Michelle Craft, Cheng Ly
The Effects of Background Noise on a Biophysical Model of Olfactory Bulb Mitral Cells
Bulletin of mathematical biology
study demonstrated radiative rate constant phosphorescent metal complexes substantially enhanced using monodentate ancillary ligands containing heavy donor atoms thus chlorido coligand ptii complex bearing monoanionic tridentate cnn luminophore ptlcl replaced triphenylphosphane pph3 heavier pnictogen congeners ie pnph3 yield ptlpnph3 due high tridentateligandcentered character excited states prelated radiative rate rather low showing significant boost upon replacement p donor heavier sbbased units syntheses three complexes containing pph3 asph3 sbph3 completed unambiguous characterization clean products using exact mass spectrometry xray diffractometry bidimensional nmr 121sbmssbauer spectroscopy ptlsbph3 well steady state timeresolved photoluminescence spectroscopies hence shown hybridization defects vth maingroup atoms overcome complexation pt center notably enhancement radiative rate constants mediated heavier coligands achieved without significantly influencing character excited states rationalization results achieved tddft even though bibased homologue accessible due phenylation side reactions experimental data allowed reasonable extrapolation structural features whereas hybridization defects excited state properties related bispecies phosphorescence rate predicted theory three complexes showed interesting antiprotozoal activity unexpectedly notorious pcontaining complex work could pave road toward new efficient materials optoelectronics novel antiparasitic drugs