The structure of the Old Testament depends on the denomination of the Bible in question. The Protestant Bible's Old Testament contains 39 chapters. The Catholic Bible's Old Testament contains 46 chapters. Orthodox and other denominations contain up to 53 chapters. These chapters are typically divided into four sections: the Pentateuch (aka Torah), the historical books, the wisdom books, and the prophets. However, there are several differences between the Old Testament and the Hebrew Bible. Naturally, the foundational texts are different, and the Hebrew Bible only contains 24 chapters. The arrangement of the categories of chapters are different, and the titles of some of the chapters differ as well. In summary, the Jewish and Christian Bibles are quite dissimilar in structure and content, and thorough study is required to fully comprehend the discrepancies.
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