<p>Acetone is smelly nasty stuff.  Here's a sample recommendation for PEI maintenance from one of a few (million?) 3d printing help sites. </p>

<blockquote>
  <p>Use isopropyl alcohol, methyl alcohol, soap, Heptane, Hexane, or
  Naphtha. Avoid ketones (such as MEK) or strong bases (such as sodium
  hydroxide).</p>
</blockquote>

CC BY-SA 4.0
2019-04-18T04:50:13.993Z
Maybe it's just me but in my experience Naphta smells even worse than acetone and doesn't evaporate as quickly so the smell lingers around longer.
anttix
CC BY-SA 4.0
2019-04-18T11:59:38.790Z
@anttix naphta is a complex mix of aromates, which is why it smells. it is also a super good solvent for most fats, like grease or fingerprints.It is, as an aromate, at least *possibly cancer inducing* (actual classification depends on the exact mix)
Trish
CC BY-SA 4.0
2019-04-17T17:04:42.680Z
2019-04-17T17:04:42.680Z
Carl Witthoft
<p>Rejuvenate is probably a bit of an exaggerated term. The number one adhesion suppressor is grease. The stuff that comes off of the fingers used to handle the sheet. Even if you are careful and only handle the sides, the grease will be carried to the center of the plate next time its cleaned with less aggressive solvents.</p>

<p>Isopropyl alchohol does break down grease but not to the extent that acetone does. Acetone also attacks plastic particles that accumulate on the print surface over time.</p>

<p>PEI is resistant to a wide array of chemicals[1] including acetone but it can become brittle if exposed to it too much especially when hot so acetone is not recommended for daily cleaning. </p>

<p>[1] <a href="https://www.emcoplastics.com/assets/pdf/ultem/ULTEM%20Product%20Brochure%20GE.pdf" rel="noreferrer">Ultem Product Broshure</a> table 4-3</p>

CC BY-SA 4.0
2019-04-20T18:20:51.823Z
Excellent reference. Your last point is the one I'm trying to understand in more detail.  What physical or chemical change takes place that makes the PEI brittle?  This is more for intellectual knowledge than for practical considerations, of course.
Mark Harrison
CC BY-SA 4.0
2019-04-20T20:16:25.577Z
@mark-harrison unfortunately GE does not specify what happens to polyethermide when it's attacked by ketones, they only list the failure mode after immersion which is rupture. My wild guess is that this is due to loss of molecular mass. PEI molecule does contain a methyl group (CH3) so acetone may be able to eventually break that away from the molecule.I'm not a chemist though and I am really grasping at straws here. This is probably a question for chemistry.stackexchange.com
anttix
CC BY-SA 4.0
2019-04-20T22:31:01.827Z
TIL, there's a chemistry stack exchange!
Mark Harrison
CC BY-SA 4.0
2019-04-18T04:36:43.823Z
2019-04-18T04:55:10.373Z
2019-04-18T04:55:10.373Z
anttix
<p>The <a href="https://help.prusa3d.com/article/6Gtws6Yqjg-pei-print-surface-preparation" rel="noreferrer">Prusa3d knowledge base</a> mentions that acetone will "rejuvenate" PEI in addition to cleaning oil and grease from the surface.</p>

<blockquote>
  <p>About once a week, or when <strong>prints stop sticking</strong>, use <strong>ACETONE</strong> to clean the bed. It removes grease better than IPA or Windex. It also <strong>rejuvenates</strong> the print surface. However, if you use acetone every day, PEI will become brittle and start cracking.</p>
</blockquote>

<p>From a chemical or physical perspective, how does acetone affect the PEI surface?</p>

CC BY-SA 4.0
2019-04-17T17:03:48.700Z
Looks like marketingspeak.  A cleaned surface should behave like a new surface, assuming the PEI is homogeneous material.
Carl Witthoft
CC BY-SA 4.0
2019-04-17T21:59:43.393Z
Thanks!  I can verify that it's customersupportspeak, as that's what they advised me when I contacted them.  Interestingly enough, it worked very well and restored my print surface to like-new condition.  I don't know if their PEI surface is homogenous, although they don't say anything to the contrary.
Mark Harrison
<print-quality><acetone><pei><chemistry>
How does acetone "rejuvenate" PEI?
Mark Harrison
# How does acetone "rejuvenate" PEI?

(Asked by: username_0 on 2019-04-17)

The [Prusa3d knowledge base](https://help.prusa3d.com/article/6Gtws6Yqjg-pei-print-surface-preparation) mentions that acetone will "rejuvenate" PEI in addition to cleaning oil and grease from the surface.

> About once a week, or when **prints stop sticking**, use **ACETONE** to clean the bed. It removes grease better than IPA or Windex. It also **rejuvenates** the print surface. However, if you use acetone every day, PEI will become brittle and start cracking.

From a chemical or physical perspective, how does acetone affect the PEI surface?

**Tags:** print-quality, acetone, pei, chemistry

> **Comments:**
> **username_1**: Looks like marketingspeak.  A cleaned surface should behave like a new surface, assuming the PEI is homogeneous material.  
> **username_0**: Thanks!  I can verify that it's customersupportspeak, as that's what they advised me when I contacted them.  Interestingly enough, it worked very well and restored my print surface to like-new condition.  I don't know if their PEI surface is homogenous, although they don't say anything to the contrary.  

---

## 2 answers

### Answer by username_2 on 2019-04-18. Score: 8 | Accepted answer

Rejuvenate is probably a bit of an exaggerated term. The number one adhesion suppressor is grease. The stuff that comes off of the fingers used to handle the sheet. Even if you are careful and only handle the sides, the grease will be carried to the center of the plate next time its cleaned with less aggressive solvents.

Isopropyl alchohol does break down grease but not to the extent that acetone does. Acetone also attacks plastic particles that accumulate on the print surface over time.

PEI is resistant to a wide array of chemicals[1] including acetone but it can become brittle if exposed to it too much especially when hot so acetone is not recommended for daily cleaning.

[1] [Ultem Product Broshure](https://www.emcoplastics.com/assets/pdf/ultem/ULTEM%20Product%20Brochure%20GE.pdf) table 4-3

> **Comments:**
> **username_0**: Excellent reference. Your last point is the one I'm trying to understand in more detail.  What physical or chemical change takes place that makes the PEI brittle?  This is more for intellectual knowledge than for practical considerations, of course.  
> **username_2**: @mark-username_0 unfortunately GE does not specify what happens to polyethermide when it's attacked by ketones, they only list the failure mode after immersion which is rupture. My wild guess is that this is due to loss of molecular mass. PEI molecule does contain a methyl group (CH3) so acetone may be able to eventually break that away from the molecule.I'm not a chemist though and I am really grasping at straws here. This is probably a question for chemistry.stackexchange.com  
> **username_0**: TIL, there's a chemistry stack exchange!  

---

### Answer by username_1 on 2019-04-17. Score: -1

Acetone is smelly nasty stuff. Here's a sample recommendation for PEI maintenance from one of a few (million?) 3d printing help sites.

> Use isopropyl alcohol, methyl alcohol, soap, Heptane, Hexane, or
> Naphtha. Avoid ketones (such as MEK) or strong bases (such as sodium
> hydroxide).

> **Comments:**
> **username_2**: Maybe it's just me but in my experience Naphta smells even worse than acetone and doesn't evaporate as quickly so the smell lingers around longer.  
> **username_3**: @username_2 naphta is a complex mix of aromates, which is why it smells. it is also a super good solvent for most fats, like grease or fingerprints.It is, as an aromate, at least *possibly cancer inducing* (actual classification depends on the exact mix)  

---

