurate rate evaluation aided sensitivity analysis rates key reactions constrained less investigated low intermediatetemperature conditions using highfidelity flow reactor data good performance constructed mechanism confirmed validation target highfidelity flow reactor data study demonstrates systematic approach reaction rate evaluation uncertainty quantification