Construction of Zeolite-Like Cluster Organic Frameworks from 3 d-4 d/3 d-3 d Heterometallic Supertetrahedral Secondary Building Units: Syntheses, Structures, and Properties.Two zeolite-like cluster organic frameworks based on Cd-Cu/Mn-Cu heterometallic supertetrahedral secondary building units have been successfully constructed under solvothermal conditions, namely, Cu[Cd4 Cu6 (L)4 (H2 O)18 ](Ac)9 ⋅DMA⋅3 H2 O (1), and Cu[Mn4 Cu6 (L)4 (Ac)3 (H2 O)12 ](Ac)6 ⋅CH3 CN⋅13 H2 O (2), where H3 L=2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol, Ac=CH3 COO- , DMA=N,N'-dimethylacetamide.  Furthermore, the magnetic properties and porous nature of 1 and 2 were also studied.
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