I hope this isn't knocked for being too general, but... I recently had occasion to learn web2py for a final year university project. In this subject teams of four had 8 weeks to design a web app. Ultimately i found that web2py was quite versatile, with it being very easy to get a site up and running fast, a lot of options (janrain etc) - but the end "style" result relied almost entirely on us.
Amongst the other teams, who used other frameworks (each team a different one on the whole), a few of the sites came out with a very slick polished look, without them having to spend much photoshop/css design time and effort. I got the impression that some frameworks are more "friendly" when it came to out of the box design elements (buttons, navigation options, widgets, base css etc) while others aren't.
I have a python (/C/java) background, and intend to learn PHP some point. What frameworks exist out there that provided a base for site design beyond the bare bones? And to emphasise, I have browsed the python page listing frameworks, i am more interested in the design aspect - even if just to see if my assumption was correct.
I feel your pain.  As a developer coming from the desktop world and doing some web development, I'm used to setting up the appearance of my application at the same time I select and arrange my user interface widgets.
You will just have to accept that browser based software does not work that way.  You must separately learn CSS.  Hopefully, you'll learn to like this method of specifying the appearance of the application but whether you do or not there really isn't any alternative to this approach in the browser.
Web Frameworks with site style inbuilt