Rịba ama amaokwu a dị n'okpuru ma zaa ajụjụ ahụ mgbe e mesịrị n'otu asụsụ ahụ dị ka amaokwu ahụ:  Nkọwa: Ntọala kemịkal maka Iwu Markovnikov bụ nhazi nke carbocation kachasị kwụsie ike n'oge usoro mgbakwunye. Mgbakwunye nke hydrogen ion na otu carbon atom na alkene na-emepụta ụgwọ dị mma na carbon ọzọ, na-akpụ carbocation intermediate. Ka a na-edochi carbocation, otú ahụ ka ọ na-adịgide adịgide, n'ihi ntinye na hyperconjugation. Isi ngwaahịa nke mmeghachi omume mgbakwunye ga-abụ nke a kpụrụ site na etiti kwụsiri ike. Ya mere, isi ngwaahịa nke mgbakwunye nke HX (ebe X bụ ụfọdụ atọm ọzọ electronegative karịa H) na alkene nwere atọm hydrogen na ọnọdụ na-erughị dochie anya na X na ọnọdụ dochie anya. Ma ndị ọzọ na-erughị dochie anya, obere kwụsie ike carbocation ka ga-guzobere na ụfọdụ ịta, na ga-anọgide na-na obere ngwaahịa na-abụghị, conjugate njikọ nke X.  Ajụjụ: Gịnị ga-eme ma ọ bụrụ na carbonation bụ ihe ọzọ substituted?
ọ na- adịgide adịgide karị