 The Rodionova sisters defeated top seeds Yan Zi and Alisa Kleybanova in straight sets in the second round.However, in the finals, they lost to second seeds Zheng Jie and Chan Yung-jan in a close two-setter and match tie-breaker 7–6, 2–6, [7–10].Rodionova's debut for the Australian Fed Cup team was in Kharkov, Ukraine, on 24 April 2010, where she opened the tie with an emphatic win over Alona Bondarenko, coming back from losing the first seven games, 0–6, 6–3, 7–5.