Pd-Catalyzed Rearrangement of N-Alloc-N-allyl Ynamides via Auto-Tandem Catalysis: Evidence for Reversible C-N Activation and Pd(0)-Accelerated Ketenimine Aza-Claisen Rearrangement.An auto-tandem catalytic double allylic rearrangement of N-alloc-N-allyl ynamides was developed. 
Pd-Catalyzed Rearrangement
Pd-Catalyzed Rearrangement of N-Alloc-N-allyl Ynamides via Auto-Tandem Catalysis: Evidence for Reversible C-N Activation and Pd(0)-Accelerated Ketenimine Aza-Claisen Rearrangement.An auto-tandem catalytic double allylic rearrangement of N-alloc-N-allyl ynamides was developed. 
Auto-Tandem Catalysis
Pd-Catalyzed Rearrangement of N-Alloc-N-allyl Ynamides via Auto-Tandem Catalysis: Evidence for Reversible C-N Activation and Pd(0)-Accelerated Ketenimine Aza-Claisen Rearrangement.An auto-tandem catalytic double allylic rearrangement of N-alloc-N-allyl ynamides was developed. 
Pd(0)-Accelerated Ketenimine Aza-Claisen Rearrangement