na-agafe n'okpuru na mgbe ahụ zaa ajụjụ mgbe e mesịrị na otu asụsụ dị ka agafe: Passage: The chemical ndabere maka Markovnikov si Rule bụ e guzobere nke kasị mụ carbocation n'oge mgbakwunye usoro. The mgbakwunye nke hydrogen ion ka otu carbon atọm na alkene emepụta a mma ụgwọ na ndị ọzọ carbon, na-akpụ a carbocation etiti. The ọzọ dochie anya na carbocation, na ndị ọzọ mụ ọ bụ, n'ihi na itinye n'ọkwa na hyperconjugation. Isi ngwaahịa nke mgbakwunye mmeghachi omume ga-abụ onye kpụrụ si ọzọ mụ intermediate. Ya mere, isi ngwaahịa nke mgbakwunye nke HX (ebe X bụ ụfọdụ ọzọ electronegative atọm karịa H) na alkene nwere hydrogen atọm na ndị na-erughị dochie anya ọnọdụ na X na ndị ọzọ dochie anya ọnọdụ. Ma ndị ọzọ na-erughị dochie anya, obere kwụsie ike carbocation ka ga-kere na ụfọdụ ịta, na ga-aga n'ihu na-na obere na conjugate, na-ejikọta na conjugate nke X carbon. Ajụjụ: Gịnị ma
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