X
Assembly of 3-allyl-3-ethynyl-oxindole motifs via palladium(ii)-catalyzed quaternary allylation of 3-ethynyl-3-OBoc-oxindoles
Nandarapu Kumarswamyreddy, Muthuraj Prakash, Samydurai Jayakumar,
Published in Royal Society of Chemistry
2015
Volume: 5
   
Issue: 67
Pages: 54316 - 54320
Abstract
Palladium(ii)-catalyzed C3-allylation of 3-ethynyl-3-OBoc oxindole derivatives was achieved for the first time to access highly functionalized 3-allyl-3-ethynyl substituted oxindole derivatives for a broad range of substrates in very good yields (up to 94%). The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. © The Royal Society of Chemistry.
About the journal
JournalData powered by TypesetRSC Advances
PublisherData powered by TypesetRoyal Society of Chemistry
ISSN20462069
Open AccessNo
Concepts (6)
  • Allylation
  • Catalysis
  • Diastereoselectivities
  • Functionalized
  • Synthetic application
  • Palladium compounds
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data-testid=\"tab-anchor-1\">Figures &amp; Tables (2)</a></div><div id=\"sticky-tab-2\" class=\"StickyHeader__StickTabHeader-fdifqv-5 kBAYLW\"><a data-testid=\"tab-anchor-2\">Citations (5)</a></div><div id=\"sticky-"], "copyright__copyright__copyright": [" The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds", " The synthetic applications of the allylated products were explored by synthesizing five and six membered carbocyclic spirooxindoles in moderate to very good diastereoselectivities. \u00a9 The Royal Society of Chemistry.\nAbout the journal\nJournalData powered by TypesetRSC Advances\nPublisherData powered by TypesetRoyal Society of Chemistry\nISSN20462069\nOpen AccessNo\nConcepts (6)\n  \u2022 Allylation\n  \u2022 Catalysis\n  \u2022 Diastereoselectivities\n  \u2022 Functionalized\n  \u2022 Synthetic application\n  \u2022 Palladium compounds"]}