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Chemical compound
Benzoxepin is an oxygen-containing bicyclic molecule consisting of an oxepin ring and a benzene ring. There are three isomers, varying in where the oxygen is positioned in the oxepin heterocycle relative where the benzene is fused to it.
Natural occurrence.
1-Benzoxepin, with the oxygen closest to the benzene, is found in the skeleton of several fungal metabolites.
2-Benzoxepin skeletons are likewise found in fungal metabolites.
3-Benzoxepin, with the oxygen furthest from the benzene, is the core of natural products such as perilloxin from "Perilla frutescens" (variant Acuta) and tenual and tenucarb from "Asphodeline tenuior".
References.
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