Sure, here is a sample code to accomplish this task:

import tkinter as tk
from tkinter import filedialog
import pandas as pd
import urllib.request

def process_csv():
    root = tk.Tk()
    root.withdraw()

    csv_file = filedialog.askopenfilename(title='Select the CSV file', filetypes=[('CSV Files', '*.csv')])
    output_path = filedialog.askdirectory(title='Select the output folder')

    df = pd.read_csv(csv_file)
    for i, row in df.iterrows():
        name = row['Name']
        url = row['URL']
        rating = row['Rating']
        
        folder = output_path + '/' + rating
        if not os.path.exists(folder):
            os.makedirs(folder)
        
        image_path = folder + '/' + name + '.png'
        urllib.request.urlretrieve(url, image_path)

process_csv()

This code uses the tkinter library to create a GUI that allows you to select the CSV file and output path. The code reads the CSV file using the pandas library, and then iterates over each row to download the image and save it as a PNG file. The name of the file is based on the "Name" column and the rating is used to create a subfolder in the output path.
spam fails_task lang_mismatch pii not_appropriate hate_speech sexual_content quality toxicity humor helpfulness creativity violence