 Llorente officially became a Juventus player on 1 July 2013 after passing a medical at the club.He was given the number 14 shirt, and scored his first goal in Serie A on 22 September when he started in a 2–1 home win against Hellas Verona.Llorente found the net in his second and third ever appearances in the UEFA Champions League, both times against Real Madrid in the 2013–14 group stage (a 1–2 away loss, and a 2–2 home draw).