3 butynyl and the higher homologs and isomers typically an alkyl or alkylene group will have from 1 to 30 carbon atoms that is in some embodiments alkyl refers to an alkyl having a number of carbons selected from c 1 c 2 c 3 c 4 c 5 c 6 c 7 c 8 c 9 c 10 c 11 c 12 c 13 c 14 c 15 c 16 c 17 c 18 c 19 c 20 c 21 c 22 c 23 c 24 c 25 c 26 c 27 c 28 c 29 c 30 and any combination thereof in some embodiments alkyl refers to c 1 c 25 alkyl in some embodiments alkyl refers to c 1 c 20 alkyl in some embodiments alkyl refers to c 1 c 15 alkyl in some embodiments alkyl refers to c 1 c 10 alkyl in some embodiments alkyl refers to c 1 c 6 alkyl the term u201c heteroaryl u201d refers to aryl containing 1 2 3 or 4 heteroatoms selected from n o and s wherein the nitrogen and sulfur atoms are optionally oxidized and the nitrogen atom s are optionally quaternized a heteroaryl group can be attached to the remainder of the molecule through a heteroatom non limiting examples of aryl and heteroaryl groups include phenyl 1 naphthyl 2 naphthyl 4 biphenyl 1 pyrrolyl 2 pyrrolyl 3 pyrrolyl 3 pyrazolyl 2 imidazolyl 4 imidazolyl pyrazinyl 2 oxazolyl 4 oxazolyl 2 phenyl 4 oxazolyl 5 oxazolyl 3 isoxazolyl 4 isoxazolyl 5 isoxazolyl 2 thiazolyl 4 thiazolyl 2 furyl 3 furyl 2 thienyl 3 thienyl 2 pyridyl 3 pyridyl 4 pyridyl 2 pyrimidyl 4 pyrimidyl 5 benzothiazolyl purinyl 2 benzimidazolyl 5 indolyl 1 isoquinolyl 5 isoquinolyl 2 quinoxalinyl.