title: Periodinane
text: # Periodinane
  
  Periodinanes also known as $λ^5-iodanes$ are organoiodine compounds with iodine in the +5 oxidation state. These compounds are described as hypervalent because the iodine center has more than 8 valence electrons.
  
  ## Periodinane compounds
  
  The $λ^5-iodanes$ such as the Dess-Martin periodinane have square pyramidal geometry with 4 heteroatoms in basal positions and one apical phenyl group.
  
  Iodoxybenzene or iodylbenzene, $C_6H_5IO_2,$ is a known oxidizing agent.
  
  Dess-Martin periodinane (1983) is another powerful oxidant and an improvement of the IBX acid already in existence in 1983. The IBX acid is prepared from 2-iodobenzoic acid and potassium bromate and sulfuric acid and is insoluble in most solvents whereas the Dess-Martin reagent prepared from reaction of the IBX acid with acetic anhydride is very soluble. The oxidation mechanism ordinarily consists of a ligand exchange reaction followed by a reductive elimination.
  
  ## Uses
  
  The predominant use of periodinanes is as oxidizing reagents replacing toxic reagents based on heavy metals.
  
  