 He was, however, selected for the 2010 FIFA World Cup in South Africa as third-choice striker, where he played in one match for the eventual champions, the last thirty minutes of the 1–0 round of 16 win over Portugal.On 8 October 2010, benefiting from an injury to Fernando Torres, Llorente started in a Euro 2012 qualifier against Lithuania in Salamanca, scoring with two headers in a 3–1 win.Four days later, as a substitute, he scored the winner against Scotland in a 3–2 win at Hampden Park.