Rapid and hot oxidation of a material
Fire is the rapid oxidation of a material (the fuel) in the exothermic chemical process of combustion, releasing heat, light, and various reaction products.
At a certain point in the combustion reaction, called the ignition point, flames are produced. The "flame" is the visible portion of the fire. Flames consist primarily of carbon dioxide, water vapor, oxygen and nitrogen. If hot enough, the gases may become ionized to produce plasma. Depending on the substances alight, and any impurities outside, the color of the flame and the fire's intensity will be different.
Fire, in its most common form, has the potential to result in conflagration, which can lead to physical damage, which can be permanent, through burning. Fire is a significant process that influences ecological systems worldwide. The positive effects of fire include stimulating growth and maintaining various ecological systems.
Its negative effects include hazard to life and property, atmospheric pollution, and water contamination. When fire removes protective vegetation, heavy rainfall can contribute to increased soil erosion by water. Additionally, the burning of vegetation releases nitrogen into the atmosphere, unlike elements such as potassium and phosphorus which remain in the ash and are quickly recycled into the soil. This loss of nitrogen caused by a fire produces a long-term reduction in the fertility of the soil, which can be recovered as atmospheric nitrogen is fixed and converted to ammonia by natural phenomena such as lightning or by leguminous plants such as clover, peas, and green beans.
Fire is one of the four classical elements and has been used by humans in rituals, in agriculture for clearing land, for cooking, generating heat and light, for signaling, propulsion purposes, smelting, forging, incineration of waste, cremation, and as a weapon or mode of destruction.
Etymology.
The word "fire" originated from ang " Fyr" 'Fire, a fire', which can be traced back to the Germanic root , which itself comes from the Proto-Indo-European from the root 'fire'. The current spelling of "fire" has been in use since as early as 1200, but it was not until around 1600 that it completely replaced the Middle English term (which is still preserved in the word "fiery").
History.
Fossil record.
The fossil record of fire first appears with the establishment of a land-based flora in the Middle Ordovician period,  million years ago, permitting the accumulation of oxygen in the atmosphere as never before, as the new hordes of land plants pumped it out as a waste product. When this concentration rose above 13%, it permitted the possibility of wildfire. Wildfire is first recorded in the Late Silurian fossil record,  million years ago, by fossils of charcoalified plants. Apart from a controversial gap in the Late Devonian, charcoal is present ever since. The level of atmospheric oxygen is closely related to the prevalence of charcoal: clearly oxygen is the key factor in the abundance of wildfire. Fire also became more abundant when grasses radiated and became the dominant component of many ecosystems, around 7; this kindling provided tinder which allowed for the more rapid spread of fire. These widespread fires may have initiated a positive feedback process, whereby they produced a warmer, drier climate more conducive to fire.
Human control of fire.
Early human control.
The ability to control fire was a dramatic change in the habits of early humans. Making fire to generate heat and light made it possible for people to cook food, simultaneously increasing the variety and availability of nutrients and reducing disease by killing pathogenic microorganisms in the food. The heat produced would also help people stay warm in cold weather, enabling them to live in cooler climates. Fire also kept nocturnal predators at bay. Evidence of occasional cooked food is found from  million years ago. Although this evidence shows that fire may have been used in a controlled fashion about 1 million years ago, other sources put the date of regular use at 400,000 years ago. Evidence becomes widespread around 50 to 100 thousand years ago, suggesting regular use from this time; resistance to air pollution started to evolve in human populations at a similar point in time. The use of fire became progressively more sophisticated, as it was used to create charcoal and to control wildlife from tens of thousands of years ago.
Fire has also been used for centuries as a method of torture and execution, as evidenced by death by burning as well as torture devices such as the iron boot, which could be filled with water, oil, or even lead and then heated over an open fire to the agony of the wearer.
By the Neolithic Revolution, during the introduction of grain-based agriculture, people all over the world used fire as a tool in landscape management. These fires were typically controlled burns or "cool fires", as opposed to uncontrolled "hot fires", which damage the soil. Hot fires destroy plants and animals, and endanger communities. This is especially a problem in the forests of today where traditional burning is prevented in order to encourage the growth of timber crops. Cool fires are generally conducted in the spring and autumn. They clear undergrowth, burning up biomass that could trigger a hot fire should it get too dense. They provide a greater variety of environments, which encourages game and plant diversity. For humans, they make dense, impassable forests traversable. Another human use for fire in regards to landscape management is its use to clear land for agriculture. Slash-and-burn agriculture is still common across much of tropical Africa, Asia and South America. For small farmers, controlled fires are a convenient way to clear overgrown areas and release nutrients from standing vegetation back into the soil. However, this useful strategy is also problematic. Growing population, fragmentation of forests and warming climate are making the earth's surface more prone to ever-larger escaped fires. These harm ecosystems and human infrastructure, cause health problems, and send up spirals of carbon and soot that may encourage even more warming of the atmosphere – and thus feed back into more fires. Globally today, as much as 5 million square kilometres – an area more than half the size of the United States – burns in a given year.
Later human control.
There are numerous modern applications of fire. In its broadest sense, fire is used by nearly every human being on Earth in a controlled setting every day. Users of internal combustion vehicles employ fire every time they drive. Thermal power stations provide electricity for a large percentage of humanity by igniting fuels such as coal, oil or natural gas, then using the resultant heat to boil water into steam, which then drives turbines.
Use of fire in war.
The use of fire in warfare has a long history. Fire was the basis of all early thermal weapons. The Byzantine fleet used Greek fire to attack ships and men.
The invention of gunpowder in China led to the fire lance, a flame-thrower weapon dating to around 1000 CE which was a precursor to projectile weapons driven by burning gunpowder.
The earliest modern flamethrowers were used by infantry in the First World War, first used by German troops against entrenched French troops near Verdun in February 1915. They were later successfully mounted on armoured vehicles in the Second World War.
Hand-thrown incendiary bombs improvised from glass bottles, later known as Molotov cocktails, were deployed during the Spanish Civil War in the 1930s. Also during that war, incendiary bombs were deployed against Guernica by Fascist Italian and Nazi German air forces that had been created specifically to support Franco's Nationalists.
Incendiary bombs were dropped by Axis and Allies during the Second World War, notably on Coventry, Tokyo, Rotterdam, London, Hamburg and Dresden; in the latter two cases firestorms were deliberately caused in which a ring of fire surrounding each city was drawn inward by an updraft caused by a central cluster of fires. The United States Army Air Force also extensively used incendiaries against Japanese targets in the latter months of the war, devastating entire cities constructed primarily of wood and paper houses. The incendiary fluid napalm was used in July 1944, towards the end of the Second World War, although its use did not gain public attention until the Vietnam War.
Fire management.
Controlling a fire to optimize its size, shape, and intensity is generally called "fire management", and the more advanced forms of it, as traditionally (and sometimes still) practiced by skilled cooks, blacksmiths, ironmasters, and others, are highly skilled activities. They include knowledge of which fuel to burn; how to arrange the fuel; how to stoke the fire both in early phases and in maintenance phases; how to modulate the heat, flame, and smoke as suited to the desired application; how best to bank a fire to be revived later; how to choose, design, or modify stoves, fireplaces, bakery ovens, or industrial furnaces; and so on. Detailed expositions of fire management are available in various books about blacksmithing, about skilled camping or military scouting, and about domestic arts.
Productive use for energy.
Burning fuel converts chemical energy into heat energy; wood has been used as fuel since prehistory. The International Energy Agency states that nearly 80% of the world's power has consistently come from fossil fuels such as petroleum, natural gas, and coal in the past decades. The fire in a power station is used to heat water, creating steam that drives turbines. The turbines then spin an electric generator to produce electricity. Fire is also used to provide mechanical work directly by thermal expansion, in both external and internal combustion engines.
The unburnable solid remains of a combustible material left after a fire is called "clinker" if its melting point is below the flame temperature, so that it fuses and then solidifies as it cools, and "ash" if its melting point is above the flame temperature.
Physical properties.
Chemistry.
Fire is a chemical process in which a fuel and an oxidizing agent react, yielding carbon dioxide and water. This process, known as a combustion reaction, does not proceed directly and involves intermediates. Although the oxidizing agent is typically oxygen, other compounds are able to fulfill the role. For instance, chlorine trifluoride is able to ignite sand.
Fires start when a flammable or a combustible material, in combination with a sufficient quantity of an oxidizer such as oxygen gas or another oxygen-rich compound (though non-oxygen oxidizers exist), is exposed to a source of heat or ambient temperature above the flash point for the fuel/oxidizer mix, and is able to sustain a rate of rapid oxidation that produces a chain reaction. This is commonly called the fire tetrahedron. Fire cannot exist without all of these elements in place and in the right proportions. For example, a flammable liquid will start burning only if the fuel and oxygen are in the right proportions. Some fuel-oxygen mixes may require a catalyst, a substance that is not consumed, when added, in any chemical reaction during combustion, but which enables the reactants to combust more readily.
Once ignited, a chain reaction must take place whereby fires can sustain their own heat by the further release of heat energy in the process of combustion and may propagate, provided there is a continuous supply of an oxidizer and fuel.
If the oxidizer is oxygen from the surrounding air, the presence of a force of gravity, or of some similar force caused by acceleration, is necessary to produce convection, which removes combustion products and brings a supply of oxygen to the fire. Without gravity, a fire rapidly surrounds itself with its own combustion products and non-oxidizing gases from the air, which exclude oxygen and extinguish the fire. Because of this, the risk of fire in a spacecraft is small when it is coasting in inertial flight. This does not apply if oxygen is supplied to the fire by some process other than thermal convection.
Fire can be extinguished by removing any one of the elements of the fire tetrahedron. Consider a natural gas flame, such as from a stove-top burner. The fire can be extinguished by any of the following:
In contrast, fire is intensified by increasing the overall rate of combustion. Methods to do this include balancing the input of fuel and oxidizer to stoichiometric proportions, increasing fuel and oxidizer input in this balanced mix, increasing the ambient temperature so the fire's own heat is better able to sustain combustion, or providing a catalyst, a non-reactant medium in which the fuel and oxidizer can