Framework/CMS suggestions for enterprise website & intranet (I've got to convince the president its solid!)
"Enterprise" is a marketing term. It has pretty much zero technical meaning. If your boss wants to hear Enterprise, then he will, but this won't mean that a given system is suitable for your needs. 
Beware of lists of companies that use a given suite of software. "Ebay uses Plone", and "Ebay runs on Plone" are two very different statements. 
Mostly, if you're doing "Enterprise" CMS (for whatever that term is worth) you should expect to have a learning curve that will only just begin to flatten out by the end of a significant project. 
For your project, I'd suggest you try to figure out what you really need. If you think TurboGears (or any other framework) is a good fit, discuss some risk management strategies with your boss. Maybe a small pilot to start with. Adopting a new technology is risky. Many "large corporation" web sites are mission-critical these days. 
For what it's worth. I like Plone, but I've only ever used it for non-corporate stuff. I don't personally know of any "Enterprise" implementations. At work I use Tridion, and I know of numerous implementations at that level. (If you're looking for a choice that will let you work in Python, Tridion isn't a good fit.)
Dear stack overflow community,
I've been given the task of overhauling a couple of websites for a large corporation I'm working for, as well as developing an internal intranet site for content management and document storage within the organization.
My "problem" is this: They want me to use a framework/set of languages/technologies that I can prove to them are "stable, enterprise-ready technologies with a proven track record."
The spec's "big picture" really isn't too complicated: Implement an enterprise-class CMS for management of each division's web pages that deal mostly with product information and documentation (i.e. a simpler version of www.linksys.com).
As an open-source programmer, I'd like to use Python with TurboGears and build it from scratch, but I can't really find a way to prove to the president that TurboGears has a huge enterprise track record. Zope seems to have a lot of enterprise usage, but it looks a bit bloated to me. Django could be an option, but doesn't seem as flexible as TurboGears.
I'd rather not use PHP, but Drupal has a very nice resume with the "right" names under it (AOL, Sony, MTV); plus it could save me building many of the CMS components from scratch.
Rails might be another option, but I'm not too familiar with it (and as a Python/PHP programmer, Ruby's syntax drives me crazy).
What would the S.O. community suggest for a project like this? I'm sure many of you have faced the same dilemma. What ended up working/not working for you? As I said before, my first choice would be Python, second would be PHP, third would be Rails.
Thank you,
Seth