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Chemical compound
Quinolizinium refers to the heterocyclic cation with the formula . The cation is isoelectronic and nearly isostructural with naphthalene, the difference being the replacement of one of the two carbons at the fusion positions with N+. The parent quinolizine has not been isolated but salts of these aromatic quinolizinium compounds are well known. Several syntheses begin with 2-substituted pyridines and involve N-alkylation and various dehydrogenation reactions. The quinolizinium core is represented in the berberine family of natural products. It is formally derived from the elusive quinolizines by hydrde abstraction. According to X-ray crystallography of the hexafluorophosphate salt, which is colorless, is planar.
Reactions.
Being a cation, quinolinizium resists electrophilic attack, although it can be brominated. Catalytic hydrogenation gives quinolizidine. 