powders thereof e g kiwi cranberry sunflower raspberry jojoba etc botanical shell husk powders e g almond coconut pecan walnut wheat etc oyster shell powder jojoba esters polymeric beads or powders e g polybutylene polyethylene polyisobutylene polymethylstyrene polypropylene polystyrene polyurethane nylon polytetrafluoroethylene etc microcrystalline or synthetic wax metal oxides e g aluminum tin titanium etc silicates e g aluminum zirconium etc chalk chitin clay microcrystalline cellulose perlite sericite silica talc and so forth in a further particular embodiment the scrubbing layer may comprise a fabric including fibers or yarns having a relatively coarse texture and or having an average diameter greater than 75 microns and more desirably may have diameters in excess of about 100 microns in a further aspect the filaments and or yarns may have diameters between about 75 microns and about 1000 microns or in further aspects between about 100 microns and about 500 microns suitable polymers for forming the large fibers and or yarns include but are not limited to polyolefins e g polyethylene and polypropylene polyesters e g polyethylene terephthalate polyamides e g nylon and combinations thereof a specific example of material suitable for use in the scrubbing layer include a fabric woven from filament bundles or yarns ranging in size between about 200 800 microns wherein the i the first filament bundle comprises individual nylon filaments having an average fiber size of approximately 60 microns and ii the second filament bundle comprises individual polyethylene terephthalate filaments having an average fiber size of approximately 20 microns in certain embodiments larger and or abrasive staple length fibers may be used in the formation of the web.