You can create a .reg file with the following contents:
Windows Registry Editor Version 5.00
```
[HKEY_CURRENT_USER\Software\Classes\Directory\shell\YourCommand]
"FriendlyName"="Your command name"

[HKEY_CURRENT_USER\Software\Classes\Directory\shell\YourCommand\command]
@="\"C:\\Path\\To\\Executable.exe\" \"%V\""
```
This will add a new menu item called "Your command name" to the context menu for folders. When clicked, it will run the executable at C:\Path\To\Executable.exe with the folder path passed as a parameter.
Obviously, modify the path and name as appropriate for your needs.
Save that as a .reg file, double-click it, and confirm the changes to add the registry key.
Note that this will only apply to the current user - for all users, use HKEY_CLASSES_ROOT instead of HKEY_CURRENT_USER.
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