4522 ÷ 6 = 753 R4
No problem, we've got 4522 and 6 for the division.

Step 1:
6 goes into 4 0 times with a remainder of 4.
Write down 0 as next digit of of the result. 
Result so far: 0
Subtract 0 from 4 to get 4.
Bring next digit (5) of the dividend behind the 4 and repeat the process: 45 / 6

Step 2:
6 goes into 45 7 times with a remainder of 3.
Write down 7 as next digit of of the result. 
Result so far: 7
Subtract 42 from 45 to get 3.
Bring next digit (2) of the dividend behind the 3 and repeat the process: 32 / 6

Step 3:
6 goes into 32 5 times with a remainder of 2.
Write down 5 as next digit of of the result. 
Result so far: 75
Subtract 30 from 32 to get 2.
Bring next digit (2) of the dividend behind the 2 and repeat the process: 22 / 6

Step 4:
6 goes into 22 3 times with a remainder of 4.
Write down 3 as next digit of of the result. 
Result so far: 753
Subtract 18 from 22 to get 4.

The final result is 753 with a remainder of 4.