 This early postulate in classical thermochemistry became the controversial foundation of a research program that would last three decades.This principle came to be associated with what was called the "thermal theory of affinity", which postulated that the heat evolved in a chemical reaction was the true measure of its affinity.This hypothesis was later disproved, however, when in 1882 the German scientist Hermann von Helmholtz proved that affinity was not given by the heat evolved in a chemical reaction but rather by the maximum work, or free energy, produced when the reaction was carried out reversibly.