4514 ÷ 6 = 752 R2
No problem, we've got 4514 and 6 for the division.

Step 1:
6 goes into 4 0 times with a remainder of 4.
Write down 0 as next digit of of the result. 
Result so far: 0
Subtract 0 from 4 to get 4.
Bring next digit (5) of the dividend behind the 4 and repeat the process: 45 / 6

Step 2:
6 goes into 45 7 times with a remainder of 3.
Write down 7 as next digit of of the result. 
Result so far: 7
Subtract 42 from 45 to get 3.
Bring next digit (1) of the dividend behind the 3 and repeat the process: 31 / 6

Step 3:
6 goes into 31 5 times with a remainder of 1.
Write down 5 as next digit of of the result. 
Result so far: 75
Subtract 30 from 31 to get 1.
Bring next digit (4) of the dividend behind the 1 and repeat the process: 14 / 6

Step 4:
6 goes into 14 2 times with a remainder of 2.
Write down 2 as next digit of of the result. 
Result so far: 752
Subtract 12 from 14 to get 2.

The final result is 752 with a remainder of 2.