Charlles Brito, Rachel D Cossetti, Diego Agra de Souza, Marcos Catanha, Pablo de Matos Monteiro, Flavia Castello Branco Vidal
Prevalence of HPV genotypes and assessment of their clinical relevance in laryngeal squamous cell carcinoma in a northeastern state of Brazil-a retrospective study
PeerJ
smallest nanodrop tractable macroscopic notions interfacial energy could determined comparing heterogeneous nucleation observations capillary theory predictions decreasing drop diameters dp done condensation nbutanol vapors polyethylene glycol nanoglobules 3 nm dp 9 nm use published activation probability measurements pwdp w accurately controlled saturation ratio nbutanol vapor gas stream exiting saturator maximal saturation ratio achieved nucleation region cooling gasvapor stream apparatus gallar et al satisfies smax cw key unknown constant c preexponential term k governing nucleation rate determined assuming classical theory applies largest particles used yields psmaxdp data directly comparable capillary theory perfect wetting excellent agreement found 5 nm critical dependence smaxdp resulting constraint psmaxdp 05 entire psmaxdp curves also agree closely 5 7 nm smaller particles depart slightly theory even dp 3 nm capillary theory hence describes accurately heterogeneous nucleation process 35 nm provides reliable method determine smax yields experimentally nucleation rate constant k