As expected for this large energy gap, compound 1 exhibits, in a zero direct-current field, thermally activated slow relaxation of the magnetization with a large Ueff =140 K. The isostructural Zn-Er-Zn species does not present significant SMM behavior as expected for the prolate electron-density distribution of the Er(III) ion leading to an easy-plane anisotropy of the ground doublet state.
THERM