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Please login to access the full content or check if you have access via2.4.7 Method 7: Synthesis of Optically Active Arene Complexes
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Kündig, E. P.; Pache, S. H., Science of Synthesis, (2003) 2, 188.
The synthesis of optically active arene complexes has been developed only for chromium–arene complexes (for applications, see Section 2.4.10). Distinct categories in this class of compound are shown in Scheme 36. Chirality may be associated with (a) a stereogenic center in an aryl substituent, (b) a chiral ligand on the metal, (c) a stereogenic metal center, or (d) different ortho or meta arene substituents (planar chirality).
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References
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