Novel Nitrogen-Phosphorus Flame Retardant Based on Phosphonamidate: Thermal Stability and Flame Retardancy.A novel nitrogen-phosphorus flame retardant (P-N FR) based on phosphonamidate, dimethyl N,N'-1,3-phenylenebis(P-methylphosphonamidate) (DMPMP), was successfully synthesized and its flame-retarding performances and thermal degradation were compared with those of other P-N FRs and a phosphorus-based FR such as resorcinol bis(diphenyl phosphate) (RDP).  The results from thermogravimetric analysis, Fourier transform infrared, and UL-94V indicated that DMPMP is a highly efficient FR and acts mainly in a gas-phase flame-retarding mode of action. 
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