Cassie E McDonald, Catherine L Granger, Julie Louie, Thy Tran, Louisa J Remedios
Health information and resources in hospital outpatient waiting areas may not meet the needs of older adults from culturally and linguistically diverse backgrounds: A cross-cultural qualitative study
Health information and libraries journal
chemical reasoning based ligandfield theory suggests homoleptic cyano complexes exhibit lowspin configurations particularly coordination sphere nearly saturated recently wellknown chromium hexacyano complex anion crcn64 shown lose cyanide afford crcn53 absence coordinating cations furthermore net 43crcn5 found highspin s2 ground state challenges common notion cyanide strong field ligand always enforce lowspin configurations using density functional theory coupled continuum solvation model examined instability hexacyanochromateii anion relative energies different spin states pentacyanochromateii anion making direct comparisons analogous fe ii complex found cyanide electronically behaves strongfield ligand metals orbital interaction energetically favorable lowspin configuration corresponding highspin configuration coulombic repulsion anionic cyanide ligands however dominates overall energetics ultimately gives preference highspin complex ligandligand separation larger calculations highlight quantitative understanding spinstate energetic ordering transition metal complex ligandligand electrostatic interactions must taken account addition classical ligandfield arguments based ml orbital interaction energies