Force resulting from the quantisation of a field
In quantum field theory, the Casimir effect (or Casimir force) is a physical force acting on the macroscopic boundaries of a confined space which arises from the quantum fluctuations of a field. The term Casimir pressure is sometimes used when it is described in units of force per unit area. It is named after the Dutch physicist Hendrik Casimir, who predicted the effect for electromagnetic systems in 1948.
In the same year Casimir, together with Dirk Polder, described a similar effect experienced by a neutral atom in the vicinity of a macroscopic interface which is called the Casimir–Polder force. Their result is a generalization of the London–van der Waals force and includes retardation due to the finite speed of light. The fundamental principles leading to the London–van der Waals force, the Casimir force, and the Casimir–Polder force can be formulated on the same footing.
In 1997 a direct experiment by Steven K. Lamoreaux quantitatively measured the Casimir force to be within 5% of the value predicted by the theory.
The Casimir effect can be understood by the idea that the presence of macroscopic material interfaces, such as electrical conductors and dielectrics, alter the vacuum expectation value of the energy of the second-quantized electromagnetic field. Since the value of this energy depends on the shapes and positions of the materials, the Casimir effect manifests itself as a force between such objects.
Any medium supporting oscillations has an analogue of the Casimir effect. For example, beads on a string as well as plates submerged in turbulent water or gas illustrate the Casimir force.
In modern theoretical physics, the Casimir effect plays an important role in the chiral bag model of the nucleon; in applied physics it is significant in some aspects of emerging microtechnologies and nanotechnologies.
Physical properties.
The typical example is of two uncharged conductive plates in a vacuum, placed a few nanometers apart. In a classical description, the lack of an external field means that no field exists between the plates, and no force connects them. When this field is instead studied using the quantum electrodynamic vacuum, it is seen that the plates do affect the virtual photons that constitute the field, and generate a net force – either an attraction or a repulsion depending on the plates' specific arrangement. Although the Casimir effect can be expressed in terms of virtual particles interacting with the objects, it is best described and more easily calculated in terms of the zero-point energy of a quantized field in the intervening space between the objects. This force has been measured and is a striking example of an effect captured formally by second quantization.
The treatment of boundary conditions in these calculations is controversial. In fact, "Casimir's original goal was to compute the van der Waals force between polarizable molecules" of the conductive plates. Thus it can be interpreted without any reference to the zero-point energy (vacuum energy) of quantum fields.
Because the strength of the force falls off rapidly with distance, it is measurable only when the distance between the objects is small. This force becomes so strong that it becomes the dominant force between uncharged conductors at submicron scales. In fact, at separations of 10 nm – about 100 times the typical size of an atom – the Casimir effect produces the equivalent of about 1 atmosphere of pressure (the precise value depends on surface geometry and other factors).
History.
Dutch physicists Hendrik Casimir and Dirk Polder at Philips Research Labs proposed the existence of a force between two polarizable atoms and between such an atom and a conducting plate in 1947; this special form is called the Casimir–Polder force. After a conversation with Niels Bohr, who suggested it had something to do with zero-point energy, Casimir alone formulated the theory predicting a force between neutral conducting plates in 1948. This latter phenomenon is called the Casimir effect.
Predictions of the force were later extended to finite-conductivity metals and dielectrics, while later calculations considered more general geometries. Experiments before 1997 observed the force qualitatively, and indirect validation of the predicted Casimir energy was made by measuring the thickness of liquid helium films. Finally, in 1997 Lamoreaux's direct experiment quantitatively measured the force to within 5% of the value predicted by the theory. Subsequent experiments approached an accuracy of a few percent.
Possible causes.
Vacuum energy.
The causes of the Casimir effect are described by quantum field theory, which states that all of the various fundamental fields, such as the electromagnetic field, must be quantized at each and every point in space. In a simplified view, a "field" in physics may be envisioned as if space were filled with interconnected vibrating balls and springs, and the strength of the field can be visualized as the displacement of a ball from its rest position. Vibrations in this field propagate and are governed by the appropriate wave equation for the particular field in question. The second quantization of quantum field theory requires that each such ball-spring combination be quantized, that is, that the strength of the field be quantized at each point in space. At the most basic level, the field at each point in space is a simple harmonic oscillator, and its quantization places a quantum harmonic oscillator at each point. Excitations of the field correspond to the elementary particles of particle physics. However, even the vacuum has a vastly complex structure, so all calculations of quantum field theory must be made in relation to this model of the vacuum.
The vacuum has, implicitly, all of the properties that a particle may have: spin, or polarization in the case of light, energy, and so on. On average, most of these properties cancel out: the vacuum is, after all, "empty" in this sense. One important exception is the vacuum energy or the vacuum expectation value of the energy. The quantization of a simple harmonic oscillator states that the lowest possible energy or zero-point energy that such an oscillator may have is
formula_1
Summing over all possible oscillators at all points in space gives an infinite quantity. Since only "differences" in energy are physically measurable (with the notable exception of gravitation, which remains beyond the scope of quantum field theory), this infinity may be considered a feature of the mathematics rather than of the physics. This argument is the underpinning of the theory of renormalization. Dealing with infinite quantities in this way was a cause of widespread unease among quantum field theorists before the development in the 1970s of the renormalization group, a mathematical formalism for scale transformations that provides a natural basis for the process.
When the scope of the physics is widened to include gravity, the interpretation of this formally infinite quantity remains problematic. There is currently no compelling explanation as to why it should not result in a cosmological constant that is many orders of magnitude larger than observed. However, since we do not yet have any fully coherent quantum theory of gravity, there is likewise no compelling reason as to why it should instead actually result in the value of the cosmological constant that we observe.
The Casimir effect for fermions can be understood as the spectral asymmetry of the fermion operator (−1)"F", where it is known as the Witten index.
Relativistic van der Waals force.
Alternatively, a 2005 paper by Robert Jaffe of MIT states that "Casimir effects can be formulated and Casimir forces can be computed without reference to zero-point energies. They are relativistic, quantum forces between charges and currents. The Casimir force (per unit area) between parallel plates vanishes as alpha, the fine structure constant, goes to zero, and the standard result, which appears to be independent of alpha, corresponds to the alpha approaching infinity limit", and that "The Casimir force is simply the (relativistic, retarded) van der Waals force between the metal plates." Casimir and Polder's original paper used this method to derive the Casimir–Polder force. In 1978, Schwinger, DeRadd, and Milton published a similar derivation for the Casimir effect between two parallel plates. More recently, Nikolic proved from first principles of quantum electrodynamics that the Casimir force does not originate from the vacuum energy of the electromagnetic field, and explained in simple terms why the fundamental microscopic origin of Casimir force lies in van der Waals forces.
Effects.
Casimir's observation was that the second-quantized quantum electromagnetic field, in the presence of bulk bodies such as metals or dielectrics, must obey the same boundary conditions that the classical electromagnetic field must obey. In particular, this affects the calculation of the vacuum energy in the presence of a conductor or dielectric.
Consider, for example, the calculation of the vacuum expectation value of the electromagnetic field inside a metal cavity, such as, for example, a radar cavity or a microwave waveguide. In this case, the correct way to find the zero-point energy of the field is to sum the energies of the standing waves of the cavity. To each and every possible standing wave corresponds an energy; say the energy of the nth standing wave is En. The vacuum expectation value of the energy of the electromagnetic field in the cavity is then
formula_2
with the sum running over all possible values of n enumerating the standing waves. The factor of is present because the zero-point energy of the nth mode is "En", where En is the energy increment for the nth mode. (It is the same as appears in the equation "E" 
 "ħω".) Written in this way, this sum is clearly divergent; however, it can be used to create finite expressions.
In particular, one may ask how the zero-point energy depends on the shape s of the cavity. Each energy level En depends on the shape, and so one should write "En"("s") for the energy level, and for the vacuum expectation value. At this point comes an important observation: The force at point p on the wall of the cavity is equal to the change in the vacuum energy if the shape s of the wall is perturbed a little bit, say by "δs", at p. That is, one has
formula_3
This value is finite in many practical calculations.
Attraction between the plates can be easily understood by focusing on the one-dimensional situation. Suppose that a moveable conductive plate is positioned at a short distance a from one of two widely separated plates (distance l apart). With "a" ≪ "l", the states within the slot of width a are highly constrained so that the energy E of any one mode is widely separated from that of the next. This is not the case in the large region l where there is a large number of states (about ) with energy evenly spaced between E and the next mode in the narrow slot, or in other words, all slightly larger than E. Now on shortening a by an amount da (which is negative), the mode in the narrow slot shrinks in wavelength and therefore increases in energy proportional to −, whereas all the states that lie in the large region lengthen and correspondingly decrease their energy by an amount proportional to − (note the different denominator). The two effects nearly cancel, but the net change is slightly negative, because the energy of all the modes in the large region are slightly larger than the single mode in the slot. Thus the force is attractive: it tends to make a slightly smaller, the plates drawing each other closer, across the thin slot.
Derivation of Casimir effect assuming zeta-regularization.
In the original calculation done by Casimir, he considered the space between a pair of conducting metal plates at distance a apart. In this case, the standing waves are particularly easy to calculate, because the transverse component of the electric field and the normal component of the magnetic field must vanish on the surface of a conductor. Assuming the plates lie parallel to the xy-plane, the standing waves are
formula_4
where ψ stands for the electric component of the electromagnetic field, and, for brevity, the polarization and the magnetic components are ignored here. Here, kx and ky are the wavenumbers in directions parallel to the plates, and
formula_5
is the wavenumber perpendicular to the plates. Here, n is an integer, resulting from the requirement that ψ vanish on the metal plates. The frequency of this wave is
formula_6
where c is the speed of light. The vacuum energy is then the sum over all possible excitation modes. Since the area of the plates is large, we