Kerry L Gaskin, David Barron, Jo Wray
Parents' Journeys of Mastery and Knowledge Construction After Their Infant's First Stage of Surgery for Complex Congenital Heart Disease
Comprehensive child and adolescent nursing
virtue modularity structures tunable optical magnetic properties versatile applications photogenerated tripletradical systems provide ideal platform study factors controlling spin communication molecular frameworks typically compounds consist organic chromophore covalently attached stable radical formation chromophore triplet state photoexcitation two spin centres present molecule interact nature interaction governed magnitude exchange interaction studied making use transient electron paramagnetic resonance epr techniques investigate three perylenenitroxide dyads differ respect position nitroxide radical attached perylene core comparison results transient uvvis epr experiments reveals major differences excited state properties three dyads notably triplet state formation yield excited state deactivation kinetics spin coherence times spectral simulations quantum chemical calculations used rationalise findings demonstrate importance considering structural flexibility contribution rotational conformers accurate interpretation data