 During the 1996–97 season, he was named Napoli's captain, and he helped the club to reach the 1997 Coppa Italia Final under manager Luigi Simoni, in which Napoli was defeated by Vicenza in extra time; during the first leg of the final, Pecchia scored Napoli's winning goal.Despite his attachment to the club, he was sold to Juventus in 1997 for 10 billion Lit., in an attempt to manage the club's debts; he would later return to Napoli, on loan, however, for a single season, in 2001.In total, he made 152 appearances for Napoli, scoring 21 goals.