Mezue ahịrịokwu na-esonụ: Puyol meriri egwuregwu mbụ ya maka Spain na 15 Nọvemba 2000 megide Netherlands, ma nọgide na-abụ onye a na-ahụkarị n'afọ ndị sochirinụ. Ọ gbaara mba ya bọọlụ n'egwuregwu Olimpik nke afọ 2000, n'asọmpi Iko Mbaụwa nke afọ 2002,
Euro 2004, 2006 World Cup, Euro 2008, 2009 FIFA Confederations Cup na 2010 World Cup.