V A Dantas Melo, J R Santos Silva, R La Corte
Use of mosquito repellents to protect against Zika virus infection among pregnant women in Brazil
Public health
rotating disc electrode rde voltammetry widely adopted study heterogenized molecular electrocatalysts multistep fuelforming reactions tool never comprehensively applied homogeneous analogues utility limitations rde techniques mechanistic kinetic analysis homogeneous molecular catalysts mediate multielectron multisubstrate redox transformations explored using ecec reaction mechanism case study two theoretical models derived based nernst diffusion layer model hale transformation currentpotential curves generated computational strategies compared variety limiting conditions identify conditions minimalist nernst diffusion layer approach applied based theoretical treatment strategies extracting kinetic information plateau current foot catalytic wave derived rdev applied cobaloxime hydrogen evolution reaction catalyst nonaqueous conditions order experimentally validate theoretical framework explore feasibility rde tool studying homogeneous catalysts crucially analysis footofthewave via theoretical framework provides rate constants elementary reaction steps agree extracted stationary voltammetric methods supporting application rde study homogeneous fuelforming catalysts finally obstacles encountered kinetic analysis cobaloxime along voltammetric signatures used diagnose reactivity discussed goal guiding groups working improve rde setups help researchers avoid misinterpretation rde data