Jari Haverinen, Terttu Harju, Hanna Mikkonen, Pia Liljamo, Miia Turpeinen, Jarmo Reponen
Digital Care Pathway for Patients With Sleep Apnea in Specialized Care: Mixed Methods Study
JMIR human factors
assessing validity drivingforcedependent kinetic theory unimolecular elementary reaction step difficult observed reaction rate strongly influenced properties preceding following elementary reaction step wellknown example occurs bimolecular reactions weak orbital overlap outersphere electron transfer bimolecular collisional encounters precede fast unimolecular electrontransfer step limit observed rate lesserappreciated example occurs bimolecular reactions stronger orbital overlap including many protontransfer reactions equilibration endergonic unimolecular protontransfer step results relatively small concentration reaction products thus slowing rate following step becomes rate limiting incomplete consideration points led discrepancies interpretation data literature reanalysis data suggests protontransfer elementary reaction steps nonzero intrinsic free energy barrier implying parlance marcus theory nonnegligible nuclear reorganization outcomes analyses generalizable innersphere electrontransfer reactions involved photoelectrochemical fuelforming reactions