Expanding my search for paintings and keeping in mind that some details may be inaccurate, I still cannot find an illustration or painting of a man, in a business suit, with an eyeball as his head.

However I did find a famous painting by René Magritte called "The Son of Man". The painting depicts a man in smart dress, much like a business suit, and a bowler hat with a green apple obscuring his face. The green apple obscures most of his face but does not replace it. 

Please let me know if this is what you were looking for.
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