Measurement of charge carrier mobilities in thin films on metal substrates by reflection time resolved terahertz spectroscopy.We show that charge carrier mobilities can be measured by reflection time resolved THz spectroscopy (R-TRTS) even for thin films on metal contacts, such as polycrystalline Cu2SnZnSe4 grown on molybdenum.  In the measurement a reduced THz reflection upon photo-excitation is observed in contrast to increased THz reflection commonly observed on insulating substrates, and which excludes standard analytic R-TRTS analyses.  We show that R-TRTS on metal substrates is ~100x less sensitive compared to measurements on insulating substrates.  These sensitivity of these R-TRTS measurements can be increased by using lower substrate refractive indices, lower substrate conductivities, thicker sample layers or higher THz probe frequencies.
R-TRTS
Measurement of charge carrier mobilities in thin films on metal substrates by reflection time resolved terahertz spectroscopy.We show that charge carrier mobilities can be measured by reflection time resolved THz spectroscopy (R-TRTS) even for thin films on metal contacts, such as polycrystalline Cu2SnZnSe4 grown on molybdenum. 
THz spectroscopy
Instead, a numerical transfer matrix method is used to model the THz reflection from which we derive carrier mobilities of 100 cm2/Vs consistent with literature. 
transfer matrix method