Introducing Python
I don't think it's a matter of a programming language as such. 
What is the proficiency level of PHP in the team you're talking about? Are they doing spaghetti code or using some structured framework like Zend? If this is the first case then I absolutely understand the guy's interest in Python and Django. It this is the latter, it's just a hype.
The company I used to work with has two developers working fulltime, and a handful of freelancers. They're in the process of hiring a new lead developer to try to bring order and management to the development.
But, currently, one of the developers has seen the light of Django (the company has only developed in PHP to date) while the other developer is concerned that introducing a new language (Python) is a bad idea right now.
How should they approach introducing this new technology? Obviously with only one of the developers actually knowing Python, there will be no redundancy when that dev is away or leaves the company.
Should they bother to introduce Python, or should they look for PHP-only solutions until such a time when the team actually have more than one Pythonion? Without a team leader, the decisions are having to fall to them.