Physical phenomenon
A fluidized bed is a physical phenomenon that occurs when a solid particulate substance (usually present in a holding vessel) is under the right conditions so that it behaves like a fluid. The usual way to achieve a fluidized bed is to pump pressurized fluid into the particles. The resulting medium then has many properties and characteristics of normal fluids, such as the ability to free-flow under gravity, or to be pumped using fluid technologies.
The resulting phenomenon is called fluidization. Fluidized beds are used for several purposes, such as fluidized bed reactors (types of chemical reactors), solids separation, fluid catalytic cracking, fluidized bed combustion, heat or mass transfer or interface modification, such as applying a coating onto solid items. This technique is also becoming more common in aquaculture for the production of shellfish in integrated multi-trophic aquaculture systems.
Properties.
A fluidized bed consists of fluid-solid mixture that exhibits fluid-like properties. As such, the upper surface of the bed is relatively horizontal, which is analogous to hydrostatic behavior. The bed can be considered to be a heterogeneous mixture of fluid and solid that can be represented by a single bulk density.
Furthermore, an object with a higher density than the bed will sink, whereas an object with a lower density than the bed will float, thus the bed can be considered to exhibit the fluid behavior expected of Archimedes' principle. As the "density", (actually the solid volume fraction of the suspension), of the bed can be altered by changing the fluid fraction, objects with different densities comparative to the bed can, by altering either the fluid or solid fraction, be caused to sink or float.
In fluidised beds, the contact of the solid particles with the fluidisation medium (a gas or a liquid) is greatly enhanced when compared to packed beds. This behavior in fluidised combustion beds enables good thermal transport inside the system and good heat transfer between the bed and its container. Similarly to the good heat transfer, which enables thermal uniformity analogous to that of a well mixed gas, the bed can have a significant heat-capacity whilst maintaining a homogeneous temperature field.
Application.
Fluidized beds are used as a technical process which has the ability to promote high levels of contact between gases and solids. In a fluidised bed a characteristic set of basic properties can be utilised, indispensable to modern process and chemical engineering, these properties include:
Taking an example from the food processing industry: Fluidized beds are used to accelerate freezing in some individually quick frozen (IQF) tunnel freezers. These Fluidized bed tunnels are typically used on small food products like peas, shrimp or sliced vegetables, and may use cryogenic or vapor-compression refrigeration. The fluid used in Fluidized beds may also contain a fluid of catalytic type; that's why it is also used to catalyse the chemical reaction and also to improve the rate of reaction.
Fluidized beds are also used for efficient bulk drying of materials. Fluidized bed technology in dryers increases efficiency by allowing for the entire surface of the drying material to be suspended and therefore exposed to the air. This process can also be combined with heating or cooling, if necessary, according to the specifications of the application.
History.
In 1922, Fritz Winkler made the first industrial application of fluidization in a reactor for a coal gasification process. In 1942, the first circulating fluid bed was built for catalytic cracking of mineral oils, with fluidisation technology applied to metallurgical processing (roasting arsenopyrite) in the late 1940s. During this time theoretical and experimental research improved the design of the fluidised bed. In the 1960s VAW-Lippewerk in Lünen, Germany implemented the first industrial bed for the combustion of coal and later for the calcination of aluminium hydroxide.
Fluidized bed types.
Bed types can be coarsely classified by their flow behavior, including:
Bed design.
Basic model.
When the packed bed has a fluid passed over it, the pressure drop of the fluid is approximately proportional to the fluid's superficial velocity. In order to transition from a packed bed to a fluidised condition, the gas velocity is continually raised. For a free-standing bed there will exist a point, known as the minimum or incipient fluidisation point, whereby the bed's mass is suspended directly by the flow of the fluid stream. The corresponding fluid velocity, known as the "minimum
fluidisation velocity", formula_1.
Beyond the minimum fluidisation velocity (formula_2), the bed material will be suspended by the gas-stream and further increases in the velocity will have a reduced effect on the pressure, owing to sufficient percolation of the gas flow. Thus the pressure drop for formula_3 is relatively constant.
At the base of the vessel the apparent pressure drop multiplied by the cross-section area of the bed can be equated to the force of the weight of the solid particles (less the buoyancy of the solid in the fluid).
formula_4
where:
formula_5 is the bed pressure drop
formula_6 is the bed height
formula_7 is the bed voidage, i.e. the fraction of the bed volume that is occupied by the voids (the fluid spaces between the particles)
formula_8 is the apparent density of bed particles
formula_9 is the density of the fluidising fluid
formula_10 is the acceleration due to gravity
formula_11 is the total mass of solids in the bed
formula_12 is the cross-sectional area of the bed
Geldart Groupings.
In 1973, Professor D. Geldart proposed the grouping of powders in to four so-called "Geldart Groups". The groups are defined by their locations on a diagram of solid-fluid density difference and particle size. Design methods for fluidised
beds can be tailored based upon the particle's Geldart grouping:
Group A For this group the particle size is between 20 and 100 μm, and the particle density is typically less than 1.4g/cm3. Prior to the initiation of a bubbling bed phase, beds from these particles will expand by a factor of 2 to 3 at incipient fluidisation, due to a decreased bulk density. Most powder-catalyzed beds utilize this group.
Group B The particle size lies between 40 and 500 μm and the particle density between 1.4-4g/cm3. Bubbling typically forms directly at incipient fluidisation.
Group C This group contains extremely fine and consequently the most cohesive particles. With a size of 20 to 30 μm, these particles fluidise under very difficult to achieve conditions, and may require the application of an external force, such as mechanical agitation.
Group D The particles in this region are above 600 μm and typically have high particle densities. Fluidisation of this group requires very high fluid energies and is typically associated with high levels of abrasion. Drying grains and peas, roasting coffee beans, gasifying coals, and some roasting metal ores are such solids, and they are usually processed in shallow beds or in the spouting mode.
Distributor.
Typically, pressurized gas or liquid enters the fluidised bed vessel through numerous holes via a plate known as a distributor plate, located at the bottom of the fluidised bed. The fluid flows upward through the bed, causing the solid particles to be suspended. If the inlet fluid is disabled, the bed may settle, pack onto the plate or trickle down through the plate.
Many industrial beds use a sparger distributor instead of a distributor plate. The fluid is then distributed through a series of perforated tubes.
References.
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